The compound described by K2PtC4(NS)4 crystallizes in the monoclinic P2_1/c space group. K(1) is bonded in a 7-coordinate geometry to one Pt(1), one N(2), two equivalent N(1), one S(2), and two equivalent S(1) atoms. Pt(1) is bonded in a linear geometry to two equivalent K(1) and two equivalent N(2) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one N(1) and one S(1) atom. In the second C site, C(2) is bonded in a distorted linear geometry to one N(2) and one S(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to two equivalent K(1) and one C(1) atom. In the second N site, N(2) is bonded in a 3-coordinate geometry to one K(1), one Pt(1), and one C(2) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a 3-coordinate geometry to two equivalent K(1) and one C(1) atom. In the second S site, S(2) is bonded in a bent 120 degrees geometry to one K(1) and one C(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_K2PtC4(SN)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   15.272
_cell_length_b   4.471
_cell_length_c   11.484
_cell_angle_alpha   77.371
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   765.219
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.812  0.655  0.961  1.0
  K  K1  1  0.188  0.345  0.039  1.0
  K  K2  1  0.688  0.655  0.461  1.0
  K  K3  1  0.312  0.345  0.539  1.0
  Pt  Pt4  1  0.000  0.000  0.000  1.0
  Pt  Pt5  1  0.500  0.000  0.500  1.0
  C  C6  1  0.656  0.221  0.212  1.0
  C  C7  1  0.156  0.779  0.288  1.0
  C  C8  1  0.844  0.221  0.712  1.0
  C  C9  1  0.922  0.010  0.225  1.0
  C  C10  1  0.344  0.779  0.788  1.0
  C  C11  1  0.578  0.010  0.725  1.0
  C  C12  1  0.078  0.990  0.775  1.0
  C  C13  1  0.422  0.990  0.275  1.0
  S  S14  1  0.660  0.160  0.077  1.0
  S  S15  1  0.160  0.840  0.423  1.0
  S  S16  1  0.840  0.160  0.577  1.0
  S  S17  1  0.907  0.824  0.356  1.0
  S  S18  1  0.407  0.176  0.144  1.0
  S  S19  1  0.593  0.824  0.856  1.0
  S  S20  1  0.093  0.176  0.644  1.0
  S  S21  1  0.340  0.840  0.923  1.0
  N  N22  1  0.653  0.263  0.311  1.0
  N  N23  1  0.065  0.857  0.878  1.0
  N  N24  1  0.435  0.857  0.378  1.0
  N  N25  1  0.935  0.143  0.122  1.0
  N  N26  1  0.565  0.143  0.622  1.0
  N  N27  1  0.153  0.737  0.189  1.0
  N  N28  1  0.847  0.263  0.811  1.0
  N  N29  1  0.347  0.737  0.689  1.0
[/CIF]
.
The compound described by K2PtC4(NS)4 crystallizes in the monoclinic P2_1/c space group. K(1) is bonded in a 7-coordinate geometry to one Pt(1), one N(2), two equivalent N(1), one S(2), and two equivalent S(1) atoms. Pt(1) is bonded in a linear geometry to two equivalent K(1) and two equivalent N(2) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one N(1) and one S(1) atom. In the second C site, C(2) is bonded in a distorted linear geometry to one N(2) and one S(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to two equivalent K(1) and one C(1) atom. In the second N site, N(2) is bonded in a 3-coordinate geometry to one K(1), one Pt(1), and one C(2) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a 3-coordinate geometry to two equivalent K(1) and one C(1) atom. In the second S site, S(2) is bonded in a bent 120 degrees geometry to one K(1) and one C(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_K2PtC4(SN)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   15.272
_cell_length_b   4.471
_cell_length_c   11.484
_cell_angle_alpha   77.371
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   765.219
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.812  0.655  0.961  1.0
  K  K1  1  0.188  0.345  0.039  1.0
  K  K2  1  0.688  0.655  0.461  1.0
  K  K3  1  0.312  0.345  0.539  1.0
  Pt  Pt4  1  0.000  0.000  0.000  1.0
  Pt  Pt5  1  0.500  0.000  0.500  1.0
  C  C6  1  0.656  0.221  0.212  1.0
  C  C7  1  0.156  0.779  0.288  1.0
  C  C8  1  0.844  0.221  0.712  1.0
  C  C9  1  0.922  0.010  0.225  1.0
  C  C10  1  0.344  0.779  0.788  1.0
  C  C11  1  0.578  0.010  0.725  1.0
  C  C12  1  0.078  0.990  0.775  1.0
  C  C13  1  0.422  0.990  0.275  1.0
  S  S14  1  0.660  0.160  0.077  1.0
  S  S15  1  0.160  0.840  0.423  1.0
  S  S16  1  0.840  0.160  0.577  1.0
  S  S17  1  0.907  0.824  0.356  1.0
  S  S18  1  0.407  0.176  0.144  1.0
  S  S19  1  0.593  0.824  0.856  1.0
  S  S20  1  0.093  0.176  0.644  1.0
  S  S21  1  0.340  0.840  0.923  1.0
  N  N22  1  0.653  0.263  0.311  1.0
  N  N23  1  0.065  0.857  0.878  1.0
  N  N24  1  0.435  0.857  0.378  1.0
  N  N25  1  0.935  0.143  0.122  1.0
  N  N26  1  0.565  0.143  0.622  1.0
  N  N27  1  0.153  0.737  0.189  1.0
  N  N28  1  0.847  0.263  0.811  1.0
  N  N29  1  0.347  0.737  0.689  1.0
[/CIF]
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