The structure described by U2Cu(SO10)2O2 crystallizes in the triclinic P-1 space group. The structure consists of two water atoms inside a U2Cu(SO10)2 framework. In the U2Cu(SO10)2 framework, U(1) is bonded to one O(1), one O(2), one O(4), one O(5), one O(6), and two equivalent O(3) atoms to form distorted UO7 pentagonal bipyramids that share  a cornercorner with one Cu(1)O6 octahedra, corners with three equivalent S(1)O4 tetrahedra, and  an edgeedge with one U(1)O7 pentagonal bipyramid. The corner-sharing octahedral tilt angles are 16°. Cu(1) is bonded to two equivalent O(2), two equivalent O(8), and two equivalent O(9) atoms to form CuO6 octahedra that share corners with two equivalent U(1)O7 pentagonal bipyramids. S(1) is bonded to one O(4), one O(5), one O(6), and one O(7) atom to form SO4 tetrahedra that share corners with three equivalent U(1)O7 pentagonal bipyramids. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one U(1) atom. In the second O site, O(2) is bonded in a distorted linear geometry to one U(1) and one Cu(1) atom. In the third O site, O(3) is bonded in a water-like geometry to two equivalent U(1) atoms. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one U(1) and one S(1) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one U(1) and one S(1) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one U(1) and one S(1) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one S(1) atom. In the eighth O site, O(8) is bonded in an L-shaped geometry to one Cu(1) and one O(10) atom. In the ninth O site, O(9) is bonded in an L-shaped geometry to one Cu(1) and one O(10) atom. In the tenth O site, O(10) is bonded in a water-like geometry to one O(8) and one O(9) atom. is represented by the CIF file [CIF]
data_U2Cu(SO11)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.865
_cell_length_b   8.981
_cell_length_c   9.368
_cell_angle_alpha   62.499
_cell_angle_beta   70.591
_cell_angle_gamma   68.422
_symmetry_Int_Tables_number   1
_cell_volume   467.057
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  U  U0  1  0.116  0.997  0.803  1.0
  U  U1  1  0.884  0.003  0.197  1.0
  Cu  Cu2  1  0.000  0.500  0.500  1.0
  S  S3  1  0.675  0.055  0.611  1.0
  S  S4  1  0.325  0.945  0.389  1.0
  O  O5  1  0.206  0.763  0.872  1.0
  O  O6  1  0.794  0.237  0.128  1.0
  O  O7  1  0.043  0.238  0.690  1.0
  O  O8  1  0.957  0.762  0.310  1.0
  O  O9  1  0.170  0.012  0.007  1.0
  O  O10  1  0.830  0.988  0.993  1.0
  O  O11  1  0.491  0.986  0.733  1.0
  O  O12  1  0.509  0.014  0.267  1.0
  O  O13  1  0.740  0.979  0.485  1.0
  O  O14  1  0.260  0.021  0.515  1.0
  O  O15  1  0.858  0.974  0.699  1.0
  O  O16  1  0.142  0.026  0.301  1.0
  O  O17  1  0.622  0.243  0.543  1.0
  O  O18  1  0.378  0.757  0.457  1.0
  O  O19  1  0.730  0.554  0.664  1.0
  O  O20  1  0.270  0.446  0.336  1.0
  O  O21  1  0.042  0.558  0.668  1.0
  O  O22  1  0.958  0.442  0.332  1.0
  O  O23  1  0.837  0.577  0.745  1.0
  O  O24  1  0.163  0.423  0.255  1.0
  O  O25  1  0.405  0.237  0.929  1.0
  O  O26  1  0.595  0.763  0.071  1.0
[/CIF]
.
The structure described by U2Cu(SO10)2O2 crystallizes in the triclinic P-1 space group. The structure consists of two water atoms inside a U2Cu(SO10)2 framework. In the U2Cu(SO10)2 framework, U(1) is bonded to one O(1), one O(2), one O(4), one O(5), one O(6), and two equivalent O(3) atoms to form distorted UO7 pentagonal bipyramids that share  a cornercorner with one Cu(1)O6 octahedra, corners with three equivalent S(1)O4 tetrahedra, and  an edgeedge with one U(1)O7 pentagonal bipyramid. The corner-sharing octahedral tilt angles are 16°. Cu(1) is bonded to two equivalent O(2), two equivalent O(8), and two equivalent O(9) atoms to form CuO6 octahedra that share corners with two equivalent U(1)O7 pentagonal bipyramids. S(1) is bonded to one O(4), one O(5), one O(6), and one O(7) atom to form SO4 tetrahedra that share corners with three equivalent U(1)O7 pentagonal bipyramids. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one U(1) atom. In the second O site, O(2) is bonded in a distorted linear geometry to one U(1) and one Cu(1) atom. In the third O site, O(3) is bonded in a water-like geometry to two equivalent U(1) atoms. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one U(1) and one S(1) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one U(1) and one S(1) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one U(1) and one S(1) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one S(1) atom. In the eighth O site, O(8) is bonded in an L-shaped geometry to one Cu(1) and one O(10) atom. In the ninth O site, O(9) is bonded in an L-shaped geometry to one Cu(1) and one O(10) atom. In the tenth O site, O(10) is bonded in a water-like geometry to one O(8) and one O(9) atom. is represented by the CIF file [CIF]
data_U2Cu(SO11)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.865
_cell_length_b   8.981
_cell_length_c   9.368
_cell_angle_alpha   62.499
_cell_angle_beta   70.591
_cell_angle_gamma   68.422
_symmetry_Int_Tables_number   1
_cell_volume   467.057
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  U  U0  1  0.116  0.997  0.803  1.0
  U  U1  1  0.884  0.003  0.197  1.0
  Cu  Cu2  1  0.000  0.500  0.500  1.0
  S  S3  1  0.675  0.055  0.611  1.0
  S  S4  1  0.325  0.945  0.389  1.0
  O  O5  1  0.206  0.763  0.872  1.0
  O  O6  1  0.794  0.237  0.128  1.0
  O  O7  1  0.043  0.238  0.690  1.0
  O  O8  1  0.957  0.762  0.310  1.0
  O  O9  1  0.170  0.012  0.007  1.0
  O  O10  1  0.830  0.988  0.993  1.0
  O  O11  1  0.491  0.986  0.733  1.0
  O  O12  1  0.509  0.014  0.267  1.0
  O  O13  1  0.740  0.979  0.485  1.0
  O  O14  1  0.260  0.021  0.515  1.0
  O  O15  1  0.858  0.974  0.699  1.0
  O  O16  1  0.142  0.026  0.301  1.0
  O  O17  1  0.622  0.243  0.543  1.0
  O  O18  1  0.378  0.757  0.457  1.0
  O  O19  1  0.730  0.554  0.664  1.0
  O  O20  1  0.270  0.446  0.336  1.0
  O  O21  1  0.042  0.558  0.668  1.0
  O  O22  1  0.958  0.442  0.332  1.0
  O  O23  1  0.837  0.577  0.745  1.0
  O  O24  1  0.163  0.423  0.255  1.0
  O  O25  1  0.405  0.237  0.929  1.0
  O  O26  1  0.595  0.763  0.071  1.0
[/CIF]
.