The compound described by Ag6GeS4Br2 crystallizes in the orthorhombic Pnma space group. There are four inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to two equivalent S(2), one Br(1), and one Br(2) atom to form distorted AgS2Br2 tetrahedra that share corners with two equivalent Ge(1)S4 tetrahedra. In the second Ag site, Ag(2) is bonded in a 4-coordinate geometry to one S(2), two equivalent S(3), and one Br(2) atom. In the third Ag site, Ag(3) is bonded in a 3-coordinate geometry to one S(1), one S(2), and two equivalent Br(1) atoms. In the fourth Ag site, Ag(4) is bonded in a distorted square co-planar geometry to two equivalent S(1) and two equivalent Br(1) atoms. Ge(1) is bonded to one S(1), one S(3), and two equivalent S(2) atoms to form GeS4 tetrahedra that share corners with two equivalent Ag(1)S2Br2 tetrahedra. There are three inequivalent S sites. In the first S site, S(2) is bonded to one Ag(1), one Ag(2), one Ag(3), and one Ge(1) atom to form distorted SAg3Ge tetrahedra that share corners with two equivalent S(1)Ag4Ge square pyramids and corners with two equivalent S(2)Ag3Ge tetrahedra. In the second S site, S(3) is bonded in a 5-coordinate geometry to four equivalent Ag(2) and one Ge(1) atom. In the third S site, S(1) is bonded to two equivalent Ag(3), two equivalent Ag(4), and one Ge(1) atom to form distorted SAg4Ge square pyramids that share corners with two equivalent S(1)Ag4Ge square pyramids and corners with four equivalent S(2)Ag3Ge tetrahedra. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in a 7-coordinate geometry to one Ag(1), two equivalent Ag(4), and four equivalent Ag(3) atoms. In the second Br site, Br(2) is bonded in a distorted trigonal planar geometry to one Ag(1) and two equivalent Ag(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ag6Ge(S2Br)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.608
_cell_length_b   7.832
_cell_length_c   23.409
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1211.537
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.469  0.250  0.644  1.0
  Ag  Ag1  1  0.531  0.750  0.356  1.0
  Ag  Ag2  1  0.031  0.750  0.144  1.0
  Ag  Ag3  1  0.969  0.250  0.856  1.0
  Ag  Ag4  1  0.096  0.044  0.281  1.0
  Ag  Ag5  1  0.904  0.956  0.719  1.0
  Ag  Ag6  1  0.404  0.956  0.781  1.0
  Ag  Ag7  1  0.904  0.544  0.719  1.0
  Ag  Ag8  1  0.596  0.044  0.219  1.0
  Ag  Ag9  1  0.096  0.456  0.281  1.0
  Ag  Ag10  1  0.596  0.456  0.219  1.0
  Ag  Ag11  1  0.404  0.544  0.781  1.0
  Ag  Ag12  1  0.002  0.065  0.428  1.0
  Ag  Ag13  1  0.998  0.935  0.572  1.0
  Ag  Ag14  1  0.498  0.935  0.928  1.0
  Ag  Ag15  1  0.998  0.565  0.572  1.0
  Ag  Ag16  1  0.502  0.065  0.072  1.0
  Ag  Ag17  1  0.002  0.435  0.428  1.0
  Ag  Ag18  1  0.502  0.435  0.072  1.0
  Ag  Ag19  1  0.498  0.565  0.928  1.0
  Ag  Ag20  1  0.000  0.000  0.000  1.0
  Ag  Ag21  1  0.500  0.000  0.500  1.0
  Ag  Ag22  1  0.000  0.500  0.000  1.0
  Ag  Ag23  1  0.500  0.500  0.500  1.0
  Ge  Ge24  1  0.004  0.250  0.131  1.0
  Ge  Ge25  1  0.996  0.750  0.869  1.0
  Ge  Ge26  1  0.496  0.750  0.631  1.0
  Ge  Ge27  1  0.504  0.250  0.369  1.0
  S  S28  1  0.188  0.250  0.048  1.0
  S  S29  1  0.812  0.750  0.952  1.0
  S  S30  1  0.312  0.750  0.548  1.0
  S  S31  1  0.688  0.250  0.452  1.0
  S  S32  1  0.313  0.012  0.372  1.0
  S  S33  1  0.687  0.988  0.628  1.0
  S  S34  1  0.187  0.988  0.872  1.0
  S  S35  1  0.687  0.512  0.628  1.0
  S  S36  1  0.813  0.012  0.128  1.0
  S  S37  1  0.313  0.488  0.372  1.0
  S  S38  1  0.813  0.488  0.128  1.0
  S  S39  1  0.187  0.512  0.872  1.0
  S  S40  1  0.216  0.250  0.205  1.0
  S  S41  1  0.784  0.750  0.795  1.0
  S  S42  1  0.284  0.750  0.705  1.0
  S  S43  1  0.716  0.250  0.295  1.0
  Br  Br44  1  0.170  0.250  0.541  1.0
  Br  Br45  1  0.830  0.750  0.459  1.0
  Br  Br46  1  0.330  0.750  0.041  1.0
  Br  Br47  1  0.670  0.250  0.959  1.0
  Br  Br48  1  0.134  0.250  0.709  1.0
  Br  Br49  1  0.866  0.750  0.291  1.0
  Br  Br50  1  0.366  0.750  0.209  1.0
  Br  Br51  1  0.634  0.250  0.791  1.0
[/CIF]
.
The compound described by Ag6GeS4Br2 crystallizes in the orthorhombic Pnma space group. There are four inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to two equivalent S(2), one Br(1), and one Br(2) atom to form distorted AgS2Br2 tetrahedra that share corners with two equivalent Ge(1)S4 tetrahedra. In the second Ag site, Ag(2) is bonded in a 4-coordinate geometry to one S(2), two equivalent S(3), and one Br(2) atom. In the third Ag site, Ag(3) is bonded in a 3-coordinate geometry to one S(1), one S(2), and two equivalent Br(1) atoms. In the fourth Ag site, Ag(4) is bonded in a distorted square co-planar geometry to two equivalent S(1) and two equivalent Br(1) atoms. Ge(1) is bonded to one S(1), one S(3), and two equivalent S(2) atoms to form GeS4 tetrahedra that share corners with two equivalent Ag(1)S2Br2 tetrahedra. There are three inequivalent S sites. In the first S site, S(2) is bonded to one Ag(1), one Ag(2), one Ag(3), and one Ge(1) atom to form distorted SAg3Ge tetrahedra that share corners with two equivalent S(1)Ag4Ge square pyramids and corners with two equivalent S(2)Ag3Ge tetrahedra. In the second S site, S(3) is bonded in a 5-coordinate geometry to four equivalent Ag(2) and one Ge(1) atom. In the third S site, S(1) is bonded to two equivalent Ag(3), two equivalent Ag(4), and one Ge(1) atom to form distorted SAg4Ge square pyramids that share corners with two equivalent S(1)Ag4Ge square pyramids and corners with four equivalent S(2)Ag3Ge tetrahedra. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in a 7-coordinate geometry to one Ag(1), two equivalent Ag(4), and four equivalent Ag(3) atoms. In the second Br site, Br(2) is bonded in a distorted trigonal planar geometry to one Ag(1) and two equivalent Ag(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ag6Ge(S2Br)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.608
_cell_length_b   7.832
_cell_length_c   23.409
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1211.537
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.469  0.250  0.644  1.0
  Ag  Ag1  1  0.531  0.750  0.356  1.0
  Ag  Ag2  1  0.031  0.750  0.144  1.0
  Ag  Ag3  1  0.969  0.250  0.856  1.0
  Ag  Ag4  1  0.096  0.044  0.281  1.0
  Ag  Ag5  1  0.904  0.956  0.719  1.0
  Ag  Ag6  1  0.404  0.956  0.781  1.0
  Ag  Ag7  1  0.904  0.544  0.719  1.0
  Ag  Ag8  1  0.596  0.044  0.219  1.0
  Ag  Ag9  1  0.096  0.456  0.281  1.0
  Ag  Ag10  1  0.596  0.456  0.219  1.0
  Ag  Ag11  1  0.404  0.544  0.781  1.0
  Ag  Ag12  1  0.002  0.065  0.428  1.0
  Ag  Ag13  1  0.998  0.935  0.572  1.0
  Ag  Ag14  1  0.498  0.935  0.928  1.0
  Ag  Ag15  1  0.998  0.565  0.572  1.0
  Ag  Ag16  1  0.502  0.065  0.072  1.0
  Ag  Ag17  1  0.002  0.435  0.428  1.0
  Ag  Ag18  1  0.502  0.435  0.072  1.0
  Ag  Ag19  1  0.498  0.565  0.928  1.0
  Ag  Ag20  1  0.000  0.000  0.000  1.0
  Ag  Ag21  1  0.500  0.000  0.500  1.0
  Ag  Ag22  1  0.000  0.500  0.000  1.0
  Ag  Ag23  1  0.500  0.500  0.500  1.0
  Ge  Ge24  1  0.004  0.250  0.131  1.0
  Ge  Ge25  1  0.996  0.750  0.869  1.0
  Ge  Ge26  1  0.496  0.750  0.631  1.0
  Ge  Ge27  1  0.504  0.250  0.369  1.0
  S  S28  1  0.188  0.250  0.048  1.0
  S  S29  1  0.812  0.750  0.952  1.0
  S  S30  1  0.312  0.750  0.548  1.0
  S  S31  1  0.688  0.250  0.452  1.0
  S  S32  1  0.313  0.012  0.372  1.0
  S  S33  1  0.687  0.988  0.628  1.0
  S  S34  1  0.187  0.988  0.872  1.0
  S  S35  1  0.687  0.512  0.628  1.0
  S  S36  1  0.813  0.012  0.128  1.0
  S  S37  1  0.313  0.488  0.372  1.0
  S  S38  1  0.813  0.488  0.128  1.0
  S  S39  1  0.187  0.512  0.872  1.0
  S  S40  1  0.216  0.250  0.205  1.0
  S  S41  1  0.784  0.750  0.795  1.0
  S  S42  1  0.284  0.750  0.705  1.0
  S  S43  1  0.716  0.250  0.295  1.0
  Br  Br44  1  0.170  0.250  0.541  1.0
  Br  Br45  1  0.830  0.750  0.459  1.0
  Br  Br46  1  0.330  0.750  0.041  1.0
  Br  Br47  1  0.670  0.250  0.959  1.0
  Br  Br48  1  0.134  0.250  0.709  1.0
  Br  Br49  1  0.866  0.750  0.291  1.0
  Br  Br50  1  0.366  0.750  0.209  1.0
  Br  Br51  1  0.634  0.250  0.791  1.0
[/CIF]
.