The compound described by Tb2Ru3Si5 crystallizes in the orthorhombic Ibam space group. Tb(1) is bonded in a 16-coordinate geometry to two equivalent Ru(2), four equivalent Ru(1), two equivalent Si(1), four equivalent Si(2), and four equivalent Si(3) atoms. There are two inequivalent Ru sites. In the first Ru site, Ru(1) is bonded in a 9-coordinate geometry to four equivalent Tb(1), one Si(3), two equivalent Si(1), and two equivalent Si(2) atoms. In the second Ru site, Ru(2) is bonded in a 6-coordinate geometry to four equivalent Tb(1), two equivalent Si(2), and four equivalent Si(3) atoms. There are three inequivalent Si sites. In the first Si site, Si(1) is bonded in a 4-coordinate geometry to four equivalent Tb(1) and four equivalent Ru(1) atoms. In the second Si site, Si(2) is bonded in a 11-coordinate geometry to four equivalent Tb(1), one Ru(2), two equivalent Ru(1), two equivalent Si(2), and two equivalent Si(3) atoms. In the third Si site, Si(3) is bonded in a 9-coordinate geometry to four equivalent Tb(1), one Ru(1), two equivalent Ru(2), and two equivalent Si(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Tb2Si5Ru3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.596
_cell_length_b   8.218
_cell_length_c   8.218
_cell_angle_alpha   71.555
_cell_angle_beta   70.094
_cell_angle_gamma   70.094
_symmetry_Int_Tables_number   1
_cell_volume   325.413
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tb  Tb0  1  0.135  0.633  0.097  1.0
  Tb  Tb1  1  0.865  0.367  0.903  1.0
  Tb  Tb2  1  0.365  0.903  0.367  1.0
  Tb  Tb3  1  0.635  0.097  0.633  1.0
  Si  Si4  1  0.250  0.000  0.000  1.0
  Si  Si5  1  0.750  0.000  0.000  1.0
  Si  Si6  1  0.958  0.292  0.292  1.0
  Si  Si7  1  0.542  0.708  0.708  1.0
  Si  Si8  1  0.042  0.708  0.708  1.0
  Si  Si9  1  0.458  0.292  0.292  1.0
  Si  Si10  1  0.404  0.429  0.764  1.0
  Si  Si11  1  0.904  0.764  0.429  1.0
  Si  Si12  1  0.096  0.236  0.571  1.0
  Si  Si13  1  0.596  0.571  0.236  1.0
  Ru  Ru14  1  0.854  0.052  0.239  1.0
  Ru  Ru15  1  0.750  0.500  0.500  1.0
  Ru  Ru16  1  0.354  0.239  0.052  1.0
  Ru  Ru17  1  0.646  0.761  0.948  1.0
  Ru  Ru18  1  0.146  0.948  0.761  1.0
  Ru  Ru19  1  0.250  0.500  0.500  1.0
[/CIF]
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The compound described by Tb2Ru3Si5 crystallizes in the orthorhombic Ibam space group. Tb(1) is bonded in a 16-coordinate geometry to two equivalent Ru(2), four equivalent Ru(1), two equivalent Si(1), four equivalent Si(2), and four equivalent Si(3) atoms. There are two inequivalent Ru sites. In the first Ru site, Ru(1) is bonded in a 9-coordinate geometry to four equivalent Tb(1), one Si(3), two equivalent Si(1), and two equivalent Si(2) atoms. In the second Ru site, Ru(2) is bonded in a 6-coordinate geometry to four equivalent Tb(1), two equivalent Si(2), and four equivalent Si(3) atoms. There are three inequivalent Si sites. In the first Si site, Si(1) is bonded in a 4-coordinate geometry to four equivalent Tb(1) and four equivalent Ru(1) atoms. In the second Si site, Si(2) is bonded in a 11-coordinate geometry to four equivalent Tb(1), one Ru(2), two equivalent Ru(1), two equivalent Si(2), and two equivalent Si(3) atoms. In the third Si site, Si(3) is bonded in a 9-coordinate geometry to four equivalent Tb(1), one Ru(1), two equivalent Ru(2), and two equivalent Si(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Tb2Si5Ru3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.596
_cell_length_b   8.218
_cell_length_c   8.218
_cell_angle_alpha   71.555
_cell_angle_beta   70.094
_cell_angle_gamma   70.094
_symmetry_Int_Tables_number   1
_cell_volume   325.413
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tb  Tb0  1  0.135  0.633  0.097  1.0
  Tb  Tb1  1  0.865  0.367  0.903  1.0
  Tb  Tb2  1  0.365  0.903  0.367  1.0
  Tb  Tb3  1  0.635  0.097  0.633  1.0
  Si  Si4  1  0.250  0.000  0.000  1.0
  Si  Si5  1  0.750  0.000  0.000  1.0
  Si  Si6  1  0.958  0.292  0.292  1.0
  Si  Si7  1  0.542  0.708  0.708  1.0
  Si  Si8  1  0.042  0.708  0.708  1.0
  Si  Si9  1  0.458  0.292  0.292  1.0
  Si  Si10  1  0.404  0.429  0.764  1.0
  Si  Si11  1  0.904  0.764  0.429  1.0
  Si  Si12  1  0.096  0.236  0.571  1.0
  Si  Si13  1  0.596  0.571  0.236  1.0
  Ru  Ru14  1  0.854  0.052  0.239  1.0
  Ru  Ru15  1  0.750  0.500  0.500  1.0
  Ru  Ru16  1  0.354  0.239  0.052  1.0
  Ru  Ru17  1  0.646  0.761  0.948  1.0
  Ru  Ru18  1  0.146  0.948  0.761  1.0
  Ru  Ru19  1  0.250  0.500  0.500  1.0
[/CIF]
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