The crystal structure described by CsMnH4(OF2)2 crystallizes in the monoclinic C2/c space group. Cs(1) is bonded in a 10-coordinate geometry to two equivalent O(1), four equivalent F(1), and four equivalent F(2) atoms. Mn(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent F(1), and two equivalent F(2) atoms. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. O(1) is bonded in a distorted water-like geometry to one Cs(1), one Mn(1), one H(1), and one H(2) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to two equivalent Cs(1) and one Mn(1) atom. In the second F site, F(2) is bonded in a distorted single-bond geometry to two equivalent Cs(1) and one Mn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CsMnH4(OF2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.724
_cell_length_b   6.900
_cell_length_c   8.725
_cell_angle_alpha   84.537
_cell_angle_beta   67.350
_cell_angle_gamma   60.847
_symmetry_Int_Tables_number   1
_cell_volume   324.055
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.028  0.500  0.500  1.0
  Cs  Cs1  1  0.976  1.000  1.000  1.0
  F  F2  1  0.441  0.048  0.230  1.0
  F  F3  1  0.564  0.452  0.270  1.0
  F  F4  1  0.286  0.548  0.730  1.0
  F  F5  1  0.718  0.952  0.770  1.0
  F  F6  1  0.326  0.151  0.683  1.0
  F  F7  1  0.679  0.349  0.817  1.0
  F  F8  1  0.845  0.651  0.183  1.0
  F  F9  1  0.160  0.849  0.317  1.0
  H  H10  1  0.908  0.077  0.426  1.0
  H  H11  1  0.593  0.577  0.926  1.0
  H  H12  1  0.097  0.423  0.074  1.0
  H  H13  1  0.411  0.923  0.574  1.0
  H  H14  1  0.319  0.199  0.097  1.0
  H  H15  1  0.686  0.301  0.403  1.0
  H  H16  1  0.389  0.699  0.597  1.0
  H  H17  1  0.615  0.801  0.903  1.0
  Mn  Mn18  1  0.502  0.250  0.750  1.0
  Mn  Mn19  1  0.502  0.750  0.250  1.0
  O  O20  1  0.757  0.221  0.485  1.0
  O  O21  1  0.247  0.279  0.015  1.0
  O  O22  1  0.541  0.721  0.985  1.0
  O  O23  1  0.463  0.779  0.515  1.0
[/CIF]
.
The crystal structure described by CsMnH4(OF2)2 crystallizes in the monoclinic C2/c space group. Cs(1) is bonded in a 10-coordinate geometry to two equivalent O(1), four equivalent F(1), and four equivalent F(2) atoms. Mn(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent F(1), and two equivalent F(2) atoms. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. O(1) is bonded in a distorted water-like geometry to one Cs(1), one Mn(1), one H(1), and one H(2) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to two equivalent Cs(1) and one Mn(1) atom. In the second F site, F(2) is bonded in a distorted single-bond geometry to two equivalent Cs(1) and one Mn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CsMnH4(OF2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.724
_cell_length_b   6.900
_cell_length_c   8.725
_cell_angle_alpha   84.537
_cell_angle_beta   67.350
_cell_angle_gamma   60.847
_symmetry_Int_Tables_number   1
_cell_volume   324.055
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.028  0.500  0.500  1.0
  Cs  Cs1  1  0.976  1.000  1.000  1.0
  F  F2  1  0.441  0.048  0.230  1.0
  F  F3  1  0.564  0.452  0.270  1.0
  F  F4  1  0.286  0.548  0.730  1.0
  F  F5  1  0.718  0.952  0.770  1.0
  F  F6  1  0.326  0.151  0.683  1.0
  F  F7  1  0.679  0.349  0.817  1.0
  F  F8  1  0.845  0.651  0.183  1.0
  F  F9  1  0.160  0.849  0.317  1.0
  H  H10  1  0.908  0.077  0.426  1.0
  H  H11  1  0.593  0.577  0.926  1.0
  H  H12  1  0.097  0.423  0.074  1.0
  H  H13  1  0.411  0.923  0.574  1.0
  H  H14  1  0.319  0.199  0.097  1.0
  H  H15  1  0.686  0.301  0.403  1.0
  H  H16  1  0.389  0.699  0.597  1.0
  H  H17  1  0.615  0.801  0.903  1.0
  Mn  Mn18  1  0.502  0.250  0.750  1.0
  Mn  Mn19  1  0.502  0.750  0.250  1.0
  O  O20  1  0.757  0.221  0.485  1.0
  O  O21  1  0.247  0.279  0.015  1.0
  O  O22  1  0.541  0.721  0.985  1.0
  O  O23  1  0.463  0.779  0.515  1.0
[/CIF]
.