The structure described by CNH3SOF2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight CNH3SOF2 clusters. C(1) is bonded to one N(1), one H(1), one H(2), and one H(3) atom to form CH3N tetrahedra that share  a cornercorner with one S(1)NOF2 tetrahedra. N(1) is bonded in a bent 120 degrees geometry to one C(1) and one S(1) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. S(1) is bonded to one N(1), one O(1), one F(1), and one F(2) atom to form SNOF2 tetrahedra that share  a cornercorner with one C(1)H3N tetrahedra. O(1) is bonded in a single-bond geometry to one S(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one S(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one S(1) atom. is represented by the CIF file [CIF]
data_H3CSNOF2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.346
_cell_length_b   7.346
_cell_length_c   11.407
_cell_angle_alpha   84.905
_cell_angle_beta   84.905
_cell_angle_gamma   66.017
_symmetry_Int_Tables_number   1
_cell_volume   559.210
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.666  0.488  0.836  1.0
  H  H1  1  0.512  0.334  0.664  1.0
  H  H2  1  0.334  0.512  0.164  1.0
  H  H3  1  0.488  0.666  0.336  1.0
  H  H4  1  0.553  0.678  0.939  1.0
  H  H5  1  0.322  0.447  0.561  1.0
  H  H6  1  0.447  0.322  0.061  1.0
  H  H7  1  0.678  0.553  0.439  1.0
  H  H8  1  0.563  0.744  0.784  1.0
  H  H9  1  0.256  0.437  0.716  1.0
  H  H10  1  0.437  0.256  0.216  1.0
  H  H11  1  0.744  0.563  0.284  1.0
  C  C12  1  0.643  0.640  0.855  1.0
  C  C13  1  0.360  0.357  0.645  1.0
  C  C14  1  0.357  0.360  0.145  1.0
  C  C15  1  0.640  0.643  0.355  1.0
  S  S16  1  0.885  0.795  0.912  1.0
  S  S17  1  0.205  0.115  0.588  1.0
  S  S18  1  0.115  0.205  0.088  1.0
  S  S19  1  0.795  0.885  0.412  1.0
  N  N20  1  0.841  0.640  0.863  1.0
  N  N21  1  0.360  0.159  0.637  1.0
  N  N22  1  0.159  0.360  0.137  1.0
  N  N23  1  0.640  0.841  0.363  1.0
  O  O24  1  0.085  0.776  0.916  1.0
  O  O25  1  0.224  0.915  0.584  1.0
  O  O26  1  0.915  0.224  0.084  1.0
  O  O27  1  0.776  0.085  0.416  1.0
  F  F28  1  0.777  0.853  0.041  1.0
  F  F29  1  0.147  0.223  0.459  1.0
  F  F30  1  0.223  0.147  0.959  1.0
  F  F31  1  0.853  0.777  0.541  1.0
  F  F32  1  0.759  0.016  0.855  1.0
  F  F33  1  0.984  0.241  0.645  1.0
  F  F34  1  0.241  0.984  0.145  1.0
  F  F35  1  0.016  0.759  0.355  1.0
[/CIF]
.
The structure described by CNH3SOF2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight CNH3SOF2 clusters. C(1) is bonded to one N(1), one H(1), one H(2), and one H(3) atom to form CH3N tetrahedra that share  a cornercorner with one S(1)NOF2 tetrahedra. N(1) is bonded in a bent 120 degrees geometry to one C(1) and one S(1) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. S(1) is bonded to one N(1), one O(1), one F(1), and one F(2) atom to form SNOF2 tetrahedra that share  a cornercorner with one C(1)H3N tetrahedra. O(1) is bonded in a single-bond geometry to one S(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one S(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one S(1) atom. is represented by the CIF file [CIF]
data_H3CSNOF2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.346
_cell_length_b   7.346
_cell_length_c   11.407
_cell_angle_alpha   84.905
_cell_angle_beta   84.905
_cell_angle_gamma   66.017
_symmetry_Int_Tables_number   1
_cell_volume   559.210
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.666  0.488  0.836  1.0
  H  H1  1  0.512  0.334  0.664  1.0
  H  H2  1  0.334  0.512  0.164  1.0
  H  H3  1  0.488  0.666  0.336  1.0
  H  H4  1  0.553  0.678  0.939  1.0
  H  H5  1  0.322  0.447  0.561  1.0
  H  H6  1  0.447  0.322  0.061  1.0
  H  H7  1  0.678  0.553  0.439  1.0
  H  H8  1  0.563  0.744  0.784  1.0
  H  H9  1  0.256  0.437  0.716  1.0
  H  H10  1  0.437  0.256  0.216  1.0
  H  H11  1  0.744  0.563  0.284  1.0
  C  C12  1  0.643  0.640  0.855  1.0
  C  C13  1  0.360  0.357  0.645  1.0
  C  C14  1  0.357  0.360  0.145  1.0
  C  C15  1  0.640  0.643  0.355  1.0
  S  S16  1  0.885  0.795  0.912  1.0
  S  S17  1  0.205  0.115  0.588  1.0
  S  S18  1  0.115  0.205  0.088  1.0
  S  S19  1  0.795  0.885  0.412  1.0
  N  N20  1  0.841  0.640  0.863  1.0
  N  N21  1  0.360  0.159  0.637  1.0
  N  N22  1  0.159  0.360  0.137  1.0
  N  N23  1  0.640  0.841  0.363  1.0
  O  O24  1  0.085  0.776  0.916  1.0
  O  O25  1  0.224  0.915  0.584  1.0
  O  O26  1  0.915  0.224  0.084  1.0
  O  O27  1  0.776  0.085  0.416  1.0
  F  F28  1  0.777  0.853  0.041  1.0
  F  F29  1  0.147  0.223  0.459  1.0
  F  F30  1  0.223  0.147  0.959  1.0
  F  F31  1  0.853  0.777  0.541  1.0
  F  F32  1  0.759  0.016  0.855  1.0
  F  F33  1  0.984  0.241  0.645  1.0
  F  F34  1  0.241  0.984  0.145  1.0
  F  F35  1  0.016  0.759  0.355  1.0
[/CIF]
.