The structure described by CoN6ClCl2 crystallizes in the cubic Fm-3m space group. The structure consists of eight hydrochloric acid atoms inside a CoN6Cl framework. In the CoN6Cl framework, Co(1) is bonded to six equivalent N(1) atoms to form CoN6 octahedra that share corners with six equivalent Cl(1)N6 octahedra. The corner-sharing octahedra are not tilted. N(1) is bonded in a distorted single-bond geometry to one Co(1) and one Cl(1) atom. Cl(1) is bonded to six equivalent N(1) atoms to form ClN6 octahedra that share corners with six equivalent Co(1)N6 octahedra. The corner-sharing octahedra are not tilted. is represented by the CIF file [CIF]
data_Co(N2Cl)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.702
_cell_length_b   5.702
_cell_length_c   5.702
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   131.085
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.000  0.000  0.000  1.0
  N  N1  1  0.778  0.778  0.222  1.0
  N  N2  1  0.222  0.778  0.222  1.0
  N  N3  1  0.778  0.222  0.222  1.0
  N  N4  1  0.222  0.222  0.778  1.0
  N  N5  1  0.778  0.222  0.778  1.0
  N  N6  1  0.222  0.778  0.778  1.0
  Cl  Cl7  1  0.500  0.500  0.500  1.0
  Cl  Cl8  1  0.750  0.750  0.750  1.0
  Cl  Cl9  1  0.250  0.250  0.250  1.0
[/CIF]
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The structure described by CoN6ClCl2 crystallizes in the cubic Fm-3m space group. The structure consists of eight hydrochloric acid atoms inside a CoN6Cl framework. In the CoN6Cl framework, Co(1) is bonded to six equivalent N(1) atoms to form CoN6 octahedra that share corners with six equivalent Cl(1)N6 octahedra. The corner-sharing octahedra are not tilted. N(1) is bonded in a distorted single-bond geometry to one Co(1) and one Cl(1) atom. Cl(1) is bonded to six equivalent N(1) atoms to form ClN6 octahedra that share corners with six equivalent Co(1)N6 octahedra. The corner-sharing octahedra are not tilted. is represented by the CIF file [CIF]
data_Co(N2Cl)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.702
_cell_length_b   5.702
_cell_length_c   5.702
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   131.085
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.000  0.000  0.000  1.0
  N  N1  1  0.778  0.778  0.222  1.0
  N  N2  1  0.222  0.778  0.222  1.0
  N  N3  1  0.778  0.222  0.222  1.0
  N  N4  1  0.222  0.222  0.778  1.0
  N  N5  1  0.778  0.222  0.778  1.0
  N  N6  1  0.222  0.778  0.778  1.0
  Cl  Cl7  1  0.500  0.500  0.500  1.0
  Cl  Cl8  1  0.750  0.750  0.750  1.0
  Cl  Cl9  1  0.250  0.250  0.250  1.0
[/CIF]
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