The material structure described by AuTe4(OF5)4 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one AuTe4(OF5)4 cluster. Au(1) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent O(2) atoms. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in an octahedral geometry to one O(1), one F(1), one F(3), one F(5), one F(7), and one F(9) atom. In the second Te site, Te(2) is bonded in an octahedral geometry to one O(2), one F(10), one F(2), one F(4), one F(6), and one F(8) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Au(1) and one Te(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Au(1) and one Te(2) atom. There are ten inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Te(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Te(2) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Te(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Te(2) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Te(1) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one Te(2) atom. In the seventh F site, F(7) is bonded in a single-bond geometry to one Te(1) atom. In the eighth F site, F(8) is bonded in a single-bond geometry to one Te(2) atom. In the ninth F site, F(9) is bonded in a single-bond geometry to one Te(1) atom. In the tenth F site, F(10) is bonded in a single-bond geometry to one Te(2) atom. is represented by the CIF card [CIF]
data_Te4Au(OF5)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.823
_cell_length_b   8.815
_cell_length_c   10.525
_cell_angle_alpha   113.791
_cell_angle_beta   92.752
_cell_angle_gamma   93.447
_symmetry_Int_Tables_number   1
_cell_volume   491.952
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.745  0.368  0.255  1.0
  Te  Te1  1  0.741  0.112  0.747  1.0
  Te  Te2  1  0.255  0.632  0.745  1.0
  Te  Te3  1  0.259  0.888  0.253  1.0
  Au  Au4  1  0.500  0.000  0.000  1.0
  O  O5  1  0.750  0.130  0.146  1.0
  O  O6  1  0.715  0.978  0.854  1.0
  O  O7  1  0.250  0.870  0.854  1.0
  O  O8  1  0.285  0.022  0.146  1.0
  F  F9  1  0.590  0.329  0.392  1.0
  F  F10  1  0.891  0.943  0.618  1.0
  F  F11  1  0.410  0.671  0.608  1.0
  F  F12  1  0.109  0.057  0.382  1.0
  F  F13  1  0.911  0.412  0.123  1.0
  F  F14  1  0.589  0.285  0.876  1.0
  F  F15  1  0.089  0.588  0.877  1.0
  F  F16  1  0.411  0.715  0.124  1.0
  F  F17  1  0.462  0.371  0.161  1.0
  F  F18  1  0.029  0.209  0.842  1.0
  F  F19  1  0.538  0.629  0.839  1.0
  F  F20  1  0.971  0.791  0.158  1.0
  F  F21  1  0.025  0.369  0.349  1.0
  F  F22  1  0.458  0.017  0.644  1.0
  F  F23  1  0.975  0.631  0.651  1.0
  F  F24  1  0.542  0.983  0.356  1.0
  F  F25  1  0.738  0.596  0.357  1.0
  F  F26  1  0.775  0.240  0.643  1.0
  F  F27  1  0.262  0.404  0.643  1.0
  F  F28  1  0.225  0.760  0.357  1.0
[/CIF]
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The material structure described by AuTe4(OF5)4 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one AuTe4(OF5)4 cluster. Au(1) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent O(2) atoms. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in an octahedral geometry to one O(1), one F(1), one F(3), one F(5), one F(7), and one F(9) atom. In the second Te site, Te(2) is bonded in an octahedral geometry to one O(2), one F(10), one F(2), one F(4), one F(6), and one F(8) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Au(1) and one Te(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Au(1) and one Te(2) atom. There are ten inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Te(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Te(2) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Te(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Te(2) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Te(1) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one Te(2) atom. In the seventh F site, F(7) is bonded in a single-bond geometry to one Te(1) atom. In the eighth F site, F(8) is bonded in a single-bond geometry to one Te(2) atom. In the ninth F site, F(9) is bonded in a single-bond geometry to one Te(1) atom. In the tenth F site, F(10) is bonded in a single-bond geometry to one Te(2) atom. is represented by the CIF card [CIF]
data_Te4Au(OF5)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.823
_cell_length_b   8.815
_cell_length_c   10.525
_cell_angle_alpha   113.791
_cell_angle_beta   92.752
_cell_angle_gamma   93.447
_symmetry_Int_Tables_number   1
_cell_volume   491.952
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.745  0.368  0.255  1.0
  Te  Te1  1  0.741  0.112  0.747  1.0
  Te  Te2  1  0.255  0.632  0.745  1.0
  Te  Te3  1  0.259  0.888  0.253  1.0
  Au  Au4  1  0.500  0.000  0.000  1.0
  O  O5  1  0.750  0.130  0.146  1.0
  O  O6  1  0.715  0.978  0.854  1.0
  O  O7  1  0.250  0.870  0.854  1.0
  O  O8  1  0.285  0.022  0.146  1.0
  F  F9  1  0.590  0.329  0.392  1.0
  F  F10  1  0.891  0.943  0.618  1.0
  F  F11  1  0.410  0.671  0.608  1.0
  F  F12  1  0.109  0.057  0.382  1.0
  F  F13  1  0.911  0.412  0.123  1.0
  F  F14  1  0.589  0.285  0.876  1.0
  F  F15  1  0.089  0.588  0.877  1.0
  F  F16  1  0.411  0.715  0.124  1.0
  F  F17  1  0.462  0.371  0.161  1.0
  F  F18  1  0.029  0.209  0.842  1.0
  F  F19  1  0.538  0.629  0.839  1.0
  F  F20  1  0.971  0.791  0.158  1.0
  F  F21  1  0.025  0.369  0.349  1.0
  F  F22  1  0.458  0.017  0.644  1.0
  F  F23  1  0.975  0.631  0.651  1.0
  F  F24  1  0.542  0.983  0.356  1.0
  F  F25  1  0.738  0.596  0.357  1.0
  F  F26  1  0.775  0.240  0.643  1.0
  F  F27  1  0.262  0.404  0.643  1.0
  F  F28  1  0.225  0.760  0.357  1.0
[/CIF]
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