The structure described by SCl3ICl4 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four ICl4 clusters and four SCl3 clusters. In each ICl4 cluster, I(1) is bonded in a rectangular see-saw-like geometry to one Cl(1), one Cl(5), one Cl(6), and one Cl(7) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(7) is bonded in a single-bond geometry to one I(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one I(1) atom. In the third Cl site, Cl(5) is bonded in a single-bond geometry to one I(1) atom. In the fourth Cl site, Cl(6) is bonded in a single-bond geometry to one I(1) atom. In each SCl3 cluster, S(1) is bonded in a trigonal non-coplanar geometry to one Cl(2), one Cl(3), and one Cl(4) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one S(1) atom. In the second Cl site, Cl(4) is bonded in a single-bond geometry to one S(1) atom. In the third Cl site, Cl(2) is bonded in a single-bond geometry to one S(1) atom. is represented by the CIF card [CIF]
data_SICl7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.768
_cell_length_b   8.321
_cell_length_c   10.443
_cell_angle_alpha   71.921
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1054.800
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.918  0.761  0.139  1.0
  S  S1  1  0.582  0.261  0.139  1.0
  S  S2  1  0.082  0.239  0.861  1.0
  S  S3  1  0.418  0.739  0.861  1.0
  I  I4  1  0.602  0.342  0.729  1.0
  I  I5  1  0.102  0.158  0.271  1.0
  I  I6  1  0.398  0.658  0.271  1.0
  I  I7  1  0.898  0.842  0.729  1.0
  Cl  Cl8  1  0.725  0.418  0.896  1.0
  Cl  Cl9  1  0.775  0.918  0.896  1.0
  Cl  Cl10  1  0.275  0.582  0.104  1.0
  Cl  Cl11  1  0.225  0.082  0.104  1.0
  Cl  Cl12  1  0.894  0.541  0.103  1.0
  Cl  Cl13  1  0.394  0.959  0.897  1.0
  Cl  Cl14  1  0.106  0.459  0.897  1.0
  Cl  Cl15  1  0.606  0.041  0.103  1.0
  Cl  Cl16  1  0.809  0.747  0.280  1.0
  Cl  Cl17  1  0.309  0.753  0.720  1.0
  Cl  Cl18  1  0.191  0.253  0.720  1.0
  Cl  Cl19  1  0.691  0.247  0.280  1.0
  Cl  Cl20  1  0.049  0.712  0.249  1.0
  Cl  Cl21  1  0.549  0.788  0.751  1.0
  Cl  Cl22  1  0.951  0.288  0.751  1.0
  Cl  Cl23  1  0.451  0.212  0.249  1.0
  Cl  Cl24  1  0.053  0.859  0.887  1.0
  Cl  Cl25  1  0.553  0.641  0.113  1.0
  Cl  Cl26  1  0.947  0.141  0.113  1.0
  Cl  Cl27  1  0.447  0.359  0.887  1.0
  Cl  Cl28  1  0.749  0.831  0.582  1.0
  Cl  Cl29  1  0.249  0.669  0.418  1.0
  Cl  Cl30  1  0.251  0.169  0.418  1.0
  Cl  Cl31  1  0.751  0.331  0.582  1.0
  Cl  Cl32  1  0.023  0.765  0.578  1.0
  Cl  Cl33  1  0.523  0.735  0.422  1.0
  Cl  Cl34  1  0.977  0.235  0.422  1.0
  Cl  Cl35  1  0.477  0.265  0.578  1.0
[/CIF]
.
The structure described by SCl3ICl4 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four ICl4 clusters and four SCl3 clusters. In each ICl4 cluster, I(1) is bonded in a rectangular see-saw-like geometry to one Cl(1), one Cl(5), one Cl(6), and one Cl(7) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(7) is bonded in a single-bond geometry to one I(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one I(1) atom. In the third Cl site, Cl(5) is bonded in a single-bond geometry to one I(1) atom. In the fourth Cl site, Cl(6) is bonded in a single-bond geometry to one I(1) atom. In each SCl3 cluster, S(1) is bonded in a trigonal non-coplanar geometry to one Cl(2), one Cl(3), and one Cl(4) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one S(1) atom. In the second Cl site, Cl(4) is bonded in a single-bond geometry to one S(1) atom. In the third Cl site, Cl(2) is bonded in a single-bond geometry to one S(1) atom. is represented by the CIF card [CIF]
data_SICl7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.768
_cell_length_b   8.321
_cell_length_c   10.443
_cell_angle_alpha   71.921
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1054.800
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.918  0.761  0.139  1.0
  S  S1  1  0.582  0.261  0.139  1.0
  S  S2  1  0.082  0.239  0.861  1.0
  S  S3  1  0.418  0.739  0.861  1.0
  I  I4  1  0.602  0.342  0.729  1.0
  I  I5  1  0.102  0.158  0.271  1.0
  I  I6  1  0.398  0.658  0.271  1.0
  I  I7  1  0.898  0.842  0.729  1.0
  Cl  Cl8  1  0.725  0.418  0.896  1.0
  Cl  Cl9  1  0.775  0.918  0.896  1.0
  Cl  Cl10  1  0.275  0.582  0.104  1.0
  Cl  Cl11  1  0.225  0.082  0.104  1.0
  Cl  Cl12  1  0.894  0.541  0.103  1.0
  Cl  Cl13  1  0.394  0.959  0.897  1.0
  Cl  Cl14  1  0.106  0.459  0.897  1.0
  Cl  Cl15  1  0.606  0.041  0.103  1.0
  Cl  Cl16  1  0.809  0.747  0.280  1.0
  Cl  Cl17  1  0.309  0.753  0.720  1.0
  Cl  Cl18  1  0.191  0.253  0.720  1.0
  Cl  Cl19  1  0.691  0.247  0.280  1.0
  Cl  Cl20  1  0.049  0.712  0.249  1.0
  Cl  Cl21  1  0.549  0.788  0.751  1.0
  Cl  Cl22  1  0.951  0.288  0.751  1.0
  Cl  Cl23  1  0.451  0.212  0.249  1.0
  Cl  Cl24  1  0.053  0.859  0.887  1.0
  Cl  Cl25  1  0.553  0.641  0.113  1.0
  Cl  Cl26  1  0.947  0.141  0.113  1.0
  Cl  Cl27  1  0.447  0.359  0.887  1.0
  Cl  Cl28  1  0.749  0.831  0.582  1.0
  Cl  Cl29  1  0.249  0.669  0.418  1.0
  Cl  Cl30  1  0.251  0.169  0.418  1.0
  Cl  Cl31  1  0.751  0.331  0.582  1.0
  Cl  Cl32  1  0.023  0.765  0.578  1.0
  Cl  Cl33  1  0.523  0.735  0.422  1.0
  Cl  Cl34  1  0.977  0.235  0.422  1.0
  Cl  Cl35  1  0.477  0.265  0.578  1.0
[/CIF]
.