The compound described by LiCrO2 is Caswellsilverite-like structured and crystallizes in the monoclinic C2/c space group. Li(1) is bonded to six equivalent O(1) atoms to form LiO6 octahedra that share corners with two equivalent Cr(1)O6 octahedra, corners with four equivalent Li(1)O6 octahedra, edges with four equivalent Li(1)O6 octahedra, and edges with eight equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-10°. Cr(1) is bonded to six equivalent O(1) atoms to form CrO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with four equivalent Cr(1)O6 octahedra, edges with four equivalent Cr(1)O6 octahedra, and edges with eight equivalent Li(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-10°. O(1) is bonded to three equivalent Li(1) and three equivalent Cr(1) atoms to form a mixture of corner and edge-sharing OLi3Cr3 octahedra. The corner-sharing octahedral tilt angles range from 0-10°. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiCrO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.058
_cell_length_b   4.058
_cell_length_c   5.244
_cell_angle_alpha   67.412
_cell_angle_beta   67.412
_cell_angle_gamma   89.995
_symmetry_Int_Tables_number   1
_cell_volume   72.509
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.001  0.999  1.000  1.0
  Cr  Cr1  1  0.249  0.751  0.500  1.0
  Li  Li2  1  0.750  0.250  0.500  1.0
  Li  Li3  1  0.500  0.500  1.000  1.0
  O  O4  1  0.020  0.519  0.961  1.0
  O  O5  1  0.230  0.231  0.539  1.0
  O  O6  1  0.481  0.980  0.039  1.0
  O  O7  1  0.769  0.770  0.461  1.0
[/CIF]
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The compound described by LiCrO2 is Caswellsilverite-like structured and crystallizes in the monoclinic C2/c space group. Li(1) is bonded to six equivalent O(1) atoms to form LiO6 octahedra that share corners with two equivalent Cr(1)O6 octahedra, corners with four equivalent Li(1)O6 octahedra, edges with four equivalent Li(1)O6 octahedra, and edges with eight equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-10°. Cr(1) is bonded to six equivalent O(1) atoms to form CrO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with four equivalent Cr(1)O6 octahedra, edges with four equivalent Cr(1)O6 octahedra, and edges with eight equivalent Li(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-10°. O(1) is bonded to three equivalent Li(1) and three equivalent Cr(1) atoms to form a mixture of corner and edge-sharing OLi3Cr3 octahedra. The corner-sharing octahedral tilt angles range from 0-10°. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiCrO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.058
_cell_length_b   4.058
_cell_length_c   5.244
_cell_angle_alpha   67.412
_cell_angle_beta   67.412
_cell_angle_gamma   89.995
_symmetry_Int_Tables_number   1
_cell_volume   72.509
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.001  0.999  1.000  1.0
  Cr  Cr1  1  0.249  0.751  0.500  1.0
  Li  Li2  1  0.750  0.250  0.500  1.0
  Li  Li3  1  0.500  0.500  1.000  1.0
  O  O4  1  0.020  0.519  0.961  1.0
  O  O5  1  0.230  0.231  0.539  1.0
  O  O6  1  0.481  0.980  0.039  1.0
  O  O7  1  0.769  0.770  0.461  1.0
[/CIF]
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