The material described by N2(NSO3)2 is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Pbca space group. The structure is zero-dimensional and consists of eight ammonia atoms and eight NSO3 clusters. In each NSO3 cluster, N(2) is bonded in a single-bond geometry to one S(1) atom. S(1) is bonded in a tetrahedral geometry to one N(2), one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(1) is bonded in a single-bond geometry to one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SN2O3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.736
_cell_length_b   7.999
_cell_length_c   14.857
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   919.453
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.619  0.151  0.140  1.0
  S  S1  1  0.119  0.349  0.860  1.0
  S  S2  1  0.381  0.651  0.360  1.0
  S  S3  1  0.881  0.849  0.640  1.0
  S  S4  1  0.381  0.849  0.860  1.0
  S  S5  1  0.881  0.651  0.140  1.0
  S  S6  1  0.619  0.349  0.640  1.0
  S  S7  1  0.119  0.151  0.360  1.0
  N  N8  1  0.135  0.138  0.081  1.0
  N  N9  1  0.635  0.362  0.919  1.0
  N  N10  1  0.865  0.638  0.419  1.0
  N  N11  1  0.365  0.862  0.581  1.0
  N  N12  1  0.865  0.862  0.919  1.0
  N  N13  1  0.365  0.638  0.081  1.0
  N  N14  1  0.135  0.362  0.581  1.0
  N  N15  1  0.635  0.138  0.419  1.0
  N  N16  1  0.508  0.984  0.172  1.0
  N  N17  1  0.008  0.516  0.828  1.0
  N  N18  1  0.492  0.484  0.328  1.0
  N  N19  1  0.992  0.016  0.672  1.0
  N  N20  1  0.492  0.016  0.828  1.0
  N  N21  1  0.992  0.484  0.172  1.0
  N  N22  1  0.508  0.516  0.672  1.0
  N  N23  1  0.008  0.984  0.328  1.0
  O  O24  1  0.726  0.202  0.217  1.0
  O  O25  1  0.226  0.298  0.783  1.0
  O  O26  1  0.274  0.702  0.283  1.0
  O  O27  1  0.774  0.798  0.717  1.0
  O  O28  1  0.274  0.798  0.783  1.0
  O  O29  1  0.774  0.702  0.217  1.0
  O  O30  1  0.726  0.298  0.717  1.0
  O  O31  1  0.226  0.202  0.283  1.0
  O  O32  1  0.490  0.275  0.115  1.0
  O  O33  1  0.990  0.225  0.885  1.0
  O  O34  1  0.510  0.775  0.385  1.0
  O  O35  1  0.010  0.725  0.615  1.0
  O  O36  1  0.510  0.725  0.885  1.0
  O  O37  1  0.010  0.775  0.115  1.0
  O  O38  1  0.490  0.225  0.615  1.0
  O  O39  1  0.990  0.275  0.385  1.0
  O  O40  1  0.724  0.096  0.063  1.0
  O  O41  1  0.224  0.404  0.937  1.0
  O  O42  1  0.276  0.596  0.437  1.0
  O  O43  1  0.776  0.904  0.563  1.0
  O  O44  1  0.276  0.904  0.937  1.0
  O  O45  1  0.776  0.596  0.063  1.0
  O  O46  1  0.724  0.404  0.563  1.0
  O  O47  1  0.224  0.096  0.437  1.0
[/CIF]
.
The material described by N2(NSO3)2 is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Pbca space group. The structure is zero-dimensional and consists of eight ammonia atoms and eight NSO3 clusters. In each NSO3 cluster, N(2) is bonded in a single-bond geometry to one S(1) atom. S(1) is bonded in a tetrahedral geometry to one N(2), one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(1) is bonded in a single-bond geometry to one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SN2O3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.736
_cell_length_b   7.999
_cell_length_c   14.857
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   919.453
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.619  0.151  0.140  1.0
  S  S1  1  0.119  0.349  0.860  1.0
  S  S2  1  0.381  0.651  0.360  1.0
  S  S3  1  0.881  0.849  0.640  1.0
  S  S4  1  0.381  0.849  0.860  1.0
  S  S5  1  0.881  0.651  0.140  1.0
  S  S6  1  0.619  0.349  0.640  1.0
  S  S7  1  0.119  0.151  0.360  1.0
  N  N8  1  0.135  0.138  0.081  1.0
  N  N9  1  0.635  0.362  0.919  1.0
  N  N10  1  0.865  0.638  0.419  1.0
  N  N11  1  0.365  0.862  0.581  1.0
  N  N12  1  0.865  0.862  0.919  1.0
  N  N13  1  0.365  0.638  0.081  1.0
  N  N14  1  0.135  0.362  0.581  1.0
  N  N15  1  0.635  0.138  0.419  1.0
  N  N16  1  0.508  0.984  0.172  1.0
  N  N17  1  0.008  0.516  0.828  1.0
  N  N18  1  0.492  0.484  0.328  1.0
  N  N19  1  0.992  0.016  0.672  1.0
  N  N20  1  0.492  0.016  0.828  1.0
  N  N21  1  0.992  0.484  0.172  1.0
  N  N22  1  0.508  0.516  0.672  1.0
  N  N23  1  0.008  0.984  0.328  1.0
  O  O24  1  0.726  0.202  0.217  1.0
  O  O25  1  0.226  0.298  0.783  1.0
  O  O26  1  0.274  0.702  0.283  1.0
  O  O27  1  0.774  0.798  0.717  1.0
  O  O28  1  0.274  0.798  0.783  1.0
  O  O29  1  0.774  0.702  0.217  1.0
  O  O30  1  0.726  0.298  0.717  1.0
  O  O31  1  0.226  0.202  0.283  1.0
  O  O32  1  0.490  0.275  0.115  1.0
  O  O33  1  0.990  0.225  0.885  1.0
  O  O34  1  0.510  0.775  0.385  1.0
  O  O35  1  0.010  0.725  0.615  1.0
  O  O36  1  0.510  0.725  0.885  1.0
  O  O37  1  0.010  0.775  0.115  1.0
  O  O38  1  0.490  0.225  0.615  1.0
  O  O39  1  0.990  0.275  0.385  1.0
  O  O40  1  0.724  0.096  0.063  1.0
  O  O41  1  0.224  0.404  0.937  1.0
  O  O42  1  0.276  0.596  0.437  1.0
  O  O43  1  0.776  0.904  0.563  1.0
  O  O44  1  0.276  0.904  0.937  1.0
  O  O45  1  0.776  0.596  0.063  1.0
  O  O46  1  0.724  0.404  0.563  1.0
  O  O47  1  0.224  0.096  0.437  1.0
[/CIF]
.