The material structure described by AgZnF5 crystallizes in the monoclinic P2_1/c space group. Ag(1) is bonded to one F(1), one F(2), one F(3), one F(4), and two equivalent F(5) atoms to form corner-sharing AgF6 octahedra. The corner-sharing octahedral tilt angles are 39°. Zn(1) is bonded in a 4-coordinate geometry to one F(1), one F(2), one F(3), one F(4), and one F(5) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a distorted bent 120 degrees geometry to one Ag(1) and one Zn(1) atom. In the second F site, F(2) is bonded in a distorted bent 150 degrees geometry to one Ag(1) and one Zn(1) atom. In the third F site, F(3) is bonded in a bent 150 degrees geometry to one Ag(1) and one Zn(1) atom. In the fourth F site, F(4) is bonded in a linear geometry to one Ag(1) and one Zn(1) atom. In the fifth F site, F(5) is bonded in a 3-coordinate geometry to two equivalent Ag(1) and one Zn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZnAgF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.135
_cell_length_b   5.353
_cell_length_c   7.971
_cell_angle_alpha   69.054
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   403.898
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.003  0.515  0.752  1.0
  Zn  Zn1  1  0.503  0.485  0.748  1.0
  Zn  Zn2  1  0.997  0.485  0.248  1.0
  Zn  Zn3  1  0.497  0.515  0.252  1.0
  Ag  Ag4  1  0.754  0.104  0.601  1.0
  Ag  Ag5  1  0.254  0.896  0.899  1.0
  Ag  Ag6  1  0.246  0.896  0.399  1.0
  Ag  Ag7  1  0.746  0.104  0.101  1.0
  F  F8  1  0.895  0.406  0.573  1.0
  F  F9  1  0.395  0.594  0.927  1.0
  F  F10  1  0.105  0.594  0.427  1.0
  F  F11  1  0.605  0.406  0.073  1.0
  F  F12  1  0.602  0.369  0.490  1.0
  F  F13  1  0.102  0.631  0.010  1.0
  F  F14  1  0.398  0.631  0.510  1.0
  F  F15  1  0.898  0.369  0.990  1.0
  F  F16  1  0.413  0.152  0.803  1.0
  F  F17  1  0.913  0.848  0.697  1.0
  F  F18  1  0.587  0.848  0.197  1.0
  F  F19  1  0.087  0.152  0.303  1.0
  F  F20  1  0.123  0.226  0.842  1.0
  F  F21  1  0.623  0.774  0.658  1.0
  F  F22  1  0.877  0.774  0.158  1.0
  F  F23  1  0.377  0.226  0.342  1.0
  F  F24  1  0.684  0.152  0.839  1.0
  F  F25  1  0.184  0.848  0.661  1.0
  F  F26  1  0.316  0.848  0.161  1.0
  F  F27  1  0.816  0.152  0.339  1.0
[/CIF]
.
The material structure described by AgZnF5 crystallizes in the monoclinic P2_1/c space group. Ag(1) is bonded to one F(1), one F(2), one F(3), one F(4), and two equivalent F(5) atoms to form corner-sharing AgF6 octahedra. The corner-sharing octahedral tilt angles are 39°. Zn(1) is bonded in a 4-coordinate geometry to one F(1), one F(2), one F(3), one F(4), and one F(5) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a distorted bent 120 degrees geometry to one Ag(1) and one Zn(1) atom. In the second F site, F(2) is bonded in a distorted bent 150 degrees geometry to one Ag(1) and one Zn(1) atom. In the third F site, F(3) is bonded in a bent 150 degrees geometry to one Ag(1) and one Zn(1) atom. In the fourth F site, F(4) is bonded in a linear geometry to one Ag(1) and one Zn(1) atom. In the fifth F site, F(5) is bonded in a 3-coordinate geometry to two equivalent Ag(1) and one Zn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZnAgF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.135
_cell_length_b   5.353
_cell_length_c   7.971
_cell_angle_alpha   69.054
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   403.898
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.003  0.515  0.752  1.0
  Zn  Zn1  1  0.503  0.485  0.748  1.0
  Zn  Zn2  1  0.997  0.485  0.248  1.0
  Zn  Zn3  1  0.497  0.515  0.252  1.0
  Ag  Ag4  1  0.754  0.104  0.601  1.0
  Ag  Ag5  1  0.254  0.896  0.899  1.0
  Ag  Ag6  1  0.246  0.896  0.399  1.0
  Ag  Ag7  1  0.746  0.104  0.101  1.0
  F  F8  1  0.895  0.406  0.573  1.0
  F  F9  1  0.395  0.594  0.927  1.0
  F  F10  1  0.105  0.594  0.427  1.0
  F  F11  1  0.605  0.406  0.073  1.0
  F  F12  1  0.602  0.369  0.490  1.0
  F  F13  1  0.102  0.631  0.010  1.0
  F  F14  1  0.398  0.631  0.510  1.0
  F  F15  1  0.898  0.369  0.990  1.0
  F  F16  1  0.413  0.152  0.803  1.0
  F  F17  1  0.913  0.848  0.697  1.0
  F  F18  1  0.587  0.848  0.197  1.0
  F  F19  1  0.087  0.152  0.303  1.0
  F  F20  1  0.123  0.226  0.842  1.0
  F  F21  1  0.623  0.774  0.658  1.0
  F  F22  1  0.877  0.774  0.158  1.0
  F  F23  1  0.377  0.226  0.342  1.0
  F  F24  1  0.684  0.152  0.839  1.0
  F  F25  1  0.184  0.848  0.661  1.0
  F  F26  1  0.316  0.848  0.161  1.0
  F  F27  1  0.816  0.152  0.339  1.0
[/CIF]
.