The material structure described by Rb2PtC4(N2I)2 crystallizes in the monoclinic P2_1/c space group. Rb(1) is bonded in a 3-coordinate geometry to one N(1), two equivalent N(2), and three equivalent I(1) atoms. Pt(1) is bonded in an octahedral geometry to two equivalent C(1), two equivalent C(2), and two equivalent I(1) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one Pt(1) and one N(1) atom. In the second C site, C(2) is bonded in a distorted linear geometry to one Pt(1) and one N(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted single-bond geometry to one Rb(1) and one C(1) atom. In the second N site, N(2) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one C(2) atom. I(1) is bonded in a 4-coordinate geometry to three equivalent Rb(1) and one Pt(1) atom. is represented by the CIF card [CIF]
data_Rb2PtC4(IN2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.733
_cell_length_b   7.633
_cell_length_c   9.403
_cell_angle_alpha   72.765
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   667.185
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.783  0.524  0.617  1.0
  Rb  Rb1  1  0.283  0.476  0.883  1.0
  Rb  Rb2  1  0.217  0.476  0.383  1.0
  Rb  Rb3  1  0.717  0.524  0.117  1.0
  Pt  Pt4  1  0.000  0.000  0.000  1.0
  Pt  Pt5  1  0.500  0.000  0.500  1.0
  C  C6  1  0.032  0.195  0.102  1.0
  C  C7  1  0.532  0.805  0.398  1.0
  C  C8  1  0.968  0.805  0.898  1.0
  C  C9  1  0.468  0.195  0.602  1.0
  C  C10  1  0.961  0.811  0.197  1.0
  C  C11  1  0.461  0.189  0.303  1.0
  C  C12  1  0.039  0.189  0.803  1.0
  C  C13  1  0.539  0.811  0.697  1.0
  I  I14  1  0.273  0.911  0.029  1.0
  I  I15  1  0.773  0.089  0.471  1.0
  I  I16  1  0.727  0.089  0.971  1.0
  I  I17  1  0.227  0.911  0.529  1.0
  N  N18  1  0.053  0.312  0.156  1.0
  N  N19  1  0.553  0.688  0.344  1.0
  N  N20  1  0.947  0.688  0.844  1.0
  N  N21  1  0.447  0.312  0.656  1.0
  N  N22  1  0.937  0.697  0.308  1.0
  N  N23  1  0.437  0.303  0.192  1.0
  N  N24  1  0.063  0.303  0.692  1.0
  N  N25  1  0.563  0.697  0.808  1.0
[/CIF]
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The material structure described by Rb2PtC4(N2I)2 crystallizes in the monoclinic P2_1/c space group. Rb(1) is bonded in a 3-coordinate geometry to one N(1), two equivalent N(2), and three equivalent I(1) atoms. Pt(1) is bonded in an octahedral geometry to two equivalent C(1), two equivalent C(2), and two equivalent I(1) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one Pt(1) and one N(1) atom. In the second C site, C(2) is bonded in a distorted linear geometry to one Pt(1) and one N(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted single-bond geometry to one Rb(1) and one C(1) atom. In the second N site, N(2) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one C(2) atom. I(1) is bonded in a 4-coordinate geometry to three equivalent Rb(1) and one Pt(1) atom. is represented by the CIF card [CIF]
data_Rb2PtC4(IN2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.733
_cell_length_b   7.633
_cell_length_c   9.403
_cell_angle_alpha   72.765
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   667.185
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.783  0.524  0.617  1.0
  Rb  Rb1  1  0.283  0.476  0.883  1.0
  Rb  Rb2  1  0.217  0.476  0.383  1.0
  Rb  Rb3  1  0.717  0.524  0.117  1.0
  Pt  Pt4  1  0.000  0.000  0.000  1.0
  Pt  Pt5  1  0.500  0.000  0.500  1.0
  C  C6  1  0.032  0.195  0.102  1.0
  C  C7  1  0.532  0.805  0.398  1.0
  C  C8  1  0.968  0.805  0.898  1.0
  C  C9  1  0.468  0.195  0.602  1.0
  C  C10  1  0.961  0.811  0.197  1.0
  C  C11  1  0.461  0.189  0.303  1.0
  C  C12  1  0.039  0.189  0.803  1.0
  C  C13  1  0.539  0.811  0.697  1.0
  I  I14  1  0.273  0.911  0.029  1.0
  I  I15  1  0.773  0.089  0.471  1.0
  I  I16  1  0.727  0.089  0.971  1.0
  I  I17  1  0.227  0.911  0.529  1.0
  N  N18  1  0.053  0.312  0.156  1.0
  N  N19  1  0.553  0.688  0.344  1.0
  N  N20  1  0.947  0.688  0.844  1.0
  N  N21  1  0.447  0.312  0.656  1.0
  N  N22  1  0.937  0.697  0.308  1.0
  N  N23  1  0.437  0.303  0.192  1.0
  N  N24  1  0.063  0.303  0.692  1.0
  N  N25  1  0.563  0.697  0.808  1.0
[/CIF]
.