The material described by XeF5AsF6 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four AsF6 clusters and four XeF5 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to one F(10), one F(11), one F(4), one F(6), one F(7), and one F(9) atom. There are six inequivalent F sites. In the first F site, F(10) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(11) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(6) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(7) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(9) is bonded in a single-bond geometry to one As(1) atom. In each XeF5 cluster, Xe(1) is bonded in a distorted square pyramidal geometry to one F(1), one F(2), one F(3), one F(5), and one F(8) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Xe(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Xe(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Xe(1) atom. In the fourth F site, F(5) is bonded in a single-bond geometry to one Xe(1) atom. In the fifth F site, F(8) is bonded in a single-bond geometry to one Xe(1) atom. is represented by the CIF card [CIF]
data_AsXeF11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   16.683
_cell_length_b   6.158
_cell_length_c   8.308
_cell_angle_alpha   87.259
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   852.551
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.606  0.604  0.799  1.0
  As  As1  1  0.106  0.396  0.701  1.0
  As  As2  1  0.394  0.396  0.201  1.0
  As  As3  1  0.894  0.604  0.299  1.0
  Xe  Xe4  1  0.106  0.797  0.252  1.0
  Xe  Xe5  1  0.394  0.797  0.752  1.0
  Xe  Xe6  1  0.606  0.203  0.248  1.0
  Xe  Xe7  1  0.894  0.203  0.748  1.0
  F  F8  1  0.308  0.927  0.620  1.0
  F  F9  1  0.921  0.895  0.722  1.0
  F  F10  1  0.312  0.838  0.921  1.0
  F  F11  1  0.540  0.828  0.856  1.0
  F  F12  1  0.341  0.526  0.691  1.0
  F  F13  1  0.692  0.073  0.380  1.0
  F  F14  1  0.917  0.476  0.495  1.0
  F  F15  1  0.417  0.524  0.005  1.0
  F  F16  1  0.188  0.838  0.421  1.0
  F  F17  1  0.960  0.828  0.356  1.0
  F  F18  1  0.879  0.738  0.112  1.0
  F  F19  1  0.460  0.172  0.144  1.0
  F  F20  1  0.192  0.927  0.120  1.0
  F  F21  1  0.448  0.818  0.542  1.0
  F  F22  1  0.159  0.526  0.191  1.0
  F  F23  1  0.841  0.474  0.809  1.0
  F  F24  1  0.948  0.182  0.958  1.0
  F  F25  1  0.687  0.734  0.886  1.0
  F  F26  1  0.083  0.524  0.505  1.0
  F  F27  1  0.052  0.818  0.042  1.0
  F  F28  1  0.808  0.073  0.880  1.0
  F  F29  1  0.313  0.266  0.114  1.0
  F  F30  1  0.621  0.738  0.612  1.0
  F  F31  1  0.187  0.266  0.614  1.0
  F  F32  1  0.421  0.105  0.778  1.0
  F  F33  1  0.813  0.734  0.386  1.0
  F  F34  1  0.812  0.162  0.579  1.0
  F  F35  1  0.486  0.512  0.272  1.0
  F  F36  1  0.014  0.512  0.772  1.0
  F  F37  1  0.379  0.262  0.388  1.0
  F  F38  1  0.688  0.162  0.079  1.0
  F  F39  1  0.583  0.476  0.995  1.0
  F  F40  1  0.840  0.376  0.247  1.0
  F  F41  1  0.040  0.172  0.644  1.0
  F  F42  1  0.121  0.262  0.888  1.0
  F  F43  1  0.340  0.624  0.253  1.0
  F  F44  1  0.660  0.376  0.747  1.0
  F  F45  1  0.514  0.488  0.728  1.0
  F  F46  1  0.579  0.895  0.222  1.0
  F  F47  1  0.659  0.474  0.309  1.0
  F  F48  1  0.160  0.624  0.753  1.0
  F  F49  1  0.986  0.488  0.228  1.0
  F  F50  1  0.552  0.182  0.458  1.0
  F  F51  1  0.079  0.105  0.278  1.0
[/CIF]
.
The material described by XeF5AsF6 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four AsF6 clusters and four XeF5 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to one F(10), one F(11), one F(4), one F(6), one F(7), and one F(9) atom. There are six inequivalent F sites. In the first F site, F(10) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(11) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(6) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(7) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(9) is bonded in a single-bond geometry to one As(1) atom. In each XeF5 cluster, Xe(1) is bonded in a distorted square pyramidal geometry to one F(1), one F(2), one F(3), one F(5), and one F(8) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Xe(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Xe(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Xe(1) atom. In the fourth F site, F(5) is bonded in a single-bond geometry to one Xe(1) atom. In the fifth F site, F(8) is bonded in a single-bond geometry to one Xe(1) atom. is represented by the CIF card [CIF]
data_AsXeF11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   16.683
_cell_length_b   6.158
_cell_length_c   8.308
_cell_angle_alpha   87.259
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   852.551
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.606  0.604  0.799  1.0
  As  As1  1  0.106  0.396  0.701  1.0
  As  As2  1  0.394  0.396  0.201  1.0
  As  As3  1  0.894  0.604  0.299  1.0
  Xe  Xe4  1  0.106  0.797  0.252  1.0
  Xe  Xe5  1  0.394  0.797  0.752  1.0
  Xe  Xe6  1  0.606  0.203  0.248  1.0
  Xe  Xe7  1  0.894  0.203  0.748  1.0
  F  F8  1  0.308  0.927  0.620  1.0
  F  F9  1  0.921  0.895  0.722  1.0
  F  F10  1  0.312  0.838  0.921  1.0
  F  F11  1  0.540  0.828  0.856  1.0
  F  F12  1  0.341  0.526  0.691  1.0
  F  F13  1  0.692  0.073  0.380  1.0
  F  F14  1  0.917  0.476  0.495  1.0
  F  F15  1  0.417  0.524  0.005  1.0
  F  F16  1  0.188  0.838  0.421  1.0
  F  F17  1  0.960  0.828  0.356  1.0
  F  F18  1  0.879  0.738  0.112  1.0
  F  F19  1  0.460  0.172  0.144  1.0
  F  F20  1  0.192  0.927  0.120  1.0
  F  F21  1  0.448  0.818  0.542  1.0
  F  F22  1  0.159  0.526  0.191  1.0
  F  F23  1  0.841  0.474  0.809  1.0
  F  F24  1  0.948  0.182  0.958  1.0
  F  F25  1  0.687  0.734  0.886  1.0
  F  F26  1  0.083  0.524  0.505  1.0
  F  F27  1  0.052  0.818  0.042  1.0
  F  F28  1  0.808  0.073  0.880  1.0
  F  F29  1  0.313  0.266  0.114  1.0
  F  F30  1  0.621  0.738  0.612  1.0
  F  F31  1  0.187  0.266  0.614  1.0
  F  F32  1  0.421  0.105  0.778  1.0
  F  F33  1  0.813  0.734  0.386  1.0
  F  F34  1  0.812  0.162  0.579  1.0
  F  F35  1  0.486  0.512  0.272  1.0
  F  F36  1  0.014  0.512  0.772  1.0
  F  F37  1  0.379  0.262  0.388  1.0
  F  F38  1  0.688  0.162  0.079  1.0
  F  F39  1  0.583  0.476  0.995  1.0
  F  F40  1  0.840  0.376  0.247  1.0
  F  F41  1  0.040  0.172  0.644  1.0
  F  F42  1  0.121  0.262  0.888  1.0
  F  F43  1  0.340  0.624  0.253  1.0
  F  F44  1  0.660  0.376  0.747  1.0
  F  F45  1  0.514  0.488  0.728  1.0
  F  F46  1  0.579  0.895  0.222  1.0
  F  F47  1  0.659  0.474  0.309  1.0
  F  F48  1  0.160  0.624  0.753  1.0
  F  F49  1  0.986  0.488  0.228  1.0
  F  F50  1  0.552  0.182  0.458  1.0
  F  F51  1  0.079  0.105  0.278  1.0
[/CIF]
.