The material described by Ce2ZnBi4 crystallizes in the tetragonal P-4m2 space group. Ce(1) is bonded in a 10-coordinate geometry to two equivalent Zn(1), two equivalent Bi(2), two equivalent Bi(3), and four equivalent Bi(1) atoms. Zn(1) is bonded in a 8-coordinate geometry to four equivalent Ce(1) and four equivalent Bi(1) atoms. There are three inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a 6-coordinate geometry to four equivalent Ce(1) and two equivalent Zn(1) atoms. In the second Bi site, Bi(2) is bonded in a 8-coordinate geometry to four equivalent Ce(1) and four equivalent Bi(3) atoms. In the third Bi site, Bi(3) is bonded in a 8-coordinate geometry to four equivalent Ce(1) and four equivalent Bi(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ce2ZnBi4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.580
_cell_length_b   4.582
_cell_length_c   10.041
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   210.744
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.500  0.000  0.741  1.0
  Ce  Ce1  1  0.000  0.500  0.258  1.0
  Zn  Zn2  1  0.500  0.500  0.500  1.0
  Bi  Bi3  1  0.500  0.000  0.344  1.0
  Bi  Bi4  1  0.000  0.500  0.656  1.0
  Bi  Bi5  1  0.500  0.500  1.000  1.0
  Bi  Bi6  1  0.000  0.000  0.000  1.0
[/CIF]
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The material described by Ce2ZnBi4 crystallizes in the tetragonal P-4m2 space group. Ce(1) is bonded in a 10-coordinate geometry to two equivalent Zn(1), two equivalent Bi(2), two equivalent Bi(3), and four equivalent Bi(1) atoms. Zn(1) is bonded in a 8-coordinate geometry to four equivalent Ce(1) and four equivalent Bi(1) atoms. There are three inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a 6-coordinate geometry to four equivalent Ce(1) and two equivalent Zn(1) atoms. In the second Bi site, Bi(2) is bonded in a 8-coordinate geometry to four equivalent Ce(1) and four equivalent Bi(3) atoms. In the third Bi site, Bi(3) is bonded in a 8-coordinate geometry to four equivalent Ce(1) and four equivalent Bi(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ce2ZnBi4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.580
_cell_length_b   4.582
_cell_length_c   10.041
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   210.744
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.500  0.000  0.741  1.0
  Ce  Ce1  1  0.000  0.500  0.258  1.0
  Zn  Zn2  1  0.500  0.500  0.500  1.0
  Bi  Bi3  1  0.500  0.000  0.344  1.0
  Bi  Bi4  1  0.000  0.500  0.656  1.0
  Bi  Bi5  1  0.500  0.500  1.000  1.0
  Bi  Bi6  1  0.000  0.000  0.000  1.0
[/CIF]
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