The material described by RbPO4 crystallizes in the monoclinic P2_1/m space group. Rb(1) is bonded in a 10-coordinate geometry to one O(1), three equivalent O(2), and six equivalent O(3) atoms. P(1) is bonded in a tetrahedral geometry to one O(1), one O(2), and two equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Rb(1) and one P(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to three equivalent Rb(1) and one P(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to three equivalent Rb(1) and one P(1) atom. is represented by the CIF file [CIF]
data_RbPO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.272
_cell_length_b   5.866
_cell_length_c   7.795
_cell_angle_alpha   90.000
_cell_angle_beta   104.610
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   233.273
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.250  0.250  0.236  1.0
  Rb  Rb1  1  0.750  0.750  0.764  1.0
  P  P2  1  0.732  0.750  0.251  1.0
  P  P3  1  0.268  0.250  0.749  1.0
  O  O4  1  0.961  0.750  0.422  1.0
  O  O5  1  0.039  0.250  0.578  1.0
  O  O6  1  0.491  0.750  0.330  1.0
  O  O7  1  0.509  0.250  0.670  1.0
  O  O8  1  0.750  0.963  0.139  1.0
  O  O9  1  0.250  0.463  0.861  1.0
  O  O10  1  0.250  0.037  0.861  1.0
  O  O11  1  0.750  0.537  0.139  1.0
[/CIF]
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The material described by RbPO4 crystallizes in the monoclinic P2_1/m space group. Rb(1) is bonded in a 10-coordinate geometry to one O(1), three equivalent O(2), and six equivalent O(3) atoms. P(1) is bonded in a tetrahedral geometry to one O(1), one O(2), and two equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Rb(1) and one P(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to three equivalent Rb(1) and one P(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to three equivalent Rb(1) and one P(1) atom. is represented by the CIF file [CIF]
data_RbPO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.272
_cell_length_b   5.866
_cell_length_c   7.795
_cell_angle_alpha   90.000
_cell_angle_beta   104.610
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   233.273
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.250  0.250  0.236  1.0
  Rb  Rb1  1  0.750  0.750  0.764  1.0
  P  P2  1  0.732  0.750  0.251  1.0
  P  P3  1  0.268  0.250  0.749  1.0
  O  O4  1  0.961  0.750  0.422  1.0
  O  O5  1  0.039  0.250  0.578  1.0
  O  O6  1  0.491  0.750  0.330  1.0
  O  O7  1  0.509  0.250  0.670  1.0
  O  O8  1  0.750  0.963  0.139  1.0
  O  O9  1  0.250  0.463  0.861  1.0
  O  O10  1  0.250  0.037  0.861  1.0
  O  O11  1  0.750  0.537  0.139  1.0
[/CIF]
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