The structure described by LiVOF3 crystallizes in the orthorhombic Pca2_1 space group. Li(1) is bonded to one O(1), one F(2), one F(3), and two equivalent F(1) atoms to form distorted corner-sharing LiOF4 square pyramids. V(1) is bonded in a 5-coordinate geometry to one O(1), one F(1), one F(2), and two equivalent F(3) atoms. O(1) is bonded in a distorted bent 150 degrees geometry to one Li(1) and one V(1) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to two equivalent Li(1) and one V(1) atom. In the second F site, F(2) is bonded in a bent 120 degrees geometry to one Li(1) and one V(1) atom. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one Li(1) and two equivalent V(1) atoms. is represented by the CIF file [CIF]
data_LiVOF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.176
_cell_length_b   7.137
_cell_length_c   8.165
_cell_angle_alpha   90.026
_cell_angle_beta   89.971
_cell_angle_gamma   89.997
_symmetry_Int_Tables_number   1
_cell_volume   301.630
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.453  0.174  0.138  1.0
  Li  Li1  1  0.453  0.326  0.638  1.0
  Li  Li2  1  0.547  0.674  0.138  1.0
  Li  Li3  1  0.547  0.826  0.638  1.0
  V  V4  1  0.043  0.494  0.957  1.0
  V  V5  1  0.043  0.006  0.457  1.0
  V  V6  1  0.957  0.994  0.958  1.0
  V  V7  1  0.957  0.506  0.458  1.0
  O  O8  1  0.154  0.042  0.271  1.0
  O  O9  1  0.154  0.458  0.771  1.0
  O  O10  1  0.845  0.542  0.271  1.0
  O  O11  1  0.845  0.958  0.771  1.0
  F  F12  1  0.317  0.065  0.607  1.0
  F  F13  1  0.317  0.435  0.107  1.0
  F  F14  1  0.683  0.565  0.608  1.0
  F  F15  1  0.683  0.935  0.108  1.0
  F  F16  1  0.289  0.100  0.940  1.0
  F  F17  1  0.289  0.400  0.439  1.0
  F  F18  1  0.711  0.600  0.940  1.0
  F  F19  1  0.711  0.900  0.440  1.0
  F  F20  1  0.849  0.244  0.507  1.0
  F  F21  1  0.849  0.256  0.007  1.0
  F  F22  1  0.151  0.744  0.507  1.0
  F  F23  1  0.151  0.756  0.007  1.0
[/CIF]
.
The structure described by LiVOF3 crystallizes in the orthorhombic Pca2_1 space group. Li(1) is bonded to one O(1), one F(2), one F(3), and two equivalent F(1) atoms to form distorted corner-sharing LiOF4 square pyramids. V(1) is bonded in a 5-coordinate geometry to one O(1), one F(1), one F(2), and two equivalent F(3) atoms. O(1) is bonded in a distorted bent 150 degrees geometry to one Li(1) and one V(1) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to two equivalent Li(1) and one V(1) atom. In the second F site, F(2) is bonded in a bent 120 degrees geometry to one Li(1) and one V(1) atom. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one Li(1) and two equivalent V(1) atoms. is represented by the CIF file [CIF]
data_LiVOF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.176
_cell_length_b   7.137
_cell_length_c   8.165
_cell_angle_alpha   90.026
_cell_angle_beta   89.971
_cell_angle_gamma   89.997
_symmetry_Int_Tables_number   1
_cell_volume   301.630
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.453  0.174  0.138  1.0
  Li  Li1  1  0.453  0.326  0.638  1.0
  Li  Li2  1  0.547  0.674  0.138  1.0
  Li  Li3  1  0.547  0.826  0.638  1.0
  V  V4  1  0.043  0.494  0.957  1.0
  V  V5  1  0.043  0.006  0.457  1.0
  V  V6  1  0.957  0.994  0.958  1.0
  V  V7  1  0.957  0.506  0.458  1.0
  O  O8  1  0.154  0.042  0.271  1.0
  O  O9  1  0.154  0.458  0.771  1.0
  O  O10  1  0.845  0.542  0.271  1.0
  O  O11  1  0.845  0.958  0.771  1.0
  F  F12  1  0.317  0.065  0.607  1.0
  F  F13  1  0.317  0.435  0.107  1.0
  F  F14  1  0.683  0.565  0.608  1.0
  F  F15  1  0.683  0.935  0.108  1.0
  F  F16  1  0.289  0.100  0.940  1.0
  F  F17  1  0.289  0.400  0.439  1.0
  F  F18  1  0.711  0.600  0.940  1.0
  F  F19  1  0.711  0.900  0.440  1.0
  F  F20  1  0.849  0.244  0.507  1.0
  F  F21  1  0.849  0.256  0.007  1.0
  F  F22  1  0.151  0.744  0.507  1.0
  F  F23  1  0.151  0.756  0.007  1.0
[/CIF]
.