The structure described by AlO6NO3(IO3)2 is Indium-derived structured and crystallizes in the trigonal P321 space group. The structure is zero-dimensional and consists of one nitric acid molecule, one AlO6 cluster, and two IO3 clusters. In the AlO6 cluster, Al(1) is bonded in an octahedral geometry to six equivalent O(2) atoms. O(2) is bonded in a single-bond geometry to one Al(1) atom. In each IO3 cluster, O(3) is bonded in a single-bond geometry to one I(1) atom. I(1) is bonded in a trigonal non-coplanar geometry to three equivalent O(3) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_AlI2NO15
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.867
_cell_length_b   6.867
_cell_length_c   8.004
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   326.927
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  0.000  0.000  0.500  1.0
  I  I1  1  0.333  0.667  0.883  1.0
  I  I2  1  0.667  0.333  0.117  1.0
  N  N3  1  0.000  0.000  0.000  1.0
  O  O4  1  0.182  0.000  0.000  1.0
  O  O5  1  0.818  0.818  0.000  1.0
  O  O6  1  0.000  0.182  0.000  1.0
  O  O7  1  0.891  0.744  0.632  1.0
  O  O8  1  0.853  0.109  0.632  1.0
  O  O9  1  0.256  0.147  0.632  1.0
  O  O10  1  0.109  0.853  0.368  1.0
  O  O11  1  0.744  0.891  0.368  1.0
  O  O12  1  0.147  0.256  0.368  1.0
  O  O13  1  0.492  0.946  0.786  1.0
  O  O14  1  0.454  0.508  0.786  1.0
  O  O15  1  0.054  0.546  0.786  1.0
  O  O16  1  0.508  0.454  0.214  1.0
  O  O17  1  0.946  0.492  0.214  1.0
  O  O18  1  0.546  0.054  0.214  1.0
[/CIF]
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The structure described by AlO6NO3(IO3)2 is Indium-derived structured and crystallizes in the trigonal P321 space group. The structure is zero-dimensional and consists of one nitric acid molecule, one AlO6 cluster, and two IO3 clusters. In the AlO6 cluster, Al(1) is bonded in an octahedral geometry to six equivalent O(2) atoms. O(2) is bonded in a single-bond geometry to one Al(1) atom. In each IO3 cluster, O(3) is bonded in a single-bond geometry to one I(1) atom. I(1) is bonded in a trigonal non-coplanar geometry to three equivalent O(3) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_AlI2NO15
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.867
_cell_length_b   6.867
_cell_length_c   8.004
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   326.927
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  0.000  0.000  0.500  1.0
  I  I1  1  0.333  0.667  0.883  1.0
  I  I2  1  0.667  0.333  0.117  1.0
  N  N3  1  0.000  0.000  0.000  1.0
  O  O4  1  0.182  0.000  0.000  1.0
  O  O5  1  0.818  0.818  0.000  1.0
  O  O6  1  0.000  0.182  0.000  1.0
  O  O7  1  0.891  0.744  0.632  1.0
  O  O8  1  0.853  0.109  0.632  1.0
  O  O9  1  0.256  0.147  0.632  1.0
  O  O10  1  0.109  0.853  0.368  1.0
  O  O11  1  0.744  0.891  0.368  1.0
  O  O12  1  0.147  0.256  0.368  1.0
  O  O13  1  0.492  0.946  0.786  1.0
  O  O14  1  0.454  0.508  0.786  1.0
  O  O15  1  0.054  0.546  0.786  1.0
  O  O16  1  0.508  0.454  0.214  1.0
  O  O17  1  0.946  0.492  0.214  1.0
  O  O18  1  0.546  0.054  0.214  1.0
[/CIF]
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