The material structure described by (Ag3MoO3F3)(Ag3MoO4)Cl crystallizes in the trigonal P3m1 space group. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(3) and three equivalent O(2) atoms to form MoO4 tetrahedra that share corners with six equivalent Ag(1)ClO3F2 pentagonal pyramids. In the second Mo site, Mo(2) is bonded to three equivalent O(1) and three equivalent F(1) atoms to form distorted MoO3F3 octahedra that share corners with three equivalent Ag(1)ClO3F2 pentagonal pyramids and edges with three equivalent Ag(1)ClO3F2 pentagonal pyramids. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to one O(1), two equivalent O(2), one Cl(1), and two equivalent F(1) atoms to form distorted AgClO3F2 pentagonal pyramids that share  a cornercorner with one Mo(2)O3F3 octahedra, corners with two equivalent Ag(1)ClO3F2 pentagonal pyramids, corners with two equivalent Mo(1)O4 tetrahedra,  an edgeedge with one Mo(2)O3F3 octahedra, and edges with two equivalent Ag(1)ClO3F2 pentagonal pyramids. The corner-sharing octahedral tilt angles are 46°. In the second Ag site, Ag(2) is bonded in a 5-coordinate geometry to one O(2), one O(3), two equivalent O(1), and one Cl(1) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to one Mo(2), one Ag(1), and two equivalent Ag(2) atoms. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one Mo(1), one Ag(2), and two equivalent Ag(1) atoms. In the third O site, O(3) is bonded to one Mo(1) and three equivalent Ag(2) atoms to form distorted OAg3Mo tetrahedra that share corners with three equivalent Cl(1)Ag6 octahedra. The corner-sharing octahedral tilt angles are 60°. Cl(1) is bonded to three equivalent Ag(1) and three equivalent Ag(2) atoms to form ClAg6 octahedra that share corners with three equivalent O(3)Ag3Mo tetrahedra. F(1) is bonded in a trigonal non-coplanar geometry to one Mo(2) and two equivalent Ag(1) atoms. is represented by the CIF file [CIF]
data_Ag6Mo2ClO7F3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.597
_cell_length_b   7.597
_cell_length_c   6.020
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   300.850
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.157  0.843  0.189  1.0
  Ag  Ag1  1  0.828  0.172  0.730  1.0
  Ag  Ag2  1  0.828  0.657  0.730  1.0
  Ag  Ag3  1  0.157  0.314  0.189  1.0
  Ag  Ag4  1  0.686  0.843  0.189  1.0
  Ag  Ag5  1  0.343  0.172  0.730  1.0
  Mo  Mo6  1  0.667  0.333  0.238  1.0
  Mo  Mo7  1  0.333  0.667  0.685  1.0
  Cl  Cl8  1  0.000  0.000  0.492  1.0
  O  O9  1  0.210  0.790  0.818  1.0
  O  O10  1  0.794  0.206  0.124  1.0
  O  O11  1  0.580  0.790  0.818  1.0
  O  O12  1  0.667  0.333  0.543  1.0
  O  O13  1  0.413  0.206  0.124  1.0
  O  O14  1  0.210  0.420  0.818  1.0
  O  O15  1  0.794  0.587  0.124  1.0
  F  F16  1  0.102  0.551  0.440  1.0
  F  F17  1  0.449  0.551  0.440  1.0
  F  F18  1  0.449  0.898  0.440  1.0
[/CIF]
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The material structure described by (Ag3MoO3F3)(Ag3MoO4)Cl crystallizes in the trigonal P3m1 space group. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(3) and three equivalent O(2) atoms to form MoO4 tetrahedra that share corners with six equivalent Ag(1)ClO3F2 pentagonal pyramids. In the second Mo site, Mo(2) is bonded to three equivalent O(1) and three equivalent F(1) atoms to form distorted MoO3F3 octahedra that share corners with three equivalent Ag(1)ClO3F2 pentagonal pyramids and edges with three equivalent Ag(1)ClO3F2 pentagonal pyramids. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to one O(1), two equivalent O(2), one Cl(1), and two equivalent F(1) atoms to form distorted AgClO3F2 pentagonal pyramids that share  a cornercorner with one Mo(2)O3F3 octahedra, corners with two equivalent Ag(1)ClO3F2 pentagonal pyramids, corners with two equivalent Mo(1)O4 tetrahedra,  an edgeedge with one Mo(2)O3F3 octahedra, and edges with two equivalent Ag(1)ClO3F2 pentagonal pyramids. The corner-sharing octahedral tilt angles are 46°. In the second Ag site, Ag(2) is bonded in a 5-coordinate geometry to one O(2), one O(3), two equivalent O(1), and one Cl(1) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to one Mo(2), one Ag(1), and two equivalent Ag(2) atoms. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one Mo(1), one Ag(2), and two equivalent Ag(1) atoms. In the third O site, O(3) is bonded to one Mo(1) and three equivalent Ag(2) atoms to form distorted OAg3Mo tetrahedra that share corners with three equivalent Cl(1)Ag6 octahedra. The corner-sharing octahedral tilt angles are 60°. Cl(1) is bonded to three equivalent Ag(1) and three equivalent Ag(2) atoms to form ClAg6 octahedra that share corners with three equivalent O(3)Ag3Mo tetrahedra. F(1) is bonded in a trigonal non-coplanar geometry to one Mo(2) and two equivalent Ag(1) atoms. is represented by the CIF file [CIF]
data_Ag6Mo2ClO7F3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.597
_cell_length_b   7.597
_cell_length_c   6.020
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   300.850
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.157  0.843  0.189  1.0
  Ag  Ag1  1  0.828  0.172  0.730  1.0
  Ag  Ag2  1  0.828  0.657  0.730  1.0
  Ag  Ag3  1  0.157  0.314  0.189  1.0
  Ag  Ag4  1  0.686  0.843  0.189  1.0
  Ag  Ag5  1  0.343  0.172  0.730  1.0
  Mo  Mo6  1  0.667  0.333  0.238  1.0
  Mo  Mo7  1  0.333  0.667  0.685  1.0
  Cl  Cl8  1  0.000  0.000  0.492  1.0
  O  O9  1  0.210  0.790  0.818  1.0
  O  O10  1  0.794  0.206  0.124  1.0
  O  O11  1  0.580  0.790  0.818  1.0
  O  O12  1  0.667  0.333  0.543  1.0
  O  O13  1  0.413  0.206  0.124  1.0
  O  O14  1  0.210  0.420  0.818  1.0
  O  O15  1  0.794  0.587  0.124  1.0
  F  F16  1  0.102  0.551  0.440  1.0
  F  F17  1  0.449  0.551  0.440  1.0
  F  F18  1  0.449  0.898  0.440  1.0
[/CIF]
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