The structure described by Li3Ag2F5 crystallizes in the triclinic P1 space group. There are twelve inequivalent Li sites. In the first Li site, Li(1) is bonded to one F(1), one F(17), one F(19), and one F(7) atom to form a mixture of corner and edge-sharing LiF4 tetrahedra. In the second Li site, Li(2) is bonded to one F(16), one F(19), one F(5), and one F(6) atom to form corner-sharing LiF4 tetrahedra. In the third Li site, Li(3) is bonded to one F(13), one F(3), one F(4), and one F(6) atom to form a mixture of distorted corner and edge-sharing LiF4 trigonal pyramids. In the fourth Li site, Li(4) is bonded to one F(2), one F(20), one F(3), and one F(9) atom to form corner-sharing LiF4 tetrahedra. In the fifth Li site, Li(5) is bonded to one F(10), one F(11), one F(14), and one F(4) atom to form distorted corner-sharing LiF4 tetrahedra. In the sixth Li site, Li(6) is bonded to one F(12), one F(17), one F(7), and one F(9) atom to form corner-sharing LiF4 tetrahedra. In the seventh Li site, Li(7) is bonded to one F(10), one F(13), one F(16), and one F(6) atom to form a mixture of corner and edge-sharing LiF4 tetrahedra. In the eighth Li site, Li(8) is bonded to one F(12), one F(15), one F(18), and one F(8) atom to form distorted corner-sharing LiF4 tetrahedra. In the ninth Li site, Li(9) is bonded in a 3-coordinate geometry to one Ag(3), one F(15), one F(17), one F(18), one F(20), and one F(9) atom. In the tenth Li site, Li(10) is bonded to one F(1), one F(14), one F(19), and one F(4) atom to form a mixture of corner and edge-sharing LiF4 tetrahedra. In the eleventh Li site, Li(11) is bonded in a distorted trigonal planar geometry to one F(1), one F(15), and one F(5) atom. In the twelfth Li site, Li(12) is bonded to one F(11), one F(18), one F(2), and one F(8) atom to form corner-sharing LiF4 tetrahedra. There are eight inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to one F(10), one F(14), one F(2), and one F(6) atom. In the second Ag site, Ag(2) is bonded in a 4-coordinate geometry to one F(11), one F(12), one F(3), and one F(8) atom. In the third Ag site, Ag(3) is bonded in a 6-coordinate geometry to one Li(9), one F(17), one F(20), one F(5), one F(7), and one F(9) atom. In the fourth Ag site, Ag(4) is bonded in a 5-coordinate geometry to one F(10), one F(13), one F(18), one F(2), and one F(20) atom. In the fifth Ag site, Ag(5) is bonded in a 5-coordinate geometry to one F(16), one F(17), one F(19), one F(5), and one F(7) atom. In the sixth Ag site, Ag(6) is bonded in a 3-coordinate geometry to one F(1), one F(15), and one F(16) atom. In the seventh Ag site, Ag(7) is bonded in a 3-coordinate geometry to one F(11), one F(13), and one F(3) atom. In the eighth Ag site, Ag(8) is bonded in a distorted T-shaped geometry to one F(12), one F(20), and one F(8) atom. There are twenty inequivalent F sites. In the first F site, F(1) is bonded to one Li(1), one Li(10), one Li(11), and one Ag(6) atom to form distorted corner-sharing FLi3Ag trigonal pyramids. In the second F site, F(2) is bonded in a 4-coordinate geometry to one Li(12), one Li(4), one Ag(1), and one Ag(4) atom. In the third F site, F(3) is bonded in a 3-coordinate geometry to one Li(3), one Li(4), one Ag(2), and one Ag(7) atom. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one Li(10), one Li(3), and one Li(5) atom. In the fifth F site, F(5) is bonded in a distorted see-saw-like geometry to one Li(11), one Li(2), one Ag(3), and one Ag(5) atom. In the sixth F site, F(6) is bonded in a 3-coordinate geometry to one Li(2), one Li(3), one Li(7), and one Ag(1) atom. In the seventh F site, F(7) is bonded in a 4-coordinate geometry to one Li(1), one Li(6), one Ag(3), and one Ag(5) atom. In the eighth F site, F(8) is bonded in a 4-coordinate geometry to one Li(12), one Li(8), one Ag(2), and one Ag(8) atom. In the ninth F site, F(9) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one Li(6), one Li(9), and one Ag(3) atom. In the tenth F site, F(10) is bonded in a 4-coordinate geometry to one Li(5), one Li(7), one Ag(1), and one Ag(4) atom. In the eleventh F site, F(11) is bonded in a 4-coordinate geometry to one Li(12), one Li(5), one Ag(2), and one Ag(7) atom. In the twelfth F site, F(12) is bonded in a distorted bent 120 degrees geometry to one Li(6), one Li(8), one Ag(2), and one Ag(8) atom. In the thirteenth F site, F(13) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one Li(7), one Ag(4), and one Ag(7) atom. In the fourteenth F site, F(14) is bonded in a 3-coordinate geometry to one Li(10), one Li(5), and one Ag(1) atom. In the fifteenth F site, F(15) is bonded in a distorted bent 120 degrees geometry to one Li(11), one Li(8), one Li(9), and one Ag(6) atom. In the sixteenth F site, F(16) is bonded to one Li(2), one Li(7), one Ag(5), and one Ag(6) atom to form distorted corner-sharing FLi2Ag2 trigonal pyramids. In the seventeenth F site, F(17) is bonded in a 3-coordinate geometry to one Li(1), one Li(6), one Li(9), one Ag(3), and one Ag(5) atom. In the eighteenth F site, F(18) is bonded in a 3-coordinate geometry to one Li(12), one Li(8), one Li(9), and one Ag(4) atom. In the nineteenth F site, F(19) is bonded in a 4-coordinate geometry to one Li(1), one Li(10), one Li(2), and one Ag(5) atom. In the twentieth F site, F(20) is bonded in a 5-coordinate geometry to one Li(4), one Li(9), one Ag(3), one Ag(4), and one Ag(8) atom. is represented by the CIF card [CIF]
data_Li3Ag2F5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.758
_cell_length_b   8.164
_cell_length_c   11.949
_cell_angle_alpha   90.151
_cell_angle_beta   97.849
_cell_angle_gamma   98.982
_symmetry_Int_Tables_number   1
_cell_volume   549.441
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.021  0.713  0.403  1.0
  Li  Li1  1  0.007  0.418  0.562  1.0
  Li  Li2  1  0.364  0.635  0.758  1.0
  Li  Li3  1  0.159  0.507  0.009  1.0
  Li  Li4  1  0.569  0.986  0.770  1.0
  Li  Li5  1  0.507  0.686  0.243  1.0
  Li  Li6  1  0.571  0.373  0.711  1.0
  Li  Li7  1  0.494  0.073  0.213  1.0
  Li  Li8  1  0.634  0.398  0.208  1.0
  Li  Li9  1  0.998  0.838  0.605  1.0
  Li  Li10  1  0.913  0.123  0.411  1.0
  Li  Li11  1  0.923  0.152  0.037  1.0
  Ag  Ag12  1  0.067  0.167  0.766  1.0
  Ag  Ag13  1  0.373  0.970  0.989  1.0
  Ag  Ag14  1  0.102  0.410  0.259  1.0
  Ag  Ag15  1  0.567  0.402  0.954  1.0
  Ag  Ag16  1  0.519  0.497  0.472  1.0
  Ag  Ag17  1  0.447  0.063  0.519  1.0
  Ag  Ag18  1  0.970  0.796  0.863  1.0
  Ag  Ag19  1  0.969  0.817  0.122  1.0
  F  F20  1  0.052  0.941  0.460  1.0
  F  F21  1  0.106  0.293  0.947  1.0
  F  F22  1  0.281  0.658  0.907  1.0
  F  F23  1  0.288  0.846  0.705  1.0
  F  F24  1  0.127  0.314  0.441  1.0
  F  F25  1  0.266  0.434  0.672  1.0
  F  F26  1  0.310  0.687  0.356  1.0
  F  F27  1  0.164  0.077  0.149  1.0
  F  F28  1  0.383  0.497  0.141  1.0
  F  F29  1  0.491  0.192  0.804  1.0
  F  F30  1  0.750  0.978  0.926  1.0
  F  F31  1  0.578  0.877  0.167  1.0
  F  F32  1  0.677  0.575  0.795  1.0
  F  F33  1  0.795  0.953  0.675  1.0
  F  F34  1  0.623  0.178  0.349  1.0
  F  F35  1  0.722  0.291  0.598  1.0
  F  F36  1  0.774  0.583  0.303  1.0
  F  F37  1  0.686  0.221  0.118  1.0
  F  F38  1  0.917  0.626  0.538  1.0
  F  F39  1  0.903  0.551  0.079  1.0
[/CIF]
.
The structure described by Li3Ag2F5 crystallizes in the triclinic P1 space group. There are twelve inequivalent Li sites. In the first Li site, Li(1) is bonded to one F(1), one F(17), one F(19), and one F(7) atom to form a mixture of corner and edge-sharing LiF4 tetrahedra. In the second Li site, Li(2) is bonded to one F(16), one F(19), one F(5), and one F(6) atom to form corner-sharing LiF4 tetrahedra. In the third Li site, Li(3) is bonded to one F(13), one F(3), one F(4), and one F(6) atom to form a mixture of distorted corner and edge-sharing LiF4 trigonal pyramids. In the fourth Li site, Li(4) is bonded to one F(2), one F(20), one F(3), and one F(9) atom to form corner-sharing LiF4 tetrahedra. In the fifth Li site, Li(5) is bonded to one F(10), one F(11), one F(14), and one F(4) atom to form distorted corner-sharing LiF4 tetrahedra. In the sixth Li site, Li(6) is bonded to one F(12), one F(17), one F(7), and one F(9) atom to form corner-sharing LiF4 tetrahedra. In the seventh Li site, Li(7) is bonded to one F(10), one F(13), one F(16), and one F(6) atom to form a mixture of corner and edge-sharing LiF4 tetrahedra. In the eighth Li site, Li(8) is bonded to one F(12), one F(15), one F(18), and one F(8) atom to form distorted corner-sharing LiF4 tetrahedra. In the ninth Li site, Li(9) is bonded in a 3-coordinate geometry to one Ag(3), one F(15), one F(17), one F(18), one F(20), and one F(9) atom. In the tenth Li site, Li(10) is bonded to one F(1), one F(14), one F(19), and one F(4) atom to form a mixture of corner and edge-sharing LiF4 tetrahedra. In the eleventh Li site, Li(11) is bonded in a distorted trigonal planar geometry to one F(1), one F(15), and one F(5) atom. In the twelfth Li site, Li(12) is bonded to one F(11), one F(18), one F(2), and one F(8) atom to form corner-sharing LiF4 tetrahedra. There are eight inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to one F(10), one F(14), one F(2), and one F(6) atom. In the second Ag site, Ag(2) is bonded in a 4-coordinate geometry to one F(11), one F(12), one F(3), and one F(8) atom. In the third Ag site, Ag(3) is bonded in a 6-coordinate geometry to one Li(9), one F(17), one F(20), one F(5), one F(7), and one F(9) atom. In the fourth Ag site, Ag(4) is bonded in a 5-coordinate geometry to one F(10), one F(13), one F(18), one F(2), and one F(20) atom. In the fifth Ag site, Ag(5) is bonded in a 5-coordinate geometry to one F(16), one F(17), one F(19), one F(5), and one F(7) atom. In the sixth Ag site, Ag(6) is bonded in a 3-coordinate geometry to one F(1), one F(15), and one F(16) atom. In the seventh Ag site, Ag(7) is bonded in a 3-coordinate geometry to one F(11), one F(13), and one F(3) atom. In the eighth Ag site, Ag(8) is bonded in a distorted T-shaped geometry to one F(12), one F(20), and one F(8) atom. There are twenty inequivalent F sites. In the first F site, F(1) is bonded to one Li(1), one Li(10), one Li(11), and one Ag(6) atom to form distorted corner-sharing FLi3Ag trigonal pyramids. In the second F site, F(2) is bonded in a 4-coordinate geometry to one Li(12), one Li(4), one Ag(1), and one Ag(4) atom. In the third F site, F(3) is bonded in a 3-coordinate geometry to one Li(3), one Li(4), one Ag(2), and one Ag(7) atom. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one Li(10), one Li(3), and one Li(5) atom. In the fifth F site, F(5) is bonded in a distorted see-saw-like geometry to one Li(11), one Li(2), one Ag(3), and one Ag(5) atom. In the sixth F site, F(6) is bonded in a 3-coordinate geometry to one Li(2), one Li(3), one Li(7), and one Ag(1) atom. In the seventh F site, F(7) is bonded in a 4-coordinate geometry to one Li(1), one Li(6), one Ag(3), and one Ag(5) atom. In the eighth F site, F(8) is bonded in a 4-coordinate geometry to one Li(12), one Li(8), one Ag(2), and one Ag(8) atom. In the ninth F site, F(9) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one Li(6), one Li(9), and one Ag(3) atom. In the tenth F site, F(10) is bonded in a 4-coordinate geometry to one Li(5), one Li(7), one Ag(1), and one Ag(4) atom. In the eleventh F site, F(11) is bonded in a 4-coordinate geometry to one Li(12), one Li(5), one Ag(2), and one Ag(7) atom. In the twelfth F site, F(12) is bonded in a distorted bent 120 degrees geometry to one Li(6), one Li(8), one Ag(2), and one Ag(8) atom. In the thirteenth F site, F(13) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one Li(7), one Ag(4), and one Ag(7) atom. In the fourteenth F site, F(14) is bonded in a 3-coordinate geometry to one Li(10), one Li(5), and one Ag(1) atom. In the fifteenth F site, F(15) is bonded in a distorted bent 120 degrees geometry to one Li(11), one Li(8), one Li(9), and one Ag(6) atom. In the sixteenth F site, F(16) is bonded to one Li(2), one Li(7), one Ag(5), and one Ag(6) atom to form distorted corner-sharing FLi2Ag2 trigonal pyramids. In the seventeenth F site, F(17) is bonded in a 3-coordinate geometry to one Li(1), one Li(6), one Li(9), one Ag(3), and one Ag(5) atom. In the eighteenth F site, F(18) is bonded in a 3-coordinate geometry to one Li(12), one Li(8), one Li(9), and one Ag(4) atom. In the nineteenth F site, F(19) is bonded in a 4-coordinate geometry to one Li(1), one Li(10), one Li(2), and one Ag(5) atom. In the twentieth F site, F(20) is bonded in a 5-coordinate geometry to one Li(4), one Li(9), one Ag(3), one Ag(4), and one Ag(8) atom. is represented by the CIF card [CIF]
data_Li3Ag2F5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.758
_cell_length_b   8.164
_cell_length_c   11.949
_cell_angle_alpha   90.151
_cell_angle_beta   97.849
_cell_angle_gamma   98.982
_symmetry_Int_Tables_number   1
_cell_volume   549.441
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.021  0.713  0.403  1.0
  Li  Li1  1  0.007  0.418  0.562  1.0
  Li  Li2  1  0.364  0.635  0.758  1.0
  Li  Li3  1  0.159  0.507  0.009  1.0
  Li  Li4  1  0.569  0.986  0.770  1.0
  Li  Li5  1  0.507  0.686  0.243  1.0
  Li  Li6  1  0.571  0.373  0.711  1.0
  Li  Li7  1  0.494  0.073  0.213  1.0
  Li  Li8  1  0.634  0.398  0.208  1.0
  Li  Li9  1  0.998  0.838  0.605  1.0
  Li  Li10  1  0.913  0.123  0.411  1.0
  Li  Li11  1  0.923  0.152  0.037  1.0
  Ag  Ag12  1  0.067  0.167  0.766  1.0
  Ag  Ag13  1  0.373  0.970  0.989  1.0
  Ag  Ag14  1  0.102  0.410  0.259  1.0
  Ag  Ag15  1  0.567  0.402  0.954  1.0
  Ag  Ag16  1  0.519  0.497  0.472  1.0
  Ag  Ag17  1  0.447  0.063  0.519  1.0
  Ag  Ag18  1  0.970  0.796  0.863  1.0
  Ag  Ag19  1  0.969  0.817  0.122  1.0
  F  F20  1  0.052  0.941  0.460  1.0
  F  F21  1  0.106  0.293  0.947  1.0
  F  F22  1  0.281  0.658  0.907  1.0
  F  F23  1  0.288  0.846  0.705  1.0
  F  F24  1  0.127  0.314  0.441  1.0
  F  F25  1  0.266  0.434  0.672  1.0
  F  F26  1  0.310  0.687  0.356  1.0
  F  F27  1  0.164  0.077  0.149  1.0
  F  F28  1  0.383  0.497  0.141  1.0
  F  F29  1  0.491  0.192  0.804  1.0
  F  F30  1  0.750  0.978  0.926  1.0
  F  F31  1  0.578  0.877  0.167  1.0
  F  F32  1  0.677  0.575  0.795  1.0
  F  F33  1  0.795  0.953  0.675  1.0
  F  F34  1  0.623  0.178  0.349  1.0
  F  F35  1  0.722  0.291  0.598  1.0
  F  F36  1  0.774  0.583  0.303  1.0
  F  F37  1  0.686  0.221  0.118  1.0
  F  F38  1  0.917  0.626  0.538  1.0
  F  F39  1  0.903  0.551  0.079  1.0
[/CIF]
.