The crystal structure described by VBO4 crystallizes in the monoclinic P2_1/c space group. V(1) is bonded in a 6-coordinate geometry to one O(1), one O(4), two equivalent O(2), and two equivalent O(3) atoms. B(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one V(1) and one B(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent V(1) and one B(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to two equivalent V(1) atoms. In the fourth O site, O(4) is bonded in a linear geometry to one V(1) and one B(1) atom. is represented by the CIF card [CIF]
data_VBO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.047
_cell_length_b   5.036
_cell_length_c   11.397
_cell_angle_alpha   70.090
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   272.385
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.742  0.313  0.073  1.0
  V  V1  1  0.758  0.313  0.573  1.0
  V  V2  1  0.242  0.687  0.427  1.0
  V  V3  1  0.258  0.687  0.927  1.0
  B  B4  1  0.529  0.273  0.328  1.0
  B  B5  1  0.029  0.727  0.172  1.0
  B  B6  1  0.971  0.273  0.828  1.0
  B  B7  1  0.471  0.727  0.672  1.0
  O  O8  1  0.346  0.611  0.783  1.0
  O  O9  1  0.946  0.401  0.920  1.0
  O  O10  1  0.446  0.599  0.580  1.0
  O  O11  1  0.450  0.242  0.026  1.0
  O  O12  1  0.846  0.389  0.717  1.0
  O  O13  1  0.392  0.022  0.355  1.0
  O  O14  1  0.892  0.978  0.145  1.0
  O  O15  1  0.950  0.758  0.474  1.0
  O  O16  1  0.050  0.242  0.526  1.0
  O  O17  1  0.108  0.022  0.855  1.0
  O  O18  1  0.608  0.978  0.645  1.0
  O  O19  1  0.154  0.611  0.283  1.0
  O  O20  1  0.550  0.758  0.974  1.0
  O  O21  1  0.554  0.401  0.420  1.0
  O  O22  1  0.054  0.599  0.080  1.0
  O  O23  1  0.654  0.389  0.217  1.0
[/CIF]
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The crystal structure described by VBO4 crystallizes in the monoclinic P2_1/c space group. V(1) is bonded in a 6-coordinate geometry to one O(1), one O(4), two equivalent O(2), and two equivalent O(3) atoms. B(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one V(1) and one B(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent V(1) and one B(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to two equivalent V(1) atoms. In the fourth O site, O(4) is bonded in a linear geometry to one V(1) and one B(1) atom. is represented by the CIF card [CIF]
data_VBO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.047
_cell_length_b   5.036
_cell_length_c   11.397
_cell_angle_alpha   70.090
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   272.385
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.742  0.313  0.073  1.0
  V  V1  1  0.758  0.313  0.573  1.0
  V  V2  1  0.242  0.687  0.427  1.0
  V  V3  1  0.258  0.687  0.927  1.0
  B  B4  1  0.529  0.273  0.328  1.0
  B  B5  1  0.029  0.727  0.172  1.0
  B  B6  1  0.971  0.273  0.828  1.0
  B  B7  1  0.471  0.727  0.672  1.0
  O  O8  1  0.346  0.611  0.783  1.0
  O  O9  1  0.946  0.401  0.920  1.0
  O  O10  1  0.446  0.599  0.580  1.0
  O  O11  1  0.450  0.242  0.026  1.0
  O  O12  1  0.846  0.389  0.717  1.0
  O  O13  1  0.392  0.022  0.355  1.0
  O  O14  1  0.892  0.978  0.145  1.0
  O  O15  1  0.950  0.758  0.474  1.0
  O  O16  1  0.050  0.242  0.526  1.0
  O  O17  1  0.108  0.022  0.855  1.0
  O  O18  1  0.608  0.978  0.645  1.0
  O  O19  1  0.154  0.611  0.283  1.0
  O  O20  1  0.550  0.758  0.974  1.0
  O  O21  1  0.554  0.401  0.420  1.0
  O  O22  1  0.054  0.599  0.080  1.0
  O  O23  1  0.654  0.389  0.217  1.0
[/CIF]
.