The compound described by CsSbTeO6 crystallizes in the orthorhombic Imma space group. Cs(1) is bonded to one O(1), one O(2), and four equivalent O(3) atoms to form CsO6 octahedra that share corners with six equivalent Sb(1)O6 octahedra and corners with six equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 67-68°. Sb(1) is bonded to two equivalent O(2) and four equivalent O(3) atoms to form SbO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra, corners with four equivalent Te(1)O6 octahedra, and corners with six equivalent Cs(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-68°. Te(1) is bonded to two equivalent O(1) and four equivalent O(3) atoms to form TeO6 octahedra that share corners with two equivalent Te(1)O6 octahedra, corners with four equivalent Sb(1)O6 octahedra, and corners with six equivalent Cs(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-68°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Cs(1) and two equivalent Te(1) atoms. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Cs(1) and two equivalent Sb(1) atoms. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Cs(1), one Sb(1), and one Te(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CsSbTeO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.329
_cell_length_b   7.329
_cell_length_c   7.329
_cell_angle_alpha   120.374
_cell_angle_beta   119.758
_cell_angle_gamma   89.887
_symmetry_Int_Tables_number   1
_cell_volume   278.057
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.374  0.624  0.750  1.0
  Cs  Cs1  1  0.626  0.376  0.250  1.0
  Sb  Sb2  1  0.000  0.000  0.500  1.0
  Sb  Sb3  1  0.000  0.500  0.000  1.0
  Te  Te4  1  0.000  0.000  0.000  1.0
  Te  Te5  1  0.500  0.000  0.500  1.0
  O  O6  1  0.321  0.071  0.250  1.0
  O  O7  1  0.926  0.676  0.250  1.0
  O  O8  1  0.327  0.683  0.256  1.0
  O  O9  1  0.927  0.072  0.244  1.0
  O  O10  1  0.327  0.072  0.644  1.0
  O  O11  1  0.927  0.683  0.856  1.0
  O  O12  1  0.679  0.929  0.750  1.0
  O  O13  1  0.074  0.324  0.750  1.0
  O  O14  1  0.673  0.317  0.744  1.0
  O  O15  1  0.073  0.928  0.756  1.0
  O  O16  1  0.673  0.928  0.356  1.0
  O  O17  1  0.073  0.317  0.144  1.0
[/CIF]
.
The compound described by CsSbTeO6 crystallizes in the orthorhombic Imma space group. Cs(1) is bonded to one O(1), one O(2), and four equivalent O(3) atoms to form CsO6 octahedra that share corners with six equivalent Sb(1)O6 octahedra and corners with six equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 67-68°. Sb(1) is bonded to two equivalent O(2) and four equivalent O(3) atoms to form SbO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra, corners with four equivalent Te(1)O6 octahedra, and corners with six equivalent Cs(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-68°. Te(1) is bonded to two equivalent O(1) and four equivalent O(3) atoms to form TeO6 octahedra that share corners with two equivalent Te(1)O6 octahedra, corners with four equivalent Sb(1)O6 octahedra, and corners with six equivalent Cs(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-68°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Cs(1) and two equivalent Te(1) atoms. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Cs(1) and two equivalent Sb(1) atoms. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Cs(1), one Sb(1), and one Te(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CsSbTeO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.329
_cell_length_b   7.329
_cell_length_c   7.329
_cell_angle_alpha   120.374
_cell_angle_beta   119.758
_cell_angle_gamma   89.887
_symmetry_Int_Tables_number   1
_cell_volume   278.057
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.374  0.624  0.750  1.0
  Cs  Cs1  1  0.626  0.376  0.250  1.0
  Sb  Sb2  1  0.000  0.000  0.500  1.0
  Sb  Sb3  1  0.000  0.500  0.000  1.0
  Te  Te4  1  0.000  0.000  0.000  1.0
  Te  Te5  1  0.500  0.000  0.500  1.0
  O  O6  1  0.321  0.071  0.250  1.0
  O  O7  1  0.926  0.676  0.250  1.0
  O  O8  1  0.327  0.683  0.256  1.0
  O  O9  1  0.927  0.072  0.244  1.0
  O  O10  1  0.327  0.072  0.644  1.0
  O  O11  1  0.927  0.683  0.856  1.0
  O  O12  1  0.679  0.929  0.750  1.0
  O  O13  1  0.074  0.324  0.750  1.0
  O  O14  1  0.673  0.317  0.744  1.0
  O  O15  1  0.073  0.928  0.756  1.0
  O  O16  1  0.673  0.928  0.356  1.0
  O  O17  1  0.073  0.317  0.144  1.0
[/CIF]
.