The structure described by RhInO3 is Hausmannite-derived structured and crystallizes in the orthorhombic Pnma space group. Rh(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent O(2) and four equivalent O(1) atoms. In(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form corner-sharing InO6 octahedra. The corner-sharing octahedral tilt angles range from 54-56°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to two equivalent Rh(1) and two equivalent In(1) atoms. In the second O site, O(2) is bonded in a distorted see-saw-like geometry to two equivalent Rh(1) and two equivalent In(1) atoms. is represented by the CIF card [CIF]
data_InRhO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.341
_cell_length_b   5.530
_cell_length_c   8.245
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   243.509
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.000  0.000  0.000  1.0
  In  In1  1  0.500  0.500  0.000  1.0
  In  In2  1  0.000  0.000  0.500  1.0
  In  In3  1  0.500  0.500  0.500  1.0
  Rh  Rh4  1  0.006  0.449  0.250  1.0
  Rh  Rh5  1  0.994  0.551  0.750  1.0
  Rh  Rh6  1  0.506  0.051  0.750  1.0
  Rh  Rh7  1  0.494  0.949  0.250  1.0
  O  O8  1  0.327  0.181  0.097  1.0
  O  O9  1  0.673  0.819  0.903  1.0
  O  O10  1  0.827  0.319  0.903  1.0
  O  O11  1  0.673  0.819  0.597  1.0
  O  O12  1  0.173  0.681  0.097  1.0
  O  O13  1  0.327  0.181  0.403  1.0
  O  O14  1  0.173  0.681  0.403  1.0
  O  O15  1  0.827  0.319  0.597  1.0
  O  O16  1  0.666  0.618  0.250  1.0
  O  O17  1  0.334  0.382  0.750  1.0
  O  O18  1  0.166  0.882  0.750  1.0
  O  O19  1  0.834  0.118  0.250  1.0
[/CIF]
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The structure described by RhInO3 is Hausmannite-derived structured and crystallizes in the orthorhombic Pnma space group. Rh(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent O(2) and four equivalent O(1) atoms. In(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form corner-sharing InO6 octahedra. The corner-sharing octahedral tilt angles range from 54-56°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to two equivalent Rh(1) and two equivalent In(1) atoms. In the second O site, O(2) is bonded in a distorted see-saw-like geometry to two equivalent Rh(1) and two equivalent In(1) atoms. is represented by the CIF card [CIF]
data_InRhO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.341
_cell_length_b   5.530
_cell_length_c   8.245
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   243.509
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.000  0.000  0.000  1.0
  In  In1  1  0.500  0.500  0.000  1.0
  In  In2  1  0.000  0.000  0.500  1.0
  In  In3  1  0.500  0.500  0.500  1.0
  Rh  Rh4  1  0.006  0.449  0.250  1.0
  Rh  Rh5  1  0.994  0.551  0.750  1.0
  Rh  Rh6  1  0.506  0.051  0.750  1.0
  Rh  Rh7  1  0.494  0.949  0.250  1.0
  O  O8  1  0.327  0.181  0.097  1.0
  O  O9  1  0.673  0.819  0.903  1.0
  O  O10  1  0.827  0.319  0.903  1.0
  O  O11  1  0.673  0.819  0.597  1.0
  O  O12  1  0.173  0.681  0.097  1.0
  O  O13  1  0.327  0.181  0.403  1.0
  O  O14  1  0.173  0.681  0.403  1.0
  O  O15  1  0.827  0.319  0.597  1.0
  O  O16  1  0.666  0.618  0.250  1.0
  O  O17  1  0.334  0.382  0.750  1.0
  O  O18  1  0.166  0.882  0.750  1.0
  O  O19  1  0.834  0.118  0.250  1.0
[/CIF]
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