The structure described by V(CrTe2)2 crystallizes in the monoclinic C2/m space group. V(1) is bonded to two equivalent Te(1) and four equivalent Te(2) atoms to form VTe6 octahedra that share corners with twelve equivalent Cr(1)Te6 octahedra, edges with two equivalent V(1)Te6 octahedra, and faces with two equivalent Cr(1)Te6 octahedra. The corner-sharing octahedral tilt angles range from 50-52°. Cr(1) is bonded to three equivalent Te(1) and three equivalent Te(2) atoms to form CrTe6 octahedra that share corners with six equivalent V(1)Te6 octahedra, edges with six equivalent Cr(1)Te6 octahedra, and  a faceface with one V(1)Te6 octahedra. The corner-sharing octahedral tilt angles range from 50-52°. There are two inequivalent Te sites. In the first Te site, Te(2) is bonded to two equivalent V(1) and three equivalent Cr(1) atoms to form a mixture of distorted edge and corner-sharing TeV2Cr3 square pyramids. In the second Te site, Te(1) is bonded in a rectangular see-saw-like geometry to one V(1) and three equivalent Cr(1) atoms. is represented by the CIF card [CIF]
data_V(CrTe2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.006
_cell_length_b   6.991
_cell_length_c   7.272
_cell_angle_alpha   117.496
_cell_angle_beta   105.987
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   171.721
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.000  0.000  0.000  1.0
  Cr  Cr1  1  0.260  0.277  0.519  1.0
  Cr  Cr2  1  0.740  0.723  0.481  1.0
  Te  Te3  1  0.120  0.451  0.241  1.0
  Te  Te4  1  0.880  0.549  0.759  1.0
  Te  Te5  1  0.369  0.029  0.737  1.0
  Te  Te6  1  0.631  0.971  0.263  1.0
[/CIF]
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The structure described by V(CrTe2)2 crystallizes in the monoclinic C2/m space group. V(1) is bonded to two equivalent Te(1) and four equivalent Te(2) atoms to form VTe6 octahedra that share corners with twelve equivalent Cr(1)Te6 octahedra, edges with two equivalent V(1)Te6 octahedra, and faces with two equivalent Cr(1)Te6 octahedra. The corner-sharing octahedral tilt angles range from 50-52°. Cr(1) is bonded to three equivalent Te(1) and three equivalent Te(2) atoms to form CrTe6 octahedra that share corners with six equivalent V(1)Te6 octahedra, edges with six equivalent Cr(1)Te6 octahedra, and  a faceface with one V(1)Te6 octahedra. The corner-sharing octahedral tilt angles range from 50-52°. There are two inequivalent Te sites. In the first Te site, Te(2) is bonded to two equivalent V(1) and three equivalent Cr(1) atoms to form a mixture of distorted edge and corner-sharing TeV2Cr3 square pyramids. In the second Te site, Te(1) is bonded in a rectangular see-saw-like geometry to one V(1) and three equivalent Cr(1) atoms. is represented by the CIF card [CIF]
data_V(CrTe2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.006
_cell_length_b   6.991
_cell_length_c   7.272
_cell_angle_alpha   117.496
_cell_angle_beta   105.987
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   171.721
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.000  0.000  0.000  1.0
  Cr  Cr1  1  0.260  0.277  0.519  1.0
  Cr  Cr2  1  0.740  0.723  0.481  1.0
  Te  Te3  1  0.120  0.451  0.241  1.0
  Te  Te4  1  0.880  0.549  0.759  1.0
  Te  Te5  1  0.369  0.029  0.737  1.0
  Te  Te6  1  0.631  0.971  0.263  1.0
[/CIF]
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