The crystal structure described by (Nb3O7)2O2(Cl2)6 is Indium-derived structured and crystallizes in the cubic Fm-3m space group. The structure is zero-dimensional and consists of twenty-four 7782-50-5 molecules, eight water atoms, and four Nb3O7 clusters. In each Nb3O7 cluster, Nb(1) is bonded in a 5-coordinate geometry to one O(1) and four equivalent O(3) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Nb(1) atom. In the second O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Nb(1) atoms. is represented by the CIF file [CIF]
data_Nb3(Cl3O4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.770
_cell_length_b   11.770
_cell_length_c   11.770
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   1153.000
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Nb  Nb0  1  0.863  0.137  0.137  1.0
  Nb  Nb1  1  0.863  0.863  0.137  1.0
  Nb  Nb2  1  0.137  0.863  0.137  1.0
  Nb  Nb3  1  0.137  0.137  0.863  1.0
  Nb  Nb4  1  0.863  0.137  0.863  1.0
  Nb  Nb5  1  0.137  0.863  0.863  1.0
  Cl  Cl6  1  0.584  0.000  0.416  1.0
  Cl  Cl7  1  0.000  0.584  0.416  1.0
  Cl  Cl8  1  0.000  0.000  0.416  1.0
  Cl  Cl9  1  0.000  0.416  0.000  1.0
  Cl  Cl10  1  0.000  0.416  0.584  1.0
  Cl  Cl11  1  0.584  0.416  0.000  1.0
  Cl  Cl12  1  0.416  0.000  0.584  1.0
  Cl  Cl13  1  0.416  0.000  0.000  1.0
  Cl  Cl14  1  0.416  0.584  0.000  1.0
  Cl  Cl15  1  0.000  0.584  0.000  1.0
  Cl  Cl16  1  0.584  0.000  0.000  1.0
  Cl  Cl17  1  0.000  0.000  0.584  1.0
  O  O18  1  0.759  0.241  0.241  1.0
  O  O19  1  0.759  0.759  0.241  1.0
  O  O20  1  0.241  0.759  0.241  1.0
  O  O21  1  0.241  0.241  0.759  1.0
  O  O22  1  0.759  0.241  0.759  1.0
  O  O23  1  0.241  0.759  0.759  1.0
  O  O24  1  0.750  0.750  0.750  1.0
  O  O25  1  0.250  0.250  0.250  1.0
  O  O26  1  0.921  0.921  0.238  1.0
  O  O27  1  0.921  0.238  0.921  1.0
  O  O28  1  0.238  0.921  0.921  1.0
  O  O29  1  0.921  0.921  0.921  1.0
  O  O30  1  0.079  0.079  0.762  1.0
  O  O31  1  0.079  0.762  0.079  1.0
  O  O32  1  0.762  0.079  0.079  1.0
  O  O33  1  0.079  0.079  0.079  1.0
[/CIF]
.
The crystal structure described by (Nb3O7)2O2(Cl2)6 is Indium-derived structured and crystallizes in the cubic Fm-3m space group. The structure is zero-dimensional and consists of twenty-four 7782-50-5 molecules, eight water atoms, and four Nb3O7 clusters. In each Nb3O7 cluster, Nb(1) is bonded in a 5-coordinate geometry to one O(1) and four equivalent O(3) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Nb(1) atom. In the second O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Nb(1) atoms. is represented by the CIF file [CIF]
data_Nb3(Cl3O4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.770
_cell_length_b   11.770
_cell_length_c   11.770
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   1153.000
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Nb  Nb0  1  0.863  0.137  0.137  1.0
  Nb  Nb1  1  0.863  0.863  0.137  1.0
  Nb  Nb2  1  0.137  0.863  0.137  1.0
  Nb  Nb3  1  0.137  0.137  0.863  1.0
  Nb  Nb4  1  0.863  0.137  0.863  1.0
  Nb  Nb5  1  0.137  0.863  0.863  1.0
  Cl  Cl6  1  0.584  0.000  0.416  1.0
  Cl  Cl7  1  0.000  0.584  0.416  1.0
  Cl  Cl8  1  0.000  0.000  0.416  1.0
  Cl  Cl9  1  0.000  0.416  0.000  1.0
  Cl  Cl10  1  0.000  0.416  0.584  1.0
  Cl  Cl11  1  0.584  0.416  0.000  1.0
  Cl  Cl12  1  0.416  0.000  0.584  1.0
  Cl  Cl13  1  0.416  0.000  0.000  1.0
  Cl  Cl14  1  0.416  0.584  0.000  1.0
  Cl  Cl15  1  0.000  0.584  0.000  1.0
  Cl  Cl16  1  0.584  0.000  0.000  1.0
  Cl  Cl17  1  0.000  0.000  0.584  1.0
  O  O18  1  0.759  0.241  0.241  1.0
  O  O19  1  0.759  0.759  0.241  1.0
  O  O20  1  0.241  0.759  0.241  1.0
  O  O21  1  0.241  0.241  0.759  1.0
  O  O22  1  0.759  0.241  0.759  1.0
  O  O23  1  0.241  0.759  0.759  1.0
  O  O24  1  0.750  0.750  0.750  1.0
  O  O25  1  0.250  0.250  0.250  1.0
  O  O26  1  0.921  0.921  0.238  1.0
  O  O27  1  0.921  0.238  0.921  1.0
  O  O28  1  0.238  0.921  0.921  1.0
  O  O29  1  0.921  0.921  0.921  1.0
  O  O30  1  0.079  0.079  0.762  1.0
  O  O31  1  0.079  0.762  0.079  1.0
  O  O32  1  0.762  0.079  0.079  1.0
  O  O33  1  0.079  0.079  0.079  1.0
[/CIF]
.