The compound described by AlCl4SCl3 is Indium-derived structured and crystallizes in the monoclinic Pc space group. The structure is zero-dimensional and consists of two AlCl4 clusters and two SCl3 clusters. In each AlCl4 cluster, Al(1) is bonded in a tetrahedral geometry to one Cl(3), one Cl(5), one Cl(6), and one Cl(7) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one Al(1) atom. In the second Cl site, Cl(5) is bonded in a single-bond geometry to one Al(1) atom. In the third Cl site, Cl(6) is bonded in a single-bond geometry to one Al(1) atom. In the fourth Cl site, Cl(7) is bonded in a single-bond geometry to one Al(1) atom. In each SCl3 cluster, S(1) is bonded in a trigonal non-coplanar geometry to one Cl(1), one Cl(2), and one Cl(4) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(4) is bonded in a single-bond geometry to one S(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one S(1) atom. In the third Cl site, Cl(2) is bonded in a single-bond geometry to one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_AlSCl7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.274
_cell_length_b   6.451
_cell_length_c   13.280
_cell_angle_alpha   102.820
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   524.064
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  0.490  0.451  0.857  1.0
  Al  Al1  1  0.510  0.451  0.357  1.0
  S  S2  1  0.071  0.120  0.689  1.0
  S  S3  1  0.929  0.120  0.189  1.0
  Cl  Cl4  1  0.712  0.946  0.097  1.0
  Cl  Cl5  1  0.120  0.209  0.086  1.0
  Cl  Cl6  1  0.356  0.672  0.985  1.0
  Cl  Cl7  1  0.288  0.946  0.597  1.0
  Cl  Cl8  1  0.902  0.895  0.735  1.0
  Cl  Cl9  1  0.644  0.672  0.485  1.0
  Cl  Cl10  1  0.169  0.475  0.359  1.0
  Cl  Cl11  1  0.397  0.134  0.867  1.0
  Cl  Cl12  1  0.831  0.475  0.859  1.0
  Cl  Cl13  1  0.603  0.134  0.367  1.0
  Cl  Cl14  1  0.627  0.507  0.213  1.0
  Cl  Cl15  1  0.880  0.209  0.586  1.0
  Cl  Cl16  1  0.373  0.507  0.713  1.0
  Cl  Cl17  1  0.098  0.895  0.235  1.0
[/CIF]
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The compound described by AlCl4SCl3 is Indium-derived structured and crystallizes in the monoclinic Pc space group. The structure is zero-dimensional and consists of two AlCl4 clusters and two SCl3 clusters. In each AlCl4 cluster, Al(1) is bonded in a tetrahedral geometry to one Cl(3), one Cl(5), one Cl(6), and one Cl(7) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one Al(1) atom. In the second Cl site, Cl(5) is bonded in a single-bond geometry to one Al(1) atom. In the third Cl site, Cl(6) is bonded in a single-bond geometry to one Al(1) atom. In the fourth Cl site, Cl(7) is bonded in a single-bond geometry to one Al(1) atom. In each SCl3 cluster, S(1) is bonded in a trigonal non-coplanar geometry to one Cl(1), one Cl(2), and one Cl(4) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(4) is bonded in a single-bond geometry to one S(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one S(1) atom. In the third Cl site, Cl(2) is bonded in a single-bond geometry to one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_AlSCl7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.274
_cell_length_b   6.451
_cell_length_c   13.280
_cell_angle_alpha   102.820
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   524.064
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  0.490  0.451  0.857  1.0
  Al  Al1  1  0.510  0.451  0.357  1.0
  S  S2  1  0.071  0.120  0.689  1.0
  S  S3  1  0.929  0.120  0.189  1.0
  Cl  Cl4  1  0.712  0.946  0.097  1.0
  Cl  Cl5  1  0.120  0.209  0.086  1.0
  Cl  Cl6  1  0.356  0.672  0.985  1.0
  Cl  Cl7  1  0.288  0.946  0.597  1.0
  Cl  Cl8  1  0.902  0.895  0.735  1.0
  Cl  Cl9  1  0.644  0.672  0.485  1.0
  Cl  Cl10  1  0.169  0.475  0.359  1.0
  Cl  Cl11  1  0.397  0.134  0.867  1.0
  Cl  Cl12  1  0.831  0.475  0.859  1.0
  Cl  Cl13  1  0.603  0.134  0.367  1.0
  Cl  Cl14  1  0.627  0.507  0.213  1.0
  Cl  Cl15  1  0.880  0.209  0.586  1.0
  Cl  Cl16  1  0.373  0.507  0.713  1.0
  Cl  Cl17  1  0.098  0.895  0.235  1.0
[/CIF]
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