The compound described by NaH8(Al(O2Cl)2)2 is Indium-derived structured and crystallizes in the tetragonal P4/nmm space group. The structure is zero-dimensional and consists of four Al(O2Cl)2 clusters and two NaH8 clusters. In each Al(O2Cl)2 cluster, Al(1) is bonded in an octahedral geometry to four equivalent O(1) and two equivalent Cl(1) atoms. O(1) is bonded in a distorted single-bond geometry to one Al(1) atom. Cl(1) is bonded in a single-bond geometry to one Al(1) atom. In each NaH8 cluster, Na(1) is bonded in a 8-coordinate geometry to eight equivalent H(1) atoms. H(1) is bonded in a distorted L-shaped geometry to one Na(1) and one H(1) atom. is represented by the CIF file [CIF]
data_NaAl2H8(ClO2)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.999
_cell_length_b   10.146
_cell_length_c   10.146
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   823.424
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.000  0.000  0.000  1.0
  Na  Na1  1  0.000  0.500  0.500  1.0
  Al  Al2  1  0.500  0.750  0.250  1.0
  Al  Al3  1  0.500  0.250  0.750  1.0
  Al  Al4  1  0.500  0.250  0.250  1.0
  Al  Al5  1  0.500  0.750  0.750  1.0
  H  H6  1  0.782  0.124  0.037  1.0
  H  H7  1  0.782  0.876  0.963  1.0
  H  H8  1  0.782  0.463  0.624  1.0
  H  H9  1  0.218  0.376  0.537  1.0
  H  H10  1  0.218  0.376  0.463  1.0
  H  H11  1  0.782  0.537  0.376  1.0
  H  H12  1  0.218  0.624  0.463  1.0
  H  H13  1  0.218  0.624  0.537  1.0
  H  H14  1  0.218  0.037  0.124  1.0
  H  H15  1  0.218  0.037  0.876  1.0
  H  H16  1  0.218  0.963  0.876  1.0
  H  H17  1  0.218  0.963  0.124  1.0
  H  H18  1  0.782  0.124  0.963  1.0
  H  H19  1  0.782  0.876  0.037  1.0
  H  H20  1  0.782  0.537  0.624  1.0
  H  H21  1  0.782  0.463  0.376  1.0
  Cl  Cl22  1  0.263  0.180  0.320  1.0
  Cl  Cl23  1  0.263  0.820  0.680  1.0
  Cl  Cl24  1  0.263  0.180  0.680  1.0
  Cl  Cl25  1  0.737  0.320  0.820  1.0
  Cl  Cl26  1  0.737  0.320  0.180  1.0
  Cl  Cl27  1  0.263  0.820  0.320  1.0
  Cl  Cl28  1  0.737  0.680  0.180  1.0
  Cl  Cl29  1  0.737  0.680  0.820  1.0
  O  O30  1  0.608  0.264  0.565  1.0
  O  O31  1  0.608  0.736  0.435  1.0
  O  O32  1  0.608  0.935  0.764  1.0
  O  O33  1  0.392  0.236  0.065  1.0
  O  O34  1  0.392  0.236  0.935  1.0
  O  O35  1  0.608  0.065  0.236  1.0
  O  O36  1  0.392  0.764  0.935  1.0
  O  O37  1  0.392  0.764  0.065  1.0
  O  O38  1  0.392  0.565  0.264  1.0
  O  O39  1  0.392  0.565  0.736  1.0
  O  O40  1  0.392  0.435  0.736  1.0
  O  O41  1  0.392  0.435  0.264  1.0
  O  O42  1  0.608  0.264  0.435  1.0
  O  O43  1  0.608  0.736  0.565  1.0
  O  O44  1  0.608  0.065  0.764  1.0
  O  O45  1  0.608  0.935  0.236  1.0
[/CIF]
.
The compound described by NaH8(Al(O2Cl)2)2 is Indium-derived structured and crystallizes in the tetragonal P4/nmm space group. The structure is zero-dimensional and consists of four Al(O2Cl)2 clusters and two NaH8 clusters. In each Al(O2Cl)2 cluster, Al(1) is bonded in an octahedral geometry to four equivalent O(1) and two equivalent Cl(1) atoms. O(1) is bonded in a distorted single-bond geometry to one Al(1) atom. Cl(1) is bonded in a single-bond geometry to one Al(1) atom. In each NaH8 cluster, Na(1) is bonded in a 8-coordinate geometry to eight equivalent H(1) atoms. H(1) is bonded in a distorted L-shaped geometry to one Na(1) and one H(1) atom. is represented by the CIF file [CIF]
data_NaAl2H8(ClO2)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.999
_cell_length_b   10.146
_cell_length_c   10.146
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   823.424
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.000  0.000  0.000  1.0
  Na  Na1  1  0.000  0.500  0.500  1.0
  Al  Al2  1  0.500  0.750  0.250  1.0
  Al  Al3  1  0.500  0.250  0.750  1.0
  Al  Al4  1  0.500  0.250  0.250  1.0
  Al  Al5  1  0.500  0.750  0.750  1.0
  H  H6  1  0.782  0.124  0.037  1.0
  H  H7  1  0.782  0.876  0.963  1.0
  H  H8  1  0.782  0.463  0.624  1.0
  H  H9  1  0.218  0.376  0.537  1.0
  H  H10  1  0.218  0.376  0.463  1.0
  H  H11  1  0.782  0.537  0.376  1.0
  H  H12  1  0.218  0.624  0.463  1.0
  H  H13  1  0.218  0.624  0.537  1.0
  H  H14  1  0.218  0.037  0.124  1.0
  H  H15  1  0.218  0.037  0.876  1.0
  H  H16  1  0.218  0.963  0.876  1.0
  H  H17  1  0.218  0.963  0.124  1.0
  H  H18  1  0.782  0.124  0.963  1.0
  H  H19  1  0.782  0.876  0.037  1.0
  H  H20  1  0.782  0.537  0.624  1.0
  H  H21  1  0.782  0.463  0.376  1.0
  Cl  Cl22  1  0.263  0.180  0.320  1.0
  Cl  Cl23  1  0.263  0.820  0.680  1.0
  Cl  Cl24  1  0.263  0.180  0.680  1.0
  Cl  Cl25  1  0.737  0.320  0.820  1.0
  Cl  Cl26  1  0.737  0.320  0.180  1.0
  Cl  Cl27  1  0.263  0.820  0.320  1.0
  Cl  Cl28  1  0.737  0.680  0.180  1.0
  Cl  Cl29  1  0.737  0.680  0.820  1.0
  O  O30  1  0.608  0.264  0.565  1.0
  O  O31  1  0.608  0.736  0.435  1.0
  O  O32  1  0.608  0.935  0.764  1.0
  O  O33  1  0.392  0.236  0.065  1.0
  O  O34  1  0.392  0.236  0.935  1.0
  O  O35  1  0.608  0.065  0.236  1.0
  O  O36  1  0.392  0.764  0.935  1.0
  O  O37  1  0.392  0.764  0.065  1.0
  O  O38  1  0.392  0.565  0.264  1.0
  O  O39  1  0.392  0.565  0.736  1.0
  O  O40  1  0.392  0.435  0.736  1.0
  O  O41  1  0.392  0.435  0.264  1.0
  O  O42  1  0.608  0.264  0.435  1.0
  O  O43  1  0.608  0.736  0.565  1.0
  O  O44  1  0.608  0.065  0.764  1.0
  O  O45  1  0.608  0.935  0.236  1.0
[/CIF]
.