The material described by Ag3P3O10 crystallizes in the monoclinic C2/m space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted rectangular see-saw-like geometry to one O(3), one O(4), one O(5), and one O(7) atom. In the second Ag site, Ag(2) is bonded in a distorted rectangular see-saw-like geometry to two equivalent O(4) and two equivalent O(6) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form corner-sharing PO4 tetrahedra. In the second P site, P(2) is bonded to one O(5), one O(6), and two equivalent O(2) atoms to form corner-sharing PO4 tetrahedra. There are seven inequivalent O sites. In the first O site, O(4) is bonded in a distorted single-bond geometry to one Ag(1), one Ag(2), and one P(1) atom. In the second O site, O(5) is bonded in a distorted single-bond geometry to two equivalent Ag(1) and one P(2) atom. In the third O site, O(6) is bonded in a distorted single-bond geometry to two equivalent Ag(2) and one P(2) atom. In the fourth O site, O(7) is bonded in a bent 120 degrees geometry to two equivalent Ag(1) atoms. In the fifth O site, O(1) is bonded in a distorted bent 120 degrees geometry to two equivalent P(1) atoms. In the sixth O site, O(2) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the seventh O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Ag(1) and one P(1) atom. is represented by the CIF card [CIF]
data_Ag3P3O10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.896
_cell_length_b   7.896
_cell_length_c   9.237
_cell_angle_alpha   64.767
_cell_angle_beta   64.767
_cell_angle_gamma   85.563
_symmetry_Int_Tables_number   1
_cell_volume   467.389
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.005  0.327  0.950  1.0
  Ag  Ag1  1  0.673  0.995  0.050  1.0
  Ag  Ag2  1  0.995  0.673  0.050  1.0
  Ag  Ag3  1  0.327  0.005  0.950  1.0
  Ag  Ag4  1  0.174  0.826  0.500  1.0
  Ag  Ag5  1  0.826  0.174  0.500  1.0
  P  P6  1  0.438  0.715  0.736  1.0
  P  P7  1  0.285  0.562  0.264  1.0
  P  P8  1  0.562  0.285  0.264  1.0
  P  P9  1  0.715  0.438  0.736  1.0
  P  P10  1  0.785  0.785  0.419  1.0
  P  P11  1  0.215  0.215  0.581  1.0
  O  O12  1  0.514  0.514  0.806  1.0
  O  O13  1  0.486  0.486  0.194  1.0
  O  O14  1  0.561  0.796  0.521  1.0
  O  O15  1  0.204  0.439  0.479  1.0
  O  O16  1  0.439  0.204  0.479  1.0
  O  O17  1  0.796  0.561  0.521  1.0
  O  O18  1  0.484  0.842  0.800  1.0
  O  O19  1  0.158  0.516  0.200  1.0
  O  O20  1  0.516  0.158  0.200  1.0
  O  O21  1  0.842  0.484  0.800  1.0
  O  O22  1  0.235  0.677  0.770  1.0
  O  O23  1  0.323  0.765  0.230  1.0
  O  O24  1  0.765  0.323  0.230  1.0
  O  O25  1  0.677  0.235  0.770  1.0
  O  O26  1  0.822  0.822  0.233  1.0
  O  O27  1  0.178  0.178  0.767  1.0
  O  O28  1  0.899  0.899  0.448  1.0
  O  O29  1  0.101  0.101  0.552  1.0
  O  O30  1  0.823  0.823  0.941  1.0
  O  O31  1  0.177  0.177  0.059  1.0
[/CIF]
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The material described by Ag3P3O10 crystallizes in the monoclinic C2/m space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted rectangular see-saw-like geometry to one O(3), one O(4), one O(5), and one O(7) atom. In the second Ag site, Ag(2) is bonded in a distorted rectangular see-saw-like geometry to two equivalent O(4) and two equivalent O(6) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form corner-sharing PO4 tetrahedra. In the second P site, P(2) is bonded to one O(5), one O(6), and two equivalent O(2) atoms to form corner-sharing PO4 tetrahedra. There are seven inequivalent O sites. In the first O site, O(4) is bonded in a distorted single-bond geometry to one Ag(1), one Ag(2), and one P(1) atom. In the second O site, O(5) is bonded in a distorted single-bond geometry to two equivalent Ag(1) and one P(2) atom. In the third O site, O(6) is bonded in a distorted single-bond geometry to two equivalent Ag(2) and one P(2) atom. In the fourth O site, O(7) is bonded in a bent 120 degrees geometry to two equivalent Ag(1) atoms. In the fifth O site, O(1) is bonded in a distorted bent 120 degrees geometry to two equivalent P(1) atoms. In the sixth O site, O(2) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the seventh O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Ag(1) and one P(1) atom. is represented by the CIF card [CIF]
data_Ag3P3O10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.896
_cell_length_b   7.896
_cell_length_c   9.237
_cell_angle_alpha   64.767
_cell_angle_beta   64.767
_cell_angle_gamma   85.563
_symmetry_Int_Tables_number   1
_cell_volume   467.389
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.005  0.327  0.950  1.0
  Ag  Ag1  1  0.673  0.995  0.050  1.0
  Ag  Ag2  1  0.995  0.673  0.050  1.0
  Ag  Ag3  1  0.327  0.005  0.950  1.0
  Ag  Ag4  1  0.174  0.826  0.500  1.0
  Ag  Ag5  1  0.826  0.174  0.500  1.0
  P  P6  1  0.438  0.715  0.736  1.0
  P  P7  1  0.285  0.562  0.264  1.0
  P  P8  1  0.562  0.285  0.264  1.0
  P  P9  1  0.715  0.438  0.736  1.0
  P  P10  1  0.785  0.785  0.419  1.0
  P  P11  1  0.215  0.215  0.581  1.0
  O  O12  1  0.514  0.514  0.806  1.0
  O  O13  1  0.486  0.486  0.194  1.0
  O  O14  1  0.561  0.796  0.521  1.0
  O  O15  1  0.204  0.439  0.479  1.0
  O  O16  1  0.439  0.204  0.479  1.0
  O  O17  1  0.796  0.561  0.521  1.0
  O  O18  1  0.484  0.842  0.800  1.0
  O  O19  1  0.158  0.516  0.200  1.0
  O  O20  1  0.516  0.158  0.200  1.0
  O  O21  1  0.842  0.484  0.800  1.0
  O  O22  1  0.235  0.677  0.770  1.0
  O  O23  1  0.323  0.765  0.230  1.0
  O  O24  1  0.765  0.323  0.230  1.0
  O  O25  1  0.677  0.235  0.770  1.0
  O  O26  1  0.822  0.822  0.233  1.0
  O  O27  1  0.178  0.178  0.767  1.0
  O  O28  1  0.899  0.899  0.448  1.0
  O  O29  1  0.101  0.101  0.552  1.0
  O  O30  1  0.823  0.823  0.941  1.0
  O  O31  1  0.177  0.177  0.059  1.0
[/CIF]
.