The crystal structure described by VMnSb crystallizes in the hexagonal P6_3/mmc space group. V(1) is bonded in a 14-coordinate geometry to two equivalent V(1), six equivalent Mn(1), and six equivalent Sb(1) atoms. Mn(1) is bonded to six equivalent V(1) and five equivalent Sb(1) atoms to form a mixture of distorted corner and face-sharing MnV6Sb5 trigonal bipyramids. Sb(1) is bonded in a 11-coordinate geometry to six equivalent V(1) and five equivalent Mn(1) atoms. is represented by the CIF card [CIF]
data_MnVSb
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.469
_cell_length_b   4.469
_cell_length_c   5.410
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   93.578
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.333  0.667  0.250  1.0
  Mn  Mn1  1  0.667  0.333  0.750  1.0
  V  V2  1  0.000  0.000  0.000  1.0
  V  V3  1  0.000  0.000  0.500  1.0
  Sb  Sb4  1  0.333  0.667  0.750  1.0
  Sb  Sb5  1  0.667  0.333  0.250  1.0
[/CIF]
.
The crystal structure described by VMnSb crystallizes in the hexagonal P6_3/mmc space group. V(1) is bonded in a 14-coordinate geometry to two equivalent V(1), six equivalent Mn(1), and six equivalent Sb(1) atoms. Mn(1) is bonded to six equivalent V(1) and five equivalent Sb(1) atoms to form a mixture of distorted corner and face-sharing MnV6Sb5 trigonal bipyramids. Sb(1) is bonded in a 11-coordinate geometry to six equivalent V(1) and five equivalent Mn(1) atoms. is represented by the CIF card [CIF]
data_MnVSb
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.469
_cell_length_b   4.469
_cell_length_c   5.410
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   93.578
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.333  0.667  0.250  1.0
  Mn  Mn1  1  0.667  0.333  0.750  1.0
  V  V2  1  0.000  0.000  0.000  1.0
  V  V3  1  0.000  0.000  0.500  1.0
  Sb  Sb4  1  0.333  0.667  0.750  1.0
  Sb  Sb5  1  0.667  0.333  0.250  1.0
[/CIF]
.