The structure described by LiMnF3 is Calcite structured and crystallizes in the trigonal R-3c space group. Li(1) is bonded in a trigonal planar geometry to three equivalent F(1) atoms. Mn(1) is bonded to six equivalent F(1) atoms to form corner-sharing MnF6 octahedra. The corner-sharing octahedral tilt angles are 45°. F(1) is bonded in a trigonal planar geometry to one Li(1) and two equivalent Mn(1) atoms. is represented by the CIF card [CIF]
data_LiMnF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.830
_cell_length_b   5.830
_cell_length_c   5.830
_cell_angle_alpha   55.155
_cell_angle_beta   55.155
_cell_angle_gamma   55.155
_symmetry_Int_Tables_number   1
_cell_volume   124.314
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.750  0.750  0.750  1.0
  Li  Li1  1  0.250  0.250  0.250  1.0
  Mn  Mn2  1  0.500  0.500  0.500  1.0
  Mn  Mn3  1  0.000  0.000  0.000  1.0
  F  F4  1  0.250  0.597  0.903  1.0
  F  F5  1  0.403  0.097  0.750  1.0
  F  F6  1  0.097  0.750  0.403  1.0
  F  F7  1  0.903  0.250  0.597  1.0
  F  F8  1  0.597  0.903  0.250  1.0
  F  F9  1  0.750  0.403  0.097  1.0
[/CIF]
.
The structure described by LiMnF3 is Calcite structured and crystallizes in the trigonal R-3c space group. Li(1) is bonded in a trigonal planar geometry to three equivalent F(1) atoms. Mn(1) is bonded to six equivalent F(1) atoms to form corner-sharing MnF6 octahedra. The corner-sharing octahedral tilt angles are 45°. F(1) is bonded in a trigonal planar geometry to one Li(1) and two equivalent Mn(1) atoms. is represented by the CIF card [CIF]
data_LiMnF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.830
_cell_length_b   5.830
_cell_length_c   5.830
_cell_angle_alpha   55.155
_cell_angle_beta   55.155
_cell_angle_gamma   55.155
_symmetry_Int_Tables_number   1
_cell_volume   124.314
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.750  0.750  0.750  1.0
  Li  Li1  1  0.250  0.250  0.250  1.0
  Mn  Mn2  1  0.500  0.500  0.500  1.0
  Mn  Mn3  1  0.000  0.000  0.000  1.0
  F  F4  1  0.250  0.597  0.903  1.0
  F  F5  1  0.403  0.097  0.750  1.0
  F  F6  1  0.097  0.750  0.403  1.0
  F  F7  1  0.903  0.250  0.597  1.0
  F  F8  1  0.597  0.903  0.250  1.0
  F  F9  1  0.750  0.403  0.097  1.0
[/CIF]
.