The material structure described by (VP2(HO4)2)6N2(NH4)4 crystallizes in the triclinic P-1 space group. The structure consists of one ammonia atom and two ammonium molecules inside a VP2(HO4)2 framework. In the VP2(HO4)2 framework, there are two inequivalent V sites. In the first V site, V(1) is bonded to two equivalent O(4), two equivalent O(6), and two equivalent O(9) atoms to form VO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. In the second V site, V(2) is bonded to one O(1), one O(10), one O(11), one O(3), one O(5), and one O(7) atom to form VO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra and corners with two equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 16-46°. In the second P site, P(2) is bonded to one O(5), one O(6), one O(7), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra and corners with two equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 29-54°. In the third P site, P(3) is bonded to one O(10), one O(11), one O(12), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra and corners with two equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 27-49°. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(2) atom. In the second H site, H(2) is bonded in a distorted linear geometry to one O(10) and one O(8) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(12) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one V(2) and one P(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one P(1) and one H(1) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one V(2) and one P(1) atom. In the fourth O site, O(4) is bonded in a distorted linear geometry to one V(1) and one P(1) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one V(2) and one P(2) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one V(1) and one P(2) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one V(2) and one P(2) atom. In the eighth O site, O(8) is bonded in a water-like geometry to one P(2) and one H(2) atom. In the ninth O site, O(9) is bonded in a 2-coordinate geometry to one V(1) and one P(3) atom. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one V(2), one P(3), and one H(2) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to one V(2) and one P(3) atom. In the twelfth O site, O(12) is bonded in a water-like geometry to one P(3) and one H(3) atom. is represented by the CIF card [CIF]
data_V3P6H14(NO8)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.361
_cell_length_b   8.962
_cell_length_c   9.531
_cell_angle_alpha   64.736
_cell_angle_beta   70.848
_cell_angle_gamma   68.681
_symmetry_Int_Tables_number   1
_cell_volume   518.466
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.000  0.500  0.500  1.0
  V  V1  1  0.801  0.282  0.052  1.0
  V  V2  1  0.199  0.718  0.948  1.0
  P  P3  1  0.550  0.449  0.778  1.0
  P  P4  1  0.450  0.551  0.222  1.0
  P  P5  1  0.080  0.122  0.766  1.0
  P  P6  1  0.920  0.878  0.234  1.0
  P  P7  1  0.910  0.656  0.781  1.0
  P  P8  1  0.090  0.344  0.219  1.0
  H  H9  1  0.282  0.451  0.714  1.0
  H  H10  1  0.718  0.549  0.286  1.0
  H  H11  1  0.916  0.965  0.769  1.0
  H  H12  1  0.084  0.035  0.231  1.0
  H  H13  1  0.604  0.748  0.751  1.0
  H  H14  1  0.396  0.252  0.249  1.0
  H  H15  1  0.697  0.217  0.564  1.0
  H  H16  1  0.303  0.783  0.436  1.0
  H  H17  1  0.647  0.195  0.414  1.0
  H  H18  1  0.353  0.805  0.586  1.0
  H  H19  1  0.638  0.039  0.599  1.0
  H  H20  1  0.362  0.961  0.401  1.0
  H  H21  1  0.461  0.228  0.566  1.0
  H  H22  1  0.539  0.772  0.434  1.0
  N  N23  1  0.500  0.000  0.000  1.0
  N  N24  1  0.611  0.169  0.535  1.0
  N  N25  1  0.389  0.831  0.465  1.0
  O  O26  1  0.606  0.319  0.936  1.0
  O  O27  1  0.394  0.681  0.064  1.0
  O  O28  1  0.412  0.374  0.742  1.0
  O  O29  1  0.588  0.626  0.258  1.0
  O  O30  1  0.428  0.629  0.789  1.0
  O  O31  1  0.572  0.371  0.211  1.0
  O  O32  1  0.728  0.470  0.640  1.0
  O  O33  1  0.272  0.530  0.360  1.0
  O  O34  1  0.009  0.184  0.909  1.0
  O  O35  1  0.991  0.816  0.091  1.0
  O  O36  1  0.156  0.261  0.616  1.0
  O  O37  1  0.844  0.739  0.384  1.0
  O  O38  1  0.243  0.952  0.799  1.0
  O  O39  1  0.757  0.048  0.201  1.0
  O  O40  1  0.899  0.092  0.735  1.0
  O  O41  1  0.101  0.908  0.265  1.0
  O  O42  1  0.054  0.584  0.650  1.0
  O  O43  1  0.946  0.416  0.350  1.0
  O  O44  1  0.012  0.760  0.809  1.0
  O  O45  1  0.988  0.240  0.191  1.0
  O  O46  1  0.838  0.519  0.930  1.0
  O  O47  1  0.162  0.481  0.070  1.0
  O  O48  1  0.720  0.797  0.714  1.0
  O  O49  1  0.280  0.203  0.286  1.0
[/CIF]
.
The material structure described by (VP2(HO4)2)6N2(NH4)4 crystallizes in the triclinic P-1 space group. The structure consists of one ammonia atom and two ammonium molecules inside a VP2(HO4)2 framework. In the VP2(HO4)2 framework, there are two inequivalent V sites. In the first V site, V(1) is bonded to two equivalent O(4), two equivalent O(6), and two equivalent O(9) atoms to form VO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. In the second V site, V(2) is bonded to one O(1), one O(10), one O(11), one O(3), one O(5), and one O(7) atom to form VO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra and corners with two equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 16-46°. In the second P site, P(2) is bonded to one O(5), one O(6), one O(7), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra and corners with two equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 29-54°. In the third P site, P(3) is bonded to one O(10), one O(11), one O(12), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra and corners with two equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 27-49°. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(2) atom. In the second H site, H(2) is bonded in a distorted linear geometry to one O(10) and one O(8) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(12) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one V(2) and one P(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one P(1) and one H(1) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one V(2) and one P(1) atom. In the fourth O site, O(4) is bonded in a distorted linear geometry to one V(1) and one P(1) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one V(2) and one P(2) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one V(1) and one P(2) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one V(2) and one P(2) atom. In the eighth O site, O(8) is bonded in a water-like geometry to one P(2) and one H(2) atom. In the ninth O site, O(9) is bonded in a 2-coordinate geometry to one V(1) and one P(3) atom. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one V(2), one P(3), and one H(2) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to one V(2) and one P(3) atom. In the twelfth O site, O(12) is bonded in a water-like geometry to one P(3) and one H(3) atom. is represented by the CIF card [CIF]
data_V3P6H14(NO8)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.361
_cell_length_b   8.962
_cell_length_c   9.531
_cell_angle_alpha   64.736
_cell_angle_beta   70.848
_cell_angle_gamma   68.681
_symmetry_Int_Tables_number   1
_cell_volume   518.466
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.000  0.500  0.500  1.0
  V  V1  1  0.801  0.282  0.052  1.0
  V  V2  1  0.199  0.718  0.948  1.0
  P  P3  1  0.550  0.449  0.778  1.0
  P  P4  1  0.450  0.551  0.222  1.0
  P  P5  1  0.080  0.122  0.766  1.0
  P  P6  1  0.920  0.878  0.234  1.0
  P  P7  1  0.910  0.656  0.781  1.0
  P  P8  1  0.090  0.344  0.219  1.0
  H  H9  1  0.282  0.451  0.714  1.0
  H  H10  1  0.718  0.549  0.286  1.0
  H  H11  1  0.916  0.965  0.769  1.0
  H  H12  1  0.084  0.035  0.231  1.0
  H  H13  1  0.604  0.748  0.751  1.0
  H  H14  1  0.396  0.252  0.249  1.0
  H  H15  1  0.697  0.217  0.564  1.0
  H  H16  1  0.303  0.783  0.436  1.0
  H  H17  1  0.647  0.195  0.414  1.0
  H  H18  1  0.353  0.805  0.586  1.0
  H  H19  1  0.638  0.039  0.599  1.0
  H  H20  1  0.362  0.961  0.401  1.0
  H  H21  1  0.461  0.228  0.566  1.0
  H  H22  1  0.539  0.772  0.434  1.0
  N  N23  1  0.500  0.000  0.000  1.0
  N  N24  1  0.611  0.169  0.535  1.0
  N  N25  1  0.389  0.831  0.465  1.0
  O  O26  1  0.606  0.319  0.936  1.0
  O  O27  1  0.394  0.681  0.064  1.0
  O  O28  1  0.412  0.374  0.742  1.0
  O  O29  1  0.588  0.626  0.258  1.0
  O  O30  1  0.428  0.629  0.789  1.0
  O  O31  1  0.572  0.371  0.211  1.0
  O  O32  1  0.728  0.470  0.640  1.0
  O  O33  1  0.272  0.530  0.360  1.0
  O  O34  1  0.009  0.184  0.909  1.0
  O  O35  1  0.991  0.816  0.091  1.0
  O  O36  1  0.156  0.261  0.616  1.0
  O  O37  1  0.844  0.739  0.384  1.0
  O  O38  1  0.243  0.952  0.799  1.0
  O  O39  1  0.757  0.048  0.201  1.0
  O  O40  1  0.899  0.092  0.735  1.0
  O  O41  1  0.101  0.908  0.265  1.0
  O  O42  1  0.054  0.584  0.650  1.0
  O  O43  1  0.946  0.416  0.350  1.0
  O  O44  1  0.012  0.760  0.809  1.0
  O  O45  1  0.988  0.240  0.191  1.0
  O  O46  1  0.838  0.519  0.930  1.0
  O  O47  1  0.162  0.481  0.070  1.0
  O  O48  1  0.720  0.797  0.714  1.0
  O  O49  1  0.280  0.203  0.286  1.0
[/CIF]
.