The material described by Ag3O4 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a rectangular see-saw-like geometry to two equivalent O(1) and two equivalent O(2) atoms. In the second Ag site, Ag(2) is bonded in a distorted square co-planar geometry to two equivalent O(1) and two equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Ag(2) and two equivalent Ag(1) atoms. In the second O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Ag(2) and two equivalent Ag(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ag3O4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.601
_cell_length_b   5.676
_cell_length_c   9.232
_cell_angle_alpha   90.002
_cell_angle_beta   90.001
_cell_angle_gamma   104.604
_symmetry_Int_Tables_number   1
_cell_volume   182.605
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.287  0.549  0.858  1.0
  Ag  Ag1  1  0.713  0.951  0.358  1.0
  Ag  Ag2  1  0.713  0.451  0.142  1.0
  Ag  Ag3  1  0.287  0.049  0.642  1.0
  Ag  Ag4  1  0.000  0.500  0.500  1.0
  Ag  Ag5  1  0.000  0.000  0.000  1.0
  O  O6  1  0.046  0.331  0.691  1.0
  O  O7  1  0.954  0.169  0.191  1.0
  O  O8  1  0.954  0.669  0.309  1.0
  O  O9  1  0.046  0.831  0.809  1.0
  O  O10  1  0.475  0.273  0.955  1.0
  O  O11  1  0.525  0.227  0.455  1.0
  O  O12  1  0.475  0.773  0.545  1.0
  O  O13  1  0.525  0.727  0.045  1.0
[/CIF]
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The material described by Ag3O4 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a rectangular see-saw-like geometry to two equivalent O(1) and two equivalent O(2) atoms. In the second Ag site, Ag(2) is bonded in a distorted square co-planar geometry to two equivalent O(1) and two equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Ag(2) and two equivalent Ag(1) atoms. In the second O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Ag(2) and two equivalent Ag(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ag3O4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.601
_cell_length_b   5.676
_cell_length_c   9.232
_cell_angle_alpha   90.002
_cell_angle_beta   90.001
_cell_angle_gamma   104.604
_symmetry_Int_Tables_number   1
_cell_volume   182.605
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.287  0.549  0.858  1.0
  Ag  Ag1  1  0.713  0.951  0.358  1.0
  Ag  Ag2  1  0.713  0.451  0.142  1.0
  Ag  Ag3  1  0.287  0.049  0.642  1.0
  Ag  Ag4  1  0.000  0.500  0.500  1.0
  Ag  Ag5  1  0.000  0.000  0.000  1.0
  O  O6  1  0.046  0.331  0.691  1.0
  O  O7  1  0.954  0.169  0.191  1.0
  O  O8  1  0.954  0.669  0.309  1.0
  O  O9  1  0.046  0.831  0.809  1.0
  O  O10  1  0.475  0.273  0.955  1.0
  O  O11  1  0.525  0.227  0.455  1.0
  O  O12  1  0.475  0.773  0.545  1.0
  O  O13  1  0.525  0.727  0.045  1.0
[/CIF]
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