The material structure described by Na2Mn(PO3)5 crystallizes in the monoclinic P2_1/m space group. Na(1) is bonded in a 6-coordinate geometry to one O(3), one O(5), one O(7), one O(8), and two equivalent O(4) atoms. Mn(1) is bonded to two equivalent O(3), two equivalent O(5), and two equivalent O(6) atoms to form MnO6 octahedra that share corners with two equivalent P(3)O4 tetrahedra and corners with four equivalent P(2)O4 tetrahedra. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(7), one O(8), and two equivalent O(2) atoms to form corner-sharing PO4 tetrahedra. In the second P site, P(2) is bonded to one O(1), one O(5), one O(6), and one O(9) atom to form PO4 tetrahedra that share corners with two equivalent Mn(1)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra, and  a cornercorner with one P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 48-53°. In the third P site, P(3) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 44°. There are nine inequivalent O sites. In the first O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Na(1) and one P(1) atom. In the second O site, O(9) is bonded in a bent 150 degrees geometry to two equivalent P(2) atoms. In the third O site, O(1) is bonded in a bent 150 degrees geometry to one P(2) and one P(3) atom. In the fourth O site, O(2) is bonded in a bent 120 degrees geometry to one P(1) and one P(3) atom. In the fifth O site, O(3) is bonded in a 2-coordinate geometry to one Na(1), one Mn(1), and one P(3) atom. In the sixth O site, O(4) is bonded in a distorted trigonal planar geometry to two equivalent Na(1) and one P(3) atom. In the seventh O site, O(5) is bonded in a distorted trigonal planar geometry to one Na(1), one Mn(1), and one P(2) atom. In the eighth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one P(2) atom. In the ninth O site, O(7) is bonded in a distorted trigonal planar geometry to two equivalent Na(1) and one P(1) atom. is represented by the CIF card [CIF]
data_Na2Mn(PO3)5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.743
_cell_length_b   5.298
_cell_length_c   8.916
_cell_angle_alpha   76.885
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   632.253
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.110  0.925  0.128  1.0
  Na  Na1  1  0.390  0.925  0.128  1.0
  Na  Na2  1  0.890  0.075  0.872  1.0
  Na  Na3  1  0.610  0.075  0.872  1.0
  Mn  Mn4  1  0.500  0.500  0.500  1.0
  Mn  Mn5  1  0.000  0.500  0.500  1.0
  P  P6  1  0.750  0.541  0.996  1.0
  P  P7  1  0.860  0.983  0.487  1.0
  P  P8  1  0.579  0.345  0.192  1.0
  P  P9  1  0.140  0.017  0.513  1.0
  P  P10  1  0.079  0.655  0.808  1.0
  P  P11  1  0.250  0.459  0.004  1.0
  P  P12  1  0.921  0.345  0.192  1.0
  P  P13  1  0.360  0.017  0.513  1.0
  P  P14  1  0.640  0.983  0.487  1.0
  P  P15  1  0.421  0.655  0.808  1.0
  O  O16  1  0.145  0.863  0.689  1.0
  O  O17  1  0.659  0.553  0.115  1.0
  O  O18  1  0.987  0.487  0.284  1.0
  O  O19  1  0.645  0.137  0.311  1.0
  O  O20  1  0.341  0.447  0.885  1.0
  O  O21  1  0.031  0.787  0.918  1.0
  O  O22  1  0.013  0.513  0.716  1.0
  O  O23  1  0.079  0.878  0.418  1.0
  O  O24  1  0.579  0.122  0.582  1.0
  O  O25  1  0.621  0.699  0.493  1.0
  O  O26  1  0.121  0.301  0.507  1.0
  O  O27  1  0.250  0.712  0.050  1.0
  O  O28  1  0.969  0.213  0.082  1.0
  O  O29  1  0.355  0.863  0.689  1.0
  O  O30  1  0.379  0.301  0.507  1.0
  O  O31  1  0.879  0.699  0.493  1.0
  O  O32  1  0.250  0.206  0.118  1.0
  O  O33  1  0.159  0.447  0.885  1.0
  O  O34  1  0.421  0.878  0.418  1.0
  O  O35  1  0.469  0.787  0.918  1.0
  O  O36  1  0.531  0.213  0.082  1.0
  O  O37  1  0.750  0.794  0.882  1.0
  O  O38  1  0.487  0.513  0.716  1.0
  O  O39  1  0.250  0.997  0.459  1.0
  O  O40  1  0.921  0.122  0.582  1.0
  O  O41  1  0.855  0.137  0.311  1.0
  O  O42  1  0.513  0.487  0.284  1.0
  O  O43  1  0.841  0.553  0.115  1.0
  O  O44  1  0.750  0.288  0.950  1.0
  O  O45  1  0.750  0.003  0.541  1.0
[/CIF]
.
The material structure described by Na2Mn(PO3)5 crystallizes in the monoclinic P2_1/m space group. Na(1) is bonded in a 6-coordinate geometry to one O(3), one O(5), one O(7), one O(8), and two equivalent O(4) atoms. Mn(1) is bonded to two equivalent O(3), two equivalent O(5), and two equivalent O(6) atoms to form MnO6 octahedra that share corners with two equivalent P(3)O4 tetrahedra and corners with four equivalent P(2)O4 tetrahedra. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(7), one O(8), and two equivalent O(2) atoms to form corner-sharing PO4 tetrahedra. In the second P site, P(2) is bonded to one O(1), one O(5), one O(6), and one O(9) atom to form PO4 tetrahedra that share corners with two equivalent Mn(1)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra, and  a cornercorner with one P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 48-53°. In the third P site, P(3) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 44°. There are nine inequivalent O sites. In the first O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Na(1) and one P(1) atom. In the second O site, O(9) is bonded in a bent 150 degrees geometry to two equivalent P(2) atoms. In the third O site, O(1) is bonded in a bent 150 degrees geometry to one P(2) and one P(3) atom. In the fourth O site, O(2) is bonded in a bent 120 degrees geometry to one P(1) and one P(3) atom. In the fifth O site, O(3) is bonded in a 2-coordinate geometry to one Na(1), one Mn(1), and one P(3) atom. In the sixth O site, O(4) is bonded in a distorted trigonal planar geometry to two equivalent Na(1) and one P(3) atom. In the seventh O site, O(5) is bonded in a distorted trigonal planar geometry to one Na(1), one Mn(1), and one P(2) atom. In the eighth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one P(2) atom. In the ninth O site, O(7) is bonded in a distorted trigonal planar geometry to two equivalent Na(1) and one P(1) atom. is represented by the CIF card [CIF]
data_Na2Mn(PO3)5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.743
_cell_length_b   5.298
_cell_length_c   8.916
_cell_angle_alpha   76.885
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   632.253
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.110  0.925  0.128  1.0
  Na  Na1  1  0.390  0.925  0.128  1.0
  Na  Na2  1  0.890  0.075  0.872  1.0
  Na  Na3  1  0.610  0.075  0.872  1.0
  Mn  Mn4  1  0.500  0.500  0.500  1.0
  Mn  Mn5  1  0.000  0.500  0.500  1.0
  P  P6  1  0.750  0.541  0.996  1.0
  P  P7  1  0.860  0.983  0.487  1.0
  P  P8  1  0.579  0.345  0.192  1.0
  P  P9  1  0.140  0.017  0.513  1.0
  P  P10  1  0.079  0.655  0.808  1.0
  P  P11  1  0.250  0.459  0.004  1.0
  P  P12  1  0.921  0.345  0.192  1.0
  P  P13  1  0.360  0.017  0.513  1.0
  P  P14  1  0.640  0.983  0.487  1.0
  P  P15  1  0.421  0.655  0.808  1.0
  O  O16  1  0.145  0.863  0.689  1.0
  O  O17  1  0.659  0.553  0.115  1.0
  O  O18  1  0.987  0.487  0.284  1.0
  O  O19  1  0.645  0.137  0.311  1.0
  O  O20  1  0.341  0.447  0.885  1.0
  O  O21  1  0.031  0.787  0.918  1.0
  O  O22  1  0.013  0.513  0.716  1.0
  O  O23  1  0.079  0.878  0.418  1.0
  O  O24  1  0.579  0.122  0.582  1.0
  O  O25  1  0.621  0.699  0.493  1.0
  O  O26  1  0.121  0.301  0.507  1.0
  O  O27  1  0.250  0.712  0.050  1.0
  O  O28  1  0.969  0.213  0.082  1.0
  O  O29  1  0.355  0.863  0.689  1.0
  O  O30  1  0.379  0.301  0.507  1.0
  O  O31  1  0.879  0.699  0.493  1.0
  O  O32  1  0.250  0.206  0.118  1.0
  O  O33  1  0.159  0.447  0.885  1.0
  O  O34  1  0.421  0.878  0.418  1.0
  O  O35  1  0.469  0.787  0.918  1.0
  O  O36  1  0.531  0.213  0.082  1.0
  O  O37  1  0.750  0.794  0.882  1.0
  O  O38  1  0.487  0.513  0.716  1.0
  O  O39  1  0.250  0.997  0.459  1.0
  O  O40  1  0.921  0.122  0.582  1.0
  O  O41  1  0.855  0.137  0.311  1.0
  O  O42  1  0.513  0.487  0.284  1.0
  O  O43  1  0.841  0.553  0.115  1.0
  O  O44  1  0.750  0.288  0.950  1.0
  O  O45  1  0.750  0.003  0.541  1.0
[/CIF]
.