The crystal structure described by Na5SnP3 crystallizes in the monoclinic P2_1/c space group. There are five inequivalent Na sites. In the first Na site, Na(1) is bonded in a 4-coordinate geometry to one P(1), one P(3), and two equivalent P(2) atoms. In the second Na site, Na(2) is bonded in a 3-coordinate geometry to one P(2), two equivalent P(1), and two equivalent P(3) atoms. In the third Na site, Na(3) is bonded in a 5-coordinate geometry to one P(1), two equivalent P(2), and two equivalent P(3) atoms. In the fourth Na site, Na(4) is bonded to one P(1), one P(3), and two equivalent P(2) atoms to form a mixture of distorted edge and corner-sharing NaP4 tetrahedra. In the fifth Na site, Na(5) is bonded to one P(1), one P(2), and two equivalent P(3) atoms to form a mixture of distorted edge and corner-sharing NaP4 tetrahedra. Sn(1) is bonded in a 4-coordinate geometry to one P(2), one P(3), and two equivalent P(1) atoms. There are three inequivalent P sites. In the first P site, P(3) is bonded in a 9-coordinate geometry to one Na(1), one Na(4), two equivalent Na(2), two equivalent Na(3), two equivalent Na(5), and one Sn(1) atom. In the second P site, P(1) is bonded in a 8-coordinate geometry to one Na(1), one Na(3), one Na(4), one Na(5), two equivalent Na(2), and two equivalent Sn(1) atoms. In the third P site, P(2) is bonded in a 9-coordinate geometry to one Na(2), one Na(5), two equivalent Na(1), two equivalent Na(3), two equivalent Na(4), and one Sn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Na5SnP3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.416
_cell_length_b   8.267
_cell_length_c   15.581
_cell_angle_alpha   58.360
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   813.247
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.497  0.092  0.240  1.0
  Na  Na1  1  0.997  0.908  0.260  1.0
  Na  Na2  1  0.503  0.908  0.760  1.0
  Na  Na3  1  0.003  0.092  0.740  1.0
  Na  Na4  1  0.040  0.411  0.411  1.0
  Na  Na5  1  0.540  0.589  0.089  1.0
  Na  Na6  1  0.960  0.589  0.589  1.0
  Na  Na7  1  0.460  0.411  0.911  1.0
  Na  Na8  1  0.522  0.253  0.412  1.0
  Na  Na9  1  0.022  0.747  0.088  1.0
  Na  Na10  1  0.478  0.747  0.588  1.0
  Na  Na11  1  0.978  0.253  0.912  1.0
  Na  Na12  1  0.661  0.995  0.082  1.0
  Na  Na13  1  0.161  0.005  0.418  1.0
  Na  Na14  1  0.339  0.005  0.918  1.0
  Na  Na15  1  0.839  0.995  0.582  1.0
  Na  Na16  1  0.857  0.314  0.258  1.0
  Na  Na17  1  0.357  0.686  0.242  1.0
  Na  Na18  1  0.143  0.686  0.742  1.0
  Na  Na19  1  0.643  0.314  0.758  1.0
  Sn  Sn20  1  0.648  0.662  0.410  1.0
  Sn  Sn21  1  0.148  0.338  0.090  1.0
  Sn  Sn22  1  0.352  0.338  0.590  1.0
  Sn  Sn23  1  0.852  0.662  0.910  1.0
  P  P24  1  0.702  0.335  0.571  1.0
  P  P25  1  0.202  0.665  0.929  1.0
  P  P26  1  0.298  0.665  0.429  1.0
  P  P27  1  0.798  0.335  0.071  1.0
  P  P28  1  0.767  0.939  0.418  1.0
  P  P29  1  0.267  0.061  0.082  1.0
  P  P30  1  0.233  0.061  0.582  1.0
  P  P31  1  0.733  0.939  0.918  1.0
  P  P32  1  0.745  0.639  0.263  1.0
  P  P33  1  0.245  0.361  0.237  1.0
  P  P34  1  0.255  0.361  0.737  1.0
  P  P35  1  0.755  0.639  0.763  1.0
[/CIF]
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The crystal structure described by Na5SnP3 crystallizes in the monoclinic P2_1/c space group. There are five inequivalent Na sites. In the first Na site, Na(1) is bonded in a 4-coordinate geometry to one P(1), one P(3), and two equivalent P(2) atoms. In the second Na site, Na(2) is bonded in a 3-coordinate geometry to one P(2), two equivalent P(1), and two equivalent P(3) atoms. In the third Na site, Na(3) is bonded in a 5-coordinate geometry to one P(1), two equivalent P(2), and two equivalent P(3) atoms. In the fourth Na site, Na(4) is bonded to one P(1), one P(3), and two equivalent P(2) atoms to form a mixture of distorted edge and corner-sharing NaP4 tetrahedra. In the fifth Na site, Na(5) is bonded to one P(1), one P(2), and two equivalent P(3) atoms to form a mixture of distorted edge and corner-sharing NaP4 tetrahedra. Sn(1) is bonded in a 4-coordinate geometry to one P(2), one P(3), and two equivalent P(1) atoms. There are three inequivalent P sites. In the first P site, P(3) is bonded in a 9-coordinate geometry to one Na(1), one Na(4), two equivalent Na(2), two equivalent Na(3), two equivalent Na(5), and one Sn(1) atom. In the second P site, P(1) is bonded in a 8-coordinate geometry to one Na(1), one Na(3), one Na(4), one Na(5), two equivalent Na(2), and two equivalent Sn(1) atoms. In the third P site, P(2) is bonded in a 9-coordinate geometry to one Na(2), one Na(5), two equivalent Na(1), two equivalent Na(3), two equivalent Na(4), and one Sn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Na5SnP3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.416
_cell_length_b   8.267
_cell_length_c   15.581
_cell_angle_alpha   58.360
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   813.247
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.497  0.092  0.240  1.0
  Na  Na1  1  0.997  0.908  0.260  1.0
  Na  Na2  1  0.503  0.908  0.760  1.0
  Na  Na3  1  0.003  0.092  0.740  1.0
  Na  Na4  1  0.040  0.411  0.411  1.0
  Na  Na5  1  0.540  0.589  0.089  1.0
  Na  Na6  1  0.960  0.589  0.589  1.0
  Na  Na7  1  0.460  0.411  0.911  1.0
  Na  Na8  1  0.522  0.253  0.412  1.0
  Na  Na9  1  0.022  0.747  0.088  1.0
  Na  Na10  1  0.478  0.747  0.588  1.0
  Na  Na11  1  0.978  0.253  0.912  1.0
  Na  Na12  1  0.661  0.995  0.082  1.0
  Na  Na13  1  0.161  0.005  0.418  1.0
  Na  Na14  1  0.339  0.005  0.918  1.0
  Na  Na15  1  0.839  0.995  0.582  1.0
  Na  Na16  1  0.857  0.314  0.258  1.0
  Na  Na17  1  0.357  0.686  0.242  1.0
  Na  Na18  1  0.143  0.686  0.742  1.0
  Na  Na19  1  0.643  0.314  0.758  1.0
  Sn  Sn20  1  0.648  0.662  0.410  1.0
  Sn  Sn21  1  0.148  0.338  0.090  1.0
  Sn  Sn22  1  0.352  0.338  0.590  1.0
  Sn  Sn23  1  0.852  0.662  0.910  1.0
  P  P24  1  0.702  0.335  0.571  1.0
  P  P25  1  0.202  0.665  0.929  1.0
  P  P26  1  0.298  0.665  0.429  1.0
  P  P27  1  0.798  0.335  0.071  1.0
  P  P28  1  0.767  0.939  0.418  1.0
  P  P29  1  0.267  0.061  0.082  1.0
  P  P30  1  0.233  0.061  0.582  1.0
  P  P31  1  0.733  0.939  0.918  1.0
  P  P32  1  0.745  0.639  0.263  1.0
  P  P33  1  0.245  0.361  0.237  1.0
  P  P34  1  0.255  0.361  0.737  1.0
  P  P35  1  0.755  0.639  0.763  1.0
[/CIF]
.