The crystal structure described by Li4WO5 crystallizes in the triclinic P-1 space group. There are five inequivalent Li sites. In the first Li site, Li(1) is bonded in a 2-coordinate geometry to one W(1), one O(2), and two equivalent O(5) atoms. In the second Li site, Li(2) is bonded in a 2-coordinate geometry to one W(1), one O(2), one O(4), and one O(5) atom. In the third Li site, Li(3) is bonded in a 2-coordinate geometry to one W(1), one O(3), and one O(5) atom. In the fourth Li site, Li(4) is bonded in a 8-coordinate geometry to two equivalent W(1), two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms. In the fifth Li site, Li(5) is bonded in a 2-coordinate geometry to two equivalent O(1) and two equivalent O(5) atoms. W(1) is bonded in a 12-coordinate geometry to one Li(1), one Li(2), one Li(3), one Li(4), one O(1), one O(2), two equivalent O(3), two equivalent O(4), and two equivalent O(5) atoms. There are five inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Li(4), one Li(5), and one W(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Li(1), one Li(2), and one W(1) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Li(3), one Li(4), and two equivalent W(1) atoms. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Li(2), one Li(4), and two equivalent W(1) atoms. In the fifth O site, O(5) is bonded in a 7-coordinate geometry to one Li(2), one Li(3), one Li(5), two equivalent Li(1), and two equivalent W(1) atoms. is represented by the CIF file [CIF]
data_Li4WO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.158
_cell_length_b   5.189
_cell_length_c   7.863
_cell_angle_alpha   108.546
_cell_angle_beta   101.638
_cell_angle_gamma   101.342
_symmetry_Int_Tables_number   1
_cell_volume   187.535
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.306  0.997  0.391  1.0
  Li  Li1  1  0.680  0.496  0.099  1.0
  Li  Li2  1  0.874  0.498  0.696  1.0
  Li  Li3  1  0.500  0.000  0.000  1.0
  Li  Li4  1  0.320  0.504  0.901  1.0
  Li  Li5  1  0.126  0.502  0.304  1.0
  Li  Li6  1  0.694  0.003  0.609  1.0
  Li  Li7  1  0.500  0.500  0.500  1.0
  W  W8  1  0.107  0.000  0.784  1.0
  W  W9  1  0.893  1.000  0.216  1.0
  O  O10  1  0.716  0.232  0.335  1.0
  O  O11  1  0.529  0.761  0.249  1.0
  O  O12  1  0.471  0.239  0.751  1.0
  O  O13  1  0.272  0.236  0.155  1.0
  O  O14  1  0.284  0.768  0.665  1.0
  O  O15  1  0.090  0.784  0.042  1.0
  O  O16  1  0.906  0.760  0.428  1.0
  O  O17  1  0.910  0.216  0.958  1.0
  O  O18  1  0.728  0.764  0.845  1.0
  O  O19  1  0.094  0.240  0.572  1.0
[/CIF]
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The crystal structure described by Li4WO5 crystallizes in the triclinic P-1 space group. There are five inequivalent Li sites. In the first Li site, Li(1) is bonded in a 2-coordinate geometry to one W(1), one O(2), and two equivalent O(5) atoms. In the second Li site, Li(2) is bonded in a 2-coordinate geometry to one W(1), one O(2), one O(4), and one O(5) atom. In the third Li site, Li(3) is bonded in a 2-coordinate geometry to one W(1), one O(3), and one O(5) atom. In the fourth Li site, Li(4) is bonded in a 8-coordinate geometry to two equivalent W(1), two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms. In the fifth Li site, Li(5) is bonded in a 2-coordinate geometry to two equivalent O(1) and two equivalent O(5) atoms. W(1) is bonded in a 12-coordinate geometry to one Li(1), one Li(2), one Li(3), one Li(4), one O(1), one O(2), two equivalent O(3), two equivalent O(4), and two equivalent O(5) atoms. There are five inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Li(4), one Li(5), and one W(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Li(1), one Li(2), and one W(1) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Li(3), one Li(4), and two equivalent W(1) atoms. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Li(2), one Li(4), and two equivalent W(1) atoms. In the fifth O site, O(5) is bonded in a 7-coordinate geometry to one Li(2), one Li(3), one Li(5), two equivalent Li(1), and two equivalent W(1) atoms. is represented by the CIF file [CIF]
data_Li4WO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.158
_cell_length_b   5.189
_cell_length_c   7.863
_cell_angle_alpha   108.546
_cell_angle_beta   101.638
_cell_angle_gamma   101.342
_symmetry_Int_Tables_number   1
_cell_volume   187.535
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.306  0.997  0.391  1.0
  Li  Li1  1  0.680  0.496  0.099  1.0
  Li  Li2  1  0.874  0.498  0.696  1.0
  Li  Li3  1  0.500  0.000  0.000  1.0
  Li  Li4  1  0.320  0.504  0.901  1.0
  Li  Li5  1  0.126  0.502  0.304  1.0
  Li  Li6  1  0.694  0.003  0.609  1.0
  Li  Li7  1  0.500  0.500  0.500  1.0
  W  W8  1  0.107  0.000  0.784  1.0
  W  W9  1  0.893  1.000  0.216  1.0
  O  O10  1  0.716  0.232  0.335  1.0
  O  O11  1  0.529  0.761  0.249  1.0
  O  O12  1  0.471  0.239  0.751  1.0
  O  O13  1  0.272  0.236  0.155  1.0
  O  O14  1  0.284  0.768  0.665  1.0
  O  O15  1  0.090  0.784  0.042  1.0
  O  O16  1  0.906  0.760  0.428  1.0
  O  O17  1  0.910  0.216  0.958  1.0
  O  O18  1  0.728  0.764  0.845  1.0
  O  O19  1  0.094  0.240  0.572  1.0
[/CIF]
.