The material structure described by RuZn2N3 is Enargite-like structured and crystallizes in the orthorhombic Cmc2_1 space group. Ru(1) is bonded to two equivalent N(1) and two equivalent N(2) atoms to form RuN4 tetrahedra that share corners with two equivalent Ru(1)N4 tetrahedra and corners with ten equivalent Zn(1)N4 tetrahedra. Zn(1) is bonded to one N(2) and three equivalent N(1) atoms to form ZnN4 tetrahedra that share corners with five equivalent Ru(1)N4 tetrahedra and corners with seven equivalent Zn(1)N4 tetrahedra. There are two inequivalent N sites. In the first N site, N(1) is bonded to one Ru(1) and three equivalent Zn(1) atoms to form NZn3Ru tetrahedra that share corners with five equivalent N(2)Zn2Ru2 tetrahedra and corners with seven equivalent N(1)Zn3Ru tetrahedra. In the second N site, N(2) is bonded to two equivalent Ru(1) and two equivalent Zn(1) atoms to form NZn2Ru2 tetrahedra that share corners with two equivalent N(2)Zn2Ru2 tetrahedra and corners with ten equivalent N(1)Zn3Ru tetrahedra. is represented by the CIF card [CIF]
data_Zn2RuN3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.629
_cell_length_b   5.589
_cell_length_c   5.278
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   119.767
_symmetry_Int_Tables_number   1
_cell_volume   144.146
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.335  0.828  0.473  1.0
  Zn  Zn1  1  0.665  0.493  0.473  1.0
  Zn  Zn2  1  0.665  0.172  0.973  1.0
  Zn  Zn3  1  0.335  0.507  0.973  1.0
  Ru  Ru4  1  0.000  0.831  0.962  1.0
  Ru  Ru5  1  0.000  0.169  0.462  1.0
  N  N6  1  0.320  0.840  0.854  1.0
  N  N7  1  0.680  0.520  0.854  1.0
  N  N8  1  0.680  0.160  0.354  1.0
  N  N9  1  0.320  0.480  0.354  1.0
  N  N10  1  0.000  0.851  0.327  1.0
  N  N11  1  0.000  0.149  0.827  1.0
[/CIF]
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The material structure described by RuZn2N3 is Enargite-like structured and crystallizes in the orthorhombic Cmc2_1 space group. Ru(1) is bonded to two equivalent N(1) and two equivalent N(2) atoms to form RuN4 tetrahedra that share corners with two equivalent Ru(1)N4 tetrahedra and corners with ten equivalent Zn(1)N4 tetrahedra. Zn(1) is bonded to one N(2) and three equivalent N(1) atoms to form ZnN4 tetrahedra that share corners with five equivalent Ru(1)N4 tetrahedra and corners with seven equivalent Zn(1)N4 tetrahedra. There are two inequivalent N sites. In the first N site, N(1) is bonded to one Ru(1) and three equivalent Zn(1) atoms to form NZn3Ru tetrahedra that share corners with five equivalent N(2)Zn2Ru2 tetrahedra and corners with seven equivalent N(1)Zn3Ru tetrahedra. In the second N site, N(2) is bonded to two equivalent Ru(1) and two equivalent Zn(1) atoms to form NZn2Ru2 tetrahedra that share corners with two equivalent N(2)Zn2Ru2 tetrahedra and corners with ten equivalent N(1)Zn3Ru tetrahedra. is represented by the CIF card [CIF]
data_Zn2RuN3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.629
_cell_length_b   5.589
_cell_length_c   5.278
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   119.767
_symmetry_Int_Tables_number   1
_cell_volume   144.146
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.335  0.828  0.473  1.0
  Zn  Zn1  1  0.665  0.493  0.473  1.0
  Zn  Zn2  1  0.665  0.172  0.973  1.0
  Zn  Zn3  1  0.335  0.507  0.973  1.0
  Ru  Ru4  1  0.000  0.831  0.962  1.0
  Ru  Ru5  1  0.000  0.169  0.462  1.0
  N  N6  1  0.320  0.840  0.854  1.0
  N  N7  1  0.680  0.520  0.854  1.0
  N  N8  1  0.680  0.160  0.354  1.0
  N  N9  1  0.320  0.480  0.354  1.0
  N  N10  1  0.000  0.851  0.327  1.0
  N  N11  1  0.000  0.149  0.827  1.0
[/CIF]
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