The crystal structure described by Tb5(NiIn2)2 crystallizes in the orthorhombic Pbam space group. There are three inequivalent Tb sites. In the first Tb site, Tb(1) is bonded in a distorted body-centered cubic geometry to four equivalent In(1) and four equivalent In(2) atoms. In the second Tb site, Tb(2) is bonded in a 10-coordinate geometry to four equivalent Ni(1), two equivalent In(1), and four equivalent In(2) atoms. In the third Tb site, Tb(3) is bonded in a 8-coordinate geometry to two equivalent Ni(1), two equivalent In(2), and four equivalent In(1) atoms. Ni(1) is bonded in a 8-coordinate geometry to two equivalent Tb(3), four equivalent Tb(2), one In(1), and one In(2) atom. There are two inequivalent In sites. In the first In site, In(1) is bonded in a 9-coordinate geometry to two equivalent Tb(1), two equivalent Tb(2), four equivalent Tb(3), and one Ni(1) atom. In the second In site, In(2) is bonded in a 9-coordinate geometry to two equivalent Tb(1), two equivalent Tb(3), four equivalent Tb(2), and one Ni(1) atom. is represented by the CIF file [CIF]
data_Tb5(In2Ni)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.597
_cell_length_b   8.091
_cell_length_c   18.103
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   526.880
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tb  Tb0  1  0.000  0.500  0.500  1.0
  Tb  Tb1  1  0.000  0.000  0.000  1.0
  Tb  Tb2  1  0.000  0.746  0.278  1.0
  Tb  Tb3  1  0.000  0.254  0.722  1.0
  Tb  Tb4  1  0.000  0.754  0.778  1.0
  Tb  Tb5  1  0.000  0.246  0.222  1.0
  Tb  Tb6  1  0.000  0.618  0.088  1.0
  Tb  Tb7  1  0.000  0.382  0.912  1.0
  Tb  Tb8  1  0.000  0.882  0.588  1.0
  Tb  Tb9  1  0.000  0.118  0.412  1.0
  In  In10  1  0.500  0.706  0.930  1.0
  In  In11  1  0.500  0.294  0.070  1.0
  In  In12  1  0.500  0.794  0.430  1.0
  In  In13  1  0.500  0.206  0.570  1.0
  In  In14  1  0.500  0.571  0.652  1.0
  In  In15  1  0.500  0.429  0.348  1.0
  In  In16  1  0.500  0.929  0.152  1.0
  In  In17  1  0.500  0.071  0.848  1.0
  Ni  Ni18  1  0.500  0.524  0.196  1.0
  Ni  Ni19  1  0.500  0.476  0.804  1.0
  Ni  Ni20  1  0.500  0.976  0.696  1.0
  Ni  Ni21  1  0.500  0.024  0.304  1.0
[/CIF]
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The crystal structure described by Tb5(NiIn2)2 crystallizes in the orthorhombic Pbam space group. There are three inequivalent Tb sites. In the first Tb site, Tb(1) is bonded in a distorted body-centered cubic geometry to four equivalent In(1) and four equivalent In(2) atoms. In the second Tb site, Tb(2) is bonded in a 10-coordinate geometry to four equivalent Ni(1), two equivalent In(1), and four equivalent In(2) atoms. In the third Tb site, Tb(3) is bonded in a 8-coordinate geometry to two equivalent Ni(1), two equivalent In(2), and four equivalent In(1) atoms. Ni(1) is bonded in a 8-coordinate geometry to two equivalent Tb(3), four equivalent Tb(2), one In(1), and one In(2) atom. There are two inequivalent In sites. In the first In site, In(1) is bonded in a 9-coordinate geometry to two equivalent Tb(1), two equivalent Tb(2), four equivalent Tb(3), and one Ni(1) atom. In the second In site, In(2) is bonded in a 9-coordinate geometry to two equivalent Tb(1), two equivalent Tb(3), four equivalent Tb(2), and one Ni(1) atom. is represented by the CIF file [CIF]
data_Tb5(In2Ni)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.597
_cell_length_b   8.091
_cell_length_c   18.103
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   526.880
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tb  Tb0  1  0.000  0.500  0.500  1.0
  Tb  Tb1  1  0.000  0.000  0.000  1.0
  Tb  Tb2  1  0.000  0.746  0.278  1.0
  Tb  Tb3  1  0.000  0.254  0.722  1.0
  Tb  Tb4  1  0.000  0.754  0.778  1.0
  Tb  Tb5  1  0.000  0.246  0.222  1.0
  Tb  Tb6  1  0.000  0.618  0.088  1.0
  Tb  Tb7  1  0.000  0.382  0.912  1.0
  Tb  Tb8  1  0.000  0.882  0.588  1.0
  Tb  Tb9  1  0.000  0.118  0.412  1.0
  In  In10  1  0.500  0.706  0.930  1.0
  In  In11  1  0.500  0.294  0.070  1.0
  In  In12  1  0.500  0.794  0.430  1.0
  In  In13  1  0.500  0.206  0.570  1.0
  In  In14  1  0.500  0.571  0.652  1.0
  In  In15  1  0.500  0.429  0.348  1.0
  In  In16  1  0.500  0.929  0.152  1.0
  In  In17  1  0.500  0.071  0.848  1.0
  Ni  Ni18  1  0.500  0.524  0.196  1.0
  Ni  Ni19  1  0.500  0.476  0.804  1.0
  Ni  Ni20  1  0.500  0.976  0.696  1.0
  Ni  Ni21  1  0.500  0.024  0.304  1.0
[/CIF]
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