The compound described by SbCl3F2 is Indium-like structured and crystallizes in the tetragonal I4 space group. The structure is zero-dimensional and consists of two SbCl3F2 clusters. Sb(1) is bonded to one Cl(1), one Cl(2), one Cl(3), one F(2), and two equivalent F(1) atoms to form distorted corner-sharing SbCl3F3 octahedra. The corner-sharing octahedral tilt angles are 12°. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Sb(1) atom. There are two inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(1) is bonded in a linear geometry to two equivalent Sb(1) atoms. is represented by the CIF file [CIF]
data_SbCl3F2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.912
_cell_length_b   9.912
_cell_length_c   9.913
_cell_angle_alpha   97.399
_cell_angle_beta   97.399
_cell_angle_gamma   137.939
_symmetry_Int_Tables_number   1
_cell_volume   609.048
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.967  0.794  0.735  1.0
  Sb  Sb1  1  0.794  0.060  0.827  1.0
  Sb  Sb2  1  0.060  0.232  0.265  1.0
  Sb  Sb3  1  0.232  0.967  0.173  1.0
  Cl  Cl4  1  0.673  0.969  0.581  1.0
  Cl  Cl5  1  0.969  0.388  0.296  1.0
  Cl  Cl6  1  0.888  0.654  0.155  1.0
  Cl  Cl7  1  0.388  0.092  0.419  1.0
  Cl  Cl8  1  0.092  0.673  0.704  1.0
  Cl  Cl9  1  0.825  0.727  0.499  1.0
  Cl  Cl10  1  0.727  0.229  0.903  1.0
  Cl  Cl11  1  0.326  0.825  0.097  1.0
  Cl  Cl12  1  0.499  0.733  0.845  1.0
  Cl  Cl13  1  0.733  0.888  0.234  1.0
  Cl  Cl14  1  0.654  0.499  0.766  1.0
  Cl  Cl15  1  0.229  0.326  0.501  1.0
  F  F16  1  0.140  0.098  0.197  1.0
  F  F17  1  0.468  0.232  0.153  1.0
  F  F18  1  0.315  0.468  0.236  1.0
  F  F19  1  0.232  0.079  0.764  1.0
  F  F20  1  0.098  0.901  0.958  1.0
  F  F21  1  0.943  0.140  0.042  1.0
  F  F22  1  0.079  0.315  0.847  1.0
  F  F23  1  0.901  0.943  0.803  1.0
[/CIF]
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The compound described by SbCl3F2 is Indium-like structured and crystallizes in the tetragonal I4 space group. The structure is zero-dimensional and consists of two SbCl3F2 clusters. Sb(1) is bonded to one Cl(1), one Cl(2), one Cl(3), one F(2), and two equivalent F(1) atoms to form distorted corner-sharing SbCl3F3 octahedra. The corner-sharing octahedral tilt angles are 12°. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Sb(1) atom. There are two inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(1) is bonded in a linear geometry to two equivalent Sb(1) atoms. is represented by the CIF file [CIF]
data_SbCl3F2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.912
_cell_length_b   9.912
_cell_length_c   9.913
_cell_angle_alpha   97.399
_cell_angle_beta   97.399
_cell_angle_gamma   137.939
_symmetry_Int_Tables_number   1
_cell_volume   609.048
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.967  0.794  0.735  1.0
  Sb  Sb1  1  0.794  0.060  0.827  1.0
  Sb  Sb2  1  0.060  0.232  0.265  1.0
  Sb  Sb3  1  0.232  0.967  0.173  1.0
  Cl  Cl4  1  0.673  0.969  0.581  1.0
  Cl  Cl5  1  0.969  0.388  0.296  1.0
  Cl  Cl6  1  0.888  0.654  0.155  1.0
  Cl  Cl7  1  0.388  0.092  0.419  1.0
  Cl  Cl8  1  0.092  0.673  0.704  1.0
  Cl  Cl9  1  0.825  0.727  0.499  1.0
  Cl  Cl10  1  0.727  0.229  0.903  1.0
  Cl  Cl11  1  0.326  0.825  0.097  1.0
  Cl  Cl12  1  0.499  0.733  0.845  1.0
  Cl  Cl13  1  0.733  0.888  0.234  1.0
  Cl  Cl14  1  0.654  0.499  0.766  1.0
  Cl  Cl15  1  0.229  0.326  0.501  1.0
  F  F16  1  0.140  0.098  0.197  1.0
  F  F17  1  0.468  0.232  0.153  1.0
  F  F18  1  0.315  0.468  0.236  1.0
  F  F19  1  0.232  0.079  0.764  1.0
  F  F20  1  0.098  0.901  0.958  1.0
  F  F21  1  0.943  0.140  0.042  1.0
  F  F22  1  0.079  0.315  0.847  1.0
  F  F23  1  0.901  0.943  0.803  1.0
[/CIF]
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