The material structure described by MgV4ZnO10 crystallizes in the orthorhombic Amm2 space group. Mg(1) is bonded to one O(2) and four equivalent O(5) atoms to form distorted MgO5 square pyramids that share corners with six equivalent V(1)O5 trigonal bipyramids and edges with two equivalent Mg(1)O5 square pyramids. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(2), one O(3), one O(5), and two equivalent O(4) atoms to form distorted VO5 trigonal bipyramids that share corners with three equivalent Mg(1)O5 square pyramids and corners with three equivalent V(1)O5 trigonal bipyramids. In the second V site, V(2) is bonded in a 5-coordinate geometry to one O(1), one O(4), one O(6), and two equivalent O(3) atoms. Zn(1) is bonded in a 6-coordinate geometry to two equivalent O(2), two equivalent O(4), and two equivalent O(5) atoms. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to two equivalent V(2) atoms. In the second O site, O(2) is bonded in a 5-coordinate geometry to one Mg(1), two equivalent V(1), and two equivalent Zn(1) atoms. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one V(1) and two equivalent V(2) atoms. In the fourth O site, O(4) is bonded in a distorted see-saw-like geometry to one V(2), two equivalent V(1), and one Zn(1) atom. In the fifth O site, O(5) is bonded in a distorted see-saw-like geometry to two equivalent Mg(1), one V(1), and one Zn(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one V(2) atom. is represented by the CIF file [CIF]
data_MgV4ZnO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.801
_cell_length_b   5.615
_cell_length_c   11.410
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   109.784
_symmetry_Int_Tables_number   1
_cell_volume   229.171
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.543  0.085  0.750  1.0
  V  V1  1  0.205  0.411  0.594  1.0
  V  V2  1  0.799  0.598  0.401  1.0
  V  V3  1  0.799  0.598  0.099  1.0
  V  V4  1  0.205  0.411  0.906  1.0
  Zn  Zn5  1  0.866  0.733  0.750  1.0
  O  O6  1  0.750  0.500  0.250  1.0
  O  O7  1  0.322  0.644  0.750  1.0
  O  O8  1  0.250  0.500  0.065  1.0
  O  O9  1  0.754  0.508  0.911  1.0
  O  O10  1  0.754  0.508  0.589  1.0
  O  O11  1  0.250  0.500  0.435  1.0
  O  O12  1  0.043  0.086  0.644  1.0
  O  O13  1  0.952  0.903  0.399  1.0
  O  O14  1  0.043  0.086  0.856  1.0
  O  O15  1  0.952  0.903  0.101  1.0
[/CIF]
.
The material structure described by MgV4ZnO10 crystallizes in the orthorhombic Amm2 space group. Mg(1) is bonded to one O(2) and four equivalent O(5) atoms to form distorted MgO5 square pyramids that share corners with six equivalent V(1)O5 trigonal bipyramids and edges with two equivalent Mg(1)O5 square pyramids. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(2), one O(3), one O(5), and two equivalent O(4) atoms to form distorted VO5 trigonal bipyramids that share corners with three equivalent Mg(1)O5 square pyramids and corners with three equivalent V(1)O5 trigonal bipyramids. In the second V site, V(2) is bonded in a 5-coordinate geometry to one O(1), one O(4), one O(6), and two equivalent O(3) atoms. Zn(1) is bonded in a 6-coordinate geometry to two equivalent O(2), two equivalent O(4), and two equivalent O(5) atoms. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to two equivalent V(2) atoms. In the second O site, O(2) is bonded in a 5-coordinate geometry to one Mg(1), two equivalent V(1), and two equivalent Zn(1) atoms. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one V(1) and two equivalent V(2) atoms. In the fourth O site, O(4) is bonded in a distorted see-saw-like geometry to one V(2), two equivalent V(1), and one Zn(1) atom. In the fifth O site, O(5) is bonded in a distorted see-saw-like geometry to two equivalent Mg(1), one V(1), and one Zn(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one V(2) atom. is represented by the CIF file [CIF]
data_MgV4ZnO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.801
_cell_length_b   5.615
_cell_length_c   11.410
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   109.784
_symmetry_Int_Tables_number   1
_cell_volume   229.171
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.543  0.085  0.750  1.0
  V  V1  1  0.205  0.411  0.594  1.0
  V  V2  1  0.799  0.598  0.401  1.0
  V  V3  1  0.799  0.598  0.099  1.0
  V  V4  1  0.205  0.411  0.906  1.0
  Zn  Zn5  1  0.866  0.733  0.750  1.0
  O  O6  1  0.750  0.500  0.250  1.0
  O  O7  1  0.322  0.644  0.750  1.0
  O  O8  1  0.250  0.500  0.065  1.0
  O  O9  1  0.754  0.508  0.911  1.0
  O  O10  1  0.754  0.508  0.589  1.0
  O  O11  1  0.250  0.500  0.435  1.0
  O  O12  1  0.043  0.086  0.644  1.0
  O  O13  1  0.952  0.903  0.399  1.0
  O  O14  1  0.043  0.086  0.856  1.0
  O  O15  1  0.952  0.903  0.101  1.0
[/CIF]
.