The structure described by NaBrO3 crystallizes in the cubic P2_13 space group. Na(1) is bonded to six equivalent O(1) atoms to form corner-sharing NaO6 octahedra. The corner-sharing octahedral tilt angles are 62°. O(1) is bonded in a trigonal planar geometry to two equivalent Na(1) and one Br(1) atom. Br(1) is bonded in a trigonal non-coplanar geometry to three equivalent O(1) atoms. is represented by the CIF card [CIF]
data_NaBrO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.640
_cell_length_b   6.640
_cell_length_c   6.640
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   292.775
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.079  0.079  0.079  1.0
  Na  Na1  1  0.421  0.921  0.579  1.0
  Na  Na2  1  0.579  0.421  0.921  1.0
  Na  Na3  1  0.921  0.579  0.421  1.0
  Br  Br4  1  0.403  0.403  0.403  1.0
  Br  Br5  1  0.097  0.597  0.903  1.0
  Br  Br6  1  0.903  0.097  0.597  1.0
  Br  Br7  1  0.597  0.903  0.097  1.0
  O  O8  1  0.217  0.401  0.006  1.0
  O  O9  1  0.717  0.099  0.994  1.0
  O  O10  1  0.783  0.901  0.494  1.0
  O  O11  1  0.099  0.994  0.717  1.0
  O  O12  1  0.494  0.783  0.901  1.0
  O  O13  1  0.994  0.717  0.099  1.0
  O  O14  1  0.401  0.006  0.217  1.0
  O  O15  1  0.006  0.217  0.401  1.0
  O  O16  1  0.283  0.599  0.506  1.0
  O  O17  1  0.506  0.283  0.599  1.0
  O  O18  1  0.599  0.506  0.283  1.0
  O  O19  1  0.901  0.494  0.783  1.0
[/CIF]
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The structure described by NaBrO3 crystallizes in the cubic P2_13 space group. Na(1) is bonded to six equivalent O(1) atoms to form corner-sharing NaO6 octahedra. The corner-sharing octahedral tilt angles are 62°. O(1) is bonded in a trigonal planar geometry to two equivalent Na(1) and one Br(1) atom. Br(1) is bonded in a trigonal non-coplanar geometry to three equivalent O(1) atoms. is represented by the CIF card [CIF]
data_NaBrO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.640
_cell_length_b   6.640
_cell_length_c   6.640
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   292.775
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.079  0.079  0.079  1.0
  Na  Na1  1  0.421  0.921  0.579  1.0
  Na  Na2  1  0.579  0.421  0.921  1.0
  Na  Na3  1  0.921  0.579  0.421  1.0
  Br  Br4  1  0.403  0.403  0.403  1.0
  Br  Br5  1  0.097  0.597  0.903  1.0
  Br  Br6  1  0.903  0.097  0.597  1.0
  Br  Br7  1  0.597  0.903  0.097  1.0
  O  O8  1  0.217  0.401  0.006  1.0
  O  O9  1  0.717  0.099  0.994  1.0
  O  O10  1  0.783  0.901  0.494  1.0
  O  O11  1  0.099  0.994  0.717  1.0
  O  O12  1  0.494  0.783  0.901  1.0
  O  O13  1  0.994  0.717  0.099  1.0
  O  O14  1  0.401  0.006  0.217  1.0
  O  O15  1  0.006  0.217  0.401  1.0
  O  O16  1  0.283  0.599  0.506  1.0
  O  O17  1  0.506  0.283  0.599  1.0
  O  O18  1  0.599  0.506  0.283  1.0
  O  O19  1  0.901  0.494  0.783  1.0
[/CIF]
.