The crystal structure described by VO(PO3)2 crystallizes in the triclinic P-1 space group. V(1) is bonded to one O(1), one O(3), one O(5), one O(7), and two equivalent O(6) atoms to form VO6 octahedra that share corners with three equivalent P(1)O4 tetrahedra, corners with three equivalent P(2)O4 tetrahedra, and  an edgeedge with one V(1)O6 octahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(4), one O(5), and one O(7) atom to form PO4 tetrahedra that share corners with three equivalent V(1)O6 octahedra and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 34-46°. In the second P site, P(2) is bonded to one O(2), one O(3), one O(4), and one O(6) atom to form PO4 tetrahedra that share corners with three equivalent V(1)O6 octahedra and  a cornercorner with one P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 34-57°. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one V(1) and one P(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one P(2) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one V(1) and one P(2) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one P(1) and one P(2) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one V(1) and one P(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to two equivalent V(1) and one P(2) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one V(1) and one P(1) atom. is represented by the CIF card [CIF]
data_VP2O7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.273
_cell_length_b   6.393
_cell_length_c   6.887
_cell_angle_alpha   88.773
_cell_angle_beta   113.730
_cell_angle_gamma   94.974
_symmetry_Int_Tables_number   1
_cell_volume   251.865
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.093  0.353  0.204  1.0
  V  V1  1  0.907  0.647  0.796  1.0
  P  P2  1  0.337  0.614  0.647  1.0
  P  P3  1  0.663  0.386  0.353  1.0
  P  P4  1  0.237  0.866  0.246  1.0
  P  P5  1  0.763  0.134  0.754  1.0
  O  O6  1  0.402  0.386  0.208  1.0
  O  O7  1  0.560  0.102  0.811  1.0
  O  O8  1  0.440  0.898  0.189  1.0
  O  O9  1  0.906  0.944  0.776  1.0
  O  O10  1  0.301  0.807  0.492  1.0
  O  O11  1  0.203  0.647  0.787  1.0
  O  O12  1  0.060  0.669  0.120  1.0
  O  O13  1  0.598  0.614  0.792  1.0
  O  O14  1  0.699  0.193  0.508  1.0
  O  O15  1  0.238  0.413  0.512  1.0
  O  O16  1  0.094  0.056  0.224  1.0
  O  O17  1  0.940  0.331  0.880  1.0
  O  O18  1  0.797  0.353  0.213  1.0
  O  O19  1  0.762  0.587  0.488  1.0
[/CIF]
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The crystal structure described by VO(PO3)2 crystallizes in the triclinic P-1 space group. V(1) is bonded to one O(1), one O(3), one O(5), one O(7), and two equivalent O(6) atoms to form VO6 octahedra that share corners with three equivalent P(1)O4 tetrahedra, corners with three equivalent P(2)O4 tetrahedra, and  an edgeedge with one V(1)O6 octahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(4), one O(5), and one O(7) atom to form PO4 tetrahedra that share corners with three equivalent V(1)O6 octahedra and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 34-46°. In the second P site, P(2) is bonded to one O(2), one O(3), one O(4), and one O(6) atom to form PO4 tetrahedra that share corners with three equivalent V(1)O6 octahedra and  a cornercorner with one P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 34-57°. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one V(1) and one P(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one P(2) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one V(1) and one P(2) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one P(1) and one P(2) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one V(1) and one P(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to two equivalent V(1) and one P(2) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one V(1) and one P(1) atom. is represented by the CIF card [CIF]
data_VP2O7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.273
_cell_length_b   6.393
_cell_length_c   6.887
_cell_angle_alpha   88.773
_cell_angle_beta   113.730
_cell_angle_gamma   94.974
_symmetry_Int_Tables_number   1
_cell_volume   251.865
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.093  0.353  0.204  1.0
  V  V1  1  0.907  0.647  0.796  1.0
  P  P2  1  0.337  0.614  0.647  1.0
  P  P3  1  0.663  0.386  0.353  1.0
  P  P4  1  0.237  0.866  0.246  1.0
  P  P5  1  0.763  0.134  0.754  1.0
  O  O6  1  0.402  0.386  0.208  1.0
  O  O7  1  0.560  0.102  0.811  1.0
  O  O8  1  0.440  0.898  0.189  1.0
  O  O9  1  0.906  0.944  0.776  1.0
  O  O10  1  0.301  0.807  0.492  1.0
  O  O11  1  0.203  0.647  0.787  1.0
  O  O12  1  0.060  0.669  0.120  1.0
  O  O13  1  0.598  0.614  0.792  1.0
  O  O14  1  0.699  0.193  0.508  1.0
  O  O15  1  0.238  0.413  0.512  1.0
  O  O16  1  0.094  0.056  0.224  1.0
  O  O17  1  0.940  0.331  0.880  1.0
  O  O18  1  0.797  0.353  0.213  1.0
  O  O19  1  0.762  0.587  0.488  1.0
[/CIF]
.