The material structure described by CsO4Br crystallizes in the tetragonal I4_1/amd space group. Cs(1) is bonded in a 12-coordinate geometry to twelve equivalent O(1) atoms. O(1) is bonded in a distorted single-bond geometry to three equivalent Cs(1) and one Br(1) atom. Br(1) is bonded in a tetrahedral geometry to four equivalent O(1) atoms. is represented by the CIF file [CIF]
data_CsBrO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.643
_cell_length_b   8.643
_cell_length_c   8.643
_cell_angle_alpha   140.276
_cell_angle_beta   140.276
_cell_angle_gamma   57.434
_symmetry_Int_Tables_number   1
_cell_volume   261.446
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.000  0.000  0.000  1.0
  Cs  Cs1  1  0.750  0.250  0.500  1.0
  Br  Br2  1  0.500  0.500  0.000  1.0
  Br  Br3  1  0.250  0.750  0.500  1.0
  O  O4  1  0.562  0.330  0.768  1.0
  O  O5  1  0.080  0.812  0.268  1.0
  O  O6  1  0.544  0.812  0.732  1.0
  O  O7  1  0.562  0.794  0.232  1.0
  O  O8  1  0.188  0.456  0.268  1.0
  O  O9  1  0.206  0.438  0.768  1.0
  O  O10  1  0.670  0.438  0.232  1.0
  O  O11  1  0.188  0.920  0.732  1.0
[/CIF]
.
The material structure described by CsO4Br crystallizes in the tetragonal I4_1/amd space group. Cs(1) is bonded in a 12-coordinate geometry to twelve equivalent O(1) atoms. O(1) is bonded in a distorted single-bond geometry to three equivalent Cs(1) and one Br(1) atom. Br(1) is bonded in a tetrahedral geometry to four equivalent O(1) atoms. is represented by the CIF file [CIF]
data_CsBrO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.643
_cell_length_b   8.643
_cell_length_c   8.643
_cell_angle_alpha   140.276
_cell_angle_beta   140.276
_cell_angle_gamma   57.434
_symmetry_Int_Tables_number   1
_cell_volume   261.446
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.000  0.000  0.000  1.0
  Cs  Cs1  1  0.750  0.250  0.500  1.0
  Br  Br2  1  0.500  0.500  0.000  1.0
  Br  Br3  1  0.250  0.750  0.500  1.0
  O  O4  1  0.562  0.330  0.768  1.0
  O  O5  1  0.080  0.812  0.268  1.0
  O  O6  1  0.544  0.812  0.732  1.0
  O  O7  1  0.562  0.794  0.232  1.0
  O  O8  1  0.188  0.456  0.268  1.0
  O  O9  1  0.206  0.438  0.768  1.0
  O  O10  1  0.670  0.438  0.232  1.0
  O  O11  1  0.188  0.920  0.732  1.0
[/CIF]
.