The material described by (ReO3)2Pt(N2O)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one Pt(N2O)2 cluster and two ReO3 clusters. In the Pt(N2O)2 cluster, Pt(1) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent N(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Pt(1) and one O(3) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Pt(1) atom. O(3) is bonded in a single-bond geometry to one N(1) atom. In each ReO3 cluster, Re(1) is bonded in a trigonal non-coplanar geometry to one O(1), one O(2), and one O(4) atom. There are three inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one Re(1) atom. In the second O site, O(4) is bonded in a single-bond geometry to one Re(1) atom. In the third O site, O(1) is bonded in a single-bond geometry to one Re(1) atom. is represented by the CIF card [CIF]
data_Re2Pt(NO2)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.543
_cell_length_b   9.600
_cell_length_c   11.405
_cell_angle_alpha   64.293
_cell_angle_beta   98.129
_cell_angle_gamma   86.137
_symmetry_Int_Tables_number   1
_cell_volume   535.687
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.959  0.644  0.690  1.0
  Re  Re1  1  0.041  0.356  0.310  1.0
  Pt  Pt2  1  0.500  0.000  0.000  1.0
  N  N3  1  0.648  0.903  0.214  1.0
  N  N4  1  0.352  0.097  0.786  1.0
  N  N5  1  0.630  0.175  0.972  1.0
  N  N6  1  0.370  0.825  0.028  1.0
  O  O7  1  0.679  0.678  0.730  1.0
  O  O8  1  0.321  0.322  0.270  1.0
  O  O9  1  0.134  0.468  0.801  1.0
  O  O10  1  0.866  0.532  0.199  1.0
  O  O11  1  0.141  0.111  0.751  1.0
  O  O12  1  0.859  0.889  0.249  1.0
  O  O13  1  0.065  0.318  0.474  1.0
  O  O14  1  0.935  0.682  0.526  1.0
[/CIF]
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The material described by (ReO3)2Pt(N2O)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one Pt(N2O)2 cluster and two ReO3 clusters. In the Pt(N2O)2 cluster, Pt(1) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent N(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Pt(1) and one O(3) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Pt(1) atom. O(3) is bonded in a single-bond geometry to one N(1) atom. In each ReO3 cluster, Re(1) is bonded in a trigonal non-coplanar geometry to one O(1), one O(2), and one O(4) atom. There are three inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one Re(1) atom. In the second O site, O(4) is bonded in a single-bond geometry to one Re(1) atom. In the third O site, O(1) is bonded in a single-bond geometry to one Re(1) atom. is represented by the CIF card [CIF]
data_Re2Pt(NO2)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.543
_cell_length_b   9.600
_cell_length_c   11.405
_cell_angle_alpha   64.293
_cell_angle_beta   98.129
_cell_angle_gamma   86.137
_symmetry_Int_Tables_number   1
_cell_volume   535.687
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.959  0.644  0.690  1.0
  Re  Re1  1  0.041  0.356  0.310  1.0
  Pt  Pt2  1  0.500  0.000  0.000  1.0
  N  N3  1  0.648  0.903  0.214  1.0
  N  N4  1  0.352  0.097  0.786  1.0
  N  N5  1  0.630  0.175  0.972  1.0
  N  N6  1  0.370  0.825  0.028  1.0
  O  O7  1  0.679  0.678  0.730  1.0
  O  O8  1  0.321  0.322  0.270  1.0
  O  O9  1  0.134  0.468  0.801  1.0
  O  O10  1  0.866  0.532  0.199  1.0
  O  O11  1  0.141  0.111  0.751  1.0
  O  O12  1  0.859  0.889  0.249  1.0
  O  O13  1  0.065  0.318  0.474  1.0
  O  O14  1  0.935  0.682  0.526  1.0
[/CIF]
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