The compound described by (AgZn2P3O16)2(O2)3 crystallizes in the triclinic P-1 space group. The structure consists of two trioxidane molecules inside a AgZn2P3O16 framework. In the AgZn2P3O16 framework, Ag(1) is bonded to one O(11), one O(12), one O(2), one O(3), and one O(8) atom to form distorted AgO5 square pyramids that share  a cornercorner with one P(1)O4 tetrahedra and  a cornercorner with one P(2)O4 tetrahedra. There are three inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(13), one O(14), one O(4), and one O(9) atom to form ZnO4 tetrahedra that share corners with two equivalent P(2)O4 tetrahedra and corners with two equivalent P(3)O4 tetrahedra. In the second Zn site, Zn(2) is bonded in a square co-planar geometry to two equivalent O(11) and two equivalent O(2) atoms. In the third Zn site, Zn(3) is bonded in a square co-planar geometry to two equivalent O(10) and two equivalent O(15) atoms. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(10), one O(16), one O(19), and one O(2) atom to form PO4 tetrahedra that share  a cornercorner with one Ag(1)O5 square pyramid,  a cornercorner with one P(2)O4 tetrahedra, and  a cornercorner with one P(3)O4 tetrahedra. In the second P site, P(2) is bonded to one O(11), one O(13), one O(19), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Ag(1)O5 square pyramid,  a cornercorner with one P(1)O4 tetrahedra, and corners with two equivalent Zn(1)O4 tetrahedra. In the third P site, P(3) is bonded to one O(14), one O(15), one O(16), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one P(1)O4 tetrahedra and corners with two equivalent Zn(1)O4 tetrahedra. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one O(3) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Ag(1), one Zn(2), and one P(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Ag(1) and one O(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one P(3) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one O(12) atom. In the sixth O site, O(7) is bonded in a single-bond geometry to one O(8) atom. In the seventh O site, O(8) is bonded in a bent 120 degrees geometry to one Ag(1) and one O(7) atom. In the eighth O site, O(9) is bonded in a bent 120 degrees geometry to one Zn(1) and one P(2) atom. In the ninth O site, O(10) is bonded in a bent 120 degrees geometry to one Zn(3) and one P(1) atom. In the tenth O site, O(11) is bonded in a distorted trigonal planar geometry to one Ag(1), one Zn(2), and one P(2) atom. In the eleventh O site, O(12) is bonded in a bent 120 degrees geometry to one Ag(1) and one O(5) atom. In the twelfth O site, O(13) is bonded in a bent 150 degrees geometry to one Zn(1) and one P(2) atom. In the thirteenth O site, O(14) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one P(3) atom. In the fourteenth O site, O(15) is bonded in a bent 150 degrees geometry to one Zn(3) and one P(3) atom. In the fifteenth O site, O(16) is bonded in a bent 120 degrees geometry to one P(1) and one P(3) atom. In the sixteenth O site, O(19) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Zn2AgP3O19
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.309
_cell_length_b   10.617
_cell_length_c   11.032
_cell_angle_alpha   98.677
_cell_angle_beta   105.696
_cell_angle_gamma   109.033
_symmetry_Int_Tables_number   1
_cell_volume   854.603
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.732  0.004  0.452  1.0
  Zn  Zn1  1  0.268  0.996  0.548  1.0
  Zn  Zn2  1  0.500  0.500  0.500  1.0
  Zn  Zn3  1  0.000  0.000  0.000  1.0
  Ag  Ag4  1  0.082  0.500  0.355  1.0
  Ag  Ag5  1  0.918  0.500  0.645  1.0
  P  P6  1  0.206  0.223  0.273  1.0
  P  P7  1  0.794  0.777  0.727  1.0
  P  P8  1  0.543  0.216  0.443  1.0
  P  P9  1  0.457  0.784  0.557  1.0
  P  P10  1  0.026  0.045  0.717  1.0
  P  P11  1  0.974  0.955  0.283  1.0
  O  O12  1  0.234  0.402  0.663  1.0
  O  O13  1  0.766  0.598  0.337  1.0
  O  O14  1  0.263  0.373  0.353  1.0
  O  O15  1  0.737  0.627  0.647  1.0
  O  O16  1  0.077  0.376  0.589  1.0
  O  O17  1  0.923  0.624  0.411  1.0
  O  O18  1  0.105  0.904  0.367  1.0
  O  O19  1  0.895  0.096  0.633  1.0
  O  O20  1  0.671  0.386  0.192  1.0
  O  O21  1  0.329  0.614  0.808  1.0
  O  O22  1  0.495  0.860  0.075  1.0
  O  O23  1  0.505  0.140  0.925  1.0
  O  O24  1  0.931  0.609  0.092  1.0
  O  O25  1  0.069  0.391  0.908  1.0
  O  O26  1  0.077  0.606  0.154  1.0
  O  O27  1  0.923  0.394  0.846  1.0
  O  O28  1  0.670  0.158  0.404  1.0
  O  O29  1  0.330  0.842  0.596  1.0
  O  O30  1  0.125  0.196  0.129  1.0
  O  O31  1  0.875  0.804  0.871  1.0
  O  O32  1  0.634  0.378  0.490  1.0
  O  O33  1  0.366  0.622  0.510  1.0
  O  O34  1  0.798  0.347  0.216  1.0
  O  O35  1  0.202  0.653  0.784  1.0
  O  O36  1  0.461  0.159  0.540  1.0
  O  O37  1  0.539  0.841  0.460  1.0
  O  O38  1  0.202  0.074  0.688  1.0
  O  O39  1  0.798  0.926  0.312  1.0
  O  O40  1  0.052  0.086  0.861  1.0
  O  O41  1  0.948  0.914  0.139  1.0
  O  O42  1  0.075  0.129  0.334  1.0
  O  O43  1  0.925  0.871  0.666  1.0
  O  O44  1  0.667  0.011  0.942  1.0
  O  O45  1  0.333  0.989  0.058  1.0
  O  O46  1  0.340  0.867  0.053  1.0
  O  O47  1  0.660  0.133  0.947  1.0
  O  O48  1  0.382  0.186  0.305  1.0
  O  O49  1  0.618  0.814  0.695  1.0
[/CIF]
.
The compound described by (AgZn2P3O16)2(O2)3 crystallizes in the triclinic P-1 space group. The structure consists of two trioxidane molecules inside a AgZn2P3O16 framework. In the AgZn2P3O16 framework, Ag(1) is bonded to one O(11), one O(12), one O(2), one O(3), and one O(8) atom to form distorted AgO5 square pyramids that share  a cornercorner with one P(1)O4 tetrahedra and  a cornercorner with one P(2)O4 tetrahedra. There are three inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(13), one O(14), one O(4), and one O(9) atom to form ZnO4 tetrahedra that share corners with two equivalent P(2)O4 tetrahedra and corners with two equivalent P(3)O4 tetrahedra. In the second Zn site, Zn(2) is bonded in a square co-planar geometry to two equivalent O(11) and two equivalent O(2) atoms. In the third Zn site, Zn(3) is bonded in a square co-planar geometry to two equivalent O(10) and two equivalent O(15) atoms. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(10), one O(16), one O(19), and one O(2) atom to form PO4 tetrahedra that share  a cornercorner with one Ag(1)O5 square pyramid,  a cornercorner with one P(2)O4 tetrahedra, and  a cornercorner with one P(3)O4 tetrahedra. In the second P site, P(2) is bonded to one O(11), one O(13), one O(19), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Ag(1)O5 square pyramid,  a cornercorner with one P(1)O4 tetrahedra, and corners with two equivalent Zn(1)O4 tetrahedra. In the third P site, P(3) is bonded to one O(14), one O(15), one O(16), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one P(1)O4 tetrahedra and corners with two equivalent Zn(1)O4 tetrahedra. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one O(3) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Ag(1), one Zn(2), and one P(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Ag(1) and one O(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one P(3) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one O(12) atom. In the sixth O site, O(7) is bonded in a single-bond geometry to one O(8) atom. In the seventh O site, O(8) is bonded in a bent 120 degrees geometry to one Ag(1) and one O(7) atom. In the eighth O site, O(9) is bonded in a bent 120 degrees geometry to one Zn(1) and one P(2) atom. In the ninth O site, O(10) is bonded in a bent 120 degrees geometry to one Zn(3) and one P(1) atom. In the tenth O site, O(11) is bonded in a distorted trigonal planar geometry to one Ag(1), one Zn(2), and one P(2) atom. In the eleventh O site, O(12) is bonded in a bent 120 degrees geometry to one Ag(1) and one O(5) atom. In the twelfth O site, O(13) is bonded in a bent 150 degrees geometry to one Zn(1) and one P(2) atom. In the thirteenth O site, O(14) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one P(3) atom. In the fourteenth O site, O(15) is bonded in a bent 150 degrees geometry to one Zn(3) and one P(3) atom. In the fifteenth O site, O(16) is bonded in a bent 120 degrees geometry to one P(1) and one P(3) atom. In the sixteenth O site, O(19) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Zn2AgP3O19
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.309
_cell_length_b   10.617
_cell_length_c   11.032
_cell_angle_alpha   98.677
_cell_angle_beta   105.696
_cell_angle_gamma   109.033
_symmetry_Int_Tables_number   1
_cell_volume   854.603
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.732  0.004  0.452  1.0
  Zn  Zn1  1  0.268  0.996  0.548  1.0
  Zn  Zn2  1  0.500  0.500  0.500  1.0
  Zn  Zn3  1  0.000  0.000  0.000  1.0
  Ag  Ag4  1  0.082  0.500  0.355  1.0
  Ag  Ag5  1  0.918  0.500  0.645  1.0
  P  P6  1  0.206  0.223  0.273  1.0
  P  P7  1  0.794  0.777  0.727  1.0
  P  P8  1  0.543  0.216  0.443  1.0
  P  P9  1  0.457  0.784  0.557  1.0
  P  P10  1  0.026  0.045  0.717  1.0
  P  P11  1  0.974  0.955  0.283  1.0
  O  O12  1  0.234  0.402  0.663  1.0
  O  O13  1  0.766  0.598  0.337  1.0
  O  O14  1  0.263  0.373  0.353  1.0
  O  O15  1  0.737  0.627  0.647  1.0
  O  O16  1  0.077  0.376  0.589  1.0
  O  O17  1  0.923  0.624  0.411  1.0
  O  O18  1  0.105  0.904  0.367  1.0
  O  O19  1  0.895  0.096  0.633  1.0
  O  O20  1  0.671  0.386  0.192  1.0
  O  O21  1  0.329  0.614  0.808  1.0
  O  O22  1  0.495  0.860  0.075  1.0
  O  O23  1  0.505  0.140  0.925  1.0
  O  O24  1  0.931  0.609  0.092  1.0
  O  O25  1  0.069  0.391  0.908  1.0
  O  O26  1  0.077  0.606  0.154  1.0
  O  O27  1  0.923  0.394  0.846  1.0
  O  O28  1  0.670  0.158  0.404  1.0
  O  O29  1  0.330  0.842  0.596  1.0
  O  O30  1  0.125  0.196  0.129  1.0
  O  O31  1  0.875  0.804  0.871  1.0
  O  O32  1  0.634  0.378  0.490  1.0
  O  O33  1  0.366  0.622  0.510  1.0
  O  O34  1  0.798  0.347  0.216  1.0
  O  O35  1  0.202  0.653  0.784  1.0
  O  O36  1  0.461  0.159  0.540  1.0
  O  O37  1  0.539  0.841  0.460  1.0
  O  O38  1  0.202  0.074  0.688  1.0
  O  O39  1  0.798  0.926  0.312  1.0
  O  O40  1  0.052  0.086  0.861  1.0
  O  O41  1  0.948  0.914  0.139  1.0
  O  O42  1  0.075  0.129  0.334  1.0
  O  O43  1  0.925  0.871  0.666  1.0
  O  O44  1  0.667  0.011  0.942  1.0
  O  O45  1  0.333  0.989  0.058  1.0
  O  O46  1  0.340  0.867  0.053  1.0
  O  O47  1  0.660  0.133  0.947  1.0
  O  O48  1  0.382  0.186  0.305  1.0
  O  O49  1  0.618  0.814  0.695  1.0
[/CIF]
.