The material described by LiGdO2 crystallizes in the tetragonal I4_1/amd space group. Li(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. Gd(1) is bonded to six equivalent O(1) atoms to form a mixture of corner and edge-sharing GdO6 octahedra. The corner-sharing octahedral tilt angles are 15°. O(1) is bonded to two equivalent Li(1) and three equivalent Gd(1) atoms to form a mixture of corner and edge-sharing OLi2Gd3 square pyramids. is represented by the CIF card [CIF]
data_LiGdO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.201
_cell_length_b   6.201
_cell_length_c   6.201
_cell_angle_alpha   137.213
_cell_angle_beta   137.213
_cell_angle_gamma   62.110
_symmetry_Int_Tables_number   1
_cell_volume   108.726
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.500  0.500  0.000  1.0
  Li  Li1  1  0.250  0.750  0.500  1.0
  Gd  Gd2  1  0.000  0.000  0.000  1.0
  Gd  Gd3  1  0.750  0.250  0.500  1.0
  O  O4  1  0.777  0.777  0.000  1.0
  O  O5  1  0.223  0.223  0.000  1.0
  O  O6  1  0.973  0.473  0.500  1.0
  O  O7  1  0.527  0.027  0.500  1.0
[/CIF]
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The material described by LiGdO2 crystallizes in the tetragonal I4_1/amd space group. Li(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. Gd(1) is bonded to six equivalent O(1) atoms to form a mixture of corner and edge-sharing GdO6 octahedra. The corner-sharing octahedral tilt angles are 15°. O(1) is bonded to two equivalent Li(1) and three equivalent Gd(1) atoms to form a mixture of corner and edge-sharing OLi2Gd3 square pyramids. is represented by the CIF card [CIF]
data_LiGdO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.201
_cell_length_b   6.201
_cell_length_c   6.201
_cell_angle_alpha   137.213
_cell_angle_beta   137.213
_cell_angle_gamma   62.110
_symmetry_Int_Tables_number   1
_cell_volume   108.726
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.500  0.500  0.000  1.0
  Li  Li1  1  0.250  0.750  0.500  1.0
  Gd  Gd2  1  0.000  0.000  0.000  1.0
  Gd  Gd3  1  0.750  0.250  0.500  1.0
  O  O4  1  0.777  0.777  0.000  1.0
  O  O5  1  0.223  0.223  0.000  1.0
  O  O6  1  0.973  0.473  0.500  1.0
  O  O7  1  0.527  0.027  0.500  1.0
[/CIF]
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