The structure described by Sc16Os7Sc6Os crystallizes in the cubic Fm-3m space group. The structure consists of four Sc6Os clusters inside a Sc16Os7 framework. In each Sc6Os cluster, Sc(2) is bonded in a single-bond geometry to one Os(3) atom. Os(3) is bonded in an octahedral geometry to six equivalent Sc(2) atoms. In the Sc16Os7 framework, there are two inequivalent Sc sites. In the first Sc site, Sc(1) is bonded in a distorted trigonal planar geometry to three equivalent Os(1) atoms. In the second Sc site, Sc(3) is bonded to one Os(2) and three equivalent Os(1) atoms to form a mixture of distorted corner and edge-sharing ScOs4 tetrahedra. There are two inequivalent Os sites. In the first Os site, Os(2) is bonded in a body-centered cubic geometry to eight equivalent Sc(3) atoms. In the second Os site, Os(1) is bonded in a 8-coordinate geometry to four equivalent Sc(1) and four equivalent Sc(3) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sc11Os4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.443
_cell_length_b   9.443
_cell_length_c   9.443
_cell_angle_alpha   59.999
_cell_angle_beta   59.999
_cell_angle_gamma   59.999
_symmetry_Int_Tables_number   1
_cell_volume   595.321
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc0  1  0.845  0.845  0.845  1.0
  Sc  Sc1  1  0.155  0.155  0.534  1.0
  Sc  Sc2  1  0.155  0.534  0.155  1.0
  Sc  Sc3  1  0.534  0.155  0.155  1.0
  Sc  Sc4  1  0.845  0.466  0.845  1.0
  Sc  Sc5  1  0.466  0.845  0.845  1.0
  Sc  Sc6  1  0.845  0.845  0.466  1.0
  Sc  Sc7  1  0.155  0.155  0.155  1.0
  Sc  Sc8  1  0.801  0.199  0.199  1.0
  Sc  Sc9  1  0.801  0.801  0.199  1.0
  Sc  Sc10  1  0.199  0.199  0.801  1.0
  Sc  Sc11  1  0.801  0.199  0.801  1.0
  Sc  Sc12  1  0.199  0.801  0.199  1.0
  Sc  Sc13  1  0.199  0.801  0.801  1.0
  Sc  Sc14  1  0.383  0.383  0.383  1.0
  Sc  Sc15  1  0.617  0.617  0.149  1.0
  Sc  Sc16  1  0.149  0.617  0.617  1.0
  Sc  Sc17  1  0.617  0.149  0.617  1.0
  Sc  Sc18  1  0.851  0.383  0.383  1.0
  Sc  Sc19  1  0.383  0.851  0.383  1.0
  Sc  Sc20  1  0.383  0.383  0.851  1.0
  Sc  Sc21  1  0.617  0.617  0.617  1.0
  Os  Os22  1  0.500  0.000  0.500  1.0
  Os  Os23  1  0.000  0.500  0.000  1.0
  Os  Os24  1  0.000  0.500  0.500  1.0
  Os  Os25  1  0.500  0.500  0.000  1.0
  Os  Os26  1  0.000  0.000  0.500  1.0
  Os  Os27  1  0.500  0.000  0.000  1.0
  Os  Os28  1  0.500  0.500  0.500  1.0
  Os  Os29  1  0.000  0.000  0.000  1.0
[/CIF]
.
The structure described by Sc16Os7Sc6Os crystallizes in the cubic Fm-3m space group. The structure consists of four Sc6Os clusters inside a Sc16Os7 framework. In each Sc6Os cluster, Sc(2) is bonded in a single-bond geometry to one Os(3) atom. Os(3) is bonded in an octahedral geometry to six equivalent Sc(2) atoms. In the Sc16Os7 framework, there are two inequivalent Sc sites. In the first Sc site, Sc(1) is bonded in a distorted trigonal planar geometry to three equivalent Os(1) atoms. In the second Sc site, Sc(3) is bonded to one Os(2) and three equivalent Os(1) atoms to form a mixture of distorted corner and edge-sharing ScOs4 tetrahedra. There are two inequivalent Os sites. In the first Os site, Os(2) is bonded in a body-centered cubic geometry to eight equivalent Sc(3) atoms. In the second Os site, Os(1) is bonded in a 8-coordinate geometry to four equivalent Sc(1) and four equivalent Sc(3) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sc11Os4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.443
_cell_length_b   9.443
_cell_length_c   9.443
_cell_angle_alpha   59.999
_cell_angle_beta   59.999
_cell_angle_gamma   59.999
_symmetry_Int_Tables_number   1
_cell_volume   595.321
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc0  1  0.845  0.845  0.845  1.0
  Sc  Sc1  1  0.155  0.155  0.534  1.0
  Sc  Sc2  1  0.155  0.534  0.155  1.0
  Sc  Sc3  1  0.534  0.155  0.155  1.0
  Sc  Sc4  1  0.845  0.466  0.845  1.0
  Sc  Sc5  1  0.466  0.845  0.845  1.0
  Sc  Sc6  1  0.845  0.845  0.466  1.0
  Sc  Sc7  1  0.155  0.155  0.155  1.0
  Sc  Sc8  1  0.801  0.199  0.199  1.0
  Sc  Sc9  1  0.801  0.801  0.199  1.0
  Sc  Sc10  1  0.199  0.199  0.801  1.0
  Sc  Sc11  1  0.801  0.199  0.801  1.0
  Sc  Sc12  1  0.199  0.801  0.199  1.0
  Sc  Sc13  1  0.199  0.801  0.801  1.0
  Sc  Sc14  1  0.383  0.383  0.383  1.0
  Sc  Sc15  1  0.617  0.617  0.149  1.0
  Sc  Sc16  1  0.149  0.617  0.617  1.0
  Sc  Sc17  1  0.617  0.149  0.617  1.0
  Sc  Sc18  1  0.851  0.383  0.383  1.0
  Sc  Sc19  1  0.383  0.851  0.383  1.0
  Sc  Sc20  1  0.383  0.383  0.851  1.0
  Sc  Sc21  1  0.617  0.617  0.617  1.0
  Os  Os22  1  0.500  0.000  0.500  1.0
  Os  Os23  1  0.000  0.500  0.000  1.0
  Os  Os24  1  0.000  0.500  0.500  1.0
  Os  Os25  1  0.500  0.500  0.000  1.0
  Os  Os26  1  0.000  0.000  0.500  1.0
  Os  Os27  1  0.500  0.000  0.000  1.0
  Os  Os28  1  0.500  0.500  0.500  1.0
  Os  Os29  1  0.000  0.000  0.000  1.0
[/CIF]
.