The compound described by NaIn(WO3)2 crystallizes in the cubic Fm-3m space group. Na(1) is bonded to twelve equivalent O(1) atoms to form NaO12 cuboctahedra that share corners with twelve equivalent Na(1)O12 cuboctahedra, faces with six equivalent In(1)O12 cuboctahedra, and faces with eight equivalent W(1)O6 octahedra. W(1) is bonded to six equivalent O(1) atoms to form WO6 octahedra that share corners with six equivalent W(1)O6 octahedra, faces with four equivalent Na(1)O12 cuboctahedra, and faces with four equivalent In(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. In(1) is bonded to twelve equivalent O(1) atoms to form distorted InO12 cuboctahedra that share corners with twelve equivalent In(1)O12 cuboctahedra, faces with six equivalent Na(1)O12 cuboctahedra, and faces with eight equivalent W(1)O6 octahedra. O(1) is bonded in a distorted linear geometry to two equivalent Na(1), two equivalent W(1), and two equivalent In(1) atoms. is represented by the CIF card [CIF]
data_NaIn(WO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.682
_cell_length_b   5.682
_cell_length_c   5.682
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   129.723
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.500  0.500  0.500  1.0
  In  In1  1  0.000  0.000  0.000  1.0
  W  W2  1  0.250  0.250  0.250  1.0
  W  W3  1  0.750  0.750  0.750  1.0
  O  O4  1  0.000  0.000  0.500  1.0
  O  O5  1  0.500  0.500  0.000  1.0
  O  O6  1  0.000  0.500  0.500  1.0
  O  O7  1  0.500  0.000  0.000  1.0
  O  O8  1  0.000  0.500  0.000  1.0
  O  O9  1  0.500  0.000  0.500  1.0
[/CIF]
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The compound described by NaIn(WO3)2 crystallizes in the cubic Fm-3m space group. Na(1) is bonded to twelve equivalent O(1) atoms to form NaO12 cuboctahedra that share corners with twelve equivalent Na(1)O12 cuboctahedra, faces with six equivalent In(1)O12 cuboctahedra, and faces with eight equivalent W(1)O6 octahedra. W(1) is bonded to six equivalent O(1) atoms to form WO6 octahedra that share corners with six equivalent W(1)O6 octahedra, faces with four equivalent Na(1)O12 cuboctahedra, and faces with four equivalent In(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. In(1) is bonded to twelve equivalent O(1) atoms to form distorted InO12 cuboctahedra that share corners with twelve equivalent In(1)O12 cuboctahedra, faces with six equivalent Na(1)O12 cuboctahedra, and faces with eight equivalent W(1)O6 octahedra. O(1) is bonded in a distorted linear geometry to two equivalent Na(1), two equivalent W(1), and two equivalent In(1) atoms. is represented by the CIF card [CIF]
data_NaIn(WO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.682
_cell_length_b   5.682
_cell_length_c   5.682
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   129.723
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.500  0.500  0.500  1.0
  In  In1  1  0.000  0.000  0.000  1.0
  W  W2  1  0.250  0.250  0.250  1.0
  W  W3  1  0.750  0.750  0.750  1.0
  O  O4  1  0.000  0.000  0.500  1.0
  O  O5  1  0.500  0.500  0.000  1.0
  O  O6  1  0.000  0.500  0.500  1.0
  O  O7  1  0.500  0.000  0.000  1.0
  O  O8  1  0.000  0.500  0.000  1.0
  O  O9  1  0.500  0.000  0.500  1.0
[/CIF]
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