The crystal structure described by AgSbS2 crystallizes in the monoclinic Cc space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a tetrahedral geometry to one S(1), one S(2), one S(3), and one S(4) atom. In the second Ag site, Ag(2) is bonded in a distorted square co-planar geometry to one S(1), one S(2), one S(3), and one S(4) atom. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a distorted T-shaped geometry to one S(1), one S(2), and one S(4) atom. In the second Sb site, Sb(2) is bonded in a distorted T-shaped geometry to one S(1), one S(2), and one S(3) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a distorted trigonal pyramidal geometry to one Ag(1), one Ag(2), one Sb(1), and one Sb(2) atom. In the second S site, S(2) is bonded in a 4-coordinate geometry to one Ag(1), one Ag(2), one Sb(1), and one Sb(2) atom. In the third S site, S(3) is bonded in a trigonal non-coplanar geometry to one Ag(1), one Ag(2), and one Sb(2) atom. In the fourth S site, S(4) is bonded in a trigonal non-coplanar geometry to one Ag(1), one Ag(2), and one Sb(1) atom. is represented by the CIF card [CIF]
data_AgSbS2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.913
_cell_length_b   6.913
_cell_length_c   13.303
_cell_angle_alpha   82.297
_cell_angle_beta   82.297
_cell_angle_gamma   38.488
_symmetry_Int_Tables_number   1
_cell_volume   391.632
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.011  0.997  0.254  1.0
  Ag  Ag1  1  0.997  0.011  0.754  1.0
  Ag  Ag2  1  0.518  0.496  0.004  1.0
  Ag  Ag3  1  0.496  0.518  0.504  1.0
  Sb  Sb4  1  0.232  0.289  0.882  1.0
  Sb  Sb5  1  0.289  0.232  0.382  1.0
  Sb  Sb6  1  0.782  0.716  0.135  1.0
  Sb  Sb7  1  0.716  0.782  0.635  1.0
  S  S8  1  0.496  0.801  0.808  1.0
  S  S9  1  0.801  0.496  0.308  1.0
  S  S10  1  0.505  0.211  0.206  1.0
  S  S11  1  0.211  0.505  0.706  1.0
  S  S12  1  0.305  0.922  0.090  1.0
  S  S13  1  0.922  0.305  0.590  1.0
  S  S14  1  0.717  0.073  0.921  1.0
  S  S15  1  0.073  0.717  0.421  1.0
[/CIF]
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The crystal structure described by AgSbS2 crystallizes in the monoclinic Cc space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a tetrahedral geometry to one S(1), one S(2), one S(3), and one S(4) atom. In the second Ag site, Ag(2) is bonded in a distorted square co-planar geometry to one S(1), one S(2), one S(3), and one S(4) atom. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a distorted T-shaped geometry to one S(1), one S(2), and one S(4) atom. In the second Sb site, Sb(2) is bonded in a distorted T-shaped geometry to one S(1), one S(2), and one S(3) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a distorted trigonal pyramidal geometry to one Ag(1), one Ag(2), one Sb(1), and one Sb(2) atom. In the second S site, S(2) is bonded in a 4-coordinate geometry to one Ag(1), one Ag(2), one Sb(1), and one Sb(2) atom. In the third S site, S(3) is bonded in a trigonal non-coplanar geometry to one Ag(1), one Ag(2), and one Sb(2) atom. In the fourth S site, S(4) is bonded in a trigonal non-coplanar geometry to one Ag(1), one Ag(2), and one Sb(1) atom. is represented by the CIF card [CIF]
data_AgSbS2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.913
_cell_length_b   6.913
_cell_length_c   13.303
_cell_angle_alpha   82.297
_cell_angle_beta   82.297
_cell_angle_gamma   38.488
_symmetry_Int_Tables_number   1
_cell_volume   391.632
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.011  0.997  0.254  1.0
  Ag  Ag1  1  0.997  0.011  0.754  1.0
  Ag  Ag2  1  0.518  0.496  0.004  1.0
  Ag  Ag3  1  0.496  0.518  0.504  1.0
  Sb  Sb4  1  0.232  0.289  0.882  1.0
  Sb  Sb5  1  0.289  0.232  0.382  1.0
  Sb  Sb6  1  0.782  0.716  0.135  1.0
  Sb  Sb7  1  0.716  0.782  0.635  1.0
  S  S8  1  0.496  0.801  0.808  1.0
  S  S9  1  0.801  0.496  0.308  1.0
  S  S10  1  0.505  0.211  0.206  1.0
  S  S11  1  0.211  0.505  0.706  1.0
  S  S12  1  0.305  0.922  0.090  1.0
  S  S13  1  0.922  0.305  0.590  1.0
  S  S14  1  0.717  0.073  0.921  1.0
  S  S15  1  0.073  0.717  0.421  1.0
[/CIF]
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