The material structure described by La(WO3)11 crystallizes in the triclinic P-1 space group. La(1) is bonded to two equivalent O(1), two equivalent O(15), two equivalent O(17), two equivalent O(2), two equivalent O(5), and two equivalent O(9) atoms to form LaO12 cuboctahedra that share faces with two equivalent W(1)O6 octahedra, faces with two equivalent W(2)O6 octahedra, faces with two equivalent W(3)O6 octahedra, and faces with two equivalent W(6)O6 octahedra. There are six inequivalent W sites. In the first W site, W(1) is bonded to one O(15), one O(16), one O(17), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share  a cornercorner with one W(3)O6 octahedra,  a cornercorner with one W(5)O6 octahedra, corners with two equivalent W(2)O6 octahedra, corners with two equivalent W(6)O6 octahedra, and  a faceface with one La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 2-8°. In the second W site, W(2) is bonded to one O(15), one O(2), one O(6), one O(7), one O(8), and one O(9) atom to form WO6 octahedra that share  a cornercorner with one W(3)O6 octahedra,  a cornercorner with one W(6)O6 octahedra, corners with two equivalent W(1)O6 octahedra, corners with two equivalent W(4)O6 octahedra, and  a faceface with one La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 1-7°. In the third W site, W(3) is bonded to one O(1), one O(10), one O(11), one O(12), one O(5), and one O(9) atom to form WO6 octahedra that share  a cornercorner with one W(1)O6 octahedra,  a cornercorner with one W(2)O6 octahedra,  a cornercorner with one W(3)O6 octahedra,  a cornercorner with one W(4)O6 octahedra,  a cornercorner with one W(5)O6 octahedra,  a cornercorner with one W(6)O6 octahedra, and  a faceface with one La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-8°. In the fourth W site, W(4) is bonded to one O(12), one O(13), one O(14), one O(3), one O(7), and one O(8) atom to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the fifth W site, W(5) is bonded to two equivalent O(10), two equivalent O(14), and two equivalent O(4) atoms to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the sixth W site, W(6) is bonded to one O(1), one O(16), one O(17), one O(18), one O(2), and one O(3) atom to form WO6 octahedra that share  a cornercorner with one W(2)O6 octahedra,  a cornercorner with one W(3)O6 octahedra,  a cornercorner with one W(4)O6 octahedra,  a cornercorner with one W(6)O6 octahedra, corners with two equivalent W(1)O6 octahedra, and  a faceface with one La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-7°. There are eighteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one La(1), one W(3), and one W(6) atom. In the second O site, O(2) is bonded in a distorted T-shaped geometry to one La(1), one W(2), and one W(6) atom. In the third O site, O(3) is bonded in a linear geometry to one W(4) and one W(6) atom. In the fourth O site, O(4) is bonded in a linear geometry to one W(1) and one W(5) atom. In the fifth O site, O(5) is bonded in a distorted T-shaped geometry to one La(1), one W(1), and one W(3) atom. In the sixth O site, O(6) is bonded in a linear geometry to one W(1) and one W(2) atom. In the seventh O site, O(7) is bonded in a linear geometry to one W(2) and one W(4) atom. In the eighth O site, O(8) is bonded in a linear geometry to one W(2) and one W(4) atom. In the ninth O site, O(9) is bonded in a distorted T-shaped geometry to one La(1), one W(2), and one W(3) atom. In the tenth O site, O(10) is bonded in a linear geometry to one W(3) and one W(5) atom. In the eleventh O site, O(11) is bonded in a linear geometry to two equivalent W(3) atoms. In the twelfth O site, O(12) is bonded in a linear geometry to one W(3) and one W(4) atom. In the thirteenth O site, O(13) is bonded in a linear geometry to two equivalent W(4) atoms. In the fourteenth O site, O(14) is bonded in a linear geometry to one W(4) and one W(5) atom. In the fifteenth O site, O(15) is bonded in a distorted T-shaped geometry to one La(1), one W(1), and one W(2) atom. In the sixteenth O site, O(16) is bonded in a linear geometry to one W(1) and one W(6) atom. In the seventeenth O site, O(17) is bonded in a distorted T-shaped geometry to one La(1), one W(1), and one W(6) atom. In the eighteenth O site, O(18) is bonded in a linear geometry to two equivalent W(6) atoms. is represented by the CIF card [CIF]
data_La(WO3)11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.561
_cell_length_b   8.558
_cell_length_c   9.369
_cell_angle_alpha   90.014
_cell_angle_beta   100.497
_cell_angle_gamma   113.571
_symmetry_Int_Tables_number   1
_cell_volume   616.520
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.500  0.500  0.000  1.0
  W  W1  1  0.686  0.269  0.860  1.0
  W  W2  1  0.134  0.459  0.767  1.0
  W  W3  1  0.598  0.643  0.676  1.0
  W  W4  1  0.050  0.822  0.587  1.0
  W  W5  1  0.500  0.000  0.500  1.0
  W  W6  1  0.950  0.178  0.413  1.0
  W  W7  1  0.402  0.357  0.324  1.0
  W  W8  1  0.866  0.541  0.233  1.0
  W  W9  1  0.314  0.731  0.140  1.0
  W  W10  1  0.777  0.915  0.050  1.0
  W  W11  1  0.223  0.085  0.950  1.0
  O  O12  1  0.677  0.766  0.867  1.0
  O  O13  1  0.190  0.278  0.867  1.0
  O  O14  1  0.137  0.955  0.772  1.0
  O  O15  1  0.591  0.136  0.682  1.0
  O  O16  1  0.634  0.456  0.779  1.0
  O  O17  1  0.910  0.364  0.818  1.0
  O  O18  1  0.045  0.319  0.591  1.0
  O  O19  1  0.092  0.637  0.681  1.0
  O  O20  1  0.367  0.544  0.734  1.0
  O  O21  1  0.546  0.818  0.591  1.0
  O  O22  1  0.500  0.500  0.500  1.0
  O  O23  1  0.820  0.728  0.636  1.0
  O  O24  1  0.955  0.681  0.409  1.0
  O  O25  1  0.000  0.000  0.500  1.0
  O  O26  1  0.273  0.910  0.545  1.0
  O  O27  1  0.409  0.864  0.318  1.0
  O  O28  1  0.454  0.182  0.409  1.0
  O  O29  1  0.727  0.090  0.455  1.0
  O  O30  1  0.908  0.363  0.319  1.0
  O  O31  1  0.863  0.045  0.228  1.0
  O  O32  1  0.180  0.272  0.364  1.0
  O  O33  1  0.366  0.544  0.221  1.0
  O  O34  1  0.323  0.234  0.133  1.0
  O  O35  1  0.633  0.456  0.266  1.0
  O  O36  1  0.766  0.411  0.044  1.0
  O  O37  1  0.810  0.722  0.133  1.0
  O  O38  1  0.090  0.636  0.182  1.0
  O  O39  1  0.273  0.909  0.045  1.0
  O  O40  1  0.234  0.589  0.956  1.0
  O  O41  1  0.544  0.810  0.089  1.0
  O  O42  1  0.727  0.091  0.955  1.0
  O  O43  1  0.000  0.000  0.000  1.0
  O  O44  1  0.456  0.190  0.911  1.0
[/CIF]
.
The material structure described by La(WO3)11 crystallizes in the triclinic P-1 space group. La(1) is bonded to two equivalent O(1), two equivalent O(15), two equivalent O(17), two equivalent O(2), two equivalent O(5), and two equivalent O(9) atoms to form LaO12 cuboctahedra that share faces with two equivalent W(1)O6 octahedra, faces with two equivalent W(2)O6 octahedra, faces with two equivalent W(3)O6 octahedra, and faces with two equivalent W(6)O6 octahedra. There are six inequivalent W sites. In the first W site, W(1) is bonded to one O(15), one O(16), one O(17), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share  a cornercorner with one W(3)O6 octahedra,  a cornercorner with one W(5)O6 octahedra, corners with two equivalent W(2)O6 octahedra, corners with two equivalent W(6)O6 octahedra, and  a faceface with one La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 2-8°. In the second W site, W(2) is bonded to one O(15), one O(2), one O(6), one O(7), one O(8), and one O(9) atom to form WO6 octahedra that share  a cornercorner with one W(3)O6 octahedra,  a cornercorner with one W(6)O6 octahedra, corners with two equivalent W(1)O6 octahedra, corners with two equivalent W(4)O6 octahedra, and  a faceface with one La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 1-7°. In the third W site, W(3) is bonded to one O(1), one O(10), one O(11), one O(12), one O(5), and one O(9) atom to form WO6 octahedra that share  a cornercorner with one W(1)O6 octahedra,  a cornercorner with one W(2)O6 octahedra,  a cornercorner with one W(3)O6 octahedra,  a cornercorner with one W(4)O6 octahedra,  a cornercorner with one W(5)O6 octahedra,  a cornercorner with one W(6)O6 octahedra, and  a faceface with one La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-8°. In the fourth W site, W(4) is bonded to one O(12), one O(13), one O(14), one O(3), one O(7), and one O(8) atom to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the fifth W site, W(5) is bonded to two equivalent O(10), two equivalent O(14), and two equivalent O(4) atoms to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the sixth W site, W(6) is bonded to one O(1), one O(16), one O(17), one O(18), one O(2), and one O(3) atom to form WO6 octahedra that share  a cornercorner with one W(2)O6 octahedra,  a cornercorner with one W(3)O6 octahedra,  a cornercorner with one W(4)O6 octahedra,  a cornercorner with one W(6)O6 octahedra, corners with two equivalent W(1)O6 octahedra, and  a faceface with one La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-7°. There are eighteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one La(1), one W(3), and one W(6) atom. In the second O site, O(2) is bonded in a distorted T-shaped geometry to one La(1), one W(2), and one W(6) atom. In the third O site, O(3) is bonded in a linear geometry to one W(4) and one W(6) atom. In the fourth O site, O(4) is bonded in a linear geometry to one W(1) and one W(5) atom. In the fifth O site, O(5) is bonded in a distorted T-shaped geometry to one La(1), one W(1), and one W(3) atom. In the sixth O site, O(6) is bonded in a linear geometry to one W(1) and one W(2) atom. In the seventh O site, O(7) is bonded in a linear geometry to one W(2) and one W(4) atom. In the eighth O site, O(8) is bonded in a linear geometry to one W(2) and one W(4) atom. In the ninth O site, O(9) is bonded in a distorted T-shaped geometry to one La(1), one W(2), and one W(3) atom. In the tenth O site, O(10) is bonded in a linear geometry to one W(3) and one W(5) atom. In the eleventh O site, O(11) is bonded in a linear geometry to two equivalent W(3) atoms. In the twelfth O site, O(12) is bonded in a linear geometry to one W(3) and one W(4) atom. In the thirteenth O site, O(13) is bonded in a linear geometry to two equivalent W(4) atoms. In the fourteenth O site, O(14) is bonded in a linear geometry to one W(4) and one W(5) atom. In the fifteenth O site, O(15) is bonded in a distorted T-shaped geometry to one La(1), one W(1), and one W(2) atom. In the sixteenth O site, O(16) is bonded in a linear geometry to one W(1) and one W(6) atom. In the seventeenth O site, O(17) is bonded in a distorted T-shaped geometry to one La(1), one W(1), and one W(6) atom. In the eighteenth O site, O(18) is bonded in a linear geometry to two equivalent W(6) atoms. is represented by the CIF card [CIF]
data_La(WO3)11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.561
_cell_length_b   8.558
_cell_length_c   9.369
_cell_angle_alpha   90.014
_cell_angle_beta   100.497
_cell_angle_gamma   113.571
_symmetry_Int_Tables_number   1
_cell_volume   616.520
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.500  0.500  0.000  1.0
  W  W1  1  0.686  0.269  0.860  1.0
  W  W2  1  0.134  0.459  0.767  1.0
  W  W3  1  0.598  0.643  0.676  1.0
  W  W4  1  0.050  0.822  0.587  1.0
  W  W5  1  0.500  0.000  0.500  1.0
  W  W6  1  0.950  0.178  0.413  1.0
  W  W7  1  0.402  0.357  0.324  1.0
  W  W8  1  0.866  0.541  0.233  1.0
  W  W9  1  0.314  0.731  0.140  1.0
  W  W10  1  0.777  0.915  0.050  1.0
  W  W11  1  0.223  0.085  0.950  1.0
  O  O12  1  0.677  0.766  0.867  1.0
  O  O13  1  0.190  0.278  0.867  1.0
  O  O14  1  0.137  0.955  0.772  1.0
  O  O15  1  0.591  0.136  0.682  1.0
  O  O16  1  0.634  0.456  0.779  1.0
  O  O17  1  0.910  0.364  0.818  1.0
  O  O18  1  0.045  0.319  0.591  1.0
  O  O19  1  0.092  0.637  0.681  1.0
  O  O20  1  0.367  0.544  0.734  1.0
  O  O21  1  0.546  0.818  0.591  1.0
  O  O22  1  0.500  0.500  0.500  1.0
  O  O23  1  0.820  0.728  0.636  1.0
  O  O24  1  0.955  0.681  0.409  1.0
  O  O25  1  0.000  0.000  0.500  1.0
  O  O26  1  0.273  0.910  0.545  1.0
  O  O27  1  0.409  0.864  0.318  1.0
  O  O28  1  0.454  0.182  0.409  1.0
  O  O29  1  0.727  0.090  0.455  1.0
  O  O30  1  0.908  0.363  0.319  1.0
  O  O31  1  0.863  0.045  0.228  1.0
  O  O32  1  0.180  0.272  0.364  1.0
  O  O33  1  0.366  0.544  0.221  1.0
  O  O34  1  0.323  0.234  0.133  1.0
  O  O35  1  0.633  0.456  0.266  1.0
  O  O36  1  0.766  0.411  0.044  1.0
  O  O37  1  0.810  0.722  0.133  1.0
  O  O38  1  0.090  0.636  0.182  1.0
  O  O39  1  0.273  0.909  0.045  1.0
  O  O40  1  0.234  0.589  0.956  1.0
  O  O41  1  0.544  0.810  0.089  1.0
  O  O42  1  0.727  0.091  0.955  1.0
  O  O43  1  0.000  0.000  0.000  1.0
  O  O44  1  0.456  0.190  0.911  1.0
[/CIF]
.