The material structure described by OsSb2(OF7)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two OsSb2(OF7)2 clusters. Os(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one F(12), one F(13), one F(5), and one F(6) atom. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one F(1), one F(11), one F(3), one F(4), one F(6), and one F(9) atom to form corner-sharing SbF6 octahedra. The corner-sharing octahedral tilt angles are 9°. In the second Sb site, Sb(2) is bonded to one F(10), one F(14), one F(2), one F(7), one F(8), and one F(9) atom to form corner-sharing SbF6 octahedra. The corner-sharing octahedral tilt angles are 9°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Os(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Os(1) atom. There are fourteen inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Sb(2) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Os(1) atom. In the sixth F site, F(6) is bonded in a linear geometry to one Os(1) and one Sb(1) atom. In the seventh F site, F(7) is bonded in a single-bond geometry to one Sb(2) atom. In the eighth F site, F(8) is bonded in a single-bond geometry to one Sb(2) atom. In the ninth F site, F(9) is bonded in a linear geometry to one Sb(1) and one Sb(2) atom. In the tenth F site, F(10) is bonded in a single-bond geometry to one Sb(2) atom. In the eleventh F site, F(11) is bonded in a single-bond geometry to one Sb(1) atom. In the twelfth F site, F(12) is bonded in a single-bond geometry to one Os(1) atom. In the thirteenth F site, F(13) is bonded in a single-bond geometry to one Os(1) atom. In the fourteenth F site, F(14) is bonded in a single-bond geometry to one Sb(2) atom. is represented by the CIF card [CIF]
data_Sb2Os(OF7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.409
_cell_length_b   8.594
_cell_length_c   10.063
_cell_angle_alpha   96.986
_cell_angle_beta   111.415
_cell_angle_gamma   111.524
_symmetry_Int_Tables_number   1
_cell_volume   530.176
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.914  0.197  0.864  1.0
  Sb  Sb1  1  0.086  0.803  0.136  1.0
  Sb  Sb2  1  0.444  0.350  0.680  1.0
  Sb  Sb3  1  0.556  0.650  0.320  1.0
  Os  Os4  1  0.824  0.240  0.253  1.0
  Os  Os5  1  0.176  0.760  0.747  1.0
  O  O6  1  0.014  0.448  0.301  1.0
  O  O7  1  0.986  0.552  0.699  1.0
  O  O8  1  0.770  0.236  0.401  1.0
  O  O9  1  0.230  0.764  0.599  1.0
  F  F10  1  0.107  0.435  0.939  1.0
  F  F11  1  0.893  0.565  0.061  1.0
  F  F12  1  0.664  0.581  0.764  1.0
  F  F13  1  0.336  0.419  0.236  1.0
  F  F14  1  0.123  0.123  0.951  1.0
  F  F15  1  0.877  0.877  0.049  1.0
  F  F16  1  0.921  0.184  0.679  1.0
  F  F17  1  0.079  0.816  0.321  1.0
  F  F18  1  0.026  0.154  0.304  1.0
  F  F19  1  0.974  0.846  0.696  1.0
  F  F20  1  0.872  0.224  0.046  1.0
  F  F21  1  0.128  0.776  0.954  1.0
  F  F22  1  0.515  0.327  0.521  1.0
  F  F23  1  0.485  0.673  0.479  1.0
  F  F24  1  0.406  0.362  0.854  1.0
  F  F25  1  0.594  0.638  0.146  1.0
  F  F26  1  0.683  0.279  0.790  1.0
  F  F27  1  0.317  0.721  0.210  1.0
  F  F28  1  0.258  0.109  0.608  1.0
  F  F29  1  0.742  0.891  0.392  1.0
  F  F30  1  0.681  0.975  0.789  1.0
  F  F31  1  0.319  0.025  0.211  1.0
  F  F32  1  0.604  0.283  0.133  1.0
  F  F33  1  0.396  0.717  0.867  1.0
  F  F34  1  0.638  0.008  0.134  1.0
  F  F35  1  0.362  0.992  0.866  1.0
  F  F36  1  0.225  0.417  0.585  1.0
  F  F37  1  0.775  0.583  0.415  1.0
[/CIF]
.
The material structure described by OsSb2(OF7)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two OsSb2(OF7)2 clusters. Os(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one F(12), one F(13), one F(5), and one F(6) atom. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one F(1), one F(11), one F(3), one F(4), one F(6), and one F(9) atom to form corner-sharing SbF6 octahedra. The corner-sharing octahedral tilt angles are 9°. In the second Sb site, Sb(2) is bonded to one F(10), one F(14), one F(2), one F(7), one F(8), and one F(9) atom to form corner-sharing SbF6 octahedra. The corner-sharing octahedral tilt angles are 9°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Os(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Os(1) atom. There are fourteen inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Sb(2) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Os(1) atom. In the sixth F site, F(6) is bonded in a linear geometry to one Os(1) and one Sb(1) atom. In the seventh F site, F(7) is bonded in a single-bond geometry to one Sb(2) atom. In the eighth F site, F(8) is bonded in a single-bond geometry to one Sb(2) atom. In the ninth F site, F(9) is bonded in a linear geometry to one Sb(1) and one Sb(2) atom. In the tenth F site, F(10) is bonded in a single-bond geometry to one Sb(2) atom. In the eleventh F site, F(11) is bonded in a single-bond geometry to one Sb(1) atom. In the twelfth F site, F(12) is bonded in a single-bond geometry to one Os(1) atom. In the thirteenth F site, F(13) is bonded in a single-bond geometry to one Os(1) atom. In the fourteenth F site, F(14) is bonded in a single-bond geometry to one Sb(2) atom. is represented by the CIF card [CIF]
data_Sb2Os(OF7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.409
_cell_length_b   8.594
_cell_length_c   10.063
_cell_angle_alpha   96.986
_cell_angle_beta   111.415
_cell_angle_gamma   111.524
_symmetry_Int_Tables_number   1
_cell_volume   530.176
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.914  0.197  0.864  1.0
  Sb  Sb1  1  0.086  0.803  0.136  1.0
  Sb  Sb2  1  0.444  0.350  0.680  1.0
  Sb  Sb3  1  0.556  0.650  0.320  1.0
  Os  Os4  1  0.824  0.240  0.253  1.0
  Os  Os5  1  0.176  0.760  0.747  1.0
  O  O6  1  0.014  0.448  0.301  1.0
  O  O7  1  0.986  0.552  0.699  1.0
  O  O8  1  0.770  0.236  0.401  1.0
  O  O9  1  0.230  0.764  0.599  1.0
  F  F10  1  0.107  0.435  0.939  1.0
  F  F11  1  0.893  0.565  0.061  1.0
  F  F12  1  0.664  0.581  0.764  1.0
  F  F13  1  0.336  0.419  0.236  1.0
  F  F14  1  0.123  0.123  0.951  1.0
  F  F15  1  0.877  0.877  0.049  1.0
  F  F16  1  0.921  0.184  0.679  1.0
  F  F17  1  0.079  0.816  0.321  1.0
  F  F18  1  0.026  0.154  0.304  1.0
  F  F19  1  0.974  0.846  0.696  1.0
  F  F20  1  0.872  0.224  0.046  1.0
  F  F21  1  0.128  0.776  0.954  1.0
  F  F22  1  0.515  0.327  0.521  1.0
  F  F23  1  0.485  0.673  0.479  1.0
  F  F24  1  0.406  0.362  0.854  1.0
  F  F25  1  0.594  0.638  0.146  1.0
  F  F26  1  0.683  0.279  0.790  1.0
  F  F27  1  0.317  0.721  0.210  1.0
  F  F28  1  0.258  0.109  0.608  1.0
  F  F29  1  0.742  0.891  0.392  1.0
  F  F30  1  0.681  0.975  0.789  1.0
  F  F31  1  0.319  0.025  0.211  1.0
  F  F32  1  0.604  0.283  0.133  1.0
  F  F33  1  0.396  0.717  0.867  1.0
  F  F34  1  0.638  0.008  0.134  1.0
  F  F35  1  0.362  0.992  0.866  1.0
  F  F36  1  0.225  0.417  0.585  1.0
  F  F37  1  0.775  0.583  0.415  1.0
[/CIF]
.