The crystal structure described by Cr4N2S3 crystallizes in the monoclinic C2/m space group. There are two inequivalent Cr sites. In the first Cr site, Cr(1) is bonded in a 6-coordinate geometry to three equivalent N(1), one S(1), and two equivalent S(2) atoms. In the second Cr site, Cr(2) is bonded in a 6-coordinate geometry to one N(1), two equivalent S(1), and three equivalent S(2) atoms. N(1) is bonded in a see-saw-like geometry to one Cr(2) and three equivalent Cr(1) atoms. There are two inequivalent S sites. In the first S site, S(1) is bonded in a 6-coordinate geometry to two equivalent Cr(1) and four equivalent Cr(2) atoms. In the second S site, S(2) is bonded in a 5-coordinate geometry to two equivalent Cr(1) and three equivalent Cr(2) atoms. is represented by the CIF file [CIF]
data_Cr4S3N2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.832
_cell_length_b   3.137
_cell_length_c   8.467
_cell_angle_alpha   90.000
_cell_angle_beta   52.933
_cell_angle_gamma   74.400
_symmetry_Int_Tables_number   1
_cell_volume   116.373
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.320  0.840  0.645  1.0
  Cr  Cr1  1  0.680  0.160  0.355  1.0
  Cr  Cr2  1  0.539  0.730  0.114  1.0
  Cr  Cr3  1  0.461  0.270  0.886  1.0
  S  S4  1  0.000  0.000  0.000  1.0
  S  S5  1  0.825  0.588  0.774  1.0
  S  S6  1  0.175  0.412  0.226  1.0
  N  N7  1  0.482  0.759  0.368  1.0
  N  N8  1  0.518  0.241  0.632  1.0
[/CIF]
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The crystal structure described by Cr4N2S3 crystallizes in the monoclinic C2/m space group. There are two inequivalent Cr sites. In the first Cr site, Cr(1) is bonded in a 6-coordinate geometry to three equivalent N(1), one S(1), and two equivalent S(2) atoms. In the second Cr site, Cr(2) is bonded in a 6-coordinate geometry to one N(1), two equivalent S(1), and three equivalent S(2) atoms. N(1) is bonded in a see-saw-like geometry to one Cr(2) and three equivalent Cr(1) atoms. There are two inequivalent S sites. In the first S site, S(1) is bonded in a 6-coordinate geometry to two equivalent Cr(1) and four equivalent Cr(2) atoms. In the second S site, S(2) is bonded in a 5-coordinate geometry to two equivalent Cr(1) and three equivalent Cr(2) atoms. is represented by the CIF file [CIF]
data_Cr4S3N2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.832
_cell_length_b   3.137
_cell_length_c   8.467
_cell_angle_alpha   90.000
_cell_angle_beta   52.933
_cell_angle_gamma   74.400
_symmetry_Int_Tables_number   1
_cell_volume   116.373
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.320  0.840  0.645  1.0
  Cr  Cr1  1  0.680  0.160  0.355  1.0
  Cr  Cr2  1  0.539  0.730  0.114  1.0
  Cr  Cr3  1  0.461  0.270  0.886  1.0
  S  S4  1  0.000  0.000  0.000  1.0
  S  S5  1  0.825  0.588  0.774  1.0
  S  S6  1  0.175  0.412  0.226  1.0
  N  N7  1  0.482  0.759  0.368  1.0
  N  N8  1  0.518  0.241  0.632  1.0
[/CIF]
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