The material structure described by PtCl6(IrN5Cl2)2 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four IrN5Cl2 clusters and two PtCl6 clusters. In each IrN5Cl2 cluster, Ir(1) is bonded in a 6-coordinate geometry to one N(3), two equivalent N(1), two equivalent N(2), and one Cl(5) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in an L-shaped geometry to one Ir(1) and one Cl(4) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Ir(1) atom. In the third N site, N(3) is bonded in a single-bond geometry to one Ir(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(4) is bonded in a bent 120 degrees geometry to two equivalent N(1) atoms. In the second Cl site, Cl(5) is bonded in a single-bond geometry to one Ir(1) atom. In each PtCl6 cluster, Pt(1) is bonded in an octahedral geometry to two equivalent Cl(3) and four equivalent Cl(1,2) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(1,2) is bonded in a single-bond geometry to one Pt(1) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one Pt(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ir2Pt(NCl)10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.395
_cell_length_b   7.395
_cell_length_c   11.186
_cell_angle_alpha   77.219
_cell_angle_beta   77.219
_cell_angle_gamma   68.791
_symmetry_Int_Tables_number   1
_cell_volume   549.469
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ir  Ir0  1  0.171  0.171  0.235  1.0
  Ir  Ir1  1  0.829  0.829  0.765  1.0
  Pt  Pt2  1  0.500  0.500  0.500  1.0
  N  N3  1  0.998  0.307  0.071  1.0
  N  N4  1  0.307  0.998  0.071  1.0
  N  N5  1  0.002  0.693  0.929  1.0
  N  N6  1  0.693  0.002  0.929  1.0
  N  N7  1  0.036  0.380  0.314  1.0
  N  N8  1  0.380  0.036  0.314  1.0
  N  N9  1  0.964  0.620  0.686  1.0
  N  N10  1  0.620  0.964  0.686  1.0
  N  N11  1  0.018  0.018  0.289  1.0
  N  N12  1  0.982  0.982  0.711  1.0
  Cl  Cl13  1  0.578  0.578  0.284  1.0
  Cl  Cl14  1  0.422  0.422  0.716  1.0
  Cl  Cl15  1  0.684  0.684  0.526  1.0
  Cl  Cl16  1  0.316  0.316  0.474  1.0
  Cl  Cl17  1  0.779  0.221  0.500  1.0
  Cl  Cl18  1  0.221  0.779  0.500  1.0
  Cl  Cl19  1  0.853  0.853  0.003  1.0
  Cl  Cl20  1  0.147  0.147  0.997  1.0
  Cl  Cl21  1  0.369  0.369  0.111  1.0
  Cl  Cl22  1  0.631  0.631  0.889  1.0
[/CIF]
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The material structure described by PtCl6(IrN5Cl2)2 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four IrN5Cl2 clusters and two PtCl6 clusters. In each IrN5Cl2 cluster, Ir(1) is bonded in a 6-coordinate geometry to one N(3), two equivalent N(1), two equivalent N(2), and one Cl(5) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in an L-shaped geometry to one Ir(1) and one Cl(4) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Ir(1) atom. In the third N site, N(3) is bonded in a single-bond geometry to one Ir(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(4) is bonded in a bent 120 degrees geometry to two equivalent N(1) atoms. In the second Cl site, Cl(5) is bonded in a single-bond geometry to one Ir(1) atom. In each PtCl6 cluster, Pt(1) is bonded in an octahedral geometry to two equivalent Cl(3) and four equivalent Cl(1,2) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(1,2) is bonded in a single-bond geometry to one Pt(1) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one Pt(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ir2Pt(NCl)10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.395
_cell_length_b   7.395
_cell_length_c   11.186
_cell_angle_alpha   77.219
_cell_angle_beta   77.219
_cell_angle_gamma   68.791
_symmetry_Int_Tables_number   1
_cell_volume   549.469
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ir  Ir0  1  0.171  0.171  0.235  1.0
  Ir  Ir1  1  0.829  0.829  0.765  1.0
  Pt  Pt2  1  0.500  0.500  0.500  1.0
  N  N3  1  0.998  0.307  0.071  1.0
  N  N4  1  0.307  0.998  0.071  1.0
  N  N5  1  0.002  0.693  0.929  1.0
  N  N6  1  0.693  0.002  0.929  1.0
  N  N7  1  0.036  0.380  0.314  1.0
  N  N8  1  0.380  0.036  0.314  1.0
  N  N9  1  0.964  0.620  0.686  1.0
  N  N10  1  0.620  0.964  0.686  1.0
  N  N11  1  0.018  0.018  0.289  1.0
  N  N12  1  0.982  0.982  0.711  1.0
  Cl  Cl13  1  0.578  0.578  0.284  1.0
  Cl  Cl14  1  0.422  0.422  0.716  1.0
  Cl  Cl15  1  0.684  0.684  0.526  1.0
  Cl  Cl16  1  0.316  0.316  0.474  1.0
  Cl  Cl17  1  0.779  0.221  0.500  1.0
  Cl  Cl18  1  0.221  0.779  0.500  1.0
  Cl  Cl19  1  0.853  0.853  0.003  1.0
  Cl  Cl20  1  0.147  0.147  0.997  1.0
  Cl  Cl21  1  0.369  0.369  0.111  1.0
  Cl  Cl22  1  0.631  0.631  0.889  1.0
[/CIF]
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