The structure described by KMnP(OF)3 crystallizes in the monoclinic P2_1/c space group. K(1) is bonded in a 10-coordinate geometry to one O(2), one O(3), two equivalent O(1), one F(1), two equivalent F(2), and three equivalent F(3) atoms. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent F(1) atoms to form MnO4F2 octahedra that share corners with two equivalent Mn(2)O2F4 octahedra and corners with four equivalent P(1)O3F tetrahedra. The corner-sharing octahedral tilt angles are 47°. In the second Mn site, Mn(2) is bonded to two equivalent O(2), two equivalent F(1), and two equivalent F(2) atoms to form MnO2F4 octahedra that share corners with two equivalent Mn(1)O4F2 octahedra and corners with two equivalent P(1)O3F tetrahedra. The corner-sharing octahedral tilt angles are 47°. P(1) is bonded to one O(1), one O(2), one O(3), and one F(3) atom to form PO3F tetrahedra that share  a cornercorner with one Mn(2)O2F4 octahedra and corners with two equivalent Mn(1)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 40-53°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to two equivalent K(1), one Mn(1), and one P(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one K(1), one Mn(2), and one P(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one K(1), one Mn(1), and one P(1) atom. There are three inequivalent F sites. In the first F site, F(3) is bonded in a single-bond geometry to three equivalent K(1) and one P(1) atom. In the second F site, F(1) is bonded in a distorted trigonal planar geometry to one K(1), one Mn(1), and one Mn(2) atom. In the third F site, F(2) is bonded in a distorted single-bond geometry to two equivalent K(1) and one Mn(2) atom. is represented by the CIF card [CIF]
data_KMnP(OF)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.874
_cell_length_b   5.518
_cell_length_c   7.880
_cell_angle_alpha   65.762
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   510.420
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.201  0.647  0.811  1.0
  K  K1  1  0.299  0.647  0.311  1.0
  K  K2  1  0.799  0.353  0.189  1.0
  K  K3  1  0.701  0.353  0.689  1.0
  Mn  Mn4  1  0.000  0.500  0.500  1.0
  Mn  Mn5  1  0.500  0.500  0.000  1.0
  Mn  Mn6  1  0.000  0.000  0.000  1.0
  Mn  Mn7  1  0.500  0.000  0.500  1.0
  P  P8  1  0.107  0.126  0.315  1.0
  P  P9  1  0.393  0.126  0.815  1.0
  P  P10  1  0.893  0.874  0.685  1.0
  P  P11  1  0.607  0.874  0.185  1.0
  O  O12  1  0.115  0.833  0.443  1.0
  O  O13  1  0.385  0.833  0.943  1.0
  O  O14  1  0.885  0.167  0.557  1.0
  O  O15  1  0.615  0.167  0.057  1.0
  O  O16  1  0.028  0.196  0.156  1.0
  O  O17  1  0.472  0.196  0.656  1.0
  O  O18  1  0.972  0.804  0.844  1.0
  O  O19  1  0.528  0.804  0.344  1.0
  O  O20  1  0.102  0.313  0.414  1.0
  O  O21  1  0.398  0.313  0.914  1.0
  O  O22  1  0.898  0.687  0.586  1.0
  O  O23  1  0.602  0.687  0.086  1.0
  F  F24  1  0.055  0.335  0.743  1.0
  F  F25  1  0.445  0.335  0.243  1.0
  F  F26  1  0.945  0.665  0.257  1.0
  F  F27  1  0.555  0.665  0.757  1.0
  F  F28  1  0.135  0.866  0.038  1.0
  F  F29  1  0.365  0.866  0.538  1.0
  F  F30  1  0.865  0.134  0.962  1.0
  F  F31  1  0.635  0.134  0.462  1.0
  F  F32  1  0.217  0.206  0.212  1.0
  F  F33  1  0.283  0.206  0.712  1.0
  F  F34  1  0.783  0.794  0.788  1.0
  F  F35  1  0.717  0.794  0.288  1.0
[/CIF]
.
The structure described by KMnP(OF)3 crystallizes in the monoclinic P2_1/c space group. K(1) is bonded in a 10-coordinate geometry to one O(2), one O(3), two equivalent O(1), one F(1), two equivalent F(2), and three equivalent F(3) atoms. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent F(1) atoms to form MnO4F2 octahedra that share corners with two equivalent Mn(2)O2F4 octahedra and corners with four equivalent P(1)O3F tetrahedra. The corner-sharing octahedral tilt angles are 47°. In the second Mn site, Mn(2) is bonded to two equivalent O(2), two equivalent F(1), and two equivalent F(2) atoms to form MnO2F4 octahedra that share corners with two equivalent Mn(1)O4F2 octahedra and corners with two equivalent P(1)O3F tetrahedra. The corner-sharing octahedral tilt angles are 47°. P(1) is bonded to one O(1), one O(2), one O(3), and one F(3) atom to form PO3F tetrahedra that share  a cornercorner with one Mn(2)O2F4 octahedra and corners with two equivalent Mn(1)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 40-53°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to two equivalent K(1), one Mn(1), and one P(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one K(1), one Mn(2), and one P(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one K(1), one Mn(1), and one P(1) atom. There are three inequivalent F sites. In the first F site, F(3) is bonded in a single-bond geometry to three equivalent K(1) and one P(1) atom. In the second F site, F(1) is bonded in a distorted trigonal planar geometry to one K(1), one Mn(1), and one Mn(2) atom. In the third F site, F(2) is bonded in a distorted single-bond geometry to two equivalent K(1) and one Mn(2) atom. is represented by the CIF card [CIF]
data_KMnP(OF)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.874
_cell_length_b   5.518
_cell_length_c   7.880
_cell_angle_alpha   65.762
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   510.420
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.201  0.647  0.811  1.0
  K  K1  1  0.299  0.647  0.311  1.0
  K  K2  1  0.799  0.353  0.189  1.0
  K  K3  1  0.701  0.353  0.689  1.0
  Mn  Mn4  1  0.000  0.500  0.500  1.0
  Mn  Mn5  1  0.500  0.500  0.000  1.0
  Mn  Mn6  1  0.000  0.000  0.000  1.0
  Mn  Mn7  1  0.500  0.000  0.500  1.0
  P  P8  1  0.107  0.126  0.315  1.0
  P  P9  1  0.393  0.126  0.815  1.0
  P  P10  1  0.893  0.874  0.685  1.0
  P  P11  1  0.607  0.874  0.185  1.0
  O  O12  1  0.115  0.833  0.443  1.0
  O  O13  1  0.385  0.833  0.943  1.0
  O  O14  1  0.885  0.167  0.557  1.0
  O  O15  1  0.615  0.167  0.057  1.0
  O  O16  1  0.028  0.196  0.156  1.0
  O  O17  1  0.472  0.196  0.656  1.0
  O  O18  1  0.972  0.804  0.844  1.0
  O  O19  1  0.528  0.804  0.344  1.0
  O  O20  1  0.102  0.313  0.414  1.0
  O  O21  1  0.398  0.313  0.914  1.0
  O  O22  1  0.898  0.687  0.586  1.0
  O  O23  1  0.602  0.687  0.086  1.0
  F  F24  1  0.055  0.335  0.743  1.0
  F  F25  1  0.445  0.335  0.243  1.0
  F  F26  1  0.945  0.665  0.257  1.0
  F  F27  1  0.555  0.665  0.757  1.0
  F  F28  1  0.135  0.866  0.038  1.0
  F  F29  1  0.365  0.866  0.538  1.0
  F  F30  1  0.865  0.134  0.962  1.0
  F  F31  1  0.635  0.134  0.462  1.0
  F  F32  1  0.217  0.206  0.212  1.0
  F  F33  1  0.283  0.206  0.712  1.0
  F  F34  1  0.783  0.794  0.788  1.0
  F  F35  1  0.717  0.794  0.288  1.0
[/CIF]
.