The structure described by BaMgV2Mn(AgO4)2 crystallizes in the triclinic P1 space group. Ba(1) is bonded in a 8-coordinate geometry to one O(2), one O(4), one O(5), one O(6), one O(7), one O(8), and two equivalent O(1) atoms. Mg(1) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(2), one O(3), and one O(5) atom. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(3), one O(4), and one O(5) atom to form distorted VO4 tetrahedra that share corners with three equivalent Mn(1)O6 octahedra and  a cornercorner with one Ag(2)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 19-49°. In the second V site, V(2) is bonded to one O(2), one O(6), one O(7), and one O(8) atom to form VO4 tetrahedra that share corners with three equivalent Mn(1)O6 octahedra and corners with three equivalent Ag(2)O4 trigonal pyramids. The corner-sharing octahedral tilt angles range from 33-41°. Mn(1) is bonded to one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom to form MnO6 octahedra that share corners with three equivalent V(1)O4 tetrahedra, corners with three equivalent V(2)O4 tetrahedra, and corners with three equivalent Ag(2)O4 trigonal pyramids. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 3-coordinate geometry to one O(3), one O(4), and one O(6) atom. In the second Ag site, Ag(2) is bonded to one O(1), one O(6), one O(7), and one O(8) atom to form distorted AgO4 trigonal pyramids that share corners with three equivalent Mn(1)O6 octahedra,  a cornercorner with one V(1)O4 tetrahedra, and corners with three equivalent V(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 71-81°. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to two equivalent Ba(1), one Mg(1), one V(1), and one Ag(2) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Ba(1), one Mg(1), and one V(2) atom. In the third O site, O(3) is bonded in a distorted see-saw-like geometry to one Mg(1), one V(1), one Mn(1), and one Ag(1) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Ba(1), one V(1), one Mn(1), and one Ag(1) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Ba(1), one Mg(1), one V(1), and one Mn(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal bipyramidal geometry to one Ba(1), one V(2), one Mn(1), one Ag(1), and one Ag(2) atom. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one Ba(1), one V(2), one Mn(1), and one Ag(2) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one Ba(1), one V(2), one Mn(1), and one Ag(2) atom. is represented by the CIF file [CIF]
data_BaMgMnV2(AgO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.703
_cell_length_b   6.147
_cell_length_c   7.647
_cell_angle_alpha   97.611
_cell_angle_beta   89.239
_cell_angle_gamma   122.252
_symmetry_Int_Tables_number   1
_cell_volume   224.185
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.059  0.157  0.949  1.0
  Mg  Mg1  1  0.032  0.679  0.135  1.0
  Mn  Mn2  1  0.983  0.981  0.498  1.0
  V  V3  1  0.631  0.248  0.256  1.0
  V  V4  1  0.333  0.711  0.748  1.0
  Ag  Ag5  1  0.347  0.546  0.369  1.0
  Ag  Ag6  1  0.682  0.367  0.693  1.0
  O  O7  1  0.708  0.328  0.028  1.0
  O  O8  1  0.317  0.681  0.984  1.0
  O  O9  1  0.769  0.603  0.337  1.0
  O  O10  1  0.898  0.197  0.313  1.0
  O  O11  1  0.263  0.029  0.269  1.0
  O  O12  1  0.274  0.384  0.660  1.0
  O  O13  1  0.657  0.954  0.663  1.0
  O  O14  1  0.081  0.799  0.704  1.0
[/CIF]
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The structure described by BaMgV2Mn(AgO4)2 crystallizes in the triclinic P1 space group. Ba(1) is bonded in a 8-coordinate geometry to one O(2), one O(4), one O(5), one O(6), one O(7), one O(8), and two equivalent O(1) atoms. Mg(1) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(2), one O(3), and one O(5) atom. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(3), one O(4), and one O(5) atom to form distorted VO4 tetrahedra that share corners with three equivalent Mn(1)O6 octahedra and  a cornercorner with one Ag(2)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 19-49°. In the second V site, V(2) is bonded to one O(2), one O(6), one O(7), and one O(8) atom to form VO4 tetrahedra that share corners with three equivalent Mn(1)O6 octahedra and corners with three equivalent Ag(2)O4 trigonal pyramids. The corner-sharing octahedral tilt angles range from 33-41°. Mn(1) is bonded to one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom to form MnO6 octahedra that share corners with three equivalent V(1)O4 tetrahedra, corners with three equivalent V(2)O4 tetrahedra, and corners with three equivalent Ag(2)O4 trigonal pyramids. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 3-coordinate geometry to one O(3), one O(4), and one O(6) atom. In the second Ag site, Ag(2) is bonded to one O(1), one O(6), one O(7), and one O(8) atom to form distorted AgO4 trigonal pyramids that share corners with three equivalent Mn(1)O6 octahedra,  a cornercorner with one V(1)O4 tetrahedra, and corners with three equivalent V(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 71-81°. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to two equivalent Ba(1), one Mg(1), one V(1), and one Ag(2) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Ba(1), one Mg(1), and one V(2) atom. In the third O site, O(3) is bonded in a distorted see-saw-like geometry to one Mg(1), one V(1), one Mn(1), and one Ag(1) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Ba(1), one V(1), one Mn(1), and one Ag(1) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Ba(1), one Mg(1), one V(1), and one Mn(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal bipyramidal geometry to one Ba(1), one V(2), one Mn(1), one Ag(1), and one Ag(2) atom. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one Ba(1), one V(2), one Mn(1), and one Ag(2) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one Ba(1), one V(2), one Mn(1), and one Ag(2) atom. is represented by the CIF file [CIF]
data_BaMgMnV2(AgO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.703
_cell_length_b   6.147
_cell_length_c   7.647
_cell_angle_alpha   97.611
_cell_angle_beta   89.239
_cell_angle_gamma   122.252
_symmetry_Int_Tables_number   1
_cell_volume   224.185
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.059  0.157  0.949  1.0
  Mg  Mg1  1  0.032  0.679  0.135  1.0
  Mn  Mn2  1  0.983  0.981  0.498  1.0
  V  V3  1  0.631  0.248  0.256  1.0
  V  V4  1  0.333  0.711  0.748  1.0
  Ag  Ag5  1  0.347  0.546  0.369  1.0
  Ag  Ag6  1  0.682  0.367  0.693  1.0
  O  O7  1  0.708  0.328  0.028  1.0
  O  O8  1  0.317  0.681  0.984  1.0
  O  O9  1  0.769  0.603  0.337  1.0
  O  O10  1  0.898  0.197  0.313  1.0
  O  O11  1  0.263  0.029  0.269  1.0
  O  O12  1  0.274  0.384  0.660  1.0
  O  O13  1  0.657  0.954  0.663  1.0
  O  O14  1  0.081  0.799  0.704  1.0
[/CIF]
.