The structure described by SnNH3F3 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight SnNH3F3 clusters. Sn(1) is bonded in a 3-coordinate geometry to one F(1), one F(2), and one F(3) atom. N(1) is bonded in a trigonal non-coplanar geometry to one H(1), one H(2), and one H(3) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a distorted linear geometry to one N(1) and one F(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to one Sn(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Sn(1) atom. In the third F site, F(3) is bonded in a bent 120 degrees geometry to one Sn(1) and one H(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SnH3NF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.412
_cell_length_b   8.412
_cell_length_c   5.843
_cell_angle_alpha   78.746
_cell_angle_beta   78.746
_cell_angle_gamma   100.798
_symmetry_Int_Tables_number   1
_cell_volume   386.676
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.908  0.704  0.521  1.0
  Sn  Sn1  1  0.296  0.092  0.979  1.0
  Sn  Sn2  1  0.092  0.296  0.479  1.0
  Sn  Sn3  1  0.704  0.908  0.021  1.0
  H  H4  1  0.842  0.380  0.131  1.0
  H  H5  1  0.620  0.158  0.369  1.0
  H  H6  1  0.158  0.620  0.869  1.0
  H  H7  1  0.380  0.842  0.631  1.0
  H  H8  1  0.706  0.513  0.132  1.0
  H  H9  1  0.487  0.294  0.368  1.0
  H  H10  1  0.294  0.487  0.868  1.0
  H  H11  1  0.513  0.706  0.632  1.0
  H  H12  1  0.673  0.345  0.999  1.0
  H  H13  1  0.655  0.327  0.501  1.0
  H  H14  1  0.327  0.655  0.001  1.0
  H  H15  1  0.345  0.673  0.499  1.0
  N  N16  1  0.715  0.389  0.137  1.0
  N  N17  1  0.611  0.285  0.363  1.0
  N  N18  1  0.285  0.611  0.863  1.0
  N  N19  1  0.389  0.715  0.637  1.0
  F  F20  1  0.674  0.679  0.767  1.0
  F  F21  1  0.321  0.326  0.733  1.0
  F  F22  1  0.326  0.321  0.233  1.0
  F  F23  1  0.679  0.674  0.267  1.0
  F  F24  1  0.827  0.443  0.585  1.0
  F  F25  1  0.557  0.173  0.915  1.0
  F  F26  1  0.173  0.557  0.415  1.0
  F  F27  1  0.443  0.827  0.085  1.0
  F  F28  1  0.991  0.663  0.847  1.0
  F  F29  1  0.337  0.009  0.653  1.0
  F  F30  1  0.009  0.337  0.153  1.0
  F  F31  1  0.663  0.991  0.347  1.0
[/CIF]
.
The structure described by SnNH3F3 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight SnNH3F3 clusters. Sn(1) is bonded in a 3-coordinate geometry to one F(1), one F(2), and one F(3) atom. N(1) is bonded in a trigonal non-coplanar geometry to one H(1), one H(2), and one H(3) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a distorted linear geometry to one N(1) and one F(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to one Sn(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Sn(1) atom. In the third F site, F(3) is bonded in a bent 120 degrees geometry to one Sn(1) and one H(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SnH3NF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.412
_cell_length_b   8.412
_cell_length_c   5.843
_cell_angle_alpha   78.746
_cell_angle_beta   78.746
_cell_angle_gamma   100.798
_symmetry_Int_Tables_number   1
_cell_volume   386.676
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.908  0.704  0.521  1.0
  Sn  Sn1  1  0.296  0.092  0.979  1.0
  Sn  Sn2  1  0.092  0.296  0.479  1.0
  Sn  Sn3  1  0.704  0.908  0.021  1.0
  H  H4  1  0.842  0.380  0.131  1.0
  H  H5  1  0.620  0.158  0.369  1.0
  H  H6  1  0.158  0.620  0.869  1.0
  H  H7  1  0.380  0.842  0.631  1.0
  H  H8  1  0.706  0.513  0.132  1.0
  H  H9  1  0.487  0.294  0.368  1.0
  H  H10  1  0.294  0.487  0.868  1.0
  H  H11  1  0.513  0.706  0.632  1.0
  H  H12  1  0.673  0.345  0.999  1.0
  H  H13  1  0.655  0.327  0.501  1.0
  H  H14  1  0.327  0.655  0.001  1.0
  H  H15  1  0.345  0.673  0.499  1.0
  N  N16  1  0.715  0.389  0.137  1.0
  N  N17  1  0.611  0.285  0.363  1.0
  N  N18  1  0.285  0.611  0.863  1.0
  N  N19  1  0.389  0.715  0.637  1.0
  F  F20  1  0.674  0.679  0.767  1.0
  F  F21  1  0.321  0.326  0.733  1.0
  F  F22  1  0.326  0.321  0.233  1.0
  F  F23  1  0.679  0.674  0.267  1.0
  F  F24  1  0.827  0.443  0.585  1.0
  F  F25  1  0.557  0.173  0.915  1.0
  F  F26  1  0.173  0.557  0.415  1.0
  F  F27  1  0.443  0.827  0.085  1.0
  F  F28  1  0.991  0.663  0.847  1.0
  F  F29  1  0.337  0.009  0.653  1.0
  F  F30  1  0.009  0.337  0.153  1.0
  F  F31  1  0.663  0.991  0.347  1.0
[/CIF]
.