The structure described by Li7Mn2(CoO4)3 is Caswellsilverite-derived structured and crystallizes in the triclinic P1 space group. There are fourteen inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(17), one O(19), one O(21), one O(23), one O(5), and one O(7) atom to form LiO6 octahedra that share  a cornercorner with one Li(11)O6 octahedra,  a cornercorner with one Li(13)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra, edges with three equivalent Co(3)O6 octahedra, and edges with three equivalent Co(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-5°. In the second Li site, Li(2) is bonded to one O(18), one O(20), one O(22), one O(24), one O(6), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(12)O6 octahedra,  a cornercorner with one Li(14)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra, edges with three equivalent Co(4)O6 octahedra, and edges with three equivalent Co(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-5°. In the third Li site, Li(3) is bonded to one O(1), one O(11), one O(21), one O(23), one O(7), and one O(9) atom to form distorted LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, edges with three equivalent Li(11)O6 octahedra, and edges with three equivalent Li(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-15°. In the fourth Li site, Li(4) is bonded to one O(10), one O(12), one O(2), one O(22), one O(24), and one O(8) atom to form distorted LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, edges with three equivalent Li(12)O6 octahedra, and edges with three equivalent Li(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-16°. In the fifth Li site, Li(5) is bonded to one O(13), one O(15), one O(17), one O(19), one O(3), and one O(5) atom to form distorted LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, edges with three equivalent Li(13)O6 octahedra, and edges with three equivalent Li(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-16°. In the sixth Li site, Li(6) is bonded to one O(14), one O(16), one O(18), one O(20), one O(4), and one O(6) atom to form distorted LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, edges with three equivalent Li(10)O6 octahedra, and edges with three equivalent Li(14)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-14°. In the seventh Li site, Li(7) is bonded to one O(1), one O(11), one O(21), one O(23), one O(7), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, edges with three equivalent Li(11)O6 octahedra, and edges with three equivalent Li(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-14°. In the eighth Li site, Li(8) is bonded to one O(10), one O(12), one O(2), one O(22), one O(24), and one O(8) atom to form distorted LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, edges with three equivalent Li(12)O6 octahedra, and edges with three equivalent Li(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-15°. In the ninth Li site, Li(9) is bonded to one O(13), one O(15), one O(17), one O(19), one O(3), and one O(5) atom to form distorted LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, edges with three equivalent Li(13)O6 octahedra, and edges with three equivalent Li(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-15°. In the tenth Li site, Li(10) is bonded to one O(14), one O(16), one O(18), one O(20), one O(4), and one O(6) atom to form LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, edges with three equivalent Li(14)O6 octahedra, and edges with three equivalent Li(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-14°. In the eleventh Li site, Li(11) is bonded to one O(1), one O(11), one O(21), one O(23), one O(7), and one O(9) atom to form distorted LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, edges with three equivalent Li(3)O6 octahedra, and edges with three equivalent Li(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-15°. In the twelfth Li site, Li(12) is bonded to one O(10), one O(12), one O(2), one O(22), one O(24), and one O(8) atom to form distorted LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, edges with three equivalent Li(4)O6 octahedra, and edges with three equivalent Li(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-14°. In the thirteenth Li site, Li(13) is bonded to one O(13), one O(15), one O(17), one O(19), one O(3), and one O(5) atom to form distorted LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, edges with three equivalent Li(5)O6 octahedra, and edges with three equivalent Li(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-14°. In the fourteenth Li site, Li(14) is bonded to one O(14), one O(16), one O(18), one O(20), one O(4), and one O(6) atom to form distorted LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, edges with three equivalent Li(10)O6 octahedra, and edges with three equivalent Li(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-15°. There are four inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(10), one O(12), one O(13), one O(15), one O(2), and one O(3) atom to form MnO6 octahedra that share  a cornercorner with one Li(12)O6 octahedra,  a cornercorner with one Li(13)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra, edges with three equivalent Mn(3)O6 octahedra, and edges with three equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 13-16°. In the second Mn site, Mn(2) is bonded to one O(1), one O(11), one O(14), one O(16), one O(4), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(11)O6 octahedra,  a cornercorner with one Li(14)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra, edges with three equivalent Mn(4)O6 octahedra, and edges with three equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 14-15°. In the third Mn site, Mn(3) is bonded to one O(10), one O(12), one O(13), one O(15), one O(2), and one O(3) atom to form MnO6 octahedra that share  a cornercorner with one Li(12)O6 octahedra,  a cornercorner with one Li(13)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra, edges with three equivalent Mn(1)O6 octahedra, and edges with three equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-14°. In the fourth Mn site, Mn(4) is bonded to one O(1), one O(11), one O(14), one O(16), one O(4), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(11)O6 octahedra,  a cornercorner with one Li(14)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra, edges with three equivalent Mn(2)O6 octahedra, and edges with three equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-13°. There are six inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(11), one O(14), one O(16), one O(4), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(11)O6 octahedra,  a cornercorner with one Li(14)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra, edges with three equivalent Mn(2)O6 octahedra, and edges with three equivalent Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-12°. In the second Co site, Co(2) is bonded to one O(10), one O(12), one O(13), one O(15), one O(2), and one O(3) atom to form CoO6 octahedra that share  a cornercorner with one Li(12)O6 octahedra,  a cornercorner with one Li(13)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra, edges with three equivalent Mn(1)O6 octahedra, and edges with three equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-13°. In the third Co site, Co(3) is bonded to one O(17), one O(19), one O(21), one O(23), one O(5), and one O(7) atom to form CoO6 octahedra that share  a cornercorner with one Li(11)O6 octahedra,  a cornercorner with one Li(13)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and edges with three equivalent Co(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-10°. In the fourth Co site, Co(4) is bonded to one O(18), one O(20), one O(22), one O(24), one O(6), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(12)O6 octahedra,  a cornercorner with one Li(14)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra, edges with three equivalent Li(2)O6 octahedra, and edges with three equivalent Co(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-10°. In the fifth Co site, Co(5) is bonded to one O(17), one O(19), one O(21), one O(23), one O(5), and one O(7) atom to form CoO6 octahedra that share  a cornercorner with one Li(11)O6 octahedra,  a cornercorner with one Li(13)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and edges with three equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-7°. In the sixth Co site, Co(6) is bonded to one O(18), one O(20), one O(22), one O(24), one O(6), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(12)O6 octahedra,  a cornercorner with one Li(14)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra, edges with three equivalent Li(2)O6 octahedra, and edges with three equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-7°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded to one Li(11), one Li(3), one Li(7), one Mn(2), one Mn(4), and one Co(1) atom to form OLi3Mn2Co octahedra that share  a cornercorner with one O(14)Li3Mn2Co octahedra,  a cornercorner with one O(16)Li3Mn2Co octahedra,  a cornercorner with one O(4)Li3Mn2Co octahedra,  a cornercorner with one O(21)Li4Co2 octahedra,  a cornercorner with one O(23)Li4Co2 octahedra,  a cornercorner with one O(7)Li4Co2 octahedra,  an edgeedge with one O(14)Li3Mn2Co octahedra,  an edgeedge with one O(16)Li3Mn2Co octahedra,  an edgeedge with one O(4)Li3Mn2Co octahedra,  an edgeedge with one O(21)Li4Co2 octahedra,  an edgeedge with one O(23)Li4Co2 octahedra,  an edgeedge with one O(7)Li4Co2 octahedra, edges with three equivalent O(11)Li3Mn2Co octahedra, and edges with three equivalent O(9)Li3Mn2Co octahedra. The corner-sharing octahedral tilt angles range from 0-13°. In the second O site, O(2) is bonded to one Li(12), one Li(4), one Li(8), one Mn(1), one Mn(3), and one Co(2) atom to form OLi3Mn2Co octahedra that share  a cornercorner with one O(13)Li3Mn2Co octahedra,  a cornercorner with one O(15)Li3Mn2Co octahedra,  a cornercorner with one O(3)Li3Mn2Co octahedra,  a cornercorner with one O(22)Li4Co2 octahedra,  a cornercorner with one O(24)Li4Co2 octahedra,  a cornercorner with one O(8)Li4Co2 octahedra,  an edgeedge with one O(13)Li3Mn2Co octahedra,  an edgeedge with one O(15)Li3Mn2Co octahedra,  an edgeedge with one O(3)Li3Mn2Co octahedra,  an edgeedge with one O(22)Li4Co2 octahedra,  an edgeedge with one O(24)Li4Co2 octahedra,  an edgeedge with one O(8)Li4Co2 octahedra, edges with three equivalent O(10)Li3Mn2Co octahedra, and edges with three equivalent O(12)Li3Mn2Co octahedra. The corner-sharing octahedral tilt angles range from 1-13°. In the third O site, O(3) is bonded to one Li(13), one Li(5), one Li(9), one Mn(1), one Mn(3), and one Co(2) atom to form OLi3Mn2Co octahedra that share  a cornercorner with one O(10)Li3Mn2Co octahedra,  a cornercorner with one O(12)Li3Mn2Co octahedra,  a cornercorner with one O(2)Li3Mn2Co octahedra,  a cornercorner with one O(17)Li4Co2 octahedra,  a cornercorner with one O(19)Li4Co2 octahedra,  a cornercorner with one O(5)Li4Co2 octahedra,  an edgeedge with one O(10)Li3Mn2Co octahedra,  an edgeedge with one O(12)Li3Mn2Co octahedra,  an edgeedge with one O(2)Li3Mn2Co octahedra,  an edgeedge with one O(17)Li4Co2 octahedra,  an edgeedge with one O(19)Li4Co2 octahedra,  an edgeedge with one O(5)Li4Co2 octahedra, edges with three equivalent O(13)Li3Mn2Co octahedra, and edges with three equivalent O(15)Li3Mn2Co octahedra. The corner-sharing octahedral tilt angles range from 1-13°. In the fourth O site, O(4) is bonded to one Li(10), one Li(14), one Li(6), one Mn(2), one Mn(4), and one Co(1) atom to form OLi3Mn2Co octahedra that share  a cornercorner with one O(1)Li3Mn2Co octahedra,  a cornercorner with one O(11)Li3Mn2Co octahedra,  a cornercorner with one O(9)Li3Mn2Co octahedra,  a cornercorner with one O(18)Li4Co2 octahedra,  a cornercorner with one O(20)Li4Co2 octahedra,  a cornercorner with one O(6)Li4Co2 octahedra,  an edgeedge with one O(1)Li3Mn2Co octahedra,  an edgeedge with one O(11)Li3Mn2Co octahedra,  an edgeedge with one O(9)Li3Mn2Co octahedra,  an edgeedge with one O(18)Li4Co2 octahedra,  an edgeedge with one O(20)Li4Co2 octahedra,  an edgeedge with one O(6)Li4Co2 octahedra, edges with three equivalent O(14)Li3Mn2Co octahedra, and edges with three equivalent O(16)Li3Mn2Co octahedra. The corner-sharing octahedral tilt angles range from 0-13°. In the fifth O site, O(5) is bonded to one Li(1), one Li(13), one Li(5), one Li(9), one Co(3), and one Co(5) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(13)Li3Mn2Co octahedra,  a cornercorner with one O(15)Li3Mn2Co octahedra,  a cornercorner with one O(3)Li3Mn2Co octahedra,  a cornercorner with one O(21)Li4Co2 octahedra,  a cornercorner with one O(23)Li4Co2 octahedra,  a cornercorner with one O(7)Li4Co2 octahedra,  an edgeedge with one O(13)Li3Mn2Co octahedra,  an edgeedge with one O(15)Li3Mn2Co octahedra,  an edgeedge with one O(3)Li3Mn2Co octahedra,  an edgeedge with one O(21)Li4Co2 octahedra,  an edgeedge with one O(23)Li4Co2 octahedra,  an edgeedge with one O(7)Li4Co2 octahedra, edges with three equivalent O(17)Li4Co2 octahedra, and edges with three equivalent O(19)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 4-12°. In the sixth O site, O(6) is bonded to one Li(10), one Li(14), one Li(2), one Li(6), one Co(4), and one Co(6) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(14)Li3Mn2Co octahedra,  a cornercorner with one O(16)Li3Mn2Co octahedra,  a cornercorner with one O(4)Li3Mn2Co octahedra,  a cornercorner with one O(22)Li4Co2 octahedra,  a cornercorner with one O(24)Li4Co2 octahedra,  a cornercorner with one O(8)Li4Co2 octahedra,  an edgeedge with one O(14)Li3Mn2Co octahedra,  an edgeedge with one O(16)Li3Mn2Co octahedra,  an edgeedge with one O(4)Li3Mn2Co octahedra,  an edgeedge with one O(22)Li4Co2 octahedra,  an edgeedge with one O(24)Li4Co2 octahedra,  an edgeedge with one O(8)Li4Co2 octahedra, edges with three equivalent O(18)Li4Co2 octahedra, and edges with three equivalent O(20)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 4-10°. In the seventh O site, O(7) is bonded to one Li(1), one Li(11), one Li(3), one Li(7), one Co(3), and one Co(5) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(1)Li3Mn2Co octahedra,  a cornercorner with one O(11)Li3Mn2Co octahedra,  a cornercorner with one O(9)Li3Mn2Co octahedra,  a cornercorner with one O(17)Li4Co2 octahedra,  a cornercorner with one O(19)Li4Co2 octahedra,  a cornercorner with one O(5)Li4Co2 octahedra,  an edgeedge with one O(1)Li3Mn2Co octahedra,  an edgeedge with one O(11)Li3Mn2Co octahedra,  an edgeedge with one O(9)Li3Mn2Co octahedra,  an edgeedge with one O(17)Li4Co2 octahedra,  an edgeedge with one O(19)Li4Co2 octahedra,  an edgeedge with one O(5)Li4Co2 octahedra, edges with three equivalent O(21)Li4Co2 octahedra, and edges with three equivalent O(23)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 4-10°. In the eighth O site, O(8) is bonded to one Li(12), one Li(2), one Li(4), one Li(8), one Co(4), and one Co(6) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(10)Li3Mn2Co octahedra,  a cornercorner with one O(12)Li3Mn2Co octahedra,  a cornercorner with one O(2)Li3Mn2Co octahedra,  a cornercorner with one O(18)Li4Co2 octahedra,  a cornercorner with one O(20)Li4Co2 octahedra,  a cornercorner with one O(6)Li4Co2 octahedra,  an edgeedge with one O(10)Li3Mn2Co octahedra,  an edgeedge with one O(12)Li3Mn2Co octahedra,  an edgeedge with one O(2)Li3Mn2Co octahedra,  an edgeedge with one O(18)Li4Co2 octahedra,  an edgeedge with one O(20)Li4Co2 octahedra,  an edgeedge with one O(6)Li4Co2 octahedra, edges with three equivalent O(22)Li4Co2 octahedra, and edges with three equivalent O(24)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 4-12°. In the ninth O site, O(9) is bonded to one Li(11), one Li(3), one Li(7), one Mn(2), one Mn(4), and one Co(1) atom to form OLi3Mn2Co octahedra that share  a cornercorner with one O(14)Li3Mn2Co octahedra,  a cornercorner with one O(16)Li3Mn2Co octahedra,  a cornercorner with one O(4)Li3Mn2Co octahedra,  a cornercorner with one O(21)Li4Co2 octahedra,  a cornercorner with one O(23)Li4Co2 octahedra,  a cornercorner with one O(7)Li4Co2 octahedra,  an edgeedge with one O(14)Li3Mn2Co octahedra,  an edgeedge with one O(16)Li3Mn2Co octahedra,  an edgeedge with one O(4)Li3Mn2Co octahedra,  an edgeedge with one O(21)Li4Co2 octahedra,  an edgeedge with one O(23)Li4Co2 octahedra,  an edgeedge with one O(7)Li4Co2 octahedra, edges with three equivalent O(1)Li3Mn2Co octahedra, and edges with three equivalent O(11)Li3Mn2Co octahedra. The corner-sharing octahedral tilt angles range from 0-14°. In the tenth O site, O(10) is bonded to one Li(12), one Li(4), one Li(8), one Mn(1), one Mn(3), and one Co(2) atom to form distorted OLi3Mn2Co octahedra that share  a cornercorner with one O(13)Li3Mn2Co octahedra,  a cornercorner with one O(15)Li3Mn2Co octahedra,  a cornercorner with one O(3)Li3Mn2Co octahedra,  a cornercorner with one O(22)Li4Co2 octahedra,  a cornercorner with one O(24)Li4Co2 octahedra,  a cornercorner with one O(8)Li4Co2 octahedra,  an edgeedge with one O(13)Li3Mn2Co octahedra,  an edgeedge with one O(15)Li3Mn2Co octahedra,  an edgeedge with one O(3)Li3Mn2Co octahedra,  an edgeedge with one O(22)Li4Co2 octahedra,  an edgeedge with one O(24)Li4Co2 octahedra,  an edgeedge with one O(8)Li4Co2 octahedra, edges with three equivalent O(12)Li3Mn2Co octahedra, and edges with three equivalent O(2)Li3Mn2Co octahedra. The corner-sharing octahedral tilt angles range from 1-16°. In the eleventh O site, O(11) is bonded to one Li(11), one Li(3), one Li(7), one Mn(2), one Mn(4), and one Co(1) atom to form OLi3Mn2Co octahedra that share  a cornercorner with one O(14)Li3Mn2Co octahedra,  a cornercorner with one O(16)Li3Mn2Co octahedra,  a cornercorner with one O(4)Li3Mn2Co octahedra,  a cornercorner with one O(21)Li4Co2 octahedra,  a cornercorner with one O(23)Li4Co2 octahedra,  a cornercorner with one O(7)Li4Co2 octahedra,  an edgeedge with one O(14)Li3Mn2Co octahedra,  an edgeedge with one O(16)Li3Mn2Co octahedra,  an edgeedge with one O(4)Li3Mn2Co octahedra,  an edgeedge with one O(21)Li4Co2 octahedra,  an edgeedge with one O(23)Li4Co2 octahedra,  an edgeedge with one O(7)Li4Co2 octahedra, edges with three equivalent O(1)Li3Mn2Co octahedra, and edges with three equivalent O(9)Li3Mn2Co octahedra. The corner-sharing octahedral tilt angles range from 0-13°. In the twelfth O site, O(12) is bonded to one Li(12), one Li(4), one Li(8), one Mn(1), one Mn(3), and one Co(2) atom to form OLi3Mn2Co octahedra that share  a cornercorner with one O(13)Li3Mn2Co octahedra,  a cornercorner with one O(15)Li3Mn2Co octahedra,  a cornercorner with one O(3)Li3Mn2Co octahedra,  a cornercorner with one O(22)Li4Co2 octahedra,  a cornercorner with one O(24)Li4Co2 octahedra,  a cornercorner with one O(8)Li4Co2 octahedra,  an edgeedge with one O(13)Li3Mn2Co octahedra,  an edgeedge with one O(15)Li3Mn2Co octahedra,  an edgeedge with one O(3)Li3Mn2Co octahedra,  an edgeedge with one O(22)Li4Co2 octahedra,  an edgeedge with one O(24)Li4Co2 octahedra,  an edgeedge with one O(8)Li4Co2 octahedra, edges with three equivalent O(10)Li3Mn2Co octahedra, and edges with three equivalent O(2)Li3Mn2Co octahedra. The corner-sharing octahedral tilt angles range from 1-13°. In the thirteenth O site, O(13) is bonded to one Li(13), one Li(5), one Li(9), one Mn(1), one Mn(3), and one Co(2) atom to form distorted OLi3Mn2Co octahedra that share  a cornercorner with one O(10)Li3Mn2Co octahedra,  a cornercorner with one O(12)Li3Mn2Co octahedra,  a cornercorner with one O(2)Li3Mn2Co octahedra,  a cornercorner with one O(17)Li4Co2 octahedra,  a cornercorner with one O(19)Li4Co2 octahedra,  a cornercorner with one O(5)Li4Co2 octahedra,  an edgeedge with one O(10)Li3Mn2Co octahedra,  an edgeedge with one O(12)Li3Mn2Co octahedra,  an edgeedge with one O(2)Li3Mn2Co octahedra,  an edgeedge with one O(17)Li4Co2 octahedra,  an edgeedge with one O(19)Li4Co2 octahedra,  an edgeedge with one O(5)Li4Co2 octahedra, edges with three equivalent O(15)Li3Mn2Co octahedra, and edges with three equivalent O(3)Li3Mn2Co octahedra. The corner-sharing octahedral tilt angles range from 1-15°. In the fourteenth O site, O(14) is bonded to one Li(10), one Li(14), one Li(6), one Mn(2), one Mn(4), and one Co(1) atom to form OLi3Mn2Co octahedra that share  a cornercorner with one O(1)Li3Mn2Co octahedra,  a cornercorner with one O(11)Li3Mn2Co octahedra,  a cornercorner with one O(9)Li3Mn2Co octahedra,  a cornercorner with one O(18)Li4Co2 octahedra,  a cornercorner with one O(20)Li4Co2 octahedra,  a cornercorner with one O(6)Li4Co2 octahedra,  an edgeedge with one O(1)Li3Mn2Co octahedra,  an edgeedge with one O(11)Li3Mn2Co octahedra,  an edgeedge with one O(9)Li3Mn2Co octahedra,  an edgeedge with one O(18)Li4Co2 octahedra,  an edgeedge with one O(20)Li4Co2 octahedra,  an edgeedge with one O(6)Li4Co2 octahedra, edges with three equivalent O(16)Li3Mn2Co octahedra, and edges with three equivalent O(4)Li3Mn2Co octahedra. The corner-sharing octahedral tilt angles range from 0-14°. In the fifteenth O site, O(15) is bonded to one Li(13), one Li(5), one Li(9), one Mn(1), one Mn(3), and one Co(2) atom to form OLi3Mn2Co octahedra that share  a cornercorner with one O(10)Li3Mn2Co octahedra,  a cornercorner with one O(12)Li3Mn2Co octahedra,  a cornercorner with one O(2)Li3Mn2Co octahedra,  a cornercorner with one O(17)Li4Co2 octahedra,  a cornercorner with one O(19)Li4Co2 octahedra,  a cornercorner with one O(5)Li4Co2 octahedra,  an edgeedge with one O(10)Li3Mn2Co octahedra,  an edgeedge with one O(12)Li3Mn2Co octahedra,  an edgeedge with one O(2)Li3Mn2Co octahedra,  an edgeedge with one O(17)Li4Co2 octahedra,  an edgeedge with one O(19)Li4Co2 octahedra,  an edgeedge with one O(5)Li4Co2 octahedra, edges with three equivalent O(13)Li3Mn2Co octahedra, and edges with three equivalent O(3)Li3Mn2Co octahedra. The corner-sharing octahedral tilt angles range from 1-13°. In the sixteenth O site, O(16) is bonded to one Li(10), one Li(14), one Li(6), one Mn(2), one Mn(4), and one Co(1) atom to form OLi3Mn2Co octahedra that share  a cornercorner with one O(1)Li3Mn2Co octahedra,  a cornercorner with one O(11)Li3Mn2Co octahedra,  a cornercorner with one O(9)Li3Mn2Co octahedra,  a cornercorner with one O(18)Li4Co2 octahedra,  a cornercorner with one O(20)Li4Co2 octahedra,  a cornercorner with one O(6)Li4Co2 octahedra,  an edgeedge with one O(1)Li3Mn2Co octahedra,  an edgeedge with one O(11)Li3Mn2Co octahedra,  an edgeedge with one O(9)Li3Mn2Co octahedra,  an edgeedge with one O(18)Li4Co2 octahedra,  an edgeedge with one O(20)Li4Co2 octahedra,  an edgeedge with one O(6)Li4Co2 octahedra, edges with three equivalent O(14)Li3Mn2Co octahedra, and edges with three equivalent O(4)Li3Mn2Co octahedra. The corner-sharing octahedral tilt angles range from 0-13°. In the seventeenth O site, O(17) is bonded to one Li(1), one Li(13), one Li(5), one Li(9), one Co(3), and one Co(5) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(13)Li3Mn2Co octahedra,  a cornercorner with one O(15)Li3Mn2Co octahedra,  a cornercorner with one O(3)Li3Mn2Co octahedra,  a cornercorner with one O(21)Li4Co2 octahedra,  a cornercorner with one O(23)Li4Co2 octahedra,  a cornercorner with one O(7)Li4Co2 octahedra,  an edgeedge with one O(13)Li3Mn2Co octahedra,  an edgeedge with one O(15)Li3Mn2Co octahedra,  an edgeedge with one O(3)Li3Mn2Co octahedra,  an edgeedge with one O(21)Li4Co2 octahedra,  an edgeedge with one O(23)Li4Co2 octahedra,  an edgeedge with one O(7)Li4Co2 octahedra, edges with three equivalent O(19)Li4Co2 octahedra, and edges with three equivalent O(5)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 4-10°. In the eighteenth O site, O(18) is bonded to one Li(10), one Li(14), one Li(2), one Li(6), one Co(4), and one Co(6) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(14)Li3Mn2Co octahedra,  a cornercorner with one O(16)Li3Mn2Co octahedra,  a cornercorner with one O(4)Li3Mn2Co octahedra,  a cornercorner with one O(22)Li4Co2 octahedra,  a cornercorner with one O(24)Li4Co2 octahedra,  a cornercorner with one O(8)Li4Co2 octahedra,  an edgeedge with one O(14)Li3Mn2Co octahedra,  an edgeedge with one O(16)Li3Mn2Co octahedra,  an edgeedge with one O(4)Li3Mn2Co octahedra,  an edgeedge with one O(22)Li4Co2 octahedra,  an edgeedge with one O(24)Li4Co2 octahedra,  an edgeedge with one O(8)Li4Co2 octahedra, edges with three equivalent O(20)Li4Co2 octahedra, and edges with three equivalent O(6)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 3-14°. In the nineteenth O site, O(19) is bonded to one Li(1), one Li(13), one Li(5), one Li(9), one Co(3), and one Co(5) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(13)Li3Mn2Co octahedra,  a cornercorner with one O(15)Li3Mn2Co octahedra,  a cornercorner with one O(3)Li3Mn2Co octahedra,  a cornercorner with one O(21)Li4Co2 octahedra,  a cornercorner with one O(23)Li4Co2 octahedra,  a cornercorner with one O(7)Li4Co2 octahedra,  an edgeedge with one O(13)Li3Mn2Co octahedra,  an edgeedge with one O(15)Li3Mn2Co octahedra,  an edgeedge with one O(3)Li3Mn2Co octahedra,  an edgeedge with one O(21)Li4Co2 octahedra,  an edgeedge with one O(23)Li4Co2 octahedra,  an edgeedge with one O(7)Li4Co2 octahedra, edges with three equivalent O(17)Li4Co2 octahedra, and edges with three equivalent O(5)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 3-15°. In the twentieth O site, O(20) is bonded to one Li(10), one Li(14), one Li(2), one Li(6), one Co(4), and one Co(6) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(14)Li3Mn2Co octahedra,  a cornercorner with one O(16)Li3Mn2Co octahedra,  a cornercorner with one O(4)Li3Mn2Co octahedra,  a cornercorner with one O(22)Li4Co2 octahedra,  a cornercorner with one O(24)Li4Co2 octahedra,  a cornercorner with one O(8)Li4Co2 octahedra,  an edgeedge with one O(14)Li3Mn2Co octahedra,  an edgeedge with one O(16)Li3Mn2Co octahedra,  an edgeedge with one O(4)Li3Mn2Co octahedra,  an edgeedge with one O(22)Li4Co2 octahedra,  an edgeedge with one O(24)Li4Co2 octahedra,  an edgeedge with one O(8)Li4Co2 octahedra, edges with three equivalent O(18)Li4Co2 octahedra, and edges with three equivalent O(6)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 4-12°. In the twenty-first O site, O(21) is bonded to one Li(1), one Li(11), one Li(3), one Li(7), one Co(3), and one Co(5) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(1)Li3Mn2Co octahedra,  a cornercorner with one O(11)Li3Mn2Co octahedra,  a cornercorner with one O(9)Li3Mn2Co octahedra,  a cornercorner with one O(17)Li4Co2 octahedra,  a cornercorner with one O(19)Li4Co2 octahedra,  a cornercorner with one O(5)Li4Co2 octahedra,  an edgeedge with one O(1)Li3Mn2Co octahedra,  an edgeedge with one O(11)Li3Mn2Co octahedra,  an edgeedge with one O(9)Li3Mn2Co octahedra,  an edgeedge with one O(17)Li4Co2 octahedra,  an edgeedge with one O(19)Li4Co2 octahedra,  an edgeedge with one O(5)Li4Co2 octahedra, edges with three equivalent O(23)Li4Co2 octahedra, and edges with three equivalent O(7)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 3-14°. In the twenty-second O site, O(22) is bonded to one Li(12), one Li(2), one Li(4), one Li(8), one Co(4), and one Co(6) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(10)Li3Mn2Co octahedra,  a cornercorner with one O(12)Li3Mn2Co octahedra,  a cornercorner with one O(2)Li3Mn2Co octahedra,  a cornercorner with one O(18)Li4Co2 octahedra,  a cornercorner with one O(20)Li4Co2 octahedra,  a cornercorner with one O(6)Li4Co2 octahedra,  an edgeedge with one O(10)Li3Mn2Co octahedra,  an edgeedge with one O(12)Li3Mn2Co octahedra,  an edgeedge with one O(2)Li3Mn2Co octahedra,  an edgeedge with one O(18)Li4Co2 octahedra,  an edgeedge with one O(20)Li4Co2 octahedra,  an edgeedge with one O(6)Li4Co2 octahedra, edges with three equivalent O(24)Li4Co2 octahedra, and edges with three equivalent O(8)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 3-10°. In the twenty-third O site, O(23) is bonded to one Li(1), one Li(11), one Li(3), one Li(7), one Co(3), and one Co(5) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(1)Li3Mn2Co octahedra,  a cornercorner with one O(11)Li3Mn2Co octahedra,  a cornercorner with one O(9)Li3Mn2Co octahedra,  a cornercorner with one O(17)Li4Co2 octahedra,  a cornercorner with one O(19)Li4Co2 octahedra,  a cornercorner with one O(5)Li4Co2 octahedra,  an edgeedge with one O(1)Li3Mn2Co octahedra,  an edgeedge with one O(11)Li3Mn2Co octahedra,  an edgeedge with one O(9)Li3Mn2Co octahedra,  an edgeedge with one O(17)Li4Co2 octahedra,  an edgeedge with one O(19)Li4Co2 octahedra,  an edgeedge with one O(5)Li4Co2 octahedra, edges with three equivalent O(21)Li4Co2 octahedra, and edges with three equivalent O(7)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 4-11°. In the twenty-fourth O site, O(24) is bonded to one Li(12), one Li(2), one Li(4), one Li(8), one Co(4), and one Co(6) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(10)Li3Mn2Co octahedra,  a cornercorner with one O(12)Li3Mn2Co octahedra,  a cornercorner with one O(2)Li3Mn2Co octahedra,  a cornercorner with one O(18)Li4Co2 octahedra,  a cornercorner with one O(20)Li4Co2 octahedra,  a cornercorner with one O(6)Li4Co2 octahedra,  an edgeedge with one O(10)Li3Mn2Co octahedra,  an edgeedge with one O(12)Li3Mn2Co octahedra,  an edgeedge with one O(2)Li3Mn2Co octahedra,  an edgeedge with one O(18)Li4Co2 octahedra,  an edgeedge with one O(20)Li4Co2 octahedra,  an edgeedge with one O(6)Li4Co2 octahedra, edges with three equivalent O(22)Li4Co2 octahedra, and edges with three equivalent O(8)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 3-16°. is represented by the CIF card [CIF]
data_Li7Mn2(CoO4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.013
_cell_length_b   5.013
_cell_length_c   19.487
_cell_angle_alpha   86.876
_cell_angle_beta   86.922
_cell_angle_gamma   118.949
_symmetry_Int_Tables_number   1
_cell_volume   426.031
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.588  0.920  0.250  1.0
  Li  Li1  1  0.079  0.412  0.750  1.0
  Li  Li2  1  0.957  0.284  0.137  1.0
  Li  Li3  1  0.450  0.792  0.638  1.0
  Li  Li4  1  0.208  0.549  0.363  1.0
  Li  Li5  1  0.717  0.045  0.863  1.0
  Li  Li6  1  0.292  0.943  0.135  1.0
  Li  Li7  1  0.803  0.461  0.636  1.0
  Li  Li8  1  0.538  0.196  0.364  1.0
  Li  Li9  1  0.057  0.709  0.865  1.0
  Li  Li10  1  0.632  0.640  0.137  1.0
  Li  Li11  1  0.114  0.131  0.636  1.0
  Li  Li12  1  0.868  0.884  0.364  1.0
  Li  Li13  1  0.361  0.370  0.863  1.0
  Mn  Mn14  1  0.498  0.501  0.500  1.0
  Mn  Mn15  1  0.669  0.332  0.000  1.0
  Mn  Mn16  1  0.162  0.837  0.500  1.0
  Mn  Mn17  1  0.005  0.995  1.000  1.0
  Co  Co18  1  0.334  0.666  1.000  1.0
  Co  Co19  1  0.833  0.166  0.500  1.0
  Co  Co20  1  0.254  0.249  0.250  1.0
  Co  Co21  1  0.750  0.746  0.750  1.0
  Co  Co22  1  0.912  0.583  0.250  1.0
  Co  Co23  1  0.417  0.089  0.750  1.0
  O  O24  1  0.646  0.971  0.053  1.0
  O  O25  1  0.138  0.479  0.553  1.0
  O  O26  1  0.520  0.861  0.447  1.0
  O  O27  1  0.029  0.355  0.947  1.0
  O  O28  1  0.905  0.261  0.307  1.0
  O  O29  1  0.418  0.756  0.806  1.0
  O  O30  1  0.246  0.583  0.194  1.0
  O  O31  1  0.739  0.095  0.693  1.0
  O  O32  1  0.010  0.675  0.056  1.0
  O  O33  1  0.475  0.140  0.552  1.0
  O  O34  1  0.307  0.310  0.053  1.0
  O  O35  1  0.842  0.842  0.557  1.0
  O  O36  1  0.859  0.524  0.448  1.0
  O  O37  1  0.325  0.990  0.944  1.0
  O  O38  1  0.157  0.157  0.443  1.0
  O  O39  1  0.691  0.693  0.947  1.0
  O  O40  1  0.202  0.889  0.306  1.0
  O  O41  1  0.701  0.378  0.808  1.0
  O  O42  1  0.577  0.552  0.308  1.0
  O  O43  1  0.082  0.051  0.807  1.0
  O  O44  1  0.624  0.301  0.192  1.0
  O  O45  1  0.109  0.797  0.694  1.0
  O  O46  1  0.950  0.919  0.193  1.0
  O  O47  1  0.447  0.422  0.692  1.0
[/CIF]
.
The structure described by Li7Mn2(CoO4)3 is Caswellsilverite-derived structured and crystallizes in the triclinic P1 space group. There are fourteen inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(17), one O(19), one O(21), one O(23), one O(5), and one O(7) atom to form LiO6 octahedra that share  a cornercorner with one Li(11)O6 octahedra,  a cornercorner with one Li(13)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra, edges with three equivalent Co(3)O6 octahedra, and edges with three equivalent Co(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-5°. In the second Li site, Li(2) is bonded to one O(18), one O(20), one O(22), one O(24), one O(6), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(12)O6 octahedra,  a cornercorner with one Li(14)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra, edges with three equivalent Co(4)O6 octahedra, and edges with three equivalent Co(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-5°. In the third Li site, Li(3) is bonded to one O(1), one O(11), one O(21), one O(23), one O(7), and one O(9) atom to form distorted LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, edges with three equivalent Li(11)O6 octahedra, and edges with three equivalent Li(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-15°. In the fourth Li site, Li(4) is bonded to one O(10), one O(12), one O(2), one O(22), one O(24), and one O(8) atom to form distorted LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, edges with three equivalent Li(12)O6 octahedra, and edges with three equivalent Li(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-16°. In the fifth Li site, Li(5) is bonded to one O(13), one O(15), one O(17), one O(19), one O(3), and one O(5) atom to form distorted LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, edges with three equivalent Li(13)O6 octahedra, and edges with three equivalent Li(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-16°. In the sixth Li site, Li(6) is bonded to one O(14), one O(16), one O(18), one O(20), one O(4), and one O(6) atom to form distorted LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, edges with three equivalent Li(10)O6 octahedra, and edges with three equivalent Li(14)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-14°. In the seventh Li site, Li(7) is bonded to one O(1), one O(11), one O(21), one O(23), one O(7), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, edges with three equivalent Li(11)O6 octahedra, and edges with three equivalent Li(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-14°. In the eighth Li site, Li(8) is bonded to one O(10), one O(12), one O(2), one O(22), one O(24), and one O(8) atom to form distorted LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, edges with three equivalent Li(12)O6 octahedra, and edges with three equivalent Li(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-15°. In the ninth Li site, Li(9) is bonded to one O(13), one O(15), one O(17), one O(19), one O(3), and one O(5) atom to form distorted LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, edges with three equivalent Li(13)O6 octahedra, and edges with three equivalent Li(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-15°. In the tenth Li site, Li(10) is bonded to one O(14), one O(16), one O(18), one O(20), one O(4), and one O(6) atom to form LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, edges with three equivalent Li(14)O6 octahedra, and edges with three equivalent Li(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-14°. In the eleventh Li site, Li(11) is bonded to one O(1), one O(11), one O(21), one O(23), one O(7), and one O(9) atom to form distorted LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, edges with three equivalent Li(3)O6 octahedra, and edges with three equivalent Li(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-15°. In the twelfth Li site, Li(12) is bonded to one O(10), one O(12), one O(2), one O(22), one O(24), and one O(8) atom to form distorted LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, edges with three equivalent Li(4)O6 octahedra, and edges with three equivalent Li(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-14°. In the thirteenth Li site, Li(13) is bonded to one O(13), one O(15), one O(17), one O(19), one O(3), and one O(5) atom to form distorted LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, edges with three equivalent Li(5)O6 octahedra, and edges with three equivalent Li(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-14°. In the fourteenth Li site, Li(14) is bonded to one O(14), one O(16), one O(18), one O(20), one O(4), and one O(6) atom to form distorted LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, edges with three equivalent Li(10)O6 octahedra, and edges with three equivalent Li(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-15°. There are four inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(10), one O(12), one O(13), one O(15), one O(2), and one O(3) atom to form MnO6 octahedra that share  a cornercorner with one Li(12)O6 octahedra,  a cornercorner with one Li(13)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra, edges with three equivalent Mn(3)O6 octahedra, and edges with three equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 13-16°. In the second Mn site, Mn(2) is bonded to one O(1), one O(11), one O(14), one O(16), one O(4), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(11)O6 octahedra,  a cornercorner with one Li(14)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra, edges with three equivalent Mn(4)O6 octahedra, and edges with three equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 14-15°. In the third Mn site, Mn(3) is bonded to one O(10), one O(12), one O(13), one O(15), one O(2), and one O(3) atom to form MnO6 octahedra that share  a cornercorner with one Li(12)O6 octahedra,  a cornercorner with one Li(13)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra, edges with three equivalent Mn(1)O6 octahedra, and edges with three equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-14°. In the fourth Mn site, Mn(4) is bonded to one O(1), one O(11), one O(14), one O(16), one O(4), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(11)O6 octahedra,  a cornercorner with one Li(14)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra, edges with three equivalent Mn(2)O6 octahedra, and edges with three equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-13°. There are six inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(11), one O(14), one O(16), one O(4), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(11)O6 octahedra,  a cornercorner with one Li(14)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra, edges with three equivalent Mn(2)O6 octahedra, and edges with three equivalent Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-12°. In the second Co site, Co(2) is bonded to one O(10), one O(12), one O(13), one O(15), one O(2), and one O(3) atom to form CoO6 octahedra that share  a cornercorner with one Li(12)O6 octahedra,  a cornercorner with one Li(13)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra, edges with three equivalent Mn(1)O6 octahedra, and edges with three equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-13°. In the third Co site, Co(3) is bonded to one O(17), one O(19), one O(21), one O(23), one O(5), and one O(7) atom to form CoO6 octahedra that share  a cornercorner with one Li(11)O6 octahedra,  a cornercorner with one Li(13)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and edges with three equivalent Co(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-10°. In the fourth Co site, Co(4) is bonded to one O(18), one O(20), one O(22), one O(24), one O(6), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(12)O6 octahedra,  a cornercorner with one Li(14)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra, edges with three equivalent Li(2)O6 octahedra, and edges with three equivalent Co(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-10°. In the fifth Co site, Co(5) is bonded to one O(17), one O(19), one O(21), one O(23), one O(5), and one O(7) atom to form CoO6 octahedra that share  a cornercorner with one Li(11)O6 octahedra,  a cornercorner with one Li(13)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(7)O6 octahedra,  a cornercorner with one Li(9)O6 octahedra,  an edgeedge with one Li(11)O6 octahedra,  an edgeedge with one Li(13)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(7)O6 octahedra,  an edgeedge with one Li(9)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and edges with three equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-7°. In the sixth Co site, Co(6) is bonded to one O(18), one O(20), one O(22), one O(24), one O(6), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one Li(10)O6 octahedra,  a cornercorner with one Li(12)O6 octahedra,  a cornercorner with one Li(14)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra,  a cornercorner with one Li(8)O6 octahedra,  an edgeedge with one Li(10)O6 octahedra,  an edgeedge with one Li(12)O6 octahedra,  an edgeedge with one Li(14)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Li(8)O6 octahedra, edges with three equivalent Li(2)O6 octahedra, and edges with three equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-7°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded to one Li(11), one Li(3), one Li(7), one Mn(2), one Mn(4), and one Co(1) atom to form OLi3Mn2Co octahedra that share  a cornercorner with one O(14)Li3Mn2Co octahedra,  a cornercorner with one O(16)Li3Mn2Co octahedra,  a cornercorner with one O(4)Li3Mn2Co octahedra,  a cornercorner with one O(21)Li4Co2 octahedra,  a cornercorner with one O(23)Li4Co2 octahedra,  a cornercorner with one O(7)Li4Co2 octahedra,  an edgeedge with one O(14)Li3Mn2Co octahedra,  an edgeedge with one O(16)Li3Mn2Co octahedra,  an edgeedge with one O(4)Li3Mn2Co octahedra,  an edgeedge with one O(21)Li4Co2 octahedra,  an edgeedge with one O(23)Li4Co2 octahedra,  an edgeedge with one O(7)Li4Co2 octahedra, edges with three equivalent O(11)Li3Mn2Co octahedra, and edges with three equivalent O(9)Li3Mn2Co octahedra. The corner-sharing octahedral tilt angles range from 0-13°. In the second O site, O(2) is bonded to one Li(12), one Li(4), one Li(8), one Mn(1), one Mn(3), and one Co(2) atom to form OLi3Mn2Co octahedra that share  a cornercorner with one O(13)Li3Mn2Co octahedra,  a cornercorner with one O(15)Li3Mn2Co octahedra,  a cornercorner with one O(3)Li3Mn2Co octahedra,  a cornercorner with one O(22)Li4Co2 octahedra,  a cornercorner with one O(24)Li4Co2 octahedra,  a cornercorner with one O(8)Li4Co2 octahedra,  an edgeedge with one O(13)Li3Mn2Co octahedra,  an edgeedge with one O(15)Li3Mn2Co octahedra,  an edgeedge with one O(3)Li3Mn2Co octahedra,  an edgeedge with one O(22)Li4Co2 octahedra,  an edgeedge with one O(24)Li4Co2 octahedra,  an edgeedge with one O(8)Li4Co2 octahedra, edges with three equivalent O(10)Li3Mn2Co octahedra, and edges with three equivalent O(12)Li3Mn2Co octahedra. The corner-sharing octahedral tilt angles range from 1-13°. In the third O site, O(3) is bonded to one Li(13), one Li(5), one Li(9), one Mn(1), one Mn(3), and one Co(2) atom to form OLi3Mn2Co octahedra that share  a cornercorner with one O(10)Li3Mn2Co octahedra,  a cornercorner with one O(12)Li3Mn2Co octahedra,  a cornercorner with one O(2)Li3Mn2Co octahedra,  a cornercorner with one O(17)Li4Co2 octahedra,  a cornercorner with one O(19)Li4Co2 octahedra,  a cornercorner with one O(5)Li4Co2 octahedra,  an edgeedge with one O(10)Li3Mn2Co octahedra,  an edgeedge with one O(12)Li3Mn2Co octahedra,  an edgeedge with one O(2)Li3Mn2Co octahedra,  an edgeedge with one O(17)Li4Co2 octahedra,  an edgeedge with one O(19)Li4Co2 octahedra,  an edgeedge with one O(5)Li4Co2 octahedra, edges with three equivalent O(13)Li3Mn2Co octahedra, and edges with three equivalent O(15)Li3Mn2Co octahedra. The corner-sharing octahedral tilt angles range from 1-13°. In the fourth O site, O(4) is bonded to one Li(10), one Li(14), one Li(6), one Mn(2), one Mn(4), and one Co(1) atom to form OLi3Mn2Co octahedra that share  a cornercorner with one O(1)Li3Mn2Co octahedra,  a cornercorner with one O(11)Li3Mn2Co octahedra,  a cornercorner with one O(9)Li3Mn2Co octahedra,  a cornercorner with one O(18)Li4Co2 octahedra,  a cornercorner with one O(20)Li4Co2 octahedra,  a cornercorner with one O(6)Li4Co2 octahedra,  an edgeedge with one O(1)Li3Mn2Co octahedra,  an edgeedge with one O(11)Li3Mn2Co octahedra,  an edgeedge with one O(9)Li3Mn2Co octahedra,  an edgeedge with one O(18)Li4Co2 octahedra,  an edgeedge with one O(20)Li4Co2 octahedra,  an edgeedge with one O(6)Li4Co2 octahedra, edges with three equivalent O(14)Li3Mn2Co octahedra, and edges with three equivalent O(16)Li3Mn2Co octahedra. The corner-sharing octahedral tilt angles range from 0-13°. In the fifth O site, O(5) is bonded to one Li(1), one Li(13), one Li(5), one Li(9), one Co(3), and one Co(5) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(13)Li3Mn2Co octahedra,  a cornercorner with one O(15)Li3Mn2Co octahedra,  a cornercorner with one O(3)Li3Mn2Co octahedra,  a cornercorner with one O(21)Li4Co2 octahedra,  a cornercorner with one O(23)Li4Co2 octahedra,  a cornercorner with one O(7)Li4Co2 octahedra,  an edgeedge with one O(13)Li3Mn2Co octahedra,  an edgeedge with one O(15)Li3Mn2Co octahedra,  an edgeedge with one O(3)Li3Mn2Co octahedra,  an edgeedge with one O(21)Li4Co2 octahedra,  an edgeedge with one O(23)Li4Co2 octahedra,  an edgeedge with one O(7)Li4Co2 octahedra, edges with three equivalent O(17)Li4Co2 octahedra, and edges with three equivalent O(19)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 4-12°. In the sixth O site, O(6) is bonded to one Li(10), one Li(14), one Li(2), one Li(6), one Co(4), and one Co(6) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(14)Li3Mn2Co octahedra,  a cornercorner with one O(16)Li3Mn2Co octahedra,  a cornercorner with one O(4)Li3Mn2Co octahedra,  a cornercorner with one O(22)Li4Co2 octahedra,  a cornercorner with one O(24)Li4Co2 octahedra,  a cornercorner with one O(8)Li4Co2 octahedra,  an edgeedge with one O(14)Li3Mn2Co octahedra,  an edgeedge with one O(16)Li3Mn2Co octahedra,  an edgeedge with one O(4)Li3Mn2Co octahedra,  an edgeedge with one O(22)Li4Co2 octahedra,  an edgeedge with one O(24)Li4Co2 octahedra,  an edgeedge with one O(8)Li4Co2 octahedra, edges with three equivalent O(18)Li4Co2 octahedra, and edges with three equivalent O(20)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 4-10°. In the seventh O site, O(7) is bonded to one Li(1), one Li(11), one Li(3), one Li(7), one Co(3), and one Co(5) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(1)Li3Mn2Co octahedra,  a cornercorner with one O(11)Li3Mn2Co octahedra,  a cornercorner with one O(9)Li3Mn2Co octahedra,  a cornercorner with one O(17)Li4Co2 octahedra,  a cornercorner with one O(19)Li4Co2 octahedra,  a cornercorner with one O(5)Li4Co2 octahedra,  an edgeedge with one O(1)Li3Mn2Co octahedra,  an edgeedge with one O(11)Li3Mn2Co octahedra,  an edgeedge with one O(9)Li3Mn2Co octahedra,  an edgeedge with one O(17)Li4Co2 octahedra,  an edgeedge with one O(19)Li4Co2 octahedra,  an edgeedge with one O(5)Li4Co2 octahedra, edges with three equivalent O(21)Li4Co2 octahedra, and edges with three equivalent O(23)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 4-10°. In the eighth O site, O(8) is bonded to one Li(12), one Li(2), one Li(4), one Li(8), one Co(4), and one Co(6) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(10)Li3Mn2Co octahedra,  a cornercorner with one O(12)Li3Mn2Co octahedra,  a cornercorner with one O(2)Li3Mn2Co octahedra,  a cornercorner with one O(18)Li4Co2 octahedra,  a cornercorner with one O(20)Li4Co2 octahedra,  a cornercorner with one O(6)Li4Co2 octahedra,  an edgeedge with one O(10)Li3Mn2Co octahedra,  an edgeedge with one O(12)Li3Mn2Co octahedra,  an edgeedge with one O(2)Li3Mn2Co octahedra,  an edgeedge with one O(18)Li4Co2 octahedra,  an edgeedge with one O(20)Li4Co2 octahedra,  an edgeedge with one O(6)Li4Co2 octahedra, edges with three equivalent O(22)Li4Co2 octahedra, and edges with three equivalent O(24)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 4-12°. In the ninth O site, O(9) is bonded to one Li(11), one Li(3), one Li(7), one Mn(2), one Mn(4), and one Co(1) atom to form OLi3Mn2Co octahedra that share  a cornercorner with one O(14)Li3Mn2Co octahedra,  a cornercorner with one O(16)Li3Mn2Co octahedra,  a cornercorner with one O(4)Li3Mn2Co octahedra,  a cornercorner with one O(21)Li4Co2 octahedra,  a cornercorner with one O(23)Li4Co2 octahedra,  a cornercorner with one O(7)Li4Co2 octahedra,  an edgeedge with one O(14)Li3Mn2Co octahedra,  an edgeedge with one O(16)Li3Mn2Co octahedra,  an edgeedge with one O(4)Li3Mn2Co octahedra,  an edgeedge with one O(21)Li4Co2 octahedra,  an edgeedge with one O(23)Li4Co2 octahedra,  an edgeedge with one O(7)Li4Co2 octahedra, edges with three equivalent O(1)Li3Mn2Co octahedra, and edges with three equivalent O(11)Li3Mn2Co octahedra. The corner-sharing octahedral tilt angles range from 0-14°. In the tenth O site, O(10) is bonded to one Li(12), one Li(4), one Li(8), one Mn(1), one Mn(3), and one Co(2) atom to form distorted OLi3Mn2Co octahedra that share  a cornercorner with one O(13)Li3Mn2Co octahedra,  a cornercorner with one O(15)Li3Mn2Co octahedra,  a cornercorner with one O(3)Li3Mn2Co octahedra,  a cornercorner with one O(22)Li4Co2 octahedra,  a cornercorner with one O(24)Li4Co2 octahedra,  a cornercorner with one O(8)Li4Co2 octahedra,  an edgeedge with one O(13)Li3Mn2Co octahedra,  an edgeedge with one O(15)Li3Mn2Co octahedra,  an edgeedge with one O(3)Li3Mn2Co octahedra,  an edgeedge with one O(22)Li4Co2 octahedra,  an edgeedge with one O(24)Li4Co2 octahedra,  an edgeedge with one O(8)Li4Co2 octahedra, edges with three equivalent O(12)Li3Mn2Co octahedra, and edges with three equivalent O(2)Li3Mn2Co octahedra. The corner-sharing octahedral tilt angles range from 1-16°. In the eleventh O site, O(11) is bonded to one Li(11), one Li(3), one Li(7), one Mn(2), one Mn(4), and one Co(1) atom to form OLi3Mn2Co octahedra that share  a cornercorner with one O(14)Li3Mn2Co octahedra,  a cornercorner with one O(16)Li3Mn2Co octahedra,  a cornercorner with one O(4)Li3Mn2Co octahedra,  a cornercorner with one O(21)Li4Co2 octahedra,  a cornercorner with one O(23)Li4Co2 octahedra,  a cornercorner with one O(7)Li4Co2 octahedra,  an edgeedge with one O(14)Li3Mn2Co octahedra,  an edgeedge with one O(16)Li3Mn2Co octahedra,  an edgeedge with one O(4)Li3Mn2Co octahedra,  an edgeedge with one O(21)Li4Co2 octahedra,  an edgeedge with one O(23)Li4Co2 octahedra,  an edgeedge with one O(7)Li4Co2 octahedra, edges with three equivalent O(1)Li3Mn2Co octahedra, and edges with three equivalent O(9)Li3Mn2Co octahedra. The corner-sharing octahedral tilt angles range from 0-13°. In the twelfth O site, O(12) is bonded to one Li(12), one Li(4), one Li(8), one Mn(1), one Mn(3), and one Co(2) atom to form OLi3Mn2Co octahedra that share  a cornercorner with one O(13)Li3Mn2Co octahedra,  a cornercorner with one O(15)Li3Mn2Co octahedra,  a cornercorner with one O(3)Li3Mn2Co octahedra,  a cornercorner with one O(22)Li4Co2 octahedra,  a cornercorner with one O(24)Li4Co2 octahedra,  a cornercorner with one O(8)Li4Co2 octahedra,  an edgeedge with one O(13)Li3Mn2Co octahedra,  an edgeedge with one O(15)Li3Mn2Co octahedra,  an edgeedge with one O(3)Li3Mn2Co octahedra,  an edgeedge with one O(22)Li4Co2 octahedra,  an edgeedge with one O(24)Li4Co2 octahedra,  an edgeedge with one O(8)Li4Co2 octahedra, edges with three equivalent O(10)Li3Mn2Co octahedra, and edges with three equivalent O(2)Li3Mn2Co octahedra. The corner-sharing octahedral tilt angles range from 1-13°. In the thirteenth O site, O(13) is bonded to one Li(13), one Li(5), one Li(9), one Mn(1), one Mn(3), and one Co(2) atom to form distorted OLi3Mn2Co octahedra that share  a cornercorner with one O(10)Li3Mn2Co octahedra,  a cornercorner with one O(12)Li3Mn2Co octahedra,  a cornercorner with one O(2)Li3Mn2Co octahedra,  a cornercorner with one O(17)Li4Co2 octahedra,  a cornercorner with one O(19)Li4Co2 octahedra,  a cornercorner with one O(5)Li4Co2 octahedra,  an edgeedge with one O(10)Li3Mn2Co octahedra,  an edgeedge with one O(12)Li3Mn2Co octahedra,  an edgeedge with one O(2)Li3Mn2Co octahedra,  an edgeedge with one O(17)Li4Co2 octahedra,  an edgeedge with one O(19)Li4Co2 octahedra,  an edgeedge with one O(5)Li4Co2 octahedra, edges with three equivalent O(15)Li3Mn2Co octahedra, and edges with three equivalent O(3)Li3Mn2Co octahedra. The corner-sharing octahedral tilt angles range from 1-15°. In the fourteenth O site, O(14) is bonded to one Li(10), one Li(14), one Li(6), one Mn(2), one Mn(4), and one Co(1) atom to form OLi3Mn2Co octahedra that share  a cornercorner with one O(1)Li3Mn2Co octahedra,  a cornercorner with one O(11)Li3Mn2Co octahedra,  a cornercorner with one O(9)Li3Mn2Co octahedra,  a cornercorner with one O(18)Li4Co2 octahedra,  a cornercorner with one O(20)Li4Co2 octahedra,  a cornercorner with one O(6)Li4Co2 octahedra,  an edgeedge with one O(1)Li3Mn2Co octahedra,  an edgeedge with one O(11)Li3Mn2Co octahedra,  an edgeedge with one O(9)Li3Mn2Co octahedra,  an edgeedge with one O(18)Li4Co2 octahedra,  an edgeedge with one O(20)Li4Co2 octahedra,  an edgeedge with one O(6)Li4Co2 octahedra, edges with three equivalent O(16)Li3Mn2Co octahedra, and edges with three equivalent O(4)Li3Mn2Co octahedra. The corner-sharing octahedral tilt angles range from 0-14°. In the fifteenth O site, O(15) is bonded to one Li(13), one Li(5), one Li(9), one Mn(1), one Mn(3), and one Co(2) atom to form OLi3Mn2Co octahedra that share  a cornercorner with one O(10)Li3Mn2Co octahedra,  a cornercorner with one O(12)Li3Mn2Co octahedra,  a cornercorner with one O(2)Li3Mn2Co octahedra,  a cornercorner with one O(17)Li4Co2 octahedra,  a cornercorner with one O(19)Li4Co2 octahedra,  a cornercorner with one O(5)Li4Co2 octahedra,  an edgeedge with one O(10)Li3Mn2Co octahedra,  an edgeedge with one O(12)Li3Mn2Co octahedra,  an edgeedge with one O(2)Li3Mn2Co octahedra,  an edgeedge with one O(17)Li4Co2 octahedra,  an edgeedge with one O(19)Li4Co2 octahedra,  an edgeedge with one O(5)Li4Co2 octahedra, edges with three equivalent O(13)Li3Mn2Co octahedra, and edges with three equivalent O(3)Li3Mn2Co octahedra. The corner-sharing octahedral tilt angles range from 1-13°. In the sixteenth O site, O(16) is bonded to one Li(10), one Li(14), one Li(6), one Mn(2), one Mn(4), and one Co(1) atom to form OLi3Mn2Co octahedra that share  a cornercorner with one O(1)Li3Mn2Co octahedra,  a cornercorner with one O(11)Li3Mn2Co octahedra,  a cornercorner with one O(9)Li3Mn2Co octahedra,  a cornercorner with one O(18)Li4Co2 octahedra,  a cornercorner with one O(20)Li4Co2 octahedra,  a cornercorner with one O(6)Li4Co2 octahedra,  an edgeedge with one O(1)Li3Mn2Co octahedra,  an edgeedge with one O(11)Li3Mn2Co octahedra,  an edgeedge with one O(9)Li3Mn2Co octahedra,  an edgeedge with one O(18)Li4Co2 octahedra,  an edgeedge with one O(20)Li4Co2 octahedra,  an edgeedge with one O(6)Li4Co2 octahedra, edges with three equivalent O(14)Li3Mn2Co octahedra, and edges with three equivalent O(4)Li3Mn2Co octahedra. The corner-sharing octahedral tilt angles range from 0-13°. In the seventeenth O site, O(17) is bonded to one Li(1), one Li(13), one Li(5), one Li(9), one Co(3), and one Co(5) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(13)Li3Mn2Co octahedra,  a cornercorner with one O(15)Li3Mn2Co octahedra,  a cornercorner with one O(3)Li3Mn2Co octahedra,  a cornercorner with one O(21)Li4Co2 octahedra,  a cornercorner with one O(23)Li4Co2 octahedra,  a cornercorner with one O(7)Li4Co2 octahedra,  an edgeedge with one O(13)Li3Mn2Co octahedra,  an edgeedge with one O(15)Li3Mn2Co octahedra,  an edgeedge with one O(3)Li3Mn2Co octahedra,  an edgeedge with one O(21)Li4Co2 octahedra,  an edgeedge with one O(23)Li4Co2 octahedra,  an edgeedge with one O(7)Li4Co2 octahedra, edges with three equivalent O(19)Li4Co2 octahedra, and edges with three equivalent O(5)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 4-10°. In the eighteenth O site, O(18) is bonded to one Li(10), one Li(14), one Li(2), one Li(6), one Co(4), and one Co(6) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(14)Li3Mn2Co octahedra,  a cornercorner with one O(16)Li3Mn2Co octahedra,  a cornercorner with one O(4)Li3Mn2Co octahedra,  a cornercorner with one O(22)Li4Co2 octahedra,  a cornercorner with one O(24)Li4Co2 octahedra,  a cornercorner with one O(8)Li4Co2 octahedra,  an edgeedge with one O(14)Li3Mn2Co octahedra,  an edgeedge with one O(16)Li3Mn2Co octahedra,  an edgeedge with one O(4)Li3Mn2Co octahedra,  an edgeedge with one O(22)Li4Co2 octahedra,  an edgeedge with one O(24)Li4Co2 octahedra,  an edgeedge with one O(8)Li4Co2 octahedra, edges with three equivalent O(20)Li4Co2 octahedra, and edges with three equivalent O(6)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 3-14°. In the nineteenth O site, O(19) is bonded to one Li(1), one Li(13), one Li(5), one Li(9), one Co(3), and one Co(5) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(13)Li3Mn2Co octahedra,  a cornercorner with one O(15)Li3Mn2Co octahedra,  a cornercorner with one O(3)Li3Mn2Co octahedra,  a cornercorner with one O(21)Li4Co2 octahedra,  a cornercorner with one O(23)Li4Co2 octahedra,  a cornercorner with one O(7)Li4Co2 octahedra,  an edgeedge with one O(13)Li3Mn2Co octahedra,  an edgeedge with one O(15)Li3Mn2Co octahedra,  an edgeedge with one O(3)Li3Mn2Co octahedra,  an edgeedge with one O(21)Li4Co2 octahedra,  an edgeedge with one O(23)Li4Co2 octahedra,  an edgeedge with one O(7)Li4Co2 octahedra, edges with three equivalent O(17)Li4Co2 octahedra, and edges with three equivalent O(5)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 3-15°. In the twentieth O site, O(20) is bonded to one Li(10), one Li(14), one Li(2), one Li(6), one Co(4), and one Co(6) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(14)Li3Mn2Co octahedra,  a cornercorner with one O(16)Li3Mn2Co octahedra,  a cornercorner with one O(4)Li3Mn2Co octahedra,  a cornercorner with one O(22)Li4Co2 octahedra,  a cornercorner with one O(24)Li4Co2 octahedra,  a cornercorner with one O(8)Li4Co2 octahedra,  an edgeedge with one O(14)Li3Mn2Co octahedra,  an edgeedge with one O(16)Li3Mn2Co octahedra,  an edgeedge with one O(4)Li3Mn2Co octahedra,  an edgeedge with one O(22)Li4Co2 octahedra,  an edgeedge with one O(24)Li4Co2 octahedra,  an edgeedge with one O(8)Li4Co2 octahedra, edges with three equivalent O(18)Li4Co2 octahedra, and edges with three equivalent O(6)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 4-12°. In the twenty-first O site, O(21) is bonded to one Li(1), one Li(11), one Li(3), one Li(7), one Co(3), and one Co(5) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(1)Li3Mn2Co octahedra,  a cornercorner with one O(11)Li3Mn2Co octahedra,  a cornercorner with one O(9)Li3Mn2Co octahedra,  a cornercorner with one O(17)Li4Co2 octahedra,  a cornercorner with one O(19)Li4Co2 octahedra,  a cornercorner with one O(5)Li4Co2 octahedra,  an edgeedge with one O(1)Li3Mn2Co octahedra,  an edgeedge with one O(11)Li3Mn2Co octahedra,  an edgeedge with one O(9)Li3Mn2Co octahedra,  an edgeedge with one O(17)Li4Co2 octahedra,  an edgeedge with one O(19)Li4Co2 octahedra,  an edgeedge with one O(5)Li4Co2 octahedra, edges with three equivalent O(23)Li4Co2 octahedra, and edges with three equivalent O(7)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 3-14°. In the twenty-second O site, O(22) is bonded to one Li(12), one Li(2), one Li(4), one Li(8), one Co(4), and one Co(6) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(10)Li3Mn2Co octahedra,  a cornercorner with one O(12)Li3Mn2Co octahedra,  a cornercorner with one O(2)Li3Mn2Co octahedra,  a cornercorner with one O(18)Li4Co2 octahedra,  a cornercorner with one O(20)Li4Co2 octahedra,  a cornercorner with one O(6)Li4Co2 octahedra,  an edgeedge with one O(10)Li3Mn2Co octahedra,  an edgeedge with one O(12)Li3Mn2Co octahedra,  an edgeedge with one O(2)Li3Mn2Co octahedra,  an edgeedge with one O(18)Li4Co2 octahedra,  an edgeedge with one O(20)Li4Co2 octahedra,  an edgeedge with one O(6)Li4Co2 octahedra, edges with three equivalent O(24)Li4Co2 octahedra, and edges with three equivalent O(8)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 3-10°. In the twenty-third O site, O(23) is bonded to one Li(1), one Li(11), one Li(3), one Li(7), one Co(3), and one Co(5) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(1)Li3Mn2Co octahedra,  a cornercorner with one O(11)Li3Mn2Co octahedra,  a cornercorner with one O(9)Li3Mn2Co octahedra,  a cornercorner with one O(17)Li4Co2 octahedra,  a cornercorner with one O(19)Li4Co2 octahedra,  a cornercorner with one O(5)Li4Co2 octahedra,  an edgeedge with one O(1)Li3Mn2Co octahedra,  an edgeedge with one O(11)Li3Mn2Co octahedra,  an edgeedge with one O(9)Li3Mn2Co octahedra,  an edgeedge with one O(17)Li4Co2 octahedra,  an edgeedge with one O(19)Li4Co2 octahedra,  an edgeedge with one O(5)Li4Co2 octahedra, edges with three equivalent O(21)Li4Co2 octahedra, and edges with three equivalent O(7)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 4-11°. In the twenty-fourth O site, O(24) is bonded to one Li(12), one Li(2), one Li(4), one Li(8), one Co(4), and one Co(6) atom to form OLi4Co2 octahedra that share  a cornercorner with one O(10)Li3Mn2Co octahedra,  a cornercorner with one O(12)Li3Mn2Co octahedra,  a cornercorner with one O(2)Li3Mn2Co octahedra,  a cornercorner with one O(18)Li4Co2 octahedra,  a cornercorner with one O(20)Li4Co2 octahedra,  a cornercorner with one O(6)Li4Co2 octahedra,  an edgeedge with one O(10)Li3Mn2Co octahedra,  an edgeedge with one O(12)Li3Mn2Co octahedra,  an edgeedge with one O(2)Li3Mn2Co octahedra,  an edgeedge with one O(18)Li4Co2 octahedra,  an edgeedge with one O(20)Li4Co2 octahedra,  an edgeedge with one O(6)Li4Co2 octahedra, edges with three equivalent O(22)Li4Co2 octahedra, and edges with three equivalent O(8)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 3-16°. is represented by the CIF card [CIF]
data_Li7Mn2(CoO4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.013
_cell_length_b   5.013
_cell_length_c   19.487
_cell_angle_alpha   86.876
_cell_angle_beta   86.922
_cell_angle_gamma   118.949
_symmetry_Int_Tables_number   1
_cell_volume   426.031
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.588  0.920  0.250  1.0
  Li  Li1  1  0.079  0.412  0.750  1.0
  Li  Li2  1  0.957  0.284  0.137  1.0
  Li  Li3  1  0.450  0.792  0.638  1.0
  Li  Li4  1  0.208  0.549  0.363  1.0
  Li  Li5  1  0.717  0.045  0.863  1.0
  Li  Li6  1  0.292  0.943  0.135  1.0
  Li  Li7  1  0.803  0.461  0.636  1.0
  Li  Li8  1  0.538  0.196  0.364  1.0
  Li  Li9  1  0.057  0.709  0.865  1.0
  Li  Li10  1  0.632  0.640  0.137  1.0
  Li  Li11  1  0.114  0.131  0.636  1.0
  Li  Li12  1  0.868  0.884  0.364  1.0
  Li  Li13  1  0.361  0.370  0.863  1.0
  Mn  Mn14  1  0.498  0.501  0.500  1.0
  Mn  Mn15  1  0.669  0.332  0.000  1.0
  Mn  Mn16  1  0.162  0.837  0.500  1.0
  Mn  Mn17  1  0.005  0.995  1.000  1.0
  Co  Co18  1  0.334  0.666  1.000  1.0
  Co  Co19  1  0.833  0.166  0.500  1.0
  Co  Co20  1  0.254  0.249  0.250  1.0
  Co  Co21  1  0.750  0.746  0.750  1.0
  Co  Co22  1  0.912  0.583  0.250  1.0
  Co  Co23  1  0.417  0.089  0.750  1.0
  O  O24  1  0.646  0.971  0.053  1.0
  O  O25  1  0.138  0.479  0.553  1.0
  O  O26  1  0.520  0.861  0.447  1.0
  O  O27  1  0.029  0.355  0.947  1.0
  O  O28  1  0.905  0.261  0.307  1.0
  O  O29  1  0.418  0.756  0.806  1.0
  O  O30  1  0.246  0.583  0.194  1.0
  O  O31  1  0.739  0.095  0.693  1.0
  O  O32  1  0.010  0.675  0.056  1.0
  O  O33  1  0.475  0.140  0.552  1.0
  O  O34  1  0.307  0.310  0.053  1.0
  O  O35  1  0.842  0.842  0.557  1.0
  O  O36  1  0.859  0.524  0.448  1.0
  O  O37  1  0.325  0.990  0.944  1.0
  O  O38  1  0.157  0.157  0.443  1.0
  O  O39  1  0.691  0.693  0.947  1.0
  O  O40  1  0.202  0.889  0.306  1.0
  O  O41  1  0.701  0.378  0.808  1.0
  O  O42  1  0.577  0.552  0.308  1.0
  O  O43  1  0.082  0.051  0.807  1.0
  O  O44  1  0.624  0.301  0.192  1.0
  O  O45  1  0.109  0.797  0.694  1.0
  O  O46  1  0.950  0.919  0.193  1.0
  O  O47  1  0.447  0.422  0.692  1.0
[/CIF]
.