The compound described by P2S3 is black P structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four P2S3 clusters. There are four inequivalent P sites. In the first P site, P(1) is bonded in a tetrahedral geometry to one S(1), one S(2), one S(3), and one S(4) atom. In the second P site, P(2) is bonded in a distorted water-like geometry to one P(3), one S(2), and one S(5) atom. In the third P site, P(3) is bonded in a distorted water-like geometry to one P(2), one S(3), and one S(6) atom. In the fourth P site, P(4) is bonded in a trigonal non-coplanar geometry to one S(1), one S(5), and one S(6) atom. There are six inequivalent S sites. In the first S site, S(5) is bonded in a water-like geometry to one P(2) and one P(4) atom. In the second S site, S(6) is bonded in a water-like geometry to one P(3) and one P(4) atom. In the third S site, S(1) is bonded in a bent 120 degrees geometry to one P(1) and one P(4) atom. In the fourth S site, S(2) is bonded in a water-like geometry to one P(1) and one P(2) atom. In the fifth S site, S(3) is bonded in a water-like geometry to one P(1) and one P(3) atom. In the sixth S site, S(4) is bonded in a single-bond geometry to one P(1) atom. is represented by the CIF card [CIF]
data_P2S3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.164
_cell_length_b   11.831
_cell_length_c   12.468
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   102.958
_symmetry_Int_Tables_number   1
_cell_volume   1029.753
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.279  0.164  0.916  1.0
  P  P1  1  0.721  0.336  0.416  1.0
  P  P2  1  0.721  0.836  0.084  1.0
  P  P3  1  0.279  0.664  0.584  1.0
  P  P4  1  0.262  0.439  0.937  1.0
  P  P5  1  0.738  0.061  0.437  1.0
  P  P6  1  0.738  0.561  0.063  1.0
  P  P7  1  0.262  0.939  0.563  1.0
  P  P8  1  0.229  0.349  0.104  1.0
  P  P9  1  0.771  0.151  0.604  1.0
  P  P10  1  0.771  0.651  0.896  1.0
  P  P11  1  0.229  0.849  0.396  1.0
  P  P12  1  0.838  0.245  0.953  1.0
  P  P13  1  0.162  0.255  0.453  1.0
  P  P14  1  0.162  0.755  0.047  1.0
  P  P15  1  0.838  0.745  0.547  1.0
  S  S16  1  0.983  0.117  0.894  1.0
  S  S17  1  0.017  0.383  0.394  1.0
  S  S18  1  0.017  0.883  0.106  1.0
  S  S19  1  0.983  0.617  0.606  1.0
  S  S20  1  0.393  0.327  0.847  1.0
  S  S21  1  0.607  0.173  0.347  1.0
  S  S22  1  0.607  0.673  0.153  1.0
  S  S23  1  0.393  0.827  0.653  1.0
  S  S24  1  0.346  0.202  0.078  1.0
  S  S25  1  0.654  0.298  0.578  1.0
  S  S26  1  0.654  0.798  0.922  1.0
  S  S27  1  0.346  0.702  0.422  1.0
  S  S28  1  0.385  0.042  0.857  1.0
  S  S29  1  0.615  0.458  0.357  1.0
  S  S30  1  0.615  0.958  0.143  1.0
  S  S31  1  0.385  0.542  0.643  1.0
  S  S32  1  0.975  0.402  0.880  1.0
  S  S33  1  0.025  0.098  0.380  1.0
  S  S34  1  0.025  0.598  0.120  1.0
  S  S35  1  0.975  0.902  0.620  1.0
  S  S36  1  0.931  0.282  0.112  1.0
  S  S37  1  0.069  0.218  0.612  1.0
  S  S38  1  0.069  0.718  0.888  1.0
  S  S39  1  0.931  0.782  0.388  1.0
[/CIF]
.
The compound described by P2S3 is black P structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four P2S3 clusters. There are four inequivalent P sites. In the first P site, P(1) is bonded in a tetrahedral geometry to one S(1), one S(2), one S(3), and one S(4) atom. In the second P site, P(2) is bonded in a distorted water-like geometry to one P(3), one S(2), and one S(5) atom. In the third P site, P(3) is bonded in a distorted water-like geometry to one P(2), one S(3), and one S(6) atom. In the fourth P site, P(4) is bonded in a trigonal non-coplanar geometry to one S(1), one S(5), and one S(6) atom. There are six inequivalent S sites. In the first S site, S(5) is bonded in a water-like geometry to one P(2) and one P(4) atom. In the second S site, S(6) is bonded in a water-like geometry to one P(3) and one P(4) atom. In the third S site, S(1) is bonded in a bent 120 degrees geometry to one P(1) and one P(4) atom. In the fourth S site, S(2) is bonded in a water-like geometry to one P(1) and one P(2) atom. In the fifth S site, S(3) is bonded in a water-like geometry to one P(1) and one P(3) atom. In the sixth S site, S(4) is bonded in a single-bond geometry to one P(1) atom. is represented by the CIF card [CIF]
data_P2S3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.164
_cell_length_b   11.831
_cell_length_c   12.468
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   102.958
_symmetry_Int_Tables_number   1
_cell_volume   1029.753
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.279  0.164  0.916  1.0
  P  P1  1  0.721  0.336  0.416  1.0
  P  P2  1  0.721  0.836  0.084  1.0
  P  P3  1  0.279  0.664  0.584  1.0
  P  P4  1  0.262  0.439  0.937  1.0
  P  P5  1  0.738  0.061  0.437  1.0
  P  P6  1  0.738  0.561  0.063  1.0
  P  P7  1  0.262  0.939  0.563  1.0
  P  P8  1  0.229  0.349  0.104  1.0
  P  P9  1  0.771  0.151  0.604  1.0
  P  P10  1  0.771  0.651  0.896  1.0
  P  P11  1  0.229  0.849  0.396  1.0
  P  P12  1  0.838  0.245  0.953  1.0
  P  P13  1  0.162  0.255  0.453  1.0
  P  P14  1  0.162  0.755  0.047  1.0
  P  P15  1  0.838  0.745  0.547  1.0
  S  S16  1  0.983  0.117  0.894  1.0
  S  S17  1  0.017  0.383  0.394  1.0
  S  S18  1  0.017  0.883  0.106  1.0
  S  S19  1  0.983  0.617  0.606  1.0
  S  S20  1  0.393  0.327  0.847  1.0
  S  S21  1  0.607  0.173  0.347  1.0
  S  S22  1  0.607  0.673  0.153  1.0
  S  S23  1  0.393  0.827  0.653  1.0
  S  S24  1  0.346  0.202  0.078  1.0
  S  S25  1  0.654  0.298  0.578  1.0
  S  S26  1  0.654  0.798  0.922  1.0
  S  S27  1  0.346  0.702  0.422  1.0
  S  S28  1  0.385  0.042  0.857  1.0
  S  S29  1  0.615  0.458  0.357  1.0
  S  S30  1  0.615  0.958  0.143  1.0
  S  S31  1  0.385  0.542  0.643  1.0
  S  S32  1  0.975  0.402  0.880  1.0
  S  S33  1  0.025  0.098  0.380  1.0
  S  S34  1  0.025  0.598  0.120  1.0
  S  S35  1  0.975  0.902  0.620  1.0
  S  S36  1  0.931  0.282  0.112  1.0
  S  S37  1  0.069  0.218  0.612  1.0
  S  S38  1  0.069  0.718  0.888  1.0
  S  S39  1  0.931  0.782  0.388  1.0
[/CIF]
.