The crystal structure described by RbGe2N3 crystallizes in the orthorhombic Cmc2_1 space group. Rb(1) is bonded in a 10-coordinate geometry to four equivalent N(2) and six equivalent N(1) atoms. Ge(1) is bonded to one N(2) and three equivalent N(1) atoms to form corner-sharing GeN4 tetrahedra. There are two inequivalent N sites. In the first N site, N(2) is bonded in a 2-coordinate geometry to four equivalent Rb(1) and two equivalent Ge(1) atoms. In the second N site, N(1) is bonded in a distorted trigonal planar geometry to three equivalent Rb(1) and three equivalent Ge(1) atoms. is represented by the CIF card [CIF]
data_RbGe2N3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.922
_cell_length_b   5.922
_cell_length_c   5.387
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   118.148
_symmetry_Int_Tables_number   1
_cell_volume   166.576
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.348  0.348  0.519  1.0
  Rb  Rb1  1  0.652  0.652  0.019  1.0
  Ge  Ge2  1  0.686  0.034  0.507  1.0
  Ge  Ge3  1  0.034  0.686  0.507  1.0
  Ge  Ge4  1  0.314  0.966  0.007  1.0
  Ge  Ge5  1  0.966  0.314  0.007  1.0
  N  N6  1  0.642  0.124  0.174  1.0
  N  N7  1  0.124  0.642  0.174  1.0
  N  N8  1  0.358  0.876  0.674  1.0
  N  N9  1  0.876  0.358  0.674  1.0
  N  N10  1  0.184  0.184  0.030  1.0
  N  N11  1  0.816  0.816  0.530  1.0
[/CIF]
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The crystal structure described by RbGe2N3 crystallizes in the orthorhombic Cmc2_1 space group. Rb(1) is bonded in a 10-coordinate geometry to four equivalent N(2) and six equivalent N(1) atoms. Ge(1) is bonded to one N(2) and three equivalent N(1) atoms to form corner-sharing GeN4 tetrahedra. There are two inequivalent N sites. In the first N site, N(2) is bonded in a 2-coordinate geometry to four equivalent Rb(1) and two equivalent Ge(1) atoms. In the second N site, N(1) is bonded in a distorted trigonal planar geometry to three equivalent Rb(1) and three equivalent Ge(1) atoms. is represented by the CIF card [CIF]
data_RbGe2N3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.922
_cell_length_b   5.922
_cell_length_c   5.387
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   118.148
_symmetry_Int_Tables_number   1
_cell_volume   166.576
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.348  0.348  0.519  1.0
  Rb  Rb1  1  0.652  0.652  0.019  1.0
  Ge  Ge2  1  0.686  0.034  0.507  1.0
  Ge  Ge3  1  0.034  0.686  0.507  1.0
  Ge  Ge4  1  0.314  0.966  0.007  1.0
  Ge  Ge5  1  0.966  0.314  0.007  1.0
  N  N6  1  0.642  0.124  0.174  1.0
  N  N7  1  0.124  0.642  0.174  1.0
  N  N8  1  0.358  0.876  0.674  1.0
  N  N9  1  0.876  0.358  0.674  1.0
  N  N10  1  0.184  0.184  0.030  1.0
  N  N11  1  0.816  0.816  0.530  1.0
[/CIF]
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