The material structure described by Li2Mn(FeO3)2 crystallizes in the triclinic P-1 space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(3), one O(5), one O(8), one O(9), and two equivalent O(2) atoms to form LiO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Fe(1)O6 octahedra,  a cornercorner with one Fe(3)O6 octahedra, corners with three equivalent Fe(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Fe(1)O6 octahedra,  an edgeedge with one Fe(2)O6 octahedra, and edges with two equivalent Fe(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-13°. In the second Li site, Li(2) is bonded to one O(3), one O(6), one O(7), one O(8), and two equivalent O(1) atoms to form LiO6 octahedra that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Fe(2)O6 octahedra, corners with two equivalent Fe(1)O6 octahedra, corners with two equivalent Fe(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Fe(1)O6 octahedra, and edges with two equivalent Fe(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-12°. In the third Li site, Li(3) is bonded to one O(5), one O(6), one O(7), one O(9), and two equivalent O(4) atoms to form LiO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Fe(1)O6 octahedra,  a cornercorner with one Fe(3)O6 octahedra, corners with three equivalent Mn(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Fe(1)O6 octahedra,  an edgeedge with one Fe(2)O6 octahedra, and edges with two equivalent Fe(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-11°. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(5) atoms to form MnO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Fe(2)O6 octahedra, and edges with two equivalent Fe(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-8°. In the second Mn site, Mn(2) is bonded to one O(1), one O(3), one O(4), one O(5), and two equivalent O(7) atoms to form MnO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra, corners with three equivalent Li(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Fe(2)O6 octahedra,  an edgeedge with one Fe(3)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, and edges with two equivalent Fe(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-11°. There are three inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to one O(1), one O(3), one O(6), one O(7), one O(8), and one O(9) atom to form FeO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra, corners with two equivalent Li(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Fe(2)O6 octahedra, and edges with two equivalent Fe(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-13°. In the second Fe site, Fe(2) is bonded to one O(1), one O(2), one O(5), one O(6), and two equivalent O(8) atoms to form FeO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra, corners with three equivalent Li(1)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Fe(2)O6 octahedra,  an edgeedge with one Fe(3)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, and edges with two equivalent Fe(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-12°. In the third Fe site, Fe(3) is bonded to one O(2), one O(3), one O(4), one O(6), and two equivalent O(9) atoms to form FeO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra, corners with two equivalent Li(2)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Fe(2)O6 octahedra,  an edgeedge with one Fe(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, and edges with two equivalent Fe(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-12°. There are nine inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Li(2), one Mn(2), one Fe(1), and one Fe(2) atom to form OLi2MnFe2 square pyramids that share  a cornercorner with one O(8)Li2Fe3 square pyramid,  a cornercorner with one O(9)Li2Fe3 square pyramid,  a cornercorner with one O(4)Li2Mn2Fe square pyramid,  a cornercorner with one O(7)Li2Mn2Fe square pyramid,  a cornercorner with one O(2)Li2MnFe2 square pyramid, corners with two equivalent O(6)Li2Fe3 square pyramids, corners with two equivalent O(3)Li2MnFe2 square pyramids,  an edgeedge with one O(6)Li2Fe3 square pyramid,  an edgeedge with one O(5)Li2Mn2Fe square pyramid,  an edgeedge with one O(1)Li2MnFe2 square pyramid,  an edgeedge with one O(3)Li2MnFe2 square pyramid, edges with two equivalent O(8)Li2Fe3 square pyramids, and edges with two equivalent O(7)Li2Mn2Fe square pyramids. In the second O site, O(2) is bonded to two equivalent Li(1), one Mn(1), one Fe(2), and one Fe(3) atom to form OLi2MnFe2 square pyramids that share  a cornercorner with one O(4)Li2Mn2Fe square pyramid,  a cornercorner with one O(5)Li2Mn2Fe square pyramid,  a cornercorner with one O(1)Li2MnFe2 square pyramid,  a cornercorner with one O(2)Li2MnFe2 square pyramid,  a cornercorner with one O(3)Li2MnFe2 square pyramid, corners with two equivalent O(8)Li2Fe3 square pyramids, corners with two equivalent O(9)Li2Fe3 square pyramids,  an edgeedge with one O(6)Li2Fe3 square pyramid,  an edgeedge with one O(8)Li2Fe3 square pyramid,  an edgeedge with one O(9)Li2Fe3 square pyramid,  an edgeedge with one O(4)Li2Mn2Fe square pyramid,  an edgeedge with one O(2)Li2MnFe2 square pyramid,  an edgeedge with one O(3)Li2MnFe2 square pyramid, and edges with two equivalent O(5)Li2Mn2Fe square pyramids. In the third O site, O(3) is bonded to one Li(1), one Li(2), one Mn(2), one Fe(1), and one Fe(3) atom to form OLi2MnFe2 square pyramids that share  a cornercorner with one O(8)Li2Fe3 square pyramid,  a cornercorner with one O(2)Li2MnFe2 square pyramid, corners with two equivalent O(9)Li2Fe3 square pyramids, corners with two equivalent O(1)Li2MnFe2 square pyramids, corners with three equivalent O(6)Li2Fe3 square pyramids,  an edgeedge with one O(8)Li2Fe3 square pyramid,  an edgeedge with one O(9)Li2Fe3 square pyramid,  an edgeedge with one O(4)Li2Mn2Fe square pyramid,  an edgeedge with one O(5)Li2Mn2Fe square pyramid,  an edgeedge with one O(1)Li2MnFe2 square pyramid,  an edgeedge with one O(2)Li2MnFe2 square pyramid, and edges with two equivalent O(7)Li2Mn2Fe square pyramids. In the fourth O site, O(4) is bonded to two equivalent Li(3), one Mn(1), one Mn(2), and one Fe(3) atom to form OLi2Mn2Fe square pyramids that share  a cornercorner with one O(6)Li2Fe3 square pyramid,  a cornercorner with one O(4)Li2Mn2Fe square pyramid,  a cornercorner with one O(5)Li2Mn2Fe square pyramid,  a cornercorner with one O(1)Li2MnFe2 square pyramid,  a cornercorner with one O(2)Li2MnFe2 square pyramid, corners with two equivalent O(9)Li2Fe3 square pyramids, corners with two equivalent O(7)Li2Mn2Fe square pyramids,  an edgeedge with one O(6)Li2Fe3 square pyramid,  an edgeedge with one O(9)Li2Fe3 square pyramid,  an edgeedge with one O(4)Li2Mn2Fe square pyramid,  an edgeedge with one O(7)Li2Mn2Fe square pyramid,  an edgeedge with one O(2)Li2MnFe2 square pyramid,  an edgeedge with one O(3)Li2MnFe2 square pyramid, and edges with two equivalent O(5)Li2Mn2Fe square pyramids. In the fifth O site, O(5) is bonded to one Li(1), one Li(3), one Mn(1), one Mn(2), and one Fe(2) atom to form OLi2Mn2Fe square pyramids that share  a cornercorner with one O(4)Li2Mn2Fe square pyramid,  a cornercorner with one O(5)Li2Mn2Fe square pyramid,  a cornercorner with one O(2)Li2MnFe2 square pyramid, corners with three equivalent O(8)Li2Fe3 square pyramids, corners with three equivalent O(7)Li2Mn2Fe square pyramids,  an edgeedge with one O(6)Li2Fe3 square pyramid,  an edgeedge with one O(9)Li2Fe3 square pyramid,  an edgeedge with one O(1)Li2MnFe2 square pyramid,  an edgeedge with one O(3)Li2MnFe2 square pyramid, edges with two equivalent O(4)Li2Mn2Fe square pyramids, and edges with two equivalent O(2)Li2MnFe2 square pyramids. In the sixth O site, O(6) is bonded to one Li(2), one Li(3), one Fe(1), one Fe(2), and one Fe(3) atom to form OLi2Fe3 square pyramids that share  a cornercorner with one O(4)Li2Mn2Fe square pyramid,  a cornercorner with one O(7)Li2Mn2Fe square pyramid, corners with two equivalent O(9)Li2Fe3 square pyramids, corners with two equivalent O(1)Li2MnFe2 square pyramids, corners with three equivalent O(3)Li2MnFe2 square pyramids,  an edgeedge with one O(9)Li2Fe3 square pyramid,  an edgeedge with one O(4)Li2Mn2Fe square pyramid,  an edgeedge with one O(5)Li2Mn2Fe square pyramid,  an edgeedge with one O(7)Li2Mn2Fe square pyramid,  an edgeedge with one O(1)Li2MnFe2 square pyramid,  an edgeedge with one O(2)Li2MnFe2 square pyramid, and edges with two equivalent O(8)Li2Fe3 square pyramids. In the seventh O site, O(7) is bonded to one Li(2), one Li(3), two equivalent Mn(2), and one Fe(1) atom to form OLi2Mn2Fe square pyramids that share  a cornercorner with one O(6)Li2Fe3 square pyramid,  a cornercorner with one O(1)Li2MnFe2 square pyramid, corners with two equivalent O(8)Li2Fe3 square pyramids, corners with two equivalent O(4)Li2Mn2Fe square pyramids, corners with three equivalent O(5)Li2Mn2Fe square pyramids,  an edgeedge with one O(6)Li2Fe3 square pyramid,  an edgeedge with one O(9)Li2Fe3 square pyramid,  an edgeedge with one O(4)Li2Mn2Fe square pyramid,  an edgeedge with one O(7)Li2Mn2Fe square pyramid, edges with two equivalent O(1)Li2MnFe2 square pyramids, and edges with two equivalent O(3)Li2MnFe2 square pyramids. In the eighth O site, O(8) is bonded to one Li(1), one Li(2), one Fe(1), and two equivalent Fe(2) atoms to form OLi2Fe3 square pyramids that share  a cornercorner with one O(1)Li2MnFe2 square pyramid,  a cornercorner with one O(3)Li2MnFe2 square pyramid, corners with two equivalent O(7)Li2Mn2Fe square pyramids, corners with two equivalent O(2)Li2MnFe2 square pyramids, corners with three equivalent O(5)Li2Mn2Fe square pyramids,  an edgeedge with one O(8)Li2Fe3 square pyramid,  an edgeedge with one O(9)Li2Fe3 square pyramid,  an edgeedge with one O(2)Li2MnFe2 square pyramid,  an edgeedge with one O(3)Li2MnFe2 square pyramid, edges with two equivalent O(6)Li2Fe3 square pyramids, and edges with two equivalent O(1)Li2MnFe2 square pyramids. In the ninth O site, O(9) is bonded to one Li(1), one Li(3), one Fe(1), and two equivalent Fe(3) atoms to form OLi2Fe3 square pyramids that share  a cornercorner with one O(1)Li2MnFe2 square pyramid, corners with two equivalent O(6)Li2Fe3 square pyramids, corners with two equivalent O(4)Li2Mn2Fe square pyramids, corners with two equivalent O(2)Li2MnFe2 square pyramids, corners with two equivalent O(3)Li2MnFe2 square pyramids,  an edgeedge with one O(6)Li2Fe3 square pyramid,  an edgeedge with one O(8)Li2Fe3 square pyramid,  an edgeedge with one O(9)Li2Fe3 square pyramid,  an edgeedge with one O(4)Li2Mn2Fe square pyramid,  an edgeedge with one O(5)Li2Mn2Fe square pyramid,  an edgeedge with one O(7)Li2Mn2Fe square pyramid,  an edgeedge with one O(2)Li2MnFe2 square pyramid, and  an edgeedge with one O(3)Li2MnFe2 square pyramid. is represented by the CIF card [CIF]
data_Li2Mn(FeO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.702
_cell_length_b   6.738
_cell_length_c   8.421
_cell_angle_alpha   71.074
_cell_angle_beta   70.742
_cell_angle_gamma   83.073
_symmetry_Int_Tables_number   1
_cell_volume   339.541
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.500  0.827  0.668  1.0
  Li  Li1  1  0.168  0.826  0.002  1.0
  Li  Li2  1  0.168  0.502  0.329  1.0
  Li  Li3  1  0.832  0.498  0.671  1.0
  Li  Li4  1  0.832  0.174  0.998  1.0
  Li  Li5  1  0.500  0.173  0.332  1.0
  Mn  Mn6  1  0.500  0.500  0.500  1.0
  Mn  Mn7  1  0.168  0.499  0.834  1.0
  Mn  Mn8  1  0.832  0.501  0.166  1.0
  Fe  Fe9  1  0.832  0.842  0.832  1.0
  Fe  Fe10  1  0.503  0.834  0.165  1.0
  Fe  Fe11  1  0.163  0.838  0.498  1.0
  Fe  Fe12  1  0.497  0.166  0.835  1.0
  Fe  Fe13  1  0.168  0.158  0.168  1.0
  Fe  Fe14  1  0.837  0.162  0.502  1.0
  O  O15  1  0.823  0.806  0.078  1.0
  O  O16  1  0.481  0.805  0.423  1.0
  O  O17  1  0.158  0.799  0.755  1.0
  O  O18  1  0.813  0.487  0.409  1.0
  O  O19  1  0.480  0.493  0.736  1.0
  O  O20  1  0.815  0.162  0.751  1.0
  O  O21  1  0.520  0.507  0.264  1.0
  O  O22  1  0.187  0.513  0.591  1.0
  O  O23  1  0.519  0.195  0.577  1.0
  O  O24  1  0.137  0.494  0.078  1.0
  O  O25  1  0.491  0.146  0.086  1.0
  O  O26  1  0.156  0.157  0.407  1.0
  O  O27  1  0.863  0.506  0.922  1.0
  O  O28  1  0.177  0.194  0.922  1.0
  O  O29  1  0.842  0.201  0.245  1.0
  O  O30  1  0.509  0.854  0.914  1.0
  O  O31  1  0.185  0.838  0.249  1.0
  O  O32  1  0.844  0.843  0.593  1.0
[/CIF]
.
The material structure described by Li2Mn(FeO3)2 crystallizes in the triclinic P-1 space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(3), one O(5), one O(8), one O(9), and two equivalent O(2) atoms to form LiO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Fe(1)O6 octahedra,  a cornercorner with one Fe(3)O6 octahedra, corners with three equivalent Fe(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Fe(1)O6 octahedra,  an edgeedge with one Fe(2)O6 octahedra, and edges with two equivalent Fe(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-13°. In the second Li site, Li(2) is bonded to one O(3), one O(6), one O(7), one O(8), and two equivalent O(1) atoms to form LiO6 octahedra that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Fe(2)O6 octahedra, corners with two equivalent Fe(1)O6 octahedra, corners with two equivalent Fe(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Fe(1)O6 octahedra, and edges with two equivalent Fe(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-12°. In the third Li site, Li(3) is bonded to one O(5), one O(6), one O(7), one O(9), and two equivalent O(4) atoms to form LiO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Fe(1)O6 octahedra,  a cornercorner with one Fe(3)O6 octahedra, corners with three equivalent Mn(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Fe(1)O6 octahedra,  an edgeedge with one Fe(2)O6 octahedra, and edges with two equivalent Fe(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-11°. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(5) atoms to form MnO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Fe(2)O6 octahedra, and edges with two equivalent Fe(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-8°. In the second Mn site, Mn(2) is bonded to one O(1), one O(3), one O(4), one O(5), and two equivalent O(7) atoms to form MnO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra, corners with three equivalent Li(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Fe(2)O6 octahedra,  an edgeedge with one Fe(3)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, and edges with two equivalent Fe(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-11°. There are three inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to one O(1), one O(3), one O(6), one O(7), one O(8), and one O(9) atom to form FeO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra, corners with two equivalent Li(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Fe(2)O6 octahedra, and edges with two equivalent Fe(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-13°. In the second Fe site, Fe(2) is bonded to one O(1), one O(2), one O(5), one O(6), and two equivalent O(8) atoms to form FeO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra, corners with three equivalent Li(1)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Fe(2)O6 octahedra,  an edgeedge with one Fe(3)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, and edges with two equivalent Fe(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-12°. In the third Fe site, Fe(3) is bonded to one O(2), one O(3), one O(4), one O(6), and two equivalent O(9) atoms to form FeO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra, corners with two equivalent Li(2)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Fe(2)O6 octahedra,  an edgeedge with one Fe(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, and edges with two equivalent Fe(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-12°. There are nine inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Li(2), one Mn(2), one Fe(1), and one Fe(2) atom to form OLi2MnFe2 square pyramids that share  a cornercorner with one O(8)Li2Fe3 square pyramid,  a cornercorner with one O(9)Li2Fe3 square pyramid,  a cornercorner with one O(4)Li2Mn2Fe square pyramid,  a cornercorner with one O(7)Li2Mn2Fe square pyramid,  a cornercorner with one O(2)Li2MnFe2 square pyramid, corners with two equivalent O(6)Li2Fe3 square pyramids, corners with two equivalent O(3)Li2MnFe2 square pyramids,  an edgeedge with one O(6)Li2Fe3 square pyramid,  an edgeedge with one O(5)Li2Mn2Fe square pyramid,  an edgeedge with one O(1)Li2MnFe2 square pyramid,  an edgeedge with one O(3)Li2MnFe2 square pyramid, edges with two equivalent O(8)Li2Fe3 square pyramids, and edges with two equivalent O(7)Li2Mn2Fe square pyramids. In the second O site, O(2) is bonded to two equivalent Li(1), one Mn(1), one Fe(2), and one Fe(3) atom to form OLi2MnFe2 square pyramids that share  a cornercorner with one O(4)Li2Mn2Fe square pyramid,  a cornercorner with one O(5)Li2Mn2Fe square pyramid,  a cornercorner with one O(1)Li2MnFe2 square pyramid,  a cornercorner with one O(2)Li2MnFe2 square pyramid,  a cornercorner with one O(3)Li2MnFe2 square pyramid, corners with two equivalent O(8)Li2Fe3 square pyramids, corners with two equivalent O(9)Li2Fe3 square pyramids,  an edgeedge with one O(6)Li2Fe3 square pyramid,  an edgeedge with one O(8)Li2Fe3 square pyramid,  an edgeedge with one O(9)Li2Fe3 square pyramid,  an edgeedge with one O(4)Li2Mn2Fe square pyramid,  an edgeedge with one O(2)Li2MnFe2 square pyramid,  an edgeedge with one O(3)Li2MnFe2 square pyramid, and edges with two equivalent O(5)Li2Mn2Fe square pyramids. In the third O site, O(3) is bonded to one Li(1), one Li(2), one Mn(2), one Fe(1), and one Fe(3) atom to form OLi2MnFe2 square pyramids that share  a cornercorner with one O(8)Li2Fe3 square pyramid,  a cornercorner with one O(2)Li2MnFe2 square pyramid, corners with two equivalent O(9)Li2Fe3 square pyramids, corners with two equivalent O(1)Li2MnFe2 square pyramids, corners with three equivalent O(6)Li2Fe3 square pyramids,  an edgeedge with one O(8)Li2Fe3 square pyramid,  an edgeedge with one O(9)Li2Fe3 square pyramid,  an edgeedge with one O(4)Li2Mn2Fe square pyramid,  an edgeedge with one O(5)Li2Mn2Fe square pyramid,  an edgeedge with one O(1)Li2MnFe2 square pyramid,  an edgeedge with one O(2)Li2MnFe2 square pyramid, and edges with two equivalent O(7)Li2Mn2Fe square pyramids. In the fourth O site, O(4) is bonded to two equivalent Li(3), one Mn(1), one Mn(2), and one Fe(3) atom to form OLi2Mn2Fe square pyramids that share  a cornercorner with one O(6)Li2Fe3 square pyramid,  a cornercorner with one O(4)Li2Mn2Fe square pyramid,  a cornercorner with one O(5)Li2Mn2Fe square pyramid,  a cornercorner with one O(1)Li2MnFe2 square pyramid,  a cornercorner with one O(2)Li2MnFe2 square pyramid, corners with two equivalent O(9)Li2Fe3 square pyramids, corners with two equivalent O(7)Li2Mn2Fe square pyramids,  an edgeedge with one O(6)Li2Fe3 square pyramid,  an edgeedge with one O(9)Li2Fe3 square pyramid,  an edgeedge with one O(4)Li2Mn2Fe square pyramid,  an edgeedge with one O(7)Li2Mn2Fe square pyramid,  an edgeedge with one O(2)Li2MnFe2 square pyramid,  an edgeedge with one O(3)Li2MnFe2 square pyramid, and edges with two equivalent O(5)Li2Mn2Fe square pyramids. In the fifth O site, O(5) is bonded to one Li(1), one Li(3), one Mn(1), one Mn(2), and one Fe(2) atom to form OLi2Mn2Fe square pyramids that share  a cornercorner with one O(4)Li2Mn2Fe square pyramid,  a cornercorner with one O(5)Li2Mn2Fe square pyramid,  a cornercorner with one O(2)Li2MnFe2 square pyramid, corners with three equivalent O(8)Li2Fe3 square pyramids, corners with three equivalent O(7)Li2Mn2Fe square pyramids,  an edgeedge with one O(6)Li2Fe3 square pyramid,  an edgeedge with one O(9)Li2Fe3 square pyramid,  an edgeedge with one O(1)Li2MnFe2 square pyramid,  an edgeedge with one O(3)Li2MnFe2 square pyramid, edges with two equivalent O(4)Li2Mn2Fe square pyramids, and edges with two equivalent O(2)Li2MnFe2 square pyramids. In the sixth O site, O(6) is bonded to one Li(2), one Li(3), one Fe(1), one Fe(2), and one Fe(3) atom to form OLi2Fe3 square pyramids that share  a cornercorner with one O(4)Li2Mn2Fe square pyramid,  a cornercorner with one O(7)Li2Mn2Fe square pyramid, corners with two equivalent O(9)Li2Fe3 square pyramids, corners with two equivalent O(1)Li2MnFe2 square pyramids, corners with three equivalent O(3)Li2MnFe2 square pyramids,  an edgeedge with one O(9)Li2Fe3 square pyramid,  an edgeedge with one O(4)Li2Mn2Fe square pyramid,  an edgeedge with one O(5)Li2Mn2Fe square pyramid,  an edgeedge with one O(7)Li2Mn2Fe square pyramid,  an edgeedge with one O(1)Li2MnFe2 square pyramid,  an edgeedge with one O(2)Li2MnFe2 square pyramid, and edges with two equivalent O(8)Li2Fe3 square pyramids. In the seventh O site, O(7) is bonded to one Li(2), one Li(3), two equivalent Mn(2), and one Fe(1) atom to form OLi2Mn2Fe square pyramids that share  a cornercorner with one O(6)Li2Fe3 square pyramid,  a cornercorner with one O(1)Li2MnFe2 square pyramid, corners with two equivalent O(8)Li2Fe3 square pyramids, corners with two equivalent O(4)Li2Mn2Fe square pyramids, corners with three equivalent O(5)Li2Mn2Fe square pyramids,  an edgeedge with one O(6)Li2Fe3 square pyramid,  an edgeedge with one O(9)Li2Fe3 square pyramid,  an edgeedge with one O(4)Li2Mn2Fe square pyramid,  an edgeedge with one O(7)Li2Mn2Fe square pyramid, edges with two equivalent O(1)Li2MnFe2 square pyramids, and edges with two equivalent O(3)Li2MnFe2 square pyramids. In the eighth O site, O(8) is bonded to one Li(1), one Li(2), one Fe(1), and two equivalent Fe(2) atoms to form OLi2Fe3 square pyramids that share  a cornercorner with one O(1)Li2MnFe2 square pyramid,  a cornercorner with one O(3)Li2MnFe2 square pyramid, corners with two equivalent O(7)Li2Mn2Fe square pyramids, corners with two equivalent O(2)Li2MnFe2 square pyramids, corners with three equivalent O(5)Li2Mn2Fe square pyramids,  an edgeedge with one O(8)Li2Fe3 square pyramid,  an edgeedge with one O(9)Li2Fe3 square pyramid,  an edgeedge with one O(2)Li2MnFe2 square pyramid,  an edgeedge with one O(3)Li2MnFe2 square pyramid, edges with two equivalent O(6)Li2Fe3 square pyramids, and edges with two equivalent O(1)Li2MnFe2 square pyramids. In the ninth O site, O(9) is bonded to one Li(1), one Li(3), one Fe(1), and two equivalent Fe(3) atoms to form OLi2Fe3 square pyramids that share  a cornercorner with one O(1)Li2MnFe2 square pyramid, corners with two equivalent O(6)Li2Fe3 square pyramids, corners with two equivalent O(4)Li2Mn2Fe square pyramids, corners with two equivalent O(2)Li2MnFe2 square pyramids, corners with two equivalent O(3)Li2MnFe2 square pyramids,  an edgeedge with one O(6)Li2Fe3 square pyramid,  an edgeedge with one O(8)Li2Fe3 square pyramid,  an edgeedge with one O(9)Li2Fe3 square pyramid,  an edgeedge with one O(4)Li2Mn2Fe square pyramid,  an edgeedge with one O(5)Li2Mn2Fe square pyramid,  an edgeedge with one O(7)Li2Mn2Fe square pyramid,  an edgeedge with one O(2)Li2MnFe2 square pyramid, and  an edgeedge with one O(3)Li2MnFe2 square pyramid. is represented by the CIF card [CIF]
data_Li2Mn(FeO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.702
_cell_length_b   6.738
_cell_length_c   8.421
_cell_angle_alpha   71.074
_cell_angle_beta   70.742
_cell_angle_gamma   83.073
_symmetry_Int_Tables_number   1
_cell_volume   339.541
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.500  0.827  0.668  1.0
  Li  Li1  1  0.168  0.826  0.002  1.0
  Li  Li2  1  0.168  0.502  0.329  1.0
  Li  Li3  1  0.832  0.498  0.671  1.0
  Li  Li4  1  0.832  0.174  0.998  1.0
  Li  Li5  1  0.500  0.173  0.332  1.0
  Mn  Mn6  1  0.500  0.500  0.500  1.0
  Mn  Mn7  1  0.168  0.499  0.834  1.0
  Mn  Mn8  1  0.832  0.501  0.166  1.0
  Fe  Fe9  1  0.832  0.842  0.832  1.0
  Fe  Fe10  1  0.503  0.834  0.165  1.0
  Fe  Fe11  1  0.163  0.838  0.498  1.0
  Fe  Fe12  1  0.497  0.166  0.835  1.0
  Fe  Fe13  1  0.168  0.158  0.168  1.0
  Fe  Fe14  1  0.837  0.162  0.502  1.0
  O  O15  1  0.823  0.806  0.078  1.0
  O  O16  1  0.481  0.805  0.423  1.0
  O  O17  1  0.158  0.799  0.755  1.0
  O  O18  1  0.813  0.487  0.409  1.0
  O  O19  1  0.480  0.493  0.736  1.0
  O  O20  1  0.815  0.162  0.751  1.0
  O  O21  1  0.520  0.507  0.264  1.0
  O  O22  1  0.187  0.513  0.591  1.0
  O  O23  1  0.519  0.195  0.577  1.0
  O  O24  1  0.137  0.494  0.078  1.0
  O  O25  1  0.491  0.146  0.086  1.0
  O  O26  1  0.156  0.157  0.407  1.0
  O  O27  1  0.863  0.506  0.922  1.0
  O  O28  1  0.177  0.194  0.922  1.0
  O  O29  1  0.842  0.201  0.245  1.0
  O  O30  1  0.509  0.854  0.914  1.0
  O  O31  1  0.185  0.838  0.249  1.0
  O  O32  1  0.844  0.843  0.593  1.0
[/CIF]
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