The material described by Rb2Ni(PS3)2 crystallizes in the monoclinic P2_1/c space group. Rb(1) is bonded in a 8-coordinate geometry to two equivalent S(2), three equivalent S(1), and three equivalent S(3) atoms. Ni(1) is bonded in an octahedral geometry to two equivalent S(1), two equivalent S(2), and two equivalent S(3) atoms. P(1) is bonded in a 3-coordinate geometry to one S(1), one S(2), and one S(3) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded to three equivalent Rb(1), one Ni(1), and one P(1) atom to form a mixture of distorted corner and edge-sharing SRb3NiP trigonal bipyramids. In the second S site, S(2) is bonded in a 4-coordinate geometry to two equivalent Rb(1), one Ni(1), and one P(1) atom. In the third S site, S(3) is bonded in a 2-coordinate geometry to three equivalent Rb(1), one Ni(1), and one P(1) atom. is represented by the CIF card [CIF]
data_Rb2Ni(PS3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.664
_cell_length_b   5.967
_cell_length_c   8.935
_cell_angle_alpha   57.932
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   572.139
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.681  0.691  0.033  1.0
  Rb  Rb1  1  0.319  0.309  0.967  1.0
  Rb  Rb2  1  0.181  0.309  0.467  1.0
  Rb  Rb3  1  0.819  0.691  0.533  1.0
  Ni  Ni4  1  0.000  0.000  0.000  1.0
  Ni  Ni5  1  0.500  0.000  0.500  1.0
  P  P6  1  0.964  0.345  0.126  1.0
  P  P7  1  0.036  0.655  0.874  1.0
  P  P8  1  0.464  0.655  0.374  1.0
  P  P9  1  0.536  0.345  0.626  1.0
  S  S10  1  0.934  0.558  0.238  1.0
  S  S11  1  0.066  0.442  0.762  1.0
  S  S12  1  0.434  0.442  0.262  1.0
  S  S13  1  0.566  0.558  0.738  1.0
  S  S14  1  0.573  0.951  0.261  1.0
  S  S15  1  0.427  0.049  0.739  1.0
  S  S16  1  0.073  0.049  0.239  1.0
  S  S17  1  0.927  0.951  0.761  1.0
  S  S18  1  0.841  0.201  0.054  1.0
  S  S19  1  0.159  0.799  0.946  1.0
  S  S20  1  0.341  0.799  0.446  1.0
  S  S21  1  0.659  0.201  0.554  1.0
[/CIF]
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The material described by Rb2Ni(PS3)2 crystallizes in the monoclinic P2_1/c space group. Rb(1) is bonded in a 8-coordinate geometry to two equivalent S(2), three equivalent S(1), and three equivalent S(3) atoms. Ni(1) is bonded in an octahedral geometry to two equivalent S(1), two equivalent S(2), and two equivalent S(3) atoms. P(1) is bonded in a 3-coordinate geometry to one S(1), one S(2), and one S(3) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded to three equivalent Rb(1), one Ni(1), and one P(1) atom to form a mixture of distorted corner and edge-sharing SRb3NiP trigonal bipyramids. In the second S site, S(2) is bonded in a 4-coordinate geometry to two equivalent Rb(1), one Ni(1), and one P(1) atom. In the third S site, S(3) is bonded in a 2-coordinate geometry to three equivalent Rb(1), one Ni(1), and one P(1) atom. is represented by the CIF card [CIF]
data_Rb2Ni(PS3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.664
_cell_length_b   5.967
_cell_length_c   8.935
_cell_angle_alpha   57.932
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   572.139
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.681  0.691  0.033  1.0
  Rb  Rb1  1  0.319  0.309  0.967  1.0
  Rb  Rb2  1  0.181  0.309  0.467  1.0
  Rb  Rb3  1  0.819  0.691  0.533  1.0
  Ni  Ni4  1  0.000  0.000  0.000  1.0
  Ni  Ni5  1  0.500  0.000  0.500  1.0
  P  P6  1  0.964  0.345  0.126  1.0
  P  P7  1  0.036  0.655  0.874  1.0
  P  P8  1  0.464  0.655  0.374  1.0
  P  P9  1  0.536  0.345  0.626  1.0
  S  S10  1  0.934  0.558  0.238  1.0
  S  S11  1  0.066  0.442  0.762  1.0
  S  S12  1  0.434  0.442  0.262  1.0
  S  S13  1  0.566  0.558  0.738  1.0
  S  S14  1  0.573  0.951  0.261  1.0
  S  S15  1  0.427  0.049  0.739  1.0
  S  S16  1  0.073  0.049  0.239  1.0
  S  S17  1  0.927  0.951  0.761  1.0
  S  S18  1  0.841  0.201  0.054  1.0
  S  S19  1  0.159  0.799  0.946  1.0
  S  S20  1  0.341  0.799  0.446  1.0
  S  S21  1  0.659  0.201  0.554  1.0
[/CIF]
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