The structure described by In(CoN)2 crystallizes in the monoclinic C2/m space group. Co(1) is bonded to one In(1) and four equivalent N(1) atoms to form distorted CoInN4 tetrahedra that share corners with six equivalent In(1)In6Co2 hexagonal bipyramids, corners with seven equivalent Co(1)InN4 tetrahedra, and edges with three equivalent Co(1)InN4 tetrahedra. In(1) is bonded to two equivalent Co(1) and six equivalent In(1) atoms to form distorted InIn6Co2 hexagonal bipyramids that share corners with six equivalent In(1)In6Co2 hexagonal bipyramids, corners with twelve equivalent Co(1)InN4 tetrahedra, corners with eight equivalent N(1)Co4 trigonal pyramids, and edges with twelve equivalent In(1)In6Co2 hexagonal bipyramids. N(1) is bonded to four equivalent Co(1) atoms to form distorted NCo4 trigonal pyramids that share corners with four equivalent In(1)In6Co2 hexagonal bipyramids, corners with six equivalent N(1)Co4 trigonal pyramids, and edges with three equivalent N(1)Co4 trigonal pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_In(CoN)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.151
_cell_length_b   3.161
_cell_length_c   8.317
_cell_angle_alpha   90.000
_cell_angle_beta   68.652
_cell_angle_gamma   120.106
_symmetry_Int_Tables_number   1
_cell_volume   65.013
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.000  0.000  0.500  1.0
  Co  Co1  1  0.529  0.265  0.108  1.0
  Co  Co2  1  0.471  0.735  0.892  1.0
  N  N3  1  0.865  0.432  0.845  1.0
  N  N4  1  0.135  0.568  0.155  1.0
[/CIF]
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The structure described by In(CoN)2 crystallizes in the monoclinic C2/m space group. Co(1) is bonded to one In(1) and four equivalent N(1) atoms to form distorted CoInN4 tetrahedra that share corners with six equivalent In(1)In6Co2 hexagonal bipyramids, corners with seven equivalent Co(1)InN4 tetrahedra, and edges with three equivalent Co(1)InN4 tetrahedra. In(1) is bonded to two equivalent Co(1) and six equivalent In(1) atoms to form distorted InIn6Co2 hexagonal bipyramids that share corners with six equivalent In(1)In6Co2 hexagonal bipyramids, corners with twelve equivalent Co(1)InN4 tetrahedra, corners with eight equivalent N(1)Co4 trigonal pyramids, and edges with twelve equivalent In(1)In6Co2 hexagonal bipyramids. N(1) is bonded to four equivalent Co(1) atoms to form distorted NCo4 trigonal pyramids that share corners with four equivalent In(1)In6Co2 hexagonal bipyramids, corners with six equivalent N(1)Co4 trigonal pyramids, and edges with three equivalent N(1)Co4 trigonal pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_In(CoN)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.151
_cell_length_b   3.161
_cell_length_c   8.317
_cell_angle_alpha   90.000
_cell_angle_beta   68.652
_cell_angle_gamma   120.106
_symmetry_Int_Tables_number   1
_cell_volume   65.013
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.000  0.000  0.500  1.0
  Co  Co1  1  0.529  0.265  0.108  1.0
  Co  Co2  1  0.471  0.735  0.892  1.0
  N  N3  1  0.865  0.432  0.845  1.0
  N  N4  1  0.135  0.568  0.155  1.0
[/CIF]
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