The crystal structure described by VBO4 crystallizes in the triclinic P-1 space group. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(4), one O(5), and one O(8) atom to form VO4 tetrahedra that share  a cornercorner with one B(2)O4 tetrahedra,  a cornercorner with one B(3)O4 tetrahedra, and corners with two equivalent B(1)O4 tetrahedra. In the second V site, V(2) is bonded to one O(10), one O(2), one O(3), and one O(9) atom to form VO4 tetrahedra that share  a cornercorner with one B(1)O4 tetrahedra,  a cornercorner with one B(3)O4 tetrahedra, and corners with two equivalent B(2)O4 tetrahedra. In the third V site, V(3) is bonded to one O(11), one O(12), one O(6), and one O(7) atom to form VO4 tetrahedra that share  a cornercorner with one B(1)O4 tetrahedra,  a cornercorner with one B(2)O4 tetrahedra, and corners with two equivalent B(3)O4 tetrahedra. There are three inequivalent B sites. In the first B site, B(1) is bonded to one O(1), one O(11), one O(3), and one O(4) atom to form BO4 tetrahedra that share  a cornercorner with one V(2)O4 tetrahedra,  a cornercorner with one V(3)O4 tetrahedra, and corners with two equivalent V(1)O4 tetrahedra. In the second B site, B(2) is bonded to one O(2), one O(6), one O(8), and one O(9) atom to form BO4 tetrahedra that share  a cornercorner with one V(1)O4 tetrahedra,  a cornercorner with one V(3)O4 tetrahedra, and corners with two equivalent V(2)O4 tetrahedra. In the third B site, B(3) is bonded to one O(10), one O(12), one O(5), and one O(7) atom to form BO4 tetrahedra that share  a cornercorner with one V(1)O4 tetrahedra,  a cornercorner with one V(2)O4 tetrahedra, and corners with two equivalent V(3)O4 tetrahedra. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one V(1) and one B(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one V(2) and one B(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one V(2) and one B(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one V(1) and one B(1) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one V(1) and one B(3) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one V(3) and one B(2) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one V(3) and one B(3) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one V(1) and one B(2) atom. In the ninth O site, O(9) is bonded in a linear geometry to one V(2) and one B(2) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one V(2) and one B(3) atom. In the eleventh O site, O(11) is bonded in a linear geometry to one V(3) and one B(1) atom. In the twelfth O site, O(12) is bonded in a bent 150 degrees geometry to one V(3) and one B(3) atom. is represented by the CIF file [CIF]
data_VBO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.602
_cell_length_b   7.833
_cell_length_c   8.666
_cell_angle_alpha   107.521
_cell_angle_beta   96.185
_cell_angle_gamma   112.865
_symmetry_Int_Tables_number   1
_cell_volume   438.401
_cell_formula_units_Z   6
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.951  0.008  0.256  1.0
  V  V1  1  0.182  0.637  0.335  1.0
  V  V2  1  0.495  0.718  0.848  1.0
  V  V3  1  0.505  0.282  0.152  1.0
  V  V4  1  0.818  0.363  0.665  1.0
  V  V5  1  0.049  0.992  0.744  1.0
  B  B6  1  0.922  0.735  0.937  1.0
  B  B7  1  0.184  0.365  0.547  1.0
  B  B8  1  0.513  0.905  0.219  1.0
  B  B9  1  0.487  0.095  0.781  1.0
  B  B10  1  0.816  0.635  0.453  1.0
  B  B11  1  0.078  0.265  0.063  1.0
  O  O12  1  0.066  0.860  0.867  1.0
  O  O13  1  1.000  0.705  0.396  1.0
  O  O14  1  0.088  0.464  0.132  1.0
  O  O15  1  0.990  0.816  0.119  1.0
  O  O16  1  0.283  0.061  0.709  1.0
  O  O17  1  0.348  0.473  0.698  1.0
  O  O18  1  0.482  0.900  0.778  1.0
  O  O19  1  0.167  0.177  0.423  1.0
  O  O20  1  0.204  0.507  0.460  1.0
  O  O21  1  0.389  0.833  0.325  1.0
  O  O22  1  0.271  0.268  0.116  1.0
  O  O23  1  0.438  0.760  0.042  1.0
  O  O24  1  0.562  0.240  0.958  1.0
  O  O25  1  0.729  0.732  0.884  1.0
  O  O26  1  0.611  0.167  0.675  1.0
  O  O27  1  0.796  0.493  0.540  1.0
  O  O28  1  0.833  0.823  0.577  1.0
  O  O29  1  0.518  0.100  0.222  1.0
  O  O30  1  0.652  0.527  0.302  1.0
  O  O31  1  0.717  0.939  0.291  1.0
  O  O32  1  0.010  0.184  0.881  1.0
  O  O33  1  0.912  0.536  0.868  1.0
  O  O34  1  0.000  0.295  0.604  1.0
  O  O35  1  0.934  0.140  0.133  1.0
[/CIF]
.
The crystal structure described by VBO4 crystallizes in the triclinic P-1 space group. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(4), one O(5), and one O(8) atom to form VO4 tetrahedra that share  a cornercorner with one B(2)O4 tetrahedra,  a cornercorner with one B(3)O4 tetrahedra, and corners with two equivalent B(1)O4 tetrahedra. In the second V site, V(2) is bonded to one O(10), one O(2), one O(3), and one O(9) atom to form VO4 tetrahedra that share  a cornercorner with one B(1)O4 tetrahedra,  a cornercorner with one B(3)O4 tetrahedra, and corners with two equivalent B(2)O4 tetrahedra. In the third V site, V(3) is bonded to one O(11), one O(12), one O(6), and one O(7) atom to form VO4 tetrahedra that share  a cornercorner with one B(1)O4 tetrahedra,  a cornercorner with one B(2)O4 tetrahedra, and corners with two equivalent B(3)O4 tetrahedra. There are three inequivalent B sites. In the first B site, B(1) is bonded to one O(1), one O(11), one O(3), and one O(4) atom to form BO4 tetrahedra that share  a cornercorner with one V(2)O4 tetrahedra,  a cornercorner with one V(3)O4 tetrahedra, and corners with two equivalent V(1)O4 tetrahedra. In the second B site, B(2) is bonded to one O(2), one O(6), one O(8), and one O(9) atom to form BO4 tetrahedra that share  a cornercorner with one V(1)O4 tetrahedra,  a cornercorner with one V(3)O4 tetrahedra, and corners with two equivalent V(2)O4 tetrahedra. In the third B site, B(3) is bonded to one O(10), one O(12), one O(5), and one O(7) atom to form BO4 tetrahedra that share  a cornercorner with one V(1)O4 tetrahedra,  a cornercorner with one V(2)O4 tetrahedra, and corners with two equivalent V(3)O4 tetrahedra. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one V(1) and one B(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one V(2) and one B(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one V(2) and one B(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one V(1) and one B(1) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one V(1) and one B(3) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one V(3) and one B(2) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one V(3) and one B(3) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one V(1) and one B(2) atom. In the ninth O site, O(9) is bonded in a linear geometry to one V(2) and one B(2) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one V(2) and one B(3) atom. In the eleventh O site, O(11) is bonded in a linear geometry to one V(3) and one B(1) atom. In the twelfth O site, O(12) is bonded in a bent 150 degrees geometry to one V(3) and one B(3) atom. is represented by the CIF file [CIF]
data_VBO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.602
_cell_length_b   7.833
_cell_length_c   8.666
_cell_angle_alpha   107.521
_cell_angle_beta   96.185
_cell_angle_gamma   112.865
_symmetry_Int_Tables_number   1
_cell_volume   438.401
_cell_formula_units_Z   6
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.951  0.008  0.256  1.0
  V  V1  1  0.182  0.637  0.335  1.0
  V  V2  1  0.495  0.718  0.848  1.0
  V  V3  1  0.505  0.282  0.152  1.0
  V  V4  1  0.818  0.363  0.665  1.0
  V  V5  1  0.049  0.992  0.744  1.0
  B  B6  1  0.922  0.735  0.937  1.0
  B  B7  1  0.184  0.365  0.547  1.0
  B  B8  1  0.513  0.905  0.219  1.0
  B  B9  1  0.487  0.095  0.781  1.0
  B  B10  1  0.816  0.635  0.453  1.0
  B  B11  1  0.078  0.265  0.063  1.0
  O  O12  1  0.066  0.860  0.867  1.0
  O  O13  1  1.000  0.705  0.396  1.0
  O  O14  1  0.088  0.464  0.132  1.0
  O  O15  1  0.990  0.816  0.119  1.0
  O  O16  1  0.283  0.061  0.709  1.0
  O  O17  1  0.348  0.473  0.698  1.0
  O  O18  1  0.482  0.900  0.778  1.0
  O  O19  1  0.167  0.177  0.423  1.0
  O  O20  1  0.204  0.507  0.460  1.0
  O  O21  1  0.389  0.833  0.325  1.0
  O  O22  1  0.271  0.268  0.116  1.0
  O  O23  1  0.438  0.760  0.042  1.0
  O  O24  1  0.562  0.240  0.958  1.0
  O  O25  1  0.729  0.732  0.884  1.0
  O  O26  1  0.611  0.167  0.675  1.0
  O  O27  1  0.796  0.493  0.540  1.0
  O  O28  1  0.833  0.823  0.577  1.0
  O  O29  1  0.518  0.100  0.222  1.0
  O  O30  1  0.652  0.527  0.302  1.0
  O  O31  1  0.717  0.939  0.291  1.0
  O  O32  1  0.010  0.184  0.881  1.0
  O  O33  1  0.912  0.536  0.868  1.0
  O  O34  1  0.000  0.295  0.604  1.0
  O  O35  1  0.934  0.140  0.133  1.0
[/CIF]
.