The compound described by Li2WO4 crystallizes in the monoclinic C2/c space group. Li(1) is bonded in a 6-coordinate geometry to three equivalent O(1) and three equivalent O(2) atoms. W(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form distorted edge-sharing WO6 octahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded to three equivalent Li(1) and one W(1) atom to form a mixture of edge and corner-sharing OLi3W trigonal pyramids. In the second O site, O(2) is bonded in a 5-coordinate geometry to three equivalent Li(1) and two equivalent W(1) atoms. is represented by the CIF file [CIF]
data_Li2WO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.004
_cell_length_b   5.707
_cell_length_c   5.707
_cell_angle_alpha   62.218
_cell_angle_beta   88.482
_cell_angle_gamma   88.482
_symmetry_Int_Tables_number   1
_cell_volume   144.138
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.264  0.452  0.152  1.0
  Li  Li1  1  0.236  0.848  0.548  1.0
  Li  Li2  1  0.736  0.548  0.848  1.0
  Li  Li3  1  0.764  0.152  0.452  1.0
  W  W4  1  0.250  0.172  0.828  1.0
  W  W5  1  0.750  0.828  0.172  1.0
  O  O6  1  0.875  0.770  0.487  1.0
  O  O7  1  0.375  0.487  0.770  1.0
  O  O8  1  0.433  0.005  0.208  1.0
  O  O9  1  0.067  0.792  0.995  1.0
  O  O10  1  0.567  0.995  0.792  1.0
  O  O11  1  0.933  0.208  0.005  1.0
  O  O12  1  0.125  0.230  0.513  1.0
  O  O13  1  0.625  0.513  0.230  1.0
[/CIF]
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The compound described by Li2WO4 crystallizes in the monoclinic C2/c space group. Li(1) is bonded in a 6-coordinate geometry to three equivalent O(1) and three equivalent O(2) atoms. W(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form distorted edge-sharing WO6 octahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded to three equivalent Li(1) and one W(1) atom to form a mixture of edge and corner-sharing OLi3W trigonal pyramids. In the second O site, O(2) is bonded in a 5-coordinate geometry to three equivalent Li(1) and two equivalent W(1) atoms. is represented by the CIF file [CIF]
data_Li2WO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.004
_cell_length_b   5.707
_cell_length_c   5.707
_cell_angle_alpha   62.218
_cell_angle_beta   88.482
_cell_angle_gamma   88.482
_symmetry_Int_Tables_number   1
_cell_volume   144.138
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.264  0.452  0.152  1.0
  Li  Li1  1  0.236  0.848  0.548  1.0
  Li  Li2  1  0.736  0.548  0.848  1.0
  Li  Li3  1  0.764  0.152  0.452  1.0
  W  W4  1  0.250  0.172  0.828  1.0
  W  W5  1  0.750  0.828  0.172  1.0
  O  O6  1  0.875  0.770  0.487  1.0
  O  O7  1  0.375  0.487  0.770  1.0
  O  O8  1  0.433  0.005  0.208  1.0
  O  O9  1  0.067  0.792  0.995  1.0
  O  O10  1  0.567  0.995  0.792  1.0
  O  O11  1  0.933  0.208  0.005  1.0
  O  O12  1  0.125  0.230  0.513  1.0
  O  O13  1  0.625  0.513  0.230  1.0
[/CIF]
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