The material structure described by WIrZn2O6 crystallizes in the monoclinic P2_1/c space group. W(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form WO6 octahedra that share corners with six equivalent Ir(1)O6 octahedra and corners with eight equivalent Zn(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 42-47°. Ir(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form IrO6 octahedra that share corners with six equivalent W(1)O6 octahedra and corners with eight equivalent Zn(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 42-47°. Zn(1) is bonded to one O(2), one O(3), and two equivalent O(1) atoms to form distorted ZnO4 tetrahedra that share corners with four equivalent W(1)O6 octahedra, corners with four equivalent Ir(1)O6 octahedra, and corners with two equivalent Zn(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 65-81°. There are three inequivalent O sites. In the first O site, O(1) is bonded to one W(1), one Ir(1), and two equivalent Zn(1) atoms to form distorted corner-sharing OZn2IrW tetrahedra. In the second O site, O(2) is bonded in a trigonal planar geometry to one W(1), one Ir(1), and one Zn(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one W(1), one Ir(1), and one Zn(1) atom. is represented by the CIF card [CIF]
data_Zn2IrWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.306
_cell_length_b   5.316
_cell_length_c   9.313
_cell_angle_alpha   56.331
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   218.612
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.979  0.732  0.252  1.0
  Zn  Zn1  1  0.479  0.268  0.248  1.0
  Zn  Zn2  1  0.521  0.732  0.752  1.0
  Zn  Zn3  1  0.021  0.268  0.748  1.0
  Ir  Ir4  1  0.500  0.500  0.500  1.0
  Ir  Ir5  1  0.000  0.500  0.000  1.0
  W  W6  1  0.500  0.000  0.000  1.0
  W  W7  1  0.000  0.000  0.500  1.0
  O  O8  1  0.399  0.362  0.753  1.0
  O  O9  1  0.177  0.095  0.074  1.0
  O  O10  1  0.168  0.735  0.443  1.0
  O  O11  1  0.668  0.265  0.057  1.0
  O  O12  1  0.677  0.905  0.426  1.0
  O  O13  1  0.899  0.638  0.747  1.0
  O  O14  1  0.101  0.362  0.253  1.0
  O  O15  1  0.323  0.095  0.574  1.0
  O  O16  1  0.332  0.735  0.943  1.0
  O  O17  1  0.823  0.905  0.926  1.0
  O  O18  1  0.832  0.265  0.557  1.0
  O  O19  1  0.601  0.638  0.247  1.0
[/CIF]
.
The material structure described by WIrZn2O6 crystallizes in the monoclinic P2_1/c space group. W(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form WO6 octahedra that share corners with six equivalent Ir(1)O6 octahedra and corners with eight equivalent Zn(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 42-47°. Ir(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form IrO6 octahedra that share corners with six equivalent W(1)O6 octahedra and corners with eight equivalent Zn(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 42-47°. Zn(1) is bonded to one O(2), one O(3), and two equivalent O(1) atoms to form distorted ZnO4 tetrahedra that share corners with four equivalent W(1)O6 octahedra, corners with four equivalent Ir(1)O6 octahedra, and corners with two equivalent Zn(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 65-81°. There are three inequivalent O sites. In the first O site, O(1) is bonded to one W(1), one Ir(1), and two equivalent Zn(1) atoms to form distorted corner-sharing OZn2IrW tetrahedra. In the second O site, O(2) is bonded in a trigonal planar geometry to one W(1), one Ir(1), and one Zn(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one W(1), one Ir(1), and one Zn(1) atom. is represented by the CIF card [CIF]
data_Zn2IrWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.306
_cell_length_b   5.316
_cell_length_c   9.313
_cell_angle_alpha   56.331
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   218.612
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.979  0.732  0.252  1.0
  Zn  Zn1  1  0.479  0.268  0.248  1.0
  Zn  Zn2  1  0.521  0.732  0.752  1.0
  Zn  Zn3  1  0.021  0.268  0.748  1.0
  Ir  Ir4  1  0.500  0.500  0.500  1.0
  Ir  Ir5  1  0.000  0.500  0.000  1.0
  W  W6  1  0.500  0.000  0.000  1.0
  W  W7  1  0.000  0.000  0.500  1.0
  O  O8  1  0.399  0.362  0.753  1.0
  O  O9  1  0.177  0.095  0.074  1.0
  O  O10  1  0.168  0.735  0.443  1.0
  O  O11  1  0.668  0.265  0.057  1.0
  O  O12  1  0.677  0.905  0.426  1.0
  O  O13  1  0.899  0.638  0.747  1.0
  O  O14  1  0.101  0.362  0.253  1.0
  O  O15  1  0.323  0.095  0.574  1.0
  O  O16  1  0.332  0.735  0.943  1.0
  O  O17  1  0.823  0.905  0.926  1.0
  O  O18  1  0.832  0.265  0.557  1.0
  O  O19  1  0.601  0.638  0.247  1.0
[/CIF]
.