The crystal structure described by Na2U(MoO4)3 is Zircon-derived structured and crystallizes in the monoclinic C2/c space group. Na(1) is bonded in a 8-coordinate geometry to one O(1), one O(3), one O(4), one O(5), two equivalent O(2), and two equivalent O(6) atoms. U(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(3), two equivalent O(4), and two equivalent O(5) atoms. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a tetrahedral geometry to one O(1), one O(3), one O(5), and one O(6) atom. In the second Mo site, Mo(2) is bonded in a tetrahedral geometry to two equivalent O(2) and two equivalent O(4) atoms. There are six inequivalent O sites. In the first O site, O(6) is bonded in a 3-coordinate geometry to two equivalent Na(1) and one Mo(1) atom. In the second O site, O(1) is bonded in a 3-coordinate geometry to one Na(1), one U(1), and one Mo(1) atom. In the third O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Na(1) and one Mo(2) atom. In the fourth O site, O(3) is bonded in a distorted trigonal planar geometry to one Na(1), one U(1), and one Mo(1) atom. In the fifth O site, O(4) is bonded in a distorted trigonal planar geometry to one Na(1), one U(1), and one Mo(2) atom. In the sixth O site, O(5) is bonded in a 3-coordinate geometry to one Na(1), one U(1), and one Mo(1) atom. is represented by the CIF card [CIF]
data_Na2U(MoO4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.922
_cell_length_b   6.922
_cell_length_c   11.813
_cell_angle_alpha   80.162
_cell_angle_beta   80.162
_cell_angle_gamma   114.554
_symmetry_Int_Tables_number   1
_cell_volume   488.451
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.209  0.460  0.580  1.0
  Na  Na1  1  0.540  0.791  0.920  1.0
  Na  Na2  1  0.460  0.209  0.080  1.0
  Na  Na3  1  0.791  0.540  0.420  1.0
  U  U4  1  0.877  0.123  0.250  1.0
  U  U5  1  0.123  0.877  0.750  1.0
  Mo  Mo6  1  0.707  0.957  0.586  1.0
  Mo  Mo7  1  0.043  0.293  0.914  1.0
  Mo  Mo8  1  0.374  0.626  0.250  1.0
  Mo  Mo9  1  0.293  0.043  0.414  1.0
  Mo  Mo10  1  0.626  0.374  0.750  1.0
  Mo  Mo11  1  0.957  0.707  0.086  1.0
  O  O12  1  0.071  0.504  0.787  1.0
  O  O13  1  0.385  0.812  0.124  1.0
  O  O14  1  0.747  0.144  0.444  1.0
  O  O15  1  0.496  0.929  0.713  1.0
  O  O16  1  0.856  0.253  0.056  1.0
  O  O17  1  0.188  0.615  0.376  1.0
  O  O18  1  0.749  0.650  0.780  1.0
  O  O19  1  0.043  0.973  0.121  1.0
  O  O20  1  0.386  0.307  0.438  1.0
  O  O21  1  0.350  0.251  0.720  1.0
  O  O22  1  0.693  0.614  0.062  1.0
  O  O23  1  0.027  0.957  0.379  1.0
  O  O24  1  0.615  0.188  0.876  1.0
  O  O25  1  0.929  0.496  0.213  1.0
  O  O26  1  0.253  0.856  0.556  1.0
  O  O27  1  0.144  0.747  0.944  1.0
  O  O28  1  0.504  0.071  0.287  1.0
  O  O29  1  0.812  0.385  0.624  1.0
  O  O30  1  0.957  0.027  0.879  1.0
  O  O31  1  0.251  0.350  0.220  1.0
  O  O32  1  0.614  0.693  0.562  1.0
  O  O33  1  0.307  0.386  0.938  1.0
  O  O34  1  0.650  0.749  0.280  1.0
  O  O35  1  0.973  0.043  0.621  1.0
[/CIF]
.
The crystal structure described by Na2U(MoO4)3 is Zircon-derived structured and crystallizes in the monoclinic C2/c space group. Na(1) is bonded in a 8-coordinate geometry to one O(1), one O(3), one O(4), one O(5), two equivalent O(2), and two equivalent O(6) atoms. U(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(3), two equivalent O(4), and two equivalent O(5) atoms. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a tetrahedral geometry to one O(1), one O(3), one O(5), and one O(6) atom. In the second Mo site, Mo(2) is bonded in a tetrahedral geometry to two equivalent O(2) and two equivalent O(4) atoms. There are six inequivalent O sites. In the first O site, O(6) is bonded in a 3-coordinate geometry to two equivalent Na(1) and one Mo(1) atom. In the second O site, O(1) is bonded in a 3-coordinate geometry to one Na(1), one U(1), and one Mo(1) atom. In the third O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Na(1) and one Mo(2) atom. In the fourth O site, O(3) is bonded in a distorted trigonal planar geometry to one Na(1), one U(1), and one Mo(1) atom. In the fifth O site, O(4) is bonded in a distorted trigonal planar geometry to one Na(1), one U(1), and one Mo(2) atom. In the sixth O site, O(5) is bonded in a 3-coordinate geometry to one Na(1), one U(1), and one Mo(1) atom. is represented by the CIF card [CIF]
data_Na2U(MoO4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.922
_cell_length_b   6.922
_cell_length_c   11.813
_cell_angle_alpha   80.162
_cell_angle_beta   80.162
_cell_angle_gamma   114.554
_symmetry_Int_Tables_number   1
_cell_volume   488.451
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.209  0.460  0.580  1.0
  Na  Na1  1  0.540  0.791  0.920  1.0
  Na  Na2  1  0.460  0.209  0.080  1.0
  Na  Na3  1  0.791  0.540  0.420  1.0
  U  U4  1  0.877  0.123  0.250  1.0
  U  U5  1  0.123  0.877  0.750  1.0
  Mo  Mo6  1  0.707  0.957  0.586  1.0
  Mo  Mo7  1  0.043  0.293  0.914  1.0
  Mo  Mo8  1  0.374  0.626  0.250  1.0
  Mo  Mo9  1  0.293  0.043  0.414  1.0
  Mo  Mo10  1  0.626  0.374  0.750  1.0
  Mo  Mo11  1  0.957  0.707  0.086  1.0
  O  O12  1  0.071  0.504  0.787  1.0
  O  O13  1  0.385  0.812  0.124  1.0
  O  O14  1  0.747  0.144  0.444  1.0
  O  O15  1  0.496  0.929  0.713  1.0
  O  O16  1  0.856  0.253  0.056  1.0
  O  O17  1  0.188  0.615  0.376  1.0
  O  O18  1  0.749  0.650  0.780  1.0
  O  O19  1  0.043  0.973  0.121  1.0
  O  O20  1  0.386  0.307  0.438  1.0
  O  O21  1  0.350  0.251  0.720  1.0
  O  O22  1  0.693  0.614  0.062  1.0
  O  O23  1  0.027  0.957  0.379  1.0
  O  O24  1  0.615  0.188  0.876  1.0
  O  O25  1  0.929  0.496  0.213  1.0
  O  O26  1  0.253  0.856  0.556  1.0
  O  O27  1  0.144  0.747  0.944  1.0
  O  O28  1  0.504  0.071  0.287  1.0
  O  O29  1  0.812  0.385  0.624  1.0
  O  O30  1  0.957  0.027  0.879  1.0
  O  O31  1  0.251  0.350  0.220  1.0
  O  O32  1  0.614  0.693  0.562  1.0
  O  O33  1  0.307  0.386  0.938  1.0
  O  O34  1  0.650  0.749  0.280  1.0
  O  O35  1  0.973  0.043  0.621  1.0
[/CIF]
.