The structure described by SbO2F crystallizes in the monoclinic C2/c space group. Sb(1) is bonded to four equivalent O(1) and two equivalent F(1) atoms to form corner-sharing SbO4F2 octahedra. The corner-sharing octahedral tilt angles range from 37-42°. O(1) is bonded in a bent 150 degrees geometry to two equivalent Sb(1) atoms. F(1) is bonded in a bent 150 degrees geometry to two equivalent Sb(1) atoms. is represented by the CIF card [CIF]
data_SbO2F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.164
_cell_length_b   5.164
_cell_length_c   5.256
_cell_angle_alpha   63.062
_cell_angle_beta   63.062
_cell_angle_gamma   56.609
_symmetry_Int_Tables_number   1
_cell_volume   100.345
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.500  0.000  0.500  1.0
  Sb  Sb1  1  0.000  0.500  0.000  1.0
  O  O2  1  0.258  0.115  0.245  1.0
  O  O3  1  0.885  0.742  0.255  1.0
  O  O4  1  0.115  0.258  0.745  1.0
  O  O5  1  0.742  0.885  0.755  1.0
  F  F6  1  0.384  0.616  0.750  1.0
  F  F7  1  0.616  0.384  0.250  1.0
[/CIF]
.
The structure described by SbO2F crystallizes in the monoclinic C2/c space group. Sb(1) is bonded to four equivalent O(1) and two equivalent F(1) atoms to form corner-sharing SbO4F2 octahedra. The corner-sharing octahedral tilt angles range from 37-42°. O(1) is bonded in a bent 150 degrees geometry to two equivalent Sb(1) atoms. F(1) is bonded in a bent 150 degrees geometry to two equivalent Sb(1) atoms. is represented by the CIF card [CIF]
data_SbO2F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.164
_cell_length_b   5.164
_cell_length_c   5.256
_cell_angle_alpha   63.062
_cell_angle_beta   63.062
_cell_angle_gamma   56.609
_symmetry_Int_Tables_number   1
_cell_volume   100.345
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.500  0.000  0.500  1.0
  Sb  Sb1  1  0.000  0.500  0.000  1.0
  O  O2  1  0.258  0.115  0.245  1.0
  O  O3  1  0.885  0.742  0.255  1.0
  O  O4  1  0.115  0.258  0.745  1.0
  O  O5  1  0.742  0.885  0.755  1.0
  F  F6  1  0.384  0.616  0.750  1.0
  F  F7  1  0.616  0.384  0.250  1.0
[/CIF]
.