The structure described by VBi2 crystallizes in the monoclinic C2/m space group. V(1) is bonded in a 8-coordinate geometry to three equivalent Bi(2) and five equivalent Bi(1) atoms. There are two inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a 5-coordinate geometry to five equivalent V(1) atoms. In the second Bi site, Bi(2) is bonded in a 3-coordinate geometry to three equivalent V(1) atoms. is represented by the CIF file [CIF]
data_VBi2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.691
_cell_length_b   5.691
_cell_length_c   8.438
_cell_angle_alpha   60.416
_cell_angle_beta   60.416
_cell_angle_gamma   38.643
_symmetry_Int_Tables_number   1
_cell_volume   145.421
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.144  0.144  0.817  1.0
  V  V1  1  0.856  0.856  0.183  1.0
  Bi  Bi2  1  0.409  0.409  0.886  1.0
  Bi  Bi3  1  0.591  0.591  0.114  1.0
  Bi  Bi4  1  0.842  0.842  0.549  1.0
  Bi  Bi5  1  0.158  0.158  0.451  1.0
[/CIF]
.
The structure described by VBi2 crystallizes in the monoclinic C2/m space group. V(1) is bonded in a 8-coordinate geometry to three equivalent Bi(2) and five equivalent Bi(1) atoms. There are two inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a 5-coordinate geometry to five equivalent V(1) atoms. In the second Bi site, Bi(2) is bonded in a 3-coordinate geometry to three equivalent V(1) atoms. is represented by the CIF file [CIF]
data_VBi2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.691
_cell_length_b   5.691
_cell_length_c   8.438
_cell_angle_alpha   60.416
_cell_angle_beta   60.416
_cell_angle_gamma   38.643
_symmetry_Int_Tables_number   1
_cell_volume   145.421
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.144  0.144  0.817  1.0
  V  V1  1  0.856  0.856  0.183  1.0
  Bi  Bi2  1  0.409  0.409  0.886  1.0
  Bi  Bi3  1  0.591  0.591  0.114  1.0
  Bi  Bi4  1  0.842  0.842  0.549  1.0
  Bi  Bi5  1  0.158  0.158  0.451  1.0
[/CIF]
.