The material described by V(CO3)2 crystallizes in the triclinic P1 space group. There are four inequivalent V sites. In the first V site, V(1) is bonded in an octahedral geometry to one O(1), one O(11), one O(15), one O(18), one O(22), and one O(4) atom. In the second V site, V(2) is bonded in an octahedral geometry to one O(13), one O(20), one O(24), one O(6), one O(7), and one O(9) atom. In the third V site, V(3) is bonded in an octahedral geometry to one O(12), one O(16), one O(17), one O(2), one O(21), and one O(3) atom. In the fourth V site, V(4) is bonded in an octahedral geometry to one O(10), one O(14), one O(19), one O(23), one O(5), and one O(8) atom. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one O(11), one O(17), and one O(8) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one O(12), one O(18), and one O(7) atom. In the third C site, C(3) is bonded in a trigonal planar geometry to one O(19), one O(4), and one O(9) atom. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one O(10), one O(20), and one O(3) atom. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one O(15), one O(21), and one O(6) atom. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one O(16), one O(22), and one O(5) atom. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one O(13), one O(2), and one O(23) atom. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one O(1), one O(14), and one O(24) atom. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one V(1) and one C(8) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one V(3) and one C(7) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one V(3) and one C(4) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one V(1) and one C(3) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one V(4) and one C(6) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one V(2) and one C(5) atom. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one V(2) and one C(2) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one V(4) and one C(1) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one V(2) and one C(3) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one V(4) and one C(4) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to one V(1) and one C(1) atom. In the twelfth O site, O(12) is bonded in a bent 150 degrees geometry to one V(3) and one C(2) atom. In the thirteenth O site, O(13) is bonded in a bent 150 degrees geometry to one V(2) and one C(7) atom. In the fourteenth O site, O(14) is bonded in a bent 150 degrees geometry to one V(4) and one C(8) atom. In the fifteenth O site, O(15) is bonded in a bent 150 degrees geometry to one V(1) and one C(5) atom. In the sixteenth O site, O(16) is bonded in a bent 150 degrees geometry to one V(3) and one C(6) atom. In the seventeenth O site, O(17) is bonded in a bent 150 degrees geometry to one V(3) and one C(1) atom. In the eighteenth O site, O(18) is bonded in a bent 150 degrees geometry to one V(1) and one C(2) atom. In the nineteenth O site, O(19) is bonded in a distorted bent 150 degrees geometry to one V(4) and one C(3) atom. In the twentieth O site, O(20) is bonded in a bent 150 degrees geometry to one V(2) and one C(4) atom. In the twenty-first O site, O(21) is bonded in a distorted bent 150 degrees geometry to one V(3) and one C(5) atom. In the twenty-second O site, O(22) is bonded in a bent 150 degrees geometry to one V(1) and one C(6) atom. In the twenty-third O site, O(23) is bonded in a bent 150 degrees geometry to one V(4) and one C(7) atom. In the twenty-fourth O site, O(24) is bonded in a bent 150 degrees geometry to one V(2) and one C(8) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_V(CO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.090
_cell_length_b   6.096
_cell_length_c   6.775
_cell_angle_alpha   102.783
_cell_angle_beta   103.060
_cell_angle_gamma   92.681
_symmetry_Int_Tables_number   1
_cell_volume   237.683
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  C  C0  1  0.897  0.692  0.805  1.0
  C  C1  1  0.689  0.899  0.305  1.0
  C  C2  1  0.311  0.101  0.695  1.0
  C  C3  1  0.103  0.308  0.195  1.0
  O  O4  1  0.917  0.269  0.047  1.0
  O  O5  1  0.722  0.085  0.452  1.0
  O  O6  1  0.277  0.915  0.548  1.0
  O  O7  1  0.083  0.731  0.953  1.0
  O  O8  1  0.856  0.808  0.247  1.0
  O  O9  1  0.799  0.852  0.741  1.0
  O  O10  1  0.203  0.147  0.258  1.0
  O  O11  1  0.144  0.193  0.752  1.0
  O  O12  1  0.812  0.488  0.714  1.0
  O  O13  1  0.489  0.807  0.211  1.0
  O  O14  1  0.511  0.192  0.789  1.0
  O  O15  1  0.188  0.512  0.286  1.0
  V  V16  1  0.822  0.179  0.749  1.0
  V  V17  1  0.178  0.821  0.251  1.0
[/CIF]
.
The material described by V(CO3)2 crystallizes in the triclinic P1 space group. There are four inequivalent V sites. In the first V site, V(1) is bonded in an octahedral geometry to one O(1), one O(11), one O(15), one O(18), one O(22), and one O(4) atom. In the second V site, V(2) is bonded in an octahedral geometry to one O(13), one O(20), one O(24), one O(6), one O(7), and one O(9) atom. In the third V site, V(3) is bonded in an octahedral geometry to one O(12), one O(16), one O(17), one O(2), one O(21), and one O(3) atom. In the fourth V site, V(4) is bonded in an octahedral geometry to one O(10), one O(14), one O(19), one O(23), one O(5), and one O(8) atom. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one O(11), one O(17), and one O(8) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one O(12), one O(18), and one O(7) atom. In the third C site, C(3) is bonded in a trigonal planar geometry to one O(19), one O(4), and one O(9) atom. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one O(10), one O(20), and one O(3) atom. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one O(15), one O(21), and one O(6) atom. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one O(16), one O(22), and one O(5) atom. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one O(13), one O(2), and one O(23) atom. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one O(1), one O(14), and one O(24) atom. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one V(1) and one C(8) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one V(3) and one C(7) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one V(3) and one C(4) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one V(1) and one C(3) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one V(4) and one C(6) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one V(2) and one C(5) atom. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one V(2) and one C(2) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one V(4) and one C(1) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one V(2) and one C(3) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one V(4) and one C(4) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to one V(1) and one C(1) atom. In the twelfth O site, O(12) is bonded in a bent 150 degrees geometry to one V(3) and one C(2) atom. In the thirteenth O site, O(13) is bonded in a bent 150 degrees geometry to one V(2) and one C(7) atom. In the fourteenth O site, O(14) is bonded in a bent 150 degrees geometry to one V(4) and one C(8) atom. In the fifteenth O site, O(15) is bonded in a bent 150 degrees geometry to one V(1) and one C(5) atom. In the sixteenth O site, O(16) is bonded in a bent 150 degrees geometry to one V(3) and one C(6) atom. In the seventeenth O site, O(17) is bonded in a bent 150 degrees geometry to one V(3) and one C(1) atom. In the eighteenth O site, O(18) is bonded in a bent 150 degrees geometry to one V(1) and one C(2) atom. In the nineteenth O site, O(19) is bonded in a distorted bent 150 degrees geometry to one V(4) and one C(3) atom. In the twentieth O site, O(20) is bonded in a bent 150 degrees geometry to one V(2) and one C(4) atom. In the twenty-first O site, O(21) is bonded in a distorted bent 150 degrees geometry to one V(3) and one C(5) atom. In the twenty-second O site, O(22) is bonded in a bent 150 degrees geometry to one V(1) and one C(6) atom. In the twenty-third O site, O(23) is bonded in a bent 150 degrees geometry to one V(4) and one C(7) atom. In the twenty-fourth O site, O(24) is bonded in a bent 150 degrees geometry to one V(2) and one C(8) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_V(CO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.090
_cell_length_b   6.096
_cell_length_c   6.775
_cell_angle_alpha   102.783
_cell_angle_beta   103.060
_cell_angle_gamma   92.681
_symmetry_Int_Tables_number   1
_cell_volume   237.683
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  C  C0  1  0.897  0.692  0.805  1.0
  C  C1  1  0.689  0.899  0.305  1.0
  C  C2  1  0.311  0.101  0.695  1.0
  C  C3  1  0.103  0.308  0.195  1.0
  O  O4  1  0.917  0.269  0.047  1.0
  O  O5  1  0.722  0.085  0.452  1.0
  O  O6  1  0.277  0.915  0.548  1.0
  O  O7  1  0.083  0.731  0.953  1.0
  O  O8  1  0.856  0.808  0.247  1.0
  O  O9  1  0.799  0.852  0.741  1.0
  O  O10  1  0.203  0.147  0.258  1.0
  O  O11  1  0.144  0.193  0.752  1.0
  O  O12  1  0.812  0.488  0.714  1.0
  O  O13  1  0.489  0.807  0.211  1.0
  O  O14  1  0.511  0.192  0.789  1.0
  O  O15  1  0.188  0.512  0.286  1.0
  V  V16  1  0.822  0.179  0.749  1.0
  V  V17  1  0.178  0.821  0.251  1.0
[/CIF]
.