The compound described by LiSb3O8 is Hydrophilite-derived structured and crystallizes in the monoclinic P2_1/c space group. Li(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form LiO6 octahedra that share corners with four equivalent Sb(1)O6 octahedra, corners with four equivalent Sb(2)O6 octahedra, and edges with two equivalent Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-54°. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form SbO6 octahedra that share corners with four equivalent Li(1)O6 octahedra, corners with four equivalent Sb(2)O6 octahedra, and edges with two equivalent Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-54°. In the second Sb site, Sb(2) is bonded to one O(1), one O(3), two equivalent O(2), and two equivalent O(4) atoms to form SbO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Sb(1)O6 octahedra, corners with four equivalent Sb(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra, and  an edgeedge with one Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-52°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Li(1), one Sb(1), and one Sb(2) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Sb(1) and two equivalent Sb(2) atoms. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Li(1), one Sb(1), and one Sb(2) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Li(1) and two equivalent Sb(2) atoms. is represented by the CIF card [CIF]
data_LiSb3O8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.708
_cell_length_b   5.620
_cell_length_c   10.301
_cell_angle_alpha   83.559
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   270.851
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.500  0.000  0.500  1.0
  Li  Li1  1  0.000  0.000  0.000  1.0
  Sb  Sb2  1  0.500  0.500  0.000  1.0
  Sb  Sb3  1  0.000  0.500  0.500  1.0
  Sb  Sb4  1  0.980  0.763  0.751  1.0
  Sb  Sb5  1  0.480  0.237  0.749  1.0
  Sb  Sb6  1  0.020  0.237  0.249  1.0
  Sb  Sb7  1  0.520  0.763  0.251  1.0
  O  O8  1  0.328  0.764  0.082  1.0
  O  O9  1  0.828  0.236  0.418  1.0
  O  O10  1  0.672  0.236  0.918  1.0
  O  O11  1  0.172  0.764  0.582  1.0
  O  O12  1  0.219  0.520  0.326  1.0
  O  O13  1  0.719  0.480  0.174  1.0
  O  O14  1  0.781  0.480  0.674  1.0
  O  O15  1  0.281  0.520  0.826  1.0
  O  O16  1  0.708  0.719  0.420  1.0
  O  O17  1  0.208  0.281  0.080  1.0
  O  O18  1  0.292  0.281  0.580  1.0
  O  O19  1  0.792  0.719  0.920  1.0
  O  O20  1  0.192  0.013  0.824  1.0
  O  O21  1  0.692  0.987  0.676  1.0
  O  O22  1  0.808  0.987  0.176  1.0
  O  O23  1  0.308  0.013  0.324  1.0
[/CIF]
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The compound described by LiSb3O8 is Hydrophilite-derived structured and crystallizes in the monoclinic P2_1/c space group. Li(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form LiO6 octahedra that share corners with four equivalent Sb(1)O6 octahedra, corners with four equivalent Sb(2)O6 octahedra, and edges with two equivalent Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-54°. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form SbO6 octahedra that share corners with four equivalent Li(1)O6 octahedra, corners with four equivalent Sb(2)O6 octahedra, and edges with two equivalent Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-54°. In the second Sb site, Sb(2) is bonded to one O(1), one O(3), two equivalent O(2), and two equivalent O(4) atoms to form SbO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Sb(1)O6 octahedra, corners with four equivalent Sb(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra, and  an edgeedge with one Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-52°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Li(1), one Sb(1), and one Sb(2) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Sb(1) and two equivalent Sb(2) atoms. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Li(1), one Sb(1), and one Sb(2) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Li(1) and two equivalent Sb(2) atoms. is represented by the CIF card [CIF]
data_LiSb3O8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.708
_cell_length_b   5.620
_cell_length_c   10.301
_cell_angle_alpha   83.559
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   270.851
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.500  0.000  0.500  1.0
  Li  Li1  1  0.000  0.000  0.000  1.0
  Sb  Sb2  1  0.500  0.500  0.000  1.0
  Sb  Sb3  1  0.000  0.500  0.500  1.0
  Sb  Sb4  1  0.980  0.763  0.751  1.0
  Sb  Sb5  1  0.480  0.237  0.749  1.0
  Sb  Sb6  1  0.020  0.237  0.249  1.0
  Sb  Sb7  1  0.520  0.763  0.251  1.0
  O  O8  1  0.328  0.764  0.082  1.0
  O  O9  1  0.828  0.236  0.418  1.0
  O  O10  1  0.672  0.236  0.918  1.0
  O  O11  1  0.172  0.764  0.582  1.0
  O  O12  1  0.219  0.520  0.326  1.0
  O  O13  1  0.719  0.480  0.174  1.0
  O  O14  1  0.781  0.480  0.674  1.0
  O  O15  1  0.281  0.520  0.826  1.0
  O  O16  1  0.708  0.719  0.420  1.0
  O  O17  1  0.208  0.281  0.080  1.0
  O  O18  1  0.292  0.281  0.580  1.0
  O  O19  1  0.792  0.719  0.920  1.0
  O  O20  1  0.192  0.013  0.824  1.0
  O  O21  1  0.692  0.987  0.676  1.0
  O  O22  1  0.808  0.987  0.176  1.0
  O  O23  1  0.308  0.013  0.324  1.0
[/CIF]
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