The crystal structure described by Na2PH3TeO11 crystallizes in the hexagonal P6_3 space group. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded to three equivalent O(4) and three equivalent O(5) atoms to form NaO6 octahedra that share corners with three equivalent Te(1)O6 octahedra and corners with three equivalent P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 24°. In the second Na site, Na(2) is bonded in a 7-coordinate geometry to one O(2), three equivalent O(1), and three equivalent O(5) atoms. P(1) is bonded to one O(3) and three equivalent O(4) atoms to form PO4 tetrahedra that share corners with three equivalent Na(1)O6 octahedra. The corner-sharing octahedral tilt angles are 57°. H(1) is bonded in a linear geometry to one O(2) and one O(4) atom. Te(1) is bonded to three equivalent O(1) and three equivalent O(5) atoms to form TeO6 octahedra that share corners with three equivalent Na(1)O6 octahedra. The corner-sharing octahedral tilt angles are 24°. There are five inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Na(2) and one Te(1) atom. In the second O site, O(2) is bonded in a trigonal non-coplanar geometry to one Na(2) and three equivalent H(1) atoms. In the third O site, O(3) is bonded in a single-bond geometry to one P(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Na(1), one P(1), and one H(1) atom. In the fifth O site, O(5) is bonded in a distorted T-shaped geometry to one Na(1), one Na(2), and one Te(1) atom. is represented by the CIF card [CIF]
data_Na2TePH3O11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.010
_cell_length_b   6.010
_cell_length_c   15.234
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   476.574
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.667  0.333  0.949  1.0
  Na  Na1  1  0.333  0.667  0.449  1.0
  Na  Na2  1  0.667  0.333  0.729  1.0
  Na  Na3  1  0.333  0.667  0.229  1.0
  Te  Te4  1  0.667  0.333  0.280  1.0
  Te  Te5  1  0.333  0.667  0.780  1.0
  P  P6  1  0.000  0.000  0.993  1.0
  P  P7  1  0.000  0.000  0.493  1.0
  H  H8  1  0.811  0.296  0.545  1.0
  H  H9  1  0.484  0.189  0.545  1.0
  H  H10  1  0.189  0.704  0.045  1.0
  H  H11  1  0.704  0.516  0.545  1.0
  H  H12  1  0.516  0.811  0.045  1.0
  H  H13  1  0.296  0.484  0.045  1.0
  O  O14  1  0.610  0.919  0.707  1.0
  O  O15  1  0.309  0.390  0.707  1.0
  O  O16  1  0.390  0.081  0.207  1.0
  O  O17  1  0.081  0.691  0.707  1.0
  O  O18  1  0.691  0.610  0.207  1.0
  O  O19  1  0.919  0.309  0.207  1.0
  O  O20  1  0.667  0.333  0.566  1.0
  O  O21  1  0.333  0.667  0.066  1.0
  O  O22  1  0.000  0.000  0.889  1.0
  O  O23  1  0.000  0.000  0.389  1.0
  O  O24  1  0.740  0.770  0.520  1.0
  O  O25  1  0.030  0.260  0.520  1.0
  O  O26  1  0.260  0.230  0.020  1.0
  O  O27  1  0.230  0.970  0.520  1.0
  O  O28  1  0.970  0.740  0.020  1.0
  O  O29  1  0.770  0.030  0.020  1.0
  O  O30  1  0.556  0.574  0.842  1.0
  O  O31  1  0.018  0.444  0.842  1.0
  O  O32  1  0.444  0.426  0.342  1.0
  O  O33  1  0.426  0.982  0.842  1.0
  O  O34  1  0.982  0.556  0.342  1.0
  O  O35  1  0.574  0.018  0.342  1.0
[/CIF]
.
The crystal structure described by Na2PH3TeO11 crystallizes in the hexagonal P6_3 space group. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded to three equivalent O(4) and three equivalent O(5) atoms to form NaO6 octahedra that share corners with three equivalent Te(1)O6 octahedra and corners with three equivalent P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 24°. In the second Na site, Na(2) is bonded in a 7-coordinate geometry to one O(2), three equivalent O(1), and three equivalent O(5) atoms. P(1) is bonded to one O(3) and three equivalent O(4) atoms to form PO4 tetrahedra that share corners with three equivalent Na(1)O6 octahedra. The corner-sharing octahedral tilt angles are 57°. H(1) is bonded in a linear geometry to one O(2) and one O(4) atom. Te(1) is bonded to three equivalent O(1) and three equivalent O(5) atoms to form TeO6 octahedra that share corners with three equivalent Na(1)O6 octahedra. The corner-sharing octahedral tilt angles are 24°. There are five inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Na(2) and one Te(1) atom. In the second O site, O(2) is bonded in a trigonal non-coplanar geometry to one Na(2) and three equivalent H(1) atoms. In the third O site, O(3) is bonded in a single-bond geometry to one P(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Na(1), one P(1), and one H(1) atom. In the fifth O site, O(5) is bonded in a distorted T-shaped geometry to one Na(1), one Na(2), and one Te(1) atom. is represented by the CIF card [CIF]
data_Na2TePH3O11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.010
_cell_length_b   6.010
_cell_length_c   15.234
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   476.574
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.667  0.333  0.949  1.0
  Na  Na1  1  0.333  0.667  0.449  1.0
  Na  Na2  1  0.667  0.333  0.729  1.0
  Na  Na3  1  0.333  0.667  0.229  1.0
  Te  Te4  1  0.667  0.333  0.280  1.0
  Te  Te5  1  0.333  0.667  0.780  1.0
  P  P6  1  0.000  0.000  0.993  1.0
  P  P7  1  0.000  0.000  0.493  1.0
  H  H8  1  0.811  0.296  0.545  1.0
  H  H9  1  0.484  0.189  0.545  1.0
  H  H10  1  0.189  0.704  0.045  1.0
  H  H11  1  0.704  0.516  0.545  1.0
  H  H12  1  0.516  0.811  0.045  1.0
  H  H13  1  0.296  0.484  0.045  1.0
  O  O14  1  0.610  0.919  0.707  1.0
  O  O15  1  0.309  0.390  0.707  1.0
  O  O16  1  0.390  0.081  0.207  1.0
  O  O17  1  0.081  0.691  0.707  1.0
  O  O18  1  0.691  0.610  0.207  1.0
  O  O19  1  0.919  0.309  0.207  1.0
  O  O20  1  0.667  0.333  0.566  1.0
  O  O21  1  0.333  0.667  0.066  1.0
  O  O22  1  0.000  0.000  0.889  1.0
  O  O23  1  0.000  0.000  0.389  1.0
  O  O24  1  0.740  0.770  0.520  1.0
  O  O25  1  0.030  0.260  0.520  1.0
  O  O26  1  0.260  0.230  0.020  1.0
  O  O27  1  0.230  0.970  0.520  1.0
  O  O28  1  0.970  0.740  0.020  1.0
  O  O29  1  0.770  0.030  0.020  1.0
  O  O30  1  0.556  0.574  0.842  1.0
  O  O31  1  0.018  0.444  0.842  1.0
  O  O32  1  0.444  0.426  0.342  1.0
  O  O33  1  0.426  0.982  0.842  1.0
  O  O34  1  0.982  0.556  0.342  1.0
  O  O35  1  0.574  0.018  0.342  1.0
[/CIF]
.