The crystal structure described by TiBr4 is Silicon tetrafluoride-like structured and crystallizes in the cubic Pa-3 space group. The structure is zero-dimensional and consists of eight titanium(iv) bromide molecules. Ti(1) is bonded in a tetrahedral geometry to four equivalent Br(1,2) atoms. Br(1,2) is bonded in a single-bond geometry to one Ti(1) atom. is represented by the CIF card [CIF]
data_TiBr4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.444
_cell_length_b   11.444
_cell_length_c   11.444
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1498.951
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.131  0.131  0.131  1.0
  Ti  Ti1  1  0.369  0.631  0.131  1.0
  Ti  Ti2  1  0.631  0.369  0.869  1.0
  Ti  Ti3  1  0.131  0.369  0.631  1.0
  Ti  Ti4  1  0.869  0.869  0.869  1.0
  Ti  Ti5  1  0.369  0.869  0.631  1.0
  Ti  Ti6  1  0.869  0.631  0.369  1.0
  Ti  Ti7  1  0.631  0.131  0.369  1.0
  Br  Br8  1  0.752  0.752  0.752  1.0
  Br  Br9  1  0.011  0.248  0.016  1.0
  Br  Br10  1  0.248  0.248  0.248  1.0
  Br  Br11  1  0.252  0.984  0.511  1.0
  Br  Br12  1  0.248  0.484  0.511  1.0
  Br  Br13  1  0.248  0.016  0.011  1.0
  Br  Br14  1  0.748  0.016  0.489  1.0
  Br  Br15  1  0.489  0.748  0.016  1.0
  Br  Br16  1  0.489  0.752  0.516  1.0
  Br  Br17  1  0.752  0.516  0.489  1.0
  Br  Br18  1  0.248  0.252  0.748  1.0
  Br  Br19  1  0.989  0.748  0.484  1.0
  Br  Br20  1  0.511  0.248  0.484  1.0
  Br  Br21  1  0.252  0.516  0.011  1.0
  Br  Br22  1  0.016  0.011  0.248  1.0
  Br  Br23  1  0.752  0.984  0.989  1.0
  Br  Br24  1  0.984  0.989  0.752  1.0
  Br  Br25  1  0.516  0.489  0.752  1.0
  Br  Br26  1  0.252  0.752  0.748  1.0
  Br  Br27  1  0.748  0.252  0.752  1.0
  Br  Br28  1  0.989  0.752  0.984  1.0
  Br  Br29  1  0.511  0.252  0.984  1.0
  Br  Br30  1  0.484  0.511  0.248  1.0
  Br  Br31  1  0.748  0.248  0.252  1.0
  Br  Br32  1  0.748  0.484  0.989  1.0
  Br  Br33  1  0.484  0.989  0.748  1.0
  Br  Br34  1  0.516  0.011  0.252  1.0
  Br  Br35  1  0.011  0.252  0.516  1.0
  Br  Br36  1  0.252  0.748  0.248  1.0
  Br  Br37  1  0.752  0.748  0.252  1.0
  Br  Br38  1  0.016  0.489  0.748  1.0
  Br  Br39  1  0.984  0.511  0.252  1.0
[/CIF]
.
The crystal structure described by TiBr4 is Silicon tetrafluoride-like structured and crystallizes in the cubic Pa-3 space group. The structure is zero-dimensional and consists of eight titanium(iv) bromide molecules. Ti(1) is bonded in a tetrahedral geometry to four equivalent Br(1,2) atoms. Br(1,2) is bonded in a single-bond geometry to one Ti(1) atom. is represented by the CIF card [CIF]
data_TiBr4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.444
_cell_length_b   11.444
_cell_length_c   11.444
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1498.951
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.131  0.131  0.131  1.0
  Ti  Ti1  1  0.369  0.631  0.131  1.0
  Ti  Ti2  1  0.631  0.369  0.869  1.0
  Ti  Ti3  1  0.131  0.369  0.631  1.0
  Ti  Ti4  1  0.869  0.869  0.869  1.0
  Ti  Ti5  1  0.369  0.869  0.631  1.0
  Ti  Ti6  1  0.869  0.631  0.369  1.0
  Ti  Ti7  1  0.631  0.131  0.369  1.0
  Br  Br8  1  0.752  0.752  0.752  1.0
  Br  Br9  1  0.011  0.248  0.016  1.0
  Br  Br10  1  0.248  0.248  0.248  1.0
  Br  Br11  1  0.252  0.984  0.511  1.0
  Br  Br12  1  0.248  0.484  0.511  1.0
  Br  Br13  1  0.248  0.016  0.011  1.0
  Br  Br14  1  0.748  0.016  0.489  1.0
  Br  Br15  1  0.489  0.748  0.016  1.0
  Br  Br16  1  0.489  0.752  0.516  1.0
  Br  Br17  1  0.752  0.516  0.489  1.0
  Br  Br18  1  0.248  0.252  0.748  1.0
  Br  Br19  1  0.989  0.748  0.484  1.0
  Br  Br20  1  0.511  0.248  0.484  1.0
  Br  Br21  1  0.252  0.516  0.011  1.0
  Br  Br22  1  0.016  0.011  0.248  1.0
  Br  Br23  1  0.752  0.984  0.989  1.0
  Br  Br24  1  0.984  0.989  0.752  1.0
  Br  Br25  1  0.516  0.489  0.752  1.0
  Br  Br26  1  0.252  0.752  0.748  1.0
  Br  Br27  1  0.748  0.252  0.752  1.0
  Br  Br28  1  0.989  0.752  0.984  1.0
  Br  Br29  1  0.511  0.252  0.984  1.0
  Br  Br30  1  0.484  0.511  0.248  1.0
  Br  Br31  1  0.748  0.248  0.252  1.0
  Br  Br32  1  0.748  0.484  0.989  1.0
  Br  Br33  1  0.484  0.989  0.748  1.0
  Br  Br34  1  0.516  0.011  0.252  1.0
  Br  Br35  1  0.011  0.252  0.516  1.0
  Br  Br36  1  0.252  0.748  0.248  1.0
  Br  Br37  1  0.752  0.748  0.252  1.0
  Br  Br38  1  0.016  0.489  0.748  1.0
  Br  Br39  1  0.984  0.511  0.252  1.0
[/CIF]
.