The structure described by VCd2BiO6 crystallizes in the orthorhombic Cmc2_1 space group. V(1) is bonded to one O(3), one O(4), and two equivalent O(1) atoms to form VO4 tetrahedra that share corners with eight equivalent Cd(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-70°. Cd(1) is bonded to one O(3), one O(4), two equivalent O(1), and two equivalent O(2) atoms to form distorted CdO6 octahedra that share corners with four equivalent Cd(1)O6 octahedra, corners with four equivalent V(1)O4 tetrahedra, and  an edgeedge with one Cd(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-65°. Bi(1) is bonded in a 5-coordinate geometry to one O(3) and four equivalent O(2) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(1) and two equivalent Cd(1) atoms. In the second O site, O(2) is bonded to two equivalent Cd(1) and two equivalent Bi(1) atoms to form a mixture of corner and edge-sharing OCd2Bi2 tetrahedra. In the third O site, O(3) is bonded in a 4-coordinate geometry to one V(1), two equivalent Cd(1), and one Bi(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one V(1) and two equivalent Cd(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_VCd2BiO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.284
_cell_length_b   7.284
_cell_length_c   5.739
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   104.706
_symmetry_Int_Tables_number   1
_cell_volume   294.543
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.836  0.164  0.481  1.0
  V  V1  1  0.164  0.836  0.981  1.0
  Cd  Cd2  1  0.092  0.320  0.983  1.0
  Cd  Cd3  1  0.908  0.680  0.483  1.0
  Cd  Cd4  1  0.320  0.092  0.483  1.0
  Cd  Cd5  1  0.680  0.908  0.983  1.0
  Bi  Bi6  1  0.595  0.405  0.977  1.0
  Bi  Bi7  1  0.405  0.595  0.477  1.0
  O  O8  1  0.938  0.379  0.624  1.0
  O  O9  1  0.062  0.621  0.124  1.0
  O  O10  1  0.379  0.938  0.124  1.0
  O  O11  1  0.621  0.062  0.624  1.0
  O  O12  1  0.343  0.348  0.728  1.0
  O  O13  1  0.657  0.652  0.228  1.0
  O  O14  1  0.348  0.343  0.228  1.0
  O  O15  1  0.652  0.657  0.728  1.0
  O  O16  1  0.794  0.206  0.184  1.0
  O  O17  1  0.206  0.794  0.684  1.0
  O  O18  1  0.985  0.015  0.477  1.0
  O  O19  1  0.015  0.985  0.977  1.0
[/CIF]
.
The structure described by VCd2BiO6 crystallizes in the orthorhombic Cmc2_1 space group. V(1) is bonded to one O(3), one O(4), and two equivalent O(1) atoms to form VO4 tetrahedra that share corners with eight equivalent Cd(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-70°. Cd(1) is bonded to one O(3), one O(4), two equivalent O(1), and two equivalent O(2) atoms to form distorted CdO6 octahedra that share corners with four equivalent Cd(1)O6 octahedra, corners with four equivalent V(1)O4 tetrahedra, and  an edgeedge with one Cd(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-65°. Bi(1) is bonded in a 5-coordinate geometry to one O(3) and four equivalent O(2) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(1) and two equivalent Cd(1) atoms. In the second O site, O(2) is bonded to two equivalent Cd(1) and two equivalent Bi(1) atoms to form a mixture of corner and edge-sharing OCd2Bi2 tetrahedra. In the third O site, O(3) is bonded in a 4-coordinate geometry to one V(1), two equivalent Cd(1), and one Bi(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one V(1) and two equivalent Cd(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_VCd2BiO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.284
_cell_length_b   7.284
_cell_length_c   5.739
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   104.706
_symmetry_Int_Tables_number   1
_cell_volume   294.543
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.836  0.164  0.481  1.0
  V  V1  1  0.164  0.836  0.981  1.0
  Cd  Cd2  1  0.092  0.320  0.983  1.0
  Cd  Cd3  1  0.908  0.680  0.483  1.0
  Cd  Cd4  1  0.320  0.092  0.483  1.0
  Cd  Cd5  1  0.680  0.908  0.983  1.0
  Bi  Bi6  1  0.595  0.405  0.977  1.0
  Bi  Bi7  1  0.405  0.595  0.477  1.0
  O  O8  1  0.938  0.379  0.624  1.0
  O  O9  1  0.062  0.621  0.124  1.0
  O  O10  1  0.379  0.938  0.124  1.0
  O  O11  1  0.621  0.062  0.624  1.0
  O  O12  1  0.343  0.348  0.728  1.0
  O  O13  1  0.657  0.652  0.228  1.0
  O  O14  1  0.348  0.343  0.228  1.0
  O  O15  1  0.652  0.657  0.728  1.0
  O  O16  1  0.794  0.206  0.184  1.0
  O  O17  1  0.206  0.794  0.684  1.0
  O  O18  1  0.985  0.015  0.477  1.0
  O  O19  1  0.015  0.985  0.977  1.0
[/CIF]
.