The structure described by LiZnAsH2O5 crystallizes in the orthorhombic Pna2_1 space group. Li(1) is bonded to one O(1), one O(3), one O(4), and one O(5) atom to form LiO4 tetrahedra that share corners with three equivalent Zn(1)O4 tetrahedra and corners with three equivalent As(1)O4 tetrahedra. Zn(1) is bonded to one O(2), one O(3), one O(4), and one O(5) atom to form ZnO4 tetrahedra that share corners with three equivalent Li(1)O4 tetrahedra and corners with four equivalent As(1)O4 tetrahedra. As(1) is bonded to one O(2), one O(3), one O(4), and one O(5) atom to form AsO4 tetrahedra that share corners with three equivalent Li(1)O4 tetrahedra and corners with four equivalent Zn(1)O4 tetrahedra. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one As(1) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Li(1), one Zn(1), and one As(1) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Li(1), one Zn(1), and one As(1) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one Li(1), one Zn(1), and one As(1) atom. is represented by the CIF file [CIF]
data_LiZnAsH2O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.216
_cell_length_b   8.466
_cell_length_c   11.086
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   489.504
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.264  0.675  0.180  1.0
  Li  Li1  1  0.764  0.175  0.320  1.0
  Li  Li2  1  0.264  0.825  0.680  1.0
  Li  Li3  1  0.764  0.325  0.820  1.0
  Zn  Zn4  1  0.763  0.869  0.124  1.0
  Zn  Zn5  1  0.263  0.369  0.376  1.0
  Zn  Zn6  1  0.763  0.631  0.624  1.0
  Zn  Zn7  1  0.263  0.131  0.876  1.0
  As  As8  1  0.258  0.079  0.171  1.0
  As  As9  1  0.758  0.579  0.329  1.0
  As  As10  1  0.258  0.421  0.671  1.0
  As  As11  1  0.758  0.921  0.829  1.0
  H  H12  1  0.593  0.451  0.016  1.0
  H  H13  1  0.822  0.331  0.041  1.0
  H  H14  1  0.322  0.831  0.459  1.0
  H  H15  1  0.093  0.951  0.484  1.0
  H  H16  1  0.593  0.049  0.516  1.0
  H  H17  1  0.822  0.169  0.541  1.0
  H  H18  1  0.322  0.669  0.959  1.0
  H  H19  1  0.093  0.549  0.984  1.0
  O  O20  1  0.256  0.588  0.015  1.0
  O  O21  1  0.171  0.181  0.043  1.0
  O  O22  1  0.127  0.891  0.168  1.0
  O  O23  1  0.585  0.060  0.190  1.0
  O  O24  1  0.632  0.678  0.207  1.0
  O  O25  1  0.132  0.178  0.293  1.0
  O  O26  1  0.085  0.560  0.310  1.0
  O  O27  1  0.627  0.391  0.332  1.0
  O  O28  1  0.671  0.681  0.457  1.0
  O  O29  1  0.756  0.088  0.485  1.0
  O  O30  1  0.256  0.912  0.515  1.0
  O  O31  1  0.171  0.319  0.543  1.0
  O  O32  1  0.127  0.609  0.668  1.0
  O  O33  1  0.585  0.440  0.690  1.0
  O  O34  1  0.632  0.822  0.707  1.0
  O  O35  1  0.132  0.322  0.793  1.0
  O  O36  1  0.085  0.940  0.810  1.0
  O  O37  1  0.627  0.109  0.832  1.0
  O  O38  1  0.671  0.819  0.957  1.0
  O  O39  1  0.756  0.412  0.985  1.0
[/CIF]
.
The structure described by LiZnAsH2O5 crystallizes in the orthorhombic Pna2_1 space group. Li(1) is bonded to one O(1), one O(3), one O(4), and one O(5) atom to form LiO4 tetrahedra that share corners with three equivalent Zn(1)O4 tetrahedra and corners with three equivalent As(1)O4 tetrahedra. Zn(1) is bonded to one O(2), one O(3), one O(4), and one O(5) atom to form ZnO4 tetrahedra that share corners with three equivalent Li(1)O4 tetrahedra and corners with four equivalent As(1)O4 tetrahedra. As(1) is bonded to one O(2), one O(3), one O(4), and one O(5) atom to form AsO4 tetrahedra that share corners with three equivalent Li(1)O4 tetrahedra and corners with four equivalent Zn(1)O4 tetrahedra. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one As(1) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Li(1), one Zn(1), and one As(1) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Li(1), one Zn(1), and one As(1) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one Li(1), one Zn(1), and one As(1) atom. is represented by the CIF file [CIF]
data_LiZnAsH2O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.216
_cell_length_b   8.466
_cell_length_c   11.086
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   489.504
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.264  0.675  0.180  1.0
  Li  Li1  1  0.764  0.175  0.320  1.0
  Li  Li2  1  0.264  0.825  0.680  1.0
  Li  Li3  1  0.764  0.325  0.820  1.0
  Zn  Zn4  1  0.763  0.869  0.124  1.0
  Zn  Zn5  1  0.263  0.369  0.376  1.0
  Zn  Zn6  1  0.763  0.631  0.624  1.0
  Zn  Zn7  1  0.263  0.131  0.876  1.0
  As  As8  1  0.258  0.079  0.171  1.0
  As  As9  1  0.758  0.579  0.329  1.0
  As  As10  1  0.258  0.421  0.671  1.0
  As  As11  1  0.758  0.921  0.829  1.0
  H  H12  1  0.593  0.451  0.016  1.0
  H  H13  1  0.822  0.331  0.041  1.0
  H  H14  1  0.322  0.831  0.459  1.0
  H  H15  1  0.093  0.951  0.484  1.0
  H  H16  1  0.593  0.049  0.516  1.0
  H  H17  1  0.822  0.169  0.541  1.0
  H  H18  1  0.322  0.669  0.959  1.0
  H  H19  1  0.093  0.549  0.984  1.0
  O  O20  1  0.256  0.588  0.015  1.0
  O  O21  1  0.171  0.181  0.043  1.0
  O  O22  1  0.127  0.891  0.168  1.0
  O  O23  1  0.585  0.060  0.190  1.0
  O  O24  1  0.632  0.678  0.207  1.0
  O  O25  1  0.132  0.178  0.293  1.0
  O  O26  1  0.085  0.560  0.310  1.0
  O  O27  1  0.627  0.391  0.332  1.0
  O  O28  1  0.671  0.681  0.457  1.0
  O  O29  1  0.756  0.088  0.485  1.0
  O  O30  1  0.256  0.912  0.515  1.0
  O  O31  1  0.171  0.319  0.543  1.0
  O  O32  1  0.127  0.609  0.668  1.0
  O  O33  1  0.585  0.440  0.690  1.0
  O  O34  1  0.632  0.822  0.707  1.0
  O  O35  1  0.132  0.322  0.793  1.0
  O  O36  1  0.085  0.940  0.810  1.0
  O  O37  1  0.627  0.109  0.832  1.0
  O  O38  1  0.671  0.819  0.957  1.0
  O  O39  1  0.756  0.412  0.985  1.0
[/CIF]
.