The crystal structure described by Rb2Pt3S4 crystallizes in the orthorhombic Fmmm space group. Rb(1) is bonded in a 14-coordinate geometry to two equivalent Pt(2), four equivalent Pt(1), and eight equivalent S(1) atoms. There are two inequivalent Pt sites. In the first Pt site, Pt(1) is bonded in a distorted square co-planar geometry to four equivalent Rb(1) and four equivalent S(1) atoms. In the second Pt site, Pt(2) is bonded in a distorted square co-planar geometry to four equivalent Rb(1) and four equivalent S(1) atoms. S(1) is bonded in a 7-coordinate geometry to four equivalent Rb(1), one Pt(2), and two equivalent Pt(1) atoms. is represented by the CIF card [CIF]
data_Rb2Pt3S4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.334
_cell_length_b   6.334
_cell_length_c   7.260
_cell_angle_alpha   102.932
_cell_angle_beta   102.932
_cell_angle_gamma   119.139
_symmetry_Int_Tables_number   1
_cell_volume   228.213
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.349  0.349  0.697  1.0
  Rb  Rb1  1  0.651  0.651  0.303  1.0
  Pt  Pt2  1  0.000  0.500  0.000  1.0
  Pt  Pt3  1  0.500  0.000  0.000  1.0
  Pt  Pt4  1  0.000  0.000  0.000  1.0
  S  S5  1  0.719  0.054  0.773  1.0
  S  S6  1  0.281  0.946  0.227  1.0
  S  S7  1  0.946  0.281  0.227  1.0
  S  S8  1  0.054  0.719  0.773  1.0
[/CIF]
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The crystal structure described by Rb2Pt3S4 crystallizes in the orthorhombic Fmmm space group. Rb(1) is bonded in a 14-coordinate geometry to two equivalent Pt(2), four equivalent Pt(1), and eight equivalent S(1) atoms. There are two inequivalent Pt sites. In the first Pt site, Pt(1) is bonded in a distorted square co-planar geometry to four equivalent Rb(1) and four equivalent S(1) atoms. In the second Pt site, Pt(2) is bonded in a distorted square co-planar geometry to four equivalent Rb(1) and four equivalent S(1) atoms. S(1) is bonded in a 7-coordinate geometry to four equivalent Rb(1), one Pt(2), and two equivalent Pt(1) atoms. is represented by the CIF card [CIF]
data_Rb2Pt3S4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.334
_cell_length_b   6.334
_cell_length_c   7.260
_cell_angle_alpha   102.932
_cell_angle_beta   102.932
_cell_angle_gamma   119.139
_symmetry_Int_Tables_number   1
_cell_volume   228.213
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.349  0.349  0.697  1.0
  Rb  Rb1  1  0.651  0.651  0.303  1.0
  Pt  Pt2  1  0.000  0.500  0.000  1.0
  Pt  Pt3  1  0.500  0.000  0.000  1.0
  Pt  Pt4  1  0.000  0.000  0.000  1.0
  S  S5  1  0.719  0.054  0.773  1.0
  S  S6  1  0.281  0.946  0.227  1.0
  S  S7  1  0.946  0.281  0.227  1.0
  S  S8  1  0.054  0.719  0.773  1.0
[/CIF]
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