The compound described by HoMnO3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. Ho(1) is bonded in a 8-coordinate geometry to two equivalent O(2) and six equivalent O(1) atoms. Mn(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 37-41°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to three equivalent Ho(1) and two equivalent Mn(1) atoms. In the second O site, O(2) is bonded to two equivalent Ho(1) and two equivalent Mn(1) atoms to form distorted corner-sharing OHo2Mn2 trigonal pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_HoMnO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.312
_cell_length_b   5.857
_cell_length_c   7.478
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   232.649
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ho  Ho0  1  0.019  0.917  0.750  1.0
  Ho  Ho1  1  0.519  0.583  0.250  1.0
  Ho  Ho2  1  0.481  0.417  0.750  1.0
  Ho  Ho3  1  0.981  0.083  0.250  1.0
  Mn  Mn4  1  0.500  0.000  0.500  1.0
  Mn  Mn5  1  0.000  0.500  0.500  1.0
  Mn  Mn6  1  0.000  0.500  0.000  1.0
  Mn  Mn7  1  0.500  0.000  0.000  1.0
  O  O8  1  0.700  0.326  0.442  1.0
  O  O9  1  0.200  0.174  0.558  1.0
  O  O10  1  0.800  0.826  0.058  1.0
  O  O11  1  0.300  0.674  0.942  1.0
  O  O12  1  0.300  0.674  0.558  1.0
  O  O13  1  0.800  0.826  0.442  1.0
  O  O14  1  0.200  0.174  0.942  1.0
  O  O15  1  0.700  0.326  0.058  1.0
  O  O16  1  0.122  0.456  0.250  1.0
  O  O17  1  0.622  0.044  0.750  1.0
  O  O18  1  0.378  0.956  0.250  1.0
  O  O19  1  0.878  0.544  0.750  1.0
[/CIF]
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The compound described by HoMnO3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. Ho(1) is bonded in a 8-coordinate geometry to two equivalent O(2) and six equivalent O(1) atoms. Mn(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles range from 37-41°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to three equivalent Ho(1) and two equivalent Mn(1) atoms. In the second O site, O(2) is bonded to two equivalent Ho(1) and two equivalent Mn(1) atoms to form distorted corner-sharing OHo2Mn2 trigonal pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_HoMnO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.312
_cell_length_b   5.857
_cell_length_c   7.478
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   232.649
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ho  Ho0  1  0.019  0.917  0.750  1.0
  Ho  Ho1  1  0.519  0.583  0.250  1.0
  Ho  Ho2  1  0.481  0.417  0.750  1.0
  Ho  Ho3  1  0.981  0.083  0.250  1.0
  Mn  Mn4  1  0.500  0.000  0.500  1.0
  Mn  Mn5  1  0.000  0.500  0.500  1.0
  Mn  Mn6  1  0.000  0.500  0.000  1.0
  Mn  Mn7  1  0.500  0.000  0.000  1.0
  O  O8  1  0.700  0.326  0.442  1.0
  O  O9  1  0.200  0.174  0.558  1.0
  O  O10  1  0.800  0.826  0.058  1.0
  O  O11  1  0.300  0.674  0.942  1.0
  O  O12  1  0.300  0.674  0.558  1.0
  O  O13  1  0.800  0.826  0.442  1.0
  O  O14  1  0.200  0.174  0.942  1.0
  O  O15  1  0.700  0.326  0.058  1.0
  O  O16  1  0.122  0.456  0.250  1.0
  O  O17  1  0.622  0.044  0.750  1.0
  O  O18  1  0.378  0.956  0.250  1.0
  O  O19  1  0.878  0.544  0.750  1.0
[/CIF]
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