The compound described by Sr5Ca3TiMn7O24 is (Cubic) Perovskite-derived structured and crystallizes in the monoclinic Cm space group. There are four inequivalent Sr sites. In the first Sr site, Sr(1) is bonded to one O(1), one O(10), one O(13), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), one O(8), and two equivalent O(9) atoms to form SrO12 cuboctahedra that share corners with four equivalent Sr(1)O12 cuboctahedra, corners with four equivalent Sr(4)O12 cuboctahedra, corners with four equivalent Ca(2)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, faces with two equivalent Ca(1)O12 cuboctahedra,  a faceface with one Ti(1)O6 octahedra,  a faceface with one Mn(2)O6 octahedra,  a faceface with one Mn(4)O6 octahedra,  a faceface with one Mn(5)O6 octahedra, faces with two equivalent Mn(1)O6 octahedra, and faces with two equivalent Mn(3)O6 octahedra. In the second Sr site, Sr(2) is bonded to one O(10), one O(13), two equivalent O(1), two equivalent O(2), two equivalent O(3), two equivalent O(4), and two equivalent O(9) atoms to form SrO12 cuboctahedra that share corners with four equivalent Sr(3)O12 cuboctahedra, corners with eight equivalent Ca(1)O12 cuboctahedra, faces with two equivalent Ca(2)O12 cuboctahedra, faces with four equivalent Sr(1)O12 cuboctahedra,  a faceface with one Ti(1)O6 octahedra,  a faceface with one Mn(2)O6 octahedra,  a faceface with one Mn(4)O6 octahedra,  a faceface with one Mn(5)O6 octahedra, faces with two equivalent Mn(1)O6 octahedra, and faces with two equivalent Mn(3)O6 octahedra. In the third Sr site, Sr(3) is bonded to one O(10), one O(13), two equivalent O(5), two equivalent O(6), two equivalent O(7), two equivalent O(8), and two equivalent O(9) atoms to form SrO12 cuboctahedra that share corners with four equivalent Sr(2)O12 cuboctahedra, corners with eight equivalent Ca(1)O12 cuboctahedra, faces with two equivalent Sr(4)O12 cuboctahedra, faces with four equivalent Sr(1)O12 cuboctahedra,  a faceface with one Ti(1)O6 octahedra,  a faceface with one Mn(2)O6 octahedra,  a faceface with one Mn(4)O6 octahedra,  a faceface with one Mn(5)O6 octahedra, faces with two equivalent Mn(1)O6 octahedra, and faces with two equivalent Mn(3)O6 octahedra. In the fourth Sr site, Sr(4) is bonded to one O(12), one O(14), two equivalent O(11), two equivalent O(5), two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms to form SrO12 cuboctahedra that share corners with four equivalent Ca(2)O12 cuboctahedra, corners with eight equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, faces with four equivalent Ca(1)O12 cuboctahedra,  a faceface with one Ti(1)O6 octahedra,  a faceface with one Mn(2)O6 octahedra,  a faceface with one Mn(4)O6 octahedra,  a faceface with one Mn(5)O6 octahedra, faces with two equivalent Mn(1)O6 octahedra, and faces with two equivalent Mn(3)O6 octahedra. There are two inequivalent Ca sites. In the first Ca site, Ca(1) is bonded to one O(1), one O(12), one O(14), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), one O(8), and two equivalent O(11) atoms to form CaO12 cuboctahedra that share corners with four equivalent Sr(2)O12 cuboctahedra, corners with four equivalent Sr(3)O12 cuboctahedra, corners with four equivalent Ca(1)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(4)O12 cuboctahedra, faces with two equivalent Ca(2)O12 cuboctahedra,  a faceface with one Ti(1)O6 octahedra,  a faceface with one Mn(2)O6 octahedra,  a faceface with one Mn(4)O6 octahedra,  a faceface with one Mn(5)O6 octahedra, faces with two equivalent Mn(1)O6 octahedra, and faces with two equivalent Mn(3)O6 octahedra. In the second Ca site, Ca(2) is bonded to one O(12), one O(14), two equivalent O(1), two equivalent O(11), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form CaO12 cuboctahedra that share corners with four equivalent Sr(4)O12 cuboctahedra, corners with eight equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with four equivalent Ca(1)O12 cuboctahedra,  a faceface with one Ti(1)O6 octahedra,  a faceface with one Mn(2)O6 octahedra,  a faceface with one Mn(4)O6 octahedra,  a faceface with one Mn(5)O6 octahedra, faces with two equivalent Mn(1)O6 octahedra, and faces with two equivalent Mn(3)O6 octahedra. Ti(1) is bonded to one O(10), one O(12), two equivalent O(4), and two equivalent O(8) atoms to form TiO6 octahedra that share corners with two equivalent Mn(2)O6 octahedra, corners with four equivalent Mn(3)O6 octahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra,  a faceface with one Ca(2)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, and faces with two equivalent Ca(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. There are five inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(11), one O(2), one O(5), one O(6), and one O(9) atom to form MnO6 octahedra that share corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra, corners with two equivalent Mn(4)O6 octahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra,  a faceface with one Ca(2)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, and faces with two equivalent Ca(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the second Mn site, Mn(2) is bonded to one O(10), one O(12), two equivalent O(2), and two equivalent O(6) atoms to form MnO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with four equivalent Mn(1)O6 octahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra,  a faceface with one Ca(2)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, and faces with two equivalent Ca(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the third Mn site, Mn(3) is bonded to one O(11), one O(3), one O(4), one O(7), one O(8), and one O(9) atom to form MnO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Mn(5)O6 octahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra,  a faceface with one Ca(2)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, and faces with two equivalent Ca(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the fourth Mn site, Mn(4) is bonded to one O(13), one O(14), two equivalent O(1), and two equivalent O(5) atoms to form MnO6 octahedra that share corners with two equivalent Mn(5)O6 octahedra, corners with four equivalent Mn(1)O6 octahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra,  a faceface with one Ca(2)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, and faces with two equivalent Ca(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the fifth Mn site, Mn(5) is bonded to one O(13), one O(14), two equivalent O(3), and two equivalent O(7) atoms to form MnO6 octahedra that share corners with two equivalent Mn(4)O6 octahedra, corners with four equivalent Mn(3)O6 octahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra,  a faceface with one Ca(2)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, and faces with two equivalent Ca(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), one Ca(1), one Ca(2), one Mn(1), and one Mn(4) atom. In the second O site, O(2) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), one Ca(1), one Ca(2), one Mn(1), and one Mn(2) atom. In the third O site, O(3) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), one Ca(1), one Ca(2), one Mn(3), and one Mn(5) atom. In the fourth O site, O(4) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), one Ca(1), one Ca(2), one Ti(1), and one Mn(3) atom. In the fifth O site, O(5) is bonded in a distorted linear geometry to one Sr(1), one Sr(3), one Sr(4), one Ca(1), one Mn(1), and one Mn(4) atom. In the sixth O site, O(6) is bonded in a distorted linear geometry to one Sr(1), one Sr(3), one Sr(4), one Ca(1), one Mn(1), and one Mn(2) atom. In the seventh O site, O(7) is bonded in a distorted linear geometry to one Sr(1), one Sr(3), one Sr(4), one Ca(1), one Mn(3), and one Mn(5) atom. In the eighth O site, O(8) is bonded in a distorted linear geometry to one Sr(1), one Sr(3), one Sr(4), one Ca(1), one Ti(1), and one Mn(3) atom. In the ninth O site, O(9) is bonded in a distorted linear geometry to one Sr(2), one Sr(3), two equivalent Sr(1), one Mn(1), and one Mn(3) atom. In the tenth O site, O(10) is bonded in a distorted linear geometry to one Sr(2), one Sr(3), two equivalent Sr(1), one Ti(1), and one Mn(2) atom. In the eleventh O site, O(11) is bonded in a distorted linear geometry to one Sr(4), one Ca(2), two equivalent Ca(1), one Mn(1), and one Mn(3) atom. In the twelfth O site, O(12) is bonded in a distorted linear geometry to one Sr(4), one Ca(2), two equivalent Ca(1), one Ti(1), and one Mn(2) atom. In the thirteenth O site, O(13) is bonded in a distorted octahedral geometry to one Sr(2), one Sr(3), two equivalent Sr(1), one Mn(4), and one Mn(5) atom. In the fourteenth O site, O(14) is bonded in a distorted linear geometry to one Sr(4), one Ca(2), two equivalent Ca(1), one Mn(4), and one Mn(5) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sr5Ca3TiMn7O24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.722
_cell_length_b   7.722
_cell_length_c   7.719
_cell_angle_alpha   89.992
_cell_angle_beta   89.992
_cell_angle_gamma   89.990
_symmetry_Int_Tables_number   1
_cell_volume   460.271
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.249  0.751  0.752  1.0
  Sr  Sr1  1  0.751  0.751  0.752  1.0
  Sr  Sr2  1  0.249  0.249  0.751  1.0
  Sr  Sr3  1  0.751  0.249  0.752  1.0
  Sr  Sr4  1  0.248  0.248  0.249  1.0
  Ca  Ca5  1  0.248  0.752  0.248  1.0
  Ca  Ca6  1  0.752  0.752  0.248  1.0
  Ca  Ca7  1  0.752  0.248  0.248  1.0
  Ti  Ti8  1  0.501  0.501  0.497  1.0
  Mn  Mn9  1  1.000  0.500  0.001  1.0
  Mn  Mn10  1  0.501  0.501  0.001  1.0
  Mn  Mn11  1  1.000  0.501  0.498  1.0
  Mn  Mn12  1  1.000  1.000  0.001  1.0
  Mn  Mn13  1  0.500  1.000  0.001  1.0
  Mn  Mn14  1  1.000  1.000  0.498  1.0
  Mn  Mn15  1  0.501  1.000  0.498  1.0
  O  O16  1  1.000  0.750  0.005  1.0
  O  O17  1  0.500  0.750  0.005  1.0
  O  O18  1  1.000  0.750  0.495  1.0
  O  O19  1  0.500  0.753  0.496  1.0
  O  O20  1  0.997  0.250  0.003  1.0
  O  O21  1  0.503  0.250  0.003  1.0
  O  O22  1  0.997  0.250  0.497  1.0
  O  O23  1  0.502  0.247  0.497  1.0
  O  O24  1  1.000  0.500  0.750  1.0
  O  O25  1  0.500  0.500  0.753  1.0
  O  O26  1  0.997  0.503  0.250  1.0
  O  O27  1  0.502  0.502  0.247  1.0
  O  O28  1  1.000  1.000  0.750  1.0
  O  O29  1  0.500  1.000  0.750  1.0
  O  O30  1  0.997  0.997  0.250  1.0
  O  O31  1  0.503  0.997  0.250  1.0
  O  O32  1  0.250  0.503  0.003  1.0
  O  O33  1  0.750  0.500  0.005  1.0
  O  O34  1  0.247  0.502  0.497  1.0
  O  O35  1  0.753  0.500  0.496  1.0
  O  O36  1  0.250  0.997  0.003  1.0
  O  O37  1  0.750  1.000  0.005  1.0
  O  O38  1  0.250  0.997  0.497  1.0
  O  O39  1  0.750  1.000  0.495  1.0
[/CIF]
.
The compound described by Sr5Ca3TiMn7O24 is (Cubic) Perovskite-derived structured and crystallizes in the monoclinic Cm space group. There are four inequivalent Sr sites. In the first Sr site, Sr(1) is bonded to one O(1), one O(10), one O(13), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), one O(8), and two equivalent O(9) atoms to form SrO12 cuboctahedra that share corners with four equivalent Sr(1)O12 cuboctahedra, corners with four equivalent Sr(4)O12 cuboctahedra, corners with four equivalent Ca(2)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, faces with two equivalent Ca(1)O12 cuboctahedra,  a faceface with one Ti(1)O6 octahedra,  a faceface with one Mn(2)O6 octahedra,  a faceface with one Mn(4)O6 octahedra,  a faceface with one Mn(5)O6 octahedra, faces with two equivalent Mn(1)O6 octahedra, and faces with two equivalent Mn(3)O6 octahedra. In the second Sr site, Sr(2) is bonded to one O(10), one O(13), two equivalent O(1), two equivalent O(2), two equivalent O(3), two equivalent O(4), and two equivalent O(9) atoms to form SrO12 cuboctahedra that share corners with four equivalent Sr(3)O12 cuboctahedra, corners with eight equivalent Ca(1)O12 cuboctahedra, faces with two equivalent Ca(2)O12 cuboctahedra, faces with four equivalent Sr(1)O12 cuboctahedra,  a faceface with one Ti(1)O6 octahedra,  a faceface with one Mn(2)O6 octahedra,  a faceface with one Mn(4)O6 octahedra,  a faceface with one Mn(5)O6 octahedra, faces with two equivalent Mn(1)O6 octahedra, and faces with two equivalent Mn(3)O6 octahedra. In the third Sr site, Sr(3) is bonded to one O(10), one O(13), two equivalent O(5), two equivalent O(6), two equivalent O(7), two equivalent O(8), and two equivalent O(9) atoms to form SrO12 cuboctahedra that share corners with four equivalent Sr(2)O12 cuboctahedra, corners with eight equivalent Ca(1)O12 cuboctahedra, faces with two equivalent Sr(4)O12 cuboctahedra, faces with four equivalent Sr(1)O12 cuboctahedra,  a faceface with one Ti(1)O6 octahedra,  a faceface with one Mn(2)O6 octahedra,  a faceface with one Mn(4)O6 octahedra,  a faceface with one Mn(5)O6 octahedra, faces with two equivalent Mn(1)O6 octahedra, and faces with two equivalent Mn(3)O6 octahedra. In the fourth Sr site, Sr(4) is bonded to one O(12), one O(14), two equivalent O(11), two equivalent O(5), two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms to form SrO12 cuboctahedra that share corners with four equivalent Ca(2)O12 cuboctahedra, corners with eight equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, faces with four equivalent Ca(1)O12 cuboctahedra,  a faceface with one Ti(1)O6 octahedra,  a faceface with one Mn(2)O6 octahedra,  a faceface with one Mn(4)O6 octahedra,  a faceface with one Mn(5)O6 octahedra, faces with two equivalent Mn(1)O6 octahedra, and faces with two equivalent Mn(3)O6 octahedra. There are two inequivalent Ca sites. In the first Ca site, Ca(1) is bonded to one O(1), one O(12), one O(14), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), one O(8), and two equivalent O(11) atoms to form CaO12 cuboctahedra that share corners with four equivalent Sr(2)O12 cuboctahedra, corners with four equivalent Sr(3)O12 cuboctahedra, corners with four equivalent Ca(1)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(4)O12 cuboctahedra, faces with two equivalent Ca(2)O12 cuboctahedra,  a faceface with one Ti(1)O6 octahedra,  a faceface with one Mn(2)O6 octahedra,  a faceface with one Mn(4)O6 octahedra,  a faceface with one Mn(5)O6 octahedra, faces with two equivalent Mn(1)O6 octahedra, and faces with two equivalent Mn(3)O6 octahedra. In the second Ca site, Ca(2) is bonded to one O(12), one O(14), two equivalent O(1), two equivalent O(11), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form CaO12 cuboctahedra that share corners with four equivalent Sr(4)O12 cuboctahedra, corners with eight equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with four equivalent Ca(1)O12 cuboctahedra,  a faceface with one Ti(1)O6 octahedra,  a faceface with one Mn(2)O6 octahedra,  a faceface with one Mn(4)O6 octahedra,  a faceface with one Mn(5)O6 octahedra, faces with two equivalent Mn(1)O6 octahedra, and faces with two equivalent Mn(3)O6 octahedra. Ti(1) is bonded to one O(10), one O(12), two equivalent O(4), and two equivalent O(8) atoms to form TiO6 octahedra that share corners with two equivalent Mn(2)O6 octahedra, corners with four equivalent Mn(3)O6 octahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra,  a faceface with one Ca(2)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, and faces with two equivalent Ca(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. There are five inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(11), one O(2), one O(5), one O(6), and one O(9) atom to form MnO6 octahedra that share corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra, corners with two equivalent Mn(4)O6 octahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra,  a faceface with one Ca(2)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, and faces with two equivalent Ca(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the second Mn site, Mn(2) is bonded to one O(10), one O(12), two equivalent O(2), and two equivalent O(6) atoms to form MnO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with four equivalent Mn(1)O6 octahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra,  a faceface with one Ca(2)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, and faces with two equivalent Ca(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the third Mn site, Mn(3) is bonded to one O(11), one O(3), one O(4), one O(7), one O(8), and one O(9) atom to form MnO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Mn(5)O6 octahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra,  a faceface with one Ca(2)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, and faces with two equivalent Ca(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the fourth Mn site, Mn(4) is bonded to one O(13), one O(14), two equivalent O(1), and two equivalent O(5) atoms to form MnO6 octahedra that share corners with two equivalent Mn(5)O6 octahedra, corners with four equivalent Mn(1)O6 octahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra,  a faceface with one Ca(2)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, and faces with two equivalent Ca(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the fifth Mn site, Mn(5) is bonded to one O(13), one O(14), two equivalent O(3), and two equivalent O(7) atoms to form MnO6 octahedra that share corners with two equivalent Mn(4)O6 octahedra, corners with four equivalent Mn(3)O6 octahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra,  a faceface with one Ca(2)O12 cuboctahedra, faces with two equivalent Sr(1)O12 cuboctahedra, and faces with two equivalent Ca(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), one Ca(1), one Ca(2), one Mn(1), and one Mn(4) atom. In the second O site, O(2) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), one Ca(1), one Ca(2), one Mn(1), and one Mn(2) atom. In the third O site, O(3) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), one Ca(1), one Ca(2), one Mn(3), and one Mn(5) atom. In the fourth O site, O(4) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), one Ca(1), one Ca(2), one Ti(1), and one Mn(3) atom. In the fifth O site, O(5) is bonded in a distorted linear geometry to one Sr(1), one Sr(3), one Sr(4), one Ca(1), one Mn(1), and one Mn(4) atom. In the sixth O site, O(6) is bonded in a distorted linear geometry to one Sr(1), one Sr(3), one Sr(4), one Ca(1), one Mn(1), and one Mn(2) atom. In the seventh O site, O(7) is bonded in a distorted linear geometry to one Sr(1), one Sr(3), one Sr(4), one Ca(1), one Mn(3), and one Mn(5) atom. In the eighth O site, O(8) is bonded in a distorted linear geometry to one Sr(1), one Sr(3), one Sr(4), one Ca(1), one Ti(1), and one Mn(3) atom. In the ninth O site, O(9) is bonded in a distorted linear geometry to one Sr(2), one Sr(3), two equivalent Sr(1), one Mn(1), and one Mn(3) atom. In the tenth O site, O(10) is bonded in a distorted linear geometry to one Sr(2), one Sr(3), two equivalent Sr(1), one Ti(1), and one Mn(2) atom. In the eleventh O site, O(11) is bonded in a distorted linear geometry to one Sr(4), one Ca(2), two equivalent Ca(1), one Mn(1), and one Mn(3) atom. In the twelfth O site, O(12) is bonded in a distorted linear geometry to one Sr(4), one Ca(2), two equivalent Ca(1), one Ti(1), and one Mn(2) atom. In the thirteenth O site, O(13) is bonded in a distorted octahedral geometry to one Sr(2), one Sr(3), two equivalent Sr(1), one Mn(4), and one Mn(5) atom. In the fourteenth O site, O(14) is bonded in a distorted linear geometry to one Sr(4), one Ca(2), two equivalent Ca(1), one Mn(4), and one Mn(5) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sr5Ca3TiMn7O24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.722
_cell_length_b   7.722
_cell_length_c   7.719
_cell_angle_alpha   89.992
_cell_angle_beta   89.992
_cell_angle_gamma   89.990
_symmetry_Int_Tables_number   1
_cell_volume   460.271
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.249  0.751  0.752  1.0
  Sr  Sr1  1  0.751  0.751  0.752  1.0
  Sr  Sr2  1  0.249  0.249  0.751  1.0
  Sr  Sr3  1  0.751  0.249  0.752  1.0
  Sr  Sr4  1  0.248  0.248  0.249  1.0
  Ca  Ca5  1  0.248  0.752  0.248  1.0
  Ca  Ca6  1  0.752  0.752  0.248  1.0
  Ca  Ca7  1  0.752  0.248  0.248  1.0
  Ti  Ti8  1  0.501  0.501  0.497  1.0
  Mn  Mn9  1  1.000  0.500  0.001  1.0
  Mn  Mn10  1  0.501  0.501  0.001  1.0
  Mn  Mn11  1  1.000  0.501  0.498  1.0
  Mn  Mn12  1  1.000  1.000  0.001  1.0
  Mn  Mn13  1  0.500  1.000  0.001  1.0
  Mn  Mn14  1  1.000  1.000  0.498  1.0
  Mn  Mn15  1  0.501  1.000  0.498  1.0
  O  O16  1  1.000  0.750  0.005  1.0
  O  O17  1  0.500  0.750  0.005  1.0
  O  O18  1  1.000  0.750  0.495  1.0
  O  O19  1  0.500  0.753  0.496  1.0
  O  O20  1  0.997  0.250  0.003  1.0
  O  O21  1  0.503  0.250  0.003  1.0
  O  O22  1  0.997  0.250  0.497  1.0
  O  O23  1  0.502  0.247  0.497  1.0
  O  O24  1  1.000  0.500  0.750  1.0
  O  O25  1  0.500  0.500  0.753  1.0
  O  O26  1  0.997  0.503  0.250  1.0
  O  O27  1  0.502  0.502  0.247  1.0
  O  O28  1  1.000  1.000  0.750  1.0
  O  O29  1  0.500  1.000  0.750  1.0
  O  O30  1  0.997  0.997  0.250  1.0
  O  O31  1  0.503  0.997  0.250  1.0
  O  O32  1  0.250  0.503  0.003  1.0
  O  O33  1  0.750  0.500  0.005  1.0
  O  O34  1  0.247  0.502  0.497  1.0
  O  O35  1  0.753  0.500  0.496  1.0
  O  O36  1  0.250  0.997  0.003  1.0
  O  O37  1  0.750  1.000  0.005  1.0
  O  O38  1  0.250  0.997  0.497  1.0
  O  O39  1  0.750  1.000  0.495  1.0
[/CIF]
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