The structure described by RbMg(O2Cl)3 crystallizes in the triclinic P1 space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 3-coordinate geometry to one O(4), one O(6), and one O(8) atom. In the second Rb site, Rb(2) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(11), one O(9), one Cl(1), and one Cl(6) atom. There are two inequivalent Mg sites. In the first Mg site, Mg(1) is bonded in a square pyramidal geometry to one O(1), one O(10), one O(12), one O(3), and one O(6) atom. In the second Mg site, Mg(2) is bonded in a trigonal bipyramidal geometry to one O(11), one O(2), one O(4), one O(5), and one O(9) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Rb(2), one Mg(1), and one Cl(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Mg(2) and one Cl(3) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Mg(1) and one Cl(6) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Rb(1), one Mg(2), and one Cl(2) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Mg(2) and one O(7) atom. In the sixth O site, O(6) is bonded in a distorted trigonal non-coplanar geometry to one Rb(1), one Mg(1), and one Cl(4) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one O(5) atom. In the eighth O site, O(8) is bonded in a water-like geometry to one Rb(1) and one Cl(4) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Rb(2), one Mg(2), and one Cl(6) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Rb(2), one Mg(1), and one Cl(5) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one Rb(2), one Mg(2), and one Cl(3) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Mg(1) and one Cl(5) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted single-bond geometry to one Rb(2) and one O(1) atom. In the second Cl site, Cl(2) is bonded in a distorted single-bond geometry to one O(4) atom. In the third Cl site, Cl(3) is bonded in a 2-coordinate geometry to one O(11) and one O(2) atom. In the fourth Cl site, Cl(4) is bonded in a bent 120 degrees geometry to one O(6) and one O(8) atom. In the fifth Cl site, Cl(5) is bonded in a distorted linear geometry to one O(10) and one O(12) atom. In the sixth Cl site, Cl(6) is bonded in a 2-coordinate geometry to one Rb(2), one O(3), and one O(9) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbMg(ClO2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.181
_cell_length_b   6.079
_cell_length_c   13.178
_cell_angle_alpha   90.714
_cell_angle_beta   89.855
_cell_angle_gamma   111.059
_symmetry_Int_Tables_number   1
_cell_volume   462.062
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.436  0.277  0.404  1.0
  Rb  Rb1  1  0.457  0.223  0.891  1.0
  Mg  Mg2  1  0.066  0.914  0.658  1.0
  Mg  Mg3  1  0.100  0.882  0.137  1.0
  Cl  Cl4  1  0.110  0.551  0.823  1.0
  Cl  Cl5  1  0.089  0.607  0.346  1.0
  Cl  Cl6  1  0.597  0.416  0.155  1.0
  Cl  Cl7  1  0.776  0.916  0.452  1.0
  Cl  Cl8  1  0.609  0.433  0.647  1.0
  Cl  Cl9  1  0.865  0.962  0.884  1.0
  O  O10  1  0.245  0.795  0.760  1.0
  O  O11  1  0.765  0.705  0.173  1.0
  O  O12  1  0.830  0.969  0.757  1.0
  O  O13  1  0.203  0.854  0.281  1.0
  O  O14  1  0.143  0.542  0.097  1.0
  O  O15  1  0.995  0.051  0.518  1.0
  O  O16  1  0.006  0.346  0.128  1.0
  O  O17  1  0.546  0.892  0.502  1.0
  O  O18  1  0.980  0.948  1.000  1.0
  O  O19  1  0.336  0.224  0.673  1.0
  O  O20  1  0.406  0.139  0.116  1.0
  O  O21  1  0.867  0.592  0.596  1.0
[/CIF]
.
The structure described by RbMg(O2Cl)3 crystallizes in the triclinic P1 space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 3-coordinate geometry to one O(4), one O(6), and one O(8) atom. In the second Rb site, Rb(2) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(11), one O(9), one Cl(1), and one Cl(6) atom. There are two inequivalent Mg sites. In the first Mg site, Mg(1) is bonded in a square pyramidal geometry to one O(1), one O(10), one O(12), one O(3), and one O(6) atom. In the second Mg site, Mg(2) is bonded in a trigonal bipyramidal geometry to one O(11), one O(2), one O(4), one O(5), and one O(9) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Rb(2), one Mg(1), and one Cl(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Mg(2) and one Cl(3) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Mg(1) and one Cl(6) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Rb(1), one Mg(2), and one Cl(2) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Mg(2) and one O(7) atom. In the sixth O site, O(6) is bonded in a distorted trigonal non-coplanar geometry to one Rb(1), one Mg(1), and one Cl(4) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one O(5) atom. In the eighth O site, O(8) is bonded in a water-like geometry to one Rb(1) and one Cl(4) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Rb(2), one Mg(2), and one Cl(6) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Rb(2), one Mg(1), and one Cl(5) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one Rb(2), one Mg(2), and one Cl(3) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Mg(1) and one Cl(5) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted single-bond geometry to one Rb(2) and one O(1) atom. In the second Cl site, Cl(2) is bonded in a distorted single-bond geometry to one O(4) atom. In the third Cl site, Cl(3) is bonded in a 2-coordinate geometry to one O(11) and one O(2) atom. In the fourth Cl site, Cl(4) is bonded in a bent 120 degrees geometry to one O(6) and one O(8) atom. In the fifth Cl site, Cl(5) is bonded in a distorted linear geometry to one O(10) and one O(12) atom. In the sixth Cl site, Cl(6) is bonded in a 2-coordinate geometry to one Rb(2), one O(3), and one O(9) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbMg(ClO2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.181
_cell_length_b   6.079
_cell_length_c   13.178
_cell_angle_alpha   90.714
_cell_angle_beta   89.855
_cell_angle_gamma   111.059
_symmetry_Int_Tables_number   1
_cell_volume   462.062
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.436  0.277  0.404  1.0
  Rb  Rb1  1  0.457  0.223  0.891  1.0
  Mg  Mg2  1  0.066  0.914  0.658  1.0
  Mg  Mg3  1  0.100  0.882  0.137  1.0
  Cl  Cl4  1  0.110  0.551  0.823  1.0
  Cl  Cl5  1  0.089  0.607  0.346  1.0
  Cl  Cl6  1  0.597  0.416  0.155  1.0
  Cl  Cl7  1  0.776  0.916  0.452  1.0
  Cl  Cl8  1  0.609  0.433  0.647  1.0
  Cl  Cl9  1  0.865  0.962  0.884  1.0
  O  O10  1  0.245  0.795  0.760  1.0
  O  O11  1  0.765  0.705  0.173  1.0
  O  O12  1  0.830  0.969  0.757  1.0
  O  O13  1  0.203  0.854  0.281  1.0
  O  O14  1  0.143  0.542  0.097  1.0
  O  O15  1  0.995  0.051  0.518  1.0
  O  O16  1  0.006  0.346  0.128  1.0
  O  O17  1  0.546  0.892  0.502  1.0
  O  O18  1  0.980  0.948  1.000  1.0
  O  O19  1  0.336  0.224  0.673  1.0
  O  O20  1  0.406  0.139  0.116  1.0
  O  O21  1  0.867  0.592  0.596  1.0
[/CIF]
.