The compound described by ReC4H12O5F is Silicon tetrafluoride-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two ReC4H12O5F clusters. Re(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one F(1) atom. There are four inequivalent C sites. In the first C site, C(1) is bonded to one H(10), one H(11), one H(9), and one O(2) atom to form corner-sharing CH3O tetrahedra. In the second C site, C(2) is bonded to one H(12), one H(4), one H(8), and one O(2) atom to form corner-sharing CH3O tetrahedra. In the third C site, C(3) is bonded to one H(5), one H(6), one H(7), and one O(1) atom to form corner-sharing CH3O tetrahedra. In the fourth C site, C(4) is bonded to one H(1), one H(2), one H(3), and one O(1) atom to form corner-sharing CH3O tetrahedra. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(3) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(2) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(1) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(1) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(1) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(2) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Re(1), one C(3), and one C(4) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Re(1), one C(1), and one C(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Re(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Re(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Re(1) atom. F(1) is bonded in a single-bond geometry to one Re(1) atom. is represented by the CIF file [CIF]
data_ReH12C4O5F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.378
_cell_length_b   6.888
_cell_length_c   12.782
_cell_angle_alpha   78.317
_cell_angle_beta   81.810
_cell_angle_gamma   63.516
_symmetry_Int_Tables_number   1
_cell_volume   491.303
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.661  0.592  0.733  1.0
  Re  Re1  1  0.339  0.408  0.267  1.0
  H  H2  1  0.039  0.661  0.865  1.0
  H  H3  1  0.961  0.339  0.135  1.0
  H  H4  1  0.181  0.835  0.866  1.0
  H  H5  1  0.819  0.165  0.134  1.0
  H  H6  1  0.156  0.657  0.986  1.0
  H  H7  1  0.844  0.343  0.014  1.0
  H  H8  1  0.843  0.989  0.654  1.0
  H  H9  1  0.157  0.011  0.346  1.0
  H  H10  1  0.409  0.267  0.998  1.0
  H  H11  1  0.591  0.733  0.002  1.0
  H  H12  1  0.604  0.175  0.883  1.0
  H  H13  1  0.396  0.825  0.117  1.0
  H  H14  1  0.294  0.262  0.878  1.0
  H  H15  1  0.706  0.738  0.122  1.0
  H  H16  1  0.988  0.163  0.643  1.0
  H  H17  1  0.012  0.837  0.357  1.0
  H  H18  1  0.576  0.843  0.346  1.0
  H  H19  1  0.424  0.157  0.654  1.0
  H  H20  1  0.733  0.556  0.334  1.0
  H  H21  1  0.267  0.444  0.666  1.0
  H  H22  1  0.592  0.637  0.460  1.0
  H  H23  1  0.408  0.363  0.540  1.0
  H  H24  1  0.840  0.172  0.531  1.0
  H  H25  1  0.160  0.828  0.469  1.0
  C  C26  1  0.418  0.321  0.627  1.0
  C  C27  1  0.162  0.850  0.381  1.0
  C  C28  1  0.429  0.289  0.910  1.0
  C  C29  1  0.582  0.679  0.373  1.0
  C  C30  1  0.819  0.325  0.102  1.0
  C  C31  1  0.181  0.675  0.898  1.0
  C  C32  1  0.571  0.711  0.090  1.0
  C  C33  1  0.838  0.150  0.619  1.0
  O  O34  1  0.407  0.508  0.869  1.0
  O  O35  1  0.593  0.492  0.131  1.0
  O  O36  1  0.627  0.321  0.658  1.0
  O  O37  1  0.177  0.362  0.383  1.0
  O  O38  1  0.866  0.357  0.805  1.0
  O  O39  1  0.134  0.643  0.195  1.0
  O  O40  1  0.823  0.638  0.617  1.0
  O  O41  1  0.379  0.200  0.199  1.0
  O  O42  1  0.621  0.800  0.801  1.0
  O  O43  1  0.373  0.679  0.342  1.0
  F  F44  1  0.354  0.736  0.673  1.0
  F  F45  1  0.646  0.264  0.327  1.0
[/CIF]
.
The compound described by ReC4H12O5F is Silicon tetrafluoride-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two ReC4H12O5F clusters. Re(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one F(1) atom. There are four inequivalent C sites. In the first C site, C(1) is bonded to one H(10), one H(11), one H(9), and one O(2) atom to form corner-sharing CH3O tetrahedra. In the second C site, C(2) is bonded to one H(12), one H(4), one H(8), and one O(2) atom to form corner-sharing CH3O tetrahedra. In the third C site, C(3) is bonded to one H(5), one H(6), one H(7), and one O(1) atom to form corner-sharing CH3O tetrahedra. In the fourth C site, C(4) is bonded to one H(1), one H(2), one H(3), and one O(1) atom to form corner-sharing CH3O tetrahedra. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(3) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(2) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(1) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(1) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(1) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(2) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Re(1), one C(3), and one C(4) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Re(1), one C(1), and one C(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Re(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Re(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Re(1) atom. F(1) is bonded in a single-bond geometry to one Re(1) atom. is represented by the CIF file [CIF]
data_ReH12C4O5F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.378
_cell_length_b   6.888
_cell_length_c   12.782
_cell_angle_alpha   78.317
_cell_angle_beta   81.810
_cell_angle_gamma   63.516
_symmetry_Int_Tables_number   1
_cell_volume   491.303
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.661  0.592  0.733  1.0
  Re  Re1  1  0.339  0.408  0.267  1.0
  H  H2  1  0.039  0.661  0.865  1.0
  H  H3  1  0.961  0.339  0.135  1.0
  H  H4  1  0.181  0.835  0.866  1.0
  H  H5  1  0.819  0.165  0.134  1.0
  H  H6  1  0.156  0.657  0.986  1.0
  H  H7  1  0.844  0.343  0.014  1.0
  H  H8  1  0.843  0.989  0.654  1.0
  H  H9  1  0.157  0.011  0.346  1.0
  H  H10  1  0.409  0.267  0.998  1.0
  H  H11  1  0.591  0.733  0.002  1.0
  H  H12  1  0.604  0.175  0.883  1.0
  H  H13  1  0.396  0.825  0.117  1.0
  H  H14  1  0.294  0.262  0.878  1.0
  H  H15  1  0.706  0.738  0.122  1.0
  H  H16  1  0.988  0.163  0.643  1.0
  H  H17  1  0.012  0.837  0.357  1.0
  H  H18  1  0.576  0.843  0.346  1.0
  H  H19  1  0.424  0.157  0.654  1.0
  H  H20  1  0.733  0.556  0.334  1.0
  H  H21  1  0.267  0.444  0.666  1.0
  H  H22  1  0.592  0.637  0.460  1.0
  H  H23  1  0.408  0.363  0.540  1.0
  H  H24  1  0.840  0.172  0.531  1.0
  H  H25  1  0.160  0.828  0.469  1.0
  C  C26  1  0.418  0.321  0.627  1.0
  C  C27  1  0.162  0.850  0.381  1.0
  C  C28  1  0.429  0.289  0.910  1.0
  C  C29  1  0.582  0.679  0.373  1.0
  C  C30  1  0.819  0.325  0.102  1.0
  C  C31  1  0.181  0.675  0.898  1.0
  C  C32  1  0.571  0.711  0.090  1.0
  C  C33  1  0.838  0.150  0.619  1.0
  O  O34  1  0.407  0.508  0.869  1.0
  O  O35  1  0.593  0.492  0.131  1.0
  O  O36  1  0.627  0.321  0.658  1.0
  O  O37  1  0.177  0.362  0.383  1.0
  O  O38  1  0.866  0.357  0.805  1.0
  O  O39  1  0.134  0.643  0.195  1.0
  O  O40  1  0.823  0.638  0.617  1.0
  O  O41  1  0.379  0.200  0.199  1.0
  O  O42  1  0.621  0.800  0.801  1.0
  O  O43  1  0.373  0.679  0.342  1.0
  F  F44  1  0.354  0.736  0.673  1.0
  F  F45  1  0.646  0.264  0.327  1.0
[/CIF]
.