The material structure described by V2MnP2(H4O7)2 crystallizes in the tetragonal I4/m space group. V(1) is bonded to one O(2) and four equivalent O(1) atoms to form distorted VO5 trigonal bipyramids that share  a cornercorner with one Mn(1)O6 octahedra and corners with four equivalent P(1)O4 tetrahedra. The corner-sharing octahedra are not tilted. Mn(1) is bonded to two equivalent O(2) and four equivalent O(3) atoms to form MnO6 octahedra that share corners with two equivalent V(1)O5 trigonal bipyramids. P(1) is bonded to four equivalent O(1) atoms to form PO4 tetrahedra that share corners with four equivalent V(1)O5 trigonal bipyramids. H(1) is bonded in a single-bond geometry to one O(3) atom. There are three inequivalent O sites. In the first O site, O(2) is bonded in a linear geometry to one V(1) and one Mn(1) atom. In the second O site, O(3) is bonded in a distorted water-like geometry to one Mn(1) and two equivalent H(1) atoms. In the third O site, O(1) is bonded in a bent 120 degrees geometry to one V(1) and one P(1) atom. is represented by the CIF card [CIF]
data_MnV2P2(H4O7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.331
_cell_length_b   6.331
_cell_length_c   8.206
_cell_angle_alpha   67.309
_cell_angle_beta   67.309
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   275.655
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.000  0.000  0.000  1.0
  V  V1  1  0.274  0.274  0.451  1.0
  V  V2  1  0.726  0.726  0.549  1.0
  P  P3  1  0.250  0.750  0.500  1.0
  P  P4  1  0.750  0.250  0.500  1.0
  H  H5  1  0.273  0.402  0.884  1.0
  H  H6  1  0.843  0.714  0.884  1.0
  H  H7  1  0.714  0.273  0.884  1.0
  H  H8  1  0.402  0.843  0.884  1.0
  H  H9  1  0.727  0.598  0.116  1.0
  H  H10  1  0.157  0.286  0.116  1.0
  H  H11  1  0.286  0.727  0.116  1.0
  H  H12  1  0.598  0.157  0.116  1.0
  O  O13  1  0.283  0.620  0.368  1.0
  O  O14  1  0.350  0.012  0.368  1.0
  O  O15  1  0.012  0.283  0.368  1.0
  O  O16  1  0.620  0.350  0.368  1.0
  O  O17  1  0.717  0.380  0.632  1.0
  O  O18  1  0.650  0.988  0.632  1.0
  O  O19  1  0.988  0.717  0.632  1.0
  O  O20  1  0.380  0.650  0.632  1.0
  O  O21  1  0.155  0.155  0.691  1.0
  O  O22  1  0.845  0.845  0.309  1.0
  O  O23  1  0.232  0.254  0.000  1.0
  O  O24  1  0.768  0.746  0.000  1.0
  O  O25  1  0.746  0.232  0.000  1.0
  O  O26  1  0.254  0.768  0.000  1.0
[/CIF]
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The material structure described by V2MnP2(H4O7)2 crystallizes in the tetragonal I4/m space group. V(1) is bonded to one O(2) and four equivalent O(1) atoms to form distorted VO5 trigonal bipyramids that share  a cornercorner with one Mn(1)O6 octahedra and corners with four equivalent P(1)O4 tetrahedra. The corner-sharing octahedra are not tilted. Mn(1) is bonded to two equivalent O(2) and four equivalent O(3) atoms to form MnO6 octahedra that share corners with two equivalent V(1)O5 trigonal bipyramids. P(1) is bonded to four equivalent O(1) atoms to form PO4 tetrahedra that share corners with four equivalent V(1)O5 trigonal bipyramids. H(1) is bonded in a single-bond geometry to one O(3) atom. There are three inequivalent O sites. In the first O site, O(2) is bonded in a linear geometry to one V(1) and one Mn(1) atom. In the second O site, O(3) is bonded in a distorted water-like geometry to one Mn(1) and two equivalent H(1) atoms. In the third O site, O(1) is bonded in a bent 120 degrees geometry to one V(1) and one P(1) atom. is represented by the CIF card [CIF]
data_MnV2P2(H4O7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.331
_cell_length_b   6.331
_cell_length_c   8.206
_cell_angle_alpha   67.309
_cell_angle_beta   67.309
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   275.655
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.000  0.000  0.000  1.0
  V  V1  1  0.274  0.274  0.451  1.0
  V  V2  1  0.726  0.726  0.549  1.0
  P  P3  1  0.250  0.750  0.500  1.0
  P  P4  1  0.750  0.250  0.500  1.0
  H  H5  1  0.273  0.402  0.884  1.0
  H  H6  1  0.843  0.714  0.884  1.0
  H  H7  1  0.714  0.273  0.884  1.0
  H  H8  1  0.402  0.843  0.884  1.0
  H  H9  1  0.727  0.598  0.116  1.0
  H  H10  1  0.157  0.286  0.116  1.0
  H  H11  1  0.286  0.727  0.116  1.0
  H  H12  1  0.598  0.157  0.116  1.0
  O  O13  1  0.283  0.620  0.368  1.0
  O  O14  1  0.350  0.012  0.368  1.0
  O  O15  1  0.012  0.283  0.368  1.0
  O  O16  1  0.620  0.350  0.368  1.0
  O  O17  1  0.717  0.380  0.632  1.0
  O  O18  1  0.650  0.988  0.632  1.0
  O  O19  1  0.988  0.717  0.632  1.0
  O  O20  1  0.380  0.650  0.632  1.0
  O  O21  1  0.155  0.155  0.691  1.0
  O  O22  1  0.845  0.845  0.309  1.0
  O  O23  1  0.232  0.254  0.000  1.0
  O  O24  1  0.768  0.746  0.000  1.0
  O  O25  1  0.746  0.232  0.000  1.0
  O  O26  1  0.254  0.768  0.000  1.0
[/CIF]
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