The structure described by Sc4Rh6Ge19 crystallizes in the cubic I23 space group. Sc(1) is bonded in a 10-coordinate geometry to one Ge(2), three equivalent Ge(1), and six equivalent Ge(3) atoms. Rh(1) is bonded in a 6-coordinate geometry to two equivalent Ge(1) and four equivalent Ge(3) atoms. There are three inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 4-coordinate geometry to two equivalent Sc(1), two equivalent Rh(1), and one Ge(2) atom. In the second Ge site, Ge(2) is bonded in a distorted tetrahedral geometry to four equivalent Sc(1) and six equivalent Ge(1) atoms. In the third Ge site, Ge(3) is bonded in a 4-coordinate geometry to two equivalent Sc(1) and two equivalent Rh(1) atoms. is represented by the CIF file [CIF]
data_Sc4Ge19Rh6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.840
_cell_length_b   8.840
_cell_length_c   8.840
_cell_angle_alpha   109.471
_cell_angle_beta   109.471
_cell_angle_gamma   109.471
_symmetry_Int_Tables_number   1
_cell_volume   531.704
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc0  1  0.647  0.647  0.647  1.0
  Sc  Sc1  1  0.353  0.000  0.000  1.0
  Sc  Sc2  1  0.000  0.353  0.000  1.0
  Sc  Sc3  1  0.000  0.000  0.353  1.0
  Ge  Ge4  1  0.700  0.700  0.000  1.0
  Ge  Ge5  1  0.300  0.300  0.000  1.0
  Ge  Ge6  1  0.700  0.000  0.700  1.0
  Ge  Ge7  1  0.300  0.000  0.300  1.0
  Ge  Ge8  1  0.000  0.700  0.700  1.0
  Ge  Ge9  1  0.000  0.300  0.300  1.0
  Ge  Ge10  1  0.000  0.000  0.000  1.0
  Ge  Ge11  1  0.332  0.554  0.334  1.0
  Ge  Ge12  1  0.668  0.002  0.222  1.0
  Ge  Ge13  1  0.780  0.446  0.778  1.0
  Ge  Ge14  1  0.554  0.334  0.332  1.0
  Ge  Ge15  1  0.220  0.998  0.666  1.0
  Ge  Ge16  1  0.002  0.222  0.668  1.0
  Ge  Ge17  1  0.446  0.778  0.780  1.0
  Ge  Ge18  1  0.998  0.666  0.220  1.0
  Ge  Ge19  1  0.334  0.332  0.554  1.0
  Ge  Ge20  1  0.778  0.780  0.446  1.0
  Ge  Ge21  1  0.666  0.220  0.998  1.0
  Ge  Ge22  1  0.222  0.668  0.002  1.0
  Rh  Rh23  1  0.358  0.858  0.500  1.0
  Rh  Rh24  1  0.642  0.142  0.500  1.0
  Rh  Rh25  1  0.858  0.500  0.358  1.0
  Rh  Rh26  1  0.142  0.500  0.642  1.0
  Rh  Rh27  1  0.500  0.358  0.858  1.0
  Rh  Rh28  1  0.500  0.642  0.142  1.0
[/CIF]
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The structure described by Sc4Rh6Ge19 crystallizes in the cubic I23 space group. Sc(1) is bonded in a 10-coordinate geometry to one Ge(2), three equivalent Ge(1), and six equivalent Ge(3) atoms. Rh(1) is bonded in a 6-coordinate geometry to two equivalent Ge(1) and four equivalent Ge(3) atoms. There are three inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 4-coordinate geometry to two equivalent Sc(1), two equivalent Rh(1), and one Ge(2) atom. In the second Ge site, Ge(2) is bonded in a distorted tetrahedral geometry to four equivalent Sc(1) and six equivalent Ge(1) atoms. In the third Ge site, Ge(3) is bonded in a 4-coordinate geometry to two equivalent Sc(1) and two equivalent Rh(1) atoms. is represented by the CIF file [CIF]
data_Sc4Ge19Rh6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.840
_cell_length_b   8.840
_cell_length_c   8.840
_cell_angle_alpha   109.471
_cell_angle_beta   109.471
_cell_angle_gamma   109.471
_symmetry_Int_Tables_number   1
_cell_volume   531.704
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc0  1  0.647  0.647  0.647  1.0
  Sc  Sc1  1  0.353  0.000  0.000  1.0
  Sc  Sc2  1  0.000  0.353  0.000  1.0
  Sc  Sc3  1  0.000  0.000  0.353  1.0
  Ge  Ge4  1  0.700  0.700  0.000  1.0
  Ge  Ge5  1  0.300  0.300  0.000  1.0
  Ge  Ge6  1  0.700  0.000  0.700  1.0
  Ge  Ge7  1  0.300  0.000  0.300  1.0
  Ge  Ge8  1  0.000  0.700  0.700  1.0
  Ge  Ge9  1  0.000  0.300  0.300  1.0
  Ge  Ge10  1  0.000  0.000  0.000  1.0
  Ge  Ge11  1  0.332  0.554  0.334  1.0
  Ge  Ge12  1  0.668  0.002  0.222  1.0
  Ge  Ge13  1  0.780  0.446  0.778  1.0
  Ge  Ge14  1  0.554  0.334  0.332  1.0
  Ge  Ge15  1  0.220  0.998  0.666  1.0
  Ge  Ge16  1  0.002  0.222  0.668  1.0
  Ge  Ge17  1  0.446  0.778  0.780  1.0
  Ge  Ge18  1  0.998  0.666  0.220  1.0
  Ge  Ge19  1  0.334  0.332  0.554  1.0
  Ge  Ge20  1  0.778  0.780  0.446  1.0
  Ge  Ge21  1  0.666  0.220  0.998  1.0
  Ge  Ge22  1  0.222  0.668  0.002  1.0
  Rh  Rh23  1  0.358  0.858  0.500  1.0
  Rh  Rh24  1  0.642  0.142  0.500  1.0
  Rh  Rh25  1  0.858  0.500  0.358  1.0
  Rh  Rh26  1  0.142  0.500  0.642  1.0
  Rh  Rh27  1  0.500  0.358  0.858  1.0
  Rh  Rh28  1  0.500  0.642  0.142  1.0
[/CIF]
.