The structure described by Sr10P6O24ClF crystallizes in the trigonal P3 space group. There are six inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 9-coordinate geometry to three equivalent O(1), three equivalent O(5), and three equivalent O(8) atoms. In the second Sr site, Sr(2) is bonded in a 9-coordinate geometry to three equivalent O(2), three equivalent O(6), and three equivalent O(7) atoms. In the third Sr site, Sr(3) is bonded in a 9-coordinate geometry to three equivalent O(2), three equivalent O(3), and three equivalent O(7) atoms. In the fourth Sr site, Sr(4) is bonded in a 9-coordinate geometry to three equivalent O(1), three equivalent O(4), and three equivalent O(8) atoms. In the fifth Sr site, Sr(5) is bonded in a 7-coordinate geometry to one O(1), one O(3), one O(4), one O(5), one O(6), one O(7), and one Cl(1) atom. In the sixth Sr site, Sr(6) is bonded in a 7-coordinate geometry to one O(2), one O(3), one O(4), one O(5), one O(6), one O(8), and one F(1) atom. There are two inequivalent P sites. In the first P site, P(1) is bonded in a tetrahedral geometry to one O(1), one O(3), one O(6), and one O(7) atom. In the second P site, P(2) is bonded in a tetrahedral geometry to one O(2), one O(4), one O(5), and one O(8) atom. There are eight inequivalent O sites. In the first O site, O(6) is bonded in a 1-coordinate geometry to one Sr(2), one Sr(5), one Sr(6), and one P(1) atom. In the second O site, O(7) is bonded in a 4-coordinate geometry to one Sr(2), one Sr(3), one Sr(5), and one P(1) atom. In the third O site, O(8) is bonded in a 4-coordinate geometry to one Sr(1), one Sr(4), one Sr(6), and one P(2) atom. In the fourth O site, O(1) is bonded in a distorted single-bond geometry to one Sr(1), one Sr(4), one Sr(5), and one P(1) atom. In the fifth O site, O(2) is bonded in a 1-coordinate geometry to one Sr(2), one Sr(3), one Sr(6), and one P(2) atom. In the sixth O site, O(3) is bonded in a distorted single-bond geometry to one Sr(3), one Sr(5), one Sr(6), and one P(1) atom. In the seventh O site, O(4) is bonded in a 1-coordinate geometry to one Sr(4), one Sr(5), one Sr(6), and one P(2) atom. In the eighth O site, O(5) is bonded in a 1-coordinate geometry to one Sr(1), one Sr(5), one Sr(6), and one P(2) atom. Cl(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Sr(5) atoms. F(1) is bonded in a trigonal non-coplanar geometry to three equivalent Sr(6) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sr10P6ClO24F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.941
_cell_length_b   9.941
_cell_length_c   7.334
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   627.659
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.000  0.000  0.502  1.0
  Sr  Sr1  1  0.333  0.667  0.001  1.0
  Sr  Sr2  1  0.333  0.667  0.501  1.0
  Sr  Sr3  1  0.000  0.000  0.997  1.0
  Sr  Sr4  1  0.923  0.326  0.251  1.0
  Sr  Sr5  1  0.403  0.077  0.251  1.0
  Sr  Sr6  1  0.674  0.597  0.251  1.0
  Sr  Sr7  1  0.428  0.339  0.752  1.0
  Sr  Sr8  1  0.912  0.572  0.752  1.0
  Sr  Sr9  1  0.661  0.088  0.752  1.0
  P  P10  1  0.638  0.934  0.250  1.0
  P  P11  1  0.296  0.362  0.250  1.0
  P  P12  1  0.066  0.704  0.250  1.0
  P  P13  1  0.694  0.735  0.749  1.0
  P  P14  1  0.040  0.306  0.749  1.0
  P  P15  1  0.265  0.960  0.749  1.0
  Cl  Cl16  1  0.667  0.333  0.084  1.0
  O  O17  1  0.817  0.997  0.250  1.0
  O  O18  1  0.180  0.183  0.250  1.0
  O  O19  1  0.003  0.820  0.250  1.0
  O  O20  1  0.516  0.670  0.749  1.0
  O  O21  1  0.153  0.484  0.749  1.0
  O  O22  1  0.330  0.847  0.749  1.0
  O  O23  1  0.590  0.996  0.419  1.0
  O  O24  1  0.405  0.410  0.419  1.0
  O  O25  1  0.004  0.595  0.419  1.0
  O  O26  1  0.745  0.679  0.921  1.0
  O  O27  1  0.934  0.255  0.921  1.0
  O  O28  1  0.321  0.066  0.921  1.0
  O  O29  1  0.745  0.677  0.579  1.0
  O  O30  1  0.933  0.255  0.579  1.0
  O  O31  1  0.323  0.067  0.579  1.0
  O  O32  1  0.585  0.983  0.075  1.0
  O  O33  1  0.398  0.415  0.075  1.0
  O  O34  1  0.017  0.602  0.075  1.0
  O  O35  1  0.547  0.752  0.255  1.0
  O  O36  1  0.205  0.453  0.255  1.0
  O  O37  1  0.248  0.795  0.255  1.0
  O  O38  1  0.785  0.916  0.748  1.0
  O  O39  1  0.132  0.215  0.748  1.0
  O  O40  1  0.084  0.868  0.748  1.0
  F  F41  1  0.667  0.333  0.670  1.0
[/CIF]
.
The structure described by Sr10P6O24ClF crystallizes in the trigonal P3 space group. There are six inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 9-coordinate geometry to three equivalent O(1), three equivalent O(5), and three equivalent O(8) atoms. In the second Sr site, Sr(2) is bonded in a 9-coordinate geometry to three equivalent O(2), three equivalent O(6), and three equivalent O(7) atoms. In the third Sr site, Sr(3) is bonded in a 9-coordinate geometry to three equivalent O(2), three equivalent O(3), and three equivalent O(7) atoms. In the fourth Sr site, Sr(4) is bonded in a 9-coordinate geometry to three equivalent O(1), three equivalent O(4), and three equivalent O(8) atoms. In the fifth Sr site, Sr(5) is bonded in a 7-coordinate geometry to one O(1), one O(3), one O(4), one O(5), one O(6), one O(7), and one Cl(1) atom. In the sixth Sr site, Sr(6) is bonded in a 7-coordinate geometry to one O(2), one O(3), one O(4), one O(5), one O(6), one O(8), and one F(1) atom. There are two inequivalent P sites. In the first P site, P(1) is bonded in a tetrahedral geometry to one O(1), one O(3), one O(6), and one O(7) atom. In the second P site, P(2) is bonded in a tetrahedral geometry to one O(2), one O(4), one O(5), and one O(8) atom. There are eight inequivalent O sites. In the first O site, O(6) is bonded in a 1-coordinate geometry to one Sr(2), one Sr(5), one Sr(6), and one P(1) atom. In the second O site, O(7) is bonded in a 4-coordinate geometry to one Sr(2), one Sr(3), one Sr(5), and one P(1) atom. In the third O site, O(8) is bonded in a 4-coordinate geometry to one Sr(1), one Sr(4), one Sr(6), and one P(2) atom. In the fourth O site, O(1) is bonded in a distorted single-bond geometry to one Sr(1), one Sr(4), one Sr(5), and one P(1) atom. In the fifth O site, O(2) is bonded in a 1-coordinate geometry to one Sr(2), one Sr(3), one Sr(6), and one P(2) atom. In the sixth O site, O(3) is bonded in a distorted single-bond geometry to one Sr(3), one Sr(5), one Sr(6), and one P(1) atom. In the seventh O site, O(4) is bonded in a 1-coordinate geometry to one Sr(4), one Sr(5), one Sr(6), and one P(2) atom. In the eighth O site, O(5) is bonded in a 1-coordinate geometry to one Sr(1), one Sr(5), one Sr(6), and one P(2) atom. Cl(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Sr(5) atoms. F(1) is bonded in a trigonal non-coplanar geometry to three equivalent Sr(6) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sr10P6ClO24F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.941
_cell_length_b   9.941
_cell_length_c   7.334
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   627.659
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.000  0.000  0.502  1.0
  Sr  Sr1  1  0.333  0.667  0.001  1.0
  Sr  Sr2  1  0.333  0.667  0.501  1.0
  Sr  Sr3  1  0.000  0.000  0.997  1.0
  Sr  Sr4  1  0.923  0.326  0.251  1.0
  Sr  Sr5  1  0.403  0.077  0.251  1.0
  Sr  Sr6  1  0.674  0.597  0.251  1.0
  Sr  Sr7  1  0.428  0.339  0.752  1.0
  Sr  Sr8  1  0.912  0.572  0.752  1.0
  Sr  Sr9  1  0.661  0.088  0.752  1.0
  P  P10  1  0.638  0.934  0.250  1.0
  P  P11  1  0.296  0.362  0.250  1.0
  P  P12  1  0.066  0.704  0.250  1.0
  P  P13  1  0.694  0.735  0.749  1.0
  P  P14  1  0.040  0.306  0.749  1.0
  P  P15  1  0.265  0.960  0.749  1.0
  Cl  Cl16  1  0.667  0.333  0.084  1.0
  O  O17  1  0.817  0.997  0.250  1.0
  O  O18  1  0.180  0.183  0.250  1.0
  O  O19  1  0.003  0.820  0.250  1.0
  O  O20  1  0.516  0.670  0.749  1.0
  O  O21  1  0.153  0.484  0.749  1.0
  O  O22  1  0.330  0.847  0.749  1.0
  O  O23  1  0.590  0.996  0.419  1.0
  O  O24  1  0.405  0.410  0.419  1.0
  O  O25  1  0.004  0.595  0.419  1.0
  O  O26  1  0.745  0.679  0.921  1.0
  O  O27  1  0.934  0.255  0.921  1.0
  O  O28  1  0.321  0.066  0.921  1.0
  O  O29  1  0.745  0.677  0.579  1.0
  O  O30  1  0.933  0.255  0.579  1.0
  O  O31  1  0.323  0.067  0.579  1.0
  O  O32  1  0.585  0.983  0.075  1.0
  O  O33  1  0.398  0.415  0.075  1.0
  O  O34  1  0.017  0.602  0.075  1.0
  O  O35  1  0.547  0.752  0.255  1.0
  O  O36  1  0.205  0.453  0.255  1.0
  O  O37  1  0.248  0.795  0.255  1.0
  O  O38  1  0.785  0.916  0.748  1.0
  O  O39  1  0.132  0.215  0.748  1.0
  O  O40  1  0.084  0.868  0.748  1.0
  F  F41  1  0.667  0.333  0.670  1.0
[/CIF]
.