The compound described by K2PtCP4NSO11 crystallizes in the triclinic P-1 space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 7-coordinate geometry to one N(1), one S(1), one O(10), one O(3), one O(5), one O(8), and one O(9) atom. In the second K site, K(2) is bonded in a 7-coordinate geometry to one N(1), one O(11), one O(2), one O(4), one O(5), one O(7), and one O(8) atom. Pt(1) is bonded in a 4-coordinate geometry to one P(2), one P(3), one S(1), and one O(2) atom. C(1) is bonded in a distorted linear geometry to one N(1) and one S(1) atom. There are four inequivalent P sites. In the first P site, P(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(5) atom. In the second P site, P(2) is bonded in a distorted trigonal non-coplanar geometry to one Pt(1), one O(1), one O(4), and one O(5) atom. In the third P site, P(3) is bonded in a distorted trigonal non-coplanar geometry to one Pt(1), one O(6), one O(7), and one O(8) atom. In the fourth P site, P(4) is bonded in a trigonal planar geometry to one O(10), one O(6), and one O(9) atom. N(1) is bonded in a distorted trigonal planar geometry to one K(1), one K(2), and one C(1) atom. S(1) is bonded in a distorted trigonal planar geometry to one K(1), one Pt(1), and one C(1) atom. There are eleven inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the second O site, O(2) is bonded in a 1-coordinate geometry to one K(2), one Pt(1), and one P(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one K(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one K(2) and one P(2) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one K(1), one K(2), one P(1), and one P(2) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one P(3) and one P(4) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one K(2) and one P(3) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one K(1), one K(2), and one P(3) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one K(1) and one P(4) atom. In the tenth O site, O(10) is bonded in a single-bond geometry to one K(1) and one P(4) atom. In the eleventh O site, O(11) is bonded in a water-like geometry to one K(2) and one O(11) atom. is represented by the CIF card [CIF]
data_K2P4PtCSNO11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.583
_cell_length_b   7.912
_cell_length_c   10.987
_cell_angle_alpha   109.312
_cell_angle_beta   120.613
_cell_angle_gamma   84.703
_symmetry_Int_Tables_number   1
_cell_volume   814.266
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.285  0.750  0.584  1.0
  K  K1  1  0.715  0.250  0.416  1.0
  K  K2  1  0.169  0.475  0.811  1.0
  K  K3  1  0.831  0.525  0.189  1.0
  P  P4  1  0.157  0.450  0.210  1.0
  P  P5  1  0.843  0.550  0.790  1.0
  P  P6  1  0.946  0.261  0.909  1.0
  P  P7  1  0.054  0.739  0.091  1.0
  P  P8  1  0.856  0.033  0.163  1.0
  P  P9  1  0.144  0.967  0.837  1.0
  P  P10  1  0.588  0.959  0.866  1.0
  P  P11  1  0.412  0.041  0.134  1.0
  Pt  Pt12  1  0.056  0.037  0.164  1.0
  Pt  Pt13  1  0.944  0.963  0.836  1.0
  C  C14  1  0.243  0.272  0.524  1.0
  C  C15  1  0.757  0.728  0.476  1.0
  S  S16  1  0.227  0.061  0.418  1.0
  S  S17  1  0.773  0.939  0.582  1.0
  N  N18  1  0.257  0.421  0.603  1.0
  N  N19  1  0.743  0.579  0.397  1.0
  O  O20  1  0.101  0.354  0.032  1.0
  O  O21  1  0.899  0.646  0.968  1.0
  O  O22  1  0.087  0.337  0.247  1.0
  O  O23  1  0.913  0.663  0.753  1.0
  O  O24  1  0.304  0.494  0.301  1.0
  O  O25  1  0.696  0.506  0.699  1.0
  O  O26  1  0.846  0.313  0.958  1.0
  O  O27  1  0.154  0.687  0.042  1.0
  O  O28  1  0.918  0.357  0.784  1.0
  O  O29  1  0.082  0.643  0.216  1.0
  O  O30  1  0.739  0.025  0.981  1.0
  O  O31  1  0.261  0.975  0.019  1.0
  O  O32  1  0.829  0.867  0.185  1.0
  O  O33  1  0.171  0.133  0.815  1.0
  O  O34  1  0.852  0.217  0.259  1.0
  O  O35  1  0.148  0.783  0.741  1.0
  O  O36  1  0.525  0.815  0.876  1.0
  O  O37  1  0.475  0.185  0.124  1.0
  O  O38  1  0.522  0.048  0.751  1.0
  O  O39  1  0.478  0.952  0.249  1.0
  O  O40  1  0.473  0.422  0.961  1.0
  O  O41  1  0.527  0.578  0.039  1.0
[/CIF]
.
The compound described by K2PtCP4NSO11 crystallizes in the triclinic P-1 space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 7-coordinate geometry to one N(1), one S(1), one O(10), one O(3), one O(5), one O(8), and one O(9) atom. In the second K site, K(2) is bonded in a 7-coordinate geometry to one N(1), one O(11), one O(2), one O(4), one O(5), one O(7), and one O(8) atom. Pt(1) is bonded in a 4-coordinate geometry to one P(2), one P(3), one S(1), and one O(2) atom. C(1) is bonded in a distorted linear geometry to one N(1) and one S(1) atom. There are four inequivalent P sites. In the first P site, P(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(5) atom. In the second P site, P(2) is bonded in a distorted trigonal non-coplanar geometry to one Pt(1), one O(1), one O(4), and one O(5) atom. In the third P site, P(3) is bonded in a distorted trigonal non-coplanar geometry to one Pt(1), one O(6), one O(7), and one O(8) atom. In the fourth P site, P(4) is bonded in a trigonal planar geometry to one O(10), one O(6), and one O(9) atom. N(1) is bonded in a distorted trigonal planar geometry to one K(1), one K(2), and one C(1) atom. S(1) is bonded in a distorted trigonal planar geometry to one K(1), one Pt(1), and one C(1) atom. There are eleven inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the second O site, O(2) is bonded in a 1-coordinate geometry to one K(2), one Pt(1), and one P(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one K(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one K(2) and one P(2) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one K(1), one K(2), one P(1), and one P(2) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one P(3) and one P(4) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one K(2) and one P(3) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one K(1), one K(2), and one P(3) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one K(1) and one P(4) atom. In the tenth O site, O(10) is bonded in a single-bond geometry to one K(1) and one P(4) atom. In the eleventh O site, O(11) is bonded in a water-like geometry to one K(2) and one O(11) atom. is represented by the CIF card [CIF]
data_K2P4PtCSNO11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.583
_cell_length_b   7.912
_cell_length_c   10.987
_cell_angle_alpha   109.312
_cell_angle_beta   120.613
_cell_angle_gamma   84.703
_symmetry_Int_Tables_number   1
_cell_volume   814.266
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.285  0.750  0.584  1.0
  K  K1  1  0.715  0.250  0.416  1.0
  K  K2  1  0.169  0.475  0.811  1.0
  K  K3  1  0.831  0.525  0.189  1.0
  P  P4  1  0.157  0.450  0.210  1.0
  P  P5  1  0.843  0.550  0.790  1.0
  P  P6  1  0.946  0.261  0.909  1.0
  P  P7  1  0.054  0.739  0.091  1.0
  P  P8  1  0.856  0.033  0.163  1.0
  P  P9  1  0.144  0.967  0.837  1.0
  P  P10  1  0.588  0.959  0.866  1.0
  P  P11  1  0.412  0.041  0.134  1.0
  Pt  Pt12  1  0.056  0.037  0.164  1.0
  Pt  Pt13  1  0.944  0.963  0.836  1.0
  C  C14  1  0.243  0.272  0.524  1.0
  C  C15  1  0.757  0.728  0.476  1.0
  S  S16  1  0.227  0.061  0.418  1.0
  S  S17  1  0.773  0.939  0.582  1.0
  N  N18  1  0.257  0.421  0.603  1.0
  N  N19  1  0.743  0.579  0.397  1.0
  O  O20  1  0.101  0.354  0.032  1.0
  O  O21  1  0.899  0.646  0.968  1.0
  O  O22  1  0.087  0.337  0.247  1.0
  O  O23  1  0.913  0.663  0.753  1.0
  O  O24  1  0.304  0.494  0.301  1.0
  O  O25  1  0.696  0.506  0.699  1.0
  O  O26  1  0.846  0.313  0.958  1.0
  O  O27  1  0.154  0.687  0.042  1.0
  O  O28  1  0.918  0.357  0.784  1.0
  O  O29  1  0.082  0.643  0.216  1.0
  O  O30  1  0.739  0.025  0.981  1.0
  O  O31  1  0.261  0.975  0.019  1.0
  O  O32  1  0.829  0.867  0.185  1.0
  O  O33  1  0.171  0.133  0.815  1.0
  O  O34  1  0.852  0.217  0.259  1.0
  O  O35  1  0.148  0.783  0.741  1.0
  O  O36  1  0.525  0.815  0.876  1.0
  O  O37  1  0.475  0.185  0.124  1.0
  O  O38  1  0.522  0.048  0.751  1.0
  O  O39  1  0.478  0.952  0.249  1.0
  O  O40  1  0.473  0.422  0.961  1.0
  O  O41  1  0.527  0.578  0.039  1.0
[/CIF]
.