The material structure described by Hg2Os2O7 crystallizes in the cubic Fd-3m space group. The structure consists of one HgHgO framework and one OsO3 framework. In the HgHgO framework, Hg(1) is bonded in a distorted linear geometry to two equivalent O(1) atoms. O(1) is bonded to four equivalent Hg(1) atoms to form corner-sharing OHg4 tetrahedra. In the OsO3 framework, Os(1) is bonded to six equivalent O(2) atoms to form corner-sharing OsO6 octahedra. The corner-sharing octahedral tilt angles are 39°. O(2) is bonded in a distorted bent 150 degrees geometry to two equivalent Os(1) atoms. is represented by the CIF file [CIF]
data_Hg2Os2O7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.354
_cell_length_b   7.354
_cell_length_c   7.354
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   281.271
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Hg  Hg0  1  0.125  0.125  0.125  1.0
  Hg  Hg1  1  0.625  0.125  0.125  1.0
  Hg  Hg2  1  0.125  0.125  0.625  1.0
  Hg  Hg3  1  0.125  0.625  0.125  1.0
  Os  Os4  1  0.625  0.625  0.625  1.0
  Os  Os5  1  0.125  0.625  0.625  1.0
  Os  Os6  1  0.625  0.625  0.125  1.0
  Os  Os7  1  0.625  0.125  0.625  1.0
  O  O8  1  0.000  0.000  0.000  1.0
  O  O9  1  0.250  0.250  0.250  1.0
  O  O10  1  0.312  0.312  0.688  1.0
  O  O11  1  0.562  0.562  0.938  1.0
  O  O12  1  0.688  0.312  0.688  1.0
  O  O13  1  0.688  0.312  0.312  1.0
  O  O14  1  0.312  0.688  0.688  1.0
  O  O15  1  0.312  0.688  0.312  1.0
  O  O16  1  0.688  0.688  0.312  1.0
  O  O17  1  0.938  0.562  0.562  1.0
  O  O18  1  0.562  0.938  0.938  1.0
  O  O19  1  0.938  0.938  0.562  1.0
  O  O20  1  0.938  0.562  0.938  1.0
  O  O21  1  0.562  0.938  0.562  1.0
[/CIF]
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The material structure described by Hg2Os2O7 crystallizes in the cubic Fd-3m space group. The structure consists of one HgHgO framework and one OsO3 framework. In the HgHgO framework, Hg(1) is bonded in a distorted linear geometry to two equivalent O(1) atoms. O(1) is bonded to four equivalent Hg(1) atoms to form corner-sharing OHg4 tetrahedra. In the OsO3 framework, Os(1) is bonded to six equivalent O(2) atoms to form corner-sharing OsO6 octahedra. The corner-sharing octahedral tilt angles are 39°. O(2) is bonded in a distorted bent 150 degrees geometry to two equivalent Os(1) atoms. is represented by the CIF file [CIF]
data_Hg2Os2O7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.354
_cell_length_b   7.354
_cell_length_c   7.354
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   281.271
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Hg  Hg0  1  0.125  0.125  0.125  1.0
  Hg  Hg1  1  0.625  0.125  0.125  1.0
  Hg  Hg2  1  0.125  0.125  0.625  1.0
  Hg  Hg3  1  0.125  0.625  0.125  1.0
  Os  Os4  1  0.625  0.625  0.625  1.0
  Os  Os5  1  0.125  0.625  0.625  1.0
  Os  Os6  1  0.625  0.625  0.125  1.0
  Os  Os7  1  0.625  0.125  0.625  1.0
  O  O8  1  0.000  0.000  0.000  1.0
  O  O9  1  0.250  0.250  0.250  1.0
  O  O10  1  0.312  0.312  0.688  1.0
  O  O11  1  0.562  0.562  0.938  1.0
  O  O12  1  0.688  0.312  0.688  1.0
  O  O13  1  0.688  0.312  0.312  1.0
  O  O14  1  0.312  0.688  0.688  1.0
  O  O15  1  0.312  0.688  0.312  1.0
  O  O16  1  0.688  0.688  0.312  1.0
  O  O17  1  0.938  0.562  0.562  1.0
  O  O18  1  0.562  0.938  0.938  1.0
  O  O19  1  0.938  0.938  0.562  1.0
  O  O20  1  0.938  0.562  0.938  1.0
  O  O21  1  0.562  0.938  0.562  1.0
[/CIF]
.