The structure described by Be(NO3)4(NO)2 is Indium-derived structured and crystallizes in the orthorhombic Fdd2 space group. The structure is zero-dimensional and consists of sixteen nitroxyl molecules and eight Be(NO3)4 clusters. In each Be(NO3)4 cluster, Be(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(4) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(4), one O(5), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one N(1) atom. In the second O site, O(4) is bonded in a bent 120 degrees geometry to one Be(1) and one N(2) atom. In the third O site, O(5) is bonded in a single-bond geometry to one N(2) atom. In the fourth O site, O(6) is bonded in a single-bond geometry to one N(2) atom. In the fifth O site, O(1) is bonded in a bent 120 degrees geometry to one Be(1) and one N(1) atom. In the sixth O site, O(2) is bonded in a single-bond geometry to one N(1) atom. is represented by the CIF file [CIF]
data_Be(N3O7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   14.261
_cell_length_b   12.884
_cell_length_c   7.588
_cell_angle_alpha   84.067
_cell_angle_beta   63.979
_cell_angle_gamma   31.954
_symmetry_Int_Tables_number   1
_cell_volume   546.957
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Be  Be0  1  0.098  0.902  0.902  1.0
  Be  Be1  1  0.348  0.152  0.152  1.0
  N  N2  1  0.659  0.228  0.150  1.0
  N  N3  1  0.963  0.150  0.228  1.0
  N  N4  1  0.100  0.287  0.591  1.0
  N  N5  1  0.022  0.591  0.287  1.0
  N  N6  1  0.322  0.789  0.480  1.0
  N  N7  1  0.409  0.480  0.789  1.0
  N  N8  1  0.770  0.841  0.928  1.0
  N  N9  1  0.461  0.928  0.841  1.0
  N  N10  1  0.613  0.026  0.435  1.0
  N  N11  1  0.926  0.435  0.026  1.0
  N  N12  1  0.815  0.324  0.637  1.0
  N  N13  1  0.224  0.637  0.324  1.0
  O  O14  1  0.872  0.018  0.064  1.0
  O  O15  1  0.045  0.064  0.018  1.0
  O  O16  1  0.186  0.205  0.378  1.0
  O  O17  1  0.232  0.378  0.205  1.0
  O  O18  1  0.589  0.381  0.148  1.0
  O  O19  1  0.881  0.148  0.381  1.0
  O  O20  1  0.102  0.369  0.661  1.0
  O  O21  1  0.869  0.661  0.369  1.0
  O  O22  1  0.522  0.273  0.240  1.0
  O  O23  1  0.965  0.240  0.273  1.0
  O  O24  1  0.010  0.285  0.728  1.0
  O  O25  1  0.977  0.728  0.285  1.0
  O  O26  1  0.135  0.900  0.666  1.0
  O  O27  1  0.299  0.666  0.900  1.0
  O  O28  1  0.584  0.951  0.115  1.0
  O  O29  1  0.350  0.115  0.951  1.0
  O  O30  1  0.473  0.678  0.488  1.0
  O  O31  1  0.361  0.488  0.678  1.0
  O  O32  1  0.762  0.889  0.777  1.0
  O  O33  1  0.572  0.777  0.889  1.0
  O  O34  1  0.331  0.806  0.313  1.0
  O  O35  1  0.550  0.313  0.806  1.0
  O  O36  1  0.937  0.700  0.919  1.0
  O  O37  1  0.444  0.919  0.700  1.0
  O  O38  1  0.475  0.169  0.624  1.0
  O  O39  1  0.731  0.624  0.169  1.0
  O  O40  1  0.626  0.519  0.775  1.0
  O  O41  1  0.081  0.775  0.519  1.0
[/CIF]
.
The structure described by Be(NO3)4(NO)2 is Indium-derived structured and crystallizes in the orthorhombic Fdd2 space group. The structure is zero-dimensional and consists of sixteen nitroxyl molecules and eight Be(NO3)4 clusters. In each Be(NO3)4 cluster, Be(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(4) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(4), one O(5), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one N(1) atom. In the second O site, O(4) is bonded in a bent 120 degrees geometry to one Be(1) and one N(2) atom. In the third O site, O(5) is bonded in a single-bond geometry to one N(2) atom. In the fourth O site, O(6) is bonded in a single-bond geometry to one N(2) atom. In the fifth O site, O(1) is bonded in a bent 120 degrees geometry to one Be(1) and one N(1) atom. In the sixth O site, O(2) is bonded in a single-bond geometry to one N(1) atom. is represented by the CIF file [CIF]
data_Be(N3O7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   14.261
_cell_length_b   12.884
_cell_length_c   7.588
_cell_angle_alpha   84.067
_cell_angle_beta   63.979
_cell_angle_gamma   31.954
_symmetry_Int_Tables_number   1
_cell_volume   546.957
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Be  Be0  1  0.098  0.902  0.902  1.0
  Be  Be1  1  0.348  0.152  0.152  1.0
  N  N2  1  0.659  0.228  0.150  1.0
  N  N3  1  0.963  0.150  0.228  1.0
  N  N4  1  0.100  0.287  0.591  1.0
  N  N5  1  0.022  0.591  0.287  1.0
  N  N6  1  0.322  0.789  0.480  1.0
  N  N7  1  0.409  0.480  0.789  1.0
  N  N8  1  0.770  0.841  0.928  1.0
  N  N9  1  0.461  0.928  0.841  1.0
  N  N10  1  0.613  0.026  0.435  1.0
  N  N11  1  0.926  0.435  0.026  1.0
  N  N12  1  0.815  0.324  0.637  1.0
  N  N13  1  0.224  0.637  0.324  1.0
  O  O14  1  0.872  0.018  0.064  1.0
  O  O15  1  0.045  0.064  0.018  1.0
  O  O16  1  0.186  0.205  0.378  1.0
  O  O17  1  0.232  0.378  0.205  1.0
  O  O18  1  0.589  0.381  0.148  1.0
  O  O19  1  0.881  0.148  0.381  1.0
  O  O20  1  0.102  0.369  0.661  1.0
  O  O21  1  0.869  0.661  0.369  1.0
  O  O22  1  0.522  0.273  0.240  1.0
  O  O23  1  0.965  0.240  0.273  1.0
  O  O24  1  0.010  0.285  0.728  1.0
  O  O25  1  0.977  0.728  0.285  1.0
  O  O26  1  0.135  0.900  0.666  1.0
  O  O27  1  0.299  0.666  0.900  1.0
  O  O28  1  0.584  0.951  0.115  1.0
  O  O29  1  0.350  0.115  0.951  1.0
  O  O30  1  0.473  0.678  0.488  1.0
  O  O31  1  0.361  0.488  0.678  1.0
  O  O32  1  0.762  0.889  0.777  1.0
  O  O33  1  0.572  0.777  0.889  1.0
  O  O34  1  0.331  0.806  0.313  1.0
  O  O35  1  0.550  0.313  0.806  1.0
  O  O36  1  0.937  0.700  0.919  1.0
  O  O37  1  0.444  0.919  0.700  1.0
  O  O38  1  0.475  0.169  0.624  1.0
  O  O39  1  0.731  0.624  0.169  1.0
  O  O40  1  0.626  0.519  0.775  1.0
  O  O41  1  0.081  0.775  0.519  1.0
[/CIF]
.