The material structure described by Pb2Cl2CO3 crystallizes in the triclinic P1 space group. There are eight inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 6-coordinate geometry to one O(10), one O(12), one O(2), one O(5), one O(8), and one Cl(7) atom. In the second Pb site, Pb(2) is bonded in a 4-coordinate geometry to one O(12), one Cl(1), one Cl(2), and one Cl(4) atom. In the third Pb site, Pb(3) is bonded in a 4-coordinate geometry to one O(5), one O(6), one Cl(5), one Cl(6), and one Cl(8) atom. In the fourth Pb site, Pb(4) is bonded in a 6-coordinate geometry to one O(11), one O(6), one O(7), one O(8), one Cl(5), and one Cl(7) atom. In the fifth Pb site, Pb(5) is bonded in a distorted rectangular see-saw-like geometry to one O(8), one Cl(3), one Cl(5), and one Cl(8) atom. In the sixth Pb site, Pb(6) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(11), one O(3), one O(4), and one Cl(1) atom. In the seventh Pb site, Pb(7) is bonded in a 5-coordinate geometry to one O(4), one O(9), one Cl(1), one Cl(4), and one Cl(6) atom. In the eighth Pb site, Pb(8) is bonded in a 5-coordinate geometry to one O(3), one O(7), one O(9), one Cl(2), and one Cl(3) atom. There are four inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one O(12), one O(2), and one O(9) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one O(1), one O(11), and one O(6) atom. In the third C site, C(3) is bonded in a trigonal planar geometry to one O(10), one O(4), and one O(5) atom. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one O(3), one O(7), and one O(8) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Pb(6) and one C(2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Pb(1) and one C(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Pb(6), one Pb(8), and one C(4) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Pb(6), one Pb(7), and one C(3) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Pb(1), one Pb(3), and one C(3) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Pb(3), one Pb(4), and one C(2) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one Pb(4), one Pb(8), and one C(4) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one Pb(1), one Pb(4), one Pb(5), and one C(4) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one Pb(7), one Pb(8), and one C(1) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to one Pb(1), one Pb(6), and one C(3) atom. In the eleventh O site, O(11) is bonded in a distorted single-bond geometry to one Pb(4), one Pb(6), and one C(2) atom. In the twelfth O site, O(12) is bonded in a distorted single-bond geometry to one Pb(1), one Pb(2), and one C(1) atom. There are eight inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a T-shaped geometry to one Pb(2), one Pb(6), and one Pb(7) atom. In the second Cl site, Cl(2) is bonded in a water-like geometry to one Pb(2) and one Pb(8) atom. In the third Cl site, Cl(3) is bonded in a distorted bent 150 degrees geometry to one Pb(5) and one Pb(8) atom. In the fourth Cl site, Cl(4) is bonded in a distorted L-shaped geometry to one Pb(2) and one Pb(7) atom. In the fifth Cl site, Cl(5) is bonded in a 3-coordinate geometry to one Pb(3), one Pb(4), and one Pb(5) atom. In the sixth Cl site, Cl(6) is bonded in an L-shaped geometry to one Pb(3) and one Pb(7) atom. In the seventh Cl site, Cl(7) is bonded in a water-like geometry to one Pb(1) and one Pb(4) atom. In the eighth Cl site, Cl(8) is bonded in a water-like geometry to one Pb(3) and one Pb(5) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Pb2CCl2O3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.710
_cell_length_b   8.995
_cell_length_c   9.078
_cell_angle_alpha   88.055
_cell_angle_beta   89.135
_cell_angle_gamma   86.862
_symmetry_Int_Tables_number   1
_cell_volume   709.788
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pb  Pb0  1  0.138  0.685  0.651  1.0
  Pb  Pb1  1  0.211  0.178  0.665  1.0
  Pb  Pb2  1  0.696  0.780  0.886  1.0
  Pb  Pb3  1  0.429  0.720  0.262  1.0
  Pb  Pb4  1  0.889  0.805  0.313  1.0
  Pb  Pb5  1  0.806  0.321  0.408  1.0
  Pb  Pb6  1  0.639  0.233  0.829  1.0
  Pb  Pb7  1  0.248  0.245  0.123  1.0
  C  C8  1  0.314  0.471  0.819  1.0
  C  C9  1  0.678  0.501  0.167  1.0
  C  C10  1  0.844  0.512  0.671  1.0
  C  C11  1  0.171  0.515  0.285  1.0
  Cl  Cl12  1  0.513  0.204  0.542  1.0
  Cl  Cl13  1  0.025  0.250  0.914  1.0
  Cl  Cl14  1  0.089  0.041  0.338  1.0
  Cl  Cl15  1  0.379  0.009  0.871  1.0
  Cl  Cl16  1  0.639  0.973  0.173  1.0
  Cl  Cl17  1  0.848  0.999  0.676  1.0
  Cl  Cl18  1  0.446  0.767  0.555  1.0
  Cl  Cl19  1  0.974  0.790  0.031  1.0
  O  O20  1  0.730  0.368  0.147  1.0
  O  O21  1  0.287  0.602  0.865  1.0
  O  O22  1  0.068  0.425  0.251  1.0
  O  O23  1  0.723  0.435  0.673  1.0
  O  O24  1  0.872  0.606  0.771  1.0
  O  O25  1  0.616  0.588  0.065  1.0
  O  O26  1  0.316  0.476  0.259  1.0
  O  O27  1  0.140  0.645  0.340  1.0
  O  O28  1  0.389  0.366  0.895  1.0
  O  O29  1  0.942  0.498  0.562  1.0
  O  O30  1  0.681  0.555  0.303  1.0
  O  O31  1  0.259  0.439  0.689  1.0
[/CIF]
.
The material structure described by Pb2Cl2CO3 crystallizes in the triclinic P1 space group. There are eight inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 6-coordinate geometry to one O(10), one O(12), one O(2), one O(5), one O(8), and one Cl(7) atom. In the second Pb site, Pb(2) is bonded in a 4-coordinate geometry to one O(12), one Cl(1), one Cl(2), and one Cl(4) atom. In the third Pb site, Pb(3) is bonded in a 4-coordinate geometry to one O(5), one O(6), one Cl(5), one Cl(6), and one Cl(8) atom. In the fourth Pb site, Pb(4) is bonded in a 6-coordinate geometry to one O(11), one O(6), one O(7), one O(8), one Cl(5), and one Cl(7) atom. In the fifth Pb site, Pb(5) is bonded in a distorted rectangular see-saw-like geometry to one O(8), one Cl(3), one Cl(5), and one Cl(8) atom. In the sixth Pb site, Pb(6) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(11), one O(3), one O(4), and one Cl(1) atom. In the seventh Pb site, Pb(7) is bonded in a 5-coordinate geometry to one O(4), one O(9), one Cl(1), one Cl(4), and one Cl(6) atom. In the eighth Pb site, Pb(8) is bonded in a 5-coordinate geometry to one O(3), one O(7), one O(9), one Cl(2), and one Cl(3) atom. There are four inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one O(12), one O(2), and one O(9) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one O(1), one O(11), and one O(6) atom. In the third C site, C(3) is bonded in a trigonal planar geometry to one O(10), one O(4), and one O(5) atom. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one O(3), one O(7), and one O(8) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Pb(6) and one C(2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Pb(1) and one C(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Pb(6), one Pb(8), and one C(4) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Pb(6), one Pb(7), and one C(3) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Pb(1), one Pb(3), and one C(3) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Pb(3), one Pb(4), and one C(2) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one Pb(4), one Pb(8), and one C(4) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one Pb(1), one Pb(4), one Pb(5), and one C(4) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one Pb(7), one Pb(8), and one C(1) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to one Pb(1), one Pb(6), and one C(3) atom. In the eleventh O site, O(11) is bonded in a distorted single-bond geometry to one Pb(4), one Pb(6), and one C(2) atom. In the twelfth O site, O(12) is bonded in a distorted single-bond geometry to one Pb(1), one Pb(2), and one C(1) atom. There are eight inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a T-shaped geometry to one Pb(2), one Pb(6), and one Pb(7) atom. In the second Cl site, Cl(2) is bonded in a water-like geometry to one Pb(2) and one Pb(8) atom. In the third Cl site, Cl(3) is bonded in a distorted bent 150 degrees geometry to one Pb(5) and one Pb(8) atom. In the fourth Cl site, Cl(4) is bonded in a distorted L-shaped geometry to one Pb(2) and one Pb(7) atom. In the fifth Cl site, Cl(5) is bonded in a 3-coordinate geometry to one Pb(3), one Pb(4), and one Pb(5) atom. In the sixth Cl site, Cl(6) is bonded in an L-shaped geometry to one Pb(3) and one Pb(7) atom. In the seventh Cl site, Cl(7) is bonded in a water-like geometry to one Pb(1) and one Pb(4) atom. In the eighth Cl site, Cl(8) is bonded in a water-like geometry to one Pb(3) and one Pb(5) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Pb2CCl2O3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.710
_cell_length_b   8.995
_cell_length_c   9.078
_cell_angle_alpha   88.055
_cell_angle_beta   89.135
_cell_angle_gamma   86.862
_symmetry_Int_Tables_number   1
_cell_volume   709.788
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pb  Pb0  1  0.138  0.685  0.651  1.0
  Pb  Pb1  1  0.211  0.178  0.665  1.0
  Pb  Pb2  1  0.696  0.780  0.886  1.0
  Pb  Pb3  1  0.429  0.720  0.262  1.0
  Pb  Pb4  1  0.889  0.805  0.313  1.0
  Pb  Pb5  1  0.806  0.321  0.408  1.0
  Pb  Pb6  1  0.639  0.233  0.829  1.0
  Pb  Pb7  1  0.248  0.245  0.123  1.0
  C  C8  1  0.314  0.471  0.819  1.0
  C  C9  1  0.678  0.501  0.167  1.0
  C  C10  1  0.844  0.512  0.671  1.0
  C  C11  1  0.171  0.515  0.285  1.0
  Cl  Cl12  1  0.513  0.204  0.542  1.0
  Cl  Cl13  1  0.025  0.250  0.914  1.0
  Cl  Cl14  1  0.089  0.041  0.338  1.0
  Cl  Cl15  1  0.379  0.009  0.871  1.0
  Cl  Cl16  1  0.639  0.973  0.173  1.0
  Cl  Cl17  1  0.848  0.999  0.676  1.0
  Cl  Cl18  1  0.446  0.767  0.555  1.0
  Cl  Cl19  1  0.974  0.790  0.031  1.0
  O  O20  1  0.730  0.368  0.147  1.0
  O  O21  1  0.287  0.602  0.865  1.0
  O  O22  1  0.068  0.425  0.251  1.0
  O  O23  1  0.723  0.435  0.673  1.0
  O  O24  1  0.872  0.606  0.771  1.0
  O  O25  1  0.616  0.588  0.065  1.0
  O  O26  1  0.316  0.476  0.259  1.0
  O  O27  1  0.140  0.645  0.340  1.0
  O  O28  1  0.389  0.366  0.895  1.0
  O  O29  1  0.942  0.498  0.562  1.0
  O  O30  1  0.681  0.555  0.303  1.0
  O  O31  1  0.259  0.439  0.689  1.0
[/CIF]
.