The compound described by Zr3Rh5 crystallizes in the orthorhombic Cmcm space group. There are two inequivalent Zr sites. In the first Zr site, Zr(1) is bonded in a 9-coordinate geometry to one Rh(3), four equivalent Rh(1), and four equivalent Rh(2) atoms. In the second Zr site, Zr(2) is bonded in a 10-coordinate geometry to two equivalent Rh(3), four equivalent Rh(1), and four equivalent Rh(2) atoms. There are three inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 6-coordinate geometry to two equivalent Zr(1) and four equivalent Zr(2) atoms. In the second Rh site, Rh(2) is bonded in a 6-coordinate geometry to two equivalent Zr(1) and four equivalent Zr(2) atoms. In the third Rh site, Rh(3) is bonded in a 5-coordinate geometry to one Zr(1) and four equivalent Zr(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Zr3Rh5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.593
_cell_length_b   5.593
_cell_length_c   8.635
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   102.481
_symmetry_Int_Tables_number   1
_cell_volume   263.698
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr0  1  0.564  0.564  0.750  1.0
  Zr  Zr1  1  0.436  0.436  0.250  1.0
  Zr  Zr2  1  0.207  0.793  0.500  1.0
  Zr  Zr3  1  0.793  0.207  0.000  1.0
  Zr  Zr4  1  0.793  0.207  0.500  1.0
  Zr  Zr5  1  0.207  0.793  0.000  1.0
  Rh  Rh6  1  0.712  0.712  0.026  1.0
  Rh  Rh7  1  0.712  0.712  0.474  1.0
  Rh  Rh8  1  0.288  0.288  0.974  1.0
  Rh  Rh9  1  0.288  0.288  0.526  1.0
  Rh  Rh10  1  0.024  0.494  0.750  1.0
  Rh  Rh11  1  0.976  0.506  0.250  1.0
  Rh  Rh12  1  0.012  0.012  0.250  1.0
  Rh  Rh13  1  0.988  0.988  0.750  1.0
  Rh  Rh14  1  0.494  0.024  0.750  1.0
  Rh  Rh15  1  0.506  0.976  0.250  1.0
[/CIF]
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The compound described by Zr3Rh5 crystallizes in the orthorhombic Cmcm space group. There are two inequivalent Zr sites. In the first Zr site, Zr(1) is bonded in a 9-coordinate geometry to one Rh(3), four equivalent Rh(1), and four equivalent Rh(2) atoms. In the second Zr site, Zr(2) is bonded in a 10-coordinate geometry to two equivalent Rh(3), four equivalent Rh(1), and four equivalent Rh(2) atoms. There are three inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 6-coordinate geometry to two equivalent Zr(1) and four equivalent Zr(2) atoms. In the second Rh site, Rh(2) is bonded in a 6-coordinate geometry to two equivalent Zr(1) and four equivalent Zr(2) atoms. In the third Rh site, Rh(3) is bonded in a 5-coordinate geometry to one Zr(1) and four equivalent Zr(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Zr3Rh5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.593
_cell_length_b   5.593
_cell_length_c   8.635
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   102.481
_symmetry_Int_Tables_number   1
_cell_volume   263.698
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr0  1  0.564  0.564  0.750  1.0
  Zr  Zr1  1  0.436  0.436  0.250  1.0
  Zr  Zr2  1  0.207  0.793  0.500  1.0
  Zr  Zr3  1  0.793  0.207  0.000  1.0
  Zr  Zr4  1  0.793  0.207  0.500  1.0
  Zr  Zr5  1  0.207  0.793  0.000  1.0
  Rh  Rh6  1  0.712  0.712  0.026  1.0
  Rh  Rh7  1  0.712  0.712  0.474  1.0
  Rh  Rh8  1  0.288  0.288  0.974  1.0
  Rh  Rh9  1  0.288  0.288  0.526  1.0
  Rh  Rh10  1  0.024  0.494  0.750  1.0
  Rh  Rh11  1  0.976  0.506  0.250  1.0
  Rh  Rh12  1  0.012  0.012  0.250  1.0
  Rh  Rh13  1  0.988  0.988  0.750  1.0
  Rh  Rh14  1  0.494  0.024  0.750  1.0
  Rh  Rh15  1  0.506  0.976  0.250  1.0
[/CIF]
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