The compound described by Eu2MnRhO6 is Orthorhombic Perovskite-derived structured and crystallizes in the monoclinic P2_1/c space group. Eu(1) is bonded in a 8-coordinate geometry to two equivalent O(3), three equivalent O(1), and three equivalent O(2) atoms. Mn(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form MnO6 octahedra that share corners with six equivalent Rh(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 31-32°. Rh(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form RhO6 octahedra that share corners with six equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 31-32°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to three equivalent Eu(1), one Mn(1), and one Rh(1) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to three equivalent Eu(1), one Mn(1), and one Rh(1) atom. In the third O site, O(3) is bonded to two equivalent Eu(1), one Mn(1), and one Rh(1) atom to form distorted corner-sharing OEu2MnRh tetrahedra. is represented by the CIF file [CIF]
data_Eu2MnRhO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.755
_cell_length_b   5.544
_cell_length_c   9.434
_cell_angle_alpha   54.705
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   245.690
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Eu  Eu0  1  0.559  0.736  0.750  1.0
  Eu  Eu1  1  0.059  0.264  0.750  1.0
  Eu  Eu2  1  0.441  0.264  0.250  1.0
  Eu  Eu3  1  0.941  0.736  0.250  1.0
  Mn  Mn4  1  0.500  0.000  0.000  1.0
  Mn  Mn5  1  0.000  0.000  0.500  1.0
  Rh  Rh6  1  0.500  0.500  0.500  1.0
  Rh  Rh7  1  0.000  0.500  0.000  1.0
  O  O8  1  0.803  0.247  0.952  1.0
  O  O9  1  0.303  0.753  0.548  1.0
  O  O10  1  0.202  0.354  0.452  1.0
  O  O11  1  0.702  0.646  0.048  1.0
  O  O12  1  0.197  0.753  0.048  1.0
  O  O13  1  0.697  0.247  0.452  1.0
  O  O14  1  0.798  0.646  0.548  1.0
  O  O15  1  0.298  0.354  0.952  1.0
  O  O16  1  0.971  0.851  0.745  1.0
  O  O17  1  0.471  0.149  0.755  1.0
  O  O18  1  0.029  0.149  0.255  1.0
  O  O19  1  0.529  0.851  0.245  1.0
[/CIF]
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The compound described by Eu2MnRhO6 is Orthorhombic Perovskite-derived structured and crystallizes in the monoclinic P2_1/c space group. Eu(1) is bonded in a 8-coordinate geometry to two equivalent O(3), three equivalent O(1), and three equivalent O(2) atoms. Mn(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form MnO6 octahedra that share corners with six equivalent Rh(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 31-32°. Rh(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form RhO6 octahedra that share corners with six equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 31-32°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to three equivalent Eu(1), one Mn(1), and one Rh(1) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to three equivalent Eu(1), one Mn(1), and one Rh(1) atom. In the third O site, O(3) is bonded to two equivalent Eu(1), one Mn(1), and one Rh(1) atom to form distorted corner-sharing OEu2MnRh tetrahedra. is represented by the CIF file [CIF]
data_Eu2MnRhO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.755
_cell_length_b   5.544
_cell_length_c   9.434
_cell_angle_alpha   54.705
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   245.690
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Eu  Eu0  1  0.559  0.736  0.750  1.0
  Eu  Eu1  1  0.059  0.264  0.750  1.0
  Eu  Eu2  1  0.441  0.264  0.250  1.0
  Eu  Eu3  1  0.941  0.736  0.250  1.0
  Mn  Mn4  1  0.500  0.000  0.000  1.0
  Mn  Mn5  1  0.000  0.000  0.500  1.0
  Rh  Rh6  1  0.500  0.500  0.500  1.0
  Rh  Rh7  1  0.000  0.500  0.000  1.0
  O  O8  1  0.803  0.247  0.952  1.0
  O  O9  1  0.303  0.753  0.548  1.0
  O  O10  1  0.202  0.354  0.452  1.0
  O  O11  1  0.702  0.646  0.048  1.0
  O  O12  1  0.197  0.753  0.048  1.0
  O  O13  1  0.697  0.247  0.452  1.0
  O  O14  1  0.798  0.646  0.548  1.0
  O  O15  1  0.298  0.354  0.952  1.0
  O  O16  1  0.971  0.851  0.745  1.0
  O  O17  1  0.471  0.149  0.755  1.0
  O  O18  1  0.029  0.149  0.255  1.0
  O  O19  1  0.529  0.851  0.245  1.0
[/CIF]
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