The crystal structure described by MgAg4Te8(MoO12)2 crystallizes in the triclinic P1 space group. Mg(1) is bonded to one O(20), one O(23), one O(24), one O(5), and one O(9) atom to form distorted MgO5 trigonal bipyramids that share  a cornercorner with one Mo(2)O6 octahedra. The corner-sharing octahedral tilt angles are 49°. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in an octahedral geometry to one O(1), one O(13), one O(14), one O(2), one O(7), and one O(8) atom. In the second Mo site, Mo(2) is bonded to one O(15), one O(16), one O(3), one O(4), one O(5), and one O(6) atom to form distorted MoO6 octahedra that share  a cornercorner with one Mg(1)O5 trigonal bipyramid. There are four inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to one O(10), one O(12), one O(20), and one O(6) atom. In the second Ag site, Ag(2) is bonded in a 4-coordinate geometry to one O(10), one O(19), one O(23), and one O(24) atom. In the third Ag site, Ag(3) is bonded in a 6-coordinate geometry to one O(11), one O(12), one O(17), one O(21), one O(22), and one O(8) atom. In the fourth Ag site, Ag(4) is bonded in a 4-coordinate geometry to one O(12), one O(17), one O(21), one O(22), and one O(7) atom. There are eight inequivalent Te sites. In the first Te site, Te(1) is bonded in a 5-coordinate geometry to one O(11), one O(17), one O(24), one O(5), and one O(9) atom. In the second Te site, Te(2) is bonded in a 3-coordinate geometry to one O(10), one O(12), one O(18), and one O(6) atom. In the third Te site, Te(3) is bonded in a 4-coordinate geometry to one O(11), one O(19), one O(22), and one O(7) atom. In the fourth Te site, Te(4) is bonded in a 5-coordinate geometry to one O(10), one O(12), one O(20), one O(21), and one O(8) atom. In the fifth Te site, Te(5) is bonded in a distorted see-saw-like geometry to one O(1), one O(13), one O(17), and one O(21) atom. In the sixth Te site, Te(6) is bonded in a distorted rectangular see-saw-like geometry to one O(14), one O(18), one O(2), and one O(22) atom. In the seventh Te site, Te(7) is bonded in a 3-coordinate geometry to one O(19), one O(23), and one O(3) atom. In the eighth Te site, Te(8) is bonded in a 4-coordinate geometry to one O(16), one O(20), one O(24), and one O(4) atom. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Mo(1) and one Te(5) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Mo(1) and one Te(6) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Mo(2) and one Te(7) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to one Mo(2) and one Te(8) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Mg(1), one Mo(2), and one Te(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Mo(2), one Ag(1), and one Te(2) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Mo(1), one Ag(4), and one Te(3) atom. In the eighth O site, O(8) is bonded in a trigonal planar geometry to one Mo(1), one Ag(3), and one Te(4) atom. In the ninth O site, O(9) is bonded in an L-shaped geometry to one Mg(1) and one Te(1) atom. In the tenth O site, O(10) is bonded in a 4-coordinate geometry to one Ag(1), one Ag(2), one Te(2), and one Te(4) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one Ag(3), one Te(1), and one Te(3) atom. In the twelfth O site, O(12) is bonded in a 5-coordinate geometry to one Ag(1), one Ag(3), one Ag(4), one Te(2), and one Te(4) atom. In the thirteenth O site, O(13) is bonded in a bent 150 degrees geometry to one Mo(1) and one Te(5) atom. In the fourteenth O site, O(14) is bonded in a distorted single-bond geometry to one Mo(1) and one Te(6) atom. In the fifteenth O site, O(15) is bonded in a single-bond geometry to one Mo(2) atom. In the sixteenth O site, O(16) is bonded in a bent 150 degrees geometry to one Mo(2) and one Te(8) atom. In the seventeenth O site, O(17) is bonded in a 4-coordinate geometry to one Ag(3), one Ag(4), one Te(1), and one Te(5) atom. In the eighteenth O site, O(18) is bonded in a distorted bent 120 degrees geometry to one Te(2) and one Te(6) atom. In the nineteenth O site, O(19) is bonded in a distorted trigonal planar geometry to one Ag(2), one Te(3), and one Te(7) atom. In the twentieth O site, O(20) is bonded in a 4-coordinate geometry to one Mg(1), one Ag(1), one Te(4), and one Te(8) atom. In the twenty-first O site, O(21) is bonded in a distorted trigonal pyramidal geometry to one Ag(3), one Ag(4), one Te(4), and one Te(5) atom. In the twenty-second O site, O(22) is bonded in a 4-coordinate geometry to one Ag(3), one Ag(4), one Te(3), and one Te(6) atom. In the twenty-third O site, O(23) is bonded in a 2-coordinate geometry to one Mg(1), one Ag(2), and one Te(7) atom. In the twenty-fourth O site, O(24) is bonded in a distorted trigonal non-coplanar geometry to one Mg(1), one Ag(2), one Te(1), and one Te(8) atom. is represented by the CIF card [CIF]
data_MgAg4Te8(MoO12)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.901
_cell_length_b   9.514
_cell_length_c   12.118
_cell_angle_alpha   103.865
_cell_angle_beta   89.675
_cell_angle_gamma   110.940
_symmetry_Int_Tables_number   1
_cell_volume   614.488
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.769  0.590  0.246  1.0
  Ag  Ag1  1  0.898  0.432  0.416  1.0
  Ag  Ag2  1  0.205  0.475  0.230  1.0
  Ag  Ag3  1  0.044  0.580  0.742  1.0
  Ag  Ag4  1  0.522  0.452  0.773  1.0
  Te  Te5  1  0.985  0.685  0.042  1.0
  Te  Te6  1  0.339  0.308  0.436  1.0
  Te  Te7  1  0.010  0.300  0.909  1.0
  Te  Te8  1  0.686  0.690  0.561  1.0
  Te  Te9  1  0.579  0.846  0.880  1.0
  Te  Te10  1  0.836  0.175  0.593  1.0
  Te  Te11  1  0.411  0.206  0.096  1.0
  Te  Te12  1  0.281  0.852  0.392  1.0
  Mo  Mo13  1  0.170  0.998  0.736  1.0
  Mo  Mo14  1  0.868  1.000  0.241  1.0
  O  O15  1  0.882  0.985  0.848  1.0
  O  O16  1  0.904  0.010  0.625  1.0
  O  O17  1  0.170  0.043  0.143  1.0
  O  O18  1  0.146  0.995  0.364  1.0
  O  O19  1  0.794  0.773  0.170  1.0
  O  O20  1  0.015  0.224  0.351  1.0
  O  O21  1  0.253  0.234  0.829  1.0
  O  O22  1  0.999  0.772  0.663  1.0
  O  O23  1  0.805  0.495  0.079  1.0
  O  O24  1  0.335  0.509  0.439  1.0
  O  O25  1  0.169  0.516  0.922  1.0
  O  O26  1  0.670  0.487  0.573  1.0
  O  O27  1  0.377  0.967  0.853  1.0
  O  O28  1  0.399  0.046  0.642  1.0
  O  O29  1  0.695  0.050  0.152  1.0
  O  O30  1  0.616  0.948  0.357  1.0
  O  O31  1  0.788  0.676  0.916  1.0
  O  O32  1  0.184  0.298  0.581  1.0
  O  O33  1  0.191  0.304  0.062  1.0
  O  O34  1  0.850  0.671  0.419  1.0
  O  O35  1  0.483  0.694  0.738  1.0
  O  O36  1  0.855  0.303  0.743  1.0
  O  O37  1  0.522  0.360  0.241  1.0
  O  O38  1  0.159  0.699  0.252  1.0
[/CIF]
.
The crystal structure described by MgAg4Te8(MoO12)2 crystallizes in the triclinic P1 space group. Mg(1) is bonded to one O(20), one O(23), one O(24), one O(5), and one O(9) atom to form distorted MgO5 trigonal bipyramids that share  a cornercorner with one Mo(2)O6 octahedra. The corner-sharing octahedral tilt angles are 49°. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in an octahedral geometry to one O(1), one O(13), one O(14), one O(2), one O(7), and one O(8) atom. In the second Mo site, Mo(2) is bonded to one O(15), one O(16), one O(3), one O(4), one O(5), and one O(6) atom to form distorted MoO6 octahedra that share  a cornercorner with one Mg(1)O5 trigonal bipyramid. There are four inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to one O(10), one O(12), one O(20), and one O(6) atom. In the second Ag site, Ag(2) is bonded in a 4-coordinate geometry to one O(10), one O(19), one O(23), and one O(24) atom. In the third Ag site, Ag(3) is bonded in a 6-coordinate geometry to one O(11), one O(12), one O(17), one O(21), one O(22), and one O(8) atom. In the fourth Ag site, Ag(4) is bonded in a 4-coordinate geometry to one O(12), one O(17), one O(21), one O(22), and one O(7) atom. There are eight inequivalent Te sites. In the first Te site, Te(1) is bonded in a 5-coordinate geometry to one O(11), one O(17), one O(24), one O(5), and one O(9) atom. In the second Te site, Te(2) is bonded in a 3-coordinate geometry to one O(10), one O(12), one O(18), and one O(6) atom. In the third Te site, Te(3) is bonded in a 4-coordinate geometry to one O(11), one O(19), one O(22), and one O(7) atom. In the fourth Te site, Te(4) is bonded in a 5-coordinate geometry to one O(10), one O(12), one O(20), one O(21), and one O(8) atom. In the fifth Te site, Te(5) is bonded in a distorted see-saw-like geometry to one O(1), one O(13), one O(17), and one O(21) atom. In the sixth Te site, Te(6) is bonded in a distorted rectangular see-saw-like geometry to one O(14), one O(18), one O(2), and one O(22) atom. In the seventh Te site, Te(7) is bonded in a 3-coordinate geometry to one O(19), one O(23), and one O(3) atom. In the eighth Te site, Te(8) is bonded in a 4-coordinate geometry to one O(16), one O(20), one O(24), and one O(4) atom. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Mo(1) and one Te(5) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Mo(1) and one Te(6) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Mo(2) and one Te(7) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to one Mo(2) and one Te(8) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Mg(1), one Mo(2), and one Te(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Mo(2), one Ag(1), and one Te(2) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Mo(1), one Ag(4), and one Te(3) atom. In the eighth O site, O(8) is bonded in a trigonal planar geometry to one Mo(1), one Ag(3), and one Te(4) atom. In the ninth O site, O(9) is bonded in an L-shaped geometry to one Mg(1) and one Te(1) atom. In the tenth O site, O(10) is bonded in a 4-coordinate geometry to one Ag(1), one Ag(2), one Te(2), and one Te(4) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one Ag(3), one Te(1), and one Te(3) atom. In the twelfth O site, O(12) is bonded in a 5-coordinate geometry to one Ag(1), one Ag(3), one Ag(4), one Te(2), and one Te(4) atom. In the thirteenth O site, O(13) is bonded in a bent 150 degrees geometry to one Mo(1) and one Te(5) atom. In the fourteenth O site, O(14) is bonded in a distorted single-bond geometry to one Mo(1) and one Te(6) atom. In the fifteenth O site, O(15) is bonded in a single-bond geometry to one Mo(2) atom. In the sixteenth O site, O(16) is bonded in a bent 150 degrees geometry to one Mo(2) and one Te(8) atom. In the seventeenth O site, O(17) is bonded in a 4-coordinate geometry to one Ag(3), one Ag(4), one Te(1), and one Te(5) atom. In the eighteenth O site, O(18) is bonded in a distorted bent 120 degrees geometry to one Te(2) and one Te(6) atom. In the nineteenth O site, O(19) is bonded in a distorted trigonal planar geometry to one Ag(2), one Te(3), and one Te(7) atom. In the twentieth O site, O(20) is bonded in a 4-coordinate geometry to one Mg(1), one Ag(1), one Te(4), and one Te(8) atom. In the twenty-first O site, O(21) is bonded in a distorted trigonal pyramidal geometry to one Ag(3), one Ag(4), one Te(4), and one Te(5) atom. In the twenty-second O site, O(22) is bonded in a 4-coordinate geometry to one Ag(3), one Ag(4), one Te(3), and one Te(6) atom. In the twenty-third O site, O(23) is bonded in a 2-coordinate geometry to one Mg(1), one Ag(2), and one Te(7) atom. In the twenty-fourth O site, O(24) is bonded in a distorted trigonal non-coplanar geometry to one Mg(1), one Ag(2), one Te(1), and one Te(8) atom. is represented by the CIF card [CIF]
data_MgAg4Te8(MoO12)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.901
_cell_length_b   9.514
_cell_length_c   12.118
_cell_angle_alpha   103.865
_cell_angle_beta   89.675
_cell_angle_gamma   110.940
_symmetry_Int_Tables_number   1
_cell_volume   614.488
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.769  0.590  0.246  1.0
  Ag  Ag1  1  0.898  0.432  0.416  1.0
  Ag  Ag2  1  0.205  0.475  0.230  1.0
  Ag  Ag3  1  0.044  0.580  0.742  1.0
  Ag  Ag4  1  0.522  0.452  0.773  1.0
  Te  Te5  1  0.985  0.685  0.042  1.0
  Te  Te6  1  0.339  0.308  0.436  1.0
  Te  Te7  1  0.010  0.300  0.909  1.0
  Te  Te8  1  0.686  0.690  0.561  1.0
  Te  Te9  1  0.579  0.846  0.880  1.0
  Te  Te10  1  0.836  0.175  0.593  1.0
  Te  Te11  1  0.411  0.206  0.096  1.0
  Te  Te12  1  0.281  0.852  0.392  1.0
  Mo  Mo13  1  0.170  0.998  0.736  1.0
  Mo  Mo14  1  0.868  1.000  0.241  1.0
  O  O15  1  0.882  0.985  0.848  1.0
  O  O16  1  0.904  0.010  0.625  1.0
  O  O17  1  0.170  0.043  0.143  1.0
  O  O18  1  0.146  0.995  0.364  1.0
  O  O19  1  0.794  0.773  0.170  1.0
  O  O20  1  0.015  0.224  0.351  1.0
  O  O21  1  0.253  0.234  0.829  1.0
  O  O22  1  0.999  0.772  0.663  1.0
  O  O23  1  0.805  0.495  0.079  1.0
  O  O24  1  0.335  0.509  0.439  1.0
  O  O25  1  0.169  0.516  0.922  1.0
  O  O26  1  0.670  0.487  0.573  1.0
  O  O27  1  0.377  0.967  0.853  1.0
  O  O28  1  0.399  0.046  0.642  1.0
  O  O29  1  0.695  0.050  0.152  1.0
  O  O30  1  0.616  0.948  0.357  1.0
  O  O31  1  0.788  0.676  0.916  1.0
  O  O32  1  0.184  0.298  0.581  1.0
  O  O33  1  0.191  0.304  0.062  1.0
  O  O34  1  0.850  0.671  0.419  1.0
  O  O35  1  0.483  0.694  0.738  1.0
  O  O36  1  0.855  0.303  0.743  1.0
  O  O37  1  0.522  0.360  0.241  1.0
  O  O38  1  0.159  0.699  0.252  1.0
[/CIF]
.