The material structure described by TlEuPS4 crystallizes in the orthorhombic Pnma space group. The structure consists of four 7440-28-0 atoms inside a EuPS4 framework. In the EuPS4 framework, Eu(1) is bonded in a 8-coordinate geometry to one S(3), three equivalent S(2), and four equivalent S(1) atoms. P(1) is bonded in a tetrahedral geometry to one S(2), one S(3), and two equivalent S(1) atoms. There are three inequivalent S sites. In the first S site, S(1) is bonded in a 3-coordinate geometry to two equivalent Eu(1) and one P(1) atom. In the second S site, S(2) is bonded in a 4-coordinate geometry to three equivalent Eu(1) and one P(1) atom. In the third S site, S(3) is bonded in an L-shaped geometry to one Eu(1) and one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_EuTlPS4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.640
_cell_length_b   9.006
_cell_length_c   12.152
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   726.646
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Eu  Eu0  1  0.250  0.395  0.143  1.0
  Eu  Eu1  1  0.750  0.605  0.857  1.0
  Eu  Eu2  1  0.750  0.895  0.357  1.0
  Eu  Eu3  1  0.250  0.105  0.643  1.0
  Tl  Tl4  1  0.250  0.869  0.104  1.0
  Tl  Tl5  1  0.750  0.369  0.396  1.0
  Tl  Tl6  1  0.250  0.631  0.604  1.0
  Tl  Tl7  1  0.750  0.131  0.896  1.0
  P  P8  1  0.250  0.123  0.346  1.0
  P  P9  1  0.750  0.877  0.654  1.0
  P  P10  1  0.750  0.623  0.154  1.0
  P  P11  1  0.250  0.377  0.846  1.0
  S  S12  1  0.498  0.367  0.744  1.0
  S  S13  1  0.250  0.573  0.933  1.0
  S  S14  1  0.750  0.073  0.567  1.0
  S  S15  1  0.250  0.927  0.433  1.0
  S  S16  1  0.750  0.427  0.067  1.0
  S  S17  1  0.250  0.196  0.949  1.0
  S  S18  1  0.502  0.867  0.756  1.0
  S  S19  1  0.498  0.133  0.244  1.0
  S  S20  1  0.250  0.304  0.449  1.0
  S  S21  1  0.502  0.633  0.256  1.0
  S  S22  1  0.750  0.804  0.051  1.0
  S  S23  1  0.998  0.867  0.756  1.0
  S  S24  1  0.002  0.133  0.244  1.0
  S  S25  1  0.998  0.633  0.256  1.0
  S  S26  1  0.750  0.696  0.551  1.0
  S  S27  1  0.002  0.367  0.744  1.0
[/CIF]
.
The material structure described by TlEuPS4 crystallizes in the orthorhombic Pnma space group. The structure consists of four 7440-28-0 atoms inside a EuPS4 framework. In the EuPS4 framework, Eu(1) is bonded in a 8-coordinate geometry to one S(3), three equivalent S(2), and four equivalent S(1) atoms. P(1) is bonded in a tetrahedral geometry to one S(2), one S(3), and two equivalent S(1) atoms. There are three inequivalent S sites. In the first S site, S(1) is bonded in a 3-coordinate geometry to two equivalent Eu(1) and one P(1) atom. In the second S site, S(2) is bonded in a 4-coordinate geometry to three equivalent Eu(1) and one P(1) atom. In the third S site, S(3) is bonded in an L-shaped geometry to one Eu(1) and one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_EuTlPS4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.640
_cell_length_b   9.006
_cell_length_c   12.152
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   726.646
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Eu  Eu0  1  0.250  0.395  0.143  1.0
  Eu  Eu1  1  0.750  0.605  0.857  1.0
  Eu  Eu2  1  0.750  0.895  0.357  1.0
  Eu  Eu3  1  0.250  0.105  0.643  1.0
  Tl  Tl4  1  0.250  0.869  0.104  1.0
  Tl  Tl5  1  0.750  0.369  0.396  1.0
  Tl  Tl6  1  0.250  0.631  0.604  1.0
  Tl  Tl7  1  0.750  0.131  0.896  1.0
  P  P8  1  0.250  0.123  0.346  1.0
  P  P9  1  0.750  0.877  0.654  1.0
  P  P10  1  0.750  0.623  0.154  1.0
  P  P11  1  0.250  0.377  0.846  1.0
  S  S12  1  0.498  0.367  0.744  1.0
  S  S13  1  0.250  0.573  0.933  1.0
  S  S14  1  0.750  0.073  0.567  1.0
  S  S15  1  0.250  0.927  0.433  1.0
  S  S16  1  0.750  0.427  0.067  1.0
  S  S17  1  0.250  0.196  0.949  1.0
  S  S18  1  0.502  0.867  0.756  1.0
  S  S19  1  0.498  0.133  0.244  1.0
  S  S20  1  0.250  0.304  0.449  1.0
  S  S21  1  0.502  0.633  0.256  1.0
  S  S22  1  0.750  0.804  0.051  1.0
  S  S23  1  0.998  0.867  0.756  1.0
  S  S24  1  0.002  0.133  0.244  1.0
  S  S25  1  0.998  0.633  0.256  1.0
  S  S26  1  0.750  0.696  0.551  1.0
  S  S27  1  0.002  0.367  0.744  1.0
[/CIF]
.