The structure described by AgPbO3 is Ilmenite structured and crystallizes in the trigonal R-3 space group. Ag(1) is bonded to six equivalent O(1) atoms to form distorted AgO6 octahedra that share corners with nine equivalent Pb(1)O6 octahedra, edges with three equivalent Ag(1)O6 octahedra, and  a faceface with one Pb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-63°. Pb(1) is bonded to six equivalent O(1) atoms to form distorted PbO6 octahedra that share corners with nine equivalent Ag(1)O6 octahedra, edges with three equivalent Pb(1)O6 octahedra, and  a faceface with one Ag(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-63°. O(1) is bonded to two equivalent Ag(1) and two equivalent Pb(1) atoms to form a mixture of distorted edge and corner-sharing OAg2Pb2 trigonal pyramids. is represented by the CIF file [CIF]
data_AgPbO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.064
_cell_length_b   6.064
_cell_length_c   6.064
_cell_angle_alpha   56.914
_cell_angle_beta   56.914
_cell_angle_gamma   56.914
_symmetry_Int_Tables_number   1
_cell_volume   146.418
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.857  0.857  0.857  1.0
  Ag  Ag1  1  0.143  0.143  0.143  1.0
  Pb  Pb2  1  0.354  0.354  0.354  1.0
  Pb  Pb3  1  0.646  0.646  0.646  1.0
  O  O4  1  0.544  0.952  0.261  1.0
  O  O5  1  0.739  0.456  0.048  1.0
  O  O6  1  0.048  0.739  0.456  1.0
  O  O7  1  0.952  0.261  0.544  1.0
  O  O8  1  0.261  0.544  0.952  1.0
  O  O9  1  0.456  0.048  0.739  1.0
[/CIF]
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The structure described by AgPbO3 is Ilmenite structured and crystallizes in the trigonal R-3 space group. Ag(1) is bonded to six equivalent O(1) atoms to form distorted AgO6 octahedra that share corners with nine equivalent Pb(1)O6 octahedra, edges with three equivalent Ag(1)O6 octahedra, and  a faceface with one Pb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-63°. Pb(1) is bonded to six equivalent O(1) atoms to form distorted PbO6 octahedra that share corners with nine equivalent Ag(1)O6 octahedra, edges with three equivalent Pb(1)O6 octahedra, and  a faceface with one Ag(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-63°. O(1) is bonded to two equivalent Ag(1) and two equivalent Pb(1) atoms to form a mixture of distorted edge and corner-sharing OAg2Pb2 trigonal pyramids. is represented by the CIF file [CIF]
data_AgPbO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.064
_cell_length_b   6.064
_cell_length_c   6.064
_cell_angle_alpha   56.914
_cell_angle_beta   56.914
_cell_angle_gamma   56.914
_symmetry_Int_Tables_number   1
_cell_volume   146.418
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.857  0.857  0.857  1.0
  Ag  Ag1  1  0.143  0.143  0.143  1.0
  Pb  Pb2  1  0.354  0.354  0.354  1.0
  Pb  Pb3  1  0.646  0.646  0.646  1.0
  O  O4  1  0.544  0.952  0.261  1.0
  O  O5  1  0.739  0.456  0.048  1.0
  O  O6  1  0.048  0.739  0.456  1.0
  O  O7  1  0.952  0.261  0.544  1.0
  O  O8  1  0.261  0.544  0.952  1.0
  O  O9  1  0.456  0.048  0.739  1.0
[/CIF]
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