The compound described by Li2VMnP2(O4F)2 crystallizes in the triclinic P-1 space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(3), one O(4), one O(7), one O(8), and one F(2) atom to form distorted LiO4F square pyramids that share  a cornercorner with one V(2)O4F2 octahedra,  a cornercorner with one Mn(2)O4F2 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  an edgeedge with one V(1)O4F2 octahedra,  an edgeedge with one Mn(1)O4F2 octahedra,  an edgeedge with one Li(2)O4F square pyramid, and  an edgeedge with one P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 53-59°. In the second Li site, Li(2) is bonded to one O(2), one O(6), one O(7), one O(8), and one F(1) atom to form distorted LiO4F square pyramids that share  a cornercorner with one V(2)O4F2 octahedra,  a cornercorner with one Mn(2)O4F2 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  an edgeedge with one V(1)O4F2 octahedra,  an edgeedge with one Mn(1)O4F2 octahedra,  an edgeedge with one Li(1)O4F square pyramid, and  an edgeedge with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 52-60°. There are two inequivalent V sites. In the first V site, V(1) is bonded to two equivalent O(3), two equivalent O(7), and two equivalent F(1) atoms to form VO4F2 octahedra that share corners with two equivalent V(2)O4F2 octahedra, corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, edges with two equivalent Li(1)O4F square pyramids, and edges with two equivalent Li(2)O4F square pyramids. The corner-sharing octahedral tilt angles are 47°. In the second V site, V(2) is bonded to two equivalent O(1), two equivalent O(4), and two equivalent F(1) atoms to form VO4F2 octahedra that share corners with two equivalent V(1)O4F2 octahedra, corners with two equivalent Li(1)O4F square pyramids, corners with two equivalent Li(2)O4F square pyramids, corners with two equivalent P(1)O4 tetrahedra, and corners with two equivalent P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 47°. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to two equivalent O(2), two equivalent O(8), and two equivalent F(2) atoms to form MnO4F2 octahedra that share corners with two equivalent Mn(2)O4F2 octahedra, corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, edges with two equivalent Li(1)O4F square pyramids, and edges with two equivalent Li(2)O4F square pyramids. The corner-sharing octahedral tilt angles are 51°. In the second Mn site, Mn(2) is bonded to two equivalent O(5), two equivalent O(6), and two equivalent F(2) atoms to form MnO4F2 octahedra that share corners with two equivalent Mn(1)O4F2 octahedra, corners with two equivalent Li(1)O4F square pyramids, corners with two equivalent Li(2)O4F square pyramids, corners with two equivalent P(1)O4 tetrahedra, and corners with two equivalent P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 51°. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(3), one O(4), one O(5), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O4F2 octahedra,  a cornercorner with one V(2)O4F2 octahedra,  a cornercorner with one Mn(1)O4F2 octahedra,  a cornercorner with one Mn(2)O4F2 octahedra,  a cornercorner with one Li(1)O4F square pyramid,  a cornercorner with one Li(2)O4F square pyramid, and  an edgeedge with one Li(1)O4F square pyramid. The corner-sharing octahedral tilt angles range from 32-55°. In the second P site, P(2) is bonded to one O(1), one O(2), one O(6), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O4F2 octahedra,  a cornercorner with one V(2)O4F2 octahedra,  a cornercorner with one Mn(1)O4F2 octahedra,  a cornercorner with one Mn(2)O4F2 octahedra,  a cornercorner with one Li(1)O4F square pyramid,  a cornercorner with one Li(2)O4F square pyramid, and  an edgeedge with one Li(2)O4F square pyramid. The corner-sharing octahedral tilt angles range from 33-53°. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one V(2) and one P(2) atom. In the second O site, O(2) is bonded in a distorted T-shaped geometry to one Li(2), one Mn(1), and one P(2) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to one Li(1), one V(1), and one P(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Li(1), one V(2), and one P(1) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Mn(2) and one P(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Li(2), one Mn(2), and one P(2) atom. In the seventh O site, O(7) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(2), one V(1), and one P(2) atom. In the eighth O site, O(8) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(2), one Mn(1), and one P(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one Li(2), one V(1), and one V(2) atom. In the second F site, F(2) is bonded in a trigonal planar geometry to one Li(1), one Mn(1), and one Mn(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li2MnVP2(O4F)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.912
_cell_length_b   7.424
_cell_length_c   7.981
_cell_angle_alpha   87.103
_cell_angle_beta   88.371
_cell_angle_gamma   62.853
_symmetry_Int_Tables_number   1
_cell_volume   363.982
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.744  0.812  0.826  1.0
  Li  Li1  1  0.246  0.812  0.325  1.0
  Li  Li2  1  0.754  0.188  0.675  1.0
  Li  Li3  1  0.256  0.188  0.174  1.0
  Mn  Mn4  1  0.500  0.000  0.500  1.0
  Mn  Mn5  1  0.000  0.500  0.500  1.0
  V  V6  1  0.000  0.000  0.000  1.0
  V  V7  1  0.500  0.500  0.000  1.0
  P  P8  1  0.282  0.239  0.837  1.0
  P  P9  1  0.781  0.236  0.340  1.0
  P  P10  1  0.219  0.764  0.660  1.0
  P  P11  1  0.718  0.761  0.163  1.0
  O  O12  1  0.408  0.612  0.767  1.0
  O  O13  1  0.278  0.918  0.559  1.0
  O  O14  1  0.221  0.087  0.940  1.0
  O  O15  1  0.329  0.346  0.982  1.0
  O  O16  1  0.092  0.389  0.728  1.0
  O  O17  1  0.838  0.338  0.483  1.0
  O  O18  1  0.010  0.888  0.768  1.0
  O  O19  1  0.508  0.884  0.268  1.0
  O  O20  1  0.492  0.116  0.732  1.0
  O  O21  1  0.990  0.112  0.232  1.0
  O  O22  1  0.162  0.662  0.517  1.0
  O  O23  1  0.908  0.611  0.272  1.0
  O  O24  1  0.671  0.654  0.018  1.0
  O  O25  1  0.779  0.913  0.060  1.0
  O  O26  1  0.722  0.082  0.441  1.0
  O  O27  1  0.592  0.388  0.233  1.0
  F  F28  1  0.766  0.262  0.900  1.0
  F  F29  1  0.730  0.737  0.609  1.0
  F  F30  1  0.270  0.263  0.391  1.0
  F  F31  1  0.234  0.738  0.100  1.0
[/CIF]
.
The compound described by Li2VMnP2(O4F)2 crystallizes in the triclinic P-1 space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(3), one O(4), one O(7), one O(8), and one F(2) atom to form distorted LiO4F square pyramids that share  a cornercorner with one V(2)O4F2 octahedra,  a cornercorner with one Mn(2)O4F2 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  an edgeedge with one V(1)O4F2 octahedra,  an edgeedge with one Mn(1)O4F2 octahedra,  an edgeedge with one Li(2)O4F square pyramid, and  an edgeedge with one P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 53-59°. In the second Li site, Li(2) is bonded to one O(2), one O(6), one O(7), one O(8), and one F(1) atom to form distorted LiO4F square pyramids that share  a cornercorner with one V(2)O4F2 octahedra,  a cornercorner with one Mn(2)O4F2 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  an edgeedge with one V(1)O4F2 octahedra,  an edgeedge with one Mn(1)O4F2 octahedra,  an edgeedge with one Li(1)O4F square pyramid, and  an edgeedge with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 52-60°. There are two inequivalent V sites. In the first V site, V(1) is bonded to two equivalent O(3), two equivalent O(7), and two equivalent F(1) atoms to form VO4F2 octahedra that share corners with two equivalent V(2)O4F2 octahedra, corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, edges with two equivalent Li(1)O4F square pyramids, and edges with two equivalent Li(2)O4F square pyramids. The corner-sharing octahedral tilt angles are 47°. In the second V site, V(2) is bonded to two equivalent O(1), two equivalent O(4), and two equivalent F(1) atoms to form VO4F2 octahedra that share corners with two equivalent V(1)O4F2 octahedra, corners with two equivalent Li(1)O4F square pyramids, corners with two equivalent Li(2)O4F square pyramids, corners with two equivalent P(1)O4 tetrahedra, and corners with two equivalent P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 47°. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to two equivalent O(2), two equivalent O(8), and two equivalent F(2) atoms to form MnO4F2 octahedra that share corners with two equivalent Mn(2)O4F2 octahedra, corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, edges with two equivalent Li(1)O4F square pyramids, and edges with two equivalent Li(2)O4F square pyramids. The corner-sharing octahedral tilt angles are 51°. In the second Mn site, Mn(2) is bonded to two equivalent O(5), two equivalent O(6), and two equivalent F(2) atoms to form MnO4F2 octahedra that share corners with two equivalent Mn(1)O4F2 octahedra, corners with two equivalent Li(1)O4F square pyramids, corners with two equivalent Li(2)O4F square pyramids, corners with two equivalent P(1)O4 tetrahedra, and corners with two equivalent P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 51°. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(3), one O(4), one O(5), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O4F2 octahedra,  a cornercorner with one V(2)O4F2 octahedra,  a cornercorner with one Mn(1)O4F2 octahedra,  a cornercorner with one Mn(2)O4F2 octahedra,  a cornercorner with one Li(1)O4F square pyramid,  a cornercorner with one Li(2)O4F square pyramid, and  an edgeedge with one Li(1)O4F square pyramid. The corner-sharing octahedral tilt angles range from 32-55°. In the second P site, P(2) is bonded to one O(1), one O(2), one O(6), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O4F2 octahedra,  a cornercorner with one V(2)O4F2 octahedra,  a cornercorner with one Mn(1)O4F2 octahedra,  a cornercorner with one Mn(2)O4F2 octahedra,  a cornercorner with one Li(1)O4F square pyramid,  a cornercorner with one Li(2)O4F square pyramid, and  an edgeedge with one Li(2)O4F square pyramid. The corner-sharing octahedral tilt angles range from 33-53°. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one V(2) and one P(2) atom. In the second O site, O(2) is bonded in a distorted T-shaped geometry to one Li(2), one Mn(1), and one P(2) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to one Li(1), one V(1), and one P(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Li(1), one V(2), and one P(1) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Mn(2) and one P(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Li(2), one Mn(2), and one P(2) atom. In the seventh O site, O(7) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(2), one V(1), and one P(2) atom. In the eighth O site, O(8) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(2), one Mn(1), and one P(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one Li(2), one V(1), and one V(2) atom. In the second F site, F(2) is bonded in a trigonal planar geometry to one Li(1), one Mn(1), and one Mn(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li2MnVP2(O4F)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.912
_cell_length_b   7.424
_cell_length_c   7.981
_cell_angle_alpha   87.103
_cell_angle_beta   88.371
_cell_angle_gamma   62.853
_symmetry_Int_Tables_number   1
_cell_volume   363.982
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.744  0.812  0.826  1.0
  Li  Li1  1  0.246  0.812  0.325  1.0
  Li  Li2  1  0.754  0.188  0.675  1.0
  Li  Li3  1  0.256  0.188  0.174  1.0
  Mn  Mn4  1  0.500  0.000  0.500  1.0
  Mn  Mn5  1  0.000  0.500  0.500  1.0
  V  V6  1  0.000  0.000  0.000  1.0
  V  V7  1  0.500  0.500  0.000  1.0
  P  P8  1  0.282  0.239  0.837  1.0
  P  P9  1  0.781  0.236  0.340  1.0
  P  P10  1  0.219  0.764  0.660  1.0
  P  P11  1  0.718  0.761  0.163  1.0
  O  O12  1  0.408  0.612  0.767  1.0
  O  O13  1  0.278  0.918  0.559  1.0
  O  O14  1  0.221  0.087  0.940  1.0
  O  O15  1  0.329  0.346  0.982  1.0
  O  O16  1  0.092  0.389  0.728  1.0
  O  O17  1  0.838  0.338  0.483  1.0
  O  O18  1  0.010  0.888  0.768  1.0
  O  O19  1  0.508  0.884  0.268  1.0
  O  O20  1  0.492  0.116  0.732  1.0
  O  O21  1  0.990  0.112  0.232  1.0
  O  O22  1  0.162  0.662  0.517  1.0
  O  O23  1  0.908  0.611  0.272  1.0
  O  O24  1  0.671  0.654  0.018  1.0
  O  O25  1  0.779  0.913  0.060  1.0
  O  O26  1  0.722  0.082  0.441  1.0
  O  O27  1  0.592  0.388  0.233  1.0
  F  F28  1  0.766  0.262  0.900  1.0
  F  F29  1  0.730  0.737  0.609  1.0
  F  F30  1  0.270  0.263  0.391  1.0
  F  F31  1  0.234  0.738  0.100  1.0
[/CIF]
.