The material structure described by NaSbN2 is Caswellsilverite structured and crystallizes in the trigonal R-3m space group. Na(1) is bonded to six equivalent N(1) atoms to form distorted NaN6 octahedra that share corners with six equivalent Sb(1)N6 octahedra, edges with six equivalent Na(1)N6 octahedra, and edges with six equivalent Sb(1)N6 octahedra. The corner-sharing octahedral tilt angles are 12°. Sb(1) is bonded to six equivalent N(1) atoms to form SbN6 octahedra that share corners with six equivalent Na(1)N6 octahedra, edges with six equivalent Na(1)N6 octahedra, and edges with six equivalent Sb(1)N6 octahedra. The corner-sharing octahedral tilt angles are 12°. N(1) is bonded to three equivalent Na(1) and three equivalent Sb(1) atoms to form a mixture of corner and edge-sharing NNa3Sb3 octahedra. The corner-sharing octahedra are not tilted. is represented by the CIF file [CIF]
data_NaSbN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.205
_cell_length_b   3.205
_cell_length_c   6.111
_cell_angle_alpha   74.797
_cell_angle_beta   74.804
_cell_angle_gamma   60.001
_symmetry_Int_Tables_number   1
_cell_volume   51.802
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.500  0.500  0.500  1.0
  Sb  Sb1  1  0.000  0.000  0.000  1.0
  N  N2  1  0.268  0.268  0.196  1.0
  N  N3  1  0.732  0.732  0.804  1.0
[/CIF]
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The material structure described by NaSbN2 is Caswellsilverite structured and crystallizes in the trigonal R-3m space group. Na(1) is bonded to six equivalent N(1) atoms to form distorted NaN6 octahedra that share corners with six equivalent Sb(1)N6 octahedra, edges with six equivalent Na(1)N6 octahedra, and edges with six equivalent Sb(1)N6 octahedra. The corner-sharing octahedral tilt angles are 12°. Sb(1) is bonded to six equivalent N(1) atoms to form SbN6 octahedra that share corners with six equivalent Na(1)N6 octahedra, edges with six equivalent Na(1)N6 octahedra, and edges with six equivalent Sb(1)N6 octahedra. The corner-sharing octahedral tilt angles are 12°. N(1) is bonded to three equivalent Na(1) and three equivalent Sb(1) atoms to form a mixture of corner and edge-sharing NNa3Sb3 octahedra. The corner-sharing octahedra are not tilted. is represented by the CIF file [CIF]
data_NaSbN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.205
_cell_length_b   3.205
_cell_length_c   6.111
_cell_angle_alpha   74.797
_cell_angle_beta   74.804
_cell_angle_gamma   60.001
_symmetry_Int_Tables_number   1
_cell_volume   51.802
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.500  0.500  0.500  1.0
  Sb  Sb1  1  0.000  0.000  0.000  1.0
  N  N2  1  0.268  0.268  0.196  1.0
  N  N3  1  0.732  0.732  0.804  1.0
[/CIF]
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