The structure described by Os(S3Cl4)2(Cl2)8 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of sixteen 7782-50-5 molecules and two Os(S3Cl4)2 clusters. In each Os(S3Cl4)2 cluster, Os(1) is bonded in a distorted octahedral geometry to two equivalent S(1) and four equivalent S(2) atoms. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted single-bond geometry to one Os(1) and two equivalent Cl(3) atoms. In the second S site, S(2) is bonded in a 2-coordinate geometry to one Os(1) and one S(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Cl(3) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one S(1) and one Cl(2) atom. is represented by the CIF card [CIF]
data_Os(SCl4)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.112
_cell_length_b   13.112
_cell_length_c   15.411
_cell_angle_alpha   83.938
_cell_angle_beta   83.938
_cell_angle_gamma   125.432
_symmetry_Int_Tables_number   1
_cell_volume   2100.891
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Os  Os0  1  0.000  0.000  0.000  1.0
  S  S1  1  0.945  0.945  0.152  1.0
  S  S2  1  0.055  0.055  0.848  1.0
  S  S3  1  0.987  0.174  0.003  1.0
  S  S4  1  0.013  0.826  0.997  1.0
  S  S5  1  0.174  0.987  0.003  1.0
  S  S6  1  0.826  0.013  0.997  1.0
  Cl  Cl7  1  0.202  0.745  0.068  1.0
  Cl  Cl8  1  0.798  0.255  0.932  1.0
  Cl  Cl9  1  0.712  0.077  0.254  1.0
  Cl  Cl10  1  0.255  0.798  0.932  1.0
  Cl  Cl11  1  0.288  0.923  0.746  1.0
  Cl  Cl12  1  0.745  0.202  0.068  1.0
  Cl  Cl13  1  0.996  0.177  0.785  1.0
  Cl  Cl14  1  0.923  0.288  0.746  1.0
  Cl  Cl15  1  0.004  0.823  0.215  1.0
  Cl  Cl16  1  0.077  0.712  0.254  1.0
  Cl  Cl17  1  0.823  0.004  0.215  1.0
  Cl  Cl18  1  0.177  0.996  0.785  1.0
  Cl  Cl19  1  0.461  0.547  0.258  1.0
  Cl  Cl20  1  0.539  0.453  0.742  1.0
  Cl  Cl21  1  0.511  0.208  0.448  1.0
  Cl  Cl22  1  0.453  0.539  0.742  1.0
  Cl  Cl23  1  0.489  0.792  0.552  1.0
  Cl  Cl24  1  0.547  0.461  0.258  1.0
  Cl  Cl25  1  0.241  0.428  0.545  1.0
  Cl  Cl26  1  0.792  0.489  0.552  1.0
  Cl  Cl27  1  0.759  0.572  0.455  1.0
  Cl  Cl28  1  0.208  0.511  0.448  1.0
  Cl  Cl29  1  0.572  0.759  0.455  1.0
  Cl  Cl30  1  0.428  0.241  0.545  1.0
[/CIF]
.
The structure described by Os(S3Cl4)2(Cl2)8 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of sixteen 7782-50-5 molecules and two Os(S3Cl4)2 clusters. In each Os(S3Cl4)2 cluster, Os(1) is bonded in a distorted octahedral geometry to two equivalent S(1) and four equivalent S(2) atoms. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted single-bond geometry to one Os(1) and two equivalent Cl(3) atoms. In the second S site, S(2) is bonded in a 2-coordinate geometry to one Os(1) and one S(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Cl(3) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one S(1) and one Cl(2) atom. is represented by the CIF card [CIF]
data_Os(SCl4)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.112
_cell_length_b   13.112
_cell_length_c   15.411
_cell_angle_alpha   83.938
_cell_angle_beta   83.938
_cell_angle_gamma   125.432
_symmetry_Int_Tables_number   1
_cell_volume   2100.891
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Os  Os0  1  0.000  0.000  0.000  1.0
  S  S1  1  0.945  0.945  0.152  1.0
  S  S2  1  0.055  0.055  0.848  1.0
  S  S3  1  0.987  0.174  0.003  1.0
  S  S4  1  0.013  0.826  0.997  1.0
  S  S5  1  0.174  0.987  0.003  1.0
  S  S6  1  0.826  0.013  0.997  1.0
  Cl  Cl7  1  0.202  0.745  0.068  1.0
  Cl  Cl8  1  0.798  0.255  0.932  1.0
  Cl  Cl9  1  0.712  0.077  0.254  1.0
  Cl  Cl10  1  0.255  0.798  0.932  1.0
  Cl  Cl11  1  0.288  0.923  0.746  1.0
  Cl  Cl12  1  0.745  0.202  0.068  1.0
  Cl  Cl13  1  0.996  0.177  0.785  1.0
  Cl  Cl14  1  0.923  0.288  0.746  1.0
  Cl  Cl15  1  0.004  0.823  0.215  1.0
  Cl  Cl16  1  0.077  0.712  0.254  1.0
  Cl  Cl17  1  0.823  0.004  0.215  1.0
  Cl  Cl18  1  0.177  0.996  0.785  1.0
  Cl  Cl19  1  0.461  0.547  0.258  1.0
  Cl  Cl20  1  0.539  0.453  0.742  1.0
  Cl  Cl21  1  0.511  0.208  0.448  1.0
  Cl  Cl22  1  0.453  0.539  0.742  1.0
  Cl  Cl23  1  0.489  0.792  0.552  1.0
  Cl  Cl24  1  0.547  0.461  0.258  1.0
  Cl  Cl25  1  0.241  0.428  0.545  1.0
  Cl  Cl26  1  0.792  0.489  0.552  1.0
  Cl  Cl27  1  0.759  0.572  0.455  1.0
  Cl  Cl28  1  0.208  0.511  0.448  1.0
  Cl  Cl29  1  0.572  0.759  0.455  1.0
  Cl  Cl30  1  0.428  0.241  0.545  1.0
[/CIF]
.