The material described by CoS2(NO7)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two CoS2(NO7)2 clusters. Co(1) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(6) atoms to form CoO6 octahedra that share corners with two equivalent S(1)O4 tetrahedra. N(1) is bonded in a bent 120 degrees geometry to one O(5) and one O(7) atom. S(1) is bonded to one O(1), one O(3), one O(4), and one O(7) atom to form SO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra. The corner-sharing octahedral tilt angles are 54°. There are seven inequivalent O sites. In the first O site, O(7) is bonded in a distorted bent 120 degrees geometry to one N(1) and one S(1) atom. In the second O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(2) is bonded in a single-bond geometry to one Co(1) atom. In the fourth O site, O(3) is bonded in a bent 120 degrees geometry to one Co(1) and one S(1) atom. In the fifth O site, O(4) is bonded in a single-bond geometry to one S(1) atom. In the sixth O site, O(5) is bonded in a single-bond geometry to one N(1) atom. In the seventh O site, O(6) is bonded in a single-bond geometry to one Co(1) atom. is represented by the CIF card [CIF]
data_CoS2(NO7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.435
_cell_length_b   9.568
_cell_length_c   12.894
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   131.276
_symmetry_Int_Tables_number   1
_cell_volume   596.612
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.500  0.000  0.000  1.0
  Co  Co1  1  0.500  0.500  0.500  1.0
  S  S2  1  0.976  0.665  0.882  1.0
  S  S3  1  0.024  0.335  0.118  1.0
  S  S4  1  0.024  0.835  0.382  1.0
  S  S5  1  0.976  0.165  0.618  1.0
  N  N6  1  0.836  0.631  0.169  1.0
  N  N7  1  0.164  0.369  0.831  1.0
  N  N8  1  0.164  0.869  0.669  1.0
  N  N9  1  0.836  0.131  0.331  1.0
  O  O10  1  0.863  0.740  0.933  1.0
  O  O11  1  0.137  0.260  0.067  1.0
  O  O12  1  0.137  0.760  0.433  1.0
  O  O13  1  0.863  0.240  0.567  1.0
  O  O14  1  0.798  0.039  0.957  1.0
  O  O15  1  0.202  0.961  0.043  1.0
  O  O16  1  0.202  0.461  0.457  1.0
  O  O17  1  0.798  0.539  0.543  1.0
  O  O18  1  0.292  0.797  0.900  1.0
  O  O19  1  0.708  0.203  0.100  1.0
  O  O20  1  0.708  0.703  0.400  1.0
  O  O21  1  0.292  0.297  0.600  1.0
  O  O22  1  0.850  0.978  0.588  1.0
  O  O23  1  0.150  0.022  0.412  1.0
  O  O24  1  0.150  0.522  0.088  1.0
  O  O25  1  0.850  0.478  0.912  1.0
  O  O26  1  0.340  0.509  0.796  1.0
  O  O27  1  0.660  0.491  0.204  1.0
  O  O28  1  0.660  0.991  0.296  1.0
  O  O29  1  0.340  0.009  0.704  1.0
  O  O30  1  0.467  0.622  0.592  1.0
  O  O31  1  0.533  0.378  0.408  1.0
  O  O32  1  0.533  0.878  0.092  1.0
  O  O33  1  0.467  0.122  0.908  1.0
  O  O34  1  0.944  0.661  0.764  1.0
  O  O35  1  0.056  0.339  0.236  1.0
  O  O36  1  0.056  0.839  0.264  1.0
  O  O37  1  0.944  0.161  0.736  1.0
[/CIF]
.
The material described by CoS2(NO7)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two CoS2(NO7)2 clusters. Co(1) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(6) atoms to form CoO6 octahedra that share corners with two equivalent S(1)O4 tetrahedra. N(1) is bonded in a bent 120 degrees geometry to one O(5) and one O(7) atom. S(1) is bonded to one O(1), one O(3), one O(4), and one O(7) atom to form SO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra. The corner-sharing octahedral tilt angles are 54°. There are seven inequivalent O sites. In the first O site, O(7) is bonded in a distorted bent 120 degrees geometry to one N(1) and one S(1) atom. In the second O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(2) is bonded in a single-bond geometry to one Co(1) atom. In the fourth O site, O(3) is bonded in a bent 120 degrees geometry to one Co(1) and one S(1) atom. In the fifth O site, O(4) is bonded in a single-bond geometry to one S(1) atom. In the sixth O site, O(5) is bonded in a single-bond geometry to one N(1) atom. In the seventh O site, O(6) is bonded in a single-bond geometry to one Co(1) atom. is represented by the CIF card [CIF]
data_CoS2(NO7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.435
_cell_length_b   9.568
_cell_length_c   12.894
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   131.276
_symmetry_Int_Tables_number   1
_cell_volume   596.612
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.500  0.000  0.000  1.0
  Co  Co1  1  0.500  0.500  0.500  1.0
  S  S2  1  0.976  0.665  0.882  1.0
  S  S3  1  0.024  0.335  0.118  1.0
  S  S4  1  0.024  0.835  0.382  1.0
  S  S5  1  0.976  0.165  0.618  1.0
  N  N6  1  0.836  0.631  0.169  1.0
  N  N7  1  0.164  0.369  0.831  1.0
  N  N8  1  0.164  0.869  0.669  1.0
  N  N9  1  0.836  0.131  0.331  1.0
  O  O10  1  0.863  0.740  0.933  1.0
  O  O11  1  0.137  0.260  0.067  1.0
  O  O12  1  0.137  0.760  0.433  1.0
  O  O13  1  0.863  0.240  0.567  1.0
  O  O14  1  0.798  0.039  0.957  1.0
  O  O15  1  0.202  0.961  0.043  1.0
  O  O16  1  0.202  0.461  0.457  1.0
  O  O17  1  0.798  0.539  0.543  1.0
  O  O18  1  0.292  0.797  0.900  1.0
  O  O19  1  0.708  0.203  0.100  1.0
  O  O20  1  0.708  0.703  0.400  1.0
  O  O21  1  0.292  0.297  0.600  1.0
  O  O22  1  0.850  0.978  0.588  1.0
  O  O23  1  0.150  0.022  0.412  1.0
  O  O24  1  0.150  0.522  0.088  1.0
  O  O25  1  0.850  0.478  0.912  1.0
  O  O26  1  0.340  0.509  0.796  1.0
  O  O27  1  0.660  0.491  0.204  1.0
  O  O28  1  0.660  0.991  0.296  1.0
  O  O29  1  0.340  0.009  0.704  1.0
  O  O30  1  0.467  0.622  0.592  1.0
  O  O31  1  0.533  0.378  0.408  1.0
  O  O32  1  0.533  0.878  0.092  1.0
  O  O33  1  0.467  0.122  0.908  1.0
  O  O34  1  0.944  0.661  0.764  1.0
  O  O35  1  0.056  0.339  0.236  1.0
  O  O36  1  0.056  0.839  0.264  1.0
  O  O37  1  0.944  0.161  0.736  1.0
[/CIF]
.