The structure described by Cs5Bi(MoO4)4 crystallizes in the triclinic P1 space group. There are ten inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a 9-coordinate geometry to one O(10), one O(13), one O(20), one O(27), one O(28), one O(32), one O(4), one O(5), and one O(9) atom. In the second Cs site, Cs(2) is bonded in a 8-coordinate geometry to one O(1), one O(12), one O(13), one O(18), one O(19), one O(2), one O(30), and one O(9) atom. In the third Cs site, Cs(3) is bonded in a 8-coordinate geometry to one O(1), one O(12), one O(16), one O(18), one O(19), one O(21), one O(22), and one O(24) atom. In the fourth Cs site, Cs(4) is bonded in a 9-coordinate geometry to one O(11), one O(15), one O(28), one O(29), one O(30), one O(5), one O(6), one O(7), and one O(8) atom. In the fifth Cs site, Cs(5) is bonded in a 8-coordinate geometry to one O(14), one O(15), one O(16), one O(18), one O(2), one O(23), one O(30), and one O(9) atom. In the sixth Cs site, Cs(6) is bonded in a 10-coordinate geometry to one O(12), one O(14), one O(16), one O(17), one O(19), one O(21), one O(22), one O(24), one O(26), and one O(3) atom. In the seventh Cs site, Cs(7) is bonded in a 8-coordinate geometry to one O(14), one O(16), one O(19), one O(2), one O(21), one O(23), one O(24), and one O(26) atom. In the eighth Cs site, Cs(8) is bonded in a 9-coordinate geometry to one O(11), one O(21), one O(26), one O(28), one O(29), one O(3), one O(31), one O(32), and one O(7) atom. In the ninth Cs site, Cs(9) is bonded in a 10-coordinate geometry to one O(1), one O(13), one O(15), one O(18), one O(2), one O(23), one O(30), one O(4), one O(8), and one O(9) atom. In the tenth Cs site, Cs(10) is bonded in a 9-coordinate geometry to one O(10), one O(17), one O(22), one O(24), one O(25), one O(27), one O(32), one O(5), and one O(7) atom. There are eight inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(14), one O(18), one O(25), and one O(26) atom to form MoO4 tetrahedra that share  a cornercorner with one Bi(2)O6 octahedra. The corner-sharing octahedral tilt angles are 37°. In the second Mo site, Mo(2) is bonded to one O(11), one O(24), one O(3), and one O(5) atom to form MoO4 tetrahedra that share  a cornercorner with one Bi(1)O6 octahedra and  a cornercorner with one Bi(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-62°. In the third Mo site, Mo(3) is bonded to one O(10), one O(30), one O(4), and one O(7) atom to form MoO4 tetrahedra that share  a cornercorner with one Bi(1)O6 octahedra and  a cornercorner with one Bi(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-62°. In the fourth Mo site, Mo(4) is bonded to one O(1), one O(13), one O(16), and one O(6) atom to form MoO4 tetrahedra that share  a cornercorner with one Bi(1)O6 octahedra. The corner-sharing octahedral tilt angles are 37°. In the fifth Mo site, Mo(5) is bonded to one O(17), one O(21), one O(27), and one O(28) atom to form MoO4 tetrahedra that share  a cornercorner with one Bi(1)O6 octahedra and  a cornercorner with one Bi(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-62°. In the sixth Mo site, Mo(6) is bonded to one O(29), one O(32), one O(8), and one O(9) atom to form MoO4 tetrahedra that share  a cornercorner with one Bi(1)O6 octahedra and  a cornercorner with one Bi(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-62°. In the seventh Mo site, Mo(7) is bonded to one O(12), one O(2), one O(22), and one O(31) atom to form MoO4 tetrahedra that share  a cornercorner with one Bi(2)O6 octahedra. The corner-sharing octahedral tilt angles are 37°. In the eighth Mo site, Mo(8) is bonded to one O(15), one O(19), one O(20), and one O(23) atom to form MoO4 tetrahedra that share  a cornercorner with one Bi(1)O6 octahedra. The corner-sharing octahedral tilt angles are 37°. There are two inequivalent Bi sites. In the first Bi site, Bi(1) is bonded to one O(10), one O(20), one O(28), one O(29), one O(5), and one O(6) atom to form BiO6 octahedra that share  a cornercorner with one Mo(2)O4 tetrahedra,  a cornercorner with one Mo(3)O4 tetrahedra,  a cornercorner with one Mo(4)O4 tetrahedra,  a cornercorner with one Mo(5)O4 tetrahedra,  a cornercorner with one Mo(6)O4 tetrahedra, and  a cornercorner with one Mo(8)O4 tetrahedra. In the second Bi site, Bi(2) is bonded to one O(11), one O(25), one O(27), one O(31), one O(32), and one O(7) atom to form BiO6 octahedra that share  a cornercorner with one Mo(1)O4 tetrahedra,  a cornercorner with one Mo(2)O4 tetrahedra,  a cornercorner with one Mo(3)O4 tetrahedra,  a cornercorner with one Mo(5)O4 tetrahedra,  a cornercorner with one Mo(6)O4 tetrahedra, and  a cornercorner with one Mo(7)O4 tetrahedra. There are thirty-two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cs(2), one Cs(3), one Cs(9), and one Mo(4) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cs(2), one Cs(5), one Cs(7), one Cs(9), and one Mo(7) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Cs(6), one Cs(8), and one Mo(2) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Cs(1), one Cs(9), and one Mo(3) atom. In the fifth O site, O(5) is bonded in a 1-coordinate geometry to one Cs(1), one Cs(10), one Cs(4), one Mo(2), and one Bi(1) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Cs(4), one Mo(4), and one Bi(1) atom. In the seventh O site, O(7) is bonded in a 1-coordinate geometry to one Cs(10), one Cs(4), one Cs(8), one Mo(3), and one Bi(2) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one Cs(4), one Cs(9), and one Mo(6) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one Cs(1), one Cs(2), one Cs(5), one Cs(9), and one Mo(6) atom. In the tenth O site, O(10) is bonded in a 2-coordinate geometry to one Cs(1), one Cs(10), one Mo(3), and one Bi(1) atom. In the eleventh O site, O(11) is bonded in a 2-coordinate geometry to one Cs(4), one Cs(8), one Mo(2), and one Bi(2) atom. In the twelfth O site, O(12) is bonded in a 4-coordinate geometry to one Cs(2), one Cs(3), one Cs(6), and one Mo(7) atom. In the thirteenth O site, O(13) is bonded in a distorted single-bond geometry to one Cs(1), one Cs(2), one Cs(9), and one Mo(4) atom. In the fourteenth O site, O(14) is bonded in a distorted single-bond geometry to one Cs(5), one Cs(6), one Cs(7), and one Mo(1) atom. In the fifteenth O site, O(15) is bonded in a distorted single-bond geometry to one Cs(4), one Cs(5), one Cs(9), and one Mo(8) atom. In the sixteenth O site, O(16) is bonded in a distorted single-bond geometry to one Cs(3), one Cs(5), one Cs(6), one Cs(7), and one Mo(4) atom. In the seventeenth O site, O(17) is bonded in a distorted single-bond geometry to one Cs(10), one Cs(6), and one Mo(5) atom. In the eighteenth O site, O(18) is bonded in a distorted single-bond geometry to one Cs(2), one Cs(3), one Cs(5), one Cs(9), and one Mo(1) atom. In the nineteenth O site, O(19) is bonded in a distorted single-bond geometry to one Cs(2), one Cs(3), one Cs(6), one Cs(7), and one Mo(8) atom. In the twentieth O site, O(20) is bonded in a distorted bent 150 degrees geometry to one Cs(1), one Mo(8), and one Bi(1) atom. In the twenty-first O site, O(21) is bonded in a distorted single-bond geometry to one Cs(3), one Cs(6), one Cs(7), one Cs(8), and one Mo(5) atom. In the twenty-second O site, O(22) is bonded in a distorted single-bond geometry to one Cs(10), one Cs(3), one Cs(6), and one Mo(7) atom. In the twenty-third O site, O(23) is bonded in a 4-coordinate geometry to one Cs(5), one Cs(7), one Cs(9), and one Mo(8) atom. In the twenty-fourth O site, O(24) is bonded in a distorted single-bond geometry to one Cs(10), one Cs(3), one Cs(6), one Cs(7), and one Mo(2) atom. In the twenty-fifth O site, O(25) is bonded in a distorted bent 150 degrees geometry to one Cs(10), one Mo(1), and one Bi(2) atom. In the twenty-sixth O site, O(26) is bonded in a distorted single-bond geometry to one Cs(6), one Cs(7), one Cs(8), and one Mo(1) atom. In the twenty-seventh O site, O(27) is bonded in a 2-coordinate geometry to one Cs(1), one Cs(10), one Mo(5), and one Bi(2) atom. In the twenty-eighth O site, O(28) is bonded in a 1-coordinate geometry to one Cs(1), one Cs(4), one Cs(8), one Mo(5), and one Bi(1) atom. In the twenty-ninth O site, O(29) is bonded in a 2-coordinate geometry to one Cs(4), one Cs(8), one Mo(6), and one Bi(1) atom. In the thirtieth O site, O(30) is bonded in a distorted single-bond geometry to one Cs(2), one Cs(4), one Cs(5), one Cs(9), and one Mo(3) atom. In the thirty-first O site, O(31) is bonded in a distorted bent 150 degrees geometry to one Cs(8), one Mo(7), and one Bi(2) atom. In the thirty-second O site, O(32) is bonded in a 1-coordinate geometry to one Cs(1), one Cs(10), one Cs(8), one Mo(6), and one Bi(2) atom. is represented by the CIF file [CIF]
data_Cs5Bi(MoO4)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.752
_cell_length_b   13.752
_cell_length_c   10.706
_cell_angle_alpha   83.881
_cell_angle_beta   83.881
_cell_angle_gamma   143.937
_symmetry_Int_Tables_number   1
_cell_volume   1119.022
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.190  0.564  0.453  1.0
  Cs  Cs1  1  0.052  0.169  0.560  1.0
  Cs  Cs2  1  0.947  0.827  0.449  1.0
  Cs  Cs3  1  0.436  0.810  0.047  1.0
  Cs  Cs4  1  0.827  0.947  0.949  1.0
  Cs  Cs5  1  0.562  0.438  0.250  1.0
  Cs  Cs6  1  0.169  0.052  0.060  1.0
  Cs  Cs7  1  0.564  0.190  0.953  1.0
  Cs  Cs8  1  0.438  0.562  0.750  1.0
  Cs  Cs9  1  0.810  0.436  0.547  1.0
  Bi  Bi10  1  0.806  0.194  0.250  1.0
  Bi  Bi11  1  0.194  0.806  0.750  1.0
  Mo  Mo12  1  0.792  0.649  0.858  1.0
  Mo  Mo13  1  0.975  0.596  0.140  1.0
  Mo  Mo14  1  0.596  0.975  0.640  1.0
  Mo  Mo15  1  0.649  0.792  0.358  1.0
  Mo  Mo16  1  0.404  0.025  0.360  1.0
  Mo  Mo17  1  0.025  0.404  0.860  1.0
  Mo  Mo18  1  0.351  0.208  0.642  1.0
  Mo  Mo19  1  0.208  0.351  0.142  1.0
  O  O20  1  0.744  0.863  0.488  1.0
  O  O21  1  0.238  0.202  0.759  1.0
  O  O22  1  0.782  0.424  0.101  1.0
  O  O23  1  0.424  0.782  0.601  1.0
  O  O24  1  0.011  0.511  0.230  1.0
  O  O25  1  0.679  0.943  0.266  1.0
  O  O26  1  0.511  0.011  0.730  1.0
  O  O27  1  0.208  0.565  0.909  1.0
  O  O28  1  0.048  0.327  0.759  1.0
  O  O29  1  0.772  0.158  0.482  1.0
  O  O30  1  0.158  0.772  0.982  1.0
  O  O31  1  0.256  0.137  0.512  1.0
  O  O32  1  0.425  0.577  0.430  1.0
  O  O33  1  0.863  0.744  0.988  1.0
  O  O34  1  0.421  0.576  0.081  1.0
  O  O35  1  0.762  0.798  0.241  1.0
  O  O36  1  0.565  0.208  0.409  1.0
  O  O37  1  0.798  0.762  0.741  1.0
  O  O38  1  0.202  0.238  0.259  1.0
  O  O39  1  0.057  0.321  0.234  1.0
  O  O40  1  0.327  0.048  0.259  1.0
  O  O41  1  0.576  0.421  0.581  1.0
  O  O42  1  0.137  0.256  0.012  1.0
  O  O43  1  0.952  0.673  0.241  1.0
  O  O44  1  0.943  0.679  0.766  1.0
  O  O45  1  0.577  0.425  0.930  1.0
  O  O46  1  0.228  0.842  0.518  1.0
  O  O47  1  0.489  0.989  0.270  1.0
  O  O48  1  0.830  0.214  0.020  1.0
  O  O49  1  0.673  0.952  0.741  1.0
  O  O50  1  0.321  0.057  0.734  1.0
  O  O51  1  0.989  0.489  0.770  1.0
[/CIF]
.
The structure described by Cs5Bi(MoO4)4 crystallizes in the triclinic P1 space group. There are ten inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a 9-coordinate geometry to one O(10), one O(13), one O(20), one O(27), one O(28), one O(32), one O(4), one O(5), and one O(9) atom. In the second Cs site, Cs(2) is bonded in a 8-coordinate geometry to one O(1), one O(12), one O(13), one O(18), one O(19), one O(2), one O(30), and one O(9) atom. In the third Cs site, Cs(3) is bonded in a 8-coordinate geometry to one O(1), one O(12), one O(16), one O(18), one O(19), one O(21), one O(22), and one O(24) atom. In the fourth Cs site, Cs(4) is bonded in a 9-coordinate geometry to one O(11), one O(15), one O(28), one O(29), one O(30), one O(5), one O(6), one O(7), and one O(8) atom. In the fifth Cs site, Cs(5) is bonded in a 8-coordinate geometry to one O(14), one O(15), one O(16), one O(18), one O(2), one O(23), one O(30), and one O(9) atom. In the sixth Cs site, Cs(6) is bonded in a 10-coordinate geometry to one O(12), one O(14), one O(16), one O(17), one O(19), one O(21), one O(22), one O(24), one O(26), and one O(3) atom. In the seventh Cs site, Cs(7) is bonded in a 8-coordinate geometry to one O(14), one O(16), one O(19), one O(2), one O(21), one O(23), one O(24), and one O(26) atom. In the eighth Cs site, Cs(8) is bonded in a 9-coordinate geometry to one O(11), one O(21), one O(26), one O(28), one O(29), one O(3), one O(31), one O(32), and one O(7) atom. In the ninth Cs site, Cs(9) is bonded in a 10-coordinate geometry to one O(1), one O(13), one O(15), one O(18), one O(2), one O(23), one O(30), one O(4), one O(8), and one O(9) atom. In the tenth Cs site, Cs(10) is bonded in a 9-coordinate geometry to one O(10), one O(17), one O(22), one O(24), one O(25), one O(27), one O(32), one O(5), and one O(7) atom. There are eight inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(14), one O(18), one O(25), and one O(26) atom to form MoO4 tetrahedra that share  a cornercorner with one Bi(2)O6 octahedra. The corner-sharing octahedral tilt angles are 37°. In the second Mo site, Mo(2) is bonded to one O(11), one O(24), one O(3), and one O(5) atom to form MoO4 tetrahedra that share  a cornercorner with one Bi(1)O6 octahedra and  a cornercorner with one Bi(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-62°. In the third Mo site, Mo(3) is bonded to one O(10), one O(30), one O(4), and one O(7) atom to form MoO4 tetrahedra that share  a cornercorner with one Bi(1)O6 octahedra and  a cornercorner with one Bi(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-62°. In the fourth Mo site, Mo(4) is bonded to one O(1), one O(13), one O(16), and one O(6) atom to form MoO4 tetrahedra that share  a cornercorner with one Bi(1)O6 octahedra. The corner-sharing octahedral tilt angles are 37°. In the fifth Mo site, Mo(5) is bonded to one O(17), one O(21), one O(27), and one O(28) atom to form MoO4 tetrahedra that share  a cornercorner with one Bi(1)O6 octahedra and  a cornercorner with one Bi(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-62°. In the sixth Mo site, Mo(6) is bonded to one O(29), one O(32), one O(8), and one O(9) atom to form MoO4 tetrahedra that share  a cornercorner with one Bi(1)O6 octahedra and  a cornercorner with one Bi(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-62°. In the seventh Mo site, Mo(7) is bonded to one O(12), one O(2), one O(22), and one O(31) atom to form MoO4 tetrahedra that share  a cornercorner with one Bi(2)O6 octahedra. The corner-sharing octahedral tilt angles are 37°. In the eighth Mo site, Mo(8) is bonded to one O(15), one O(19), one O(20), and one O(23) atom to form MoO4 tetrahedra that share  a cornercorner with one Bi(1)O6 octahedra. The corner-sharing octahedral tilt angles are 37°. There are two inequivalent Bi sites. In the first Bi site, Bi(1) is bonded to one O(10), one O(20), one O(28), one O(29), one O(5), and one O(6) atom to form BiO6 octahedra that share  a cornercorner with one Mo(2)O4 tetrahedra,  a cornercorner with one Mo(3)O4 tetrahedra,  a cornercorner with one Mo(4)O4 tetrahedra,  a cornercorner with one Mo(5)O4 tetrahedra,  a cornercorner with one Mo(6)O4 tetrahedra, and  a cornercorner with one Mo(8)O4 tetrahedra. In the second Bi site, Bi(2) is bonded to one O(11), one O(25), one O(27), one O(31), one O(32), and one O(7) atom to form BiO6 octahedra that share  a cornercorner with one Mo(1)O4 tetrahedra,  a cornercorner with one Mo(2)O4 tetrahedra,  a cornercorner with one Mo(3)O4 tetrahedra,  a cornercorner with one Mo(5)O4 tetrahedra,  a cornercorner with one Mo(6)O4 tetrahedra, and  a cornercorner with one Mo(7)O4 tetrahedra. There are thirty-two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cs(2), one Cs(3), one Cs(9), and one Mo(4) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cs(2), one Cs(5), one Cs(7), one Cs(9), and one Mo(7) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Cs(6), one Cs(8), and one Mo(2) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Cs(1), one Cs(9), and one Mo(3) atom. In the fifth O site, O(5) is bonded in a 1-coordinate geometry to one Cs(1), one Cs(10), one Cs(4), one Mo(2), and one Bi(1) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Cs(4), one Mo(4), and one Bi(1) atom. In the seventh O site, O(7) is bonded in a 1-coordinate geometry to one Cs(10), one Cs(4), one Cs(8), one Mo(3), and one Bi(2) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one Cs(4), one Cs(9), and one Mo(6) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one Cs(1), one Cs(2), one Cs(5), one Cs(9), and one Mo(6) atom. In the tenth O site, O(10) is bonded in a 2-coordinate geometry to one Cs(1), one Cs(10), one Mo(3), and one Bi(1) atom. In the eleventh O site, O(11) is bonded in a 2-coordinate geometry to one Cs(4), one Cs(8), one Mo(2), and one Bi(2) atom. In the twelfth O site, O(12) is bonded in a 4-coordinate geometry to one Cs(2), one Cs(3), one Cs(6), and one Mo(7) atom. In the thirteenth O site, O(13) is bonded in a distorted single-bond geometry to one Cs(1), one Cs(2), one Cs(9), and one Mo(4) atom. In the fourteenth O site, O(14) is bonded in a distorted single-bond geometry to one Cs(5), one Cs(6), one Cs(7), and one Mo(1) atom. In the fifteenth O site, O(15) is bonded in a distorted single-bond geometry to one Cs(4), one Cs(5), one Cs(9), and one Mo(8) atom. In the sixteenth O site, O(16) is bonded in a distorted single-bond geometry to one Cs(3), one Cs(5), one Cs(6), one Cs(7), and one Mo(4) atom. In the seventeenth O site, O(17) is bonded in a distorted single-bond geometry to one Cs(10), one Cs(6), and one Mo(5) atom. In the eighteenth O site, O(18) is bonded in a distorted single-bond geometry to one Cs(2), one Cs(3), one Cs(5), one Cs(9), and one Mo(1) atom. In the nineteenth O site, O(19) is bonded in a distorted single-bond geometry to one Cs(2), one Cs(3), one Cs(6), one Cs(7), and one Mo(8) atom. In the twentieth O site, O(20) is bonded in a distorted bent 150 degrees geometry to one Cs(1), one Mo(8), and one Bi(1) atom. In the twenty-first O site, O(21) is bonded in a distorted single-bond geometry to one Cs(3), one Cs(6), one Cs(7), one Cs(8), and one Mo(5) atom. In the twenty-second O site, O(22) is bonded in a distorted single-bond geometry to one Cs(10), one Cs(3), one Cs(6), and one Mo(7) atom. In the twenty-third O site, O(23) is bonded in a 4-coordinate geometry to one Cs(5), one Cs(7), one Cs(9), and one Mo(8) atom. In the twenty-fourth O site, O(24) is bonded in a distorted single-bond geometry to one Cs(10), one Cs(3), one Cs(6), one Cs(7), and one Mo(2) atom. In the twenty-fifth O site, O(25) is bonded in a distorted bent 150 degrees geometry to one Cs(10), one Mo(1), and one Bi(2) atom. In the twenty-sixth O site, O(26) is bonded in a distorted single-bond geometry to one Cs(6), one Cs(7), one Cs(8), and one Mo(1) atom. In the twenty-seventh O site, O(27) is bonded in a 2-coordinate geometry to one Cs(1), one Cs(10), one Mo(5), and one Bi(2) atom. In the twenty-eighth O site, O(28) is bonded in a 1-coordinate geometry to one Cs(1), one Cs(4), one Cs(8), one Mo(5), and one Bi(1) atom. In the twenty-ninth O site, O(29) is bonded in a 2-coordinate geometry to one Cs(4), one Cs(8), one Mo(6), and one Bi(1) atom. In the thirtieth O site, O(30) is bonded in a distorted single-bond geometry to one Cs(2), one Cs(4), one Cs(5), one Cs(9), and one Mo(3) atom. In the thirty-first O site, O(31) is bonded in a distorted bent 150 degrees geometry to one Cs(8), one Mo(7), and one Bi(2) atom. In the thirty-second O site, O(32) is bonded in a 1-coordinate geometry to one Cs(1), one Cs(10), one Cs(8), one Mo(6), and one Bi(2) atom. is represented by the CIF file [CIF]
data_Cs5Bi(MoO4)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.752
_cell_length_b   13.752
_cell_length_c   10.706
_cell_angle_alpha   83.881
_cell_angle_beta   83.881
_cell_angle_gamma   143.937
_symmetry_Int_Tables_number   1
_cell_volume   1119.022
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.190  0.564  0.453  1.0
  Cs  Cs1  1  0.052  0.169  0.560  1.0
  Cs  Cs2  1  0.947  0.827  0.449  1.0
  Cs  Cs3  1  0.436  0.810  0.047  1.0
  Cs  Cs4  1  0.827  0.947  0.949  1.0
  Cs  Cs5  1  0.562  0.438  0.250  1.0
  Cs  Cs6  1  0.169  0.052  0.060  1.0
  Cs  Cs7  1  0.564  0.190  0.953  1.0
  Cs  Cs8  1  0.438  0.562  0.750  1.0
  Cs  Cs9  1  0.810  0.436  0.547  1.0
  Bi  Bi10  1  0.806  0.194  0.250  1.0
  Bi  Bi11  1  0.194  0.806  0.750  1.0
  Mo  Mo12  1  0.792  0.649  0.858  1.0
  Mo  Mo13  1  0.975  0.596  0.140  1.0
  Mo  Mo14  1  0.596  0.975  0.640  1.0
  Mo  Mo15  1  0.649  0.792  0.358  1.0
  Mo  Mo16  1  0.404  0.025  0.360  1.0
  Mo  Mo17  1  0.025  0.404  0.860  1.0
  Mo  Mo18  1  0.351  0.208  0.642  1.0
  Mo  Mo19  1  0.208  0.351  0.142  1.0
  O  O20  1  0.744  0.863  0.488  1.0
  O  O21  1  0.238  0.202  0.759  1.0
  O  O22  1  0.782  0.424  0.101  1.0
  O  O23  1  0.424  0.782  0.601  1.0
  O  O24  1  0.011  0.511  0.230  1.0
  O  O25  1  0.679  0.943  0.266  1.0
  O  O26  1  0.511  0.011  0.730  1.0
  O  O27  1  0.208  0.565  0.909  1.0
  O  O28  1  0.048  0.327  0.759  1.0
  O  O29  1  0.772  0.158  0.482  1.0
  O  O30  1  0.158  0.772  0.982  1.0
  O  O31  1  0.256  0.137  0.512  1.0
  O  O32  1  0.425  0.577  0.430  1.0
  O  O33  1  0.863  0.744  0.988  1.0
  O  O34  1  0.421  0.576  0.081  1.0
  O  O35  1  0.762  0.798  0.241  1.0
  O  O36  1  0.565  0.208  0.409  1.0
  O  O37  1  0.798  0.762  0.741  1.0
  O  O38  1  0.202  0.238  0.259  1.0
  O  O39  1  0.057  0.321  0.234  1.0
  O  O40  1  0.327  0.048  0.259  1.0
  O  O41  1  0.576  0.421  0.581  1.0
  O  O42  1  0.137  0.256  0.012  1.0
  O  O43  1  0.952  0.673  0.241  1.0
  O  O44  1  0.943  0.679  0.766  1.0
  O  O45  1  0.577  0.425  0.930  1.0
  O  O46  1  0.228  0.842  0.518  1.0
  O  O47  1  0.489  0.989  0.270  1.0
  O  O48  1  0.830  0.214  0.020  1.0
  O  O49  1  0.673  0.952  0.741  1.0
  O  O50  1  0.321  0.057  0.734  1.0
  O  O51  1  0.989  0.489  0.770  1.0
[/CIF]
.