The crystal structure described by (Co6Te4O15)2O2 crystallizes in the hexagonal P6_3mc space group. The structure consists of two water atoms inside a Co6Te4O15 framework. In the Co6Te4O15 framework, Co(1) is bonded to one O(1), one O(3), two equivalent O(2), and two equivalent O(4) atoms to form a mixture of edge, face, and corner-sharing CoO6 octahedra. The corner-sharing octahedral tilt angles range from 28-57°. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a distorted trigonal non-coplanar geometry to one O(1) and two equivalent O(2) atoms. In the second Te site, Te(2) is bonded in a distorted T-shaped geometry to three equivalent O(3) atoms. There are four inequivalent O sites. In the first O site, O(3) is bonded in a trigonal non-coplanar geometry to two equivalent Co(1) and one Te(2) atom. In the second O site, O(4) is bonded in a distorted square co-planar geometry to four equivalent Co(1) atoms. In the third O site, O(1) is bonded in a trigonal non-coplanar geometry to two equivalent Co(1) and one Te(1) atom. In the fourth O site, O(2) is bonded in a distorted T-shaped geometry to two equivalent Co(1) and one Te(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Co3(TeO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.019
_cell_length_b   13.019
_cell_length_c   5.008
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   735.126
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.567  0.928  0.442  1.0
  Co  Co1  1  0.072  0.639  0.442  1.0
  Co  Co2  1  0.361  0.433  0.442  1.0
  Co  Co3  1  0.072  0.433  0.442  1.0
  Co  Co4  1  0.361  0.928  0.442  1.0
  Co  Co5  1  0.567  0.639  0.442  1.0
  Co  Co6  1  0.433  0.072  0.942  1.0
  Co  Co7  1  0.928  0.361  0.942  1.0
  Co  Co8  1  0.639  0.567  0.942  1.0
  Co  Co9  1  0.928  0.567  0.942  1.0
  Co  Co10  1  0.639  0.072  0.942  1.0
  Co  Co11  1  0.433  0.361  0.942  1.0
  Te  Te12  1  0.860  0.720  0.502  1.0
  Te  Te13  1  0.280  0.140  0.502  1.0
  Te  Te14  1  0.860  0.140  0.502  1.0
  Te  Te15  1  0.140  0.280  0.002  1.0
  Te  Te16  1  0.720  0.860  0.002  1.0
  Te  Te17  1  0.140  0.860  0.002  1.0
  Te  Te18  1  0.333  0.667  0.373  1.0
  Te  Te19  1  0.667  0.333  0.873  1.0
  O  O20  1  0.794  0.588  0.744  1.0
  O  O21  1  0.412  0.206  0.744  1.0
  O  O22  1  0.794  0.206  0.744  1.0
  O  O23  1  0.206  0.412  0.244  1.0
  O  O24  1  0.588  0.794  0.244  1.0
  O  O25  1  0.206  0.794  0.244  1.0
  O  O26  1  0.673  0.727  0.766  1.0
  O  O27  1  0.273  0.946  0.766  1.0
  O  O28  1  0.054  0.327  0.766  1.0
  O  O29  1  0.273  0.327  0.766  1.0
  O  O30  1  0.054  0.727  0.766  1.0
  O  O31  1  0.673  0.946  0.766  1.0
  O  O32  1  0.327  0.273  0.266  1.0
  O  O33  1  0.727  0.054  0.266  1.0
  O  O34  1  0.946  0.673  0.266  1.0
  O  O35  1  0.727  0.673  0.266  1.0
  O  O36  1  0.946  0.273  0.266  1.0
  O  O37  1  0.327  0.054  0.266  1.0
  O  O38  1  0.596  0.193  0.085  1.0
  O  O39  1  0.807  0.404  0.085  1.0
  O  O40  1  0.596  0.404  0.085  1.0
  O  O41  1  0.404  0.807  0.585  1.0
  O  O42  1  0.193  0.596  0.585  1.0
  O  O43  1  0.404  0.596  0.585  1.0
  O  O44  1  0.522  0.043  0.667  1.0
  O  O45  1  0.957  0.478  0.667  1.0
  O  O46  1  0.522  0.478  0.667  1.0
  O  O47  1  0.478  0.957  0.167  1.0
  O  O48  1  0.043  0.522  0.167  1.0
  O  O49  1  0.478  0.522  0.167  1.0
  O  O50  1  0.000  0.000  0.642  1.0
  O  O51  1  0.000  0.000  0.142  1.0
[/CIF]
.
The crystal structure described by (Co6Te4O15)2O2 crystallizes in the hexagonal P6_3mc space group. The structure consists of two water atoms inside a Co6Te4O15 framework. In the Co6Te4O15 framework, Co(1) is bonded to one O(1), one O(3), two equivalent O(2), and two equivalent O(4) atoms to form a mixture of edge, face, and corner-sharing CoO6 octahedra. The corner-sharing octahedral tilt angles range from 28-57°. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a distorted trigonal non-coplanar geometry to one O(1) and two equivalent O(2) atoms. In the second Te site, Te(2) is bonded in a distorted T-shaped geometry to three equivalent O(3) atoms. There are four inequivalent O sites. In the first O site, O(3) is bonded in a trigonal non-coplanar geometry to two equivalent Co(1) and one Te(2) atom. In the second O site, O(4) is bonded in a distorted square co-planar geometry to four equivalent Co(1) atoms. In the third O site, O(1) is bonded in a trigonal non-coplanar geometry to two equivalent Co(1) and one Te(1) atom. In the fourth O site, O(2) is bonded in a distorted T-shaped geometry to two equivalent Co(1) and one Te(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Co3(TeO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.019
_cell_length_b   13.019
_cell_length_c   5.008
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   735.126
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.567  0.928  0.442  1.0
  Co  Co1  1  0.072  0.639  0.442  1.0
  Co  Co2  1  0.361  0.433  0.442  1.0
  Co  Co3  1  0.072  0.433  0.442  1.0
  Co  Co4  1  0.361  0.928  0.442  1.0
  Co  Co5  1  0.567  0.639  0.442  1.0
  Co  Co6  1  0.433  0.072  0.942  1.0
  Co  Co7  1  0.928  0.361  0.942  1.0
  Co  Co8  1  0.639  0.567  0.942  1.0
  Co  Co9  1  0.928  0.567  0.942  1.0
  Co  Co10  1  0.639  0.072  0.942  1.0
  Co  Co11  1  0.433  0.361  0.942  1.0
  Te  Te12  1  0.860  0.720  0.502  1.0
  Te  Te13  1  0.280  0.140  0.502  1.0
  Te  Te14  1  0.860  0.140  0.502  1.0
  Te  Te15  1  0.140  0.280  0.002  1.0
  Te  Te16  1  0.720  0.860  0.002  1.0
  Te  Te17  1  0.140  0.860  0.002  1.0
  Te  Te18  1  0.333  0.667  0.373  1.0
  Te  Te19  1  0.667  0.333  0.873  1.0
  O  O20  1  0.794  0.588  0.744  1.0
  O  O21  1  0.412  0.206  0.744  1.0
  O  O22  1  0.794  0.206  0.744  1.0
  O  O23  1  0.206  0.412  0.244  1.0
  O  O24  1  0.588  0.794  0.244  1.0
  O  O25  1  0.206  0.794  0.244  1.0
  O  O26  1  0.673  0.727  0.766  1.0
  O  O27  1  0.273  0.946  0.766  1.0
  O  O28  1  0.054  0.327  0.766  1.0
  O  O29  1  0.273  0.327  0.766  1.0
  O  O30  1  0.054  0.727  0.766  1.0
  O  O31  1  0.673  0.946  0.766  1.0
  O  O32  1  0.327  0.273  0.266  1.0
  O  O33  1  0.727  0.054  0.266  1.0
  O  O34  1  0.946  0.673  0.266  1.0
  O  O35  1  0.727  0.673  0.266  1.0
  O  O36  1  0.946  0.273  0.266  1.0
  O  O37  1  0.327  0.054  0.266  1.0
  O  O38  1  0.596  0.193  0.085  1.0
  O  O39  1  0.807  0.404  0.085  1.0
  O  O40  1  0.596  0.404  0.085  1.0
  O  O41  1  0.404  0.807  0.585  1.0
  O  O42  1  0.193  0.596  0.585  1.0
  O  O43  1  0.404  0.596  0.585  1.0
  O  O44  1  0.522  0.043  0.667  1.0
  O  O45  1  0.957  0.478  0.667  1.0
  O  O46  1  0.522  0.478  0.667  1.0
  O  O47  1  0.478  0.957  0.167  1.0
  O  O48  1  0.043  0.522  0.167  1.0
  O  O49  1  0.478  0.522  0.167  1.0
  O  O50  1  0.000  0.000  0.642  1.0
  O  O51  1  0.000  0.000  0.142  1.0
[/CIF]
.