The material structure described by KLi2MnCPO7 crystallizes in the monoclinic P2_1 space group. K(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(5), one O(6), and one O(7) atom. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(2), one O(3), and one O(6) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one P(1)O4 tetrahedra and corners with two equivalent Mn(1)O5 trigonal bipyramids. In the second Li site, Li(2) is bonded in a 3-coordinate geometry to one O(1), one O(3), and one O(4) atom. Mn(1) is bonded to one O(3), one O(4), one O(5), one O(6), and one O(7) atom to form distorted MnO5 trigonal bipyramids that share corners with two equivalent Li(1)O4 tetrahedra and corners with four equivalent P(1)O4 tetrahedra. C(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. P(1) is bonded to one O(4), one O(5), one O(6), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Li(1)O4 tetrahedra and corners with four equivalent Mn(1)O5 trigonal bipyramids. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one K(1), one Li(1), one Li(2), and one C(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one K(1), one Li(1), and one C(1) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to one K(1), one Li(1), one Li(2), one Mn(1), and one C(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Li(2), one Mn(1), and one P(1) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one K(1), one Mn(1), and one P(1) atom. In the sixth O site, O(6) is bonded in a distorted rectangular see-saw-like geometry to one K(1), one Li(1), one Mn(1), and one P(1) atom. In the seventh O site, O(7) is bonded in a distorted trigonal non-coplanar geometry to one K(1), one Mn(1), and one P(1) atom. is represented by the CIF card [CIF]
data_KLi2MnPCO7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.557
_cell_length_b   6.867
_cell_length_c   8.836
_cell_angle_alpha   89.999
_cell_angle_beta   87.648
_cell_angle_gamma   90.001
_symmetry_Int_Tables_number   1
_cell_volume   336.887
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.221  0.466  0.772  1.0
  K  K1  1  0.779  0.966  0.228  1.0
  Li  Li2  1  0.206  0.919  0.800  1.0
  Li  Li3  1  0.659  0.070  0.852  1.0
  Li  Li4  1  0.341  0.570  0.148  1.0
  Li  Li5  1  0.794  0.419  0.200  1.0
  Mn  Mn6  1  0.778  0.770  0.623  1.0
  Mn  Mn7  1  0.222  0.270  0.377  1.0
  P  P8  1  0.716  0.279  0.570  1.0
  P  P9  1  0.284  0.779  0.430  1.0
  C  C10  1  0.716  0.730  0.944  1.0
  C  C11  1  0.284  0.230  0.056  1.0
  O  O12  1  0.346  0.137  0.934  1.0
  O  O13  1  0.937  0.787  0.917  1.0
  O  O14  1  0.553  0.778  0.846  1.0
  O  O15  1  0.804  0.096  0.658  1.0
  O  O16  1  0.782  0.461  0.663  1.0
  O  O17  1  0.162  0.785  0.593  1.0
  O  O18  1  0.440  0.266  0.557  1.0
  O  O19  1  0.560  0.766  0.443  1.0
  O  O20  1  0.838  0.285  0.407  1.0
  O  O21  1  0.218  0.961  0.337  1.0
  O  O22  1  0.196  0.596  0.342  1.0
  O  O23  1  0.447  0.278  0.154  1.0
  O  O24  1  0.063  0.287  0.083  1.0
  O  O25  1  0.654  0.637  0.066  1.0
[/CIF]
.
The material structure described by KLi2MnCPO7 crystallizes in the monoclinic P2_1 space group. K(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(5), one O(6), and one O(7) atom. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(2), one O(3), and one O(6) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one P(1)O4 tetrahedra and corners with two equivalent Mn(1)O5 trigonal bipyramids. In the second Li site, Li(2) is bonded in a 3-coordinate geometry to one O(1), one O(3), and one O(4) atom. Mn(1) is bonded to one O(3), one O(4), one O(5), one O(6), and one O(7) atom to form distorted MnO5 trigonal bipyramids that share corners with two equivalent Li(1)O4 tetrahedra and corners with four equivalent P(1)O4 tetrahedra. C(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. P(1) is bonded to one O(4), one O(5), one O(6), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Li(1)O4 tetrahedra and corners with four equivalent Mn(1)O5 trigonal bipyramids. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one K(1), one Li(1), one Li(2), and one C(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one K(1), one Li(1), and one C(1) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to one K(1), one Li(1), one Li(2), one Mn(1), and one C(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Li(2), one Mn(1), and one P(1) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one K(1), one Mn(1), and one P(1) atom. In the sixth O site, O(6) is bonded in a distorted rectangular see-saw-like geometry to one K(1), one Li(1), one Mn(1), and one P(1) atom. In the seventh O site, O(7) is bonded in a distorted trigonal non-coplanar geometry to one K(1), one Mn(1), and one P(1) atom. is represented by the CIF card [CIF]
data_KLi2MnPCO7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.557
_cell_length_b   6.867
_cell_length_c   8.836
_cell_angle_alpha   89.999
_cell_angle_beta   87.648
_cell_angle_gamma   90.001
_symmetry_Int_Tables_number   1
_cell_volume   336.887
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.221  0.466  0.772  1.0
  K  K1  1  0.779  0.966  0.228  1.0
  Li  Li2  1  0.206  0.919  0.800  1.0
  Li  Li3  1  0.659  0.070  0.852  1.0
  Li  Li4  1  0.341  0.570  0.148  1.0
  Li  Li5  1  0.794  0.419  0.200  1.0
  Mn  Mn6  1  0.778  0.770  0.623  1.0
  Mn  Mn7  1  0.222  0.270  0.377  1.0
  P  P8  1  0.716  0.279  0.570  1.0
  P  P9  1  0.284  0.779  0.430  1.0
  C  C10  1  0.716  0.730  0.944  1.0
  C  C11  1  0.284  0.230  0.056  1.0
  O  O12  1  0.346  0.137  0.934  1.0
  O  O13  1  0.937  0.787  0.917  1.0
  O  O14  1  0.553  0.778  0.846  1.0
  O  O15  1  0.804  0.096  0.658  1.0
  O  O16  1  0.782  0.461  0.663  1.0
  O  O17  1  0.162  0.785  0.593  1.0
  O  O18  1  0.440  0.266  0.557  1.0
  O  O19  1  0.560  0.766  0.443  1.0
  O  O20  1  0.838  0.285  0.407  1.0
  O  O21  1  0.218  0.961  0.337  1.0
  O  O22  1  0.196  0.596  0.342  1.0
  O  O23  1  0.447  0.278  0.154  1.0
  O  O24  1  0.063  0.287  0.083  1.0
  O  O25  1  0.654  0.637  0.066  1.0
[/CIF]
.