The material described by OsN2OBrONBr is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four nitrosyl bromide molecules and four OsN2OBr clusters. In each OsN2OBr cluster, Os(1) is bonded in a tetrahedral geometry to one N(2), one N(3), one O(2), and one Br(2) atom. There are two inequivalent N sites. In the first N site, N(2) is bonded in a single-bond geometry to one Os(1) atom. In the second N site, N(3) is bonded in a single-bond geometry to one Os(1) atom. O(2) is bonded in a single-bond geometry to one Os(1) atom. Br(2) is bonded in a single-bond geometry to one Os(1) atom. is represented by the CIF card [CIF]
data_OsBr2N3O2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.762
_cell_length_b   9.168
_cell_length_c   11.583
_cell_angle_alpha   51.478
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   977.212
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Os  Os0  1  0.793  0.539  0.531  1.0
  Os  Os1  1  0.293  0.461  0.969  1.0
  Os  Os2  1  0.207  0.461  0.469  1.0
  Os  Os3  1  0.707  0.539  0.031  1.0
  Br  Br4  1  0.770  0.952  0.528  1.0
  Br  Br5  1  0.270  0.048  0.972  1.0
  Br  Br6  1  0.230  0.048  0.472  1.0
  Br  Br7  1  0.730  0.952  0.028  1.0
  Br  Br8  1  0.606  0.522  0.623  1.0
  Br  Br9  1  0.106  0.478  0.877  1.0
  Br  Br10  1  0.394  0.478  0.377  1.0
  Br  Br11  1  0.894  0.522  0.123  1.0
  N  N12  1  0.629  0.957  0.398  1.0
  N  N13  1  0.129  0.043  0.102  1.0
  N  N14  1  0.371  0.043  0.602  1.0
  N  N15  1  0.871  0.957  0.898  1.0
  N  N16  1  0.830  0.770  0.391  1.0
  N  N17  1  0.330  0.230  0.109  1.0
  N  N18  1  0.170  0.230  0.609  1.0
  N  N19  1  0.670  0.770  0.891  1.0
  N  N20  1  0.784  0.445  0.441  1.0
  N  N21  1  0.284  0.555  0.059  1.0
  N  N22  1  0.216  0.555  0.559  1.0
  N  N23  1  0.716  0.445  0.941  1.0
  O  O24  1  0.551  0.045  0.379  1.0
  O  O25  1  0.051  0.955  0.121  1.0
  O  O26  1  0.449  0.955  0.621  1.0
  O  O27  1  0.949  0.045  0.879  1.0
  O  O28  1  0.897  0.423  0.670  1.0
  O  O29  1  0.397  0.577  0.830  1.0
  O  O30  1  0.103  0.577  0.330  1.0
  O  O31  1  0.603  0.423  0.170  1.0
[/CIF]
.
The material described by OsN2OBrONBr is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four nitrosyl bromide molecules and four OsN2OBr clusters. In each OsN2OBr cluster, Os(1) is bonded in a tetrahedral geometry to one N(2), one N(3), one O(2), and one Br(2) atom. There are two inequivalent N sites. In the first N site, N(2) is bonded in a single-bond geometry to one Os(1) atom. In the second N site, N(3) is bonded in a single-bond geometry to one Os(1) atom. O(2) is bonded in a single-bond geometry to one Os(1) atom. Br(2) is bonded in a single-bond geometry to one Os(1) atom. is represented by the CIF card [CIF]
data_OsBr2N3O2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.762
_cell_length_b   9.168
_cell_length_c   11.583
_cell_angle_alpha   51.478
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   977.212
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Os  Os0  1  0.793  0.539  0.531  1.0
  Os  Os1  1  0.293  0.461  0.969  1.0
  Os  Os2  1  0.207  0.461  0.469  1.0
  Os  Os3  1  0.707  0.539  0.031  1.0
  Br  Br4  1  0.770  0.952  0.528  1.0
  Br  Br5  1  0.270  0.048  0.972  1.0
  Br  Br6  1  0.230  0.048  0.472  1.0
  Br  Br7  1  0.730  0.952  0.028  1.0
  Br  Br8  1  0.606  0.522  0.623  1.0
  Br  Br9  1  0.106  0.478  0.877  1.0
  Br  Br10  1  0.394  0.478  0.377  1.0
  Br  Br11  1  0.894  0.522  0.123  1.0
  N  N12  1  0.629  0.957  0.398  1.0
  N  N13  1  0.129  0.043  0.102  1.0
  N  N14  1  0.371  0.043  0.602  1.0
  N  N15  1  0.871  0.957  0.898  1.0
  N  N16  1  0.830  0.770  0.391  1.0
  N  N17  1  0.330  0.230  0.109  1.0
  N  N18  1  0.170  0.230  0.609  1.0
  N  N19  1  0.670  0.770  0.891  1.0
  N  N20  1  0.784  0.445  0.441  1.0
  N  N21  1  0.284  0.555  0.059  1.0
  N  N22  1  0.216  0.555  0.559  1.0
  N  N23  1  0.716  0.445  0.941  1.0
  O  O24  1  0.551  0.045  0.379  1.0
  O  O25  1  0.051  0.955  0.121  1.0
  O  O26  1  0.449  0.955  0.621  1.0
  O  O27  1  0.949  0.045  0.879  1.0
  O  O28  1  0.897  0.423  0.670  1.0
  O  O29  1  0.397  0.577  0.830  1.0
  O  O30  1  0.103  0.577  0.330  1.0
  O  O31  1  0.603  0.423  0.170  1.0
[/CIF]
.