The crystal structure described by Na4CO4 crystallizes in the tetragonal I-42m space group. Na(1) is bonded in a 5-coordinate geometry to five equivalent O(1) atoms. C(1) is bonded in a tetrahedral geometry to four equivalent O(1) atoms. O(1) is bonded in a distorted single-bond geometry to five equivalent Na(1) and one C(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Na4CO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.705
_cell_length_b   5.705
_cell_length_c   5.705
_cell_angle_alpha   99.840
_cell_angle_beta   99.840
_cell_angle_gamma   131.162
_symmetry_Int_Tables_number   1
_cell_volume   127.312
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.676  0.676  0.653  1.0
  Na  Na1  1  0.324  0.977  0.000  1.0
  Na  Na2  1  0.023  0.023  0.347  1.0
  Na  Na3  1  0.977  0.324  0.000  1.0
  C  C4  1  0.500  0.500  0.000  1.0
  O  O5  1  0.784  0.559  0.000  1.0
  O  O6  1  0.216  0.216  0.775  1.0
  O  O7  1  0.559  0.784  0.000  1.0
  O  O8  1  0.441  0.441  0.225  1.0
[/CIF]
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The crystal structure described by Na4CO4 crystallizes in the tetragonal I-42m space group. Na(1) is bonded in a 5-coordinate geometry to five equivalent O(1) atoms. C(1) is bonded in a tetrahedral geometry to four equivalent O(1) atoms. O(1) is bonded in a distorted single-bond geometry to five equivalent Na(1) and one C(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Na4CO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.705
_cell_length_b   5.705
_cell_length_c   5.705
_cell_angle_alpha   99.840
_cell_angle_beta   99.840
_cell_angle_gamma   131.162
_symmetry_Int_Tables_number   1
_cell_volume   127.312
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.676  0.676  0.653  1.0
  Na  Na1  1  0.324  0.977  0.000  1.0
  Na  Na2  1  0.023  0.023  0.347  1.0
  Na  Na3  1  0.977  0.324  0.000  1.0
  C  C4  1  0.500  0.500  0.000  1.0
  O  O5  1  0.784  0.559  0.000  1.0
  O  O6  1  0.216  0.216  0.775  1.0
  O  O7  1  0.559  0.784  0.000  1.0
  O  O8  1  0.441  0.441  0.225  1.0
[/CIF]
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