The material described by AsF6SeCl3 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four AsF6 clusters and four SeCl3 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. There are six inequivalent F sites. In the first F site, F(6) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In each SeCl3 cluster, Se(1) is bonded in a distorted trigonal non-coplanar geometry to one Cl(1), one Cl(2), and one Cl(3) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Se(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Se(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Se(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_AsSe(ClF2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.612
_cell_length_b   7.893
_cell_length_c   12.202
_cell_angle_alpha   81.625
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   915.891
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.263  0.812  0.072  1.0
  As  As1  1  0.737  0.188  0.928  1.0
  As  As2  1  0.237  0.812  0.572  1.0
  As  As3  1  0.763  0.188  0.428  1.0
  Se  Se4  1  0.179  0.187  0.305  1.0
  Se  Se5  1  0.821  0.813  0.695  1.0
  Se  Se6  1  0.321  0.187  0.805  1.0
  Se  Se7  1  0.679  0.813  0.195  1.0
  Cl  Cl8  1  0.562  0.716  0.340  1.0
  Cl  Cl9  1  0.113  0.215  0.742  1.0
  Cl  Cl10  1  0.613  0.785  0.758  1.0
  Cl  Cl11  1  0.887  0.785  0.258  1.0
  Cl  Cl12  1  0.438  0.284  0.660  1.0
  Cl  Cl13  1  0.173  0.402  0.394  1.0
  Cl  Cl14  1  0.062  0.284  0.160  1.0
  Cl  Cl15  1  0.387  0.215  0.242  1.0
  Cl  Cl16  1  0.938  0.716  0.840  1.0
  Cl  Cl17  1  0.827  0.598  0.606  1.0
  Cl  Cl18  1  0.673  0.598  0.106  1.0
  Cl  Cl19  1  0.327  0.402  0.894  1.0
  F  F20  1  0.285  0.017  0.498  1.0
  F  F21  1  0.785  0.983  0.002  1.0
  F  F22  1  0.071  0.900  0.601  1.0
  F  F23  1  0.332  0.756  0.947  1.0
  F  F24  1  0.901  0.272  0.956  1.0
  F  F25  1  0.215  0.017  0.998  1.0
  F  F26  1  0.186  0.613  0.646  1.0
  F  F27  1  0.668  0.244  0.053  1.0
  F  F28  1  0.686  0.387  0.854  1.0
  F  F29  1  0.099  0.728  0.044  1.0
  F  F30  1  0.571  0.100  0.899  1.0
  F  F31  1  0.599  0.272  0.456  1.0
  F  F32  1  0.168  0.756  0.447  1.0
  F  F33  1  0.929  0.100  0.399  1.0
  F  F34  1  0.814  0.387  0.354  1.0
  F  F35  1  0.715  0.983  0.502  1.0
  F  F36  1  0.303  0.878  0.695  1.0
  F  F37  1  0.697  0.122  0.305  1.0
  F  F38  1  0.401  0.728  0.544  1.0
  F  F39  1  0.832  0.244  0.553  1.0
  F  F40  1  0.429  0.900  0.101  1.0
  F  F41  1  0.197  0.878  0.195  1.0
  F  F42  1  0.314  0.613  0.146  1.0
  F  F43  1  0.803  0.122  0.805  1.0
[/CIF]
.
The material described by AsF6SeCl3 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four AsF6 clusters and four SeCl3 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. There are six inequivalent F sites. In the first F site, F(6) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In each SeCl3 cluster, Se(1) is bonded in a distorted trigonal non-coplanar geometry to one Cl(1), one Cl(2), and one Cl(3) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Se(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Se(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Se(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_AsSe(ClF2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.612
_cell_length_b   7.893
_cell_length_c   12.202
_cell_angle_alpha   81.625
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   915.891
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.263  0.812  0.072  1.0
  As  As1  1  0.737  0.188  0.928  1.0
  As  As2  1  0.237  0.812  0.572  1.0
  As  As3  1  0.763  0.188  0.428  1.0
  Se  Se4  1  0.179  0.187  0.305  1.0
  Se  Se5  1  0.821  0.813  0.695  1.0
  Se  Se6  1  0.321  0.187  0.805  1.0
  Se  Se7  1  0.679  0.813  0.195  1.0
  Cl  Cl8  1  0.562  0.716  0.340  1.0
  Cl  Cl9  1  0.113  0.215  0.742  1.0
  Cl  Cl10  1  0.613  0.785  0.758  1.0
  Cl  Cl11  1  0.887  0.785  0.258  1.0
  Cl  Cl12  1  0.438  0.284  0.660  1.0
  Cl  Cl13  1  0.173  0.402  0.394  1.0
  Cl  Cl14  1  0.062  0.284  0.160  1.0
  Cl  Cl15  1  0.387  0.215  0.242  1.0
  Cl  Cl16  1  0.938  0.716  0.840  1.0
  Cl  Cl17  1  0.827  0.598  0.606  1.0
  Cl  Cl18  1  0.673  0.598  0.106  1.0
  Cl  Cl19  1  0.327  0.402  0.894  1.0
  F  F20  1  0.285  0.017  0.498  1.0
  F  F21  1  0.785  0.983  0.002  1.0
  F  F22  1  0.071  0.900  0.601  1.0
  F  F23  1  0.332  0.756  0.947  1.0
  F  F24  1  0.901  0.272  0.956  1.0
  F  F25  1  0.215  0.017  0.998  1.0
  F  F26  1  0.186  0.613  0.646  1.0
  F  F27  1  0.668  0.244  0.053  1.0
  F  F28  1  0.686  0.387  0.854  1.0
  F  F29  1  0.099  0.728  0.044  1.0
  F  F30  1  0.571  0.100  0.899  1.0
  F  F31  1  0.599  0.272  0.456  1.0
  F  F32  1  0.168  0.756  0.447  1.0
  F  F33  1  0.929  0.100  0.399  1.0
  F  F34  1  0.814  0.387  0.354  1.0
  F  F35  1  0.715  0.983  0.502  1.0
  F  F36  1  0.303  0.878  0.695  1.0
  F  F37  1  0.697  0.122  0.305  1.0
  F  F38  1  0.401  0.728  0.544  1.0
  F  F39  1  0.832  0.244  0.553  1.0
  F  F40  1  0.429  0.900  0.101  1.0
  F  F41  1  0.197  0.878  0.195  1.0
  F  F42  1  0.314  0.613  0.146  1.0
  F  F43  1  0.803  0.122  0.805  1.0
[/CIF]
.