The material structure described by K4Th(MoO4)4 crystallizes in the tetragonal I4_1/a space group. K(1) is bonded in a 7-coordinate geometry to one O(1), one O(4), two equivalent O(3), and three equivalent O(2) atoms. Th(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(4) atoms. Mo(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one K(1), one Th(1), and one Mo(1) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to three equivalent K(1) and one Mo(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to two equivalent K(1) and one Mo(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one K(1), one Th(1), and one Mo(1) atom. is represented by the CIF file [CIF]
data_K4Th(MoO4)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.694
_cell_length_b   10.694
_cell_length_c   10.694
_cell_angle_alpha   112.826
_cell_angle_beta   112.826
_cell_angle_gamma   102.951
_symmetry_Int_Tables_number   1
_cell_volume   932.340
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.422  0.780  0.165  1.0
  K  K1  1  0.530  0.865  0.859  1.0
  K  K2  1  0.615  0.256  0.835  1.0
  K  K3  1  0.006  0.672  0.141  1.0
  K  K4  1  0.220  0.385  0.641  1.0
  K  K5  1  0.744  0.578  0.359  1.0
  K  K6  1  0.328  0.470  0.335  1.0
  K  K7  1  0.135  0.994  0.665  1.0
  Th  Th8  1  0.000  0.000  0.000  1.0
  Th  Th9  1  0.750  0.250  0.500  1.0
  Mo  Mo10  1  0.081  0.669  0.768  1.0
  Mo  Mo11  1  0.901  0.313  0.232  1.0
  Mo  Mo12  1  0.849  0.937  0.268  1.0
  Mo  Mo13  1  0.331  0.099  0.412  1.0
  Mo  Mo14  1  0.669  0.581  0.732  1.0
  Mo  Mo15  1  0.419  0.151  0.088  1.0
  Mo  Mo16  1  0.063  0.331  0.912  1.0
  Mo  Mo17  1  0.687  0.919  0.588  1.0
  O  O18  1  0.213  0.039  0.967  1.0
  O  O19  1  0.864  0.416  0.137  1.0
  O  O20  1  0.026  0.713  0.618  1.0
  O  O21  1  0.718  0.485  0.587  1.0
  O  O22  1  0.754  0.787  0.825  1.0
  O  O23  1  0.789  0.322  0.325  1.0
  O  O24  1  0.592  0.974  0.687  1.0
  O  O25  1  0.279  0.727  0.863  1.0
  O  O26  1  0.273  0.136  0.552  1.0
  O  O27  1  0.471  0.523  0.637  1.0
  O  O28  1  0.678  0.004  0.467  1.0
  O  O29  1  0.166  0.529  0.052  1.0
  O  O30  1  0.852  0.119  0.087  1.0
  O  O31  1  0.537  0.211  0.533  1.0
  O  O32  1  0.898  0.131  0.413  1.0
  O  O33  1  0.869  0.282  0.767  1.0
  O  O34  1  0.724  0.537  0.882  1.0
  O  O35  1  0.655  0.842  0.118  1.0
  O  O36  1  0.881  0.968  0.733  1.0
  O  O37  1  0.996  0.463  0.675  1.0
  O  O38  1  0.095  0.408  0.382  1.0
  O  O39  1  0.072  0.246  0.033  1.0
  O  O40  1  0.515  0.102  0.233  1.0
  O  O41  1  0.886  0.834  0.363  1.0
  O  O42  1  0.463  0.345  0.187  1.0
  O  O43  1  0.477  0.114  0.948  1.0
  O  O44  1  0.961  0.928  0.175  1.0
  O  O45  1  0.158  0.276  0.813  1.0
  O  O46  1  0.032  0.765  0.913  1.0
  O  O47  1  0.287  0.905  0.313  1.0
  O  O48  1  0.235  0.148  0.267  1.0
  O  O49  1  0.584  0.721  0.448  1.0
[/CIF]
.
The material structure described by K4Th(MoO4)4 crystallizes in the tetragonal I4_1/a space group. K(1) is bonded in a 7-coordinate geometry to one O(1), one O(4), two equivalent O(3), and three equivalent O(2) atoms. Th(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(4) atoms. Mo(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one K(1), one Th(1), and one Mo(1) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to three equivalent K(1) and one Mo(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to two equivalent K(1) and one Mo(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one K(1), one Th(1), and one Mo(1) atom. is represented by the CIF file [CIF]
data_K4Th(MoO4)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.694
_cell_length_b   10.694
_cell_length_c   10.694
_cell_angle_alpha   112.826
_cell_angle_beta   112.826
_cell_angle_gamma   102.951
_symmetry_Int_Tables_number   1
_cell_volume   932.340
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.422  0.780  0.165  1.0
  K  K1  1  0.530  0.865  0.859  1.0
  K  K2  1  0.615  0.256  0.835  1.0
  K  K3  1  0.006  0.672  0.141  1.0
  K  K4  1  0.220  0.385  0.641  1.0
  K  K5  1  0.744  0.578  0.359  1.0
  K  K6  1  0.328  0.470  0.335  1.0
  K  K7  1  0.135  0.994  0.665  1.0
  Th  Th8  1  0.000  0.000  0.000  1.0
  Th  Th9  1  0.750  0.250  0.500  1.0
  Mo  Mo10  1  0.081  0.669  0.768  1.0
  Mo  Mo11  1  0.901  0.313  0.232  1.0
  Mo  Mo12  1  0.849  0.937  0.268  1.0
  Mo  Mo13  1  0.331  0.099  0.412  1.0
  Mo  Mo14  1  0.669  0.581  0.732  1.0
  Mo  Mo15  1  0.419  0.151  0.088  1.0
  Mo  Mo16  1  0.063  0.331  0.912  1.0
  Mo  Mo17  1  0.687  0.919  0.588  1.0
  O  O18  1  0.213  0.039  0.967  1.0
  O  O19  1  0.864  0.416  0.137  1.0
  O  O20  1  0.026  0.713  0.618  1.0
  O  O21  1  0.718  0.485  0.587  1.0
  O  O22  1  0.754  0.787  0.825  1.0
  O  O23  1  0.789  0.322  0.325  1.0
  O  O24  1  0.592  0.974  0.687  1.0
  O  O25  1  0.279  0.727  0.863  1.0
  O  O26  1  0.273  0.136  0.552  1.0
  O  O27  1  0.471  0.523  0.637  1.0
  O  O28  1  0.678  0.004  0.467  1.0
  O  O29  1  0.166  0.529  0.052  1.0
  O  O30  1  0.852  0.119  0.087  1.0
  O  O31  1  0.537  0.211  0.533  1.0
  O  O32  1  0.898  0.131  0.413  1.0
  O  O33  1  0.869  0.282  0.767  1.0
  O  O34  1  0.724  0.537  0.882  1.0
  O  O35  1  0.655  0.842  0.118  1.0
  O  O36  1  0.881  0.968  0.733  1.0
  O  O37  1  0.996  0.463  0.675  1.0
  O  O38  1  0.095  0.408  0.382  1.0
  O  O39  1  0.072  0.246  0.033  1.0
  O  O40  1  0.515  0.102  0.233  1.0
  O  O41  1  0.886  0.834  0.363  1.0
  O  O42  1  0.463  0.345  0.187  1.0
  O  O43  1  0.477  0.114  0.948  1.0
  O  O44  1  0.961  0.928  0.175  1.0
  O  O45  1  0.158  0.276  0.813  1.0
  O  O46  1  0.032  0.765  0.913  1.0
  O  O47  1  0.287  0.905  0.313  1.0
  O  O48  1  0.235  0.148  0.267  1.0
  O  O49  1  0.584  0.721  0.448  1.0
[/CIF]
.