The material structure described by LiH4(NO2)3 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four LiH4(NO2)3 clusters. Li(1) is bonded in a rectangular see-saw-like geometry to two equivalent O(1) and two equivalent O(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to two equivalent N(2) atoms. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one N(1), one O(1), and one O(3) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(2) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Li(1) and one N(2) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Li(1), one H(1), and one H(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one N(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiH4(NO2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.424
_cell_length_b   7.424
_cell_length_c   6.921
_cell_angle_alpha   71.398
_cell_angle_beta   71.398
_cell_angle_gamma   63.014
_symmetry_Int_Tables_number   1
_cell_volume   315.277
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.926  0.074  0.750  1.0
  Li  Li1  1  0.074  0.926  0.250  1.0
  H  H2  1  0.316  0.903  0.774  1.0
  H  H3  1  0.684  0.097  0.226  1.0
  H  H4  1  0.097  0.684  0.726  1.0
  H  H5  1  0.903  0.316  0.274  1.0
  H  H6  1  0.230  0.131  0.797  1.0
  H  H7  1  0.770  0.869  0.203  1.0
  H  H8  1  0.869  0.770  0.703  1.0
  H  H9  1  0.131  0.230  0.297  1.0
  N  N10  1  0.472  0.528  0.750  1.0
  N  N11  1  0.528  0.472  0.250  1.0
  N  N12  1  0.468  0.341  0.762  1.0
  N  N13  1  0.532  0.659  0.238  1.0
  N  N14  1  0.659  0.532  0.738  1.0
  N  N15  1  0.341  0.468  0.262  1.0
  O  O16  1  0.617  0.172  0.759  1.0
  O  O17  1  0.383  0.828  0.241  1.0
  O  O18  1  0.828  0.383  0.741  1.0
  O  O19  1  0.172  0.617  0.259  1.0
  O  O20  1  0.188  0.018  0.815  1.0
  O  O21  1  0.812  0.982  0.185  1.0
  O  O22  1  0.982  0.812  0.685  1.0
  O  O23  1  0.018  0.188  0.315  1.0
  O  O24  1  0.637  0.714  0.726  1.0
  O  O25  1  0.363  0.286  0.274  1.0
  O  O26  1  0.286  0.363  0.774  1.0
  O  O27  1  0.714  0.637  0.226  1.0
[/CIF]
.
The material structure described by LiH4(NO2)3 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four LiH4(NO2)3 clusters. Li(1) is bonded in a rectangular see-saw-like geometry to two equivalent O(1) and two equivalent O(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to two equivalent N(2) atoms. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one N(1), one O(1), and one O(3) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(2) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Li(1) and one N(2) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Li(1), one H(1), and one H(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one N(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiH4(NO2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.424
_cell_length_b   7.424
_cell_length_c   6.921
_cell_angle_alpha   71.398
_cell_angle_beta   71.398
_cell_angle_gamma   63.014
_symmetry_Int_Tables_number   1
_cell_volume   315.277
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.926  0.074  0.750  1.0
  Li  Li1  1  0.074  0.926  0.250  1.0
  H  H2  1  0.316  0.903  0.774  1.0
  H  H3  1  0.684  0.097  0.226  1.0
  H  H4  1  0.097  0.684  0.726  1.0
  H  H5  1  0.903  0.316  0.274  1.0
  H  H6  1  0.230  0.131  0.797  1.0
  H  H7  1  0.770  0.869  0.203  1.0
  H  H8  1  0.869  0.770  0.703  1.0
  H  H9  1  0.131  0.230  0.297  1.0
  N  N10  1  0.472  0.528  0.750  1.0
  N  N11  1  0.528  0.472  0.250  1.0
  N  N12  1  0.468  0.341  0.762  1.0
  N  N13  1  0.532  0.659  0.238  1.0
  N  N14  1  0.659  0.532  0.738  1.0
  N  N15  1  0.341  0.468  0.262  1.0
  O  O16  1  0.617  0.172  0.759  1.0
  O  O17  1  0.383  0.828  0.241  1.0
  O  O18  1  0.828  0.383  0.741  1.0
  O  O19  1  0.172  0.617  0.259  1.0
  O  O20  1  0.188  0.018  0.815  1.0
  O  O21  1  0.812  0.982  0.185  1.0
  O  O22  1  0.982  0.812  0.685  1.0
  O  O23  1  0.018  0.188  0.315  1.0
  O  O24  1  0.637  0.714  0.726  1.0
  O  O25  1  0.363  0.286  0.274  1.0
  O  O26  1  0.286  0.363  0.774  1.0
  O  O27  1  0.714  0.637  0.226  1.0
[/CIF]
.