The structure described by WSCl4 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight WSCl4 clusters. W(1) is bonded in a distorted trigonal bipyramidal geometry to one S(1), one Cl(1), one Cl(2), one Cl(4), and one Cl(6) atom. S(1) is bonded in a single-bond geometry to one W(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one W(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one W(1) atom. In the third Cl site, Cl(4) is bonded in a single-bond geometry to one W(1) atom. In the fourth Cl site, Cl(6) is bonded in a single-bond geometry to one W(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_WSCl4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.638
_cell_length_b   9.606
_cell_length_c   13.452
_cell_angle_alpha   68.215
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1636.403
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  W  W0  1  0.913  0.629  0.662  1.0
  W  W1  1  0.413  0.371  0.838  1.0
  W  W2  1  0.360  0.956  0.416  1.0
  W  W3  1  0.640  0.044  0.584  1.0
  W  W4  1  0.087  0.371  0.338  1.0
  W  W5  1  0.140  0.956  0.916  1.0
  W  W6  1  0.587  0.629  0.162  1.0
  W  W7  1  0.860  0.044  0.084  1.0
  S  S8  1  0.539  0.494  0.768  1.0
  S  S9  1  0.786  0.011  0.228  1.0
  S  S10  1  0.039  0.506  0.732  1.0
  S  S11  1  0.214  0.989  0.772  1.0
  S  S12  1  0.461  0.506  0.232  1.0
  S  S13  1  0.286  0.989  0.272  1.0
  S  S14  1  0.714  0.011  0.728  1.0
  S  S15  1  0.961  0.494  0.268  1.0
  Cl  Cl16  1  0.048  0.130  0.354  1.0
  Cl  Cl17  1  0.058  0.293  0.519  1.0
  Cl  Cl18  1  0.556  0.264  0.550  1.0
  Cl  Cl19  1  0.952  0.870  0.646  1.0
  Cl  Cl20  1  0.944  0.264  0.050  1.0
  Cl  Cl21  1  0.309  0.547  0.858  1.0
  Cl  Cl22  1  0.442  0.293  0.019  1.0
  Cl  Cl23  1  0.508  0.080  0.355  1.0
  Cl  Cl24  1  0.558  0.707  0.981  1.0
  Cl  Cl25  1  0.818  0.616  0.807  1.0
  Cl  Cl26  1  0.749  0.177  0.956  1.0
  Cl  Cl27  1  0.318  0.384  0.693  1.0
  Cl  Cl28  1  0.191  0.547  0.358  1.0
  Cl  Cl29  1  0.684  0.837  0.546  1.0
  Cl  Cl30  1  0.682  0.616  0.307  1.0
  Cl  Cl31  1  0.444  0.736  0.450  1.0
  Cl  Cl32  1  0.251  0.823  0.044  1.0
  Cl  Cl33  1  0.249  0.823  0.544  1.0
  Cl  Cl34  1  0.816  0.837  0.046  1.0
  Cl  Cl35  1  0.452  0.130  0.854  1.0
  Cl  Cl36  1  0.056  0.736  0.950  1.0
  Cl  Cl37  1  0.992  0.080  0.855  1.0
  Cl  Cl38  1  0.691  0.453  0.142  1.0
  Cl  Cl39  1  0.492  0.920  0.645  1.0
  Cl  Cl40  1  0.548  0.870  0.146  1.0
  Cl  Cl41  1  0.751  0.177  0.456  1.0
  Cl  Cl42  1  0.184  0.163  0.954  1.0
  Cl  Cl43  1  0.316  0.163  0.454  1.0
  Cl  Cl44  1  0.182  0.384  0.193  1.0
  Cl  Cl45  1  0.942  0.707  0.481  1.0
  Cl  Cl46  1  0.008  0.920  0.145  1.0
  Cl  Cl47  1  0.809  0.453  0.642  1.0
[/CIF]
.
The structure described by WSCl4 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight WSCl4 clusters. W(1) is bonded in a distorted trigonal bipyramidal geometry to one S(1), one Cl(1), one Cl(2), one Cl(4), and one Cl(6) atom. S(1) is bonded in a single-bond geometry to one W(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one W(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one W(1) atom. In the third Cl site, Cl(4) is bonded in a single-bond geometry to one W(1) atom. In the fourth Cl site, Cl(6) is bonded in a single-bond geometry to one W(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_WSCl4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.638
_cell_length_b   9.606
_cell_length_c   13.452
_cell_angle_alpha   68.215
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1636.403
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  W  W0  1  0.913  0.629  0.662  1.0
  W  W1  1  0.413  0.371  0.838  1.0
  W  W2  1  0.360  0.956  0.416  1.0
  W  W3  1  0.640  0.044  0.584  1.0
  W  W4  1  0.087  0.371  0.338  1.0
  W  W5  1  0.140  0.956  0.916  1.0
  W  W6  1  0.587  0.629  0.162  1.0
  W  W7  1  0.860  0.044  0.084  1.0
  S  S8  1  0.539  0.494  0.768  1.0
  S  S9  1  0.786  0.011  0.228  1.0
  S  S10  1  0.039  0.506  0.732  1.0
  S  S11  1  0.214  0.989  0.772  1.0
  S  S12  1  0.461  0.506  0.232  1.0
  S  S13  1  0.286  0.989  0.272  1.0
  S  S14  1  0.714  0.011  0.728  1.0
  S  S15  1  0.961  0.494  0.268  1.0
  Cl  Cl16  1  0.048  0.130  0.354  1.0
  Cl  Cl17  1  0.058  0.293  0.519  1.0
  Cl  Cl18  1  0.556  0.264  0.550  1.0
  Cl  Cl19  1  0.952  0.870  0.646  1.0
  Cl  Cl20  1  0.944  0.264  0.050  1.0
  Cl  Cl21  1  0.309  0.547  0.858  1.0
  Cl  Cl22  1  0.442  0.293  0.019  1.0
  Cl  Cl23  1  0.508  0.080  0.355  1.0
  Cl  Cl24  1  0.558  0.707  0.981  1.0
  Cl  Cl25  1  0.818  0.616  0.807  1.0
  Cl  Cl26  1  0.749  0.177  0.956  1.0
  Cl  Cl27  1  0.318  0.384  0.693  1.0
  Cl  Cl28  1  0.191  0.547  0.358  1.0
  Cl  Cl29  1  0.684  0.837  0.546  1.0
  Cl  Cl30  1  0.682  0.616  0.307  1.0
  Cl  Cl31  1  0.444  0.736  0.450  1.0
  Cl  Cl32  1  0.251  0.823  0.044  1.0
  Cl  Cl33  1  0.249  0.823  0.544  1.0
  Cl  Cl34  1  0.816  0.837  0.046  1.0
  Cl  Cl35  1  0.452  0.130  0.854  1.0
  Cl  Cl36  1  0.056  0.736  0.950  1.0
  Cl  Cl37  1  0.992  0.080  0.855  1.0
  Cl  Cl38  1  0.691  0.453  0.142  1.0
  Cl  Cl39  1  0.492  0.920  0.645  1.0
  Cl  Cl40  1  0.548  0.870  0.146  1.0
  Cl  Cl41  1  0.751  0.177  0.456  1.0
  Cl  Cl42  1  0.184  0.163  0.954  1.0
  Cl  Cl43  1  0.316  0.163  0.454  1.0
  Cl  Cl44  1  0.182  0.384  0.193  1.0
  Cl  Cl45  1  0.942  0.707  0.481  1.0
  Cl  Cl46  1  0.008  0.920  0.145  1.0
  Cl  Cl47  1  0.809  0.453  0.642  1.0
[/CIF]
.