The material structure described by Li2CrO2 crystallizes in the monoclinic P2/c space group. Li(1) is bonded to four equivalent O(1) atoms to form a mixture of edge and corner-sharing LiO4 tetrahedra. Cr(1) is bonded in a rectangular see-saw-like geometry to four equivalent O(1) atoms. O(1) is bonded to four equivalent Li(1) and two equivalent Cr(1) atoms to form a mixture of distorted edge and corner-sharing OLi4Cr2 pentagonal pyramids. is represented by the CIF file [CIF]
data_Li2CrO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.932
_cell_length_b   3.486
_cell_length_c   5.516
_cell_angle_alpha   100.617
_cell_angle_beta   90.000
_cell_angle_gamma   114.871
_symmetry_Int_Tables_number   1
_cell_volume   50.083
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.000  0.000  0.000  1.0
  Li  Li1  1  0.327  0.655  0.369  1.0
  Li  Li2  1  0.672  0.345  0.631  1.0
  O  O3  1  0.388  0.775  0.740  1.0
  O  O4  1  0.612  0.225  0.260  1.0
[/CIF]
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The material structure described by Li2CrO2 crystallizes in the monoclinic P2/c space group. Li(1) is bonded to four equivalent O(1) atoms to form a mixture of edge and corner-sharing LiO4 tetrahedra. Cr(1) is bonded in a rectangular see-saw-like geometry to four equivalent O(1) atoms. O(1) is bonded to four equivalent Li(1) and two equivalent Cr(1) atoms to form a mixture of distorted edge and corner-sharing OLi4Cr2 pentagonal pyramids. is represented by the CIF file [CIF]
data_Li2CrO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.932
_cell_length_b   3.486
_cell_length_c   5.516
_cell_angle_alpha   100.617
_cell_angle_beta   90.000
_cell_angle_gamma   114.871
_symmetry_Int_Tables_number   1
_cell_volume   50.083
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.000  0.000  0.000  1.0
  Li  Li1  1  0.327  0.655  0.369  1.0
  Li  Li2  1  0.672  0.345  0.631  1.0
  O  O3  1  0.388  0.775  0.740  1.0
  O  O4  1  0.612  0.225  0.260  1.0
[/CIF]
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