The structure described by K2Pt(N2O5)2 crystallizes in the triclinic P-1 space group. K(1) is bonded in a 9-coordinate geometry to one O(3), two equivalent O(1), two equivalent O(2), two equivalent O(4), and two equivalent O(5) atoms. Pt(1) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent N(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Pt(1), one O(1), and one O(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Pt(1), one O(3), and one O(4) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent K(1) and one N(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent K(1) and one N(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one K(1) and one N(2) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to two equivalent K(1) and one N(2) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to two equivalent K(1) and one O(5) atom. is represented by the CIF card [CIF]
data_K2Pt(N2O5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.838
_cell_length_b   7.099
_cell_length_c   7.285
_cell_angle_alpha   118.905
_cell_angle_beta   102.501
_cell_angle_gamma   93.829
_symmetry_Int_Tables_number   1
_cell_volume   296.127
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.887  0.822  0.160  1.0
  K  K1  1  0.113  0.178  0.840  1.0
  Pt  Pt2  1  0.500  0.500  0.500  1.0
  N  N3  1  0.315  0.200  0.376  1.0
  N  N4  1  0.685  0.800  0.624  1.0
  N  N5  1  0.755  0.372  0.543  1.0
  N  N6  1  0.245  0.628  0.457  1.0
  O  O7  1  0.225  0.090  0.176  1.0
  O  O8  1  0.775  0.910  0.824  1.0
  O  O9  1  0.286  0.130  0.498  1.0
  O  O10  1  0.714  0.870  0.502  1.0
  O  O11  1  0.804  0.238  0.380  1.0
  O  O12  1  0.196  0.762  0.620  1.0
  O  O13  1  0.859  0.430  0.733  1.0
  O  O14  1  0.141  0.570  0.267  1.0
  O  O15  1  0.548  0.457  0.048  1.0
  O  O16  1  0.452  0.543  0.952  1.0
[/CIF]
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The structure described by K2Pt(N2O5)2 crystallizes in the triclinic P-1 space group. K(1) is bonded in a 9-coordinate geometry to one O(3), two equivalent O(1), two equivalent O(2), two equivalent O(4), and two equivalent O(5) atoms. Pt(1) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent N(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Pt(1), one O(1), and one O(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Pt(1), one O(3), and one O(4) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent K(1) and one N(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent K(1) and one N(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one K(1) and one N(2) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to two equivalent K(1) and one N(2) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to two equivalent K(1) and one O(5) atom. is represented by the CIF card [CIF]
data_K2Pt(N2O5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.838
_cell_length_b   7.099
_cell_length_c   7.285
_cell_angle_alpha   118.905
_cell_angle_beta   102.501
_cell_angle_gamma   93.829
_symmetry_Int_Tables_number   1
_cell_volume   296.127
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.887  0.822  0.160  1.0
  K  K1  1  0.113  0.178  0.840  1.0
  Pt  Pt2  1  0.500  0.500  0.500  1.0
  N  N3  1  0.315  0.200  0.376  1.0
  N  N4  1  0.685  0.800  0.624  1.0
  N  N5  1  0.755  0.372  0.543  1.0
  N  N6  1  0.245  0.628  0.457  1.0
  O  O7  1  0.225  0.090  0.176  1.0
  O  O8  1  0.775  0.910  0.824  1.0
  O  O9  1  0.286  0.130  0.498  1.0
  O  O10  1  0.714  0.870  0.502  1.0
  O  O11  1  0.804  0.238  0.380  1.0
  O  O12  1  0.196  0.762  0.620  1.0
  O  O13  1  0.859  0.430  0.733  1.0
  O  O14  1  0.141  0.570  0.267  1.0
  O  O15  1  0.548  0.457  0.048  1.0
  O  O16  1  0.452  0.543  0.952  1.0
[/CIF]
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