The structure described by K2LiInAs2 crystallizes in the orthorhombic Cmce space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 5-coordinate geometry to two equivalent As(2) and three equivalent As(1) atoms. In the second K site, K(2) is bonded in a 5-coordinate geometry to two equivalent As(1) and three equivalent As(2) atoms. Li(1) is bonded to two equivalent As(1) and two equivalent As(2) atoms to form a mixture of distorted corner and edge-sharing LiAs4 tetrahedra. In(1) is bonded in a 4-coordinate geometry to two equivalent As(1) and two equivalent As(2) atoms. There are two inequivalent As sites. In the first As site, As(1) is bonded in a 9-coordinate geometry to two equivalent K(2), three equivalent K(1), two equivalent Li(1), and two equivalent In(1) atoms. In the second As site, As(2) is bonded in a 9-coordinate geometry to two equivalent K(1), three equivalent K(2), two equivalent Li(1), and two equivalent In(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_K2LiInAs2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.237
_cell_length_b   10.237
_cell_length_c   6.454
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   101.000
_symmetry_Int_Tables_number   1
_cell_volume   663.945
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.574  0.926  0.750  1.0
  K  K1  1  0.926  0.574  0.250  1.0
  K  K2  1  0.426  0.074  0.250  1.0
  K  K3  1  0.074  0.426  0.750  1.0
  K  K4  1  0.673  0.327  0.776  1.0
  K  K5  1  0.827  0.173  0.276  1.0
  K  K6  1  0.327  0.673  0.224  1.0
  K  K7  1  0.173  0.827  0.724  1.0
  Li  Li8  1  0.620  0.620  0.000  1.0
  Li  Li9  1  0.880  0.880  0.500  1.0
  Li  Li10  1  0.380  0.380  0.000  1.0
  Li  Li11  1  0.120  0.120  0.500  1.0
  In  In12  1  0.868  0.868  0.000  1.0
  In  In13  1  0.632  0.632  0.500  1.0
  In  In14  1  0.132  0.132  0.000  1.0
  In  In15  1  0.368  0.368  0.500  1.0
  As  As16  1  0.351  0.149  0.750  1.0
  As  As17  1  0.149  0.351  0.250  1.0
  As  As18  1  0.649  0.851  0.250  1.0
  As  As19  1  0.851  0.649  0.750  1.0
  As  As20  1  0.902  0.098  0.769  1.0
  As  As21  1  0.598  0.402  0.269  1.0
  As  As22  1  0.098  0.902  0.231  1.0
  As  As23  1  0.402  0.598  0.731  1.0
[/CIF]
.
The structure described by K2LiInAs2 crystallizes in the orthorhombic Cmce space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 5-coordinate geometry to two equivalent As(2) and three equivalent As(1) atoms. In the second K site, K(2) is bonded in a 5-coordinate geometry to two equivalent As(1) and three equivalent As(2) atoms. Li(1) is bonded to two equivalent As(1) and two equivalent As(2) atoms to form a mixture of distorted corner and edge-sharing LiAs4 tetrahedra. In(1) is bonded in a 4-coordinate geometry to two equivalent As(1) and two equivalent As(2) atoms. There are two inequivalent As sites. In the first As site, As(1) is bonded in a 9-coordinate geometry to two equivalent K(2), three equivalent K(1), two equivalent Li(1), and two equivalent In(1) atoms. In the second As site, As(2) is bonded in a 9-coordinate geometry to two equivalent K(1), three equivalent K(2), two equivalent Li(1), and two equivalent In(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_K2LiInAs2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.237
_cell_length_b   10.237
_cell_length_c   6.454
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   101.000
_symmetry_Int_Tables_number   1
_cell_volume   663.945
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.574  0.926  0.750  1.0
  K  K1  1  0.926  0.574  0.250  1.0
  K  K2  1  0.426  0.074  0.250  1.0
  K  K3  1  0.074  0.426  0.750  1.0
  K  K4  1  0.673  0.327  0.776  1.0
  K  K5  1  0.827  0.173  0.276  1.0
  K  K6  1  0.327  0.673  0.224  1.0
  K  K7  1  0.173  0.827  0.724  1.0
  Li  Li8  1  0.620  0.620  0.000  1.0
  Li  Li9  1  0.880  0.880  0.500  1.0
  Li  Li10  1  0.380  0.380  0.000  1.0
  Li  Li11  1  0.120  0.120  0.500  1.0
  In  In12  1  0.868  0.868  0.000  1.0
  In  In13  1  0.632  0.632  0.500  1.0
  In  In14  1  0.132  0.132  0.000  1.0
  In  In15  1  0.368  0.368  0.500  1.0
  As  As16  1  0.351  0.149  0.750  1.0
  As  As17  1  0.149  0.351  0.250  1.0
  As  As18  1  0.649  0.851  0.250  1.0
  As  As19  1  0.851  0.649  0.750  1.0
  As  As20  1  0.902  0.098  0.769  1.0
  As  As21  1  0.598  0.402  0.269  1.0
  As  As22  1  0.098  0.902  0.231  1.0
  As  As23  1  0.402  0.598  0.731  1.0
[/CIF]
.