The compound described by (MnO4)2NiO6 is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of four mangan(iv)-hydroxyd molecules and two NiO6 clusters. In each NiO6 cluster, Ni(1) is bonded in an octahedral geometry to one O(7), one O(9), two equivalent O(10), and two equivalent O(8) atoms. There are four inequivalent O sites. In the first O site, O(7) is bonded in a single-bond geometry to one Ni(1) atom. In the second O site, O(8) is bonded in a single-bond geometry to one Ni(1) atom. In the third O site, O(9) is bonded in a single-bond geometry to one Ni(1) atom. In the fourth O site, O(10) is bonded in a single-bond geometry to one Ni(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mn2NiO14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.209
_cell_length_b   7.688
_cell_length_c   7.860
_cell_angle_alpha   120.745
_cell_angle_beta   90.000
_cell_angle_gamma   88.932
_symmetry_Int_Tables_number   1
_cell_volume   270.442
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.497  0.666  0.333  1.0
  Mn  Mn1  1  0.005  0.332  0.666  1.0
  Ni  Ni2  1  0.737  0.000  0.000  1.0
  O  O3  1  0.185  0.668  0.334  1.0
  O  O4  1  0.589  0.901  0.451  1.0
  O  O5  1  0.602  0.552  0.444  1.0
  O  O6  1  0.602  0.552  0.109  1.0
  O  O7  1  0.692  0.334  0.667  1.0
  O  O8  1  0.110  0.100  0.550  1.0
  O  O9  1  0.103  0.449  0.557  1.0
  O  O10  1  0.103  0.449  0.892  1.0
  O  O11  1  0.996  0.186  0.093  1.0
  O  O12  1  0.971  0.927  0.125  1.0
  O  O13  1  0.971  0.927  0.802  1.0
  O  O14  1  0.483  0.810  0.905  1.0
  O  O15  1  0.507  0.072  0.874  1.0
  O  O16  1  0.507  0.072  0.198  1.0
[/CIF]
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The compound described by (MnO4)2NiO6 is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of four mangan(iv)-hydroxyd molecules and two NiO6 clusters. In each NiO6 cluster, Ni(1) is bonded in an octahedral geometry to one O(7), one O(9), two equivalent O(10), and two equivalent O(8) atoms. There are four inequivalent O sites. In the first O site, O(7) is bonded in a single-bond geometry to one Ni(1) atom. In the second O site, O(8) is bonded in a single-bond geometry to one Ni(1) atom. In the third O site, O(9) is bonded in a single-bond geometry to one Ni(1) atom. In the fourth O site, O(10) is bonded in a single-bond geometry to one Ni(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mn2NiO14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.209
_cell_length_b   7.688
_cell_length_c   7.860
_cell_angle_alpha   120.745
_cell_angle_beta   90.000
_cell_angle_gamma   88.932
_symmetry_Int_Tables_number   1
_cell_volume   270.442
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.497  0.666  0.333  1.0
  Mn  Mn1  1  0.005  0.332  0.666  1.0
  Ni  Ni2  1  0.737  0.000  0.000  1.0
  O  O3  1  0.185  0.668  0.334  1.0
  O  O4  1  0.589  0.901  0.451  1.0
  O  O5  1  0.602  0.552  0.444  1.0
  O  O6  1  0.602  0.552  0.109  1.0
  O  O7  1  0.692  0.334  0.667  1.0
  O  O8  1  0.110  0.100  0.550  1.0
  O  O9  1  0.103  0.449  0.557  1.0
  O  O10  1  0.103  0.449  0.892  1.0
  O  O11  1  0.996  0.186  0.093  1.0
  O  O12  1  0.971  0.927  0.125  1.0
  O  O13  1  0.971  0.927  0.802  1.0
  O  O14  1  0.483  0.810  0.905  1.0
  O  O15  1  0.507  0.072  0.874  1.0
  O  O16  1  0.507  0.072  0.198  1.0
[/CIF]
.