The compound described by CNH2SbHS2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four methylamine molecules and two SbHS2 clusters. In each SbHS2 cluster, there are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 3-coordinate geometry to one S(1), one S(2), and one S(3) atom. In the second Sb site, Sb(2) is bonded in a 3-coordinate geometry to one S(2), one S(3), and one S(4) atom. H(2,4) is bonded in a single-bond geometry to one S(1) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a distorted single-bond geometry to one Sb(1) and one H(2,4) atom. In the second S site, S(2) is bonded in an L-shaped geometry to one Sb(1) and one Sb(2) atom. In the third S site, S(3) is bonded in an L-shaped geometry to one Sb(1) and one Sb(2) atom. In the fourth S site, S(4) is bonded in a distorted single-bond geometry to one Sb(2) and one H(2,4) atom. is represented by the CIF file [CIF]
data_SbH3CS2N
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.970
_cell_length_b   7.927
_cell_length_c   12.195
_cell_angle_alpha   94.592
_cell_angle_beta   97.520
_cell_angle_gamma   107.872
_symmetry_Int_Tables_number   1
_cell_volume   630.609
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.518  0.698  0.375  1.0
  Sb  Sb1  1  0.482  0.302  0.625  1.0
  Sb  Sb2  1  0.124  0.708  0.155  1.0
  Sb  Sb3  1  0.876  0.292  0.845  1.0
  H  H4  1  0.110  0.705  0.582  1.0
  H  H5  1  0.890  0.295  0.418  1.0
  H  H6  1  0.729  0.682  0.635  1.0
  H  H7  1  0.271  0.318  0.365  1.0
  H  H8  1  0.079  0.717  0.723  1.0
  H  H9  1  0.921  0.283  0.277  1.0
  H  H10  1  0.887  0.670  0.901  1.0
  H  H11  1  0.113  0.330  0.099  1.0
  H  H12  1  0.546  0.706  0.825  1.0
  H  H13  1  0.454  0.294  0.175  1.0
  H  H14  1  0.532  0.714  0.968  1.0
  H  H15  1  0.468  0.286  0.032  1.0
  C  C16  1  0.147  0.955  0.659  1.0
  C  C17  1  0.853  0.045  0.341  1.0
  C  C18  1  0.682  0.951  0.918  1.0
  C  C19  1  0.318  0.049  0.082  1.0
  S  S20  1  0.475  0.358  0.369  1.0
  S  S21  1  0.525  0.642  0.631  1.0
  S  S22  1  0.159  0.676  0.368  1.0
  S  S23  1  0.841  0.324  0.632  1.0
  S  S24  1  0.466  0.681  0.162  1.0
  S  S25  1  0.534  0.319  0.838  1.0
  S  S26  1  0.933  0.360  0.103  1.0
  S  S27  1  0.067  0.640  0.897  1.0
  N  N28  1  0.108  0.785  0.653  1.0
  N  N29  1  0.892  0.215  0.347  1.0
  N  N30  1  0.584  0.784  0.903  1.0
  N  N31  1  0.416  0.216  0.097  1.0
[/CIF]
.
The compound described by CNH2SbHS2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four methylamine molecules and two SbHS2 clusters. In each SbHS2 cluster, there are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 3-coordinate geometry to one S(1), one S(2), and one S(3) atom. In the second Sb site, Sb(2) is bonded in a 3-coordinate geometry to one S(2), one S(3), and one S(4) atom. H(2,4) is bonded in a single-bond geometry to one S(1) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a distorted single-bond geometry to one Sb(1) and one H(2,4) atom. In the second S site, S(2) is bonded in an L-shaped geometry to one Sb(1) and one Sb(2) atom. In the third S site, S(3) is bonded in an L-shaped geometry to one Sb(1) and one Sb(2) atom. In the fourth S site, S(4) is bonded in a distorted single-bond geometry to one Sb(2) and one H(2,4) atom. is represented by the CIF file [CIF]
data_SbH3CS2N
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.970
_cell_length_b   7.927
_cell_length_c   12.195
_cell_angle_alpha   94.592
_cell_angle_beta   97.520
_cell_angle_gamma   107.872
_symmetry_Int_Tables_number   1
_cell_volume   630.609
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.518  0.698  0.375  1.0
  Sb  Sb1  1  0.482  0.302  0.625  1.0
  Sb  Sb2  1  0.124  0.708  0.155  1.0
  Sb  Sb3  1  0.876  0.292  0.845  1.0
  H  H4  1  0.110  0.705  0.582  1.0
  H  H5  1  0.890  0.295  0.418  1.0
  H  H6  1  0.729  0.682  0.635  1.0
  H  H7  1  0.271  0.318  0.365  1.0
  H  H8  1  0.079  0.717  0.723  1.0
  H  H9  1  0.921  0.283  0.277  1.0
  H  H10  1  0.887  0.670  0.901  1.0
  H  H11  1  0.113  0.330  0.099  1.0
  H  H12  1  0.546  0.706  0.825  1.0
  H  H13  1  0.454  0.294  0.175  1.0
  H  H14  1  0.532  0.714  0.968  1.0
  H  H15  1  0.468  0.286  0.032  1.0
  C  C16  1  0.147  0.955  0.659  1.0
  C  C17  1  0.853  0.045  0.341  1.0
  C  C18  1  0.682  0.951  0.918  1.0
  C  C19  1  0.318  0.049  0.082  1.0
  S  S20  1  0.475  0.358  0.369  1.0
  S  S21  1  0.525  0.642  0.631  1.0
  S  S22  1  0.159  0.676  0.368  1.0
  S  S23  1  0.841  0.324  0.632  1.0
  S  S24  1  0.466  0.681  0.162  1.0
  S  S25  1  0.534  0.319  0.838  1.0
  S  S26  1  0.933  0.360  0.103  1.0
  S  S27  1  0.067  0.640  0.897  1.0
  N  N28  1  0.108  0.785  0.653  1.0
  N  N29  1  0.892  0.215  0.347  1.0
  N  N30  1  0.584  0.784  0.903  1.0
  N  N31  1  0.416  0.216  0.097  1.0
[/CIF]
.