The material described by GeC4NCl3 is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four GeC4NCl3 clusters. Ge(1) is bonded in a distorted T-shaped geometry to one Cl(2) and two equivalent Cl(1) atoms. There are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to two equivalent C(3) and one N(1) atom. In the second C site, C(2) is bonded in a single-bond geometry to one N(1) atom. In the third C site, C(3) is bonded in a 3-coordinate geometry to one C(1), one C(3), and one Cl(1) atom. N(1) is bonded in a linear geometry to one C(1) and one C(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Ge(1) atom. In the second Cl site, Cl(1) is bonded in an L-shaped geometry to one Ge(1) and one C(3) atom. is represented by the CIF file [CIF]
data_GeC4NCl3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.956
_cell_length_b   8.129
_cell_length_c   15.148
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   979.638
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ge  Ge0  1  0.246  0.750  0.782  1.0
  Ge  Ge1  1  0.254  0.750  0.282  1.0
  Ge  Ge2  1  0.754  0.250  0.218  1.0
  Ge  Ge3  1  0.746  0.250  0.718  1.0
  C  C4  1  0.307  0.250  0.027  1.0
  C  C5  1  0.193  0.250  0.527  1.0
  C  C6  1  0.693  0.750  0.973  1.0
  C  C7  1  0.807  0.750  0.473  1.0
  C  C8  1  0.149  0.250  0.884  1.0
  C  C9  1  0.351  0.250  0.384  1.0
  C  C10  1  0.851  0.750  0.116  1.0
  C  C11  1  0.649  0.750  0.616  1.0
  C  C12  1  0.378  0.167  0.097  1.0
  C  C13  1  0.122  0.333  0.597  1.0
  C  C14  1  0.622  0.667  0.903  1.0
  C  C15  1  0.878  0.833  0.403  1.0
  C  C16  1  0.622  0.833  0.903  1.0
  C  C17  1  0.878  0.667  0.403  1.0
  C  C18  1  0.378  0.333  0.097  1.0
  C  C19  1  0.122  0.167  0.597  1.0
  N  N20  1  0.226  0.250  0.952  1.0
  N  N21  1  0.274  0.250  0.452  1.0
  N  N22  1  0.774  0.750  0.048  1.0
  N  N23  1  0.726  0.750  0.548  1.0
  Cl  Cl24  1  0.454  0.976  0.796  1.0
  Cl  Cl25  1  0.046  0.524  0.296  1.0
  Cl  Cl26  1  0.546  0.476  0.204  1.0
  Cl  Cl27  1  0.954  0.024  0.704  1.0
  Cl  Cl28  1  0.546  0.024  0.204  1.0
  Cl  Cl29  1  0.954  0.476  0.704  1.0
  Cl  Cl30  1  0.454  0.524  0.796  1.0
  Cl  Cl31  1  0.046  0.976  0.296  1.0
  Cl  Cl32  1  0.175  0.750  0.928  1.0
  Cl  Cl33  1  0.325  0.750  0.428  1.0
  Cl  Cl34  1  0.825  0.250  0.072  1.0
  Cl  Cl35  1  0.675  0.250  0.572  1.0
[/CIF]
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The material described by GeC4NCl3 is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four GeC4NCl3 clusters. Ge(1) is bonded in a distorted T-shaped geometry to one Cl(2) and two equivalent Cl(1) atoms. There are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to two equivalent C(3) and one N(1) atom. In the second C site, C(2) is bonded in a single-bond geometry to one N(1) atom. In the third C site, C(3) is bonded in a 3-coordinate geometry to one C(1), one C(3), and one Cl(1) atom. N(1) is bonded in a linear geometry to one C(1) and one C(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Ge(1) atom. In the second Cl site, Cl(1) is bonded in an L-shaped geometry to one Ge(1) and one C(3) atom. is represented by the CIF file [CIF]
data_GeC4NCl3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.956
_cell_length_b   8.129
_cell_length_c   15.148
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   979.638
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ge  Ge0  1  0.246  0.750  0.782  1.0
  Ge  Ge1  1  0.254  0.750  0.282  1.0
  Ge  Ge2  1  0.754  0.250  0.218  1.0
  Ge  Ge3  1  0.746  0.250  0.718  1.0
  C  C4  1  0.307  0.250  0.027  1.0
  C  C5  1  0.193  0.250  0.527  1.0
  C  C6  1  0.693  0.750  0.973  1.0
  C  C7  1  0.807  0.750  0.473  1.0
  C  C8  1  0.149  0.250  0.884  1.0
  C  C9  1  0.351  0.250  0.384  1.0
  C  C10  1  0.851  0.750  0.116  1.0
  C  C11  1  0.649  0.750  0.616  1.0
  C  C12  1  0.378  0.167  0.097  1.0
  C  C13  1  0.122  0.333  0.597  1.0
  C  C14  1  0.622  0.667  0.903  1.0
  C  C15  1  0.878  0.833  0.403  1.0
  C  C16  1  0.622  0.833  0.903  1.0
  C  C17  1  0.878  0.667  0.403  1.0
  C  C18  1  0.378  0.333  0.097  1.0
  C  C19  1  0.122  0.167  0.597  1.0
  N  N20  1  0.226  0.250  0.952  1.0
  N  N21  1  0.274  0.250  0.452  1.0
  N  N22  1  0.774  0.750  0.048  1.0
  N  N23  1  0.726  0.750  0.548  1.0
  Cl  Cl24  1  0.454  0.976  0.796  1.0
  Cl  Cl25  1  0.046  0.524  0.296  1.0
  Cl  Cl26  1  0.546  0.476  0.204  1.0
  Cl  Cl27  1  0.954  0.024  0.704  1.0
  Cl  Cl28  1  0.546  0.024  0.204  1.0
  Cl  Cl29  1  0.954  0.476  0.704  1.0
  Cl  Cl30  1  0.454  0.524  0.796  1.0
  Cl  Cl31  1  0.046  0.976  0.296  1.0
  Cl  Cl32  1  0.175  0.750  0.928  1.0
  Cl  Cl33  1  0.325  0.750  0.428  1.0
  Cl  Cl34  1  0.825  0.250  0.072  1.0
  Cl  Cl35  1  0.675  0.250  0.572  1.0
[/CIF]
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