The structure described by AlVMoO7 crystallizes in the orthorhombic Pnma space group. V(1) is bonded in a 5-coordinate geometry to one O(1) and four equivalent O(2) atoms. Mo(1) is bonded to one O(4), one O(5), and two equivalent O(3) atoms to form MoO4 tetrahedra that share corners with four equivalent Al(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 11-17°. Al(1) is bonded to one O(4), one O(5), two equivalent O(2), and two equivalent O(3) atoms to form AlO6 octahedra that share corners with four equivalent Mo(1)O4 tetrahedra. There are five inequivalent O sites. In the first O site, O(4) is bonded in a linear geometry to one Mo(1) and one Al(1) atom. In the second O site, O(5) is bonded in a linear geometry to one Mo(1) and one Al(1) atom. In the third O site, O(1) is bonded in a single-bond geometry to one V(1) atom. In the fourth O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to two equivalent V(1) and one Al(1) atom. In the fifth O site, O(3) is bonded in a linear geometry to one Mo(1) and one Al(1) atom. is represented by the CIF file [CIF]
data_AlVMoO7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.451
_cell_length_b   8.305
_cell_length_c   12.962
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   586.848
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  0.750  0.234  0.112  1.0
  Al  Al1  1  0.250  0.766  0.888  1.0
  Al  Al2  1  0.250  0.734  0.388  1.0
  Al  Al3  1  0.750  0.266  0.612  1.0
  V  V4  1  0.250  0.433  0.985  1.0
  V  V5  1  0.750  0.567  0.015  1.0
  V  V6  1  0.750  0.933  0.515  1.0
  V  V7  1  0.250  0.067  0.485  1.0
  Mo  Mo8  1  0.750  0.045  0.855  1.0
  Mo  Mo9  1  0.250  0.955  0.145  1.0
  Mo  Mo10  1  0.250  0.545  0.645  1.0
  Mo  Mo11  1  0.750  0.455  0.355  1.0
  O  O12  1  0.250  0.284  0.905  1.0
  O  O13  1  0.750  0.716  0.095  1.0
  O  O14  1  0.750  0.784  0.595  1.0
  O  O15  1  0.250  0.216  0.405  1.0
  O  O16  1  0.022  0.599  0.931  1.0
  O  O17  1  0.522  0.401  0.069  1.0
  O  O18  1  0.978  0.099  0.569  1.0
  O  O19  1  0.478  0.901  0.431  1.0
  O  O20  1  0.978  0.401  0.069  1.0
  O  O21  1  0.478  0.599  0.931  1.0
  O  O22  1  0.022  0.901  0.431  1.0
  O  O23  1  0.522  0.099  0.569  1.0
  O  O24  1  0.491  0.586  0.351  1.0
  O  O25  1  0.991  0.414  0.649  1.0
  O  O26  1  0.509  0.086  0.149  1.0
  O  O27  1  0.009  0.914  0.851  1.0
  O  O28  1  0.509  0.414  0.649  1.0
  O  O29  1  0.009  0.586  0.351  1.0
  O  O30  1  0.491  0.914  0.851  1.0
  O  O31  1  0.991  0.086  0.149  1.0
  O  O32  1  0.750  0.344  0.474  1.0
  O  O33  1  0.250  0.656  0.526  1.0
  O  O34  1  0.250  0.844  0.026  1.0
  O  O35  1  0.750  0.156  0.974  1.0
  O  O36  1  0.750  0.322  0.246  1.0
  O  O37  1  0.250  0.678  0.754  1.0
  O  O38  1  0.250  0.822  0.254  1.0
  O  O39  1  0.750  0.178  0.746  1.0
[/CIF]
.
The structure described by AlVMoO7 crystallizes in the orthorhombic Pnma space group. V(1) is bonded in a 5-coordinate geometry to one O(1) and four equivalent O(2) atoms. Mo(1) is bonded to one O(4), one O(5), and two equivalent O(3) atoms to form MoO4 tetrahedra that share corners with four equivalent Al(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 11-17°. Al(1) is bonded to one O(4), one O(5), two equivalent O(2), and two equivalent O(3) atoms to form AlO6 octahedra that share corners with four equivalent Mo(1)O4 tetrahedra. There are five inequivalent O sites. In the first O site, O(4) is bonded in a linear geometry to one Mo(1) and one Al(1) atom. In the second O site, O(5) is bonded in a linear geometry to one Mo(1) and one Al(1) atom. In the third O site, O(1) is bonded in a single-bond geometry to one V(1) atom. In the fourth O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to two equivalent V(1) and one Al(1) atom. In the fifth O site, O(3) is bonded in a linear geometry to one Mo(1) and one Al(1) atom. is represented by the CIF file [CIF]
data_AlVMoO7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.451
_cell_length_b   8.305
_cell_length_c   12.962
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   586.848
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  0.750  0.234  0.112  1.0
  Al  Al1  1  0.250  0.766  0.888  1.0
  Al  Al2  1  0.250  0.734  0.388  1.0
  Al  Al3  1  0.750  0.266  0.612  1.0
  V  V4  1  0.250  0.433  0.985  1.0
  V  V5  1  0.750  0.567  0.015  1.0
  V  V6  1  0.750  0.933  0.515  1.0
  V  V7  1  0.250  0.067  0.485  1.0
  Mo  Mo8  1  0.750  0.045  0.855  1.0
  Mo  Mo9  1  0.250  0.955  0.145  1.0
  Mo  Mo10  1  0.250  0.545  0.645  1.0
  Mo  Mo11  1  0.750  0.455  0.355  1.0
  O  O12  1  0.250  0.284  0.905  1.0
  O  O13  1  0.750  0.716  0.095  1.0
  O  O14  1  0.750  0.784  0.595  1.0
  O  O15  1  0.250  0.216  0.405  1.0
  O  O16  1  0.022  0.599  0.931  1.0
  O  O17  1  0.522  0.401  0.069  1.0
  O  O18  1  0.978  0.099  0.569  1.0
  O  O19  1  0.478  0.901  0.431  1.0
  O  O20  1  0.978  0.401  0.069  1.0
  O  O21  1  0.478  0.599  0.931  1.0
  O  O22  1  0.022  0.901  0.431  1.0
  O  O23  1  0.522  0.099  0.569  1.0
  O  O24  1  0.491  0.586  0.351  1.0
  O  O25  1  0.991  0.414  0.649  1.0
  O  O26  1  0.509  0.086  0.149  1.0
  O  O27  1  0.009  0.914  0.851  1.0
  O  O28  1  0.509  0.414  0.649  1.0
  O  O29  1  0.009  0.586  0.351  1.0
  O  O30  1  0.491  0.914  0.851  1.0
  O  O31  1  0.991  0.086  0.149  1.0
  O  O32  1  0.750  0.344  0.474  1.0
  O  O33  1  0.250  0.656  0.526  1.0
  O  O34  1  0.250  0.844  0.026  1.0
  O  O35  1  0.750  0.156  0.974  1.0
  O  O36  1  0.750  0.322  0.246  1.0
  O  O37  1  0.250  0.678  0.754  1.0
  O  O38  1  0.250  0.822  0.254  1.0
  O  O39  1  0.750  0.178  0.746  1.0
[/CIF]
.