The crystal structure described by Li2V3O6 crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(2), one O(4), one O(6), one O(8), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one V(5)O6 octahedra,  a cornercorner with one V(6)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one V(5)O6 octahedra,  an edgeedge with one V(6)O6 octahedra, and edges with two equivalent Li(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-11°. In the second Li site, Li(2) is bonded to one O(1), one O(10), one O(12), one O(3), one O(5), and one O(7) atom to form LiO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one V(5)O6 octahedra,  a cornercorner with one V(6)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one V(5)O6 octahedra,  an edgeedge with one V(6)O6 octahedra, and edges with two equivalent Li(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-12°. In the third Li site, Li(3) is bonded to one O(10), one O(12), one O(2), one O(4), one O(5), and one O(7) atom to form LiO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one V(5)O6 octahedra,  a cornercorner with one V(6)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one V(5)O6 octahedra,  an edgeedge with one V(6)O6 octahedra, and edges with two equivalent Li(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-12°. In the fourth Li site, Li(4) is bonded to one O(1), one O(11), one O(3), one O(6), one O(8), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one V(5)O6 octahedra,  a cornercorner with one V(6)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one V(5)O6 octahedra,  an edgeedge with one V(6)O6 octahedra, and edges with two equivalent Li(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-12°. There are six inequivalent V sites. In the first V site, V(1) is bonded to one O(11), one O(2), one O(3), one O(5), one O(7), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one V(6)O6 octahedra, edges with two equivalent V(3)O6 octahedra, and edges with two equivalent V(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 10-12°. In the second V site, V(2) is bonded to one O(1), one O(10), one O(12), one O(4), one O(6), and one O(8) atom to form VO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(5)O6 octahedra, edges with two equivalent V(4)O6 octahedra, and edges with two equivalent V(6)O6 octahedra. The corner-sharing octahedral tilt angles are 8°. In the third V site, V(3) is bonded to one O(1), one O(11), one O(4), one O(5), one O(7), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(5)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent V(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-8°. In the fourth V site, V(4) is bonded to one O(10), one O(12), one O(2), one O(3), one O(6), and one O(8) atom to form VO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(6)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with two equivalent V(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-12°. In the fifth V site, V(5) is bonded to one O(10), one O(11), one O(2), one O(3), one O(6), and one O(7) atom to form VO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-12°. In the sixth V site, V(6) is bonded to one O(1), one O(12), one O(4), one O(5), one O(8), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with two equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-10°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded to one Li(2), one Li(4), one V(2), one V(3), and one V(6) atom to form a mixture of edge and corner-sharing OLi2V3 square pyramids. In the second O site, O(2) is bonded to one Li(1), one Li(3), one V(1), one V(4), and one V(5) atom to form a mixture of edge and corner-sharing OLi2V3 square pyramids. In the third O site, O(3) is bonded to one Li(2), one Li(4), one V(1), one V(4), and one V(5) atom to form a mixture of edge and corner-sharing OLi2V3 square pyramids. In the fourth O site, O(4) is bonded to one Li(1), one Li(3), one V(2), one V(3), and one V(6) atom to form a mixture of edge and corner-sharing OLi2V3 square pyramids. In the fifth O site, O(5) is bonded to one Li(2), one Li(3), one V(1), one V(3), and one V(6) atom to form a mixture of edge and corner-sharing OLi2V3 square pyramids. In the sixth O site, O(6) is bonded to one Li(1), one Li(4), one V(2), one V(4), and one V(5) atom to form a mixture of edge and corner-sharing OLi2V3 square pyramids. In the seventh O site, O(7) is bonded to one Li(2), one Li(3), one V(1), one V(3), and one V(5) atom to form a mixture of edge and corner-sharing OLi2V3 square pyramids. In the eighth O site, O(8) is bonded to one Li(1), one Li(4), one V(2), one V(4), and one V(6) atom to form a mixture of edge and corner-sharing OLi2V3 square pyramids. In the ninth O site, O(9) is bonded to one Li(1), one Li(4), one V(1), one V(3), and one V(6) atom to form a mixture of edge and corner-sharing OLi2V3 square pyramids. In the tenth O site, O(10) is bonded to one Li(2), one Li(3), one V(2), one V(4), and one V(5) atom to form a mixture of edge and corner-sharing OLi2V3 square pyramids. In the eleventh O site, O(11) is bonded to one Li(1), one Li(4), one V(1), one V(3), and one V(5) atom to form a mixture of edge and corner-sharing OLi2V3 square pyramids. In the twelfth O site, O(12) is bonded to one Li(2), one Li(3), one V(2), one V(4), and one V(6) atom to form a mixture of edge and corner-sharing OLi2V3 square pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li2V3O6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.183
_cell_length_b   6.752
_cell_length_c   6.685
_cell_angle_alpha   96.856
_cell_angle_beta   82.371
_cell_angle_gamma   98.381
_symmetry_Int_Tables_number   1
_cell_volume   228.187
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.005  0.674  0.670  1.0
  Li  Li1  1  0.494  0.168  0.171  1.0
  Li  Li2  1  0.001  0.329  0.327  1.0
  Li  Li3  1  0.496  0.829  0.830  1.0
  V  V4  1  0.748  0.583  0.083  1.0
  V  V5  1  0.253  0.086  0.589  1.0
  V  V6  1  0.249  0.412  0.908  1.0
  V  V7  1  0.751  0.917  0.417  1.0
  V  V8  1  0.248  0.752  0.250  1.0
  V  V9  1  0.751  0.249  0.752  1.0
  O  O10  1  0.386  0.144  0.866  1.0
  O  O11  1  0.904  0.643  0.355  1.0
  O  O12  1  0.595  0.852  0.142  1.0
  O  O13  1  0.121  0.370  0.650  1.0
  O  O14  1  0.879  0.316  0.033  1.0
  O  O15  1  0.370  0.809  0.527  1.0
  O  O16  1  0.357  0.468  0.181  1.0
  O  O17  1  0.877  0.971  0.690  1.0
  O  O18  1  0.619  0.527  0.812  1.0
  O  O19  1  0.134  0.027  0.310  1.0
  O  O20  1  0.135  0.686  0.969  1.0
  O  O21  1  0.627  0.188  0.468  1.0
[/CIF]
.
The crystal structure described by Li2V3O6 crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(2), one O(4), one O(6), one O(8), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one V(5)O6 octahedra,  a cornercorner with one V(6)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one V(5)O6 octahedra,  an edgeedge with one V(6)O6 octahedra, and edges with two equivalent Li(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-11°. In the second Li site, Li(2) is bonded to one O(1), one O(10), one O(12), one O(3), one O(5), and one O(7) atom to form LiO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one V(5)O6 octahedra,  a cornercorner with one V(6)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one V(5)O6 octahedra,  an edgeedge with one V(6)O6 octahedra, and edges with two equivalent Li(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-12°. In the third Li site, Li(3) is bonded to one O(10), one O(12), one O(2), one O(4), one O(5), and one O(7) atom to form LiO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one V(5)O6 octahedra,  a cornercorner with one V(6)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one V(5)O6 octahedra,  an edgeedge with one V(6)O6 octahedra, and edges with two equivalent Li(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-12°. In the fourth Li site, Li(4) is bonded to one O(1), one O(11), one O(3), one O(6), one O(8), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one V(5)O6 octahedra,  a cornercorner with one V(6)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one V(5)O6 octahedra,  an edgeedge with one V(6)O6 octahedra, and edges with two equivalent Li(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-12°. There are six inequivalent V sites. In the first V site, V(1) is bonded to one O(11), one O(2), one O(3), one O(5), one O(7), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one V(6)O6 octahedra, edges with two equivalent V(3)O6 octahedra, and edges with two equivalent V(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 10-12°. In the second V site, V(2) is bonded to one O(1), one O(10), one O(12), one O(4), one O(6), and one O(8) atom to form VO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(5)O6 octahedra, edges with two equivalent V(4)O6 octahedra, and edges with two equivalent V(6)O6 octahedra. The corner-sharing octahedral tilt angles are 8°. In the third V site, V(3) is bonded to one O(1), one O(11), one O(4), one O(5), one O(7), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(5)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent V(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-8°. In the fourth V site, V(4) is bonded to one O(10), one O(12), one O(2), one O(3), one O(6), and one O(8) atom to form VO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(6)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with two equivalent V(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-12°. In the fifth V site, V(5) is bonded to one O(10), one O(11), one O(2), one O(3), one O(6), and one O(7) atom to form VO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-12°. In the sixth V site, V(6) is bonded to one O(1), one O(12), one O(4), one O(5), one O(8), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(4)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with two equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-10°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded to one Li(2), one Li(4), one V(2), one V(3), and one V(6) atom to form a mixture of edge and corner-sharing OLi2V3 square pyramids. In the second O site, O(2) is bonded to one Li(1), one Li(3), one V(1), one V(4), and one V(5) atom to form a mixture of edge and corner-sharing OLi2V3 square pyramids. In the third O site, O(3) is bonded to one Li(2), one Li(4), one V(1), one V(4), and one V(5) atom to form a mixture of edge and corner-sharing OLi2V3 square pyramids. In the fourth O site, O(4) is bonded to one Li(1), one Li(3), one V(2), one V(3), and one V(6) atom to form a mixture of edge and corner-sharing OLi2V3 square pyramids. In the fifth O site, O(5) is bonded to one Li(2), one Li(3), one V(1), one V(3), and one V(6) atom to form a mixture of edge and corner-sharing OLi2V3 square pyramids. In the sixth O site, O(6) is bonded to one Li(1), one Li(4), one V(2), one V(4), and one V(5) atom to form a mixture of edge and corner-sharing OLi2V3 square pyramids. In the seventh O site, O(7) is bonded to one Li(2), one Li(3), one V(1), one V(3), and one V(5) atom to form a mixture of edge and corner-sharing OLi2V3 square pyramids. In the eighth O site, O(8) is bonded to one Li(1), one Li(4), one V(2), one V(4), and one V(6) atom to form a mixture of edge and corner-sharing OLi2V3 square pyramids. In the ninth O site, O(9) is bonded to one Li(1), one Li(4), one V(1), one V(3), and one V(6) atom to form a mixture of edge and corner-sharing OLi2V3 square pyramids. In the tenth O site, O(10) is bonded to one Li(2), one Li(3), one V(2), one V(4), and one V(5) atom to form a mixture of edge and corner-sharing OLi2V3 square pyramids. In the eleventh O site, O(11) is bonded to one Li(1), one Li(4), one V(1), one V(3), and one V(5) atom to form a mixture of edge and corner-sharing OLi2V3 square pyramids. In the twelfth O site, O(12) is bonded to one Li(2), one Li(3), one V(2), one V(4), and one V(6) atom to form a mixture of edge and corner-sharing OLi2V3 square pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li2V3O6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.183
_cell_length_b   6.752
_cell_length_c   6.685
_cell_angle_alpha   96.856
_cell_angle_beta   82.371
_cell_angle_gamma   98.381
_symmetry_Int_Tables_number   1
_cell_volume   228.187
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.005  0.674  0.670  1.0
  Li  Li1  1  0.494  0.168  0.171  1.0
  Li  Li2  1  0.001  0.329  0.327  1.0
  Li  Li3  1  0.496  0.829  0.830  1.0
  V  V4  1  0.748  0.583  0.083  1.0
  V  V5  1  0.253  0.086  0.589  1.0
  V  V6  1  0.249  0.412  0.908  1.0
  V  V7  1  0.751  0.917  0.417  1.0
  V  V8  1  0.248  0.752  0.250  1.0
  V  V9  1  0.751  0.249  0.752  1.0
  O  O10  1  0.386  0.144  0.866  1.0
  O  O11  1  0.904  0.643  0.355  1.0
  O  O12  1  0.595  0.852  0.142  1.0
  O  O13  1  0.121  0.370  0.650  1.0
  O  O14  1  0.879  0.316  0.033  1.0
  O  O15  1  0.370  0.809  0.527  1.0
  O  O16  1  0.357  0.468  0.181  1.0
  O  O17  1  0.877  0.971  0.690  1.0
  O  O18  1  0.619  0.527  0.812  1.0
  O  O19  1  0.134  0.027  0.310  1.0
  O  O20  1  0.135  0.686  0.969  1.0
  O  O21  1  0.627  0.188  0.468  1.0
[/CIF]
.