The structure described by Hg3(AsF6)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two 7439-97-6 atoms and four HgAsF6 clusters. In each HgAsF6 cluster, Hg(1) is bonded in a single-bond geometry to one F(1) atom. As(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. There are six inequivalent F sites. In the first F site, F(1) is bonded in a bent 120 degrees geometry to one Hg(1) and one As(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one As(1) atom. is represented by the CIF card [CIF]
data_Hg3As2F12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.535
_cell_length_b   5.711
_cell_length_c   11.276
_cell_angle_alpha   87.601
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   549.129
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Hg  Hg0  1  0.742  0.756  0.569  1.0
  Hg  Hg1  1  0.242  0.244  0.931  1.0
  Hg  Hg2  1  0.258  0.244  0.431  1.0
  Hg  Hg3  1  0.758  0.756  0.069  1.0
  Hg  Hg4  1  0.500  0.000  0.500  1.0
  Hg  Hg5  1  0.000  0.000  0.000  1.0
  As  As6  1  0.147  0.696  0.671  1.0
  As  As7  1  0.647  0.304  0.829  1.0
  As  As8  1  0.853  0.304  0.329  1.0
  As  As9  1  0.353  0.696  0.171  1.0
  F  F10  1  0.978  0.548  0.623  1.0
  F  F11  1  0.478  0.452  0.877  1.0
  F  F12  1  0.022  0.452  0.377  1.0
  F  F13  1  0.522  0.548  0.123  1.0
  F  F14  1  0.234  0.423  0.702  1.0
  F  F15  1  0.734  0.577  0.798  1.0
  F  F16  1  0.766  0.577  0.298  1.0
  F  F17  1  0.266  0.423  0.202  1.0
  F  F18  1  0.072  0.692  0.815  1.0
  F  F19  1  0.572  0.308  0.685  1.0
  F  F20  1  0.187  0.844  0.216  1.0
  F  F21  1  0.687  0.156  0.284  1.0
  F  F22  1  0.813  0.156  0.784  1.0
  F  F23  1  0.313  0.844  0.716  1.0
  F  F24  1  0.278  0.689  0.027  1.0
  F  F25  1  0.778  0.311  0.473  1.0
  F  F26  1  0.722  0.311  0.973  1.0
  F  F27  1  0.222  0.689  0.527  1.0
  F  F28  1  0.448  0.959  0.135  1.0
  F  F29  1  0.948  0.041  0.365  1.0
  F  F30  1  0.552  0.041  0.865  1.0
  F  F31  1  0.052  0.959  0.635  1.0
  F  F32  1  0.428  0.692  0.315  1.0
  F  F33  1  0.928  0.308  0.185  1.0
[/CIF]
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The structure described by Hg3(AsF6)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two 7439-97-6 atoms and four HgAsF6 clusters. In each HgAsF6 cluster, Hg(1) is bonded in a single-bond geometry to one F(1) atom. As(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. There are six inequivalent F sites. In the first F site, F(1) is bonded in a bent 120 degrees geometry to one Hg(1) and one As(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one As(1) atom. is represented by the CIF card [CIF]
data_Hg3As2F12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.535
_cell_length_b   5.711
_cell_length_c   11.276
_cell_angle_alpha   87.601
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   549.129
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Hg  Hg0  1  0.742  0.756  0.569  1.0
  Hg  Hg1  1  0.242  0.244  0.931  1.0
  Hg  Hg2  1  0.258  0.244  0.431  1.0
  Hg  Hg3  1  0.758  0.756  0.069  1.0
  Hg  Hg4  1  0.500  0.000  0.500  1.0
  Hg  Hg5  1  0.000  0.000  0.000  1.0
  As  As6  1  0.147  0.696  0.671  1.0
  As  As7  1  0.647  0.304  0.829  1.0
  As  As8  1  0.853  0.304  0.329  1.0
  As  As9  1  0.353  0.696  0.171  1.0
  F  F10  1  0.978  0.548  0.623  1.0
  F  F11  1  0.478  0.452  0.877  1.0
  F  F12  1  0.022  0.452  0.377  1.0
  F  F13  1  0.522  0.548  0.123  1.0
  F  F14  1  0.234  0.423  0.702  1.0
  F  F15  1  0.734  0.577  0.798  1.0
  F  F16  1  0.766  0.577  0.298  1.0
  F  F17  1  0.266  0.423  0.202  1.0
  F  F18  1  0.072  0.692  0.815  1.0
  F  F19  1  0.572  0.308  0.685  1.0
  F  F20  1  0.187  0.844  0.216  1.0
  F  F21  1  0.687  0.156  0.284  1.0
  F  F22  1  0.813  0.156  0.784  1.0
  F  F23  1  0.313  0.844  0.716  1.0
  F  F24  1  0.278  0.689  0.027  1.0
  F  F25  1  0.778  0.311  0.473  1.0
  F  F26  1  0.722  0.311  0.973  1.0
  F  F27  1  0.222  0.689  0.527  1.0
  F  F28  1  0.448  0.959  0.135  1.0
  F  F29  1  0.948  0.041  0.365  1.0
  F  F30  1  0.552  0.041  0.865  1.0
  F  F31  1  0.052  0.959  0.635  1.0
  F  F32  1  0.428  0.692  0.315  1.0
  F  F33  1  0.928  0.308  0.185  1.0
[/CIF]
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