The structure described by CsRe3(O3F5)2 crystallizes in the triclinic P-1 space group. Cs(1) is bonded in a 12-coordinate geometry to one O(3), one O(6), one F(1), one F(10), one F(4), one F(5), one F(6), one F(9), two equivalent F(2), and two equivalent F(8) atoms. There are three inequivalent Re sites. In the first Re site, Re(1) is bonded to one O(1), one O(2), one F(1), one F(2), one F(3), and one F(4) atom to form distorted corner-sharing ReO2F4 octahedra. The corner-sharing octahedral tilt angles are 39°. In the second Re site, Re(2) is bonded to one O(3), one O(4), one F(4), one F(5), one F(6), and one F(7) atom to form distorted corner-sharing ReO2F4 octahedra. The corner-sharing octahedral tilt angles range from 2-39°. In the third Re site, Re(3) is bonded to one O(5), one O(6), one F(10), one F(7), one F(8), and one F(9) atom to form distorted corner-sharing ReO2F4 octahedra. The corner-sharing octahedral tilt angles are 2°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Re(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Re(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Cs(1) and one Re(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Re(2) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Re(3) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one Cs(1) and one Re(3) atom. There are ten inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to one Cs(1) and one Re(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to two equivalent Cs(1) and one Re(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Re(1) atom. In the fourth F site, F(4) is bonded in a 2-coordinate geometry to one Cs(1), one Re(1), and one Re(2) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Cs(1) and one Re(2) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one Cs(1) and one Re(2) atom. In the seventh F site, F(7) is bonded in a linear geometry to one Re(2) and one Re(3) atom. In the eighth F site, F(8) is bonded in a distorted single-bond geometry to two equivalent Cs(1) and one Re(3) atom. In the ninth F site, F(9) is bonded in a distorted single-bond geometry to one Cs(1) and one Re(3) atom. In the tenth F site, F(10) is bonded in a single-bond geometry to one Cs(1) and one Re(3) atom. is represented by the CIF file [CIF]
data_CsRe3(O3F5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.347
_cell_length_b   10.101
_cell_length_c   10.678
_cell_angle_alpha   113.563
_cell_angle_beta   91.010
_cell_angle_gamma   92.224
_symmetry_Int_Tables_number   1
_cell_volume   725.276
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.695  0.704  0.121  1.0
  Cs  Cs1  1  0.305  0.296  0.879  1.0
  Re  Re2  1  0.230  0.625  0.368  1.0
  Re  Re3  1  0.770  0.375  0.632  1.0
  Re  Re4  1  0.259  0.014  0.326  1.0
  Re  Re5  1  0.741  0.986  0.674  1.0
  Re  Re6  1  0.239  0.778  0.889  1.0
  Re  Re7  1  0.761  0.222  0.111  1.0
  O  O8  1  0.167  0.480  0.403  1.0
  O  O9  1  0.833  0.520  0.597  1.0
  O  O10  1  0.130  0.766  0.494  1.0
  O  O11  1  0.870  0.234  0.506  1.0
  O  O12  1  0.278  0.077  0.500  1.0
  O  O13  1  0.722  0.923  0.500  1.0
  O  O14  1  0.203  0.165  0.302  1.0
  O  O15  1  0.797  0.835  0.698  1.0
  O  O16  1  0.237  0.669  0.720  1.0
  O  O17  1  0.763  0.331  0.280  1.0
  O  O18  1  0.189  0.943  0.889  1.0
  O  O19  1  0.811  0.057  0.111  1.0
  F  F20  1  0.043  0.603  0.235  1.0
  F  F21  1  0.957  0.397  0.765  1.0
  F  F22  1  0.369  0.529  0.204  1.0
  F  F23  1  0.631  0.471  0.796  1.0
  F  F24  1  0.464  0.665  0.454  1.0
  F  F25  1  0.536  0.335  0.546  1.0
  F  F26  1  0.327  0.805  0.306  1.0
  F  F27  1  0.673  0.195  0.694  1.0
  F  F28  1  0.022  0.928  0.305  1.0
  F  F29  1  0.978  0.072  0.695  1.0
  F  F30  1  0.509  0.022  0.294  1.0
  F  F31  1  0.491  0.978  0.706  1.0
  F  F32  1  0.250  0.897  0.114  1.0
  F  F33  1  0.750  0.103  0.886  1.0
  F  F34  1  0.299  0.631  0.958  1.0
  F  F35  1  0.701  0.369  0.042  1.0
  F  F36  1  0.998  0.732  0.925  1.0
  F  F37  1  0.002  0.268  0.075  1.0
  F  F38  1  0.493  0.822  0.917  1.0
  F  F39  1  0.507  0.178  0.083  1.0
[/CIF]
.
The structure described by CsRe3(O3F5)2 crystallizes in the triclinic P-1 space group. Cs(1) is bonded in a 12-coordinate geometry to one O(3), one O(6), one F(1), one F(10), one F(4), one F(5), one F(6), one F(9), two equivalent F(2), and two equivalent F(8) atoms. There are three inequivalent Re sites. In the first Re site, Re(1) is bonded to one O(1), one O(2), one F(1), one F(2), one F(3), and one F(4) atom to form distorted corner-sharing ReO2F4 octahedra. The corner-sharing octahedral tilt angles are 39°. In the second Re site, Re(2) is bonded to one O(3), one O(4), one F(4), one F(5), one F(6), and one F(7) atom to form distorted corner-sharing ReO2F4 octahedra. The corner-sharing octahedral tilt angles range from 2-39°. In the third Re site, Re(3) is bonded to one O(5), one O(6), one F(10), one F(7), one F(8), and one F(9) atom to form distorted corner-sharing ReO2F4 octahedra. The corner-sharing octahedral tilt angles are 2°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Re(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Re(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Cs(1) and one Re(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Re(2) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Re(3) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one Cs(1) and one Re(3) atom. There are ten inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to one Cs(1) and one Re(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to two equivalent Cs(1) and one Re(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Re(1) atom. In the fourth F site, F(4) is bonded in a 2-coordinate geometry to one Cs(1), one Re(1), and one Re(2) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Cs(1) and one Re(2) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one Cs(1) and one Re(2) atom. In the seventh F site, F(7) is bonded in a linear geometry to one Re(2) and one Re(3) atom. In the eighth F site, F(8) is bonded in a distorted single-bond geometry to two equivalent Cs(1) and one Re(3) atom. In the ninth F site, F(9) is bonded in a distorted single-bond geometry to one Cs(1) and one Re(3) atom. In the tenth F site, F(10) is bonded in a single-bond geometry to one Cs(1) and one Re(3) atom. is represented by the CIF file [CIF]
data_CsRe3(O3F5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.347
_cell_length_b   10.101
_cell_length_c   10.678
_cell_angle_alpha   113.563
_cell_angle_beta   91.010
_cell_angle_gamma   92.224
_symmetry_Int_Tables_number   1
_cell_volume   725.276
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.695  0.704  0.121  1.0
  Cs  Cs1  1  0.305  0.296  0.879  1.0
  Re  Re2  1  0.230  0.625  0.368  1.0
  Re  Re3  1  0.770  0.375  0.632  1.0
  Re  Re4  1  0.259  0.014  0.326  1.0
  Re  Re5  1  0.741  0.986  0.674  1.0
  Re  Re6  1  0.239  0.778  0.889  1.0
  Re  Re7  1  0.761  0.222  0.111  1.0
  O  O8  1  0.167  0.480  0.403  1.0
  O  O9  1  0.833  0.520  0.597  1.0
  O  O10  1  0.130  0.766  0.494  1.0
  O  O11  1  0.870  0.234  0.506  1.0
  O  O12  1  0.278  0.077  0.500  1.0
  O  O13  1  0.722  0.923  0.500  1.0
  O  O14  1  0.203  0.165  0.302  1.0
  O  O15  1  0.797  0.835  0.698  1.0
  O  O16  1  0.237  0.669  0.720  1.0
  O  O17  1  0.763  0.331  0.280  1.0
  O  O18  1  0.189  0.943  0.889  1.0
  O  O19  1  0.811  0.057  0.111  1.0
  F  F20  1  0.043  0.603  0.235  1.0
  F  F21  1  0.957  0.397  0.765  1.0
  F  F22  1  0.369  0.529  0.204  1.0
  F  F23  1  0.631  0.471  0.796  1.0
  F  F24  1  0.464  0.665  0.454  1.0
  F  F25  1  0.536  0.335  0.546  1.0
  F  F26  1  0.327  0.805  0.306  1.0
  F  F27  1  0.673  0.195  0.694  1.0
  F  F28  1  0.022  0.928  0.305  1.0
  F  F29  1  0.978  0.072  0.695  1.0
  F  F30  1  0.509  0.022  0.294  1.0
  F  F31  1  0.491  0.978  0.706  1.0
  F  F32  1  0.250  0.897  0.114  1.0
  F  F33  1  0.750  0.103  0.886  1.0
  F  F34  1  0.299  0.631  0.958  1.0
  F  F35  1  0.701  0.369  0.042  1.0
  F  F36  1  0.998  0.732  0.925  1.0
  F  F37  1  0.002  0.268  0.075  1.0
  F  F38  1  0.493  0.822  0.917  1.0
  F  F39  1  0.507  0.178  0.083  1.0
[/CIF]
.