The compound described by Mn6OF11 is alpha bismuth trifluoride-derived structured and crystallizes in the orthorhombic Cmm2 space group. There are nine inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a body-centered cubic geometry to two equivalent F(2), two equivalent F(5), two equivalent F(7), and two equivalent F(9) atoms. In the second Mn site, Mn(2) is bonded in a body-centered cubic geometry to two equivalent O(1), two equivalent F(1), two equivalent F(2), and two equivalent F(7) atoms. In the third Mn site, Mn(3) is bonded in a 6-coordinate geometry to two equivalent F(1), two equivalent F(11), and two equivalent F(4) atoms. In the fourth Mn site, Mn(4) is bonded in a body-centered cubic geometry to two equivalent F(11), two equivalent F(3), two equivalent F(4), and two equivalent F(8) atoms. In the fifth Mn site, Mn(5) is bonded in a body-centered cubic geometry to two equivalent F(10), two equivalent F(3), two equivalent F(6), and two equivalent F(8) atoms. In the sixth Mn site, Mn(6) is bonded in a body-centered cubic geometry to two equivalent F(10), two equivalent F(5), two equivalent F(6), and two equivalent F(9) atoms. In the seventh Mn site, Mn(7) is bonded in a body-centered cubic geometry to two equivalent F(2), two equivalent F(5), two equivalent F(7), and two equivalent F(9) atoms. In the eighth Mn site, Mn(8) is bonded in a body-centered cubic geometry to two equivalent F(10), two equivalent F(3), two equivalent F(6), and two equivalent F(8) atoms. In the ninth Mn site, Mn(9) is bonded in a distorted body-centered cubic geometry to two equivalent O(1), two equivalent F(1), two equivalent F(11), and two equivalent F(4) atoms. O(1) is bonded in a 3-coordinate geometry to one Mn(9) and two equivalent Mn(2) atoms. There are eleven inequivalent F sites. In the first F site, F(1) is bonded in a 4-coordinate geometry to one Mn(3), one Mn(9), and two equivalent Mn(2) atoms. In the second F site, F(2) is bonded to one Mn(1), one Mn(7), and two equivalent Mn(2) atoms to form a mixture of corner and edge-sharing FMn4 tetrahedra. In the third F site, F(3) is bonded to one Mn(5), one Mn(8), and two equivalent Mn(4) atoms to form a mixture of corner and edge-sharing FMn4 tetrahedra. In the fourth F site, F(4) is bonded to one Mn(3), one Mn(9), and two equivalent Mn(4) atoms to form a mixture of corner and edge-sharing FMn4 tetrahedra. In the fifth F site, F(5) is bonded to one Mn(1), one Mn(7), and two equivalent Mn(6) atoms to form a mixture of corner and edge-sharing FMn4 tetrahedra. In the sixth F site, F(6) is bonded to one Mn(5), one Mn(8), and two equivalent Mn(6) atoms to form a mixture of corner and edge-sharing FMn4 tetrahedra. In the seventh F site, F(7) is bonded to one Mn(1), one Mn(7), and two equivalent Mn(2) atoms to form a mixture of corner and edge-sharing FMn4 tetrahedra. In the eighth F site, F(8) is bonded to one Mn(5), one Mn(8), and two equivalent Mn(4) atoms to form a mixture of corner and edge-sharing FMn4 tetrahedra. In the ninth F site, F(9) is bonded to one Mn(1), one Mn(7), and two equivalent Mn(6) atoms to form a mixture of corner and edge-sharing FMn4 tetrahedra. In the tenth F site, F(10) is bonded to one Mn(5), one Mn(8), and two equivalent Mn(6) atoms to form a mixture of corner and edge-sharing FMn4 tetrahedra. In the eleventh F site, F(11) is bonded to one Mn(3), one Mn(9), and two equivalent Mn(4) atoms to form a mixture of corner and edge-sharing FMn4 tetrahedra. is represented by the CIF card [CIF]
data_Mn6OF11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.234
_cell_length_b   5.234
_cell_length_c   15.713
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   91.343
_symmetry_Int_Tables_number   1
_cell_volume   430.353
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.000  0.000  0.003  1.0
  Mn  Mn1  1  0.000  0.500  0.174  1.0
  Mn  Mn2  1  0.000  0.000  0.338  1.0
  Mn  Mn3  1  0.000  0.500  0.500  1.0
  Mn  Mn4  1  0.000  0.000  0.668  1.0
  Mn  Mn5  1  0.000  0.500  0.835  1.0
  Mn  Mn6  1  0.500  0.000  0.174  1.0
  Mn  Mn7  1  0.500  0.500  0.002  1.0
  Mn  Mn8  1  0.500  0.500  0.666  1.0
  Mn  Mn9  1  0.500  0.000  0.500  1.0
  Mn  Mn10  1  0.500  0.500  0.322  1.0
  Mn  Mn11  1  0.500  0.000  0.835  1.0
  O  O12  1  0.305  0.695  0.247  1.0
  O  O13  1  0.695  0.305  0.247  1.0
  F  F14  1  0.200  0.200  0.244  1.0
  F  F15  1  0.231  0.769  0.088  1.0
  F  F16  1  0.236  0.236  0.579  1.0
  F  F17  1  0.235  0.765  0.419  1.0
  F  F18  1  0.236  0.236  0.916  1.0
  F  F19  1  0.238  0.762  0.752  1.0
  F  F20  1  0.267  0.267  0.084  1.0
  F  F21  1  0.263  0.737  0.584  1.0
  F  F22  1  0.263  0.737  0.919  1.0
  F  F23  1  0.262  0.262  0.748  1.0
  F  F24  1  0.272  0.272  0.411  1.0
  F  F25  1  0.737  0.263  0.919  1.0
  F  F26  1  0.737  0.263  0.584  1.0
  F  F27  1  0.733  0.733  0.084  1.0
  F  F28  1  0.728  0.728  0.411  1.0
  F  F29  1  0.738  0.738  0.748  1.0
  F  F30  1  0.765  0.235  0.419  1.0
  F  F31  1  0.769  0.231  0.088  1.0
  F  F32  1  0.762  0.238  0.752  1.0
  F  F33  1  0.764  0.764  0.579  1.0
  F  F34  1  0.764  0.764  0.916  1.0
  F  F35  1  0.800  0.800  0.244  1.0
[/CIF]
.
The compound described by Mn6OF11 is alpha bismuth trifluoride-derived structured and crystallizes in the orthorhombic Cmm2 space group. There are nine inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a body-centered cubic geometry to two equivalent F(2), two equivalent F(5), two equivalent F(7), and two equivalent F(9) atoms. In the second Mn site, Mn(2) is bonded in a body-centered cubic geometry to two equivalent O(1), two equivalent F(1), two equivalent F(2), and two equivalent F(7) atoms. In the third Mn site, Mn(3) is bonded in a 6-coordinate geometry to two equivalent F(1), two equivalent F(11), and two equivalent F(4) atoms. In the fourth Mn site, Mn(4) is bonded in a body-centered cubic geometry to two equivalent F(11), two equivalent F(3), two equivalent F(4), and two equivalent F(8) atoms. In the fifth Mn site, Mn(5) is bonded in a body-centered cubic geometry to two equivalent F(10), two equivalent F(3), two equivalent F(6), and two equivalent F(8) atoms. In the sixth Mn site, Mn(6) is bonded in a body-centered cubic geometry to two equivalent F(10), two equivalent F(5), two equivalent F(6), and two equivalent F(9) atoms. In the seventh Mn site, Mn(7) is bonded in a body-centered cubic geometry to two equivalent F(2), two equivalent F(5), two equivalent F(7), and two equivalent F(9) atoms. In the eighth Mn site, Mn(8) is bonded in a body-centered cubic geometry to two equivalent F(10), two equivalent F(3), two equivalent F(6), and two equivalent F(8) atoms. In the ninth Mn site, Mn(9) is bonded in a distorted body-centered cubic geometry to two equivalent O(1), two equivalent F(1), two equivalent F(11), and two equivalent F(4) atoms. O(1) is bonded in a 3-coordinate geometry to one Mn(9) and two equivalent Mn(2) atoms. There are eleven inequivalent F sites. In the first F site, F(1) is bonded in a 4-coordinate geometry to one Mn(3), one Mn(9), and two equivalent Mn(2) atoms. In the second F site, F(2) is bonded to one Mn(1), one Mn(7), and two equivalent Mn(2) atoms to form a mixture of corner and edge-sharing FMn4 tetrahedra. In the third F site, F(3) is bonded to one Mn(5), one Mn(8), and two equivalent Mn(4) atoms to form a mixture of corner and edge-sharing FMn4 tetrahedra. In the fourth F site, F(4) is bonded to one Mn(3), one Mn(9), and two equivalent Mn(4) atoms to form a mixture of corner and edge-sharing FMn4 tetrahedra. In the fifth F site, F(5) is bonded to one Mn(1), one Mn(7), and two equivalent Mn(6) atoms to form a mixture of corner and edge-sharing FMn4 tetrahedra. In the sixth F site, F(6) is bonded to one Mn(5), one Mn(8), and two equivalent Mn(6) atoms to form a mixture of corner and edge-sharing FMn4 tetrahedra. In the seventh F site, F(7) is bonded to one Mn(1), one Mn(7), and two equivalent Mn(2) atoms to form a mixture of corner and edge-sharing FMn4 tetrahedra. In the eighth F site, F(8) is bonded to one Mn(5), one Mn(8), and two equivalent Mn(4) atoms to form a mixture of corner and edge-sharing FMn4 tetrahedra. In the ninth F site, F(9) is bonded to one Mn(1), one Mn(7), and two equivalent Mn(6) atoms to form a mixture of corner and edge-sharing FMn4 tetrahedra. In the tenth F site, F(10) is bonded to one Mn(5), one Mn(8), and two equivalent Mn(6) atoms to form a mixture of corner and edge-sharing FMn4 tetrahedra. In the eleventh F site, F(11) is bonded to one Mn(3), one Mn(9), and two equivalent Mn(4) atoms to form a mixture of corner and edge-sharing FMn4 tetrahedra. is represented by the CIF card [CIF]
data_Mn6OF11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.234
_cell_length_b   5.234
_cell_length_c   15.713
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   91.343
_symmetry_Int_Tables_number   1
_cell_volume   430.353
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.000  0.000  0.003  1.0
  Mn  Mn1  1  0.000  0.500  0.174  1.0
  Mn  Mn2  1  0.000  0.000  0.338  1.0
  Mn  Mn3  1  0.000  0.500  0.500  1.0
  Mn  Mn4  1  0.000  0.000  0.668  1.0
  Mn  Mn5  1  0.000  0.500  0.835  1.0
  Mn  Mn6  1  0.500  0.000  0.174  1.0
  Mn  Mn7  1  0.500  0.500  0.002  1.0
  Mn  Mn8  1  0.500  0.500  0.666  1.0
  Mn  Mn9  1  0.500  0.000  0.500  1.0
  Mn  Mn10  1  0.500  0.500  0.322  1.0
  Mn  Mn11  1  0.500  0.000  0.835  1.0
  O  O12  1  0.305  0.695  0.247  1.0
  O  O13  1  0.695  0.305  0.247  1.0
  F  F14  1  0.200  0.200  0.244  1.0
  F  F15  1  0.231  0.769  0.088  1.0
  F  F16  1  0.236  0.236  0.579  1.0
  F  F17  1  0.235  0.765  0.419  1.0
  F  F18  1  0.236  0.236  0.916  1.0
  F  F19  1  0.238  0.762  0.752  1.0
  F  F20  1  0.267  0.267  0.084  1.0
  F  F21  1  0.263  0.737  0.584  1.0
  F  F22  1  0.263  0.737  0.919  1.0
  F  F23  1  0.262  0.262  0.748  1.0
  F  F24  1  0.272  0.272  0.411  1.0
  F  F25  1  0.737  0.263  0.919  1.0
  F  F26  1  0.737  0.263  0.584  1.0
  F  F27  1  0.733  0.733  0.084  1.0
  F  F28  1  0.728  0.728  0.411  1.0
  F  F29  1  0.738  0.738  0.748  1.0
  F  F30  1  0.765  0.235  0.419  1.0
  F  F31  1  0.769  0.231  0.088  1.0
  F  F32  1  0.762  0.238  0.752  1.0
  F  F33  1  0.764  0.764  0.579  1.0
  F  F34  1  0.764  0.764  0.916  1.0
  F  F35  1  0.800  0.800  0.244  1.0
[/CIF]
.