The crystal structure described by PtN5OClPO3O2 is Indium-derived structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two hydrogen peroxide molecules, two phosphonic acid molecules, and two PtN5OCl clusters. In each PtN5OCl cluster, Pt(1) is bonded in a 5-coordinate geometry to one N(3), two equivalent N(1), and two equivalent N(2) atoms. There are three inequivalent N sites. In the first N site, N(1) is bonded in an L-shaped geometry to one Pt(1) and one Cl(1) atom. In the second N site, N(2) is bonded in an L-shaped geometry to one Pt(1) and one O(2) atom. In the third N site, N(3) is bonded in a single-bond geometry to one Pt(1) atom. O(2) is bonded in a water-like geometry to two equivalent N(2) atoms. Cl(1) is bonded in an L-shaped geometry to two equivalent N(1) atoms. is represented by the CIF card [CIF]
data_PPtN5ClO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.106
_cell_length_b   9.444
_cell_length_c   9.633
_cell_angle_alpha   62.184
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   571.781
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.750  0.957  0.728  1.0
  P  P1  1  0.250  0.043  0.272  1.0
  Pt  Pt2  1  0.250  0.185  0.698  1.0
  Pt  Pt3  1  0.750  0.815  0.302  1.0
  N  N4  1  0.077  0.339  0.526  1.0
  N  N5  1  0.577  0.661  0.474  1.0
  N  N6  1  0.923  0.661  0.474  1.0
  N  N7  1  0.423  0.339  0.526  1.0
  N  N8  1  0.097  0.221  0.858  1.0
  N  N9  1  0.597  0.779  0.142  1.0
  N  N10  1  0.903  0.779  0.142  1.0
  N  N11  1  0.403  0.221  0.858  1.0
  N  N12  1  0.250  0.986  0.729  1.0
  N  N13  1  0.750  0.014  0.271  1.0
  Cl  Cl14  1  0.250  0.423  0.399  1.0
  Cl  Cl15  1  0.750  0.577  0.601  1.0
  O  O16  1  0.337  0.556  0.887  1.0
  O  O17  1  0.837  0.444  0.113  1.0
  O  O18  1  0.663  0.444  0.113  1.0
  O  O19  1  0.163  0.556  0.887  1.0
  O  O20  1  0.750  0.777  0.060  1.0
  O  O21  1  0.250  0.223  0.940  1.0
  O  O22  1  0.750  0.108  0.740  1.0
  O  O23  1  0.250  0.892  0.260  1.0
  O  O24  1  0.571  0.875  0.723  1.0
  O  O25  1  0.071  0.125  0.277  1.0
  O  O26  1  0.429  0.125  0.277  1.0
  O  O27  1  0.929  0.875  0.723  1.0
[/CIF]
.
The crystal structure described by PtN5OClPO3O2 is Indium-derived structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two hydrogen peroxide molecules, two phosphonic acid molecules, and two PtN5OCl clusters. In each PtN5OCl cluster, Pt(1) is bonded in a 5-coordinate geometry to one N(3), two equivalent N(1), and two equivalent N(2) atoms. There are three inequivalent N sites. In the first N site, N(1) is bonded in an L-shaped geometry to one Pt(1) and one Cl(1) atom. In the second N site, N(2) is bonded in an L-shaped geometry to one Pt(1) and one O(2) atom. In the third N site, N(3) is bonded in a single-bond geometry to one Pt(1) atom. O(2) is bonded in a water-like geometry to two equivalent N(2) atoms. Cl(1) is bonded in an L-shaped geometry to two equivalent N(1) atoms. is represented by the CIF card [CIF]
data_PPtN5ClO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.106
_cell_length_b   9.444
_cell_length_c   9.633
_cell_angle_alpha   62.184
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   571.781
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.750  0.957  0.728  1.0
  P  P1  1  0.250  0.043  0.272  1.0
  Pt  Pt2  1  0.250  0.185  0.698  1.0
  Pt  Pt3  1  0.750  0.815  0.302  1.0
  N  N4  1  0.077  0.339  0.526  1.0
  N  N5  1  0.577  0.661  0.474  1.0
  N  N6  1  0.923  0.661  0.474  1.0
  N  N7  1  0.423  0.339  0.526  1.0
  N  N8  1  0.097  0.221  0.858  1.0
  N  N9  1  0.597  0.779  0.142  1.0
  N  N10  1  0.903  0.779  0.142  1.0
  N  N11  1  0.403  0.221  0.858  1.0
  N  N12  1  0.250  0.986  0.729  1.0
  N  N13  1  0.750  0.014  0.271  1.0
  Cl  Cl14  1  0.250  0.423  0.399  1.0
  Cl  Cl15  1  0.750  0.577  0.601  1.0
  O  O16  1  0.337  0.556  0.887  1.0
  O  O17  1  0.837  0.444  0.113  1.0
  O  O18  1  0.663  0.444  0.113  1.0
  O  O19  1  0.163  0.556  0.887  1.0
  O  O20  1  0.750  0.777  0.060  1.0
  O  O21  1  0.250  0.223  0.940  1.0
  O  O22  1  0.750  0.108  0.740  1.0
  O  O23  1  0.250  0.892  0.260  1.0
  O  O24  1  0.571  0.875  0.723  1.0
  O  O25  1  0.071  0.125  0.277  1.0
  O  O26  1  0.429  0.125  0.277  1.0
  O  O27  1  0.929  0.875  0.723  1.0
[/CIF]
.