The compound described by (C3N2)2(I)3 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four methenamine molecules and four I clusters. In each I cluster, there are three inequivalent I sites. In the first I site, I(1) is bonded in a single-bond geometry to one I(2) atom. In the second I site, I(3) is bonded in a single-bond geometry to one I(2) atom. In the third I site, I(2) is bonded in a linear geometry to one I(1) and one I(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_C6I3N4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.173
_cell_length_b   9.390
_cell_length_c   10.893
_cell_angle_alpha   86.339
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1140.501
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  C  C0  1  0.354  0.616  0.911  1.0
  C  C1  1  0.854  0.384  0.589  1.0
  C  C2  1  0.646  0.384  0.089  1.0
  C  C3  1  0.146  0.616  0.411  1.0
  C  C4  1  0.418  0.844  0.902  1.0
  C  C5  1  0.918  0.156  0.598  1.0
  C  C6  1  0.582  0.156  0.098  1.0
  C  C7  1  0.082  0.844  0.402  1.0
  C  C8  1  0.352  0.869  0.111  1.0
  C  C9  1  0.852  0.131  0.389  1.0
  C  C10  1  0.648  0.131  0.889  1.0
  C  C11  1  0.148  0.869  0.611  1.0
  C  C12  1  0.215  0.795  0.963  1.0
  C  C13  1  0.715  0.205  0.537  1.0
  C  C14  1  0.785  0.205  0.037  1.0
  C  C15  1  0.285  0.795  0.463  1.0
  C  C16  1  0.287  0.630  0.116  1.0
  C  C17  1  0.787  0.370  0.384  1.0
  C  C18  1  0.713  0.370  0.884  1.0
  C  C19  1  0.213  0.630  0.616  1.0
  C  C20  1  0.483  0.691  0.064  1.0
  C  C21  1  0.983  0.309  0.436  1.0
  C  C22  1  0.517  0.309  0.936  1.0
  C  C23  1  0.017  0.691  0.564  1.0
  I  I24  1  0.066  0.106  0.136  1.0
  I  I25  1  0.566  0.894  0.364  1.0
  I  I26  1  0.934  0.894  0.864  1.0
  I  I27  1  0.434  0.106  0.636  1.0
  I  I28  1  0.261  0.243  0.253  1.0
  I  I29  1  0.761  0.757  0.247  1.0
  I  I30  1  0.739  0.757  0.747  1.0
  I  I31  1  0.239  0.243  0.753  1.0
  I  I32  1  0.446  0.407  0.366  1.0
  I  I33  1  0.946  0.593  0.134  1.0
  I  I34  1  0.554  0.593  0.634  1.0
  I  I35  1  0.054  0.407  0.866  1.0
  N  N36  1  0.385  0.599  0.039  1.0
  N  N37  1  0.885  0.401  0.461  1.0
  N  N38  1  0.615  0.401  0.961  1.0
  N  N39  1  0.115  0.599  0.539  1.0
  N  N40  1  0.316  0.759  0.889  1.0
  N  N41  1  0.816  0.241  0.611  1.0
  N  N42  1  0.684  0.241  0.111  1.0
  N  N43  1  0.184  0.759  0.389  1.0
  N  N44  1  0.447  0.834  0.031  1.0
  N  N45  1  0.947  0.166  0.469  1.0
  N  N46  1  0.553  0.166  0.969  1.0
  N  N47  1  0.053  0.834  0.531  1.0
  N  N48  1  0.257  0.776  0.084  1.0
  N  N49  1  0.757  0.224  0.416  1.0
  N  N50  1  0.743  0.224  0.916  1.0
  N  N51  1  0.243  0.776  0.584  1.0
[/CIF]
.
The compound described by (C3N2)2(I)3 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four methenamine molecules and four I clusters. In each I cluster, there are three inequivalent I sites. In the first I site, I(1) is bonded in a single-bond geometry to one I(2) atom. In the second I site, I(3) is bonded in a single-bond geometry to one I(2) atom. In the third I site, I(2) is bonded in a linear geometry to one I(1) and one I(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_C6I3N4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.173
_cell_length_b   9.390
_cell_length_c   10.893
_cell_angle_alpha   86.339
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1140.501
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  C  C0  1  0.354  0.616  0.911  1.0
  C  C1  1  0.854  0.384  0.589  1.0
  C  C2  1  0.646  0.384  0.089  1.0
  C  C3  1  0.146  0.616  0.411  1.0
  C  C4  1  0.418  0.844  0.902  1.0
  C  C5  1  0.918  0.156  0.598  1.0
  C  C6  1  0.582  0.156  0.098  1.0
  C  C7  1  0.082  0.844  0.402  1.0
  C  C8  1  0.352  0.869  0.111  1.0
  C  C9  1  0.852  0.131  0.389  1.0
  C  C10  1  0.648  0.131  0.889  1.0
  C  C11  1  0.148  0.869  0.611  1.0
  C  C12  1  0.215  0.795  0.963  1.0
  C  C13  1  0.715  0.205  0.537  1.0
  C  C14  1  0.785  0.205  0.037  1.0
  C  C15  1  0.285  0.795  0.463  1.0
  C  C16  1  0.287  0.630  0.116  1.0
  C  C17  1  0.787  0.370  0.384  1.0
  C  C18  1  0.713  0.370  0.884  1.0
  C  C19  1  0.213  0.630  0.616  1.0
  C  C20  1  0.483  0.691  0.064  1.0
  C  C21  1  0.983  0.309  0.436  1.0
  C  C22  1  0.517  0.309  0.936  1.0
  C  C23  1  0.017  0.691  0.564  1.0
  I  I24  1  0.066  0.106  0.136  1.0
  I  I25  1  0.566  0.894  0.364  1.0
  I  I26  1  0.934  0.894  0.864  1.0
  I  I27  1  0.434  0.106  0.636  1.0
  I  I28  1  0.261  0.243  0.253  1.0
  I  I29  1  0.761  0.757  0.247  1.0
  I  I30  1  0.739  0.757  0.747  1.0
  I  I31  1  0.239  0.243  0.753  1.0
  I  I32  1  0.446  0.407  0.366  1.0
  I  I33  1  0.946  0.593  0.134  1.0
  I  I34  1  0.554  0.593  0.634  1.0
  I  I35  1  0.054  0.407  0.866  1.0
  N  N36  1  0.385  0.599  0.039  1.0
  N  N37  1  0.885  0.401  0.461  1.0
  N  N38  1  0.615  0.401  0.961  1.0
  N  N39  1  0.115  0.599  0.539  1.0
  N  N40  1  0.316  0.759  0.889  1.0
  N  N41  1  0.816  0.241  0.611  1.0
  N  N42  1  0.684  0.241  0.111  1.0
  N  N43  1  0.184  0.759  0.389  1.0
  N  N44  1  0.447  0.834  0.031  1.0
  N  N45  1  0.947  0.166  0.469  1.0
  N  N46  1  0.553  0.166  0.969  1.0
  N  N47  1  0.053  0.834  0.531  1.0
  N  N48  1  0.257  0.776  0.084  1.0
  N  N49  1  0.757  0.224  0.416  1.0
  N  N50  1  0.743  0.224  0.916  1.0
  N  N51  1  0.243  0.776  0.584  1.0
[/CIF]
.