The compound described by SnC6H12(NS2)2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four SnC6H12(NS2)2 clusters. Sn(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent S(1) and two equivalent S(2) atoms. There are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one N(1), one S(1), and one S(2) atom. In the second C site, C(2) is bonded to one N(1), one H(1), one H(2), and one H(3) atom to form corner-sharing CH3N tetrahedra. In the third C site, C(3) is bonded to one N(1), one H(4), one H(5), and one H(6) atom to form corner-sharing CH3N tetrahedra. N(1) is bonded in a trigonal planar geometry to one C(1), one C(2), and one C(3) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(3) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in an L-shaped geometry to one Sn(1) and one C(1) atom. In the second S site, S(2) is bonded in an L-shaped geometry to one Sn(1) and one C(1) atom. is represented by the CIF file [CIF]
data_SnH12C6(S2N)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.698
_cell_length_b   7.698
_cell_length_c   12.444
_cell_angle_alpha   78.669
_cell_angle_beta   78.669
_cell_angle_gamma   107.525
_symmetry_Int_Tables_number   1
_cell_volume   663.160
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.523  0.477  0.250  1.0
  Sn  Sn1  1  0.477  0.523  0.750  1.0
  H  H2  1  0.020  0.226  0.631  1.0
  H  H3  1  0.774  0.980  0.869  1.0
  H  H4  1  0.980  0.774  0.369  1.0
  H  H5  1  0.226  0.020  0.131  1.0
  H  H6  1  0.830  0.018  0.639  1.0
  H  H7  1  0.982  0.170  0.861  1.0
  H  H8  1  0.170  0.982  0.361  1.0
  H  H9  1  0.018  0.830  0.139  1.0
  H  H10  1  0.787  0.234  0.639  1.0
  H  H11  1  0.766  0.213  0.861  1.0
  H  H12  1  0.213  0.766  0.361  1.0
  H  H13  1  0.234  0.787  0.139  1.0
  H  H14  1  0.820  0.204  0.342  1.0
  H  H15  1  0.796  0.180  0.158  1.0
  H  H16  1  0.180  0.796  0.658  1.0
  H  H17  1  0.204  0.820  0.842  1.0
  H  H18  1  0.668  0.222  0.465  1.0
  H  H19  1  0.778  0.332  0.035  1.0
  H  H20  1  0.332  0.778  0.535  1.0
  H  H21  1  0.222  0.668  0.965  1.0
  H  H22  1  0.710  0.005  0.465  1.0
  H  H23  1  0.995  0.290  0.035  1.0
  H  H24  1  0.290  0.995  0.535  1.0
  H  H25  1  0.005  0.710  0.965  1.0
  C  C26  1  0.113  0.325  0.414  1.0
  C  C27  1  0.675  0.887  0.086  1.0
  C  C28  1  0.887  0.675  0.586  1.0
  C  C29  1  0.325  0.113  0.914  1.0
  C  C30  1  0.891  0.173  0.605  1.0
  C  C31  1  0.827  0.109  0.895  1.0
  C  C32  1  0.109  0.827  0.395  1.0
  C  C33  1  0.173  0.891  0.105  1.0
  C  C34  1  0.774  0.160  0.435  1.0
  C  C35  1  0.840  0.226  0.065  1.0
  C  C36  1  0.226  0.840  0.565  1.0
  C  C37  1  0.160  0.774  0.935  1.0
  S  S38  1  0.160  0.382  0.266  1.0
  S  S39  1  0.618  0.840  0.234  1.0
  S  S40  1  0.840  0.618  0.734  1.0
  S  S41  1  0.382  0.160  0.766  1.0
  S  S42  1  0.300  0.400  0.471  1.0
  S  S43  1  0.600  0.700  0.029  1.0
  S  S44  1  0.700  0.600  0.529  1.0
  S  S45  1  0.400  0.300  0.971  1.0
  N  N46  1  0.936  0.225  0.481  1.0
  N  N47  1  0.775  0.064  0.019  1.0
  N  N48  1  0.064  0.775  0.519  1.0
  N  N49  1  0.225  0.936  0.981  1.0
[/CIF]
.
The compound described by SnC6H12(NS2)2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four SnC6H12(NS2)2 clusters. Sn(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent S(1) and two equivalent S(2) atoms. There are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one N(1), one S(1), and one S(2) atom. In the second C site, C(2) is bonded to one N(1), one H(1), one H(2), and one H(3) atom to form corner-sharing CH3N tetrahedra. In the third C site, C(3) is bonded to one N(1), one H(4), one H(5), and one H(6) atom to form corner-sharing CH3N tetrahedra. N(1) is bonded in a trigonal planar geometry to one C(1), one C(2), and one C(3) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(3) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in an L-shaped geometry to one Sn(1) and one C(1) atom. In the second S site, S(2) is bonded in an L-shaped geometry to one Sn(1) and one C(1) atom. is represented by the CIF file [CIF]
data_SnH12C6(S2N)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.698
_cell_length_b   7.698
_cell_length_c   12.444
_cell_angle_alpha   78.669
_cell_angle_beta   78.669
_cell_angle_gamma   107.525
_symmetry_Int_Tables_number   1
_cell_volume   663.160
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.523  0.477  0.250  1.0
  Sn  Sn1  1  0.477  0.523  0.750  1.0
  H  H2  1  0.020  0.226  0.631  1.0
  H  H3  1  0.774  0.980  0.869  1.0
  H  H4  1  0.980  0.774  0.369  1.0
  H  H5  1  0.226  0.020  0.131  1.0
  H  H6  1  0.830  0.018  0.639  1.0
  H  H7  1  0.982  0.170  0.861  1.0
  H  H8  1  0.170  0.982  0.361  1.0
  H  H9  1  0.018  0.830  0.139  1.0
  H  H10  1  0.787  0.234  0.639  1.0
  H  H11  1  0.766  0.213  0.861  1.0
  H  H12  1  0.213  0.766  0.361  1.0
  H  H13  1  0.234  0.787  0.139  1.0
  H  H14  1  0.820  0.204  0.342  1.0
  H  H15  1  0.796  0.180  0.158  1.0
  H  H16  1  0.180  0.796  0.658  1.0
  H  H17  1  0.204  0.820  0.842  1.0
  H  H18  1  0.668  0.222  0.465  1.0
  H  H19  1  0.778  0.332  0.035  1.0
  H  H20  1  0.332  0.778  0.535  1.0
  H  H21  1  0.222  0.668  0.965  1.0
  H  H22  1  0.710  0.005  0.465  1.0
  H  H23  1  0.995  0.290  0.035  1.0
  H  H24  1  0.290  0.995  0.535  1.0
  H  H25  1  0.005  0.710  0.965  1.0
  C  C26  1  0.113  0.325  0.414  1.0
  C  C27  1  0.675  0.887  0.086  1.0
  C  C28  1  0.887  0.675  0.586  1.0
  C  C29  1  0.325  0.113  0.914  1.0
  C  C30  1  0.891  0.173  0.605  1.0
  C  C31  1  0.827  0.109  0.895  1.0
  C  C32  1  0.109  0.827  0.395  1.0
  C  C33  1  0.173  0.891  0.105  1.0
  C  C34  1  0.774  0.160  0.435  1.0
  C  C35  1  0.840  0.226  0.065  1.0
  C  C36  1  0.226  0.840  0.565  1.0
  C  C37  1  0.160  0.774  0.935  1.0
  S  S38  1  0.160  0.382  0.266  1.0
  S  S39  1  0.618  0.840  0.234  1.0
  S  S40  1  0.840  0.618  0.734  1.0
  S  S41  1  0.382  0.160  0.766  1.0
  S  S42  1  0.300  0.400  0.471  1.0
  S  S43  1  0.600  0.700  0.029  1.0
  S  S44  1  0.700  0.600  0.529  1.0
  S  S45  1  0.400  0.300  0.971  1.0
  N  N46  1  0.936  0.225  0.481  1.0
  N  N47  1  0.775  0.064  0.019  1.0
  N  N48  1  0.064  0.775  0.519  1.0
  N  N49  1  0.225  0.936  0.981  1.0
[/CIF]
.