The structure described by K2MnP2H2(O4F)2 crystallizes in the triclinic P-1 space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 8-coordinate geometry to one H(1), one O(1), one O(3), one O(5), one O(6), one O(7), one F(1), and one F(2) atom. In the second K site, K(2) is bonded in a 5-coordinate geometry to one O(4), one O(7), one O(8), one F(1), and one F(2) atom. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to two equivalent O(6), two equivalent O(8), and two equivalent F(2) atoms to form MnO4F2 octahedra that share corners with four equivalent P(2)O4 tetrahedra. In the second Mn site, Mn(2) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent F(1) atoms to form MnO4F2 octahedra that share corners with four equivalent P(1)O4 tetrahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form PO4 tetrahedra that share corners with two equivalent Mn(2)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 48-49°. In the second P site, P(2) is bonded to one O(5), one O(6), one O(7), and one O(8) atom to form PO4 tetrahedra that share corners with two equivalent Mn(1)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 47-51°. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one K(1) and one O(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(4) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one K(1), one Mn(2), and one P(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Mn(2) and one P(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one K(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a distorted water-like geometry to one K(2), one P(1), and one H(2) atom. In the fifth O site, O(5) is bonded in a distorted water-like geometry to one K(1), one P(2), and one H(1) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one K(1), one Mn(1), and one P(2) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one K(1), one K(2), and one P(2) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one K(2), one Mn(1), and one P(2) atom. There are two inequivalent F sites. In the first F site, F(2) is bonded in a distorted single-bond geometry to one K(1), one K(2), and one Mn(1) atom. In the second F site, F(1) is bonded in a distorted single-bond geometry to one K(1), one K(2), and one Mn(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_K2MnP2H2(O4F)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.662
_cell_length_b   8.264
_cell_length_c   12.545
_cell_angle_alpha   89.686
_cell_angle_beta   88.824
_cell_angle_gamma   89.380
_symmetry_Int_Tables_number   1
_cell_volume   483.208
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.508  0.604  0.693  1.0
  K  K1  1  0.492  0.396  0.307  1.0
  K  K2  1  0.489  0.104  0.801  1.0
  K  K3  1  0.511  0.896  0.199  1.0
  Mn  Mn4  1  0.500  0.000  0.500  1.0
  Mn  Mn5  1  0.500  0.500  0.000  1.0
  P  P6  1  1.000  0.277  0.094  1.0
  P  P7  1  0.000  0.723  0.906  1.0
  P  P8  1  0.997  0.225  0.588  1.0
  P  P9  1  0.003  0.775  0.412  1.0
  H  H10  1  0.942  0.409  0.466  1.0
  H  H11  1  0.058  0.591  0.534  1.0
  H  H12  1  0.940  0.098  0.970  1.0
  H  H13  1  0.060  0.902  0.030  1.0
  O  O14  1  0.755  0.405  0.105  1.0
  O  O15  1  0.245  0.595  0.895  1.0
  O  O16  1  0.241  0.317  0.011  1.0
  O  O17  1  0.759  0.683  0.989  1.0
  O  O18  1  0.903  0.773  0.797  1.0
  O  O19  1  0.097  0.227  0.203  1.0
  O  O20  1  0.848  0.121  0.039  1.0
  O  O21  1  0.152  0.879  0.961  1.0
  O  O22  1  0.837  0.380  0.531  1.0
  O  O23  1  0.163  0.620  0.469  1.0
  O  O24  1  0.760  0.815  0.495  1.0
  O  O25  1  0.240  0.185  0.505  1.0
  O  O26  1  0.094  0.276  0.696  1.0
  O  O27  1  0.906  0.724  0.304  1.0
  O  O28  1  0.757  0.097  0.601  1.0
  O  O29  1  0.243  0.903  0.399  1.0
  F  F30  1  0.676  0.396  0.885  1.0
  F  F31  1  0.324  0.604  0.115  1.0
  F  F32  1  0.321  0.905  0.616  1.0
  F  F33  1  0.679  0.095  0.384  1.0
[/CIF]
.
The structure described by K2MnP2H2(O4F)2 crystallizes in the triclinic P-1 space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 8-coordinate geometry to one H(1), one O(1), one O(3), one O(5), one O(6), one O(7), one F(1), and one F(2) atom. In the second K site, K(2) is bonded in a 5-coordinate geometry to one O(4), one O(7), one O(8), one F(1), and one F(2) atom. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to two equivalent O(6), two equivalent O(8), and two equivalent F(2) atoms to form MnO4F2 octahedra that share corners with four equivalent P(2)O4 tetrahedra. In the second Mn site, Mn(2) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent F(1) atoms to form MnO4F2 octahedra that share corners with four equivalent P(1)O4 tetrahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form PO4 tetrahedra that share corners with two equivalent Mn(2)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 48-49°. In the second P site, P(2) is bonded to one O(5), one O(6), one O(7), and one O(8) atom to form PO4 tetrahedra that share corners with two equivalent Mn(1)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 47-51°. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one K(1) and one O(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(4) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one K(1), one Mn(2), and one P(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Mn(2) and one P(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one K(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a distorted water-like geometry to one K(2), one P(1), and one H(2) atom. In the fifth O site, O(5) is bonded in a distorted water-like geometry to one K(1), one P(2), and one H(1) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one K(1), one Mn(1), and one P(2) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one K(1), one K(2), and one P(2) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one K(2), one Mn(1), and one P(2) atom. There are two inequivalent F sites. In the first F site, F(2) is bonded in a distorted single-bond geometry to one K(1), one K(2), and one Mn(1) atom. In the second F site, F(1) is bonded in a distorted single-bond geometry to one K(1), one K(2), and one Mn(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_K2MnP2H2(O4F)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.662
_cell_length_b   8.264
_cell_length_c   12.545
_cell_angle_alpha   89.686
_cell_angle_beta   88.824
_cell_angle_gamma   89.380
_symmetry_Int_Tables_number   1
_cell_volume   483.208
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.508  0.604  0.693  1.0
  K  K1  1  0.492  0.396  0.307  1.0
  K  K2  1  0.489  0.104  0.801  1.0
  K  K3  1  0.511  0.896  0.199  1.0
  Mn  Mn4  1  0.500  0.000  0.500  1.0
  Mn  Mn5  1  0.500  0.500  0.000  1.0
  P  P6  1  1.000  0.277  0.094  1.0
  P  P7  1  0.000  0.723  0.906  1.0
  P  P8  1  0.997  0.225  0.588  1.0
  P  P9  1  0.003  0.775  0.412  1.0
  H  H10  1  0.942  0.409  0.466  1.0
  H  H11  1  0.058  0.591  0.534  1.0
  H  H12  1  0.940  0.098  0.970  1.0
  H  H13  1  0.060  0.902  0.030  1.0
  O  O14  1  0.755  0.405  0.105  1.0
  O  O15  1  0.245  0.595  0.895  1.0
  O  O16  1  0.241  0.317  0.011  1.0
  O  O17  1  0.759  0.683  0.989  1.0
  O  O18  1  0.903  0.773  0.797  1.0
  O  O19  1  0.097  0.227  0.203  1.0
  O  O20  1  0.848  0.121  0.039  1.0
  O  O21  1  0.152  0.879  0.961  1.0
  O  O22  1  0.837  0.380  0.531  1.0
  O  O23  1  0.163  0.620  0.469  1.0
  O  O24  1  0.760  0.815  0.495  1.0
  O  O25  1  0.240  0.185  0.505  1.0
  O  O26  1  0.094  0.276  0.696  1.0
  O  O27  1  0.906  0.724  0.304  1.0
  O  O28  1  0.757  0.097  0.601  1.0
  O  O29  1  0.243  0.903  0.399  1.0
  F  F30  1  0.676  0.396  0.885  1.0
  F  F31  1  0.324  0.604  0.115  1.0
  F  F32  1  0.321  0.905  0.616  1.0
  F  F33  1  0.679  0.095  0.384  1.0
[/CIF]
.