The crystal structure described by CoCdAsHO5 crystallizes in the orthorhombic Pnma space group. Co(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form CoO6 octahedra that share corners with four equivalent As(1)O4 tetrahedra and edges with two equivalent Co(1)O6 octahedra. Cd(1) is bonded in a 7-coordinate geometry to one O(2), one O(3), one O(4), and four equivalent O(1) atoms. As(1) is bonded to one O(2), one O(3), and two equivalent O(1) atoms to form AsO4 tetrahedra that share corners with four equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-56°. H(1) is bonded in a single-bond geometry to one O(2) and one O(4) atom. There are four inequivalent O sites. In the first O site, O(4) is bonded in a distorted single-bond geometry to two equivalent Co(1), one Cd(1), and one H(1) atom. In the second O site, O(1) is bonded in a 4-coordinate geometry to one Co(1), two equivalent Cd(1), and one As(1) atom. In the third O site, O(2) is bonded in a 3-coordinate geometry to one Cd(1), one As(1), and one H(1) atom. In the fourth O site, O(3) is bonded to two equivalent Co(1), one Cd(1), and one As(1) atom to form distorted corner-sharing OCdCo2As trigonal pyramids. is represented by the CIF card [CIF]
data_CdCoAsHO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.231
_cell_length_b   7.661
_cell_length_c   8.823
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   421.126
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.250  0.631  0.327  1.0
  Cd  Cd1  1  0.250  0.131  0.173  1.0
  Cd  Cd2  1  0.750  0.369  0.673  1.0
  Cd  Cd3  1  0.750  0.869  0.827  1.0
  Co  Co4  1  0.500  0.500  0.000  1.0
  Co  Co5  1  0.000  0.000  0.500  1.0
  Co  Co6  1  0.000  0.500  0.000  1.0
  Co  Co7  1  0.500  0.000  0.500  1.0
  As  As8  1  0.250  0.629  0.673  1.0
  As  As9  1  0.250  0.129  0.827  1.0
  As  As10  1  0.750  0.371  0.327  1.0
  As  As11  1  0.750  0.871  0.173  1.0
  H  H12  1  0.250  0.759  0.040  1.0
  H  H13  1  0.250  0.259  0.460  1.0
  H  H14  1  0.750  0.241  0.960  1.0
  H  H15  1  0.750  0.741  0.540  1.0
  O  O16  1  0.518  0.379  0.219  1.0
  O  O17  1  0.982  0.879  0.281  1.0
  O  O18  1  0.018  0.621  0.781  1.0
  O  O19  1  0.482  0.121  0.719  1.0
  O  O20  1  0.482  0.621  0.781  1.0
  O  O21  1  0.018  0.121  0.719  1.0
  O  O22  1  0.982  0.379  0.219  1.0
  O  O23  1  0.518  0.879  0.281  1.0
  O  O24  1  0.250  0.467  0.538  1.0
  O  O25  1  0.250  0.967  0.962  1.0
  O  O26  1  0.750  0.533  0.462  1.0
  O  O27  1  0.750  0.033  0.038  1.0
  O  O28  1  0.250  0.815  0.557  1.0
  O  O29  1  0.250  0.315  0.943  1.0
  O  O30  1  0.750  0.185  0.443  1.0
  O  O31  1  0.750  0.685  0.057  1.0
  O  O32  1  0.250  0.638  0.080  1.0
  O  O33  1  0.250  0.138  0.420  1.0
  O  O34  1  0.750  0.362  0.920  1.0
  O  O35  1  0.750  0.862  0.580  1.0
[/CIF]
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The crystal structure described by CoCdAsHO5 crystallizes in the orthorhombic Pnma space group. Co(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form CoO6 octahedra that share corners with four equivalent As(1)O4 tetrahedra and edges with two equivalent Co(1)O6 octahedra. Cd(1) is bonded in a 7-coordinate geometry to one O(2), one O(3), one O(4), and four equivalent O(1) atoms. As(1) is bonded to one O(2), one O(3), and two equivalent O(1) atoms to form AsO4 tetrahedra that share corners with four equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-56°. H(1) is bonded in a single-bond geometry to one O(2) and one O(4) atom. There are four inequivalent O sites. In the first O site, O(4) is bonded in a distorted single-bond geometry to two equivalent Co(1), one Cd(1), and one H(1) atom. In the second O site, O(1) is bonded in a 4-coordinate geometry to one Co(1), two equivalent Cd(1), and one As(1) atom. In the third O site, O(2) is bonded in a 3-coordinate geometry to one Cd(1), one As(1), and one H(1) atom. In the fourth O site, O(3) is bonded to two equivalent Co(1), one Cd(1), and one As(1) atom to form distorted corner-sharing OCdCo2As trigonal pyramids. is represented by the CIF card [CIF]
data_CdCoAsHO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.231
_cell_length_b   7.661
_cell_length_c   8.823
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   421.126
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.250  0.631  0.327  1.0
  Cd  Cd1  1  0.250  0.131  0.173  1.0
  Cd  Cd2  1  0.750  0.369  0.673  1.0
  Cd  Cd3  1  0.750  0.869  0.827  1.0
  Co  Co4  1  0.500  0.500  0.000  1.0
  Co  Co5  1  0.000  0.000  0.500  1.0
  Co  Co6  1  0.000  0.500  0.000  1.0
  Co  Co7  1  0.500  0.000  0.500  1.0
  As  As8  1  0.250  0.629  0.673  1.0
  As  As9  1  0.250  0.129  0.827  1.0
  As  As10  1  0.750  0.371  0.327  1.0
  As  As11  1  0.750  0.871  0.173  1.0
  H  H12  1  0.250  0.759  0.040  1.0
  H  H13  1  0.250  0.259  0.460  1.0
  H  H14  1  0.750  0.241  0.960  1.0
  H  H15  1  0.750  0.741  0.540  1.0
  O  O16  1  0.518  0.379  0.219  1.0
  O  O17  1  0.982  0.879  0.281  1.0
  O  O18  1  0.018  0.621  0.781  1.0
  O  O19  1  0.482  0.121  0.719  1.0
  O  O20  1  0.482  0.621  0.781  1.0
  O  O21  1  0.018  0.121  0.719  1.0
  O  O22  1  0.982  0.379  0.219  1.0
  O  O23  1  0.518  0.879  0.281  1.0
  O  O24  1  0.250  0.467  0.538  1.0
  O  O25  1  0.250  0.967  0.962  1.0
  O  O26  1  0.750  0.533  0.462  1.0
  O  O27  1  0.750  0.033  0.038  1.0
  O  O28  1  0.250  0.815  0.557  1.0
  O  O29  1  0.250  0.315  0.943  1.0
  O  O30  1  0.750  0.185  0.443  1.0
  O  O31  1  0.750  0.685  0.057  1.0
  O  O32  1  0.250  0.638  0.080  1.0
  O  O33  1  0.250  0.138  0.420  1.0
  O  O34  1  0.750  0.362  0.920  1.0
  O  O35  1  0.750  0.862  0.580  1.0
[/CIF]
.