The material structure described by K2MnH4(OCl2)2 crystallizes in the tetragonal I-42m space group. K(1) is bonded in a body-centered cubic geometry to eight equivalent Cl(1) atoms. Mn(1) is bonded in an octahedral geometry to two equivalent O(1) and four equivalent Cl(1) atoms. H(1) is bonded in a single-bond geometry to one O(1) atom. O(1) is bonded in a distorted trigonal planar geometry to one Mn(1) and two equivalent H(1) atoms. Cl(1) is bonded to four equivalent K(1) and one Mn(1) atom to form a mixture of distorted edge, face, and corner-sharing ClK4Mn square pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_K2MnH4(Cl2O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.709
_cell_length_b   6.709
_cell_length_c   6.712
_cell_angle_alpha   112.592
_cell_angle_beta   112.592
_cell_angle_gamma   103.378
_symmetry_Int_Tables_number   1
_cell_volume   230.669
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cl  Cl0  1  0.235  0.748  1.000  1.0
  Cl  Cl1  1  0.765  0.765  0.513  1.0
  Cl  Cl2  1  0.252  0.252  0.487  1.0
  Cl  Cl3  1  0.748  0.235  1.000  1.0
  H  H4  1  0.738  0.738  0.150  1.0
  H  H5  1  0.412  0.262  1.000  1.0
  H  H6  1  0.262  0.412  1.000  1.0
  H  H7  1  0.588  0.588  0.850  1.0
  K  K8  1  0.250  0.750  0.500  1.0
  K  K9  1  0.750  0.250  0.500  1.0
  Mn  Mn10  1  0.000  0.000  0.000  1.0
  O  O11  1  0.266  0.266  1.000  1.0
  O  O12  1  0.734  0.734  0.000  1.0
[/CIF]
.
The material structure described by K2MnH4(OCl2)2 crystallizes in the tetragonal I-42m space group. K(1) is bonded in a body-centered cubic geometry to eight equivalent Cl(1) atoms. Mn(1) is bonded in an octahedral geometry to two equivalent O(1) and four equivalent Cl(1) atoms. H(1) is bonded in a single-bond geometry to one O(1) atom. O(1) is bonded in a distorted trigonal planar geometry to one Mn(1) and two equivalent H(1) atoms. Cl(1) is bonded to four equivalent K(1) and one Mn(1) atom to form a mixture of distorted edge, face, and corner-sharing ClK4Mn square pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_K2MnH4(Cl2O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.709
_cell_length_b   6.709
_cell_length_c   6.712
_cell_angle_alpha   112.592
_cell_angle_beta   112.592
_cell_angle_gamma   103.378
_symmetry_Int_Tables_number   1
_cell_volume   230.669
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cl  Cl0  1  0.235  0.748  1.000  1.0
  Cl  Cl1  1  0.765  0.765  0.513  1.0
  Cl  Cl2  1  0.252  0.252  0.487  1.0
  Cl  Cl3  1  0.748  0.235  1.000  1.0
  H  H4  1  0.738  0.738  0.150  1.0
  H  H5  1  0.412  0.262  1.000  1.0
  H  H6  1  0.262  0.412  1.000  1.0
  H  H7  1  0.588  0.588  0.850  1.0
  K  K8  1  0.250  0.750  0.500  1.0
  K  K9  1  0.750  0.250  0.500  1.0
  Mn  Mn10  1  0.000  0.000  0.000  1.0
  O  O11  1  0.266  0.266  1.000  1.0
  O  O12  1  0.734  0.734  0.000  1.0
[/CIF]
.