The structure described by Sr2CoWO6 is Orthorhombic Perovskite-derived structured and crystallizes in the monoclinic P2_1/c space group. Sr(1) is bonded in a 12-coordinate geometry to four equivalent O(1), four equivalent O(2), and four equivalent O(3) atoms. W(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form WO6 octahedra that share corners with six equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-20°. Co(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form CoO6 octahedra that share corners with six equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-20°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to four equivalent Sr(1), one W(1), and one Co(1) atom. In the second O site, O(2) is bonded in a 6-coordinate geometry to four equivalent Sr(1), one W(1), and one Co(1) atom. In the third O site, O(3) is bonded in a 6-coordinate geometry to four equivalent Sr(1), one W(1), and one Co(1) atom. is represented by the CIF card [CIF]
data_Sr2CoWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.667
_cell_length_b   5.673
_cell_length_c   5.673
_cell_angle_alpha   60.064
_cell_angle_beta   89.376
_cell_angle_gamma   119.383
_symmetry_Int_Tables_number   1
_cell_volume   129.591
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.000  0.500  0.500  1.0
  O  O1  1  0.318  0.560  0.242  1.0
  O  O2  1  0.230  0.503  0.790  1.0
  O  O3  1  0.770  0.497  0.210  1.0
  O  O4  1  0.770  0.980  0.727  1.0
  O  O5  1  0.230  0.020  0.273  1.0
  O  O6  1  0.682  0.440  0.758  1.0
  Sr  Sr7  1  0.245  0.996  0.751  1.0
  Sr  Sr8  1  0.755  0.004  0.249  1.0
  W  W9  1  0.500  0.500  0.000  1.0
[/CIF]
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The structure described by Sr2CoWO6 is Orthorhombic Perovskite-derived structured and crystallizes in the monoclinic P2_1/c space group. Sr(1) is bonded in a 12-coordinate geometry to four equivalent O(1), four equivalent O(2), and four equivalent O(3) atoms. W(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form WO6 octahedra that share corners with six equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-20°. Co(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form CoO6 octahedra that share corners with six equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-20°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to four equivalent Sr(1), one W(1), and one Co(1) atom. In the second O site, O(2) is bonded in a 6-coordinate geometry to four equivalent Sr(1), one W(1), and one Co(1) atom. In the third O site, O(3) is bonded in a 6-coordinate geometry to four equivalent Sr(1), one W(1), and one Co(1) atom. is represented by the CIF card [CIF]
data_Sr2CoWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.667
_cell_length_b   5.673
_cell_length_c   5.673
_cell_angle_alpha   60.064
_cell_angle_beta   89.376
_cell_angle_gamma   119.383
_symmetry_Int_Tables_number   1
_cell_volume   129.591
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.000  0.500  0.500  1.0
  O  O1  1  0.318  0.560  0.242  1.0
  O  O2  1  0.230  0.503  0.790  1.0
  O  O3  1  0.770  0.497  0.210  1.0
  O  O4  1  0.770  0.980  0.727  1.0
  O  O5  1  0.230  0.020  0.273  1.0
  O  O6  1  0.682  0.440  0.758  1.0
  Sr  Sr7  1  0.245  0.996  0.751  1.0
  Sr  Sr8  1  0.755  0.004  0.249  1.0
  W  W9  1  0.500  0.500  0.000  1.0
[/CIF]
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