The material described by Ba(PdP2)2 crystallizes in the tetragonal I4/mmm space group. Ba(1) is bonded in a 24-coordinate geometry to eight equivalent Pd(1) and sixteen equivalent P(1) atoms. Pd(1) is bonded to four equivalent Ba(1) and four equivalent P(1) atoms to form a mixture of distorted face, corner, and edge-sharing PdBa4P4 tetrahedra. P(1) is bonded in a 6-coordinate geometry to four equivalent Ba(1), two equivalent Pd(1), and two equivalent P(1) atoms. is represented by the CIF card [CIF]
data_Ba(P2Pd)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.687
_cell_length_b   5.687
_cell_length_c   5.687
_cell_angle_alpha   106.013
_cell_angle_beta   106.013
_cell_angle_gamma   116.633
_symmetry_Int_Tables_number   1
_cell_volume   139.900
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.000  0.000  0.000  1.0
  P  P1  1  0.500  0.274  0.774  1.0
  P  P2  1  0.274  0.500  0.774  1.0
  P  P3  1  0.726  0.500  0.226  1.0
  P  P4  1  0.500  0.726  0.226  1.0
  Pd  Pd5  1  0.750  0.250  0.500  1.0
  Pd  Pd6  1  0.250  0.750  0.500  1.0
[/CIF]
.
The material described by Ba(PdP2)2 crystallizes in the tetragonal I4/mmm space group. Ba(1) is bonded in a 24-coordinate geometry to eight equivalent Pd(1) and sixteen equivalent P(1) atoms. Pd(1) is bonded to four equivalent Ba(1) and four equivalent P(1) atoms to form a mixture of distorted face, corner, and edge-sharing PdBa4P4 tetrahedra. P(1) is bonded in a 6-coordinate geometry to four equivalent Ba(1), two equivalent Pd(1), and two equivalent P(1) atoms. is represented by the CIF card [CIF]
data_Ba(P2Pd)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.687
_cell_length_b   5.687
_cell_length_c   5.687
_cell_angle_alpha   106.013
_cell_angle_beta   106.013
_cell_angle_gamma   116.633
_symmetry_Int_Tables_number   1
_cell_volume   139.900
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.000  0.000  0.000  1.0
  P  P1  1  0.500  0.274  0.774  1.0
  P  P2  1  0.274  0.500  0.774  1.0
  P  P3  1  0.726  0.500  0.226  1.0
  P  P4  1  0.500  0.726  0.226  1.0
  Pd  Pd5  1  0.750  0.250  0.500  1.0
  Pd  Pd6  1  0.250  0.750  0.500  1.0
[/CIF]
.