The structure described by RbLi2CdC2O6F crystallizes in the hexagonal P6_3/m space group. Rb(1) is bonded in a 9-coordinate geometry to six equivalent O(1) and three equivalent F(1) atoms. Li(1) is bonded to three equivalent O(1) and one F(1) atom to form LiO3F tetrahedra that share corners with three equivalent Cd(1)O6 octahedra and  a cornercorner with one Li(1)O3F tetrahedra. The corner-sharing octahedral tilt angles are 71°. Cd(1) is bonded to six equivalent O(1) atoms to form CdO6 octahedra that share corners with six equivalent Li(1)O3F tetrahedra. C(1) is bonded in a trigonal planar geometry to three equivalent O(1) atoms. O(1) is bonded in a 3-coordinate geometry to one Rb(1), one Li(1), one Cd(1), and one C(1) atom. F(1) is bonded in a distorted linear geometry to three equivalent Rb(1) and two equivalent Li(1) atoms. is represented by the CIF card [CIF]
data_RbLi2CdC2O6F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.988
_cell_length_b   4.988
_cell_length_c   15.624
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   336.706
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.000  0.000  0.750  1.0
  Rb  Rb1  1  0.000  0.000  0.250  1.0
  Li  Li2  1  0.333  0.667  0.630  1.0
  Li  Li3  1  0.667  0.333  0.130  1.0
  Li  Li4  1  0.667  0.333  0.370  1.0
  Li  Li5  1  0.333  0.667  0.870  1.0
  Cd  Cd6  1  0.000  0.000  0.500  1.0
  Cd  Cd7  1  0.000  0.000  0.000  1.0
  C  C8  1  0.667  0.333  0.590  1.0
  C  C9  1  0.333  0.667  0.090  1.0
  C  C10  1  0.333  0.667  0.410  1.0
  C  C11  1  0.667  0.333  0.910  1.0
  O  O12  1  0.667  0.594  0.591  1.0
  O  O13  1  0.406  0.072  0.591  1.0
  O  O14  1  0.928  0.333  0.591  1.0
  O  O15  1  0.333  0.406  0.091  1.0
  O  O16  1  0.594  0.928  0.091  1.0
  O  O17  1  0.072  0.667  0.091  1.0
  O  O18  1  0.333  0.406  0.409  1.0
  O  O19  1  0.594  0.928  0.409  1.0
  O  O20  1  0.072  0.667  0.409  1.0
  O  O21  1  0.667  0.594  0.909  1.0
  O  O22  1  0.406  0.072  0.909  1.0
  O  O23  1  0.928  0.333  0.909  1.0
  F  F24  1  0.333  0.667  0.750  1.0
  F  F25  1  0.667  0.333  0.250  1.0
[/CIF]
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The structure described by RbLi2CdC2O6F crystallizes in the hexagonal P6_3/m space group. Rb(1) is bonded in a 9-coordinate geometry to six equivalent O(1) and three equivalent F(1) atoms. Li(1) is bonded to three equivalent O(1) and one F(1) atom to form LiO3F tetrahedra that share corners with three equivalent Cd(1)O6 octahedra and  a cornercorner with one Li(1)O3F tetrahedra. The corner-sharing octahedral tilt angles are 71°. Cd(1) is bonded to six equivalent O(1) atoms to form CdO6 octahedra that share corners with six equivalent Li(1)O3F tetrahedra. C(1) is bonded in a trigonal planar geometry to three equivalent O(1) atoms. O(1) is bonded in a 3-coordinate geometry to one Rb(1), one Li(1), one Cd(1), and one C(1) atom. F(1) is bonded in a distorted linear geometry to three equivalent Rb(1) and two equivalent Li(1) atoms. is represented by the CIF card [CIF]
data_RbLi2CdC2O6F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.988
_cell_length_b   4.988
_cell_length_c   15.624
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   336.706
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.000  0.000  0.750  1.0
  Rb  Rb1  1  0.000  0.000  0.250  1.0
  Li  Li2  1  0.333  0.667  0.630  1.0
  Li  Li3  1  0.667  0.333  0.130  1.0
  Li  Li4  1  0.667  0.333  0.370  1.0
  Li  Li5  1  0.333  0.667  0.870  1.0
  Cd  Cd6  1  0.000  0.000  0.500  1.0
  Cd  Cd7  1  0.000  0.000  0.000  1.0
  C  C8  1  0.667  0.333  0.590  1.0
  C  C9  1  0.333  0.667  0.090  1.0
  C  C10  1  0.333  0.667  0.410  1.0
  C  C11  1  0.667  0.333  0.910  1.0
  O  O12  1  0.667  0.594  0.591  1.0
  O  O13  1  0.406  0.072  0.591  1.0
  O  O14  1  0.928  0.333  0.591  1.0
  O  O15  1  0.333  0.406  0.091  1.0
  O  O16  1  0.594  0.928  0.091  1.0
  O  O17  1  0.072  0.667  0.091  1.0
  O  O18  1  0.333  0.406  0.409  1.0
  O  O19  1  0.594  0.928  0.409  1.0
  O  O20  1  0.072  0.667  0.409  1.0
  O  O21  1  0.667  0.594  0.909  1.0
  O  O22  1  0.406  0.072  0.909  1.0
  O  O23  1  0.928  0.333  0.909  1.0
  F  F24  1  0.333  0.667  0.750  1.0
  F  F25  1  0.667  0.333  0.250  1.0
[/CIF]
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