The material described by (Xe)2Sb4F19 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 7440-63-3 atoms and two Sb4F19 clusters. In each Sb4F19 cluster, there are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom to form SbF6 octahedra that share  a cornercorner with one Sb(1)F6 octahedra and  a cornercorner with one Sb(2)F5 trigonal bipyramid. The corner-sharing octahedra are not tilted. In the second Sb site, Sb(2) is bonded to one F(10), one F(6), one F(7), one F(8), and one F(9) atom to form distorted corner-sharing SbF5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 35°. There are ten inequivalent F sites. In the first F site, F(7) is bonded in a single-bond geometry to one Sb(2) atom. In the second F site, F(8) is bonded in a single-bond geometry to one Sb(2) atom. In the third F site, F(9) is bonded in a single-bond geometry to one Sb(2) atom. In the fourth F site, F(1) is bonded in a linear geometry to two equivalent Sb(1) atoms. In the fifth F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(10) is bonded in a single-bond geometry to one Sb(2) atom. In the seventh F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the eighth F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the ninth F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom. In the tenth F site, F(6) is bonded in a bent 150 degrees geometry to one Sb(1) and one Sb(2) atom. is represented by the CIF card [CIF]
data_Sb4Xe2F19
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.930
_cell_length_b   10.952
_cell_length_c   15.921
_cell_angle_alpha   50.146
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1195.329
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.582  0.188  0.845  1.0
  Sb  Sb1  1  0.918  0.188  0.345  1.0
  Sb  Sb2  1  0.418  0.812  0.155  1.0
  Sb  Sb3  1  0.082  0.812  0.655  1.0
  Sb  Sb4  1  0.903  0.234  0.003  1.0
  Sb  Sb5  1  0.597  0.234  0.503  1.0
  Sb  Sb6  1  0.097  0.766  0.997  1.0
  Sb  Sb7  1  0.403  0.766  0.497  1.0
  Xe  Xe8  1  0.421  0.311  0.149  1.0
  Xe  Xe9  1  0.079  0.311  0.649  1.0
  Xe  Xe10  1  0.579  0.689  0.851  1.0
  Xe  Xe11  1  0.921  0.689  0.351  1.0
  F  F12  1  0.500  0.000  0.000  1.0
  F  F13  1  0.000  0.000  0.500  1.0
  F  F14  1  0.521  0.315  0.880  1.0
  F  F15  1  0.979  0.315  0.380  1.0
  F  F16  1  0.479  0.685  0.120  1.0
  F  F17  1  0.021  0.685  0.620  1.0
  F  F18  1  0.671  0.356  0.711  1.0
  F  F19  1  0.829  0.356  0.211  1.0
  F  F20  1  0.329  0.644  0.289  1.0
  F  F21  1  0.171  0.644  0.789  1.0
  F  F22  1  0.393  0.189  0.792  1.0
  F  F23  1  0.107  0.189  0.292  1.0
  F  F24  1  0.607  0.811  0.208  1.0
  F  F25  1  0.893  0.811  0.708  1.0
  F  F26  1  0.658  0.027  0.845  1.0
  F  F27  1  0.842  0.027  0.345  1.0
  F  F28  1  0.342  0.973  0.155  1.0
  F  F29  1  0.158  0.973  0.655  1.0
  F  F30  1  0.773  0.152  0.930  1.0
  F  F31  1  0.727  0.152  0.430  1.0
  F  F32  1  0.227  0.848  0.070  1.0
  F  F33  1  0.273  0.848  0.570  1.0
  F  F34  1  0.886  0.436  0.858  1.0
  F  F35  1  0.614  0.436  0.358  1.0
  F  F36  1  0.114  0.564  0.142  1.0
  F  F37  1  0.386  0.564  0.642  1.0
  F  F38  1  0.976  0.019  0.097  1.0
  F  F39  1  0.524  0.019  0.597  1.0
  F  F40  1  0.024  0.981  0.903  1.0
  F  F41  1  0.476  0.981  0.403  1.0
  F  F42  1  0.734  0.223  0.079  1.0
  F  F43  1  0.766  0.223  0.579  1.0
  F  F44  1  0.266  0.777  0.921  1.0
  F  F45  1  0.234  0.777  0.421  1.0
  F  F46  1  0.053  0.306  0.047  1.0
  F  F47  1  0.447  0.306  0.547  1.0
  F  F48  1  0.947  0.694  0.953  1.0
  F  F49  1  0.553  0.694  0.453  1.0
[/CIF]
.
The material described by (Xe)2Sb4F19 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 7440-63-3 atoms and two Sb4F19 clusters. In each Sb4F19 cluster, there are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom to form SbF6 octahedra that share  a cornercorner with one Sb(1)F6 octahedra and  a cornercorner with one Sb(2)F5 trigonal bipyramid. The corner-sharing octahedra are not tilted. In the second Sb site, Sb(2) is bonded to one F(10), one F(6), one F(7), one F(8), and one F(9) atom to form distorted corner-sharing SbF5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 35°. There are ten inequivalent F sites. In the first F site, F(7) is bonded in a single-bond geometry to one Sb(2) atom. In the second F site, F(8) is bonded in a single-bond geometry to one Sb(2) atom. In the third F site, F(9) is bonded in a single-bond geometry to one Sb(2) atom. In the fourth F site, F(1) is bonded in a linear geometry to two equivalent Sb(1) atoms. In the fifth F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(10) is bonded in a single-bond geometry to one Sb(2) atom. In the seventh F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the eighth F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the ninth F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom. In the tenth F site, F(6) is bonded in a bent 150 degrees geometry to one Sb(1) and one Sb(2) atom. is represented by the CIF card [CIF]
data_Sb4Xe2F19
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.930
_cell_length_b   10.952
_cell_length_c   15.921
_cell_angle_alpha   50.146
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1195.329
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.582  0.188  0.845  1.0
  Sb  Sb1  1  0.918  0.188  0.345  1.0
  Sb  Sb2  1  0.418  0.812  0.155  1.0
  Sb  Sb3  1  0.082  0.812  0.655  1.0
  Sb  Sb4  1  0.903  0.234  0.003  1.0
  Sb  Sb5  1  0.597  0.234  0.503  1.0
  Sb  Sb6  1  0.097  0.766  0.997  1.0
  Sb  Sb7  1  0.403  0.766  0.497  1.0
  Xe  Xe8  1  0.421  0.311  0.149  1.0
  Xe  Xe9  1  0.079  0.311  0.649  1.0
  Xe  Xe10  1  0.579  0.689  0.851  1.0
  Xe  Xe11  1  0.921  0.689  0.351  1.0
  F  F12  1  0.500  0.000  0.000  1.0
  F  F13  1  0.000  0.000  0.500  1.0
  F  F14  1  0.521  0.315  0.880  1.0
  F  F15  1  0.979  0.315  0.380  1.0
  F  F16  1  0.479  0.685  0.120  1.0
  F  F17  1  0.021  0.685  0.620  1.0
  F  F18  1  0.671  0.356  0.711  1.0
  F  F19  1  0.829  0.356  0.211  1.0
  F  F20  1  0.329  0.644  0.289  1.0
  F  F21  1  0.171  0.644  0.789  1.0
  F  F22  1  0.393  0.189  0.792  1.0
  F  F23  1  0.107  0.189  0.292  1.0
  F  F24  1  0.607  0.811  0.208  1.0
  F  F25  1  0.893  0.811  0.708  1.0
  F  F26  1  0.658  0.027  0.845  1.0
  F  F27  1  0.842  0.027  0.345  1.0
  F  F28  1  0.342  0.973  0.155  1.0
  F  F29  1  0.158  0.973  0.655  1.0
  F  F30  1  0.773  0.152  0.930  1.0
  F  F31  1  0.727  0.152  0.430  1.0
  F  F32  1  0.227  0.848  0.070  1.0
  F  F33  1  0.273  0.848  0.570  1.0
  F  F34  1  0.886  0.436  0.858  1.0
  F  F35  1  0.614  0.436  0.358  1.0
  F  F36  1  0.114  0.564  0.142  1.0
  F  F37  1  0.386  0.564  0.642  1.0
  F  F38  1  0.976  0.019  0.097  1.0
  F  F39  1  0.524  0.019  0.597  1.0
  F  F40  1  0.024  0.981  0.903  1.0
  F  F41  1  0.476  0.981  0.403  1.0
  F  F42  1  0.734  0.223  0.079  1.0
  F  F43  1  0.766  0.223  0.579  1.0
  F  F44  1  0.266  0.777  0.921  1.0
  F  F45  1  0.234  0.777  0.421  1.0
  F  F46  1  0.053  0.306  0.047  1.0
  F  F47  1  0.447  0.306  0.547  1.0
  F  F48  1  0.947  0.694  0.953  1.0
  F  F49  1  0.553  0.694  0.453  1.0
[/CIF]
.