The structure described by Li7VO5F is Aluminum carbonitride-derived structured and crystallizes in the triclinic P1 space group. There are fourteen inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(4), one O(8), and one F(2) atom to form LiO3F tetrahedra that share  a cornercorner with one Li(2)O3F tetrahedra,  a cornercorner with one V(1)O4 tetrahedra,  a cornercorner with one V(2)O4 tetrahedra, corners with three equivalent Li(6)O3F tetrahedra,  a cornercorner with one Li(13)O3F trigonal pyramid,  a cornercorner with one Li(7)O3F trigonal pyramid, corners with three equivalent Li(5)O3F trigonal pyramids,  an edgeedge with one Li(2)O3F tetrahedra,  an edgeedge with one Li(4)O4 tetrahedra,  an edgeedge with one Li(11)O3F trigonal pyramid, and  an edgeedge with one Li(7)O3F trigonal pyramid. In the second Li site, Li(2) is bonded to one O(1), one O(2), one O(4), and one F(2) atom to form distorted LiO3F tetrahedra that share  a cornercorner with one Li(1)O3F tetrahedra,  a cornercorner with one Li(6)O3F tetrahedra,  a cornercorner with one Li(10)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(11)O3F trigonal pyramid,  a cornercorner with one Li(3)O3F trigonal pyramid,  a cornercorner with one Li(5)O3F trigonal pyramid,  a cornercorner with one Li(8)O3F trigonal pyramid, corners with three equivalent Li(7)O3F trigonal pyramids,  an edgeedge with one Li(1)O3F tetrahedra,  an edgeedge with one Li(6)O3F tetrahedra,  an edgeedge with one V(2)O4 tetrahedra, and  an edgeedge with one Li(5)O3F trigonal pyramid. In the third Li site, Li(3) is bonded to one O(2), one O(3), one O(6), and one F(1) atom to form LiO3F trigonal pyramids that share  a cornercorner with one Li(2)O3F tetrahedra, corners with three equivalent Li(10)O4 tetrahedra, corners with three equivalent V(2)O4 tetrahedra,  a cornercorner with one Li(12)O3F trigonal pyramid,  a cornercorner with one Li(13)O3F trigonal pyramid,  a cornercorner with one Li(7)O3F trigonal pyramid,  an edgeedge with one Li(14)O3F tetrahedra,  an edgeedge with one Li(9)O3F tetrahedra, and  an edgeedge with one Li(8)O3F trigonal pyramid. In the fourth Li site, Li(4) is bonded to one O(4), one O(5), one O(8), and one O(9) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(2)O3F tetrahedra, corners with three equivalent V(1)O4 tetrahedra,  a cornercorner with one Li(12)O3F trigonal pyramid,  a cornercorner with one Li(13)O3F trigonal pyramid,  a cornercorner with one Li(7)O3F trigonal pyramid, corners with three equivalent Li(11)O3F trigonal pyramids,  an edgeedge with one Li(1)O3F tetrahedra,  an edgeedge with one Li(6)O3F tetrahedra, and  an edgeedge with one Li(5)O3F trigonal pyramid. In the fifth Li site, Li(5) is bonded to one O(1), one O(4), one O(5), and one F(2) atom to form distorted LiO3F trigonal pyramids that share  a cornercorner with one Li(2)O3F tetrahedra,  a cornercorner with one V(1)O4 tetrahedra,  a cornercorner with one V(2)O4 tetrahedra, corners with three equivalent Li(1)O3F tetrahedra, corners with three equivalent Li(6)O3F tetrahedra,  a cornercorner with one Li(7)O3F trigonal pyramid,  an edgeedge with one Li(2)O3F tetrahedra,  an edgeedge with one Li(4)O4 tetrahedra,  an edgeedge with one Li(11)O3F trigonal pyramid, and  an edgeedge with one Li(7)O3F trigonal pyramid. In the sixth Li site, Li(6) is bonded to one O(1), one O(4), one O(9), and one F(2) atom to form LiO3F tetrahedra that share  a cornercorner with one Li(2)O3F tetrahedra,  a cornercorner with one V(1)O4 tetrahedra,  a cornercorner with one V(2)O4 tetrahedra, corners with three equivalent Li(1)O3F tetrahedra,  a cornercorner with one Li(12)O3F trigonal pyramid,  a cornercorner with one Li(7)O3F trigonal pyramid, corners with three equivalent Li(5)O3F trigonal pyramids,  an edgeedge with one Li(2)O3F tetrahedra,  an edgeedge with one Li(4)O4 tetrahedra,  an edgeedge with one Li(11)O3F trigonal pyramid, and  an edgeedge with one Li(7)O3F trigonal pyramid. In the seventh Li site, Li(7) is bonded to one O(1), one O(4), one O(6), and one F(2) atom to form distorted LiO3F trigonal pyramids that share  a cornercorner with one Li(1)O3F tetrahedra,  a cornercorner with one Li(6)O3F tetrahedra,  a cornercorner with one Li(9)O3F tetrahedra,  a cornercorner with one Li(10)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with three equivalent Li(2)O3F tetrahedra,  a cornercorner with one Li(11)O3F trigonal pyramid,  a cornercorner with one Li(3)O3F trigonal pyramid,  a cornercorner with one Li(5)O3F trigonal pyramid,  an edgeedge with one Li(1)O3F tetrahedra,  an edgeedge with one Li(6)O3F tetrahedra,  an edgeedge with one V(2)O4 tetrahedra, and  an edgeedge with one Li(5)O3F trigonal pyramid. In the eighth Li site, Li(8) is bonded to one O(10), one O(2), one O(7), and one F(1) atom to form LiO3F trigonal pyramids that share  a cornercorner with one Li(2)O3F tetrahedra,  a cornercorner with one V(1)O4 tetrahedra,  a cornercorner with one V(2)O4 tetrahedra, corners with three equivalent Li(14)O3F tetrahedra, corners with three equivalent Li(9)O3F tetrahedra,  a cornercorner with one Li(12)O3F trigonal pyramid,  a cornercorner with one Li(13)O3F trigonal pyramid,  an edgeedge with one Li(10)O4 tetrahedra,  an edgeedge with one Li(12)O3F trigonal pyramid,  an edgeedge with one Li(13)O3F trigonal pyramid, and  an edgeedge with one Li(3)O3F trigonal pyramid. In the ninth Li site, Li(9) is bonded to one O(10), one O(6), one O(7), and one F(1) atom to form LiO3F tetrahedra that share  a cornercorner with one V(1)O4 tetrahedra,  a cornercorner with one V(2)O4 tetrahedra, corners with three equivalent Li(14)O3F tetrahedra,  a cornercorner with one Li(12)O3F trigonal pyramid,  a cornercorner with one Li(13)O3F trigonal pyramid,  a cornercorner with one Li(7)O3F trigonal pyramid, corners with three equivalent Li(8)O3F trigonal pyramids,  an edgeedge with one Li(10)O4 tetrahedra,  an edgeedge with one Li(12)O3F trigonal pyramid,  an edgeedge with one Li(13)O3F trigonal pyramid, and  an edgeedge with one Li(3)O3F trigonal pyramid. In the tenth Li site, Li(10) is bonded to one O(2), one O(3), one O(6), and one O(7) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(2)O3F tetrahedra, corners with three equivalent V(2)O4 tetrahedra,  a cornercorner with one Li(12)O3F trigonal pyramid,  a cornercorner with one Li(13)O3F trigonal pyramid,  a cornercorner with one Li(7)O3F trigonal pyramid, corners with three equivalent Li(3)O3F trigonal pyramids,  an edgeedge with one Li(14)O3F tetrahedra,  an edgeedge with one Li(9)O3F tetrahedra, and  an edgeedge with one Li(8)O3F trigonal pyramid. In the eleventh Li site, Li(11) is bonded to one O(5), one O(8), one O(9), and one F(2) atom to form LiO3F trigonal pyramids that share  a cornercorner with one Li(2)O3F tetrahedra, corners with three equivalent Li(4)O4 tetrahedra, corners with three equivalent V(1)O4 tetrahedra,  a cornercorner with one Li(12)O3F trigonal pyramid,  a cornercorner with one Li(13)O3F trigonal pyramid,  a cornercorner with one Li(7)O3F trigonal pyramid,  an edgeedge with one Li(1)O3F tetrahedra,  an edgeedge with one Li(6)O3F tetrahedra, and  an edgeedge with one Li(5)O3F trigonal pyramid. In the twelfth Li site, Li(12) is bonded to one O(10), one O(7), one O(9), and one F(1) atom to form distorted LiO3F trigonal pyramids that share  a cornercorner with one Li(14)O3F tetrahedra,  a cornercorner with one Li(6)O3F tetrahedra,  a cornercorner with one Li(9)O3F tetrahedra,  a cornercorner with one Li(10)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(11)O3F trigonal pyramid,  a cornercorner with one Li(3)O3F trigonal pyramid,  a cornercorner with one Li(8)O3F trigonal pyramid, corners with three equivalent Li(13)O3F trigonal pyramids,  an edgeedge with one Li(14)O3F tetrahedra,  an edgeedge with one Li(9)O3F tetrahedra,  an edgeedge with one V(1)O4 tetrahedra, and  an edgeedge with one Li(8)O3F trigonal pyramid. In the thirteenth Li site, Li(13) is bonded to one O(10), one O(7), one O(8), and one F(1) atom to form distorted LiO3F trigonal pyramids that share  a cornercorner with one Li(1)O3F tetrahedra,  a cornercorner with one Li(14)O3F tetrahedra,  a cornercorner with one Li(9)O3F tetrahedra,  a cornercorner with one Li(10)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(11)O3F trigonal pyramid,  a cornercorner with one Li(3)O3F trigonal pyramid,  a cornercorner with one Li(8)O3F trigonal pyramid, corners with three equivalent Li(12)O3F trigonal pyramids,  an edgeedge with one Li(14)O3F tetrahedra,  an edgeedge with one Li(9)O3F tetrahedra,  an edgeedge with one V(1)O4 tetrahedra, and  an edgeedge with one Li(8)O3F trigonal pyramid. In the fourteenth Li site, Li(14) is bonded to one O(10), one O(3), one O(7), and one F(1) atom to form LiO3F tetrahedra that share  a cornercorner with one V(1)O4 tetrahedra,  a cornercorner with one V(2)O4 tetrahedra, corners with three equivalent Li(9)O3F tetrahedra,  a cornercorner with one Li(12)O3F trigonal pyramid,  a cornercorner with one Li(13)O3F trigonal pyramid, corners with three equivalent Li(8)O3F trigonal pyramids,  an edgeedge with one Li(10)O4 tetrahedra,  an edgeedge with one Li(12)O3F trigonal pyramid,  an edgeedge with one Li(13)O3F trigonal pyramid, and  an edgeedge with one Li(3)O3F trigonal pyramid. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(10), one O(5), one O(8), and one O(9) atom to form VO4 tetrahedra that share  a cornercorner with one Li(1)O3F tetrahedra,  a cornercorner with one Li(14)O3F tetrahedra,  a cornercorner with one Li(6)O3F tetrahedra,  a cornercorner with one Li(9)O3F tetrahedra, corners with three equivalent Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O3F trigonal pyramid,  a cornercorner with one Li(8)O3F trigonal pyramid, corners with three equivalent Li(11)O3F trigonal pyramids,  an edgeedge with one Li(12)O3F trigonal pyramid, and  an edgeedge with one Li(13)O3F trigonal pyramid. In the second V site, V(2) is bonded to one O(1), one O(2), one O(3), and one O(6) atom to form VO4 tetrahedra that share  a cornercorner with one Li(1)O3F tetrahedra,  a cornercorner with one Li(14)O3F tetrahedra,  a cornercorner with one Li(6)O3F tetrahedra,  a cornercorner with one Li(9)O3F tetrahedra, corners with three equivalent Li(10)O4 tetrahedra,  a cornercorner with one Li(5)O3F trigonal pyramid,  a cornercorner with one Li(8)O3F trigonal pyramid, corners with three equivalent Li(3)O3F trigonal pyramids,  an edgeedge with one Li(2)O3F tetrahedra, and  an edgeedge with one Li(7)O3F trigonal pyramid. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a 6-coordinate geometry to one Li(1), one Li(2), one Li(5), one Li(6), one Li(7), and one V(2) atom. In the second O site, O(2) is bonded to one Li(10), one Li(2), one Li(3), one Li(8), and one V(2) atom to form OLi4V trigonal bipyramids that share corners with three equivalent O(6)Li4V trigonal bipyramids and corners with three equivalent O(3)Li3V trigonal pyramids. In the third O site, O(3) is bonded to one Li(10), one Li(14), one Li(3), and one V(2) atom to form distorted corner-sharing OLi3V trigonal pyramids. In the fourth O site, O(4) is bonded in a 6-coordinate geometry to one Li(1), one Li(2), one Li(4), one Li(5), one Li(6), and one Li(7) atom. In the fifth O site, O(5) is bonded to one Li(11), one Li(4), one Li(5), and one V(1) atom to form distorted corner-sharing OLi3V trigonal pyramids. In the sixth O site, O(6) is bonded to one Li(10), one Li(3), one Li(7), one Li(9), and one V(2) atom to form OLi4V trigonal bipyramids that share corners with three equivalent O(2)Li4V trigonal bipyramids and corners with three equivalent O(3)Li3V trigonal pyramids. In the seventh O site, O(7) is bonded in a 6-coordinate geometry to one Li(10), one Li(12), one Li(13), one Li(14), one Li(8), and one Li(9) atom. In the eighth O site, O(8) is bonded to one Li(1), one Li(11), one Li(13), one Li(4), and one V(1) atom to form OLi4V trigonal bipyramids that share corners with three equivalent O(9)Li4V trigonal bipyramids and corners with three equivalent O(5)Li3V trigonal pyramids. In the ninth O site, O(9) is bonded to one Li(11), one Li(12), one Li(4), one Li(6), and one V(1) atom to form OLi4V trigonal bipyramids that share corners with three equivalent O(8)Li4V trigonal bipyramids and corners with three equivalent O(5)Li3V trigonal pyramids. In the tenth O site, O(10) is bonded in a 6-coordinate geometry to one Li(12), one Li(13), one Li(14), one Li(8), one Li(9), and one V(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a 6-coordinate geometry to one Li(12), one Li(13), one Li(14), one Li(3), one Li(8), and one Li(9) atom. In the second F site, F(2) is bonded in a 6-coordinate geometry to one Li(1), one Li(11), one Li(2), one Li(5), one Li(6), and one Li(7) atom. is represented by the CIF file [CIF]
data_Li7VO5F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.591
_cell_length_b   5.596
_cell_length_c   10.798
_cell_angle_alpha   89.000
_cell_angle_beta   88.716
_cell_angle_gamma   60.395
_symmetry_Int_Tables_number   1
_cell_volume   293.632
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.357  0.982  0.758  1.0
  Li  Li1  1  0.393  0.630  0.630  1.0
  Li  Li2  1  0.651  0.670  0.428  1.0
  Li  Li3  1  0.671  0.648  0.909  1.0
  Li  Li4  1  0.954  0.732  0.757  1.0
  Li  Li5  1  0.707  0.292  0.770  1.0
  Li  Li6  1  0.993  0.387  0.627  1.0
  Li  Li7  1  0.268  0.686  0.267  1.0
  Li  Li8  1  0.010  0.342  0.259  1.0
  Li  Li9  1  0.347  0.314  0.410  1.0
  Li  Li10  1  0.315  0.344  0.929  1.0
  Li  Li11  1  0.613  0.381  0.128  1.0
  Li  Li12  1  0.370  0.026  0.128  1.0
  Li  Li13  1  0.705  0.001  0.261  1.0
  V  V14  1  0.009  0.981  0.995  1.0
  V  V15  1  0.984  0.007  0.495  1.0
  O  O16  1  0.027  0.001  0.669  1.0
  O  O17  1  0.304  0.684  0.452  1.0
  O  O18  1  0.699  0.982  0.441  1.0
  O  O19  1  0.677  0.637  0.722  1.0
  O  O20  1  0.989  0.695  0.938  1.0
  O  O21  1  0.995  0.313  0.448  1.0
  O  O22  1  0.359  0.317  0.223  1.0
  O  O23  1  0.313  0.000  0.949  1.0
  O  O24  1  0.684  0.300  0.952  1.0
  O  O25  1  0.003  0.025  0.168  1.0
  F  F26  1  0.636  0.678  0.219  1.0
  F  F27  1  0.316  0.357  0.719  1.0
[/CIF]
.
The structure described by Li7VO5F is Aluminum carbonitride-derived structured and crystallizes in the triclinic P1 space group. There are fourteen inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(4), one O(8), and one F(2) atom to form LiO3F tetrahedra that share  a cornercorner with one Li(2)O3F tetrahedra,  a cornercorner with one V(1)O4 tetrahedra,  a cornercorner with one V(2)O4 tetrahedra, corners with three equivalent Li(6)O3F tetrahedra,  a cornercorner with one Li(13)O3F trigonal pyramid,  a cornercorner with one Li(7)O3F trigonal pyramid, corners with three equivalent Li(5)O3F trigonal pyramids,  an edgeedge with one Li(2)O3F tetrahedra,  an edgeedge with one Li(4)O4 tetrahedra,  an edgeedge with one Li(11)O3F trigonal pyramid, and  an edgeedge with one Li(7)O3F trigonal pyramid. In the second Li site, Li(2) is bonded to one O(1), one O(2), one O(4), and one F(2) atom to form distorted LiO3F tetrahedra that share  a cornercorner with one Li(1)O3F tetrahedra,  a cornercorner with one Li(6)O3F tetrahedra,  a cornercorner with one Li(10)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(11)O3F trigonal pyramid,  a cornercorner with one Li(3)O3F trigonal pyramid,  a cornercorner with one Li(5)O3F trigonal pyramid,  a cornercorner with one Li(8)O3F trigonal pyramid, corners with three equivalent Li(7)O3F trigonal pyramids,  an edgeedge with one Li(1)O3F tetrahedra,  an edgeedge with one Li(6)O3F tetrahedra,  an edgeedge with one V(2)O4 tetrahedra, and  an edgeedge with one Li(5)O3F trigonal pyramid. In the third Li site, Li(3) is bonded to one O(2), one O(3), one O(6), and one F(1) atom to form LiO3F trigonal pyramids that share  a cornercorner with one Li(2)O3F tetrahedra, corners with three equivalent Li(10)O4 tetrahedra, corners with three equivalent V(2)O4 tetrahedra,  a cornercorner with one Li(12)O3F trigonal pyramid,  a cornercorner with one Li(13)O3F trigonal pyramid,  a cornercorner with one Li(7)O3F trigonal pyramid,  an edgeedge with one Li(14)O3F tetrahedra,  an edgeedge with one Li(9)O3F tetrahedra, and  an edgeedge with one Li(8)O3F trigonal pyramid. In the fourth Li site, Li(4) is bonded to one O(4), one O(5), one O(8), and one O(9) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(2)O3F tetrahedra, corners with three equivalent V(1)O4 tetrahedra,  a cornercorner with one Li(12)O3F trigonal pyramid,  a cornercorner with one Li(13)O3F trigonal pyramid,  a cornercorner with one Li(7)O3F trigonal pyramid, corners with three equivalent Li(11)O3F trigonal pyramids,  an edgeedge with one Li(1)O3F tetrahedra,  an edgeedge with one Li(6)O3F tetrahedra, and  an edgeedge with one Li(5)O3F trigonal pyramid. In the fifth Li site, Li(5) is bonded to one O(1), one O(4), one O(5), and one F(2) atom to form distorted LiO3F trigonal pyramids that share  a cornercorner with one Li(2)O3F tetrahedra,  a cornercorner with one V(1)O4 tetrahedra,  a cornercorner with one V(2)O4 tetrahedra, corners with three equivalent Li(1)O3F tetrahedra, corners with three equivalent Li(6)O3F tetrahedra,  a cornercorner with one Li(7)O3F trigonal pyramid,  an edgeedge with one Li(2)O3F tetrahedra,  an edgeedge with one Li(4)O4 tetrahedra,  an edgeedge with one Li(11)O3F trigonal pyramid, and  an edgeedge with one Li(7)O3F trigonal pyramid. In the sixth Li site, Li(6) is bonded to one O(1), one O(4), one O(9), and one F(2) atom to form LiO3F tetrahedra that share  a cornercorner with one Li(2)O3F tetrahedra,  a cornercorner with one V(1)O4 tetrahedra,  a cornercorner with one V(2)O4 tetrahedra, corners with three equivalent Li(1)O3F tetrahedra,  a cornercorner with one Li(12)O3F trigonal pyramid,  a cornercorner with one Li(7)O3F trigonal pyramid, corners with three equivalent Li(5)O3F trigonal pyramids,  an edgeedge with one Li(2)O3F tetrahedra,  an edgeedge with one Li(4)O4 tetrahedra,  an edgeedge with one Li(11)O3F trigonal pyramid, and  an edgeedge with one Li(7)O3F trigonal pyramid. In the seventh Li site, Li(7) is bonded to one O(1), one O(4), one O(6), and one F(2) atom to form distorted LiO3F trigonal pyramids that share  a cornercorner with one Li(1)O3F tetrahedra,  a cornercorner with one Li(6)O3F tetrahedra,  a cornercorner with one Li(9)O3F tetrahedra,  a cornercorner with one Li(10)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with three equivalent Li(2)O3F tetrahedra,  a cornercorner with one Li(11)O3F trigonal pyramid,  a cornercorner with one Li(3)O3F trigonal pyramid,  a cornercorner with one Li(5)O3F trigonal pyramid,  an edgeedge with one Li(1)O3F tetrahedra,  an edgeedge with one Li(6)O3F tetrahedra,  an edgeedge with one V(2)O4 tetrahedra, and  an edgeedge with one Li(5)O3F trigonal pyramid. In the eighth Li site, Li(8) is bonded to one O(10), one O(2), one O(7), and one F(1) atom to form LiO3F trigonal pyramids that share  a cornercorner with one Li(2)O3F tetrahedra,  a cornercorner with one V(1)O4 tetrahedra,  a cornercorner with one V(2)O4 tetrahedra, corners with three equivalent Li(14)O3F tetrahedra, corners with three equivalent Li(9)O3F tetrahedra,  a cornercorner with one Li(12)O3F trigonal pyramid,  a cornercorner with one Li(13)O3F trigonal pyramid,  an edgeedge with one Li(10)O4 tetrahedra,  an edgeedge with one Li(12)O3F trigonal pyramid,  an edgeedge with one Li(13)O3F trigonal pyramid, and  an edgeedge with one Li(3)O3F trigonal pyramid. In the ninth Li site, Li(9) is bonded to one O(10), one O(6), one O(7), and one F(1) atom to form LiO3F tetrahedra that share  a cornercorner with one V(1)O4 tetrahedra,  a cornercorner with one V(2)O4 tetrahedra, corners with three equivalent Li(14)O3F tetrahedra,  a cornercorner with one Li(12)O3F trigonal pyramid,  a cornercorner with one Li(13)O3F trigonal pyramid,  a cornercorner with one Li(7)O3F trigonal pyramid, corners with three equivalent Li(8)O3F trigonal pyramids,  an edgeedge with one Li(10)O4 tetrahedra,  an edgeedge with one Li(12)O3F trigonal pyramid,  an edgeedge with one Li(13)O3F trigonal pyramid, and  an edgeedge with one Li(3)O3F trigonal pyramid. In the tenth Li site, Li(10) is bonded to one O(2), one O(3), one O(6), and one O(7) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(2)O3F tetrahedra, corners with three equivalent V(2)O4 tetrahedra,  a cornercorner with one Li(12)O3F trigonal pyramid,  a cornercorner with one Li(13)O3F trigonal pyramid,  a cornercorner with one Li(7)O3F trigonal pyramid, corners with three equivalent Li(3)O3F trigonal pyramids,  an edgeedge with one Li(14)O3F tetrahedra,  an edgeedge with one Li(9)O3F tetrahedra, and  an edgeedge with one Li(8)O3F trigonal pyramid. In the eleventh Li site, Li(11) is bonded to one O(5), one O(8), one O(9), and one F(2) atom to form LiO3F trigonal pyramids that share  a cornercorner with one Li(2)O3F tetrahedra, corners with three equivalent Li(4)O4 tetrahedra, corners with three equivalent V(1)O4 tetrahedra,  a cornercorner with one Li(12)O3F trigonal pyramid,  a cornercorner with one Li(13)O3F trigonal pyramid,  a cornercorner with one Li(7)O3F trigonal pyramid,  an edgeedge with one Li(1)O3F tetrahedra,  an edgeedge with one Li(6)O3F tetrahedra, and  an edgeedge with one Li(5)O3F trigonal pyramid. In the twelfth Li site, Li(12) is bonded to one O(10), one O(7), one O(9), and one F(1) atom to form distorted LiO3F trigonal pyramids that share  a cornercorner with one Li(14)O3F tetrahedra,  a cornercorner with one Li(6)O3F tetrahedra,  a cornercorner with one Li(9)O3F tetrahedra,  a cornercorner with one Li(10)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(11)O3F trigonal pyramid,  a cornercorner with one Li(3)O3F trigonal pyramid,  a cornercorner with one Li(8)O3F trigonal pyramid, corners with three equivalent Li(13)O3F trigonal pyramids,  an edgeedge with one Li(14)O3F tetrahedra,  an edgeedge with one Li(9)O3F tetrahedra,  an edgeedge with one V(1)O4 tetrahedra, and  an edgeedge with one Li(8)O3F trigonal pyramid. In the thirteenth Li site, Li(13) is bonded to one O(10), one O(7), one O(8), and one F(1) atom to form distorted LiO3F trigonal pyramids that share  a cornercorner with one Li(1)O3F tetrahedra,  a cornercorner with one Li(14)O3F tetrahedra,  a cornercorner with one Li(9)O3F tetrahedra,  a cornercorner with one Li(10)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(11)O3F trigonal pyramid,  a cornercorner with one Li(3)O3F trigonal pyramid,  a cornercorner with one Li(8)O3F trigonal pyramid, corners with three equivalent Li(12)O3F trigonal pyramids,  an edgeedge with one Li(14)O3F tetrahedra,  an edgeedge with one Li(9)O3F tetrahedra,  an edgeedge with one V(1)O4 tetrahedra, and  an edgeedge with one Li(8)O3F trigonal pyramid. In the fourteenth Li site, Li(14) is bonded to one O(10), one O(3), one O(7), and one F(1) atom to form LiO3F tetrahedra that share  a cornercorner with one V(1)O4 tetrahedra,  a cornercorner with one V(2)O4 tetrahedra, corners with three equivalent Li(9)O3F tetrahedra,  a cornercorner with one Li(12)O3F trigonal pyramid,  a cornercorner with one Li(13)O3F trigonal pyramid, corners with three equivalent Li(8)O3F trigonal pyramids,  an edgeedge with one Li(10)O4 tetrahedra,  an edgeedge with one Li(12)O3F trigonal pyramid,  an edgeedge with one Li(13)O3F trigonal pyramid, and  an edgeedge with one Li(3)O3F trigonal pyramid. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(10), one O(5), one O(8), and one O(9) atom to form VO4 tetrahedra that share  a cornercorner with one Li(1)O3F tetrahedra,  a cornercorner with one Li(14)O3F tetrahedra,  a cornercorner with one Li(6)O3F tetrahedra,  a cornercorner with one Li(9)O3F tetrahedra, corners with three equivalent Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O3F trigonal pyramid,  a cornercorner with one Li(8)O3F trigonal pyramid, corners with three equivalent Li(11)O3F trigonal pyramids,  an edgeedge with one Li(12)O3F trigonal pyramid, and  an edgeedge with one Li(13)O3F trigonal pyramid. In the second V site, V(2) is bonded to one O(1), one O(2), one O(3), and one O(6) atom to form VO4 tetrahedra that share  a cornercorner with one Li(1)O3F tetrahedra,  a cornercorner with one Li(14)O3F tetrahedra,  a cornercorner with one Li(6)O3F tetrahedra,  a cornercorner with one Li(9)O3F tetrahedra, corners with three equivalent Li(10)O4 tetrahedra,  a cornercorner with one Li(5)O3F trigonal pyramid,  a cornercorner with one Li(8)O3F trigonal pyramid, corners with three equivalent Li(3)O3F trigonal pyramids,  an edgeedge with one Li(2)O3F tetrahedra, and  an edgeedge with one Li(7)O3F trigonal pyramid. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a 6-coordinate geometry to one Li(1), one Li(2), one Li(5), one Li(6), one Li(7), and one V(2) atom. In the second O site, O(2) is bonded to one Li(10), one Li(2), one Li(3), one Li(8), and one V(2) atom to form OLi4V trigonal bipyramids that share corners with three equivalent O(6)Li4V trigonal bipyramids and corners with three equivalent O(3)Li3V trigonal pyramids. In the third O site, O(3) is bonded to one Li(10), one Li(14), one Li(3), and one V(2) atom to form distorted corner-sharing OLi3V trigonal pyramids. In the fourth O site, O(4) is bonded in a 6-coordinate geometry to one Li(1), one Li(2), one Li(4), one Li(5), one Li(6), and one Li(7) atom. In the fifth O site, O(5) is bonded to one Li(11), one Li(4), one Li(5), and one V(1) atom to form distorted corner-sharing OLi3V trigonal pyramids. In the sixth O site, O(6) is bonded to one Li(10), one Li(3), one Li(7), one Li(9), and one V(2) atom to form OLi4V trigonal bipyramids that share corners with three equivalent O(2)Li4V trigonal bipyramids and corners with three equivalent O(3)Li3V trigonal pyramids. In the seventh O site, O(7) is bonded in a 6-coordinate geometry to one Li(10), one Li(12), one Li(13), one Li(14), one Li(8), and one Li(9) atom. In the eighth O site, O(8) is bonded to one Li(1), one Li(11), one Li(13), one Li(4), and one V(1) atom to form OLi4V trigonal bipyramids that share corners with three equivalent O(9)Li4V trigonal bipyramids and corners with three equivalent O(5)Li3V trigonal pyramids. In the ninth O site, O(9) is bonded to one Li(11), one Li(12), one Li(4), one Li(6), and one V(1) atom to form OLi4V trigonal bipyramids that share corners with three equivalent O(8)Li4V trigonal bipyramids and corners with three equivalent O(5)Li3V trigonal pyramids. In the tenth O site, O(10) is bonded in a 6-coordinate geometry to one Li(12), one Li(13), one Li(14), one Li(8), one Li(9), and one V(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a 6-coordinate geometry to one Li(12), one Li(13), one Li(14), one Li(3), one Li(8), and one Li(9) atom. In the second F site, F(2) is bonded in a 6-coordinate geometry to one Li(1), one Li(11), one Li(2), one Li(5), one Li(6), and one Li(7) atom. is represented by the CIF file [CIF]
data_Li7VO5F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.591
_cell_length_b   5.596
_cell_length_c   10.798
_cell_angle_alpha   89.000
_cell_angle_beta   88.716
_cell_angle_gamma   60.395
_symmetry_Int_Tables_number   1
_cell_volume   293.632
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.357  0.982  0.758  1.0
  Li  Li1  1  0.393  0.630  0.630  1.0
  Li  Li2  1  0.651  0.670  0.428  1.0
  Li  Li3  1  0.671  0.648  0.909  1.0
  Li  Li4  1  0.954  0.732  0.757  1.0
  Li  Li5  1  0.707  0.292  0.770  1.0
  Li  Li6  1  0.993  0.387  0.627  1.0
  Li  Li7  1  0.268  0.686  0.267  1.0
  Li  Li8  1  0.010  0.342  0.259  1.0
  Li  Li9  1  0.347  0.314  0.410  1.0
  Li  Li10  1  0.315  0.344  0.929  1.0
  Li  Li11  1  0.613  0.381  0.128  1.0
  Li  Li12  1  0.370  0.026  0.128  1.0
  Li  Li13  1  0.705  0.001  0.261  1.0
  V  V14  1  0.009  0.981  0.995  1.0
  V  V15  1  0.984  0.007  0.495  1.0
  O  O16  1  0.027  0.001  0.669  1.0
  O  O17  1  0.304  0.684  0.452  1.0
  O  O18  1  0.699  0.982  0.441  1.0
  O  O19  1  0.677  0.637  0.722  1.0
  O  O20  1  0.989  0.695  0.938  1.0
  O  O21  1  0.995  0.313  0.448  1.0
  O  O22  1  0.359  0.317  0.223  1.0
  O  O23  1  0.313  0.000  0.949  1.0
  O  O24  1  0.684  0.300  0.952  1.0
  O  O25  1  0.003  0.025  0.168  1.0
  F  F26  1  0.636  0.678  0.219  1.0
  F  F27  1  0.316  0.357  0.719  1.0
[/CIF]
.