The material structure described by PuCP2O7 crystallizes in the monoclinic P2_1 space group. Pu(1) is bonded in a 7-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), and one O(7) atom. C(1) is bonded in a bent 150 degrees geometry to one P(1) and one P(2) atom. There are two inequivalent P sites. In the first P site, P(1) is bonded to one C(1), one O(1), one O(2), and one O(7) atom to form corner-sharing PCO3 tetrahedra. In the second P site, P(2) is bonded to one C(1), one O(3), one O(5), and one O(6) atom to form corner-sharing PCO3 tetrahedra. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a linear geometry to one Pu(1) and one P(1) atom. In the second O site, O(2) is bonded in a linear geometry to one Pu(1) and one P(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Pu(1) and one P(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Pu(1) atom. In the fifth O site, O(5) is bonded in a linear geometry to one Pu(1) and one P(2) atom. In the sixth O site, O(6) is bonded in a linear geometry to one Pu(1) and one P(2) atom. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Pu(1) and one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_PuP2CO7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.943
_cell_length_b   6.673
_cell_length_c   8.994
_cell_angle_alpha   102.738
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   347.855
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pu  Pu0  1  0.256  0.626  0.289  1.0
  Pu  Pu1  1  0.756  0.374  0.711  1.0
  P  P2  1  0.757  0.984  0.327  1.0
  P  P3  1  0.257  0.016  0.673  1.0
  P  P4  1  0.755  0.318  0.100  1.0
  P  P5  1  0.255  0.682  0.900  1.0
  C  C6  1  0.763  0.089  0.164  1.0
  C  C7  1  0.263  0.911  0.836  1.0
  O  O8  1  0.542  0.857  0.316  1.0
  O  O9  1  0.042  0.143  0.684  1.0
  O  O10  1  0.466  0.151  0.678  1.0
  O  O11  1  0.966  0.849  0.322  1.0
  O  O12  1  0.752  0.258  0.924  1.0
  O  O13  1  0.252  0.742  0.076  1.0
  O  O14  1  0.252  0.439  0.408  1.0
  O  O15  1  0.752  0.561  0.592  1.0
  O  O16  1  0.974  0.430  0.160  1.0
  O  O17  1  0.474  0.570  0.840  1.0
  O  O18  1  0.038  0.572  0.837  1.0
  O  O19  1  0.538  0.428  0.163  1.0
  O  O20  1  0.761  0.175  0.456  1.0
  O  O21  1  0.261  0.825  0.544  1.0
[/CIF]
.
The material structure described by PuCP2O7 crystallizes in the monoclinic P2_1 space group. Pu(1) is bonded in a 7-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), and one O(7) atom. C(1) is bonded in a bent 150 degrees geometry to one P(1) and one P(2) atom. There are two inequivalent P sites. In the first P site, P(1) is bonded to one C(1), one O(1), one O(2), and one O(7) atom to form corner-sharing PCO3 tetrahedra. In the second P site, P(2) is bonded to one C(1), one O(3), one O(5), and one O(6) atom to form corner-sharing PCO3 tetrahedra. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a linear geometry to one Pu(1) and one P(1) atom. In the second O site, O(2) is bonded in a linear geometry to one Pu(1) and one P(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Pu(1) and one P(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Pu(1) atom. In the fifth O site, O(5) is bonded in a linear geometry to one Pu(1) and one P(2) atom. In the sixth O site, O(6) is bonded in a linear geometry to one Pu(1) and one P(2) atom. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Pu(1) and one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_PuP2CO7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.943
_cell_length_b   6.673
_cell_length_c   8.994
_cell_angle_alpha   102.738
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   347.855
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pu  Pu0  1  0.256  0.626  0.289  1.0
  Pu  Pu1  1  0.756  0.374  0.711  1.0
  P  P2  1  0.757  0.984  0.327  1.0
  P  P3  1  0.257  0.016  0.673  1.0
  P  P4  1  0.755  0.318  0.100  1.0
  P  P5  1  0.255  0.682  0.900  1.0
  C  C6  1  0.763  0.089  0.164  1.0
  C  C7  1  0.263  0.911  0.836  1.0
  O  O8  1  0.542  0.857  0.316  1.0
  O  O9  1  0.042  0.143  0.684  1.0
  O  O10  1  0.466  0.151  0.678  1.0
  O  O11  1  0.966  0.849  0.322  1.0
  O  O12  1  0.752  0.258  0.924  1.0
  O  O13  1  0.252  0.742  0.076  1.0
  O  O14  1  0.252  0.439  0.408  1.0
  O  O15  1  0.752  0.561  0.592  1.0
  O  O16  1  0.974  0.430  0.160  1.0
  O  O17  1  0.474  0.570  0.840  1.0
  O  O18  1  0.038  0.572  0.837  1.0
  O  O19  1  0.538  0.428  0.163  1.0
  O  O20  1  0.761  0.175  0.456  1.0
  O  O21  1  0.261  0.825  0.544  1.0
[/CIF]
.