The material structure described by K2OsH4O6 crystallizes in the tetragonal I4/mmm space group. K(1) is bonded in a 8-coordinate geometry to eight equivalent O(2) atoms. Os(1) is bonded in an octahedral geometry to two equivalent O(1) and four equivalent O(2) atoms. H(1) is bonded in a single-bond geometry to one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Os(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to four equivalent K(1), one Os(1), and one H(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_K2H4OsO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.704
_cell_length_b   5.704
_cell_length_c   5.704
_cell_angle_alpha   105.268
_cell_angle_beta   111.613
_cell_angle_gamma   111.613
_symmetry_Int_Tables_number   1
_cell_volume   142.315
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.500  0.250  0.750  1.0
  K  K1  1  0.500  0.750  0.250  1.0
  H  H2  1  0.655  0.828  0.828  1.0
  H  H3  1  0.345  0.172  0.172  1.0
  H  H4  1  0.000  0.172  0.828  1.0
  H  H5  1  0.000  0.828  0.172  1.0
  Os  Os6  1  0.000  0.500  0.500  1.0
  O  O7  1  0.000  0.239  0.239  1.0
  O  O8  1  0.000  0.761  0.761  1.0
  O  O9  1  0.441  0.720  0.720  1.0
  O  O10  1  0.559  0.280  0.280  1.0
  O  O11  1  0.000  0.280  0.720  1.0
  O  O12  1  0.000  0.720  0.280  1.0
[/CIF]
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The material structure described by K2OsH4O6 crystallizes in the tetragonal I4/mmm space group. K(1) is bonded in a 8-coordinate geometry to eight equivalent O(2) atoms. Os(1) is bonded in an octahedral geometry to two equivalent O(1) and four equivalent O(2) atoms. H(1) is bonded in a single-bond geometry to one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Os(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to four equivalent K(1), one Os(1), and one H(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_K2H4OsO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.704
_cell_length_b   5.704
_cell_length_c   5.704
_cell_angle_alpha   105.268
_cell_angle_beta   111.613
_cell_angle_gamma   111.613
_symmetry_Int_Tables_number   1
_cell_volume   142.315
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.500  0.250  0.750  1.0
  K  K1  1  0.500  0.750  0.250  1.0
  H  H2  1  0.655  0.828  0.828  1.0
  H  H3  1  0.345  0.172  0.172  1.0
  H  H4  1  0.000  0.172  0.828  1.0
  H  H5  1  0.000  0.828  0.172  1.0
  Os  Os6  1  0.000  0.500  0.500  1.0
  O  O7  1  0.000  0.239  0.239  1.0
  O  O8  1  0.000  0.761  0.761  1.0
  O  O9  1  0.441  0.720  0.720  1.0
  O  O10  1  0.559  0.280  0.280  1.0
  O  O11  1  0.000  0.280  0.720  1.0
  O  O12  1  0.000  0.720  0.280  1.0
[/CIF]
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