The structure described by ZrPP is Cotunnite structured and crystallizes in the orthorhombic Pnma space group. Zr(1) is bonded in a 9-coordinate geometry to four equivalent P(2) and five equivalent P(1) atoms. There are two inequivalent P sites. In the first P site, P(2) is bonded in a 8-coordinate geometry to four equivalent Zr(1), two equivalent P(1), and two equivalent P(2) atoms. In the second P site, P(1) is bonded in a 5-coordinate geometry to five equivalent Zr(1) and two equivalent P(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZrP2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.526
_cell_length_b   6.526
_cell_length_c   8.788
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   202.200
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr0  1  0.250  0.781  0.337  1.0
  Zr  Zr1  1  0.750  0.219  0.663  1.0
  Zr  Zr2  1  0.250  0.281  0.163  1.0
  Zr  Zr3  1  0.750  0.719  0.837  1.0
  P  P4  1  0.250  0.404  0.855  1.0
  P  P5  1  0.750  0.596  0.145  1.0
  P  P6  1  0.250  0.904  0.645  1.0
  P  P7  1  0.750  0.096  0.355  1.0
  P  P8  1  0.750  0.107  0.961  1.0
  P  P9  1  0.250  0.893  0.039  1.0
  P  P10  1  0.750  0.607  0.539  1.0
  P  P11  1  0.250  0.393  0.461  1.0
[/CIF]
.
The structure described by ZrPP is Cotunnite structured and crystallizes in the orthorhombic Pnma space group. Zr(1) is bonded in a 9-coordinate geometry to four equivalent P(2) and five equivalent P(1) atoms. There are two inequivalent P sites. In the first P site, P(2) is bonded in a 8-coordinate geometry to four equivalent Zr(1), two equivalent P(1), and two equivalent P(2) atoms. In the second P site, P(1) is bonded in a 5-coordinate geometry to five equivalent Zr(1) and two equivalent P(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZrP2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.526
_cell_length_b   6.526
_cell_length_c   8.788
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   202.200
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr0  1  0.250  0.781  0.337  1.0
  Zr  Zr1  1  0.750  0.219  0.663  1.0
  Zr  Zr2  1  0.250  0.281  0.163  1.0
  Zr  Zr3  1  0.750  0.719  0.837  1.0
  P  P4  1  0.250  0.404  0.855  1.0
  P  P5  1  0.750  0.596  0.145  1.0
  P  P6  1  0.250  0.904  0.645  1.0
  P  P7  1  0.750  0.096  0.355  1.0
  P  P8  1  0.750  0.107  0.961  1.0
  P  P9  1  0.250  0.893  0.039  1.0
  P  P10  1  0.750  0.607  0.539  1.0
  P  P11  1  0.250  0.393  0.461  1.0
[/CIF]
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