The material structure described by TmWO4Cl crystallizes in the triclinic P-1 space group. Tm(1) is bonded in a 7-coordinate geometry to one O(1), one O(2), one O(3), two equivalent O(4), and two equivalent Cl(1) atoms. W(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a linear geometry to one Tm(1) and one W(1) atom. In the second O site, O(2) is bonded in a linear geometry to one Tm(1) and one W(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Tm(1) and one W(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to two equivalent Tm(1) and one W(1) atom. Cl(1) is bonded in a water-like geometry to two equivalent Tm(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_TmWClO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.051
_cell_length_b   6.566
_cell_length_c   6.975
_cell_angle_alpha   73.798
_cell_angle_beta   77.251
_cell_angle_gamma   70.733
_symmetry_Int_Tables_number   1
_cell_volume   248.703
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tm  Tm0  1  0.239  0.205  0.868  1.0
  Tm  Tm1  1  0.761  0.795  0.132  1.0
  W  W2  1  0.377  0.355  0.265  1.0
  W  W3  1  0.623  0.645  0.735  1.0
  Cl  Cl4  1  0.006  0.024  0.224  1.0
  Cl  Cl5  1  0.994  0.976  0.776  1.0
  O  O6  1  0.344  0.258  0.535  1.0
  O  O7  1  0.656  0.742  0.465  1.0
  O  O8  1  0.427  0.471  0.807  1.0
  O  O9  1  0.573  0.529  0.193  1.0
  O  O10  1  0.910  0.483  0.810  1.0
  O  O11  1  0.090  0.517  0.190  1.0
  O  O12  1  0.480  0.125  0.132  1.0
  O  O13  1  0.520  0.875  0.868  1.0
[/CIF]
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The material structure described by TmWO4Cl crystallizes in the triclinic P-1 space group. Tm(1) is bonded in a 7-coordinate geometry to one O(1), one O(2), one O(3), two equivalent O(4), and two equivalent Cl(1) atoms. W(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a linear geometry to one Tm(1) and one W(1) atom. In the second O site, O(2) is bonded in a linear geometry to one Tm(1) and one W(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Tm(1) and one W(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to two equivalent Tm(1) and one W(1) atom. Cl(1) is bonded in a water-like geometry to two equivalent Tm(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_TmWClO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.051
_cell_length_b   6.566
_cell_length_c   6.975
_cell_angle_alpha   73.798
_cell_angle_beta   77.251
_cell_angle_gamma   70.733
_symmetry_Int_Tables_number   1
_cell_volume   248.703
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tm  Tm0  1  0.239  0.205  0.868  1.0
  Tm  Tm1  1  0.761  0.795  0.132  1.0
  W  W2  1  0.377  0.355  0.265  1.0
  W  W3  1  0.623  0.645  0.735  1.0
  Cl  Cl4  1  0.006  0.024  0.224  1.0
  Cl  Cl5  1  0.994  0.976  0.776  1.0
  O  O6  1  0.344  0.258  0.535  1.0
  O  O7  1  0.656  0.742  0.465  1.0
  O  O8  1  0.427  0.471  0.807  1.0
  O  O9  1  0.573  0.529  0.193  1.0
  O  O10  1  0.910  0.483  0.810  1.0
  O  O11  1  0.090  0.517  0.190  1.0
  O  O12  1  0.480  0.125  0.132  1.0
  O  O13  1  0.520  0.875  0.868  1.0
[/CIF]
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