The compound described by KUVO6 crystallizes in the monoclinic P2_1/c space group. K(1) is bonded in a 6-coordinate geometry to one O(1), one O(4), two equivalent O(2), and two equivalent O(3) atoms. U(1) is bonded to one O(1), one O(2), one O(6), two equivalent O(4), and two equivalent O(5) atoms to form distorted UO7 pentagonal bipyramids that share corners with two equivalent U(1)O7 pentagonal bipyramids, corners with two equivalent V(1)O5 trigonal bipyramids,  an edgeedge with one U(1)O7 pentagonal bipyramid, and edges with two equivalent V(1)O5 trigonal bipyramids. V(1) is bonded to one O(3), one O(4), one O(5), and two equivalent O(6) atoms to form distorted VO5 trigonal bipyramids that share corners with two equivalent U(1)O7 pentagonal bipyramids, edges with two equivalent U(1)O7 pentagonal bipyramids, and  an edgeedge with one V(1)O5 trigonal bipyramid. There are six inequivalent O sites. In the first O site, O(6) is bonded in a distorted T-shaped geometry to one U(1) and two equivalent V(1) atoms. In the second O site, O(1) is bonded in a distorted single-bond geometry to one K(1) and one U(1) atom. In the third O site, O(2) is bonded in a distorted single-bond geometry to two equivalent K(1) and one U(1) atom. In the fourth O site, O(3) is bonded in a distorted single-bond geometry to two equivalent K(1) and one V(1) atom. In the fifth O site, O(4) is bonded in a 4-coordinate geometry to one K(1), two equivalent U(1), and one V(1) atom. In the sixth O site, O(5) is bonded in a 3-coordinate geometry to two equivalent U(1) and one V(1) atom. is represented by the CIF card [CIF]
data_KUVO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.245
_cell_length_b   7.157
_cell_length_c   10.839
_cell_angle_alpha   76.797
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   622.765
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.681  0.470  0.826  1.0
  K  K1  1  0.181  0.530  0.674  1.0
  K  K2  1  0.319  0.530  0.174  1.0
  K  K3  1  0.819  0.470  0.326  1.0
  U  U4  1  0.495  0.009  0.678  1.0
  U  U5  1  0.995  0.991  0.822  1.0
  U  U6  1  0.505  0.991  0.322  1.0
  U  U7  1  0.005  0.009  0.178  1.0
  V  V8  1  0.642  0.881  0.974  1.0
  V  V9  1  0.142  0.119  0.526  1.0
  V  V10  1  0.358  0.119  0.026  1.0
  V  V11  1  0.858  0.881  0.474  1.0
  O  O12  1  0.562  0.260  0.643  1.0
  O  O13  1  0.062  0.740  0.857  1.0
  O  O14  1  0.438  0.740  0.357  1.0
  O  O15  1  0.938  0.260  0.143  1.0
  O  O16  1  0.435  0.755  0.714  1.0
  O  O17  1  0.935  0.245  0.786  1.0
  O  O18  1  0.565  0.245  0.286  1.0
  O  O19  1  0.065  0.755  0.214  1.0
  O  O20  1  0.609  0.649  0.024  1.0
  O  O21  1  0.109  0.351  0.476  1.0
  O  O22  1  0.391  0.351  0.976  1.0
  O  O23  1  0.891  0.649  0.524  1.0
  O  O24  1  0.720  0.904  0.809  1.0
  O  O25  1  0.220  0.096  0.691  1.0
  O  O26  1  0.280  0.096  0.191  1.0
  O  O27  1  0.780  0.904  0.309  1.0
  O  O28  1  0.844  0.943  0.017  1.0
  O  O29  1  0.344  0.057  0.483  1.0
  O  O30  1  0.156  0.057  0.983  1.0
  O  O31  1  0.656  0.943  0.517  1.0
  O  O32  1  0.459  0.021  0.891  1.0
  O  O33  1  0.959  0.979  0.609  1.0
  O  O34  1  0.541  0.979  0.109  1.0
  O  O35  1  0.041  0.021  0.391  1.0
[/CIF]
.
The compound described by KUVO6 crystallizes in the monoclinic P2_1/c space group. K(1) is bonded in a 6-coordinate geometry to one O(1), one O(4), two equivalent O(2), and two equivalent O(3) atoms. U(1) is bonded to one O(1), one O(2), one O(6), two equivalent O(4), and two equivalent O(5) atoms to form distorted UO7 pentagonal bipyramids that share corners with two equivalent U(1)O7 pentagonal bipyramids, corners with two equivalent V(1)O5 trigonal bipyramids,  an edgeedge with one U(1)O7 pentagonal bipyramid, and edges with two equivalent V(1)O5 trigonal bipyramids. V(1) is bonded to one O(3), one O(4), one O(5), and two equivalent O(6) atoms to form distorted VO5 trigonal bipyramids that share corners with two equivalent U(1)O7 pentagonal bipyramids, edges with two equivalent U(1)O7 pentagonal bipyramids, and  an edgeedge with one V(1)O5 trigonal bipyramid. There are six inequivalent O sites. In the first O site, O(6) is bonded in a distorted T-shaped geometry to one U(1) and two equivalent V(1) atoms. In the second O site, O(1) is bonded in a distorted single-bond geometry to one K(1) and one U(1) atom. In the third O site, O(2) is bonded in a distorted single-bond geometry to two equivalent K(1) and one U(1) atom. In the fourth O site, O(3) is bonded in a distorted single-bond geometry to two equivalent K(1) and one V(1) atom. In the fifth O site, O(4) is bonded in a 4-coordinate geometry to one K(1), two equivalent U(1), and one V(1) atom. In the sixth O site, O(5) is bonded in a 3-coordinate geometry to two equivalent U(1) and one V(1) atom. is represented by the CIF card [CIF]
data_KUVO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.245
_cell_length_b   7.157
_cell_length_c   10.839
_cell_angle_alpha   76.797
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   622.765
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.681  0.470  0.826  1.0
  K  K1  1  0.181  0.530  0.674  1.0
  K  K2  1  0.319  0.530  0.174  1.0
  K  K3  1  0.819  0.470  0.326  1.0
  U  U4  1  0.495  0.009  0.678  1.0
  U  U5  1  0.995  0.991  0.822  1.0
  U  U6  1  0.505  0.991  0.322  1.0
  U  U7  1  0.005  0.009  0.178  1.0
  V  V8  1  0.642  0.881  0.974  1.0
  V  V9  1  0.142  0.119  0.526  1.0
  V  V10  1  0.358  0.119  0.026  1.0
  V  V11  1  0.858  0.881  0.474  1.0
  O  O12  1  0.562  0.260  0.643  1.0
  O  O13  1  0.062  0.740  0.857  1.0
  O  O14  1  0.438  0.740  0.357  1.0
  O  O15  1  0.938  0.260  0.143  1.0
  O  O16  1  0.435  0.755  0.714  1.0
  O  O17  1  0.935  0.245  0.786  1.0
  O  O18  1  0.565  0.245  0.286  1.0
  O  O19  1  0.065  0.755  0.214  1.0
  O  O20  1  0.609  0.649  0.024  1.0
  O  O21  1  0.109  0.351  0.476  1.0
  O  O22  1  0.391  0.351  0.976  1.0
  O  O23  1  0.891  0.649  0.524  1.0
  O  O24  1  0.720  0.904  0.809  1.0
  O  O25  1  0.220  0.096  0.691  1.0
  O  O26  1  0.280  0.096  0.191  1.0
  O  O27  1  0.780  0.904  0.309  1.0
  O  O28  1  0.844  0.943  0.017  1.0
  O  O29  1  0.344  0.057  0.483  1.0
  O  O30  1  0.156  0.057  0.983  1.0
  O  O31  1  0.656  0.943  0.517  1.0
  O  O32  1  0.459  0.021  0.891  1.0
  O  O33  1  0.959  0.979  0.609  1.0
  O  O34  1  0.541  0.979  0.109  1.0
  O  O35  1  0.041  0.021  0.391  1.0
[/CIF]
.