The structure described by TiCo(PO4)2 crystallizes in the triclinic P1 space group. There are four inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to one O(1), one O(17), one O(19), one O(25), one O(27), and one O(9) atom to form distorted TiO6 pentagonal pyramids that share corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(3)O6 octahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, corners with two equivalent P(1)O4 tetrahedra, and  an edgeedge with one P(5)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 47-49°. In the second Ti site, Ti(2) is bonded to one O(10), one O(18), one O(2), one O(20), one O(26), and one O(28) atom to form distorted TiO6 pentagonal pyramids that share corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(3)O6 octahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and  an edgeedge with one P(6)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 47-50°. In the third Ti site, Ti(3) is bonded to one O(11), one O(21), one O(23), one O(29), one O(3), and one O(31) atom to form distorted TiO6 pentagonal pyramids that share corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Co(4)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(8)O4 tetrahedra, corners with two equivalent P(3)O4 tetrahedra, and  an edgeedge with one P(7)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 47-49°. In the fourth Ti site, Ti(4) is bonded to one O(12), one O(22), one O(24), one O(30), one O(32), and one O(4) atom to form distorted TiO6 pentagonal pyramids that share corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Co(4)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra, corners with two equivalent P(4)O4 tetrahedra, and  an edgeedge with one P(8)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 47-50°. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(13), one O(17), one O(19), one O(26), one O(28), and one O(6) atom to form distorted CoO6 octahedra that share corners with two equivalent Ti(1)O6 pentagonal pyramids, corners with two equivalent Ti(2)O6 pentagonal pyramids,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra, corners with two equivalent P(6)O4 tetrahedra, and  an edgeedge with one P(1)O4 tetrahedra. In the second Co site, Co(2) is bonded to one O(15), one O(21), one O(23), one O(30), one O(32), and one O(8) atom to form distorted CoO6 octahedra that share corners with two equivalent Ti(3)O6 pentagonal pyramids, corners with two equivalent Ti(4)O6 pentagonal pyramids,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, corners with two equivalent P(8)O4 tetrahedra, and  an edgeedge with one P(3)O4 tetrahedra. In the third Co site, Co(3) is bonded to one O(14), one O(18), one O(20), one O(25), one O(27), and one O(5) atom to form distorted CoO6 octahedra that share corners with two equivalent Ti(1)O6 pentagonal pyramids, corners with two equivalent Ti(2)O6 pentagonal pyramids,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(8)O4 tetrahedra, corners with two equivalent P(5)O4 tetrahedra, and  an edgeedge with one P(2)O4 tetrahedra. In the fourth Co site, Co(4) is bonded to one O(16), one O(22), one O(24), one O(29), one O(31), and one O(7) atom to form distorted CoO6 octahedra that share corners with two equivalent Ti(3)O6 pentagonal pyramids, corners with two equivalent Ti(4)O6 pentagonal pyramids,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, corners with two equivalent P(7)O4 tetrahedra, and  an edgeedge with one P(4)O4 tetrahedra. There are eight inequivalent P sites. In the first P site, P(1) is bonded to one O(17), one O(19), one O(4), and one O(5) atom to form PO4 tetrahedra that share  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Ti(4)O6 pentagonal pyramid, corners with two equivalent Ti(1)O6 pentagonal pyramids, and  an edgeedge with one Co(1)O6 octahedra. The corner-sharing octahedral tilt angles are 53°. In the second P site, P(2) is bonded to one O(18), one O(20), one O(3), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Ti(3)O6 pentagonal pyramid, corners with two equivalent Ti(2)O6 pentagonal pyramids, and  an edgeedge with one Co(3)O6 octahedra. The corner-sharing octahedral tilt angles are 52°. In the third P site, P(3) is bonded to one O(2), one O(21), one O(23), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Ti(2)O6 pentagonal pyramid, corners with two equivalent Ti(3)O6 pentagonal pyramids, and  an edgeedge with one Co(2)O6 octahedra. The corner-sharing octahedral tilt angles are 53°. In the fourth P site, P(4) is bonded to one O(1), one O(22), one O(24), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Ti(1)O6 pentagonal pyramid, corners with two equivalent Ti(4)O6 pentagonal pyramids, and  an edgeedge with one Co(4)O6 octahedra. The corner-sharing octahedral tilt angles are 52°. In the fifth P site, P(5) is bonded to one O(10), one O(15), one O(25), and one O(27) atom to form PO4 tetrahedra that share  a cornercorner with one Co(2)O6 octahedra, corners with two equivalent Co(3)O6 octahedra,  a cornercorner with one Ti(2)O6 pentagonal pyramid, and  an edgeedge with one Ti(1)O6 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 32-61°. In the sixth P site, P(6) is bonded to one O(16), one O(26), one O(28), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Co(4)O6 octahedra, corners with two equivalent Co(1)O6 octahedra,  a cornercorner with one Ti(1)O6 pentagonal pyramid, and  an edgeedge with one Ti(2)O6 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 35-60°. In the seventh P site, P(7) is bonded to one O(12), one O(13), one O(29), and one O(31) atom to form PO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra, corners with two equivalent Co(4)O6 octahedra,  a cornercorner with one Ti(4)O6 pentagonal pyramid, and  an edgeedge with one Ti(3)O6 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 32-61°. In the eighth P site, P(8) is bonded to one O(11), one O(14), one O(30), and one O(32) atom to form PO4 tetrahedra that share  a cornercorner with one Co(3)O6 octahedra, corners with two equivalent Co(2)O6 octahedra,  a cornercorner with one Ti(3)O6 pentagonal pyramid, and  an edgeedge with one Ti(4)O6 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 35-60°. There are thirty-two inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Ti(1) and one P(4) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Ti(2) and one P(3) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Ti(3) and one P(2) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Ti(4) and one P(1) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Co(3) and one P(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Co(1) and one P(2) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Co(4) and one P(3) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Co(2) and one P(4) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one Ti(1) and one P(6) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one Ti(2) and one P(5) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to one Ti(3) and one P(8) atom. In the twelfth O site, O(12) is bonded in a bent 150 degrees geometry to one Ti(4) and one P(7) atom. In the thirteenth O site, O(13) is bonded in a bent 150 degrees geometry to one Co(1) and one P(7) atom. In the fourteenth O site, O(14) is bonded in a bent 150 degrees geometry to one Co(3) and one P(8) atom. In the fifteenth O site, O(15) is bonded in a bent 150 degrees geometry to one Co(2) and one P(5) atom. In the sixteenth O site, O(16) is bonded in a bent 150 degrees geometry to one Co(4) and one P(6) atom. In the seventeenth O site, O(17) is bonded in a 3-coordinate geometry to one Ti(1), one Co(1), and one P(1) atom. In the eighteenth O site, O(18) is bonded in a 3-coordinate geometry to one Ti(2), one Co(3), and one P(2) atom. In the nineteenth O site, O(19) is bonded in a 3-coordinate geometry to one Ti(1), one Co(1), and one P(1) atom. In the twentieth O site, O(20) is bonded in a 3-coordinate geometry to one Ti(2), one Co(3), and one P(2) atom. In the twenty-first O site, O(21) is bonded in a 3-coordinate geometry to one Ti(3), one Co(2), and one P(3) atom. In the twenty-second O site, O(22) is bonded in a 3-coordinate geometry to one Ti(4), one Co(4), and one P(4) atom. In the twenty-third O site, O(23) is bonded in a 3-coordinate geometry to one Ti(3), one Co(2), and one P(3) atom. In the twenty-fourth O site, O(24) is bonded in a 3-coordinate geometry to one Ti(4), one Co(4), and one P(4) atom. In the twenty-fifth O site, O(25) is bonded in a distorted trigonal planar geometry to one Ti(1), one Co(3), and one P(5) atom. In the twenty-sixth O site, O(26) is bonded in a distorted trigonal planar geometry to one Ti(2), one Co(1), and one P(6) atom. In the twenty-seventh O site, O(27) is bonded in a distorted trigonal planar geometry to one Ti(1), one Co(3), and one P(5) atom. In the twenty-eighth O site, O(28) is bonded in a distorted trigonal planar geometry to one Ti(2), one Co(1), and one P(6) atom. In the twenty-ninth O site, O(29) is bonded in a distorted trigonal planar geometry to one Ti(3), one Co(4), and one P(7) atom. In the thirtieth O site, O(30) is bonded in a distorted trigonal planar geometry to one Ti(4), one Co(2), and one P(8) atom. In the thirty-first O site, O(31) is bonded in a distorted trigonal planar geometry to one Ti(3), one Co(4), and one P(7) atom. In the thirty-second O site, O(32) is bonded in a distorted trigonal planar geometry to one Ti(4), one Co(2), and one P(8) atom. is represented by the CIF card [CIF]
data_TiCo(PO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.934
_cell_length_b   5.972
_cell_length_c   9.976
_cell_angle_alpha   89.987
_cell_angle_beta   90.718
_cell_angle_gamma   89.976
_symmetry_Int_Tables_number   1
_cell_volume   293.893
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.035  0.251  0.272  1.0
  Co  Co1  1  0.964  0.750  0.727  1.0
  O  O2  1  0.358  0.751  0.052  1.0
  O  O3  1  0.643  0.251  0.948  1.0
  O  O4  1  0.254  0.249  0.108  1.0
  O  O5  1  0.746  0.749  0.892  1.0
  O  O6  1  0.801  0.751  0.359  1.0
  O  O7  1  0.199  0.251  0.641  1.0
  O  O8  1  0.857  0.250  0.451  1.0
  O  O9  1  0.143  0.750  0.549  1.0
  O  O10  1  0.700  0.045  0.170  1.0
  O  O11  1  0.698  0.455  0.172  1.0
  O  O12  1  0.300  0.545  0.830  1.0
  O  O13  1  0.302  0.955  0.829  1.0
  O  O14  1  0.256  0.553  0.326  1.0
  O  O15  1  0.257  0.947  0.326  1.0
  O  O16  1  0.745  0.053  0.674  1.0
  O  O17  1  0.743  0.446  0.674  1.0
  P  P18  1  0.559  0.250  0.098  1.0
  P  P19  1  0.441  0.750  0.902  1.0
  P  P20  1  0.105  0.750  0.400  1.0
  P  P21  1  0.896  0.250  0.600  1.0
  Ti  Ti22  1  0.527  0.750  0.224  1.0
  Ti  Ti23  1  0.473  0.250  0.776  1.0
[/CIF]
.
The structure described by TiCo(PO4)2 crystallizes in the triclinic P1 space group. There are four inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to one O(1), one O(17), one O(19), one O(25), one O(27), and one O(9) atom to form distorted TiO6 pentagonal pyramids that share corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(3)O6 octahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, corners with two equivalent P(1)O4 tetrahedra, and  an edgeedge with one P(5)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 47-49°. In the second Ti site, Ti(2) is bonded to one O(10), one O(18), one O(2), one O(20), one O(26), and one O(28) atom to form distorted TiO6 pentagonal pyramids that share corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(3)O6 octahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and  an edgeedge with one P(6)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 47-50°. In the third Ti site, Ti(3) is bonded to one O(11), one O(21), one O(23), one O(29), one O(3), and one O(31) atom to form distorted TiO6 pentagonal pyramids that share corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Co(4)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(8)O4 tetrahedra, corners with two equivalent P(3)O4 tetrahedra, and  an edgeedge with one P(7)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 47-49°. In the fourth Ti site, Ti(4) is bonded to one O(12), one O(22), one O(24), one O(30), one O(32), and one O(4) atom to form distorted TiO6 pentagonal pyramids that share corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Co(4)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra, corners with two equivalent P(4)O4 tetrahedra, and  an edgeedge with one P(8)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 47-50°. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(13), one O(17), one O(19), one O(26), one O(28), and one O(6) atom to form distorted CoO6 octahedra that share corners with two equivalent Ti(1)O6 pentagonal pyramids, corners with two equivalent Ti(2)O6 pentagonal pyramids,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra, corners with two equivalent P(6)O4 tetrahedra, and  an edgeedge with one P(1)O4 tetrahedra. In the second Co site, Co(2) is bonded to one O(15), one O(21), one O(23), one O(30), one O(32), and one O(8) atom to form distorted CoO6 octahedra that share corners with two equivalent Ti(3)O6 pentagonal pyramids, corners with two equivalent Ti(4)O6 pentagonal pyramids,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, corners with two equivalent P(8)O4 tetrahedra, and  an edgeedge with one P(3)O4 tetrahedra. In the third Co site, Co(3) is bonded to one O(14), one O(18), one O(20), one O(25), one O(27), and one O(5) atom to form distorted CoO6 octahedra that share corners with two equivalent Ti(1)O6 pentagonal pyramids, corners with two equivalent Ti(2)O6 pentagonal pyramids,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(8)O4 tetrahedra, corners with two equivalent P(5)O4 tetrahedra, and  an edgeedge with one P(2)O4 tetrahedra. In the fourth Co site, Co(4) is bonded to one O(16), one O(22), one O(24), one O(29), one O(31), and one O(7) atom to form distorted CoO6 octahedra that share corners with two equivalent Ti(3)O6 pentagonal pyramids, corners with two equivalent Ti(4)O6 pentagonal pyramids,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, corners with two equivalent P(7)O4 tetrahedra, and  an edgeedge with one P(4)O4 tetrahedra. There are eight inequivalent P sites. In the first P site, P(1) is bonded to one O(17), one O(19), one O(4), and one O(5) atom to form PO4 tetrahedra that share  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Ti(4)O6 pentagonal pyramid, corners with two equivalent Ti(1)O6 pentagonal pyramids, and  an edgeedge with one Co(1)O6 octahedra. The corner-sharing octahedral tilt angles are 53°. In the second P site, P(2) is bonded to one O(18), one O(20), one O(3), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Ti(3)O6 pentagonal pyramid, corners with two equivalent Ti(2)O6 pentagonal pyramids, and  an edgeedge with one Co(3)O6 octahedra. The corner-sharing octahedral tilt angles are 52°. In the third P site, P(3) is bonded to one O(2), one O(21), one O(23), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Ti(2)O6 pentagonal pyramid, corners with two equivalent Ti(3)O6 pentagonal pyramids, and  an edgeedge with one Co(2)O6 octahedra. The corner-sharing octahedral tilt angles are 53°. In the fourth P site, P(4) is bonded to one O(1), one O(22), one O(24), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Ti(1)O6 pentagonal pyramid, corners with two equivalent Ti(4)O6 pentagonal pyramids, and  an edgeedge with one Co(4)O6 octahedra. The corner-sharing octahedral tilt angles are 52°. In the fifth P site, P(5) is bonded to one O(10), one O(15), one O(25), and one O(27) atom to form PO4 tetrahedra that share  a cornercorner with one Co(2)O6 octahedra, corners with two equivalent Co(3)O6 octahedra,  a cornercorner with one Ti(2)O6 pentagonal pyramid, and  an edgeedge with one Ti(1)O6 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 32-61°. In the sixth P site, P(6) is bonded to one O(16), one O(26), one O(28), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Co(4)O6 octahedra, corners with two equivalent Co(1)O6 octahedra,  a cornercorner with one Ti(1)O6 pentagonal pyramid, and  an edgeedge with one Ti(2)O6 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 35-60°. In the seventh P site, P(7) is bonded to one O(12), one O(13), one O(29), and one O(31) atom to form PO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra, corners with two equivalent Co(4)O6 octahedra,  a cornercorner with one Ti(4)O6 pentagonal pyramid, and  an edgeedge with one Ti(3)O6 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 32-61°. In the eighth P site, P(8) is bonded to one O(11), one O(14), one O(30), and one O(32) atom to form PO4 tetrahedra that share  a cornercorner with one Co(3)O6 octahedra, corners with two equivalent Co(2)O6 octahedra,  a cornercorner with one Ti(3)O6 pentagonal pyramid, and  an edgeedge with one Ti(4)O6 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 35-60°. There are thirty-two inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Ti(1) and one P(4) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Ti(2) and one P(3) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Ti(3) and one P(2) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Ti(4) and one P(1) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Co(3) and one P(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Co(1) and one P(2) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Co(4) and one P(3) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Co(2) and one P(4) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one Ti(1) and one P(6) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one Ti(2) and one P(5) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to one Ti(3) and one P(8) atom. In the twelfth O site, O(12) is bonded in a bent 150 degrees geometry to one Ti(4) and one P(7) atom. In the thirteenth O site, O(13) is bonded in a bent 150 degrees geometry to one Co(1) and one P(7) atom. In the fourteenth O site, O(14) is bonded in a bent 150 degrees geometry to one Co(3) and one P(8) atom. In the fifteenth O site, O(15) is bonded in a bent 150 degrees geometry to one Co(2) and one P(5) atom. In the sixteenth O site, O(16) is bonded in a bent 150 degrees geometry to one Co(4) and one P(6) atom. In the seventeenth O site, O(17) is bonded in a 3-coordinate geometry to one Ti(1), one Co(1), and one P(1) atom. In the eighteenth O site, O(18) is bonded in a 3-coordinate geometry to one Ti(2), one Co(3), and one P(2) atom. In the nineteenth O site, O(19) is bonded in a 3-coordinate geometry to one Ti(1), one Co(1), and one P(1) atom. In the twentieth O site, O(20) is bonded in a 3-coordinate geometry to one Ti(2), one Co(3), and one P(2) atom. In the twenty-first O site, O(21) is bonded in a 3-coordinate geometry to one Ti(3), one Co(2), and one P(3) atom. In the twenty-second O site, O(22) is bonded in a 3-coordinate geometry to one Ti(4), one Co(4), and one P(4) atom. In the twenty-third O site, O(23) is bonded in a 3-coordinate geometry to one Ti(3), one Co(2), and one P(3) atom. In the twenty-fourth O site, O(24) is bonded in a 3-coordinate geometry to one Ti(4), one Co(4), and one P(4) atom. In the twenty-fifth O site, O(25) is bonded in a distorted trigonal planar geometry to one Ti(1), one Co(3), and one P(5) atom. In the twenty-sixth O site, O(26) is bonded in a distorted trigonal planar geometry to one Ti(2), one Co(1), and one P(6) atom. In the twenty-seventh O site, O(27) is bonded in a distorted trigonal planar geometry to one Ti(1), one Co(3), and one P(5) atom. In the twenty-eighth O site, O(28) is bonded in a distorted trigonal planar geometry to one Ti(2), one Co(1), and one P(6) atom. In the twenty-ninth O site, O(29) is bonded in a distorted trigonal planar geometry to one Ti(3), one Co(4), and one P(7) atom. In the thirtieth O site, O(30) is bonded in a distorted trigonal planar geometry to one Ti(4), one Co(2), and one P(8) atom. In the thirty-first O site, O(31) is bonded in a distorted trigonal planar geometry to one Ti(3), one Co(4), and one P(7) atom. In the thirty-second O site, O(32) is bonded in a distorted trigonal planar geometry to one Ti(4), one Co(2), and one P(8) atom. is represented by the CIF card [CIF]
data_TiCo(PO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.934
_cell_length_b   5.972
_cell_length_c   9.976
_cell_angle_alpha   89.987
_cell_angle_beta   90.718
_cell_angle_gamma   89.976
_symmetry_Int_Tables_number   1
_cell_volume   293.893
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.035  0.251  0.272  1.0
  Co  Co1  1  0.964  0.750  0.727  1.0
  O  O2  1  0.358  0.751  0.052  1.0
  O  O3  1  0.643  0.251  0.948  1.0
  O  O4  1  0.254  0.249  0.108  1.0
  O  O5  1  0.746  0.749  0.892  1.0
  O  O6  1  0.801  0.751  0.359  1.0
  O  O7  1  0.199  0.251  0.641  1.0
  O  O8  1  0.857  0.250  0.451  1.0
  O  O9  1  0.143  0.750  0.549  1.0
  O  O10  1  0.700  0.045  0.170  1.0
  O  O11  1  0.698  0.455  0.172  1.0
  O  O12  1  0.300  0.545  0.830  1.0
  O  O13  1  0.302  0.955  0.829  1.0
  O  O14  1  0.256  0.553  0.326  1.0
  O  O15  1  0.257  0.947  0.326  1.0
  O  O16  1  0.745  0.053  0.674  1.0
  O  O17  1  0.743  0.446  0.674  1.0
  P  P18  1  0.559  0.250  0.098  1.0
  P  P19  1  0.441  0.750  0.902  1.0
  P  P20  1  0.105  0.750  0.400  1.0
  P  P21  1  0.896  0.250  0.600  1.0
  Ti  Ti22  1  0.527  0.750  0.224  1.0
  Ti  Ti23  1  0.473  0.250  0.776  1.0
[/CIF]
.