The crystal structure described by Cs2NbAgS4 crystallizes in the orthorhombic Fddd space group. Cs(1) is bonded in a 8-coordinate geometry to eight equivalent S(1) atoms. Nb(1) is bonded to four equivalent S(1) atoms to form NbS4 tetrahedra that share edges with two equivalent Ag(1)S4 tetrahedra. Ag(1) is bonded to four equivalent S(1) atoms to form distorted AgS4 tetrahedra that share edges with two equivalent Nb(1)S4 tetrahedra. S(1) is bonded in a 6-coordinate geometry to four equivalent Cs(1), one Nb(1), and one Ag(1) atom. is represented by the CIF file [CIF]
data_Cs2NbAgS4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   14.532
_cell_length_b   12.942
_cell_length_c   7.851
_cell_angle_alpha   84.925
_cell_angle_beta   62.516
_cell_angle_gamma   32.559
_symmetry_Int_Tables_number   1
_cell_volume   547.814
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.821  0.821  0.179  1.0
  Cs  Cs1  1  0.179  0.179  0.821  1.0
  Cs  Cs2  1  0.429  0.429  0.071  1.0
  Cs  Cs3  1  0.071  0.071  0.429  1.0
  Nb  Nb4  1  0.250  0.250  0.250  1.0
  Nb  Nb5  1  0.000  0.000  0.000  1.0
  Ag  Ag6  1  0.500  0.500  0.500  1.0
  Ag  Ag7  1  0.750  0.750  0.750  1.0
  S  S8  1  0.744  0.363  0.067  1.0
  S  S9  1  0.424  0.183  0.887  1.0
  S  S10  1  0.887  0.506  0.424  1.0
  S  S11  1  0.183  0.424  0.506  1.0
  S  S12  1  0.067  0.826  0.744  1.0
  S  S13  1  0.363  0.744  0.826  1.0
  S  S14  1  0.506  0.887  0.183  1.0
  S  S15  1  0.826  0.067  0.363  1.0
[/CIF]
.
The crystal structure described by Cs2NbAgS4 crystallizes in the orthorhombic Fddd space group. Cs(1) is bonded in a 8-coordinate geometry to eight equivalent S(1) atoms. Nb(1) is bonded to four equivalent S(1) atoms to form NbS4 tetrahedra that share edges with two equivalent Ag(1)S4 tetrahedra. Ag(1) is bonded to four equivalent S(1) atoms to form distorted AgS4 tetrahedra that share edges with two equivalent Nb(1)S4 tetrahedra. S(1) is bonded in a 6-coordinate geometry to four equivalent Cs(1), one Nb(1), and one Ag(1) atom. is represented by the CIF file [CIF]
data_Cs2NbAgS4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   14.532
_cell_length_b   12.942
_cell_length_c   7.851
_cell_angle_alpha   84.925
_cell_angle_beta   62.516
_cell_angle_gamma   32.559
_symmetry_Int_Tables_number   1
_cell_volume   547.814
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.821  0.821  0.179  1.0
  Cs  Cs1  1  0.179  0.179  0.821  1.0
  Cs  Cs2  1  0.429  0.429  0.071  1.0
  Cs  Cs3  1  0.071  0.071  0.429  1.0
  Nb  Nb4  1  0.250  0.250  0.250  1.0
  Nb  Nb5  1  0.000  0.000  0.000  1.0
  Ag  Ag6  1  0.500  0.500  0.500  1.0
  Ag  Ag7  1  0.750  0.750  0.750  1.0
  S  S8  1  0.744  0.363  0.067  1.0
  S  S9  1  0.424  0.183  0.887  1.0
  S  S10  1  0.887  0.506  0.424  1.0
  S  S11  1  0.183  0.424  0.506  1.0
  S  S12  1  0.067  0.826  0.744  1.0
  S  S13  1  0.363  0.744  0.826  1.0
  S  S14  1  0.506  0.887  0.183  1.0
  S  S15  1  0.826  0.067  0.363  1.0
[/CIF]
.