The material structure described by LiSr4Mn2(GaO5)2 is Pb (Zr_0.50 Ti_0.48) O_3-derived structured and crystallizes in the triclinic P1 space group. Li(1) is bonded in a 4-coordinate geometry to one O(10), one O(5), one O(7), and one O(9) atom. There are four inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 7-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one O(7), and one O(9) atom. In the second Sr site, Sr(2) is bonded in a 8-coordinate geometry to one O(1), one O(10), one O(2), one O(3), one O(4), one O(8), and two equivalent O(6) atoms. In the third Sr site, Sr(3) is bonded in a 7-coordinate geometry to one O(1), one O(10), one O(2), one O(3), one O(4), one O(5), and one O(7) atom. In the fourth Sr site, Sr(4) is bonded in a 9-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(9), two equivalent O(6), and two equivalent O(8) atoms. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form distorted MnO6 octahedra that share corners with four equivalent Mn(2)O6 octahedra,  a cornercorner with one Ga(1)O4 trigonal pyramid, and  a cornercorner with one Ga(2)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 1-10°. In the second Mn site, Mn(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(7), and one O(8) atom to form distorted MnO6 octahedra that share corners with four equivalent Mn(1)O6 octahedra,  a cornercorner with one Ga(1)O4 trigonal pyramid, and  a cornercorner with one Ga(2)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 1-10°. There are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded to one O(10), one O(5), one O(8), and one O(9) atom to form distorted GaO4 trigonal pyramids that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, and  an edgeedge with one Ga(2)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 31-35°. In the second Ga site, Ga(2) is bonded to one O(10), one O(6), one O(7), and one O(9) atom to form distorted GaO4 trigonal pyramids that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, and  an edgeedge with one Ga(1)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 28-37°. There are ten inequivalent O sites. In the first O site, O(1) is bonded to one Sr(1), one Sr(2), one Sr(3), one Sr(4), one Mn(1), and one Mn(2) atom to form distorted OSr4Mn2 octahedra that share corners with two equivalent O(4)Sr4Mn2 octahedra, corners with two equivalent O(10)Sr2LiGa2 trigonal bipyramids, corners with two equivalent O(9)Sr2LiGa2 trigonal bipyramids, edges with two equivalent O(4)Sr4Mn2 octahedra, faces with two equivalent O(2)Sr4Mn2 octahedra, and faces with two equivalent O(3)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 4-6°. In the second O site, O(2) is bonded to one Sr(1), one Sr(2), one Sr(3), one Sr(4), one Mn(1), and one Mn(2) atom to form distorted OSr4Mn2 octahedra that share corners with two equivalent O(3)Sr4Mn2 octahedra, corners with two equivalent O(10)Sr2LiGa2 trigonal bipyramids, corners with two equivalent O(9)Sr2LiGa2 trigonal bipyramids, edges with two equivalent O(3)Sr4Mn2 octahedra, faces with two equivalent O(1)Sr4Mn2 octahedra, and faces with two equivalent O(4)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 5-7°. In the third O site, O(3) is bonded to one Sr(1), one Sr(2), one Sr(3), one Sr(4), one Mn(1), and one Mn(2) atom to form distorted OSr4Mn2 octahedra that share corners with two equivalent O(2)Sr4Mn2 octahedra, corners with two equivalent O(10)Sr2LiGa2 trigonal bipyramids, corners with two equivalent O(9)Sr2LiGa2 trigonal bipyramids, edges with two equivalent O(2)Sr4Mn2 octahedra, faces with two equivalent O(1)Sr4Mn2 octahedra, and faces with two equivalent O(4)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 5-7°. In the fourth O site, O(4) is bonded to one Sr(1), one Sr(2), one Sr(3), one Sr(4), one Mn(1), and one Mn(2) atom to form distorted OSr4Mn2 octahedra that share corners with two equivalent O(1)Sr4Mn2 octahedra, corners with two equivalent O(10)Sr2LiGa2 trigonal bipyramids, corners with two equivalent O(9)Sr2LiGa2 trigonal bipyramids, edges with two equivalent O(1)Sr4Mn2 octahedra, faces with two equivalent O(2)Sr4Mn2 octahedra, and faces with two equivalent O(3)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 4-6°. In the fifth O site, O(5) is bonded in a 2-coordinate geometry to one Li(1), one Sr(1), one Sr(3), one Mn(1), and one Ga(1) atom. In the sixth O site, O(6) is bonded in a 5-coordinate geometry to two equivalent Sr(2), two equivalent Sr(4), one Mn(1), and one Ga(2) atom. In the seventh O site, O(7) is bonded in a 2-coordinate geometry to one Li(1), one Sr(1), one Sr(3), one Mn(2), and one Ga(2) atom. In the eighth O site, O(8) is bonded in a 5-coordinate geometry to one Sr(2), two equivalent Sr(4), one Mn(2), and one Ga(1) atom. In the ninth O site, O(9) is bonded to one Li(1), one Sr(1), one Sr(4), one Ga(1), and one Ga(2) atom to form distorted OSr2LiGa2 trigonal bipyramids that share corners with two equivalent O(1)Sr4Mn2 octahedra, corners with two equivalent O(2)Sr4Mn2 octahedra, corners with two equivalent O(3)Sr4Mn2 octahedra, corners with two equivalent O(4)Sr4Mn2 octahedra,  a cornercorner with one O(10)Sr2LiGa2 trigonal bipyramid, and  an edgeedge with one O(10)Sr2LiGa2 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 29-72°. In the tenth O site, O(10) is bonded to one Li(1), one Sr(2), one Sr(3), one Ga(1), and one Ga(2) atom to form distorted OSr2LiGa2 trigonal bipyramids that share corners with two equivalent O(1)Sr4Mn2 octahedra, corners with two equivalent O(2)Sr4Mn2 octahedra, corners with two equivalent O(3)Sr4Mn2 octahedra, corners with two equivalent O(4)Sr4Mn2 octahedra,  a cornercorner with one O(9)Sr2LiGa2 trigonal bipyramid, and  an edgeedge with one O(9)Sr2LiGa2 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 28-72°. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sr4LiMn2(GaO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.677
_cell_length_b   5.733
_cell_length_c   9.172
_cell_angle_alpha   71.868
_cell_angle_beta   72.170
_cell_angle_gamma   90.263
_symmetry_Int_Tables_number   1
_cell_volume   268.404
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.091  0.628  0.802  1.0
  Sr  Sr1  1  0.905  0.372  0.216  1.0
  Sr  Sr2  1  0.605  0.070  0.802  1.0
  Sr  Sr3  1  0.379  0.911  0.216  1.0
  Li  Li4  1  0.960  0.457  0.582  1.0
  Mn  Mn5  1  0.495  0.489  0.016  1.0
  Mn  Mn6  1  0.992  0.997  0.011  1.0
  Ga  Ga7  1  0.646  0.702  0.497  1.0
  Ga  Ga8  1  0.359  0.304  0.492  1.0
  O  O9  1  0.245  0.246  0.994  1.0
  O  O10  1  0.238  0.755  0.007  1.0
  O  O11  1  0.761  0.245  0.993  1.0
  O  O12  1  0.749  0.751  0.014  1.0
  O  O13  1  0.696  0.667  0.692  1.0
  O  O14  1  0.361  0.316  0.290  1.0
  O  O15  1  0.111  0.139  0.682  1.0
  O  O16  1  0.850  0.897  0.299  1.0
  O  O17  1  0.306  0.646  0.504  1.0
  O  O18  1  0.689  0.350  0.504  1.0
[/CIF]
.
The material structure described by LiSr4Mn2(GaO5)2 is Pb (Zr_0.50 Ti_0.48) O_3-derived structured and crystallizes in the triclinic P1 space group. Li(1) is bonded in a 4-coordinate geometry to one O(10), one O(5), one O(7), and one O(9) atom. There are four inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 7-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one O(7), and one O(9) atom. In the second Sr site, Sr(2) is bonded in a 8-coordinate geometry to one O(1), one O(10), one O(2), one O(3), one O(4), one O(8), and two equivalent O(6) atoms. In the third Sr site, Sr(3) is bonded in a 7-coordinate geometry to one O(1), one O(10), one O(2), one O(3), one O(4), one O(5), and one O(7) atom. In the fourth Sr site, Sr(4) is bonded in a 9-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(9), two equivalent O(6), and two equivalent O(8) atoms. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form distorted MnO6 octahedra that share corners with four equivalent Mn(2)O6 octahedra,  a cornercorner with one Ga(1)O4 trigonal pyramid, and  a cornercorner with one Ga(2)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 1-10°. In the second Mn site, Mn(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(7), and one O(8) atom to form distorted MnO6 octahedra that share corners with four equivalent Mn(1)O6 octahedra,  a cornercorner with one Ga(1)O4 trigonal pyramid, and  a cornercorner with one Ga(2)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 1-10°. There are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded to one O(10), one O(5), one O(8), and one O(9) atom to form distorted GaO4 trigonal pyramids that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, and  an edgeedge with one Ga(2)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 31-35°. In the second Ga site, Ga(2) is bonded to one O(10), one O(6), one O(7), and one O(9) atom to form distorted GaO4 trigonal pyramids that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, and  an edgeedge with one Ga(1)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 28-37°. There are ten inequivalent O sites. In the first O site, O(1) is bonded to one Sr(1), one Sr(2), one Sr(3), one Sr(4), one Mn(1), and one Mn(2) atom to form distorted OSr4Mn2 octahedra that share corners with two equivalent O(4)Sr4Mn2 octahedra, corners with two equivalent O(10)Sr2LiGa2 trigonal bipyramids, corners with two equivalent O(9)Sr2LiGa2 trigonal bipyramids, edges with two equivalent O(4)Sr4Mn2 octahedra, faces with two equivalent O(2)Sr4Mn2 octahedra, and faces with two equivalent O(3)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 4-6°. In the second O site, O(2) is bonded to one Sr(1), one Sr(2), one Sr(3), one Sr(4), one Mn(1), and one Mn(2) atom to form distorted OSr4Mn2 octahedra that share corners with two equivalent O(3)Sr4Mn2 octahedra, corners with two equivalent O(10)Sr2LiGa2 trigonal bipyramids, corners with two equivalent O(9)Sr2LiGa2 trigonal bipyramids, edges with two equivalent O(3)Sr4Mn2 octahedra, faces with two equivalent O(1)Sr4Mn2 octahedra, and faces with two equivalent O(4)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 5-7°. In the third O site, O(3) is bonded to one Sr(1), one Sr(2), one Sr(3), one Sr(4), one Mn(1), and one Mn(2) atom to form distorted OSr4Mn2 octahedra that share corners with two equivalent O(2)Sr4Mn2 octahedra, corners with two equivalent O(10)Sr2LiGa2 trigonal bipyramids, corners with two equivalent O(9)Sr2LiGa2 trigonal bipyramids, edges with two equivalent O(2)Sr4Mn2 octahedra, faces with two equivalent O(1)Sr4Mn2 octahedra, and faces with two equivalent O(4)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 5-7°. In the fourth O site, O(4) is bonded to one Sr(1), one Sr(2), one Sr(3), one Sr(4), one Mn(1), and one Mn(2) atom to form distorted OSr4Mn2 octahedra that share corners with two equivalent O(1)Sr4Mn2 octahedra, corners with two equivalent O(10)Sr2LiGa2 trigonal bipyramids, corners with two equivalent O(9)Sr2LiGa2 trigonal bipyramids, edges with two equivalent O(1)Sr4Mn2 octahedra, faces with two equivalent O(2)Sr4Mn2 octahedra, and faces with two equivalent O(3)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 4-6°. In the fifth O site, O(5) is bonded in a 2-coordinate geometry to one Li(1), one Sr(1), one Sr(3), one Mn(1), and one Ga(1) atom. In the sixth O site, O(6) is bonded in a 5-coordinate geometry to two equivalent Sr(2), two equivalent Sr(4), one Mn(1), and one Ga(2) atom. In the seventh O site, O(7) is bonded in a 2-coordinate geometry to one Li(1), one Sr(1), one Sr(3), one Mn(2), and one Ga(2) atom. In the eighth O site, O(8) is bonded in a 5-coordinate geometry to one Sr(2), two equivalent Sr(4), one Mn(2), and one Ga(1) atom. In the ninth O site, O(9) is bonded to one Li(1), one Sr(1), one Sr(4), one Ga(1), and one Ga(2) atom to form distorted OSr2LiGa2 trigonal bipyramids that share corners with two equivalent O(1)Sr4Mn2 octahedra, corners with two equivalent O(2)Sr4Mn2 octahedra, corners with two equivalent O(3)Sr4Mn2 octahedra, corners with two equivalent O(4)Sr4Mn2 octahedra,  a cornercorner with one O(10)Sr2LiGa2 trigonal bipyramid, and  an edgeedge with one O(10)Sr2LiGa2 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 29-72°. In the tenth O site, O(10) is bonded to one Li(1), one Sr(2), one Sr(3), one Ga(1), and one Ga(2) atom to form distorted OSr2LiGa2 trigonal bipyramids that share corners with two equivalent O(1)Sr4Mn2 octahedra, corners with two equivalent O(2)Sr4Mn2 octahedra, corners with two equivalent O(3)Sr4Mn2 octahedra, corners with two equivalent O(4)Sr4Mn2 octahedra,  a cornercorner with one O(9)Sr2LiGa2 trigonal bipyramid, and  an edgeedge with one O(9)Sr2LiGa2 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 28-72°. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sr4LiMn2(GaO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.677
_cell_length_b   5.733
_cell_length_c   9.172
_cell_angle_alpha   71.868
_cell_angle_beta   72.170
_cell_angle_gamma   90.263
_symmetry_Int_Tables_number   1
_cell_volume   268.404
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.091  0.628  0.802  1.0
  Sr  Sr1  1  0.905  0.372  0.216  1.0
  Sr  Sr2  1  0.605  0.070  0.802  1.0
  Sr  Sr3  1  0.379  0.911  0.216  1.0
  Li  Li4  1  0.960  0.457  0.582  1.0
  Mn  Mn5  1  0.495  0.489  0.016  1.0
  Mn  Mn6  1  0.992  0.997  0.011  1.0
  Ga  Ga7  1  0.646  0.702  0.497  1.0
  Ga  Ga8  1  0.359  0.304  0.492  1.0
  O  O9  1  0.245  0.246  0.994  1.0
  O  O10  1  0.238  0.755  0.007  1.0
  O  O11  1  0.761  0.245  0.993  1.0
  O  O12  1  0.749  0.751  0.014  1.0
  O  O13  1  0.696  0.667  0.692  1.0
  O  O14  1  0.361  0.316  0.290  1.0
  O  O15  1  0.111  0.139  0.682  1.0
  O  O16  1  0.850  0.897  0.299  1.0
  O  O17  1  0.306  0.646  0.504  1.0
  O  O18  1  0.689  0.350  0.504  1.0
[/CIF]
.