The material structure described by RbPbPS4 crystallizes in the orthorhombic P2_12_12_1 space group. Rb(1) is bonded in a 8-coordinate geometry to one S(1), two equivalent S(2), two equivalent S(3), and three equivalent S(4) atoms. Pb(1) is bonded in a 6-coordinate geometry to one S(2), one S(4), two equivalent S(1), and two equivalent S(3) atoms. P(1) is bonded in a tetrahedral geometry to one S(1), one S(2), one S(3), and one S(4) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a 4-coordinate geometry to one Rb(1), two equivalent Pb(1), and one P(1) atom. In the second S site, S(2) is bonded in a distorted single-bond geometry to two equivalent Rb(1), one Pb(1), and one P(1) atom. In the third S site, S(3) is bonded in a distorted single-bond geometry to two equivalent Rb(1), two equivalent Pb(1), and one P(1) atom. In the fourth S site, S(4) is bonded in a distorted single-bond geometry to three equivalent Rb(1), one Pb(1), and one P(1) atom. is represented by the CIF card [CIF]
data_RbPPbS4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.558
_cell_length_b   6.834
_cell_length_c   17.650
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   790.981
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.019  0.003  0.043  1.0
  Rb  Rb1  1  0.519  0.497  0.957  1.0
  Rb  Rb2  1  0.981  0.503  0.457  1.0
  Rb  Rb3  1  0.481  0.997  0.543  1.0
  P  P4  1  0.219  0.011  0.347  1.0
  P  P5  1  0.281  0.989  0.847  1.0
  P  P6  1  0.719  0.489  0.653  1.0
  P  P7  1  0.781  0.511  0.153  1.0
  Pb  Pb8  1  0.286  0.471  0.231  1.0
  Pb  Pb9  1  0.786  0.029  0.769  1.0
  Pb  Pb10  1  0.714  0.971  0.269  1.0
  Pb  Pb11  1  0.214  0.529  0.731  1.0
  S  S12  1  0.349  0.964  0.733  1.0
  S  S13  1  0.151  0.036  0.233  1.0
  S  S14  1  0.397  0.248  0.374  1.0
  S  S15  1  0.897  0.252  0.626  1.0
  S  S16  1  0.888  0.737  0.633  1.0
  S  S17  1  0.956  0.004  0.410  1.0
  S  S18  1  0.044  0.504  0.090  1.0
  S  S19  1  0.112  0.237  0.867  1.0
  S  S20  1  0.651  0.464  0.767  1.0
  S  S21  1  0.103  0.752  0.874  1.0
  S  S22  1  0.603  0.748  0.126  1.0
  S  S23  1  0.849  0.536  0.267  1.0
  S  S24  1  0.388  0.763  0.367  1.0
  S  S25  1  0.456  0.496  0.590  1.0
  S  S26  1  0.544  0.996  0.910  1.0
  S  S27  1  0.612  0.263  0.133  1.0
[/CIF]
.
The material structure described by RbPbPS4 crystallizes in the orthorhombic P2_12_12_1 space group. Rb(1) is bonded in a 8-coordinate geometry to one S(1), two equivalent S(2), two equivalent S(3), and three equivalent S(4) atoms. Pb(1) is bonded in a 6-coordinate geometry to one S(2), one S(4), two equivalent S(1), and two equivalent S(3) atoms. P(1) is bonded in a tetrahedral geometry to one S(1), one S(2), one S(3), and one S(4) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a 4-coordinate geometry to one Rb(1), two equivalent Pb(1), and one P(1) atom. In the second S site, S(2) is bonded in a distorted single-bond geometry to two equivalent Rb(1), one Pb(1), and one P(1) atom. In the third S site, S(3) is bonded in a distorted single-bond geometry to two equivalent Rb(1), two equivalent Pb(1), and one P(1) atom. In the fourth S site, S(4) is bonded in a distorted single-bond geometry to three equivalent Rb(1), one Pb(1), and one P(1) atom. is represented by the CIF card [CIF]
data_RbPPbS4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.558
_cell_length_b   6.834
_cell_length_c   17.650
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   790.981
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.019  0.003  0.043  1.0
  Rb  Rb1  1  0.519  0.497  0.957  1.0
  Rb  Rb2  1  0.981  0.503  0.457  1.0
  Rb  Rb3  1  0.481  0.997  0.543  1.0
  P  P4  1  0.219  0.011  0.347  1.0
  P  P5  1  0.281  0.989  0.847  1.0
  P  P6  1  0.719  0.489  0.653  1.0
  P  P7  1  0.781  0.511  0.153  1.0
  Pb  Pb8  1  0.286  0.471  0.231  1.0
  Pb  Pb9  1  0.786  0.029  0.769  1.0
  Pb  Pb10  1  0.714  0.971  0.269  1.0
  Pb  Pb11  1  0.214  0.529  0.731  1.0
  S  S12  1  0.349  0.964  0.733  1.0
  S  S13  1  0.151  0.036  0.233  1.0
  S  S14  1  0.397  0.248  0.374  1.0
  S  S15  1  0.897  0.252  0.626  1.0
  S  S16  1  0.888  0.737  0.633  1.0
  S  S17  1  0.956  0.004  0.410  1.0
  S  S18  1  0.044  0.504  0.090  1.0
  S  S19  1  0.112  0.237  0.867  1.0
  S  S20  1  0.651  0.464  0.767  1.0
  S  S21  1  0.103  0.752  0.874  1.0
  S  S22  1  0.603  0.748  0.126  1.0
  S  S23  1  0.849  0.536  0.267  1.0
  S  S24  1  0.388  0.763  0.367  1.0
  S  S25  1  0.456  0.496  0.590  1.0
  S  S26  1  0.544  0.996  0.910  1.0
  S  S27  1  0.612  0.263  0.133  1.0
[/CIF]
.