The compound described by MoF3 crystallizes in the trigonal R-3c space group. Mo(1) is bonded to six equivalent F(1) atoms to form corner-sharing MoF6 octahedra. The corner-sharing octahedral tilt angles are 43°. F(1) is bonded in a bent 150 degrees geometry to two equivalent Mo(1) atoms. is represented by the CIF card [CIF]
data_MoF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.672
_cell_length_b   5.672
_cell_length_c   5.668
_cell_angle_alpha   53.940
_cell_angle_beta   53.940
_cell_angle_gamma   53.925
_symmetry_Int_Tables_number   1
_cell_volume   110.670
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.500  0.500  0.500  1.0
  Mo  Mo1  1  0.000  0.000  0.000  1.0
  F  F2  1  0.398  0.750  0.102  1.0
  F  F3  1  0.750  0.102  0.398  1.0
  F  F4  1  0.897  0.603  0.250  1.0
  F  F5  1  0.250  0.898  0.602  1.0
  F  F6  1  0.602  0.250  0.898  1.0
  F  F7  1  0.103  0.397  0.750  1.0
[/CIF]
.
The compound described by MoF3 crystallizes in the trigonal R-3c space group. Mo(1) is bonded to six equivalent F(1) atoms to form corner-sharing MoF6 octahedra. The corner-sharing octahedral tilt angles are 43°. F(1) is bonded in a bent 150 degrees geometry to two equivalent Mo(1) atoms. is represented by the CIF card [CIF]
data_MoF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.672
_cell_length_b   5.672
_cell_length_c   5.668
_cell_angle_alpha   53.940
_cell_angle_beta   53.940
_cell_angle_gamma   53.925
_symmetry_Int_Tables_number   1
_cell_volume   110.670
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.500  0.500  0.500  1.0
  Mo  Mo1  1  0.000  0.000  0.000  1.0
  F  F2  1  0.398  0.750  0.102  1.0
  F  F3  1  0.750  0.102  0.398  1.0
  F  F4  1  0.897  0.603  0.250  1.0
  F  F5  1  0.250  0.898  0.602  1.0
  F  F6  1  0.602  0.250  0.898  1.0
  F  F7  1  0.103  0.397  0.750  1.0
[/CIF]
.