The material described by Mo6AgCl13 crystallizes in the triclinic P-1 space group. There are six inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one Cl(1), one Cl(12), one Cl(2), one Cl(5), and one Cl(6) atom to form MoCl5 square pyramids that share  a cornercorner with one Ag(1)Cl4 trigonal pyramid, edges with two equivalent Mo(2)Cl5 square pyramids, and edges with two equivalent Mo(5)Cl5 square pyramids. In the second Mo site, Mo(2) is bonded to one Cl(12), one Cl(13), one Cl(2), one Cl(5), and one Cl(6) atom to form MoCl5 square pyramids that share  a cornercorner with one Ag(1)Cl4 trigonal pyramid, edges with two equivalent Mo(1)Cl5 square pyramids, and edges with two equivalent Mo(5)Cl5 square pyramids. In the third Mo site, Mo(3) is bonded to one Cl(10), one Cl(11), one Cl(4), one Cl(7), and one Cl(8) atom to form MoCl5 square pyramids that share  a cornercorner with one Ag(1)Cl4 trigonal pyramid, edges with two equivalent Mo(4)Cl5 square pyramids, and edges with two equivalent Mo(6)Cl5 square pyramids. In the fourth Mo site, Mo(4) is bonded to one Cl(10), one Cl(3), one Cl(4), one Cl(7), and one Cl(8) atom to form MoCl5 square pyramids that share  a cornercorner with one Ag(1)Cl4 trigonal pyramid, edges with two equivalent Mo(3)Cl5 square pyramids, and edges with two equivalent Mo(6)Cl5 square pyramids. In the fifth Mo site, Mo(5) is bonded to one Cl(12), one Cl(2), one Cl(5), one Cl(6), and one Cl(9) atom to form a mixture of corner and edge-sharing MoCl5 square pyramids. In the sixth Mo site, Mo(6) is bonded to one Cl(10), one Cl(4), one Cl(7), one Cl(8), and one Cl(9) atom to form a mixture of corner and edge-sharing MoCl5 square pyramids. Ag(1) is bonded to one Cl(1), one Cl(11), one Cl(13), and one Cl(3) atom to form distorted AgCl4 trigonal pyramids that share  a cornercorner with one Mo(1)Cl5 square pyramid,  a cornercorner with one Mo(2)Cl5 square pyramid,  a cornercorner with one Mo(3)Cl5 square pyramid, and  a cornercorner with one Mo(4)Cl5 square pyramid. There are thirteen inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a bent 120 degrees geometry to one Mo(1) and one Ag(1) atom. In the second Cl site, Cl(2) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(2), and one Mo(5) atom. In the third Cl site, Cl(3) is bonded in a bent 120 degrees geometry to one Mo(4) and one Ag(1) atom. In the fourth Cl site, Cl(4) is bonded in a 3-coordinate geometry to one Mo(3), one Mo(4), and one Mo(6) atom. In the fifth Cl site, Cl(5) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(2), and one Mo(5) atom. In the sixth Cl site, Cl(6) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(2), and one Mo(5) atom. In the seventh Cl site, Cl(7) is bonded in a 3-coordinate geometry to one Mo(3), one Mo(4), and one Mo(6) atom. In the eighth Cl site, Cl(8) is bonded in a 3-coordinate geometry to one Mo(3), one Mo(4), and one Mo(6) atom. In the ninth Cl site, Cl(9) is bonded in a bent 120 degrees geometry to one Mo(5) and one Mo(6) atom. In the tenth Cl site, Cl(10) is bonded in a 3-coordinate geometry to one Mo(3), one Mo(4), and one Mo(6) atom. In the eleventh Cl site, Cl(11) is bonded in a bent 120 degrees geometry to one Mo(3) and one Ag(1) atom. In the twelfth Cl site, Cl(12) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(2), and one Mo(5) atom. In the thirteenth Cl site, Cl(13) is bonded in a bent 150 degrees geometry to one Mo(2) and one Ag(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_AgMo6Cl13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.916
_cell_length_b   9.078
_cell_length_c   13.942
_cell_angle_alpha   96.157
_cell_angle_beta   102.524
_cell_angle_gamma   113.241
_symmetry_Int_Tables_number   1
_cell_volume   988.523
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.039  0.269  0.774  1.0
  Ag  Ag1  1  0.961  0.731  0.226  1.0
  Mo  Mo2  1  0.315  0.383  0.542  1.0
  Mo  Mo3  1  0.685  0.617  0.458  1.0
  Mo  Mo4  1  0.362  0.548  0.402  1.0
  Mo  Mo5  1  0.638  0.452  0.598  1.0
  Mo  Mo6  1  0.702  0.998  0.065  1.0
  Mo  Mo7  1  0.298  0.002  0.935  1.0
  Mo  Mo8  1  0.605  0.225  0.025  1.0
  Mo  Mo9  1  0.395  0.775  0.975  1.0
  Mo  Mo10  1  0.458  0.313  0.412  1.0
  Mo  Mo11  1  0.542  0.687  0.588  1.0
  Mo  Mo12  1  0.446  0.013  0.120  1.0
  Mo  Mo13  1  0.554  0.987  0.880  1.0
  Cl  Cl14  1  0.067  0.219  0.595  1.0
  Cl  Cl15  1  0.933  0.781  0.405  1.0
  Cl  Cl16  1  0.232  0.614  0.531  1.0
  Cl  Cl17  1  0.768  0.386  0.469  1.0
  Cl  Cl18  1  0.744  0.524  0.062  1.0
  Cl  Cl19  1  0.256  0.476  0.938  1.0
  Cl  Cl20  1  0.157  0.796  0.029  1.0
  Cl  Cl21  1  0.843  0.204  0.971  1.0
  Cl  Cl22  1  0.415  0.163  0.549  1.0
  Cl  Cl23  1  0.585  0.837  0.451  1.0
  Cl  Cl24  1  0.510  0.481  0.283  1.0
  Cl  Cl25  1  0.490  0.519  0.717  1.0
  Cl  Cl26  1  0.352  0.223  0.074  1.0
  Cl  Cl27  1  0.648  0.777  0.926  1.0
  Cl  Cl28  1  0.540  0.795  0.154  1.0
  Cl  Cl29  1  0.460  0.205  0.846  1.0
  Cl  Cl30  1  0.388  0.047  0.291  1.0
  Cl  Cl31  1  0.612  0.953  0.709  1.0
  Cl  Cl32  1  0.742  0.225  0.200  1.0
  Cl  Cl33  1  0.258  0.775  0.800  1.0
  Cl  Cl34  1  0.966  0.987  0.149  1.0
  Cl  Cl35  1  0.034  0.013  0.851  1.0
  Cl  Cl36  1  0.153  0.256  0.365  1.0
  Cl  Cl37  1  0.847  0.744  0.635  1.0
  Cl  Cl38  1  0.179  0.598  0.264  1.0
  Cl  Cl39  1  0.821  0.402  0.736  1.0
[/CIF]
.
The material described by Mo6AgCl13 crystallizes in the triclinic P-1 space group. There are six inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one Cl(1), one Cl(12), one Cl(2), one Cl(5), and one Cl(6) atom to form MoCl5 square pyramids that share  a cornercorner with one Ag(1)Cl4 trigonal pyramid, edges with two equivalent Mo(2)Cl5 square pyramids, and edges with two equivalent Mo(5)Cl5 square pyramids. In the second Mo site, Mo(2) is bonded to one Cl(12), one Cl(13), one Cl(2), one Cl(5), and one Cl(6) atom to form MoCl5 square pyramids that share  a cornercorner with one Ag(1)Cl4 trigonal pyramid, edges with two equivalent Mo(1)Cl5 square pyramids, and edges with two equivalent Mo(5)Cl5 square pyramids. In the third Mo site, Mo(3) is bonded to one Cl(10), one Cl(11), one Cl(4), one Cl(7), and one Cl(8) atom to form MoCl5 square pyramids that share  a cornercorner with one Ag(1)Cl4 trigonal pyramid, edges with two equivalent Mo(4)Cl5 square pyramids, and edges with two equivalent Mo(6)Cl5 square pyramids. In the fourth Mo site, Mo(4) is bonded to one Cl(10), one Cl(3), one Cl(4), one Cl(7), and one Cl(8) atom to form MoCl5 square pyramids that share  a cornercorner with one Ag(1)Cl4 trigonal pyramid, edges with two equivalent Mo(3)Cl5 square pyramids, and edges with two equivalent Mo(6)Cl5 square pyramids. In the fifth Mo site, Mo(5) is bonded to one Cl(12), one Cl(2), one Cl(5), one Cl(6), and one Cl(9) atom to form a mixture of corner and edge-sharing MoCl5 square pyramids. In the sixth Mo site, Mo(6) is bonded to one Cl(10), one Cl(4), one Cl(7), one Cl(8), and one Cl(9) atom to form a mixture of corner and edge-sharing MoCl5 square pyramids. Ag(1) is bonded to one Cl(1), one Cl(11), one Cl(13), and one Cl(3) atom to form distorted AgCl4 trigonal pyramids that share  a cornercorner with one Mo(1)Cl5 square pyramid,  a cornercorner with one Mo(2)Cl5 square pyramid,  a cornercorner with one Mo(3)Cl5 square pyramid, and  a cornercorner with one Mo(4)Cl5 square pyramid. There are thirteen inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a bent 120 degrees geometry to one Mo(1) and one Ag(1) atom. In the second Cl site, Cl(2) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(2), and one Mo(5) atom. In the third Cl site, Cl(3) is bonded in a bent 120 degrees geometry to one Mo(4) and one Ag(1) atom. In the fourth Cl site, Cl(4) is bonded in a 3-coordinate geometry to one Mo(3), one Mo(4), and one Mo(6) atom. In the fifth Cl site, Cl(5) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(2), and one Mo(5) atom. In the sixth Cl site, Cl(6) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(2), and one Mo(5) atom. In the seventh Cl site, Cl(7) is bonded in a 3-coordinate geometry to one Mo(3), one Mo(4), and one Mo(6) atom. In the eighth Cl site, Cl(8) is bonded in a 3-coordinate geometry to one Mo(3), one Mo(4), and one Mo(6) atom. In the ninth Cl site, Cl(9) is bonded in a bent 120 degrees geometry to one Mo(5) and one Mo(6) atom. In the tenth Cl site, Cl(10) is bonded in a 3-coordinate geometry to one Mo(3), one Mo(4), and one Mo(6) atom. In the eleventh Cl site, Cl(11) is bonded in a bent 120 degrees geometry to one Mo(3) and one Ag(1) atom. In the twelfth Cl site, Cl(12) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(2), and one Mo(5) atom. In the thirteenth Cl site, Cl(13) is bonded in a bent 150 degrees geometry to one Mo(2) and one Ag(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_AgMo6Cl13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.916
_cell_length_b   9.078
_cell_length_c   13.942
_cell_angle_alpha   96.157
_cell_angle_beta   102.524
_cell_angle_gamma   113.241
_symmetry_Int_Tables_number   1
_cell_volume   988.523
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.039  0.269  0.774  1.0
  Ag  Ag1  1  0.961  0.731  0.226  1.0
  Mo  Mo2  1  0.315  0.383  0.542  1.0
  Mo  Mo3  1  0.685  0.617  0.458  1.0
  Mo  Mo4  1  0.362  0.548  0.402  1.0
  Mo  Mo5  1  0.638  0.452  0.598  1.0
  Mo  Mo6  1  0.702  0.998  0.065  1.0
  Mo  Mo7  1  0.298  0.002  0.935  1.0
  Mo  Mo8  1  0.605  0.225  0.025  1.0
  Mo  Mo9  1  0.395  0.775  0.975  1.0
  Mo  Mo10  1  0.458  0.313  0.412  1.0
  Mo  Mo11  1  0.542  0.687  0.588  1.0
  Mo  Mo12  1  0.446  0.013  0.120  1.0
  Mo  Mo13  1  0.554  0.987  0.880  1.0
  Cl  Cl14  1  0.067  0.219  0.595  1.0
  Cl  Cl15  1  0.933  0.781  0.405  1.0
  Cl  Cl16  1  0.232  0.614  0.531  1.0
  Cl  Cl17  1  0.768  0.386  0.469  1.0
  Cl  Cl18  1  0.744  0.524  0.062  1.0
  Cl  Cl19  1  0.256  0.476  0.938  1.0
  Cl  Cl20  1  0.157  0.796  0.029  1.0
  Cl  Cl21  1  0.843  0.204  0.971  1.0
  Cl  Cl22  1  0.415  0.163  0.549  1.0
  Cl  Cl23  1  0.585  0.837  0.451  1.0
  Cl  Cl24  1  0.510  0.481  0.283  1.0
  Cl  Cl25  1  0.490  0.519  0.717  1.0
  Cl  Cl26  1  0.352  0.223  0.074  1.0
  Cl  Cl27  1  0.648  0.777  0.926  1.0
  Cl  Cl28  1  0.540  0.795  0.154  1.0
  Cl  Cl29  1  0.460  0.205  0.846  1.0
  Cl  Cl30  1  0.388  0.047  0.291  1.0
  Cl  Cl31  1  0.612  0.953  0.709  1.0
  Cl  Cl32  1  0.742  0.225  0.200  1.0
  Cl  Cl33  1  0.258  0.775  0.800  1.0
  Cl  Cl34  1  0.966  0.987  0.149  1.0
  Cl  Cl35  1  0.034  0.013  0.851  1.0
  Cl  Cl36  1  0.153  0.256  0.365  1.0
  Cl  Cl37  1  0.847  0.744  0.635  1.0
  Cl  Cl38  1  0.179  0.598  0.264  1.0
  Cl  Cl39  1  0.821  0.402  0.736  1.0
[/CIF]
.