The crystal structure described by TiF6(C4NH10)2 is Fluorite structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two tetramethylammonium molecules and one TiF6 cluster. In the TiF6 cluster, Ti(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. There are six inequivalent F sites. In the first F site, F(3) is bonded in a single-bond geometry to one Ti(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Ti(1) atom. In the third F site, F(5) is bonded in a single-bond geometry to one Ti(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Ti(1) atom. In the fifth F site, F(6) is bonded in a single-bond geometry to one Ti(1) atom. In the sixth F site, F(1) is bonded in a single-bond geometry to one Ti(1) atom. is represented by the CIF file [CIF]
data_TiH20C8(NF3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.954
_cell_length_b   7.959
_cell_length_c   8.002
_cell_angle_alpha   118.929
_cell_angle_beta   119.413
_cell_angle_gamma   90.205
_symmetry_Int_Tables_number   1
_cell_volume   366.399
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.996  1.000  0.999  1.0
  H  H1  1  0.007  0.209  0.480  1.0
  H  H2  1  0.473  0.012  0.267  1.0
  H  H3  1  0.792  0.524  0.797  1.0
  H  H4  1  0.993  0.791  0.520  1.0
  H  H5  1  0.523  0.996  0.724  1.0
  H  H6  1  0.214  0.475  0.217  1.0
  H  H7  1  0.037  0.232  0.731  1.0
  H  H8  1  0.687  0.979  0.467  1.0
  H  H9  1  0.775  0.303  0.805  1.0
  H  H10  1  0.971  0.778  0.277  1.0
  H  H11  1  0.302  0.031  0.532  1.0
  H  H12  1  0.225  0.691  0.197  1.0
  H  H13  1  0.060  0.453  0.722  1.0
  H  H14  1  0.680  0.956  0.227  1.0
  H  H15  1  0.550  0.328  0.606  1.0
  H  H16  1  0.946  0.551  0.275  1.0
  H  H17  1  0.327  0.049  0.777  1.0
  H  H18  1  0.455  0.671  0.398  1.0
  H  H19  1  0.734  0.244  0.244  1.0
  H  H20  1  0.492  0.717  0.730  1.0
  C  C21  1  0.984  0.290  0.620  1.0
  C  C22  1  0.636  0.031  0.350  1.0
  C  C23  1  0.716  0.362  0.696  1.0
  C  C24  1  0.021  0.715  0.383  1.0
  C  C25  1  0.359  0.975  0.645  1.0
  C  C26  1  0.289  0.637  0.312  1.0
  C  C27  1  0.651  0.289  0.330  1.0
  C  C28  1  0.324  0.668  0.635  1.0
  N  N29  1  0.760  0.260  0.514  1.0
  N  N30  1  0.246  0.751  0.496  1.0
  F  F31  1  0.153  0.109  0.939  1.0
  F  F32  1  0.783  0.852  0.676  1.0
  F  F33  1  0.885  0.217  0.052  1.0
  F  F34  1  0.823  0.884  0.045  1.0
  F  F35  1  0.205  0.146  0.319  1.0
  F  F36  1  0.105  0.783  0.955  1.0
[/CIF]
.
The crystal structure described by TiF6(C4NH10)2 is Fluorite structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two tetramethylammonium molecules and one TiF6 cluster. In the TiF6 cluster, Ti(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. There are six inequivalent F sites. In the first F site, F(3) is bonded in a single-bond geometry to one Ti(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Ti(1) atom. In the third F site, F(5) is bonded in a single-bond geometry to one Ti(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Ti(1) atom. In the fifth F site, F(6) is bonded in a single-bond geometry to one Ti(1) atom. In the sixth F site, F(1) is bonded in a single-bond geometry to one Ti(1) atom. is represented by the CIF file [CIF]
data_TiH20C8(NF3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.954
_cell_length_b   7.959
_cell_length_c   8.002
_cell_angle_alpha   118.929
_cell_angle_beta   119.413
_cell_angle_gamma   90.205
_symmetry_Int_Tables_number   1
_cell_volume   366.399
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.996  1.000  0.999  1.0
  H  H1  1  0.007  0.209  0.480  1.0
  H  H2  1  0.473  0.012  0.267  1.0
  H  H3  1  0.792  0.524  0.797  1.0
  H  H4  1  0.993  0.791  0.520  1.0
  H  H5  1  0.523  0.996  0.724  1.0
  H  H6  1  0.214  0.475  0.217  1.0
  H  H7  1  0.037  0.232  0.731  1.0
  H  H8  1  0.687  0.979  0.467  1.0
  H  H9  1  0.775  0.303  0.805  1.0
  H  H10  1  0.971  0.778  0.277  1.0
  H  H11  1  0.302  0.031  0.532  1.0
  H  H12  1  0.225  0.691  0.197  1.0
  H  H13  1  0.060  0.453  0.722  1.0
  H  H14  1  0.680  0.956  0.227  1.0
  H  H15  1  0.550  0.328  0.606  1.0
  H  H16  1  0.946  0.551  0.275  1.0
  H  H17  1  0.327  0.049  0.777  1.0
  H  H18  1  0.455  0.671  0.398  1.0
  H  H19  1  0.734  0.244  0.244  1.0
  H  H20  1  0.492  0.717  0.730  1.0
  C  C21  1  0.984  0.290  0.620  1.0
  C  C22  1  0.636  0.031  0.350  1.0
  C  C23  1  0.716  0.362  0.696  1.0
  C  C24  1  0.021  0.715  0.383  1.0
  C  C25  1  0.359  0.975  0.645  1.0
  C  C26  1  0.289  0.637  0.312  1.0
  C  C27  1  0.651  0.289  0.330  1.0
  C  C28  1  0.324  0.668  0.635  1.0
  N  N29  1  0.760  0.260  0.514  1.0
  N  N30  1  0.246  0.751  0.496  1.0
  F  F31  1  0.153  0.109  0.939  1.0
  F  F32  1  0.783  0.852  0.676  1.0
  F  F33  1  0.885  0.217  0.052  1.0
  F  F34  1  0.823  0.884  0.045  1.0
  F  F35  1  0.205  0.146  0.319  1.0
  F  F36  1  0.105  0.783  0.955  1.0
[/CIF]
.