The material described by RbSb2P(SO6)2 crystallizes in the triclinic P-1 space group. Rb(1) is bonded in a 11-coordinate geometry to one O(10), one O(11), one O(12), one O(2), one O(6), two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 3-coordinate geometry to one O(10), one O(11), and one O(9) atom. In the second Sb site, Sb(2) is bonded to one O(12), one O(3), one O(4), one O(5), and one O(8) atom to form distorted SbO5 square pyramids that share  a cornercorner with one P(1)O4 tetrahedra, corners with two equivalent S(1)O4 tetrahedra, and corners with two equivalent S(2)O4 tetrahedra. P(1) is bonded to one O(10), one O(11), one O(12), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Sb(2)O5 square pyramid. There are two inequivalent S sites. In the first S site, S(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form SO4 tetrahedra that share corners with two equivalent Sb(2)O5 square pyramids. In the second S site, S(2) is bonded to one O(5), one O(6), one O(7), and one O(8) atom to form SO4 tetrahedra that share corners with two equivalent Sb(2)O5 square pyramids. There are twelve inequivalent O sites. In the first O site, O(11) is bonded in a 2-coordinate geometry to one Rb(1), one Sb(1), and one P(1) atom. In the second O site, O(12) is bonded in a distorted bent 150 degrees geometry to one Rb(1), one Sb(2), and one P(1) atom. In the third O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one S(1) atom. In the fourth O site, O(2) is bonded in a single-bond geometry to one Rb(1) and one S(1) atom. In the fifth O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Rb(1), one Sb(2), and one S(1) atom. In the sixth O site, O(4) is bonded in a 2-coordinate geometry to two equivalent Rb(1), one Sb(2), and one S(1) atom. In the seventh O site, O(5) is bonded in a distorted single-bond geometry to one Sb(2) and one S(2) atom. In the eighth O site, O(6) is bonded in a distorted single-bond geometry to one Rb(1) and one S(2) atom. In the ninth O site, O(7) is bonded in a single-bond geometry to one S(2) atom. In the tenth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Sb(2) and one S(2) atom. In the eleventh O site, O(9) is bonded in a distorted bent 150 degrees geometry to one Sb(1) and one P(1) atom. In the twelfth O site, O(10) is bonded in a 2-coordinate geometry to one Rb(1), one Sb(1), and one P(1) atom. is represented by the CIF card [CIF]
data_RbSb2P(SO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.246
_cell_length_b   8.203
_cell_length_c   13.115
_cell_angle_alpha   82.020
_cell_angle_beta   87.770
_cell_angle_gamma   86.777
_symmetry_Int_Tables_number   1
_cell_volume   557.723
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.724  0.335  0.647  1.0
  Rb  Rb1  1  0.276  0.665  0.353  1.0
  Sb  Sb2  1  0.780  0.239  0.963  1.0
  Sb  Sb3  1  0.220  0.761  0.037  1.0
  Sb  Sb4  1  0.188  0.804  0.676  1.0
  Sb  Sb5  1  0.812  0.196  0.324  1.0
  P  P6  1  0.266  0.469  0.860  1.0
  P  P7  1  0.734  0.531  0.140  1.0
  S  S8  1  0.741  0.790  0.528  1.0
  S  S9  1  0.259  0.210  0.472  1.0
  S  S10  1  0.709  0.891  0.843  1.0
  S  S11  1  0.291  0.109  0.157  1.0
  O  O12  1  0.768  0.789  0.417  1.0
  O  O13  1  0.232  0.211  0.583  1.0
  O  O14  1  0.746  0.953  0.562  1.0
  O  O15  1  0.254  0.047  0.438  1.0
  O  O16  1  0.505  0.702  0.569  1.0
  O  O17  1  0.495  0.298  0.431  1.0
  O  O18  1  0.968  0.680  0.579  1.0
  O  O19  1  0.032  0.320  0.421  1.0
  O  O20  1  0.436  0.895  0.817  1.0
  O  O21  1  0.564  0.105  0.183  1.0
  O  O22  1  0.819  0.056  0.816  1.0
  O  O23  1  0.181  0.944  0.184  1.0
  O  O24  1  0.735  0.832  0.955  1.0
  O  O25  1  0.265  0.168  0.045  1.0
  O  O26  1  0.855  0.768  0.783  1.0
  O  O27  1  0.145  0.232  0.217  1.0
  O  O28  1  0.249  0.567  0.952  1.0
  O  O29  1  0.751  0.433  0.048  1.0
  O  O30  1  0.512  0.355  0.864  1.0
  O  O31  1  0.488  0.645  0.136  1.0
  O  O32  1  0.973  0.635  0.140  1.0
  O  O33  1  0.027  0.365  0.860  1.0
  O  O34  1  0.286  0.574  0.753  1.0
  O  O35  1  0.714  0.426  0.247  1.0
[/CIF]
.
The material described by RbSb2P(SO6)2 crystallizes in the triclinic P-1 space group. Rb(1) is bonded in a 11-coordinate geometry to one O(10), one O(11), one O(12), one O(2), one O(6), two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 3-coordinate geometry to one O(10), one O(11), and one O(9) atom. In the second Sb site, Sb(2) is bonded to one O(12), one O(3), one O(4), one O(5), and one O(8) atom to form distorted SbO5 square pyramids that share  a cornercorner with one P(1)O4 tetrahedra, corners with two equivalent S(1)O4 tetrahedra, and corners with two equivalent S(2)O4 tetrahedra. P(1) is bonded to one O(10), one O(11), one O(12), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Sb(2)O5 square pyramid. There are two inequivalent S sites. In the first S site, S(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form SO4 tetrahedra that share corners with two equivalent Sb(2)O5 square pyramids. In the second S site, S(2) is bonded to one O(5), one O(6), one O(7), and one O(8) atom to form SO4 tetrahedra that share corners with two equivalent Sb(2)O5 square pyramids. There are twelve inequivalent O sites. In the first O site, O(11) is bonded in a 2-coordinate geometry to one Rb(1), one Sb(1), and one P(1) atom. In the second O site, O(12) is bonded in a distorted bent 150 degrees geometry to one Rb(1), one Sb(2), and one P(1) atom. In the third O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one S(1) atom. In the fourth O site, O(2) is bonded in a single-bond geometry to one Rb(1) and one S(1) atom. In the fifth O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Rb(1), one Sb(2), and one S(1) atom. In the sixth O site, O(4) is bonded in a 2-coordinate geometry to two equivalent Rb(1), one Sb(2), and one S(1) atom. In the seventh O site, O(5) is bonded in a distorted single-bond geometry to one Sb(2) and one S(2) atom. In the eighth O site, O(6) is bonded in a distorted single-bond geometry to one Rb(1) and one S(2) atom. In the ninth O site, O(7) is bonded in a single-bond geometry to one S(2) atom. In the tenth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Sb(2) and one S(2) atom. In the eleventh O site, O(9) is bonded in a distorted bent 150 degrees geometry to one Sb(1) and one P(1) atom. In the twelfth O site, O(10) is bonded in a 2-coordinate geometry to one Rb(1), one Sb(1), and one P(1) atom. is represented by the CIF card [CIF]
data_RbSb2P(SO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.246
_cell_length_b   8.203
_cell_length_c   13.115
_cell_angle_alpha   82.020
_cell_angle_beta   87.770
_cell_angle_gamma   86.777
_symmetry_Int_Tables_number   1
_cell_volume   557.723
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.724  0.335  0.647  1.0
  Rb  Rb1  1  0.276  0.665  0.353  1.0
  Sb  Sb2  1  0.780  0.239  0.963  1.0
  Sb  Sb3  1  0.220  0.761  0.037  1.0
  Sb  Sb4  1  0.188  0.804  0.676  1.0
  Sb  Sb5  1  0.812  0.196  0.324  1.0
  P  P6  1  0.266  0.469  0.860  1.0
  P  P7  1  0.734  0.531  0.140  1.0
  S  S8  1  0.741  0.790  0.528  1.0
  S  S9  1  0.259  0.210  0.472  1.0
  S  S10  1  0.709  0.891  0.843  1.0
  S  S11  1  0.291  0.109  0.157  1.0
  O  O12  1  0.768  0.789  0.417  1.0
  O  O13  1  0.232  0.211  0.583  1.0
  O  O14  1  0.746  0.953  0.562  1.0
  O  O15  1  0.254  0.047  0.438  1.0
  O  O16  1  0.505  0.702  0.569  1.0
  O  O17  1  0.495  0.298  0.431  1.0
  O  O18  1  0.968  0.680  0.579  1.0
  O  O19  1  0.032  0.320  0.421  1.0
  O  O20  1  0.436  0.895  0.817  1.0
  O  O21  1  0.564  0.105  0.183  1.0
  O  O22  1  0.819  0.056  0.816  1.0
  O  O23  1  0.181  0.944  0.184  1.0
  O  O24  1  0.735  0.832  0.955  1.0
  O  O25  1  0.265  0.168  0.045  1.0
  O  O26  1  0.855  0.768  0.783  1.0
  O  O27  1  0.145  0.232  0.217  1.0
  O  O28  1  0.249  0.567  0.952  1.0
  O  O29  1  0.751  0.433  0.048  1.0
  O  O30  1  0.512  0.355  0.864  1.0
  O  O31  1  0.488  0.645  0.136  1.0
  O  O32  1  0.973  0.635  0.140  1.0
  O  O33  1  0.027  0.365  0.860  1.0
  O  O34  1  0.286  0.574  0.753  1.0
  O  O35  1  0.714  0.426  0.247  1.0
[/CIF]
.