The compound described by V5Te4 is Titanium telluride structured and crystallizes in the tetragonal I4/m space group. There are two inequivalent V sites. In the first V site, V(1) is bonded to eight equivalent V(2) and four equivalent Te(1) atoms to form face-sharing VV8Te4 cuboctahedra. In the second V site, V(2) is bonded in a 9-coordinate geometry to two equivalent V(1), two equivalent V(2), and five equivalent Te(1) atoms. Te(1) is bonded in a 6-coordinate geometry to one V(1) and five equivalent V(2) atoms. is represented by the CIF card [CIF]
data_V5Te4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.138
_cell_length_b   7.138
_cell_length_c   7.138
_cell_angle_alpha   94.450
_cell_angle_beta   94.450
_cell_angle_gamma   147.654
_symmetry_Int_Tables_number   1
_cell_volume   186.899
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.000  0.000  0.000  1.0
  V  V1  1  0.660  0.410  0.071  1.0
  V  V2  1  0.410  0.340  0.750  1.0
  V  V3  1  0.590  0.660  0.250  1.0
  V  V4  1  0.340  0.590  0.929  1.0
  Te  Te5  1  0.926  0.276  0.202  1.0
  Te  Te6  1  0.276  0.074  0.350  1.0
  Te  Te7  1  0.724  0.926  0.650  1.0
  Te  Te8  1  0.074  0.724  0.798  1.0
[/CIF]
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The compound described by V5Te4 is Titanium telluride structured and crystallizes in the tetragonal I4/m space group. There are two inequivalent V sites. In the first V site, V(1) is bonded to eight equivalent V(2) and four equivalent Te(1) atoms to form face-sharing VV8Te4 cuboctahedra. In the second V site, V(2) is bonded in a 9-coordinate geometry to two equivalent V(1), two equivalent V(2), and five equivalent Te(1) atoms. Te(1) is bonded in a 6-coordinate geometry to one V(1) and five equivalent V(2) atoms. is represented by the CIF card [CIF]
data_V5Te4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.138
_cell_length_b   7.138
_cell_length_c   7.138
_cell_angle_alpha   94.450
_cell_angle_beta   94.450
_cell_angle_gamma   147.654
_symmetry_Int_Tables_number   1
_cell_volume   186.899
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.000  0.000  0.000  1.0
  V  V1  1  0.660  0.410  0.071  1.0
  V  V2  1  0.410  0.340  0.750  1.0
  V  V3  1  0.590  0.660  0.250  1.0
  V  V4  1  0.340  0.590  0.929  1.0
  Te  Te5  1  0.926  0.276  0.202  1.0
  Te  Te6  1  0.276  0.074  0.350  1.0
  Te  Te7  1  0.724  0.926  0.650  1.0
  Te  Te8  1  0.074  0.724  0.798  1.0
[/CIF]
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