The crystal structure described by NHS7 is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four heptathiazocine molecules. N(1) is bonded in a distorted trigonal planar geometry to one H(1) and two equivalent S(4) atoms. H(1) is bonded in a single-bond geometry to one N(1) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one S(2) and one S(4) atom. In the second S site, S(2) is bonded in a water-like geometry to one S(1) and one S(3) atom. In the third S site, S(3) is bonded in a bent 120 degrees geometry to two equivalent S(2) atoms. In the fourth S site, S(4) is bonded in a distorted single-bond geometry to one N(1) and one S(1) atom. is represented by the CIF card [CIF]
data_HS7N
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.125
_cell_length_b   8.500
_cell_length_c   13.874
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   958.256
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.707  0.526  0.750  1.0
  H  H1  1  0.207  0.974  0.250  1.0
  H  H2  1  0.793  0.026  0.750  1.0
  H  H3  1  0.293  0.474  0.250  1.0
  S  S4  1  0.008  0.251  0.394  1.0
  S  S5  1  0.508  0.249  0.606  1.0
  S  S6  1  0.492  0.751  0.106  1.0
  S  S7  1  0.992  0.749  0.894  1.0
  S  S8  1  0.992  0.749  0.606  1.0
  S  S9  1  0.492  0.751  0.394  1.0
  S  S10  1  0.508  0.249  0.894  1.0
  S  S11  1  0.008  0.251  0.106  1.0
  S  S12  1  0.857  0.058  0.374  1.0
  S  S13  1  0.357  0.442  0.626  1.0
  S  S14  1  0.643  0.558  0.126  1.0
  S  S15  1  0.143  0.942  0.874  1.0
  S  S16  1  0.143  0.942  0.626  1.0
  S  S17  1  0.643  0.558  0.374  1.0
  S  S18  1  0.357  0.442  0.874  1.0
  S  S19  1  0.857  0.058  0.126  1.0
  S  S20  1  0.728  0.114  0.250  1.0
  S  S21  1  0.228  0.386  0.750  1.0
  S  S22  1  0.772  0.614  0.250  1.0
  S  S23  1  0.272  0.886  0.750  1.0
  S  S24  1  0.247  0.172  0.140  1.0
  S  S25  1  0.747  0.328  0.860  1.0
  S  S26  1  0.253  0.672  0.360  1.0
  S  S27  1  0.753  0.828  0.640  1.0
  S  S28  1  0.753  0.828  0.860  1.0
  S  S29  1  0.253  0.672  0.140  1.0
  S  S30  1  0.747  0.328  0.640  1.0
  S  S31  1  0.247  0.172  0.360  1.0
  N  N32  1  0.756  0.911  0.750  1.0
  N  N33  1  0.256  0.589  0.250  1.0
  N  N34  1  0.744  0.411  0.750  1.0
  N  N35  1  0.244  0.089  0.250  1.0
[/CIF]
.
The crystal structure described by NHS7 is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four heptathiazocine molecules. N(1) is bonded in a distorted trigonal planar geometry to one H(1) and two equivalent S(4) atoms. H(1) is bonded in a single-bond geometry to one N(1) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one S(2) and one S(4) atom. In the second S site, S(2) is bonded in a water-like geometry to one S(1) and one S(3) atom. In the third S site, S(3) is bonded in a bent 120 degrees geometry to two equivalent S(2) atoms. In the fourth S site, S(4) is bonded in a distorted single-bond geometry to one N(1) and one S(1) atom. is represented by the CIF card [CIF]
data_HS7N
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.125
_cell_length_b   8.500
_cell_length_c   13.874
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   958.256
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.707  0.526  0.750  1.0
  H  H1  1  0.207  0.974  0.250  1.0
  H  H2  1  0.793  0.026  0.750  1.0
  H  H3  1  0.293  0.474  0.250  1.0
  S  S4  1  0.008  0.251  0.394  1.0
  S  S5  1  0.508  0.249  0.606  1.0
  S  S6  1  0.492  0.751  0.106  1.0
  S  S7  1  0.992  0.749  0.894  1.0
  S  S8  1  0.992  0.749  0.606  1.0
  S  S9  1  0.492  0.751  0.394  1.0
  S  S10  1  0.508  0.249  0.894  1.0
  S  S11  1  0.008  0.251  0.106  1.0
  S  S12  1  0.857  0.058  0.374  1.0
  S  S13  1  0.357  0.442  0.626  1.0
  S  S14  1  0.643  0.558  0.126  1.0
  S  S15  1  0.143  0.942  0.874  1.0
  S  S16  1  0.143  0.942  0.626  1.0
  S  S17  1  0.643  0.558  0.374  1.0
  S  S18  1  0.357  0.442  0.874  1.0
  S  S19  1  0.857  0.058  0.126  1.0
  S  S20  1  0.728  0.114  0.250  1.0
  S  S21  1  0.228  0.386  0.750  1.0
  S  S22  1  0.772  0.614  0.250  1.0
  S  S23  1  0.272  0.886  0.750  1.0
  S  S24  1  0.247  0.172  0.140  1.0
  S  S25  1  0.747  0.328  0.860  1.0
  S  S26  1  0.253  0.672  0.360  1.0
  S  S27  1  0.753  0.828  0.640  1.0
  S  S28  1  0.753  0.828  0.860  1.0
  S  S29  1  0.253  0.672  0.140  1.0
  S  S30  1  0.747  0.328  0.640  1.0
  S  S31  1  0.247  0.172  0.360  1.0
  N  N32  1  0.756  0.911  0.750  1.0
  N  N33  1  0.256  0.589  0.250  1.0
  N  N34  1  0.744  0.411  0.750  1.0
  N  N35  1  0.244  0.089  0.250  1.0
[/CIF]
.