The material structure described by KAu(OCl2)2 crystallizes in the monoclinic P2_1/c space group. K(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), one Cl(1), one Cl(3), and two equivalent Cl(2) atoms. Au(1) is bonded in a rectangular see-saw-like geometry to one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to two equivalent K(1) and one Cl(4) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to two equivalent K(1) atoms. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a water-like geometry to one K(1) and one Au(1) atom. In the second Cl site, Cl(2) is bonded in a distorted single-bond geometry to two equivalent K(1) and one Au(1) atom. In the third Cl site, Cl(3) is bonded in a distorted single-bond geometry to one K(1) and one Au(1) atom. In the fourth Cl site, Cl(4) is bonded in a bent 120 degrees geometry to one Au(1) and one O(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_KAu(Cl2O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.067
_cell_length_b   8.497
_cell_length_c   10.792
_cell_angle_alpha   56.922
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   927.228
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.931  0.719  0.033  1.0
  K  K1  1  0.069  0.281  0.967  1.0
  K  K2  1  0.431  0.281  0.467  1.0
  K  K3  1  0.569  0.719  0.533  1.0
  Au  Au4  1  0.510  0.758  0.980  1.0
  Au  Au5  1  0.490  0.242  0.020  1.0
  Au  Au6  1  0.010  0.242  0.520  1.0
  Au  Au7  1  0.990  0.758  0.480  1.0
  Cl  Cl8  1  0.856  0.392  0.376  1.0
  Cl  Cl9  1  0.144  0.608  0.624  1.0
  Cl  Cl10  1  0.356  0.608  0.124  1.0
  Cl  Cl11  1  0.644  0.392  0.876  1.0
  Cl  Cl12  1  0.583  0.195  0.230  1.0
  Cl  Cl13  1  0.417  0.805  0.770  1.0
  Cl  Cl14  1  0.083  0.805  0.270  1.0
  Cl  Cl15  1  0.917  0.195  0.730  1.0
  Cl  Cl16  1  0.834  0.919  0.344  1.0
  Cl  Cl17  1  0.166  0.081  0.656  1.0
  Cl  Cl18  1  0.334  0.081  0.156  1.0
  Cl  Cl19  1  0.666  0.919  0.844  1.0
  Cl  Cl20  1  0.617  0.717  0.182  1.0
  Cl  Cl21  1  0.383  0.283  0.818  1.0
  Cl  Cl22  1  0.117  0.283  0.318  1.0
  Cl  Cl23  1  0.883  0.717  0.682  1.0
  O  O24  1  0.944  0.608  0.837  1.0
  O  O25  1  0.056  0.392  0.163  1.0
  O  O26  1  0.444  0.392  0.663  1.0
  O  O27  1  0.556  0.608  0.337  1.0
  O  O28  1  0.916  0.990  0.109  1.0
  O  O29  1  0.084  0.010  0.891  1.0
  O  O30  1  0.416  0.010  0.391  1.0
  O  O31  1  0.584  0.990  0.609  1.0
[/CIF]
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The material structure described by KAu(OCl2)2 crystallizes in the monoclinic P2_1/c space group. K(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), one Cl(1), one Cl(3), and two equivalent Cl(2) atoms. Au(1) is bonded in a rectangular see-saw-like geometry to one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to two equivalent K(1) and one Cl(4) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to two equivalent K(1) atoms. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a water-like geometry to one K(1) and one Au(1) atom. In the second Cl site, Cl(2) is bonded in a distorted single-bond geometry to two equivalent K(1) and one Au(1) atom. In the third Cl site, Cl(3) is bonded in a distorted single-bond geometry to one K(1) and one Au(1) atom. In the fourth Cl site, Cl(4) is bonded in a bent 120 degrees geometry to one Au(1) and one O(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_KAu(Cl2O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.067
_cell_length_b   8.497
_cell_length_c   10.792
_cell_angle_alpha   56.922
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   927.228
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.931  0.719  0.033  1.0
  K  K1  1  0.069  0.281  0.967  1.0
  K  K2  1  0.431  0.281  0.467  1.0
  K  K3  1  0.569  0.719  0.533  1.0
  Au  Au4  1  0.510  0.758  0.980  1.0
  Au  Au5  1  0.490  0.242  0.020  1.0
  Au  Au6  1  0.010  0.242  0.520  1.0
  Au  Au7  1  0.990  0.758  0.480  1.0
  Cl  Cl8  1  0.856  0.392  0.376  1.0
  Cl  Cl9  1  0.144  0.608  0.624  1.0
  Cl  Cl10  1  0.356  0.608  0.124  1.0
  Cl  Cl11  1  0.644  0.392  0.876  1.0
  Cl  Cl12  1  0.583  0.195  0.230  1.0
  Cl  Cl13  1  0.417  0.805  0.770  1.0
  Cl  Cl14  1  0.083  0.805  0.270  1.0
  Cl  Cl15  1  0.917  0.195  0.730  1.0
  Cl  Cl16  1  0.834  0.919  0.344  1.0
  Cl  Cl17  1  0.166  0.081  0.656  1.0
  Cl  Cl18  1  0.334  0.081  0.156  1.0
  Cl  Cl19  1  0.666  0.919  0.844  1.0
  Cl  Cl20  1  0.617  0.717  0.182  1.0
  Cl  Cl21  1  0.383  0.283  0.818  1.0
  Cl  Cl22  1  0.117  0.283  0.318  1.0
  Cl  Cl23  1  0.883  0.717  0.682  1.0
  O  O24  1  0.944  0.608  0.837  1.0
  O  O25  1  0.056  0.392  0.163  1.0
  O  O26  1  0.444  0.392  0.663  1.0
  O  O27  1  0.556  0.608  0.337  1.0
  O  O28  1  0.916  0.990  0.109  1.0
  O  O29  1  0.084  0.010  0.891  1.0
  O  O30  1  0.416  0.010  0.391  1.0
  O  O31  1  0.584  0.990  0.609  1.0
[/CIF]
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