The compound described by LiMn(PO3)4 crystallizes in the monoclinic P2_1 space group. Li(1) is bonded in a 4-coordinate geometry to one O(12), one O(6), one O(8), and one O(9) atom. Mn(1) is bonded in a 6-coordinate geometry to one O(11), one O(12), one O(2), one O(3), one O(4), and one O(9) atom. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(3), one O(5), and one O(6) atom to form corner-sharing PO4 tetrahedra. In the second P site, P(2) is bonded to one O(1), one O(2), one O(4), and one O(7) atom to form corner-sharing PO4 tetrahedra. In the third P site, P(3) is bonded to one O(10), one O(12), one O(5), and one O(9) atom to form corner-sharing PO4 tetrahedra. In the fourth P site, P(4) is bonded to one O(10), one O(11), one O(7), and one O(8) atom to form corner-sharing PO4 tetrahedra. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one P(1) and one P(2) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Mn(1) and one P(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Mn(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Mn(1) and one P(2) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one P(1) and one P(3) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Li(1) and one P(1) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one P(2) and one P(4) atom. In the eighth O site, O(8) is bonded in a water-like geometry to one Li(1) and one P(4) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one Li(1), one Mn(1), and one P(3) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one P(3) and one P(4) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to one Mn(1) and one P(4) atom. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to one Li(1), one Mn(1), and one P(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiMn(PO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.006
_cell_length_b   6.986
_cell_length_c   7.208
_cell_angle_alpha   85.173
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   451.931
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.352  0.667  0.693  1.0
  Li  Li1  1  0.852  0.333  0.307  1.0
  Mn  Mn2  1  0.927  0.768  0.233  1.0
  Mn  Mn3  1  0.427  0.232  0.767  1.0
  P  P4  1  0.370  0.020  0.416  1.0
  P  P5  1  0.570  0.925  0.091  1.0
  P  P6  1  0.733  0.604  0.588  1.0
  P  P7  1  0.387  0.564  0.064  1.0
  P  P8  1  0.887  0.436  0.936  1.0
  P  P9  1  0.233  0.396  0.412  1.0
  P  P10  1  0.070  0.075  0.909  1.0
  P  P11  1  0.870  0.980  0.584  1.0
  O  O12  1  0.948  0.980  0.782  1.0
  O  O13  1  0.543  0.021  0.898  1.0
  O  O14  1  0.978  0.883  0.458  1.0
  O  O15  1  0.722  0.930  0.172  1.0
  O  O16  1  0.737  0.827  0.631  1.0
  O  O17  1  0.310  0.828  0.479  1.0
  O  O18  1  0.530  0.699  0.092  1.0
  O  O19  1  0.267  0.674  0.963  1.0
  O  O20  1  0.790  0.588  0.389  1.0
  O  O21  1  0.860  0.506  0.720  1.0
  O  O22  1  0.940  0.614  0.023  1.0
  O  O23  1  0.582  0.529  0.636  1.0
  O  O24  1  0.082  0.471  0.364  1.0
  O  O25  1  0.440  0.386  0.977  1.0
  O  O26  1  0.360  0.494  0.280  1.0
  O  O27  1  0.290  0.412  0.611  1.0
  O  O28  1  0.767  0.326  0.037  1.0
  O  O29  1  0.030  0.301  0.908  1.0
  O  O30  1  0.810  0.172  0.521  1.0
  O  O31  1  0.237  0.173  0.369  1.0
  O  O32  1  0.222  0.070  0.828  1.0
  O  O33  1  0.478  0.117  0.542  1.0
  O  O34  1  0.043  0.979  0.102  1.0
  O  O35  1  0.448  0.020  0.218  1.0
[/CIF]
.
The compound described by LiMn(PO3)4 crystallizes in the monoclinic P2_1 space group. Li(1) is bonded in a 4-coordinate geometry to one O(12), one O(6), one O(8), and one O(9) atom. Mn(1) is bonded in a 6-coordinate geometry to one O(11), one O(12), one O(2), one O(3), one O(4), and one O(9) atom. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(3), one O(5), and one O(6) atom to form corner-sharing PO4 tetrahedra. In the second P site, P(2) is bonded to one O(1), one O(2), one O(4), and one O(7) atom to form corner-sharing PO4 tetrahedra. In the third P site, P(3) is bonded to one O(10), one O(12), one O(5), and one O(9) atom to form corner-sharing PO4 tetrahedra. In the fourth P site, P(4) is bonded to one O(10), one O(11), one O(7), and one O(8) atom to form corner-sharing PO4 tetrahedra. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one P(1) and one P(2) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Mn(1) and one P(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Mn(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Mn(1) and one P(2) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one P(1) and one P(3) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Li(1) and one P(1) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one P(2) and one P(4) atom. In the eighth O site, O(8) is bonded in a water-like geometry to one Li(1) and one P(4) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one Li(1), one Mn(1), and one P(3) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one P(3) and one P(4) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to one Mn(1) and one P(4) atom. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to one Li(1), one Mn(1), and one P(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiMn(PO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.006
_cell_length_b   6.986
_cell_length_c   7.208
_cell_angle_alpha   85.173
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   451.931
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.352  0.667  0.693  1.0
  Li  Li1  1  0.852  0.333  0.307  1.0
  Mn  Mn2  1  0.927  0.768  0.233  1.0
  Mn  Mn3  1  0.427  0.232  0.767  1.0
  P  P4  1  0.370  0.020  0.416  1.0
  P  P5  1  0.570  0.925  0.091  1.0
  P  P6  1  0.733  0.604  0.588  1.0
  P  P7  1  0.387  0.564  0.064  1.0
  P  P8  1  0.887  0.436  0.936  1.0
  P  P9  1  0.233  0.396  0.412  1.0
  P  P10  1  0.070  0.075  0.909  1.0
  P  P11  1  0.870  0.980  0.584  1.0
  O  O12  1  0.948  0.980  0.782  1.0
  O  O13  1  0.543  0.021  0.898  1.0
  O  O14  1  0.978  0.883  0.458  1.0
  O  O15  1  0.722  0.930  0.172  1.0
  O  O16  1  0.737  0.827  0.631  1.0
  O  O17  1  0.310  0.828  0.479  1.0
  O  O18  1  0.530  0.699  0.092  1.0
  O  O19  1  0.267  0.674  0.963  1.0
  O  O20  1  0.790  0.588  0.389  1.0
  O  O21  1  0.860  0.506  0.720  1.0
  O  O22  1  0.940  0.614  0.023  1.0
  O  O23  1  0.582  0.529  0.636  1.0
  O  O24  1  0.082  0.471  0.364  1.0
  O  O25  1  0.440  0.386  0.977  1.0
  O  O26  1  0.360  0.494  0.280  1.0
  O  O27  1  0.290  0.412  0.611  1.0
  O  O28  1  0.767  0.326  0.037  1.0
  O  O29  1  0.030  0.301  0.908  1.0
  O  O30  1  0.810  0.172  0.521  1.0
  O  O31  1  0.237  0.173  0.369  1.0
  O  O32  1  0.222  0.070  0.828  1.0
  O  O33  1  0.478  0.117  0.542  1.0
  O  O34  1  0.043  0.979  0.102  1.0
  O  O35  1  0.448  0.020  0.218  1.0
[/CIF]
.