The crystal structure described by Cs4Mn(AsS4)2 crystallizes in the triclinic P-1 space group. There are four inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a 9-coordinate geometry to one S(1), one S(3), one S(6), one S(7), one S(8), two equivalent S(4), and two equivalent S(5) atoms. In the second Cs site, Cs(2) is bonded in a 8-coordinate geometry to one S(3), one S(8), two equivalent S(1), two equivalent S(2), and two equivalent S(5) atoms. In the third Cs site, Cs(3) is bonded in a 8-coordinate geometry to one S(1), one S(2), one S(4), one S(6), two equivalent S(7), and two equivalent S(8) atoms. In the fourth Cs site, Cs(4) is bonded in a 7-coordinate geometry to one S(2), one S(5), one S(6), two equivalent S(3), and two equivalent S(8) atoms. Mn(1) is bonded to one S(1), one S(2), one S(4), one S(7), and two equivalent S(6) atoms to form MnS6 octahedra that share  an edgeedge with one Mn(1)S6 octahedra,  an edgeedge with one As(2)S4 tetrahedra, and edges with two equivalent As(1)S4 tetrahedra. There are two inequivalent As sites. In the first As site, As(1) is bonded to one S(1), one S(5), one S(6), and one S(7) atom to form AsS4 tetrahedra that share edges with two equivalent Mn(1)S6 octahedra. In the second As site, As(2) is bonded to one S(2), one S(3), one S(4), and one S(8) atom to form AsS4 tetrahedra that share  an edgeedge with one Mn(1)S6 octahedra. There are eight inequivalent S sites. In the first S site, S(1) is bonded in a 6-coordinate geometry to one Cs(1), one Cs(3), two equivalent Cs(2), one Mn(1), and one As(1) atom. In the second S site, S(2) is bonded in a 6-coordinate geometry to one Cs(3), one Cs(4), two equivalent Cs(2), one Mn(1), and one As(2) atom. In the third S site, S(3) is bonded to one Cs(1), one Cs(2), two equivalent Cs(4), and one As(2) atom to form distorted edge-sharing SCs4As square pyramids. In the fourth S site, S(4) is bonded in a 5-coordinate geometry to one Cs(3), two equivalent Cs(1), one Mn(1), and one As(2) atom. In the fifth S site, S(5) is bonded in a 6-coordinate geometry to one Cs(4), two equivalent Cs(1), two equivalent Cs(2), and one As(1) atom. In the sixth S site, S(6) is bonded in a 6-coordinate geometry to one Cs(1), one Cs(3), one Cs(4), two equivalent Mn(1), and one As(1) atom. In the seventh S site, S(7) is bonded in a 5-coordinate geometry to one Cs(1), two equivalent Cs(3), one Mn(1), and one As(1) atom. In the eighth S site, S(8) is bonded in a 7-coordinate geometry to one Cs(1), one Cs(2), two equivalent Cs(3), two equivalent Cs(4), and one As(2) atom. is represented by the CIF card [CIF]
data_Cs4Mn(AsS4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.602
_cell_length_b   9.763
_cell_length_c   11.584
_cell_angle_alpha   105.222
_cell_angle_beta   104.620
_cell_angle_gamma   90.749
_symmetry_Int_Tables_number   1
_cell_volume   1010.263
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.932  0.522  0.250  1.0
  Cs  Cs1  1  0.068  0.478  0.750  1.0
  Cs  Cs2  1  0.761  0.982  0.456  1.0
  Cs  Cs3  1  0.239  0.018  0.544  1.0
  Cs  Cs4  1  0.599  0.743  0.015  1.0
  Cs  Cs5  1  0.401  0.257  0.985  1.0
  Cs  Cs6  1  0.618  0.683  0.624  1.0
  Cs  Cs7  1  0.382  0.317  0.376  1.0
  Mn  Mn8  1  0.851  0.139  0.927  1.0
  Mn  Mn9  1  0.149  0.861  0.073  1.0
  As  As10  1  0.955  0.110  0.220  1.0
  As  As11  1  0.045  0.890  0.780  1.0
  As  As12  1  0.363  0.693  0.254  1.0
  As  As13  1  0.637  0.307  0.746  1.0
  S  S14  1  0.983  0.887  0.221  1.0
  S  S15  1  0.017  0.113  0.779  1.0
  S  S16  1  0.610  0.083  0.753  1.0
  S  S17  1  0.390  0.917  0.247  1.0
  S  S18  1  0.285  0.672  0.410  1.0
  S  S19  1  0.715  0.328  0.590  1.0
  S  S20  1  0.803  0.397  0.922  1.0
  S  S21  1  0.197  0.603  0.078  1.0
  S  S22  1  0.007  0.250  0.407  1.0
  S  S23  1  0.993  0.750  0.593  1.0
  S  S24  1  0.093  0.161  0.109  1.0
  S  S25  1  0.907  0.839  0.891  1.0
  S  S26  1  0.739  0.132  0.108  1.0
  S  S27  1  0.261  0.868  0.892  1.0
  S  S28  1  0.565  0.591  0.261  1.0
  S  S29  1  0.435  0.409  0.739  1.0
[/CIF]
.
The crystal structure described by Cs4Mn(AsS4)2 crystallizes in the triclinic P-1 space group. There are four inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a 9-coordinate geometry to one S(1), one S(3), one S(6), one S(7), one S(8), two equivalent S(4), and two equivalent S(5) atoms. In the second Cs site, Cs(2) is bonded in a 8-coordinate geometry to one S(3), one S(8), two equivalent S(1), two equivalent S(2), and two equivalent S(5) atoms. In the third Cs site, Cs(3) is bonded in a 8-coordinate geometry to one S(1), one S(2), one S(4), one S(6), two equivalent S(7), and two equivalent S(8) atoms. In the fourth Cs site, Cs(4) is bonded in a 7-coordinate geometry to one S(2), one S(5), one S(6), two equivalent S(3), and two equivalent S(8) atoms. Mn(1) is bonded to one S(1), one S(2), one S(4), one S(7), and two equivalent S(6) atoms to form MnS6 octahedra that share  an edgeedge with one Mn(1)S6 octahedra,  an edgeedge with one As(2)S4 tetrahedra, and edges with two equivalent As(1)S4 tetrahedra. There are two inequivalent As sites. In the first As site, As(1) is bonded to one S(1), one S(5), one S(6), and one S(7) atom to form AsS4 tetrahedra that share edges with two equivalent Mn(1)S6 octahedra. In the second As site, As(2) is bonded to one S(2), one S(3), one S(4), and one S(8) atom to form AsS4 tetrahedra that share  an edgeedge with one Mn(1)S6 octahedra. There are eight inequivalent S sites. In the first S site, S(1) is bonded in a 6-coordinate geometry to one Cs(1), one Cs(3), two equivalent Cs(2), one Mn(1), and one As(1) atom. In the second S site, S(2) is bonded in a 6-coordinate geometry to one Cs(3), one Cs(4), two equivalent Cs(2), one Mn(1), and one As(2) atom. In the third S site, S(3) is bonded to one Cs(1), one Cs(2), two equivalent Cs(4), and one As(2) atom to form distorted edge-sharing SCs4As square pyramids. In the fourth S site, S(4) is bonded in a 5-coordinate geometry to one Cs(3), two equivalent Cs(1), one Mn(1), and one As(2) atom. In the fifth S site, S(5) is bonded in a 6-coordinate geometry to one Cs(4), two equivalent Cs(1), two equivalent Cs(2), and one As(1) atom. In the sixth S site, S(6) is bonded in a 6-coordinate geometry to one Cs(1), one Cs(3), one Cs(4), two equivalent Mn(1), and one As(1) atom. In the seventh S site, S(7) is bonded in a 5-coordinate geometry to one Cs(1), two equivalent Cs(3), one Mn(1), and one As(1) atom. In the eighth S site, S(8) is bonded in a 7-coordinate geometry to one Cs(1), one Cs(2), two equivalent Cs(3), two equivalent Cs(4), and one As(2) atom. is represented by the CIF card [CIF]
data_Cs4Mn(AsS4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.602
_cell_length_b   9.763
_cell_length_c   11.584
_cell_angle_alpha   105.222
_cell_angle_beta   104.620
_cell_angle_gamma   90.749
_symmetry_Int_Tables_number   1
_cell_volume   1010.263
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.932  0.522  0.250  1.0
  Cs  Cs1  1  0.068  0.478  0.750  1.0
  Cs  Cs2  1  0.761  0.982  0.456  1.0
  Cs  Cs3  1  0.239  0.018  0.544  1.0
  Cs  Cs4  1  0.599  0.743  0.015  1.0
  Cs  Cs5  1  0.401  0.257  0.985  1.0
  Cs  Cs6  1  0.618  0.683  0.624  1.0
  Cs  Cs7  1  0.382  0.317  0.376  1.0
  Mn  Mn8  1  0.851  0.139  0.927  1.0
  Mn  Mn9  1  0.149  0.861  0.073  1.0
  As  As10  1  0.955  0.110  0.220  1.0
  As  As11  1  0.045  0.890  0.780  1.0
  As  As12  1  0.363  0.693  0.254  1.0
  As  As13  1  0.637  0.307  0.746  1.0
  S  S14  1  0.983  0.887  0.221  1.0
  S  S15  1  0.017  0.113  0.779  1.0
  S  S16  1  0.610  0.083  0.753  1.0
  S  S17  1  0.390  0.917  0.247  1.0
  S  S18  1  0.285  0.672  0.410  1.0
  S  S19  1  0.715  0.328  0.590  1.0
  S  S20  1  0.803  0.397  0.922  1.0
  S  S21  1  0.197  0.603  0.078  1.0
  S  S22  1  0.007  0.250  0.407  1.0
  S  S23  1  0.993  0.750  0.593  1.0
  S  S24  1  0.093  0.161  0.109  1.0
  S  S25  1  0.907  0.839  0.891  1.0
  S  S26  1  0.739  0.132  0.108  1.0
  S  S27  1  0.261  0.868  0.892  1.0
  S  S28  1  0.565  0.591  0.261  1.0
  S  S29  1  0.435  0.409  0.739  1.0
[/CIF]
.