The crystal structure described by (RbO6)2RbIrN6 crystallizes in the cubic Fm-3m space group. The structure consists of one RbIrN6 framework and one RbO6 framework. In the RbIrN6 framework, Rb(1) is bonded to six equivalent N(1) atoms to form RbN6 octahedra that share corners with six equivalent Ir(1)N6 octahedra. The corner-sharing octahedra are not tilted. Ir(1) is bonded to six equivalent N(1) atoms to form IrN6 octahedra that share corners with six equivalent Rb(1)N6 octahedra. The corner-sharing octahedra are not tilted. N(1) is bonded in a single-bond geometry to one Rb(1) and one Ir(1) atom. In the RbO6 framework, Rb(2) is bonded in a distorted q4 geometry to twelve equivalent O(1) atoms. O(1) is bonded in a distorted T-shaped geometry to two equivalent Rb(2) and one O(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Rb3Ir(NO2)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.986
_cell_length_b   7.986
_cell_length_c   7.986
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   360.134
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.500  0.500  0.500  1.0
  Rb  Rb1  1  0.750  0.750  0.750  1.0
  Rb  Rb2  1  0.250  0.250  0.250  1.0
  Ir  Ir3  1  0.000  0.000  0.000  1.0
  N  N4  1  0.177  0.177  0.823  1.0
  N  N5  1  0.823  0.177  0.823  1.0
  N  N6  1  0.823  0.823  0.177  1.0
  N  N7  1  0.823  0.177  0.177  1.0
  N  N8  1  0.177  0.823  0.177  1.0
  N  N9  1  0.177  0.823  0.823  1.0
  O  O10  1  0.581  0.419  0.000  1.0
  O  O11  1  0.581  0.000  0.419  1.0
  O  O12  1  0.581  0.000  0.000  1.0
  O  O13  1  0.000  0.000  0.581  1.0
  O  O14  1  0.419  0.000  0.000  1.0
  O  O15  1  0.419  0.000  0.581  1.0
  O  O16  1  0.000  0.419  0.000  1.0
  O  O17  1  0.000  0.000  0.419  1.0
  O  O18  1  0.419  0.581  0.000  1.0
  O  O19  1  0.000  0.581  0.419  1.0
  O  O20  1  0.000  0.419  0.581  1.0
  O  O21  1  0.000  0.581  0.000  1.0
[/CIF]
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The crystal structure described by (RbO6)2RbIrN6 crystallizes in the cubic Fm-3m space group. The structure consists of one RbIrN6 framework and one RbO6 framework. In the RbIrN6 framework, Rb(1) is bonded to six equivalent N(1) atoms to form RbN6 octahedra that share corners with six equivalent Ir(1)N6 octahedra. The corner-sharing octahedra are not tilted. Ir(1) is bonded to six equivalent N(1) atoms to form IrN6 octahedra that share corners with six equivalent Rb(1)N6 octahedra. The corner-sharing octahedra are not tilted. N(1) is bonded in a single-bond geometry to one Rb(1) and one Ir(1) atom. In the RbO6 framework, Rb(2) is bonded in a distorted q4 geometry to twelve equivalent O(1) atoms. O(1) is bonded in a distorted T-shaped geometry to two equivalent Rb(2) and one O(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Rb3Ir(NO2)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.986
_cell_length_b   7.986
_cell_length_c   7.986
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   360.134
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.500  0.500  0.500  1.0
  Rb  Rb1  1  0.750  0.750  0.750  1.0
  Rb  Rb2  1  0.250  0.250  0.250  1.0
  Ir  Ir3  1  0.000  0.000  0.000  1.0
  N  N4  1  0.177  0.177  0.823  1.0
  N  N5  1  0.823  0.177  0.823  1.0
  N  N6  1  0.823  0.823  0.177  1.0
  N  N7  1  0.823  0.177  0.177  1.0
  N  N8  1  0.177  0.823  0.177  1.0
  N  N9  1  0.177  0.823  0.823  1.0
  O  O10  1  0.581  0.419  0.000  1.0
  O  O11  1  0.581  0.000  0.419  1.0
  O  O12  1  0.581  0.000  0.000  1.0
  O  O13  1  0.000  0.000  0.581  1.0
  O  O14  1  0.419  0.000  0.000  1.0
  O  O15  1  0.419  0.000  0.581  1.0
  O  O16  1  0.000  0.419  0.000  1.0
  O  O17  1  0.000  0.000  0.419  1.0
  O  O18  1  0.419  0.581  0.000  1.0
  O  O19  1  0.000  0.581  0.419  1.0
  O  O20  1  0.000  0.419  0.581  1.0
  O  O21  1  0.000  0.581  0.000  1.0
[/CIF]
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