The material described by MgSbOF3 crystallizes in the monoclinic Cm space group. Mg(1) is bonded to one O(1), one F(1), one F(2), and two equivalent F(3) atoms to form distorted corner-sharing MgOF4 trigonal bipyramids. Sb(1) is bonded in a 5-coordinate geometry to two equivalent O(1), one F(1), one F(2), and one F(3) atom. O(1) is bonded in a trigonal non-coplanar geometry to one Mg(1) and two equivalent Sb(1) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted bent 120 degrees geometry to one Mg(1) and one Sb(1) atom. In the second F site, F(2) is bonded in a bent 120 degrees geometry to one Mg(1) and one Sb(1) atom. In the third F site, F(3) is bonded in a distorted T-shaped geometry to two equivalent Mg(1) and one Sb(1) atom. is represented by the CIF card [CIF]
data_MgSbOF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.860
_cell_length_b   6.576
_cell_length_c   4.615
_cell_angle_alpha   60.779
_cell_angle_beta   90.003
_cell_angle_gamma   107.064
_symmetry_Int_Tables_number   1
_cell_volume   96.301
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.747  0.495  0.828  1.0
  Sb  Sb1  1  0.009  0.018  0.957  1.0
  O  O2  1  0.562  0.125  0.019  1.0
  F  F3  1  0.797  0.595  0.170  1.0
  F  F4  1  0.925  0.851  0.472  1.0
  F  F5  1  0.227  0.454  0.788  1.0
[/CIF]
.
The material described by MgSbOF3 crystallizes in the monoclinic Cm space group. Mg(1) is bonded to one O(1), one F(1), one F(2), and two equivalent F(3) atoms to form distorted corner-sharing MgOF4 trigonal bipyramids. Sb(1) is bonded in a 5-coordinate geometry to two equivalent O(1), one F(1), one F(2), and one F(3) atom. O(1) is bonded in a trigonal non-coplanar geometry to one Mg(1) and two equivalent Sb(1) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted bent 120 degrees geometry to one Mg(1) and one Sb(1) atom. In the second F site, F(2) is bonded in a bent 120 degrees geometry to one Mg(1) and one Sb(1) atom. In the third F site, F(3) is bonded in a distorted T-shaped geometry to two equivalent Mg(1) and one Sb(1) atom. is represented by the CIF card [CIF]
data_MgSbOF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.860
_cell_length_b   6.576
_cell_length_c   4.615
_cell_angle_alpha   60.779
_cell_angle_beta   90.003
_cell_angle_gamma   107.064
_symmetry_Int_Tables_number   1
_cell_volume   96.301
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.747  0.495  0.828  1.0
  Sb  Sb1  1  0.009  0.018  0.957  1.0
  O  O2  1  0.562  0.125  0.019  1.0
  F  F3  1  0.797  0.595  0.170  1.0
  F  F4  1  0.925  0.851  0.472  1.0
  F  F5  1  0.227  0.454  0.788  1.0
[/CIF]
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