The structure described by WCo6N4 crystallizes in the tetragonal P4_2/nmc space group. W(1) is bonded in a 4-coordinate geometry to four equivalent N(1) atoms. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a linear geometry to two equivalent N(1) atoms. In the second Co site, Co(2) is bonded in a 4-coordinate geometry to four equivalent N(1) atoms. N(1) is bonded in a 6-coordinate geometry to one W(1), one Co(1), and four equivalent Co(2) atoms. is represented by the CIF file [CIF]
data_Co6WN4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.502
_cell_length_b   6.502
_cell_length_c   5.242
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   221.567
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.000  0.500  0.214  1.0
  Co  Co1  1  0.500  0.000  0.286  1.0
  Co  Co2  1  0.500  0.000  0.786  1.0
  Co  Co3  1  0.000  0.500  0.714  1.0
  Co  Co4  1  0.208  0.208  0.500  1.0
  Co  Co5  1  0.792  0.792  0.500  1.0
  Co  Co6  1  0.708  0.708  0.000  1.0
  Co  Co7  1  0.292  0.292  0.000  1.0
  Co  Co8  1  0.792  0.208  0.500  1.0
  Co  Co9  1  0.208  0.792  0.500  1.0
  Co  Co10  1  0.292  0.708  0.000  1.0
  Co  Co11  1  0.708  0.292  0.000  1.0
  W  W12  1  0.500  0.500  0.500  1.0
  W  W13  1  0.000  0.000  0.000  1.0
  N  N14  1  0.279  0.500  0.244  1.0
  N  N15  1  0.721  0.500  0.244  1.0
  N  N16  1  0.779  0.000  0.256  1.0
  N  N17  1  0.221  0.000  0.256  1.0
  N  N18  1  0.500  0.279  0.756  1.0
  N  N19  1  0.500  0.721  0.756  1.0
  N  N20  1  0.000  0.779  0.744  1.0
  N  N21  1  0.000  0.221  0.744  1.0
[/CIF]
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The structure described by WCo6N4 crystallizes in the tetragonal P4_2/nmc space group. W(1) is bonded in a 4-coordinate geometry to four equivalent N(1) atoms. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a linear geometry to two equivalent N(1) atoms. In the second Co site, Co(2) is bonded in a 4-coordinate geometry to four equivalent N(1) atoms. N(1) is bonded in a 6-coordinate geometry to one W(1), one Co(1), and four equivalent Co(2) atoms. is represented by the CIF file [CIF]
data_Co6WN4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.502
_cell_length_b   6.502
_cell_length_c   5.242
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   221.567
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.000  0.500  0.214  1.0
  Co  Co1  1  0.500  0.000  0.286  1.0
  Co  Co2  1  0.500  0.000  0.786  1.0
  Co  Co3  1  0.000  0.500  0.714  1.0
  Co  Co4  1  0.208  0.208  0.500  1.0
  Co  Co5  1  0.792  0.792  0.500  1.0
  Co  Co6  1  0.708  0.708  0.000  1.0
  Co  Co7  1  0.292  0.292  0.000  1.0
  Co  Co8  1  0.792  0.208  0.500  1.0
  Co  Co9  1  0.208  0.792  0.500  1.0
  Co  Co10  1  0.292  0.708  0.000  1.0
  Co  Co11  1  0.708  0.292  0.000  1.0
  W  W12  1  0.500  0.500  0.500  1.0
  W  W13  1  0.000  0.000  0.000  1.0
  N  N14  1  0.279  0.500  0.244  1.0
  N  N15  1  0.721  0.500  0.244  1.0
  N  N16  1  0.779  0.000  0.256  1.0
  N  N17  1  0.221  0.000  0.256  1.0
  N  N18  1  0.500  0.279  0.756  1.0
  N  N19  1  0.500  0.721  0.756  1.0
  N  N20  1  0.000  0.779  0.744  1.0
  N  N21  1  0.000  0.221  0.744  1.0
[/CIF]
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