The crystal structure described by Pb5(VO4)3OH crystallizes in the hexagonal P6_3 space group. V(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form VO4 tetrahedra that share corners with three equivalent Pb(3)O6 pentagonal pyramids and  an edgeedge with one Pb(3)O6 pentagonal pyramid. There are three inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 6-coordinate geometry to three equivalent O(1) and three equivalent O(2) atoms. In the second Pb site, Pb(2) is bonded in a 6-coordinate geometry to three equivalent O(1) and three equivalent O(2) atoms. In the third Pb site, Pb(3) is bonded to one O(2), one O(5), two equivalent O(3), and two equivalent O(4) atoms to form distorted PbO6 pentagonal pyramids that share corners with six equivalent Pb(3)O6 pentagonal pyramids, corners with three equivalent V(1)O4 tetrahedra, and  an edgeedge with one V(1)O4 tetrahedra. H(1) is bonded in a single-bond geometry to one O(5) atom. There are five inequivalent O sites. In the first O site, O(4) is bonded in a distorted single-bond geometry to one V(1) and two equivalent Pb(3) atoms. In the second O site, O(5) is bonded in a single-bond geometry to three equivalent Pb(3) and one H(1) atom. In the third O site, O(1) is bonded in a distorted single-bond geometry to one V(1), one Pb(1), and one Pb(2) atom. In the fourth O site, O(2) is bonded in a distorted single-bond geometry to one V(1), one Pb(1), one Pb(2), and one Pb(3) atom. In the fifth O site, O(3) is bonded in a distorted single-bond geometry to one V(1) and two equivalent Pb(3) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_V3HPb5O13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.361
_cell_length_b   10.361
_cell_length_c   7.563
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   703.178
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.399  0.369  0.744  1.0
  V  V1  1  0.631  0.030  0.744  1.0
  V  V2  1  0.970  0.601  0.744  1.0
  V  V3  1  0.601  0.631  0.244  1.0
  V  V4  1  0.369  0.970  0.244  1.0
  V  V5  1  0.030  0.399  0.244  1.0
  H  H6  1  0.000  0.000  0.936  1.0
  H  H7  1  0.000  0.000  0.436  1.0
  Pb  Pb8  1  0.333  0.667  0.499  1.0
  Pb  Pb9  1  0.667  0.333  0.483  1.0
  Pb  Pb10  1  0.667  0.333  0.999  1.0
  Pb  Pb11  1  0.333  0.667  0.983  1.0
  Pb  Pb12  1  0.251  0.007  0.750  1.0
  Pb  Pb13  1  0.993  0.244  0.750  1.0
  Pb  Pb14  1  0.756  0.749  0.750  1.0
  Pb  Pb15  1  0.749  0.993  0.250  1.0
  Pb  Pb16  1  0.007  0.756  0.250  1.0
  Pb  Pb17  1  0.244  0.251  0.250  1.0
  O  O18  1  0.327  0.491  0.747  1.0
  O  O19  1  0.509  0.837  0.747  1.0
  O  O20  1  0.163  0.673  0.747  1.0
  O  O21  1  0.673  0.509  0.247  1.0
  O  O22  1  0.491  0.163  0.247  1.0
  O  O23  1  0.837  0.327  0.247  1.0
  O  O24  1  0.595  0.470  0.741  1.0
  O  O25  1  0.530  0.125  0.741  1.0
  O  O26  1  0.875  0.405  0.741  1.0
  O  O27  1  0.405  0.530  0.241  1.0
  O  O28  1  0.470  0.875  0.241  1.0
  O  O29  1  0.125  0.595  0.241  1.0
  O  O30  1  0.337  0.250  0.562  1.0
  O  O31  1  0.750  0.087  0.562  1.0
  O  O32  1  0.913  0.663  0.562  1.0
  O  O33  1  0.654  0.750  0.426  1.0
  O  O34  1  0.250  0.904  0.426  1.0
  O  O35  1  0.096  0.346  0.426  1.0
  O  O36  1  0.663  0.750  0.062  1.0
  O  O37  1  0.250  0.913  0.062  1.0
  O  O38  1  0.087  0.337  0.062  1.0
  O  O39  1  0.346  0.250  0.926  1.0
  O  O40  1  0.750  0.096  0.926  1.0
  O  O41  1  0.904  0.654  0.926  1.0
  O  O42  1  0.000  0.000  0.807  1.0
  O  O43  1  0.000  0.000  0.307  1.0
[/CIF]
.
The crystal structure described by Pb5(VO4)3OH crystallizes in the hexagonal P6_3 space group. V(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form VO4 tetrahedra that share corners with three equivalent Pb(3)O6 pentagonal pyramids and  an edgeedge with one Pb(3)O6 pentagonal pyramid. There are three inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 6-coordinate geometry to three equivalent O(1) and three equivalent O(2) atoms. In the second Pb site, Pb(2) is bonded in a 6-coordinate geometry to three equivalent O(1) and three equivalent O(2) atoms. In the third Pb site, Pb(3) is bonded to one O(2), one O(5), two equivalent O(3), and two equivalent O(4) atoms to form distorted PbO6 pentagonal pyramids that share corners with six equivalent Pb(3)O6 pentagonal pyramids, corners with three equivalent V(1)O4 tetrahedra, and  an edgeedge with one V(1)O4 tetrahedra. H(1) is bonded in a single-bond geometry to one O(5) atom. There are five inequivalent O sites. In the first O site, O(4) is bonded in a distorted single-bond geometry to one V(1) and two equivalent Pb(3) atoms. In the second O site, O(5) is bonded in a single-bond geometry to three equivalent Pb(3) and one H(1) atom. In the third O site, O(1) is bonded in a distorted single-bond geometry to one V(1), one Pb(1), and one Pb(2) atom. In the fourth O site, O(2) is bonded in a distorted single-bond geometry to one V(1), one Pb(1), one Pb(2), and one Pb(3) atom. In the fifth O site, O(3) is bonded in a distorted single-bond geometry to one V(1) and two equivalent Pb(3) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_V3HPb5O13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.361
_cell_length_b   10.361
_cell_length_c   7.563
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   703.178
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.399  0.369  0.744  1.0
  V  V1  1  0.631  0.030  0.744  1.0
  V  V2  1  0.970  0.601  0.744  1.0
  V  V3  1  0.601  0.631  0.244  1.0
  V  V4  1  0.369  0.970  0.244  1.0
  V  V5  1  0.030  0.399  0.244  1.0
  H  H6  1  0.000  0.000  0.936  1.0
  H  H7  1  0.000  0.000  0.436  1.0
  Pb  Pb8  1  0.333  0.667  0.499  1.0
  Pb  Pb9  1  0.667  0.333  0.483  1.0
  Pb  Pb10  1  0.667  0.333  0.999  1.0
  Pb  Pb11  1  0.333  0.667  0.983  1.0
  Pb  Pb12  1  0.251  0.007  0.750  1.0
  Pb  Pb13  1  0.993  0.244  0.750  1.0
  Pb  Pb14  1  0.756  0.749  0.750  1.0
  Pb  Pb15  1  0.749  0.993  0.250  1.0
  Pb  Pb16  1  0.007  0.756  0.250  1.0
  Pb  Pb17  1  0.244  0.251  0.250  1.0
  O  O18  1  0.327  0.491  0.747  1.0
  O  O19  1  0.509  0.837  0.747  1.0
  O  O20  1  0.163  0.673  0.747  1.0
  O  O21  1  0.673  0.509  0.247  1.0
  O  O22  1  0.491  0.163  0.247  1.0
  O  O23  1  0.837  0.327  0.247  1.0
  O  O24  1  0.595  0.470  0.741  1.0
  O  O25  1  0.530  0.125  0.741  1.0
  O  O26  1  0.875  0.405  0.741  1.0
  O  O27  1  0.405  0.530  0.241  1.0
  O  O28  1  0.470  0.875  0.241  1.0
  O  O29  1  0.125  0.595  0.241  1.0
  O  O30  1  0.337  0.250  0.562  1.0
  O  O31  1  0.750  0.087  0.562  1.0
  O  O32  1  0.913  0.663  0.562  1.0
  O  O33  1  0.654  0.750  0.426  1.0
  O  O34  1  0.250  0.904  0.426  1.0
  O  O35  1  0.096  0.346  0.426  1.0
  O  O36  1  0.663  0.750  0.062  1.0
  O  O37  1  0.250  0.913  0.062  1.0
  O  O38  1  0.087  0.337  0.062  1.0
  O  O39  1  0.346  0.250  0.926  1.0
  O  O40  1  0.750  0.096  0.926  1.0
  O  O41  1  0.904  0.654  0.926  1.0
  O  O42  1  0.000  0.000  0.807  1.0
  O  O43  1  0.000  0.000  0.307  1.0
[/CIF]
.