The material structure described by Zn(AgO2)2 crystallizes in the orthorhombic Pbcm space group. Ag(1) is bonded in a 5-coordinate geometry to one O(3), two equivalent O(1), and two equivalent O(2) atoms. Zn(1) is bonded in a 6-coordinate geometry to two equivalent O(3) and four equivalent O(1) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to two equivalent Ag(1) and two equivalent Zn(1) atoms. In the second O site, O(2) is bonded in a distorted rectangular see-saw-like geometry to four equivalent Ag(1) atoms. In the third O site, O(3) is bonded to two equivalent Ag(1) and two equivalent Zn(1) atoms to form corner-sharing OZn2Ag2 tetrahedra. is represented by the CIF card [CIF]
data_Zn(AgO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.186
_cell_length_b   9.898
_cell_length_c   10.817
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   341.167
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.315  0.250  0.849  1.0
  Zn  Zn1  1  0.315  0.750  0.651  1.0
  Zn  Zn2  1  0.685  0.250  0.349  1.0
  Zn  Zn3  1  0.685  0.750  0.151  1.0
  Ag  Ag4  1  0.823  0.071  0.615  1.0
  Ag  Ag5  1  0.823  0.571  0.885  1.0
  Ag  Ag6  1  0.177  0.571  0.385  1.0
  Ag  Ag7  1  0.823  0.929  0.885  1.0
  Ag  Ag8  1  0.177  0.929  0.385  1.0
  Ag  Ag9  1  0.823  0.429  0.615  1.0
  Ag  Ag10  1  0.177  0.429  0.115  1.0
  Ag  Ag11  1  0.177  0.071  0.115  1.0
  O  O12  1  0.125  0.376  0.451  1.0
  O  O13  1  0.875  0.624  0.549  1.0
  O  O14  1  0.454  0.500  0.750  1.0
  O  O15  1  0.875  0.376  0.951  1.0
  O  O16  1  0.875  0.124  0.951  1.0
  O  O17  1  0.803  0.750  0.785  1.0
  O  O18  1  0.125  0.624  0.049  1.0
  O  O19  1  0.197  0.750  0.285  1.0
  O  O20  1  0.454  0.000  0.750  1.0
  O  O21  1  0.546  0.500  0.250  1.0
  O  O22  1  0.125  0.124  0.451  1.0
  O  O23  1  0.197  0.250  0.215  1.0
  O  O24  1  0.803  0.250  0.715  1.0
  O  O25  1  0.546  0.000  0.250  1.0
  O  O26  1  0.125  0.876  0.049  1.0
  O  O27  1  0.875  0.876  0.549  1.0
[/CIF]
.
The material structure described by Zn(AgO2)2 crystallizes in the orthorhombic Pbcm space group. Ag(1) is bonded in a 5-coordinate geometry to one O(3), two equivalent O(1), and two equivalent O(2) atoms. Zn(1) is bonded in a 6-coordinate geometry to two equivalent O(3) and four equivalent O(1) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to two equivalent Ag(1) and two equivalent Zn(1) atoms. In the second O site, O(2) is bonded in a distorted rectangular see-saw-like geometry to four equivalent Ag(1) atoms. In the third O site, O(3) is bonded to two equivalent Ag(1) and two equivalent Zn(1) atoms to form corner-sharing OZn2Ag2 tetrahedra. is represented by the CIF card [CIF]
data_Zn(AgO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.186
_cell_length_b   9.898
_cell_length_c   10.817
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   341.167
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.315  0.250  0.849  1.0
  Zn  Zn1  1  0.315  0.750  0.651  1.0
  Zn  Zn2  1  0.685  0.250  0.349  1.0
  Zn  Zn3  1  0.685  0.750  0.151  1.0
  Ag  Ag4  1  0.823  0.071  0.615  1.0
  Ag  Ag5  1  0.823  0.571  0.885  1.0
  Ag  Ag6  1  0.177  0.571  0.385  1.0
  Ag  Ag7  1  0.823  0.929  0.885  1.0
  Ag  Ag8  1  0.177  0.929  0.385  1.0
  Ag  Ag9  1  0.823  0.429  0.615  1.0
  Ag  Ag10  1  0.177  0.429  0.115  1.0
  Ag  Ag11  1  0.177  0.071  0.115  1.0
  O  O12  1  0.125  0.376  0.451  1.0
  O  O13  1  0.875  0.624  0.549  1.0
  O  O14  1  0.454  0.500  0.750  1.0
  O  O15  1  0.875  0.376  0.951  1.0
  O  O16  1  0.875  0.124  0.951  1.0
  O  O17  1  0.803  0.750  0.785  1.0
  O  O18  1  0.125  0.624  0.049  1.0
  O  O19  1  0.197  0.750  0.285  1.0
  O  O20  1  0.454  0.000  0.750  1.0
  O  O21  1  0.546  0.500  0.250  1.0
  O  O22  1  0.125  0.124  0.451  1.0
  O  O23  1  0.197  0.250  0.215  1.0
  O  O24  1  0.803  0.250  0.715  1.0
  O  O25  1  0.546  0.000  0.250  1.0
  O  O26  1  0.125  0.876  0.049  1.0
  O  O27  1  0.875  0.876  0.549  1.0
[/CIF]
.