The crystal structure described by (ReOCl3)3O2 is Indium-derived structured and crystallizes in the orthorhombic Ama2 space group. The structure is zero-dimensional and consists of eight water atoms and four ReOCl3 clusters. In each ReOCl3 cluster, there are three inequivalent Re sites. In the first Re site, Re(1) is bonded in a 5-coordinate geometry to one O(1), one Cl(4), one Cl(6), and two equivalent Cl(1) atoms. In the second Re site, Re(2) is bonded in a 5-coordinate geometry to one O(3), one Cl(5), one Cl(6), and two equivalent Cl(3) atoms. In the third Re site, Re(3) is bonded in a distorted trigonal bipyramidal geometry to one O(2), one Cl(4), one Cl(5), and two equivalent Cl(2) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Re(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Re(3) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Re(2) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Re(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Re(3) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Re(2) atom. In the fourth Cl site, Cl(4) is bonded in a bent 120 degrees geometry to one Re(1) and one Re(3) atom. In the fifth Cl site, Cl(5) is bonded in a bent 120 degrees geometry to one Re(2) and one Re(3) atom. In the sixth Cl site, Cl(6) is bonded in a bent 120 degrees geometry to one Re(1) and one Re(2) atom. is represented by the CIF file [CIF]
data_Re3Cl9O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.123
_cell_length_b   10.123
_cell_length_c   15.534
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.676
_symmetry_Int_Tables_number   1
_cell_volume   1369.106
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.392  0.457  0.250  1.0
  Re  Re1  1  0.063  0.603  0.250  1.0
  Re  Re2  1  0.540  0.935  0.250  1.0
  Re  Re3  1  0.457  0.392  0.750  1.0
  Re  Re4  1  0.603  0.063  0.750  1.0
  Re  Re5  1  0.935  0.540  0.750  1.0
  Cl  Cl6  1  0.503  0.392  0.607  1.0
  Cl  Cl7  1  0.889  0.499  0.606  1.0
  Cl  Cl8  1  0.611  0.112  0.607  1.0
  Cl  Cl9  1  0.503  0.392  0.893  1.0
  Cl  Cl10  1  0.889  0.499  0.894  1.0
  Cl  Cl11  1  0.611  0.112  0.893  1.0
  Cl  Cl12  1  0.392  0.503  0.107  1.0
  Cl  Cl13  1  0.499  0.889  0.106  1.0
  Cl  Cl14  1  0.112  0.611  0.107  1.0
  Cl  Cl15  1  0.392  0.503  0.393  1.0
  Cl  Cl16  1  0.499  0.889  0.394  1.0
  Cl  Cl17  1  0.112  0.611  0.393  1.0
  Cl  Cl18  1  0.738  0.605  0.750  1.0
  Cl  Cl19  1  0.873  0.270  0.750  1.0
  Cl  Cl20  1  0.395  0.127  0.750  1.0
  Cl  Cl21  1  0.605  0.738  0.250  1.0
  Cl  Cl22  1  0.270  0.873  0.250  1.0
  Cl  Cl23  1  0.127  0.395  0.250  1.0
  O  O24  1  0.308  0.422  0.750  1.0
  O  O25  1  0.118  0.687  0.750  1.0
  O  O26  1  0.565  0.880  0.750  1.0
  O  O27  1  0.422  0.308  0.250  1.0
  O  O28  1  0.687  0.118  0.250  1.0
  O  O29  1  0.880  0.565  0.250  1.0
  O  O30  1  0.334  0.671  0.624  1.0
  O  O31  1  0.334  0.671  0.876  1.0
  O  O32  1  0.671  0.334  0.124  1.0
  O  O33  1  0.671  0.334  0.376  1.0
[/CIF]
.
The crystal structure described by (ReOCl3)3O2 is Indium-derived structured and crystallizes in the orthorhombic Ama2 space group. The structure is zero-dimensional and consists of eight water atoms and four ReOCl3 clusters. In each ReOCl3 cluster, there are three inequivalent Re sites. In the first Re site, Re(1) is bonded in a 5-coordinate geometry to one O(1), one Cl(4), one Cl(6), and two equivalent Cl(1) atoms. In the second Re site, Re(2) is bonded in a 5-coordinate geometry to one O(3), one Cl(5), one Cl(6), and two equivalent Cl(3) atoms. In the third Re site, Re(3) is bonded in a distorted trigonal bipyramidal geometry to one O(2), one Cl(4), one Cl(5), and two equivalent Cl(2) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Re(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Re(3) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Re(2) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Re(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Re(3) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Re(2) atom. In the fourth Cl site, Cl(4) is bonded in a bent 120 degrees geometry to one Re(1) and one Re(3) atom. In the fifth Cl site, Cl(5) is bonded in a bent 120 degrees geometry to one Re(2) and one Re(3) atom. In the sixth Cl site, Cl(6) is bonded in a bent 120 degrees geometry to one Re(1) and one Re(2) atom. is represented by the CIF file [CIF]
data_Re3Cl9O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.123
_cell_length_b   10.123
_cell_length_c   15.534
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.676
_symmetry_Int_Tables_number   1
_cell_volume   1369.106
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.392  0.457  0.250  1.0
  Re  Re1  1  0.063  0.603  0.250  1.0
  Re  Re2  1  0.540  0.935  0.250  1.0
  Re  Re3  1  0.457  0.392  0.750  1.0
  Re  Re4  1  0.603  0.063  0.750  1.0
  Re  Re5  1  0.935  0.540  0.750  1.0
  Cl  Cl6  1  0.503  0.392  0.607  1.0
  Cl  Cl7  1  0.889  0.499  0.606  1.0
  Cl  Cl8  1  0.611  0.112  0.607  1.0
  Cl  Cl9  1  0.503  0.392  0.893  1.0
  Cl  Cl10  1  0.889  0.499  0.894  1.0
  Cl  Cl11  1  0.611  0.112  0.893  1.0
  Cl  Cl12  1  0.392  0.503  0.107  1.0
  Cl  Cl13  1  0.499  0.889  0.106  1.0
  Cl  Cl14  1  0.112  0.611  0.107  1.0
  Cl  Cl15  1  0.392  0.503  0.393  1.0
  Cl  Cl16  1  0.499  0.889  0.394  1.0
  Cl  Cl17  1  0.112  0.611  0.393  1.0
  Cl  Cl18  1  0.738  0.605  0.750  1.0
  Cl  Cl19  1  0.873  0.270  0.750  1.0
  Cl  Cl20  1  0.395  0.127  0.750  1.0
  Cl  Cl21  1  0.605  0.738  0.250  1.0
  Cl  Cl22  1  0.270  0.873  0.250  1.0
  Cl  Cl23  1  0.127  0.395  0.250  1.0
  O  O24  1  0.308  0.422  0.750  1.0
  O  O25  1  0.118  0.687  0.750  1.0
  O  O26  1  0.565  0.880  0.750  1.0
  O  O27  1  0.422  0.308  0.250  1.0
  O  O28  1  0.687  0.118  0.250  1.0
  O  O29  1  0.880  0.565  0.250  1.0
  O  O30  1  0.334  0.671  0.624  1.0
  O  O31  1  0.334  0.671  0.876  1.0
  O  O32  1  0.671  0.334  0.124  1.0
  O  O33  1  0.671  0.334  0.376  1.0
[/CIF]
.