The crystal structure described by Ag2F5 crystallizes in the triclinic P-1 space group. There are six inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 6-coordinate geometry to two equivalent F(2), two equivalent F(7), and two equivalent F(8) atoms. In the second Ag site, Ag(2) is bonded in a distorted square co-planar geometry to two equivalent F(1), two equivalent F(10), and two equivalent F(5) atoms. In the third Ag site, Ag(3) is bonded to one F(2), one F(4), one F(5), one F(6), one F(8), and one F(9) atom to form corner-sharing AgF6 octahedra. The corner-sharing octahedral tilt angles range from 35-66°. In the fourth Ag site, Ag(4) is bonded in a square co-planar geometry to two equivalent F(2) and two equivalent F(3) atoms. In the fifth Ag site, Ag(5) is bonded to two equivalent F(1), two equivalent F(6), and two equivalent F(9) atoms to form distorted corner-sharing AgF6 octahedra. The corner-sharing octahedral tilt angles range from 35-66°. In the sixth Ag site, Ag(6) is bonded in a rectangular see-saw-like geometry to one F(10), one F(4), one F(7), and one F(9) atom. There are ten inequivalent F sites. In the first F site, F(1) is bonded in a bent 120 degrees geometry to one Ag(2) and one Ag(5) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one Ag(1), one Ag(3), and one Ag(4) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Ag(4) atom. In the fourth F site, F(4) is bonded in a distorted bent 120 degrees geometry to one Ag(3) and one Ag(6) atom. In the fifth F site, F(5) is bonded in a bent 150 degrees geometry to one Ag(2) and one Ag(3) atom. In the sixth F site, F(6) is bonded in a bent 150 degrees geometry to one Ag(3) and one Ag(5) atom. In the seventh F site, F(7) is bonded in a bent 120 degrees geometry to one Ag(1) and one Ag(6) atom. In the eighth F site, F(8) is bonded in a bent 150 degrees geometry to one Ag(1) and one Ag(3) atom. In the ninth F site, F(9) is bonded in a distorted trigonal planar geometry to one Ag(3), one Ag(5), and one Ag(6) atom. In the tenth F site, F(10) is bonded in a distorted single-bond geometry to one Ag(2) and one Ag(6) atom. is represented by the CIF file [CIF]
data_Ag2F5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.879
_cell_length_b   7.357
_cell_length_c   11.130
_cell_angle_alpha   88.621
_cell_angle_beta   89.184
_cell_angle_gamma   74.543
_symmetry_Int_Tables_number   1
_cell_volume   384.938
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.500  0.500  0.000  1.0
  Ag  Ag1  1  0.500  0.000  0.500  1.0
  Ag  Ag2  1  0.045  0.278  0.751  1.0
  Ag  Ag3  1  0.955  0.722  0.249  1.0
  Ag  Ag4  1  0.500  0.000  0.000  1.0
  Ag  Ag5  1  0.500  0.500  0.500  1.0
  Ag  Ag6  1  0.044  0.788  0.767  1.0
  Ag  Ag7  1  0.956  0.212  0.233  1.0
  F  F8  1  0.426  0.276  0.423  1.0
  F  F9  1  0.574  0.724  0.577  1.0
  F  F10  1  0.666  0.768  0.092  1.0
  F  F11  1  0.334  0.232  0.908  1.0
  F  F12  1  0.488  0.160  0.136  1.0
  F  F13  1  0.512  0.840  0.864  1.0
  F  F14  1  0.939  0.025  0.853  1.0
  F  F15  1  0.061  0.975  0.147  1.0
  F  F16  1  0.609  0.875  0.339  1.0
  F  F17  1  0.391  0.125  0.661  1.0
  F  F18  1  0.813  0.331  0.586  1.0
  F  F19  1  0.187  0.669  0.414  1.0
  F  F20  1  0.892  0.356  0.080  1.0
  F  F21  1  0.108  0.644  0.920  1.0
  F  F22  1  0.707  0.445  0.839  1.0
  F  F23  1  0.293  0.555  0.161  1.0
  F  F24  1  0.158  0.550  0.683  1.0
  F  F25  1  0.842  0.450  0.317  1.0
  F  F26  1  0.975  0.930  0.619  1.0
  F  F27  1  0.025  0.070  0.381  1.0
[/CIF]
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The crystal structure described by Ag2F5 crystallizes in the triclinic P-1 space group. There are six inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 6-coordinate geometry to two equivalent F(2), two equivalent F(7), and two equivalent F(8) atoms. In the second Ag site, Ag(2) is bonded in a distorted square co-planar geometry to two equivalent F(1), two equivalent F(10), and two equivalent F(5) atoms. In the third Ag site, Ag(3) is bonded to one F(2), one F(4), one F(5), one F(6), one F(8), and one F(9) atom to form corner-sharing AgF6 octahedra. The corner-sharing octahedral tilt angles range from 35-66°. In the fourth Ag site, Ag(4) is bonded in a square co-planar geometry to two equivalent F(2) and two equivalent F(3) atoms. In the fifth Ag site, Ag(5) is bonded to two equivalent F(1), two equivalent F(6), and two equivalent F(9) atoms to form distorted corner-sharing AgF6 octahedra. The corner-sharing octahedral tilt angles range from 35-66°. In the sixth Ag site, Ag(6) is bonded in a rectangular see-saw-like geometry to one F(10), one F(4), one F(7), and one F(9) atom. There are ten inequivalent F sites. In the first F site, F(1) is bonded in a bent 120 degrees geometry to one Ag(2) and one Ag(5) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one Ag(1), one Ag(3), and one Ag(4) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Ag(4) atom. In the fourth F site, F(4) is bonded in a distorted bent 120 degrees geometry to one Ag(3) and one Ag(6) atom. In the fifth F site, F(5) is bonded in a bent 150 degrees geometry to one Ag(2) and one Ag(3) atom. In the sixth F site, F(6) is bonded in a bent 150 degrees geometry to one Ag(3) and one Ag(5) atom. In the seventh F site, F(7) is bonded in a bent 120 degrees geometry to one Ag(1) and one Ag(6) atom. In the eighth F site, F(8) is bonded in a bent 150 degrees geometry to one Ag(1) and one Ag(3) atom. In the ninth F site, F(9) is bonded in a distorted trigonal planar geometry to one Ag(3), one Ag(5), and one Ag(6) atom. In the tenth F site, F(10) is bonded in a distorted single-bond geometry to one Ag(2) and one Ag(6) atom. is represented by the CIF file [CIF]
data_Ag2F5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.879
_cell_length_b   7.357
_cell_length_c   11.130
_cell_angle_alpha   88.621
_cell_angle_beta   89.184
_cell_angle_gamma   74.543
_symmetry_Int_Tables_number   1
_cell_volume   384.938
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.500  0.500  0.000  1.0
  Ag  Ag1  1  0.500  0.000  0.500  1.0
  Ag  Ag2  1  0.045  0.278  0.751  1.0
  Ag  Ag3  1  0.955  0.722  0.249  1.0
  Ag  Ag4  1  0.500  0.000  0.000  1.0
  Ag  Ag5  1  0.500  0.500  0.500  1.0
  Ag  Ag6  1  0.044  0.788  0.767  1.0
  Ag  Ag7  1  0.956  0.212  0.233  1.0
  F  F8  1  0.426  0.276  0.423  1.0
  F  F9  1  0.574  0.724  0.577  1.0
  F  F10  1  0.666  0.768  0.092  1.0
  F  F11  1  0.334  0.232  0.908  1.0
  F  F12  1  0.488  0.160  0.136  1.0
  F  F13  1  0.512  0.840  0.864  1.0
  F  F14  1  0.939  0.025  0.853  1.0
  F  F15  1  0.061  0.975  0.147  1.0
  F  F16  1  0.609  0.875  0.339  1.0
  F  F17  1  0.391  0.125  0.661  1.0
  F  F18  1  0.813  0.331  0.586  1.0
  F  F19  1  0.187  0.669  0.414  1.0
  F  F20  1  0.892  0.356  0.080  1.0
  F  F21  1  0.108  0.644  0.920  1.0
  F  F22  1  0.707  0.445  0.839  1.0
  F  F23  1  0.293  0.555  0.161  1.0
  F  F24  1  0.158  0.550  0.683  1.0
  F  F25  1  0.842  0.450  0.317  1.0
  F  F26  1  0.975  0.930  0.619  1.0
  F  F27  1  0.025  0.070  0.381  1.0
[/CIF]
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