The structure described by Mn2FeC6(N3O2)2(O2)2 crystallizes in the monoclinic P2_1/c space group. The structure consists of four 7782-44-7 molecules inside a Mn2FeC6(N3O2)2 framework. In the Mn2FeC6(N3O2)2 framework, Mn(1) is bonded to one N(1), one N(2), one N(3), one O(1), and two equivalent O(2) atoms to form distorted edge-sharing MnN3O3 octahedra. Fe(1) is bonded in an octahedral geometry to two equivalent C(1), two equivalent C(2), and two equivalent C(3) atoms. There are three inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Fe(1) and one N(1) atom. In the second C site, C(2) is bonded in a linear geometry to one Fe(1) and one N(2) atom. In the third C site, C(3) is bonded in a linear geometry to one Fe(1) and one N(3) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to one Mn(1) and one C(1) atom. In the second N site, N(2) is bonded in a linear geometry to one Mn(1) and one C(2) atom. In the third N site, N(3) is bonded in a linear geometry to one Mn(1) and one C(3) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in a water-like geometry to two equivalent Mn(1) atoms. In the second O site, O(1) is bonded in a single-bond geometry to one Mn(1) atom. is represented by the CIF card [CIF]
data_Mn2FeC6(N3O4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.870
_cell_length_b   7.208
_cell_length_c   8.609
_cell_angle_alpha   81.116
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   727.774
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.419  0.089  0.080  1.0
  Mn  Mn1  1  0.081  0.589  0.580  1.0
  Mn  Mn2  1  0.581  0.911  0.920  1.0
  Mn  Mn3  1  0.919  0.411  0.420  1.0
  Fe  Fe4  1  0.000  0.000  0.000  1.0
  Fe  Fe5  1  0.500  0.500  0.500  1.0
  C  C6  1  0.154  0.020  0.075  1.0
  C  C7  1  0.346  0.520  0.575  1.0
  C  C8  1  0.846  0.980  0.925  1.0
  C  C9  1  0.654  0.480  0.425  1.0
  C  C10  1  0.950  0.169  0.142  1.0
  C  C11  1  0.550  0.669  0.642  1.0
  C  C12  1  0.050  0.831  0.858  1.0
  C  C13  1  0.450  0.331  0.358  1.0
  C  C14  1  0.036  0.221  0.847  1.0
  C  C15  1  0.464  0.721  0.347  1.0
  C  C16  1  0.964  0.779  0.153  1.0
  C  C17  1  0.536  0.279  0.653  1.0
  N  N18  1  0.249  0.043  0.107  1.0
  N  N19  1  0.251  0.543  0.607  1.0
  N  N20  1  0.751  0.957  0.893  1.0
  N  N21  1  0.749  0.457  0.393  1.0
  N  N22  1  0.927  0.268  0.233  1.0
  N  N23  1  0.573  0.768  0.733  1.0
  N  N24  1  0.073  0.732  0.767  1.0
  N  N25  1  0.427  0.232  0.267  1.0
  N  N26  1  0.060  0.354  0.757  1.0
  N  N27  1  0.440  0.854  0.257  1.0
  N  N28  1  0.940  0.646  0.243  1.0
  N  N29  1  0.560  0.146  0.743  1.0
  O  O30  1  0.393  0.296  0.962  1.0
  O  O31  1  0.107  0.796  0.462  1.0
  O  O32  1  0.607  0.704  0.038  1.0
  O  O33  1  0.893  0.204  0.538  1.0
  O  O34  1  0.426  0.923  0.939  1.0
  O  O35  1  0.074  0.423  0.439  1.0
  O  O36  1  0.574  0.077  0.061  1.0
  O  O37  1  0.926  0.577  0.561  1.0
  O  O38  1  0.255  0.095  0.666  1.0
  O  O39  1  0.245  0.595  0.166  1.0
  O  O40  1  0.745  0.905  0.334  1.0
  O  O41  1  0.755  0.405  0.834  1.0
  O  O42  1  0.217  0.098  0.534  1.0
  O  O43  1  0.283  0.598  0.034  1.0
  O  O44  1  0.783  0.902  0.466  1.0
  O  O45  1  0.717  0.402  0.966  1.0
[/CIF]
.
The structure described by Mn2FeC6(N3O2)2(O2)2 crystallizes in the monoclinic P2_1/c space group. The structure consists of four 7782-44-7 molecules inside a Mn2FeC6(N3O2)2 framework. In the Mn2FeC6(N3O2)2 framework, Mn(1) is bonded to one N(1), one N(2), one N(3), one O(1), and two equivalent O(2) atoms to form distorted edge-sharing MnN3O3 octahedra. Fe(1) is bonded in an octahedral geometry to two equivalent C(1), two equivalent C(2), and two equivalent C(3) atoms. There are three inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Fe(1) and one N(1) atom. In the second C site, C(2) is bonded in a linear geometry to one Fe(1) and one N(2) atom. In the third C site, C(3) is bonded in a linear geometry to one Fe(1) and one N(3) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to one Mn(1) and one C(1) atom. In the second N site, N(2) is bonded in a linear geometry to one Mn(1) and one C(2) atom. In the third N site, N(3) is bonded in a linear geometry to one Mn(1) and one C(3) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in a water-like geometry to two equivalent Mn(1) atoms. In the second O site, O(1) is bonded in a single-bond geometry to one Mn(1) atom. is represented by the CIF card [CIF]
data_Mn2FeC6(N3O4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.870
_cell_length_b   7.208
_cell_length_c   8.609
_cell_angle_alpha   81.116
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   727.774
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.419  0.089  0.080  1.0
  Mn  Mn1  1  0.081  0.589  0.580  1.0
  Mn  Mn2  1  0.581  0.911  0.920  1.0
  Mn  Mn3  1  0.919  0.411  0.420  1.0
  Fe  Fe4  1  0.000  0.000  0.000  1.0
  Fe  Fe5  1  0.500  0.500  0.500  1.0
  C  C6  1  0.154  0.020  0.075  1.0
  C  C7  1  0.346  0.520  0.575  1.0
  C  C8  1  0.846  0.980  0.925  1.0
  C  C9  1  0.654  0.480  0.425  1.0
  C  C10  1  0.950  0.169  0.142  1.0
  C  C11  1  0.550  0.669  0.642  1.0
  C  C12  1  0.050  0.831  0.858  1.0
  C  C13  1  0.450  0.331  0.358  1.0
  C  C14  1  0.036  0.221  0.847  1.0
  C  C15  1  0.464  0.721  0.347  1.0
  C  C16  1  0.964  0.779  0.153  1.0
  C  C17  1  0.536  0.279  0.653  1.0
  N  N18  1  0.249  0.043  0.107  1.0
  N  N19  1  0.251  0.543  0.607  1.0
  N  N20  1  0.751  0.957  0.893  1.0
  N  N21  1  0.749  0.457  0.393  1.0
  N  N22  1  0.927  0.268  0.233  1.0
  N  N23  1  0.573  0.768  0.733  1.0
  N  N24  1  0.073  0.732  0.767  1.0
  N  N25  1  0.427  0.232  0.267  1.0
  N  N26  1  0.060  0.354  0.757  1.0
  N  N27  1  0.440  0.854  0.257  1.0
  N  N28  1  0.940  0.646  0.243  1.0
  N  N29  1  0.560  0.146  0.743  1.0
  O  O30  1  0.393  0.296  0.962  1.0
  O  O31  1  0.107  0.796  0.462  1.0
  O  O32  1  0.607  0.704  0.038  1.0
  O  O33  1  0.893  0.204  0.538  1.0
  O  O34  1  0.426  0.923  0.939  1.0
  O  O35  1  0.074  0.423  0.439  1.0
  O  O36  1  0.574  0.077  0.061  1.0
  O  O37  1  0.926  0.577  0.561  1.0
  O  O38  1  0.255  0.095  0.666  1.0
  O  O39  1  0.245  0.595  0.166  1.0
  O  O40  1  0.745  0.905  0.334  1.0
  O  O41  1  0.755  0.405  0.834  1.0
  O  O42  1  0.217  0.098  0.534  1.0
  O  O43  1  0.283  0.598  0.034  1.0
  O  O44  1  0.783  0.902  0.466  1.0
  O  O45  1  0.717  0.402  0.966  1.0
[/CIF]
.