The compound described by N2S3S2O6Cl is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two N2S3 clusters and two S2O6Cl clusters. In each N2S3 cluster, there are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(2) and one S(3) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one S(3) and one S(5) atom. There are three inequivalent S sites. In the first S site, S(2) is bonded in a single-bond geometry to one N(1) atom. In the second S site, S(3) is bonded in a water-like geometry to one N(1) and one N(2) atom. In the third S site, S(5) is bonded in a single-bond geometry to one N(2) atom. In each S2O6Cl cluster, there are two inequivalent S sites. In the first S site, S(1) is bonded to one O(2), one O(4), one O(5), and one O(6) atom to form corner-sharing SO4 tetrahedra. In the second S site, S(4) is bonded to one O(1), one O(2), one O(3), and one Cl(1) atom to form distorted corner-sharing SClO3 tetrahedra. There are six inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(4) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one S(1) and one S(4) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(4) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one S(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one S(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one S(1) atom. Cl(1) is bonded in a single-bond geometry to one S(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_S5N2ClO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.851
_cell_length_b   7.890
_cell_length_c   10.970
_cell_angle_alpha   91.497
_cell_angle_beta   100.570
_cell_angle_gamma   113.795
_symmetry_Int_Tables_number   1
_cell_volume   530.079
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.574  0.831  0.211  1.0
  S  S1  1  0.002  0.232  0.978  1.0
  S  S2  1  0.968  0.697  0.769  1.0
  S  S3  1  0.796  0.641  0.381  1.0
  S  S4  1  0.741  0.828  0.902  1.0
  S  S5  1  0.426  0.169  0.789  1.0
  S  S6  1  0.204  0.359  0.619  1.0
  S  S7  1  0.998  0.768  0.022  1.0
  S  S8  1  0.032  0.303  0.231  1.0
  S  S9  1  0.259  0.172  0.098  1.0
  N  N10  1  0.076  0.698  0.910  1.0
  N  N11  1  0.924  0.302  0.090  1.0
  N  N12  1  0.219  0.235  0.227  1.0
  N  N13  1  0.781  0.765  0.773  1.0
  Cl  Cl14  1  0.889  0.165  0.595  1.0
  Cl  Cl15  1  0.111  0.835  0.405  1.0
  O  O16  1  0.755  0.518  0.270  1.0
  O  O17  1  0.245  0.482  0.730  1.0
  O  O18  1  0.663  0.764  0.360  1.0
  O  O19  1  0.771  0.570  0.498  1.0
  O  O20  1  0.536  0.986  0.256  1.0
  O  O21  1  0.229  0.430  0.502  1.0
  O  O22  1  0.337  0.236  0.640  1.0
  O  O23  1  0.614  0.336  0.847  1.0
  O  O24  1  0.464  0.014  0.744  1.0
  O  O25  1  0.764  0.882  0.154  1.0
  O  O26  1  0.236  0.118  0.846  1.0
  O  O27  1  0.386  0.664  0.153  1.0
[/CIF]
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The compound described by N2S3S2O6Cl is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two N2S3 clusters and two S2O6Cl clusters. In each N2S3 cluster, there are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(2) and one S(3) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one S(3) and one S(5) atom. There are three inequivalent S sites. In the first S site, S(2) is bonded in a single-bond geometry to one N(1) atom. In the second S site, S(3) is bonded in a water-like geometry to one N(1) and one N(2) atom. In the third S site, S(5) is bonded in a single-bond geometry to one N(2) atom. In each S2O6Cl cluster, there are two inequivalent S sites. In the first S site, S(1) is bonded to one O(2), one O(4), one O(5), and one O(6) atom to form corner-sharing SO4 tetrahedra. In the second S site, S(4) is bonded to one O(1), one O(2), one O(3), and one Cl(1) atom to form distorted corner-sharing SClO3 tetrahedra. There are six inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(4) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one S(1) and one S(4) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(4) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one S(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one S(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one S(1) atom. Cl(1) is bonded in a single-bond geometry to one S(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_S5N2ClO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.851
_cell_length_b   7.890
_cell_length_c   10.970
_cell_angle_alpha   91.497
_cell_angle_beta   100.570
_cell_angle_gamma   113.795
_symmetry_Int_Tables_number   1
_cell_volume   530.079
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.574  0.831  0.211  1.0
  S  S1  1  0.002  0.232  0.978  1.0
  S  S2  1  0.968  0.697  0.769  1.0
  S  S3  1  0.796  0.641  0.381  1.0
  S  S4  1  0.741  0.828  0.902  1.0
  S  S5  1  0.426  0.169  0.789  1.0
  S  S6  1  0.204  0.359  0.619  1.0
  S  S7  1  0.998  0.768  0.022  1.0
  S  S8  1  0.032  0.303  0.231  1.0
  S  S9  1  0.259  0.172  0.098  1.0
  N  N10  1  0.076  0.698  0.910  1.0
  N  N11  1  0.924  0.302  0.090  1.0
  N  N12  1  0.219  0.235  0.227  1.0
  N  N13  1  0.781  0.765  0.773  1.0
  Cl  Cl14  1  0.889  0.165  0.595  1.0
  Cl  Cl15  1  0.111  0.835  0.405  1.0
  O  O16  1  0.755  0.518  0.270  1.0
  O  O17  1  0.245  0.482  0.730  1.0
  O  O18  1  0.663  0.764  0.360  1.0
  O  O19  1  0.771  0.570  0.498  1.0
  O  O20  1  0.536  0.986  0.256  1.0
  O  O21  1  0.229  0.430  0.502  1.0
  O  O22  1  0.337  0.236  0.640  1.0
  O  O23  1  0.614  0.336  0.847  1.0
  O  O24  1  0.464  0.014  0.744  1.0
  O  O25  1  0.764  0.882  0.154  1.0
  O  O26  1  0.236  0.118  0.846  1.0
  O  O27  1  0.386  0.664  0.153  1.0
[/CIF]
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