The crystal structure described by B5F6 is Indium-like structured and crystallizes in the tetragonal I4_1/a space group. The structure is zero-dimensional and consists of four B5F6 clusters. There are three inequivalent B sites. In the first B site, B(1) is bonded in a 5-coordinate geometry to one B(2), one B(3), and three equivalent B(1) atoms. In the second B site, B(2) is bonded in a bent 120 degrees geometry to two equivalent B(1) and two equivalent F(1) atoms. In the third B site, B(3) is bonded in a bent 120 degrees geometry to one B(1), one F(2), and one F(3) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one B(2) atom. In the second F site, F(2) is bonded in a single-bond geometry to one B(3) atom. In the third F site, F(3) is bonded in a single-bond geometry to one B(3) atom. is represented by the CIF card [CIF]
data_B5F6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   14.766
_cell_length_b   14.766
_cell_length_c   14.766
_cell_angle_alpha   154.313
_cell_angle_beta   154.313
_cell_angle_gamma   36.645
_symmetry_Int_Tables_number   1
_cell_volume   604.108
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.395  0.568  0.011  1.0
  B  B1  1  0.318  0.807  0.672  1.0
  B  B2  1  0.135  0.645  0.328  1.0
  B  B3  1  0.557  0.385  0.989  1.0
  B  B4  1  0.355  0.682  0.489  1.0
  B  B5  1  0.432  0.443  0.828  1.0
  B  B6  1  0.615  0.605  0.172  1.0
  B  B7  1  0.193  0.865  0.511  1.0
  B  B8  1  0.419  0.419  0.000  1.0
  B  B9  1  0.169  0.669  0.500  1.0
  B  B10  1  0.331  0.831  0.500  1.0
  B  B11  1  0.581  0.581  0.000  1.0
  B  B12  1  0.203  0.721  0.013  1.0
  B  B13  1  0.471  0.958  0.017  1.0
  B  B14  1  0.940  0.453  0.983  1.0
  B  B15  1  0.708  0.190  0.987  1.0
  B  B16  1  0.547  0.529  0.487  1.0
  B  B17  1  0.279  0.292  0.483  1.0
  B  B18  1  0.810  0.797  0.517  1.0
  B  B19  1  0.042  0.060  0.513  1.0
  F  F20  1  0.255  0.287  0.755  1.0
  F  F21  1  0.037  0.782  0.532  1.0
  F  F22  1  0.250  0.505  0.468  1.0
  F  F23  1  0.532  0.500  0.245  1.0
  F  F24  1  0.495  0.963  0.745  1.0
  F  F25  1  0.713  0.468  0.968  1.0
  F  F26  1  0.500  0.745  0.032  1.0
  F  F27  1  0.218  0.750  0.255  1.0
  F  F28  1  0.010  0.647  0.789  1.0
  F  F29  1  0.397  0.108  0.136  1.0
  F  F30  1  0.971  0.260  0.864  1.0
  F  F31  1  0.858  0.221  0.211  1.0
  F  F32  1  0.740  0.603  0.711  1.0
  F  F33  1  0.353  0.142  0.364  1.0
  F  F34  1  0.779  0.990  0.636  1.0
  F  F35  1  0.892  0.029  0.289  1.0
  F  F36  1  0.243  0.927  0.243  1.0
  F  F37  1  0.677  0.935  0.184  1.0
  F  F38  1  0.750  0.493  0.816  1.0
  F  F39  1  0.685  0.000  0.757  1.0
  F  F40  1  0.507  0.323  0.257  1.0
  F  F41  1  0.073  0.315  0.316  1.0
  F  F42  1  1.000  0.757  0.684  1.0
  F  F43  1  0.065  0.250  0.743  1.0
[/CIF]
.
The crystal structure described by B5F6 is Indium-like structured and crystallizes in the tetragonal I4_1/a space group. The structure is zero-dimensional and consists of four B5F6 clusters. There are three inequivalent B sites. In the first B site, B(1) is bonded in a 5-coordinate geometry to one B(2), one B(3), and three equivalent B(1) atoms. In the second B site, B(2) is bonded in a bent 120 degrees geometry to two equivalent B(1) and two equivalent F(1) atoms. In the third B site, B(3) is bonded in a bent 120 degrees geometry to one B(1), one F(2), and one F(3) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one B(2) atom. In the second F site, F(2) is bonded in a single-bond geometry to one B(3) atom. In the third F site, F(3) is bonded in a single-bond geometry to one B(3) atom. is represented by the CIF card [CIF]
data_B5F6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   14.766
_cell_length_b   14.766
_cell_length_c   14.766
_cell_angle_alpha   154.313
_cell_angle_beta   154.313
_cell_angle_gamma   36.645
_symmetry_Int_Tables_number   1
_cell_volume   604.108
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.395  0.568  0.011  1.0
  B  B1  1  0.318  0.807  0.672  1.0
  B  B2  1  0.135  0.645  0.328  1.0
  B  B3  1  0.557  0.385  0.989  1.0
  B  B4  1  0.355  0.682  0.489  1.0
  B  B5  1  0.432  0.443  0.828  1.0
  B  B6  1  0.615  0.605  0.172  1.0
  B  B7  1  0.193  0.865  0.511  1.0
  B  B8  1  0.419  0.419  0.000  1.0
  B  B9  1  0.169  0.669  0.500  1.0
  B  B10  1  0.331  0.831  0.500  1.0
  B  B11  1  0.581  0.581  0.000  1.0
  B  B12  1  0.203  0.721  0.013  1.0
  B  B13  1  0.471  0.958  0.017  1.0
  B  B14  1  0.940  0.453  0.983  1.0
  B  B15  1  0.708  0.190  0.987  1.0
  B  B16  1  0.547  0.529  0.487  1.0
  B  B17  1  0.279  0.292  0.483  1.0
  B  B18  1  0.810  0.797  0.517  1.0
  B  B19  1  0.042  0.060  0.513  1.0
  F  F20  1  0.255  0.287  0.755  1.0
  F  F21  1  0.037  0.782  0.532  1.0
  F  F22  1  0.250  0.505  0.468  1.0
  F  F23  1  0.532  0.500  0.245  1.0
  F  F24  1  0.495  0.963  0.745  1.0
  F  F25  1  0.713  0.468  0.968  1.0
  F  F26  1  0.500  0.745  0.032  1.0
  F  F27  1  0.218  0.750  0.255  1.0
  F  F28  1  0.010  0.647  0.789  1.0
  F  F29  1  0.397  0.108  0.136  1.0
  F  F30  1  0.971  0.260  0.864  1.0
  F  F31  1  0.858  0.221  0.211  1.0
  F  F32  1  0.740  0.603  0.711  1.0
  F  F33  1  0.353  0.142  0.364  1.0
  F  F34  1  0.779  0.990  0.636  1.0
  F  F35  1  0.892  0.029  0.289  1.0
  F  F36  1  0.243  0.927  0.243  1.0
  F  F37  1  0.677  0.935  0.184  1.0
  F  F38  1  0.750  0.493  0.816  1.0
  F  F39  1  0.685  0.000  0.757  1.0
  F  F40  1  0.507  0.323  0.257  1.0
  F  F41  1  0.073  0.315  0.316  1.0
  F  F42  1  1.000  0.757  0.684  1.0
  F  F43  1  0.065  0.250  0.743  1.0
[/CIF]
.