The structure described by CsClO4 crystallizes in the orthorhombic Pnma space group. Cs(1) is bonded in a 12-coordinate geometry to three equivalent O(1), three equivalent O(3), and six equivalent O(2) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to three equivalent Cs(1) and one Cl(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to three equivalent Cs(1) and one Cl(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to three equivalent Cs(1) and one Cl(1) atom. Cl(1) is bonded in a tetrahedral geometry to one O(1), one O(3), and two equivalent O(2) atoms. is represented by the CIF file [CIF]
data_CsClO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.968
_cell_length_b   7.833
_cell_length_c   9.821
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   459.135
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.250  0.339  0.688  1.0
  Cs  Cs1  1  0.750  0.661  0.312  1.0
  Cs  Cs2  1  0.750  0.839  0.812  1.0
  Cs  Cs3  1  0.250  0.161  0.188  1.0
  Cl  Cl4  1  0.250  0.697  0.057  1.0
  Cl  Cl5  1  0.750  0.303  0.943  1.0
  Cl  Cl6  1  0.750  0.197  0.443  1.0
  Cl  Cl7  1  0.250  0.803  0.557  1.0
  O  O8  1  0.750  0.125  0.578  1.0
  O  O9  1  0.553  0.303  0.426  1.0
  O  O10  1  0.053  0.803  0.074  1.0
  O  O11  1  0.250  0.936  0.659  1.0
  O  O12  1  0.250  0.564  0.159  1.0
  O  O13  1  0.750  0.375  0.078  1.0
  O  O14  1  0.447  0.803  0.074  1.0
  O  O15  1  0.553  0.197  0.926  1.0
  O  O16  1  0.250  0.625  0.922  1.0
  O  O17  1  0.447  0.697  0.574  1.0
  O  O18  1  0.947  0.197  0.926  1.0
  O  O19  1  0.053  0.697  0.574  1.0
  O  O20  1  0.750  0.064  0.341  1.0
  O  O21  1  0.750  0.436  0.841  1.0
  O  O22  1  0.250  0.875  0.422  1.0
  O  O23  1  0.947  0.303  0.426  1.0
[/CIF]
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The structure described by CsClO4 crystallizes in the orthorhombic Pnma space group. Cs(1) is bonded in a 12-coordinate geometry to three equivalent O(1), three equivalent O(3), and six equivalent O(2) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to three equivalent Cs(1) and one Cl(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to three equivalent Cs(1) and one Cl(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to three equivalent Cs(1) and one Cl(1) atom. Cl(1) is bonded in a tetrahedral geometry to one O(1), one O(3), and two equivalent O(2) atoms. is represented by the CIF file [CIF]
data_CsClO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.968
_cell_length_b   7.833
_cell_length_c   9.821
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   459.135
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.250  0.339  0.688  1.0
  Cs  Cs1  1  0.750  0.661  0.312  1.0
  Cs  Cs2  1  0.750  0.839  0.812  1.0
  Cs  Cs3  1  0.250  0.161  0.188  1.0
  Cl  Cl4  1  0.250  0.697  0.057  1.0
  Cl  Cl5  1  0.750  0.303  0.943  1.0
  Cl  Cl6  1  0.750  0.197  0.443  1.0
  Cl  Cl7  1  0.250  0.803  0.557  1.0
  O  O8  1  0.750  0.125  0.578  1.0
  O  O9  1  0.553  0.303  0.426  1.0
  O  O10  1  0.053  0.803  0.074  1.0
  O  O11  1  0.250  0.936  0.659  1.0
  O  O12  1  0.250  0.564  0.159  1.0
  O  O13  1  0.750  0.375  0.078  1.0
  O  O14  1  0.447  0.803  0.074  1.0
  O  O15  1  0.553  0.197  0.926  1.0
  O  O16  1  0.250  0.625  0.922  1.0
  O  O17  1  0.447  0.697  0.574  1.0
  O  O18  1  0.947  0.197  0.926  1.0
  O  O19  1  0.053  0.697  0.574  1.0
  O  O20  1  0.750  0.064  0.341  1.0
  O  O21  1  0.750  0.436  0.841  1.0
  O  O22  1  0.250  0.875  0.422  1.0
  O  O23  1  0.947  0.303  0.426  1.0
[/CIF]
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