The crystal structure described by Sr3LaMn2(WO6)2 is Orthorhombic Perovskite-derived structured and crystallizes in the monoclinic P2_1 space group. There are three inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 6-coordinate geometry to one O(7), two equivalent O(2), two equivalent O(3), and two equivalent O(5) atoms. In the second Sr site, Sr(2) is bonded in a 9-coordinate geometry to one O(10), one O(8), two equivalent O(4), two equivalent O(6), and three equivalent O(1) atoms. In the third Sr site, Sr(3) is bonded in a 9-coordinate geometry to one O(10), one O(11), one O(3), one O(6), one O(7), one O(8), one O(9), and two equivalent O(12) atoms. La(1) is bonded in a 7-coordinate geometry to one O(10), one O(11), one O(12), one O(5), one O(7), one O(8), and one O(9) atom. There are two inequivalent W sites. In the first W site, W(1) is bonded to one O(11), one O(2), one O(3), one O(5), one O(7), and one O(9) atom to form WO6 octahedra that share  a cornercorner with one Mn(2)O6 octahedra and corners with five equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 18-30°. In the second W site, W(2) is bonded to one O(1), one O(10), one O(12), one O(4), one O(6), and one O(8) atom to form WO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra and corners with five equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 20-30°. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(12), one O(2), one O(3), one O(5), one O(7), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one W(2)O6 octahedra and corners with five equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 18-30°. In the second Mn site, Mn(2) is bonded to one O(1), one O(10), one O(11), one O(4), one O(6), and one O(8) atom to form MnO6 octahedra that share  a cornercorner with one W(1)O6 octahedra and corners with five equivalent W(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 20-26°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to three equivalent Sr(2), one W(2), and one Mn(2) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to two equivalent Sr(1), one W(1), and one Mn(1) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to one Sr(3), two equivalent Sr(1), one W(1), and one Mn(1) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to two equivalent Sr(2), one W(2), and one Mn(2) atom. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to two equivalent Sr(1), one La(1), one W(1), and one Mn(1) atom. In the sixth O site, O(6) is bonded in a 5-coordinate geometry to one Sr(3), two equivalent Sr(2), one W(2), and one Mn(2) atom. In the seventh O site, O(7) is bonded in a 5-coordinate geometry to one Sr(1), one Sr(3), one La(1), one W(1), and one Mn(1) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one Sr(2), one Sr(3), one La(1), one W(2), and one Mn(2) atom. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one Sr(3), one La(1), one W(1), and one Mn(1) atom. In the tenth O site, O(10) is bonded in a 5-coordinate geometry to one Sr(2), one Sr(3), one La(1), one W(2), and one Mn(2) atom. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one Sr(3), one La(1), one W(1), and one Mn(2) atom. In the twelfth O site, O(12) is bonded in a 4-coordinate geometry to two equivalent Sr(3), one La(1), one W(2), and one Mn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sr3LaMn2(WO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.817
_cell_length_b   5.795
_cell_length_c   16.177
_cell_angle_alpha   89.710
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   545.328
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.023  0.233  0.999  1.0
  Sr  Sr1  1  0.022  0.241  0.501  1.0
  Sr  Sr2  1  0.477  0.741  0.755  1.0
  Sr  Sr3  1  0.523  0.767  0.001  1.0
  Sr  Sr4  1  0.522  0.759  0.499  1.0
  Sr  Sr5  1  0.977  0.259  0.245  1.0
  La  La6  1  0.470  0.738  0.241  1.0
  La  La7  1  0.970  0.262  0.759  1.0
  Mn  Mn8  1  0.000  0.748  0.878  1.0
  Mn  Mn9  1  0.998  0.751  0.375  1.0
  Mn  Mn10  1  0.500  0.252  0.122  1.0
  Mn  Mn11  1  0.498  0.249  0.625  1.0
  W  W12  1  0.999  0.753  0.125  1.0
  W  W13  1  0.000  0.750  0.624  1.0
  W  W14  1  0.499  0.247  0.875  1.0
  W  W15  1  0.500  0.250  0.376  1.0
  O  O16  1  0.987  0.671  0.507  1.0
  O  O17  1  0.987  0.666  0.010  1.0
  O  O18  1  0.779  0.018  0.107  1.0
  O  O19  1  0.781  1.000  0.604  1.0
  O  O20  1  0.771  0.034  0.893  1.0
  O  O21  1  0.757  0.041  0.398  1.0
  O  O22  1  0.726  0.540  0.153  1.0
  O  O23  1  0.750  0.530  0.649  1.0
  O  O24  1  0.732  0.504  0.848  1.0
  O  O25  1  0.711  0.509  0.352  1.0
  O  O26  1  0.519  0.173  0.755  1.0
  O  O27  1  0.512  0.158  0.259  1.0
  O  O28  1  0.487  0.329  0.493  1.0
  O  O29  1  0.487  0.334  0.990  1.0
  O  O30  1  0.281  0.000  0.396  1.0
  O  O31  1  0.279  0.982  0.893  1.0
  O  O32  1  0.271  0.966  0.107  1.0
  O  O33  1  0.257  0.959  0.602  1.0
  O  O34  1  0.250  0.470  0.351  1.0
  O  O35  1  0.226  0.460  0.847  1.0
  O  O36  1  0.232  0.496  0.152  1.0
  O  O37  1  0.211  0.491  0.648  1.0
  O  O38  1  0.019  0.827  0.245  1.0
  O  O39  1  0.012  0.842  0.741  1.0
[/CIF]
.
The crystal structure described by Sr3LaMn2(WO6)2 is Orthorhombic Perovskite-derived structured and crystallizes in the monoclinic P2_1 space group. There are three inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 6-coordinate geometry to one O(7), two equivalent O(2), two equivalent O(3), and two equivalent O(5) atoms. In the second Sr site, Sr(2) is bonded in a 9-coordinate geometry to one O(10), one O(8), two equivalent O(4), two equivalent O(6), and three equivalent O(1) atoms. In the third Sr site, Sr(3) is bonded in a 9-coordinate geometry to one O(10), one O(11), one O(3), one O(6), one O(7), one O(8), one O(9), and two equivalent O(12) atoms. La(1) is bonded in a 7-coordinate geometry to one O(10), one O(11), one O(12), one O(5), one O(7), one O(8), and one O(9) atom. There are two inequivalent W sites. In the first W site, W(1) is bonded to one O(11), one O(2), one O(3), one O(5), one O(7), and one O(9) atom to form WO6 octahedra that share  a cornercorner with one Mn(2)O6 octahedra and corners with five equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 18-30°. In the second W site, W(2) is bonded to one O(1), one O(10), one O(12), one O(4), one O(6), and one O(8) atom to form WO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra and corners with five equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 20-30°. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(12), one O(2), one O(3), one O(5), one O(7), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one W(2)O6 octahedra and corners with five equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 18-30°. In the second Mn site, Mn(2) is bonded to one O(1), one O(10), one O(11), one O(4), one O(6), and one O(8) atom to form MnO6 octahedra that share  a cornercorner with one W(1)O6 octahedra and corners with five equivalent W(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 20-26°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to three equivalent Sr(2), one W(2), and one Mn(2) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to two equivalent Sr(1), one W(1), and one Mn(1) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to one Sr(3), two equivalent Sr(1), one W(1), and one Mn(1) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to two equivalent Sr(2), one W(2), and one Mn(2) atom. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to two equivalent Sr(1), one La(1), one W(1), and one Mn(1) atom. In the sixth O site, O(6) is bonded in a 5-coordinate geometry to one Sr(3), two equivalent Sr(2), one W(2), and one Mn(2) atom. In the seventh O site, O(7) is bonded in a 5-coordinate geometry to one Sr(1), one Sr(3), one La(1), one W(1), and one Mn(1) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one Sr(2), one Sr(3), one La(1), one W(2), and one Mn(2) atom. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one Sr(3), one La(1), one W(1), and one Mn(1) atom. In the tenth O site, O(10) is bonded in a 5-coordinate geometry to one Sr(2), one Sr(3), one La(1), one W(2), and one Mn(2) atom. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one Sr(3), one La(1), one W(1), and one Mn(2) atom. In the twelfth O site, O(12) is bonded in a 4-coordinate geometry to two equivalent Sr(3), one La(1), one W(2), and one Mn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sr3LaMn2(WO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.817
_cell_length_b   5.795
_cell_length_c   16.177
_cell_angle_alpha   89.710
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   545.328
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.023  0.233  0.999  1.0
  Sr  Sr1  1  0.022  0.241  0.501  1.0
  Sr  Sr2  1  0.477  0.741  0.755  1.0
  Sr  Sr3  1  0.523  0.767  0.001  1.0
  Sr  Sr4  1  0.522  0.759  0.499  1.0
  Sr  Sr5  1  0.977  0.259  0.245  1.0
  La  La6  1  0.470  0.738  0.241  1.0
  La  La7  1  0.970  0.262  0.759  1.0
  Mn  Mn8  1  0.000  0.748  0.878  1.0
  Mn  Mn9  1  0.998  0.751  0.375  1.0
  Mn  Mn10  1  0.500  0.252  0.122  1.0
  Mn  Mn11  1  0.498  0.249  0.625  1.0
  W  W12  1  0.999  0.753  0.125  1.0
  W  W13  1  0.000  0.750  0.624  1.0
  W  W14  1  0.499  0.247  0.875  1.0
  W  W15  1  0.500  0.250  0.376  1.0
  O  O16  1  0.987  0.671  0.507  1.0
  O  O17  1  0.987  0.666  0.010  1.0
  O  O18  1  0.779  0.018  0.107  1.0
  O  O19  1  0.781  1.000  0.604  1.0
  O  O20  1  0.771  0.034  0.893  1.0
  O  O21  1  0.757  0.041  0.398  1.0
  O  O22  1  0.726  0.540  0.153  1.0
  O  O23  1  0.750  0.530  0.649  1.0
  O  O24  1  0.732  0.504  0.848  1.0
  O  O25  1  0.711  0.509  0.352  1.0
  O  O26  1  0.519  0.173  0.755  1.0
  O  O27  1  0.512  0.158  0.259  1.0
  O  O28  1  0.487  0.329  0.493  1.0
  O  O29  1  0.487  0.334  0.990  1.0
  O  O30  1  0.281  0.000  0.396  1.0
  O  O31  1  0.279  0.982  0.893  1.0
  O  O32  1  0.271  0.966  0.107  1.0
  O  O33  1  0.257  0.959  0.602  1.0
  O  O34  1  0.250  0.470  0.351  1.0
  O  O35  1  0.226  0.460  0.847  1.0
  O  O36  1  0.232  0.496  0.152  1.0
  O  O37  1  0.211  0.491  0.648  1.0
  O  O38  1  0.019  0.827  0.245  1.0
  O  O39  1  0.012  0.842  0.741  1.0
[/CIF]
.