The compound described by Tb2Ir3Ge5 crystallizes in the orthorhombic Ibam space group. Tb(1) is bonded in a 17-coordinate geometry to two equivalent Ir(1), five equivalent Ir(2), two equivalent Ge(1), four equivalent Ge(2), and four equivalent Ge(3) atoms. There are two inequivalent Ir sites. In the first Ir site, Ir(1) is bonded in a 6-coordinate geometry to four equivalent Tb(1), two equivalent Ge(2), and four equivalent Ge(3) atoms. In the second Ir site, Ir(2) is bonded in a 8-coordinate geometry to five equivalent Tb(1), one Ge(3), two equivalent Ge(1), and two equivalent Ge(2) atoms. There are three inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 8-coordinate geometry to four equivalent Tb(1) and four equivalent Ir(2) atoms. In the second Ge site, Ge(2) is bonded in a 9-coordinate geometry to four equivalent Tb(1), one Ir(1), two equivalent Ir(2), and two equivalent Ge(3) atoms. In the third Ge site, Ge(3) is bonded in a 9-coordinate geometry to four equivalent Tb(1), one Ir(2), two equivalent Ir(1), and two equivalent Ge(2) atoms. is represented by the CIF card [CIF]
data_Tb2Ge5Ir3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.395
_cell_length_b   8.395
_cell_length_c   8.395
_cell_angle_alpha   137.695
_cell_angle_beta   104.372
_cell_angle_gamma   90.700
_symmetry_Int_Tables_number   1
_cell_volume   367.981
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tb  Tb0  1  0.861  0.633  0.229  1.0
  Tb  Tb1  1  0.139  0.367  0.771  1.0
  Tb  Tb2  1  0.404  0.133  0.271  1.0
  Tb  Tb3  1  0.596  0.867  0.729  1.0
  Ge  Ge4  1  0.500  0.750  0.250  1.0
  Ge  Ge5  1  0.500  0.250  0.750  1.0
  Ge  Ge6  1  0.226  0.976  0.750  1.0
  Ge  Ge7  1  0.774  0.524  0.750  1.0
  Ge  Ge8  1  0.774  0.024  0.250  1.0
  Ge  Ge9  1  0.226  0.476  0.250  1.0
  Ge  Ge10  1  0.059  0.899  0.160  1.0
  Ge  Ge11  1  0.941  0.101  0.840  1.0
  Ge  Ge12  1  0.739  0.399  0.340  1.0
  Ge  Ge13  1  0.261  0.601  0.660  1.0
  Ir  Ir14  1  0.000  0.750  0.750  1.0
  Ir  Ir15  1  0.000  0.250  0.250  1.0
  Ir  Ir16  1  0.247  0.859  0.388  1.0
  Ir  Ir17  1  0.753  0.141  0.612  1.0
  Ir  Ir18  1  0.471  0.359  0.112  1.0
  Ir  Ir19  1  0.529  0.641  0.888  1.0
[/CIF]
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The compound described by Tb2Ir3Ge5 crystallizes in the orthorhombic Ibam space group. Tb(1) is bonded in a 17-coordinate geometry to two equivalent Ir(1), five equivalent Ir(2), two equivalent Ge(1), four equivalent Ge(2), and four equivalent Ge(3) atoms. There are two inequivalent Ir sites. In the first Ir site, Ir(1) is bonded in a 6-coordinate geometry to four equivalent Tb(1), two equivalent Ge(2), and four equivalent Ge(3) atoms. In the second Ir site, Ir(2) is bonded in a 8-coordinate geometry to five equivalent Tb(1), one Ge(3), two equivalent Ge(1), and two equivalent Ge(2) atoms. There are three inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 8-coordinate geometry to four equivalent Tb(1) and four equivalent Ir(2) atoms. In the second Ge site, Ge(2) is bonded in a 9-coordinate geometry to four equivalent Tb(1), one Ir(1), two equivalent Ir(2), and two equivalent Ge(3) atoms. In the third Ge site, Ge(3) is bonded in a 9-coordinate geometry to four equivalent Tb(1), one Ir(2), two equivalent Ir(1), and two equivalent Ge(2) atoms. is represented by the CIF card [CIF]
data_Tb2Ge5Ir3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.395
_cell_length_b   8.395
_cell_length_c   8.395
_cell_angle_alpha   137.695
_cell_angle_beta   104.372
_cell_angle_gamma   90.700
_symmetry_Int_Tables_number   1
_cell_volume   367.981
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tb  Tb0  1  0.861  0.633  0.229  1.0
  Tb  Tb1  1  0.139  0.367  0.771  1.0
  Tb  Tb2  1  0.404  0.133  0.271  1.0
  Tb  Tb3  1  0.596  0.867  0.729  1.0
  Ge  Ge4  1  0.500  0.750  0.250  1.0
  Ge  Ge5  1  0.500  0.250  0.750  1.0
  Ge  Ge6  1  0.226  0.976  0.750  1.0
  Ge  Ge7  1  0.774  0.524  0.750  1.0
  Ge  Ge8  1  0.774  0.024  0.250  1.0
  Ge  Ge9  1  0.226  0.476  0.250  1.0
  Ge  Ge10  1  0.059  0.899  0.160  1.0
  Ge  Ge11  1  0.941  0.101  0.840  1.0
  Ge  Ge12  1  0.739  0.399  0.340  1.0
  Ge  Ge13  1  0.261  0.601  0.660  1.0
  Ir  Ir14  1  0.000  0.750  0.750  1.0
  Ir  Ir15  1  0.000  0.250  0.250  1.0
  Ir  Ir16  1  0.247  0.859  0.388  1.0
  Ir  Ir17  1  0.753  0.141  0.612  1.0
  Ir  Ir18  1  0.471  0.359  0.112  1.0
  Ir  Ir19  1  0.529  0.641  0.888  1.0
[/CIF]
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