The crystal structure described by KTeO9I crystallizes in the orthorhombic Pna2_1 space group. K(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), one O(8), and one O(9) atom. Te(1) is bonded in an octahedral geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. There are nine inequivalent O sites. In the first O site, O(6) is bonded in a distorted trigonal non-coplanar geometry to one K(1), one Te(1), and one I(1) atom. In the second O site, O(7) is bonded in a single-bond geometry to one I(1) atom. In the third O site, O(8) is bonded in a bent 120 degrees geometry to one K(1) and one I(1) atom. In the fourth O site, O(1) is bonded in a distorted bent 120 degrees geometry to one K(1) and one Te(1) atom. In the fifth O site, O(9) is bonded in a bent 120 degrees geometry to one K(1) and one I(1) atom. In the sixth O site, O(2) is bonded in a distorted single-bond geometry to one K(1) and one Te(1) atom. In the seventh O site, O(3) is bonded in a distorted bent 120 degrees geometry to one K(1) and one Te(1) atom. In the eighth O site, O(4) is bonded in a distorted water-like geometry to one K(1) and one Te(1) atom. In the ninth O site, O(5) is bonded in a bent 150 degrees geometry to one K(1) and one Te(1) atom. I(1) is bonded in a distorted see-saw-like geometry to one O(6), one O(7), one O(8), and one O(9) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_KTeIO9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.036
_cell_length_b   8.972
_cell_length_c   12.739
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   804.158
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.722  0.297  0.920  1.0
  K  K1  1  0.222  0.703  0.080  1.0
  K  K2  1  0.222  0.203  0.420  1.0
  K  K3  1  0.722  0.797  0.580  1.0
  Te  Te4  1  0.787  0.287  0.582  1.0
  Te  Te5  1  0.287  0.713  0.418  1.0
  Te  Te6  1  0.287  0.213  0.082  1.0
  Te  Te7  1  0.787  0.787  0.918  1.0
  I  I8  1  0.218  0.346  0.753  1.0
  I  I9  1  0.718  0.654  0.247  1.0
  I  I10  1  0.718  0.154  0.253  1.0
  I  I11  1  0.218  0.846  0.747  1.0
  O  O12  1  0.711  0.102  0.514  1.0
  O  O13  1  0.211  0.898  0.486  1.0
  O  O14  1  0.211  0.398  0.014  1.0
  O  O15  1  0.711  0.602  0.986  1.0
  O  O16  1  0.806  0.481  0.655  1.0
  O  O17  1  0.306  0.519  0.345  1.0
  O  O18  1  0.306  0.019  0.155  1.0
  O  O19  1  0.806  0.981  0.845  1.0
  O  O20  1  0.637  0.225  0.703  1.0
  O  O21  1  0.137  0.775  0.297  1.0
  O  O22  1  0.137  0.275  0.203  1.0
  O  O23  1  0.637  0.725  0.797  1.0
  O  O24  1  0.892  0.386  0.461  1.0
  O  O25  1  0.392  0.614  0.539  1.0
  O  O26  1  0.392  0.114  0.961  1.0
  O  O27  1  0.892  0.886  0.039  1.0
  O  O28  1  0.516  0.318  0.548  1.0
  O  O29  1  0.016  0.682  0.452  1.0
  O  O30  1  0.016  0.182  0.048  1.0
  O  O31  1  0.516  0.818  0.952  1.0
  O  O32  1  0.039  0.227  0.619  1.0
  O  O33  1  0.539  0.773  0.381  1.0
  O  O34  1  0.539  0.273  0.119  1.0
  O  O35  1  0.039  0.727  0.881  1.0
  O  O36  1  0.203  0.160  0.815  1.0
  O  O37  1  0.703  0.840  0.185  1.0
  O  O38  1  0.703  0.340  0.315  1.0
  O  O39  1  0.203  0.660  0.685  1.0
  O  O40  1  0.359  0.435  0.861  1.0
  O  O41  1  0.859  0.565  0.139  1.0
  O  O42  1  0.859  0.065  0.361  1.0
  O  O43  1  0.359  0.935  0.639  1.0
  O  O44  1  0.984  0.424  0.792  1.0
  O  O45  1  0.484  0.576  0.208  1.0
  O  O46  1  0.484  0.076  0.292  1.0
  O  O47  1  0.984  0.924  0.708  1.0
[/CIF]
.
The crystal structure described by KTeO9I crystallizes in the orthorhombic Pna2_1 space group. K(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), one O(8), and one O(9) atom. Te(1) is bonded in an octahedral geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. There are nine inequivalent O sites. In the first O site, O(6) is bonded in a distorted trigonal non-coplanar geometry to one K(1), one Te(1), and one I(1) atom. In the second O site, O(7) is bonded in a single-bond geometry to one I(1) atom. In the third O site, O(8) is bonded in a bent 120 degrees geometry to one K(1) and one I(1) atom. In the fourth O site, O(1) is bonded in a distorted bent 120 degrees geometry to one K(1) and one Te(1) atom. In the fifth O site, O(9) is bonded in a bent 120 degrees geometry to one K(1) and one I(1) atom. In the sixth O site, O(2) is bonded in a distorted single-bond geometry to one K(1) and one Te(1) atom. In the seventh O site, O(3) is bonded in a distorted bent 120 degrees geometry to one K(1) and one Te(1) atom. In the eighth O site, O(4) is bonded in a distorted water-like geometry to one K(1) and one Te(1) atom. In the ninth O site, O(5) is bonded in a bent 150 degrees geometry to one K(1) and one Te(1) atom. I(1) is bonded in a distorted see-saw-like geometry to one O(6), one O(7), one O(8), and one O(9) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_KTeIO9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.036
_cell_length_b   8.972
_cell_length_c   12.739
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   804.158
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.722  0.297  0.920  1.0
  K  K1  1  0.222  0.703  0.080  1.0
  K  K2  1  0.222  0.203  0.420  1.0
  K  K3  1  0.722  0.797  0.580  1.0
  Te  Te4  1  0.787  0.287  0.582  1.0
  Te  Te5  1  0.287  0.713  0.418  1.0
  Te  Te6  1  0.287  0.213  0.082  1.0
  Te  Te7  1  0.787  0.787  0.918  1.0
  I  I8  1  0.218  0.346  0.753  1.0
  I  I9  1  0.718  0.654  0.247  1.0
  I  I10  1  0.718  0.154  0.253  1.0
  I  I11  1  0.218  0.846  0.747  1.0
  O  O12  1  0.711  0.102  0.514  1.0
  O  O13  1  0.211  0.898  0.486  1.0
  O  O14  1  0.211  0.398  0.014  1.0
  O  O15  1  0.711  0.602  0.986  1.0
  O  O16  1  0.806  0.481  0.655  1.0
  O  O17  1  0.306  0.519  0.345  1.0
  O  O18  1  0.306  0.019  0.155  1.0
  O  O19  1  0.806  0.981  0.845  1.0
  O  O20  1  0.637  0.225  0.703  1.0
  O  O21  1  0.137  0.775  0.297  1.0
  O  O22  1  0.137  0.275  0.203  1.0
  O  O23  1  0.637  0.725  0.797  1.0
  O  O24  1  0.892  0.386  0.461  1.0
  O  O25  1  0.392  0.614  0.539  1.0
  O  O26  1  0.392  0.114  0.961  1.0
  O  O27  1  0.892  0.886  0.039  1.0
  O  O28  1  0.516  0.318  0.548  1.0
  O  O29  1  0.016  0.682  0.452  1.0
  O  O30  1  0.016  0.182  0.048  1.0
  O  O31  1  0.516  0.818  0.952  1.0
  O  O32  1  0.039  0.227  0.619  1.0
  O  O33  1  0.539  0.773  0.381  1.0
  O  O34  1  0.539  0.273  0.119  1.0
  O  O35  1  0.039  0.727  0.881  1.0
  O  O36  1  0.203  0.160  0.815  1.0
  O  O37  1  0.703  0.840  0.185  1.0
  O  O38  1  0.703  0.340  0.315  1.0
  O  O39  1  0.203  0.660  0.685  1.0
  O  O40  1  0.359  0.435  0.861  1.0
  O  O41  1  0.859  0.565  0.139  1.0
  O  O42  1  0.859  0.065  0.361  1.0
  O  O43  1  0.359  0.935  0.639  1.0
  O  O44  1  0.984  0.424  0.792  1.0
  O  O45  1  0.484  0.576  0.208  1.0
  O  O46  1  0.484  0.076  0.292  1.0
  O  O47  1  0.984  0.924  0.708  1.0
[/CIF]
.