The compound described by Rb2MnP2H3(O4F)2 crystallizes in the monoclinic P2_1 space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 5-coordinate geometry to one O(3), one O(5), one F(1), and two equivalent F(2) atoms. In the second Rb site, Rb(2) is bonded in a 5-coordinate geometry to one O(4), one O(6), one F(2), and two equivalent F(1) atoms. Mn(1) is bonded to one O(3), one O(4), one O(7), one O(8), one F(1), and one F(2) atom to form MnO4F2 octahedra that share corners with two equivalent P(1)O4 tetrahedra and corners with two equivalent P(2)O4 tetrahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(4), one O(5), and one O(7) atom to form PO4 tetrahedra that share corners with two equivalent Mn(1)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 47-48°. In the second P site, P(2) is bonded to one O(2), one O(3), one O(6), and one O(8) atom to form PO4 tetrahedra that share corners with two equivalent Mn(1)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 47-48°. There are three inequivalent H sites. In the first H site, H(1) is bonded in a distorted linear geometry to one O(1) and one O(8) atom. In the second H site, H(2) is bonded in a distorted single-bond geometry to one O(2) and one O(7) atom. In the third H site, H(3) is bonded in a linear geometry to one O(5) and one O(6) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one P(1) and one H(1) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one P(2) and one H(2) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Rb(1), one Mn(1), and one P(2) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to one Rb(2), one Mn(1), and one P(1) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Rb(1), one P(1), and one H(3) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Rb(2), one P(2), and one H(3) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Mn(1), one P(1), and one H(2) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Mn(1), one P(2), and one H(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to one Rb(1), two equivalent Rb(2), and one Mn(1) atom. In the second F site, F(2) is bonded in a distorted single-bond geometry to one Rb(2), two equivalent Rb(1), and one Mn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Rb2MnP2H3(O4F)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.106
_cell_length_b   7.525
_cell_length_c   8.644
_cell_angle_alpha   65.098
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   478.205
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.666  0.863  0.440  1.0
  Rb  Rb1  1  0.166  0.137  0.560  1.0
  Rb  Rb2  1  0.338  0.131  0.055  1.0
  Rb  Rb3  1  0.838  0.869  0.945  1.0
  Mn  Mn4  1  0.498  0.499  0.253  1.0
  Mn  Mn5  1  0.998  0.501  0.747  1.0
  P  P6  1  0.861  0.325  0.133  1.0
  P  P7  1  0.361  0.675  0.867  1.0
  P  P8  1  0.133  0.688  0.360  1.0
  P  P9  1  0.633  0.312  0.640  1.0
  H  H10  1  0.715  0.287  0.938  1.0
  H  H11  1  0.215  0.713  0.062  1.0
  H  H12  1  0.288  0.711  0.556  1.0
  H  H13  1  0.788  0.289  0.444  1.0
  H  H14  1  0.998  0.026  0.249  1.0
  H  H15  1  0.498  0.974  0.751  1.0
  O  O16  1  0.735  0.209  0.068  1.0
  O  O17  1  0.235  0.791  0.932  1.0
  O  O18  1  0.265  0.795  0.431  1.0
  O  O19  1  0.765  0.205  0.569  1.0
  O  O20  1  0.548  0.475  0.483  1.0
  O  O21  1  0.048  0.525  0.517  1.0
  O  O22  1  0.451  0.519  0.023  1.0
  O  O23  1  0.951  0.481  0.977  1.0
  O  O24  1  0.982  0.167  0.257  1.0
  O  O25  1  0.482  0.833  0.743  1.0
  O  O26  1  0.016  0.849  0.245  1.0
  O  O27  1  0.516  0.151  0.755  1.0
  O  O28  1  0.775  0.422  0.235  1.0
  O  O29  1  0.275  0.578  0.765  1.0
  O  O30  1  0.223  0.593  0.257  1.0
  O  O31  1  0.723  0.407  0.743  1.0
  F  F32  1  0.553  0.767  0.166  1.0
  F  F33  1  0.053  0.233  0.834  1.0
  F  F34  1  0.444  0.232  0.337  1.0
  F  F35  1  0.944  0.768  0.663  1.0
[/CIF]
.
The compound described by Rb2MnP2H3(O4F)2 crystallizes in the monoclinic P2_1 space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 5-coordinate geometry to one O(3), one O(5), one F(1), and two equivalent F(2) atoms. In the second Rb site, Rb(2) is bonded in a 5-coordinate geometry to one O(4), one O(6), one F(2), and two equivalent F(1) atoms. Mn(1) is bonded to one O(3), one O(4), one O(7), one O(8), one F(1), and one F(2) atom to form MnO4F2 octahedra that share corners with two equivalent P(1)O4 tetrahedra and corners with two equivalent P(2)O4 tetrahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(4), one O(5), and one O(7) atom to form PO4 tetrahedra that share corners with two equivalent Mn(1)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 47-48°. In the second P site, P(2) is bonded to one O(2), one O(3), one O(6), and one O(8) atom to form PO4 tetrahedra that share corners with two equivalent Mn(1)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 47-48°. There are three inequivalent H sites. In the first H site, H(1) is bonded in a distorted linear geometry to one O(1) and one O(8) atom. In the second H site, H(2) is bonded in a distorted single-bond geometry to one O(2) and one O(7) atom. In the third H site, H(3) is bonded in a linear geometry to one O(5) and one O(6) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one P(1) and one H(1) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one P(2) and one H(2) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Rb(1), one Mn(1), and one P(2) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to one Rb(2), one Mn(1), and one P(1) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Rb(1), one P(1), and one H(3) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Rb(2), one P(2), and one H(3) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Mn(1), one P(1), and one H(2) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Mn(1), one P(2), and one H(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to one Rb(1), two equivalent Rb(2), and one Mn(1) atom. In the second F site, F(2) is bonded in a distorted single-bond geometry to one Rb(2), two equivalent Rb(1), and one Mn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Rb2MnP2H3(O4F)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.106
_cell_length_b   7.525
_cell_length_c   8.644
_cell_angle_alpha   65.098
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   478.205
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.666  0.863  0.440  1.0
  Rb  Rb1  1  0.166  0.137  0.560  1.0
  Rb  Rb2  1  0.338  0.131  0.055  1.0
  Rb  Rb3  1  0.838  0.869  0.945  1.0
  Mn  Mn4  1  0.498  0.499  0.253  1.0
  Mn  Mn5  1  0.998  0.501  0.747  1.0
  P  P6  1  0.861  0.325  0.133  1.0
  P  P7  1  0.361  0.675  0.867  1.0
  P  P8  1  0.133  0.688  0.360  1.0
  P  P9  1  0.633  0.312  0.640  1.0
  H  H10  1  0.715  0.287  0.938  1.0
  H  H11  1  0.215  0.713  0.062  1.0
  H  H12  1  0.288  0.711  0.556  1.0
  H  H13  1  0.788  0.289  0.444  1.0
  H  H14  1  0.998  0.026  0.249  1.0
  H  H15  1  0.498  0.974  0.751  1.0
  O  O16  1  0.735  0.209  0.068  1.0
  O  O17  1  0.235  0.791  0.932  1.0
  O  O18  1  0.265  0.795  0.431  1.0
  O  O19  1  0.765  0.205  0.569  1.0
  O  O20  1  0.548  0.475  0.483  1.0
  O  O21  1  0.048  0.525  0.517  1.0
  O  O22  1  0.451  0.519  0.023  1.0
  O  O23  1  0.951  0.481  0.977  1.0
  O  O24  1  0.982  0.167  0.257  1.0
  O  O25  1  0.482  0.833  0.743  1.0
  O  O26  1  0.016  0.849  0.245  1.0
  O  O27  1  0.516  0.151  0.755  1.0
  O  O28  1  0.775  0.422  0.235  1.0
  O  O29  1  0.275  0.578  0.765  1.0
  O  O30  1  0.223  0.593  0.257  1.0
  O  O31  1  0.723  0.407  0.743  1.0
  F  F32  1  0.553  0.767  0.166  1.0
  F  F33  1  0.053  0.233  0.834  1.0
  F  F34  1  0.444  0.232  0.337  1.0
  F  F35  1  0.944  0.768  0.663  1.0
[/CIF]
.