The compound described by LiSbWO6 is Hydrophilite-derived structured and crystallizes in the orthorhombic Pbcn space group. Li(1) is bonded to two equivalent O(1) and four equivalent O(3) atoms to form LiO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra and edges with two equivalent Li(1)O6 octahedra. The corner-sharing octahedral tilt angles are 54°. W(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. Sb(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form SbO6 octahedra that share corners with two equivalent Li(1)O6 octahedra and corners with four equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-54°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Li(1), one W(1), and one Sb(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one W(1) and two equivalent Sb(1) atoms. In the third O site, O(3) is bonded in a distorted T-shaped geometry to two equivalent Li(1) and one W(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiSbWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.759
_cell_length_b   5.094
_cell_length_c   17.741
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   430.094
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.750  0.048  1.0
  Li  Li1  1  0.500  0.250  0.452  1.0
  Li  Li2  1  0.000  0.250  0.952  1.0
  Li  Li3  1  0.500  0.750  0.548  1.0
  Sb  Sb4  1  0.000  0.750  0.718  1.0
  Sb  Sb5  1  0.000  0.250  0.282  1.0
  Sb  Sb6  1  0.500  0.750  0.218  1.0
  Sb  Sb7  1  0.500  0.250  0.782  1.0
  W  W8  1  0.500  0.250  0.103  1.0
  W  W9  1  0.000  0.250  0.603  1.0
  W  W10  1  0.500  0.750  0.897  1.0
  W  W11  1  0.000  0.750  0.397  1.0
  O  O12  1  0.294  0.561  0.136  1.0
  O  O13  1  0.740  0.920  0.793  1.0
  O  O14  1  0.240  0.080  0.707  1.0
  O  O15  1  0.760  0.420  0.707  1.0
  O  O16  1  0.260  0.580  0.793  1.0
  O  O17  1  0.260  0.080  0.207  1.0
  O  O18  1  0.760  0.920  0.293  1.0
  O  O19  1  0.240  0.580  0.293  1.0
  O  O20  1  0.794  0.439  0.364  1.0
  O  O21  1  0.294  0.061  0.864  1.0
  O  O22  1  0.706  0.939  0.136  1.0
  O  O23  1  0.206  0.061  0.364  1.0
  O  O24  1  0.206  0.561  0.636  1.0
  O  O25  1  0.706  0.439  0.864  1.0
  O  O26  1  0.754  0.394  0.042  1.0
  O  O27  1  0.794  0.939  0.636  1.0
  O  O28  1  0.754  0.894  0.958  1.0
  O  O29  1  0.254  0.606  0.458  1.0
  O  O30  1  0.746  0.894  0.458  1.0
  O  O31  1  0.246  0.106  0.042  1.0
  O  O32  1  0.246  0.606  0.958  1.0
  O  O33  1  0.746  0.394  0.542  1.0
  O  O34  1  0.254  0.106  0.542  1.0
  O  O35  1  0.740  0.420  0.207  1.0
[/CIF]
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The compound described by LiSbWO6 is Hydrophilite-derived structured and crystallizes in the orthorhombic Pbcn space group. Li(1) is bonded to two equivalent O(1) and four equivalent O(3) atoms to form LiO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra and edges with two equivalent Li(1)O6 octahedra. The corner-sharing octahedral tilt angles are 54°. W(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. Sb(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form SbO6 octahedra that share corners with two equivalent Li(1)O6 octahedra and corners with four equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-54°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Li(1), one W(1), and one Sb(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one W(1) and two equivalent Sb(1) atoms. In the third O site, O(3) is bonded in a distorted T-shaped geometry to two equivalent Li(1) and one W(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiSbWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.759
_cell_length_b   5.094
_cell_length_c   17.741
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   430.094
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.750  0.048  1.0
  Li  Li1  1  0.500  0.250  0.452  1.0
  Li  Li2  1  0.000  0.250  0.952  1.0
  Li  Li3  1  0.500  0.750  0.548  1.0
  Sb  Sb4  1  0.000  0.750  0.718  1.0
  Sb  Sb5  1  0.000  0.250  0.282  1.0
  Sb  Sb6  1  0.500  0.750  0.218  1.0
  Sb  Sb7  1  0.500  0.250  0.782  1.0
  W  W8  1  0.500  0.250  0.103  1.0
  W  W9  1  0.000  0.250  0.603  1.0
  W  W10  1  0.500  0.750  0.897  1.0
  W  W11  1  0.000  0.750  0.397  1.0
  O  O12  1  0.294  0.561  0.136  1.0
  O  O13  1  0.740  0.920  0.793  1.0
  O  O14  1  0.240  0.080  0.707  1.0
  O  O15  1  0.760  0.420  0.707  1.0
  O  O16  1  0.260  0.580  0.793  1.0
  O  O17  1  0.260  0.080  0.207  1.0
  O  O18  1  0.760  0.920  0.293  1.0
  O  O19  1  0.240  0.580  0.293  1.0
  O  O20  1  0.794  0.439  0.364  1.0
  O  O21  1  0.294  0.061  0.864  1.0
  O  O22  1  0.706  0.939  0.136  1.0
  O  O23  1  0.206  0.061  0.364  1.0
  O  O24  1  0.206  0.561  0.636  1.0
  O  O25  1  0.706  0.439  0.864  1.0
  O  O26  1  0.754  0.394  0.042  1.0
  O  O27  1  0.794  0.939  0.636  1.0
  O  O28  1  0.754  0.894  0.958  1.0
  O  O29  1  0.254  0.606  0.458  1.0
  O  O30  1  0.746  0.894  0.458  1.0
  O  O31  1  0.246  0.106  0.042  1.0
  O  O32  1  0.246  0.606  0.958  1.0
  O  O33  1  0.746  0.394  0.542  1.0
  O  O34  1  0.254  0.106  0.542  1.0
  O  O35  1  0.740  0.420  0.207  1.0
[/CIF]
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