The material structure described by Rb2RuNO3Cl5 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 9-coordinate geometry to one O(3), one Cl(1), two equivalent Cl(2), two equivalent Cl(3), and three equivalent Cl(5) atoms. In the second Rb site, Rb(2) is bonded in a 8-coordinate geometry to one O(3), one Cl(2), one Cl(3), one Cl(5), two equivalent Cl(1), and two equivalent Cl(4) atoms. Ru(1) is bonded in a distorted octahedral geometry to one N(1), one O(1), one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. N(1) is bonded in a linear geometry to one Ru(1) and one O(2) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Ru(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one N(1) atom. In the third O site, O(3) is bonded in an L-shaped geometry to one Rb(1) and one Rb(2) atom. There are five inequivalent Cl sites. In the first Cl site, Cl(5) is bonded in a see-saw-like geometry to one Rb(2) and three equivalent Rb(1) atoms. In the second Cl site, Cl(1) is bonded in a distorted rectangular see-saw-like geometry to one Rb(1), two equivalent Rb(2), and one Ru(1) atom. In the third Cl site, Cl(2) is bonded in a distorted single-bond geometry to one Rb(2), two equivalent Rb(1), and one Ru(1) atom. In the fourth Cl site, Cl(3) is bonded in a 4-coordinate geometry to one Rb(2), two equivalent Rb(1), and one Ru(1) atom. In the fifth Cl site, Cl(4) is bonded in a 3-coordinate geometry to two equivalent Rb(2) and one Ru(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Rb2RuNCl5O3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.730
_cell_length_b   11.709
_cell_length_c   16.251
_cell_angle_alpha   78.378
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1254.295
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.468  0.545  0.161  1.0
  Rb  Rb1  1  0.968  0.455  0.339  1.0
  Rb  Rb2  1  0.532  0.455  0.839  1.0
  Rb  Rb3  1  0.032  0.545  0.661  1.0
  Rb  Rb4  1  0.372  0.174  0.424  1.0
  Rb  Rb5  1  0.872  0.826  0.076  1.0
  Rb  Rb6  1  0.628  0.826  0.576  1.0
  Rb  Rb7  1  0.128  0.174  0.924  1.0
  Ru  Ru8  1  0.172  0.776  0.410  1.0
  Ru  Ru9  1  0.672  0.224  0.090  1.0
  Ru  Ru10  1  0.828  0.224  0.590  1.0
  Ru  Ru11  1  0.328  0.776  0.910  1.0
  N  N12  1  0.507  0.091  0.140  1.0
  N  N13  1  0.007  0.909  0.360  1.0
  N  N14  1  0.493  0.909  0.860  1.0
  N  N15  1  0.993  0.091  0.640  1.0
  Cl  Cl16  1  0.359  0.837  0.043  1.0
  Cl  Cl17  1  0.859  0.163  0.457  1.0
  Cl  Cl18  1  0.641  0.163  0.957  1.0
  Cl  Cl19  1  0.141  0.837  0.543  1.0
  Cl  Cl20  1  0.175  0.736  0.272  1.0
  Cl  Cl21  1  0.675  0.264  0.228  1.0
  Cl  Cl22  1  0.825  0.264  0.728  1.0
  Cl  Cl23  1  0.325  0.736  0.772  1.0
  Cl  Cl24  1  0.366  0.326  0.059  1.0
  Cl  Cl25  1  0.866  0.674  0.441  1.0
  Cl  Cl26  1  0.634  0.674  0.941  1.0
  Cl  Cl27  1  0.134  0.326  0.559  1.0
  Cl  Cl28  1  0.947  0.093  0.125  1.0
  Cl  Cl29  1  0.447  0.907  0.375  1.0
  Cl  Cl30  1  0.053  0.907  0.875  1.0
  Cl  Cl31  1  0.553  0.093  0.625  1.0
  Cl  Cl32  1  0.969  0.555  0.136  1.0
  Cl  Cl33  1  0.469  0.445  0.364  1.0
  Cl  Cl34  1  0.031  0.445  0.864  1.0
  Cl  Cl35  1  0.531  0.555  0.636  1.0
  O  O36  1  0.316  0.657  0.451  1.0
  O  O37  1  0.816  0.343  0.049  1.0
  O  O38  1  0.684  0.343  0.549  1.0
  O  O39  1  0.184  0.657  0.951  1.0
  O  O40  1  0.410  0.013  0.173  1.0
  O  O41  1  0.910  0.987  0.327  1.0
  O  O42  1  0.590  0.987  0.827  1.0
  O  O43  1  0.090  0.013  0.673  1.0
  O  O44  1  0.162  0.260  0.264  1.0
  O  O45  1  0.662  0.740  0.236  1.0
  O  O46  1  0.838  0.740  0.736  1.0
  O  O47  1  0.338  0.260  0.764  1.0
[/CIF]
.
The material structure described by Rb2RuNO3Cl5 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 9-coordinate geometry to one O(3), one Cl(1), two equivalent Cl(2), two equivalent Cl(3), and three equivalent Cl(5) atoms. In the second Rb site, Rb(2) is bonded in a 8-coordinate geometry to one O(3), one Cl(2), one Cl(3), one Cl(5), two equivalent Cl(1), and two equivalent Cl(4) atoms. Ru(1) is bonded in a distorted octahedral geometry to one N(1), one O(1), one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. N(1) is bonded in a linear geometry to one Ru(1) and one O(2) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Ru(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one N(1) atom. In the third O site, O(3) is bonded in an L-shaped geometry to one Rb(1) and one Rb(2) atom. There are five inequivalent Cl sites. In the first Cl site, Cl(5) is bonded in a see-saw-like geometry to one Rb(2) and three equivalent Rb(1) atoms. In the second Cl site, Cl(1) is bonded in a distorted rectangular see-saw-like geometry to one Rb(1), two equivalent Rb(2), and one Ru(1) atom. In the third Cl site, Cl(2) is bonded in a distorted single-bond geometry to one Rb(2), two equivalent Rb(1), and one Ru(1) atom. In the fourth Cl site, Cl(3) is bonded in a 4-coordinate geometry to one Rb(2), two equivalent Rb(1), and one Ru(1) atom. In the fifth Cl site, Cl(4) is bonded in a 3-coordinate geometry to two equivalent Rb(2) and one Ru(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Rb2RuNCl5O3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.730
_cell_length_b   11.709
_cell_length_c   16.251
_cell_angle_alpha   78.378
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1254.295
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.468  0.545  0.161  1.0
  Rb  Rb1  1  0.968  0.455  0.339  1.0
  Rb  Rb2  1  0.532  0.455  0.839  1.0
  Rb  Rb3  1  0.032  0.545  0.661  1.0
  Rb  Rb4  1  0.372  0.174  0.424  1.0
  Rb  Rb5  1  0.872  0.826  0.076  1.0
  Rb  Rb6  1  0.628  0.826  0.576  1.0
  Rb  Rb7  1  0.128  0.174  0.924  1.0
  Ru  Ru8  1  0.172  0.776  0.410  1.0
  Ru  Ru9  1  0.672  0.224  0.090  1.0
  Ru  Ru10  1  0.828  0.224  0.590  1.0
  Ru  Ru11  1  0.328  0.776  0.910  1.0
  N  N12  1  0.507  0.091  0.140  1.0
  N  N13  1  0.007  0.909  0.360  1.0
  N  N14  1  0.493  0.909  0.860  1.0
  N  N15  1  0.993  0.091  0.640  1.0
  Cl  Cl16  1  0.359  0.837  0.043  1.0
  Cl  Cl17  1  0.859  0.163  0.457  1.0
  Cl  Cl18  1  0.641  0.163  0.957  1.0
  Cl  Cl19  1  0.141  0.837  0.543  1.0
  Cl  Cl20  1  0.175  0.736  0.272  1.0
  Cl  Cl21  1  0.675  0.264  0.228  1.0
  Cl  Cl22  1  0.825  0.264  0.728  1.0
  Cl  Cl23  1  0.325  0.736  0.772  1.0
  Cl  Cl24  1  0.366  0.326  0.059  1.0
  Cl  Cl25  1  0.866  0.674  0.441  1.0
  Cl  Cl26  1  0.634  0.674  0.941  1.0
  Cl  Cl27  1  0.134  0.326  0.559  1.0
  Cl  Cl28  1  0.947  0.093  0.125  1.0
  Cl  Cl29  1  0.447  0.907  0.375  1.0
  Cl  Cl30  1  0.053  0.907  0.875  1.0
  Cl  Cl31  1  0.553  0.093  0.625  1.0
  Cl  Cl32  1  0.969  0.555  0.136  1.0
  Cl  Cl33  1  0.469  0.445  0.364  1.0
  Cl  Cl34  1  0.031  0.445  0.864  1.0
  Cl  Cl35  1  0.531  0.555  0.636  1.0
  O  O36  1  0.316  0.657  0.451  1.0
  O  O37  1  0.816  0.343  0.049  1.0
  O  O38  1  0.684  0.343  0.549  1.0
  O  O39  1  0.184  0.657  0.951  1.0
  O  O40  1  0.410  0.013  0.173  1.0
  O  O41  1  0.910  0.987  0.327  1.0
  O  O42  1  0.590  0.987  0.827  1.0
  O  O43  1  0.090  0.013  0.673  1.0
  O  O44  1  0.162  0.260  0.264  1.0
  O  O45  1  0.662  0.740  0.236  1.0
  O  O46  1  0.838  0.740  0.736  1.0
  O  O47  1  0.338  0.260  0.764  1.0
[/CIF]
.