The structure described by (Zn2P3O13)2(O2)3 crystallizes in the triclinic P-1 space group. The structure consists of three 7782-44-7 molecules inside a Zn2P3O13 framework. In the Zn2P3O13 framework, there are three inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to two equivalent O(10), two equivalent O(12), and two equivalent O(5) atoms to form ZnO6 octahedra that share corners with two equivalent P(2)O4 tetrahedra and corners with two equivalent P(3)O4 tetrahedra. In the second Zn site, Zn(2) is bonded in a square co-planar geometry to two equivalent O(11), two equivalent O(2), and two equivalent O(6) atoms. In the third Zn site, Zn(3) is bonded to one O(1), one O(3), one O(8), and one O(9) atom to form ZnO4 tetrahedra that share corners with two equivalent P(1)O4 tetrahedra and corners with two equivalent P(3)O4 tetrahedra. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one P(2)O4 tetrahedra and corners with two equivalent Zn(3)O4 tetrahedra. In the second P site, P(2) is bonded to one O(4), one O(5), one O(6), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Zn(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 49°. In the third P site, P(3) is bonded to one O(10), one O(7), one O(8), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Zn(1)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra, and corners with two equivalent Zn(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 55°. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(3) and one P(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one P(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Zn(3) and one P(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one P(2) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(2) and one P(2) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one P(2) and one P(3) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one Zn(3) and one P(3) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Zn(3) and one P(3) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Zn(1) and one P(3) atom. In the eleventh O site, O(11) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one O(15) atom. In the twelfth O site, O(12) is bonded in a single-bond geometry to one Zn(1) atom. In the thirteenth O site, O(15) is bonded in a single-bond geometry to one O(11) atom. is represented by the CIF card [CIF]
data_Zn2P3O16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.841
_cell_length_b   10.350
_cell_length_c   10.594
_cell_angle_alpha   96.236
_cell_angle_beta   101.420
_cell_angle_gamma   113.100
_symmetry_Int_Tables_number   1
_cell_volume   855.166
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.000  0.000  0.000  1.0
  Zn  Zn1  1  0.500  0.500  0.500  1.0
  Zn  Zn2  1  0.235  0.518  0.949  1.0
  Zn  Zn3  1  0.765  0.482  0.051  1.0
  P  P4  1  0.516  0.552  0.203  1.0
  P  P5  1  0.484  0.448  0.797  1.0
  P  P6  1  0.269  0.278  0.233  1.0
  P  P7  1  0.731  0.722  0.767  1.0
  P  P8  1  0.961  0.289  0.078  1.0
  P  P9  1  0.039  0.711  0.922  1.0
  O  O10  1  0.415  0.614  0.114  1.0
  O  O11  1  0.585  0.386  0.886  1.0
  O  O12  1  0.532  0.602  0.347  1.0
  O  O13  1  0.468  0.398  0.653  1.0
  O  O14  1  0.311  0.423  0.822  1.0
  O  O15  1  0.689  0.577  0.178  1.0
  O  O16  1  0.405  0.376  0.162  1.0
  O  O17  1  0.595  0.624  0.838  1.0
  O  O18  1  0.207  0.125  0.163  1.0
  O  O19  1  0.793  0.875  0.837  1.0
  O  O20  1  0.346  0.313  0.380  1.0
  O  O21  1  0.654  0.687  0.620  1.0
  O  O22  1  0.116  0.330  0.210  1.0
  O  O23  1  0.884  0.670  0.790  1.0
  O  O24  1  0.036  0.357  0.971  1.0
  O  O25  1  0.964  0.643  0.029  1.0
  O  O26  1  0.839  0.343  0.122  1.0
  O  O27  1  0.161  0.657  0.878  1.0
  O  O28  1  0.874  0.124  0.033  1.0
  O  O29  1  0.126  0.876  0.967  1.0
  O  O30  1  0.755  0.437  0.470  1.0
  O  O31  1  0.245  0.563  0.530  1.0
  O  O32  1  0.138  0.093  0.875  1.0
  O  O33  1  0.862  0.907  0.125  1.0
  O  O34  1  0.919  0.299  0.640  1.0
  O  O35  1  0.081  0.701  0.360  1.0
  O  O36  1  0.465  0.040  0.002  1.0
  O  O37  1  0.535  0.960  0.998  1.0
  O  O38  1  0.738  0.341  0.381  1.0
  O  O39  1  0.262  0.659  0.619  1.0
  O  O40  1  0.010  0.287  0.571  1.0
  O  O41  1  0.990  0.713  0.429  1.0
[/CIF]
.
The structure described by (Zn2P3O13)2(O2)3 crystallizes in the triclinic P-1 space group. The structure consists of three 7782-44-7 molecules inside a Zn2P3O13 framework. In the Zn2P3O13 framework, there are three inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to two equivalent O(10), two equivalent O(12), and two equivalent O(5) atoms to form ZnO6 octahedra that share corners with two equivalent P(2)O4 tetrahedra and corners with two equivalent P(3)O4 tetrahedra. In the second Zn site, Zn(2) is bonded in a square co-planar geometry to two equivalent O(11), two equivalent O(2), and two equivalent O(6) atoms. In the third Zn site, Zn(3) is bonded to one O(1), one O(3), one O(8), and one O(9) atom to form ZnO4 tetrahedra that share corners with two equivalent P(1)O4 tetrahedra and corners with two equivalent P(3)O4 tetrahedra. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one P(2)O4 tetrahedra and corners with two equivalent Zn(3)O4 tetrahedra. In the second P site, P(2) is bonded to one O(4), one O(5), one O(6), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Zn(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 49°. In the third P site, P(3) is bonded to one O(10), one O(7), one O(8), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Zn(1)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra, and corners with two equivalent Zn(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 55°. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(3) and one P(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one P(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Zn(3) and one P(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one P(2) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(2) and one P(2) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one P(2) and one P(3) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one Zn(3) and one P(3) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Zn(3) and one P(3) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Zn(1) and one P(3) atom. In the eleventh O site, O(11) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one O(15) atom. In the twelfth O site, O(12) is bonded in a single-bond geometry to one Zn(1) atom. In the thirteenth O site, O(15) is bonded in a single-bond geometry to one O(11) atom. is represented by the CIF card [CIF]
data_Zn2P3O16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.841
_cell_length_b   10.350
_cell_length_c   10.594
_cell_angle_alpha   96.236
_cell_angle_beta   101.420
_cell_angle_gamma   113.100
_symmetry_Int_Tables_number   1
_cell_volume   855.166
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.000  0.000  0.000  1.0
  Zn  Zn1  1  0.500  0.500  0.500  1.0
  Zn  Zn2  1  0.235  0.518  0.949  1.0
  Zn  Zn3  1  0.765  0.482  0.051  1.0
  P  P4  1  0.516  0.552  0.203  1.0
  P  P5  1  0.484  0.448  0.797  1.0
  P  P6  1  0.269  0.278  0.233  1.0
  P  P7  1  0.731  0.722  0.767  1.0
  P  P8  1  0.961  0.289  0.078  1.0
  P  P9  1  0.039  0.711  0.922  1.0
  O  O10  1  0.415  0.614  0.114  1.0
  O  O11  1  0.585  0.386  0.886  1.0
  O  O12  1  0.532  0.602  0.347  1.0
  O  O13  1  0.468  0.398  0.653  1.0
  O  O14  1  0.311  0.423  0.822  1.0
  O  O15  1  0.689  0.577  0.178  1.0
  O  O16  1  0.405  0.376  0.162  1.0
  O  O17  1  0.595  0.624  0.838  1.0
  O  O18  1  0.207  0.125  0.163  1.0
  O  O19  1  0.793  0.875  0.837  1.0
  O  O20  1  0.346  0.313  0.380  1.0
  O  O21  1  0.654  0.687  0.620  1.0
  O  O22  1  0.116  0.330  0.210  1.0
  O  O23  1  0.884  0.670  0.790  1.0
  O  O24  1  0.036  0.357  0.971  1.0
  O  O25  1  0.964  0.643  0.029  1.0
  O  O26  1  0.839  0.343  0.122  1.0
  O  O27  1  0.161  0.657  0.878  1.0
  O  O28  1  0.874  0.124  0.033  1.0
  O  O29  1  0.126  0.876  0.967  1.0
  O  O30  1  0.755  0.437  0.470  1.0
  O  O31  1  0.245  0.563  0.530  1.0
  O  O32  1  0.138  0.093  0.875  1.0
  O  O33  1  0.862  0.907  0.125  1.0
  O  O34  1  0.919  0.299  0.640  1.0
  O  O35  1  0.081  0.701  0.360  1.0
  O  O36  1  0.465  0.040  0.002  1.0
  O  O37  1  0.535  0.960  0.998  1.0
  O  O38  1  0.738  0.341  0.381  1.0
  O  O39  1  0.262  0.659  0.619  1.0
  O  O40  1  0.010  0.287  0.571  1.0
  O  O41  1  0.990  0.713  0.429  1.0
[/CIF]
.