The crystal structure described by (CN2S)2C2Te(N2Cl)2(SO)2 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four n-cyanosulfimide molecules, four sulfur monoxide molecules, and two C2Te(N2Cl)2 clusters. In each C2Te(N2Cl)2 cluster, C(1) is bonded in a distorted bent 150 degrees geometry to one N(1) and one N(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one C(1) and one Te(1) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(1) and one Cl(1) atom. Te(1) is bonded in a 2-coordinate geometry to two equivalent N(1) atoms. Cl(1) is bonded in a single-bond geometry to one N(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_TeC4S4N8(ClO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.903
_cell_length_b   6.821
_cell_length_c   9.765
_cell_angle_alpha   78.713
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   908.107
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.500  0.000  0.500  1.0
  Te  Te1  1  0.000  0.000  0.000  1.0
  C  C2  1  0.699  0.930  0.580  1.0
  C  C3  1  0.199  0.070  0.920  1.0
  C  C4  1  0.301  0.070  0.420  1.0
  C  C5  1  0.801  0.930  0.080  1.0
  C  C6  1  0.541  0.821  0.843  1.0
  C  C7  1  0.041  0.179  0.657  1.0
  C  C8  1  0.459  0.179  0.157  1.0
  C  C9  1  0.959  0.821  0.343  1.0
  S  S10  1  0.691  0.211  0.515  1.0
  S  S11  1  0.191  0.789  0.985  1.0
  S  S12  1  0.309  0.789  0.485  1.0
  S  S13  1  0.809  0.211  0.015  1.0
  S  S14  1  0.551  0.185  0.700  1.0
  S  S15  1  0.051  0.815  0.800  1.0
  S  S16  1  0.449  0.815  0.300  1.0
  S  S17  1  0.949  0.185  0.200  1.0
  N  N18  1  0.627  0.839  0.531  1.0
  N  N19  1  0.127  0.161  0.969  1.0
  N  N20  1  0.373  0.161  0.469  1.0
  N  N21  1  0.873  0.839  0.031  1.0
  N  N22  1  0.779  0.890  0.650  1.0
  N  N23  1  0.279  0.110  0.850  1.0
  N  N24  1  0.221  0.110  0.350  1.0
  N  N25  1  0.721  0.890  0.150  1.0
  N  N26  1  0.552  0.013  0.834  1.0
  N  N27  1  0.052  0.987  0.666  1.0
  N  N28  1  0.448  0.987  0.166  1.0
  N  N29  1  0.948  0.013  0.334  1.0
  N  N30  1  0.530  0.647  0.856  1.0
  N  N31  1  0.030  0.353  0.644  1.0
  N  N32  1  0.470  0.353  0.144  1.0
  N  N33  1  0.970  0.647  0.356  1.0
  Cl  Cl34  1  0.796  0.652  0.736  1.0
  Cl  Cl35  1  0.296  0.348  0.764  1.0
  Cl  Cl36  1  0.204  0.348  0.264  1.0
  Cl  Cl37  1  0.704  0.652  0.236  1.0
  O  O38  1  0.724  0.319  0.055  1.0
  O  O39  1  0.224  0.681  0.445  1.0
  O  O40  1  0.276  0.681  0.945  1.0
  O  O41  1  0.776  0.319  0.555  1.0
[/CIF]
.
The crystal structure described by (CN2S)2C2Te(N2Cl)2(SO)2 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four n-cyanosulfimide molecules, four sulfur monoxide molecules, and two C2Te(N2Cl)2 clusters. In each C2Te(N2Cl)2 cluster, C(1) is bonded in a distorted bent 150 degrees geometry to one N(1) and one N(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one C(1) and one Te(1) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(1) and one Cl(1) atom. Te(1) is bonded in a 2-coordinate geometry to two equivalent N(1) atoms. Cl(1) is bonded in a single-bond geometry to one N(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_TeC4S4N8(ClO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.903
_cell_length_b   6.821
_cell_length_c   9.765
_cell_angle_alpha   78.713
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   908.107
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.500  0.000  0.500  1.0
  Te  Te1  1  0.000  0.000  0.000  1.0
  C  C2  1  0.699  0.930  0.580  1.0
  C  C3  1  0.199  0.070  0.920  1.0
  C  C4  1  0.301  0.070  0.420  1.0
  C  C5  1  0.801  0.930  0.080  1.0
  C  C6  1  0.541  0.821  0.843  1.0
  C  C7  1  0.041  0.179  0.657  1.0
  C  C8  1  0.459  0.179  0.157  1.0
  C  C9  1  0.959  0.821  0.343  1.0
  S  S10  1  0.691  0.211  0.515  1.0
  S  S11  1  0.191  0.789  0.985  1.0
  S  S12  1  0.309  0.789  0.485  1.0
  S  S13  1  0.809  0.211  0.015  1.0
  S  S14  1  0.551  0.185  0.700  1.0
  S  S15  1  0.051  0.815  0.800  1.0
  S  S16  1  0.449  0.815  0.300  1.0
  S  S17  1  0.949  0.185  0.200  1.0
  N  N18  1  0.627  0.839  0.531  1.0
  N  N19  1  0.127  0.161  0.969  1.0
  N  N20  1  0.373  0.161  0.469  1.0
  N  N21  1  0.873  0.839  0.031  1.0
  N  N22  1  0.779  0.890  0.650  1.0
  N  N23  1  0.279  0.110  0.850  1.0
  N  N24  1  0.221  0.110  0.350  1.0
  N  N25  1  0.721  0.890  0.150  1.0
  N  N26  1  0.552  0.013  0.834  1.0
  N  N27  1  0.052  0.987  0.666  1.0
  N  N28  1  0.448  0.987  0.166  1.0
  N  N29  1  0.948  0.013  0.334  1.0
  N  N30  1  0.530  0.647  0.856  1.0
  N  N31  1  0.030  0.353  0.644  1.0
  N  N32  1  0.470  0.353  0.144  1.0
  N  N33  1  0.970  0.647  0.356  1.0
  Cl  Cl34  1  0.796  0.652  0.736  1.0
  Cl  Cl35  1  0.296  0.348  0.764  1.0
  Cl  Cl36  1  0.204  0.348  0.264  1.0
  Cl  Cl37  1  0.704  0.652  0.236  1.0
  O  O38  1  0.724  0.319  0.055  1.0
  O  O39  1  0.224  0.681  0.445  1.0
  O  O40  1  0.276  0.681  0.945  1.0
  O  O41  1  0.776  0.319  0.555  1.0
[/CIF]
.