The crystal structure described by Ba2MnFe2CdF14 crystallizes in the monoclinic C2/c space group. Ba(1) is bonded in a 12-coordinate geometry to one F(3), one F(6), one F(7), two equivalent F(1), two equivalent F(2), two equivalent F(5), and three equivalent F(4) atoms. Mn(1) is bonded to two equivalent F(5), two equivalent F(6), and two equivalent F(7) atoms to form MnF6 octahedra that share corners with four equivalent Fe(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 49-57°. Fe(1) is bonded to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(7) atom to form FeF6 octahedra that share corners with two equivalent Mn(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 49-57°. Cd(1) is bonded in a 6-coordinate geometry to two equivalent F(1), two equivalent F(3), and two equivalent F(6) atoms. There are seven inequivalent F sites. In the first F site, F(3) is bonded in a distorted trigonal planar geometry to one Ba(1), one Fe(1), and one Cd(1) atom. In the second F site, F(4) is bonded in a distorted single-bond geometry to three equivalent Ba(1) and one Fe(1) atom. In the third F site, F(5) is bonded in a distorted bent 120 degrees geometry to two equivalent Ba(1), one Mn(1), and one Fe(1) atom. In the fourth F site, F(6) is bonded in a trigonal planar geometry to one Ba(1), one Mn(1), and one Cd(1) atom. In the fifth F site, F(7) is bonded in a 3-coordinate geometry to one Ba(1), one Mn(1), and one Fe(1) atom. In the sixth F site, F(1) is bonded in a 2-coordinate geometry to two equivalent Ba(1), one Fe(1), and one Cd(1) atom. In the seventh F site, F(2) is bonded in a distorted single-bond geometry to two equivalent Ba(1) and one Fe(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ba2MnCdFe2F14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.530
_cell_length_b   7.530
_cell_length_c   15.142
_cell_angle_alpha   88.983
_cell_angle_beta   88.983
_cell_angle_gamma   42.443
_symmetry_Int_Tables_number   1
_cell_volume   579.311
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.648  0.733  0.878  1.0
  Ba  Ba1  1  0.352  0.267  0.122  1.0
  Ba  Ba2  1  0.267  0.352  0.622  1.0
  Ba  Ba3  1  0.733  0.648  0.378  1.0
  Mn  Mn4  1  0.000  0.000  0.500  1.0
  Mn  Mn5  1  0.000  0.000  0.000  1.0
  Cd  Cd6  1  0.951  0.049  0.750  1.0
  Cd  Cd7  1  0.049  0.951  0.250  1.0
  Fe  Fe8  1  0.381  0.379  0.876  1.0
  Fe  Fe9  1  0.619  0.621  0.124  1.0
  Fe  Fe10  1  0.621  0.619  0.624  1.0
  Fe  Fe11  1  0.379  0.381  0.376  1.0
  F  F12  1  0.345  0.906  0.702  1.0
  F  F13  1  0.655  0.094  0.298  1.0
  F  F14  1  0.094  0.655  0.798  1.0
  F  F15  1  0.906  0.345  0.202  1.0
  F  F16  1  0.546  0.124  0.778  1.0
  F  F17  1  0.454  0.876  0.222  1.0
  F  F18  1  0.876  0.454  0.722  1.0
  F  F19  1  0.124  0.546  0.278  1.0
  F  F20  1  0.598  0.387  0.657  1.0
  F  F21  1  0.402  0.613  0.343  1.0
  F  F22  1  0.613  0.402  0.843  1.0
  F  F23  1  0.387  0.598  0.157  1.0
  F  F24  1  0.693  0.808  0.588  1.0
  F  F25  1  0.307  0.192  0.412  1.0
  F  F26  1  0.192  0.307  0.912  1.0
  F  F27  1  0.808  0.693  0.088  1.0
  F  F28  1  0.671  0.071  0.953  1.0
  F  F29  1  0.329  0.929  0.047  1.0
  F  F30  1  0.929  0.329  0.547  1.0
  F  F31  1  0.071  0.671  0.453  1.0
  F  F32  1  0.850  0.037  0.124  1.0
  F  F33  1  0.150  0.963  0.876  1.0
  F  F34  1  0.963  0.150  0.376  1.0
  F  F35  1  0.037  0.850  0.624  1.0
  F  F36  1  0.409  0.757  0.517  1.0
  F  F37  1  0.591  0.243  0.483  1.0
  F  F38  1  0.243  0.591  0.983  1.0
  F  F39  1  0.757  0.409  0.017  1.0
[/CIF]
.
The crystal structure described by Ba2MnFe2CdF14 crystallizes in the monoclinic C2/c space group. Ba(1) is bonded in a 12-coordinate geometry to one F(3), one F(6), one F(7), two equivalent F(1), two equivalent F(2), two equivalent F(5), and three equivalent F(4) atoms. Mn(1) is bonded to two equivalent F(5), two equivalent F(6), and two equivalent F(7) atoms to form MnF6 octahedra that share corners with four equivalent Fe(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 49-57°. Fe(1) is bonded to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(7) atom to form FeF6 octahedra that share corners with two equivalent Mn(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 49-57°. Cd(1) is bonded in a 6-coordinate geometry to two equivalent F(1), two equivalent F(3), and two equivalent F(6) atoms. There are seven inequivalent F sites. In the first F site, F(3) is bonded in a distorted trigonal planar geometry to one Ba(1), one Fe(1), and one Cd(1) atom. In the second F site, F(4) is bonded in a distorted single-bond geometry to three equivalent Ba(1) and one Fe(1) atom. In the third F site, F(5) is bonded in a distorted bent 120 degrees geometry to two equivalent Ba(1), one Mn(1), and one Fe(1) atom. In the fourth F site, F(6) is bonded in a trigonal planar geometry to one Ba(1), one Mn(1), and one Cd(1) atom. In the fifth F site, F(7) is bonded in a 3-coordinate geometry to one Ba(1), one Mn(1), and one Fe(1) atom. In the sixth F site, F(1) is bonded in a 2-coordinate geometry to two equivalent Ba(1), one Fe(1), and one Cd(1) atom. In the seventh F site, F(2) is bonded in a distorted single-bond geometry to two equivalent Ba(1) and one Fe(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ba2MnCdFe2F14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.530
_cell_length_b   7.530
_cell_length_c   15.142
_cell_angle_alpha   88.983
_cell_angle_beta   88.983
_cell_angle_gamma   42.443
_symmetry_Int_Tables_number   1
_cell_volume   579.311
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.648  0.733  0.878  1.0
  Ba  Ba1  1  0.352  0.267  0.122  1.0
  Ba  Ba2  1  0.267  0.352  0.622  1.0
  Ba  Ba3  1  0.733  0.648  0.378  1.0
  Mn  Mn4  1  0.000  0.000  0.500  1.0
  Mn  Mn5  1  0.000  0.000  0.000  1.0
  Cd  Cd6  1  0.951  0.049  0.750  1.0
  Cd  Cd7  1  0.049  0.951  0.250  1.0
  Fe  Fe8  1  0.381  0.379  0.876  1.0
  Fe  Fe9  1  0.619  0.621  0.124  1.0
  Fe  Fe10  1  0.621  0.619  0.624  1.0
  Fe  Fe11  1  0.379  0.381  0.376  1.0
  F  F12  1  0.345  0.906  0.702  1.0
  F  F13  1  0.655  0.094  0.298  1.0
  F  F14  1  0.094  0.655  0.798  1.0
  F  F15  1  0.906  0.345  0.202  1.0
  F  F16  1  0.546  0.124  0.778  1.0
  F  F17  1  0.454  0.876  0.222  1.0
  F  F18  1  0.876  0.454  0.722  1.0
  F  F19  1  0.124  0.546  0.278  1.0
  F  F20  1  0.598  0.387  0.657  1.0
  F  F21  1  0.402  0.613  0.343  1.0
  F  F22  1  0.613  0.402  0.843  1.0
  F  F23  1  0.387  0.598  0.157  1.0
  F  F24  1  0.693  0.808  0.588  1.0
  F  F25  1  0.307  0.192  0.412  1.0
  F  F26  1  0.192  0.307  0.912  1.0
  F  F27  1  0.808  0.693  0.088  1.0
  F  F28  1  0.671  0.071  0.953  1.0
  F  F29  1  0.329  0.929  0.047  1.0
  F  F30  1  0.929  0.329  0.547  1.0
  F  F31  1  0.071  0.671  0.453  1.0
  F  F32  1  0.850  0.037  0.124  1.0
  F  F33  1  0.150  0.963  0.876  1.0
  F  F34  1  0.963  0.150  0.376  1.0
  F  F35  1  0.037  0.850  0.624  1.0
  F  F36  1  0.409  0.757  0.517  1.0
  F  F37  1  0.591  0.243  0.483  1.0
  F  F38  1  0.243  0.591  0.983  1.0
  F  F39  1  0.757  0.409  0.017  1.0
[/CIF]
.