The material described by Rb2InOCl5 crystallizes in the orthorhombic Pnma space group. Rb(1) is bonded in a 11-coordinate geometry to one O(1), two equivalent Cl(1), two equivalent Cl(2), two equivalent Cl(3), and four equivalent Cl(4) atoms. In(1) is bonded to one O(1), one Cl(1), one Cl(2), one Cl(3), and two equivalent Cl(4) atoms to form distorted InCl5O octahedra that share  a cornercorner with one Cl(1)Rb4InO octahedra. The corner-sharing octahedral tilt angles are 108°. O(1) is bonded in a distorted single-bond geometry to two equivalent Rb(1), one In(1), and one Cl(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded to four equivalent Rb(1), one In(1), and one O(1) atom to form distorted ClRb4InO octahedra that share  a cornercorner with one In(1)Cl5O octahedra, corners with four equivalent Cl(1)Rb4InO octahedra, corners with five equivalent Cl(3)Rb4In square pyramids, edges with two equivalent Cl(3)Rb4In square pyramids, edges with three equivalent Cl(2)Rb4In square pyramids, and  a faceface with one Cl(2)Rb4In square pyramid. The corner-sharing octahedral tilt angles range from 53-108°. In the second Cl site, Cl(2) is bonded to four equivalent Rb(1) and one In(1) atom to form distorted ClRb4In square pyramids that share corners with four equivalent Cl(2)Rb4In square pyramids, corners with four equivalent Cl(3)Rb4In square pyramids, edges with three equivalent Cl(1)Rb4InO octahedra,  an edgeedge with one Cl(3)Rb4In square pyramid,  a faceface with one Cl(1)Rb4InO octahedra, and  a faceface with one Cl(3)Rb4In square pyramid. In the third Cl site, Cl(3) is bonded to four equivalent Rb(1) and one In(1) atom to form distorted ClRb4In square pyramids that share corners with five equivalent Cl(1)Rb4InO octahedra, corners with four equivalent Cl(2)Rb4In square pyramids, edges with two equivalent Cl(1)Rb4InO octahedra,  an edgeedge with one Cl(2)Rb4In square pyramid, edges with two equivalent Cl(3)Rb4In square pyramids, and  a faceface with one Cl(2)Rb4In square pyramid. The corner-sharing octahedral tilt angles range from 9-60°. In the fourth Cl site, Cl(4) is bonded in a 5-coordinate geometry to four equivalent Rb(1) and one In(1) atom. is represented by the CIF file [CIF]
data_Rb2InCl5O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.368
_cell_length_b   10.327
_cell_length_c   13.665
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1039.699
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.194  0.488  0.365  1.0
  Rb  Rb1  1  0.306  0.012  0.865  1.0
  Rb  Rb2  1  0.806  0.988  0.635  1.0
  Rb  Rb3  1  0.694  0.512  0.135  1.0
  Rb  Rb4  1  0.806  0.512  0.635  1.0
  Rb  Rb5  1  0.694  0.988  0.135  1.0
  Rb  Rb6  1  0.194  0.012  0.365  1.0
  Rb  Rb7  1  0.306  0.488  0.865  1.0
  In  In8  1  0.230  0.750  0.123  1.0
  In  In9  1  0.270  0.750  0.623  1.0
  In  In10  1  0.770  0.250  0.877  1.0
  In  In11  1  0.730  0.250  0.377  1.0
  Cl  Cl12  1  0.939  0.750  0.244  1.0
  Cl  Cl13  1  0.561  0.750  0.744  1.0
  Cl  Cl14  1  0.061  0.250  0.756  1.0
  Cl  Cl15  1  0.439  0.250  0.256  1.0
  Cl  Cl16  1  0.433  0.750  0.264  1.0
  Cl  Cl17  1  0.067  0.750  0.764  1.0
  Cl  Cl18  1  0.567  0.250  0.736  1.0
  Cl  Cl19  1  0.933  0.250  0.236  1.0
  Cl  Cl20  1  0.462  0.750  0.993  1.0
  Cl  Cl21  1  0.038  0.750  0.493  1.0
  Cl  Cl22  1  0.538  0.250  0.007  1.0
  Cl  Cl23  1  0.962  0.250  0.507  1.0
  Cl  Cl24  1  0.186  0.512  0.109  1.0
  Cl  Cl25  1  0.314  0.988  0.609  1.0
  Cl  Cl26  1  0.814  0.012  0.891  1.0
  Cl  Cl27  1  0.686  0.488  0.391  1.0
  Cl  Cl28  1  0.814  0.488  0.891  1.0
  Cl  Cl29  1  0.686  0.012  0.391  1.0
  Cl  Cl30  1  0.186  0.988  0.109  1.0
  Cl  Cl31  1  0.314  0.512  0.609  1.0
  O  O32  1  0.948  0.750  0.068  1.0
  O  O33  1  0.552  0.750  0.568  1.0
  O  O34  1  0.052  0.250  0.932  1.0
  O  O35  1  0.448  0.250  0.432  1.0
[/CIF]
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The material described by Rb2InOCl5 crystallizes in the orthorhombic Pnma space group. Rb(1) is bonded in a 11-coordinate geometry to one O(1), two equivalent Cl(1), two equivalent Cl(2), two equivalent Cl(3), and four equivalent Cl(4) atoms. In(1) is bonded to one O(1), one Cl(1), one Cl(2), one Cl(3), and two equivalent Cl(4) atoms to form distorted InCl5O octahedra that share  a cornercorner with one Cl(1)Rb4InO octahedra. The corner-sharing octahedral tilt angles are 108°. O(1) is bonded in a distorted single-bond geometry to two equivalent Rb(1), one In(1), and one Cl(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded to four equivalent Rb(1), one In(1), and one O(1) atom to form distorted ClRb4InO octahedra that share  a cornercorner with one In(1)Cl5O octahedra, corners with four equivalent Cl(1)Rb4InO octahedra, corners with five equivalent Cl(3)Rb4In square pyramids, edges with two equivalent Cl(3)Rb4In square pyramids, edges with three equivalent Cl(2)Rb4In square pyramids, and  a faceface with one Cl(2)Rb4In square pyramid. The corner-sharing octahedral tilt angles range from 53-108°. In the second Cl site, Cl(2) is bonded to four equivalent Rb(1) and one In(1) atom to form distorted ClRb4In square pyramids that share corners with four equivalent Cl(2)Rb4In square pyramids, corners with four equivalent Cl(3)Rb4In square pyramids, edges with three equivalent Cl(1)Rb4InO octahedra,  an edgeedge with one Cl(3)Rb4In square pyramid,  a faceface with one Cl(1)Rb4InO octahedra, and  a faceface with one Cl(3)Rb4In square pyramid. In the third Cl site, Cl(3) is bonded to four equivalent Rb(1) and one In(1) atom to form distorted ClRb4In square pyramids that share corners with five equivalent Cl(1)Rb4InO octahedra, corners with four equivalent Cl(2)Rb4In square pyramids, edges with two equivalent Cl(1)Rb4InO octahedra,  an edgeedge with one Cl(2)Rb4In square pyramid, edges with two equivalent Cl(3)Rb4In square pyramids, and  a faceface with one Cl(2)Rb4In square pyramid. The corner-sharing octahedral tilt angles range from 9-60°. In the fourth Cl site, Cl(4) is bonded in a 5-coordinate geometry to four equivalent Rb(1) and one In(1) atom. is represented by the CIF file [CIF]
data_Rb2InCl5O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.368
_cell_length_b   10.327
_cell_length_c   13.665
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1039.699
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.194  0.488  0.365  1.0
  Rb  Rb1  1  0.306  0.012  0.865  1.0
  Rb  Rb2  1  0.806  0.988  0.635  1.0
  Rb  Rb3  1  0.694  0.512  0.135  1.0
  Rb  Rb4  1  0.806  0.512  0.635  1.0
  Rb  Rb5  1  0.694  0.988  0.135  1.0
  Rb  Rb6  1  0.194  0.012  0.365  1.0
  Rb  Rb7  1  0.306  0.488  0.865  1.0
  In  In8  1  0.230  0.750  0.123  1.0
  In  In9  1  0.270  0.750  0.623  1.0
  In  In10  1  0.770  0.250  0.877  1.0
  In  In11  1  0.730  0.250  0.377  1.0
  Cl  Cl12  1  0.939  0.750  0.244  1.0
  Cl  Cl13  1  0.561  0.750  0.744  1.0
  Cl  Cl14  1  0.061  0.250  0.756  1.0
  Cl  Cl15  1  0.439  0.250  0.256  1.0
  Cl  Cl16  1  0.433  0.750  0.264  1.0
  Cl  Cl17  1  0.067  0.750  0.764  1.0
  Cl  Cl18  1  0.567  0.250  0.736  1.0
  Cl  Cl19  1  0.933  0.250  0.236  1.0
  Cl  Cl20  1  0.462  0.750  0.993  1.0
  Cl  Cl21  1  0.038  0.750  0.493  1.0
  Cl  Cl22  1  0.538  0.250  0.007  1.0
  Cl  Cl23  1  0.962  0.250  0.507  1.0
  Cl  Cl24  1  0.186  0.512  0.109  1.0
  Cl  Cl25  1  0.314  0.988  0.609  1.0
  Cl  Cl26  1  0.814  0.012  0.891  1.0
  Cl  Cl27  1  0.686  0.488  0.391  1.0
  Cl  Cl28  1  0.814  0.488  0.891  1.0
  Cl  Cl29  1  0.686  0.012  0.391  1.0
  Cl  Cl30  1  0.186  0.988  0.109  1.0
  Cl  Cl31  1  0.314  0.512  0.609  1.0
  O  O32  1  0.948  0.750  0.068  1.0
  O  O33  1  0.552  0.750  0.568  1.0
  O  O34  1  0.052  0.250  0.932  1.0
  O  O35  1  0.448  0.250  0.432  1.0
[/CIF]
.