The structure described by Cl3PAuCl is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four Cl3PAuCl clusters. Au(1) is bonded in a linear geometry to one P(1) and one Cl(2) atom. P(1) is bonded in a tetrahedral geometry to one Au(1), one Cl(1), one Cl(3), and one Cl(4) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one P(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Au(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one P(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_PAuCl4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   14.768
_cell_length_b   6.196
_cell_length_c   7.454
_cell_angle_alpha   84.392
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   678.798
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.870  0.478  0.756  1.0
  P  P1  1  0.630  0.978  0.756  1.0
  P  P2  1  0.130  0.522  0.244  1.0
  P  P3  1  0.370  0.022  0.244  1.0
  Au  Au4  1  0.735  0.985  0.545  1.0
  Au  Au5  1  0.235  0.515  0.455  1.0
  Au  Au6  1  0.265  0.015  0.455  1.0
  Au  Au7  1  0.765  0.485  0.545  1.0
  Cl  Cl8  1  0.520  0.159  0.696  1.0
  Cl  Cl9  1  0.980  0.659  0.696  1.0
  Cl  Cl10  1  0.480  0.841  0.304  1.0
  Cl  Cl11  1  0.020  0.341  0.304  1.0
  Cl  Cl12  1  0.654  0.491  0.330  1.0
  Cl  Cl13  1  0.154  0.009  0.670  1.0
  Cl  Cl14  1  0.346  0.509  0.670  1.0
  Cl  Cl15  1  0.846  0.991  0.330  1.0
  Cl  Cl16  1  0.827  0.581  0.987  1.0
  Cl  Cl17  1  0.327  0.919  0.013  1.0
  Cl  Cl18  1  0.173  0.419  0.013  1.0
  Cl  Cl19  1  0.673  0.081  0.987  1.0
  Cl  Cl20  1  0.922  0.184  0.832  1.0
  Cl  Cl21  1  0.422  0.316  0.168  1.0
  Cl  Cl22  1  0.078  0.816  0.168  1.0
  Cl  Cl23  1  0.578  0.684  0.832  1.0
[/CIF]
.
The structure described by Cl3PAuCl is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four Cl3PAuCl clusters. Au(1) is bonded in a linear geometry to one P(1) and one Cl(2) atom. P(1) is bonded in a tetrahedral geometry to one Au(1), one Cl(1), one Cl(3), and one Cl(4) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one P(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Au(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one P(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_PAuCl4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   14.768
_cell_length_b   6.196
_cell_length_c   7.454
_cell_angle_alpha   84.392
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   678.798
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.870  0.478  0.756  1.0
  P  P1  1  0.630  0.978  0.756  1.0
  P  P2  1  0.130  0.522  0.244  1.0
  P  P3  1  0.370  0.022  0.244  1.0
  Au  Au4  1  0.735  0.985  0.545  1.0
  Au  Au5  1  0.235  0.515  0.455  1.0
  Au  Au6  1  0.265  0.015  0.455  1.0
  Au  Au7  1  0.765  0.485  0.545  1.0
  Cl  Cl8  1  0.520  0.159  0.696  1.0
  Cl  Cl9  1  0.980  0.659  0.696  1.0
  Cl  Cl10  1  0.480  0.841  0.304  1.0
  Cl  Cl11  1  0.020  0.341  0.304  1.0
  Cl  Cl12  1  0.654  0.491  0.330  1.0
  Cl  Cl13  1  0.154  0.009  0.670  1.0
  Cl  Cl14  1  0.346  0.509  0.670  1.0
  Cl  Cl15  1  0.846  0.991  0.330  1.0
  Cl  Cl16  1  0.827  0.581  0.987  1.0
  Cl  Cl17  1  0.327  0.919  0.013  1.0
  Cl  Cl18  1  0.173  0.419  0.013  1.0
  Cl  Cl19  1  0.673  0.081  0.987  1.0
  Cl  Cl20  1  0.922  0.184  0.832  1.0
  Cl  Cl21  1  0.422  0.316  0.168  1.0
  Cl  Cl22  1  0.078  0.816  0.168  1.0
  Cl  Cl23  1  0.578  0.684  0.832  1.0
[/CIF]
.