The structure described by KGdO2 is Caswellsilverite structured and crystallizes in the trigonal R-3m space group. K(1) is bonded to six equivalent O(1) atoms to form distorted KO6 octahedra that share corners with six equivalent Gd(1)O6 octahedra, edges with six equivalent K(1)O6 octahedra, and edges with six equivalent Gd(1)O6 octahedra. The corner-sharing octahedral tilt angles are 13°. Gd(1) is bonded to six equivalent O(1) atoms to form GdO6 octahedra that share corners with six equivalent K(1)O6 octahedra, edges with six equivalent K(1)O6 octahedra, and edges with six equivalent Gd(1)O6 octahedra. The corner-sharing octahedral tilt angles are 13°. O(1) is bonded to three equivalent K(1) and three equivalent Gd(1) atoms to form a mixture of corner and edge-sharing OK3Gd3 octahedra. The corner-sharing octahedra are not tilted. is represented by the CIF card [CIF]
data_KGdO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.522
_cell_length_b   6.522
_cell_length_c   6.522
_cell_angle_alpha   31.311
_cell_angle_beta   31.311
_cell_angle_gamma   31.311
_symmetry_Int_Tables_number   1
_cell_volume   66.482
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.000  0.000  0.000  1.0
  Gd  Gd1  1  0.500  0.500  0.500  1.0
  O  O2  1  0.230  0.230  0.230  1.0
  O  O3  1  0.770  0.770  0.770  1.0
[/CIF]
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The structure described by KGdO2 is Caswellsilverite structured and crystallizes in the trigonal R-3m space group. K(1) is bonded to six equivalent O(1) atoms to form distorted KO6 octahedra that share corners with six equivalent Gd(1)O6 octahedra, edges with six equivalent K(1)O6 octahedra, and edges with six equivalent Gd(1)O6 octahedra. The corner-sharing octahedral tilt angles are 13°. Gd(1) is bonded to six equivalent O(1) atoms to form GdO6 octahedra that share corners with six equivalent K(1)O6 octahedra, edges with six equivalent K(1)O6 octahedra, and edges with six equivalent Gd(1)O6 octahedra. The corner-sharing octahedral tilt angles are 13°. O(1) is bonded to three equivalent K(1) and three equivalent Gd(1) atoms to form a mixture of corner and edge-sharing OK3Gd3 octahedra. The corner-sharing octahedra are not tilted. is represented by the CIF card [CIF]
data_KGdO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.522
_cell_length_b   6.522
_cell_length_c   6.522
_cell_angle_alpha   31.311
_cell_angle_beta   31.311
_cell_angle_gamma   31.311
_symmetry_Int_Tables_number   1
_cell_volume   66.482
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.000  0.000  0.000  1.0
  Gd  Gd1  1  0.500  0.500  0.500  1.0
  O  O2  1  0.230  0.230  0.230  1.0
  O  O3  1  0.770  0.770  0.770  1.0
[/CIF]
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