The crystal structure described by Au13Ag3Te32 crystallizes in the monoclinic C2 space group. There are seven inequivalent Au sites. In the first Au site, Au(1) is bonded in a distorted square co-planar geometry to one Te(1), one Te(10), one Te(14), one Te(7), and one Te(9) atom. In the second Au site, Au(2) is bonded in a distorted square co-planar geometry to one Te(10), one Te(13), one Te(2), one Te(8), and one Te(9) atom. In the third Au site, Au(3) is bonded in a distorted square co-planar geometry to one Te(11), one Te(12), one Te(16), one Te(3), and one Te(7) atom. In the fourth Au site, Au(4) is bonded in a distorted square co-planar geometry to one Te(11), one Te(12), one Te(15), one Te(4), and one Te(8) atom. In the fifth Au site, Au(5) is bonded to one Te(1), one Te(2), one Te(3), one Te(4), one Te(5), and one Te(8) atom to form distorted AuTe6 octahedra that share edges with two equivalent Ag(1)Te6 octahedra. In the sixth Au site, Au(6) is bonded to two equivalent Te(10), two equivalent Te(13), and two equivalent Te(14) atoms to form AuTe6 octahedra that share edges with two equivalent Ag(2)Te6 octahedra. In the seventh Au site, Au(7) is bonded to one Te(11), one Te(12), two equivalent Te(15), and two equivalent Te(16) atoms to form edge-sharing AuTe6 octahedra. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to one Te(1), one Te(2), one Te(3), one Te(4), one Te(6), and one Te(7) atom to form distorted AgTe6 octahedra that share edges with two equivalent Au(5)Te6 octahedra. In the second Ag site, Ag(2) is bonded to two equivalent Te(13), two equivalent Te(14), and two equivalent Te(9) atoms to form AgTe6 octahedra that share edges with two equivalent Au(6)Te6 octahedra. There are sixteen inequivalent Te sites. In the first Te site, Te(1) is bonded in a 4-coordinate geometry to one Au(1), one Au(5), one Ag(1), and one Te(9) atom. In the second Te site, Te(2) is bonded in a 4-coordinate geometry to one Au(2), one Au(5), one Ag(1), and one Te(10) atom. In the third Te site, Te(3) is bonded in a 4-coordinate geometry to one Au(3), one Au(5), one Ag(1), and one Te(12) atom. In the fourth Te site, Te(4) is bonded in a 4-coordinate geometry to one Au(4), one Au(5), one Ag(1), and one Te(11) atom. In the fifth Te site, Te(5) is bonded in a distorted single-bond geometry to one Au(5) and one Te(13) atom. In the sixth Te site, Te(6) is bonded in a 3-coordinate geometry to one Ag(1), one Te(14), and one Te(16) atom. In the seventh Te site, Te(7) is bonded in a trigonal non-coplanar geometry to one Au(1), one Au(3), and one Ag(1) atom. In the eighth Te site, Te(8) is bonded in a trigonal non-coplanar geometry to one Au(2), one Au(4), and one Au(5) atom. In the ninth Te site, Te(9) is bonded in a 4-coordinate geometry to one Au(1), one Au(2), one Ag(2), and one Te(1) atom. In the tenth Te site, Te(10) is bonded in a distorted water-like geometry to one Au(1), one Au(2), one Au(6), and one Te(2) atom. In the eleventh Te site, Te(11) is bonded in a distorted water-like geometry to one Au(3), one Au(4), one Au(7), and one Te(4) atom. In the twelfth Te site, Te(12) is bonded in a distorted water-like geometry to one Au(3), one Au(4), one Au(7), and one Te(3) atom. In the thirteenth Te site, Te(13) is bonded in a 4-coordinate geometry to one Au(2), one Au(6), one Ag(2), and one Te(5) atom. In the fourteenth Te site, Te(14) is bonded in a 4-coordinate geometry to one Au(1), one Au(6), one Ag(2), and one Te(6) atom. In the fifteenth Te site, Te(15) is bonded in a 3-coordinate geometry to one Au(4) and two equivalent Au(7) atoms. In the sixteenth Te site, Te(16) is bonded in a 4-coordinate geometry to one Au(3), two equivalent Au(7), and one Te(6) atom. is represented by the CIF file [CIF]
data_Ag3Te32Au13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   17.553
_cell_length_b   17.553
_cell_length_c   9.089
_cell_angle_alpha   89.934
_cell_angle_beta   89.934
_cell_angle_gamma   29.857
_symmetry_Int_Tables_number   1
_cell_volume   1394.111
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.073  0.676  0.317  1.0
  Ag  Ag1  1  0.324  0.927  0.683  1.0
  Ag  Ag2  1  0.700  0.300  0.000  1.0
  Te  Te3  1  0.406  0.467  0.369  1.0
  Te  Te4  1  0.902  0.972  0.368  1.0
  Te  Te5  1  0.533  0.594  0.631  1.0
  Te  Te6  1  0.028  0.098  0.632  1.0
  Te  Te7  1  0.283  0.344  0.369  1.0
  Te  Te8  1  0.778  0.849  0.368  1.0
  Te  Te9  1  0.656  0.717  0.631  1.0
  Te  Te10  1  0.151  0.222  0.632  1.0
  Te  Te11  1  0.599  0.152  0.019  1.0
  Te  Te12  1  0.099  0.650  0.011  1.0
  Te  Te13  1  0.848  0.401  0.981  1.0
  Te  Te14  1  0.350  0.901  0.989  1.0
  Te  Te15  1  0.142  0.607  0.614  1.0
  Te  Te16  1  0.639  0.112  0.613  1.0
  Te  Te17  1  0.393  0.858  0.386  1.0
  Te  Te18  1  0.888  0.361  0.387  1.0
  Te  Te19  1  0.649  0.346  0.698  1.0
  Te  Te20  1  0.152  0.843  0.702  1.0
  Te  Te21  1  0.654  0.351  0.302  1.0
  Te  Te22  1  0.157  0.848  0.298  1.0
  Te  Te23  1  0.407  0.098  0.702  1.0
  Te  Te24  1  0.907  0.598  0.702  1.0
  Te  Te25  1  0.902  0.593  0.298  1.0
  Te  Te26  1  0.402  0.093  0.298  1.0
  Te  Te27  1  0.872  0.007  0.961  1.0
  Te  Te28  1  0.368  0.512  0.961  1.0
  Te  Te29  1  0.993  0.128  0.039  1.0
  Te  Te30  1  0.488  0.632  0.039  1.0
  Te  Te31  1  0.742  0.879  0.962  1.0
  Te  Te32  1  0.242  0.379  0.962  1.0
  Te  Te33  1  0.121  0.258  0.038  1.0
  Te  Te34  1  0.621  0.758  0.038  1.0
  Au  Au35  1  0.390  0.484  0.666  1.0
  Au  Au36  1  0.890  0.984  0.665  1.0
  Au  Au37  1  0.516  0.610  0.334  1.0
  Au  Au38  1  0.016  0.110  0.335  1.0
  Au  Au39  1  0.267  0.358  0.667  1.0
  Au  Au40  1  0.766  0.860  0.666  1.0
  Au  Au41  1  0.642  0.733  0.333  1.0
  Au  Au42  1  0.140  0.234  0.334  1.0
  Au  Au43  1  0.583  0.167  0.318  1.0
  Au  Au44  1  0.833  0.417  0.682  1.0
  Au  Au45  1  0.192  0.808  0.000  1.0
  Au  Au46  1  0.943  0.557  0.000  1.0
  Au  Au47  1  0.443  0.057  1.000  1.0
[/CIF]
.
The crystal structure described by Au13Ag3Te32 crystallizes in the monoclinic C2 space group. There are seven inequivalent Au sites. In the first Au site, Au(1) is bonded in a distorted square co-planar geometry to one Te(1), one Te(10), one Te(14), one Te(7), and one Te(9) atom. In the second Au site, Au(2) is bonded in a distorted square co-planar geometry to one Te(10), one Te(13), one Te(2), one Te(8), and one Te(9) atom. In the third Au site, Au(3) is bonded in a distorted square co-planar geometry to one Te(11), one Te(12), one Te(16), one Te(3), and one Te(7) atom. In the fourth Au site, Au(4) is bonded in a distorted square co-planar geometry to one Te(11), one Te(12), one Te(15), one Te(4), and one Te(8) atom. In the fifth Au site, Au(5) is bonded to one Te(1), one Te(2), one Te(3), one Te(4), one Te(5), and one Te(8) atom to form distorted AuTe6 octahedra that share edges with two equivalent Ag(1)Te6 octahedra. In the sixth Au site, Au(6) is bonded to two equivalent Te(10), two equivalent Te(13), and two equivalent Te(14) atoms to form AuTe6 octahedra that share edges with two equivalent Ag(2)Te6 octahedra. In the seventh Au site, Au(7) is bonded to one Te(11), one Te(12), two equivalent Te(15), and two equivalent Te(16) atoms to form edge-sharing AuTe6 octahedra. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to one Te(1), one Te(2), one Te(3), one Te(4), one Te(6), and one Te(7) atom to form distorted AgTe6 octahedra that share edges with two equivalent Au(5)Te6 octahedra. In the second Ag site, Ag(2) is bonded to two equivalent Te(13), two equivalent Te(14), and two equivalent Te(9) atoms to form AgTe6 octahedra that share edges with two equivalent Au(6)Te6 octahedra. There are sixteen inequivalent Te sites. In the first Te site, Te(1) is bonded in a 4-coordinate geometry to one Au(1), one Au(5), one Ag(1), and one Te(9) atom. In the second Te site, Te(2) is bonded in a 4-coordinate geometry to one Au(2), one Au(5), one Ag(1), and one Te(10) atom. In the third Te site, Te(3) is bonded in a 4-coordinate geometry to one Au(3), one Au(5), one Ag(1), and one Te(12) atom. In the fourth Te site, Te(4) is bonded in a 4-coordinate geometry to one Au(4), one Au(5), one Ag(1), and one Te(11) atom. In the fifth Te site, Te(5) is bonded in a distorted single-bond geometry to one Au(5) and one Te(13) atom. In the sixth Te site, Te(6) is bonded in a 3-coordinate geometry to one Ag(1), one Te(14), and one Te(16) atom. In the seventh Te site, Te(7) is bonded in a trigonal non-coplanar geometry to one Au(1), one Au(3), and one Ag(1) atom. In the eighth Te site, Te(8) is bonded in a trigonal non-coplanar geometry to one Au(2), one Au(4), and one Au(5) atom. In the ninth Te site, Te(9) is bonded in a 4-coordinate geometry to one Au(1), one Au(2), one Ag(2), and one Te(1) atom. In the tenth Te site, Te(10) is bonded in a distorted water-like geometry to one Au(1), one Au(2), one Au(6), and one Te(2) atom. In the eleventh Te site, Te(11) is bonded in a distorted water-like geometry to one Au(3), one Au(4), one Au(7), and one Te(4) atom. In the twelfth Te site, Te(12) is bonded in a distorted water-like geometry to one Au(3), one Au(4), one Au(7), and one Te(3) atom. In the thirteenth Te site, Te(13) is bonded in a 4-coordinate geometry to one Au(2), one Au(6), one Ag(2), and one Te(5) atom. In the fourteenth Te site, Te(14) is bonded in a 4-coordinate geometry to one Au(1), one Au(6), one Ag(2), and one Te(6) atom. In the fifteenth Te site, Te(15) is bonded in a 3-coordinate geometry to one Au(4) and two equivalent Au(7) atoms. In the sixteenth Te site, Te(16) is bonded in a 4-coordinate geometry to one Au(3), two equivalent Au(7), and one Te(6) atom. is represented by the CIF file [CIF]
data_Ag3Te32Au13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   17.553
_cell_length_b   17.553
_cell_length_c   9.089
_cell_angle_alpha   89.934
_cell_angle_beta   89.934
_cell_angle_gamma   29.857
_symmetry_Int_Tables_number   1
_cell_volume   1394.111
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.073  0.676  0.317  1.0
  Ag  Ag1  1  0.324  0.927  0.683  1.0
  Ag  Ag2  1  0.700  0.300  0.000  1.0
  Te  Te3  1  0.406  0.467  0.369  1.0
  Te  Te4  1  0.902  0.972  0.368  1.0
  Te  Te5  1  0.533  0.594  0.631  1.0
  Te  Te6  1  0.028  0.098  0.632  1.0
  Te  Te7  1  0.283  0.344  0.369  1.0
  Te  Te8  1  0.778  0.849  0.368  1.0
  Te  Te9  1  0.656  0.717  0.631  1.0
  Te  Te10  1  0.151  0.222  0.632  1.0
  Te  Te11  1  0.599  0.152  0.019  1.0
  Te  Te12  1  0.099  0.650  0.011  1.0
  Te  Te13  1  0.848  0.401  0.981  1.0
  Te  Te14  1  0.350  0.901  0.989  1.0
  Te  Te15  1  0.142  0.607  0.614  1.0
  Te  Te16  1  0.639  0.112  0.613  1.0
  Te  Te17  1  0.393  0.858  0.386  1.0
  Te  Te18  1  0.888  0.361  0.387  1.0
  Te  Te19  1  0.649  0.346  0.698  1.0
  Te  Te20  1  0.152  0.843  0.702  1.0
  Te  Te21  1  0.654  0.351  0.302  1.0
  Te  Te22  1  0.157  0.848  0.298  1.0
  Te  Te23  1  0.407  0.098  0.702  1.0
  Te  Te24  1  0.907  0.598  0.702  1.0
  Te  Te25  1  0.902  0.593  0.298  1.0
  Te  Te26  1  0.402  0.093  0.298  1.0
  Te  Te27  1  0.872  0.007  0.961  1.0
  Te  Te28  1  0.368  0.512  0.961  1.0
  Te  Te29  1  0.993  0.128  0.039  1.0
  Te  Te30  1  0.488  0.632  0.039  1.0
  Te  Te31  1  0.742  0.879  0.962  1.0
  Te  Te32  1  0.242  0.379  0.962  1.0
  Te  Te33  1  0.121  0.258  0.038  1.0
  Te  Te34  1  0.621  0.758  0.038  1.0
  Au  Au35  1  0.390  0.484  0.666  1.0
  Au  Au36  1  0.890  0.984  0.665  1.0
  Au  Au37  1  0.516  0.610  0.334  1.0
  Au  Au38  1  0.016  0.110  0.335  1.0
  Au  Au39  1  0.267  0.358  0.667  1.0
  Au  Au40  1  0.766  0.860  0.666  1.0
  Au  Au41  1  0.642  0.733  0.333  1.0
  Au  Au42  1  0.140  0.234  0.334  1.0
  Au  Au43  1  0.583  0.167  0.318  1.0
  Au  Au44  1  0.833  0.417  0.682  1.0
  Au  Au45  1  0.192  0.808  0.000  1.0
  Au  Au46  1  0.943  0.557  0.000  1.0
  Au  Au47  1  0.443  0.057  1.000  1.0
[/CIF]
.