The compound described by GdPO4 crystallizes in the monoclinic P2_1/c space group. Gd(1) is bonded in a 9-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and three equivalent O(4) atoms. P(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Gd(1) and one P(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Gd(1) and one P(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to two equivalent Gd(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to three equivalent Gd(1) and one P(1) atom. is represented by the CIF file [CIF]
data_GdPO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.318
_cell_length_b   6.637
_cell_length_c   6.827
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   104.109
_symmetry_Int_Tables_number   1
_cell_volume   277.634
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Gd  Gd0  1  0.597  0.782  0.345  1.0
  Gd  Gd1  1  0.903  0.718  0.845  1.0
  Gd  Gd2  1  0.403  0.218  0.655  1.0
  Gd  Gd3  1  0.097  0.282  0.155  1.0
  P  P4  1  0.113  0.802  0.339  1.0
  P  P5  1  0.387  0.698  0.839  1.0
  P  P6  1  0.887  0.198  0.661  1.0
  P  P7  1  0.613  0.302  0.161  1.0
  O  O8  1  0.212  0.620  0.291  1.0
  O  O9  1  0.288  0.880  0.791  1.0
  O  O10  1  0.788  0.380  0.709  1.0
  O  O11  1  0.712  0.120  0.209  1.0
  O  O12  1  0.314  0.972  0.399  1.0
  O  O13  1  0.186  0.528  0.899  1.0
  O  O14  1  0.686  0.028  0.601  1.0
  O  O15  1  0.814  0.472  0.101  1.0
  O  O16  1  0.436  0.251  0.002  1.0
  O  O17  1  0.064  0.249  0.502  1.0
  O  O18  1  0.564  0.749  0.998  1.0
  O  O19  1  0.936  0.751  0.498  1.0
  O  O20  1  0.503  0.384  0.336  1.0
  O  O21  1  0.997  0.116  0.836  1.0
  O  O22  1  0.497  0.616  0.664  1.0
  O  O23  1  0.003  0.884  0.164  1.0
[/CIF]
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The compound described by GdPO4 crystallizes in the monoclinic P2_1/c space group. Gd(1) is bonded in a 9-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and three equivalent O(4) atoms. P(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Gd(1) and one P(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Gd(1) and one P(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to two equivalent Gd(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to three equivalent Gd(1) and one P(1) atom. is represented by the CIF file [CIF]
data_GdPO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.318
_cell_length_b   6.637
_cell_length_c   6.827
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   104.109
_symmetry_Int_Tables_number   1
_cell_volume   277.634
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Gd  Gd0  1  0.597  0.782  0.345  1.0
  Gd  Gd1  1  0.903  0.718  0.845  1.0
  Gd  Gd2  1  0.403  0.218  0.655  1.0
  Gd  Gd3  1  0.097  0.282  0.155  1.0
  P  P4  1  0.113  0.802  0.339  1.0
  P  P5  1  0.387  0.698  0.839  1.0
  P  P6  1  0.887  0.198  0.661  1.0
  P  P7  1  0.613  0.302  0.161  1.0
  O  O8  1  0.212  0.620  0.291  1.0
  O  O9  1  0.288  0.880  0.791  1.0
  O  O10  1  0.788  0.380  0.709  1.0
  O  O11  1  0.712  0.120  0.209  1.0
  O  O12  1  0.314  0.972  0.399  1.0
  O  O13  1  0.186  0.528  0.899  1.0
  O  O14  1  0.686  0.028  0.601  1.0
  O  O15  1  0.814  0.472  0.101  1.0
  O  O16  1  0.436  0.251  0.002  1.0
  O  O17  1  0.064  0.249  0.502  1.0
  O  O18  1  0.564  0.749  0.998  1.0
  O  O19  1  0.936  0.751  0.498  1.0
  O  O20  1  0.503  0.384  0.336  1.0
  O  O21  1  0.997  0.116  0.836  1.0
  O  O22  1  0.497  0.616  0.664  1.0
  O  O23  1  0.003  0.884  0.164  1.0
[/CIF]
.