The structure described by Sb3PbAgS6 crystallizes in the monoclinic Pc space group. Ag(1) is bonded in a distorted trigonal non-coplanar geometry to one S(2), one S(5), and one S(6) atom. Pb(1) is bonded in a distorted rectangular see-saw-like geometry to one S(2), one S(5), and two equivalent S(3) atoms. There are three inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a distorted T-shaped geometry to one S(2), one S(5), and one S(6) atom. In the second Sb site, Sb(2) is bonded in a distorted T-shaped geometry to one S(1), one S(3), and one S(4) atom. In the third Sb site, Sb(3) is bonded in a distorted trigonal non-coplanar geometry to one S(1), one S(4), and one S(6) atom. There are six inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one Sb(2) and one Sb(3) atom. In the second S site, S(2) is bonded in a T-shaped geometry to one Ag(1), one Pb(1), and one Sb(1) atom. In the third S site, S(3) is bonded in a 3-coordinate geometry to two equivalent Pb(1) and one Sb(2) atom. In the fourth S site, S(4) is bonded in an L-shaped geometry to one Sb(2) and one Sb(3) atom. In the fifth S site, S(5) is bonded in a distorted trigonal non-coplanar geometry to one Ag(1), one Pb(1), and one Sb(1) atom. In the sixth S site, S(6) is bonded in a distorted T-shaped geometry to one Ag(1), one Sb(1), and one Sb(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_AgSb3PbS6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.463
_cell_length_b   13.012
_cell_length_c   11.767
_cell_angle_alpha   113.642
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   766.291
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.384  0.944  0.256  1.0
  Ag  Ag1  1  0.616  0.444  0.756  1.0
  Sb  Sb2  1  0.638  0.703  0.044  1.0
  Sb  Sb3  1  0.712  0.772  0.499  1.0
  Sb  Sb4  1  0.281  0.549  0.244  1.0
  Sb  Sb5  1  0.719  0.050  0.744  1.0
  Sb  Sb6  1  0.288  0.272  0.999  1.0
  Sb  Sb7  1  0.362  0.203  0.544  1.0
  Pb  Pb8  1  0.663  0.256  0.287  1.0
  Pb  Pb9  1  0.337  0.756  0.787  1.0
  S  S10  1  0.541  0.102  0.956  1.0
  S  S11  1  0.520  0.374  0.531  1.0
  S  S12  1  0.480  0.874  0.031  1.0
  S  S13  1  0.459  0.602  0.456  1.0
  S  S14  1  0.192  0.290  0.210  1.0
  S  S15  1  0.808  0.790  0.710  1.0
  S  S16  1  0.593  0.433  0.091  1.0
  S  S17  1  0.407  0.933  0.591  1.0
  S  S18  1  0.348  0.589  0.888  1.0
  S  S19  1  0.652  0.089  0.388  1.0
  S  S20  1  0.411  0.738  0.244  1.0
  S  S21  1  0.589  0.238  0.744  1.0
[/CIF]
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The structure described by Sb3PbAgS6 crystallizes in the monoclinic Pc space group. Ag(1) is bonded in a distorted trigonal non-coplanar geometry to one S(2), one S(5), and one S(6) atom. Pb(1) is bonded in a distorted rectangular see-saw-like geometry to one S(2), one S(5), and two equivalent S(3) atoms. There are three inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a distorted T-shaped geometry to one S(2), one S(5), and one S(6) atom. In the second Sb site, Sb(2) is bonded in a distorted T-shaped geometry to one S(1), one S(3), and one S(4) atom. In the third Sb site, Sb(3) is bonded in a distorted trigonal non-coplanar geometry to one S(1), one S(4), and one S(6) atom. There are six inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one Sb(2) and one Sb(3) atom. In the second S site, S(2) is bonded in a T-shaped geometry to one Ag(1), one Pb(1), and one Sb(1) atom. In the third S site, S(3) is bonded in a 3-coordinate geometry to two equivalent Pb(1) and one Sb(2) atom. In the fourth S site, S(4) is bonded in an L-shaped geometry to one Sb(2) and one Sb(3) atom. In the fifth S site, S(5) is bonded in a distorted trigonal non-coplanar geometry to one Ag(1), one Pb(1), and one Sb(1) atom. In the sixth S site, S(6) is bonded in a distorted T-shaped geometry to one Ag(1), one Sb(1), and one Sb(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_AgSb3PbS6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.463
_cell_length_b   13.012
_cell_length_c   11.767
_cell_angle_alpha   113.642
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   766.291
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.384  0.944  0.256  1.0
  Ag  Ag1  1  0.616  0.444  0.756  1.0
  Sb  Sb2  1  0.638  0.703  0.044  1.0
  Sb  Sb3  1  0.712  0.772  0.499  1.0
  Sb  Sb4  1  0.281  0.549  0.244  1.0
  Sb  Sb5  1  0.719  0.050  0.744  1.0
  Sb  Sb6  1  0.288  0.272  0.999  1.0
  Sb  Sb7  1  0.362  0.203  0.544  1.0
  Pb  Pb8  1  0.663  0.256  0.287  1.0
  Pb  Pb9  1  0.337  0.756  0.787  1.0
  S  S10  1  0.541  0.102  0.956  1.0
  S  S11  1  0.520  0.374  0.531  1.0
  S  S12  1  0.480  0.874  0.031  1.0
  S  S13  1  0.459  0.602  0.456  1.0
  S  S14  1  0.192  0.290  0.210  1.0
  S  S15  1  0.808  0.790  0.710  1.0
  S  S16  1  0.593  0.433  0.091  1.0
  S  S17  1  0.407  0.933  0.591  1.0
  S  S18  1  0.348  0.589  0.888  1.0
  S  S19  1  0.652  0.089  0.388  1.0
  S  S20  1  0.411  0.738  0.244  1.0
  S  S21  1  0.589  0.238  0.744  1.0
[/CIF]
.