The structure described by (NH4)3H(SO4)2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of twelve ammonium molecules and four H(SO4)2 clusters. In each H(SO4)2 cluster, H(7) is bonded in a linear geometry to two equivalent O(2) atoms. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a water-like geometry to one H(7) and one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one S(1) atom. is represented by the CIF file [CIF]
data_H13S2N3O8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.379
_cell_length_b   8.379
_cell_length_c   10.353
_cell_angle_alpha   80.346
_cell_angle_beta   80.346
_cell_angle_gamma   41.170
_symmetry_Int_Tables_number   1
_cell_volume   470.798
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.654  0.411  0.175  1.0
  H  H1  1  0.411  0.654  0.675  1.0
  H  H2  1  0.346  0.589  0.825  1.0
  H  H3  1  0.589  0.346  0.325  1.0
  H  H4  1  0.869  0.224  0.282  1.0
  H  H5  1  0.224  0.869  0.782  1.0
  H  H6  1  0.131  0.776  0.718  1.0
  H  H7  1  0.776  0.131  0.218  1.0
  H  H8  1  0.870  0.480  0.757  1.0
  H  H9  1  0.480  0.870  0.257  1.0
  H  H10  1  0.130  0.520  0.243  1.0
  H  H11  1  0.520  0.130  0.743  1.0
  H  H12  1  0.954  0.558  0.844  1.0
  H  H13  1  0.558  0.954  0.344  1.0
  H  H14  1  0.046  0.442  0.156  1.0
  H  H15  1  0.442  0.046  0.656  1.0
  H  H16  1  0.770  0.547  0.916  1.0
  H  H17  1  0.547  0.770  0.416  1.0
  H  H18  1  0.230  0.453  0.084  1.0
  H  H19  1  0.453  0.230  0.584  1.0
  H  H20  1  0.065  0.283  0.876  1.0
  H  H21  1  0.283  0.065  0.376  1.0
  H  H22  1  0.935  0.717  0.124  1.0
  H  H23  1  0.717  0.935  0.624  1.0
  H  H24  1  0.000  0.000  0.500  1.0
  H  H25  1  0.000  0.000  0.000  1.0
  S  S26  1  0.320  0.905  0.039  1.0
  S  S27  1  0.905  0.320  0.539  1.0
  S  S28  1  0.680  0.095  0.961  1.0
  S  S29  1  0.095  0.680  0.461  1.0
  N  N30  1  0.277  0.723  0.750  1.0
  N  N31  1  0.723  0.277  0.250  1.0
  N  N32  1  0.915  0.467  0.848  1.0
  N  N33  1  0.467  0.915  0.348  1.0
  N  N34  1  0.085  0.533  0.152  1.0
  N  N35  1  0.533  0.085  0.652  1.0
  O  O36  1  0.172  0.127  0.108  1.0
  O  O37  1  0.127  0.172  0.608  1.0
  O  O38  1  0.828  0.873  0.892  1.0
  O  O39  1  0.873  0.828  0.392  1.0
  O  O40  1  0.187  0.840  0.056  1.0
  O  O41  1  0.840  0.187  0.556  1.0
  O  O42  1  0.813  0.160  0.944  1.0
  O  O43  1  0.160  0.813  0.444  1.0
  O  O44  1  0.350  0.946  0.896  1.0
  O  O45  1  0.946  0.350  0.396  1.0
  O  O46  1  0.650  0.054  0.104  1.0
  O  O47  1  0.054  0.650  0.604  1.0
  O  O48  1  0.558  0.692  0.097  1.0
  O  O49  1  0.692  0.558  0.597  1.0
  O  O50  1  0.442  0.308  0.903  1.0
  O  O51  1  0.308  0.442  0.403  1.0
[/CIF]
.
The structure described by (NH4)3H(SO4)2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of twelve ammonium molecules and four H(SO4)2 clusters. In each H(SO4)2 cluster, H(7) is bonded in a linear geometry to two equivalent O(2) atoms. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a water-like geometry to one H(7) and one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one S(1) atom. is represented by the CIF file [CIF]
data_H13S2N3O8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.379
_cell_length_b   8.379
_cell_length_c   10.353
_cell_angle_alpha   80.346
_cell_angle_beta   80.346
_cell_angle_gamma   41.170
_symmetry_Int_Tables_number   1
_cell_volume   470.798
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.654  0.411  0.175  1.0
  H  H1  1  0.411  0.654  0.675  1.0
  H  H2  1  0.346  0.589  0.825  1.0
  H  H3  1  0.589  0.346  0.325  1.0
  H  H4  1  0.869  0.224  0.282  1.0
  H  H5  1  0.224  0.869  0.782  1.0
  H  H6  1  0.131  0.776  0.718  1.0
  H  H7  1  0.776  0.131  0.218  1.0
  H  H8  1  0.870  0.480  0.757  1.0
  H  H9  1  0.480  0.870  0.257  1.0
  H  H10  1  0.130  0.520  0.243  1.0
  H  H11  1  0.520  0.130  0.743  1.0
  H  H12  1  0.954  0.558  0.844  1.0
  H  H13  1  0.558  0.954  0.344  1.0
  H  H14  1  0.046  0.442  0.156  1.0
  H  H15  1  0.442  0.046  0.656  1.0
  H  H16  1  0.770  0.547  0.916  1.0
  H  H17  1  0.547  0.770  0.416  1.0
  H  H18  1  0.230  0.453  0.084  1.0
  H  H19  1  0.453  0.230  0.584  1.0
  H  H20  1  0.065  0.283  0.876  1.0
  H  H21  1  0.283  0.065  0.376  1.0
  H  H22  1  0.935  0.717  0.124  1.0
  H  H23  1  0.717  0.935  0.624  1.0
  H  H24  1  0.000  0.000  0.500  1.0
  H  H25  1  0.000  0.000  0.000  1.0
  S  S26  1  0.320  0.905  0.039  1.0
  S  S27  1  0.905  0.320  0.539  1.0
  S  S28  1  0.680  0.095  0.961  1.0
  S  S29  1  0.095  0.680  0.461  1.0
  N  N30  1  0.277  0.723  0.750  1.0
  N  N31  1  0.723  0.277  0.250  1.0
  N  N32  1  0.915  0.467  0.848  1.0
  N  N33  1  0.467  0.915  0.348  1.0
  N  N34  1  0.085  0.533  0.152  1.0
  N  N35  1  0.533  0.085  0.652  1.0
  O  O36  1  0.172  0.127  0.108  1.0
  O  O37  1  0.127  0.172  0.608  1.0
  O  O38  1  0.828  0.873  0.892  1.0
  O  O39  1  0.873  0.828  0.392  1.0
  O  O40  1  0.187  0.840  0.056  1.0
  O  O41  1  0.840  0.187  0.556  1.0
  O  O42  1  0.813  0.160  0.944  1.0
  O  O43  1  0.160  0.813  0.444  1.0
  O  O44  1  0.350  0.946  0.896  1.0
  O  O45  1  0.946  0.350  0.396  1.0
  O  O46  1  0.650  0.054  0.104  1.0
  O  O47  1  0.054  0.650  0.604  1.0
  O  O48  1  0.558  0.692  0.097  1.0
  O  O49  1  0.692  0.558  0.597  1.0
  O  O50  1  0.442  0.308  0.903  1.0
  O  O51  1  0.308  0.442  0.403  1.0
[/CIF]
.