The structure described by Li6TiNi7O16 crystallizes in the triclinic P1 space group. There are six inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(10), one O(2), one O(3), one O(6), one O(7), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra,  a cornercorner with one Ni(3)O6 octahedra,  a cornercorner with one Ni(4)O6 octahedra,  a cornercorner with one Ni(5)O6 octahedra,  a cornercorner with one Ni(7)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra,  an edgeedge with one Ni(4)O6 octahedra,  an edgeedge with one Ni(5)O6 octahedra, and  an edgeedge with one Ni(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-12°. In the second Li site, Li(2) is bonded to one O(10), one O(13), one O(2), one O(4), one O(5), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Ni(1)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra,  a cornercorner with one Ni(3)O6 octahedra,  a cornercorner with one Ni(5)O6 octahedra,  a cornercorner with one Ni(6)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra,  an edgeedge with one Ni(4)O6 octahedra, and  an edgeedge with one Ni(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-15°. In the third Li site, Li(3) is bonded to one O(1), one O(11), one O(3), one O(5), one O(6), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Ni(1)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra,  a cornercorner with one Ni(3)O6 octahedra,  a cornercorner with one Ni(4)O6 octahedra,  a cornercorner with one Ni(6)O6 octahedra,  a cornercorner with one Ni(7)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra,  an edgeedge with one Ni(4)O6 octahedra, and  an edgeedge with one Ni(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-14°. In the fourth Li site, Li(4) is bonded to one O(11), one O(12), one O(14), one O(16), one O(6), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Ni(1)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra,  a cornercorner with one Ni(4)O6 octahedra,  a cornercorner with one Ni(5)O6 octahedra,  a cornercorner with one Ni(6)O6 octahedra,  a cornercorner with one Ni(7)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra,  an edgeedge with one Ni(4)O6 octahedra,  an edgeedge with one Ni(5)O6 octahedra,  an edgeedge with one Ni(6)O6 octahedra, and  an edgeedge with one Ni(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-14°. In the fifth Li site, Li(5) is bonded to one O(12), one O(13), one O(15), one O(4), one O(7), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra,  a cornercorner with one Ni(3)O6 octahedra,  a cornercorner with one Ni(5)O6 octahedra,  a cornercorner with one Ni(6)O6 octahedra,  a cornercorner with one Ni(7)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(4)O6 octahedra,  an edgeedge with one Ni(5)O6 octahedra,  an edgeedge with one Ni(6)O6 octahedra, and  an edgeedge with one Ni(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-16°. In the sixth Li site, Li(6) is bonded to one O(1), one O(13), one O(14), one O(15), one O(16), and one O(5) atom to form distorted LiO6 octahedra that share  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Ni(1)O6 octahedra,  a cornercorner with one Ni(3)O6 octahedra,  a cornercorner with one Ni(4)O6 octahedra,  a cornercorner with one Ni(6)O6 octahedra,  a cornercorner with one Ni(7)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra,  an edgeedge with one Ni(5)O6 octahedra,  an edgeedge with one Ni(6)O6 octahedra, and  an edgeedge with one Ni(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-16°. Ti(1) is bonded to one O(1), one O(13), one O(16), one O(4), one O(8), and one O(9) atom to form TiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra,  an edgeedge with one Ni(5)O6 octahedra,  an edgeedge with one Ni(6)O6 octahedra, and  an edgeedge with one Ni(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-13°. There are seven inequivalent Ni sites. In the first Ni site, Ni(1) is bonded to one O(1), one O(15), one O(2), one O(4), one O(5), and one O(6) atom to form NiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra,  an edgeedge with one Ni(4)O6 octahedra,  an edgeedge with one Ni(6)O6 octahedra, and  an edgeedge with one Ni(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-16°. In the second Ni site, Ni(2) is bonded to one O(16), one O(2), one O(3), one O(5), one O(7), and one O(9) atom to form NiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra,  an edgeedge with one Ni(4)O6 octahedra,  an edgeedge with one Ni(5)O6 octahedra, and  an edgeedge with one Ni(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-12°. In the third Ni site, Ni(3) is bonded to one O(10), one O(14), one O(3), one O(4), one O(6), and one O(9) atom to form NiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra,  an edgeedge with one Ni(4)O6 octahedra,  an edgeedge with one Ni(5)O6 octahedra, and  an edgeedge with one Ni(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-14°. In the fourth Ni site, Ni(4) is bonded to one O(10), one O(11), one O(12), one O(5), one O(6), and one O(7) atom to form NiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra,  an edgeedge with one Ni(5)O6 octahedra,  an edgeedge with one Ni(6)O6 octahedra, and  an edgeedge with one Ni(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-12°. In the fifth Ni site, Ni(5) is bonded to one O(11), one O(13), one O(14), one O(3), one O(7), and one O(8) atom to form NiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra,  an edgeedge with one Ni(4)O6 octahedra,  an edgeedge with one Ni(6)O6 octahedra, and  an edgeedge with one Ni(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-13°. In the sixth Ni site, Ni(6) is bonded to one O(1), one O(10), one O(12), one O(14), one O(15), and one O(8) atom to form NiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra,  an edgeedge with one Ni(4)O6 octahedra,  an edgeedge with one Ni(5)O6 octahedra, and  an edgeedge with one Ni(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-14°. In the seventh Ni site, Ni(7) is bonded to one O(11), one O(12), one O(13), one O(15), one O(16), and one O(2) atom to form NiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra,  an edgeedge with one Ni(4)O6 octahedra,  an edgeedge with one Ni(5)O6 octahedra, and  an edgeedge with one Ni(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-16°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded to one Li(3), one Li(6), one Ti(1), one Ni(1), and one Ni(6) atom to form OLi2TiNi2 square pyramids that share  a cornercorner with one O(5)Li3Ni3 octahedra,  a cornercorner with one O(10)Li2Ni3 square pyramid,  a cornercorner with one O(11)Li2Ni3 square pyramid,  a cornercorner with one O(12)Li2Ni3 square pyramid,  a cornercorner with one O(15)Li2Ni3 square pyramid,  a cornercorner with one O(2)Li2Ni3 square pyramid,  a cornercorner with one O(3)Li2Ni3 square pyramid, corners with two equivalent O(16)Li2TiNi2 square pyramids,  an edgeedge with one O(5)Li3Ni3 octahedra,  an edgeedge with one O(6)Li3Ni3 octahedra,  an edgeedge with one O(13)Li3TiNi2 octahedra,  an edgeedge with one O(8)Li3TiNi2 octahedra,  an edgeedge with one O(14)Li2Ni3 square pyramid,  an edgeedge with one O(15)Li2Ni3 square pyramid,  an edgeedge with one O(4)Li2TiNi2 square pyramid, and  an edgeedge with one O(9)Li2TiNi2 square pyramid. The corner-sharing octahedral tilt angles are 7°. In the second O site, O(2) is bonded to one Li(1), one Li(2), one Ni(1), one Ni(2), and one Ni(7) atom to form OLi2Ni3 square pyramids that share  a cornercorner with one O(5)Li3Ni3 octahedra,  a cornercorner with one O(8)Li3TiNi2 octahedra,  a cornercorner with one O(11)Li2Ni3 square pyramid,  a cornercorner with one O(12)Li2Ni3 square pyramid,  a cornercorner with one O(1)Li2TiNi2 square pyramid, corners with two equivalent O(3)Li2Ni3 square pyramids, corners with two equivalent O(4)Li2TiNi2 square pyramids,  an edgeedge with one O(5)Li3Ni3 octahedra,  an edgeedge with one O(6)Li3Ni3 octahedra,  an edgeedge with one O(13)Li3TiNi2 octahedra,  an edgeedge with one O(10)Li2Ni3 square pyramid,  an edgeedge with one O(15)Li2Ni3 square pyramid,  an edgeedge with one O(7)Li2Ni3 square pyramid,  an edgeedge with one O(16)Li2TiNi2 square pyramid, and  an edgeedge with one O(9)Li2TiNi2 square pyramid. The corner-sharing octahedral tilt angles range from 4-8°. In the third O site, O(3) is bonded to one Li(1), one Li(3), one Ni(2), one Ni(3), and one Ni(5) atom to form OLi2Ni3 square pyramids that share  a cornercorner with one O(6)Li3Ni3 octahedra,  a cornercorner with one O(13)Li3TiNi2 octahedra,  a cornercorner with one O(7)Li2Ni3 square pyramid,  a cornercorner with one O(1)Li2TiNi2 square pyramid,  a cornercorner with one O(16)Li2TiNi2 square pyramid,  a cornercorner with one O(4)Li2TiNi2 square pyramid,  a cornercorner with one O(9)Li2TiNi2 square pyramid, corners with two equivalent O(2)Li2Ni3 square pyramids,  an edgeedge with one O(5)Li3Ni3 octahedra,  an edgeedge with one O(6)Li3Ni3 octahedra,  an edgeedge with one O(8)Li3TiNi2 octahedra,  an edgeedge with one O(10)Li2Ni3 square pyramid,  an edgeedge with one O(11)Li2Ni3 square pyramid,  an edgeedge with one O(14)Li2Ni3 square pyramid,  an edgeedge with one O(7)Li2Ni3 square pyramid, and  an edgeedge with one O(9)Li2TiNi2 square pyramid. The corner-sharing octahedral tilt angles are 3°. In the fourth O site, O(4) is bonded to one Li(2), one Li(5), one Ti(1), one Ni(1), and one Ni(3) atom to form OLi2TiNi2 square pyramids that share  a cornercorner with one O(13)Li3TiNi2 octahedra,  a cornercorner with one O(12)Li2Ni3 square pyramid,  a cornercorner with one O(14)Li2Ni3 square pyramid,  a cornercorner with one O(3)Li2Ni3 square pyramid,  a cornercorner with one O(7)Li2Ni3 square pyramid,  a cornercorner with one O(16)Li2TiNi2 square pyramid,  a cornercorner with one O(9)Li2TiNi2 square pyramid, corners with two equivalent O(2)Li2Ni3 square pyramids,  an edgeedge with one O(5)Li3Ni3 octahedra,  an edgeedge with one O(6)Li3Ni3 octahedra,  an edgeedge with one O(13)Li3TiNi2 octahedra,  an edgeedge with one O(8)Li3TiNi2 octahedra,  an edgeedge with one O(10)Li2Ni3 square pyramid,  an edgeedge with one O(15)Li2Ni3 square pyramid,  an edgeedge with one O(1)Li2TiNi2 square pyramid, and  an edgeedge with one O(9)Li2TiNi2 square pyramid. The corner-sharing octahedral tilt angles are 5°. In the fifth O site, O(5) is bonded to one Li(2), one Li(3), one Li(6), one Ni(1), one Ni(2), and one Ni(4) atom to form OLi3Ni3 octahedra that share  a cornercorner with one O(6)Li3Ni3 octahedra,  a cornercorner with one O(12)Li2Ni3 square pyramid,  a cornercorner with one O(14)Li2Ni3 square pyramid,  a cornercorner with one O(2)Li2Ni3 square pyramid,  a cornercorner with one O(1)Li2TiNi2 square pyramid,  a cornercorner with one O(9)Li2TiNi2 square pyramid,  an edgeedge with one O(6)Li3Ni3 octahedra,  an edgeedge with one O(13)Li3TiNi2 octahedra,  an edgeedge with one O(10)Li2Ni3 square pyramid,  an edgeedge with one O(11)Li2Ni3 square pyramid,  an edgeedge with one O(15)Li2Ni3 square pyramid,  an edgeedge with one O(2)Li2Ni3 square pyramid,  an edgeedge with one O(3)Li2Ni3 square pyramid,  an edgeedge with one O(7)Li2Ni3 square pyramid,  an edgeedge with one O(1)Li2TiNi2 square pyramid,  an edgeedge with one O(16)Li2TiNi2 square pyramid,  an edgeedge with one O(4)Li2TiNi2 square pyramid, and  an edgeedge with one O(9)Li2TiNi2 square pyramid. The corner-sharing octahedral tilt angles are 3°. In the sixth O site, O(6) is bonded to one Li(1), one Li(3), one Li(4), one Ni(1), one Ni(3), and one Ni(4) atom to form OLi3Ni3 octahedra that share  a cornercorner with one O(5)Li3Ni3 octahedra,  a cornercorner with one O(10)Li2Ni3 square pyramid,  a cornercorner with one O(11)Li2Ni3 square pyramid,  a cornercorner with one O(15)Li2Ni3 square pyramid,  a cornercorner with one O(3)Li2Ni3 square pyramid,  a cornercorner with one O(16)Li2TiNi2 square pyramid,  an edgeedge with one O(5)Li3Ni3 octahedra,  an edgeedge with one O(8)Li3TiNi2 octahedra,  an edgeedge with one O(10)Li2Ni3 square pyramid,  an edgeedge with one O(11)Li2Ni3 square pyramid,  an edgeedge with one O(12)Li2Ni3 square pyramid,  an edgeedge with one O(14)Li2Ni3 square pyramid,  an edgeedge with one O(2)Li2Ni3 square pyramid,  an edgeedge with one O(3)Li2Ni3 square pyramid,  an edgeedge with one O(7)Li2Ni3 square pyramid,  an edgeedge with one O(1)Li2TiNi2 square pyramid,  an edgeedge with one O(4)Li2TiNi2 square pyramid, and  an edgeedge with one O(9)Li2TiNi2 square pyramid. The corner-sharing octahedral tilt angles are 3°. In the seventh O site, O(7) is bonded to one Li(1), one Li(5), one Ni(2), one Ni(4), and one Ni(5) atom to form OLi2Ni3 square pyramids that share  a cornercorner with one O(8)Li3TiNi2 octahedra,  a cornercorner with one O(14)Li2Ni3 square pyramid,  a cornercorner with one O(15)Li2Ni3 square pyramid,  a cornercorner with one O(3)Li2Ni3 square pyramid,  a cornercorner with one O(16)Li2TiNi2 square pyramid,  a cornercorner with one O(4)Li2TiNi2 square pyramid,  a cornercorner with one O(9)Li2TiNi2 square pyramid, corners with two equivalent O(10)Li2Ni3 square pyramids,  an edgeedge with one O(5)Li3Ni3 octahedra,  an edgeedge with one O(6)Li3Ni3 octahedra,  an edgeedge with one O(13)Li3TiNi2 octahedra,  an edgeedge with one O(8)Li3TiNi2 octahedra,  an edgeedge with one O(11)Li2Ni3 square pyramid,  an edgeedge with one O(12)Li2Ni3 square pyramid,  an edgeedge with one O(2)Li2Ni3 square pyramid, and  an edgeedge with one O(3)Li2Ni3 square pyramid. The corner-sharing octahedral tilt angles are 3°. In the eighth O site, O(8) is bonded to one Li(1), one Li(4), one Li(5), one Ti(1), one Ni(5), and one Ni(6) atom to form OLi3TiNi2 octahedra that share  a cornercorner with one O(13)Li3TiNi2 octahedra,  a cornercorner with one O(12)Li2Ni3 square pyramid,  a cornercorner with one O(14)Li2Ni3 square pyramid,  a cornercorner with one O(2)Li2Ni3 square pyramid,  a cornercorner with one O(7)Li2Ni3 square pyramid,  a cornercorner with one O(9)Li2TiNi2 square pyramid,  an edgeedge with one O(6)Li3Ni3 octahedra,  an edgeedge with one O(13)Li3TiNi2 octahedra,  an edgeedge with one O(10)Li2Ni3 square pyramid,  an edgeedge with one O(11)Li2Ni3 square pyramid,  an edgeedge with one O(12)Li2Ni3 square pyramid,  an edgeedge with one O(14)Li2Ni3 square pyramid,  an edgeedge with one O(15)Li2Ni3 square pyramid,  an edgeedge with one O(3)Li2Ni3 square pyramid,  an edgeedge with one O(7)Li2Ni3 square pyramid,  an edgeedge with one O(1)Li2TiNi2 square pyramid,  an edgeedge with one O(16)Li2TiNi2 square pyramid, and  an edgeedge with one O(4)Li2TiNi2 square pyramid. The corner-sharing octahedral tilt angles are 5°. In the ninth O site, O(9) is bonded to one Li(2), one Li(3), one Ti(1), one Ni(2), and one Ni(3) atom to form OLi2TiNi2 square pyramids that share  a cornercorner with one O(5)Li3Ni3 octahedra,  a cornercorner with one O(8)Li3TiNi2 octahedra,  a cornercorner with one O(11)Li2Ni3 square pyramid,  a cornercorner with one O(14)Li2Ni3 square pyramid,  a cornercorner with one O(3)Li2Ni3 square pyramid,  a cornercorner with one O(7)Li2Ni3 square pyramid,  a cornercorner with one O(4)Li2TiNi2 square pyramid, corners with two equivalent O(10)Li2Ni3 square pyramids,  an edgeedge with one O(5)Li3Ni3 octahedra,  an edgeedge with one O(6)Li3Ni3 octahedra,  an edgeedge with one O(13)Li3TiNi2 octahedra,  an edgeedge with one O(2)Li2Ni3 square pyramid,  an edgeedge with one O(3)Li2Ni3 square pyramid,  an edgeedge with one O(1)Li2TiNi2 square pyramid,  an edgeedge with one O(16)Li2TiNi2 square pyramid, and  an edgeedge with one O(4)Li2TiNi2 square pyramid. The corner-sharing octahedral tilt angles are 2°. In the tenth O site, O(10) is bonded to one Li(1), one Li(2), one Ni(3), one Ni(4), and one Ni(6) atom to form OLi2Ni3 square pyramids that share  a cornercorner with one O(6)Li3Ni3 octahedra,  a cornercorner with one O(13)Li3TiNi2 octahedra,  a cornercorner with one O(11)Li2Ni3 square pyramid,  a cornercorner with one O(15)Li2Ni3 square pyramid,  a cornercorner with one O(1)Li2TiNi2 square pyramid, corners with two equivalent O(7)Li2Ni3 square pyramids, corners with two equivalent O(9)Li2TiNi2 square pyramids,  an edgeedge with one O(5)Li3Ni3 octahedra,  an edgeedge with one O(6)Li3Ni3 octahedra,  an edgeedge with one O(8)Li3TiNi2 octahedra,  an edgeedge with one O(12)Li2Ni3 square pyramid,  an edgeedge with one O(14)Li2Ni3 square pyramid,  an edgeedge with one O(2)Li2Ni3 square pyramid,  an edgeedge with one O(3)Li2Ni3 square pyramid, and  an edgeedge with one O(4)Li2TiNi2 square pyramid. The corner-sharing octahedral tilt angles range from 3-7°. In the eleventh O site, O(11) is bonded to one Li(3), one Li(4), one Ni(4), one Ni(5), and one Ni(7) atom to form OLi2Ni3 square pyramids that share  a cornercorner with one O(6)Li3Ni3 octahedra,  a cornercorner with one O(10)Li2Ni3 square pyramid,  a cornercorner with one O(12)Li2Ni3 square pyramid,  a cornercorner with one O(15)Li2Ni3 square pyramid,  a cornercorner with one O(2)Li2Ni3 square pyramid,  a cornercorner with one O(1)Li2TiNi2 square pyramid,  a cornercorner with one O(9)Li2TiNi2 square pyramid, corners with two equivalent O(14)Li2Ni3 square pyramids,  an edgeedge with one O(5)Li3Ni3 octahedra,  an edgeedge with one O(6)Li3Ni3 octahedra,  an edgeedge with one O(13)Li3TiNi2 octahedra,  an edgeedge with one O(8)Li3TiNi2 octahedra,  an edgeedge with one O(12)Li2Ni3 square pyramid,  an edgeedge with one O(3)Li2Ni3 square pyramid,  an edgeedge with one O(7)Li2Ni3 square pyramid, and  an edgeedge with one O(16)Li2TiNi2 square pyramid. The corner-sharing octahedral tilt angles are 3°. In the twelfth O site, O(12) is bonded to one Li(4), one Li(5), one Ni(4), one Ni(6), and one Ni(7) atom to form OLi2Ni3 square pyramids that share  a cornercorner with one O(5)Li3Ni3 octahedra,  a cornercorner with one O(8)Li3TiNi2 octahedra,  a cornercorner with one O(11)Li2Ni3 square pyramid,  a cornercorner with one O(15)Li2Ni3 square pyramid,  a cornercorner with one O(2)Li2Ni3 square pyramid,  a cornercorner with one O(1)Li2TiNi2 square pyramid,  a cornercorner with one O(4)Li2TiNi2 square pyramid, corners with two equivalent O(16)Li2TiNi2 square pyramids,  an edgeedge with one O(6)Li3Ni3 octahedra,  an edgeedge with one O(13)Li3TiNi2 octahedra,  an edgeedge with one O(8)Li3TiNi2 octahedra,  an edgeedge with one O(10)Li2Ni3 square pyramid,  an edgeedge with one O(11)Li2Ni3 square pyramid,  an edgeedge with one O(14)Li2Ni3 square pyramid,  an edgeedge with one O(15)Li2Ni3 square pyramid, and  an edgeedge with one O(7)Li2Ni3 square pyramid. The corner-sharing octahedral tilt angles range from 1-5°. In the thirteenth O site, O(13) is bonded to one Li(2), one Li(5), one Li(6), one Ti(1), one Ni(5), and one Ni(7) atom to form OLi3TiNi2 octahedra that share  a cornercorner with one O(8)Li3TiNi2 octahedra,  a cornercorner with one O(10)Li2Ni3 square pyramid,  a cornercorner with one O(15)Li2Ni3 square pyramid,  a cornercorner with one O(3)Li2Ni3 square pyramid,  a cornercorner with one O(16)Li2TiNi2 square pyramid,  a cornercorner with one O(4)Li2TiNi2 square pyramid,  an edgeedge with one O(5)Li3Ni3 octahedra,  an edgeedge with one O(8)Li3TiNi2 octahedra,  an edgeedge with one O(11)Li2Ni3 square pyramid,  an edgeedge with one O(12)Li2Ni3 square pyramid,  an edgeedge with one O(14)Li2Ni3 square pyramid,  an edgeedge with one O(15)Li2Ni3 square pyramid,  an edgeedge with one O(2)Li2Ni3 square pyramid,  an edgeedge with one O(7)Li2Ni3 square pyramid,  an edgeedge with one O(1)Li2TiNi2 square pyramid,  an edgeedge with one O(16)Li2TiNi2 square pyramid,  an edgeedge with one O(4)Li2TiNi2 square pyramid, and  an edgeedge with one O(9)Li2TiNi2 square pyramid. The corner-sharing octahedral tilt angles are 5°. In the fourteenth O site, O(14) is bonded to one Li(4), one Li(6), one Ni(3), one Ni(5), and one Ni(6) atom to form OLi2Ni3 square pyramids that share  a cornercorner with one O(5)Li3Ni3 octahedra,  a cornercorner with one O(8)Li3TiNi2 octahedra,  a cornercorner with one O(7)Li2Ni3 square pyramid,  a cornercorner with one O(4)Li2TiNi2 square pyramid,  a cornercorner with one O(9)Li2TiNi2 square pyramid, corners with two equivalent O(11)Li2Ni3 square pyramids, corners with two equivalent O(15)Li2Ni3 square pyramids,  an edgeedge with one O(6)Li3Ni3 octahedra,  an edgeedge with one O(13)Li3TiNi2 octahedra,  an edgeedge with one O(8)Li3TiNi2 octahedra,  an edgeedge with one O(10)Li2Ni3 square pyramid,  an edgeedge with one O(12)Li2Ni3 square pyramid,  an edgeedge with one O(3)Li2Ni3 square pyramid,  an edgeedge with one O(1)Li2TiNi2 square pyramid, and  an edgeedge with one O(16)Li2TiNi2 square pyramid. The corner-sharing octahedral tilt angles range from 6-8°. In the fifteenth O site, O(15) is bonded to one Li(5), one Li(6), one Ni(1), one Ni(6), and one Ni(7) atom to form OLi2Ni3 square pyramids that share  a cornercorner with one O(6)Li3Ni3 octahedra,  a cornercorner with one O(13)Li3TiNi2 octahedra,  a cornercorner with one O(10)Li2Ni3 square pyramid,  a cornercorner with one O(11)Li2Ni3 square pyramid,  a cornercorner with one O(12)Li2Ni3 square pyramid,  a cornercorner with one O(7)Li2Ni3 square pyramid,  a cornercorner with one O(1)Li2TiNi2 square pyramid, corners with two equivalent O(14)Li2Ni3 square pyramids,  an edgeedge with one O(5)Li3Ni3 octahedra,  an edgeedge with one O(13)Li3TiNi2 octahedra,  an edgeedge with one O(8)Li3TiNi2 octahedra,  an edgeedge with one O(12)Li2Ni3 square pyramid,  an edgeedge with one O(2)Li2Ni3 square pyramid,  an edgeedge with one O(1)Li2TiNi2 square pyramid,  an edgeedge with one O(16)Li2TiNi2 square pyramid, and  an edgeedge with one O(4)Li2TiNi2 square pyramid. The corner-sharing octahedral tilt angles range from 2-3°. In the sixteenth O site, O(16) is bonded to one Li(4), one Li(6), one Ti(1), one Ni(2), and one Ni(7) atom to form OLi2TiNi2 square pyramids that share  a cornercorner with one O(6)Li3Ni3 octahedra,  a cornercorner with one O(13)Li3TiNi2 octahedra,  a cornercorner with one O(3)Li2Ni3 square pyramid,  a cornercorner with one O(7)Li2Ni3 square pyramid,  a cornercorner with one O(4)Li2TiNi2 square pyramid, corners with two equivalent O(12)Li2Ni3 square pyramids, corners with two equivalent O(1)Li2TiNi2 square pyramids,  an edgeedge with one O(5)Li3Ni3 octahedra,  an edgeedge with one O(13)Li3TiNi2 octahedra,  an edgeedge with one O(8)Li3TiNi2 octahedra,  an edgeedge with one O(11)Li2Ni3 square pyramid,  an edgeedge with one O(14)Li2Ni3 square pyramid,  an edgeedge with one O(15)Li2Ni3 square pyramid,  an edgeedge with one O(2)Li2Ni3 square pyramid, and  an edgeedge with one O(9)Li2TiNi2 square pyramid. The corner-sharing octahedral tilt angles range from 5-6°. is represented by the CIF card [CIF]
data_Li6TiNi7O16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.422
_cell_length_b   6.553
_cell_length_c   7.692
_cell_angle_alpha   75.970
_cell_angle_beta   65.818
_cell_angle_gamma   70.801
_symmetry_Int_Tables_number   1
_cell_volume   276.681
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.177  0.321  0.443  1.0
  Li  Li1  1  0.943  0.549  0.195  1.0
  Li  Li2  1  0.561  0.932  0.310  1.0
  Li  Li3  1  0.452  0.060  0.688  1.0
  Li  Li4  1  0.058  0.452  0.803  1.0
  Li  Li5  1  0.668  0.831  0.931  1.0
  Ti  Ti6  1  0.007  0.020  0.995  1.0
  Ni  Ni7  1  0.610  0.372  0.130  1.0
  Ni  Ni8  1  0.250  0.752  0.257  1.0
  Ni  Ni9  1  0.876  0.124  0.375  1.0
  Ni  Ni10  1  0.503  0.498  0.497  1.0
  Ni  Ni11  1  0.124  0.867  0.627  1.0
  Ni  Ni12  1  0.750  0.251  0.751  1.0
  Ni  Ni13  1  0.373  0.619  0.875  1.0
  O  O14  1  0.683  0.076  0.031  1.0
  O  O15  1  0.289  0.497  0.157  1.0
  O  O16  1  0.204  0.000  0.371  1.0
  O  O17  1  0.938  0.283  0.098  1.0
  O  O18  1  0.568  0.647  0.244  1.0
  O  O19  1  0.540  0.244  0.395  1.0
  O  O20  1  0.188  0.583  0.530  1.0
  O  O21  1  0.076  0.162  0.731  1.0
  O  O22  1  0.932  0.867  0.268  1.0
  O  O23  1  0.831  0.384  0.460  1.0
  O  O24  1  0.449  0.754  0.595  1.0
  O  O25  1  0.437  0.355  0.749  1.0
  O  O26  1  0.055  0.729  0.893  1.0
  O  O27  1  0.800  0.993  0.655  1.0
  O  O28  1  0.686  0.505  0.869  1.0
  O  O29  1  0.336  0.896  0.958  1.0
[/CIF]
.
The structure described by Li6TiNi7O16 crystallizes in the triclinic P1 space group. There are six inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(10), one O(2), one O(3), one O(6), one O(7), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra,  a cornercorner with one Ni(3)O6 octahedra,  a cornercorner with one Ni(4)O6 octahedra,  a cornercorner with one Ni(5)O6 octahedra,  a cornercorner with one Ni(7)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra,  an edgeedge with one Ni(4)O6 octahedra,  an edgeedge with one Ni(5)O6 octahedra, and  an edgeedge with one Ni(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-12°. In the second Li site, Li(2) is bonded to one O(10), one O(13), one O(2), one O(4), one O(5), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Ni(1)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra,  a cornercorner with one Ni(3)O6 octahedra,  a cornercorner with one Ni(5)O6 octahedra,  a cornercorner with one Ni(6)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra,  an edgeedge with one Ni(4)O6 octahedra, and  an edgeedge with one Ni(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-15°. In the third Li site, Li(3) is bonded to one O(1), one O(11), one O(3), one O(5), one O(6), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Ni(1)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra,  a cornercorner with one Ni(3)O6 octahedra,  a cornercorner with one Ni(4)O6 octahedra,  a cornercorner with one Ni(6)O6 octahedra,  a cornercorner with one Ni(7)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra,  an edgeedge with one Ni(4)O6 octahedra, and  an edgeedge with one Ni(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-14°. In the fourth Li site, Li(4) is bonded to one O(11), one O(12), one O(14), one O(16), one O(6), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Ni(1)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra,  a cornercorner with one Ni(4)O6 octahedra,  a cornercorner with one Ni(5)O6 octahedra,  a cornercorner with one Ni(6)O6 octahedra,  a cornercorner with one Ni(7)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra,  an edgeedge with one Ni(4)O6 octahedra,  an edgeedge with one Ni(5)O6 octahedra,  an edgeedge with one Ni(6)O6 octahedra, and  an edgeedge with one Ni(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-14°. In the fifth Li site, Li(5) is bonded to one O(12), one O(13), one O(15), one O(4), one O(7), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra,  a cornercorner with one Ni(3)O6 octahedra,  a cornercorner with one Ni(5)O6 octahedra,  a cornercorner with one Ni(6)O6 octahedra,  a cornercorner with one Ni(7)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(4)O6 octahedra,  an edgeedge with one Ni(5)O6 octahedra,  an edgeedge with one Ni(6)O6 octahedra, and  an edgeedge with one Ni(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-16°. In the sixth Li site, Li(6) is bonded to one O(1), one O(13), one O(14), one O(15), one O(16), and one O(5) atom to form distorted LiO6 octahedra that share  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Ni(1)O6 octahedra,  a cornercorner with one Ni(3)O6 octahedra,  a cornercorner with one Ni(4)O6 octahedra,  a cornercorner with one Ni(6)O6 octahedra,  a cornercorner with one Ni(7)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra,  an edgeedge with one Ni(5)O6 octahedra,  an edgeedge with one Ni(6)O6 octahedra, and  an edgeedge with one Ni(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-16°. Ti(1) is bonded to one O(1), one O(13), one O(16), one O(4), one O(8), and one O(9) atom to form TiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra,  an edgeedge with one Ni(5)O6 octahedra,  an edgeedge with one Ni(6)O6 octahedra, and  an edgeedge with one Ni(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-13°. There are seven inequivalent Ni sites. In the first Ni site, Ni(1) is bonded to one O(1), one O(15), one O(2), one O(4), one O(5), and one O(6) atom to form NiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra,  an edgeedge with one Ni(4)O6 octahedra,  an edgeedge with one Ni(6)O6 octahedra, and  an edgeedge with one Ni(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-16°. In the second Ni site, Ni(2) is bonded to one O(16), one O(2), one O(3), one O(5), one O(7), and one O(9) atom to form NiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra,  an edgeedge with one Ni(4)O6 octahedra,  an edgeedge with one Ni(5)O6 octahedra, and  an edgeedge with one Ni(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-12°. In the third Ni site, Ni(3) is bonded to one O(10), one O(14), one O(3), one O(4), one O(6), and one O(9) atom to form NiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra,  an edgeedge with one Ni(4)O6 octahedra,  an edgeedge with one Ni(5)O6 octahedra, and  an edgeedge with one Ni(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-14°. In the fourth Ni site, Ni(4) is bonded to one O(10), one O(11), one O(12), one O(5), one O(6), and one O(7) atom to form NiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra,  an edgeedge with one Ni(5)O6 octahedra,  an edgeedge with one Ni(6)O6 octahedra, and  an edgeedge with one Ni(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-12°. In the fifth Ni site, Ni(5) is bonded to one O(11), one O(13), one O(14), one O(3), one O(7), and one O(8) atom to form NiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra,  an edgeedge with one Ni(4)O6 octahedra,  an edgeedge with one Ni(6)O6 octahedra, and  an edgeedge with one Ni(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-13°. In the sixth Ni site, Ni(6) is bonded to one O(1), one O(10), one O(12), one O(14), one O(15), and one O(8) atom to form NiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra,  an edgeedge with one Ni(4)O6 octahedra,  an edgeedge with one Ni(5)O6 octahedra, and  an edgeedge with one Ni(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-14°. In the seventh Ni site, Ni(7) is bonded to one O(11), one O(12), one O(13), one O(15), one O(16), and one O(2) atom to form NiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra,  an edgeedge with one Ni(4)O6 octahedra,  an edgeedge with one Ni(5)O6 octahedra, and  an edgeedge with one Ni(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-16°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded to one Li(3), one Li(6), one Ti(1), one Ni(1), and one Ni(6) atom to form OLi2TiNi2 square pyramids that share  a cornercorner with one O(5)Li3Ni3 octahedra,  a cornercorner with one O(10)Li2Ni3 square pyramid,  a cornercorner with one O(11)Li2Ni3 square pyramid,  a cornercorner with one O(12)Li2Ni3 square pyramid,  a cornercorner with one O(15)Li2Ni3 square pyramid,  a cornercorner with one O(2)Li2Ni3 square pyramid,  a cornercorner with one O(3)Li2Ni3 square pyramid, corners with two equivalent O(16)Li2TiNi2 square pyramids,  an edgeedge with one O(5)Li3Ni3 octahedra,  an edgeedge with one O(6)Li3Ni3 octahedra,  an edgeedge with one O(13)Li3TiNi2 octahedra,  an edgeedge with one O(8)Li3TiNi2 octahedra,  an edgeedge with one O(14)Li2Ni3 square pyramid,  an edgeedge with one O(15)Li2Ni3 square pyramid,  an edgeedge with one O(4)Li2TiNi2 square pyramid, and  an edgeedge with one O(9)Li2TiNi2 square pyramid. The corner-sharing octahedral tilt angles are 7°. In the second O site, O(2) is bonded to one Li(1), one Li(2), one Ni(1), one Ni(2), and one Ni(7) atom to form OLi2Ni3 square pyramids that share  a cornercorner with one O(5)Li3Ni3 octahedra,  a cornercorner with one O(8)Li3TiNi2 octahedra,  a cornercorner with one O(11)Li2Ni3 square pyramid,  a cornercorner with one O(12)Li2Ni3 square pyramid,  a cornercorner with one O(1)Li2TiNi2 square pyramid, corners with two equivalent O(3)Li2Ni3 square pyramids, corners with two equivalent O(4)Li2TiNi2 square pyramids,  an edgeedge with one O(5)Li3Ni3 octahedra,  an edgeedge with one O(6)Li3Ni3 octahedra,  an edgeedge with one O(13)Li3TiNi2 octahedra,  an edgeedge with one O(10)Li2Ni3 square pyramid,  an edgeedge with one O(15)Li2Ni3 square pyramid,  an edgeedge with one O(7)Li2Ni3 square pyramid,  an edgeedge with one O(16)Li2TiNi2 square pyramid, and  an edgeedge with one O(9)Li2TiNi2 square pyramid. The corner-sharing octahedral tilt angles range from 4-8°. In the third O site, O(3) is bonded to one Li(1), one Li(3), one Ni(2), one Ni(3), and one Ni(5) atom to form OLi2Ni3 square pyramids that share  a cornercorner with one O(6)Li3Ni3 octahedra,  a cornercorner with one O(13)Li3TiNi2 octahedra,  a cornercorner with one O(7)Li2Ni3 square pyramid,  a cornercorner with one O(1)Li2TiNi2 square pyramid,  a cornercorner with one O(16)Li2TiNi2 square pyramid,  a cornercorner with one O(4)Li2TiNi2 square pyramid,  a cornercorner with one O(9)Li2TiNi2 square pyramid, corners with two equivalent O(2)Li2Ni3 square pyramids,  an edgeedge with one O(5)Li3Ni3 octahedra,  an edgeedge with one O(6)Li3Ni3 octahedra,  an edgeedge with one O(8)Li3TiNi2 octahedra,  an edgeedge with one O(10)Li2Ni3 square pyramid,  an edgeedge with one O(11)Li2Ni3 square pyramid,  an edgeedge with one O(14)Li2Ni3 square pyramid,  an edgeedge with one O(7)Li2Ni3 square pyramid, and  an edgeedge with one O(9)Li2TiNi2 square pyramid. The corner-sharing octahedral tilt angles are 3°. In the fourth O site, O(4) is bonded to one Li(2), one Li(5), one Ti(1), one Ni(1), and one Ni(3) atom to form OLi2TiNi2 square pyramids that share  a cornercorner with one O(13)Li3TiNi2 octahedra,  a cornercorner with one O(12)Li2Ni3 square pyramid,  a cornercorner with one O(14)Li2Ni3 square pyramid,  a cornercorner with one O(3)Li2Ni3 square pyramid,  a cornercorner with one O(7)Li2Ni3 square pyramid,  a cornercorner with one O(16)Li2TiNi2 square pyramid,  a cornercorner with one O(9)Li2TiNi2 square pyramid, corners with two equivalent O(2)Li2Ni3 square pyramids,  an edgeedge with one O(5)Li3Ni3 octahedra,  an edgeedge with one O(6)Li3Ni3 octahedra,  an edgeedge with one O(13)Li3TiNi2 octahedra,  an edgeedge with one O(8)Li3TiNi2 octahedra,  an edgeedge with one O(10)Li2Ni3 square pyramid,  an edgeedge with one O(15)Li2Ni3 square pyramid,  an edgeedge with one O(1)Li2TiNi2 square pyramid, and  an edgeedge with one O(9)Li2TiNi2 square pyramid. The corner-sharing octahedral tilt angles are 5°. In the fifth O site, O(5) is bonded to one Li(2), one Li(3), one Li(6), one Ni(1), one Ni(2), and one Ni(4) atom to form OLi3Ni3 octahedra that share  a cornercorner with one O(6)Li3Ni3 octahedra,  a cornercorner with one O(12)Li2Ni3 square pyramid,  a cornercorner with one O(14)Li2Ni3 square pyramid,  a cornercorner with one O(2)Li2Ni3 square pyramid,  a cornercorner with one O(1)Li2TiNi2 square pyramid,  a cornercorner with one O(9)Li2TiNi2 square pyramid,  an edgeedge with one O(6)Li3Ni3 octahedra,  an edgeedge with one O(13)Li3TiNi2 octahedra,  an edgeedge with one O(10)Li2Ni3 square pyramid,  an edgeedge with one O(11)Li2Ni3 square pyramid,  an edgeedge with one O(15)Li2Ni3 square pyramid,  an edgeedge with one O(2)Li2Ni3 square pyramid,  an edgeedge with one O(3)Li2Ni3 square pyramid,  an edgeedge with one O(7)Li2Ni3 square pyramid,  an edgeedge with one O(1)Li2TiNi2 square pyramid,  an edgeedge with one O(16)Li2TiNi2 square pyramid,  an edgeedge with one O(4)Li2TiNi2 square pyramid, and  an edgeedge with one O(9)Li2TiNi2 square pyramid. The corner-sharing octahedral tilt angles are 3°. In the sixth O site, O(6) is bonded to one Li(1), one Li(3), one Li(4), one Ni(1), one Ni(3), and one Ni(4) atom to form OLi3Ni3 octahedra that share  a cornercorner with one O(5)Li3Ni3 octahedra,  a cornercorner with one O(10)Li2Ni3 square pyramid,  a cornercorner with one O(11)Li2Ni3 square pyramid,  a cornercorner with one O(15)Li2Ni3 square pyramid,  a cornercorner with one O(3)Li2Ni3 square pyramid,  a cornercorner with one O(16)Li2TiNi2 square pyramid,  an edgeedge with one O(5)Li3Ni3 octahedra,  an edgeedge with one O(8)Li3TiNi2 octahedra,  an edgeedge with one O(10)Li2Ni3 square pyramid,  an edgeedge with one O(11)Li2Ni3 square pyramid,  an edgeedge with one O(12)Li2Ni3 square pyramid,  an edgeedge with one O(14)Li2Ni3 square pyramid,  an edgeedge with one O(2)Li2Ni3 square pyramid,  an edgeedge with one O(3)Li2Ni3 square pyramid,  an edgeedge with one O(7)Li2Ni3 square pyramid,  an edgeedge with one O(1)Li2TiNi2 square pyramid,  an edgeedge with one O(4)Li2TiNi2 square pyramid, and  an edgeedge with one O(9)Li2TiNi2 square pyramid. The corner-sharing octahedral tilt angles are 3°. In the seventh O site, O(7) is bonded to one Li(1), one Li(5), one Ni(2), one Ni(4), and one Ni(5) atom to form OLi2Ni3 square pyramids that share  a cornercorner with one O(8)Li3TiNi2 octahedra,  a cornercorner with one O(14)Li2Ni3 square pyramid,  a cornercorner with one O(15)Li2Ni3 square pyramid,  a cornercorner with one O(3)Li2Ni3 square pyramid,  a cornercorner with one O(16)Li2TiNi2 square pyramid,  a cornercorner with one O(4)Li2TiNi2 square pyramid,  a cornercorner with one O(9)Li2TiNi2 square pyramid, corners with two equivalent O(10)Li2Ni3 square pyramids,  an edgeedge with one O(5)Li3Ni3 octahedra,  an edgeedge with one O(6)Li3Ni3 octahedra,  an edgeedge with one O(13)Li3TiNi2 octahedra,  an edgeedge with one O(8)Li3TiNi2 octahedra,  an edgeedge with one O(11)Li2Ni3 square pyramid,  an edgeedge with one O(12)Li2Ni3 square pyramid,  an edgeedge with one O(2)Li2Ni3 square pyramid, and  an edgeedge with one O(3)Li2Ni3 square pyramid. The corner-sharing octahedral tilt angles are 3°. In the eighth O site, O(8) is bonded to one Li(1), one Li(4), one Li(5), one Ti(1), one Ni(5), and one Ni(6) atom to form OLi3TiNi2 octahedra that share  a cornercorner with one O(13)Li3TiNi2 octahedra,  a cornercorner with one O(12)Li2Ni3 square pyramid,  a cornercorner with one O(14)Li2Ni3 square pyramid,  a cornercorner with one O(2)Li2Ni3 square pyramid,  a cornercorner with one O(7)Li2Ni3 square pyramid,  a cornercorner with one O(9)Li2TiNi2 square pyramid,  an edgeedge with one O(6)Li3Ni3 octahedra,  an edgeedge with one O(13)Li3TiNi2 octahedra,  an edgeedge with one O(10)Li2Ni3 square pyramid,  an edgeedge with one O(11)Li2Ni3 square pyramid,  an edgeedge with one O(12)Li2Ni3 square pyramid,  an edgeedge with one O(14)Li2Ni3 square pyramid,  an edgeedge with one O(15)Li2Ni3 square pyramid,  an edgeedge with one O(3)Li2Ni3 square pyramid,  an edgeedge with one O(7)Li2Ni3 square pyramid,  an edgeedge with one O(1)Li2TiNi2 square pyramid,  an edgeedge with one O(16)Li2TiNi2 square pyramid, and  an edgeedge with one O(4)Li2TiNi2 square pyramid. The corner-sharing octahedral tilt angles are 5°. In the ninth O site, O(9) is bonded to one Li(2), one Li(3), one Ti(1), one Ni(2), and one Ni(3) atom to form OLi2TiNi2 square pyramids that share  a cornercorner with one O(5)Li3Ni3 octahedra,  a cornercorner with one O(8)Li3TiNi2 octahedra,  a cornercorner with one O(11)Li2Ni3 square pyramid,  a cornercorner with one O(14)Li2Ni3 square pyramid,  a cornercorner with one O(3)Li2Ni3 square pyramid,  a cornercorner with one O(7)Li2Ni3 square pyramid,  a cornercorner with one O(4)Li2TiNi2 square pyramid, corners with two equivalent O(10)Li2Ni3 square pyramids,  an edgeedge with one O(5)Li3Ni3 octahedra,  an edgeedge with one O(6)Li3Ni3 octahedra,  an edgeedge with one O(13)Li3TiNi2 octahedra,  an edgeedge with one O(2)Li2Ni3 square pyramid,  an edgeedge with one O(3)Li2Ni3 square pyramid,  an edgeedge with one O(1)Li2TiNi2 square pyramid,  an edgeedge with one O(16)Li2TiNi2 square pyramid, and  an edgeedge with one O(4)Li2TiNi2 square pyramid. The corner-sharing octahedral tilt angles are 2°. In the tenth O site, O(10) is bonded to one Li(1), one Li(2), one Ni(3), one Ni(4), and one Ni(6) atom to form OLi2Ni3 square pyramids that share  a cornercorner with one O(6)Li3Ni3 octahedra,  a cornercorner with one O(13)Li3TiNi2 octahedra,  a cornercorner with one O(11)Li2Ni3 square pyramid,  a cornercorner with one O(15)Li2Ni3 square pyramid,  a cornercorner with one O(1)Li2TiNi2 square pyramid, corners with two equivalent O(7)Li2Ni3 square pyramids, corners with two equivalent O(9)Li2TiNi2 square pyramids,  an edgeedge with one O(5)Li3Ni3 octahedra,  an edgeedge with one O(6)Li3Ni3 octahedra,  an edgeedge with one O(8)Li3TiNi2 octahedra,  an edgeedge with one O(12)Li2Ni3 square pyramid,  an edgeedge with one O(14)Li2Ni3 square pyramid,  an edgeedge with one O(2)Li2Ni3 square pyramid,  an edgeedge with one O(3)Li2Ni3 square pyramid, and  an edgeedge with one O(4)Li2TiNi2 square pyramid. The corner-sharing octahedral tilt angles range from 3-7°. In the eleventh O site, O(11) is bonded to one Li(3), one Li(4), one Ni(4), one Ni(5), and one Ni(7) atom to form OLi2Ni3 square pyramids that share  a cornercorner with one O(6)Li3Ni3 octahedra,  a cornercorner with one O(10)Li2Ni3 square pyramid,  a cornercorner with one O(12)Li2Ni3 square pyramid,  a cornercorner with one O(15)Li2Ni3 square pyramid,  a cornercorner with one O(2)Li2Ni3 square pyramid,  a cornercorner with one O(1)Li2TiNi2 square pyramid,  a cornercorner with one O(9)Li2TiNi2 square pyramid, corners with two equivalent O(14)Li2Ni3 square pyramids,  an edgeedge with one O(5)Li3Ni3 octahedra,  an edgeedge with one O(6)Li3Ni3 octahedra,  an edgeedge with one O(13)Li3TiNi2 octahedra,  an edgeedge with one O(8)Li3TiNi2 octahedra,  an edgeedge with one O(12)Li2Ni3 square pyramid,  an edgeedge with one O(3)Li2Ni3 square pyramid,  an edgeedge with one O(7)Li2Ni3 square pyramid, and  an edgeedge with one O(16)Li2TiNi2 square pyramid. The corner-sharing octahedral tilt angles are 3°. In the twelfth O site, O(12) is bonded to one Li(4), one Li(5), one Ni(4), one Ni(6), and one Ni(7) atom to form OLi2Ni3 square pyramids that share  a cornercorner with one O(5)Li3Ni3 octahedra,  a cornercorner with one O(8)Li3TiNi2 octahedra,  a cornercorner with one O(11)Li2Ni3 square pyramid,  a cornercorner with one O(15)Li2Ni3 square pyramid,  a cornercorner with one O(2)Li2Ni3 square pyramid,  a cornercorner with one O(1)Li2TiNi2 square pyramid,  a cornercorner with one O(4)Li2TiNi2 square pyramid, corners with two equivalent O(16)Li2TiNi2 square pyramids,  an edgeedge with one O(6)Li3Ni3 octahedra,  an edgeedge with one O(13)Li3TiNi2 octahedra,  an edgeedge with one O(8)Li3TiNi2 octahedra,  an edgeedge with one O(10)Li2Ni3 square pyramid,  an edgeedge with one O(11)Li2Ni3 square pyramid,  an edgeedge with one O(14)Li2Ni3 square pyramid,  an edgeedge with one O(15)Li2Ni3 square pyramid, and  an edgeedge with one O(7)Li2Ni3 square pyramid. The corner-sharing octahedral tilt angles range from 1-5°. In the thirteenth O site, O(13) is bonded to one Li(2), one Li(5), one Li(6), one Ti(1), one Ni(5), and one Ni(7) atom to form OLi3TiNi2 octahedra that share  a cornercorner with one O(8)Li3TiNi2 octahedra,  a cornercorner with one O(10)Li2Ni3 square pyramid,  a cornercorner with one O(15)Li2Ni3 square pyramid,  a cornercorner with one O(3)Li2Ni3 square pyramid,  a cornercorner with one O(16)Li2TiNi2 square pyramid,  a cornercorner with one O(4)Li2TiNi2 square pyramid,  an edgeedge with one O(5)Li3Ni3 octahedra,  an edgeedge with one O(8)Li3TiNi2 octahedra,  an edgeedge with one O(11)Li2Ni3 square pyramid,  an edgeedge with one O(12)Li2Ni3 square pyramid,  an edgeedge with one O(14)Li2Ni3 square pyramid,  an edgeedge with one O(15)Li2Ni3 square pyramid,  an edgeedge with one O(2)Li2Ni3 square pyramid,  an edgeedge with one O(7)Li2Ni3 square pyramid,  an edgeedge with one O(1)Li2TiNi2 square pyramid,  an edgeedge with one O(16)Li2TiNi2 square pyramid,  an edgeedge with one O(4)Li2TiNi2 square pyramid, and  an edgeedge with one O(9)Li2TiNi2 square pyramid. The corner-sharing octahedral tilt angles are 5°. In the fourteenth O site, O(14) is bonded to one Li(4), one Li(6), one Ni(3), one Ni(5), and one Ni(6) atom to form OLi2Ni3 square pyramids that share  a cornercorner with one O(5)Li3Ni3 octahedra,  a cornercorner with one O(8)Li3TiNi2 octahedra,  a cornercorner with one O(7)Li2Ni3 square pyramid,  a cornercorner with one O(4)Li2TiNi2 square pyramid,  a cornercorner with one O(9)Li2TiNi2 square pyramid, corners with two equivalent O(11)Li2Ni3 square pyramids, corners with two equivalent O(15)Li2Ni3 square pyramids,  an edgeedge with one O(6)Li3Ni3 octahedra,  an edgeedge with one O(13)Li3TiNi2 octahedra,  an edgeedge with one O(8)Li3TiNi2 octahedra,  an edgeedge with one O(10)Li2Ni3 square pyramid,  an edgeedge with one O(12)Li2Ni3 square pyramid,  an edgeedge with one O(3)Li2Ni3 square pyramid,  an edgeedge with one O(1)Li2TiNi2 square pyramid, and  an edgeedge with one O(16)Li2TiNi2 square pyramid. The corner-sharing octahedral tilt angles range from 6-8°. In the fifteenth O site, O(15) is bonded to one Li(5), one Li(6), one Ni(1), one Ni(6), and one Ni(7) atom to form OLi2Ni3 square pyramids that share  a cornercorner with one O(6)Li3Ni3 octahedra,  a cornercorner with one O(13)Li3TiNi2 octahedra,  a cornercorner with one O(10)Li2Ni3 square pyramid,  a cornercorner with one O(11)Li2Ni3 square pyramid,  a cornercorner with one O(12)Li2Ni3 square pyramid,  a cornercorner with one O(7)Li2Ni3 square pyramid,  a cornercorner with one O(1)Li2TiNi2 square pyramid, corners with two equivalent O(14)Li2Ni3 square pyramids,  an edgeedge with one O(5)Li3Ni3 octahedra,  an edgeedge with one O(13)Li3TiNi2 octahedra,  an edgeedge with one O(8)Li3TiNi2 octahedra,  an edgeedge with one O(12)Li2Ni3 square pyramid,  an edgeedge with one O(2)Li2Ni3 square pyramid,  an edgeedge with one O(1)Li2TiNi2 square pyramid,  an edgeedge with one O(16)Li2TiNi2 square pyramid, and  an edgeedge with one O(4)Li2TiNi2 square pyramid. The corner-sharing octahedral tilt angles range from 2-3°. In the sixteenth O site, O(16) is bonded to one Li(4), one Li(6), one Ti(1), one Ni(2), and one Ni(7) atom to form OLi2TiNi2 square pyramids that share  a cornercorner with one O(6)Li3Ni3 octahedra,  a cornercorner with one O(13)Li3TiNi2 octahedra,  a cornercorner with one O(3)Li2Ni3 square pyramid,  a cornercorner with one O(7)Li2Ni3 square pyramid,  a cornercorner with one O(4)Li2TiNi2 square pyramid, corners with two equivalent O(12)Li2Ni3 square pyramids, corners with two equivalent O(1)Li2TiNi2 square pyramids,  an edgeedge with one O(5)Li3Ni3 octahedra,  an edgeedge with one O(13)Li3TiNi2 octahedra,  an edgeedge with one O(8)Li3TiNi2 octahedra,  an edgeedge with one O(11)Li2Ni3 square pyramid,  an edgeedge with one O(14)Li2Ni3 square pyramid,  an edgeedge with one O(15)Li2Ni3 square pyramid,  an edgeedge with one O(2)Li2Ni3 square pyramid, and  an edgeedge with one O(9)Li2TiNi2 square pyramid. The corner-sharing octahedral tilt angles range from 5-6°. is represented by the CIF card [CIF]
data_Li6TiNi7O16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.422
_cell_length_b   6.553
_cell_length_c   7.692
_cell_angle_alpha   75.970
_cell_angle_beta   65.818
_cell_angle_gamma   70.801
_symmetry_Int_Tables_number   1
_cell_volume   276.681
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.177  0.321  0.443  1.0
  Li  Li1  1  0.943  0.549  0.195  1.0
  Li  Li2  1  0.561  0.932  0.310  1.0
  Li  Li3  1  0.452  0.060  0.688  1.0
  Li  Li4  1  0.058  0.452  0.803  1.0
  Li  Li5  1  0.668  0.831  0.931  1.0
  Ti  Ti6  1  0.007  0.020  0.995  1.0
  Ni  Ni7  1  0.610  0.372  0.130  1.0
  Ni  Ni8  1  0.250  0.752  0.257  1.0
  Ni  Ni9  1  0.876  0.124  0.375  1.0
  Ni  Ni10  1  0.503  0.498  0.497  1.0
  Ni  Ni11  1  0.124  0.867  0.627  1.0
  Ni  Ni12  1  0.750  0.251  0.751  1.0
  Ni  Ni13  1  0.373  0.619  0.875  1.0
  O  O14  1  0.683  0.076  0.031  1.0
  O  O15  1  0.289  0.497  0.157  1.0
  O  O16  1  0.204  0.000  0.371  1.0
  O  O17  1  0.938  0.283  0.098  1.0
  O  O18  1  0.568  0.647  0.244  1.0
  O  O19  1  0.540  0.244  0.395  1.0
  O  O20  1  0.188  0.583  0.530  1.0
  O  O21  1  0.076  0.162  0.731  1.0
  O  O22  1  0.932  0.867  0.268  1.0
  O  O23  1  0.831  0.384  0.460  1.0
  O  O24  1  0.449  0.754  0.595  1.0
  O  O25  1  0.437  0.355  0.749  1.0
  O  O26  1  0.055  0.729  0.893  1.0
  O  O27  1  0.800  0.993  0.655  1.0
  O  O28  1  0.686  0.505  0.869  1.0
  O  O29  1  0.336  0.896  0.958  1.0
[/CIF]
.