The compound described by La2CCl is Caswellsilverite structured and crystallizes in the trigonal R-3m space group. La(1) is bonded to three equivalent C(1) and three equivalent Cl(1) atoms to form a mixture of corner and edge-sharing LaC3Cl3 octahedra. The corner-sharing octahedra are not tilted. C(1) is bonded to six equivalent La(1) atoms to form CLa6 octahedra that share corners with six equivalent Cl(1)La6 octahedra, edges with six equivalent C(1)La6 octahedra, and edges with six equivalent Cl(1)La6 octahedra. The corner-sharing octahedral tilt angles are 13°. Cl(1) is bonded to six equivalent La(1) atoms to form distorted ClLa6 octahedra that share corners with six equivalent C(1)La6 octahedra, edges with six equivalent C(1)La6 octahedra, and edges with six equivalent Cl(1)La6 octahedra. The corner-sharing octahedral tilt angles are 13°. is represented by the CIF card [CIF]
data_La2CCl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.651
_cell_length_b   7.651
_cell_length_c   7.651
_cell_angle_alpha   29.216
_cell_angle_beta   29.216
_cell_angle_gamma   29.216
_symmetry_Int_Tables_number   1
_cell_volume   94.428
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.231  0.231  0.231  1.0
  La  La1  1  0.769  0.769  0.769  1.0
  C  C2  1  0.500  0.500  0.500  1.0
  Cl  Cl3  1  0.000  0.000  0.000  1.0
[/CIF]
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The compound described by La2CCl is Caswellsilverite structured and crystallizes in the trigonal R-3m space group. La(1) is bonded to three equivalent C(1) and three equivalent Cl(1) atoms to form a mixture of corner and edge-sharing LaC3Cl3 octahedra. The corner-sharing octahedra are not tilted. C(1) is bonded to six equivalent La(1) atoms to form CLa6 octahedra that share corners with six equivalent Cl(1)La6 octahedra, edges with six equivalent C(1)La6 octahedra, and edges with six equivalent Cl(1)La6 octahedra. The corner-sharing octahedral tilt angles are 13°. Cl(1) is bonded to six equivalent La(1) atoms to form distorted ClLa6 octahedra that share corners with six equivalent C(1)La6 octahedra, edges with six equivalent C(1)La6 octahedra, and edges with six equivalent Cl(1)La6 octahedra. The corner-sharing octahedral tilt angles are 13°. is represented by the CIF card [CIF]
data_La2CCl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.651
_cell_length_b   7.651
_cell_length_c   7.651
_cell_angle_alpha   29.216
_cell_angle_beta   29.216
_cell_angle_gamma   29.216
_symmetry_Int_Tables_number   1
_cell_volume   94.428
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.231  0.231  0.231  1.0
  La  La1  1  0.769  0.769  0.769  1.0
  C  C2  1  0.500  0.500  0.500  1.0
  Cl  Cl3  1  0.000  0.000  0.000  1.0
[/CIF]
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