The material described by HgCl2C4NCl is Cyanogen Chloride-derived structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of four mercuric chloride molecules and four C4NCl clusters. In two of the C4NCl clusters, there are four inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 150 degrees geometry to one C(2) and one N(1) atom. In the second C site, C(2) is bonded in a linear geometry to one C(1) and one C(4) atom. In the third C site, C(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth C site, C(4) is bonded in a distorted linear geometry to one C(2) and one Cl(6) atom. N(1) is bonded in a linear geometry to one C(1) and one C(3) atom. Cl(6) is bonded in a single-bond geometry to one C(4) atom. In two of the C4NCl clusters, there are four inequivalent C sites. In the first C site, C(5) is bonded in a single-bond geometry to one N(2) atom. In the second C site, C(6) is bonded in a 2-coordinate geometry to one C(7) and one C(8) atom. In the third C site, C(7) is bonded in a distorted single-bond geometry to one C(6), one C(8), and one Cl(2) atom. In the fourth C site, C(8) is bonded in a distorted single-bond geometry to one C(6), one C(7), and one N(2) atom. N(2) is bonded in a linear geometry to one C(5) and one C(8) atom. Cl(2) is bonded in a single-bond geometry to one C(7) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_HgC4NCl3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   15.664
_cell_length_b   7.579
_cell_length_c   10.080
_cell_angle_alpha   85.590
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1193.087
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Hg  Hg0  1  0.534  0.076  0.751  1.0
  Hg  Hg1  1  0.034  0.924  0.249  1.0
  Hg  Hg2  1  0.520  0.514  0.624  1.0
  Hg  Hg3  1  0.020  0.486  0.376  1.0
  C  C4  1  0.696  0.083  0.278  1.0
  C  C5  1  0.196  0.917  0.722  1.0
  C  C6  1  0.679  0.983  0.181  1.0
  C  C7  1  0.179  0.017  0.819  1.0
  C  C8  1  0.722  0.102  0.520  1.0
  C  C9  1  0.222  0.898  0.480  1.0
  C  C10  1  0.665  0.889  0.087  1.0
  C  C11  1  0.165  0.111  0.913  1.0
  C  C12  1  0.838  0.684  0.627  1.0
  C  C13  1  0.338  0.316  0.373  1.0
  C  C14  1  0.952  0.428  0.907  1.0
  C  C15  1  0.452  0.572  0.093  1.0
  C  C16  1  0.896  0.294  0.868  1.0
  C  C17  1  0.396  0.706  0.132  1.0
  C  C18  1  0.890  0.454  0.803  1.0
  C  C19  1  0.390  0.546  0.197  1.0
  N  N20  1  0.710  0.093  0.402  1.0
  N  N21  1  0.210  0.907  0.598  1.0
  N  N22  1  0.859  0.572  0.710  1.0
  N  N23  1  0.359  0.428  0.290  1.0
  Cl  Cl24  1  0.450  0.901  0.626  1.0
  Cl  Cl25  1  0.950  0.099  0.374  1.0
  Cl  Cl26  1  0.366  0.917  0.104  1.0
  Cl  Cl27  1  0.866  0.083  0.896  1.0
  Cl  Cl28  1  0.621  0.252  0.870  1.0
  Cl  Cl29  1  0.121  0.748  0.130  1.0
  Cl  Cl30  1  0.405  0.412  0.752  1.0
  Cl  Cl31  1  0.905  0.588  0.248  1.0
  Cl  Cl32  1  0.635  0.574  0.486  1.0
  Cl  Cl33  1  0.135  0.426  0.514  1.0
  Cl  Cl34  1  0.642  0.748  0.981  1.0
  Cl  Cl35  1  0.142  0.252  0.019  1.0
[/CIF]
.
The material described by HgCl2C4NCl is Cyanogen Chloride-derived structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of four mercuric chloride molecules and four C4NCl clusters. In two of the C4NCl clusters, there are four inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 150 degrees geometry to one C(2) and one N(1) atom. In the second C site, C(2) is bonded in a linear geometry to one C(1) and one C(4) atom. In the third C site, C(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth C site, C(4) is bonded in a distorted linear geometry to one C(2) and one Cl(6) atom. N(1) is bonded in a linear geometry to one C(1) and one C(3) atom. Cl(6) is bonded in a single-bond geometry to one C(4) atom. In two of the C4NCl clusters, there are four inequivalent C sites. In the first C site, C(5) is bonded in a single-bond geometry to one N(2) atom. In the second C site, C(6) is bonded in a 2-coordinate geometry to one C(7) and one C(8) atom. In the third C site, C(7) is bonded in a distorted single-bond geometry to one C(6), one C(8), and one Cl(2) atom. In the fourth C site, C(8) is bonded in a distorted single-bond geometry to one C(6), one C(7), and one N(2) atom. N(2) is bonded in a linear geometry to one C(5) and one C(8) atom. Cl(2) is bonded in a single-bond geometry to one C(7) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_HgC4NCl3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   15.664
_cell_length_b   7.579
_cell_length_c   10.080
_cell_angle_alpha   85.590
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1193.087
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Hg  Hg0  1  0.534  0.076  0.751  1.0
  Hg  Hg1  1  0.034  0.924  0.249  1.0
  Hg  Hg2  1  0.520  0.514  0.624  1.0
  Hg  Hg3  1  0.020  0.486  0.376  1.0
  C  C4  1  0.696  0.083  0.278  1.0
  C  C5  1  0.196  0.917  0.722  1.0
  C  C6  1  0.679  0.983  0.181  1.0
  C  C7  1  0.179  0.017  0.819  1.0
  C  C8  1  0.722  0.102  0.520  1.0
  C  C9  1  0.222  0.898  0.480  1.0
  C  C10  1  0.665  0.889  0.087  1.0
  C  C11  1  0.165  0.111  0.913  1.0
  C  C12  1  0.838  0.684  0.627  1.0
  C  C13  1  0.338  0.316  0.373  1.0
  C  C14  1  0.952  0.428  0.907  1.0
  C  C15  1  0.452  0.572  0.093  1.0
  C  C16  1  0.896  0.294  0.868  1.0
  C  C17  1  0.396  0.706  0.132  1.0
  C  C18  1  0.890  0.454  0.803  1.0
  C  C19  1  0.390  0.546  0.197  1.0
  N  N20  1  0.710  0.093  0.402  1.0
  N  N21  1  0.210  0.907  0.598  1.0
  N  N22  1  0.859  0.572  0.710  1.0
  N  N23  1  0.359  0.428  0.290  1.0
  Cl  Cl24  1  0.450  0.901  0.626  1.0
  Cl  Cl25  1  0.950  0.099  0.374  1.0
  Cl  Cl26  1  0.366  0.917  0.104  1.0
  Cl  Cl27  1  0.866  0.083  0.896  1.0
  Cl  Cl28  1  0.621  0.252  0.870  1.0
  Cl  Cl29  1  0.121  0.748  0.130  1.0
  Cl  Cl30  1  0.405  0.412  0.752  1.0
  Cl  Cl31  1  0.905  0.588  0.248  1.0
  Cl  Cl32  1  0.635  0.574  0.486  1.0
  Cl  Cl33  1  0.135  0.426  0.514  1.0
  Cl  Cl34  1  0.642  0.748  0.981  1.0
  Cl  Cl35  1  0.142  0.252  0.019  1.0
[/CIF]
.