The material described by Ni9ZnO10 is Caswellsilverite-like structured and crystallizes in the triclinic P-1 space group. There are five inequivalent Ni sites. In the first Ni site, Ni(1) is bonded to one O(1), one O(2), one O(4), one O(6), and two equivalent O(3) atoms to form NiO6 octahedra that share  a cornercorner with one Ni(1)O6 octahedra, corners with two equivalent Zn(1)O6 octahedra, corners with three equivalent Ni(4)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Zn(1)O6 octahedra, edges with two equivalent Ni(4)O6 octahedra, edges with two equivalent Ni(5)O6 octahedra, edges with three equivalent Ni(2)O6 octahedra, and edges with three equivalent Ni(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the second Ni site, Ni(2) is bonded to one O(2), one O(3), one O(4), one O(5), and two equivalent O(1) atoms to form NiO6 octahedra that share  a cornercorner with one Ni(2)O6 octahedra, corners with two equivalent Ni(5)O6 octahedra, corners with three equivalent Ni(3)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra,  an edgeedge with one Ni(5)O6 octahedra, edges with two equivalent Ni(3)O6 octahedra, edges with two equivalent Zn(1)O6 octahedra, edges with three equivalent Ni(1)O6 octahedra, and edges with three equivalent Ni(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the third Ni site, Ni(3) is bonded to one O(1), one O(2), one O(5), one O(6), and two equivalent O(4) atoms to form NiO6 octahedra that share  a cornercorner with one Ni(5)O6 octahedra, corners with two equivalent Ni(3)O6 octahedra, corners with three equivalent Ni(2)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra,  an edgeedge with one Ni(5)O6 octahedra,  an edgeedge with one Zn(1)O6 octahedra, edges with two equivalent Ni(2)O6 octahedra, edges with three equivalent Ni(1)O6 octahedra, and edges with four equivalent Ni(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the fourth Ni site, Ni(4) is bonded to one O(3), one O(4), one O(5), one O(6), and two equivalent O(2) atoms to form NiO6 octahedra that share  a cornercorner with one Zn(1)O6 octahedra, corners with two equivalent Ni(4)O6 octahedra, corners with three equivalent Ni(1)O6 octahedra,  an edgeedge with one Ni(4)O6 octahedra,  an edgeedge with one Ni(5)O6 octahedra,  an edgeedge with one Zn(1)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, edges with three equivalent Ni(2)O6 octahedra, and edges with four equivalent Ni(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the fifth Ni site, Ni(5) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form NiO6 octahedra that share corners with two equivalent Ni(3)O6 octahedra, corners with four equivalent Ni(2)O6 octahedra, edges with two equivalent Ni(2)O6 octahedra, edges with two equivalent Ni(3)O6 octahedra, edges with two equivalent Ni(4)O6 octahedra, edges with two equivalent Zn(1)O6 octahedra, and edges with four equivalent Ni(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-2°. Zn(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form ZnO6 octahedra that share corners with two equivalent Ni(4)O6 octahedra, corners with four equivalent Ni(1)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, edges with two equivalent Ni(3)O6 octahedra, edges with two equivalent Ni(4)O6 octahedra, edges with two equivalent Ni(5)O6 octahedra, and edges with four equivalent Ni(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. There are six inequivalent O sites. In the first O site, O(1) is bonded to one Ni(1), one Ni(3), one Ni(5), two equivalent Ni(2), and one Zn(1) atom to form OZnNi5 octahedra that share  a cornercorner with one O(5)Ni6 octahedra, corners with two equivalent O(1)ZnNi5 octahedra, corners with three equivalent O(4)Ni6 octahedra,  an edgeedge with one O(5)Ni6 octahedra,  an edgeedge with one O(6)Ni6 octahedra,  an edgeedge with one O(1)ZnNi5 octahedra, edges with two equivalent O(4)Ni6 octahedra, edges with three equivalent O(2)ZnNi5 octahedra, and edges with four equivalent O(3)ZnNi5 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the second O site, O(2) is bonded to one Ni(1), one Ni(2), one Ni(3), two equivalent Ni(4), and one Zn(1) atom to form OZnNi5 octahedra that share  a cornercorner with one O(2)ZnNi5 octahedra, corners with two equivalent O(6)Ni6 octahedra, corners with three equivalent O(3)ZnNi5 octahedra,  an edgeedge with one O(6)Ni6 octahedra,  an edgeedge with one O(2)ZnNi5 octahedra, edges with two equivalent O(5)Ni6 octahedra, edges with two equivalent O(3)ZnNi5 octahedra, edges with three equivalent O(4)Ni6 octahedra, and edges with three equivalent O(1)ZnNi5 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the third O site, O(3) is bonded to one Ni(2), one Ni(4), one Ni(5), two equivalent Ni(1), and one Zn(1) atom to form OZnNi5 octahedra that share  a cornercorner with one O(6)Ni6 octahedra, corners with two equivalent O(3)ZnNi5 octahedra, corners with three equivalent O(2)ZnNi5 octahedra,  an edgeedge with one O(5)Ni6 octahedra,  an edgeedge with one O(6)Ni6 octahedra,  an edgeedge with one O(3)ZnNi5 octahedra, edges with two equivalent O(2)ZnNi5 octahedra, edges with three equivalent O(4)Ni6 octahedra, and edges with four equivalent O(1)ZnNi5 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the fourth O site, O(4) is bonded to one Ni(1), one Ni(2), one Ni(4), one Ni(5), and two equivalent Ni(3) atoms to form ONi6 octahedra that share  a cornercorner with one O(4)Ni6 octahedra, corners with two equivalent O(5)Ni6 octahedra, corners with three equivalent O(1)ZnNi5 octahedra,  an edgeedge with one O(4)Ni6 octahedra,  an edgeedge with one O(5)Ni6 octahedra, edges with two equivalent O(6)Ni6 octahedra, edges with two equivalent O(1)ZnNi5 octahedra, edges with three equivalent O(2)ZnNi5 octahedra, and edges with three equivalent O(3)ZnNi5 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the fifth O site, O(5) is bonded to two equivalent Ni(2), two equivalent Ni(3), and two equivalent Ni(4) atoms to form ONi6 octahedra that share corners with two equivalent O(1)ZnNi5 octahedra, corners with four equivalent O(4)Ni6 octahedra, edges with two equivalent O(4)Ni6 octahedra, edges with two equivalent O(6)Ni6 octahedra, edges with two equivalent O(1)ZnNi5 octahedra, edges with two equivalent O(3)ZnNi5 octahedra, and edges with four equivalent O(2)ZnNi5 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the sixth O site, O(6) is bonded to two equivalent Ni(1), two equivalent Ni(3), and two equivalent Ni(4) atoms to form ONi6 octahedra that share corners with two equivalent O(3)ZnNi5 octahedra, corners with four equivalent O(2)ZnNi5 octahedra, edges with two equivalent O(5)Ni6 octahedra, edges with two equivalent O(1)ZnNi5 octahedra, edges with two equivalent O(2)ZnNi5 octahedra, edges with two equivalent O(3)ZnNi5 octahedra, and edges with four equivalent O(4)Ni6 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZnNi9O10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.195
_cell_length_b   5.998
_cell_length_c   6.708
_cell_angle_alpha   77.094
_cell_angle_beta   75.018
_cell_angle_gamma   73.214
_symmetry_Int_Tables_number   1
_cell_volume   190.823
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.000  0.500  0.000  1.0
  Ni  Ni1  1  0.400  0.099  0.201  1.0
  Ni  Ni2  1  0.401  0.600  0.200  1.0
  Ni  Ni3  1  0.800  0.199  0.402  1.0
  Ni  Ni4  1  0.201  0.300  0.599  1.0
  Ni  Ni5  1  0.799  0.700  0.401  1.0
  Ni  Ni6  1  0.200  0.801  0.598  1.0
  Ni  Ni7  1  0.599  0.400  0.800  1.0
  Ni  Ni8  1  0.600  0.901  0.799  1.0
  Ni  Ni9  1  0.000  0.000  0.000  1.0
  O  O10  1  0.696  0.298  0.100  1.0
  O  O11  1  0.101  0.399  0.304  1.0
  O  O12  1  0.697  0.803  0.101  1.0
  O  O13  1  0.099  0.901  0.300  1.0
  O  O14  1  0.901  0.099  0.700  1.0
  O  O15  1  0.500  0.500  0.500  1.0
  O  O16  1  0.303  0.197  0.899  1.0
  O  O17  1  0.899  0.601  0.696  1.0
  O  O18  1  0.500  0.000  0.500  1.0
  O  O19  1  0.304  0.702  0.900  1.0
[/CIF]
.
The material described by Ni9ZnO10 is Caswellsilverite-like structured and crystallizes in the triclinic P-1 space group. There are five inequivalent Ni sites. In the first Ni site, Ni(1) is bonded to one O(1), one O(2), one O(4), one O(6), and two equivalent O(3) atoms to form NiO6 octahedra that share  a cornercorner with one Ni(1)O6 octahedra, corners with two equivalent Zn(1)O6 octahedra, corners with three equivalent Ni(4)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Zn(1)O6 octahedra, edges with two equivalent Ni(4)O6 octahedra, edges with two equivalent Ni(5)O6 octahedra, edges with three equivalent Ni(2)O6 octahedra, and edges with three equivalent Ni(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the second Ni site, Ni(2) is bonded to one O(2), one O(3), one O(4), one O(5), and two equivalent O(1) atoms to form NiO6 octahedra that share  a cornercorner with one Ni(2)O6 octahedra, corners with two equivalent Ni(5)O6 octahedra, corners with three equivalent Ni(3)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra,  an edgeedge with one Ni(5)O6 octahedra, edges with two equivalent Ni(3)O6 octahedra, edges with two equivalent Zn(1)O6 octahedra, edges with three equivalent Ni(1)O6 octahedra, and edges with three equivalent Ni(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the third Ni site, Ni(3) is bonded to one O(1), one O(2), one O(5), one O(6), and two equivalent O(4) atoms to form NiO6 octahedra that share  a cornercorner with one Ni(5)O6 octahedra, corners with two equivalent Ni(3)O6 octahedra, corners with three equivalent Ni(2)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra,  an edgeedge with one Ni(5)O6 octahedra,  an edgeedge with one Zn(1)O6 octahedra, edges with two equivalent Ni(2)O6 octahedra, edges with three equivalent Ni(1)O6 octahedra, and edges with four equivalent Ni(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the fourth Ni site, Ni(4) is bonded to one O(3), one O(4), one O(5), one O(6), and two equivalent O(2) atoms to form NiO6 octahedra that share  a cornercorner with one Zn(1)O6 octahedra, corners with two equivalent Ni(4)O6 octahedra, corners with three equivalent Ni(1)O6 octahedra,  an edgeedge with one Ni(4)O6 octahedra,  an edgeedge with one Ni(5)O6 octahedra,  an edgeedge with one Zn(1)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, edges with three equivalent Ni(2)O6 octahedra, and edges with four equivalent Ni(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the fifth Ni site, Ni(5) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form NiO6 octahedra that share corners with two equivalent Ni(3)O6 octahedra, corners with four equivalent Ni(2)O6 octahedra, edges with two equivalent Ni(2)O6 octahedra, edges with two equivalent Ni(3)O6 octahedra, edges with two equivalent Ni(4)O6 octahedra, edges with two equivalent Zn(1)O6 octahedra, and edges with four equivalent Ni(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-2°. Zn(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form ZnO6 octahedra that share corners with two equivalent Ni(4)O6 octahedra, corners with four equivalent Ni(1)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, edges with two equivalent Ni(3)O6 octahedra, edges with two equivalent Ni(4)O6 octahedra, edges with two equivalent Ni(5)O6 octahedra, and edges with four equivalent Ni(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. There are six inequivalent O sites. In the first O site, O(1) is bonded to one Ni(1), one Ni(3), one Ni(5), two equivalent Ni(2), and one Zn(1) atom to form OZnNi5 octahedra that share  a cornercorner with one O(5)Ni6 octahedra, corners with two equivalent O(1)ZnNi5 octahedra, corners with three equivalent O(4)Ni6 octahedra,  an edgeedge with one O(5)Ni6 octahedra,  an edgeedge with one O(6)Ni6 octahedra,  an edgeedge with one O(1)ZnNi5 octahedra, edges with two equivalent O(4)Ni6 octahedra, edges with three equivalent O(2)ZnNi5 octahedra, and edges with four equivalent O(3)ZnNi5 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the second O site, O(2) is bonded to one Ni(1), one Ni(2), one Ni(3), two equivalent Ni(4), and one Zn(1) atom to form OZnNi5 octahedra that share  a cornercorner with one O(2)ZnNi5 octahedra, corners with two equivalent O(6)Ni6 octahedra, corners with three equivalent O(3)ZnNi5 octahedra,  an edgeedge with one O(6)Ni6 octahedra,  an edgeedge with one O(2)ZnNi5 octahedra, edges with two equivalent O(5)Ni6 octahedra, edges with two equivalent O(3)ZnNi5 octahedra, edges with three equivalent O(4)Ni6 octahedra, and edges with three equivalent O(1)ZnNi5 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the third O site, O(3) is bonded to one Ni(2), one Ni(4), one Ni(5), two equivalent Ni(1), and one Zn(1) atom to form OZnNi5 octahedra that share  a cornercorner with one O(6)Ni6 octahedra, corners with two equivalent O(3)ZnNi5 octahedra, corners with three equivalent O(2)ZnNi5 octahedra,  an edgeedge with one O(5)Ni6 octahedra,  an edgeedge with one O(6)Ni6 octahedra,  an edgeedge with one O(3)ZnNi5 octahedra, edges with two equivalent O(2)ZnNi5 octahedra, edges with three equivalent O(4)Ni6 octahedra, and edges with four equivalent O(1)ZnNi5 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the fourth O site, O(4) is bonded to one Ni(1), one Ni(2), one Ni(4), one Ni(5), and two equivalent Ni(3) atoms to form ONi6 octahedra that share  a cornercorner with one O(4)Ni6 octahedra, corners with two equivalent O(5)Ni6 octahedra, corners with three equivalent O(1)ZnNi5 octahedra,  an edgeedge with one O(4)Ni6 octahedra,  an edgeedge with one O(5)Ni6 octahedra, edges with two equivalent O(6)Ni6 octahedra, edges with two equivalent O(1)ZnNi5 octahedra, edges with three equivalent O(2)ZnNi5 octahedra, and edges with three equivalent O(3)ZnNi5 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the fifth O site, O(5) is bonded to two equivalent Ni(2), two equivalent Ni(3), and two equivalent Ni(4) atoms to form ONi6 octahedra that share corners with two equivalent O(1)ZnNi5 octahedra, corners with four equivalent O(4)Ni6 octahedra, edges with two equivalent O(4)Ni6 octahedra, edges with two equivalent O(6)Ni6 octahedra, edges with two equivalent O(1)ZnNi5 octahedra, edges with two equivalent O(3)ZnNi5 octahedra, and edges with four equivalent O(2)ZnNi5 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the sixth O site, O(6) is bonded to two equivalent Ni(1), two equivalent Ni(3), and two equivalent Ni(4) atoms to form ONi6 octahedra that share corners with two equivalent O(3)ZnNi5 octahedra, corners with four equivalent O(2)ZnNi5 octahedra, edges with two equivalent O(5)Ni6 octahedra, edges with two equivalent O(1)ZnNi5 octahedra, edges with two equivalent O(2)ZnNi5 octahedra, edges with two equivalent O(3)ZnNi5 octahedra, and edges with four equivalent O(4)Ni6 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZnNi9O10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.195
_cell_length_b   5.998
_cell_length_c   6.708
_cell_angle_alpha   77.094
_cell_angle_beta   75.018
_cell_angle_gamma   73.214
_symmetry_Int_Tables_number   1
_cell_volume   190.823
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.000  0.500  0.000  1.0
  Ni  Ni1  1  0.400  0.099  0.201  1.0
  Ni  Ni2  1  0.401  0.600  0.200  1.0
  Ni  Ni3  1  0.800  0.199  0.402  1.0
  Ni  Ni4  1  0.201  0.300  0.599  1.0
  Ni  Ni5  1  0.799  0.700  0.401  1.0
  Ni  Ni6  1  0.200  0.801  0.598  1.0
  Ni  Ni7  1  0.599  0.400  0.800  1.0
  Ni  Ni8  1  0.600  0.901  0.799  1.0
  Ni  Ni9  1  0.000  0.000  0.000  1.0
  O  O10  1  0.696  0.298  0.100  1.0
  O  O11  1  0.101  0.399  0.304  1.0
  O  O12  1  0.697  0.803  0.101  1.0
  O  O13  1  0.099  0.901  0.300  1.0
  O  O14  1  0.901  0.099  0.700  1.0
  O  O15  1  0.500  0.500  0.500  1.0
  O  O16  1  0.303  0.197  0.899  1.0
  O  O17  1  0.899  0.601  0.696  1.0
  O  O18  1  0.500  0.000  0.500  1.0
  O  O19  1  0.304  0.702  0.900  1.0
[/CIF]
.