The material described by Hg(SbO3)2 is Hydrophilite-derived structured and crystallizes in the tetragonal P4_2/mnm space group. Hg(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form HgO6 octahedra that share corners with eight equivalent Sb(1)O6 octahedra and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-57°. Sb(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form SbO6 octahedra that share corners with four equivalent Hg(1)O6 octahedra, corners with four equivalent Sb(1)O6 octahedra,  an edgeedge with one Hg(1)O6 octahedra, and  an edgeedge with one Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-57°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Hg(1) and two equivalent Sb(1) atoms. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Hg(1) and two equivalent Sb(1) atoms. is represented by the CIF card [CIF]
data_Hg(SbO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.925
_cell_length_b   4.925
_cell_length_c   9.807
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   237.911
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Hg  Hg0  1  0.000  0.000  0.000  1.0
  Hg  Hg1  1  0.500  0.500  0.500  1.0
  Sb  Sb2  1  0.000  0.000  0.331  1.0
  Sb  Sb3  1  0.000  0.000  0.669  1.0
  Sb  Sb4  1  0.500  0.500  0.169  1.0
  Sb  Sb5  1  0.500  0.500  0.831  1.0
  O  O6  1  0.175  0.825  0.500  1.0
  O  O7  1  0.210  0.790  0.813  1.0
  O  O8  1  0.210  0.790  0.187  1.0
  O  O9  1  0.290  0.290  0.313  1.0
  O  O10  1  0.290  0.290  0.687  1.0
  O  O11  1  0.325  0.325  0.000  1.0
  O  O12  1  0.675  0.675  0.000  1.0
  O  O13  1  0.710  0.710  0.313  1.0
  O  O14  1  0.710  0.710  0.687  1.0
  O  O15  1  0.790  0.210  0.187  1.0
  O  O16  1  0.790  0.210  0.813  1.0
  O  O17  1  0.825  0.175  0.500  1.0
[/CIF]
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The material described by Hg(SbO3)2 is Hydrophilite-derived structured and crystallizes in the tetragonal P4_2/mnm space group. Hg(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form HgO6 octahedra that share corners with eight equivalent Sb(1)O6 octahedra and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-57°. Sb(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form SbO6 octahedra that share corners with four equivalent Hg(1)O6 octahedra, corners with four equivalent Sb(1)O6 octahedra,  an edgeedge with one Hg(1)O6 octahedra, and  an edgeedge with one Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-57°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Hg(1) and two equivalent Sb(1) atoms. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Hg(1) and two equivalent Sb(1) atoms. is represented by the CIF card [CIF]
data_Hg(SbO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.925
_cell_length_b   4.925
_cell_length_c   9.807
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   237.911
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Hg  Hg0  1  0.000  0.000  0.000  1.0
  Hg  Hg1  1  0.500  0.500  0.500  1.0
  Sb  Sb2  1  0.000  0.000  0.331  1.0
  Sb  Sb3  1  0.000  0.000  0.669  1.0
  Sb  Sb4  1  0.500  0.500  0.169  1.0
  Sb  Sb5  1  0.500  0.500  0.831  1.0
  O  O6  1  0.175  0.825  0.500  1.0
  O  O7  1  0.210  0.790  0.813  1.0
  O  O8  1  0.210  0.790  0.187  1.0
  O  O9  1  0.290  0.290  0.313  1.0
  O  O10  1  0.290  0.290  0.687  1.0
  O  O11  1  0.325  0.325  0.000  1.0
  O  O12  1  0.675  0.675  0.000  1.0
  O  O13  1  0.710  0.710  0.313  1.0
  O  O14  1  0.710  0.710  0.687  1.0
  O  O15  1  0.790  0.210  0.187  1.0
  O  O16  1  0.790  0.210  0.813  1.0
  O  O17  1  0.825  0.175  0.500  1.0
[/CIF]
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