The crystal structure described by Zn(NH3)(CO3) crystallizes in the orthorhombic Pna2_1 space group. Zn(1) is bonded in a tetrahedral geometry to one N(1), one O(1), one O(2), and one O(3) atom. C(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. N(1) is bonded in a distorted tetrahedral geometry to one Zn(1), one H(1), one H(2), and one H(3) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. There are three inequivalent O sites. In the first O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the third O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. is represented by the CIF card [CIF]
data_ZnH3CNO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.354
_cell_length_b   5.324
_cell_length_c   7.494
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   373.210
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.647  0.258  0.325  1.0
  Zn  Zn1  1  0.353  0.758  0.675  1.0
  Zn  Zn2  1  0.853  0.758  0.825  1.0
  Zn  Zn3  1  0.147  0.258  0.175  1.0
  H  H4  1  0.888  0.051  0.546  1.0
  H  H5  1  0.112  0.551  0.454  1.0
  H  H6  1  0.612  0.551  0.046  1.0
  H  H7  1  0.388  0.051  0.954  1.0
  H  H8  1  0.038  0.958  0.641  1.0
  H  H9  1  0.962  0.458  0.359  1.0
  H  H10  1  0.462  0.458  0.141  1.0
  H  H11  1  0.538  0.958  0.859  1.0
  H  H12  1  0.940  0.184  0.733  1.0
  H  H13  1  0.060  0.684  0.267  1.0
  H  H14  1  0.560  0.684  0.233  1.0
  H  H15  1  0.440  0.184  0.767  1.0
  C  C16  1  0.881  0.017  0.148  1.0
  C  C17  1  0.119  0.517  0.852  1.0
  C  C18  1  0.619  0.517  0.648  1.0
  C  C19  1  0.381  0.017  0.352  1.0
  N  N20  1  0.936  0.017  0.666  1.0
  N  N21  1  0.064  0.517  0.334  1.0
  N  N22  1  0.564  0.517  0.166  1.0
  N  N23  1  0.436  0.017  0.834  1.0
  O  O24  1  0.515  0.987  0.386  1.0
  O  O25  1  0.485  0.487  0.614  1.0
  O  O26  1  0.985  0.487  0.886  1.0
  O  O27  1  0.015  0.987  0.114  1.0
  O  O28  1  0.843  0.141  0.288  1.0
  O  O29  1  0.157  0.641  0.712  1.0
  O  O30  1  0.657  0.641  0.788  1.0
  O  O31  1  0.343  0.141  0.212  1.0
  O  O32  1  0.714  0.421  0.547  1.0
  O  O33  1  0.286  0.921  0.453  1.0
  O  O34  1  0.786  0.921  0.047  1.0
  O  O35  1  0.214  0.421  0.953  1.0
[/CIF]
.
The crystal structure described by Zn(NH3)(CO3) crystallizes in the orthorhombic Pna2_1 space group. Zn(1) is bonded in a tetrahedral geometry to one N(1), one O(1), one O(2), and one O(3) atom. C(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. N(1) is bonded in a distorted tetrahedral geometry to one Zn(1), one H(1), one H(2), and one H(3) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. There are three inequivalent O sites. In the first O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the third O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. is represented by the CIF card [CIF]
data_ZnH3CNO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.354
_cell_length_b   5.324
_cell_length_c   7.494
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   373.210
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.647  0.258  0.325  1.0
  Zn  Zn1  1  0.353  0.758  0.675  1.0
  Zn  Zn2  1  0.853  0.758  0.825  1.0
  Zn  Zn3  1  0.147  0.258  0.175  1.0
  H  H4  1  0.888  0.051  0.546  1.0
  H  H5  1  0.112  0.551  0.454  1.0
  H  H6  1  0.612  0.551  0.046  1.0
  H  H7  1  0.388  0.051  0.954  1.0
  H  H8  1  0.038  0.958  0.641  1.0
  H  H9  1  0.962  0.458  0.359  1.0
  H  H10  1  0.462  0.458  0.141  1.0
  H  H11  1  0.538  0.958  0.859  1.0
  H  H12  1  0.940  0.184  0.733  1.0
  H  H13  1  0.060  0.684  0.267  1.0
  H  H14  1  0.560  0.684  0.233  1.0
  H  H15  1  0.440  0.184  0.767  1.0
  C  C16  1  0.881  0.017  0.148  1.0
  C  C17  1  0.119  0.517  0.852  1.0
  C  C18  1  0.619  0.517  0.648  1.0
  C  C19  1  0.381  0.017  0.352  1.0
  N  N20  1  0.936  0.017  0.666  1.0
  N  N21  1  0.064  0.517  0.334  1.0
  N  N22  1  0.564  0.517  0.166  1.0
  N  N23  1  0.436  0.017  0.834  1.0
  O  O24  1  0.515  0.987  0.386  1.0
  O  O25  1  0.485  0.487  0.614  1.0
  O  O26  1  0.985  0.487  0.886  1.0
  O  O27  1  0.015  0.987  0.114  1.0
  O  O28  1  0.843  0.141  0.288  1.0
  O  O29  1  0.157  0.641  0.712  1.0
  O  O30  1  0.657  0.641  0.788  1.0
  O  O31  1  0.343  0.141  0.212  1.0
  O  O32  1  0.714  0.421  0.547  1.0
  O  O33  1  0.286  0.921  0.453  1.0
  O  O34  1  0.786  0.921  0.047  1.0
  O  O35  1  0.214  0.421  0.953  1.0
[/CIF]
.