The material described by (RhN3O5)2N2(NO2)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four ammonia atoms, four nitrous acid molecules, and two RhN3O5 clusters. In each RhN3O5 cluster, Rh(1) is bonded in a 5-coordinate geometry to one N(1), one N(2), one N(4), and two equivalent O(1) atoms. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Rh(1), one O(2), and one O(3) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Rh(1), one O(4), and one O(5) atom. In the third N site, N(4) is bonded in a single-bond geometry to one Rh(1) atom. There are five inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one N(1) atom. In the second O site, O(4) is bonded in a single-bond geometry to one N(2) atom. In the third O site, O(5) is bonded in a single-bond geometry to one N(2) atom. In the fourth O site, O(1) is bonded in a water-like geometry to two equivalent Rh(1) atoms. In the fifth O site, O(2) is bonded in a single-bond geometry to one N(1) atom. is represented by the CIF file [CIF]
data_RhN5O7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.286
_cell_length_b   6.484
_cell_length_c   14.332
_cell_angle_alpha   76.955
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   840.685
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rh  Rh0  1  0.334  0.020  0.496  1.0
  Rh  Rh1  1  0.834  0.980  0.004  1.0
  Rh  Rh2  1  0.666  0.980  0.504  1.0
  Rh  Rh3  1  0.166  0.020  0.996  1.0
  N  N4  1  0.227  0.334  0.460  1.0
  N  N5  1  0.727  0.666  0.040  1.0
  N  N6  1  0.773  0.666  0.540  1.0
  N  N7  1  0.273  0.334  0.960  1.0
  N  N8  1  0.188  0.905  0.620  1.0
  N  N9  1  0.688  0.095  0.880  1.0
  N  N10  1  0.812  0.095  0.380  1.0
  N  N11  1  0.312  0.905  0.120  1.0
  N  N12  1  0.418  0.238  0.642  1.0
  N  N13  1  0.918  0.762  0.858  1.0
  N  N14  1  0.582  0.762  0.358  1.0
  N  N15  1  0.082  0.238  0.142  1.0
  N  N16  1  0.232  0.909  0.426  1.0
  N  N17  1  0.732  0.091  0.074  1.0
  N  N18  1  0.768  0.091  0.574  1.0
  N  N19  1  0.268  0.909  0.926  1.0
  N  N20  1  0.470  0.387  0.224  1.0
  N  N21  1  0.970  0.613  0.276  1.0
  N  N22  1  0.530  0.613  0.776  1.0
  N  N23  1  0.030  0.387  0.724  1.0
  O  O24  1  0.511  0.155  0.434  1.0
  O  O25  1  0.011  0.845  0.066  1.0
  O  O26  1  0.489  0.845  0.566  1.0
  O  O27  1  0.989  0.155  0.934  1.0
  O  O28  1  0.220  0.413  0.374  1.0
  O  O29  1  0.720  0.587  0.126  1.0
  O  O30  1  0.780  0.587  0.626  1.0
  O  O31  1  0.280  0.413  0.874  1.0
  O  O32  1  0.184  0.410  0.526  1.0
  O  O33  1  0.684  0.590  0.974  1.0
  O  O34  1  0.816  0.590  0.474  1.0
  O  O35  1  0.316  0.410  0.026  1.0
  O  O36  1  0.071  0.993  0.616  1.0
  O  O37  1  0.571  0.007  0.884  1.0
  O  O38  1  0.929  0.007  0.384  1.0
  O  O39  1  0.429  0.993  0.116  1.0
  O  O40  1  0.234  0.759  0.683  1.0
  O  O41  1  0.734  0.241  0.817  1.0
  O  O42  1  0.766  0.241  0.317  1.0
  O  O43  1  0.266  0.759  0.183  1.0
  O  O44  1  0.514  0.362  0.611  1.0
  O  O45  1  0.014  0.638  0.889  1.0
  O  O46  1  0.486  0.638  0.389  1.0
  O  O47  1  0.986  0.362  0.111  1.0
  O  O48  1  0.359  0.185  0.718  1.0
  O  O49  1  0.859  0.815  0.782  1.0
  O  O50  1  0.641  0.815  0.282  1.0
  O  O51  1  0.141  0.185  0.218  1.0
[/CIF]
.
The material described by (RhN3O5)2N2(NO2)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four ammonia atoms, four nitrous acid molecules, and two RhN3O5 clusters. In each RhN3O5 cluster, Rh(1) is bonded in a 5-coordinate geometry to one N(1), one N(2), one N(4), and two equivalent O(1) atoms. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Rh(1), one O(2), and one O(3) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Rh(1), one O(4), and one O(5) atom. In the third N site, N(4) is bonded in a single-bond geometry to one Rh(1) atom. There are five inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one N(1) atom. In the second O site, O(4) is bonded in a single-bond geometry to one N(2) atom. In the third O site, O(5) is bonded in a single-bond geometry to one N(2) atom. In the fourth O site, O(1) is bonded in a water-like geometry to two equivalent Rh(1) atoms. In the fifth O site, O(2) is bonded in a single-bond geometry to one N(1) atom. is represented by the CIF file [CIF]
data_RhN5O7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.286
_cell_length_b   6.484
_cell_length_c   14.332
_cell_angle_alpha   76.955
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   840.685
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rh  Rh0  1  0.334  0.020  0.496  1.0
  Rh  Rh1  1  0.834  0.980  0.004  1.0
  Rh  Rh2  1  0.666  0.980  0.504  1.0
  Rh  Rh3  1  0.166  0.020  0.996  1.0
  N  N4  1  0.227  0.334  0.460  1.0
  N  N5  1  0.727  0.666  0.040  1.0
  N  N6  1  0.773  0.666  0.540  1.0
  N  N7  1  0.273  0.334  0.960  1.0
  N  N8  1  0.188  0.905  0.620  1.0
  N  N9  1  0.688  0.095  0.880  1.0
  N  N10  1  0.812  0.095  0.380  1.0
  N  N11  1  0.312  0.905  0.120  1.0
  N  N12  1  0.418  0.238  0.642  1.0
  N  N13  1  0.918  0.762  0.858  1.0
  N  N14  1  0.582  0.762  0.358  1.0
  N  N15  1  0.082  0.238  0.142  1.0
  N  N16  1  0.232  0.909  0.426  1.0
  N  N17  1  0.732  0.091  0.074  1.0
  N  N18  1  0.768  0.091  0.574  1.0
  N  N19  1  0.268  0.909  0.926  1.0
  N  N20  1  0.470  0.387  0.224  1.0
  N  N21  1  0.970  0.613  0.276  1.0
  N  N22  1  0.530  0.613  0.776  1.0
  N  N23  1  0.030  0.387  0.724  1.0
  O  O24  1  0.511  0.155  0.434  1.0
  O  O25  1  0.011  0.845  0.066  1.0
  O  O26  1  0.489  0.845  0.566  1.0
  O  O27  1  0.989  0.155  0.934  1.0
  O  O28  1  0.220  0.413  0.374  1.0
  O  O29  1  0.720  0.587  0.126  1.0
  O  O30  1  0.780  0.587  0.626  1.0
  O  O31  1  0.280  0.413  0.874  1.0
  O  O32  1  0.184  0.410  0.526  1.0
  O  O33  1  0.684  0.590  0.974  1.0
  O  O34  1  0.816  0.590  0.474  1.0
  O  O35  1  0.316  0.410  0.026  1.0
  O  O36  1  0.071  0.993  0.616  1.0
  O  O37  1  0.571  0.007  0.884  1.0
  O  O38  1  0.929  0.007  0.384  1.0
  O  O39  1  0.429  0.993  0.116  1.0
  O  O40  1  0.234  0.759  0.683  1.0
  O  O41  1  0.734  0.241  0.817  1.0
  O  O42  1  0.766  0.241  0.317  1.0
  O  O43  1  0.266  0.759  0.183  1.0
  O  O44  1  0.514  0.362  0.611  1.0
  O  O45  1  0.014  0.638  0.889  1.0
  O  O46  1  0.486  0.638  0.389  1.0
  O  O47  1  0.986  0.362  0.111  1.0
  O  O48  1  0.359  0.185  0.718  1.0
  O  O49  1  0.859  0.815  0.782  1.0
  O  O50  1  0.641  0.815  0.282  1.0
  O  O51  1  0.141  0.185  0.218  1.0
[/CIF]
.