The structure described by LiGd(MoO4)2 crystallizes in the monoclinic P2/c space group. Li(1) is bonded in a 4-coordinate geometry to two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms. Gd(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms. Mo(1) is bonded in a 6-coordinate geometry to one O(2), one O(4), two equivalent O(1), and two equivalent O(3) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Gd(1) and two equivalent Mo(1) atoms. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Li(1), one Gd(1), and one Mo(1) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Li(1) and two equivalent Mo(1) atoms. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Li(1), one Gd(1), and one Mo(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiGd(MoO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.947
_cell_length_b   5.083
_cell_length_c   11.086
_cell_angle_alpha   66.698
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   307.740
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.705  0.000  0.750  1.0
  Li  Li1  1  0.295  0.000  0.250  1.0
  Gd  Gd2  1  0.292  0.500  0.750  1.0
  Gd  Gd3  1  0.708  0.500  0.250  1.0
  Mo  Mo4  1  0.818  0.734  0.521  1.0
  Mo  Mo5  1  0.182  0.266  0.479  1.0
  Mo  Mo6  1  0.818  0.266  0.979  1.0
  Mo  Mo7  1  0.182  0.734  0.021  1.0
  O  O8  1  0.896  0.854  0.094  1.0
  O  O9  1  0.104  0.146  0.906  1.0
  O  O10  1  0.896  0.146  0.406  1.0
  O  O11  1  0.104  0.854  0.594  1.0
  O  O12  1  0.364  0.721  0.892  1.0
  O  O13  1  0.636  0.279  0.108  1.0
  O  O14  1  0.364  0.279  0.608  1.0
  O  O15  1  0.636  0.721  0.392  1.0
  O  O16  1  0.909  0.639  0.886  1.0
  O  O17  1  0.091  0.361  0.114  1.0
  O  O18  1  0.909  0.361  0.614  1.0
  O  O19  1  0.091  0.639  0.386  1.0
  O  O20  1  0.623  0.776  0.636  1.0
  O  O21  1  0.377  0.224  0.364  1.0
  O  O22  1  0.623  0.224  0.864  1.0
  O  O23  1  0.377  0.776  0.136  1.0
[/CIF]
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The structure described by LiGd(MoO4)2 crystallizes in the monoclinic P2/c space group. Li(1) is bonded in a 4-coordinate geometry to two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms. Gd(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms. Mo(1) is bonded in a 6-coordinate geometry to one O(2), one O(4), two equivalent O(1), and two equivalent O(3) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Gd(1) and two equivalent Mo(1) atoms. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Li(1), one Gd(1), and one Mo(1) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Li(1) and two equivalent Mo(1) atoms. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Li(1), one Gd(1), and one Mo(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiGd(MoO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.947
_cell_length_b   5.083
_cell_length_c   11.086
_cell_angle_alpha   66.698
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   307.740
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.705  0.000  0.750  1.0
  Li  Li1  1  0.295  0.000  0.250  1.0
  Gd  Gd2  1  0.292  0.500  0.750  1.0
  Gd  Gd3  1  0.708  0.500  0.250  1.0
  Mo  Mo4  1  0.818  0.734  0.521  1.0
  Mo  Mo5  1  0.182  0.266  0.479  1.0
  Mo  Mo6  1  0.818  0.266  0.979  1.0
  Mo  Mo7  1  0.182  0.734  0.021  1.0
  O  O8  1  0.896  0.854  0.094  1.0
  O  O9  1  0.104  0.146  0.906  1.0
  O  O10  1  0.896  0.146  0.406  1.0
  O  O11  1  0.104  0.854  0.594  1.0
  O  O12  1  0.364  0.721  0.892  1.0
  O  O13  1  0.636  0.279  0.108  1.0
  O  O14  1  0.364  0.279  0.608  1.0
  O  O15  1  0.636  0.721  0.392  1.0
  O  O16  1  0.909  0.639  0.886  1.0
  O  O17  1  0.091  0.361  0.114  1.0
  O  O18  1  0.909  0.361  0.614  1.0
  O  O19  1  0.091  0.639  0.386  1.0
  O  O20  1  0.623  0.776  0.636  1.0
  O  O21  1  0.377  0.224  0.364  1.0
  O  O22  1  0.623  0.224  0.864  1.0
  O  O23  1  0.377  0.776  0.136  1.0
[/CIF]
.