The material structure described by Ag3Co2SbO6 crystallizes in the trigonal P3_112 space group. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form CoO6 octahedra that share edges with three equivalent Co(2)O6 octahedra and edges with three equivalent Sb(1)O6 octahedra. In the second Co site, Co(2) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form CoO6 octahedra that share edges with three equivalent Co(1)O6 octahedra and edges with three equivalent Sb(1)O6 octahedra. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a linear geometry to two equivalent O(1) atoms. In the second Ag site, Ag(2) is bonded in a linear geometry to two equivalent O(2) atoms. In the third Ag site, Ag(3) is bonded in a linear geometry to two equivalent O(3) atoms. Sb(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form SbO6 octahedra that share edges with three equivalent Co(1)O6 octahedra and edges with three equivalent Co(2)O6 octahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded to one Co(1), one Co(2), one Ag(1), and one Sb(1) atom to form a mixture of distorted edge and corner-sharing OCo2AgSb tetrahedra. In the second O site, O(2) is bonded to one Co(1), one Co(2), one Ag(2), and one Sb(1) atom to form a mixture of distorted edge and corner-sharing OCo2AgSb tetrahedra. In the third O site, O(3) is bonded to one Co(1), one Co(2), one Ag(3), and one Sb(1) atom to form a mixture of distorted edge and corner-sharing OCo2AgSb tetrahedra. is represented by the CIF file [CIF]
data_Co2Ag3SbO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.446
_cell_length_b   5.446
_cell_length_c   18.973
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   487.338
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.107  0.893  0.333  1.0
  Co  Co1  1  0.107  0.215  0.667  1.0
  Co  Co2  1  0.785  0.893  0.000  1.0
  Co  Co3  1  0.774  0.226  0.333  1.0
  Co  Co4  1  0.774  0.548  0.667  1.0
  Co  Co5  1  0.452  0.226  0.000  1.0
  Ag  Ag6  1  0.446  0.223  0.500  1.0
  Ag  Ag7  1  0.777  0.223  0.833  1.0
  Ag  Ag8  1  0.777  0.554  0.167  1.0
  Ag  Ag9  1  0.117  0.558  0.500  1.0
  Ag  Ag10  1  0.442  0.558  0.833  1.0
  Ag  Ag11  1  0.442  0.883  0.167  1.0
  Ag  Ag12  1  0.763  0.882  0.500  1.0
  Ag  Ag13  1  0.118  0.882  0.833  1.0
  Ag  Ag14  1  0.118  0.237  0.167  1.0
  Sb  Sb15  1  0.440  0.560  0.333  1.0
  Sb  Sb16  1  0.440  0.879  0.667  1.0
  Sb  Sb17  1  0.121  0.560  0.000  1.0
  O  O18  1  0.761  0.560  0.279  1.0
  O  O19  1  0.440  0.201  0.612  1.0
  O  O20  1  0.799  0.239  0.945  1.0
  O  O21  1  0.761  0.201  0.721  1.0
  O  O22  1  0.440  0.239  0.388  1.0
  O  O23  1  0.799  0.560  0.055  1.0
  O  O24  1  0.437  0.877  0.278  1.0
  O  O25  1  0.123  0.560  0.611  1.0
  O  O26  1  0.440  0.563  0.945  1.0
  O  O27  1  0.437  0.560  0.722  1.0
  O  O28  1  0.123  0.563  0.389  1.0
  O  O29  1  0.440  0.877  0.055  1.0
  O  O30  1  0.118  0.241  0.279  1.0
  O  O31  1  0.759  0.877  0.612  1.0
  O  O32  1  0.123  0.882  0.945  1.0
  O  O33  1  0.118  0.877  0.721  1.0
  O  O34  1  0.759  0.882  0.388  1.0
  O  O35  1  0.123  0.241  0.055  1.0
[/CIF]
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The material structure described by Ag3Co2SbO6 crystallizes in the trigonal P3_112 space group. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form CoO6 octahedra that share edges with three equivalent Co(2)O6 octahedra and edges with three equivalent Sb(1)O6 octahedra. In the second Co site, Co(2) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form CoO6 octahedra that share edges with three equivalent Co(1)O6 octahedra and edges with three equivalent Sb(1)O6 octahedra. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a linear geometry to two equivalent O(1) atoms. In the second Ag site, Ag(2) is bonded in a linear geometry to two equivalent O(2) atoms. In the third Ag site, Ag(3) is bonded in a linear geometry to two equivalent O(3) atoms. Sb(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form SbO6 octahedra that share edges with three equivalent Co(1)O6 octahedra and edges with three equivalent Co(2)O6 octahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded to one Co(1), one Co(2), one Ag(1), and one Sb(1) atom to form a mixture of distorted edge and corner-sharing OCo2AgSb tetrahedra. In the second O site, O(2) is bonded to one Co(1), one Co(2), one Ag(2), and one Sb(1) atom to form a mixture of distorted edge and corner-sharing OCo2AgSb tetrahedra. In the third O site, O(3) is bonded to one Co(1), one Co(2), one Ag(3), and one Sb(1) atom to form a mixture of distorted edge and corner-sharing OCo2AgSb tetrahedra. is represented by the CIF file [CIF]
data_Co2Ag3SbO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.446
_cell_length_b   5.446
_cell_length_c   18.973
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   487.338
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.107  0.893  0.333  1.0
  Co  Co1  1  0.107  0.215  0.667  1.0
  Co  Co2  1  0.785  0.893  0.000  1.0
  Co  Co3  1  0.774  0.226  0.333  1.0
  Co  Co4  1  0.774  0.548  0.667  1.0
  Co  Co5  1  0.452  0.226  0.000  1.0
  Ag  Ag6  1  0.446  0.223  0.500  1.0
  Ag  Ag7  1  0.777  0.223  0.833  1.0
  Ag  Ag8  1  0.777  0.554  0.167  1.0
  Ag  Ag9  1  0.117  0.558  0.500  1.0
  Ag  Ag10  1  0.442  0.558  0.833  1.0
  Ag  Ag11  1  0.442  0.883  0.167  1.0
  Ag  Ag12  1  0.763  0.882  0.500  1.0
  Ag  Ag13  1  0.118  0.882  0.833  1.0
  Ag  Ag14  1  0.118  0.237  0.167  1.0
  Sb  Sb15  1  0.440  0.560  0.333  1.0
  Sb  Sb16  1  0.440  0.879  0.667  1.0
  Sb  Sb17  1  0.121  0.560  0.000  1.0
  O  O18  1  0.761  0.560  0.279  1.0
  O  O19  1  0.440  0.201  0.612  1.0
  O  O20  1  0.799  0.239  0.945  1.0
  O  O21  1  0.761  0.201  0.721  1.0
  O  O22  1  0.440  0.239  0.388  1.0
  O  O23  1  0.799  0.560  0.055  1.0
  O  O24  1  0.437  0.877  0.278  1.0
  O  O25  1  0.123  0.560  0.611  1.0
  O  O26  1  0.440  0.563  0.945  1.0
  O  O27  1  0.437  0.560  0.722  1.0
  O  O28  1  0.123  0.563  0.389  1.0
  O  O29  1  0.440  0.877  0.055  1.0
  O  O30  1  0.118  0.241  0.279  1.0
  O  O31  1  0.759  0.877  0.612  1.0
  O  O32  1  0.123  0.882  0.945  1.0
  O  O33  1  0.118  0.877  0.721  1.0
  O  O34  1  0.759  0.882  0.388  1.0
  O  O35  1  0.123  0.241  0.055  1.0
[/CIF]
.