The crystal structure described by LiVP3HO10 crystallizes in the triclinic P-1 space group. Li(1) is bonded in a 4-coordinate geometry to one O(10), one O(5), one O(6), and one O(9) atom. V(1) is bonded to one O(1), one O(2), one O(5), one O(8), one O(9), and two equivalent O(6) atoms to form distorted VO7 pentagonal bipyramids that share corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, corners with three equivalent P(3)O4 tetrahedra, and  an edgeedge with one V(1)O7 pentagonal bipyramid. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(3), one O(5), and one O(7) atom to form PO4 tetrahedra that share corners with two equivalent V(1)O7 pentagonal bipyramids,  a cornercorner with one P(2)O4 tetrahedra, and  a cornercorner with one P(3)O4 tetrahedra. In the second P site, P(2) is bonded to one O(2), one O(3), one O(4), and one O(9) atom to form PO4 tetrahedra that share corners with two equivalent V(1)O7 pentagonal bipyramids and  a cornercorner with one P(1)O4 tetrahedra. In the third P site, P(3) is bonded to one O(10), one O(6), one O(7), and one O(8) atom to form PO4 tetrahedra that share corners with three equivalent V(1)O7 pentagonal bipyramids and  a cornercorner with one P(1)O4 tetrahedra. H(1) is bonded in a distorted linear geometry to one O(10) and one O(4) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one V(1) and one P(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one V(1) and one P(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one P(2) and one H(1) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Li(1), one V(1), and one P(1) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one Li(1), two equivalent V(1), and one P(3) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one P(1) and one P(3) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one V(1) and one P(3) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Li(1), one V(1), and one P(2) atom. In the tenth O site, O(10) is bonded in a distorted T-shaped geometry to one Li(1), one P(3), and one H(1) atom. is represented by the CIF file [CIF]
data_LiVP3HO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.521
_cell_length_b   7.536
_cell_length_c   8.244
_cell_angle_alpha   73.349
_cell_angle_beta   70.617
_cell_angle_gamma   83.345
_symmetry_Int_Tables_number   1
_cell_volume   366.061
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.712  0.314  0.404  1.0
  Li  Li1  1  0.288  0.686  0.596  1.0
  V  V2  1  0.811  0.362  0.980  1.0
  V  V3  1  0.189  0.638  0.020  1.0
  P  P4  1  0.863  0.966  0.866  1.0
  P  P5  1  0.687  0.754  0.694  1.0
  P  P6  1  0.622  0.688  0.165  1.0
  P  P7  1  0.378  0.312  0.835  1.0
  P  P8  1  0.313  0.246  0.306  1.0
  P  P9  1  0.137  0.034  0.134  1.0
  H  H10  1  0.685  0.779  0.424  1.0
  H  H11  1  0.315  0.221  0.576  1.0
  O  O12  1  0.895  0.169  0.829  1.0
  O  O13  1  0.834  0.597  0.756  1.0
  O  O14  1  0.729  0.939  0.743  1.0
  O  O15  1  0.762  0.834  0.486  1.0
  O  O16  1  0.938  0.161  0.158  1.0
  O  O17  1  0.833  0.562  0.122  1.0
  O  O18  1  0.702  0.900  0.066  1.0
  O  O19  1  0.526  0.347  0.930  1.0
  O  O20  1  0.444  0.720  0.755  1.0
  O  O21  1  0.529  0.680  0.361  1.0
  O  O22  1  0.471  0.320  0.639  1.0
  O  O23  1  0.556  0.280  0.245  1.0
  O  O24  1  0.474  0.653  0.070  1.0
  O  O25  1  0.298  0.100  0.934  1.0
  O  O26  1  0.167  0.438  0.878  1.0
  O  O27  1  0.062  0.839  0.842  1.0
  O  O28  1  0.238  0.166  0.514  1.0
  O  O29  1  0.271  0.061  0.257  1.0
  O  O30  1  0.166  0.403  0.244  1.0
  O  O31  1  0.105  0.831  0.171  1.0
[/CIF]
.
The crystal structure described by LiVP3HO10 crystallizes in the triclinic P-1 space group. Li(1) is bonded in a 4-coordinate geometry to one O(10), one O(5), one O(6), and one O(9) atom. V(1) is bonded to one O(1), one O(2), one O(5), one O(8), one O(9), and two equivalent O(6) atoms to form distorted VO7 pentagonal bipyramids that share corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, corners with three equivalent P(3)O4 tetrahedra, and  an edgeedge with one V(1)O7 pentagonal bipyramid. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(3), one O(5), and one O(7) atom to form PO4 tetrahedra that share corners with two equivalent V(1)O7 pentagonal bipyramids,  a cornercorner with one P(2)O4 tetrahedra, and  a cornercorner with one P(3)O4 tetrahedra. In the second P site, P(2) is bonded to one O(2), one O(3), one O(4), and one O(9) atom to form PO4 tetrahedra that share corners with two equivalent V(1)O7 pentagonal bipyramids and  a cornercorner with one P(1)O4 tetrahedra. In the third P site, P(3) is bonded to one O(10), one O(6), one O(7), and one O(8) atom to form PO4 tetrahedra that share corners with three equivalent V(1)O7 pentagonal bipyramids and  a cornercorner with one P(1)O4 tetrahedra. H(1) is bonded in a distorted linear geometry to one O(10) and one O(4) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one V(1) and one P(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one V(1) and one P(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one P(2) and one H(1) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Li(1), one V(1), and one P(1) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one Li(1), two equivalent V(1), and one P(3) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one P(1) and one P(3) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one V(1) and one P(3) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Li(1), one V(1), and one P(2) atom. In the tenth O site, O(10) is bonded in a distorted T-shaped geometry to one Li(1), one P(3), and one H(1) atom. is represented by the CIF file [CIF]
data_LiVP3HO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.521
_cell_length_b   7.536
_cell_length_c   8.244
_cell_angle_alpha   73.349
_cell_angle_beta   70.617
_cell_angle_gamma   83.345
_symmetry_Int_Tables_number   1
_cell_volume   366.061
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.712  0.314  0.404  1.0
  Li  Li1  1  0.288  0.686  0.596  1.0
  V  V2  1  0.811  0.362  0.980  1.0
  V  V3  1  0.189  0.638  0.020  1.0
  P  P4  1  0.863  0.966  0.866  1.0
  P  P5  1  0.687  0.754  0.694  1.0
  P  P6  1  0.622  0.688  0.165  1.0
  P  P7  1  0.378  0.312  0.835  1.0
  P  P8  1  0.313  0.246  0.306  1.0
  P  P9  1  0.137  0.034  0.134  1.0
  H  H10  1  0.685  0.779  0.424  1.0
  H  H11  1  0.315  0.221  0.576  1.0
  O  O12  1  0.895  0.169  0.829  1.0
  O  O13  1  0.834  0.597  0.756  1.0
  O  O14  1  0.729  0.939  0.743  1.0
  O  O15  1  0.762  0.834  0.486  1.0
  O  O16  1  0.938  0.161  0.158  1.0
  O  O17  1  0.833  0.562  0.122  1.0
  O  O18  1  0.702  0.900  0.066  1.0
  O  O19  1  0.526  0.347  0.930  1.0
  O  O20  1  0.444  0.720  0.755  1.0
  O  O21  1  0.529  0.680  0.361  1.0
  O  O22  1  0.471  0.320  0.639  1.0
  O  O23  1  0.556  0.280  0.245  1.0
  O  O24  1  0.474  0.653  0.070  1.0
  O  O25  1  0.298  0.100  0.934  1.0
  O  O26  1  0.167  0.438  0.878  1.0
  O  O27  1  0.062  0.839  0.842  1.0
  O  O28  1  0.238  0.166  0.514  1.0
  O  O29  1  0.271  0.061  0.257  1.0
  O  O30  1  0.166  0.403  0.244  1.0
  O  O31  1  0.105  0.831  0.171  1.0
[/CIF]
.