The crystal structure described by HoCoC6(N3O2)2 crystallizes in the orthorhombic Cmcm space group. Ho(1) is bonded in a 6-coordinate geometry to two equivalent N(2), four equivalent N(1), and two equivalent O(1) atoms. Co(1) is bonded in an octahedral geometry to two equivalent C(1) and four equivalent C(2) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Co(1) and one N(2) atom. In the second C site, C(2) is bonded in a linear geometry to one Co(1) and one N(1) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a linear geometry to one Ho(1) and one C(2) atom. In the second N site, N(2) is bonded in a linear geometry to one Ho(1) and one C(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Ho(1) and two equivalent O(2) atoms. In the second O site, O(2) is bonded in an L-shaped geometry to two equivalent O(1) atoms. is represented by the CIF card [CIF]
data_HoCoC6(N3O2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.371
_cell_length_b   7.466
_cell_length_c   12.952
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   119.580
_symmetry_Int_Tables_number   1
_cell_volume   619.923
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ho  Ho0  1  0.335  0.670  0.250  1.0
  Ho  Ho1  1  0.665  0.330  0.750  1.0
  Co  Co2  1  0.000  0.000  0.000  1.0
  Co  Co3  1  0.000  0.000  0.500  1.0
  C  C4  1  0.126  0.251  0.072  1.0
  C  C5  1  0.874  0.749  0.928  1.0
  C  C6  1  0.874  0.749  0.572  1.0
  C  C7  1  0.126  0.251  0.428  1.0
  C  C8  1  0.769  0.899  0.087  1.0
  C  C9  1  0.231  0.101  0.913  1.0
  C  C10  1  0.231  0.101  0.587  1.0
  C  C11  1  0.130  0.899  0.413  1.0
  C  C12  1  0.769  0.899  0.413  1.0
  C  C13  1  0.870  0.101  0.587  1.0
  C  C14  1  0.870  0.101  0.913  1.0
  C  C15  1  0.130  0.899  0.087  1.0
  N  N16  1  0.622  0.831  0.140  1.0
  N  N17  1  0.378  0.169  0.860  1.0
  N  N18  1  0.378  0.169  0.640  1.0
  N  N19  1  0.209  0.831  0.360  1.0
  N  N20  1  0.622  0.831  0.360  1.0
  N  N21  1  0.791  0.169  0.640  1.0
  N  N22  1  0.791  0.169  0.860  1.0
  N  N23  1  0.209  0.831  0.140  1.0
  N  N24  1  0.202  0.403  0.121  1.0
  N  N25  1  0.798  0.597  0.879  1.0
  N  N26  1  0.798  0.597  0.621  1.0
  N  N27  1  0.202  0.403  0.379  1.0
  O  O28  1  0.567  0.411  0.250  1.0
  O  O29  1  0.433  0.589  0.750  1.0
  O  O30  1  0.844  0.411  0.250  1.0
  O  O31  1  0.156  0.589  0.750  1.0
  O  O32  1  0.680  0.360  0.171  1.0
  O  O33  1  0.320  0.640  0.829  1.0
  O  O34  1  0.320  0.640  0.671  1.0
  O  O35  1  0.680  0.360  0.329  1.0
[/CIF]
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The crystal structure described by HoCoC6(N3O2)2 crystallizes in the orthorhombic Cmcm space group. Ho(1) is bonded in a 6-coordinate geometry to two equivalent N(2), four equivalent N(1), and two equivalent O(1) atoms. Co(1) is bonded in an octahedral geometry to two equivalent C(1) and four equivalent C(2) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Co(1) and one N(2) atom. In the second C site, C(2) is bonded in a linear geometry to one Co(1) and one N(1) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a linear geometry to one Ho(1) and one C(2) atom. In the second N site, N(2) is bonded in a linear geometry to one Ho(1) and one C(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Ho(1) and two equivalent O(2) atoms. In the second O site, O(2) is bonded in an L-shaped geometry to two equivalent O(1) atoms. is represented by the CIF card [CIF]
data_HoCoC6(N3O2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.371
_cell_length_b   7.466
_cell_length_c   12.952
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   119.580
_symmetry_Int_Tables_number   1
_cell_volume   619.923
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ho  Ho0  1  0.335  0.670  0.250  1.0
  Ho  Ho1  1  0.665  0.330  0.750  1.0
  Co  Co2  1  0.000  0.000  0.000  1.0
  Co  Co3  1  0.000  0.000  0.500  1.0
  C  C4  1  0.126  0.251  0.072  1.0
  C  C5  1  0.874  0.749  0.928  1.0
  C  C6  1  0.874  0.749  0.572  1.0
  C  C7  1  0.126  0.251  0.428  1.0
  C  C8  1  0.769  0.899  0.087  1.0
  C  C9  1  0.231  0.101  0.913  1.0
  C  C10  1  0.231  0.101  0.587  1.0
  C  C11  1  0.130  0.899  0.413  1.0
  C  C12  1  0.769  0.899  0.413  1.0
  C  C13  1  0.870  0.101  0.587  1.0
  C  C14  1  0.870  0.101  0.913  1.0
  C  C15  1  0.130  0.899  0.087  1.0
  N  N16  1  0.622  0.831  0.140  1.0
  N  N17  1  0.378  0.169  0.860  1.0
  N  N18  1  0.378  0.169  0.640  1.0
  N  N19  1  0.209  0.831  0.360  1.0
  N  N20  1  0.622  0.831  0.360  1.0
  N  N21  1  0.791  0.169  0.640  1.0
  N  N22  1  0.791  0.169  0.860  1.0
  N  N23  1  0.209  0.831  0.140  1.0
  N  N24  1  0.202  0.403  0.121  1.0
  N  N25  1  0.798  0.597  0.879  1.0
  N  N26  1  0.798  0.597  0.621  1.0
  N  N27  1  0.202  0.403  0.379  1.0
  O  O28  1  0.567  0.411  0.250  1.0
  O  O29  1  0.433  0.589  0.750  1.0
  O  O30  1  0.844  0.411  0.250  1.0
  O  O31  1  0.156  0.589  0.750  1.0
  O  O32  1  0.680  0.360  0.171  1.0
  O  O33  1  0.320  0.640  0.829  1.0
  O  O34  1  0.320  0.640  0.671  1.0
  O  O35  1  0.680  0.360  0.329  1.0
[/CIF]
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