The structure described by NiO6(NO)2(SO3)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four nitroxyl molecules, four sulfur trioxide molecules, and two NiO6 clusters. In each NiO6 cluster, Ni(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent O(6) and two equivalent O(7) atoms. There are three inequivalent O sites. In the first O site, O(7) is bonded in an L-shaped geometry to one Ni(1) and one O(5) atom. In the second O site, O(5) is bonded in a water-like geometry to one O(6) and one O(7) atom. In the third O site, O(6) is bonded in an L-shaped geometry to one Ni(1) and one O(5) atom. is represented by the CIF file [CIF]
data_NiS2(NO7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.693
_cell_length_b   6.785
_cell_length_c   9.271
_cell_angle_alpha   64.902
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   780.024
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni0  1  0.500  0.000  0.500  1.0
  Ni  Ni1  1  0.000  0.000  0.000  1.0
  S  S2  1  0.870  0.691  0.553  1.0
  S  S3  1  0.370  0.309  0.947  1.0
  S  S4  1  0.130  0.309  0.447  1.0
  S  S5  1  0.630  0.691  0.053  1.0
  N  N6  1  0.182  0.770  0.581  1.0
  N  N7  1  0.682  0.230  0.919  1.0
  N  N8  1  0.818  0.230  0.419  1.0
  N  N9  1  0.318  0.770  0.081  1.0
  O  O10  1  0.768  0.640  0.576  1.0
  O  O11  1  0.268  0.360  0.924  1.0
  O  O12  1  0.232  0.360  0.424  1.0
  O  O13  1  0.732  0.640  0.076  1.0
  O  O14  1  0.848  0.095  0.537  1.0
  O  O15  1  0.348  0.905  0.963  1.0
  O  O16  1  0.152  0.905  0.463  1.0
  O  O17  1  0.652  0.095  0.037  1.0
  O  O18  1  0.936  0.621  0.687  1.0
  O  O19  1  0.436  0.379  0.813  1.0
  O  O20  1  0.064  0.379  0.313  1.0
  O  O21  1  0.564  0.621  0.187  1.0
  O  O22  1  0.910  0.786  0.394  1.0
  O  O23  1  0.410  0.214  0.106  1.0
  O  O24  1  0.090  0.214  0.606  1.0
  O  O25  1  0.590  0.786  0.894  1.0
  O  O26  1  0.394  0.744  0.466  1.0
  O  O27  1  0.894  0.256  0.034  1.0
  O  O28  1  0.606  0.256  0.534  1.0
  O  O29  1  0.106  0.744  0.966  1.0
  O  O30  1  0.370  0.890  0.530  1.0
  O  O31  1  0.870  0.110  0.970  1.0
  O  O32  1  0.630  0.110  0.470  1.0
  O  O33  1  0.130  0.890  0.030  1.0
  O  O34  1  0.492  0.775  0.429  1.0
  O  O35  1  0.992  0.225  0.071  1.0
  O  O36  1  0.508  0.225  0.571  1.0
  O  O37  1  0.008  0.775  0.929  1.0
[/CIF]
.
The structure described by NiO6(NO)2(SO3)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four nitroxyl molecules, four sulfur trioxide molecules, and two NiO6 clusters. In each NiO6 cluster, Ni(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent O(6) and two equivalent O(7) atoms. There are three inequivalent O sites. In the first O site, O(7) is bonded in an L-shaped geometry to one Ni(1) and one O(5) atom. In the second O site, O(5) is bonded in a water-like geometry to one O(6) and one O(7) atom. In the third O site, O(6) is bonded in an L-shaped geometry to one Ni(1) and one O(5) atom. is represented by the CIF file [CIF]
data_NiS2(NO7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.693
_cell_length_b   6.785
_cell_length_c   9.271
_cell_angle_alpha   64.902
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   780.024
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni0  1  0.500  0.000  0.500  1.0
  Ni  Ni1  1  0.000  0.000  0.000  1.0
  S  S2  1  0.870  0.691  0.553  1.0
  S  S3  1  0.370  0.309  0.947  1.0
  S  S4  1  0.130  0.309  0.447  1.0
  S  S5  1  0.630  0.691  0.053  1.0
  N  N6  1  0.182  0.770  0.581  1.0
  N  N7  1  0.682  0.230  0.919  1.0
  N  N8  1  0.818  0.230  0.419  1.0
  N  N9  1  0.318  0.770  0.081  1.0
  O  O10  1  0.768  0.640  0.576  1.0
  O  O11  1  0.268  0.360  0.924  1.0
  O  O12  1  0.232  0.360  0.424  1.0
  O  O13  1  0.732  0.640  0.076  1.0
  O  O14  1  0.848  0.095  0.537  1.0
  O  O15  1  0.348  0.905  0.963  1.0
  O  O16  1  0.152  0.905  0.463  1.0
  O  O17  1  0.652  0.095  0.037  1.0
  O  O18  1  0.936  0.621  0.687  1.0
  O  O19  1  0.436  0.379  0.813  1.0
  O  O20  1  0.064  0.379  0.313  1.0
  O  O21  1  0.564  0.621  0.187  1.0
  O  O22  1  0.910  0.786  0.394  1.0
  O  O23  1  0.410  0.214  0.106  1.0
  O  O24  1  0.090  0.214  0.606  1.0
  O  O25  1  0.590  0.786  0.894  1.0
  O  O26  1  0.394  0.744  0.466  1.0
  O  O27  1  0.894  0.256  0.034  1.0
  O  O28  1  0.606  0.256  0.534  1.0
  O  O29  1  0.106  0.744  0.966  1.0
  O  O30  1  0.370  0.890  0.530  1.0
  O  O31  1  0.870  0.110  0.970  1.0
  O  O32  1  0.630  0.110  0.470  1.0
  O  O33  1  0.130  0.890  0.030  1.0
  O  O34  1  0.492  0.775  0.429  1.0
  O  O35  1  0.992  0.225  0.071  1.0
  O  O36  1  0.508  0.225  0.571  1.0
  O  O37  1  0.008  0.775  0.929  1.0
[/CIF]
.