The crystal structure described by XeAsF7 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four XeAsF7 clusters. Xe(1) is bonded in a linear geometry to one F(1) and one F(2) atom. As(1) is bonded in an octahedral geometry to one F(2), one F(3), one F(4), one F(5), one F(6), and one F(7) atom. There are seven inequivalent F sites. In the first F site, F(7) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Xe(1) atom. In the third F site, F(2) is bonded in a bent 120 degrees geometry to one Xe(1) and one As(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the seventh F site, F(6) is bonded in a single-bond geometry to one As(1) atom. is represented by the CIF file [CIF]
data_AsXeF7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.161
_cell_length_b   6.248
_cell_length_c   15.837
_cell_angle_alpha   79.889
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   600.149
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.720  0.144  0.611  1.0
  As  As1  1  0.220  0.856  0.889  1.0
  As  As2  1  0.280  0.856  0.389  1.0
  As  As3  1  0.780  0.144  0.111  1.0
  Xe  Xe4  1  0.787  0.364  0.377  1.0
  Xe  Xe5  1  0.287  0.636  0.123  1.0
  Xe  Xe6  1  0.213  0.636  0.623  1.0
  Xe  Xe7  1  0.713  0.364  0.877  1.0
  F  F8  1  0.894  0.550  0.272  1.0
  F  F9  1  0.394  0.450  0.228  1.0
  F  F10  1  0.106  0.450  0.728  1.0
  F  F11  1  0.606  0.550  0.772  1.0
  F  F12  1  0.659  0.150  0.493  1.0
  F  F13  1  0.159  0.850  0.007  1.0
  F  F14  1  0.341  0.850  0.507  1.0
  F  F15  1  0.841  0.150  0.993  1.0
  F  F16  1  0.786  0.865  0.120  1.0
  F  F17  1  0.286  0.135  0.380  1.0
  F  F18  1  0.214  0.135  0.880  1.0
  F  F19  1  0.714  0.865  0.620  1.0
  F  F20  1  0.057  0.150  0.124  1.0
  F  F21  1  0.557  0.850  0.376  1.0
  F  F22  1  0.943  0.850  0.876  1.0
  F  F23  1  0.443  0.150  0.624  1.0
  F  F24  1  0.726  0.136  0.218  1.0
  F  F25  1  0.226  0.864  0.282  1.0
  F  F26  1  0.274  0.864  0.782  1.0
  F  F27  1  0.774  0.136  0.718  1.0
  F  F28  1  0.778  0.426  0.086  1.0
  F  F29  1  0.278  0.574  0.414  1.0
  F  F30  1  0.222  0.574  0.914  1.0
  F  F31  1  0.722  0.426  0.586  1.0
  F  F32  1  0.508  0.145  0.082  1.0
  F  F33  1  0.008  0.855  0.418  1.0
  F  F34  1  0.492  0.855  0.918  1.0
  F  F35  1  0.992  0.145  0.582  1.0
[/CIF]
.
The crystal structure described by XeAsF7 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four XeAsF7 clusters. Xe(1) is bonded in a linear geometry to one F(1) and one F(2) atom. As(1) is bonded in an octahedral geometry to one F(2), one F(3), one F(4), one F(5), one F(6), and one F(7) atom. There are seven inequivalent F sites. In the first F site, F(7) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Xe(1) atom. In the third F site, F(2) is bonded in a bent 120 degrees geometry to one Xe(1) and one As(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the seventh F site, F(6) is bonded in a single-bond geometry to one As(1) atom. is represented by the CIF file [CIF]
data_AsXeF7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.161
_cell_length_b   6.248
_cell_length_c   15.837
_cell_angle_alpha   79.889
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   600.149
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.720  0.144  0.611  1.0
  As  As1  1  0.220  0.856  0.889  1.0
  As  As2  1  0.280  0.856  0.389  1.0
  As  As3  1  0.780  0.144  0.111  1.0
  Xe  Xe4  1  0.787  0.364  0.377  1.0
  Xe  Xe5  1  0.287  0.636  0.123  1.0
  Xe  Xe6  1  0.213  0.636  0.623  1.0
  Xe  Xe7  1  0.713  0.364  0.877  1.0
  F  F8  1  0.894  0.550  0.272  1.0
  F  F9  1  0.394  0.450  0.228  1.0
  F  F10  1  0.106  0.450  0.728  1.0
  F  F11  1  0.606  0.550  0.772  1.0
  F  F12  1  0.659  0.150  0.493  1.0
  F  F13  1  0.159  0.850  0.007  1.0
  F  F14  1  0.341  0.850  0.507  1.0
  F  F15  1  0.841  0.150  0.993  1.0
  F  F16  1  0.786  0.865  0.120  1.0
  F  F17  1  0.286  0.135  0.380  1.0
  F  F18  1  0.214  0.135  0.880  1.0
  F  F19  1  0.714  0.865  0.620  1.0
  F  F20  1  0.057  0.150  0.124  1.0
  F  F21  1  0.557  0.850  0.376  1.0
  F  F22  1  0.943  0.850  0.876  1.0
  F  F23  1  0.443  0.150  0.624  1.0
  F  F24  1  0.726  0.136  0.218  1.0
  F  F25  1  0.226  0.864  0.282  1.0
  F  F26  1  0.274  0.864  0.782  1.0
  F  F27  1  0.774  0.136  0.718  1.0
  F  F28  1  0.778  0.426  0.086  1.0
  F  F29  1  0.278  0.574  0.414  1.0
  F  F30  1  0.222  0.574  0.914  1.0
  F  F31  1  0.722  0.426  0.586  1.0
  F  F32  1  0.508  0.145  0.082  1.0
  F  F33  1  0.008  0.855  0.418  1.0
  F  F34  1  0.492  0.855  0.918  1.0
  F  F35  1  0.992  0.145  0.582  1.0
[/CIF]
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