The compound described by K3MoO13I crystallizes in the triclinic P-1 space group. There are three inequivalent K sites. In the first K site, K(1) is bonded in a 7-coordinate geometry to one O(1), one O(11), one O(12), one O(13), one O(4), and two equivalent O(2) atoms. In the second K site, K(2) is bonded in a 9-coordinate geometry to one O(13), one O(2), one O(4), one O(6), one O(7), one O(8), one O(9), and two equivalent O(12) atoms. In the third K site, K(3) is bonded in a 8-coordinate geometry to one O(1), one O(10), one O(11), one O(3), one O(6), one O(7), one O(8), and one O(9) atom. Mo(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), and two equivalent O(5) atoms. There are thirteen inequivalent O sites. In the first O site, O(12) is bonded in a distorted see-saw-like geometry to one K(1), two equivalent K(2), and one O(10) atom. In the second O site, O(13) is bonded in a 2-coordinate geometry to one K(1), one K(2), and one O(9) atom. In the third O site, O(1) is bonded in a distorted single-bond geometry to one K(1), one K(3), and one Mo(1) atom. In the fourth O site, O(2) is bonded in a 4-coordinate geometry to one K(2), two equivalent K(1), and one Mo(1) atom. In the fifth O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one K(3), one Mo(1), and one I(1) atom. In the sixth O site, O(4) is bonded in a 4-coordinate geometry to one K(1), one K(2), one Mo(1), and one I(1) atom. In the seventh O site, O(5) is bonded in a 3-coordinate geometry to two equivalent Mo(1) and one I(1) atom. In the eighth O site, O(6) is bonded in a 3-coordinate geometry to one K(2), one K(3), and one I(1) atom. In the ninth O site, O(7) is bonded in a 3-coordinate geometry to one K(2), one K(3), and one I(1) atom. In the tenth O site, O(8) is bonded in a distorted single-bond geometry to one K(2), one K(3), and one I(1) atom. In the eleventh O site, O(9) is bonded in a 3-coordinate geometry to one K(2), one K(3), and one O(13) atom. In the twelfth O site, O(10) is bonded in a 2-coordinate geometry to one K(3) and one O(12) atom. In the thirteenth O site, O(11) is bonded in a distorted bent 120 degrees geometry to one K(1) and one K(3) atom. I(1) is bonded in a distorted octahedral geometry to one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom. is represented by the CIF file [CIF]
data_K3MoIO13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.956
_cell_length_b   8.043
_cell_length_c   10.077
_cell_angle_alpha   109.677
_cell_angle_beta   91.459
_cell_angle_gamma   99.335
_symmetry_Int_Tables_number   1
_cell_volume   596.908
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.566  0.754  0.034  1.0
  K  K1  1  0.434  0.246  0.966  1.0
  K  K2  1  0.549  0.219  0.366  1.0
  K  K3  1  0.451  0.781  0.634  1.0
  K  K4  1  0.065  0.665  0.320  1.0
  K  K5  1  0.935  0.335  0.680  1.0
  Mo  Mo6  1  0.837  0.137  0.002  1.0
  Mo  Mo7  1  0.163  0.863  0.998  1.0
  I  I8  1  0.902  0.823  0.718  1.0
  I  I9  1  0.098  0.177  0.282  1.0
  O  O10  1  0.775  0.275  0.912  1.0
  O  O11  1  0.225  0.725  0.088  1.0
  O  O12  1  0.663  0.117  0.106  1.0
  O  O13  1  0.337  0.883  0.894  1.0
  O  O14  1  0.988  0.702  0.858  1.0
  O  O15  1  0.012  0.298  0.142  1.0
  O  O16  1  0.734  0.893  0.863  1.0
  O  O17  1  0.266  0.107  0.137  1.0
  O  O18  1  0.038  0.035  0.876  1.0
  O  O19  1  0.962  0.965  0.124  1.0
  O  O20  1  0.819  0.964  0.631  1.0
  O  O21  1  0.181  0.036  0.369  1.0
  O  O22  1  0.911  0.224  0.381  1.0
  O  O23  1  0.089  0.776  0.619  1.0
  O  O24  1  0.754  0.611  0.628  1.0
  O  O25  1  0.246  0.389  0.372  1.0
  O  O26  1  0.689  0.553  0.303  1.0
  O  O27  1  0.311  0.447  0.697  1.0
  O  O28  1  0.729  0.835  0.371  1.0
  O  O29  1  0.271  0.165  0.629  1.0
  O  O30  1  0.832  0.586  0.040  1.0
  O  O31  1  0.168  0.414  0.960  1.0
  O  O32  1  0.425  0.165  0.651  1.0
  O  O33  1  0.575  0.835  0.349  1.0
  O  O34  1  0.466  0.460  0.729  1.0
  O  O35  1  0.534  0.540  0.271  1.0
[/CIF]
.
The compound described by K3MoO13I crystallizes in the triclinic P-1 space group. There are three inequivalent K sites. In the first K site, K(1) is bonded in a 7-coordinate geometry to one O(1), one O(11), one O(12), one O(13), one O(4), and two equivalent O(2) atoms. In the second K site, K(2) is bonded in a 9-coordinate geometry to one O(13), one O(2), one O(4), one O(6), one O(7), one O(8), one O(9), and two equivalent O(12) atoms. In the third K site, K(3) is bonded in a 8-coordinate geometry to one O(1), one O(10), one O(11), one O(3), one O(6), one O(7), one O(8), and one O(9) atom. Mo(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), and two equivalent O(5) atoms. There are thirteen inequivalent O sites. In the first O site, O(12) is bonded in a distorted see-saw-like geometry to one K(1), two equivalent K(2), and one O(10) atom. In the second O site, O(13) is bonded in a 2-coordinate geometry to one K(1), one K(2), and one O(9) atom. In the third O site, O(1) is bonded in a distorted single-bond geometry to one K(1), one K(3), and one Mo(1) atom. In the fourth O site, O(2) is bonded in a 4-coordinate geometry to one K(2), two equivalent K(1), and one Mo(1) atom. In the fifth O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one K(3), one Mo(1), and one I(1) atom. In the sixth O site, O(4) is bonded in a 4-coordinate geometry to one K(1), one K(2), one Mo(1), and one I(1) atom. In the seventh O site, O(5) is bonded in a 3-coordinate geometry to two equivalent Mo(1) and one I(1) atom. In the eighth O site, O(6) is bonded in a 3-coordinate geometry to one K(2), one K(3), and one I(1) atom. In the ninth O site, O(7) is bonded in a 3-coordinate geometry to one K(2), one K(3), and one I(1) atom. In the tenth O site, O(8) is bonded in a distorted single-bond geometry to one K(2), one K(3), and one I(1) atom. In the eleventh O site, O(9) is bonded in a 3-coordinate geometry to one K(2), one K(3), and one O(13) atom. In the twelfth O site, O(10) is bonded in a 2-coordinate geometry to one K(3) and one O(12) atom. In the thirteenth O site, O(11) is bonded in a distorted bent 120 degrees geometry to one K(1) and one K(3) atom. I(1) is bonded in a distorted octahedral geometry to one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom. is represented by the CIF file [CIF]
data_K3MoIO13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.956
_cell_length_b   8.043
_cell_length_c   10.077
_cell_angle_alpha   109.677
_cell_angle_beta   91.459
_cell_angle_gamma   99.335
_symmetry_Int_Tables_number   1
_cell_volume   596.908
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.566  0.754  0.034  1.0
  K  K1  1  0.434  0.246  0.966  1.0
  K  K2  1  0.549  0.219  0.366  1.0
  K  K3  1  0.451  0.781  0.634  1.0
  K  K4  1  0.065  0.665  0.320  1.0
  K  K5  1  0.935  0.335  0.680  1.0
  Mo  Mo6  1  0.837  0.137  0.002  1.0
  Mo  Mo7  1  0.163  0.863  0.998  1.0
  I  I8  1  0.902  0.823  0.718  1.0
  I  I9  1  0.098  0.177  0.282  1.0
  O  O10  1  0.775  0.275  0.912  1.0
  O  O11  1  0.225  0.725  0.088  1.0
  O  O12  1  0.663  0.117  0.106  1.0
  O  O13  1  0.337  0.883  0.894  1.0
  O  O14  1  0.988  0.702  0.858  1.0
  O  O15  1  0.012  0.298  0.142  1.0
  O  O16  1  0.734  0.893  0.863  1.0
  O  O17  1  0.266  0.107  0.137  1.0
  O  O18  1  0.038  0.035  0.876  1.0
  O  O19  1  0.962  0.965  0.124  1.0
  O  O20  1  0.819  0.964  0.631  1.0
  O  O21  1  0.181  0.036  0.369  1.0
  O  O22  1  0.911  0.224  0.381  1.0
  O  O23  1  0.089  0.776  0.619  1.0
  O  O24  1  0.754  0.611  0.628  1.0
  O  O25  1  0.246  0.389  0.372  1.0
  O  O26  1  0.689  0.553  0.303  1.0
  O  O27  1  0.311  0.447  0.697  1.0
  O  O28  1  0.729  0.835  0.371  1.0
  O  O29  1  0.271  0.165  0.629  1.0
  O  O30  1  0.832  0.586  0.040  1.0
  O  O31  1  0.168  0.414  0.960  1.0
  O  O32  1  0.425  0.165  0.651  1.0
  O  O33  1  0.575  0.835  0.349  1.0
  O  O34  1  0.466  0.460  0.729  1.0
  O  O35  1  0.534  0.540  0.271  1.0
[/CIF]
.