The material structure described by BaEuVBiO6 is Krennerite-derived structured and crystallizes in the triclinic P-1 space group. Ba(1) is bonded in a 12-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms. Eu(1) is bonded in a 12-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms. There are two inequivalent V sites. In the first V site, V(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form VO6 octahedra that share corners with two equivalent Bi(2)O6 octahedra and corners with four equivalent Bi(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 19-23°. In the second V site, V(2) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form VO6 octahedra that share corners with two equivalent Bi(1)O6 octahedra and corners with four equivalent Bi(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 18-22°. There are two inequivalent Bi sites. In the first Bi site, Bi(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(6) atoms to form BiO6 octahedra that share corners with two equivalent V(2)O6 octahedra and corners with four equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 18-22°. In the second Bi site, Bi(2) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(5) atoms to form BiO6 octahedra that share corners with two equivalent V(1)O6 octahedra and corners with four equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 18-23°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 1-coordinate geometry to two equivalent Ba(1), two equivalent Eu(1), one V(1), and one Bi(1) atom. In the second O site, O(2) is bonded in a 1-coordinate geometry to two equivalent Ba(1), two equivalent Eu(1), one V(2), and one Bi(2) atom. In the third O site, O(3) is bonded in a 1-coordinate geometry to two equivalent Ba(1), two equivalent Eu(1), one V(1), and one Bi(1) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to two equivalent Ba(1), two equivalent Eu(1), one V(2), and one Bi(2) atom. In the fifth O site, O(5) is bonded in a 1-coordinate geometry to two equivalent Ba(1), two equivalent Eu(1), one V(1), and one Bi(2) atom. In the sixth O site, O(6) is bonded in a 1-coordinate geometry to two equivalent Ba(1), two equivalent Eu(1), one V(2), and one Bi(1) atom. is represented by the CIF card [CIF]
data_BaEuVBiO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.609
_cell_length_b   5.611
_cell_length_c   7.927
_cell_angle_alpha   90.386
_cell_angle_beta   90.320
_cell_angle_gamma   90.605
_symmetry_Int_Tables_number   1
_cell_volume   249.478
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.505  0.519  0.249  1.0
  Ba  Ba1  1  0.495  0.481  0.751  1.0
  Eu  Eu2  1  0.996  0.023  0.251  1.0
  Eu  Eu3  1  0.004  0.977  0.749  1.0
  V  V4  1  0.500  0.000  0.000  1.0
  V  V5  1  0.000  0.500  0.500  1.0
  Bi  Bi6  1  0.000  0.500  0.000  1.0
  Bi  Bi7  1  0.500  0.000  0.500  1.0
  O  O8  1  0.240  0.191  0.966  1.0
  O  O9  1  0.248  0.700  0.530  1.0
  O  O10  1  0.760  0.809  0.034  1.0
  O  O11  1  0.752  0.300  0.470  1.0
  O  O12  1  0.302  0.751  0.969  1.0
  O  O13  1  0.189  0.237  0.532  1.0
  O  O14  1  0.698  0.249  0.031  1.0
  O  O15  1  0.811  0.763  0.468  1.0
  O  O16  1  0.430  0.995  0.224  1.0
  O  O17  1  0.054  0.486  0.276  1.0
  O  O18  1  0.570  0.005  0.776  1.0
  O  O19  1  0.946  0.514  0.724  1.0
[/CIF]
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The material structure described by BaEuVBiO6 is Krennerite-derived structured and crystallizes in the triclinic P-1 space group. Ba(1) is bonded in a 12-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms. Eu(1) is bonded in a 12-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms. There are two inequivalent V sites. In the first V site, V(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form VO6 octahedra that share corners with two equivalent Bi(2)O6 octahedra and corners with four equivalent Bi(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 19-23°. In the second V site, V(2) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form VO6 octahedra that share corners with two equivalent Bi(1)O6 octahedra and corners with four equivalent Bi(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 18-22°. There are two inequivalent Bi sites. In the first Bi site, Bi(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(6) atoms to form BiO6 octahedra that share corners with two equivalent V(2)O6 octahedra and corners with four equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 18-22°. In the second Bi site, Bi(2) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(5) atoms to form BiO6 octahedra that share corners with two equivalent V(1)O6 octahedra and corners with four equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 18-23°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 1-coordinate geometry to two equivalent Ba(1), two equivalent Eu(1), one V(1), and one Bi(1) atom. In the second O site, O(2) is bonded in a 1-coordinate geometry to two equivalent Ba(1), two equivalent Eu(1), one V(2), and one Bi(2) atom. In the third O site, O(3) is bonded in a 1-coordinate geometry to two equivalent Ba(1), two equivalent Eu(1), one V(1), and one Bi(1) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to two equivalent Ba(1), two equivalent Eu(1), one V(2), and one Bi(2) atom. In the fifth O site, O(5) is bonded in a 1-coordinate geometry to two equivalent Ba(1), two equivalent Eu(1), one V(1), and one Bi(2) atom. In the sixth O site, O(6) is bonded in a 1-coordinate geometry to two equivalent Ba(1), two equivalent Eu(1), one V(2), and one Bi(1) atom. is represented by the CIF card [CIF]
data_BaEuVBiO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.609
_cell_length_b   5.611
_cell_length_c   7.927
_cell_angle_alpha   90.386
_cell_angle_beta   90.320
_cell_angle_gamma   90.605
_symmetry_Int_Tables_number   1
_cell_volume   249.478
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.505  0.519  0.249  1.0
  Ba  Ba1  1  0.495  0.481  0.751  1.0
  Eu  Eu2  1  0.996  0.023  0.251  1.0
  Eu  Eu3  1  0.004  0.977  0.749  1.0
  V  V4  1  0.500  0.000  0.000  1.0
  V  V5  1  0.000  0.500  0.500  1.0
  Bi  Bi6  1  0.000  0.500  0.000  1.0
  Bi  Bi7  1  0.500  0.000  0.500  1.0
  O  O8  1  0.240  0.191  0.966  1.0
  O  O9  1  0.248  0.700  0.530  1.0
  O  O10  1  0.760  0.809  0.034  1.0
  O  O11  1  0.752  0.300  0.470  1.0
  O  O12  1  0.302  0.751  0.969  1.0
  O  O13  1  0.189  0.237  0.532  1.0
  O  O14  1  0.698  0.249  0.031  1.0
  O  O15  1  0.811  0.763  0.468  1.0
  O  O16  1  0.430  0.995  0.224  1.0
  O  O17  1  0.054  0.486  0.276  1.0
  O  O18  1  0.570  0.005  0.776  1.0
  O  O19  1  0.946  0.514  0.724  1.0
[/CIF]
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