The compound described by CF3C2O2IClF3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four trifluoromethane molecules and four C2O2IClF3 clusters. In each C2O2IClF3 cluster, there are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. In the second C site, C(3) is bonded in a trigonal non-coplanar geometry to one I(1), one F(2), one F(3), and one F(4) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one C(1) and one I(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. I(1) is bonded in a distorted T-shaped geometry to one C(3), one O(1), and one Cl(1) atom. Cl(1) is bonded in a single-bond geometry to one I(1) atom. There are three inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one C(3) atom. In the second F site, F(3) is bonded in a single-bond geometry to one C(3) atom. In the third F site, F(4) is bonded in a single-bond geometry to one C(3) atom. is represented by the CIF card [CIF]
data_C3ICl(OF3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.015
_cell_length_b   10.265
_cell_length_c   11.324
_cell_angle_alpha   78.499
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   912.933
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  C  C0  1  0.649  0.426  0.705  1.0
  C  C1  1  0.204  0.655  0.225  1.0
  C  C2  1  0.149  0.074  0.295  1.0
  C  C3  1  0.796  0.345  0.775  1.0
  C  C4  1  0.242  0.065  0.858  1.0
  C  C5  1  0.742  0.435  0.142  1.0
  C  C6  1  0.758  0.935  0.142  1.0
  C  C7  1  0.704  0.845  0.775  1.0
  C  C8  1  0.351  0.574  0.295  1.0
  C  C9  1  0.851  0.926  0.705  1.0
  C  C10  1  0.296  0.155  0.225  1.0
  C  C11  1  0.258  0.565  0.858  1.0
  I  I12  1  0.681  0.447  0.335  1.0
  I  I13  1  0.181  0.053  0.665  1.0
  I  I14  1  0.819  0.947  0.335  1.0
  I  I15  1  0.319  0.553  0.665  1.0
  Cl  Cl16  1  0.068  0.676  0.594  1.0
  Cl  Cl17  1  0.568  0.824  0.406  1.0
  Cl  Cl18  1  0.432  0.176  0.594  1.0
  Cl  Cl19  1  0.932  0.324  0.406  1.0
  O  O20  1  0.972  0.942  0.776  1.0
  O  O21  1  0.656  0.465  0.595  1.0
  O  O22  1  0.028  0.058  0.224  1.0
  O  O23  1  0.528  0.442  0.776  1.0
  O  O24  1  0.156  0.035  0.405  1.0
  O  O25  1  0.344  0.535  0.405  1.0
  O  O26  1  0.472  0.558  0.224  1.0
  O  O27  1  0.844  0.965  0.595  1.0
  F  F28  1  0.652  0.900  0.868  1.0
  F  F29  1  0.238  0.442  0.923  1.0
  F  F30  1  0.118  0.635  0.860  1.0
  F  F31  1  0.384  0.625  0.903  1.0
  F  F32  1  0.348  0.100  0.132  1.0
  F  F33  1  0.152  0.600  0.132  1.0
  F  F34  1  0.430  0.160  0.298  1.0
  F  F35  1  0.884  0.875  0.097  1.0
  F  F36  1  0.882  0.365  0.140  1.0
  F  F37  1  0.618  0.865  0.140  1.0
  F  F38  1  0.252  0.782  0.180  1.0
  F  F39  1  0.248  0.282  0.180  1.0
  F  F40  1  0.116  0.125  0.903  1.0
  F  F41  1  0.752  0.718  0.820  1.0
  F  F42  1  0.070  0.660  0.298  1.0
  F  F43  1  0.848  0.400  0.868  1.0
  F  F44  1  0.570  0.840  0.702  1.0
  F  F45  1  0.762  0.558  0.077  1.0
  F  F46  1  0.616  0.375  0.097  1.0
  F  F47  1  0.262  0.942  0.923  1.0
  F  F48  1  0.930  0.340  0.702  1.0
  F  F49  1  0.748  0.218  0.820  1.0
  F  F50  1  0.738  0.058  0.077  1.0
  F  F51  1  0.382  0.135  0.860  1.0
[/CIF]
.
The compound described by CF3C2O2IClF3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four trifluoromethane molecules and four C2O2IClF3 clusters. In each C2O2IClF3 cluster, there are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. In the second C site, C(3) is bonded in a trigonal non-coplanar geometry to one I(1), one F(2), one F(3), and one F(4) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one C(1) and one I(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. I(1) is bonded in a distorted T-shaped geometry to one C(3), one O(1), and one Cl(1) atom. Cl(1) is bonded in a single-bond geometry to one I(1) atom. There are three inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one C(3) atom. In the second F site, F(3) is bonded in a single-bond geometry to one C(3) atom. In the third F site, F(4) is bonded in a single-bond geometry to one C(3) atom. is represented by the CIF card [CIF]
data_C3ICl(OF3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.015
_cell_length_b   10.265
_cell_length_c   11.324
_cell_angle_alpha   78.499
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   912.933
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  C  C0  1  0.649  0.426  0.705  1.0
  C  C1  1  0.204  0.655  0.225  1.0
  C  C2  1  0.149  0.074  0.295  1.0
  C  C3  1  0.796  0.345  0.775  1.0
  C  C4  1  0.242  0.065  0.858  1.0
  C  C5  1  0.742  0.435  0.142  1.0
  C  C6  1  0.758  0.935  0.142  1.0
  C  C7  1  0.704  0.845  0.775  1.0
  C  C8  1  0.351  0.574  0.295  1.0
  C  C9  1  0.851  0.926  0.705  1.0
  C  C10  1  0.296  0.155  0.225  1.0
  C  C11  1  0.258  0.565  0.858  1.0
  I  I12  1  0.681  0.447  0.335  1.0
  I  I13  1  0.181  0.053  0.665  1.0
  I  I14  1  0.819  0.947  0.335  1.0
  I  I15  1  0.319  0.553  0.665  1.0
  Cl  Cl16  1  0.068  0.676  0.594  1.0
  Cl  Cl17  1  0.568  0.824  0.406  1.0
  Cl  Cl18  1  0.432  0.176  0.594  1.0
  Cl  Cl19  1  0.932  0.324  0.406  1.0
  O  O20  1  0.972  0.942  0.776  1.0
  O  O21  1  0.656  0.465  0.595  1.0
  O  O22  1  0.028  0.058  0.224  1.0
  O  O23  1  0.528  0.442  0.776  1.0
  O  O24  1  0.156  0.035  0.405  1.0
  O  O25  1  0.344  0.535  0.405  1.0
  O  O26  1  0.472  0.558  0.224  1.0
  O  O27  1  0.844  0.965  0.595  1.0
  F  F28  1  0.652  0.900  0.868  1.0
  F  F29  1  0.238  0.442  0.923  1.0
  F  F30  1  0.118  0.635  0.860  1.0
  F  F31  1  0.384  0.625  0.903  1.0
  F  F32  1  0.348  0.100  0.132  1.0
  F  F33  1  0.152  0.600  0.132  1.0
  F  F34  1  0.430  0.160  0.298  1.0
  F  F35  1  0.884  0.875  0.097  1.0
  F  F36  1  0.882  0.365  0.140  1.0
  F  F37  1  0.618  0.865  0.140  1.0
  F  F38  1  0.252  0.782  0.180  1.0
  F  F39  1  0.248  0.282  0.180  1.0
  F  F40  1  0.116  0.125  0.903  1.0
  F  F41  1  0.752  0.718  0.820  1.0
  F  F42  1  0.070  0.660  0.298  1.0
  F  F43  1  0.848  0.400  0.868  1.0
  F  F44  1  0.570  0.840  0.702  1.0
  F  F45  1  0.762  0.558  0.077  1.0
  F  F46  1  0.616  0.375  0.097  1.0
  F  F47  1  0.262  0.942  0.923  1.0
  F  F48  1  0.930  0.340  0.702  1.0
  F  F49  1  0.748  0.218  0.820  1.0
  F  F50  1  0.738  0.058  0.077  1.0
  F  F51  1  0.382  0.135  0.860  1.0
[/CIF]
.