The compound described by Sr2La2MnZnO8 is (La,Ba)CuO4-derived structured and crystallizes in the monoclinic C2/m space group. There are two inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 9-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), two equivalent O(7), and two equivalent O(8) atoms. In the second Sr site, Sr(2) is bonded in a 9-coordinate geometry to one O(1), one O(10), one O(2), one O(3), one O(4), one O(6), one O(9), and two equivalent O(7) atoms. There are four inequivalent La sites. In the first La site, La(1) is bonded in a 9-coordinate geometry to one O(1), two equivalent O(11), two equivalent O(13), two equivalent O(5), and two equivalent O(6) atoms. In the second La site, La(2) is bonded in a 9-coordinate geometry to one O(2), two equivalent O(12), two equivalent O(13), two equivalent O(5), and two equivalent O(6) atoms. In the third La site, La(3) is bonded in a 9-coordinate geometry to one O(11), one O(12), one O(3), two equivalent O(14), two equivalent O(5), and two equivalent O(6) atoms. In the fourth La site, La(4) is bonded in a 9-coordinate geometry to one O(11), one O(12), one O(4), two equivalent O(14), two equivalent O(5), and two equivalent O(6) atoms. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(2), one O(3), one O(8), one O(9), and two equivalent O(7) atoms to form corner-sharing MnO6 octahedra. The corner-sharing octahedra are not tilted. In the second Mn site, Mn(2) is bonded to one O(1), one O(10), one O(4), one O(8), and two equivalent O(7) atoms to form corner-sharing MnO6 octahedra. The corner-sharing octahedra are not tilted. Zn(1) is bonded to one O(11), one O(12), one O(13), one O(14), one O(5), and one O(6) atom to form corner-sharing ZnO6 octahedra. The corner-sharing octahedra are not tilted. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Sr(1), two equivalent Sr(2), one La(1), and one Mn(2) atom to form distorted OSr4LaMn octahedra that share corners with two equivalent O(11)La4Zn2 octahedra, corners with two equivalent O(13)La4Zn2 octahedra, corners with two equivalent O(3)Sr4LaMn octahedra, corners with two equivalent O(8)Sr4Mn2 octahedra, corners with two equivalent O(9)Sr4Mn2 octahedra, corners with three equivalent O(4)Sr4LaMn octahedra, corners with four equivalent O(7)Sr4Mn2 octahedra,  an edgeedge with one O(3)Sr4LaMn octahedra,  an edgeedge with one O(4)Sr4LaMn octahedra, edges with two equivalent O(2)Sr4LaMn octahedra, edges with two equivalent O(5)SrLa4Zn octahedra, edges with two equivalent O(6)SrLa4Zn octahedra,  a faceface with one O(10)Sr4Mn2 octahedra,  a faceface with one O(8)Sr4Mn2 octahedra, and faces with two equivalent O(7)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 1-55°. In the second O site, O(2) is bonded to two equivalent Sr(1), two equivalent Sr(2), one La(2), and one Mn(1) atom to form distorted OSr4LaMn octahedra that share corners with two equivalent O(12)La4Zn2 octahedra, corners with two equivalent O(13)La4Zn2 octahedra, corners with two equivalent O(4)Sr4LaMn octahedra, corners with two equivalent O(10)Sr4Mn2 octahedra, corners with two equivalent O(8)Sr4Mn2 octahedra, corners with three equivalent O(3)Sr4LaMn octahedra, corners with four equivalent O(7)Sr4Mn2 octahedra,  an edgeedge with one O(3)Sr4LaMn octahedra,  an edgeedge with one O(4)Sr4LaMn octahedra, edges with two equivalent O(1)Sr4LaMn octahedra, edges with two equivalent O(5)SrLa4Zn octahedra, edges with two equivalent O(6)SrLa4Zn octahedra,  a faceface with one O(8)Sr4Mn2 octahedra,  a faceface with one O(9)Sr4Mn2 octahedra, and faces with two equivalent O(7)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 1-54°. In the third O site, O(3) is bonded to two equivalent Sr(1), two equivalent Sr(2), one La(3), and one Mn(1) atom to form distorted OSr4LaMn octahedra that share  a cornercorner with one O(11)La4Zn2 octahedra,  a cornercorner with one O(12)La4Zn2 octahedra, corners with two equivalent O(14)La4Zn2 octahedra, corners with two equivalent O(1)Sr4LaMn octahedra, corners with two equivalent O(10)Sr4Mn2 octahedra, corners with two equivalent O(8)Sr4Mn2 octahedra, corners with three equivalent O(2)Sr4LaMn octahedra, corners with four equivalent O(7)Sr4Mn2 octahedra,  an edgeedge with one O(1)Sr4LaMn octahedra,  an edgeedge with one O(2)Sr4LaMn octahedra, edges with two equivalent O(4)Sr4LaMn octahedra, edges with two equivalent O(5)SrLa4Zn octahedra, edges with two equivalent O(6)SrLa4Zn octahedra,  a faceface with one O(8)Sr4Mn2 octahedra,  a faceface with one O(9)Sr4Mn2 octahedra, and faces with two equivalent O(7)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 1-54°. In the fourth O site, O(4) is bonded to two equivalent Sr(1), two equivalent Sr(2), one La(4), and one Mn(2) atom to form distorted OSr4LaMn octahedra that share  a cornercorner with one O(11)La4Zn2 octahedra,  a cornercorner with one O(12)La4Zn2 octahedra, corners with two equivalent O(14)La4Zn2 octahedra, corners with two equivalent O(2)Sr4LaMn octahedra, corners with two equivalent O(8)Sr4Mn2 octahedra, corners with two equivalent O(9)Sr4Mn2 octahedra, corners with three equivalent O(1)Sr4LaMn octahedra, corners with four equivalent O(7)Sr4Mn2 octahedra,  an edgeedge with one O(1)Sr4LaMn octahedra,  an edgeedge with one O(2)Sr4LaMn octahedra, edges with two equivalent O(3)Sr4LaMn octahedra, edges with two equivalent O(5)SrLa4Zn octahedra, edges with two equivalent O(6)SrLa4Zn octahedra,  a faceface with one O(10)Sr4Mn2 octahedra,  a faceface with one O(8)Sr4Mn2 octahedra, and faces with two equivalent O(7)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 1-55°. In the fifth O site, O(5) is bonded to one Sr(1), one La(1), one La(2), one La(3), one La(4), and one Zn(1) atom to form distorted OSrLa4Zn octahedra that share corners with two equivalent O(11)La4Zn2 octahedra, corners with two equivalent O(12)La4Zn2 octahedra, corners with two equivalent O(13)La4Zn2 octahedra, corners with two equivalent O(14)La4Zn2 octahedra, corners with two equivalent O(7)Sr4Mn2 octahedra, corners with two equivalent O(8)Sr4Mn2 octahedra, corners with five equivalent O(6)SrLa4Zn octahedra,  an edgeedge with one O(1)Sr4LaMn octahedra,  an edgeedge with one O(2)Sr4LaMn octahedra,  an edgeedge with one O(3)Sr4LaMn octahedra,  an edgeedge with one O(4)Sr4LaMn octahedra, edges with two equivalent O(5)SrLa4Zn octahedra, edges with two equivalent O(6)SrLa4Zn octahedra,  a faceface with one O(11)La4Zn2 octahedra,  a faceface with one O(12)La4Zn2 octahedra,  a faceface with one O(13)La4Zn2 octahedra, and  a faceface with one O(14)La4Zn2 octahedra. The corner-sharing octahedral tilt angles range from 0-53°. In the sixth O site, O(6) is bonded to one Sr(2), one La(1), one La(2), one La(3), one La(4), and one Zn(1) atom to form distorted OSrLa4Zn octahedra that share  a cornercorner with one O(10)Sr4Mn2 octahedra,  a cornercorner with one O(9)Sr4Mn2 octahedra, corners with two equivalent O(11)La4Zn2 octahedra, corners with two equivalent O(12)La4Zn2 octahedra, corners with two equivalent O(13)La4Zn2 octahedra, corners with two equivalent O(14)La4Zn2 octahedra, corners with two equivalent O(7)Sr4Mn2 octahedra, corners with five equivalent O(5)SrLa4Zn octahedra,  an edgeedge with one O(1)Sr4LaMn octahedra,  an edgeedge with one O(2)Sr4LaMn octahedra,  an edgeedge with one O(3)Sr4LaMn octahedra,  an edgeedge with one O(4)Sr4LaMn octahedra, edges with two equivalent O(5)SrLa4Zn octahedra, edges with two equivalent O(6)SrLa4Zn octahedra,  a faceface with one O(11)La4Zn2 octahedra,  a faceface with one O(12)La4Zn2 octahedra,  a faceface with one O(13)La4Zn2 octahedra, and  a faceface with one O(14)La4Zn2 octahedra. The corner-sharing octahedral tilt angles range from 0-53°. In the seventh O site, O(7) is bonded to two equivalent Sr(1), two equivalent Sr(2), one Mn(1), and one Mn(2) atom to form distorted OSr4Mn2 octahedra that share corners with two equivalent O(1)Sr4LaMn octahedra, corners with two equivalent O(2)Sr4LaMn octahedra, corners with two equivalent O(3)Sr4LaMn octahedra, corners with two equivalent O(4)Sr4LaMn octahedra, corners with two equivalent O(7)Sr4Mn2 octahedra, corners with two equivalent O(5)SrLa4Zn octahedra, corners with two equivalent O(6)SrLa4Zn octahedra, edges with two equivalent O(7)Sr4Mn2 octahedra,  a faceface with one O(1)Sr4LaMn octahedra,  a faceface with one O(2)Sr4LaMn octahedra,  a faceface with one O(3)Sr4LaMn octahedra,  a faceface with one O(4)Sr4LaMn octahedra,  a faceface with one O(10)Sr4Mn2 octahedra,  a faceface with one O(9)Sr4Mn2 octahedra, and faces with two equivalent O(8)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-54°. In the eighth O site, O(8) is bonded to four equivalent Sr(1), one Mn(1), and one Mn(2) atom to form distorted OSr4Mn2 octahedra that share  a cornercorner with one O(10)Sr4Mn2 octahedra,  a cornercorner with one O(9)Sr4Mn2 octahedra, corners with two equivalent O(1)Sr4LaMn octahedra, corners with two equivalent O(2)Sr4LaMn octahedra, corners with two equivalent O(3)Sr4LaMn octahedra, corners with two equivalent O(4)Sr4LaMn octahedra, corners with four equivalent O(5)SrLa4Zn octahedra, edges with two equivalent O(8)Sr4Mn2 octahedra,  a faceface with one O(1)Sr4LaMn octahedra,  a faceface with one O(2)Sr4LaMn octahedra,  a faceface with one O(3)Sr4LaMn octahedra,  a faceface with one O(4)Sr4LaMn octahedra, and faces with four equivalent O(7)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-55°. In the ninth O site, O(9) is bonded to four equivalent Sr(2) and two equivalent Mn(1) atoms to form distorted OSr4Mn2 octahedra that share corners with two equivalent O(8)Sr4Mn2 octahedra, corners with four equivalent O(1)Sr4LaMn octahedra, corners with four equivalent O(4)Sr4LaMn octahedra, corners with four equivalent O(6)SrLa4Zn octahedra, edges with two equivalent O(10)Sr4Mn2 octahedra, faces with two equivalent O(2)Sr4LaMn octahedra, faces with two equivalent O(3)Sr4LaMn octahedra, and faces with four equivalent O(7)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-53°. In the tenth O site, O(10) is bonded to four equivalent Sr(2) and two equivalent Mn(2) atoms to form distorted OSr4Mn2 octahedra that share corners with two equivalent O(8)Sr4Mn2 octahedra, corners with four equivalent O(2)Sr4LaMn octahedra, corners with four equivalent O(3)Sr4LaMn octahedra, corners with four equivalent O(6)SrLa4Zn octahedra, edges with two equivalent O(9)Sr4Mn2 octahedra, faces with two equivalent O(1)Sr4LaMn octahedra, faces with two equivalent O(4)Sr4LaMn octahedra, and faces with four equivalent O(7)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-53°. In the eleventh O site, O(11) is bonded to one La(3), one La(4), two equivalent La(1), and two equivalent Zn(1) atoms to form distorted OLa4Zn2 octahedra that share  a cornercorner with one O(3)Sr4LaMn octahedra,  a cornercorner with one O(4)Sr4LaMn octahedra, corners with two equivalent O(12)La4Zn2 octahedra, corners with two equivalent O(1)Sr4LaMn octahedra, corners with four equivalent O(5)SrLa4Zn octahedra, corners with four equivalent O(6)SrLa4Zn octahedra,  an edgeedge with one O(11)La4Zn2 octahedra,  an edgeedge with one O(12)La4Zn2 octahedra, faces with two equivalent O(13)La4Zn2 octahedra, faces with two equivalent O(14)La4Zn2 octahedra, faces with two equivalent O(5)SrLa4Zn octahedra, and faces with two equivalent O(6)SrLa4Zn octahedra. The corner-sharing octahedral tilt angles range from 0-53°. In the twelfth O site, O(12) is bonded to one La(3), one La(4), two equivalent La(2), and two equivalent Zn(1) atoms to form distorted OLa4Zn2 octahedra that share  a cornercorner with one O(3)Sr4LaMn octahedra,  a cornercorner with one O(4)Sr4LaMn octahedra, corners with two equivalent O(11)La4Zn2 octahedra, corners with two equivalent O(2)Sr4LaMn octahedra, corners with four equivalent O(5)SrLa4Zn octahedra, corners with four equivalent O(6)SrLa4Zn octahedra,  an edgeedge with one O(11)La4Zn2 octahedra,  an edgeedge with one O(12)La4Zn2 octahedra, faces with two equivalent O(13)La4Zn2 octahedra, faces with two equivalent O(14)La4Zn2 octahedra, faces with two equivalent O(5)SrLa4Zn octahedra, and faces with two equivalent O(6)SrLa4Zn octahedra. The corner-sharing octahedral tilt angles range from 0-53°. In the thirteenth O site, O(13) is bonded to two equivalent La(1), two equivalent La(2), and two equivalent Zn(1) atoms to form distorted OLa4Zn2 octahedra that share corners with two equivalent O(14)La4Zn2 octahedra, corners with two equivalent O(1)Sr4LaMn octahedra, corners with two equivalent O(2)Sr4LaMn octahedra, corners with four equivalent O(5)SrLa4Zn octahedra, corners with four equivalent O(6)SrLa4Zn octahedra, edges with two equivalent O(13)La4Zn2 octahedra, faces with two equivalent O(11)La4Zn2 octahedra, faces with two equivalent O(12)La4Zn2 octahedra, faces with two equivalent O(5)SrLa4Zn octahedra, and faces with two equivalent O(6)SrLa4Zn octahedra. The corner-sharing octahedral tilt angles range from 0-53°. In the fourteenth O site, O(14) is bonded to two equivalent La(3), two equivalent La(4), and two equivalent Zn(1) atoms to form distorted OLa4Zn2 octahedra that share corners with two equivalent O(13)La4Zn2 octahedra, corners with two equivalent O(3)Sr4LaMn octahedra, corners with two equivalent O(4)Sr4LaMn octahedra, corners with four equivalent O(5)SrLa4Zn octahedra, corners with four equivalent O(6)SrLa4Zn octahedra, edges with two equivalent O(14)La4Zn2 octahedra, faces with two equivalent O(11)La4Zn2 octahedra, faces with two equivalent O(12)La4Zn2 octahedra, faces with two equivalent O(5)SrLa4Zn octahedra, and faces with two equivalent O(6)SrLa4Zn octahedra. The corner-sharing octahedral tilt angles range from 0-53°. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sr2La2MnZnO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.877
_cell_length_b   3.906
_cell_length_c   12.664
_cell_angle_alpha   89.998
_cell_angle_beta   89.999
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   191.789
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.500  0.500  0.144  1.0
  La  La1  1  0.500  0.500  0.856  1.0
  Mn  Mn2  1  0.500  0.500  0.500  1.0
  O  O3  1  0.500  0.500  0.337  1.0
  O  O4  1  0.500  0.500  0.663  1.0
  O  O5  1  1.000  1.000  0.825  1.0
  O  O6  1  0.000  0.000  0.175  1.0
  O  O7  1  0.000  0.500  0.500  1.0
  O  O8  1  0.500  1.000  0.500  1.0
  O  O9  1  0.500  0.000  1.000  1.0
  O  O10  1  1.000  0.500  0.000  1.0
  Sr  Sr11  1  0.000  1.000  0.637  1.0
  Sr  Sr12  1  0.000  1.000  0.363  1.0
  Zn  Zn13  1  1.000  0.000  0.000  1.0
[/CIF]
.
The compound described by Sr2La2MnZnO8 is (La,Ba)CuO4-derived structured and crystallizes in the monoclinic C2/m space group. There are two inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 9-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), two equivalent O(7), and two equivalent O(8) atoms. In the second Sr site, Sr(2) is bonded in a 9-coordinate geometry to one O(1), one O(10), one O(2), one O(3), one O(4), one O(6), one O(9), and two equivalent O(7) atoms. There are four inequivalent La sites. In the first La site, La(1) is bonded in a 9-coordinate geometry to one O(1), two equivalent O(11), two equivalent O(13), two equivalent O(5), and two equivalent O(6) atoms. In the second La site, La(2) is bonded in a 9-coordinate geometry to one O(2), two equivalent O(12), two equivalent O(13), two equivalent O(5), and two equivalent O(6) atoms. In the third La site, La(3) is bonded in a 9-coordinate geometry to one O(11), one O(12), one O(3), two equivalent O(14), two equivalent O(5), and two equivalent O(6) atoms. In the fourth La site, La(4) is bonded in a 9-coordinate geometry to one O(11), one O(12), one O(4), two equivalent O(14), two equivalent O(5), and two equivalent O(6) atoms. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(2), one O(3), one O(8), one O(9), and two equivalent O(7) atoms to form corner-sharing MnO6 octahedra. The corner-sharing octahedra are not tilted. In the second Mn site, Mn(2) is bonded to one O(1), one O(10), one O(4), one O(8), and two equivalent O(7) atoms to form corner-sharing MnO6 octahedra. The corner-sharing octahedra are not tilted. Zn(1) is bonded to one O(11), one O(12), one O(13), one O(14), one O(5), and one O(6) atom to form corner-sharing ZnO6 octahedra. The corner-sharing octahedra are not tilted. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Sr(1), two equivalent Sr(2), one La(1), and one Mn(2) atom to form distorted OSr4LaMn octahedra that share corners with two equivalent O(11)La4Zn2 octahedra, corners with two equivalent O(13)La4Zn2 octahedra, corners with two equivalent O(3)Sr4LaMn octahedra, corners with two equivalent O(8)Sr4Mn2 octahedra, corners with two equivalent O(9)Sr4Mn2 octahedra, corners with three equivalent O(4)Sr4LaMn octahedra, corners with four equivalent O(7)Sr4Mn2 octahedra,  an edgeedge with one O(3)Sr4LaMn octahedra,  an edgeedge with one O(4)Sr4LaMn octahedra, edges with two equivalent O(2)Sr4LaMn octahedra, edges with two equivalent O(5)SrLa4Zn octahedra, edges with two equivalent O(6)SrLa4Zn octahedra,  a faceface with one O(10)Sr4Mn2 octahedra,  a faceface with one O(8)Sr4Mn2 octahedra, and faces with two equivalent O(7)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 1-55°. In the second O site, O(2) is bonded to two equivalent Sr(1), two equivalent Sr(2), one La(2), and one Mn(1) atom to form distorted OSr4LaMn octahedra that share corners with two equivalent O(12)La4Zn2 octahedra, corners with two equivalent O(13)La4Zn2 octahedra, corners with two equivalent O(4)Sr4LaMn octahedra, corners with two equivalent O(10)Sr4Mn2 octahedra, corners with two equivalent O(8)Sr4Mn2 octahedra, corners with three equivalent O(3)Sr4LaMn octahedra, corners with four equivalent O(7)Sr4Mn2 octahedra,  an edgeedge with one O(3)Sr4LaMn octahedra,  an edgeedge with one O(4)Sr4LaMn octahedra, edges with two equivalent O(1)Sr4LaMn octahedra, edges with two equivalent O(5)SrLa4Zn octahedra, edges with two equivalent O(6)SrLa4Zn octahedra,  a faceface with one O(8)Sr4Mn2 octahedra,  a faceface with one O(9)Sr4Mn2 octahedra, and faces with two equivalent O(7)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 1-54°. In the third O site, O(3) is bonded to two equivalent Sr(1), two equivalent Sr(2), one La(3), and one Mn(1) atom to form distorted OSr4LaMn octahedra that share  a cornercorner with one O(11)La4Zn2 octahedra,  a cornercorner with one O(12)La4Zn2 octahedra, corners with two equivalent O(14)La4Zn2 octahedra, corners with two equivalent O(1)Sr4LaMn octahedra, corners with two equivalent O(10)Sr4Mn2 octahedra, corners with two equivalent O(8)Sr4Mn2 octahedra, corners with three equivalent O(2)Sr4LaMn octahedra, corners with four equivalent O(7)Sr4Mn2 octahedra,  an edgeedge with one O(1)Sr4LaMn octahedra,  an edgeedge with one O(2)Sr4LaMn octahedra, edges with two equivalent O(4)Sr4LaMn octahedra, edges with two equivalent O(5)SrLa4Zn octahedra, edges with two equivalent O(6)SrLa4Zn octahedra,  a faceface with one O(8)Sr4Mn2 octahedra,  a faceface with one O(9)Sr4Mn2 octahedra, and faces with two equivalent O(7)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 1-54°. In the fourth O site, O(4) is bonded to two equivalent Sr(1), two equivalent Sr(2), one La(4), and one Mn(2) atom to form distorted OSr4LaMn octahedra that share  a cornercorner with one O(11)La4Zn2 octahedra,  a cornercorner with one O(12)La4Zn2 octahedra, corners with two equivalent O(14)La4Zn2 octahedra, corners with two equivalent O(2)Sr4LaMn octahedra, corners with two equivalent O(8)Sr4Mn2 octahedra, corners with two equivalent O(9)Sr4Mn2 octahedra, corners with three equivalent O(1)Sr4LaMn octahedra, corners with four equivalent O(7)Sr4Mn2 octahedra,  an edgeedge with one O(1)Sr4LaMn octahedra,  an edgeedge with one O(2)Sr4LaMn octahedra, edges with two equivalent O(3)Sr4LaMn octahedra, edges with two equivalent O(5)SrLa4Zn octahedra, edges with two equivalent O(6)SrLa4Zn octahedra,  a faceface with one O(10)Sr4Mn2 octahedra,  a faceface with one O(8)Sr4Mn2 octahedra, and faces with two equivalent O(7)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 1-55°. In the fifth O site, O(5) is bonded to one Sr(1), one La(1), one La(2), one La(3), one La(4), and one Zn(1) atom to form distorted OSrLa4Zn octahedra that share corners with two equivalent O(11)La4Zn2 octahedra, corners with two equivalent O(12)La4Zn2 octahedra, corners with two equivalent O(13)La4Zn2 octahedra, corners with two equivalent O(14)La4Zn2 octahedra, corners with two equivalent O(7)Sr4Mn2 octahedra, corners with two equivalent O(8)Sr4Mn2 octahedra, corners with five equivalent O(6)SrLa4Zn octahedra,  an edgeedge with one O(1)Sr4LaMn octahedra,  an edgeedge with one O(2)Sr4LaMn octahedra,  an edgeedge with one O(3)Sr4LaMn octahedra,  an edgeedge with one O(4)Sr4LaMn octahedra, edges with two equivalent O(5)SrLa4Zn octahedra, edges with two equivalent O(6)SrLa4Zn octahedra,  a faceface with one O(11)La4Zn2 octahedra,  a faceface with one O(12)La4Zn2 octahedra,  a faceface with one O(13)La4Zn2 octahedra, and  a faceface with one O(14)La4Zn2 octahedra. The corner-sharing octahedral tilt angles range from 0-53°. In the sixth O site, O(6) is bonded to one Sr(2), one La(1), one La(2), one La(3), one La(4), and one Zn(1) atom to form distorted OSrLa4Zn octahedra that share  a cornercorner with one O(10)Sr4Mn2 octahedra,  a cornercorner with one O(9)Sr4Mn2 octahedra, corners with two equivalent O(11)La4Zn2 octahedra, corners with two equivalent O(12)La4Zn2 octahedra, corners with two equivalent O(13)La4Zn2 octahedra, corners with two equivalent O(14)La4Zn2 octahedra, corners with two equivalent O(7)Sr4Mn2 octahedra, corners with five equivalent O(5)SrLa4Zn octahedra,  an edgeedge with one O(1)Sr4LaMn octahedra,  an edgeedge with one O(2)Sr4LaMn octahedra,  an edgeedge with one O(3)Sr4LaMn octahedra,  an edgeedge with one O(4)Sr4LaMn octahedra, edges with two equivalent O(5)SrLa4Zn octahedra, edges with two equivalent O(6)SrLa4Zn octahedra,  a faceface with one O(11)La4Zn2 octahedra,  a faceface with one O(12)La4Zn2 octahedra,  a faceface with one O(13)La4Zn2 octahedra, and  a faceface with one O(14)La4Zn2 octahedra. The corner-sharing octahedral tilt angles range from 0-53°. In the seventh O site, O(7) is bonded to two equivalent Sr(1), two equivalent Sr(2), one Mn(1), and one Mn(2) atom to form distorted OSr4Mn2 octahedra that share corners with two equivalent O(1)Sr4LaMn octahedra, corners with two equivalent O(2)Sr4LaMn octahedra, corners with two equivalent O(3)Sr4LaMn octahedra, corners with two equivalent O(4)Sr4LaMn octahedra, corners with two equivalent O(7)Sr4Mn2 octahedra, corners with two equivalent O(5)SrLa4Zn octahedra, corners with two equivalent O(6)SrLa4Zn octahedra, edges with two equivalent O(7)Sr4Mn2 octahedra,  a faceface with one O(1)Sr4LaMn octahedra,  a faceface with one O(2)Sr4LaMn octahedra,  a faceface with one O(3)Sr4LaMn octahedra,  a faceface with one O(4)Sr4LaMn octahedra,  a faceface with one O(10)Sr4Mn2 octahedra,  a faceface with one O(9)Sr4Mn2 octahedra, and faces with two equivalent O(8)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-54°. In the eighth O site, O(8) is bonded to four equivalent Sr(1), one Mn(1), and one Mn(2) atom to form distorted OSr4Mn2 octahedra that share  a cornercorner with one O(10)Sr4Mn2 octahedra,  a cornercorner with one O(9)Sr4Mn2 octahedra, corners with two equivalent O(1)Sr4LaMn octahedra, corners with two equivalent O(2)Sr4LaMn octahedra, corners with two equivalent O(3)Sr4LaMn octahedra, corners with two equivalent O(4)Sr4LaMn octahedra, corners with four equivalent O(5)SrLa4Zn octahedra, edges with two equivalent O(8)Sr4Mn2 octahedra,  a faceface with one O(1)Sr4LaMn octahedra,  a faceface with one O(2)Sr4LaMn octahedra,  a faceface with one O(3)Sr4LaMn octahedra,  a faceface with one O(4)Sr4LaMn octahedra, and faces with four equivalent O(7)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-55°. In the ninth O site, O(9) is bonded to four equivalent Sr(2) and two equivalent Mn(1) atoms to form distorted OSr4Mn2 octahedra that share corners with two equivalent O(8)Sr4Mn2 octahedra, corners with four equivalent O(1)Sr4LaMn octahedra, corners with four equivalent O(4)Sr4LaMn octahedra, corners with four equivalent O(6)SrLa4Zn octahedra, edges with two equivalent O(10)Sr4Mn2 octahedra, faces with two equivalent O(2)Sr4LaMn octahedra, faces with two equivalent O(3)Sr4LaMn octahedra, and faces with four equivalent O(7)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-53°. In the tenth O site, O(10) is bonded to four equivalent Sr(2) and two equivalent Mn(2) atoms to form distorted OSr4Mn2 octahedra that share corners with two equivalent O(8)Sr4Mn2 octahedra, corners with four equivalent O(2)Sr4LaMn octahedra, corners with four equivalent O(3)Sr4LaMn octahedra, corners with four equivalent O(6)SrLa4Zn octahedra, edges with two equivalent O(9)Sr4Mn2 octahedra, faces with two equivalent O(1)Sr4LaMn octahedra, faces with two equivalent O(4)Sr4LaMn octahedra, and faces with four equivalent O(7)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-53°. In the eleventh O site, O(11) is bonded to one La(3), one La(4), two equivalent La(1), and two equivalent Zn(1) atoms to form distorted OLa4Zn2 octahedra that share  a cornercorner with one O(3)Sr4LaMn octahedra,  a cornercorner with one O(4)Sr4LaMn octahedra, corners with two equivalent O(12)La4Zn2 octahedra, corners with two equivalent O(1)Sr4LaMn octahedra, corners with four equivalent O(5)SrLa4Zn octahedra, corners with four equivalent O(6)SrLa4Zn octahedra,  an edgeedge with one O(11)La4Zn2 octahedra,  an edgeedge with one O(12)La4Zn2 octahedra, faces with two equivalent O(13)La4Zn2 octahedra, faces with two equivalent O(14)La4Zn2 octahedra, faces with two equivalent O(5)SrLa4Zn octahedra, and faces with two equivalent O(6)SrLa4Zn octahedra. The corner-sharing octahedral tilt angles range from 0-53°. In the twelfth O site, O(12) is bonded to one La(3), one La(4), two equivalent La(2), and two equivalent Zn(1) atoms to form distorted OLa4Zn2 octahedra that share  a cornercorner with one O(3)Sr4LaMn octahedra,  a cornercorner with one O(4)Sr4LaMn octahedra, corners with two equivalent O(11)La4Zn2 octahedra, corners with two equivalent O(2)Sr4LaMn octahedra, corners with four equivalent O(5)SrLa4Zn octahedra, corners with four equivalent O(6)SrLa4Zn octahedra,  an edgeedge with one O(11)La4Zn2 octahedra,  an edgeedge with one O(12)La4Zn2 octahedra, faces with two equivalent O(13)La4Zn2 octahedra, faces with two equivalent O(14)La4Zn2 octahedra, faces with two equivalent O(5)SrLa4Zn octahedra, and faces with two equivalent O(6)SrLa4Zn octahedra. The corner-sharing octahedral tilt angles range from 0-53°. In the thirteenth O site, O(13) is bonded to two equivalent La(1), two equivalent La(2), and two equivalent Zn(1) atoms to form distorted OLa4Zn2 octahedra that share corners with two equivalent O(14)La4Zn2 octahedra, corners with two equivalent O(1)Sr4LaMn octahedra, corners with two equivalent O(2)Sr4LaMn octahedra, corners with four equivalent O(5)SrLa4Zn octahedra, corners with four equivalent O(6)SrLa4Zn octahedra, edges with two equivalent O(13)La4Zn2 octahedra, faces with two equivalent O(11)La4Zn2 octahedra, faces with two equivalent O(12)La4Zn2 octahedra, faces with two equivalent O(5)SrLa4Zn octahedra, and faces with two equivalent O(6)SrLa4Zn octahedra. The corner-sharing octahedral tilt angles range from 0-53°. In the fourteenth O site, O(14) is bonded to two equivalent La(3), two equivalent La(4), and two equivalent Zn(1) atoms to form distorted OLa4Zn2 octahedra that share corners with two equivalent O(13)La4Zn2 octahedra, corners with two equivalent O(3)Sr4LaMn octahedra, corners with two equivalent O(4)Sr4LaMn octahedra, corners with four equivalent O(5)SrLa4Zn octahedra, corners with four equivalent O(6)SrLa4Zn octahedra, edges with two equivalent O(14)La4Zn2 octahedra, faces with two equivalent O(11)La4Zn2 octahedra, faces with two equivalent O(12)La4Zn2 octahedra, faces with two equivalent O(5)SrLa4Zn octahedra, and faces with two equivalent O(6)SrLa4Zn octahedra. The corner-sharing octahedral tilt angles range from 0-53°. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sr2La2MnZnO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.877
_cell_length_b   3.906
_cell_length_c   12.664
_cell_angle_alpha   89.998
_cell_angle_beta   89.999
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   191.789
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.500  0.500  0.144  1.0
  La  La1  1  0.500  0.500  0.856  1.0
  Mn  Mn2  1  0.500  0.500  0.500  1.0
  O  O3  1  0.500  0.500  0.337  1.0
  O  O4  1  0.500  0.500  0.663  1.0
  O  O5  1  1.000  1.000  0.825  1.0
  O  O6  1  0.000  0.000  0.175  1.0
  O  O7  1  0.000  0.500  0.500  1.0
  O  O8  1  0.500  1.000  0.500  1.0
  O  O9  1  0.500  0.000  1.000  1.0
  O  O10  1  1.000  0.500  0.000  1.0
  Sr  Sr11  1  0.000  1.000  0.637  1.0
  Sr  Sr12  1  0.000  1.000  0.363  1.0
  Zn  Zn13  1  1.000  0.000  0.000  1.0
[/CIF]
.