The structure described by Mo2Ni3TeO11 crystallizes in the monoclinic C2/m space group. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 6-coordinate geometry to two equivalent O(3), two equivalent O(4), and two equivalent O(6) atoms. In the second Mo site, Mo(2) is bonded in a 6-coordinate geometry to one O(6), one O(7), two equivalent O(1), and two equivalent O(4) atoms. There are two inequivalent Ni sites. In the first Ni site, Ni(1) is bonded to one O(1), one O(4), one O(5), one O(7), and two equivalent O(2) atoms to form edge-sharing NiO6 octahedra. In the second Ni site, Ni(2) is bonded to one O(5), one O(6), two equivalent O(3), and two equivalent O(4) atoms to form edge-sharing NiO6 octahedra. Te(1) is bonded in a distorted trigonal non-coplanar geometry to one O(5) and two equivalent O(2) atoms. There are seven inequivalent O sites. In the first O site, O(6) is bonded in a distorted see-saw-like geometry to one Mo(2), two equivalent Mo(1), and one Ni(2) atom. In the second O site, O(7) is bonded in a trigonal non-coplanar geometry to one Mo(2) and two equivalent Ni(1) atoms. In the third O site, O(1) is bonded in a linear geometry to one Mo(2) and one Ni(1) atom. In the fourth O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Ni(1) and one Te(1) atom. In the fifth O site, O(3) is bonded in a linear geometry to one Mo(1) and one Ni(2) atom. In the sixth O site, O(4) is bonded in a distorted rectangular see-saw-like geometry to one Mo(1), one Mo(2), one Ni(1), and one Ni(2) atom. In the seventh O site, O(5) is bonded in a rectangular see-saw-like geometry to one Ni(2), two equivalent Ni(1), and one Te(1) atom. is represented by the CIF card [CIF]
data_Ni3TeMo2O11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.562
_cell_length_b   6.562
_cell_length_c   10.300
_cell_angle_alpha   80.218
_cell_angle_beta   80.218
_cell_angle_gamma   84.971
_symmetry_Int_Tables_number   1
_cell_volume   429.917
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni0  1  0.912  0.560  0.869  1.0
  Ni  Ni1  1  0.088  0.440  0.131  1.0
  Ni  Ni2  1  0.440  0.088  0.131  1.0
  Ni  Ni3  1  0.738  0.738  0.611  1.0
  Ni  Ni4  1  0.560  0.912  0.869  1.0
  Ni  Ni5  1  0.262  0.262  0.389  1.0
  Te  Te6  1  0.414  0.414  0.816  1.0
  Te  Te7  1  0.586  0.586  0.184  1.0
  Mo  Mo8  1  0.212  0.788  0.500  1.0
  Mo  Mo9  1  0.969  0.969  0.239  1.0
  Mo  Mo10  1  0.788  0.212  0.500  1.0
  Mo  Mo11  1  0.031  0.031  0.761  1.0
  O  O12  1  0.717  0.030  0.198  1.0
  O  O13  1  0.802  0.471  0.068  1.0
  O  O14  1  0.221  0.548  0.443  1.0
  O  O15  1  0.529  0.198  0.932  1.0
  O  O16  1  0.726  0.033  0.670  1.0
  O  O17  1  0.452  0.779  0.557  1.0
  O  O18  1  0.381  0.381  0.192  1.0
  O  O19  1  0.198  0.529  0.932  1.0
  O  O20  1  0.779  0.452  0.557  1.0
  O  O21  1  0.030  0.717  0.198  1.0
  O  O22  1  0.970  0.283  0.802  1.0
  O  O23  1  0.033  0.726  0.670  1.0
  O  O24  1  0.471  0.802  0.068  1.0
  O  O25  1  0.619  0.619  0.808  1.0
  O  O26  1  0.106  0.106  0.562  1.0
  O  O27  1  0.894  0.894  0.438  1.0
  O  O28  1  0.274  0.967  0.330  1.0
  O  O29  1  0.283  0.970  0.802  1.0
  O  O30  1  0.866  0.866  0.894  1.0
  O  O31  1  0.967  0.274  0.330  1.0
  O  O32  1  0.134  0.134  0.106  1.0
  O  O33  1  0.548  0.221  0.443  1.0
[/CIF]
.
The structure described by Mo2Ni3TeO11 crystallizes in the monoclinic C2/m space group. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 6-coordinate geometry to two equivalent O(3), two equivalent O(4), and two equivalent O(6) atoms. In the second Mo site, Mo(2) is bonded in a 6-coordinate geometry to one O(6), one O(7), two equivalent O(1), and two equivalent O(4) atoms. There are two inequivalent Ni sites. In the first Ni site, Ni(1) is bonded to one O(1), one O(4), one O(5), one O(7), and two equivalent O(2) atoms to form edge-sharing NiO6 octahedra. In the second Ni site, Ni(2) is bonded to one O(5), one O(6), two equivalent O(3), and two equivalent O(4) atoms to form edge-sharing NiO6 octahedra. Te(1) is bonded in a distorted trigonal non-coplanar geometry to one O(5) and two equivalent O(2) atoms. There are seven inequivalent O sites. In the first O site, O(6) is bonded in a distorted see-saw-like geometry to one Mo(2), two equivalent Mo(1), and one Ni(2) atom. In the second O site, O(7) is bonded in a trigonal non-coplanar geometry to one Mo(2) and two equivalent Ni(1) atoms. In the third O site, O(1) is bonded in a linear geometry to one Mo(2) and one Ni(1) atom. In the fourth O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Ni(1) and one Te(1) atom. In the fifth O site, O(3) is bonded in a linear geometry to one Mo(1) and one Ni(2) atom. In the sixth O site, O(4) is bonded in a distorted rectangular see-saw-like geometry to one Mo(1), one Mo(2), one Ni(1), and one Ni(2) atom. In the seventh O site, O(5) is bonded in a rectangular see-saw-like geometry to one Ni(2), two equivalent Ni(1), and one Te(1) atom. is represented by the CIF card [CIF]
data_Ni3TeMo2O11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.562
_cell_length_b   6.562
_cell_length_c   10.300
_cell_angle_alpha   80.218
_cell_angle_beta   80.218
_cell_angle_gamma   84.971
_symmetry_Int_Tables_number   1
_cell_volume   429.917
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni0  1  0.912  0.560  0.869  1.0
  Ni  Ni1  1  0.088  0.440  0.131  1.0
  Ni  Ni2  1  0.440  0.088  0.131  1.0
  Ni  Ni3  1  0.738  0.738  0.611  1.0
  Ni  Ni4  1  0.560  0.912  0.869  1.0
  Ni  Ni5  1  0.262  0.262  0.389  1.0
  Te  Te6  1  0.414  0.414  0.816  1.0
  Te  Te7  1  0.586  0.586  0.184  1.0
  Mo  Mo8  1  0.212  0.788  0.500  1.0
  Mo  Mo9  1  0.969  0.969  0.239  1.0
  Mo  Mo10  1  0.788  0.212  0.500  1.0
  Mo  Mo11  1  0.031  0.031  0.761  1.0
  O  O12  1  0.717  0.030  0.198  1.0
  O  O13  1  0.802  0.471  0.068  1.0
  O  O14  1  0.221  0.548  0.443  1.0
  O  O15  1  0.529  0.198  0.932  1.0
  O  O16  1  0.726  0.033  0.670  1.0
  O  O17  1  0.452  0.779  0.557  1.0
  O  O18  1  0.381  0.381  0.192  1.0
  O  O19  1  0.198  0.529  0.932  1.0
  O  O20  1  0.779  0.452  0.557  1.0
  O  O21  1  0.030  0.717  0.198  1.0
  O  O22  1  0.970  0.283  0.802  1.0
  O  O23  1  0.033  0.726  0.670  1.0
  O  O24  1  0.471  0.802  0.068  1.0
  O  O25  1  0.619  0.619  0.808  1.0
  O  O26  1  0.106  0.106  0.562  1.0
  O  O27  1  0.894  0.894  0.438  1.0
  O  O28  1  0.274  0.967  0.330  1.0
  O  O29  1  0.283  0.970  0.802  1.0
  O  O30  1  0.866  0.866  0.894  1.0
  O  O31  1  0.967  0.274  0.330  1.0
  O  O32  1  0.134  0.134  0.106  1.0
  O  O33  1  0.548  0.221  0.443  1.0
[/CIF]
.