The structure described by H2(Pb3OCl4F)2 crystallizes in the triclinic P-1 space group. The structure consists of two 1333-74-0 atoms inside a Pb3OCl4F framework. In the Pb3OCl4F framework, there are three inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 8-coordinate geometry to one O(1), one Cl(2), one Cl(3), one Cl(4), two equivalent Cl(1), and two equivalent F(1) atoms. In the second Pb site, Pb(2) is bonded in a 7-coordinate geometry to one Cl(1), one Cl(3), two equivalent Cl(2), two equivalent Cl(4), and one F(1) atom. In the third Pb site, Pb(3) is bonded in a 3-coordinate geometry to two equivalent O(1), one Cl(2), one Cl(4), two equivalent Cl(3), and one F(1) atom. O(1) is bonded in a trigonal non-coplanar geometry to one Pb(1) and two equivalent Pb(3) atoms. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 3-coordinate geometry to one Pb(2) and two equivalent Pb(1) atoms. In the second Cl site, Cl(2) is bonded in a distorted rectangular see-saw-like geometry to one Pb(1), one Pb(3), and two equivalent Pb(2) atoms. In the third Cl site, Cl(3) is bonded in a 4-coordinate geometry to one Pb(1), one Pb(2), and two equivalent Pb(3) atoms. In the fourth Cl site, Cl(4) is bonded in a distorted rectangular see-saw-like geometry to one Pb(1), one Pb(3), and two equivalent Pb(2) atoms. F(1) is bonded to one Pb(2), one Pb(3), and two equivalent Pb(1) atoms to form edge-sharing FPb4 tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_HPb3Cl4OF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.273
_cell_length_b   7.889
_cell_length_c   8.685
_cell_angle_alpha   103.293
_cell_angle_beta   101.151
_cell_angle_gamma   89.759
_symmetry_Int_Tables_number   1
_cell_volume   475.437
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.993  0.753  0.005  1.0
  H  H1  1  0.007  0.247  0.995  1.0
  Pb  Pb2  1  0.251  0.840  0.411  1.0
  Pb  Pb3  1  0.749  0.160  0.589  1.0
  Pb  Pb4  1  0.661  0.786  0.130  1.0
  Pb  Pb5  1  0.339  0.214  0.870  1.0
  Pb  Pb6  1  0.713  0.640  0.596  1.0
  Pb  Pb7  1  0.287  0.360  0.404  1.0
  Cl  Cl8  1  0.919  0.076  0.303  1.0
  Cl  Cl9  1  0.081  0.924  0.697  1.0
  Cl  Cl10  1  0.651  0.980  0.857  1.0
  Cl  Cl11  1  0.349  0.020  0.143  1.0
  Cl  Cl12  1  0.923  0.581  0.308  1.0
  Cl  Cl13  1  0.077  0.419  0.692  1.0
  Cl  Cl14  1  0.354  0.540  0.144  1.0
  Cl  Cl15  1  0.646  0.460  0.856  1.0
  O  O16  1  0.606  0.365  0.462  1.0
  O  O17  1  0.394  0.635  0.538  1.0
  F  F18  1  0.615  0.862  0.423  1.0
  F  F19  1  0.385  0.138  0.577  1.0
[/CIF]
.
The structure described by H2(Pb3OCl4F)2 crystallizes in the triclinic P-1 space group. The structure consists of two 1333-74-0 atoms inside a Pb3OCl4F framework. In the Pb3OCl4F framework, there are three inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 8-coordinate geometry to one O(1), one Cl(2), one Cl(3), one Cl(4), two equivalent Cl(1), and two equivalent F(1) atoms. In the second Pb site, Pb(2) is bonded in a 7-coordinate geometry to one Cl(1), one Cl(3), two equivalent Cl(2), two equivalent Cl(4), and one F(1) atom. In the third Pb site, Pb(3) is bonded in a 3-coordinate geometry to two equivalent O(1), one Cl(2), one Cl(4), two equivalent Cl(3), and one F(1) atom. O(1) is bonded in a trigonal non-coplanar geometry to one Pb(1) and two equivalent Pb(3) atoms. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 3-coordinate geometry to one Pb(2) and two equivalent Pb(1) atoms. In the second Cl site, Cl(2) is bonded in a distorted rectangular see-saw-like geometry to one Pb(1), one Pb(3), and two equivalent Pb(2) atoms. In the third Cl site, Cl(3) is bonded in a 4-coordinate geometry to one Pb(1), one Pb(2), and two equivalent Pb(3) atoms. In the fourth Cl site, Cl(4) is bonded in a distorted rectangular see-saw-like geometry to one Pb(1), one Pb(3), and two equivalent Pb(2) atoms. F(1) is bonded to one Pb(2), one Pb(3), and two equivalent Pb(1) atoms to form edge-sharing FPb4 tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_HPb3Cl4OF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.273
_cell_length_b   7.889
_cell_length_c   8.685
_cell_angle_alpha   103.293
_cell_angle_beta   101.151
_cell_angle_gamma   89.759
_symmetry_Int_Tables_number   1
_cell_volume   475.437
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.993  0.753  0.005  1.0
  H  H1  1  0.007  0.247  0.995  1.0
  Pb  Pb2  1  0.251  0.840  0.411  1.0
  Pb  Pb3  1  0.749  0.160  0.589  1.0
  Pb  Pb4  1  0.661  0.786  0.130  1.0
  Pb  Pb5  1  0.339  0.214  0.870  1.0
  Pb  Pb6  1  0.713  0.640  0.596  1.0
  Pb  Pb7  1  0.287  0.360  0.404  1.0
  Cl  Cl8  1  0.919  0.076  0.303  1.0
  Cl  Cl9  1  0.081  0.924  0.697  1.0
  Cl  Cl10  1  0.651  0.980  0.857  1.0
  Cl  Cl11  1  0.349  0.020  0.143  1.0
  Cl  Cl12  1  0.923  0.581  0.308  1.0
  Cl  Cl13  1  0.077  0.419  0.692  1.0
  Cl  Cl14  1  0.354  0.540  0.144  1.0
  Cl  Cl15  1  0.646  0.460  0.856  1.0
  O  O16  1  0.606  0.365  0.462  1.0
  O  O17  1  0.394  0.635  0.538  1.0
  F  F18  1  0.615  0.862  0.423  1.0
  F  F19  1  0.385  0.138  0.577  1.0
[/CIF]
.