The structure described by Pd3V is Uranium Silicide-like structured and crystallizes in the orthorhombic Cmcm space group. V(1) is bonded to four equivalent Pd(2) and eight equivalent Pd(1) atoms to form VPd12 cuboctahedra that share corners with four equivalent Pd(2)V4Pd8 cuboctahedra, corners with six equivalent V(1)Pd12 cuboctahedra, corners with eight equivalent Pd(1)V4Pd8 cuboctahedra, edges with six equivalent Pd(2)V4Pd8 cuboctahedra, edges with twelve equivalent Pd(1)V4Pd8 cuboctahedra, faces with four equivalent Pd(2)V4Pd8 cuboctahedra, faces with eight equivalent V(1)Pd12 cuboctahedra, and faces with eight equivalent Pd(1)V4Pd8 cuboctahedra. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded to four equivalent V(1), four equivalent Pd(1), and four equivalent Pd(2) atoms to form distorted PdV4Pd8 cuboctahedra that share corners with four equivalent V(1)Pd12 cuboctahedra, corners with four equivalent Pd(2)V4Pd8 cuboctahedra, corners with ten equivalent Pd(1)V4Pd8 cuboctahedra, edges with six equivalent V(1)Pd12 cuboctahedra, edges with six equivalent Pd(1)V4Pd8 cuboctahedra, edges with six equivalent Pd(2)V4Pd8 cuboctahedra, faces with four equivalent V(1)Pd12 cuboctahedra, faces with four equivalent Pd(2)V4Pd8 cuboctahedra, and faces with twelve equivalent Pd(1)V4Pd8 cuboctahedra. In the second Pd site, Pd(2) is bonded to four equivalent V(1) and eight equivalent Pd(1) atoms to form distorted PdV4Pd8 cuboctahedra that share corners with four equivalent V(1)Pd12 cuboctahedra, corners with six equivalent Pd(2)V4Pd8 cuboctahedra, corners with eight equivalent Pd(1)V4Pd8 cuboctahedra, edges with six equivalent V(1)Pd12 cuboctahedra, edges with twelve equivalent Pd(1)V4Pd8 cuboctahedra, faces with four equivalent V(1)Pd12 cuboctahedra, faces with eight equivalent Pd(1)V4Pd8 cuboctahedra, and faces with eight equivalent Pd(2)V4Pd8 cuboctahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_VPd3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.485
_cell_length_b   5.485
_cell_length_c   4.463
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.120
_symmetry_Int_Tables_number   1
_cell_volume   116.149
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.333  0.667  0.750  1.0
  V  V1  1  0.667  0.334  0.250  1.0
  Pd  Pd2  1  0.169  0.338  0.250  1.0
  Pd  Pd3  1  0.662  0.831  0.250  1.0
  Pd  Pd4  1  0.169  0.831  0.250  1.0
  Pd  Pd5  1  0.831  0.662  0.750  1.0
  Pd  Pd6  1  0.338  0.169  0.750  1.0
  Pd  Pd7  1  0.831  0.169  0.750  1.0
[/CIF]
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The structure described by Pd3V is Uranium Silicide-like structured and crystallizes in the orthorhombic Cmcm space group. V(1) is bonded to four equivalent Pd(2) and eight equivalent Pd(1) atoms to form VPd12 cuboctahedra that share corners with four equivalent Pd(2)V4Pd8 cuboctahedra, corners with six equivalent V(1)Pd12 cuboctahedra, corners with eight equivalent Pd(1)V4Pd8 cuboctahedra, edges with six equivalent Pd(2)V4Pd8 cuboctahedra, edges with twelve equivalent Pd(1)V4Pd8 cuboctahedra, faces with four equivalent Pd(2)V4Pd8 cuboctahedra, faces with eight equivalent V(1)Pd12 cuboctahedra, and faces with eight equivalent Pd(1)V4Pd8 cuboctahedra. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded to four equivalent V(1), four equivalent Pd(1), and four equivalent Pd(2) atoms to form distorted PdV4Pd8 cuboctahedra that share corners with four equivalent V(1)Pd12 cuboctahedra, corners with four equivalent Pd(2)V4Pd8 cuboctahedra, corners with ten equivalent Pd(1)V4Pd8 cuboctahedra, edges with six equivalent V(1)Pd12 cuboctahedra, edges with six equivalent Pd(1)V4Pd8 cuboctahedra, edges with six equivalent Pd(2)V4Pd8 cuboctahedra, faces with four equivalent V(1)Pd12 cuboctahedra, faces with four equivalent Pd(2)V4Pd8 cuboctahedra, and faces with twelve equivalent Pd(1)V4Pd8 cuboctahedra. In the second Pd site, Pd(2) is bonded to four equivalent V(1) and eight equivalent Pd(1) atoms to form distorted PdV4Pd8 cuboctahedra that share corners with four equivalent V(1)Pd12 cuboctahedra, corners with six equivalent Pd(2)V4Pd8 cuboctahedra, corners with eight equivalent Pd(1)V4Pd8 cuboctahedra, edges with six equivalent V(1)Pd12 cuboctahedra, edges with twelve equivalent Pd(1)V4Pd8 cuboctahedra, faces with four equivalent V(1)Pd12 cuboctahedra, faces with eight equivalent Pd(1)V4Pd8 cuboctahedra, and faces with eight equivalent Pd(2)V4Pd8 cuboctahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_VPd3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.485
_cell_length_b   5.485
_cell_length_c   4.463
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.120
_symmetry_Int_Tables_number   1
_cell_volume   116.149
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.333  0.667  0.750  1.0
  V  V1  1  0.667  0.334  0.250  1.0
  Pd  Pd2  1  0.169  0.338  0.250  1.0
  Pd  Pd3  1  0.662  0.831  0.250  1.0
  Pd  Pd4  1  0.169  0.831  0.250  1.0
  Pd  Pd5  1  0.831  0.662  0.750  1.0
  Pd  Pd6  1  0.338  0.169  0.750  1.0
  Pd  Pd7  1  0.831  0.169  0.750  1.0
[/CIF]
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