The material described by (Na)2NaSbCl6 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-23-5 atoms inside a NaSbCl6 framework. In the NaSbCl6 framework, Na(2) is bonded to six equivalent Cl(1) atoms to form NaCl6 octahedra that share corners with six equivalent Sb(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. Sb(1) is bonded to six equivalent Cl(1) atoms to form SbCl6 octahedra that share corners with six equivalent Na(2)Cl6 octahedra. The corner-sharing octahedra are not tilted. Cl(1) is bonded in a linear geometry to one Na(2) and one Sb(1) atom. is represented by the CIF card [CIF]
data_Na3SbCl6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.559
_cell_length_b   7.559
_cell_length_c   7.559
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   305.440
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.750  0.750  0.750  1.0
  Na  Na1  1  0.250  0.250  0.250  1.0
  Na  Na2  1  0.500  0.500  0.500  1.0
  Sb  Sb3  1  0.000  0.000  0.000  1.0
  Cl  Cl4  1  0.753  0.247  0.247  1.0
  Cl  Cl5  1  0.247  0.247  0.753  1.0
  Cl  Cl6  1  0.247  0.753  0.753  1.0
  Cl  Cl7  1  0.247  0.753  0.247  1.0
  Cl  Cl8  1  0.753  0.247  0.753  1.0
  Cl  Cl9  1  0.753  0.753  0.247  1.0
[/CIF]
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The material described by (Na)2NaSbCl6 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure consists of eight 7440-23-5 atoms inside a NaSbCl6 framework. In the NaSbCl6 framework, Na(2) is bonded to six equivalent Cl(1) atoms to form NaCl6 octahedra that share corners with six equivalent Sb(1)Cl6 octahedra. The corner-sharing octahedra are not tilted. Sb(1) is bonded to six equivalent Cl(1) atoms to form SbCl6 octahedra that share corners with six equivalent Na(2)Cl6 octahedra. The corner-sharing octahedra are not tilted. Cl(1) is bonded in a linear geometry to one Na(2) and one Sb(1) atom. is represented by the CIF card [CIF]
data_Na3SbCl6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.559
_cell_length_b   7.559
_cell_length_c   7.559
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   305.440
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.750  0.750  0.750  1.0
  Na  Na1  1  0.250  0.250  0.250  1.0
  Na  Na2  1  0.500  0.500  0.500  1.0
  Sb  Sb3  1  0.000  0.000  0.000  1.0
  Cl  Cl4  1  0.753  0.247  0.247  1.0
  Cl  Cl5  1  0.247  0.247  0.753  1.0
  Cl  Cl6  1  0.247  0.753  0.753  1.0
  Cl  Cl7  1  0.247  0.753  0.247  1.0
  Cl  Cl8  1  0.753  0.247  0.753  1.0
  Cl  Cl9  1  0.753  0.753  0.247  1.0
[/CIF]
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