The material described by (W2O2F9)2O2 is Indium-derived structured and crystallizes in the monoclinic P2/c space group. The structure is zero-dimensional and consists of two water atoms and two W2O2F9 clusters. In each W2O2F9 cluster, W(1) is bonded to one O(1), one F(1), one F(2), one F(3), one F(4), and one F(5) atom to form corner-sharing WOF5 octahedra. The corner-sharing octahedral tilt angles are 35°. O(1) is bonded in a single-bond geometry to one W(1) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to two equivalent W(1) atoms. In the second F site, F(2) is bonded in a single-bond geometry to one W(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one W(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one W(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one W(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_W2(OF3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.482
_cell_length_b   5.781
_cell_length_c   15.631
_cell_angle_alpha   94.570
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   493.861
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  W  W0  1  0.266  0.252  0.619  1.0
  W  W1  1  0.734  0.748  0.381  1.0
  W  W2  1  0.266  0.248  0.881  1.0
  W  W3  1  0.734  0.752  0.119  1.0
  O  O4  1  0.360  0.250  0.512  1.0
  O  O5  1  0.640  0.750  0.488  1.0
  O  O6  1  0.360  0.250  0.988  1.0
  O  O7  1  0.640  0.750  0.012  1.0
  O  O8  1  0.818  0.750  0.750  1.0
  O  O9  1  0.182  0.250  0.250  1.0
  F  F10  1  0.148  0.250  0.750  1.0
  F  F11  1  0.852  0.750  0.250  1.0
  F  F12  1  0.532  0.087  0.661  1.0
  F  F13  1  0.468  0.913  0.339  1.0
  F  F14  1  0.532  0.413  0.839  1.0
  F  F15  1  0.468  0.587  0.161  1.0
  F  F16  1  0.419  0.534  0.660  1.0
  F  F17  1  0.581  0.466  0.340  1.0
  F  F18  1  0.419  0.966  0.840  1.0
  F  F19  1  0.581  0.034  0.160  1.0
  F  F20  1  0.972  0.424  0.610  1.0
  F  F21  1  0.028  0.576  0.390  1.0
  F  F22  1  0.972  0.076  0.890  1.0
  F  F23  1  0.028  0.924  0.110  1.0
  F  F24  1  0.082  0.973  0.608  1.0
  F  F25  1  0.918  0.027  0.392  1.0
  F  F26  1  0.082  0.527  0.892  1.0
  F  F27  1  0.918  0.473  0.108  1.0
[/CIF]
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The material described by (W2O2F9)2O2 is Indium-derived structured and crystallizes in the monoclinic P2/c space group. The structure is zero-dimensional and consists of two water atoms and two W2O2F9 clusters. In each W2O2F9 cluster, W(1) is bonded to one O(1), one F(1), one F(2), one F(3), one F(4), and one F(5) atom to form corner-sharing WOF5 octahedra. The corner-sharing octahedral tilt angles are 35°. O(1) is bonded in a single-bond geometry to one W(1) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to two equivalent W(1) atoms. In the second F site, F(2) is bonded in a single-bond geometry to one W(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one W(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one W(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one W(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_W2(OF3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.482
_cell_length_b   5.781
_cell_length_c   15.631
_cell_angle_alpha   94.570
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   493.861
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  W  W0  1  0.266  0.252  0.619  1.0
  W  W1  1  0.734  0.748  0.381  1.0
  W  W2  1  0.266  0.248  0.881  1.0
  W  W3  1  0.734  0.752  0.119  1.0
  O  O4  1  0.360  0.250  0.512  1.0
  O  O5  1  0.640  0.750  0.488  1.0
  O  O6  1  0.360  0.250  0.988  1.0
  O  O7  1  0.640  0.750  0.012  1.0
  O  O8  1  0.818  0.750  0.750  1.0
  O  O9  1  0.182  0.250  0.250  1.0
  F  F10  1  0.148  0.250  0.750  1.0
  F  F11  1  0.852  0.750  0.250  1.0
  F  F12  1  0.532  0.087  0.661  1.0
  F  F13  1  0.468  0.913  0.339  1.0
  F  F14  1  0.532  0.413  0.839  1.0
  F  F15  1  0.468  0.587  0.161  1.0
  F  F16  1  0.419  0.534  0.660  1.0
  F  F17  1  0.581  0.466  0.340  1.0
  F  F18  1  0.419  0.966  0.840  1.0
  F  F19  1  0.581  0.034  0.160  1.0
  F  F20  1  0.972  0.424  0.610  1.0
  F  F21  1  0.028  0.576  0.390  1.0
  F  F22  1  0.972  0.076  0.890  1.0
  F  F23  1  0.028  0.924  0.110  1.0
  F  F24  1  0.082  0.973  0.608  1.0
  F  F25  1  0.918  0.027  0.392  1.0
  F  F26  1  0.082  0.527  0.892  1.0
  F  F27  1  0.918  0.473  0.108  1.0
[/CIF]
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