The crystal structure described by Tb2CoTe2(SO7)2 crystallizes in the triclinic P-1 space group. Tb(1) is bonded in a 8-coordinate geometry to one O(1), one O(3), one O(6), one O(7), two equivalent O(4), and two equivalent O(5) atoms. Co(1) is bonded to two equivalent O(2), two equivalent O(6), and two equivalent O(7) atoms to form CoO6 octahedra that share corners with two equivalent S(1)O4 tetrahedra. Te(1) is bonded in a distorted T-shaped geometry to one O(5), one O(6), and one O(7) atom. S(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form SO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra. The corner-sharing octahedral tilt angles are 45°. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Tb(1) and one S(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one S(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Tb(1) and one S(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to two equivalent Tb(1) and one S(1) atom. In the fifth O site, O(5) is bonded in a trigonal non-coplanar geometry to two equivalent Tb(1) and one Te(1) atom. In the sixth O site, O(6) is bonded in a distorted T-shaped geometry to one Tb(1), one Co(1), and one Te(1) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Tb(1), one Co(1), and one Te(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Tb2CoTe2(SO7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.251
_cell_length_b   7.806
_cell_length_c   8.063
_cell_angle_alpha   115.917
_cell_angle_beta   107.190
_cell_angle_gamma   85.712
_symmetry_Int_Tables_number   1
_cell_volume   283.453
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tb  Tb0  1  0.078  0.251  0.983  1.0
  Tb  Tb1  1  0.922  0.749  0.017  1.0
  Co  Co2  1  0.000  0.000  0.500  1.0
  Te  Te3  1  0.511  0.271  0.658  1.0
  Te  Te4  1  0.489  0.729  0.342  1.0
  S  S5  1  0.763  0.246  0.252  1.0
  S  S6  1  0.237  0.754  0.748  1.0
  O  O7  1  0.899  0.408  0.259  1.0
  O  O8  1  0.101  0.592  0.741  1.0
  O  O9  1  0.868  0.226  0.431  1.0
  O  O10  1  0.132  0.774  0.569  1.0
  O  O11  1  0.475  0.270  0.217  1.0
  O  O12  1  0.525  0.730  0.783  1.0
  O  O13  1  0.819  0.076  0.087  1.0
  O  O14  1  0.181  0.924  0.913  1.0
  O  O15  1  0.748  0.439  0.894  1.0
  O  O16  1  0.252  0.561  0.106  1.0
  O  O17  1  0.275  0.193  0.751  1.0
  O  O18  1  0.725  0.807  0.249  1.0
  O  O19  1  0.744  0.075  0.666  1.0
  O  O20  1  0.256  0.925  0.334  1.0
[/CIF]
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The crystal structure described by Tb2CoTe2(SO7)2 crystallizes in the triclinic P-1 space group. Tb(1) is bonded in a 8-coordinate geometry to one O(1), one O(3), one O(6), one O(7), two equivalent O(4), and two equivalent O(5) atoms. Co(1) is bonded to two equivalent O(2), two equivalent O(6), and two equivalent O(7) atoms to form CoO6 octahedra that share corners with two equivalent S(1)O4 tetrahedra. Te(1) is bonded in a distorted T-shaped geometry to one O(5), one O(6), and one O(7) atom. S(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form SO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra. The corner-sharing octahedral tilt angles are 45°. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Tb(1) and one S(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one S(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Tb(1) and one S(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to two equivalent Tb(1) and one S(1) atom. In the fifth O site, O(5) is bonded in a trigonal non-coplanar geometry to two equivalent Tb(1) and one Te(1) atom. In the sixth O site, O(6) is bonded in a distorted T-shaped geometry to one Tb(1), one Co(1), and one Te(1) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Tb(1), one Co(1), and one Te(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Tb2CoTe2(SO7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.251
_cell_length_b   7.806
_cell_length_c   8.063
_cell_angle_alpha   115.917
_cell_angle_beta   107.190
_cell_angle_gamma   85.712
_symmetry_Int_Tables_number   1
_cell_volume   283.453
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tb  Tb0  1  0.078  0.251  0.983  1.0
  Tb  Tb1  1  0.922  0.749  0.017  1.0
  Co  Co2  1  0.000  0.000  0.500  1.0
  Te  Te3  1  0.511  0.271  0.658  1.0
  Te  Te4  1  0.489  0.729  0.342  1.0
  S  S5  1  0.763  0.246  0.252  1.0
  S  S6  1  0.237  0.754  0.748  1.0
  O  O7  1  0.899  0.408  0.259  1.0
  O  O8  1  0.101  0.592  0.741  1.0
  O  O9  1  0.868  0.226  0.431  1.0
  O  O10  1  0.132  0.774  0.569  1.0
  O  O11  1  0.475  0.270  0.217  1.0
  O  O12  1  0.525  0.730  0.783  1.0
  O  O13  1  0.819  0.076  0.087  1.0
  O  O14  1  0.181  0.924  0.913  1.0
  O  O15  1  0.748  0.439  0.894  1.0
  O  O16  1  0.252  0.561  0.106  1.0
  O  O17  1  0.275  0.193  0.751  1.0
  O  O18  1  0.725  0.807  0.249  1.0
  O  O19  1  0.744  0.075  0.666  1.0
  O  O20  1  0.256  0.925  0.334  1.0
[/CIF]
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