The structure described by La2NCl3 crystallizes in the orthorhombic Ibam space group. La(1) is bonded in a 8-coordinate geometry to two equivalent N(1), two equivalent Cl(1), and four equivalent Cl(2) atoms. N(1) is bonded to four equivalent La(1) atoms to form edge-sharing NLa4 tetrahedra. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 4-coordinate geometry to four equivalent La(1) atoms. In the second Cl site, Cl(2) is bonded in a 4-coordinate geometry to four equivalent La(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_La2NCl3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.166
_cell_length_b   6.943
_cell_length_c   8.324
_cell_angle_alpha   114.650
_cell_angle_beta   111.738
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   295.763
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.594  0.917  0.187  1.0
  La  La1  1  0.406  0.083  0.813  1.0
  La  La2  1  0.906  0.729  0.813  1.0
  La  La3  1  0.094  0.271  0.187  1.0
  N  N4  1  0.250  0.000  0.000  1.0
  N  N5  1  0.750  0.000  0.000  1.0
  Cl  Cl6  1  0.250  0.500  0.000  1.0
  Cl  Cl7  1  0.750  0.500  0.000  1.0
  Cl  Cl8  1  0.802  0.989  0.605  1.0
  Cl  Cl9  1  0.198  0.011  0.395  1.0
  Cl  Cl10  1  0.698  0.384  0.395  1.0
  Cl  Cl11  1  0.302  0.616  0.605  1.0
[/CIF]
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The structure described by La2NCl3 crystallizes in the orthorhombic Ibam space group. La(1) is bonded in a 8-coordinate geometry to two equivalent N(1), two equivalent Cl(1), and four equivalent Cl(2) atoms. N(1) is bonded to four equivalent La(1) atoms to form edge-sharing NLa4 tetrahedra. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 4-coordinate geometry to four equivalent La(1) atoms. In the second Cl site, Cl(2) is bonded in a 4-coordinate geometry to four equivalent La(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_La2NCl3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.166
_cell_length_b   6.943
_cell_length_c   8.324
_cell_angle_alpha   114.650
_cell_angle_beta   111.738
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   295.763
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.594  0.917  0.187  1.0
  La  La1  1  0.406  0.083  0.813  1.0
  La  La2  1  0.906  0.729  0.813  1.0
  La  La3  1  0.094  0.271  0.187  1.0
  N  N4  1  0.250  0.000  0.000  1.0
  N  N5  1  0.750  0.000  0.000  1.0
  Cl  Cl6  1  0.250  0.500  0.000  1.0
  Cl  Cl7  1  0.750  0.500  0.000  1.0
  Cl  Cl8  1  0.802  0.989  0.605  1.0
  Cl  Cl9  1  0.198  0.011  0.395  1.0
  Cl  Cl10  1  0.698  0.384  0.395  1.0
  Cl  Cl11  1  0.302  0.616  0.605  1.0
[/CIF]
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