The structure described by RbFeH4O2Cl3 crystallizes in the orthorhombic Pcca space group. Rb(1) is bonded in a 8-coordinate geometry to two equivalent Cl(1) and six equivalent Cl(2) atoms. Fe(1) is bonded to two equivalent O(1), two equivalent Cl(1), and two equivalent Cl(2) atoms to form corner-sharing FeCl4O2 octahedra. The corner-sharing octahedral tilt angles are 54°. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. O(1) is bonded in a distorted water-like geometry to one Fe(1), one H(1), and one H(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted see-saw-like geometry to two equivalent Rb(1) and two equivalent Fe(1) atoms. In the second Cl site, Cl(2) is bonded in a 1-coordinate geometry to three equivalent Rb(1) and one Fe(1) atom. is represented by the CIF card [CIF]
data_RbFeH4Cl3O2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.040
_cell_length_b   8.989
_cell_length_c   11.437
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   723.763
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.000  0.250  0.650  1.0
  Rb  Rb1  1  0.000  0.750  0.850  1.0
  Rb  Rb2  1  0.000  0.750  0.350  1.0
  Rb  Rb3  1  0.000  0.250  0.150  1.0
  Fe  Fe4  1  0.531  0.000  0.750  1.0
  Fe  Fe5  1  0.469  0.500  0.750  1.0
  Fe  Fe6  1  0.469  0.000  0.250  1.0
  Fe  Fe7  1  0.531  0.500  0.250  1.0
  H  H8  1  0.304  0.025  0.948  1.0
  H  H9  1  0.696  0.475  0.948  1.0
  H  H10  1  0.696  0.525  0.552  1.0
  H  H11  1  0.304  0.975  0.552  1.0
  H  H12  1  0.696  0.975  0.052  1.0
  H  H13  1  0.304  0.525  0.052  1.0
  H  H14  1  0.304  0.475  0.448  1.0
  H  H15  1  0.696  0.025  0.448  1.0
  H  H16  1  0.298  0.182  0.885  1.0
  H  H17  1  0.702  0.318  0.885  1.0
  H  H18  1  0.702  0.682  0.615  1.0
  H  H19  1  0.298  0.818  0.615  1.0
  H  H20  1  0.702  0.818  0.115  1.0
  H  H21  1  0.298  0.682  0.115  1.0
  H  H22  1  0.298  0.318  0.385  1.0
  H  H23  1  0.702  0.182  0.385  1.0
  Cl  Cl24  1  0.500  0.250  0.650  1.0
  Cl  Cl25  1  0.500  0.750  0.850  1.0
  Cl  Cl26  1  0.500  0.750  0.350  1.0
  Cl  Cl27  1  0.500  0.250  0.150  1.0
  Cl  Cl28  1  0.792  0.087  0.889  1.0
  Cl  Cl29  1  0.208  0.413  0.889  1.0
  Cl  Cl30  1  0.208  0.587  0.611  1.0
  Cl  Cl31  1  0.792  0.913  0.611  1.0
  Cl  Cl32  1  0.208  0.913  0.111  1.0
  Cl  Cl33  1  0.792  0.587  0.111  1.0
  Cl  Cl34  1  0.792  0.413  0.389  1.0
  Cl  Cl35  1  0.208  0.087  0.389  1.0
  O  O36  1  0.318  0.074  0.871  1.0
  O  O37  1  0.682  0.426  0.871  1.0
  O  O38  1  0.682  0.574  0.629  1.0
  O  O39  1  0.318  0.926  0.629  1.0
  O  O40  1  0.682  0.926  0.129  1.0
  O  O41  1  0.318  0.574  0.129  1.0
  O  O42  1  0.318  0.426  0.371  1.0
  O  O43  1  0.682  0.074  0.371  1.0
[/CIF]
.
The structure described by RbFeH4O2Cl3 crystallizes in the orthorhombic Pcca space group. Rb(1) is bonded in a 8-coordinate geometry to two equivalent Cl(1) and six equivalent Cl(2) atoms. Fe(1) is bonded to two equivalent O(1), two equivalent Cl(1), and two equivalent Cl(2) atoms to form corner-sharing FeCl4O2 octahedra. The corner-sharing octahedral tilt angles are 54°. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. O(1) is bonded in a distorted water-like geometry to one Fe(1), one H(1), and one H(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted see-saw-like geometry to two equivalent Rb(1) and two equivalent Fe(1) atoms. In the second Cl site, Cl(2) is bonded in a 1-coordinate geometry to three equivalent Rb(1) and one Fe(1) atom. is represented by the CIF card [CIF]
data_RbFeH4Cl3O2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.040
_cell_length_b   8.989
_cell_length_c   11.437
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   723.763
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.000  0.250  0.650  1.0
  Rb  Rb1  1  0.000  0.750  0.850  1.0
  Rb  Rb2  1  0.000  0.750  0.350  1.0
  Rb  Rb3  1  0.000  0.250  0.150  1.0
  Fe  Fe4  1  0.531  0.000  0.750  1.0
  Fe  Fe5  1  0.469  0.500  0.750  1.0
  Fe  Fe6  1  0.469  0.000  0.250  1.0
  Fe  Fe7  1  0.531  0.500  0.250  1.0
  H  H8  1  0.304  0.025  0.948  1.0
  H  H9  1  0.696  0.475  0.948  1.0
  H  H10  1  0.696  0.525  0.552  1.0
  H  H11  1  0.304  0.975  0.552  1.0
  H  H12  1  0.696  0.975  0.052  1.0
  H  H13  1  0.304  0.525  0.052  1.0
  H  H14  1  0.304  0.475  0.448  1.0
  H  H15  1  0.696  0.025  0.448  1.0
  H  H16  1  0.298  0.182  0.885  1.0
  H  H17  1  0.702  0.318  0.885  1.0
  H  H18  1  0.702  0.682  0.615  1.0
  H  H19  1  0.298  0.818  0.615  1.0
  H  H20  1  0.702  0.818  0.115  1.0
  H  H21  1  0.298  0.682  0.115  1.0
  H  H22  1  0.298  0.318  0.385  1.0
  H  H23  1  0.702  0.182  0.385  1.0
  Cl  Cl24  1  0.500  0.250  0.650  1.0
  Cl  Cl25  1  0.500  0.750  0.850  1.0
  Cl  Cl26  1  0.500  0.750  0.350  1.0
  Cl  Cl27  1  0.500  0.250  0.150  1.0
  Cl  Cl28  1  0.792  0.087  0.889  1.0
  Cl  Cl29  1  0.208  0.413  0.889  1.0
  Cl  Cl30  1  0.208  0.587  0.611  1.0
  Cl  Cl31  1  0.792  0.913  0.611  1.0
  Cl  Cl32  1  0.208  0.913  0.111  1.0
  Cl  Cl33  1  0.792  0.587  0.111  1.0
  Cl  Cl34  1  0.792  0.413  0.389  1.0
  Cl  Cl35  1  0.208  0.087  0.389  1.0
  O  O36  1  0.318  0.074  0.871  1.0
  O  O37  1  0.682  0.426  0.871  1.0
  O  O38  1  0.682  0.574  0.629  1.0
  O  O39  1  0.318  0.926  0.629  1.0
  O  O40  1  0.682  0.926  0.129  1.0
  O  O41  1  0.318  0.574  0.129  1.0
  O  O42  1  0.318  0.426  0.371  1.0
  O  O43  1  0.682  0.074  0.371  1.0
[/CIF]
.