The material structure described by CsAuNH3 crystallizes in the monoclinic C2/c space group. Cs(1) is bonded in a 9-coordinate geometry to six equivalent Au(1), one N(1), one H(2), and one H(3) atom. Au(1) is bonded in a 8-coordinate geometry to six equivalent Cs(1) and two equivalent Au(1) atoms. N(1) is bonded in a trigonal non-coplanar geometry to one Cs(1), one H(1), one H(2), and one H(3) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one Cs(1) and one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one Cs(1) and one N(1) atom. is represented by the CIF card [CIF]
data_CsH3AuN
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.231
_cell_length_b   5.231
_cell_length_c   18.477
_cell_angle_alpha   87.216
_cell_angle_beta   87.216
_cell_angle_gamma   86.619
_symmetry_Int_Tables_number   1
_cell_volume   503.549
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.769  0.016  0.906  1.0
  Cs  Cs1  1  0.984  0.231  0.594  1.0
  Cs  Cs2  1  0.231  0.984  0.094  1.0
  Cs  Cs3  1  0.016  0.769  0.406  1.0
  H  H4  1  0.883  0.660  0.745  1.0
  H  H5  1  0.340  0.117  0.755  1.0
  H  H6  1  0.117  0.340  0.255  1.0
  H  H7  1  0.660  0.883  0.245  1.0
  H  H8  1  0.185  0.572  0.734  1.0
  H  H9  1  0.428  0.815  0.766  1.0
  H  H10  1  0.815  0.428  0.266  1.0
  H  H11  1  0.572  0.185  0.234  1.0
  H  H12  1  0.022  0.471  0.806  1.0
  H  H13  1  0.529  0.978  0.694  1.0
  H  H14  1  0.978  0.529  0.194  1.0
  H  H15  1  0.471  0.022  0.306  1.0
  Au  Au16  1  0.735  0.492  0.049  1.0
  Au  Au17  1  0.508  0.265  0.451  1.0
  Au  Au18  1  0.265  0.508  0.951  1.0
  Au  Au19  1  0.492  0.735  0.549  1.0
  N  N20  1  0.011  0.505  0.751  1.0
  N  N21  1  0.495  0.989  0.749  1.0
  N  N22  1  0.989  0.495  0.249  1.0
  N  N23  1  0.505  0.011  0.251  1.0
[/CIF]
.
The material structure described by CsAuNH3 crystallizes in the monoclinic C2/c space group. Cs(1) is bonded in a 9-coordinate geometry to six equivalent Au(1), one N(1), one H(2), and one H(3) atom. Au(1) is bonded in a 8-coordinate geometry to six equivalent Cs(1) and two equivalent Au(1) atoms. N(1) is bonded in a trigonal non-coplanar geometry to one Cs(1), one H(1), one H(2), and one H(3) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one Cs(1) and one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one Cs(1) and one N(1) atom. is represented by the CIF card [CIF]
data_CsH3AuN
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.231
_cell_length_b   5.231
_cell_length_c   18.477
_cell_angle_alpha   87.216
_cell_angle_beta   87.216
_cell_angle_gamma   86.619
_symmetry_Int_Tables_number   1
_cell_volume   503.549
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.769  0.016  0.906  1.0
  Cs  Cs1  1  0.984  0.231  0.594  1.0
  Cs  Cs2  1  0.231  0.984  0.094  1.0
  Cs  Cs3  1  0.016  0.769  0.406  1.0
  H  H4  1  0.883  0.660  0.745  1.0
  H  H5  1  0.340  0.117  0.755  1.0
  H  H6  1  0.117  0.340  0.255  1.0
  H  H7  1  0.660  0.883  0.245  1.0
  H  H8  1  0.185  0.572  0.734  1.0
  H  H9  1  0.428  0.815  0.766  1.0
  H  H10  1  0.815  0.428  0.266  1.0
  H  H11  1  0.572  0.185  0.234  1.0
  H  H12  1  0.022  0.471  0.806  1.0
  H  H13  1  0.529  0.978  0.694  1.0
  H  H14  1  0.978  0.529  0.194  1.0
  H  H15  1  0.471  0.022  0.306  1.0
  Au  Au16  1  0.735  0.492  0.049  1.0
  Au  Au17  1  0.508  0.265  0.451  1.0
  Au  Au18  1  0.265  0.508  0.951  1.0
  Au  Au19  1  0.492  0.735  0.549  1.0
  N  N20  1  0.011  0.505  0.751  1.0
  N  N21  1  0.495  0.989  0.749  1.0
  N  N22  1  0.989  0.495  0.249  1.0
  N  N23  1  0.505  0.011  0.251  1.0
[/CIF]
.