The compound described by RuN5H13O2Cl2 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of eight hydrochloric acid atoms and four RuN5H13O2 clusters. In each RuN5H13O2 cluster, Ru(1) is bonded in an octahedral geometry to one N(1), two equivalent N(2), two equivalent N(3), and one O(2) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a linear geometry to one Ru(1) and one O(1) atom. In the second N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one Ru(1), one H(2), one H(3), and one H(4) atom. In the third N site, N(3) is bonded in a distorted trigonal non-coplanar geometry to one Ru(1), one H(5), one H(6), and one H(7) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one N(3) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one N(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Ru(1) and one H(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_H13RuN5(ClO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.908
_cell_length_b   6.908
_cell_length_c   11.223
_cell_angle_alpha   74.626
_cell_angle_beta   74.626
_cell_angle_gamma   66.987
_symmetry_Int_Tables_number   1
_cell_volume   467.354
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.897  0.897  0.820  1.0
  H  H1  1  0.103  0.103  0.180  1.0
  H  H2  1  0.068  0.429  0.881  1.0
  H  H3  1  0.429  0.068  0.881  1.0
  H  H4  1  0.932  0.571  0.119  1.0
  H  H5  1  0.571  0.932  0.119  1.0
  H  H6  1  0.939  0.272  0.976  1.0
  H  H7  1  0.272  0.939  0.976  1.0
  H  H8  1  0.061  0.728  0.024  1.0
  H  H9  1  0.728  0.061  0.024  1.0
  H  H10  1  0.824  0.459  0.862  1.0
  H  H11  1  0.459  0.824  0.862  1.0
  H  H12  1  0.176  0.541  0.138  1.0
  H  H13  1  0.541  0.176  0.138  1.0
  H  H14  1  0.742  0.375  0.698  1.0
  H  H15  1  0.375  0.742  0.698  1.0
  H  H16  1  0.258  0.625  0.302  1.0
  H  H17  1  0.625  0.258  0.302  1.0
  H  H18  1  0.826  0.147  0.645  1.0
  H  H19  1  0.147  0.826  0.645  1.0
  H  H20  1  0.174  0.853  0.355  1.0
  H  H21  1  0.853  0.174  0.355  1.0
  H  H22  1  0.924  0.336  0.565  1.0
  H  H23  1  0.336  0.924  0.565  1.0
  H  H24  1  0.076  0.664  0.435  1.0
  H  H25  1  0.664  0.076  0.435  1.0
  Ru  Ru26  1  0.125  0.125  0.761  1.0
  Ru  Ru27  1  0.875  0.875  0.239  1.0
  N  N28  1  0.276  0.276  0.659  1.0
  N  N29  1  0.724  0.724  0.341  1.0
  N  N30  1  0.967  0.350  0.884  1.0
  N  N31  1  0.350  0.967  0.884  1.0
  N  N32  1  0.033  0.650  0.116  1.0
  N  N33  1  0.650  0.033  0.116  1.0
  N  N34  1  0.874  0.266  0.654  1.0
  N  N35  1  0.266  0.874  0.654  1.0
  N  N36  1  0.126  0.734  0.346  1.0
  N  N37  1  0.734  0.126  0.346  1.0
  Cl  Cl38  1  0.431  0.431  0.859  1.0
  Cl  Cl39  1  0.569  0.569  0.141  1.0
  Cl  Cl40  1  0.815  0.815  0.648  1.0
  Cl  Cl41  1  0.185  0.185  0.352  1.0
  O  O42  1  0.371  0.371  0.580  1.0
  O  O43  1  0.629  0.629  0.420  1.0
  O  O44  1  0.952  0.952  0.871  1.0
  O  O45  1  0.048  0.048  0.129  1.0
[/CIF]
.
The compound described by RuN5H13O2Cl2 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of eight hydrochloric acid atoms and four RuN5H13O2 clusters. In each RuN5H13O2 cluster, Ru(1) is bonded in an octahedral geometry to one N(1), two equivalent N(2), two equivalent N(3), and one O(2) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a linear geometry to one Ru(1) and one O(1) atom. In the second N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one Ru(1), one H(2), one H(3), and one H(4) atom. In the third N site, N(3) is bonded in a distorted trigonal non-coplanar geometry to one Ru(1), one H(5), one H(6), and one H(7) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one N(3) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one N(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Ru(1) and one H(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_H13RuN5(ClO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.908
_cell_length_b   6.908
_cell_length_c   11.223
_cell_angle_alpha   74.626
_cell_angle_beta   74.626
_cell_angle_gamma   66.987
_symmetry_Int_Tables_number   1
_cell_volume   467.354
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.897  0.897  0.820  1.0
  H  H1  1  0.103  0.103  0.180  1.0
  H  H2  1  0.068  0.429  0.881  1.0
  H  H3  1  0.429  0.068  0.881  1.0
  H  H4  1  0.932  0.571  0.119  1.0
  H  H5  1  0.571  0.932  0.119  1.0
  H  H6  1  0.939  0.272  0.976  1.0
  H  H7  1  0.272  0.939  0.976  1.0
  H  H8  1  0.061  0.728  0.024  1.0
  H  H9  1  0.728  0.061  0.024  1.0
  H  H10  1  0.824  0.459  0.862  1.0
  H  H11  1  0.459  0.824  0.862  1.0
  H  H12  1  0.176  0.541  0.138  1.0
  H  H13  1  0.541  0.176  0.138  1.0
  H  H14  1  0.742  0.375  0.698  1.0
  H  H15  1  0.375  0.742  0.698  1.0
  H  H16  1  0.258  0.625  0.302  1.0
  H  H17  1  0.625  0.258  0.302  1.0
  H  H18  1  0.826  0.147  0.645  1.0
  H  H19  1  0.147  0.826  0.645  1.0
  H  H20  1  0.174  0.853  0.355  1.0
  H  H21  1  0.853  0.174  0.355  1.0
  H  H22  1  0.924  0.336  0.565  1.0
  H  H23  1  0.336  0.924  0.565  1.0
  H  H24  1  0.076  0.664  0.435  1.0
  H  H25  1  0.664  0.076  0.435  1.0
  Ru  Ru26  1  0.125  0.125  0.761  1.0
  Ru  Ru27  1  0.875  0.875  0.239  1.0
  N  N28  1  0.276  0.276  0.659  1.0
  N  N29  1  0.724  0.724  0.341  1.0
  N  N30  1  0.967  0.350  0.884  1.0
  N  N31  1  0.350  0.967  0.884  1.0
  N  N32  1  0.033  0.650  0.116  1.0
  N  N33  1  0.650  0.033  0.116  1.0
  N  N34  1  0.874  0.266  0.654  1.0
  N  N35  1  0.266  0.874  0.654  1.0
  N  N36  1  0.126  0.734  0.346  1.0
  N  N37  1  0.734  0.126  0.346  1.0
  Cl  Cl38  1  0.431  0.431  0.859  1.0
  Cl  Cl39  1  0.569  0.569  0.141  1.0
  Cl  Cl40  1  0.815  0.815  0.648  1.0
  Cl  Cl41  1  0.185  0.185  0.352  1.0
  O  O42  1  0.371  0.371  0.580  1.0
  O  O43  1  0.629  0.629  0.420  1.0
  O  O44  1  0.952  0.952  0.871  1.0
  O  O45  1  0.048  0.048  0.129  1.0
[/CIF]
.