The compound described by Pd6B is Indium-like structured and crystallizes in the orthorhombic Fddd space group. The structure is zero-dimensional and consists of eight Pd6B clusters. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a single-bond geometry to one B(1) atom. In the second Pd site, Pd(2) is bonded in a single-bond geometry to one B(1) atom. B(1) is bonded in an octahedral geometry to two equivalent Pd(2) and four equivalent Pd(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_BPd6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.010
_cell_length_b   5.010
_cell_length_c   9.077
_cell_angle_alpha   100.671
_cell_angle_beta   100.671
_cell_angle_gamma   109.209
_symmetry_Int_Tables_number   1
_cell_volume   203.873
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.375  0.125  0.250  1.0
  B  B1  1  0.625  0.875  0.750  1.0
  Pd  Pd2  1  0.035  0.784  0.081  1.0
  Pd  Pd3  1  0.203  0.954  0.419  1.0
  Pd  Pd4  1  0.716  0.465  0.419  1.0
  Pd  Pd5  1  0.546  0.297  0.081  1.0
  Pd  Pd6  1  0.965  0.216  0.919  1.0
  Pd  Pd7  1  0.797  0.046  0.581  1.0
  Pd  Pd8  1  0.284  0.535  0.581  1.0
  Pd  Pd9  1  0.454  0.703  0.919  1.0
  Pd  Pd10  1  0.120  0.380  0.250  1.0
  Pd  Pd11  1  0.630  0.870  0.250  1.0
  Pd  Pd12  1  0.880  0.620  0.750  1.0
  Pd  Pd13  1  0.370  0.130  0.750  1.0
[/CIF]
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The compound described by Pd6B is Indium-like structured and crystallizes in the orthorhombic Fddd space group. The structure is zero-dimensional and consists of eight Pd6B clusters. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a single-bond geometry to one B(1) atom. In the second Pd site, Pd(2) is bonded in a single-bond geometry to one B(1) atom. B(1) is bonded in an octahedral geometry to two equivalent Pd(2) and four equivalent Pd(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_BPd6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.010
_cell_length_b   5.010
_cell_length_c   9.077
_cell_angle_alpha   100.671
_cell_angle_beta   100.671
_cell_angle_gamma   109.209
_symmetry_Int_Tables_number   1
_cell_volume   203.873
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.375  0.125  0.250  1.0
  B  B1  1  0.625  0.875  0.750  1.0
  Pd  Pd2  1  0.035  0.784  0.081  1.0
  Pd  Pd3  1  0.203  0.954  0.419  1.0
  Pd  Pd4  1  0.716  0.465  0.419  1.0
  Pd  Pd5  1  0.546  0.297  0.081  1.0
  Pd  Pd6  1  0.965  0.216  0.919  1.0
  Pd  Pd7  1  0.797  0.046  0.581  1.0
  Pd  Pd8  1  0.284  0.535  0.581  1.0
  Pd  Pd9  1  0.454  0.703  0.919  1.0
  Pd  Pd10  1  0.120  0.380  0.250  1.0
  Pd  Pd11  1  0.630  0.870  0.250  1.0
  Pd  Pd12  1  0.880  0.620  0.750  1.0
  Pd  Pd13  1  0.370  0.130  0.750  1.0
[/CIF]
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