The material structure described by PdP2O6 crystallizes in the orthorhombic Pmna space group. Pd(1) is bonded in a square co-planar geometry to four equivalent O(2) atoms. P(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form corner-sharing PO4 tetrahedra. There are two inequivalent O sites. In the first O site, O(2) is bonded in a bent 120 degrees geometry to one Pd(1) and one P(1) atom. In the second O site, O(1) is bonded in a bent 120 degrees geometry to two equivalent P(1) atoms. is represented by the CIF card [CIF]
data_P2PdO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.258
_cell_length_b   4.577
_cell_length_c   12.488
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   243.420
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.500  0.500  0.672  1.0
  P  P1  1  0.000  0.500  0.828  1.0
  P  P2  1  0.500  0.500  0.328  1.0
  P  P3  1  0.000  0.500  0.172  1.0
  Pd  Pd4  1  0.500  0.000  0.500  1.0
  Pd  Pd5  1  0.000  0.000  0.000  1.0
  O  O6  1  0.750  0.647  0.750  1.0
  O  O7  1  0.250  0.353  0.750  1.0
  O  O8  1  0.250  0.353  0.250  1.0
  O  O9  1  0.750  0.647  0.250  1.0
  O  O10  1  0.829  0.264  0.886  1.0
  O  O11  1  0.329  0.736  0.614  1.0
  O  O12  1  0.829  0.264  0.114  1.0
  O  O13  1  0.329  0.736  0.386  1.0
  O  O14  1  0.671  0.264  0.386  1.0
  O  O15  1  0.171  0.736  0.114  1.0
  O  O16  1  0.171  0.736  0.886  1.0
  O  O17  1  0.671  0.264  0.614  1.0
[/CIF]
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The material structure described by PdP2O6 crystallizes in the orthorhombic Pmna space group. Pd(1) is bonded in a square co-planar geometry to four equivalent O(2) atoms. P(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form corner-sharing PO4 tetrahedra. There are two inequivalent O sites. In the first O site, O(2) is bonded in a bent 120 degrees geometry to one Pd(1) and one P(1) atom. In the second O site, O(1) is bonded in a bent 120 degrees geometry to two equivalent P(1) atoms. is represented by the CIF card [CIF]
data_P2PdO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.258
_cell_length_b   4.577
_cell_length_c   12.488
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   243.420
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.500  0.500  0.672  1.0
  P  P1  1  0.000  0.500  0.828  1.0
  P  P2  1  0.500  0.500  0.328  1.0
  P  P3  1  0.000  0.500  0.172  1.0
  Pd  Pd4  1  0.500  0.000  0.500  1.0
  Pd  Pd5  1  0.000  0.000  0.000  1.0
  O  O6  1  0.750  0.647  0.750  1.0
  O  O7  1  0.250  0.353  0.750  1.0
  O  O8  1  0.250  0.353  0.250  1.0
  O  O9  1  0.750  0.647  0.250  1.0
  O  O10  1  0.829  0.264  0.886  1.0
  O  O11  1  0.329  0.736  0.614  1.0
  O  O12  1  0.829  0.264  0.114  1.0
  O  O13  1  0.329  0.736  0.386  1.0
  O  O14  1  0.671  0.264  0.386  1.0
  O  O15  1  0.171  0.736  0.114  1.0
  O  O16  1  0.171  0.736  0.886  1.0
  O  O17  1  0.671  0.264  0.614  1.0
[/CIF]
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