The structure described by WZn2BiO6 crystallizes in the triclinic P1 space group. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), and one O(5) atom to form distorted WO5 trigonal bipyramids that share corners with three equivalent Zn(1)O4 tetrahedra and corners with four equivalent Bi(1)O5 trigonal bipyramids. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(2), one O(3), and one O(6) atom to form ZnO4 tetrahedra that share corners with three equivalent W(1)O5 trigonal bipyramids and corners with three equivalent Bi(1)O5 trigonal bipyramids. In the second Zn site, Zn(2) is bonded in a distorted rectangular see-saw-like geometry to one O(2), one O(4), one O(5), and one O(6) atom. Bi(1) is bonded to one O(1), one O(2), one O(4), one O(5), and one O(6) atom to form distorted BiO5 trigonal bipyramids that share corners with three equivalent Zn(1)O4 tetrahedra and corners with four equivalent W(1)O5 trigonal bipyramids. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one W(1), one Zn(1), and one Bi(1) atom. In the second O site, O(2) is bonded in a distorted see-saw-like geometry to one W(1), one Zn(1), one Zn(2), and one Bi(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one W(1) and one Zn(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one W(1), one Zn(2), and one Bi(1) atom. In the fifth O site, O(5) is bonded in a T-shaped geometry to one W(1), one Zn(2), and one Bi(1) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one Zn(1), one Zn(2), and one Bi(1) atom. is represented by the CIF file [CIF]
data_Zn2BiWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.492
_cell_length_b   5.533
_cell_length_c   5.670
_cell_angle_alpha   88.751
_cell_angle_beta   105.113
_cell_angle_gamma   113.134
_symmetry_Int_Tables_number   1
_cell_volume   152.335
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.622  0.374  0.879  1.0
  Zn  Zn1  1  0.687  0.852  0.462  1.0
  Bi  Bi2  1  0.024  0.488  0.490  1.0
  W  W3  1  0.022  0.015  0.993  1.0
  O  O4  1  0.957  0.663  0.119  1.0
  O  O5  1  0.789  0.165  0.748  1.0
  O  O6  1  0.370  0.269  0.098  1.0
  O  O7  1  0.816  0.071  0.218  1.0
  O  O8  1  0.048  0.858  0.689  1.0
  O  O9  1  0.457  0.561  0.607  1.0
[/CIF]
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The structure described by WZn2BiO6 crystallizes in the triclinic P1 space group. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), and one O(5) atom to form distorted WO5 trigonal bipyramids that share corners with three equivalent Zn(1)O4 tetrahedra and corners with four equivalent Bi(1)O5 trigonal bipyramids. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(2), one O(3), and one O(6) atom to form ZnO4 tetrahedra that share corners with three equivalent W(1)O5 trigonal bipyramids and corners with three equivalent Bi(1)O5 trigonal bipyramids. In the second Zn site, Zn(2) is bonded in a distorted rectangular see-saw-like geometry to one O(2), one O(4), one O(5), and one O(6) atom. Bi(1) is bonded to one O(1), one O(2), one O(4), one O(5), and one O(6) atom to form distorted BiO5 trigonal bipyramids that share corners with three equivalent Zn(1)O4 tetrahedra and corners with four equivalent W(1)O5 trigonal bipyramids. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one W(1), one Zn(1), and one Bi(1) atom. In the second O site, O(2) is bonded in a distorted see-saw-like geometry to one W(1), one Zn(1), one Zn(2), and one Bi(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one W(1) and one Zn(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one W(1), one Zn(2), and one Bi(1) atom. In the fifth O site, O(5) is bonded in a T-shaped geometry to one W(1), one Zn(2), and one Bi(1) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one Zn(1), one Zn(2), and one Bi(1) atom. is represented by the CIF file [CIF]
data_Zn2BiWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.492
_cell_length_b   5.533
_cell_length_c   5.670
_cell_angle_alpha   88.751
_cell_angle_beta   105.113
_cell_angle_gamma   113.134
_symmetry_Int_Tables_number   1
_cell_volume   152.335
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.622  0.374  0.879  1.0
  Zn  Zn1  1  0.687  0.852  0.462  1.0
  Bi  Bi2  1  0.024  0.488  0.490  1.0
  W  W3  1  0.022  0.015  0.993  1.0
  O  O4  1  0.957  0.663  0.119  1.0
  O  O5  1  0.789  0.165  0.748  1.0
  O  O6  1  0.370  0.269  0.098  1.0
  O  O7  1  0.816  0.071  0.218  1.0
  O  O8  1  0.048  0.858  0.689  1.0
  O  O9  1  0.457  0.561  0.607  1.0
[/CIF]
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