The structure described by TiCl4 is Silicon tetrafluoride-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four titanium tetrachloride molecules. Ti(1) is bonded in a tetrahedral geometry to one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Ti(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Ti(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Ti(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Ti(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_TiCl4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.606
_cell_length_b   9.879
_cell_length_c   9.868
_cell_angle_alpha   102.073
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   629.760
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.576  0.748  0.368  1.0
  Ti  Ti1  1  0.076  0.252  0.132  1.0
  Ti  Ti2  1  0.424  0.252  0.632  1.0
  Ti  Ti3  1  0.924  0.748  0.868  1.0
  Cl  Cl4  1  0.575  0.571  0.195  1.0
  Cl  Cl5  1  0.075  0.429  0.305  1.0
  Cl  Cl6  1  0.425  0.429  0.805  1.0
  Cl  Cl7  1  0.925  0.571  0.695  1.0
  Cl  Cl8  1  0.613  0.808  0.925  1.0
  Cl  Cl9  1  0.113  0.192  0.575  1.0
  Cl  Cl10  1  0.387  0.192  0.075  1.0
  Cl  Cl11  1  0.887  0.808  0.425  1.0
  Cl  Cl12  1  0.080  0.920  0.807  1.0
  Cl  Cl13  1  0.580  0.080  0.693  1.0
  Cl  Cl14  1  0.920  0.080  0.193  1.0
  Cl  Cl15  1  0.420  0.920  0.307  1.0
  Cl  Cl16  1  0.078  0.693  0.044  1.0
  Cl  Cl17  1  0.578  0.307  0.456  1.0
  Cl  Cl18  1  0.922  0.307  0.956  1.0
  Cl  Cl19  1  0.422  0.693  0.544  1.0
[/CIF]
.
The structure described by TiCl4 is Silicon tetrafluoride-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four titanium tetrachloride molecules. Ti(1) is bonded in a tetrahedral geometry to one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Ti(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Ti(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Ti(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Ti(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_TiCl4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.606
_cell_length_b   9.879
_cell_length_c   9.868
_cell_angle_alpha   102.073
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   629.760
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.576  0.748  0.368  1.0
  Ti  Ti1  1  0.076  0.252  0.132  1.0
  Ti  Ti2  1  0.424  0.252  0.632  1.0
  Ti  Ti3  1  0.924  0.748  0.868  1.0
  Cl  Cl4  1  0.575  0.571  0.195  1.0
  Cl  Cl5  1  0.075  0.429  0.305  1.0
  Cl  Cl6  1  0.425  0.429  0.805  1.0
  Cl  Cl7  1  0.925  0.571  0.695  1.0
  Cl  Cl8  1  0.613  0.808  0.925  1.0
  Cl  Cl9  1  0.113  0.192  0.575  1.0
  Cl  Cl10  1  0.387  0.192  0.075  1.0
  Cl  Cl11  1  0.887  0.808  0.425  1.0
  Cl  Cl12  1  0.080  0.920  0.807  1.0
  Cl  Cl13  1  0.580  0.080  0.693  1.0
  Cl  Cl14  1  0.920  0.080  0.193  1.0
  Cl  Cl15  1  0.420  0.920  0.307  1.0
  Cl  Cl16  1  0.078  0.693  0.044  1.0
  Cl  Cl17  1  0.578  0.307  0.456  1.0
  Cl  Cl18  1  0.922  0.307  0.956  1.0
  Cl  Cl19  1  0.422  0.693  0.544  1.0
[/CIF]
.