The crystal structure described by Cs2TeO4 crystallizes in the orthorhombic Pnma space group. There are two inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a 10-coordinate geometry to one O(3), three equivalent O(1), and six equivalent O(2) atoms. In the second Cs site, Cs(2) is bonded in a 7-coordinate geometry to one O(3), two equivalent O(1), and four equivalent O(2) atoms. Te(1) is bonded in a tetrahedral geometry to one O(1), one O(3), and two equivalent O(2) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Cs(2), three equivalent Cs(1), and one Te(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Cs(2), three equivalent Cs(1), and one Te(1) atom. In the third O site, O(3) is bonded in a 1-coordinate geometry to one Cs(1), one Cs(2), and one Te(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Cs2TeO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.681
_cell_length_b   8.538
_cell_length_c   11.700
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   667.455
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.750  0.667  0.417  1.0
  Cs  Cs1  1  0.250  0.001  0.288  1.0
  Cs  Cs2  1  0.750  0.999  0.712  1.0
  Cs  Cs3  1  0.250  0.333  0.583  1.0
  Cs  Cs4  1  0.250  0.501  0.212  1.0
  Cs  Cs5  1  0.250  0.833  0.917  1.0
  Cs  Cs6  1  0.750  0.167  0.083  1.0
  Cs  Cs7  1  0.750  0.499  0.788  1.0
  Te  Te8  1  0.750  0.719  0.079  1.0
  Te  Te9  1  0.750  0.219  0.421  1.0
  Te  Te10  1  0.250  0.281  0.921  1.0
  Te  Te11  1  0.250  0.781  0.579  1.0
  O  O12  1  0.750  0.307  0.564  1.0
  O  O13  1  0.527  0.788  0.154  1.0
  O  O14  1  0.250  0.494  0.929  1.0
  O  O15  1  0.250  0.994  0.571  1.0
  O  O16  1  0.473  0.212  0.846  1.0
  O  O17  1  0.750  0.807  0.936  1.0
  O  O18  1  0.250  0.193  0.064  1.0
  O  O19  1  0.473  0.712  0.654  1.0
  O  O20  1  0.027  0.212  0.846  1.0
  O  O21  1  0.973  0.788  0.154  1.0
  O  O22  1  0.973  0.288  0.346  1.0
  O  O23  1  0.750  0.506  0.071  1.0
  O  O24  1  0.527  0.288  0.346  1.0
  O  O25  1  0.027  0.712  0.654  1.0
  O  O26  1  0.250  0.693  0.436  1.0
  O  O27  1  0.750  0.006  0.429  1.0
[/CIF]
.
The crystal structure described by Cs2TeO4 crystallizes in the orthorhombic Pnma space group. There are two inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a 10-coordinate geometry to one O(3), three equivalent O(1), and six equivalent O(2) atoms. In the second Cs site, Cs(2) is bonded in a 7-coordinate geometry to one O(3), two equivalent O(1), and four equivalent O(2) atoms. Te(1) is bonded in a tetrahedral geometry to one O(1), one O(3), and two equivalent O(2) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Cs(2), three equivalent Cs(1), and one Te(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Cs(2), three equivalent Cs(1), and one Te(1) atom. In the third O site, O(3) is bonded in a 1-coordinate geometry to one Cs(1), one Cs(2), and one Te(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Cs2TeO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.681
_cell_length_b   8.538
_cell_length_c   11.700
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   667.455
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.750  0.667  0.417  1.0
  Cs  Cs1  1  0.250  0.001  0.288  1.0
  Cs  Cs2  1  0.750  0.999  0.712  1.0
  Cs  Cs3  1  0.250  0.333  0.583  1.0
  Cs  Cs4  1  0.250  0.501  0.212  1.0
  Cs  Cs5  1  0.250  0.833  0.917  1.0
  Cs  Cs6  1  0.750  0.167  0.083  1.0
  Cs  Cs7  1  0.750  0.499  0.788  1.0
  Te  Te8  1  0.750  0.719  0.079  1.0
  Te  Te9  1  0.750  0.219  0.421  1.0
  Te  Te10  1  0.250  0.281  0.921  1.0
  Te  Te11  1  0.250  0.781  0.579  1.0
  O  O12  1  0.750  0.307  0.564  1.0
  O  O13  1  0.527  0.788  0.154  1.0
  O  O14  1  0.250  0.494  0.929  1.0
  O  O15  1  0.250  0.994  0.571  1.0
  O  O16  1  0.473  0.212  0.846  1.0
  O  O17  1  0.750  0.807  0.936  1.0
  O  O18  1  0.250  0.193  0.064  1.0
  O  O19  1  0.473  0.712  0.654  1.0
  O  O20  1  0.027  0.212  0.846  1.0
  O  O21  1  0.973  0.788  0.154  1.0
  O  O22  1  0.973  0.288  0.346  1.0
  O  O23  1  0.750  0.506  0.071  1.0
  O  O24  1  0.527  0.288  0.346  1.0
  O  O25  1  0.027  0.712  0.654  1.0
  O  O26  1  0.250  0.693  0.436  1.0
  O  O27  1  0.750  0.006  0.429  1.0
[/CIF]
.