The material structure described by AgP2 crystallizes in the monoclinic P2_1/c space group. Ag(1) is bonded in a 4-coordinate geometry to one P(1) and three equivalent P(2) atoms. There are two inequivalent P sites. In the first P site, P(2) is bonded to three equivalent Ag(1) and two equivalent P(1) atoms to form distorted PAg3P2 trigonal bipyramids that share corners with five equivalent P(1)AgP3 tetrahedra, corners with six equivalent P(2)Ag3P2 trigonal bipyramids, and  an edgeedge with one P(2)Ag3P2 trigonal bipyramid. In the second P site, P(1) is bonded to one Ag(1), one P(1), and two equivalent P(2) atoms to form PAgP3 tetrahedra that share corners with two equivalent P(1)AgP3 tetrahedra and corners with five equivalent P(2)Ag3P2 trigonal bipyramids. is represented by the CIF card [CIF]
data_AgP2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.075
_cell_length_b   6.211
_cell_length_c   7.821
_cell_angle_alpha   113.286
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   226.417
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.048  0.759  0.902  1.0
  Ag  Ag1  1  0.548  0.741  0.598  1.0
  Ag  Ag2  1  0.952  0.241  0.098  1.0
  Ag  Ag3  1  0.452  0.259  0.402  1.0
  P  P4  1  0.406  0.673  0.084  1.0
  P  P5  1  0.906  0.827  0.416  1.0
  P  P6  1  0.594  0.327  0.916  1.0
  P  P7  1  0.094  0.173  0.584  1.0
  P  P8  1  0.770  0.423  0.700  1.0
  P  P9  1  0.270  0.077  0.800  1.0
  P  P10  1  0.230  0.577  0.300  1.0
  P  P11  1  0.730  0.923  0.200  1.0
[/CIF]
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The material structure described by AgP2 crystallizes in the monoclinic P2_1/c space group. Ag(1) is bonded in a 4-coordinate geometry to one P(1) and three equivalent P(2) atoms. There are two inequivalent P sites. In the first P site, P(2) is bonded to three equivalent Ag(1) and two equivalent P(1) atoms to form distorted PAg3P2 trigonal bipyramids that share corners with five equivalent P(1)AgP3 tetrahedra, corners with six equivalent P(2)Ag3P2 trigonal bipyramids, and  an edgeedge with one P(2)Ag3P2 trigonal bipyramid. In the second P site, P(1) is bonded to one Ag(1), one P(1), and two equivalent P(2) atoms to form PAgP3 tetrahedra that share corners with two equivalent P(1)AgP3 tetrahedra and corners with five equivalent P(2)Ag3P2 trigonal bipyramids. is represented by the CIF card [CIF]
data_AgP2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.075
_cell_length_b   6.211
_cell_length_c   7.821
_cell_angle_alpha   113.286
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   226.417
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.048  0.759  0.902  1.0
  Ag  Ag1  1  0.548  0.741  0.598  1.0
  Ag  Ag2  1  0.952  0.241  0.098  1.0
  Ag  Ag3  1  0.452  0.259  0.402  1.0
  P  P4  1  0.406  0.673  0.084  1.0
  P  P5  1  0.906  0.827  0.416  1.0
  P  P6  1  0.594  0.327  0.916  1.0
  P  P7  1  0.094  0.173  0.584  1.0
  P  P8  1  0.770  0.423  0.700  1.0
  P  P9  1  0.270  0.077  0.800  1.0
  P  P10  1  0.230  0.577  0.300  1.0
  P  P11  1  0.730  0.923  0.200  1.0
[/CIF]
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