The structure described by Co6OF11 is Hydrophilite-derived structured and crystallizes in the orthorhombic Amm2 space group. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one F(1), one F(4), one F(5), and two equivalent F(2) atoms to form CoOF5 octahedra that share corners with four equivalent Co(4)F6 octahedra, corners with four equivalent Co(3)OF5 octahedra,  an edgeedge with one Co(2)F6 octahedra, and  an edgeedge with one Co(1)OF5 octahedra. The corner-sharing octahedral tilt angles range from 46-52°. In the second Co site, Co(2) is bonded to two equivalent F(1), two equivalent F(3), and two equivalent F(5) atoms to form CoF6 octahedra that share corners with eight equivalent Co(4)F6 octahedra and edges with two equivalent Co(1)OF5 octahedra. The corner-sharing octahedral tilt angles range from 50-52°. In the third Co site, Co(3) is bonded to one O(1), one F(4), and four equivalent F(2) atoms to form CoOF5 octahedra that share corners with eight equivalent Co(1)OF5 octahedra and edges with two equivalent Co(4)F6 octahedra. The corner-sharing octahedral tilt angles range from 46-51°. In the fourth Co site, Co(4) is bonded to one F(1), one F(5), two equivalent F(2), and two equivalent F(3) atoms to form CoF6 octahedra that share corners with four equivalent Co(2)F6 octahedra, corners with four equivalent Co(1)OF5 octahedra,  an edgeedge with one Co(4)F6 octahedra, and  an edgeedge with one Co(3)OF5 octahedra. The corner-sharing octahedral tilt angles range from 50-52°. O(1) is bonded in a distorted trigonal planar geometry to one Co(3) and two equivalent Co(1) atoms. There are five inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to one Co(1), one Co(2), and one Co(4) atom. In the second F site, F(2) is bonded in a trigonal planar geometry to one Co(1), one Co(3), and one Co(4) atom. In the third F site, F(3) is bonded in a trigonal planar geometry to one Co(2) and two equivalent Co(4) atoms. In the fourth F site, F(4) is bonded in a distorted T-shaped geometry to one Co(3) and two equivalent Co(1) atoms. In the fifth F site, F(5) is bonded in a trigonal planar geometry to one Co(1), one Co(2), and one Co(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Co6OF11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.727
_cell_length_b   4.727
_cell_length_c   9.590
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   91.311
_symmetry_Int_Tables_number   1
_cell_volume   214.265
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.006  0.006  0.660  1.0
  Co  Co1  1  0.006  0.006  0.340  1.0
  Co  Co2  1  0.003  0.003  0.000  1.0
  Co  Co3  1  0.469  0.469  0.500  1.0
  Co  Co4  1  0.504  0.504  0.832  1.0
  Co  Co5  1  0.504  0.504  0.168  1.0
  O  O6  1  0.201  0.201  0.500  1.0
  F  F7  1  0.199  0.199  0.832  1.0
  F  F8  1  0.199  0.199  0.168  1.0
  F  F9  1  0.694  0.305  0.336  1.0
  F  F10  1  0.694  0.305  0.664  1.0
  F  F11  1  0.700  0.308  0.000  1.0
  F  F12  1  0.308  0.700  0.000  1.0
  F  F13  1  0.305  0.694  0.664  1.0
  F  F14  1  0.305  0.694  0.336  1.0
  F  F15  1  0.784  0.784  0.500  1.0
  F  F16  1  0.809  0.809  0.830  1.0
  F  F17  1  0.809  0.809  0.170  1.0
[/CIF]
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The structure described by Co6OF11 is Hydrophilite-derived structured and crystallizes in the orthorhombic Amm2 space group. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one F(1), one F(4), one F(5), and two equivalent F(2) atoms to form CoOF5 octahedra that share corners with four equivalent Co(4)F6 octahedra, corners with four equivalent Co(3)OF5 octahedra,  an edgeedge with one Co(2)F6 octahedra, and  an edgeedge with one Co(1)OF5 octahedra. The corner-sharing octahedral tilt angles range from 46-52°. In the second Co site, Co(2) is bonded to two equivalent F(1), two equivalent F(3), and two equivalent F(5) atoms to form CoF6 octahedra that share corners with eight equivalent Co(4)F6 octahedra and edges with two equivalent Co(1)OF5 octahedra. The corner-sharing octahedral tilt angles range from 50-52°. In the third Co site, Co(3) is bonded to one O(1), one F(4), and four equivalent F(2) atoms to form CoOF5 octahedra that share corners with eight equivalent Co(1)OF5 octahedra and edges with two equivalent Co(4)F6 octahedra. The corner-sharing octahedral tilt angles range from 46-51°. In the fourth Co site, Co(4) is bonded to one F(1), one F(5), two equivalent F(2), and two equivalent F(3) atoms to form CoF6 octahedra that share corners with four equivalent Co(2)F6 octahedra, corners with four equivalent Co(1)OF5 octahedra,  an edgeedge with one Co(4)F6 octahedra, and  an edgeedge with one Co(3)OF5 octahedra. The corner-sharing octahedral tilt angles range from 50-52°. O(1) is bonded in a distorted trigonal planar geometry to one Co(3) and two equivalent Co(1) atoms. There are five inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to one Co(1), one Co(2), and one Co(4) atom. In the second F site, F(2) is bonded in a trigonal planar geometry to one Co(1), one Co(3), and one Co(4) atom. In the third F site, F(3) is bonded in a trigonal planar geometry to one Co(2) and two equivalent Co(4) atoms. In the fourth F site, F(4) is bonded in a distorted T-shaped geometry to one Co(3) and two equivalent Co(1) atoms. In the fifth F site, F(5) is bonded in a trigonal planar geometry to one Co(1), one Co(2), and one Co(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Co6OF11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.727
_cell_length_b   4.727
_cell_length_c   9.590
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   91.311
_symmetry_Int_Tables_number   1
_cell_volume   214.265
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.006  0.006  0.660  1.0
  Co  Co1  1  0.006  0.006  0.340  1.0
  Co  Co2  1  0.003  0.003  0.000  1.0
  Co  Co3  1  0.469  0.469  0.500  1.0
  Co  Co4  1  0.504  0.504  0.832  1.0
  Co  Co5  1  0.504  0.504  0.168  1.0
  O  O6  1  0.201  0.201  0.500  1.0
  F  F7  1  0.199  0.199  0.832  1.0
  F  F8  1  0.199  0.199  0.168  1.0
  F  F9  1  0.694  0.305  0.336  1.0
  F  F10  1  0.694  0.305  0.664  1.0
  F  F11  1  0.700  0.308  0.000  1.0
  F  F12  1  0.308  0.700  0.000  1.0
  F  F13  1  0.305  0.694  0.664  1.0
  F  F14  1  0.305  0.694  0.336  1.0
  F  F15  1  0.784  0.784  0.500  1.0
  F  F16  1  0.809  0.809  0.830  1.0
  F  F17  1  0.809  0.809  0.170  1.0
[/CIF]
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