The crystal structure described by LaCo12B6 crystallizes in the trigonal R-3m space group. La(1) is bonded in a 24-coordinate geometry to six equivalent Co(2), twelve equivalent Co(1), and six equivalent B(1) atoms. There are two inequivalent Co sites. In the first Co site, Co(2) is bonded in a distorted T-shaped geometry to one La(1) and three equivalent B(1) atoms. In the second Co site, Co(1) is bonded in a 4-coordinate geometry to two equivalent La(1) and four equivalent B(1) atoms. B(1) is bonded in a 7-coordinate geometry to one La(1), three equivalent Co(2), and four equivalent Co(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_La(Co2B)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.971
_cell_length_b   5.971
_cell_length_c   5.971
_cell_angle_alpha   104.132
_cell_angle_beta   104.132
_cell_angle_gamma   104.132
_symmetry_Int_Tables_number   1
_cell_volume   189.468
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.000  0.000  0.000  1.0
  Co  Co1  1  0.134  0.866  0.500  1.0
  Co  Co2  1  0.500  0.134  0.866  1.0
  Co  Co3  1  0.866  0.500  0.134  1.0
  Co  Co4  1  0.500  0.866  0.134  1.0
  Co  Co5  1  0.134  0.500  0.866  1.0
  Co  Co6  1  0.866  0.134  0.500  1.0
  Co  Co7  1  0.538  0.813  0.538  1.0
  Co  Co8  1  0.538  0.538  0.813  1.0
  Co  Co9  1  0.813  0.538  0.538  1.0
  Co  Co10  1  0.462  0.187  0.462  1.0
  Co  Co11  1  0.462  0.462  0.187  1.0
  Co  Co12  1  0.187  0.462  0.462  1.0
  B  B13  1  0.771  0.330  0.771  1.0
  B  B14  1  0.771  0.771  0.330  1.0
  B  B15  1  0.330  0.771  0.771  1.0
  B  B16  1  0.229  0.670  0.229  1.0
  B  B17  1  0.229  0.229  0.670  1.0
  B  B18  1  0.670  0.229  0.229  1.0
[/CIF]
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The crystal structure described by LaCo12B6 crystallizes in the trigonal R-3m space group. La(1) is bonded in a 24-coordinate geometry to six equivalent Co(2), twelve equivalent Co(1), and six equivalent B(1) atoms. There are two inequivalent Co sites. In the first Co site, Co(2) is bonded in a distorted T-shaped geometry to one La(1) and three equivalent B(1) atoms. In the second Co site, Co(1) is bonded in a 4-coordinate geometry to two equivalent La(1) and four equivalent B(1) atoms. B(1) is bonded in a 7-coordinate geometry to one La(1), three equivalent Co(2), and four equivalent Co(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_La(Co2B)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.971
_cell_length_b   5.971
_cell_length_c   5.971
_cell_angle_alpha   104.132
_cell_angle_beta   104.132
_cell_angle_gamma   104.132
_symmetry_Int_Tables_number   1
_cell_volume   189.468
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.000  0.000  0.000  1.0
  Co  Co1  1  0.134  0.866  0.500  1.0
  Co  Co2  1  0.500  0.134  0.866  1.0
  Co  Co3  1  0.866  0.500  0.134  1.0
  Co  Co4  1  0.500  0.866  0.134  1.0
  Co  Co5  1  0.134  0.500  0.866  1.0
  Co  Co6  1  0.866  0.134  0.500  1.0
  Co  Co7  1  0.538  0.813  0.538  1.0
  Co  Co8  1  0.538  0.538  0.813  1.0
  Co  Co9  1  0.813  0.538  0.538  1.0
  Co  Co10  1  0.462  0.187  0.462  1.0
  Co  Co11  1  0.462  0.462  0.187  1.0
  Co  Co12  1  0.187  0.462  0.462  1.0
  B  B13  1  0.771  0.330  0.771  1.0
  B  B14  1  0.771  0.771  0.330  1.0
  B  B15  1  0.330  0.771  0.771  1.0
  B  B16  1  0.229  0.670  0.229  1.0
  B  B17  1  0.229  0.229  0.670  1.0
  B  B18  1  0.670  0.229  0.229  1.0
[/CIF]
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