The crystal structure described by (Mn(PO3)3)2N2 crystallizes in the hexagonal P-6c2 space group. The structure consists of two ammonia atoms inside a Mn(PO3)3 framework. In the Mn(PO3)3 framework, Mn(1) is bonded to six equivalent O(1) atoms to form MnO6 octahedra that share corners with six equivalent P(1)O4 tetrahedra. P(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form PO4 tetrahedra that share corners with two equivalent Mn(1)O6 octahedra and corners with two equivalent P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 40°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Mn(1) and one P(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent P(1) atoms. is represented by the CIF card [CIF]
data_MnP3NO9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.659
_cell_length_b   6.659
_cell_length_c   9.877
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   379.222
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.000  0.000  0.000  1.0
  Mn  Mn1  1  0.000  0.000  0.500  1.0
  P  P2  1  0.725  0.108  0.250  1.0
  P  P3  1  0.892  0.617  0.250  1.0
  P  P4  1  0.725  0.617  0.750  1.0
  P  P5  1  0.383  0.275  0.250  1.0
  P  P6  1  0.892  0.275  0.750  1.0
  P  P7  1  0.383  0.108  0.750  1.0
  N  N8  1  0.333  0.667  0.000  1.0
  N  N9  1  0.333  0.667  0.500  1.0
  O  O10  1  0.257  0.253  0.120  1.0
  O  O11  1  0.747  0.003  0.120  1.0
  O  O12  1  0.257  0.253  0.380  1.0
  O  O13  1  0.257  0.003  0.620  1.0
  O  O14  1  0.997  0.743  0.120  1.0
  O  O15  1  0.747  0.003  0.380  1.0
  O  O16  1  0.747  0.743  0.620  1.0
  O  O17  1  0.257  0.003  0.880  1.0
  O  O18  1  0.997  0.743  0.380  1.0
  O  O19  1  0.747  0.743  0.880  1.0
  O  O20  1  0.997  0.253  0.620  1.0
  O  O21  1  0.997  0.253  0.880  1.0
  O  O22  1  0.477  0.094  0.250  1.0
  O  O23  1  0.906  0.384  0.250  1.0
  O  O24  1  0.477  0.384  0.750  1.0
  O  O25  1  0.616  0.523  0.250  1.0
  O  O26  1  0.906  0.523  0.750  1.0
  O  O27  1  0.616  0.094  0.750  1.0
[/CIF]
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The crystal structure described by (Mn(PO3)3)2N2 crystallizes in the hexagonal P-6c2 space group. The structure consists of two ammonia atoms inside a Mn(PO3)3 framework. In the Mn(PO3)3 framework, Mn(1) is bonded to six equivalent O(1) atoms to form MnO6 octahedra that share corners with six equivalent P(1)O4 tetrahedra. P(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form PO4 tetrahedra that share corners with two equivalent Mn(1)O6 octahedra and corners with two equivalent P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 40°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Mn(1) and one P(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent P(1) atoms. is represented by the CIF card [CIF]
data_MnP3NO9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.659
_cell_length_b   6.659
_cell_length_c   9.877
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   379.222
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.000  0.000  0.000  1.0
  Mn  Mn1  1  0.000  0.000  0.500  1.0
  P  P2  1  0.725  0.108  0.250  1.0
  P  P3  1  0.892  0.617  0.250  1.0
  P  P4  1  0.725  0.617  0.750  1.0
  P  P5  1  0.383  0.275  0.250  1.0
  P  P6  1  0.892  0.275  0.750  1.0
  P  P7  1  0.383  0.108  0.750  1.0
  N  N8  1  0.333  0.667  0.000  1.0
  N  N9  1  0.333  0.667  0.500  1.0
  O  O10  1  0.257  0.253  0.120  1.0
  O  O11  1  0.747  0.003  0.120  1.0
  O  O12  1  0.257  0.253  0.380  1.0
  O  O13  1  0.257  0.003  0.620  1.0
  O  O14  1  0.997  0.743  0.120  1.0
  O  O15  1  0.747  0.003  0.380  1.0
  O  O16  1  0.747  0.743  0.620  1.0
  O  O17  1  0.257  0.003  0.880  1.0
  O  O18  1  0.997  0.743  0.380  1.0
  O  O19  1  0.747  0.743  0.880  1.0
  O  O20  1  0.997  0.253  0.620  1.0
  O  O21  1  0.997  0.253  0.880  1.0
  O  O22  1  0.477  0.094  0.250  1.0
  O  O23  1  0.906  0.384  0.250  1.0
  O  O24  1  0.477  0.384  0.750  1.0
  O  O25  1  0.616  0.523  0.250  1.0
  O  O26  1  0.906  0.523  0.750  1.0
  O  O27  1  0.616  0.094  0.750  1.0
[/CIF]
.