The structure described by MnP4 is Sylvanite-derived structured and crystallizes in the triclinic P-1 space group. Mn(1) is bonded to one P(1), one P(2), two equivalent P(3), and two equivalent P(4) atoms to form edge-sharing MnP6 octahedra. There are four inequivalent P sites. In the first P site, P(1) is bonded in a distorted single-bond geometry to one Mn(1), one P(1), one P(2), and one P(3) atom. In the second P site, P(2) is bonded in a distorted single-bond geometry to one Mn(1), one P(1), one P(2), and one P(4) atom. In the third P site, P(3) is bonded in a 4-coordinate geometry to two equivalent Mn(1), one P(1), and one P(4) atom. In the fourth P site, P(4) is bonded in a 4-coordinate geometry to two equivalent Mn(1), one P(2), and one P(3) atom. is represented by the CIF file [CIF]
data_MnP4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.088
_cell_length_b   5.808
_cell_length_c   5.838
_cell_angle_alpha   107.235
_cell_angle_beta   115.865
_cell_angle_gamma   93.699
_symmetry_Int_Tables_number   1
_cell_volume   144.431
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.786  0.276  0.784  1.0
  Mn  Mn1  1  0.214  0.724  0.216  1.0
  P  P2  1  0.400  0.803  0.955  1.0
  P  P3  1  0.600  0.197  0.045  1.0
  P  P4  1  0.938  0.305  0.489  1.0
  P  P5  1  0.062  0.695  0.511  1.0
  P  P6  1  0.245  0.331  0.119  1.0
  P  P7  1  0.755  0.669  0.881  1.0
  P  P8  1  0.301  0.152  0.421  1.0
  P  P9  1  0.699  0.848  0.579  1.0
[/CIF]
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The structure described by MnP4 is Sylvanite-derived structured and crystallizes in the triclinic P-1 space group. Mn(1) is bonded to one P(1), one P(2), two equivalent P(3), and two equivalent P(4) atoms to form edge-sharing MnP6 octahedra. There are four inequivalent P sites. In the first P site, P(1) is bonded in a distorted single-bond geometry to one Mn(1), one P(1), one P(2), and one P(3) atom. In the second P site, P(2) is bonded in a distorted single-bond geometry to one Mn(1), one P(1), one P(2), and one P(4) atom. In the third P site, P(3) is bonded in a 4-coordinate geometry to two equivalent Mn(1), one P(1), and one P(4) atom. In the fourth P site, P(4) is bonded in a 4-coordinate geometry to two equivalent Mn(1), one P(2), and one P(3) atom. is represented by the CIF file [CIF]
data_MnP4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.088
_cell_length_b   5.808
_cell_length_c   5.838
_cell_angle_alpha   107.235
_cell_angle_beta   115.865
_cell_angle_gamma   93.699
_symmetry_Int_Tables_number   1
_cell_volume   144.431
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.786  0.276  0.784  1.0
  Mn  Mn1  1  0.214  0.724  0.216  1.0
  P  P2  1  0.400  0.803  0.955  1.0
  P  P3  1  0.600  0.197  0.045  1.0
  P  P4  1  0.938  0.305  0.489  1.0
  P  P5  1  0.062  0.695  0.511  1.0
  P  P6  1  0.245  0.331  0.119  1.0
  P  P7  1  0.755  0.669  0.881  1.0
  P  P8  1  0.301  0.152  0.421  1.0
  P  P9  1  0.699  0.848  0.579  1.0
[/CIF]
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