The compound described by LiMnN is Cotunnite-derived structured and crystallizes in the orthorhombic Pnma space group. Li(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent N(1) atoms. Mn(1) is bonded to four equivalent N(1) atoms to form a mixture of distorted edge and corner-sharing MnN4 tetrahedra. N(1) is bonded to three equivalent Li(1) and four equivalent Mn(1) atoms to form a mixture of distorted edge and corner-sharing NLi3Mn4 hexagonal pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiMnN
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.788
_cell_length_b   3.147
_cell_length_c   4.966
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   106.098
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.604  0.250  0.896  1.0
  Li  Li1  1  0.104  0.250  0.604  1.0
  Li  Li2  1  0.396  0.750  0.104  1.0
  Li  Li3  1  0.896  0.750  0.396  1.0
  Mn  Mn4  1  0.626  0.250  0.415  1.0
  Mn  Mn5  1  0.126  0.250  0.085  1.0
  Mn  Mn6  1  0.374  0.750  0.585  1.0
  Mn  Mn7  1  0.874  0.750  0.915  1.0
  N  N8  1  0.844  0.250  0.146  1.0
  N  N9  1  0.344  0.250  0.354  1.0
  N  N10  1  0.156  0.750  0.854  1.0
  N  N11  1  0.656  0.750  0.646  1.0
[/CIF]
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The compound described by LiMnN is Cotunnite-derived structured and crystallizes in the orthorhombic Pnma space group. Li(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent N(1) atoms. Mn(1) is bonded to four equivalent N(1) atoms to form a mixture of distorted edge and corner-sharing MnN4 tetrahedra. N(1) is bonded to three equivalent Li(1) and four equivalent Mn(1) atoms to form a mixture of distorted edge and corner-sharing NLi3Mn4 hexagonal pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiMnN
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.788
_cell_length_b   3.147
_cell_length_c   4.966
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   106.098
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.604  0.250  0.896  1.0
  Li  Li1  1  0.104  0.250  0.604  1.0
  Li  Li2  1  0.396  0.750  0.104  1.0
  Li  Li3  1  0.896  0.750  0.396  1.0
  Mn  Mn4  1  0.626  0.250  0.415  1.0
  Mn  Mn5  1  0.126  0.250  0.085  1.0
  Mn  Mn6  1  0.374  0.750  0.585  1.0
  Mn  Mn7  1  0.874  0.750  0.915  1.0
  N  N8  1  0.844  0.250  0.146  1.0
  N  N9  1  0.344  0.250  0.354  1.0
  N  N10  1  0.156  0.750  0.854  1.0
  N  N11  1  0.656  0.750  0.646  1.0
[/CIF]
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