The material structure described by Cd(IO3)2 crystallizes in the orthorhombic P2_12_12_1 space group. Cd(1) is bonded to one O(2), one O(3), one O(4), one O(5), one O(6), and two equivalent O(1) atoms to form distorted corner-sharing CdO7 pentagonal bipyramids. There are six inequivalent O sites. In the first O site, O(6) is bonded in a 3-coordinate geometry to one Cd(1) and two equivalent I(1) atoms. In the second O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent Cd(1) and one I(2) atom. In the third O site, O(2) is bonded in a 2-coordinate geometry to one Cd(1) and one I(2) atom. In the fourth O site, O(3) is bonded in a 3-coordinate geometry to one Cd(1) and two equivalent I(2) atoms. In the fifth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one I(1) atom. In the sixth O site, O(5) is bonded in a 3-coordinate geometry to one Cd(1), one I(1), and one I(2) atom. There are two inequivalent I sites. In the first I site, I(1) is bonded in a 3-coordinate geometry to one O(4), one O(5), and two equivalent O(6) atoms. In the second I site, I(2) is bonded in a 3-coordinate geometry to one O(1), one O(2), one O(5), and two equivalent O(3) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Cd(IO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.581
_cell_length_b   5.854
_cell_length_c   17.408
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   568.714
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.709  0.173  0.094  1.0
  Cd  Cd1  1  0.209  0.327  0.906  1.0
  Cd  Cd2  1  0.291  0.673  0.406  1.0
  Cd  Cd3  1  0.791  0.827  0.594  1.0
  I  I4  1  0.248  0.780  0.710  1.0
  I  I5  1  0.748  0.720  0.290  1.0
  I  I6  1  0.752  0.280  0.790  1.0
  I  I7  1  0.252  0.220  0.210  1.0
  I  I8  1  0.037  0.638  0.077  1.0
  I  I9  1  0.537  0.862  0.923  1.0
  I  I10  1  0.963  0.138  0.423  1.0
  I  I11  1  0.463  0.362  0.577  1.0
  O  O12  1  0.541  0.604  0.516  1.0
  O  O13  1  0.041  0.896  0.484  1.0
  O  O14  1  0.459  0.104  0.984  1.0
  O  O15  1  0.959  0.396  0.016  1.0
  O  O16  1  0.608  0.494  0.661  1.0
  O  O17  1  0.108  0.006  0.339  1.0
  O  O18  1  0.392  0.994  0.839  1.0
  O  O19  1  0.892  0.506  0.161  1.0
  O  O20  1  0.717  0.185  0.547  1.0
  O  O21  1  0.217  0.315  0.453  1.0
  O  O22  1  0.283  0.685  0.953  1.0
  O  O23  1  0.783  0.815  0.047  1.0
  O  O24  1  0.044  0.024  0.164  1.0
  O  O25  1  0.544  0.476  0.836  1.0
  O  O26  1  0.956  0.524  0.336  1.0
  O  O27  1  0.456  0.976  0.664  1.0
  O  O28  1  0.361  0.374  0.125  1.0
  O  O29  1  0.861  0.126  0.875  1.0
  O  O30  1  0.639  0.874  0.375  1.0
  O  O31  1  0.139  0.626  0.625  1.0
  O  O32  1  0.515  0.037  0.209  1.0
  O  O33  1  0.015  0.463  0.791  1.0
  O  O34  1  0.485  0.537  0.291  1.0
  O  O35  1  0.985  0.963  0.709  1.0
[/CIF]
.
The material structure described by Cd(IO3)2 crystallizes in the orthorhombic P2_12_12_1 space group. Cd(1) is bonded to one O(2), one O(3), one O(4), one O(5), one O(6), and two equivalent O(1) atoms to form distorted corner-sharing CdO7 pentagonal bipyramids. There are six inequivalent O sites. In the first O site, O(6) is bonded in a 3-coordinate geometry to one Cd(1) and two equivalent I(1) atoms. In the second O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent Cd(1) and one I(2) atom. In the third O site, O(2) is bonded in a 2-coordinate geometry to one Cd(1) and one I(2) atom. In the fourth O site, O(3) is bonded in a 3-coordinate geometry to one Cd(1) and two equivalent I(2) atoms. In the fifth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one I(1) atom. In the sixth O site, O(5) is bonded in a 3-coordinate geometry to one Cd(1), one I(1), and one I(2) atom. There are two inequivalent I sites. In the first I site, I(1) is bonded in a 3-coordinate geometry to one O(4), one O(5), and two equivalent O(6) atoms. In the second I site, I(2) is bonded in a 3-coordinate geometry to one O(1), one O(2), one O(5), and two equivalent O(3) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Cd(IO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.581
_cell_length_b   5.854
_cell_length_c   17.408
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   568.714
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.709  0.173  0.094  1.0
  Cd  Cd1  1  0.209  0.327  0.906  1.0
  Cd  Cd2  1  0.291  0.673  0.406  1.0
  Cd  Cd3  1  0.791  0.827  0.594  1.0
  I  I4  1  0.248  0.780  0.710  1.0
  I  I5  1  0.748  0.720  0.290  1.0
  I  I6  1  0.752  0.280  0.790  1.0
  I  I7  1  0.252  0.220  0.210  1.0
  I  I8  1  0.037  0.638  0.077  1.0
  I  I9  1  0.537  0.862  0.923  1.0
  I  I10  1  0.963  0.138  0.423  1.0
  I  I11  1  0.463  0.362  0.577  1.0
  O  O12  1  0.541  0.604  0.516  1.0
  O  O13  1  0.041  0.896  0.484  1.0
  O  O14  1  0.459  0.104  0.984  1.0
  O  O15  1  0.959  0.396  0.016  1.0
  O  O16  1  0.608  0.494  0.661  1.0
  O  O17  1  0.108  0.006  0.339  1.0
  O  O18  1  0.392  0.994  0.839  1.0
  O  O19  1  0.892  0.506  0.161  1.0
  O  O20  1  0.717  0.185  0.547  1.0
  O  O21  1  0.217  0.315  0.453  1.0
  O  O22  1  0.283  0.685  0.953  1.0
  O  O23  1  0.783  0.815  0.047  1.0
  O  O24  1  0.044  0.024  0.164  1.0
  O  O25  1  0.544  0.476  0.836  1.0
  O  O26  1  0.956  0.524  0.336  1.0
  O  O27  1  0.456  0.976  0.664  1.0
  O  O28  1  0.361  0.374  0.125  1.0
  O  O29  1  0.861  0.126  0.875  1.0
  O  O30  1  0.639  0.874  0.375  1.0
  O  O31  1  0.139  0.626  0.625  1.0
  O  O32  1  0.515  0.037  0.209  1.0
  O  O33  1  0.015  0.463  0.791  1.0
  O  O34  1  0.485  0.537  0.291  1.0
  O  O35  1  0.985  0.963  0.709  1.0
[/CIF]
.