The material described by LiN4N2PNH2S3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four ammonia atoms, two LiN4 clusters, and two PNH2S3 clusters. In each LiN4 cluster, Li(1) is bonded in a rectangular see-saw-like geometry to one N(2), one N(4), one N(5), and one N(7) atom. There are four inequivalent N sites. In the first N site, N(2) is bonded in a single-bond geometry to one Li(1) atom. In the second N site, N(4) is bonded in a single-bond geometry to one Li(1) atom. In the third N site, N(5) is bonded in a single-bond geometry to one Li(1) atom. In the fourth N site, N(7) is bonded in a single-bond geometry to one Li(1) atom. In each PNH2S3 cluster, P(1) is bonded in a 4-coordinate geometry to one N(1), one S(1), one S(2), and one S(3) atom. N(1) is bonded in a trigonal planar geometry to one P(1), one H(1), and one H(2) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a 2-coordinate geometry to one P(1) and one S(2) atom. In the second S site, S(2) is bonded in a distorted single-bond geometry to one P(1) and one S(1) atom. In the third S site, S(3) is bonded in a single-bond geometry to one P(1) atom. is represented by the CIF card [CIF]
data_LiPH2S3N7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.599
_cell_length_b   6.755
_cell_length_c   13.524
_cell_angle_alpha   85.212
_cell_angle_beta   87.868
_cell_angle_gamma   74.635
_symmetry_Int_Tables_number   1
_cell_volume   579.197
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.105  0.250  0.419  1.0
  Li  Li1  1  0.895  0.750  0.581  1.0
  P  P2  1  0.522  0.315  0.180  1.0
  P  P3  1  0.478  0.685  0.820  1.0
  H  H4  1  0.869  0.317  0.148  1.0
  H  H5  1  0.131  0.683  0.852  1.0
  H  H6  1  0.707  0.429  0.049  1.0
  H  H7  1  0.293  0.571  0.951  1.0
  S  S8  1  0.490  0.423  0.324  1.0
  S  S9  1  0.510  0.577  0.676  1.0
  S  S10  1  0.621  0.104  0.301  1.0
  S  S11  1  0.379  0.896  0.699  1.0
  S  S12  1  0.276  0.337  0.101  1.0
  S  S13  1  0.724  0.663  0.899  1.0
  N  N14  1  0.728  0.338  0.114  1.0
  N  N15  1  0.272  0.662  0.886  1.0
  N  N16  1  0.011  0.451  0.679  1.0
  N  N17  1  0.989  0.549  0.321  1.0
  N  N18  1  0.439  0.836  0.104  1.0
  N  N19  1  0.561  0.164  0.896  1.0
  N  N20  1  0.383  0.238  0.496  1.0
  N  N21  1  0.617  0.762  0.504  1.0
  N  N22  1  0.108  0.063  0.291  1.0
  N  N23  1  0.892  0.937  0.709  1.0
  N  N24  1  0.051  0.197  0.913  1.0
  N  N25  1  0.949  0.803  0.087  1.0
  N  N26  1  0.199  0.768  0.530  1.0
  N  N27  1  0.801  0.232  0.470  1.0
[/CIF]
.
The material described by LiN4N2PNH2S3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four ammonia atoms, two LiN4 clusters, and two PNH2S3 clusters. In each LiN4 cluster, Li(1) is bonded in a rectangular see-saw-like geometry to one N(2), one N(4), one N(5), and one N(7) atom. There are four inequivalent N sites. In the first N site, N(2) is bonded in a single-bond geometry to one Li(1) atom. In the second N site, N(4) is bonded in a single-bond geometry to one Li(1) atom. In the third N site, N(5) is bonded in a single-bond geometry to one Li(1) atom. In the fourth N site, N(7) is bonded in a single-bond geometry to one Li(1) atom. In each PNH2S3 cluster, P(1) is bonded in a 4-coordinate geometry to one N(1), one S(1), one S(2), and one S(3) atom. N(1) is bonded in a trigonal planar geometry to one P(1), one H(1), and one H(2) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a 2-coordinate geometry to one P(1) and one S(2) atom. In the second S site, S(2) is bonded in a distorted single-bond geometry to one P(1) and one S(1) atom. In the third S site, S(3) is bonded in a single-bond geometry to one P(1) atom. is represented by the CIF card [CIF]
data_LiPH2S3N7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.599
_cell_length_b   6.755
_cell_length_c   13.524
_cell_angle_alpha   85.212
_cell_angle_beta   87.868
_cell_angle_gamma   74.635
_symmetry_Int_Tables_number   1
_cell_volume   579.197
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.105  0.250  0.419  1.0
  Li  Li1  1  0.895  0.750  0.581  1.0
  P  P2  1  0.522  0.315  0.180  1.0
  P  P3  1  0.478  0.685  0.820  1.0
  H  H4  1  0.869  0.317  0.148  1.0
  H  H5  1  0.131  0.683  0.852  1.0
  H  H6  1  0.707  0.429  0.049  1.0
  H  H7  1  0.293  0.571  0.951  1.0
  S  S8  1  0.490  0.423  0.324  1.0
  S  S9  1  0.510  0.577  0.676  1.0
  S  S10  1  0.621  0.104  0.301  1.0
  S  S11  1  0.379  0.896  0.699  1.0
  S  S12  1  0.276  0.337  0.101  1.0
  S  S13  1  0.724  0.663  0.899  1.0
  N  N14  1  0.728  0.338  0.114  1.0
  N  N15  1  0.272  0.662  0.886  1.0
  N  N16  1  0.011  0.451  0.679  1.0
  N  N17  1  0.989  0.549  0.321  1.0
  N  N18  1  0.439  0.836  0.104  1.0
  N  N19  1  0.561  0.164  0.896  1.0
  N  N20  1  0.383  0.238  0.496  1.0
  N  N21  1  0.617  0.762  0.504  1.0
  N  N22  1  0.108  0.063  0.291  1.0
  N  N23  1  0.892  0.937  0.709  1.0
  N  N24  1  0.051  0.197  0.913  1.0
  N  N25  1  0.949  0.803  0.087  1.0
  N  N26  1  0.199  0.768  0.530  1.0
  N  N27  1  0.801  0.232  0.470  1.0
[/CIF]
.