The material described by ReO3Cl is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four ReO3Cl clusters. Re(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one Cl(1) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Re(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Re(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Re(1) atom. Cl(1) is bonded in a single-bond geometry to one Re(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_ReClO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.048
_cell_length_b   5.590
_cell_length_c   9.017
_cell_angle_alpha   57.030
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   382.570
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.273  0.424  0.771  1.0
  Re  Re1  1  0.773  0.576  0.729  1.0
  Re  Re2  1  0.727  0.576  0.229  1.0
  Re  Re3  1  0.227  0.424  0.271  1.0
  Cl  Cl4  1  0.426  0.151  0.733  1.0
  Cl  Cl5  1  0.926  0.849  0.767  1.0
  Cl  Cl6  1  0.574  0.849  0.267  1.0
  Cl  Cl7  1  0.074  0.151  0.233  1.0
  O  O8  1  0.328  0.427  0.952  1.0
  O  O9  1  0.828  0.573  0.548  1.0
  O  O10  1  0.672  0.573  0.048  1.0
  O  O11  1  0.172  0.427  0.452  1.0
  O  O12  1  0.095  0.300  0.810  1.0
  O  O13  1  0.595  0.700  0.690  1.0
  O  O14  1  0.905  0.700  0.190  1.0
  O  O15  1  0.405  0.300  0.310  1.0
  O  O16  1  0.270  0.771  0.595  1.0
  O  O17  1  0.770  0.229  0.905  1.0
  O  O18  1  0.730  0.229  0.405  1.0
  O  O19  1  0.230  0.771  0.095  1.0
[/CIF]
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The material described by ReO3Cl is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four ReO3Cl clusters. Re(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one Cl(1) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Re(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Re(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Re(1) atom. Cl(1) is bonded in a single-bond geometry to one Re(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_ReClO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.048
_cell_length_b   5.590
_cell_length_c   9.017
_cell_angle_alpha   57.030
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   382.570
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.273  0.424  0.771  1.0
  Re  Re1  1  0.773  0.576  0.729  1.0
  Re  Re2  1  0.727  0.576  0.229  1.0
  Re  Re3  1  0.227  0.424  0.271  1.0
  Cl  Cl4  1  0.426  0.151  0.733  1.0
  Cl  Cl5  1  0.926  0.849  0.767  1.0
  Cl  Cl6  1  0.574  0.849  0.267  1.0
  Cl  Cl7  1  0.074  0.151  0.233  1.0
  O  O8  1  0.328  0.427  0.952  1.0
  O  O9  1  0.828  0.573  0.548  1.0
  O  O10  1  0.672  0.573  0.048  1.0
  O  O11  1  0.172  0.427  0.452  1.0
  O  O12  1  0.095  0.300  0.810  1.0
  O  O13  1  0.595  0.700  0.690  1.0
  O  O14  1  0.905  0.700  0.190  1.0
  O  O15  1  0.405  0.300  0.310  1.0
  O  O16  1  0.270  0.771  0.595  1.0
  O  O17  1  0.770  0.229  0.905  1.0
  O  O18  1  0.730  0.229  0.405  1.0
  O  O19  1  0.230  0.771  0.095  1.0
[/CIF]
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