The material structure described by V5P3N crystallizes in the hexagonal P6_3/mcm space group. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 2-coordinate geometry to five equivalent P(1) and two equivalent N(1) atoms. In the second V site, V(2) is bonded in a 6-coordinate geometry to six equivalent P(1) atoms. P(1) is bonded in a 9-coordinate geometry to four equivalent V(2) and five equivalent V(1) atoms. N(1) is bonded to six equivalent V(1) atoms to form face-sharing NV6 octahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_V5P3N
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.848
_cell_length_b   6.848
_cell_length_c   5.127
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   208.250
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.769  0.769  0.250  1.0
  V  V1  1  0.769  0.000  0.750  1.0
  V  V2  1  0.000  0.231  0.250  1.0
  V  V3  1  0.000  0.769  0.750  1.0
  V  V4  1  0.231  0.231  0.750  1.0
  V  V5  1  0.231  0.000  0.250  1.0
  V  V6  1  0.333  0.667  0.500  1.0
  V  V7  1  0.667  0.333  0.000  1.0
  V  V8  1  0.667  0.333  0.500  1.0
  V  V9  1  0.333  0.667  0.000  1.0
  P  P10  1  0.000  0.595  0.250  1.0
  P  P11  1  0.000  0.405  0.750  1.0
  P  P12  1  0.595  0.595  0.750  1.0
  P  P13  1  0.595  0.000  0.250  1.0
  P  P14  1  0.405  0.405  0.250  1.0
  P  P15  1  0.405  0.000  0.750  1.0
  N  N16  1  0.000  0.000  0.000  1.0
  N  N17  1  0.000  0.000  0.500  1.0
[/CIF]
.
The material structure described by V5P3N crystallizes in the hexagonal P6_3/mcm space group. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 2-coordinate geometry to five equivalent P(1) and two equivalent N(1) atoms. In the second V site, V(2) is bonded in a 6-coordinate geometry to six equivalent P(1) atoms. P(1) is bonded in a 9-coordinate geometry to four equivalent V(2) and five equivalent V(1) atoms. N(1) is bonded to six equivalent V(1) atoms to form face-sharing NV6 octahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_V5P3N
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.848
_cell_length_b   6.848
_cell_length_c   5.127
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   208.250
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.769  0.769  0.250  1.0
  V  V1  1  0.769  0.000  0.750  1.0
  V  V2  1  0.000  0.231  0.250  1.0
  V  V3  1  0.000  0.769  0.750  1.0
  V  V4  1  0.231  0.231  0.750  1.0
  V  V5  1  0.231  0.000  0.250  1.0
  V  V6  1  0.333  0.667  0.500  1.0
  V  V7  1  0.667  0.333  0.000  1.0
  V  V8  1  0.667  0.333  0.500  1.0
  V  V9  1  0.333  0.667  0.000  1.0
  P  P10  1  0.000  0.595  0.250  1.0
  P  P11  1  0.000  0.405  0.750  1.0
  P  P12  1  0.595  0.595  0.750  1.0
  P  P13  1  0.595  0.000  0.250  1.0
  P  P14  1  0.405  0.405  0.250  1.0
  P  P15  1  0.405  0.000  0.750  1.0
  N  N16  1  0.000  0.000  0.000  1.0
  N  N17  1  0.000  0.000  0.500  1.0
[/CIF]
.