The structure described by FeRh2S4 is Spinel structured and crystallizes in the cubic Fd-3m space group. Fe(1) is bonded to four equivalent S(1) atoms to form FeS4 tetrahedra that share corners with twelve equivalent Rh(1)S6 octahedra. The corner-sharing octahedral tilt angles are 58°. Rh(1) is bonded to six equivalent S(1) atoms to form RhS6 octahedra that share corners with six equivalent Fe(1)S4 tetrahedra and edges with six equivalent Rh(1)S6 octahedra. S(1) is bonded to one Fe(1) and three equivalent Rh(1) atoms to form a mixture of distorted corner and edge-sharing SFeRh3 trigonal pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_Fe(RhS2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.010
_cell_length_b   7.010
_cell_length_c   7.010
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   243.577
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.500  0.500  0.500  1.0
  Fe  Fe1  1  0.750  0.750  0.750  1.0
  Rh  Rh2  1  0.625  0.125  0.125  1.0
  Rh  Rh3  1  0.125  0.125  0.125  1.0
  Rh  Rh4  1  0.125  0.625  0.125  1.0
  Rh  Rh5  1  0.125  0.125  0.625  1.0
  S  S6  1  0.366  0.366  0.366  1.0
  S  S7  1  0.348  0.884  0.884  1.0
  S  S8  1  0.884  0.884  0.348  1.0
  S  S9  1  0.884  0.348  0.884  1.0
  S  S10  1  0.366  0.366  0.902  1.0
  S  S11  1  0.366  0.902  0.366  1.0
  S  S12  1  0.884  0.884  0.884  1.0
  S  S13  1  0.902  0.366  0.366  1.0
[/CIF]
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The structure described by FeRh2S4 is Spinel structured and crystallizes in the cubic Fd-3m space group. Fe(1) is bonded to four equivalent S(1) atoms to form FeS4 tetrahedra that share corners with twelve equivalent Rh(1)S6 octahedra. The corner-sharing octahedral tilt angles are 58°. Rh(1) is bonded to six equivalent S(1) atoms to form RhS6 octahedra that share corners with six equivalent Fe(1)S4 tetrahedra and edges with six equivalent Rh(1)S6 octahedra. S(1) is bonded to one Fe(1) and three equivalent Rh(1) atoms to form a mixture of distorted corner and edge-sharing SFeRh3 trigonal pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_Fe(RhS2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.010
_cell_length_b   7.010
_cell_length_c   7.010
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   243.577
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.500  0.500  0.500  1.0
  Fe  Fe1  1  0.750  0.750  0.750  1.0
  Rh  Rh2  1  0.625  0.125  0.125  1.0
  Rh  Rh3  1  0.125  0.125  0.125  1.0
  Rh  Rh4  1  0.125  0.625  0.125  1.0
  Rh  Rh5  1  0.125  0.125  0.625  1.0
  S  S6  1  0.366  0.366  0.366  1.0
  S  S7  1  0.348  0.884  0.884  1.0
  S  S8  1  0.884  0.884  0.348  1.0
  S  S9  1  0.884  0.348  0.884  1.0
  S  S10  1  0.366  0.366  0.902  1.0
  S  S11  1  0.366  0.902  0.366  1.0
  S  S12  1  0.884  0.884  0.884  1.0
  S  S13  1  0.902  0.366  0.366  1.0
[/CIF]
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