The crystal structure described by K2Pd3S4 crystallizes in the orthorhombic Fddd space group. K(1) is bonded in a 14-coordinate geometry to two equivalent Pd(2), four equivalent Pd(1), and eight equivalent S(1) atoms. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a distorted square co-planar geometry to four equivalent K(1) and four equivalent S(1) atoms. In the second Pd site, Pd(2) is bonded in a distorted square co-planar geometry to four equivalent K(1) and four equivalent S(1) atoms. S(1) is bonded in a 7-coordinate geometry to four equivalent K(1), one Pd(2), and two equivalent Pd(1) atoms. is represented by the CIF file [CIF]
data_K2Pd3S4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.108
_cell_length_b   6.177
_cell_length_c   13.268
_cell_angle_alpha   83.464
_cell_angle_beta   76.691
_cell_angle_gamma   60.366
_symmetry_Int_Tables_number   1
_cell_volume   423.464
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.547  0.750  0.906  1.0
  K  K1  1  0.297  0.250  0.406  1.0
  K  K2  1  0.453  0.250  0.094  1.0
  K  K3  1  0.703  0.750  0.594  1.0
  Pd  Pd4  1  0.374  0.750  0.252  1.0
  Pd  Pd5  1  0.124  0.250  0.752  1.0
  Pd  Pd6  1  0.626  0.250  0.748  1.0
  Pd  Pd7  1  0.125  0.750  0.750  1.0
  Pd  Pd8  1  0.875  0.250  0.250  1.0
  Pd  Pd9  1  0.876  0.750  0.248  1.0
  S  S10  1  0.893  0.082  0.870  1.0
  S  S11  1  0.763  0.582  0.130  1.0
  S  S12  1  0.975  0.918  0.370  1.0
  S  S13  1  0.655  0.582  0.370  1.0
  S  S14  1  0.345  0.418  0.630  1.0
  S  S15  1  0.025  0.082  0.630  1.0
  S  S16  1  0.237  0.418  0.870  1.0
  S  S17  1  0.107  0.918  0.130  1.0
[/CIF]
.
The crystal structure described by K2Pd3S4 crystallizes in the orthorhombic Fddd space group. K(1) is bonded in a 14-coordinate geometry to two equivalent Pd(2), four equivalent Pd(1), and eight equivalent S(1) atoms. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a distorted square co-planar geometry to four equivalent K(1) and four equivalent S(1) atoms. In the second Pd site, Pd(2) is bonded in a distorted square co-planar geometry to four equivalent K(1) and four equivalent S(1) atoms. S(1) is bonded in a 7-coordinate geometry to four equivalent K(1), one Pd(2), and two equivalent Pd(1) atoms. is represented by the CIF file [CIF]
data_K2Pd3S4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.108
_cell_length_b   6.177
_cell_length_c   13.268
_cell_angle_alpha   83.464
_cell_angle_beta   76.691
_cell_angle_gamma   60.366
_symmetry_Int_Tables_number   1
_cell_volume   423.464
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.547  0.750  0.906  1.0
  K  K1  1  0.297  0.250  0.406  1.0
  K  K2  1  0.453  0.250  0.094  1.0
  K  K3  1  0.703  0.750  0.594  1.0
  Pd  Pd4  1  0.374  0.750  0.252  1.0
  Pd  Pd5  1  0.124  0.250  0.752  1.0
  Pd  Pd6  1  0.626  0.250  0.748  1.0
  Pd  Pd7  1  0.125  0.750  0.750  1.0
  Pd  Pd8  1  0.875  0.250  0.250  1.0
  Pd  Pd9  1  0.876  0.750  0.248  1.0
  S  S10  1  0.893  0.082  0.870  1.0
  S  S11  1  0.763  0.582  0.130  1.0
  S  S12  1  0.975  0.918  0.370  1.0
  S  S13  1  0.655  0.582  0.370  1.0
  S  S14  1  0.345  0.418  0.630  1.0
  S  S15  1  0.025  0.082  0.630  1.0
  S  S16  1  0.237  0.418  0.870  1.0
  S  S17  1  0.107  0.918  0.130  1.0
[/CIF]
.