The compound described by W2(CN2)3 crystallizes in the trigonal R-3c space group. W(1) is bonded to six equivalent N(1) atoms to form edge-sharing WN6 octahedra. C(1) is bonded in a linear geometry to two equivalent N(1) atoms. N(1) is bonded in a 3-coordinate geometry to two equivalent W(1) and one C(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_W2(CN2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.726
_cell_length_b   5.085
_cell_length_c   30.949
_cell_angle_alpha   90.000
_cell_angle_beta   164.119
_cell_angle_gamma   76.289
_symmetry_Int_Tables_number   1
_cell_volume   230.835
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  W  W0  1  0.001  1.000  0.167  1.0
  W  W1  1  0.001  1.000  0.667  1.0
  W  W2  1  0.999  0.000  0.833  1.0
  W  W3  1  0.999  0.000  0.333  1.0
  C  C4  1  0.004  0.665  0.085  1.0
  C  C5  1  1.000  0.665  0.750  1.0
  C  C6  1  0.996  0.669  0.415  1.0
  C  C7  1  0.004  0.331  0.585  1.0
  C  C8  1  0.996  0.335  0.915  1.0
  C  C9  1  1.000  0.335  0.250  1.0
  N  N10  1  0.964  0.697  0.111  1.0
  N  N11  1  0.054  0.643  0.808  1.0
  N  N12  1  0.982  0.660  0.450  1.0
  N  N13  1  0.964  0.340  0.611  1.0
  N  N14  1  0.982  0.358  0.950  1.0
  N  N15  1  0.054  0.303  0.308  1.0
  N  N16  1  0.036  0.303  0.889  1.0
  N  N17  1  0.946  0.357  0.192  1.0
  N  N18  1  0.018  0.340  0.550  1.0
  N  N19  1  0.036  0.660  0.389  1.0
  N  N20  1  0.018  0.642  0.050  1.0
  N  N21  1  0.946  0.697  0.692  1.0
[/CIF]
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The compound described by W2(CN2)3 crystallizes in the trigonal R-3c space group. W(1) is bonded to six equivalent N(1) atoms to form edge-sharing WN6 octahedra. C(1) is bonded in a linear geometry to two equivalent N(1) atoms. N(1) is bonded in a 3-coordinate geometry to two equivalent W(1) and one C(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_W2(CN2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.726
_cell_length_b   5.085
_cell_length_c   30.949
_cell_angle_alpha   90.000
_cell_angle_beta   164.119
_cell_angle_gamma   76.289
_symmetry_Int_Tables_number   1
_cell_volume   230.835
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  W  W0  1  0.001  1.000  0.167  1.0
  W  W1  1  0.001  1.000  0.667  1.0
  W  W2  1  0.999  0.000  0.833  1.0
  W  W3  1  0.999  0.000  0.333  1.0
  C  C4  1  0.004  0.665  0.085  1.0
  C  C5  1  1.000  0.665  0.750  1.0
  C  C6  1  0.996  0.669  0.415  1.0
  C  C7  1  0.004  0.331  0.585  1.0
  C  C8  1  0.996  0.335  0.915  1.0
  C  C9  1  1.000  0.335  0.250  1.0
  N  N10  1  0.964  0.697  0.111  1.0
  N  N11  1  0.054  0.643  0.808  1.0
  N  N12  1  0.982  0.660  0.450  1.0
  N  N13  1  0.964  0.340  0.611  1.0
  N  N14  1  0.982  0.358  0.950  1.0
  N  N15  1  0.054  0.303  0.308  1.0
  N  N16  1  0.036  0.303  0.889  1.0
  N  N17  1  0.946  0.357  0.192  1.0
  N  N18  1  0.018  0.340  0.550  1.0
  N  N19  1  0.036  0.660  0.389  1.0
  N  N20  1  0.018  0.642  0.050  1.0
  N  N21  1  0.946  0.697  0.692  1.0
[/CIF]
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