The structure described by CsTm(MoO4)2 crystallizes in the orthorhombic Pccm space group. Cs(1) is bonded in a 8-coordinate geometry to four equivalent O(2) and four equivalent O(3) atoms. Tm(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(2) atoms. Mo(1) is bonded in a tetrahedral geometry to one O(1), one O(3), and two equivalent O(2) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent Tm(1) and one Mo(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Cs(1), one Tm(1), and one Mo(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Cs(1) and one Mo(1) atom. is represented by the CIF file [CIF]
data_CsTm(MoO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.074
_cell_length_b   8.061
_cell_length_c   9.599
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   392.623
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.000  0.250  0.500  1.0
  Cs  Cs1  1  0.000  0.750  0.500  1.0
  Tm  Tm2  1  0.000  0.250  0.000  1.0
  Tm  Tm3  1  0.000  0.750  0.000  1.0
  Mo  Mo4  1  0.522  0.000  0.194  1.0
  Mo  Mo5  1  0.478  0.000  0.806  1.0
  Mo  Mo6  1  0.478  0.500  0.194  1.0
  Mo  Mo7  1  0.522  0.500  0.806  1.0
  O  O8  1  0.245  0.000  0.064  1.0
  O  O9  1  0.755  0.000  0.936  1.0
  O  O10  1  0.755  0.500  0.064  1.0
  O  O11  1  0.245  0.500  0.936  1.0
  O  O12  1  0.258  0.323  0.184  1.0
  O  O13  1  0.742  0.677  0.816  1.0
  O  O14  1  0.742  0.323  0.816  1.0
  O  O15  1  0.742  0.177  0.184  1.0
  O  O16  1  0.258  0.677  0.184  1.0
  O  O17  1  0.258  0.823  0.816  1.0
  O  O18  1  0.258  0.177  0.816  1.0
  O  O19  1  0.742  0.823  0.184  1.0
  O  O20  1  0.385  0.000  0.361  1.0
  O  O21  1  0.615  0.000  0.639  1.0
  O  O22  1  0.615  0.500  0.361  1.0
  O  O23  1  0.385  0.500  0.639  1.0
[/CIF]
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The structure described by CsTm(MoO4)2 crystallizes in the orthorhombic Pccm space group. Cs(1) is bonded in a 8-coordinate geometry to four equivalent O(2) and four equivalent O(3) atoms. Tm(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(2) atoms. Mo(1) is bonded in a tetrahedral geometry to one O(1), one O(3), and two equivalent O(2) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent Tm(1) and one Mo(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Cs(1), one Tm(1), and one Mo(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Cs(1) and one Mo(1) atom. is represented by the CIF file [CIF]
data_CsTm(MoO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.074
_cell_length_b   8.061
_cell_length_c   9.599
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   392.623
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.000  0.250  0.500  1.0
  Cs  Cs1  1  0.000  0.750  0.500  1.0
  Tm  Tm2  1  0.000  0.250  0.000  1.0
  Tm  Tm3  1  0.000  0.750  0.000  1.0
  Mo  Mo4  1  0.522  0.000  0.194  1.0
  Mo  Mo5  1  0.478  0.000  0.806  1.0
  Mo  Mo6  1  0.478  0.500  0.194  1.0
  Mo  Mo7  1  0.522  0.500  0.806  1.0
  O  O8  1  0.245  0.000  0.064  1.0
  O  O9  1  0.755  0.000  0.936  1.0
  O  O10  1  0.755  0.500  0.064  1.0
  O  O11  1  0.245  0.500  0.936  1.0
  O  O12  1  0.258  0.323  0.184  1.0
  O  O13  1  0.742  0.677  0.816  1.0
  O  O14  1  0.742  0.323  0.816  1.0
  O  O15  1  0.742  0.177  0.184  1.0
  O  O16  1  0.258  0.677  0.184  1.0
  O  O17  1  0.258  0.823  0.816  1.0
  O  O18  1  0.258  0.177  0.816  1.0
  O  O19  1  0.742  0.823  0.184  1.0
  O  O20  1  0.385  0.000  0.361  1.0
  O  O21  1  0.615  0.000  0.639  1.0
  O  O22  1  0.615  0.500  0.361  1.0
  O  O23  1  0.385  0.500  0.639  1.0
[/CIF]
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