The crystal structure described by Cr2N2S crystallizes in the monoclinic C2/m space group. Cr(1) is bonded in a 4-coordinate geometry to four equivalent N(1) and three equivalent S(1) atoms. N(1) is bonded to four equivalent Cr(1) atoms to form NCr4 tetrahedra that share corners with six equivalent S(1)Cr6 octahedra, corners with six equivalent N(1)Cr4 tetrahedra, edges with three equivalent S(1)Cr6 octahedra, and edges with three equivalent N(1)Cr4 tetrahedra. The corner-sharing octahedral tilt angles range from 32-46°. S(1) is bonded to six equivalent Cr(1) atoms to form distorted SCr6 octahedra that share corners with twelve equivalent N(1)Cr4 tetrahedra, edges with six equivalent S(1)Cr6 octahedra, and edges with six equivalent N(1)Cr4 tetrahedra. is represented by the CIF card [CIF]
data_Cr2SN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.259
_cell_length_b   3.275
_cell_length_c   6.114
_cell_angle_alpha   90.000
_cell_angle_beta   89.930
_cell_angle_gamma   120.157
_symmetry_Int_Tables_number   1
_cell_volume   56.426
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.669  0.334  0.697  1.0
  Cr  Cr1  1  0.331  0.666  0.303  1.0
  S  S2  1  0.000  0.000  0.000  1.0
  N  N3  1  0.663  0.331  0.372  1.0
  N  N4  1  0.337  0.669  0.628  1.0
[/CIF]
.
The crystal structure described by Cr2N2S crystallizes in the monoclinic C2/m space group. Cr(1) is bonded in a 4-coordinate geometry to four equivalent N(1) and three equivalent S(1) atoms. N(1) is bonded to four equivalent Cr(1) atoms to form NCr4 tetrahedra that share corners with six equivalent S(1)Cr6 octahedra, corners with six equivalent N(1)Cr4 tetrahedra, edges with three equivalent S(1)Cr6 octahedra, and edges with three equivalent N(1)Cr4 tetrahedra. The corner-sharing octahedral tilt angles range from 32-46°. S(1) is bonded to six equivalent Cr(1) atoms to form distorted SCr6 octahedra that share corners with twelve equivalent N(1)Cr4 tetrahedra, edges with six equivalent S(1)Cr6 octahedra, and edges with six equivalent N(1)Cr4 tetrahedra. is represented by the CIF card [CIF]
data_Cr2SN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.259
_cell_length_b   3.275
_cell_length_c   6.114
_cell_angle_alpha   90.000
_cell_angle_beta   89.930
_cell_angle_gamma   120.157
_symmetry_Int_Tables_number   1
_cell_volume   56.426
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.669  0.334  0.697  1.0
  Cr  Cr1  1  0.331  0.666  0.303  1.0
  S  S2  1  0.000  0.000  0.000  1.0
  N  N3  1  0.663  0.331  0.372  1.0
  N  N4  1  0.337  0.669  0.628  1.0
[/CIF]
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