The crystal structure described by VO2 is Cyanogen Chloride-derived structured and crystallizes in the hexagonal P6_3/mmc space group. The structure is zero-dimensional and consists of two bis(oxidanyl)vanadium molecules. V(1) is bonded in a linear geometry to two equivalent O(1) atoms. O(1) is bonded in a single-bond geometry to one V(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_VO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.077
_cell_length_b   3.077
_cell_length_c   10.619
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   87.063
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.667  0.333  0.750  1.0
  V  V1  1  0.333  0.667  0.250  1.0
  O  O2  1  0.333  0.667  0.409  1.0
  O  O3  1  0.667  0.333  0.909  1.0
  O  O4  1  0.333  0.667  0.091  1.0
  O  O5  1  0.667  0.333  0.591  1.0
[/CIF]
.
The crystal structure described by VO2 is Cyanogen Chloride-derived structured and crystallizes in the hexagonal P6_3/mmc space group. The structure is zero-dimensional and consists of two bis(oxidanyl)vanadium molecules. V(1) is bonded in a linear geometry to two equivalent O(1) atoms. O(1) is bonded in a single-bond geometry to one V(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_VO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.077
_cell_length_b   3.077
_cell_length_c   10.619
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   87.063
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.667  0.333  0.750  1.0
  V  V1  1  0.333  0.667  0.250  1.0
  O  O2  1  0.333  0.667  0.409  1.0
  O  O3  1  0.667  0.333  0.909  1.0
  O  O4  1  0.333  0.667  0.091  1.0
  O  O5  1  0.667  0.333  0.591  1.0
[/CIF]
.