The crystal structure described by V2Zn3Pb3TeO14 crystallizes in the trigonal P321 space group. V(1) is bonded to one O(1) and three equivalent O(3) atoms to form VO4 tetrahedra that share corners with three equivalent Zn(1)O4 tetrahedra. Zn(1) is bonded to two equivalent O(2) and two equivalent O(3) atoms to form ZnO4 tetrahedra that share corners with two equivalent Te(1)O6 octahedra and corners with two equivalent V(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 61°. Pb(1) is bonded in a 4-coordinate geometry to two equivalent O(2) and two equivalent O(3) atoms. Te(1) is bonded to six equivalent O(2) atoms to form TeO6 octahedra that share corners with six equivalent Zn(1)O4 tetrahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one V(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Zn(1), one Pb(1), and one Te(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one V(1), one Zn(1), and one Pb(1) atom. is represented by the CIF file [CIF]
data_V2Zn3TePb3O14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.277
_cell_length_b   8.784
_cell_length_c   8.784
_cell_angle_alpha   120.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.001
_symmetry_Int_Tables_number   1
_cell_volume   352.636
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.546  0.667  0.333  1.0
  V  V1  1  0.454  0.333  0.667  1.0
  Zn  Zn2  1  0.500  0.242  1.000  1.0
  Zn  Zn3  1  0.500  0.000  0.242  1.0
  Zn  Zn4  1  0.500  0.758  0.758  1.0
  Te  Te5  1  0.000  0.000  0.000  1.0
  Pb  Pb6  1  1.000  0.000  0.608  1.0
  Pb  Pb7  1  0.000  0.392  0.392  1.0
  Pb  Pb8  1  1.000  0.608  1.000  1.0
  O  O9  1  0.220  0.667  0.333  1.0
  O  O10  1  0.780  0.333  0.667  1.0
  O  O11  1  0.787  0.087  0.877  1.0
  O  O12  1  0.787  0.123  0.210  1.0
  O  O13  1  0.787  0.790  0.913  1.0
  O  O14  1  0.213  0.913  0.790  1.0
  O  O15  1  0.213  0.210  0.123  1.0
  O  O16  1  0.213  0.877  0.087  1.0
  O  O17  1  0.669  0.739  0.545  1.0
  O  O18  1  0.669  0.455  0.194  1.0
  O  O19  1  0.669  0.806  0.261  1.0
  O  O20  1  0.331  0.261  0.806  1.0
  O  O21  1  0.331  0.194  0.455  1.0
  O  O22  1  0.331  0.545  0.739  1.0
[/CIF]
.
The crystal structure described by V2Zn3Pb3TeO14 crystallizes in the trigonal P321 space group. V(1) is bonded to one O(1) and three equivalent O(3) atoms to form VO4 tetrahedra that share corners with three equivalent Zn(1)O4 tetrahedra. Zn(1) is bonded to two equivalent O(2) and two equivalent O(3) atoms to form ZnO4 tetrahedra that share corners with two equivalent Te(1)O6 octahedra and corners with two equivalent V(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 61°. Pb(1) is bonded in a 4-coordinate geometry to two equivalent O(2) and two equivalent O(3) atoms. Te(1) is bonded to six equivalent O(2) atoms to form TeO6 octahedra that share corners with six equivalent Zn(1)O4 tetrahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one V(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Zn(1), one Pb(1), and one Te(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one V(1), one Zn(1), and one Pb(1) atom. is represented by the CIF file [CIF]
data_V2Zn3TePb3O14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.277
_cell_length_b   8.784
_cell_length_c   8.784
_cell_angle_alpha   120.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.001
_symmetry_Int_Tables_number   1
_cell_volume   352.636
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.546  0.667  0.333  1.0
  V  V1  1  0.454  0.333  0.667  1.0
  Zn  Zn2  1  0.500  0.242  1.000  1.0
  Zn  Zn3  1  0.500  0.000  0.242  1.0
  Zn  Zn4  1  0.500  0.758  0.758  1.0
  Te  Te5  1  0.000  0.000  0.000  1.0
  Pb  Pb6  1  1.000  0.000  0.608  1.0
  Pb  Pb7  1  0.000  0.392  0.392  1.0
  Pb  Pb8  1  1.000  0.608  1.000  1.0
  O  O9  1  0.220  0.667  0.333  1.0
  O  O10  1  0.780  0.333  0.667  1.0
  O  O11  1  0.787  0.087  0.877  1.0
  O  O12  1  0.787  0.123  0.210  1.0
  O  O13  1  0.787  0.790  0.913  1.0
  O  O14  1  0.213  0.913  0.790  1.0
  O  O15  1  0.213  0.210  0.123  1.0
  O  O16  1  0.213  0.877  0.087  1.0
  O  O17  1  0.669  0.739  0.545  1.0
  O  O18  1  0.669  0.455  0.194  1.0
  O  O19  1  0.669  0.806  0.261  1.0
  O  O20  1  0.331  0.261  0.806  1.0
  O  O21  1  0.331  0.194  0.455  1.0
  O  O22  1  0.331  0.545  0.739  1.0
[/CIF]
.