The material structure described by RbZnSO4Cl crystallizes in the monoclinic P2_1/c space group. Rb(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(3), two equivalent O(4), and three equivalent Cl(1) atoms. Zn(1) is bonded to one O(1), one O(2), one O(3), and one Cl(1) atom to form ZnClO3 tetrahedra that share corners with three equivalent S(1)O4 tetrahedra. S(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form SO4 tetrahedra that share corners with three equivalent Zn(1)ClO3 tetrahedra. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Rb(1), one Zn(1), and one S(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Rb(1), one Zn(1), and one S(1) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Rb(1), one Zn(1), and one S(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one S(1) atom. Cl(1) is bonded in a distorted single-bond geometry to three equivalent Rb(1) and one Zn(1) atom. is represented by the CIF file [CIF]
data_RbZnSClO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.819
_cell_length_b   7.368
_cell_length_c   8.501
_cell_angle_alpha   84.311
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   611.984
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.419  0.637  0.699  1.0
  Rb  Rb1  1  0.919  0.363  0.801  1.0
  Rb  Rb2  1  0.081  0.637  0.199  1.0
  Rb  Rb3  1  0.581  0.363  0.301  1.0
  Zn  Zn4  1  0.696  0.906  0.044  1.0
  Zn  Zn5  1  0.804  0.906  0.544  1.0
  Zn  Zn6  1  0.196  0.094  0.456  1.0
  Zn  Zn7  1  0.304  0.094  0.956  1.0
  S  S8  1  0.929  0.105  0.234  1.0
  S  S9  1  0.071  0.895  0.766  1.0
  S  S10  1  0.429  0.895  0.266  1.0
  S  S11  1  0.571  0.105  0.734  1.0
  Cl  Cl12  1  0.183  0.373  0.529  1.0
  Cl  Cl13  1  0.817  0.627  0.471  1.0
  Cl  Cl14  1  0.683  0.627  0.971  1.0
  Cl  Cl15  1  0.317  0.373  0.029  1.0
  O  O16  1  0.624  0.967  0.631  1.0
  O  O17  1  0.839  0.112  0.377  1.0
  O  O18  1  0.661  0.112  0.877  1.0
  O  O19  1  0.433  0.033  0.786  1.0
  O  O20  1  0.436  0.713  0.350  1.0
  O  O21  1  0.564  0.287  0.650  1.0
  O  O22  1  0.161  0.888  0.623  1.0
  O  O23  1  0.339  0.888  0.123  1.0
  O  O24  1  0.376  0.033  0.369  1.0
  O  O25  1  0.124  0.033  0.869  1.0
  O  O26  1  0.876  0.967  0.131  1.0
  O  O27  1  0.567  0.967  0.214  1.0
  O  O28  1  0.933  0.967  0.714  1.0
  O  O29  1  0.064  0.713  0.850  1.0
  O  O30  1  0.936  0.287  0.150  1.0
  O  O31  1  0.067  0.033  0.286  1.0
[/CIF]
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The material structure described by RbZnSO4Cl crystallizes in the monoclinic P2_1/c space group. Rb(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(3), two equivalent O(4), and three equivalent Cl(1) atoms. Zn(1) is bonded to one O(1), one O(2), one O(3), and one Cl(1) atom to form ZnClO3 tetrahedra that share corners with three equivalent S(1)O4 tetrahedra. S(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form SO4 tetrahedra that share corners with three equivalent Zn(1)ClO3 tetrahedra. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Rb(1), one Zn(1), and one S(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Rb(1), one Zn(1), and one S(1) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Rb(1), one Zn(1), and one S(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one S(1) atom. Cl(1) is bonded in a distorted single-bond geometry to three equivalent Rb(1) and one Zn(1) atom. is represented by the CIF file [CIF]
data_RbZnSClO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.819
_cell_length_b   7.368
_cell_length_c   8.501
_cell_angle_alpha   84.311
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   611.984
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.419  0.637  0.699  1.0
  Rb  Rb1  1  0.919  0.363  0.801  1.0
  Rb  Rb2  1  0.081  0.637  0.199  1.0
  Rb  Rb3  1  0.581  0.363  0.301  1.0
  Zn  Zn4  1  0.696  0.906  0.044  1.0
  Zn  Zn5  1  0.804  0.906  0.544  1.0
  Zn  Zn6  1  0.196  0.094  0.456  1.0
  Zn  Zn7  1  0.304  0.094  0.956  1.0
  S  S8  1  0.929  0.105  0.234  1.0
  S  S9  1  0.071  0.895  0.766  1.0
  S  S10  1  0.429  0.895  0.266  1.0
  S  S11  1  0.571  0.105  0.734  1.0
  Cl  Cl12  1  0.183  0.373  0.529  1.0
  Cl  Cl13  1  0.817  0.627  0.471  1.0
  Cl  Cl14  1  0.683  0.627  0.971  1.0
  Cl  Cl15  1  0.317  0.373  0.029  1.0
  O  O16  1  0.624  0.967  0.631  1.0
  O  O17  1  0.839  0.112  0.377  1.0
  O  O18  1  0.661  0.112  0.877  1.0
  O  O19  1  0.433  0.033  0.786  1.0
  O  O20  1  0.436  0.713  0.350  1.0
  O  O21  1  0.564  0.287  0.650  1.0
  O  O22  1  0.161  0.888  0.623  1.0
  O  O23  1  0.339  0.888  0.123  1.0
  O  O24  1  0.376  0.033  0.369  1.0
  O  O25  1  0.124  0.033  0.869  1.0
  O  O26  1  0.876  0.967  0.131  1.0
  O  O27  1  0.567  0.967  0.214  1.0
  O  O28  1  0.933  0.967  0.714  1.0
  O  O29  1  0.064  0.713  0.850  1.0
  O  O30  1  0.936  0.287  0.150  1.0
  O  O31  1  0.067  0.033  0.286  1.0
[/CIF]
.