The structure described by WN3F5 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four WN3F5 clusters. W(1) is bonded in an octahedral geometry to one N(3), one F(1), one F(2), one F(3), one F(4), and one F(5) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one N(2) atom. In the second N site, N(2) is bonded in a linear geometry to one N(1) and one N(3) atom. In the third N site, N(3) is bonded in a distorted linear geometry to one W(1) and one N(2) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one W(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one W(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one W(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one W(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one W(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_WN3F5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.026
_cell_length_b   5.480
_cell_length_c   11.314
_cell_angle_alpha   77.302
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   606.368
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  W  W0  1  0.536  0.850  0.787  1.0
  W  W1  1  0.036  0.150  0.713  1.0
  W  W2  1  0.464  0.150  0.213  1.0
  W  W3  1  0.964  0.850  0.287  1.0
  N  N4  1  0.837  0.403  0.993  1.0
  N  N5  1  0.337  0.597  0.507  1.0
  N  N6  1  0.163  0.597  0.007  1.0
  N  N7  1  0.663  0.403  0.493  1.0
  N  N8  1  0.250  0.478  0.052  1.0
  N  N9  1  0.750  0.522  0.448  1.0
  N  N10  1  0.656  0.648  0.902  1.0
  N  N11  1  0.156  0.352  0.598  1.0
  N  N12  1  0.344  0.352  0.098  1.0
  N  N13  1  0.844  0.648  0.402  1.0
  N  N14  1  0.750  0.522  0.948  1.0
  N  N15  1  0.250  0.478  0.552  1.0
  F  F16  1  0.632  0.146  0.792  1.0
  F  F17  1  0.574  0.429  0.220  1.0
  F  F18  1  0.926  0.429  0.720  1.0
  F  F19  1  0.074  0.571  0.280  1.0
  F  F20  1  0.079  0.914  0.410  1.0
  F  F21  1  0.579  0.086  0.090  1.0
  F  F22  1  0.921  0.086  0.590  1.0
  F  F23  1  0.421  0.914  0.910  1.0
  F  F24  1  0.859  0.794  0.156  1.0
  F  F25  1  0.359  0.206  0.344  1.0
  F  F26  1  0.141  0.206  0.844  1.0
  F  F27  1  0.641  0.794  0.656  1.0
  F  F28  1  0.368  0.854  0.208  1.0
  F  F29  1  0.868  0.146  0.292  1.0
  F  F30  1  0.424  0.048  0.669  1.0
  F  F31  1  0.924  0.952  0.831  1.0
  F  F32  1  0.576  0.952  0.331  1.0
  F  F33  1  0.076  0.048  0.169  1.0
  F  F34  1  0.426  0.571  0.780  1.0
  F  F35  1  0.132  0.854  0.708  1.0
[/CIF]
.
The structure described by WN3F5 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four WN3F5 clusters. W(1) is bonded in an octahedral geometry to one N(3), one F(1), one F(2), one F(3), one F(4), and one F(5) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one N(2) atom. In the second N site, N(2) is bonded in a linear geometry to one N(1) and one N(3) atom. In the third N site, N(3) is bonded in a distorted linear geometry to one W(1) and one N(2) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one W(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one W(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one W(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one W(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one W(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_WN3F5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.026
_cell_length_b   5.480
_cell_length_c   11.314
_cell_angle_alpha   77.302
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   606.368
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  W  W0  1  0.536  0.850  0.787  1.0
  W  W1  1  0.036  0.150  0.713  1.0
  W  W2  1  0.464  0.150  0.213  1.0
  W  W3  1  0.964  0.850  0.287  1.0
  N  N4  1  0.837  0.403  0.993  1.0
  N  N5  1  0.337  0.597  0.507  1.0
  N  N6  1  0.163  0.597  0.007  1.0
  N  N7  1  0.663  0.403  0.493  1.0
  N  N8  1  0.250  0.478  0.052  1.0
  N  N9  1  0.750  0.522  0.448  1.0
  N  N10  1  0.656  0.648  0.902  1.0
  N  N11  1  0.156  0.352  0.598  1.0
  N  N12  1  0.344  0.352  0.098  1.0
  N  N13  1  0.844  0.648  0.402  1.0
  N  N14  1  0.750  0.522  0.948  1.0
  N  N15  1  0.250  0.478  0.552  1.0
  F  F16  1  0.632  0.146  0.792  1.0
  F  F17  1  0.574  0.429  0.220  1.0
  F  F18  1  0.926  0.429  0.720  1.0
  F  F19  1  0.074  0.571  0.280  1.0
  F  F20  1  0.079  0.914  0.410  1.0
  F  F21  1  0.579  0.086  0.090  1.0
  F  F22  1  0.921  0.086  0.590  1.0
  F  F23  1  0.421  0.914  0.910  1.0
  F  F24  1  0.859  0.794  0.156  1.0
  F  F25  1  0.359  0.206  0.344  1.0
  F  F26  1  0.141  0.206  0.844  1.0
  F  F27  1  0.641  0.794  0.656  1.0
  F  F28  1  0.368  0.854  0.208  1.0
  F  F29  1  0.868  0.146  0.292  1.0
  F  F30  1  0.424  0.048  0.669  1.0
  F  F31  1  0.924  0.952  0.831  1.0
  F  F32  1  0.576  0.952  0.331  1.0
  F  F33  1  0.076  0.048  0.169  1.0
  F  F34  1  0.426  0.571  0.780  1.0
  F  F35  1  0.132  0.854  0.708  1.0
[/CIF]
.