The material structure described by Cs2W3(S2O)4 crystallizes in the monoclinic P2_1 space group. There are two inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a 7-coordinate geometry to one S(1), one S(2), one S(5), one S(6), one S(7), one O(2), and one O(4) atom. In the second Cs site, Cs(2) is bonded in a 1-coordinate geometry to one S(1), one S(2), one S(5), one S(6), two equivalent S(8), and one O(3) atom. There are three inequivalent W sites. In the first W site, W(1) is bonded in a 5-coordinate geometry to one S(1), one S(3), one S(5), one S(7), and one O(4) atom. In the second W site, W(2) is bonded in a tetrahedral geometry to one S(2), one S(4), one S(6), and one S(8) atom. In the third W site, W(3) is bonded in a distorted bent 150 degrees geometry to one S(3), one S(4), one S(7), one S(8), one O(3), and one O(4) atom. There are eight inequivalent S sites. In the first S site, S(1) is bonded in a distorted T-shaped geometry to one Cs(1), one Cs(2), and one W(1) atom. In the second S site, S(2) is bonded in a 3-coordinate geometry to one Cs(1), one Cs(2), and one W(2) atom. In the third S site, S(3) is bonded in a 3-coordinate geometry to one W(1), one W(3), and one O(4) atom. In the fourth S site, S(4) is bonded in an L-shaped geometry to one W(2) and one W(3) atom. In the fifth S site, S(5) is bonded in a distorted trigonal non-coplanar geometry to one Cs(1), one Cs(2), and one W(1) atom. In the sixth S site, S(6) is bonded in a 3-coordinate geometry to one Cs(1), one Cs(2), and one W(2) atom. In the seventh S site, S(7) is bonded in a 3-coordinate geometry to one Cs(1), one W(1), and one W(3) atom. In the eighth S site, S(8) is bonded in a 4-coordinate geometry to two equivalent Cs(2), one W(2), and one W(3) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one O(2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cs(1) and one O(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Cs(2) and one W(3) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Cs(1), one W(1), one W(3), and one S(3) atom. is represented by the CIF file [CIF]
data_Cs2W3(S2O)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   19.984
_cell_length_b   7.314
_cell_length_c   7.694
_cell_angle_alpha   78.441
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1101.859
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.866  0.552  0.369  1.0
  Cs  Cs1  1  0.650  0.018  0.885  1.0
  Cs  Cs2  1  0.150  0.982  0.115  1.0
  Cs  Cs3  1  0.366  0.448  0.631  1.0
  W  W4  1  0.859  0.854  0.778  1.0
  W  W5  1  0.647  0.365  0.327  1.0
  W  W6  1  0.147  0.635  0.673  1.0
  W  W7  1  0.359  0.146  0.222  1.0
  W  W8  1  0.006  0.759  0.793  1.0
  W  W9  1  0.506  0.241  0.207  1.0
  S  S10  1  0.775  0.869  0.590  1.0
  S  S11  1  0.719  0.408  0.109  1.0
  S  S12  1  0.219  0.592  0.891  1.0
  S  S13  1  0.275  0.131  0.410  1.0
  S  S14  1  0.941  0.088  0.743  1.0
  S  S15  1  0.554  0.543  0.245  1.0
  S  S16  1  0.054  0.457  0.755  1.0
  S  S17  1  0.441  0.912  0.257  1.0
  S  S18  1  0.818  0.940  0.018  1.0
  S  S19  1  0.693  0.434  0.563  1.0
  S  S20  1  0.193  0.566  0.437  1.0
  S  S21  1  0.318  0.060  0.982  1.0
  S  S22  1  0.902  0.561  0.902  1.0
  S  S23  1  0.602  0.071  0.380  1.0
  S  S24  1  0.102  0.929  0.620  1.0
  S  S25  1  0.402  0.439  0.098  1.0
  O  O26  1  0.983  0.178  0.247  1.0
  O  O27  1  0.520  0.689  0.739  1.0
  O  O28  1  0.020  0.311  0.261  1.0
  O  O29  1  0.483  0.822  0.753  1.0
  O  O30  1  0.031  0.783  0.007  1.0
  O  O31  1  0.438  0.184  0.403  1.0
  O  O32  1  0.938  0.816  0.597  1.0
  O  O33  1  0.531  0.217  0.993  1.0
[/CIF]
.
The material structure described by Cs2W3(S2O)4 crystallizes in the monoclinic P2_1 space group. There are two inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a 7-coordinate geometry to one S(1), one S(2), one S(5), one S(6), one S(7), one O(2), and one O(4) atom. In the second Cs site, Cs(2) is bonded in a 1-coordinate geometry to one S(1), one S(2), one S(5), one S(6), two equivalent S(8), and one O(3) atom. There are three inequivalent W sites. In the first W site, W(1) is bonded in a 5-coordinate geometry to one S(1), one S(3), one S(5), one S(7), and one O(4) atom. In the second W site, W(2) is bonded in a tetrahedral geometry to one S(2), one S(4), one S(6), and one S(8) atom. In the third W site, W(3) is bonded in a distorted bent 150 degrees geometry to one S(3), one S(4), one S(7), one S(8), one O(3), and one O(4) atom. There are eight inequivalent S sites. In the first S site, S(1) is bonded in a distorted T-shaped geometry to one Cs(1), one Cs(2), and one W(1) atom. In the second S site, S(2) is bonded in a 3-coordinate geometry to one Cs(1), one Cs(2), and one W(2) atom. In the third S site, S(3) is bonded in a 3-coordinate geometry to one W(1), one W(3), and one O(4) atom. In the fourth S site, S(4) is bonded in an L-shaped geometry to one W(2) and one W(3) atom. In the fifth S site, S(5) is bonded in a distorted trigonal non-coplanar geometry to one Cs(1), one Cs(2), and one W(1) atom. In the sixth S site, S(6) is bonded in a 3-coordinate geometry to one Cs(1), one Cs(2), and one W(2) atom. In the seventh S site, S(7) is bonded in a 3-coordinate geometry to one Cs(1), one W(1), and one W(3) atom. In the eighth S site, S(8) is bonded in a 4-coordinate geometry to two equivalent Cs(2), one W(2), and one W(3) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one O(2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cs(1) and one O(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Cs(2) and one W(3) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Cs(1), one W(1), one W(3), and one S(3) atom. is represented by the CIF file [CIF]
data_Cs2W3(S2O)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   19.984
_cell_length_b   7.314
_cell_length_c   7.694
_cell_angle_alpha   78.441
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1101.859
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.866  0.552  0.369  1.0
  Cs  Cs1  1  0.650  0.018  0.885  1.0
  Cs  Cs2  1  0.150  0.982  0.115  1.0
  Cs  Cs3  1  0.366  0.448  0.631  1.0
  W  W4  1  0.859  0.854  0.778  1.0
  W  W5  1  0.647  0.365  0.327  1.0
  W  W6  1  0.147  0.635  0.673  1.0
  W  W7  1  0.359  0.146  0.222  1.0
  W  W8  1  0.006  0.759  0.793  1.0
  W  W9  1  0.506  0.241  0.207  1.0
  S  S10  1  0.775  0.869  0.590  1.0
  S  S11  1  0.719  0.408  0.109  1.0
  S  S12  1  0.219  0.592  0.891  1.0
  S  S13  1  0.275  0.131  0.410  1.0
  S  S14  1  0.941  0.088  0.743  1.0
  S  S15  1  0.554  0.543  0.245  1.0
  S  S16  1  0.054  0.457  0.755  1.0
  S  S17  1  0.441  0.912  0.257  1.0
  S  S18  1  0.818  0.940  0.018  1.0
  S  S19  1  0.693  0.434  0.563  1.0
  S  S20  1  0.193  0.566  0.437  1.0
  S  S21  1  0.318  0.060  0.982  1.0
  S  S22  1  0.902  0.561  0.902  1.0
  S  S23  1  0.602  0.071  0.380  1.0
  S  S24  1  0.102  0.929  0.620  1.0
  S  S25  1  0.402  0.439  0.098  1.0
  O  O26  1  0.983  0.178  0.247  1.0
  O  O27  1  0.520  0.689  0.739  1.0
  O  O28  1  0.020  0.311  0.261  1.0
  O  O29  1  0.483  0.822  0.753  1.0
  O  O30  1  0.031  0.783  0.007  1.0
  O  O31  1  0.438  0.184  0.403  1.0
  O  O32  1  0.938  0.816  0.597  1.0
  O  O33  1  0.531  0.217  0.993  1.0
[/CIF]
.