The material structure described by BF4ClO2 is Indium-derived structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of four hydroxychloride hydrate molecules and four BF4 clusters. In each BF4 cluster, B(1) is bonded in a tetrahedral geometry to one F(1), one F(2), one F(3), and one F(4) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one B(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one B(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one B(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one B(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_BCl(OF2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.214
_cell_length_b   5.214
_cell_length_c   9.766
_cell_angle_alpha   83.539
_cell_angle_beta   83.539
_cell_angle_gamma   115.939
_symmetry_Int_Tables_number   1
_cell_volume   233.270
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.581  0.442  0.518  1.0
  B  B1  1  0.442  0.581  0.018  1.0
  Cl  Cl2  1  0.928  0.067  0.751  1.0
  Cl  Cl3  1  0.067  0.928  0.251  1.0
  O  O4  1  0.275  0.883  0.320  1.0
  O  O5  1  0.117  0.961  0.801  1.0
  O  O6  1  0.961  0.117  0.301  1.0
  O  O7  1  0.883  0.275  0.820  1.0
  F  F8  1  0.637  0.493  0.366  1.0
  F  F9  1  0.493  0.637  0.866  1.0
  F  F10  1  0.296  0.417  0.560  1.0
  F  F11  1  0.587  0.185  0.570  1.0
  F  F12  1  0.682  0.788  0.062  1.0
  F  F13  1  0.788  0.682  0.562  1.0
  F  F14  1  0.417  0.296  0.060  1.0
  F  F15  1  0.185  0.587  0.070  1.0
[/CIF]
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The material structure described by BF4ClO2 is Indium-derived structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of four hydroxychloride hydrate molecules and four BF4 clusters. In each BF4 cluster, B(1) is bonded in a tetrahedral geometry to one F(1), one F(2), one F(3), and one F(4) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one B(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one B(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one B(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one B(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_BCl(OF2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.214
_cell_length_b   5.214
_cell_length_c   9.766
_cell_angle_alpha   83.539
_cell_angle_beta   83.539
_cell_angle_gamma   115.939
_symmetry_Int_Tables_number   1
_cell_volume   233.270
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.581  0.442  0.518  1.0
  B  B1  1  0.442  0.581  0.018  1.0
  Cl  Cl2  1  0.928  0.067  0.751  1.0
  Cl  Cl3  1  0.067  0.928  0.251  1.0
  O  O4  1  0.275  0.883  0.320  1.0
  O  O5  1  0.117  0.961  0.801  1.0
  O  O6  1  0.961  0.117  0.301  1.0
  O  O7  1  0.883  0.275  0.820  1.0
  F  F8  1  0.637  0.493  0.366  1.0
  F  F9  1  0.493  0.637  0.866  1.0
  F  F10  1  0.296  0.417  0.560  1.0
  F  F11  1  0.587  0.185  0.570  1.0
  F  F12  1  0.682  0.788  0.062  1.0
  F  F13  1  0.788  0.682  0.562  1.0
  F  F14  1  0.417  0.296  0.060  1.0
  F  F15  1  0.185  0.587  0.070  1.0
[/CIF]
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