The structure described by K2IrH2OCl5 crystallizes in the orthorhombic Pnma space group. K(1) is bonded in a 8-coordinate geometry to two equivalent Cl(1), two equivalent Cl(2), two equivalent Cl(3), and two equivalent Cl(4) atoms. Ir(1) is bonded in an octahedral geometry to one O(1), one Cl(1), one Cl(3), one Cl(4), and two equivalent Cl(2) atoms. H(1) is bonded in a single-bond geometry to one O(1) atom. O(1) is bonded in a distorted water-like geometry to one Ir(1) and two equivalent H(1) atoms. There are four inequivalent Cl sites. In the first Cl site, Cl(4) is bonded to four equivalent K(1) and one Ir(1) atom to form a mixture of edge, corner, and face-sharing ClK4Ir square pyramids. In the second Cl site, Cl(1) is bonded in a 5-coordinate geometry to four equivalent K(1) and one Ir(1) atom. In the third Cl site, Cl(2) is bonded in a 1-coordinate geometry to two equivalent K(1) and one Ir(1) atom. In the fourth Cl site, Cl(3) is bonded to four equivalent K(1) and one Ir(1) atom to form a mixture of distorted edge, corner, and face-sharing ClK4Ir square pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_K2H2IrCl5O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.615
_cell_length_b   9.244
_cell_length_c   13.887
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   977.591
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.377  0.497  0.654  1.0
  K  K1  1  0.877  0.997  0.846  1.0
  K  K2  1  0.377  0.003  0.654  1.0
  K  K3  1  0.123  0.497  0.154  1.0
  K  K4  1  0.123  0.003  0.154  1.0
  K  K5  1  0.623  0.997  0.346  1.0
  K  K6  1  0.623  0.503  0.346  1.0
  K  K7  1  0.877  0.503  0.846  1.0
  H  H8  1  0.472  0.663  0.964  1.0
  H  H9  1  0.972  0.337  0.536  1.0
  H  H10  1  0.528  0.163  0.036  1.0
  H  H11  1  0.028  0.837  0.464  1.0
  H  H12  1  0.028  0.663  0.464  1.0
  H  H13  1  0.472  0.837  0.964  1.0
  H  H14  1  0.528  0.337  0.036  1.0
  H  H15  1  0.972  0.163  0.536  1.0
  Ir  Ir16  1  0.307  0.250  0.897  1.0
  Ir  Ir17  1  0.807  0.750  0.603  1.0
  Ir  Ir18  1  0.693  0.750  0.103  1.0
  Ir  Ir19  1  0.193  0.250  0.397  1.0
  Cl  Cl20  1  0.430  0.750  0.196  1.0
  Cl  Cl21  1  0.070  0.750  0.696  1.0
  Cl  Cl22  1  0.570  0.250  0.804  1.0
  Cl  Cl23  1  0.197  0.506  0.398  1.0
  Cl  Cl24  1  0.197  0.994  0.398  1.0
  Cl  Cl25  1  0.697  0.006  0.102  1.0
  Cl  Cl26  1  0.803  0.494  0.602  1.0
  Cl  Cl27  1  0.047  0.250  0.991  1.0
  Cl  Cl28  1  0.803  0.006  0.602  1.0
  Cl  Cl29  1  0.303  0.994  0.898  1.0
  Cl  Cl30  1  0.303  0.506  0.898  1.0
  Cl  Cl31  1  0.697  0.494  0.102  1.0
  Cl  Cl32  1  0.364  0.250  0.257  1.0
  Cl  Cl33  1  0.864  0.750  0.243  1.0
  Cl  Cl34  1  0.636  0.750  0.743  1.0
  Cl  Cl35  1  0.136  0.250  0.757  1.0
  Cl  Cl36  1  0.453  0.250  0.491  1.0
  Cl  Cl37  1  0.953  0.750  0.009  1.0
  Cl  Cl38  1  0.547  0.750  0.509  1.0
  Cl  Cl39  1  0.930  0.250  0.304  1.0
  O  O40  1  0.453  0.250  0.026  1.0
  O  O41  1  0.547  0.750  0.974  1.0
  O  O42  1  0.047  0.250  0.526  1.0
  O  O43  1  0.953  0.750  0.474  1.0
[/CIF]
.
The structure described by K2IrH2OCl5 crystallizes in the orthorhombic Pnma space group. K(1) is bonded in a 8-coordinate geometry to two equivalent Cl(1), two equivalent Cl(2), two equivalent Cl(3), and two equivalent Cl(4) atoms. Ir(1) is bonded in an octahedral geometry to one O(1), one Cl(1), one Cl(3), one Cl(4), and two equivalent Cl(2) atoms. H(1) is bonded in a single-bond geometry to one O(1) atom. O(1) is bonded in a distorted water-like geometry to one Ir(1) and two equivalent H(1) atoms. There are four inequivalent Cl sites. In the first Cl site, Cl(4) is bonded to four equivalent K(1) and one Ir(1) atom to form a mixture of edge, corner, and face-sharing ClK4Ir square pyramids. In the second Cl site, Cl(1) is bonded in a 5-coordinate geometry to four equivalent K(1) and one Ir(1) atom. In the third Cl site, Cl(2) is bonded in a 1-coordinate geometry to two equivalent K(1) and one Ir(1) atom. In the fourth Cl site, Cl(3) is bonded to four equivalent K(1) and one Ir(1) atom to form a mixture of distorted edge, corner, and face-sharing ClK4Ir square pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_K2H2IrCl5O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.615
_cell_length_b   9.244
_cell_length_c   13.887
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   977.591
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.377  0.497  0.654  1.0
  K  K1  1  0.877  0.997  0.846  1.0
  K  K2  1  0.377  0.003  0.654  1.0
  K  K3  1  0.123  0.497  0.154  1.0
  K  K4  1  0.123  0.003  0.154  1.0
  K  K5  1  0.623  0.997  0.346  1.0
  K  K6  1  0.623  0.503  0.346  1.0
  K  K7  1  0.877  0.503  0.846  1.0
  H  H8  1  0.472  0.663  0.964  1.0
  H  H9  1  0.972  0.337  0.536  1.0
  H  H10  1  0.528  0.163  0.036  1.0
  H  H11  1  0.028  0.837  0.464  1.0
  H  H12  1  0.028  0.663  0.464  1.0
  H  H13  1  0.472  0.837  0.964  1.0
  H  H14  1  0.528  0.337  0.036  1.0
  H  H15  1  0.972  0.163  0.536  1.0
  Ir  Ir16  1  0.307  0.250  0.897  1.0
  Ir  Ir17  1  0.807  0.750  0.603  1.0
  Ir  Ir18  1  0.693  0.750  0.103  1.0
  Ir  Ir19  1  0.193  0.250  0.397  1.0
  Cl  Cl20  1  0.430  0.750  0.196  1.0
  Cl  Cl21  1  0.070  0.750  0.696  1.0
  Cl  Cl22  1  0.570  0.250  0.804  1.0
  Cl  Cl23  1  0.197  0.506  0.398  1.0
  Cl  Cl24  1  0.197  0.994  0.398  1.0
  Cl  Cl25  1  0.697  0.006  0.102  1.0
  Cl  Cl26  1  0.803  0.494  0.602  1.0
  Cl  Cl27  1  0.047  0.250  0.991  1.0
  Cl  Cl28  1  0.803  0.006  0.602  1.0
  Cl  Cl29  1  0.303  0.994  0.898  1.0
  Cl  Cl30  1  0.303  0.506  0.898  1.0
  Cl  Cl31  1  0.697  0.494  0.102  1.0
  Cl  Cl32  1  0.364  0.250  0.257  1.0
  Cl  Cl33  1  0.864  0.750  0.243  1.0
  Cl  Cl34  1  0.636  0.750  0.743  1.0
  Cl  Cl35  1  0.136  0.250  0.757  1.0
  Cl  Cl36  1  0.453  0.250  0.491  1.0
  Cl  Cl37  1  0.953  0.750  0.009  1.0
  Cl  Cl38  1  0.547  0.750  0.509  1.0
  Cl  Cl39  1  0.930  0.250  0.304  1.0
  O  O40  1  0.453  0.250  0.026  1.0
  O  O41  1  0.547  0.750  0.974  1.0
  O  O42  1  0.047  0.250  0.526  1.0
  O  O43  1  0.953  0.750  0.474  1.0
[/CIF]
.