The compound described by Dy5Os6Sn17Sn crystallizes in the cubic F-43m space group. The structure consists of four 7440-31-5 atoms inside a Dy5Os6Sn17 framework. In the Dy5Os6Sn17 framework, there are two inequivalent Dy sites. In the first Dy site, Dy(1) is bonded in a 18-coordinate geometry to six equivalent Os(1) and twelve equivalent Sn(3) atoms. In the second Dy site, Dy(2) is bonded in a 13-coordinate geometry to three equivalent Os(1), one Sn(4), three equivalent Sn(1), and six equivalent Sn(3) atoms. Os(1) is bonded in a 8-coordinate geometry to one Dy(1), two equivalent Dy(2), two equivalent Sn(1), and four equivalent Sn(3) atoms. There are three inequivalent Sn sites. In the first Sn site, Sn(4) is bonded in a tetrahedral geometry to four equivalent Dy(2) atoms. In the second Sn site, Sn(1) is bonded in a hexagonal planar geometry to three equivalent Dy(2) and three equivalent Os(1) atoms. In the third Sn site, Sn(3) is bonded in a 2-coordinate geometry to one Dy(1), two equivalent Dy(2), and two equivalent Os(1) atoms. is represented by the CIF card [CIF]
data_Dy5(Sn3Os)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.906
_cell_length_b   9.906
_cell_length_c   9.906
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   687.281
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  1  0.000  0.000  0.000  1.0
  Dy  Dy1  1  0.372  0.372  0.885  1.0
  Dy  Dy2  1  0.372  0.885  0.372  1.0
  Dy  Dy3  1  0.885  0.372  0.372  1.0
  Dy  Dy4  1  0.372  0.372  0.372  1.0
  Sn  Sn5  1  0.590  0.590  0.230  1.0
  Sn  Sn6  1  0.590  0.230  0.590  1.0
  Sn  Sn7  1  0.230  0.590  0.590  1.0
  Sn  Sn8  1  0.590  0.590  0.590  1.0
  Sn  Sn9  1  0.750  0.750  0.750  1.0
  Sn  Sn10  1  0.998  0.351  0.653  1.0
  Sn  Sn11  1  0.998  0.998  0.653  1.0
  Sn  Sn12  1  0.351  0.998  0.653  1.0
  Sn  Sn13  1  0.998  0.653  0.351  1.0
  Sn  Sn14  1  0.351  0.653  0.998  1.0
  Sn  Sn15  1  0.998  0.653  0.998  1.0
  Sn  Sn16  1  0.653  0.998  0.998  1.0
  Sn  Sn17  1  0.653  0.351  0.998  1.0
  Sn  Sn18  1  0.653  0.998  0.351  1.0
  Sn  Sn19  1  0.351  0.998  0.998  1.0
  Sn  Sn20  1  0.998  0.998  0.351  1.0
  Sn  Sn21  1  0.998  0.351  0.998  1.0
  Sn  Sn22  1  0.250  0.250  0.250  1.0
  Os  Os23  1  0.253  0.253  0.747  1.0
  Os  Os24  1  0.747  0.253  0.747  1.0
  Os  Os25  1  0.253  0.747  0.747  1.0
  Os  Os26  1  0.747  0.747  0.253  1.0
  Os  Os27  1  0.253  0.747  0.253  1.0
  Os  Os28  1  0.747  0.253  0.253  1.0
[/CIF]
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The compound described by Dy5Os6Sn17Sn crystallizes in the cubic F-43m space group. The structure consists of four 7440-31-5 atoms inside a Dy5Os6Sn17 framework. In the Dy5Os6Sn17 framework, there are two inequivalent Dy sites. In the first Dy site, Dy(1) is bonded in a 18-coordinate geometry to six equivalent Os(1) and twelve equivalent Sn(3) atoms. In the second Dy site, Dy(2) is bonded in a 13-coordinate geometry to three equivalent Os(1), one Sn(4), three equivalent Sn(1), and six equivalent Sn(3) atoms. Os(1) is bonded in a 8-coordinate geometry to one Dy(1), two equivalent Dy(2), two equivalent Sn(1), and four equivalent Sn(3) atoms. There are three inequivalent Sn sites. In the first Sn site, Sn(4) is bonded in a tetrahedral geometry to four equivalent Dy(2) atoms. In the second Sn site, Sn(1) is bonded in a hexagonal planar geometry to three equivalent Dy(2) and three equivalent Os(1) atoms. In the third Sn site, Sn(3) is bonded in a 2-coordinate geometry to one Dy(1), two equivalent Dy(2), and two equivalent Os(1) atoms. is represented by the CIF card [CIF]
data_Dy5(Sn3Os)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.906
_cell_length_b   9.906
_cell_length_c   9.906
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   687.281
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  1  0.000  0.000  0.000  1.0
  Dy  Dy1  1  0.372  0.372  0.885  1.0
  Dy  Dy2  1  0.372  0.885  0.372  1.0
  Dy  Dy3  1  0.885  0.372  0.372  1.0
  Dy  Dy4  1  0.372  0.372  0.372  1.0
  Sn  Sn5  1  0.590  0.590  0.230  1.0
  Sn  Sn6  1  0.590  0.230  0.590  1.0
  Sn  Sn7  1  0.230  0.590  0.590  1.0
  Sn  Sn8  1  0.590  0.590  0.590  1.0
  Sn  Sn9  1  0.750  0.750  0.750  1.0
  Sn  Sn10  1  0.998  0.351  0.653  1.0
  Sn  Sn11  1  0.998  0.998  0.653  1.0
  Sn  Sn12  1  0.351  0.998  0.653  1.0
  Sn  Sn13  1  0.998  0.653  0.351  1.0
  Sn  Sn14  1  0.351  0.653  0.998  1.0
  Sn  Sn15  1  0.998  0.653  0.998  1.0
  Sn  Sn16  1  0.653  0.998  0.998  1.0
  Sn  Sn17  1  0.653  0.351  0.998  1.0
  Sn  Sn18  1  0.653  0.998  0.351  1.0
  Sn  Sn19  1  0.351  0.998  0.998  1.0
  Sn  Sn20  1  0.998  0.998  0.351  1.0
  Sn  Sn21  1  0.998  0.351  0.998  1.0
  Sn  Sn22  1  0.250  0.250  0.250  1.0
  Os  Os23  1  0.253  0.253  0.747  1.0
  Os  Os24  1  0.747  0.253  0.747  1.0
  Os  Os25  1  0.253  0.747  0.747  1.0
  Os  Os26  1  0.747  0.747  0.253  1.0
  Os  Os27  1  0.253  0.747  0.253  1.0
  Os  Os28  1  0.747  0.253  0.253  1.0
[/CIF]
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