The structure described by (LiV2P4HO14)4H2(HO2)2(O2)2 crystallizes in the triclinic P1 space group. The structure consists of one 1333-74-0 atom, one hydrogen peroxide molecule, and one water dimer molecule inside a LiV2P4HO14 framework. In the LiV2P4HO14 framework, there are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a 1-coordinate geometry to one P(4), one O(15), one O(21), one O(31), and one O(9) atom. In the second Li site, Li(2) is bonded in a distorted single-bond geometry to one P(5), one P(8), one O(12), one O(18), one O(24), and one O(28) atom. There are four inequivalent V sites. In the first V site, V(1) is bonded in a linear geometry to one O(11), one O(3), and one O(8) atom. In the second V site, V(2) is bonded in a 4-coordinate geometry to one O(13), one O(21), one O(28), and one O(5) atom. In the third V site, V(3) is bonded in a distorted rectangular see-saw-like geometry to one O(12), one O(20), one O(27), and one O(6) atom. In the fourth V site, V(4) is bonded in a linear geometry to one O(25), one O(30), and one O(31) atom. There are eight inequivalent P sites. In the first P site, P(1) is bonded in a distorted bent 120 degrees geometry to one O(10) and one O(6) atom. In the second P site, P(2) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(9) atom. In the third P site, P(3) is bonded in a distorted L-shaped geometry to one O(16) and one O(20) atom. In the fourth P site, P(4) is bonded in a 3-coordinate geometry to one Li(1), one O(21), and one O(29) atom. In the fifth P site, P(5) is bonded in a rectangular see-saw-like geometry to one Li(2), one O(12), one O(17), and one O(26) atom. In the sixth P site, P(6) is bonded in a 3-coordinate geometry to one O(13), one O(18), and one O(4) atom. In the seventh P site, P(7) is bonded in a distorted bent 120 degrees geometry to one O(23) and one O(27) atom. In the eighth P site, P(8) is bonded in a 3-coordinate geometry to one Li(2), one O(24), and one O(28) atom. There are two inequivalent H sites. In the first H site, H(2) is bonded in a distorted linear geometry to one O(26) and one O(29) atom. In the second H site, H(4) is bonded in a linear geometry to one O(1) and one O(32) atom. There are twenty-eight inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one H(4) and one O(17) atom. In the second O site, O(2) is bonded in a single-bond geometry to one O(29) atom. In the third O site, O(3) is bonded in a single-bond geometry to one V(1) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to one P(6) and one O(31) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one V(2), one P(2), and one O(21) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one V(3), one P(1), and one O(20) atom. In the seventh O site, O(8) is bonded in a single-bond geometry to one V(1) and one O(20) atom. In the eighth O site, O(9) is bonded in a distorted L-shaped geometry to one Li(1) and one P(2) atom. In the ninth O site, O(10) is bonded in a single-bond geometry to one P(1) atom. In the tenth O site, O(11) is bonded in a distorted single-bond geometry to one V(1) and one O(26) atom. In the eleventh O site, O(12) is bonded in a 5-coordinate geometry to one Li(2), one V(3), one P(5), one O(25), and one O(27) atom. In the twelfth O site, O(13) is bonded in a 3-coordinate geometry to one V(2), one P(6), and one O(28) atom. In the thirteenth O site, O(15) is bonded in a single-bond geometry to one Li(1) atom. In the fourteenth O site, O(16) is bonded in a 2-coordinate geometry to one P(3) and one O(32) atom. In the fifteenth O site, O(17) is bonded in a distorted bent 150 degrees geometry to one P(5) and one O(1) atom. In the sixteenth O site, O(18) is bonded in a single-bond geometry to one Li(2) and one P(6) atom. In the seventeenth O site, O(20) is bonded in a 4-coordinate geometry to one V(3), one P(3), one O(6), and one O(8) atom. In the eighteenth O site, O(21) is bonded in a 5-coordinate geometry to one Li(1), one V(2), one P(4), one O(30), and one O(5) atom. In the nineteenth O site, O(23) is bonded in a single-bond geometry to one P(7) atom. In the twentieth O site, O(24) is bonded in a distorted single-bond geometry to one Li(2) and one P(8) atom. In the twenty-first O site, O(25) is bonded in a single-bond geometry to one V(4) and one O(12) atom. In the twenty-second O site, O(26) is bonded in a 4-coordinate geometry to one P(5), one H(2), and one O(11) atom. In the twenty-third O site, O(27) is bonded in a 3-coordinate geometry to one V(3), one P(7), and one O(12) atom. In the twenty-fourth O site, O(28) is bonded in a 4-coordinate geometry to one Li(2), one V(2), one P(8), and one O(13) atom. In the twenty-fifth O site, O(29) is bonded in a 3-coordinate geometry to one P(4), one H(2), and one O(2) atom. In the twenty-sixth O site, O(30) is bonded in a single-bond geometry to one V(4) and one O(21) atom. In the twenty-seventh O site, O(31) is bonded in a 3-coordinate geometry to one Li(1), one V(4), and one O(4) atom. In the twenty-eighth O site, O(32) is bonded in a single-bond geometry to one H(4) and one O(16) atom. is represented by the CIF file [CIF]
data_LiV2P4(HO8)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.764
_cell_length_b   9.286
_cell_length_c   9.299
_cell_angle_alpha   116.567
_cell_angle_beta   101.908
_cell_angle_gamma   101.921
_symmetry_Int_Tables_number   1
_cell_volume   551.462
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.357  0.722  0.908  1.0
  Li  Li1  1  0.853  0.580  0.290  1.0
  V  V2  1  0.500  0.265  0.746  1.0
  V  V3  1  0.990  0.500  0.001  1.0
  V  V4  1  0.003  0.987  0.505  1.0
  V  V5  1  0.488  0.753  0.249  1.0
  P  P6  1  0.269  0.964  0.392  1.0
  P  P7  1  0.265  0.456  0.894  1.0
  P  P8  1  0.232  0.333  0.510  1.0
  P  P9  1  0.229  0.859  0.998  1.0
  P  P10  1  0.767  0.650  0.498  1.0
  P  P11  1  0.763  0.162  0.992  1.0
  P  P12  1  0.733  0.045  0.602  1.0
  P  P13  1  0.733  0.557  0.103  1.0
  H  H14  1  0.510  0.773  0.735  1.0
  H  H15  1  0.493  0.235  0.259  1.0
  H  H16  1  0.989  0.502  0.508  1.0
  H  H17  1  1.000  0.000  1.000  1.0
  O  O18  1  0.052  0.012  0.938  1.0
  O  O19  1  0.340  0.079  0.872  1.0
  O  O20  1  0.630  0.364  0.816  1.0
  O  O21  1  0.681  0.889  0.946  1.0
  O  O22  1  0.158  0.513  0.931  1.0
  O  O23  1  0.159  0.018  0.429  1.0
  O  O24  1  0.317  0.636  0.542  1.0
  O  O25  1  0.362  0.145  0.684  1.0
  O  O26  1  0.440  0.584  0.868  1.0
  O  O27  1  0.444  0.097  0.361  1.0
  O  O28  1  0.656  0.436  0.623  1.0
  O  O29  1  0.818  0.860  0.467  1.0
  O  O30  1  0.824  0.354  0.978  1.0
  O  O31  1  0.057  0.517  0.430  1.0
  O  O32  1  0.131  0.577  0.745  1.0
  O  O33  1  0.132  0.119  0.228  1.0
  O  O34  1  0.864  0.898  0.764  1.0
  O  O35  1  0.863  0.413  0.262  1.0
  O  O36  1  0.943  0.469  0.574  1.0
  O  O37  1  0.184  0.136  0.531  1.0
  O  O38  1  0.183  0.668  0.011  1.0
  O  O39  1  0.352  0.549  0.386  1.0
  O  O40  1  0.553  0.923  0.629  1.0
  O  O41  1  0.559  0.430  0.126  1.0
  O  O42  1  0.634  0.829  0.325  1.0
  O  O43  1  0.684  0.385  0.439  1.0
  O  O44  1  0.844  0.981  0.572  1.0
  O  O45  1  0.854  0.498  0.070  1.0
  O  O46  1  0.325  0.110  0.059  1.0
  O  O47  1  0.367  0.667  0.174  1.0
  O  O48  1  0.660  0.932  0.125  1.0
  O  O49  1  0.939  0.983  0.068  1.0
[/CIF]
.
The structure described by (LiV2P4HO14)4H2(HO2)2(O2)2 crystallizes in the triclinic P1 space group. The structure consists of one 1333-74-0 atom, one hydrogen peroxide molecule, and one water dimer molecule inside a LiV2P4HO14 framework. In the LiV2P4HO14 framework, there are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a 1-coordinate geometry to one P(4), one O(15), one O(21), one O(31), and one O(9) atom. In the second Li site, Li(2) is bonded in a distorted single-bond geometry to one P(5), one P(8), one O(12), one O(18), one O(24), and one O(28) atom. There are four inequivalent V sites. In the first V site, V(1) is bonded in a linear geometry to one O(11), one O(3), and one O(8) atom. In the second V site, V(2) is bonded in a 4-coordinate geometry to one O(13), one O(21), one O(28), and one O(5) atom. In the third V site, V(3) is bonded in a distorted rectangular see-saw-like geometry to one O(12), one O(20), one O(27), and one O(6) atom. In the fourth V site, V(4) is bonded in a linear geometry to one O(25), one O(30), and one O(31) atom. There are eight inequivalent P sites. In the first P site, P(1) is bonded in a distorted bent 120 degrees geometry to one O(10) and one O(6) atom. In the second P site, P(2) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(9) atom. In the third P site, P(3) is bonded in a distorted L-shaped geometry to one O(16) and one O(20) atom. In the fourth P site, P(4) is bonded in a 3-coordinate geometry to one Li(1), one O(21), and one O(29) atom. In the fifth P site, P(5) is bonded in a rectangular see-saw-like geometry to one Li(2), one O(12), one O(17), and one O(26) atom. In the sixth P site, P(6) is bonded in a 3-coordinate geometry to one O(13), one O(18), and one O(4) atom. In the seventh P site, P(7) is bonded in a distorted bent 120 degrees geometry to one O(23) and one O(27) atom. In the eighth P site, P(8) is bonded in a 3-coordinate geometry to one Li(2), one O(24), and one O(28) atom. There are two inequivalent H sites. In the first H site, H(2) is bonded in a distorted linear geometry to one O(26) and one O(29) atom. In the second H site, H(4) is bonded in a linear geometry to one O(1) and one O(32) atom. There are twenty-eight inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one H(4) and one O(17) atom. In the second O site, O(2) is bonded in a single-bond geometry to one O(29) atom. In the third O site, O(3) is bonded in a single-bond geometry to one V(1) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to one P(6) and one O(31) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one V(2), one P(2), and one O(21) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one V(3), one P(1), and one O(20) atom. In the seventh O site, O(8) is bonded in a single-bond geometry to one V(1) and one O(20) atom. In the eighth O site, O(9) is bonded in a distorted L-shaped geometry to one Li(1) and one P(2) atom. In the ninth O site, O(10) is bonded in a single-bond geometry to one P(1) atom. In the tenth O site, O(11) is bonded in a distorted single-bond geometry to one V(1) and one O(26) atom. In the eleventh O site, O(12) is bonded in a 5-coordinate geometry to one Li(2), one V(3), one P(5), one O(25), and one O(27) atom. In the twelfth O site, O(13) is bonded in a 3-coordinate geometry to one V(2), one P(6), and one O(28) atom. In the thirteenth O site, O(15) is bonded in a single-bond geometry to one Li(1) atom. In the fourteenth O site, O(16) is bonded in a 2-coordinate geometry to one P(3) and one O(32) atom. In the fifteenth O site, O(17) is bonded in a distorted bent 150 degrees geometry to one P(5) and one O(1) atom. In the sixteenth O site, O(18) is bonded in a single-bond geometry to one Li(2) and one P(6) atom. In the seventeenth O site, O(20) is bonded in a 4-coordinate geometry to one V(3), one P(3), one O(6), and one O(8) atom. In the eighteenth O site, O(21) is bonded in a 5-coordinate geometry to one Li(1), one V(2), one P(4), one O(30), and one O(5) atom. In the nineteenth O site, O(23) is bonded in a single-bond geometry to one P(7) atom. In the twentieth O site, O(24) is bonded in a distorted single-bond geometry to one Li(2) and one P(8) atom. In the twenty-first O site, O(25) is bonded in a single-bond geometry to one V(4) and one O(12) atom. In the twenty-second O site, O(26) is bonded in a 4-coordinate geometry to one P(5), one H(2), and one O(11) atom. In the twenty-third O site, O(27) is bonded in a 3-coordinate geometry to one V(3), one P(7), and one O(12) atom. In the twenty-fourth O site, O(28) is bonded in a 4-coordinate geometry to one Li(2), one V(2), one P(8), and one O(13) atom. In the twenty-fifth O site, O(29) is bonded in a 3-coordinate geometry to one P(4), one H(2), and one O(2) atom. In the twenty-sixth O site, O(30) is bonded in a single-bond geometry to one V(4) and one O(21) atom. In the twenty-seventh O site, O(31) is bonded in a 3-coordinate geometry to one Li(1), one V(4), and one O(4) atom. In the twenty-eighth O site, O(32) is bonded in a single-bond geometry to one H(4) and one O(16) atom. is represented by the CIF file [CIF]
data_LiV2P4(HO8)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.764
_cell_length_b   9.286
_cell_length_c   9.299
_cell_angle_alpha   116.567
_cell_angle_beta   101.908
_cell_angle_gamma   101.921
_symmetry_Int_Tables_number   1
_cell_volume   551.462
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.357  0.722  0.908  1.0
  Li  Li1  1  0.853  0.580  0.290  1.0
  V  V2  1  0.500  0.265  0.746  1.0
  V  V3  1  0.990  0.500  0.001  1.0
  V  V4  1  0.003  0.987  0.505  1.0
  V  V5  1  0.488  0.753  0.249  1.0
  P  P6  1  0.269  0.964  0.392  1.0
  P  P7  1  0.265  0.456  0.894  1.0
  P  P8  1  0.232  0.333  0.510  1.0
  P  P9  1  0.229  0.859  0.998  1.0
  P  P10  1  0.767  0.650  0.498  1.0
  P  P11  1  0.763  0.162  0.992  1.0
  P  P12  1  0.733  0.045  0.602  1.0
  P  P13  1  0.733  0.557  0.103  1.0
  H  H14  1  0.510  0.773  0.735  1.0
  H  H15  1  0.493  0.235  0.259  1.0
  H  H16  1  0.989  0.502  0.508  1.0
  H  H17  1  1.000  0.000  1.000  1.0
  O  O18  1  0.052  0.012  0.938  1.0
  O  O19  1  0.340  0.079  0.872  1.0
  O  O20  1  0.630  0.364  0.816  1.0
  O  O21  1  0.681  0.889  0.946  1.0
  O  O22  1  0.158  0.513  0.931  1.0
  O  O23  1  0.159  0.018  0.429  1.0
  O  O24  1  0.317  0.636  0.542  1.0
  O  O25  1  0.362  0.145  0.684  1.0
  O  O26  1  0.440  0.584  0.868  1.0
  O  O27  1  0.444  0.097  0.361  1.0
  O  O28  1  0.656  0.436  0.623  1.0
  O  O29  1  0.818  0.860  0.467  1.0
  O  O30  1  0.824  0.354  0.978  1.0
  O  O31  1  0.057  0.517  0.430  1.0
  O  O32  1  0.131  0.577  0.745  1.0
  O  O33  1  0.132  0.119  0.228  1.0
  O  O34  1  0.864  0.898  0.764  1.0
  O  O35  1  0.863  0.413  0.262  1.0
  O  O36  1  0.943  0.469  0.574  1.0
  O  O37  1  0.184  0.136  0.531  1.0
  O  O38  1  0.183  0.668  0.011  1.0
  O  O39  1  0.352  0.549  0.386  1.0
  O  O40  1  0.553  0.923  0.629  1.0
  O  O41  1  0.559  0.430  0.126  1.0
  O  O42  1  0.634  0.829  0.325  1.0
  O  O43  1  0.684  0.385  0.439  1.0
  O  O44  1  0.844  0.981  0.572  1.0
  O  O45  1  0.854  0.498  0.070  1.0
  O  O46  1  0.325  0.110  0.059  1.0
  O  O47  1  0.367  0.667  0.174  1.0
  O  O48  1  0.660  0.932  0.125  1.0
  O  O49  1  0.939  0.983  0.068  1.0
[/CIF]
.