The crystal structure described by BiVO4 crystallizes in the orthorhombic Pbcn space group. V(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. Bi(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one V(1) and two equivalent Bi(1) atoms. In the second O site, O(2) is bonded in a distorted single-bond geometry to one V(1) and two equivalent Bi(1) atoms. is represented by the CIF card [CIF]
data_VBiO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.109
_cell_length_b   5.372
_cell_length_c   12.056
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   330.842
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.000  0.750  0.394  1.0
  V  V1  1  0.500  0.250  0.106  1.0
  V  V2  1  0.000  0.250  0.606  1.0
  V  V3  1  0.500  0.750  0.894  1.0
  Bi  Bi4  1  0.000  0.750  0.116  1.0
  Bi  Bi5  1  0.500  0.250  0.384  1.0
  Bi  Bi6  1  0.000  0.250  0.884  1.0
  Bi  Bi7  1  0.500  0.750  0.616  1.0
  O  O8  1  0.244  0.081  0.034  1.0
  O  O9  1  0.744  0.919  0.466  1.0
  O  O10  1  0.256  0.581  0.466  1.0
  O  O11  1  0.756  0.419  0.034  1.0
  O  O12  1  0.756  0.919  0.966  1.0
  O  O13  1  0.256  0.081  0.534  1.0
  O  O14  1  0.744  0.419  0.534  1.0
  O  O15  1  0.244  0.581  0.966  1.0
  O  O16  1  0.649  0.044  0.194  1.0
  O  O17  1  0.149  0.956  0.306  1.0
  O  O18  1  0.851  0.544  0.306  1.0
  O  O19  1  0.351  0.456  0.194  1.0
  O  O20  1  0.351  0.956  0.806  1.0
  O  O21  1  0.851  0.044  0.694  1.0
  O  O22  1  0.149  0.456  0.694  1.0
  O  O23  1  0.649  0.544  0.806  1.0
[/CIF]
.
The crystal structure described by BiVO4 crystallizes in the orthorhombic Pbcn space group. V(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. Bi(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one V(1) and two equivalent Bi(1) atoms. In the second O site, O(2) is bonded in a distorted single-bond geometry to one V(1) and two equivalent Bi(1) atoms. is represented by the CIF card [CIF]
data_VBiO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.109
_cell_length_b   5.372
_cell_length_c   12.056
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   330.842
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.000  0.750  0.394  1.0
  V  V1  1  0.500  0.250  0.106  1.0
  V  V2  1  0.000  0.250  0.606  1.0
  V  V3  1  0.500  0.750  0.894  1.0
  Bi  Bi4  1  0.000  0.750  0.116  1.0
  Bi  Bi5  1  0.500  0.250  0.384  1.0
  Bi  Bi6  1  0.000  0.250  0.884  1.0
  Bi  Bi7  1  0.500  0.750  0.616  1.0
  O  O8  1  0.244  0.081  0.034  1.0
  O  O9  1  0.744  0.919  0.466  1.0
  O  O10  1  0.256  0.581  0.466  1.0
  O  O11  1  0.756  0.419  0.034  1.0
  O  O12  1  0.756  0.919  0.966  1.0
  O  O13  1  0.256  0.081  0.534  1.0
  O  O14  1  0.744  0.419  0.534  1.0
  O  O15  1  0.244  0.581  0.966  1.0
  O  O16  1  0.649  0.044  0.194  1.0
  O  O17  1  0.149  0.956  0.306  1.0
  O  O18  1  0.851  0.544  0.306  1.0
  O  O19  1  0.351  0.456  0.194  1.0
  O  O20  1  0.351  0.956  0.806  1.0
  O  O21  1  0.851  0.044  0.694  1.0
  O  O22  1  0.149  0.456  0.694  1.0
  O  O23  1  0.649  0.544  0.806  1.0
[/CIF]
.