The material structure described by IrN5Cl2AuCl4 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four AuCl4 clusters and four IrN5Cl2 clusters. In two of the AuCl4 clusters, Au(1) is bonded in a square co-planar geometry to two equivalent Cl(2) and two equivalent Cl(5) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(5) is bonded in a single-bond geometry to one Au(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Au(1) atom. In two of the AuCl4 clusters, Au(2) is bonded in a square co-planar geometry to four equivalent Cl(1,4) atoms. Cl(1,4) is bonded in a single-bond geometry to one Au(2) atom. In each IrN5Cl2 cluster, Ir(1) is bonded in a distorted octahedral geometry to one N(2), two equivalent N(1), two equivalent N(3), and one Cl(3) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Ir(1) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one Ir(1) and one Cl(6) atom. In the third N site, N(3) is bonded in a single-bond geometry to one Ir(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one Ir(1) atom. In the second Cl site, Cl(6) is bonded in a single-bond geometry to one N(2) atom. is represented by the CIF card [CIF]
data_IrAuN5Cl6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.578
_cell_length_b   8.822
_cell_length_c   10.729
_cell_angle_alpha   105.935
_cell_angle_beta   90.000
_cell_angle_gamma   119.089
_symmetry_Int_Tables_number   1
_cell_volume   673.622
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ir  Ir0  1  0.250  0.499  0.726  1.0
  Ir  Ir1  1  0.750  0.501  0.274  1.0
  Au  Au2  1  0.000  0.000  0.000  1.0
  Au  Au3  1  0.500  0.000  0.500  1.0
  N  N4  1  0.131  0.615  0.728  1.0
  N  N5  1  0.484  0.615  0.728  1.0
  N  N6  1  0.869  0.385  0.272  1.0
  N  N7  1  0.516  0.385  0.272  1.0
  N  N8  1  0.316  0.632  0.947  1.0
  N  N9  1  0.684  0.368  0.053  1.0
  N  N10  1  0.000  0.324  0.776  1.0
  N  N11  1  0.324  0.324  0.776  1.0
  N  N12  1  1.000  0.676  0.224  1.0
  N  N13  1  0.676  0.676  0.224  1.0
  Cl  Cl14  1  0.521  0.043  0.297  1.0
  Cl  Cl15  1  0.479  0.957  0.703  1.0
  Cl  Cl16  1  0.982  0.963  0.207  1.0
  Cl  Cl17  1  0.018  0.037  0.793  1.0
  Cl  Cl18  1  0.144  0.288  0.522  1.0
  Cl  Cl19  1  0.856  0.712  0.478  1.0
  Cl  Cl20  1  0.343  0.687  0.399  1.0
  Cl  Cl21  1  0.657  0.313  0.601  1.0
  Cl  Cl22  1  0.269  0.000  0.000  1.0
  Cl  Cl23  1  0.731  0.000  0.000  1.0
  Cl  Cl24  1  0.253  0.505  0.040  1.0
  Cl  Cl25  1  0.747  0.495  0.960  1.0
[/CIF]
.
The material structure described by IrN5Cl2AuCl4 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four AuCl4 clusters and four IrN5Cl2 clusters. In two of the AuCl4 clusters, Au(1) is bonded in a square co-planar geometry to two equivalent Cl(2) and two equivalent Cl(5) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(5) is bonded in a single-bond geometry to one Au(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Au(1) atom. In two of the AuCl4 clusters, Au(2) is bonded in a square co-planar geometry to four equivalent Cl(1,4) atoms. Cl(1,4) is bonded in a single-bond geometry to one Au(2) atom. In each IrN5Cl2 cluster, Ir(1) is bonded in a distorted octahedral geometry to one N(2), two equivalent N(1), two equivalent N(3), and one Cl(3) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Ir(1) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one Ir(1) and one Cl(6) atom. In the third N site, N(3) is bonded in a single-bond geometry to one Ir(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one Ir(1) atom. In the second Cl site, Cl(6) is bonded in a single-bond geometry to one N(2) atom. is represented by the CIF card [CIF]
data_IrAuN5Cl6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.578
_cell_length_b   8.822
_cell_length_c   10.729
_cell_angle_alpha   105.935
_cell_angle_beta   90.000
_cell_angle_gamma   119.089
_symmetry_Int_Tables_number   1
_cell_volume   673.622
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ir  Ir0  1  0.250  0.499  0.726  1.0
  Ir  Ir1  1  0.750  0.501  0.274  1.0
  Au  Au2  1  0.000  0.000  0.000  1.0
  Au  Au3  1  0.500  0.000  0.500  1.0
  N  N4  1  0.131  0.615  0.728  1.0
  N  N5  1  0.484  0.615  0.728  1.0
  N  N6  1  0.869  0.385  0.272  1.0
  N  N7  1  0.516  0.385  0.272  1.0
  N  N8  1  0.316  0.632  0.947  1.0
  N  N9  1  0.684  0.368  0.053  1.0
  N  N10  1  0.000  0.324  0.776  1.0
  N  N11  1  0.324  0.324  0.776  1.0
  N  N12  1  1.000  0.676  0.224  1.0
  N  N13  1  0.676  0.676  0.224  1.0
  Cl  Cl14  1  0.521  0.043  0.297  1.0
  Cl  Cl15  1  0.479  0.957  0.703  1.0
  Cl  Cl16  1  0.982  0.963  0.207  1.0
  Cl  Cl17  1  0.018  0.037  0.793  1.0
  Cl  Cl18  1  0.144  0.288  0.522  1.0
  Cl  Cl19  1  0.856  0.712  0.478  1.0
  Cl  Cl20  1  0.343  0.687  0.399  1.0
  Cl  Cl21  1  0.657  0.313  0.601  1.0
  Cl  Cl22  1  0.269  0.000  0.000  1.0
  Cl  Cl23  1  0.731  0.000  0.000  1.0
  Cl  Cl24  1  0.253  0.505  0.040  1.0
  Cl  Cl25  1  0.747  0.495  0.960  1.0
[/CIF]
.