The material structure described by CsAgCl2 crystallizes in the orthorhombic Cmcm space group. Cs(1) is bonded in a body-centered cubic geometry to two equivalent Cl(1) and six equivalent Cl(2) atoms. Ag(1) is bonded to one Cl(2) and four equivalent Cl(1) atoms to form a mixture of distorted corner and edge-sharing AgCl5 trigonal bipyramids. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded to two equivalent Cs(1) and four equivalent Ag(1) atoms to form a mixture of distorted corner and edge-sharing ClCs2Ag4 octahedra. The corner-sharing octahedral tilt angles are 19°. In the second Cl site, Cl(2) is bonded in a 7-coordinate geometry to six equivalent Cs(1) and one Ag(1) atom. is represented by the CIF file [CIF]
data_CsAgCl2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.421
_cell_length_b   5.642
_cell_length_c   9.894
_cell_angle_alpha   90.000
_cell_angle_beta   102.908
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   240.515
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.415  0.250  0.831  1.0
  Cs  Cs1  1  0.585  0.750  0.169  1.0
  Ag  Ag2  1  0.201  0.250  0.401  1.0
  Ag  Ag3  1  0.799  0.750  0.599  1.0
  Cl  Cl4  1  0.775  0.250  0.550  1.0
  Cl  Cl5  1  0.225  0.750  0.450  1.0
  Cl  Cl6  1  0.069  0.250  0.138  1.0
  Cl  Cl7  1  0.931  0.750  0.862  1.0
[/CIF]
.
The material structure described by CsAgCl2 crystallizes in the orthorhombic Cmcm space group. Cs(1) is bonded in a body-centered cubic geometry to two equivalent Cl(1) and six equivalent Cl(2) atoms. Ag(1) is bonded to one Cl(2) and four equivalent Cl(1) atoms to form a mixture of distorted corner and edge-sharing AgCl5 trigonal bipyramids. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded to two equivalent Cs(1) and four equivalent Ag(1) atoms to form a mixture of distorted corner and edge-sharing ClCs2Ag4 octahedra. The corner-sharing octahedral tilt angles are 19°. In the second Cl site, Cl(2) is bonded in a 7-coordinate geometry to six equivalent Cs(1) and one Ag(1) atom. is represented by the CIF file [CIF]
data_CsAgCl2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.421
_cell_length_b   5.642
_cell_length_c   9.894
_cell_angle_alpha   90.000
_cell_angle_beta   102.908
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   240.515
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.415  0.250  0.831  1.0
  Cs  Cs1  1  0.585  0.750  0.169  1.0
  Ag  Ag2  1  0.201  0.250  0.401  1.0
  Ag  Ag3  1  0.799  0.750  0.599  1.0
  Cl  Cl4  1  0.775  0.250  0.550  1.0
  Cl  Cl5  1  0.225  0.750  0.450  1.0
  Cl  Cl6  1  0.069  0.250  0.138  1.0
  Cl  Cl7  1  0.931  0.750  0.862  1.0
[/CIF]
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