The crystal structure described by CdVO3 crystallizes in the orthorhombic Pnma space group. V(1) is bonded to one O(1), one O(2), and three equivalent O(3) atoms to form distorted VO5 trigonal bipyramids that share corners with four equivalent Cd(1)O6 octahedra, corners with two equivalent V(1)O5 trigonal bipyramids, edges with two equivalent Cd(1)O6 octahedra, and edges with two equivalent V(1)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 52-67°. Cd(1) is bonded to one O(3), two equivalent O(2), and three equivalent O(1) atoms to form distorted CdO6 octahedra that share corners with four equivalent Cd(1)O6 octahedra, corners with four equivalent V(1)O5 trigonal bipyramids, edges with two equivalent Cd(1)O6 octahedra, and edges with two equivalent V(1)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 66°. There are three inequivalent O sites. In the first O site, O(1) is bonded to one V(1) and three equivalent Cd(1) atoms to form corner-sharing OVCd3 tetrahedra. In the second O site, O(2) is bonded in a 3-coordinate geometry to one V(1) and two equivalent Cd(1) atoms. In the third O site, O(3) is bonded in a 4-coordinate geometry to three equivalent V(1) and one Cd(1) atom. is represented by the CIF file [CIF]
data_VCdO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.590
_cell_length_b   5.265
_cell_length_c   14.284
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   269.954
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.750  0.581  0.419  1.0
  V  V1  1  0.750  0.919  0.919  1.0
  V  V2  1  0.250  0.419  0.581  1.0
  V  V3  1  0.250  0.081  0.081  1.0
  Cd  Cd4  1  0.750  0.626  0.179  1.0
  Cd  Cd5  1  0.250  0.126  0.321  1.0
  Cd  Cd6  1  0.250  0.374  0.821  1.0
  Cd  Cd7  1  0.750  0.874  0.679  1.0
  O  O8  1  0.250  0.887  0.193  1.0
  O  O9  1  0.750  0.891  0.389  1.0
  O  O10  1  0.750  0.539  0.556  1.0
  O  O11  1  0.750  0.961  0.056  1.0
  O  O12  1  0.250  0.461  0.444  1.0
  O  O13  1  0.750  0.113  0.807  1.0
  O  O14  1  0.250  0.391  0.111  1.0
  O  O15  1  0.250  0.039  0.944  1.0
  O  O16  1  0.250  0.613  0.693  1.0
  O  O17  1  0.250  0.109  0.611  1.0
  O  O18  1  0.750  0.387  0.307  1.0
  O  O19  1  0.750  0.609  0.889  1.0
[/CIF]
.
The crystal structure described by CdVO3 crystallizes in the orthorhombic Pnma space group. V(1) is bonded to one O(1), one O(2), and three equivalent O(3) atoms to form distorted VO5 trigonal bipyramids that share corners with four equivalent Cd(1)O6 octahedra, corners with two equivalent V(1)O5 trigonal bipyramids, edges with two equivalent Cd(1)O6 octahedra, and edges with two equivalent V(1)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 52-67°. Cd(1) is bonded to one O(3), two equivalent O(2), and three equivalent O(1) atoms to form distorted CdO6 octahedra that share corners with four equivalent Cd(1)O6 octahedra, corners with four equivalent V(1)O5 trigonal bipyramids, edges with two equivalent Cd(1)O6 octahedra, and edges with two equivalent V(1)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 66°. There are three inequivalent O sites. In the first O site, O(1) is bonded to one V(1) and three equivalent Cd(1) atoms to form corner-sharing OVCd3 tetrahedra. In the second O site, O(2) is bonded in a 3-coordinate geometry to one V(1) and two equivalent Cd(1) atoms. In the third O site, O(3) is bonded in a 4-coordinate geometry to three equivalent V(1) and one Cd(1) atom. is represented by the CIF file [CIF]
data_VCdO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.590
_cell_length_b   5.265
_cell_length_c   14.284
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   269.954
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.750  0.581  0.419  1.0
  V  V1  1  0.750  0.919  0.919  1.0
  V  V2  1  0.250  0.419  0.581  1.0
  V  V3  1  0.250  0.081  0.081  1.0
  Cd  Cd4  1  0.750  0.626  0.179  1.0
  Cd  Cd5  1  0.250  0.126  0.321  1.0
  Cd  Cd6  1  0.250  0.374  0.821  1.0
  Cd  Cd7  1  0.750  0.874  0.679  1.0
  O  O8  1  0.250  0.887  0.193  1.0
  O  O9  1  0.750  0.891  0.389  1.0
  O  O10  1  0.750  0.539  0.556  1.0
  O  O11  1  0.750  0.961  0.056  1.0
  O  O12  1  0.250  0.461  0.444  1.0
  O  O13  1  0.750  0.113  0.807  1.0
  O  O14  1  0.250  0.391  0.111  1.0
  O  O15  1  0.250  0.039  0.944  1.0
  O  O16  1  0.250  0.613  0.693  1.0
  O  O17  1  0.250  0.109  0.611  1.0
  O  O18  1  0.750  0.387  0.307  1.0
  O  O19  1  0.750  0.609  0.889  1.0
[/CIF]
.