The crystal structure described by CF3C2S2O2F is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four trifluoromethane molecules and four C2S2O2F clusters. In each C2S2O2F cluster, there are two inequivalent C sites. In the first C site, C(2) is bonded in a distorted bent 120 degrees geometry to one S(1), one O(1), and one F(1) atom. In the second C site, C(3) is bonded in a distorted single-bond geometry to one S(2) and one O(2) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one C(2) and one S(2) atom. In the second S site, S(2) is bonded in a water-like geometry to one C(3) and one S(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(3) atom. F(1) is bonded in a single-bond geometry to one C(2) atom. is represented by the CIF file [CIF]
data_C3S2(OF2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   24.018
_cell_length_b   5.404
_cell_length_c   6.528
_cell_angle_alpha   63.737
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   759.769
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  C  C0  1  0.938  0.486  0.275  1.0
  C  C1  1  0.062  0.514  0.725  1.0
  C  C2  1  0.438  0.514  0.225  1.0
  C  C3  1  0.562  0.486  0.775  1.0
  C  C4  1  0.679  0.811  0.118  1.0
  C  C5  1  0.321  0.189  0.882  1.0
  C  C6  1  0.179  0.189  0.382  1.0
  C  C7  1  0.821  0.811  0.618  1.0
  C  C8  1  0.880  0.502  0.163  1.0
  C  C9  1  0.120  0.498  0.837  1.0
  C  C10  1  0.380  0.498  0.337  1.0
  C  C11  1  0.620  0.502  0.663  1.0
  S  S12  1  0.695  0.467  0.314  1.0
  S  S13  1  0.305  0.533  0.686  1.0
  S  S14  1  0.195  0.533  0.186  1.0
  S  S15  1  0.805  0.467  0.814  1.0
  S  S16  1  0.380  0.655  0.528  1.0
  S  S17  1  0.620  0.345  0.472  1.0
  S  S18  1  0.880  0.345  0.972  1.0
  S  S19  1  0.120  0.655  0.028  1.0
  O  O20  1  0.638  0.946  0.098  1.0
  O  O21  1  0.362  0.054  0.902  1.0
  O  O22  1  0.138  0.054  0.402  1.0
  O  O23  1  0.862  0.946  0.598  1.0
  O  O24  1  0.842  0.626  0.197  1.0
  O  O25  1  0.158  0.374  0.803  1.0
  O  O26  1  0.342  0.374  0.303  1.0
  O  O27  1  0.658  0.626  0.697  1.0
  F  F28  1  0.775  0.916  0.480  1.0
  F  F29  1  0.225  0.084  0.520  1.0
  F  F30  1  0.275  0.084  0.020  1.0
  F  F31  1  0.725  0.916  0.980  1.0
  F  F32  1  0.933  0.483  0.482  1.0
  F  F33  1  0.067  0.517  0.518  1.0
  F  F34  1  0.433  0.517  0.018  1.0
  F  F35  1  0.567  0.483  0.982  1.0
  F  F36  1  0.468  0.740  0.202  1.0
  F  F37  1  0.532  0.260  0.798  1.0
  F  F38  1  0.968  0.260  0.298  1.0
  F  F39  1  0.032  0.740  0.702  1.0
  F  F40  1  0.968  0.715  0.139  1.0
  F  F41  1  0.032  0.285  0.861  1.0
  F  F42  1  0.468  0.285  0.361  1.0
  F  F43  1  0.532  0.715  0.639  1.0
[/CIF]
.
The crystal structure described by CF3C2S2O2F is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four trifluoromethane molecules and four C2S2O2F clusters. In each C2S2O2F cluster, there are two inequivalent C sites. In the first C site, C(2) is bonded in a distorted bent 120 degrees geometry to one S(1), one O(1), and one F(1) atom. In the second C site, C(3) is bonded in a distorted single-bond geometry to one S(2) and one O(2) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one C(2) and one S(2) atom. In the second S site, S(2) is bonded in a water-like geometry to one C(3) and one S(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(3) atom. F(1) is bonded in a single-bond geometry to one C(2) atom. is represented by the CIF file [CIF]
data_C3S2(OF2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   24.018
_cell_length_b   5.404
_cell_length_c   6.528
_cell_angle_alpha   63.737
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   759.769
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  C  C0  1  0.938  0.486  0.275  1.0
  C  C1  1  0.062  0.514  0.725  1.0
  C  C2  1  0.438  0.514  0.225  1.0
  C  C3  1  0.562  0.486  0.775  1.0
  C  C4  1  0.679  0.811  0.118  1.0
  C  C5  1  0.321  0.189  0.882  1.0
  C  C6  1  0.179  0.189  0.382  1.0
  C  C7  1  0.821  0.811  0.618  1.0
  C  C8  1  0.880  0.502  0.163  1.0
  C  C9  1  0.120  0.498  0.837  1.0
  C  C10  1  0.380  0.498  0.337  1.0
  C  C11  1  0.620  0.502  0.663  1.0
  S  S12  1  0.695  0.467  0.314  1.0
  S  S13  1  0.305  0.533  0.686  1.0
  S  S14  1  0.195  0.533  0.186  1.0
  S  S15  1  0.805  0.467  0.814  1.0
  S  S16  1  0.380  0.655  0.528  1.0
  S  S17  1  0.620  0.345  0.472  1.0
  S  S18  1  0.880  0.345  0.972  1.0
  S  S19  1  0.120  0.655  0.028  1.0
  O  O20  1  0.638  0.946  0.098  1.0
  O  O21  1  0.362  0.054  0.902  1.0
  O  O22  1  0.138  0.054  0.402  1.0
  O  O23  1  0.862  0.946  0.598  1.0
  O  O24  1  0.842  0.626  0.197  1.0
  O  O25  1  0.158  0.374  0.803  1.0
  O  O26  1  0.342  0.374  0.303  1.0
  O  O27  1  0.658  0.626  0.697  1.0
  F  F28  1  0.775  0.916  0.480  1.0
  F  F29  1  0.225  0.084  0.520  1.0
  F  F30  1  0.275  0.084  0.020  1.0
  F  F31  1  0.725  0.916  0.980  1.0
  F  F32  1  0.933  0.483  0.482  1.0
  F  F33  1  0.067  0.517  0.518  1.0
  F  F34  1  0.433  0.517  0.018  1.0
  F  F35  1  0.567  0.483  0.982  1.0
  F  F36  1  0.468  0.740  0.202  1.0
  F  F37  1  0.532  0.260  0.798  1.0
  F  F38  1  0.968  0.260  0.298  1.0
  F  F39  1  0.032  0.740  0.702  1.0
  F  F40  1  0.968  0.715  0.139  1.0
  F  F41  1  0.032  0.285  0.861  1.0
  F  F42  1  0.468  0.285  0.361  1.0
  F  F43  1  0.532  0.715  0.639  1.0
[/CIF]
.