The material described by Gd3InO6 crystallizes in the orthorhombic Cmc2_1 space group. There are two inequivalent Gd sites. In the first Gd site, Gd(1) is bonded in a 7-coordinate geometry to one O(4), two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. In the second Gd site, Gd(2) is bonded to one O(4), two equivalent O(2), and four equivalent O(1) atoms to form distorted edge-sharing GdO7 pentagonal bipyramids. In(1) is bonded in a rectangular see-saw-like geometry to one O(3), one O(4), and two equivalent O(2) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Gd(1) and two equivalent Gd(2) atoms to form OGd4 tetrahedra that share corners with two equivalent O(1)Gd4 tetrahedra, corners with four equivalent O(4)Gd3In tetrahedra, corners with two equivalent O(3)Gd4In trigonal bipyramids, corners with six equivalent O(2)Gd3In trigonal pyramids, edges with three equivalent O(1)Gd4 tetrahedra,  an edgeedge with one O(3)Gd4In trigonal bipyramid, and  an edgeedge with one O(2)Gd3In trigonal pyramid. In the second O site, O(2) is bonded to one Gd(2), two equivalent Gd(1), and one In(1) atom to form distorted OGd3In trigonal pyramids that share corners with two equivalent O(4)Gd3In tetrahedra, corners with six equivalent O(1)Gd4 tetrahedra, corners with three equivalent O(3)Gd4In trigonal bipyramids, corners with two equivalent O(2)Gd3In trigonal pyramids,  an edgeedge with one O(4)Gd3In tetrahedra,  an edgeedge with one O(1)Gd4 tetrahedra,  an edgeedge with one O(3)Gd4In trigonal bipyramid, and  an edgeedge with one O(2)Gd3In trigonal pyramid. In the third O site, O(3) is bonded to four equivalent Gd(1) and one In(1) atom to form distorted OGd4In trigonal bipyramids that share  a cornercorner with one O(4)Gd3In tetrahedra, corners with four equivalent O(1)Gd4 tetrahedra, corners with six equivalent O(2)Gd3In trigonal pyramids, edges with two equivalent O(4)Gd3In tetrahedra, edges with two equivalent O(1)Gd4 tetrahedra, edges with two equivalent O(3)Gd4In trigonal bipyramids, and edges with two equivalent O(2)Gd3In trigonal pyramids. In the fourth O site, O(4) is bonded to one Gd(2), two equivalent Gd(1), and one In(1) atom to form OGd3In tetrahedra that share corners with eight equivalent O(1)Gd4 tetrahedra,  a cornercorner with one O(3)Gd4In trigonal bipyramid, corners with four equivalent O(2)Gd3In trigonal pyramids, edges with two equivalent O(3)Gd4In trigonal bipyramids, and edges with two equivalent O(2)Gd3In trigonal pyramids. is represented by the CIF file [CIF]
data_Gd3InO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.307
_cell_length_b   7.307
_cell_length_c   5.679
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   103.003
_symmetry_Int_Tables_number   1
_cell_volume   295.435
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Gd  Gd0  1  0.090  0.300  0.469  1.0
  Gd  Gd1  1  0.300  0.090  0.969  1.0
  Gd  Gd2  1  0.601  0.399  0.420  1.0
  Gd  Gd3  1  0.399  0.601  0.920  1.0
  Gd  Gd4  1  0.700  0.910  0.469  1.0
  Gd  Gd5  1  0.910  0.700  0.969  1.0
  In  In6  1  0.810  0.190  0.986  1.0
  In  In7  1  0.190  0.810  0.486  1.0
  O  O8  1  0.323  0.357  0.196  1.0
  O  O9  1  0.357  0.323  0.696  1.0
  O  O10  1  0.567  0.102  0.191  1.0
  O  O11  1  0.102  0.567  0.691  1.0
  O  O12  1  0.972  0.028  0.159  1.0
  O  O13  1  0.781  0.219  0.630  1.0
  O  O14  1  0.219  0.781  0.130  1.0
  O  O15  1  0.028  0.972  0.659  1.0
  O  O16  1  0.898  0.433  0.191  1.0
  O  O17  1  0.433  0.898  0.691  1.0
  O  O18  1  0.677  0.643  0.696  1.0
  O  O19  1  0.643  0.677  0.196  1.0
[/CIF]
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The material described by Gd3InO6 crystallizes in the orthorhombic Cmc2_1 space group. There are two inequivalent Gd sites. In the first Gd site, Gd(1) is bonded in a 7-coordinate geometry to one O(4), two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. In the second Gd site, Gd(2) is bonded to one O(4), two equivalent O(2), and four equivalent O(1) atoms to form distorted edge-sharing GdO7 pentagonal bipyramids. In(1) is bonded in a rectangular see-saw-like geometry to one O(3), one O(4), and two equivalent O(2) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Gd(1) and two equivalent Gd(2) atoms to form OGd4 tetrahedra that share corners with two equivalent O(1)Gd4 tetrahedra, corners with four equivalent O(4)Gd3In tetrahedra, corners with two equivalent O(3)Gd4In trigonal bipyramids, corners with six equivalent O(2)Gd3In trigonal pyramids, edges with three equivalent O(1)Gd4 tetrahedra,  an edgeedge with one O(3)Gd4In trigonal bipyramid, and  an edgeedge with one O(2)Gd3In trigonal pyramid. In the second O site, O(2) is bonded to one Gd(2), two equivalent Gd(1), and one In(1) atom to form distorted OGd3In trigonal pyramids that share corners with two equivalent O(4)Gd3In tetrahedra, corners with six equivalent O(1)Gd4 tetrahedra, corners with three equivalent O(3)Gd4In trigonal bipyramids, corners with two equivalent O(2)Gd3In trigonal pyramids,  an edgeedge with one O(4)Gd3In tetrahedra,  an edgeedge with one O(1)Gd4 tetrahedra,  an edgeedge with one O(3)Gd4In trigonal bipyramid, and  an edgeedge with one O(2)Gd3In trigonal pyramid. In the third O site, O(3) is bonded to four equivalent Gd(1) and one In(1) atom to form distorted OGd4In trigonal bipyramids that share  a cornercorner with one O(4)Gd3In tetrahedra, corners with four equivalent O(1)Gd4 tetrahedra, corners with six equivalent O(2)Gd3In trigonal pyramids, edges with two equivalent O(4)Gd3In tetrahedra, edges with two equivalent O(1)Gd4 tetrahedra, edges with two equivalent O(3)Gd4In trigonal bipyramids, and edges with two equivalent O(2)Gd3In trigonal pyramids. In the fourth O site, O(4) is bonded to one Gd(2), two equivalent Gd(1), and one In(1) atom to form OGd3In tetrahedra that share corners with eight equivalent O(1)Gd4 tetrahedra,  a cornercorner with one O(3)Gd4In trigonal bipyramid, corners with four equivalent O(2)Gd3In trigonal pyramids, edges with two equivalent O(3)Gd4In trigonal bipyramids, and edges with two equivalent O(2)Gd3In trigonal pyramids. is represented by the CIF file [CIF]
data_Gd3InO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.307
_cell_length_b   7.307
_cell_length_c   5.679
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   103.003
_symmetry_Int_Tables_number   1
_cell_volume   295.435
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Gd  Gd0  1  0.090  0.300  0.469  1.0
  Gd  Gd1  1  0.300  0.090  0.969  1.0
  Gd  Gd2  1  0.601  0.399  0.420  1.0
  Gd  Gd3  1  0.399  0.601  0.920  1.0
  Gd  Gd4  1  0.700  0.910  0.469  1.0
  Gd  Gd5  1  0.910  0.700  0.969  1.0
  In  In6  1  0.810  0.190  0.986  1.0
  In  In7  1  0.190  0.810  0.486  1.0
  O  O8  1  0.323  0.357  0.196  1.0
  O  O9  1  0.357  0.323  0.696  1.0
  O  O10  1  0.567  0.102  0.191  1.0
  O  O11  1  0.102  0.567  0.691  1.0
  O  O12  1  0.972  0.028  0.159  1.0
  O  O13  1  0.781  0.219  0.630  1.0
  O  O14  1  0.219  0.781  0.130  1.0
  O  O15  1  0.028  0.972  0.659  1.0
  O  O16  1  0.898  0.433  0.191  1.0
  O  O17  1  0.433  0.898  0.691  1.0
  O  O18  1  0.677  0.643  0.696  1.0
  O  O19  1  0.643  0.677  0.196  1.0
[/CIF]
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