The structure described by VSO8 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two VSO8 clusters. V(1) is bonded to one O(1), one O(2), one O(4), one O(5), one O(7), and one O(8) atom to form distorted VO6 octahedra that share corners with two equivalent S(1)O4 tetrahedra. S(1) is bonded to one O(3), one O(6), one O(7), and one O(8) atom to form SO4 tetrahedra that share corners with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 37-41°. There are eight inequivalent O sites. In the first O site, O(7) is bonded in a distorted bent 150 degrees geometry to one V(1) and one S(1) atom. In the second O site, O(8) is bonded in a bent 150 degrees geometry to one V(1) and one S(1) atom. In the third O site, O(1) is bonded in a single-bond geometry to one V(1) atom. In the fourth O site, O(2) is bonded in a single-bond geometry to one V(1) atom. In the fifth O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the sixth O site, O(4) is bonded in a single-bond geometry to one V(1) atom. In the seventh O site, O(5) is bonded in a single-bond geometry to one V(1) atom. In the eighth O site, O(6) is bonded in a single-bond geometry to one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_VSO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   14.014
_cell_length_b   5.880
_cell_length_c   9.828
_cell_angle_alpha   54.679
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   660.731
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.611  0.347  0.771  1.0
  V  V1  1  0.389  0.653  0.229  1.0
  V  V2  1  0.111  0.653  0.729  1.0
  V  V3  1  0.889  0.347  0.271  1.0
  S  S4  1  0.400  0.986  0.823  1.0
  S  S5  1  0.600  0.014  0.177  1.0
  S  S6  1  0.900  0.014  0.677  1.0
  S  S7  1  0.100  0.986  0.323  1.0
  O  O8  1  0.128  0.714  0.894  1.0
  O  O9  1  0.872  0.286  0.106  1.0
  O  O10  1  0.628  0.286  0.606  1.0
  O  O11  1  0.372  0.714  0.394  1.0
  O  O12  1  0.628  0.939  0.866  1.0
  O  O13  1  0.372  0.061  0.134  1.0
  O  O14  1  0.128  0.061  0.634  1.0
  O  O15  1  0.872  0.939  0.366  1.0
  O  O16  1  0.407  0.868  0.725  1.0
  O  O17  1  0.593  0.132  0.275  1.0
  O  O18  1  0.907  0.132  0.775  1.0
  O  O19  1  0.093  0.868  0.225  1.0
  O  O20  1  0.729  0.413  0.765  1.0
  O  O21  1  0.271  0.587  0.235  1.0
  O  O22  1  0.229  0.587  0.735  1.0
  O  O23  1  0.771  0.413  0.265  1.0
  O  O24  1  0.072  0.308  0.847  1.0
  O  O25  1  0.928  0.692  0.153  1.0
  O  O26  1  0.572  0.692  0.653  1.0
  O  O27  1  0.428  0.308  0.347  1.0
  O  O28  1  0.299  0.072  0.804  1.0
  O  O29  1  0.701  0.928  0.196  1.0
  O  O30  1  0.799  0.928  0.696  1.0
  O  O31  1  0.201  0.072  0.304  1.0
  O  O32  1  0.464  0.229  0.756  1.0
  O  O33  1  0.536  0.771  0.244  1.0
  O  O34  1  0.964  0.771  0.744  1.0
  O  O35  1  0.036  0.229  0.256  1.0
  O  O36  1  0.425  0.766  0.001  1.0
  O  O37  1  0.575  0.234  0.999  1.0
  O  O38  1  0.925  0.234  0.499  1.0
  O  O39  1  0.075  0.766  0.501  1.0
[/CIF]
.
The structure described by VSO8 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two VSO8 clusters. V(1) is bonded to one O(1), one O(2), one O(4), one O(5), one O(7), and one O(8) atom to form distorted VO6 octahedra that share corners with two equivalent S(1)O4 tetrahedra. S(1) is bonded to one O(3), one O(6), one O(7), and one O(8) atom to form SO4 tetrahedra that share corners with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 37-41°. There are eight inequivalent O sites. In the first O site, O(7) is bonded in a distorted bent 150 degrees geometry to one V(1) and one S(1) atom. In the second O site, O(8) is bonded in a bent 150 degrees geometry to one V(1) and one S(1) atom. In the third O site, O(1) is bonded in a single-bond geometry to one V(1) atom. In the fourth O site, O(2) is bonded in a single-bond geometry to one V(1) atom. In the fifth O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the sixth O site, O(4) is bonded in a single-bond geometry to one V(1) atom. In the seventh O site, O(5) is bonded in a single-bond geometry to one V(1) atom. In the eighth O site, O(6) is bonded in a single-bond geometry to one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_VSO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   14.014
_cell_length_b   5.880
_cell_length_c   9.828
_cell_angle_alpha   54.679
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   660.731
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.611  0.347  0.771  1.0
  V  V1  1  0.389  0.653  0.229  1.0
  V  V2  1  0.111  0.653  0.729  1.0
  V  V3  1  0.889  0.347  0.271  1.0
  S  S4  1  0.400  0.986  0.823  1.0
  S  S5  1  0.600  0.014  0.177  1.0
  S  S6  1  0.900  0.014  0.677  1.0
  S  S7  1  0.100  0.986  0.323  1.0
  O  O8  1  0.128  0.714  0.894  1.0
  O  O9  1  0.872  0.286  0.106  1.0
  O  O10  1  0.628  0.286  0.606  1.0
  O  O11  1  0.372  0.714  0.394  1.0
  O  O12  1  0.628  0.939  0.866  1.0
  O  O13  1  0.372  0.061  0.134  1.0
  O  O14  1  0.128  0.061  0.634  1.0
  O  O15  1  0.872  0.939  0.366  1.0
  O  O16  1  0.407  0.868  0.725  1.0
  O  O17  1  0.593  0.132  0.275  1.0
  O  O18  1  0.907  0.132  0.775  1.0
  O  O19  1  0.093  0.868  0.225  1.0
  O  O20  1  0.729  0.413  0.765  1.0
  O  O21  1  0.271  0.587  0.235  1.0
  O  O22  1  0.229  0.587  0.735  1.0
  O  O23  1  0.771  0.413  0.265  1.0
  O  O24  1  0.072  0.308  0.847  1.0
  O  O25  1  0.928  0.692  0.153  1.0
  O  O26  1  0.572  0.692  0.653  1.0
  O  O27  1  0.428  0.308  0.347  1.0
  O  O28  1  0.299  0.072  0.804  1.0
  O  O29  1  0.701  0.928  0.196  1.0
  O  O30  1  0.799  0.928  0.696  1.0
  O  O31  1  0.201  0.072  0.304  1.0
  O  O32  1  0.464  0.229  0.756  1.0
  O  O33  1  0.536  0.771  0.244  1.0
  O  O34  1  0.964  0.771  0.744  1.0
  O  O35  1  0.036  0.229  0.256  1.0
  O  O36  1  0.425  0.766  0.001  1.0
  O  O37  1  0.575  0.234  0.999  1.0
  O  O38  1  0.925  0.234  0.499  1.0
  O  O39  1  0.075  0.766  0.501  1.0
[/CIF]
.