The compound described by MnRh2O4 is Spinel structured and crystallizes in the cubic Fd-3m space group. Mn(1) is bonded to four equivalent O(1) atoms to form MnO4 tetrahedra that share corners with twelve equivalent Rh(1)O6 octahedra. The corner-sharing octahedral tilt angles are 59°. Rh(1) is bonded to six equivalent O(1) atoms to form RhO6 octahedra that share corners with six equivalent Mn(1)O4 tetrahedra and edges with six equivalent Rh(1)O6 octahedra. O(1) is bonded to one Mn(1) and three equivalent Rh(1) atoms to form a mixture of distorted edge and corner-sharing OMnRh3 trigonal pyramids. is represented by the CIF file [CIF]
data_Mn(RhO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.093
_cell_length_b   6.093
_cell_length_c   6.094
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.001
_symmetry_Int_Tables_number   1
_cell_volume   159.989
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.125  0.125  0.125  1.0
  Mn  Mn1  1  0.875  0.875  0.875  1.0
  Rh  Rh2  1  0.500  0.500  0.000  1.0
  Rh  Rh3  1  0.500  0.000  0.500  1.0
  Rh  Rh4  1  0.500  0.500  0.500  1.0
  Rh  Rh5  1  0.000  0.500  0.500  1.0
  O  O6  1  0.738  0.738  0.738  1.0
  O  O7  1  0.738  0.286  0.738  1.0
  O  O8  1  0.738  0.738  0.286  1.0
  O  O9  1  0.262  0.262  0.714  1.0
  O  O10  1  0.262  0.262  0.262  1.0
  O  O11  1  0.286  0.738  0.738  1.0
  O  O12  1  0.262  0.714  0.262  1.0
  O  O13  1  0.714  0.262  0.262  1.0
[/CIF]
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The compound described by MnRh2O4 is Spinel structured and crystallizes in the cubic Fd-3m space group. Mn(1) is bonded to four equivalent O(1) atoms to form MnO4 tetrahedra that share corners with twelve equivalent Rh(1)O6 octahedra. The corner-sharing octahedral tilt angles are 59°. Rh(1) is bonded to six equivalent O(1) atoms to form RhO6 octahedra that share corners with six equivalent Mn(1)O4 tetrahedra and edges with six equivalent Rh(1)O6 octahedra. O(1) is bonded to one Mn(1) and three equivalent Rh(1) atoms to form a mixture of distorted edge and corner-sharing OMnRh3 trigonal pyramids. is represented by the CIF file [CIF]
data_Mn(RhO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.093
_cell_length_b   6.093
_cell_length_c   6.094
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.001
_symmetry_Int_Tables_number   1
_cell_volume   159.989
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.125  0.125  0.125  1.0
  Mn  Mn1  1  0.875  0.875  0.875  1.0
  Rh  Rh2  1  0.500  0.500  0.000  1.0
  Rh  Rh3  1  0.500  0.000  0.500  1.0
  Rh  Rh4  1  0.500  0.500  0.500  1.0
  Rh  Rh5  1  0.000  0.500  0.500  1.0
  O  O6  1  0.738  0.738  0.738  1.0
  O  O7  1  0.738  0.286  0.738  1.0
  O  O8  1  0.738  0.738  0.286  1.0
  O  O9  1  0.262  0.262  0.714  1.0
  O  O10  1  0.262  0.262  0.262  1.0
  O  O11  1  0.286  0.738  0.738  1.0
  O  O12  1  0.262  0.714  0.262  1.0
  O  O13  1  0.714  0.262  0.262  1.0
[/CIF]
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