The crystal structure described by Ag5Pb2O6 crystallizes in the trigonal P31m space group. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a linear geometry to one O(1) and one O(2) atom. In the second Ag site, Ag(2) is bonded in a trigonal planar geometry to three equivalent O(1) atoms. In the third Ag site, Ag(3) is bonded in a trigonal non-coplanar geometry to three equivalent O(2) atoms. Pb(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form edge-sharing PbO6 octahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded to one Ag(1), one Ag(2), and two equivalent Pb(1) atoms to form a mixture of edge and corner-sharing OAg2Pb2 tetrahedra. In the second O site, O(2) is bonded to one Ag(1), one Ag(3), and two equivalent Pb(1) atoms to form a mixture of edge and corner-sharing OAg2Pb2 tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ag5(PbO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.066
_cell_length_b   6.066
_cell_length_c   6.529
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   208.059
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.501  0.000  0.521  1.0
  Ag  Ag1  1  0.000  0.000  0.274  1.0
  Ag  Ag2  1  0.499  0.499  0.521  1.0
  Ag  Ag3  1  0.000  0.501  0.521  1.0
  Ag  Ag4  1  0.000  0.000  0.738  1.0
  Pb  Pb5  1  0.333  0.667  0.020  1.0
  Pb  Pb6  1  0.667  0.333  0.020  1.0
  O  O7  1  0.000  0.622  0.213  1.0
  O  O8  1  0.376  0.000  0.829  1.0
  O  O9  1  0.622  0.000  0.213  1.0
  O  O10  1  0.378  0.378  0.213  1.0
  O  O11  1  0.000  0.376  0.829  1.0
  O  O12  1  0.624  0.624  0.829  1.0
[/CIF]
.
The crystal structure described by Ag5Pb2O6 crystallizes in the trigonal P31m space group. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a linear geometry to one O(1) and one O(2) atom. In the second Ag site, Ag(2) is bonded in a trigonal planar geometry to three equivalent O(1) atoms. In the third Ag site, Ag(3) is bonded in a trigonal non-coplanar geometry to three equivalent O(2) atoms. Pb(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form edge-sharing PbO6 octahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded to one Ag(1), one Ag(2), and two equivalent Pb(1) atoms to form a mixture of edge and corner-sharing OAg2Pb2 tetrahedra. In the second O site, O(2) is bonded to one Ag(1), one Ag(3), and two equivalent Pb(1) atoms to form a mixture of edge and corner-sharing OAg2Pb2 tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ag5(PbO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.066
_cell_length_b   6.066
_cell_length_c   6.529
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   208.059
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.501  0.000  0.521  1.0
  Ag  Ag1  1  0.000  0.000  0.274  1.0
  Ag  Ag2  1  0.499  0.499  0.521  1.0
  Ag  Ag3  1  0.000  0.501  0.521  1.0
  Ag  Ag4  1  0.000  0.000  0.738  1.0
  Pb  Pb5  1  0.333  0.667  0.020  1.0
  Pb  Pb6  1  0.667  0.333  0.020  1.0
  O  O7  1  0.000  0.622  0.213  1.0
  O  O8  1  0.376  0.000  0.829  1.0
  O  O9  1  0.622  0.000  0.213  1.0
  O  O10  1  0.378  0.378  0.213  1.0
  O  O11  1  0.000  0.376  0.829  1.0
  O  O12  1  0.624  0.624  0.829  1.0
[/CIF]
.