The material structure described by In2VO5 crystallizes in the orthorhombic Pnma space group. V(1) is bonded to one O(2), one O(3), one O(5), and three equivalent O(1) atoms to form VO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with four equivalent In(1)O6 octahedra, corners with four equivalent In(2)O6 octahedra, and edges with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 36-64°. There are two inequivalent In sites. In the first In site, In(1) is bonded to one O(3), two equivalent O(4), and three equivalent O(5) atoms to form InO6 octahedra that share corners with two equivalent In(2)O6 octahedra, corners with four equivalent V(1)O6 octahedra, edges with two equivalent In(2)O6 octahedra, and edges with four equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 61-64°. In the second In site, In(2) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form InO6 octahedra that share corners with two equivalent In(1)O6 octahedra, corners with two equivalent In(2)O6 octahedra, corners with four equivalent V(1)O6 octahedra, edges with two equivalent In(1)O6 octahedra, and edges with two equivalent In(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-64°. There are five inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to three equivalent V(1) atoms. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one V(1) and two equivalent In(2) atoms. In the third O site, O(3) is bonded to one V(1), one In(1), and two equivalent In(2) atoms to form OVIn3 tetrahedra that share corners with two equivalent O(4)In4 tetrahedra, corners with two equivalent O(3)VIn3 tetrahedra, corners with four equivalent O(5)VIn3 tetrahedra, and edges with two equivalent O(4)In4 tetrahedra. In the fourth O site, O(4) is bonded to two equivalent In(1) and two equivalent In(2) atoms to form distorted OIn4 tetrahedra that share corners with two equivalent O(3)VIn3 tetrahedra, corners with four equivalent O(4)In4 tetrahedra, corners with four equivalent O(5)VIn3 tetrahedra,  an edgeedge with one O(5)VIn3 tetrahedra, and edges with two equivalent O(3)VIn3 tetrahedra. In the fifth O site, O(5) is bonded to one V(1) and three equivalent In(1) atoms to form OVIn3 tetrahedra that share corners with two equivalent O(5)VIn3 tetrahedra, corners with four equivalent O(4)In4 tetrahedra, corners with four equivalent O(3)VIn3 tetrahedra,  an edgeedge with one O(4)In4 tetrahedra, and edges with two equivalent O(5)VIn3 tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_VIn2O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.569
_cell_length_b   7.327
_cell_length_c   14.985
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   391.873
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.250  0.604  0.075  1.0
  V  V1  1  0.750  0.396  0.925  1.0
  V  V2  1  0.250  0.104  0.425  1.0
  V  V3  1  0.750  0.896  0.575  1.0
  In  In4  1  0.250  0.604  0.418  1.0
  In  In5  1  0.750  0.896  0.918  1.0
  In  In6  1  0.250  0.104  0.082  1.0
  In  In7  1  0.750  0.396  0.582  1.0
  In  In8  1  0.250  0.674  0.761  1.0
  In  In9  1  0.750  0.326  0.239  1.0
  In  In10  1  0.250  0.174  0.739  1.0
  In  In11  1  0.750  0.826  0.261  1.0
  O  O12  1  0.250  0.435  0.959  1.0
  O  O13  1  0.750  0.565  0.041  1.0
  O  O14  1  0.250  0.935  0.541  1.0
  O  O15  1  0.750  0.065  0.459  1.0
  O  O16  1  0.250  0.733  0.176  1.0
  O  O17  1  0.750  0.267  0.824  1.0
  O  O18  1  0.250  0.233  0.324  1.0
  O  O19  1  0.750  0.767  0.676  1.0
  O  O20  1  0.250  0.370  0.151  1.0
  O  O21  1  0.750  0.630  0.849  1.0
  O  O22  1  0.250  0.870  0.349  1.0
  O  O23  1  0.750  0.130  0.651  1.0
  O  O24  1  0.750  0.058  0.176  1.0
  O  O25  1  0.250  0.942  0.824  1.0
  O  O26  1  0.750  0.558  0.324  1.0
  O  O27  1  0.250  0.442  0.676  1.0
  O  O28  1  0.250  0.845  0.005  1.0
  O  O29  1  0.250  0.345  0.495  1.0
  O  O30  1  0.750  0.155  0.995  1.0
  O  O31  1  0.750  0.655  0.505  1.0
[/CIF]
.
The material structure described by In2VO5 crystallizes in the orthorhombic Pnma space group. V(1) is bonded to one O(2), one O(3), one O(5), and three equivalent O(1) atoms to form VO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with four equivalent In(1)O6 octahedra, corners with four equivalent In(2)O6 octahedra, and edges with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 36-64°. There are two inequivalent In sites. In the first In site, In(1) is bonded to one O(3), two equivalent O(4), and three equivalent O(5) atoms to form InO6 octahedra that share corners with two equivalent In(2)O6 octahedra, corners with four equivalent V(1)O6 octahedra, edges with two equivalent In(2)O6 octahedra, and edges with four equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 61-64°. In the second In site, In(2) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form InO6 octahedra that share corners with two equivalent In(1)O6 octahedra, corners with two equivalent In(2)O6 octahedra, corners with four equivalent V(1)O6 octahedra, edges with two equivalent In(1)O6 octahedra, and edges with two equivalent In(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-64°. There are five inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to three equivalent V(1) atoms. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one V(1) and two equivalent In(2) atoms. In the third O site, O(3) is bonded to one V(1), one In(1), and two equivalent In(2) atoms to form OVIn3 tetrahedra that share corners with two equivalent O(4)In4 tetrahedra, corners with two equivalent O(3)VIn3 tetrahedra, corners with four equivalent O(5)VIn3 tetrahedra, and edges with two equivalent O(4)In4 tetrahedra. In the fourth O site, O(4) is bonded to two equivalent In(1) and two equivalent In(2) atoms to form distorted OIn4 tetrahedra that share corners with two equivalent O(3)VIn3 tetrahedra, corners with four equivalent O(4)In4 tetrahedra, corners with four equivalent O(5)VIn3 tetrahedra,  an edgeedge with one O(5)VIn3 tetrahedra, and edges with two equivalent O(3)VIn3 tetrahedra. In the fifth O site, O(5) is bonded to one V(1) and three equivalent In(1) atoms to form OVIn3 tetrahedra that share corners with two equivalent O(5)VIn3 tetrahedra, corners with four equivalent O(4)In4 tetrahedra, corners with four equivalent O(3)VIn3 tetrahedra,  an edgeedge with one O(4)In4 tetrahedra, and edges with two equivalent O(5)VIn3 tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_VIn2O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.569
_cell_length_b   7.327
_cell_length_c   14.985
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   391.873
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.250  0.604  0.075  1.0
  V  V1  1  0.750  0.396  0.925  1.0
  V  V2  1  0.250  0.104  0.425  1.0
  V  V3  1  0.750  0.896  0.575  1.0
  In  In4  1  0.250  0.604  0.418  1.0
  In  In5  1  0.750  0.896  0.918  1.0
  In  In6  1  0.250  0.104  0.082  1.0
  In  In7  1  0.750  0.396  0.582  1.0
  In  In8  1  0.250  0.674  0.761  1.0
  In  In9  1  0.750  0.326  0.239  1.0
  In  In10  1  0.250  0.174  0.739  1.0
  In  In11  1  0.750  0.826  0.261  1.0
  O  O12  1  0.250  0.435  0.959  1.0
  O  O13  1  0.750  0.565  0.041  1.0
  O  O14  1  0.250  0.935  0.541  1.0
  O  O15  1  0.750  0.065  0.459  1.0
  O  O16  1  0.250  0.733  0.176  1.0
  O  O17  1  0.750  0.267  0.824  1.0
  O  O18  1  0.250  0.233  0.324  1.0
  O  O19  1  0.750  0.767  0.676  1.0
  O  O20  1  0.250  0.370  0.151  1.0
  O  O21  1  0.750  0.630  0.849  1.0
  O  O22  1  0.250  0.870  0.349  1.0
  O  O23  1  0.750  0.130  0.651  1.0
  O  O24  1  0.750  0.058  0.176  1.0
  O  O25  1  0.250  0.942  0.824  1.0
  O  O26  1  0.750  0.558  0.324  1.0
  O  O27  1  0.250  0.442  0.676  1.0
  O  O28  1  0.250  0.845  0.005  1.0
  O  O29  1  0.250  0.345  0.495  1.0
  O  O30  1  0.750  0.155  0.995  1.0
  O  O31  1  0.750  0.655  0.505  1.0
[/CIF]
.