The crystal structure described by RbLuS2O9 crystallizes in the monoclinic P2_1/c space group. Rb(1) is bonded in a 9-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), one O(8), and one O(9) atom. Lu(1) is bonded in a 8-coordinate geometry to one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), one O(8), and one O(9) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a tetrahedral geometry to one O(2), one O(6), one O(7), and one O(8) atom. In the second S site, S(2) is bonded in a tetrahedral geometry to one O(1), one O(3), one O(4), and one O(9) atom. There are nine inequivalent O sites. In the first O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Rb(1) and one Lu(1) atom. In the second O site, O(6) is bonded in a 3-coordinate geometry to one Rb(1), one Lu(1), and one S(1) atom. In the third O site, O(7) is bonded in a distorted single-bond geometry to one Rb(1), one Lu(1), and one S(1) atom. In the fourth O site, O(8) is bonded in a 2-coordinate geometry to one Rb(1), one Lu(1), and one S(1) atom. In the fifth O site, O(1) is bonded in a distorted single-bond geometry to one Rb(1) and one S(2) atom. In the sixth O site, O(9) is bonded in a 2-coordinate geometry to one Rb(1), one Lu(1), and one S(2) atom. In the seventh O site, O(2) is bonded in a distorted single-bond geometry to one Rb(1), one Lu(1), and one S(1) atom. In the eighth O site, O(3) is bonded in a 2-coordinate geometry to one Rb(1), one Lu(1), and one S(2) atom. In the ninth O site, O(4) is bonded in a 3-coordinate geometry to one Rb(1), one Lu(1), and one S(2) atom. is represented by the CIF file [CIF]
data_RbLuS2O9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.492
_cell_length_b   10.554
_cell_length_c   10.077
_cell_angle_alpha   120.227
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   780.346
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.334  0.682  0.963  1.0
  Rb  Rb1  1  0.666  0.318  0.037  1.0
  Rb  Rb2  1  0.834  0.818  0.537  1.0
  Rb  Rb3  1  0.166  0.182  0.463  1.0
  Lu  Lu4  1  0.371  0.970  0.718  1.0
  Lu  Lu5  1  0.629  0.030  0.282  1.0
  Lu  Lu6  1  0.871  0.530  0.782  1.0
  Lu  Lu7  1  0.129  0.470  0.218  1.0
  S  S8  1  0.131  0.316  0.877  1.0
  S  S9  1  0.869  0.684  0.123  1.0
  S  S10  1  0.631  0.184  0.623  1.0
  S  S11  1  0.369  0.816  0.377  1.0
  S  S12  1  0.196  0.610  0.598  1.0
  S  S13  1  0.804  0.390  0.402  1.0
  S  S14  1  0.696  0.890  0.902  1.0
  S  S15  1  0.304  0.110  0.098  1.0
  O  O16  1  0.794  0.024  0.970  1.0
  O  O17  1  0.206  0.976  0.030  1.0
  O  O18  1  0.294  0.476  0.530  1.0
  O  O19  1  0.706  0.524  0.470  1.0
  O  O20  1  0.207  0.177  0.764  1.0
  O  O21  1  0.793  0.823  0.236  1.0
  O  O22  1  0.707  0.323  0.736  1.0
  O  O23  1  0.293  0.677  0.264  1.0
  O  O24  1  0.299  0.744  0.681  1.0
  O  O25  1  0.701  0.256  0.319  1.0
  O  O26  1  0.799  0.756  0.819  1.0
  O  O27  1  0.201  0.244  0.181  1.0
  O  O28  1  0.394  0.119  0.976  1.0
  O  O29  1  0.606  0.881  0.024  1.0
  O  O30  1  0.894  0.381  0.524  1.0
  O  O31  1  0.106  0.619  0.476  1.0
  O  O32  1  0.124  0.938  0.780  1.0
  O  O33  1  0.876  0.062  0.220  1.0
  O  O34  1  0.624  0.562  0.720  1.0
  O  O35  1  0.376  0.438  0.280  1.0
  O  O36  1  0.251  0.422  0.990  1.0
  O  O37  1  0.749  0.578  0.010  1.0
  O  O38  1  0.751  0.078  0.510  1.0
  O  O39  1  0.249  0.922  0.490  1.0
  O  O40  1  0.012  0.300  0.975  1.0
  O  O41  1  0.988  0.700  0.025  1.0
  O  O42  1  0.512  0.200  0.525  1.0
  O  O43  1  0.488  0.800  0.475  1.0
  O  O44  1  0.059  0.381  0.790  1.0
  O  O45  1  0.941  0.619  0.210  1.0
  O  O46  1  0.559  0.119  0.710  1.0
  O  O47  1  0.441  0.881  0.290  1.0
  O  O48  1  0.588  0.888  0.785  1.0
  O  O49  1  0.412  0.112  0.215  1.0
  O  O50  1  0.088  0.612  0.715  1.0
  O  O51  1  0.912  0.388  0.285  1.0
[/CIF]
.
The crystal structure described by RbLuS2O9 crystallizes in the monoclinic P2_1/c space group. Rb(1) is bonded in a 9-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), one O(8), and one O(9) atom. Lu(1) is bonded in a 8-coordinate geometry to one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), one O(8), and one O(9) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a tetrahedral geometry to one O(2), one O(6), one O(7), and one O(8) atom. In the second S site, S(2) is bonded in a tetrahedral geometry to one O(1), one O(3), one O(4), and one O(9) atom. There are nine inequivalent O sites. In the first O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Rb(1) and one Lu(1) atom. In the second O site, O(6) is bonded in a 3-coordinate geometry to one Rb(1), one Lu(1), and one S(1) atom. In the third O site, O(7) is bonded in a distorted single-bond geometry to one Rb(1), one Lu(1), and one S(1) atom. In the fourth O site, O(8) is bonded in a 2-coordinate geometry to one Rb(1), one Lu(1), and one S(1) atom. In the fifth O site, O(1) is bonded in a distorted single-bond geometry to one Rb(1) and one S(2) atom. In the sixth O site, O(9) is bonded in a 2-coordinate geometry to one Rb(1), one Lu(1), and one S(2) atom. In the seventh O site, O(2) is bonded in a distorted single-bond geometry to one Rb(1), one Lu(1), and one S(1) atom. In the eighth O site, O(3) is bonded in a 2-coordinate geometry to one Rb(1), one Lu(1), and one S(2) atom. In the ninth O site, O(4) is bonded in a 3-coordinate geometry to one Rb(1), one Lu(1), and one S(2) atom. is represented by the CIF file [CIF]
data_RbLuS2O9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.492
_cell_length_b   10.554
_cell_length_c   10.077
_cell_angle_alpha   120.227
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   780.346
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.334  0.682  0.963  1.0
  Rb  Rb1  1  0.666  0.318  0.037  1.0
  Rb  Rb2  1  0.834  0.818  0.537  1.0
  Rb  Rb3  1  0.166  0.182  0.463  1.0
  Lu  Lu4  1  0.371  0.970  0.718  1.0
  Lu  Lu5  1  0.629  0.030  0.282  1.0
  Lu  Lu6  1  0.871  0.530  0.782  1.0
  Lu  Lu7  1  0.129  0.470  0.218  1.0
  S  S8  1  0.131  0.316  0.877  1.0
  S  S9  1  0.869  0.684  0.123  1.0
  S  S10  1  0.631  0.184  0.623  1.0
  S  S11  1  0.369  0.816  0.377  1.0
  S  S12  1  0.196  0.610  0.598  1.0
  S  S13  1  0.804  0.390  0.402  1.0
  S  S14  1  0.696  0.890  0.902  1.0
  S  S15  1  0.304  0.110  0.098  1.0
  O  O16  1  0.794  0.024  0.970  1.0
  O  O17  1  0.206  0.976  0.030  1.0
  O  O18  1  0.294  0.476  0.530  1.0
  O  O19  1  0.706  0.524  0.470  1.0
  O  O20  1  0.207  0.177  0.764  1.0
  O  O21  1  0.793  0.823  0.236  1.0
  O  O22  1  0.707  0.323  0.736  1.0
  O  O23  1  0.293  0.677  0.264  1.0
  O  O24  1  0.299  0.744  0.681  1.0
  O  O25  1  0.701  0.256  0.319  1.0
  O  O26  1  0.799  0.756  0.819  1.0
  O  O27  1  0.201  0.244  0.181  1.0
  O  O28  1  0.394  0.119  0.976  1.0
  O  O29  1  0.606  0.881  0.024  1.0
  O  O30  1  0.894  0.381  0.524  1.0
  O  O31  1  0.106  0.619  0.476  1.0
  O  O32  1  0.124  0.938  0.780  1.0
  O  O33  1  0.876  0.062  0.220  1.0
  O  O34  1  0.624  0.562  0.720  1.0
  O  O35  1  0.376  0.438  0.280  1.0
  O  O36  1  0.251  0.422  0.990  1.0
  O  O37  1  0.749  0.578  0.010  1.0
  O  O38  1  0.751  0.078  0.510  1.0
  O  O39  1  0.249  0.922  0.490  1.0
  O  O40  1  0.012  0.300  0.975  1.0
  O  O41  1  0.988  0.700  0.025  1.0
  O  O42  1  0.512  0.200  0.525  1.0
  O  O43  1  0.488  0.800  0.475  1.0
  O  O44  1  0.059  0.381  0.790  1.0
  O  O45  1  0.941  0.619  0.210  1.0
  O  O46  1  0.559  0.119  0.710  1.0
  O  O47  1  0.441  0.881  0.290  1.0
  O  O48  1  0.588  0.888  0.785  1.0
  O  O49  1  0.412  0.112  0.215  1.0
  O  O50  1  0.088  0.612  0.715  1.0
  O  O51  1  0.912  0.388  0.285  1.0
[/CIF]
.