The crystal structure described by ZnSbF5 crystallizes in the monoclinic Cc space group. Zn(1) is bonded to one F(1), one F(2), one F(3), one F(4), and one F(5) atom to form distorted ZnF5 trigonal bipyramids that share corners with five equivalent Sb(1)F5 square pyramids. Sb(1) is bonded to one F(1), one F(2), one F(3), one F(4), and one F(5) atom to form SbF5 square pyramids that share corners with five equivalent Zn(1)F5 trigonal bipyramids. There are five inequivalent F sites. In the first F site, F(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one Sb(1) atom. In the second F site, F(2) is bonded in a bent 150 degrees geometry to one Zn(1) and one Sb(1) atom. In the third F site, F(3) is bonded in a bent 150 degrees geometry to one Zn(1) and one Sb(1) atom. In the fourth F site, F(4) is bonded in a bent 150 degrees geometry to one Zn(1) and one Sb(1) atom. In the fifth F site, F(5) is bonded in a bent 120 degrees geometry to one Zn(1) and one Sb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZnSbF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.642
_cell_length_b   5.642
_cell_length_c   8.980
_cell_angle_alpha   66.186
_cell_angle_beta   66.186
_cell_angle_gamma   70.606
_symmetry_Int_Tables_number   1
_cell_volume   234.289
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.497  0.499  0.743  1.0
  Zn  Zn1  1  0.499  0.497  0.243  1.0
  Sb  Sb2  1  0.016  0.977  0.989  1.0
  Sb  Sb3  1  0.977  0.016  0.489  1.0
  F  F4  1  0.144  0.857  0.191  1.0
  F  F5  1  0.857  0.144  0.691  1.0
  F  F6  1  0.202  0.324  0.369  1.0
  F  F7  1  0.690  0.777  0.169  1.0
  F  F8  1  0.759  0.299  0.086  1.0
  F  F9  1  0.631  0.307  0.456  1.0
  F  F10  1  0.307  0.631  0.956  1.0
  F  F11  1  0.299  0.759  0.586  1.0
  F  F12  1  0.324  0.202  0.869  1.0
  F  F13  1  0.777  0.690  0.669  1.0
[/CIF]
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The crystal structure described by ZnSbF5 crystallizes in the monoclinic Cc space group. Zn(1) is bonded to one F(1), one F(2), one F(3), one F(4), and one F(5) atom to form distorted ZnF5 trigonal bipyramids that share corners with five equivalent Sb(1)F5 square pyramids. Sb(1) is bonded to one F(1), one F(2), one F(3), one F(4), and one F(5) atom to form SbF5 square pyramids that share corners with five equivalent Zn(1)F5 trigonal bipyramids. There are five inequivalent F sites. In the first F site, F(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one Sb(1) atom. In the second F site, F(2) is bonded in a bent 150 degrees geometry to one Zn(1) and one Sb(1) atom. In the third F site, F(3) is bonded in a bent 150 degrees geometry to one Zn(1) and one Sb(1) atom. In the fourth F site, F(4) is bonded in a bent 150 degrees geometry to one Zn(1) and one Sb(1) atom. In the fifth F site, F(5) is bonded in a bent 120 degrees geometry to one Zn(1) and one Sb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZnSbF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.642
_cell_length_b   5.642
_cell_length_c   8.980
_cell_angle_alpha   66.186
_cell_angle_beta   66.186
_cell_angle_gamma   70.606
_symmetry_Int_Tables_number   1
_cell_volume   234.289
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.497  0.499  0.743  1.0
  Zn  Zn1  1  0.499  0.497  0.243  1.0
  Sb  Sb2  1  0.016  0.977  0.989  1.0
  Sb  Sb3  1  0.977  0.016  0.489  1.0
  F  F4  1  0.144  0.857  0.191  1.0
  F  F5  1  0.857  0.144  0.691  1.0
  F  F6  1  0.202  0.324  0.369  1.0
  F  F7  1  0.690  0.777  0.169  1.0
  F  F8  1  0.759  0.299  0.086  1.0
  F  F9  1  0.631  0.307  0.456  1.0
  F  F10  1  0.307  0.631  0.956  1.0
  F  F11  1  0.299  0.759  0.586  1.0
  F  F12  1  0.324  0.202  0.869  1.0
  F  F13  1  0.777  0.690  0.669  1.0
[/CIF]
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