The structure described by Li5V2Ni3O10 is Caswellsilverite-derived structured and crystallizes in the triclinic P1 space group. There are five inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(10), one O(5), one O(6), one O(7), one O(8), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra, corners with two equivalent Ni(1)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-11°. In the second Li site, Li(2) is bonded to one O(10), one O(2), one O(5), one O(6), one O(7), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Ni(3)O6 octahedra, corners with two equivalent Ni(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, and edges with two equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-12°. In the third Li site, Li(3) is bonded to one O(1), one O(10), one O(5), one O(6), one O(8), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra, corners with two equivalent Ni(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, and edges with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-11°. In the fourth Li site, Li(4) is bonded to one O(1), one O(3), one O(4), one O(5), one O(8), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra,  a cornercorner with one Ni(3)O6 octahedra, corners with two equivalent V(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, and edges with two equivalent Ni(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-10°. In the fifth Li site, Li(5) is bonded to one O(10), one O(2), one O(3), one O(4), one O(6), and one O(7) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra,  a cornercorner with one Ni(3)O6 octahedra, corners with two equivalent V(1)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(2)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, and edges with two equivalent Ni(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-11°. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(3), one O(5), one O(6), one O(8), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Ni(1)O6 octahedra, corners with two equivalent Li(5)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, and edges with two equivalent Ni(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-6°. In the second V site, V(2) is bonded to one O(10), one O(2), one O(4), one O(5), one O(6), and one O(7) atom to form VO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Ni(1)O6 octahedra, corners with two equivalent Li(4)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, and edges with two equivalent Ni(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-10°. There are three inequivalent Ni sites. In the first Ni site, Ni(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(7), and one O(8) atom to form NiO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra,  a cornercorner with one Ni(3)O6 octahedra, corners with two equivalent Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Ni(2)O6 octahedra, and edges with two equivalent Ni(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-10°. In the second Ni site, Ni(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form NiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Ni(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, and edges with two equivalent Ni(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-11°. In the third Ni site, Ni(3) is bonded to one O(1), one O(10), one O(2), one O(3), one O(4), and one O(7) atom to form NiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Ni(1)O6 octahedra, corners with two equivalent Li(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one V(1)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent V(2)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, and edges with two equivalent Ni(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-12°. There are ten inequivalent O sites. In the first O site, O(1) is bonded to one Li(3), one Li(4), one V(1), one Ni(1), one Ni(2), and one Ni(3) atom to form OLi2VNi3 octahedra that share  a cornercorner with one O(2)Li2VNi3 octahedra,  a cornercorner with one O(3)Li2VNi3 octahedra,  a cornercorner with one O(8)Li3VNi2 octahedra,  a cornercorner with one O(5)Li4V2 octahedra, corners with two equivalent O(10)Li4VNi octahedra,  an edgeedge with one O(2)Li2VNi3 octahedra,  an edgeedge with one O(7)Li3VNi2 octahedra,  an edgeedge with one O(5)Li4V2 octahedra,  an edgeedge with one O(6)Li4V2 octahedra, edges with two equivalent O(3)Li2VNi3 octahedra, edges with two equivalent O(4)Li2VNi3 octahedra, edges with two equivalent O(8)Li3VNi2 octahedra, and edges with two equivalent O(9)Li4VNi octahedra. The corner-sharing octahedral tilt angles range from 0-9°. In the second O site, O(2) is bonded to one Li(2), one Li(5), one V(2), one Ni(1), one Ni(2), and one Ni(3) atom to form OLi2VNi3 octahedra that share  a cornercorner with one O(1)Li2VNi3 octahedra,  a cornercorner with one O(4)Li2VNi3 octahedra,  a cornercorner with one O(7)Li3VNi2 octahedra,  a cornercorner with one O(6)Li4V2 octahedra, corners with two equivalent O(9)Li4VNi octahedra,  an edgeedge with one O(1)Li2VNi3 octahedra,  an edgeedge with one O(8)Li3VNi2 octahedra,  an edgeedge with one O(5)Li4V2 octahedra,  an edgeedge with one O(6)Li4V2 octahedra, edges with two equivalent O(3)Li2VNi3 octahedra, edges with two equivalent O(4)Li2VNi3 octahedra, edges with two equivalent O(7)Li3VNi2 octahedra, and edges with two equivalent O(10)Li4VNi octahedra. The corner-sharing octahedral tilt angles range from 0-10°. In the third O site, O(3) is bonded to one Li(4), one Li(5), one V(1), one Ni(1), one Ni(2), and one Ni(3) atom to form OLi2VNi3 octahedra that share  a cornercorner with one O(1)Li2VNi3 octahedra,  a cornercorner with one O(4)Li2VNi3 octahedra,  a cornercorner with one O(7)Li3VNi2 octahedra,  a cornercorner with one O(9)Li4VNi octahedra, corners with two equivalent O(6)Li4V2 octahedra,  an edgeedge with one O(7)Li3VNi2 octahedra,  an edgeedge with one O(5)Li4V2 octahedra,  an edgeedge with one O(10)Li4VNi octahedra,  an edgeedge with one O(9)Li4VNi octahedra, edges with two equivalent O(1)Li2VNi3 octahedra, edges with two equivalent O(2)Li2VNi3 octahedra, edges with two equivalent O(4)Li2VNi3 octahedra, and edges with two equivalent O(8)Li3VNi2 octahedra. The corner-sharing octahedral tilt angles range from 1-9°. In the fourth O site, O(4) is bonded to one Li(4), one Li(5), one V(2), one Ni(1), one Ni(2), and one Ni(3) atom to form OLi2VNi3 octahedra that share  a cornercorner with one O(2)Li2VNi3 octahedra,  a cornercorner with one O(3)Li2VNi3 octahedra,  a cornercorner with one O(8)Li3VNi2 octahedra,  a cornercorner with one O(10)Li4VNi octahedra, corners with two equivalent O(5)Li4V2 octahedra,  an edgeedge with one O(8)Li3VNi2 octahedra,  an edgeedge with one O(6)Li4V2 octahedra,  an edgeedge with one O(10)Li4VNi octahedra,  an edgeedge with one O(9)Li4VNi octahedra, edges with two equivalent O(1)Li2VNi3 octahedra, edges with two equivalent O(2)Li2VNi3 octahedra, edges with two equivalent O(3)Li2VNi3 octahedra, and edges with two equivalent O(7)Li3VNi2 octahedra. The corner-sharing octahedral tilt angles range from 2-7°. In the fifth O site, O(5) is bonded to one Li(1), one Li(2), one Li(3), one Li(4), one V(1), and one V(2) atom to form OLi4V2 octahedra that share  a cornercorner with one O(1)Li2VNi3 octahedra,  a cornercorner with one O(7)Li3VNi2 octahedra,  a cornercorner with one O(6)Li4V2 octahedra,  a cornercorner with one O(9)Li4VNi octahedra, corners with two equivalent O(4)Li2VNi3 octahedra,  an edgeedge with one O(1)Li2VNi3 octahedra,  an edgeedge with one O(2)Li2VNi3 octahedra,  an edgeedge with one O(3)Li2VNi3 octahedra,  an edgeedge with one O(7)Li3VNi2 octahedra, edges with two equivalent O(8)Li3VNi2 octahedra, edges with two equivalent O(6)Li4V2 octahedra, edges with two equivalent O(10)Li4VNi octahedra, and edges with two equivalent O(9)Li4VNi octahedra. The corner-sharing octahedral tilt angles range from 3-9°. In the sixth O site, O(6) is bonded to one Li(1), one Li(2), one Li(3), one Li(5), one V(1), and one V(2) atom to form OLi4V2 octahedra that share  a cornercorner with one O(2)Li2VNi3 octahedra,  a cornercorner with one O(8)Li3VNi2 octahedra,  a cornercorner with one O(5)Li4V2 octahedra,  a cornercorner with one O(10)Li4VNi octahedra, corners with two equivalent O(3)Li2VNi3 octahedra,  an edgeedge with one O(1)Li2VNi3 octahedra,  an edgeedge with one O(2)Li2VNi3 octahedra,  an edgeedge with one O(4)Li2VNi3 octahedra,  an edgeedge with one O(8)Li3VNi2 octahedra, edges with two equivalent O(7)Li3VNi2 octahedra, edges with two equivalent O(5)Li4V2 octahedra, edges with two equivalent O(10)Li4VNi octahedra, and edges with two equivalent O(9)Li4VNi octahedra. The corner-sharing octahedral tilt angles range from 1-10°. In the seventh O site, O(7) is bonded to one Li(1), one Li(2), one Li(5), one V(2), one Ni(1), and one Ni(3) atom to form OLi3VNi2 octahedra that share  a cornercorner with one O(2)Li2VNi3 octahedra,  a cornercorner with one O(3)Li2VNi3 octahedra,  a cornercorner with one O(5)Li4V2 octahedra,  a cornercorner with one O(10)Li4VNi octahedra, corners with two equivalent O(8)Li3VNi2 octahedra,  an edgeedge with one O(1)Li2VNi3 octahedra,  an edgeedge with one O(3)Li2VNi3 octahedra,  an edgeedge with one O(5)Li4V2 octahedra,  an edgeedge with one O(9)Li4VNi octahedra, edges with two equivalent O(2)Li2VNi3 octahedra, edges with two equivalent O(4)Li2VNi3 octahedra, edges with two equivalent O(6)Li4V2 octahedra, and edges with two equivalent O(10)Li4VNi octahedra. The corner-sharing octahedral tilt angles range from 1-9°. In the eighth O site, O(8) is bonded to one Li(1), one Li(3), one Li(4), one V(1), one Ni(1), and one Ni(2) atom to form OLi3VNi2 octahedra that share  a cornercorner with one O(1)Li2VNi3 octahedra,  a cornercorner with one O(4)Li2VNi3 octahedra,  a cornercorner with one O(6)Li4V2 octahedra,  a cornercorner with one O(9)Li4VNi octahedra, corners with two equivalent O(7)Li3VNi2 octahedra,  an edgeedge with one O(2)Li2VNi3 octahedra,  an edgeedge with one O(4)Li2VNi3 octahedra,  an edgeedge with one O(6)Li4V2 octahedra,  an edgeedge with one O(10)Li4VNi octahedra, edges with two equivalent O(1)Li2VNi3 octahedra, edges with two equivalent O(3)Li2VNi3 octahedra, edges with two equivalent O(5)Li4V2 octahedra, and edges with two equivalent O(9)Li4VNi octahedra. The corner-sharing octahedral tilt angles range from 1-10°. In the ninth O site, O(9) is bonded to one Li(1), one Li(2), one Li(3), one Li(4), one V(1), and one Ni(2) atom to form OLi4VNi octahedra that share  a cornercorner with one O(3)Li2VNi3 octahedra,  a cornercorner with one O(8)Li3VNi2 octahedra,  a cornercorner with one O(5)Li4V2 octahedra,  a cornercorner with one O(10)Li4VNi octahedra, corners with two equivalent O(2)Li2VNi3 octahedra,  an edgeedge with one O(3)Li2VNi3 octahedra,  an edgeedge with one O(4)Li2VNi3 octahedra,  an edgeedge with one O(7)Li3VNi2 octahedra,  an edgeedge with one O(10)Li4VNi octahedra, edges with two equivalent O(1)Li2VNi3 octahedra, edges with two equivalent O(8)Li3VNi2 octahedra, edges with two equivalent O(5)Li4V2 octahedra, and edges with two equivalent O(6)Li4V2 octahedra. The corner-sharing octahedral tilt angles range from 1-10°. In the tenth O site, O(10) is bonded to one Li(1), one Li(2), one Li(3), one Li(5), one V(2), and one Ni(3) atom to form OLi4VNi octahedra that share  a cornercorner with one O(4)Li2VNi3 octahedra,  a cornercorner with one O(7)Li3VNi2 octahedra,  a cornercorner with one O(6)Li4V2 octahedra,  a cornercorner with one O(9)Li4VNi octahedra, corners with two equivalent O(1)Li2VNi3 octahedra,  an edgeedge with one O(3)Li2VNi3 octahedra,  an edgeedge with one O(4)Li2VNi3 octahedra,  an edgeedge with one O(8)Li3VNi2 octahedra,  an edgeedge with one O(9)Li4VNi octahedra, edges with two equivalent O(2)Li2VNi3 octahedra, edges with two equivalent O(7)Li3VNi2 octahedra, edges with two equivalent O(5)Li4V2 octahedra, and edges with two equivalent O(6)Li4V2 octahedra. The corner-sharing octahedral tilt angles range from 1-9°. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li5V2Ni3O10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.102
_cell_length_b   5.112
_cell_length_c   7.770
_cell_angle_alpha   108.859
_cell_angle_beta   108.423
_cell_angle_gamma   79.586
_symmetry_Int_Tables_number   1
_cell_volume   181.230
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.501  0.996  0.498  1.0
  Li  Li1  1  0.785  0.505  0.603  1.0
  Li  Li2  1  0.210  0.504  0.399  1.0
  Li  Li3  1  0.596  0.509  0.202  1.0
  Li  Li4  1  0.403  0.493  0.799  1.0
  Ni  Ni5  1  0.002  0.500  1.000  1.0
  Ni  Ni6  1  0.304  0.994  0.100  1.0
  Ni  Ni7  1  0.696  0.001  0.898  1.0
  O  O8  1  0.951  0.233  0.160  1.0
  O  O9  1  0.049  0.759  0.846  1.0
  O  O10  1  0.674  0.768  0.071  1.0
  O  O11  1  0.336  0.235  0.938  1.0
  O  O12  1  0.863  0.781  0.450  1.0
  O  O13  1  0.129  0.221  0.533  1.0
  O  O14  1  0.781  0.235  0.752  1.0
  O  O15  1  0.218  0.764  0.247  1.0
  O  O16  1  0.579  0.230  0.341  1.0
  O  O17  1  0.421  0.768  0.656  1.0
  V  V18  1  0.899  0.019  0.309  1.0
  V  V19  1  0.103  0.986  0.698  1.0
[/CIF]
.
The structure described by Li5V2Ni3O10 is Caswellsilverite-derived structured and crystallizes in the triclinic P1 space group. There are five inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(10), one O(5), one O(6), one O(7), one O(8), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra, corners with two equivalent Ni(1)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-11°. In the second Li site, Li(2) is bonded to one O(10), one O(2), one O(5), one O(6), one O(7), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Ni(3)O6 octahedra, corners with two equivalent Ni(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, and edges with two equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-12°. In the third Li site, Li(3) is bonded to one O(1), one O(10), one O(5), one O(6), one O(8), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra, corners with two equivalent Ni(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, and edges with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-11°. In the fourth Li site, Li(4) is bonded to one O(1), one O(3), one O(4), one O(5), one O(8), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra,  a cornercorner with one Ni(3)O6 octahedra, corners with two equivalent V(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, and edges with two equivalent Ni(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-10°. In the fifth Li site, Li(5) is bonded to one O(10), one O(2), one O(3), one O(4), one O(6), and one O(7) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra,  a cornercorner with one Ni(3)O6 octahedra, corners with two equivalent V(1)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(2)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, and edges with two equivalent Ni(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-11°. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(3), one O(5), one O(6), one O(8), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Ni(1)O6 octahedra, corners with two equivalent Li(5)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, and edges with two equivalent Ni(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-6°. In the second V site, V(2) is bonded to one O(10), one O(2), one O(4), one O(5), one O(6), and one O(7) atom to form VO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Ni(1)O6 octahedra, corners with two equivalent Li(4)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, and edges with two equivalent Ni(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-10°. There are three inequivalent Ni sites. In the first Ni site, Ni(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(7), and one O(8) atom to form NiO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra,  a cornercorner with one Ni(3)O6 octahedra, corners with two equivalent Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Ni(2)O6 octahedra, and edges with two equivalent Ni(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-10°. In the second Ni site, Ni(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form NiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Ni(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, and edges with two equivalent Ni(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-11°. In the third Ni site, Ni(3) is bonded to one O(1), one O(10), one O(2), one O(3), one O(4), and one O(7) atom to form NiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Ni(1)O6 octahedra, corners with two equivalent Li(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one V(1)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent V(2)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, and edges with two equivalent Ni(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-12°. There are ten inequivalent O sites. In the first O site, O(1) is bonded to one Li(3), one Li(4), one V(1), one Ni(1), one Ni(2), and one Ni(3) atom to form OLi2VNi3 octahedra that share  a cornercorner with one O(2)Li2VNi3 octahedra,  a cornercorner with one O(3)Li2VNi3 octahedra,  a cornercorner with one O(8)Li3VNi2 octahedra,  a cornercorner with one O(5)Li4V2 octahedra, corners with two equivalent O(10)Li4VNi octahedra,  an edgeedge with one O(2)Li2VNi3 octahedra,  an edgeedge with one O(7)Li3VNi2 octahedra,  an edgeedge with one O(5)Li4V2 octahedra,  an edgeedge with one O(6)Li4V2 octahedra, edges with two equivalent O(3)Li2VNi3 octahedra, edges with two equivalent O(4)Li2VNi3 octahedra, edges with two equivalent O(8)Li3VNi2 octahedra, and edges with two equivalent O(9)Li4VNi octahedra. The corner-sharing octahedral tilt angles range from 0-9°. In the second O site, O(2) is bonded to one Li(2), one Li(5), one V(2), one Ni(1), one Ni(2), and one Ni(3) atom to form OLi2VNi3 octahedra that share  a cornercorner with one O(1)Li2VNi3 octahedra,  a cornercorner with one O(4)Li2VNi3 octahedra,  a cornercorner with one O(7)Li3VNi2 octahedra,  a cornercorner with one O(6)Li4V2 octahedra, corners with two equivalent O(9)Li4VNi octahedra,  an edgeedge with one O(1)Li2VNi3 octahedra,  an edgeedge with one O(8)Li3VNi2 octahedra,  an edgeedge with one O(5)Li4V2 octahedra,  an edgeedge with one O(6)Li4V2 octahedra, edges with two equivalent O(3)Li2VNi3 octahedra, edges with two equivalent O(4)Li2VNi3 octahedra, edges with two equivalent O(7)Li3VNi2 octahedra, and edges with two equivalent O(10)Li4VNi octahedra. The corner-sharing octahedral tilt angles range from 0-10°. In the third O site, O(3) is bonded to one Li(4), one Li(5), one V(1), one Ni(1), one Ni(2), and one Ni(3) atom to form OLi2VNi3 octahedra that share  a cornercorner with one O(1)Li2VNi3 octahedra,  a cornercorner with one O(4)Li2VNi3 octahedra,  a cornercorner with one O(7)Li3VNi2 octahedra,  a cornercorner with one O(9)Li4VNi octahedra, corners with two equivalent O(6)Li4V2 octahedra,  an edgeedge with one O(7)Li3VNi2 octahedra,  an edgeedge with one O(5)Li4V2 octahedra,  an edgeedge with one O(10)Li4VNi octahedra,  an edgeedge with one O(9)Li4VNi octahedra, edges with two equivalent O(1)Li2VNi3 octahedra, edges with two equivalent O(2)Li2VNi3 octahedra, edges with two equivalent O(4)Li2VNi3 octahedra, and edges with two equivalent O(8)Li3VNi2 octahedra. The corner-sharing octahedral tilt angles range from 1-9°. In the fourth O site, O(4) is bonded to one Li(4), one Li(5), one V(2), one Ni(1), one Ni(2), and one Ni(3) atom to form OLi2VNi3 octahedra that share  a cornercorner with one O(2)Li2VNi3 octahedra,  a cornercorner with one O(3)Li2VNi3 octahedra,  a cornercorner with one O(8)Li3VNi2 octahedra,  a cornercorner with one O(10)Li4VNi octahedra, corners with two equivalent O(5)Li4V2 octahedra,  an edgeedge with one O(8)Li3VNi2 octahedra,  an edgeedge with one O(6)Li4V2 octahedra,  an edgeedge with one O(10)Li4VNi octahedra,  an edgeedge with one O(9)Li4VNi octahedra, edges with two equivalent O(1)Li2VNi3 octahedra, edges with two equivalent O(2)Li2VNi3 octahedra, edges with two equivalent O(3)Li2VNi3 octahedra, and edges with two equivalent O(7)Li3VNi2 octahedra. The corner-sharing octahedral tilt angles range from 2-7°. In the fifth O site, O(5) is bonded to one Li(1), one Li(2), one Li(3), one Li(4), one V(1), and one V(2) atom to form OLi4V2 octahedra that share  a cornercorner with one O(1)Li2VNi3 octahedra,  a cornercorner with one O(7)Li3VNi2 octahedra,  a cornercorner with one O(6)Li4V2 octahedra,  a cornercorner with one O(9)Li4VNi octahedra, corners with two equivalent O(4)Li2VNi3 octahedra,  an edgeedge with one O(1)Li2VNi3 octahedra,  an edgeedge with one O(2)Li2VNi3 octahedra,  an edgeedge with one O(3)Li2VNi3 octahedra,  an edgeedge with one O(7)Li3VNi2 octahedra, edges with two equivalent O(8)Li3VNi2 octahedra, edges with two equivalent O(6)Li4V2 octahedra, edges with two equivalent O(10)Li4VNi octahedra, and edges with two equivalent O(9)Li4VNi octahedra. The corner-sharing octahedral tilt angles range from 3-9°. In the sixth O site, O(6) is bonded to one Li(1), one Li(2), one Li(3), one Li(5), one V(1), and one V(2) atom to form OLi4V2 octahedra that share  a cornercorner with one O(2)Li2VNi3 octahedra,  a cornercorner with one O(8)Li3VNi2 octahedra,  a cornercorner with one O(5)Li4V2 octahedra,  a cornercorner with one O(10)Li4VNi octahedra, corners with two equivalent O(3)Li2VNi3 octahedra,  an edgeedge with one O(1)Li2VNi3 octahedra,  an edgeedge with one O(2)Li2VNi3 octahedra,  an edgeedge with one O(4)Li2VNi3 octahedra,  an edgeedge with one O(8)Li3VNi2 octahedra, edges with two equivalent O(7)Li3VNi2 octahedra, edges with two equivalent O(5)Li4V2 octahedra, edges with two equivalent O(10)Li4VNi octahedra, and edges with two equivalent O(9)Li4VNi octahedra. The corner-sharing octahedral tilt angles range from 1-10°. In the seventh O site, O(7) is bonded to one Li(1), one Li(2), one Li(5), one V(2), one Ni(1), and one Ni(3) atom to form OLi3VNi2 octahedra that share  a cornercorner with one O(2)Li2VNi3 octahedra,  a cornercorner with one O(3)Li2VNi3 octahedra,  a cornercorner with one O(5)Li4V2 octahedra,  a cornercorner with one O(10)Li4VNi octahedra, corners with two equivalent O(8)Li3VNi2 octahedra,  an edgeedge with one O(1)Li2VNi3 octahedra,  an edgeedge with one O(3)Li2VNi3 octahedra,  an edgeedge with one O(5)Li4V2 octahedra,  an edgeedge with one O(9)Li4VNi octahedra, edges with two equivalent O(2)Li2VNi3 octahedra, edges with two equivalent O(4)Li2VNi3 octahedra, edges with two equivalent O(6)Li4V2 octahedra, and edges with two equivalent O(10)Li4VNi octahedra. The corner-sharing octahedral tilt angles range from 1-9°. In the eighth O site, O(8) is bonded to one Li(1), one Li(3), one Li(4), one V(1), one Ni(1), and one Ni(2) atom to form OLi3VNi2 octahedra that share  a cornercorner with one O(1)Li2VNi3 octahedra,  a cornercorner with one O(4)Li2VNi3 octahedra,  a cornercorner with one O(6)Li4V2 octahedra,  a cornercorner with one O(9)Li4VNi octahedra, corners with two equivalent O(7)Li3VNi2 octahedra,  an edgeedge with one O(2)Li2VNi3 octahedra,  an edgeedge with one O(4)Li2VNi3 octahedra,  an edgeedge with one O(6)Li4V2 octahedra,  an edgeedge with one O(10)Li4VNi octahedra, edges with two equivalent O(1)Li2VNi3 octahedra, edges with two equivalent O(3)Li2VNi3 octahedra, edges with two equivalent O(5)Li4V2 octahedra, and edges with two equivalent O(9)Li4VNi octahedra. The corner-sharing octahedral tilt angles range from 1-10°. In the ninth O site, O(9) is bonded to one Li(1), one Li(2), one Li(3), one Li(4), one V(1), and one Ni(2) atom to form OLi4VNi octahedra that share  a cornercorner with one O(3)Li2VNi3 octahedra,  a cornercorner with one O(8)Li3VNi2 octahedra,  a cornercorner with one O(5)Li4V2 octahedra,  a cornercorner with one O(10)Li4VNi octahedra, corners with two equivalent O(2)Li2VNi3 octahedra,  an edgeedge with one O(3)Li2VNi3 octahedra,  an edgeedge with one O(4)Li2VNi3 octahedra,  an edgeedge with one O(7)Li3VNi2 octahedra,  an edgeedge with one O(10)Li4VNi octahedra, edges with two equivalent O(1)Li2VNi3 octahedra, edges with two equivalent O(8)Li3VNi2 octahedra, edges with two equivalent O(5)Li4V2 octahedra, and edges with two equivalent O(6)Li4V2 octahedra. The corner-sharing octahedral tilt angles range from 1-10°. In the tenth O site, O(10) is bonded to one Li(1), one Li(2), one Li(3), one Li(5), one V(2), and one Ni(3) atom to form OLi4VNi octahedra that share  a cornercorner with one O(4)Li2VNi3 octahedra,  a cornercorner with one O(7)Li3VNi2 octahedra,  a cornercorner with one O(6)Li4V2 octahedra,  a cornercorner with one O(9)Li4VNi octahedra, corners with two equivalent O(1)Li2VNi3 octahedra,  an edgeedge with one O(3)Li2VNi3 octahedra,  an edgeedge with one O(4)Li2VNi3 octahedra,  an edgeedge with one O(8)Li3VNi2 octahedra,  an edgeedge with one O(9)Li4VNi octahedra, edges with two equivalent O(2)Li2VNi3 octahedra, edges with two equivalent O(7)Li3VNi2 octahedra, edges with two equivalent O(5)Li4V2 octahedra, and edges with two equivalent O(6)Li4V2 octahedra. The corner-sharing octahedral tilt angles range from 1-9°. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li5V2Ni3O10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.102
_cell_length_b   5.112
_cell_length_c   7.770
_cell_angle_alpha   108.859
_cell_angle_beta   108.423
_cell_angle_gamma   79.586
_symmetry_Int_Tables_number   1
_cell_volume   181.230
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.501  0.996  0.498  1.0
  Li  Li1  1  0.785  0.505  0.603  1.0
  Li  Li2  1  0.210  0.504  0.399  1.0
  Li  Li3  1  0.596  0.509  0.202  1.0
  Li  Li4  1  0.403  0.493  0.799  1.0
  Ni  Ni5  1  0.002  0.500  1.000  1.0
  Ni  Ni6  1  0.304  0.994  0.100  1.0
  Ni  Ni7  1  0.696  0.001  0.898  1.0
  O  O8  1  0.951  0.233  0.160  1.0
  O  O9  1  0.049  0.759  0.846  1.0
  O  O10  1  0.674  0.768  0.071  1.0
  O  O11  1  0.336  0.235  0.938  1.0
  O  O12  1  0.863  0.781  0.450  1.0
  O  O13  1  0.129  0.221  0.533  1.0
  O  O14  1  0.781  0.235  0.752  1.0
  O  O15  1  0.218  0.764  0.247  1.0
  O  O16  1  0.579  0.230  0.341  1.0
  O  O17  1  0.421  0.768  0.656  1.0
  V  V18  1  0.899  0.019  0.309  1.0
  V  V19  1  0.103  0.986  0.698  1.0
[/CIF]
.