The crystal structure described by TiSi2 is Modderite-like structured and crystallizes in the orthorhombic Fddd space group. Ti(1) is bonded in a 6-coordinate geometry to six equivalent Si(1) atoms. Si(1) is bonded in a 6-coordinate geometry to three equivalent Ti(1) and three equivalent Si(1) atoms. is represented by the CIF file [CIF]
data_TiSi2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.309
_cell_length_b   5.262
_cell_length_c   5.052
_cell_angle_alpha   61.920
_cell_angle_beta   60.989
_cell_angle_gamma   57.091
_symmetry_Int_Tables_number   1
_cell_volume   99.410
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.875  0.875  0.875  1.0
  Ti  Ti1  1  0.125  0.125  0.125  1.0
  Si  Si2  1  0.209  0.209  0.541  1.0
  Si  Si3  1  0.541  0.541  0.209  1.0
  Si  Si4  1  0.791  0.791  0.459  1.0
  Si  Si5  1  0.459  0.459  0.791  1.0
[/CIF]
.
The crystal structure described by TiSi2 is Modderite-like structured and crystallizes in the orthorhombic Fddd space group. Ti(1) is bonded in a 6-coordinate geometry to six equivalent Si(1) atoms. Si(1) is bonded in a 6-coordinate geometry to three equivalent Ti(1) and three equivalent Si(1) atoms. is represented by the CIF file [CIF]
data_TiSi2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.309
_cell_length_b   5.262
_cell_length_c   5.052
_cell_angle_alpha   61.920
_cell_angle_beta   60.989
_cell_angle_gamma   57.091
_symmetry_Int_Tables_number   1
_cell_volume   99.410
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.875  0.875  0.875  1.0
  Ti  Ti1  1  0.125  0.125  0.125  1.0
  Si  Si2  1  0.209  0.209  0.541  1.0
  Si  Si3  1  0.541  0.541  0.209  1.0
  Si  Si4  1  0.791  0.791  0.459  1.0
  Si  Si5  1  0.459  0.459  0.791  1.0
[/CIF]
.