The crystal structure described by NaMgLaTeO6 is Orthorhombic Perovskite-derived structured and crystallizes in the monoclinic Cm space group. Na(1) is bonded in a 7-coordinate geometry to one O(3), two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms. Mg(1) is bonded to one O(3), one O(4), two equivalent O(1), and two equivalent O(2) atoms to form MgO6 octahedra that share corners with six equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 19-26°. La(1) is bonded in a 5-coordinate geometry to one O(4), two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. Te(1) is bonded to one O(3), one O(4), two equivalent O(1), and two equivalent O(2) atoms to form TeO6 octahedra that share corners with six equivalent Mg(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 19-26°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Na(1), one Mg(1), one La(1), and one Te(1) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Na(1), one Mg(1), one La(1), and one Te(1) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to one Na(1), one Mg(1), two equivalent La(1), and one Te(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to two equivalent Na(1), one Mg(1), one La(1), and one Te(1) atom. is represented by the CIF file [CIF]
data_NaLaMgTeO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.602
_cell_length_b   5.602
_cell_length_c   5.619
_cell_angle_alpha   59.819
_cell_angle_beta   59.819
_cell_angle_gamma   59.932
_symmetry_Int_Tables_number   1
_cell_volume   124.263
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.752  0.752  0.756  1.0
  La  La1  1  0.251  0.251  0.238  1.0
  Mg  Mg2  1  0.999  0.999  0.999  1.0
  Te  Te3  1  0.501  0.501  0.499  1.0
  O  O4  1  0.216  0.696  0.786  1.0
  O  O5  1  0.295  0.789  0.221  1.0
  O  O6  1  0.789  0.295  0.221  1.0
  O  O7  1  0.696  0.216  0.786  1.0
  O  O8  1  0.740  0.740  0.337  1.0
  O  O9  1  0.261  0.261  0.656  1.0
[/CIF]
.
The crystal structure described by NaMgLaTeO6 is Orthorhombic Perovskite-derived structured and crystallizes in the monoclinic Cm space group. Na(1) is bonded in a 7-coordinate geometry to one O(3), two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms. Mg(1) is bonded to one O(3), one O(4), two equivalent O(1), and two equivalent O(2) atoms to form MgO6 octahedra that share corners with six equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 19-26°. La(1) is bonded in a 5-coordinate geometry to one O(4), two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. Te(1) is bonded to one O(3), one O(4), two equivalent O(1), and two equivalent O(2) atoms to form TeO6 octahedra that share corners with six equivalent Mg(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 19-26°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Na(1), one Mg(1), one La(1), and one Te(1) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Na(1), one Mg(1), one La(1), and one Te(1) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to one Na(1), one Mg(1), two equivalent La(1), and one Te(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to two equivalent Na(1), one Mg(1), one La(1), and one Te(1) atom. is represented by the CIF file [CIF]
data_NaLaMgTeO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.602
_cell_length_b   5.602
_cell_length_c   5.619
_cell_angle_alpha   59.819
_cell_angle_beta   59.819
_cell_angle_gamma   59.932
_symmetry_Int_Tables_number   1
_cell_volume   124.263
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.752  0.752  0.756  1.0
  La  La1  1  0.251  0.251  0.238  1.0
  Mg  Mg2  1  0.999  0.999  0.999  1.0
  Te  Te3  1  0.501  0.501  0.499  1.0
  O  O4  1  0.216  0.696  0.786  1.0
  O  O5  1  0.295  0.789  0.221  1.0
  O  O6  1  0.789  0.295  0.221  1.0
  O  O7  1  0.696  0.216  0.786  1.0
  O  O8  1  0.740  0.740  0.337  1.0
  O  O9  1  0.261  0.261  0.656  1.0
[/CIF]
.