The crystal structure described by NaSbO6 crystallizes in the tetragonal P4_2/nnm space group. Na(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form NaO6 octahedra that share corners with six equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-66°. Sb(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form SbO6 octahedra that share corners with six equivalent Na(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-66°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Na(1), one Sb(1), and one O(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Na(1) and one Sb(1) atom. is represented by the CIF card [CIF]
data_NaSbO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.560
_cell_length_b   8.560
_cell_length_c   6.773
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   496.236
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.250  0.750  0.250  1.0
  Na  Na1  1  0.750  0.250  0.250  1.0
  Na  Na2  1  0.250  0.250  0.750  1.0
  Na  Na3  1  0.750  0.750  0.750  1.0
  Sb  Sb4  1  0.250  0.750  0.750  1.0
  Sb  Sb5  1  0.750  0.250  0.750  1.0
  Sb  Sb6  1  0.250  0.250  0.250  1.0
  Sb  Sb7  1  0.750  0.750  0.250  1.0
  O  O8  1  0.240  0.501  0.902  1.0
  O  O9  1  0.760  0.499  0.902  1.0
  O  O10  1  0.740  0.001  0.598  1.0
  O  O11  1  0.260  0.999  0.598  1.0
  O  O12  1  0.499  0.240  0.098  1.0
  O  O13  1  0.501  0.760  0.098  1.0
  O  O14  1  0.999  0.740  0.402  1.0
  O  O15  1  0.001  0.260  0.402  1.0
  O  O16  1  0.499  0.760  0.902  1.0
  O  O17  1  0.501  0.240  0.902  1.0
  O  O18  1  0.999  0.260  0.598  1.0
  O  O19  1  0.001  0.740  0.598  1.0
  O  O20  1  0.240  0.499  0.098  1.0
  O  O21  1  0.760  0.501  0.098  1.0
  O  O22  1  0.740  0.999  0.402  1.0
  O  O23  1  0.260  0.001  0.402  1.0
  O  O24  1  0.339  0.661  0.536  1.0
  O  O25  1  0.661  0.339  0.536  1.0
  O  O26  1  0.839  0.161  0.964  1.0
  O  O27  1  0.161  0.839  0.964  1.0
  O  O28  1  0.339  0.339  0.464  1.0
  O  O29  1  0.661  0.661  0.464  1.0
  O  O30  1  0.839  0.839  0.036  1.0
  O  O31  1  0.161  0.161  0.036  1.0
[/CIF]
.
The crystal structure described by NaSbO6 crystallizes in the tetragonal P4_2/nnm space group. Na(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form NaO6 octahedra that share corners with six equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-66°. Sb(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form SbO6 octahedra that share corners with six equivalent Na(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-66°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Na(1), one Sb(1), and one O(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Na(1) and one Sb(1) atom. is represented by the CIF card [CIF]
data_NaSbO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.560
_cell_length_b   8.560
_cell_length_c   6.773
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   496.236
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.250  0.750  0.250  1.0
  Na  Na1  1  0.750  0.250  0.250  1.0
  Na  Na2  1  0.250  0.250  0.750  1.0
  Na  Na3  1  0.750  0.750  0.750  1.0
  Sb  Sb4  1  0.250  0.750  0.750  1.0
  Sb  Sb5  1  0.750  0.250  0.750  1.0
  Sb  Sb6  1  0.250  0.250  0.250  1.0
  Sb  Sb7  1  0.750  0.750  0.250  1.0
  O  O8  1  0.240  0.501  0.902  1.0
  O  O9  1  0.760  0.499  0.902  1.0
  O  O10  1  0.740  0.001  0.598  1.0
  O  O11  1  0.260  0.999  0.598  1.0
  O  O12  1  0.499  0.240  0.098  1.0
  O  O13  1  0.501  0.760  0.098  1.0
  O  O14  1  0.999  0.740  0.402  1.0
  O  O15  1  0.001  0.260  0.402  1.0
  O  O16  1  0.499  0.760  0.902  1.0
  O  O17  1  0.501  0.240  0.902  1.0
  O  O18  1  0.999  0.260  0.598  1.0
  O  O19  1  0.001  0.740  0.598  1.0
  O  O20  1  0.240  0.499  0.098  1.0
  O  O21  1  0.760  0.501  0.098  1.0
  O  O22  1  0.740  0.999  0.402  1.0
  O  O23  1  0.260  0.001  0.402  1.0
  O  O24  1  0.339  0.661  0.536  1.0
  O  O25  1  0.661  0.339  0.536  1.0
  O  O26  1  0.839  0.161  0.964  1.0
  O  O27  1  0.161  0.839  0.964  1.0
  O  O28  1  0.339  0.339  0.464  1.0
  O  O29  1  0.661  0.661  0.464  1.0
  O  O30  1  0.839  0.839  0.036  1.0
  O  O31  1  0.161  0.161  0.036  1.0
[/CIF]
.