The crystal structure described by MnP2H4O5 crystallizes in the monoclinic P2_1/c space group. Mn(1) is bonded to one O(2), one O(3), one O(4), one O(5), and two equivalent O(1) atoms to form MnO6 octahedra that share corners with two equivalent P(2)H2O2 tetrahedra, corners with three equivalent P(1)H2O2 tetrahedra, and  an edgeedge with one Mn(1)O6 octahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to one H(1), one H(2), one O(1), and one O(2) atom to form distorted PH2O2 tetrahedra that share corners with three equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-53°. In the second P site, P(2) is bonded to one H(3), one H(4), one O(3), and one O(4) atom to form distorted PH2O2 tetrahedra that share corners with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-56°. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one P(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one P(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one P(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one P(2) atom. There are five inequivalent O sites. In the first O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one P(1) atom. In the second O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Mn(1) and one P(2) atom. In the third O site, O(4) is bonded in a bent 120 degrees geometry to one Mn(1) and one P(2) atom. In the fourth O site, O(5) is bonded in a single-bond geometry to one Mn(1) atom. In the fifth O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent Mn(1) and one P(1) atom. is represented by the CIF card [CIF]
data_MnP2H4O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.377
_cell_length_b   8.082
_cell_length_c   10.077
_cell_angle_alpha   75.541
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   581.737
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.532  0.794  0.594  1.0
  Mn  Mn1  1  0.032  0.206  0.906  1.0
  Mn  Mn2  1  0.468  0.206  0.406  1.0
  Mn  Mn3  1  0.968  0.794  0.094  1.0
  P  P4  1  0.673  0.963  0.841  1.0
  P  P5  1  0.173  0.037  0.659  1.0
  P  P6  1  0.327  0.037  0.159  1.0
  P  P7  1  0.827  0.963  0.341  1.0
  P  P8  1  0.889  0.537  0.694  1.0
  P  P9  1  0.389  0.463  0.806  1.0
  P  P10  1  0.111  0.463  0.306  1.0
  P  P11  1  0.611  0.537  0.194  1.0
  H  H12  1  0.547  0.855  0.928  1.0
  H  H13  1  0.047  0.145  0.572  1.0
  H  H14  1  0.453  0.145  0.072  1.0
  H  H15  1  0.953  0.855  0.428  1.0
  H  H16  1  0.596  0.128  0.809  1.0
  H  H17  1  0.096  0.872  0.691  1.0
  H  H18  1  0.404  0.872  0.191  1.0
  H  H19  1  0.904  0.128  0.309  1.0
  H  H20  1  0.051  0.608  0.627  1.0
  H  H21  1  0.551  0.392  0.873  1.0
  H  H22  1  0.949  0.392  0.373  1.0
  H  H23  1  0.449  0.608  0.127  1.0
  H  H24  1  0.884  0.597  0.815  1.0
  H  H25  1  0.384  0.403  0.685  1.0
  H  H26  1  0.116  0.403  0.185  1.0
  H  H27  1  0.616  0.597  0.315  1.0
  O  O28  1  0.849  0.972  0.922  1.0
  O  O29  1  0.349  0.028  0.578  1.0
  O  O30  1  0.151  0.028  0.078  1.0
  O  O31  1  0.651  0.972  0.422  1.0
  O  O32  1  0.698  0.902  0.710  1.0
  O  O33  1  0.198  0.098  0.790  1.0
  O  O34  1  0.302  0.098  0.290  1.0
  O  O35  1  0.802  0.902  0.210  1.0
  O  O36  1  0.729  0.607  0.600  1.0
  O  O37  1  0.229  0.393  0.900  1.0
  O  O38  1  0.271  0.393  0.400  1.0
  O  O39  1  0.771  0.607  0.100  1.0
  O  O40  1  0.907  0.341  0.733  1.0
  O  O41  1  0.407  0.659  0.767  1.0
  O  O42  1  0.093  0.659  0.267  1.0
  O  O43  1  0.593  0.341  0.233  1.0
  O  O44  1  0.382  0.719  0.488  1.0
  O  O45  1  0.882  0.281  0.012  1.0
  O  O46  1  0.618  0.281  0.512  1.0
  O  O47  1  0.118  0.719  0.988  1.0
[/CIF]
.
The crystal structure described by MnP2H4O5 crystallizes in the monoclinic P2_1/c space group. Mn(1) is bonded to one O(2), one O(3), one O(4), one O(5), and two equivalent O(1) atoms to form MnO6 octahedra that share corners with two equivalent P(2)H2O2 tetrahedra, corners with three equivalent P(1)H2O2 tetrahedra, and  an edgeedge with one Mn(1)O6 octahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to one H(1), one H(2), one O(1), and one O(2) atom to form distorted PH2O2 tetrahedra that share corners with three equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-53°. In the second P site, P(2) is bonded to one H(3), one H(4), one O(3), and one O(4) atom to form distorted PH2O2 tetrahedra that share corners with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-56°. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one P(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one P(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one P(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one P(2) atom. There are five inequivalent O sites. In the first O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one P(1) atom. In the second O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Mn(1) and one P(2) atom. In the third O site, O(4) is bonded in a bent 120 degrees geometry to one Mn(1) and one P(2) atom. In the fourth O site, O(5) is bonded in a single-bond geometry to one Mn(1) atom. In the fifth O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent Mn(1) and one P(1) atom. is represented by the CIF card [CIF]
data_MnP2H4O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.377
_cell_length_b   8.082
_cell_length_c   10.077
_cell_angle_alpha   75.541
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   581.737
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.532  0.794  0.594  1.0
  Mn  Mn1  1  0.032  0.206  0.906  1.0
  Mn  Mn2  1  0.468  0.206  0.406  1.0
  Mn  Mn3  1  0.968  0.794  0.094  1.0
  P  P4  1  0.673  0.963  0.841  1.0
  P  P5  1  0.173  0.037  0.659  1.0
  P  P6  1  0.327  0.037  0.159  1.0
  P  P7  1  0.827  0.963  0.341  1.0
  P  P8  1  0.889  0.537  0.694  1.0
  P  P9  1  0.389  0.463  0.806  1.0
  P  P10  1  0.111  0.463  0.306  1.0
  P  P11  1  0.611  0.537  0.194  1.0
  H  H12  1  0.547  0.855  0.928  1.0
  H  H13  1  0.047  0.145  0.572  1.0
  H  H14  1  0.453  0.145  0.072  1.0
  H  H15  1  0.953  0.855  0.428  1.0
  H  H16  1  0.596  0.128  0.809  1.0
  H  H17  1  0.096  0.872  0.691  1.0
  H  H18  1  0.404  0.872  0.191  1.0
  H  H19  1  0.904  0.128  0.309  1.0
  H  H20  1  0.051  0.608  0.627  1.0
  H  H21  1  0.551  0.392  0.873  1.0
  H  H22  1  0.949  0.392  0.373  1.0
  H  H23  1  0.449  0.608  0.127  1.0
  H  H24  1  0.884  0.597  0.815  1.0
  H  H25  1  0.384  0.403  0.685  1.0
  H  H26  1  0.116  0.403  0.185  1.0
  H  H27  1  0.616  0.597  0.315  1.0
  O  O28  1  0.849  0.972  0.922  1.0
  O  O29  1  0.349  0.028  0.578  1.0
  O  O30  1  0.151  0.028  0.078  1.0
  O  O31  1  0.651  0.972  0.422  1.0
  O  O32  1  0.698  0.902  0.710  1.0
  O  O33  1  0.198  0.098  0.790  1.0
  O  O34  1  0.302  0.098  0.290  1.0
  O  O35  1  0.802  0.902  0.210  1.0
  O  O36  1  0.729  0.607  0.600  1.0
  O  O37  1  0.229  0.393  0.900  1.0
  O  O38  1  0.271  0.393  0.400  1.0
  O  O39  1  0.771  0.607  0.100  1.0
  O  O40  1  0.907  0.341  0.733  1.0
  O  O41  1  0.407  0.659  0.767  1.0
  O  O42  1  0.093  0.659  0.267  1.0
  O  O43  1  0.593  0.341  0.233  1.0
  O  O44  1  0.382  0.719  0.488  1.0
  O  O45  1  0.882  0.281  0.012  1.0
  O  O46  1  0.618  0.281  0.512  1.0
  O  O47  1  0.118  0.719  0.988  1.0
[/CIF]
.