The material described by In(PO3)3 crystallizes in the triclinic P1 space group. There are two inequivalent In sites. In the first In site, In(1) is bonded in an octahedral geometry to one O(1), one O(10), one O(11), one O(12), one O(2), and one O(3) atom. In the second In site, In(2) is bonded in an octahedral geometry to one O(4), one O(5), one O(6), one O(7), one O(8), and one O(9) atom. There are six inequivalent P sites. In the first P site, P(1) is bonded in a trigonal planar geometry to one O(1), one O(13), and one O(7) atom. In the second P site, P(2) is bonded in a trigonal planar geometry to one O(14), one O(2), and one O(8) atom. In the third P site, P(3) is bonded in a trigonal planar geometry to one O(17), one O(3), and one O(9) atom. In the fourth P site, P(4) is bonded in a trigonal planar geometry to one O(10), one O(15), and one O(4) atom. In the fifth P site, P(5) is bonded in a trigonal planar geometry to one O(11), one O(18), and one O(5) atom. In the sixth P site, P(6) is bonded in a trigonal planar geometry to one O(12), one O(16), and one O(6) atom. There are eighteen inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one In(1) and one P(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one In(1) and one P(2) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one In(1) and one P(3) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one In(2) and one P(4) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one In(2) and one P(5) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one In(2) and one P(6) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one In(2) and one P(1) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one In(2) and one P(2) atom. In the ninth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one In(2) and one P(3) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one In(1) and one P(4) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to one In(1) and one P(5) atom. In the twelfth O site, O(12) is bonded in a bent 150 degrees geometry to one In(1) and one P(6) atom. In the thirteenth O site, O(13) is bonded in a single-bond geometry to one P(1) atom. In the fourteenth O site, O(14) is bonded in a single-bond geometry to one P(2) atom. In the fifteenth O site, O(15) is bonded in a single-bond geometry to one P(4) atom. In the sixteenth O site, O(16) is bonded in a single-bond geometry to one P(6) atom. In the seventeenth O site, O(17) is bonded in a single-bond geometry to one P(3) atom. In the eighteenth O site, O(18) is bonded in a single-bond geometry to one P(5) atom. is represented by the CIF file [CIF]
data_In(PO3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.443
_cell_length_b   8.784
_cell_length_c   8.559
_cell_angle_alpha   58.929
_cell_angle_beta   91.216
_cell_angle_gamma   90.448
_symmetry_Int_Tables_number   1
_cell_volume   479.224
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.508  0.335  0.330  1.0
  In  In1  1  0.006  0.671  0.661  1.0
  P  P2  1  0.707  0.681  0.977  1.0
  P  P3  1  0.696  0.345  0.687  1.0
  P  P4  1  0.665  0.933  0.407  1.0
  P  P5  1  0.197  0.316  0.025  1.0
  P  P6  1  0.161  0.590  0.334  1.0
  P  P7  1  0.197  0.024  0.659  1.0
  O  O8  1  0.674  0.482  0.094  1.0
  O  O9  1  0.679  0.404  0.487  1.0
  O  O10  1  0.681  0.111  0.393  1.0
  O  O11  1  0.178  0.516  0.896  1.0
  O  O12  1  0.174  0.600  0.505  1.0
  O  O13  1  0.176  0.900  0.587  1.0
  O  O14  1  0.821  0.735  0.814  1.0
  O  O15  1  0.826  0.451  0.728  1.0
  O  O16  1  0.843  0.844  0.427  1.0
  O  O17  1  0.332  0.264  0.176  1.0
  O  O18  1  0.335  0.556  0.272  1.0
  O  O19  1  0.319  0.180  0.551  1.0
  O  O20  1  0.612  0.812  0.003  1.0
  O  O21  1  0.592  0.198  0.829  1.0
  O  O22  1  0.092  0.184  0.007  1.0
  O  O23  1  0.101  0.000  0.817  1.0
  O  O24  1  0.493  0.851  0.405  1.0
  O  O25  1  0.989  0.607  0.237  1.0
[/CIF]
.
The material described by In(PO3)3 crystallizes in the triclinic P1 space group. There are two inequivalent In sites. In the first In site, In(1) is bonded in an octahedral geometry to one O(1), one O(10), one O(11), one O(12), one O(2), and one O(3) atom. In the second In site, In(2) is bonded in an octahedral geometry to one O(4), one O(5), one O(6), one O(7), one O(8), and one O(9) atom. There are six inequivalent P sites. In the first P site, P(1) is bonded in a trigonal planar geometry to one O(1), one O(13), and one O(7) atom. In the second P site, P(2) is bonded in a trigonal planar geometry to one O(14), one O(2), and one O(8) atom. In the third P site, P(3) is bonded in a trigonal planar geometry to one O(17), one O(3), and one O(9) atom. In the fourth P site, P(4) is bonded in a trigonal planar geometry to one O(10), one O(15), and one O(4) atom. In the fifth P site, P(5) is bonded in a trigonal planar geometry to one O(11), one O(18), and one O(5) atom. In the sixth P site, P(6) is bonded in a trigonal planar geometry to one O(12), one O(16), and one O(6) atom. There are eighteen inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one In(1) and one P(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one In(1) and one P(2) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one In(1) and one P(3) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one In(2) and one P(4) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one In(2) and one P(5) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one In(2) and one P(6) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one In(2) and one P(1) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one In(2) and one P(2) atom. In the ninth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one In(2) and one P(3) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one In(1) and one P(4) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to one In(1) and one P(5) atom. In the twelfth O site, O(12) is bonded in a bent 150 degrees geometry to one In(1) and one P(6) atom. In the thirteenth O site, O(13) is bonded in a single-bond geometry to one P(1) atom. In the fourteenth O site, O(14) is bonded in a single-bond geometry to one P(2) atom. In the fifteenth O site, O(15) is bonded in a single-bond geometry to one P(4) atom. In the sixteenth O site, O(16) is bonded in a single-bond geometry to one P(6) atom. In the seventeenth O site, O(17) is bonded in a single-bond geometry to one P(3) atom. In the eighteenth O site, O(18) is bonded in a single-bond geometry to one P(5) atom. is represented by the CIF file [CIF]
data_In(PO3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.443
_cell_length_b   8.784
_cell_length_c   8.559
_cell_angle_alpha   58.929
_cell_angle_beta   91.216
_cell_angle_gamma   90.448
_symmetry_Int_Tables_number   1
_cell_volume   479.224
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.508  0.335  0.330  1.0
  In  In1  1  0.006  0.671  0.661  1.0
  P  P2  1  0.707  0.681  0.977  1.0
  P  P3  1  0.696  0.345  0.687  1.0
  P  P4  1  0.665  0.933  0.407  1.0
  P  P5  1  0.197  0.316  0.025  1.0
  P  P6  1  0.161  0.590  0.334  1.0
  P  P7  1  0.197  0.024  0.659  1.0
  O  O8  1  0.674  0.482  0.094  1.0
  O  O9  1  0.679  0.404  0.487  1.0
  O  O10  1  0.681  0.111  0.393  1.0
  O  O11  1  0.178  0.516  0.896  1.0
  O  O12  1  0.174  0.600  0.505  1.0
  O  O13  1  0.176  0.900  0.587  1.0
  O  O14  1  0.821  0.735  0.814  1.0
  O  O15  1  0.826  0.451  0.728  1.0
  O  O16  1  0.843  0.844  0.427  1.0
  O  O17  1  0.332  0.264  0.176  1.0
  O  O18  1  0.335  0.556  0.272  1.0
  O  O19  1  0.319  0.180  0.551  1.0
  O  O20  1  0.612  0.812  0.003  1.0
  O  O21  1  0.592  0.198  0.829  1.0
  O  O22  1  0.092  0.184  0.007  1.0
  O  O23  1  0.101  0.000  0.817  1.0
  O  O24  1  0.493  0.851  0.405  1.0
  O  O25  1  0.989  0.607  0.237  1.0
[/CIF]
.