The compound described by V2CrTe4 crystallizes in the monoclinic C2/m space group. V(1) is bonded to three equivalent Te(1) and three equivalent Te(2) atoms to form distorted VTe6 octahedra that share corners with six equivalent Cr(1)Te6 octahedra, edges with six equivalent V(1)Te6 octahedra, and  a faceface with one Cr(1)Te6 octahedra. The corner-sharing octahedral tilt angles range from 51-54°. Cr(1) is bonded to two equivalent Te(1) and four equivalent Te(2) atoms to form CrTe6 octahedra that share corners with twelve equivalent V(1)Te6 octahedra, edges with two equivalent Cr(1)Te6 octahedra, and faces with two equivalent V(1)Te6 octahedra. The corner-sharing octahedral tilt angles range from 51-54°. There are two inequivalent Te sites. In the first Te site, Te(2) is bonded in a 5-coordinate geometry to three equivalent V(1) and two equivalent Cr(1) atoms. In the second Te site, Te(1) is bonded in a distorted rectangular see-saw-like geometry to three equivalent V(1) and one Cr(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_V2CrTe4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.333
_cell_length_b   7.333
_cell_length_c   6.827
_cell_angle_alpha   64.536
_cell_angle_beta   64.536
_cell_angle_gamma   31.221
_symmetry_Int_Tables_number   1
_cell_volume   170.284
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.743  0.743  0.300  1.0
  V  V1  1  0.257  0.257  0.700  1.0
  Cr  Cr2  1  0.000  0.000  0.000  1.0
  Te  Te3  1  0.889  0.889  0.452  1.0
  Te  Te4  1  0.111  0.111  0.548  1.0
  Te  Te5  1  0.640  0.640  0.019  1.0
  Te  Te6  1  0.360  0.360  0.981  1.0
[/CIF]
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The compound described by V2CrTe4 crystallizes in the monoclinic C2/m space group. V(1) is bonded to three equivalent Te(1) and three equivalent Te(2) atoms to form distorted VTe6 octahedra that share corners with six equivalent Cr(1)Te6 octahedra, edges with six equivalent V(1)Te6 octahedra, and  a faceface with one Cr(1)Te6 octahedra. The corner-sharing octahedral tilt angles range from 51-54°. Cr(1) is bonded to two equivalent Te(1) and four equivalent Te(2) atoms to form CrTe6 octahedra that share corners with twelve equivalent V(1)Te6 octahedra, edges with two equivalent Cr(1)Te6 octahedra, and faces with two equivalent V(1)Te6 octahedra. The corner-sharing octahedral tilt angles range from 51-54°. There are two inequivalent Te sites. In the first Te site, Te(2) is bonded in a 5-coordinate geometry to three equivalent V(1) and two equivalent Cr(1) atoms. In the second Te site, Te(1) is bonded in a distorted rectangular see-saw-like geometry to three equivalent V(1) and one Cr(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_V2CrTe4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.333
_cell_length_b   7.333
_cell_length_c   6.827
_cell_angle_alpha   64.536
_cell_angle_beta   64.536
_cell_angle_gamma   31.221
_symmetry_Int_Tables_number   1
_cell_volume   170.284
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.743  0.743  0.300  1.0
  V  V1  1  0.257  0.257  0.700  1.0
  Cr  Cr2  1  0.000  0.000  0.000  1.0
  Te  Te3  1  0.889  0.889  0.452  1.0
  Te  Te4  1  0.111  0.111  0.548  1.0
  Te  Te5  1  0.640  0.640  0.019  1.0
  Te  Te6  1  0.360  0.360  0.981  1.0
[/CIF]
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