The material described by DyTiCo11 crystallizes in the orthorhombic Imm2 space group. Dy(1) is bonded in a 20-coordinate geometry to one Ti(1), one Co(5), two equivalent Co(1), two equivalent Co(2), two equivalent Co(6), four equivalent Co(3), and eight equivalent Co(4) atoms. Ti(1) is bonded in a 14-coordinate geometry to one Dy(1), one Co(5), two equivalent Co(2), two equivalent Co(3), four equivalent Co(4), and four equivalent Co(6) atoms. There are six inequivalent Co sites. In the first Co site, Co(1) is bonded to two equivalent Dy(1), two equivalent Co(3), two equivalent Co(5), two equivalent Co(6), and four equivalent Co(4) atoms to form distorted CoDy2Co10 cuboctahedra that share corners with eight equivalent Co(4)Dy2TiCo9 cuboctahedra, edges with two equivalent Co(1)Dy2Co10 cuboctahedra, edges with four equivalent Co(4)Dy2TiCo9 cuboctahedra, and faces with eight equivalent Co(4)Dy2TiCo9 cuboctahedra. In the second Co site, Co(2) is bonded in a 12-coordinate geometry to two equivalent Dy(1), two equivalent Ti(1), two equivalent Co(3), two equivalent Co(6), and four equivalent Co(4) atoms. In the third Co site, Co(3) is bonded in a 12-coordinate geometry to two equivalent Dy(1), one Ti(1), one Co(1), one Co(2), one Co(5), two equivalent Co(6), and four equivalent Co(4) atoms. In the fourth Co site, Co(4) is bonded to two equivalent Dy(1), one Ti(1), one Co(1), one Co(2), one Co(5), two equivalent Co(3), two equivalent Co(4), and two equivalent Co(6) atoms to form distorted CoDy2TiCo9 cuboctahedra that share corners with two equivalent Co(1)Dy2Co10 cuboctahedra, corners with ten equivalent Co(4)Dy2TiCo9 cuboctahedra,  an edgeedge with one Co(1)Dy2Co10 cuboctahedra, edges with four equivalent Co(4)Dy2TiCo9 cuboctahedra, faces with two equivalent Co(1)Dy2Co10 cuboctahedra, and faces with six equivalent Co(4)Dy2TiCo9 cuboctahedra. In the fifth Co site, Co(5) is bonded in a 1-coordinate geometry to one Dy(1), one Ti(1), two equivalent Co(1), two equivalent Co(3), four equivalent Co(4), and four equivalent Co(6) atoms. In the sixth Co site, Co(6) is bonded in a 14-coordinate geometry to one Dy(1), two equivalent Ti(1), one Co(1), one Co(2), one Co(6), two equivalent Co(3), two equivalent Co(5), and four equivalent Co(4) atoms. is represented by the CIF file [CIF]
data_DyTiCo11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.689
_cell_length_b   6.345
_cell_length_c   6.345
_cell_angle_alpha   97.603
_cell_angle_beta   111.685
_cell_angle_gamma   68.315
_symmetry_Int_Tables_number   1
_cell_volume   162.987
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  1  0.007  0.993  0.007  1.0
  Ti  Ti1  1  0.630  0.370  0.630  1.0
  Co  Co2  1  0.726  0.774  0.226  1.0
  Co  Co3  1  0.281  0.219  0.781  1.0
  Co  Co4  1  0.499  0.783  0.781  1.0
  Co  Co5  1  0.499  0.219  0.217  1.0
  Co  Co6  1  0.500  0.996  0.499  1.0
  Co  Co7  1  0.004  0.996  0.499  1.0
  Co  Co8  1  0.500  0.501  0.004  1.0
  Co  Co9  1  0.004  0.501  0.004  1.0
  Co  Co10  1  0.354  0.646  0.354  1.0
  Co  Co11  1  0.999  0.360  0.358  1.0
  Co  Co12  1  0.999  0.642  0.640  1.0
[/CIF]
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The material described by DyTiCo11 crystallizes in the orthorhombic Imm2 space group. Dy(1) is bonded in a 20-coordinate geometry to one Ti(1), one Co(5), two equivalent Co(1), two equivalent Co(2), two equivalent Co(6), four equivalent Co(3), and eight equivalent Co(4) atoms. Ti(1) is bonded in a 14-coordinate geometry to one Dy(1), one Co(5), two equivalent Co(2), two equivalent Co(3), four equivalent Co(4), and four equivalent Co(6) atoms. There are six inequivalent Co sites. In the first Co site, Co(1) is bonded to two equivalent Dy(1), two equivalent Co(3), two equivalent Co(5), two equivalent Co(6), and four equivalent Co(4) atoms to form distorted CoDy2Co10 cuboctahedra that share corners with eight equivalent Co(4)Dy2TiCo9 cuboctahedra, edges with two equivalent Co(1)Dy2Co10 cuboctahedra, edges with four equivalent Co(4)Dy2TiCo9 cuboctahedra, and faces with eight equivalent Co(4)Dy2TiCo9 cuboctahedra. In the second Co site, Co(2) is bonded in a 12-coordinate geometry to two equivalent Dy(1), two equivalent Ti(1), two equivalent Co(3), two equivalent Co(6), and four equivalent Co(4) atoms. In the third Co site, Co(3) is bonded in a 12-coordinate geometry to two equivalent Dy(1), one Ti(1), one Co(1), one Co(2), one Co(5), two equivalent Co(6), and four equivalent Co(4) atoms. In the fourth Co site, Co(4) is bonded to two equivalent Dy(1), one Ti(1), one Co(1), one Co(2), one Co(5), two equivalent Co(3), two equivalent Co(4), and two equivalent Co(6) atoms to form distorted CoDy2TiCo9 cuboctahedra that share corners with two equivalent Co(1)Dy2Co10 cuboctahedra, corners with ten equivalent Co(4)Dy2TiCo9 cuboctahedra,  an edgeedge with one Co(1)Dy2Co10 cuboctahedra, edges with four equivalent Co(4)Dy2TiCo9 cuboctahedra, faces with two equivalent Co(1)Dy2Co10 cuboctahedra, and faces with six equivalent Co(4)Dy2TiCo9 cuboctahedra. In the fifth Co site, Co(5) is bonded in a 1-coordinate geometry to one Dy(1), one Ti(1), two equivalent Co(1), two equivalent Co(3), four equivalent Co(4), and four equivalent Co(6) atoms. In the sixth Co site, Co(6) is bonded in a 14-coordinate geometry to one Dy(1), two equivalent Ti(1), one Co(1), one Co(2), one Co(6), two equivalent Co(3), two equivalent Co(5), and four equivalent Co(4) atoms. is represented by the CIF file [CIF]
data_DyTiCo11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.689
_cell_length_b   6.345
_cell_length_c   6.345
_cell_angle_alpha   97.603
_cell_angle_beta   111.685
_cell_angle_gamma   68.315
_symmetry_Int_Tables_number   1
_cell_volume   162.987
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  1  0.007  0.993  0.007  1.0
  Ti  Ti1  1  0.630  0.370  0.630  1.0
  Co  Co2  1  0.726  0.774  0.226  1.0
  Co  Co3  1  0.281  0.219  0.781  1.0
  Co  Co4  1  0.499  0.783  0.781  1.0
  Co  Co5  1  0.499  0.219  0.217  1.0
  Co  Co6  1  0.500  0.996  0.499  1.0
  Co  Co7  1  0.004  0.996  0.499  1.0
  Co  Co8  1  0.500  0.501  0.004  1.0
  Co  Co9  1  0.004  0.501  0.004  1.0
  Co  Co10  1  0.354  0.646  0.354  1.0
  Co  Co11  1  0.999  0.360  0.358  1.0
  Co  Co12  1  0.999  0.642  0.640  1.0
[/CIF]
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