The structure described by Li2MnOF2 crystallizes in the orthorhombic Cmcm space group. Li(1) is bonded to one O(1) and four equivalent F(1) atoms to form LiOF4 trigonal bipyramids that share corners with three equivalent Mn(1)O3F2 trigonal bipyramids, corners with five equivalent Li(1)OF4 trigonal bipyramids, edges with two equivalent Mn(1)O3F2 trigonal bipyramids, and edges with four equivalent Li(1)OF4 trigonal bipyramids. Mn(1) is bonded to three equivalent O(1) and two equivalent F(1) atoms to form MnO3F2 trigonal bipyramids that share corners with two equivalent Mn(1)O3F2 trigonal bipyramids, corners with six equivalent Li(1)OF4 trigonal bipyramids, edges with two equivalent Mn(1)O3F2 trigonal bipyramids, and edges with four equivalent Li(1)OF4 trigonal bipyramids. O(1) is bonded to two equivalent Li(1) and three equivalent Mn(1) atoms to form OLi2Mn3 trigonal bipyramids that share corners with two equivalent O(1)Li2Mn3 trigonal bipyramids, corners with six equivalent F(1)Li4Mn trigonal bipyramids, edges with two equivalent O(1)Li2Mn3 trigonal bipyramids, and edges with four equivalent F(1)Li4Mn trigonal bipyramids. F(1) is bonded to four equivalent Li(1) and one Mn(1) atom to form FLi4Mn trigonal bipyramids that share corners with three equivalent O(1)Li2Mn3 trigonal bipyramids, corners with five equivalent F(1)Li4Mn trigonal bipyramids, edges with two equivalent O(1)Li2Mn3 trigonal bipyramids, and edges with four equivalent F(1)Li4Mn trigonal bipyramids. is represented by the CIF file [CIF]
data_Li2MnOF2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.174
_cell_length_b   6.002
_cell_length_c   6.187
_cell_angle_alpha   118.995
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   135.567
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  F  F0  1  0.055  0.163  0.641  1.0
  F  F1  1  0.555  0.478  0.641  1.0
  F  F2  1  0.055  0.522  0.359  1.0
  F  F3  1  0.555  0.837  0.359  1.0
  Li  Li4  1  0.054  0.501  0.666  1.0
  Li  Li5  1  0.554  0.165  0.666  1.0
  Li  Li6  1  0.554  0.499  0.334  1.0
  Li  Li7  1  0.054  0.835  0.334  1.0
  Mn  Mn8  1  0.055  0.167  0.000  1.0
  Mn  Mn9  1  0.555  0.833  1.000  1.0
  O  O10  1  0.555  0.189  0.000  1.0
  O  O11  1  0.055  0.811  1.000  1.0
[/CIF]
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The structure described by Li2MnOF2 crystallizes in the orthorhombic Cmcm space group. Li(1) is bonded to one O(1) and four equivalent F(1) atoms to form LiOF4 trigonal bipyramids that share corners with three equivalent Mn(1)O3F2 trigonal bipyramids, corners with five equivalent Li(1)OF4 trigonal bipyramids, edges with two equivalent Mn(1)O3F2 trigonal bipyramids, and edges with four equivalent Li(1)OF4 trigonal bipyramids. Mn(1) is bonded to three equivalent O(1) and two equivalent F(1) atoms to form MnO3F2 trigonal bipyramids that share corners with two equivalent Mn(1)O3F2 trigonal bipyramids, corners with six equivalent Li(1)OF4 trigonal bipyramids, edges with two equivalent Mn(1)O3F2 trigonal bipyramids, and edges with four equivalent Li(1)OF4 trigonal bipyramids. O(1) is bonded to two equivalent Li(1) and three equivalent Mn(1) atoms to form OLi2Mn3 trigonal bipyramids that share corners with two equivalent O(1)Li2Mn3 trigonal bipyramids, corners with six equivalent F(1)Li4Mn trigonal bipyramids, edges with two equivalent O(1)Li2Mn3 trigonal bipyramids, and edges with four equivalent F(1)Li4Mn trigonal bipyramids. F(1) is bonded to four equivalent Li(1) and one Mn(1) atom to form FLi4Mn trigonal bipyramids that share corners with three equivalent O(1)Li2Mn3 trigonal bipyramids, corners with five equivalent F(1)Li4Mn trigonal bipyramids, edges with two equivalent O(1)Li2Mn3 trigonal bipyramids, and edges with four equivalent F(1)Li4Mn trigonal bipyramids. is represented by the CIF file [CIF]
data_Li2MnOF2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.174
_cell_length_b   6.002
_cell_length_c   6.187
_cell_angle_alpha   118.995
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   135.567
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  F  F0  1  0.055  0.163  0.641  1.0
  F  F1  1  0.555  0.478  0.641  1.0
  F  F2  1  0.055  0.522  0.359  1.0
  F  F3  1  0.555  0.837  0.359  1.0
  Li  Li4  1  0.054  0.501  0.666  1.0
  Li  Li5  1  0.554  0.165  0.666  1.0
  Li  Li6  1  0.554  0.499  0.334  1.0
  Li  Li7  1  0.054  0.835  0.334  1.0
  Mn  Mn8  1  0.055  0.167  0.000  1.0
  Mn  Mn9  1  0.555  0.833  1.000  1.0
  O  O10  1  0.555  0.189  0.000  1.0
  O  O11  1  0.055  0.811  1.000  1.0
[/CIF]
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