The compound described by K5Mo4O14F crystallizes in the monoclinic C2/c space group. There are three inequivalent K sites. In the first K site, K(1) is bonded in a 8-coordinate geometry to one O(3), one O(6), one O(7), two equivalent O(4), and three equivalent O(5) atoms. In the second K site, K(2) is bonded in a 10-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(7), and four equivalent O(3) atoms. In the third K site, K(3) is bonded in a 9-coordinate geometry to one O(5), one O(7), two equivalent O(2), two equivalent O(4), two equivalent O(6), and one F(1) atom. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a tetrahedral geometry to one O(1), one O(5), one O(6), and one O(7) atom. In the second Mo site, Mo(2) is bonded in a 6-coordinate geometry to one O(2), one O(3), one O(4), two equivalent O(1), and one F(1) atom. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one K(2), one Mo(1), and two equivalent Mo(2) atoms. In the second O site, O(2) is bonded in a distorted single-bond geometry to one K(2), two equivalent K(3), and one Mo(2) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one K(1), two equivalent K(2), and one Mo(2) atom. In the fourth O site, O(4) is bonded in a 1-coordinate geometry to two equivalent K(1), two equivalent K(3), and one Mo(2) atom. In the fifth O site, O(5) is bonded in a 1-coordinate geometry to one K(3), three equivalent K(1), and one Mo(1) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one K(1), two equivalent K(3), and one Mo(1) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one K(1), one K(2), one K(3), and one Mo(1) atom. F(1) is bonded in a distorted trigonal pyramidal geometry to two equivalent K(3) and two equivalent Mo(2) atoms. is represented by the CIF card [CIF]
data_K5Mo4O14F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.620
_cell_length_b   10.620
_cell_length_c   8.633
_cell_angle_alpha   83.108
_cell_angle_beta   83.108
_cell_angle_gamma   61.812
_symmetry_Int_Tables_number   1
_cell_volume   849.831
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.323  0.117  0.909  1.0
  K  K1  1  0.883  0.677  0.591  1.0
  K  K2  1  0.677  0.883  0.091  1.0
  K  K3  1  0.117  0.323  0.409  1.0
  K  K4  1  0.059  0.941  0.750  1.0
  K  K5  1  0.941  0.059  0.250  1.0
  K  K6  1  0.682  0.546  0.228  1.0
  K  K7  1  0.454  0.318  0.272  1.0
  K  K8  1  0.318  0.454  0.772  1.0
  K  K9  1  0.546  0.682  0.728  1.0
  Mo  Mo10  1  0.369  0.933  0.396  1.0
  Mo  Mo11  1  0.067  0.631  0.104  1.0
  Mo  Mo12  1  0.631  0.067  0.604  1.0
  Mo  Mo13  1  0.933  0.369  0.896  1.0
  Mo  Mo14  1  0.207  0.698  0.429  1.0
  Mo  Mo15  1  0.302  0.793  0.071  1.0
  Mo  Mo16  1  0.793  0.302  0.571  1.0
  Mo  Mo17  1  0.698  0.207  0.929  1.0
  O  O18  1  0.249  0.874  0.309  1.0
  O  O19  1  0.126  0.751  0.191  1.0
  O  O20  1  0.751  0.126  0.691  1.0
  O  O21  1  0.874  0.249  0.809  1.0
  O  O22  1  0.323  0.679  0.571  1.0
  O  O23  1  0.321  0.677  0.929  1.0
  O  O24  1  0.677  0.321  0.429  1.0
  O  O25  1  0.679  0.323  0.071  1.0
  O  O26  1  0.035  0.822  0.505  1.0
  O  O27  1  0.178  0.965  0.995  1.0
  O  O28  1  0.965  0.178  0.495  1.0
  O  O29  1  0.822  0.035  0.005  1.0
  O  O30  1  0.197  0.533  0.450  1.0
  O  O31  1  0.467  0.803  0.050  1.0
  O  O32  1  0.803  0.467  0.550  1.0
  O  O33  1  0.533  0.197  0.950  1.0
  O  O34  1  0.364  0.085  0.278  1.0
  O  O35  1  0.915  0.636  0.222  1.0
  O  O36  1  0.636  0.915  0.722  1.0
  O  O37  1  0.085  0.364  0.778  1.0
  O  O38  1  0.549  0.797  0.400  1.0
  O  O39  1  0.203  0.451  0.100  1.0
  O  O40  1  0.451  0.203  0.600  1.0
  O  O41  1  0.797  0.549  0.900  1.0
  O  O42  1  0.303  0.984  0.589  1.0
  O  O43  1  0.016  0.697  0.911  1.0
  O  O44  1  0.697  0.016  0.411  1.0
  O  O45  1  0.984  0.303  0.089  1.0
  F  F46  1  0.392  0.608  0.250  1.0
  F  F47  1  0.608  0.392  0.750  1.0
[/CIF]
.
The compound described by K5Mo4O14F crystallizes in the monoclinic C2/c space group. There are three inequivalent K sites. In the first K site, K(1) is bonded in a 8-coordinate geometry to one O(3), one O(6), one O(7), two equivalent O(4), and three equivalent O(5) atoms. In the second K site, K(2) is bonded in a 10-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(7), and four equivalent O(3) atoms. In the third K site, K(3) is bonded in a 9-coordinate geometry to one O(5), one O(7), two equivalent O(2), two equivalent O(4), two equivalent O(6), and one F(1) atom. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a tetrahedral geometry to one O(1), one O(5), one O(6), and one O(7) atom. In the second Mo site, Mo(2) is bonded in a 6-coordinate geometry to one O(2), one O(3), one O(4), two equivalent O(1), and one F(1) atom. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one K(2), one Mo(1), and two equivalent Mo(2) atoms. In the second O site, O(2) is bonded in a distorted single-bond geometry to one K(2), two equivalent K(3), and one Mo(2) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one K(1), two equivalent K(2), and one Mo(2) atom. In the fourth O site, O(4) is bonded in a 1-coordinate geometry to two equivalent K(1), two equivalent K(3), and one Mo(2) atom. In the fifth O site, O(5) is bonded in a 1-coordinate geometry to one K(3), three equivalent K(1), and one Mo(1) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one K(1), two equivalent K(3), and one Mo(1) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one K(1), one K(2), one K(3), and one Mo(1) atom. F(1) is bonded in a distorted trigonal pyramidal geometry to two equivalent K(3) and two equivalent Mo(2) atoms. is represented by the CIF card [CIF]
data_K5Mo4O14F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.620
_cell_length_b   10.620
_cell_length_c   8.633
_cell_angle_alpha   83.108
_cell_angle_beta   83.108
_cell_angle_gamma   61.812
_symmetry_Int_Tables_number   1
_cell_volume   849.831
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.323  0.117  0.909  1.0
  K  K1  1  0.883  0.677  0.591  1.0
  K  K2  1  0.677  0.883  0.091  1.0
  K  K3  1  0.117  0.323  0.409  1.0
  K  K4  1  0.059  0.941  0.750  1.0
  K  K5  1  0.941  0.059  0.250  1.0
  K  K6  1  0.682  0.546  0.228  1.0
  K  K7  1  0.454  0.318  0.272  1.0
  K  K8  1  0.318  0.454  0.772  1.0
  K  K9  1  0.546  0.682  0.728  1.0
  Mo  Mo10  1  0.369  0.933  0.396  1.0
  Mo  Mo11  1  0.067  0.631  0.104  1.0
  Mo  Mo12  1  0.631  0.067  0.604  1.0
  Mo  Mo13  1  0.933  0.369  0.896  1.0
  Mo  Mo14  1  0.207  0.698  0.429  1.0
  Mo  Mo15  1  0.302  0.793  0.071  1.0
  Mo  Mo16  1  0.793  0.302  0.571  1.0
  Mo  Mo17  1  0.698  0.207  0.929  1.0
  O  O18  1  0.249  0.874  0.309  1.0
  O  O19  1  0.126  0.751  0.191  1.0
  O  O20  1  0.751  0.126  0.691  1.0
  O  O21  1  0.874  0.249  0.809  1.0
  O  O22  1  0.323  0.679  0.571  1.0
  O  O23  1  0.321  0.677  0.929  1.0
  O  O24  1  0.677  0.321  0.429  1.0
  O  O25  1  0.679  0.323  0.071  1.0
  O  O26  1  0.035  0.822  0.505  1.0
  O  O27  1  0.178  0.965  0.995  1.0
  O  O28  1  0.965  0.178  0.495  1.0
  O  O29  1  0.822  0.035  0.005  1.0
  O  O30  1  0.197  0.533  0.450  1.0
  O  O31  1  0.467  0.803  0.050  1.0
  O  O32  1  0.803  0.467  0.550  1.0
  O  O33  1  0.533  0.197  0.950  1.0
  O  O34  1  0.364  0.085  0.278  1.0
  O  O35  1  0.915  0.636  0.222  1.0
  O  O36  1  0.636  0.915  0.722  1.0
  O  O37  1  0.085  0.364  0.778  1.0
  O  O38  1  0.549  0.797  0.400  1.0
  O  O39  1  0.203  0.451  0.100  1.0
  O  O40  1  0.451  0.203  0.600  1.0
  O  O41  1  0.797  0.549  0.900  1.0
  O  O42  1  0.303  0.984  0.589  1.0
  O  O43  1  0.016  0.697  0.911  1.0
  O  O44  1  0.697  0.016  0.411  1.0
  O  O45  1  0.984  0.303  0.089  1.0
  F  F46  1  0.392  0.608  0.250  1.0
  F  F47  1  0.608  0.392  0.750  1.0
[/CIF]
.