The compound described by Co(NiN)2 crystallizes in the tetragonal I4/mmm space group. Co(1) is bonded in a linear geometry to two equivalent N(1) atoms. Ni(1) is bonded to five equivalent N(1) atoms to form a mixture of corner and edge-sharing NiN5 square pyramids. N(1) is bonded to one Co(1) and five equivalent Ni(1) atoms to form a mixture of corner and edge-sharing NCoNi5 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. is represented by the CIF card [CIF]
data_Co(NiN)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.854
_cell_length_b   2.859
_cell_length_c   5.901
_cell_angle_alpha   104.019
_cell_angle_beta   103.994
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   45.249
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.500  0.500  0.500  1.0
  Ni  Ni1  1  0.846  0.846  0.192  1.0
  Ni  Ni2  1  0.154  0.154  0.808  1.0
  N  N3  1  0.339  0.339  0.178  1.0
  N  N4  1  0.661  0.661  0.822  1.0
[/CIF]
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The compound described by Co(NiN)2 crystallizes in the tetragonal I4/mmm space group. Co(1) is bonded in a linear geometry to two equivalent N(1) atoms. Ni(1) is bonded to five equivalent N(1) atoms to form a mixture of corner and edge-sharing NiN5 square pyramids. N(1) is bonded to one Co(1) and five equivalent Ni(1) atoms to form a mixture of corner and edge-sharing NCoNi5 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. is represented by the CIF card [CIF]
data_Co(NiN)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.854
_cell_length_b   2.859
_cell_length_c   5.901
_cell_angle_alpha   104.019
_cell_angle_beta   103.994
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   45.249
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.500  0.500  0.500  1.0
  Ni  Ni1  1  0.846  0.846  0.192  1.0
  Ni  Ni2  1  0.154  0.154  0.808  1.0
  N  N3  1  0.339  0.339  0.178  1.0
  N  N4  1  0.661  0.661  0.822  1.0
[/CIF]
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