The crystal structure described by KSO3 crystallizes in the trigonal P321 space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), and four equivalent O(3) atoms. In the second K site, K(2) is bonded in a distorted octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. There are three inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to three equivalent O(1) atoms. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to three equivalent O(3) atoms. In the third S site, S(3) is bonded in a trigonal non-coplanar geometry to three equivalent O(2) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one K(1), one K(2), and one S(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one K(1), one K(2), and one S(3) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one K(2), two equivalent K(1), and one S(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_KSO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.872
_cell_length_b   9.872
_cell_length_c   6.299
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.001
_symmetry_Int_Tables_number   1
_cell_volume   531.658
_cell_formula_units_Z   6
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.722  0.722  0.500  1.0
  K  K1  1  0.379  0.379  0.000  1.0
  K  K2  1  0.621  0.000  0.000  1.0
  K  K3  1  0.278  1.000  0.500  1.0
  K  K4  1  1.000  0.621  0.000  1.0
  K  K5  1  0.000  0.278  0.500  1.0
  S  S6  1  0.333  0.667  0.688  1.0
  S  S7  1  1.000  1.000  0.826  1.0
  S  S8  1  0.333  0.667  0.343  1.0
  S  S9  1  0.667  0.333  0.312  1.0
  S  S10  1  0.000  1.000  0.174  1.0
  S  S11  1  0.667  0.333  0.657  1.0
  O  O12  1  0.361  0.821  0.747  1.0
  O  O13  1  0.639  0.460  0.253  1.0
  O  O14  1  0.246  0.744  0.285  1.0
  O  O15  1  0.987  0.852  0.235  1.0
  O  O16  1  0.148  0.135  0.235  1.0
  O  O17  1  0.502  0.256  0.715  1.0
  O  O18  1  0.821  0.361  0.253  1.0
  O  O19  1  0.013  0.865  0.765  1.0
  O  O20  1  0.744  0.246  0.715  1.0
  O  O21  1  0.852  0.987  0.765  1.0
  O  O22  1  0.460  0.639  0.747  1.0
  O  O23  1  0.135  0.148  0.765  1.0
  O  O24  1  0.865  0.013  0.235  1.0
  O  O25  1  0.498  0.754  0.285  1.0
  O  O26  1  0.540  0.179  0.253  1.0
  O  O27  1  0.256  0.502  0.285  1.0
  O  O28  1  0.179  0.540  0.747  1.0
  O  O29  1  0.754  0.498  0.715  1.0
[/CIF]
.
The crystal structure described by KSO3 crystallizes in the trigonal P321 space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), and four equivalent O(3) atoms. In the second K site, K(2) is bonded in a distorted octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. There are three inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to three equivalent O(1) atoms. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to three equivalent O(3) atoms. In the third S site, S(3) is bonded in a trigonal non-coplanar geometry to three equivalent O(2) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one K(1), one K(2), and one S(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one K(1), one K(2), and one S(3) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one K(2), two equivalent K(1), and one S(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_KSO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.872
_cell_length_b   9.872
_cell_length_c   6.299
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.001
_symmetry_Int_Tables_number   1
_cell_volume   531.658
_cell_formula_units_Z   6
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.722  0.722  0.500  1.0
  K  K1  1  0.379  0.379  0.000  1.0
  K  K2  1  0.621  0.000  0.000  1.0
  K  K3  1  0.278  1.000  0.500  1.0
  K  K4  1  1.000  0.621  0.000  1.0
  K  K5  1  0.000  0.278  0.500  1.0
  S  S6  1  0.333  0.667  0.688  1.0
  S  S7  1  1.000  1.000  0.826  1.0
  S  S8  1  0.333  0.667  0.343  1.0
  S  S9  1  0.667  0.333  0.312  1.0
  S  S10  1  0.000  1.000  0.174  1.0
  S  S11  1  0.667  0.333  0.657  1.0
  O  O12  1  0.361  0.821  0.747  1.0
  O  O13  1  0.639  0.460  0.253  1.0
  O  O14  1  0.246  0.744  0.285  1.0
  O  O15  1  0.987  0.852  0.235  1.0
  O  O16  1  0.148  0.135  0.235  1.0
  O  O17  1  0.502  0.256  0.715  1.0
  O  O18  1  0.821  0.361  0.253  1.0
  O  O19  1  0.013  0.865  0.765  1.0
  O  O20  1  0.744  0.246  0.715  1.0
  O  O21  1  0.852  0.987  0.765  1.0
  O  O22  1  0.460  0.639  0.747  1.0
  O  O23  1  0.135  0.148  0.765  1.0
  O  O24  1  0.865  0.013  0.235  1.0
  O  O25  1  0.498  0.754  0.285  1.0
  O  O26  1  0.540  0.179  0.253  1.0
  O  O27  1  0.256  0.502  0.285  1.0
  O  O28  1  0.179  0.540  0.747  1.0
  O  O29  1  0.754  0.498  0.715  1.0
[/CIF]
.