The material described by Ag2VO2PO4 crystallizes in the monoclinic C2/m space group. V(1) is bonded in a 6-coordinate geometry to one O(4), one O(5), two equivalent O(1), and two equivalent O(3) atoms. Ag(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(3), and one O(5) atom. P(1) is bonded in a tetrahedral geometry to one O(2), one O(5), and two equivalent O(3) atoms. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent V(1) and two equivalent Ag(1) atoms. In the second O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Ag(1) and one P(1) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one V(1), one Ag(1), and one P(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one V(1) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one V(1), two equivalent Ag(1), and one P(1) atom. is represented by the CIF file [CIF]
data_VAg2PO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.057
_cell_length_b   7.057
_cell_length_c   6.435
_cell_angle_alpha   89.970
_cell_angle_beta   89.970
_cell_angle_gamma   53.466
_symmetry_Int_Tables_number   1
_cell_volume   257.505
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.615  0.615  0.086  1.0
  V  V1  1  0.385  0.385  0.914  1.0
  Ag  Ag2  1  0.364  0.876  0.619  1.0
  Ag  Ag3  1  0.876  0.364  0.619  1.0
  Ag  Ag4  1  0.636  0.124  0.381  1.0
  Ag  Ag5  1  0.124  0.636  0.381  1.0
  P  P6  1  0.847  0.847  0.849  1.0
  P  P7  1  0.153  0.153  0.151  1.0
  O  O8  1  0.510  0.510  0.797  1.0
  O  O9  1  0.099  0.099  0.365  1.0
  O  O10  1  0.315  0.922  0.023  1.0
  O  O11  1  0.301  0.301  0.714  1.0
  O  O12  1  0.685  0.078  0.977  1.0
  O  O13  1  0.277  0.277  0.174  1.0
  O  O14  1  0.922  0.315  0.023  1.0
  O  O15  1  0.901  0.901  0.635  1.0
  O  O16  1  0.699  0.699  0.286  1.0
  O  O17  1  0.490  0.490  0.203  1.0
  O  O18  1  0.078  0.685  0.977  1.0
  O  O19  1  0.723  0.723  0.826  1.0
[/CIF]
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The material described by Ag2VO2PO4 crystallizes in the monoclinic C2/m space group. V(1) is bonded in a 6-coordinate geometry to one O(4), one O(5), two equivalent O(1), and two equivalent O(3) atoms. Ag(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(3), and one O(5) atom. P(1) is bonded in a tetrahedral geometry to one O(2), one O(5), and two equivalent O(3) atoms. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent V(1) and two equivalent Ag(1) atoms. In the second O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Ag(1) and one P(1) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one V(1), one Ag(1), and one P(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one V(1) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one V(1), two equivalent Ag(1), and one P(1) atom. is represented by the CIF file [CIF]
data_VAg2PO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.057
_cell_length_b   7.057
_cell_length_c   6.435
_cell_angle_alpha   89.970
_cell_angle_beta   89.970
_cell_angle_gamma   53.466
_symmetry_Int_Tables_number   1
_cell_volume   257.505
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.615  0.615  0.086  1.0
  V  V1  1  0.385  0.385  0.914  1.0
  Ag  Ag2  1  0.364  0.876  0.619  1.0
  Ag  Ag3  1  0.876  0.364  0.619  1.0
  Ag  Ag4  1  0.636  0.124  0.381  1.0
  Ag  Ag5  1  0.124  0.636  0.381  1.0
  P  P6  1  0.847  0.847  0.849  1.0
  P  P7  1  0.153  0.153  0.151  1.0
  O  O8  1  0.510  0.510  0.797  1.0
  O  O9  1  0.099  0.099  0.365  1.0
  O  O10  1  0.315  0.922  0.023  1.0
  O  O11  1  0.301  0.301  0.714  1.0
  O  O12  1  0.685  0.078  0.977  1.0
  O  O13  1  0.277  0.277  0.174  1.0
  O  O14  1  0.922  0.315  0.023  1.0
  O  O15  1  0.901  0.901  0.635  1.0
  O  O16  1  0.699  0.699  0.286  1.0
  O  O17  1  0.490  0.490  0.203  1.0
  O  O18  1  0.078  0.685  0.977  1.0
  O  O19  1  0.723  0.723  0.826  1.0
[/CIF]
.