The material described by Rh2TeO6 is Hydrophilite-derived structured and crystallizes in the tetragonal P4_2/mnm space group. Rh(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form RhO6 octahedra that share corners with four equivalent Rh(1)O6 octahedra, corners with four equivalent Te(1)O6 octahedra,  an edgeedge with one Rh(1)O6 octahedra, and  an edgeedge with one Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-52°. Te(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form TeO6 octahedra that share corners with eight equivalent Rh(1)O6 octahedra and edges with two equivalent Rh(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-52°. There are two inequivalent O sites. In the first O site, O(2) is bonded in a trigonal planar geometry to two equivalent Rh(1) and one Te(1) atom. In the second O site, O(1) is bonded in a trigonal planar geometry to two equivalent Rh(1) and one Te(1) atom. is represented by the CIF file [CIF]
data_Te(RhO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.681
_cell_length_b   4.681
_cell_length_c   9.553
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   209.331
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.000  0.000  0.000  1.0
  Te  Te1  1  0.500  0.500  0.500  1.0
  Rh  Rh2  1  0.000  0.000  0.332  1.0
  Rh  Rh3  1  0.000  0.000  0.668  1.0
  Rh  Rh4  1  0.500  0.500  0.832  1.0
  Rh  Rh5  1  0.500  0.500  0.168  1.0
  O  O6  1  0.310  0.310  0.000  1.0
  O  O7  1  0.690  0.690  0.000  1.0
  O  O8  1  0.190  0.810  0.500  1.0
  O  O9  1  0.810  0.190  0.500  1.0
  O  O10  1  0.305  0.305  0.333  1.0
  O  O11  1  0.695  0.695  0.667  1.0
  O  O12  1  0.695  0.695  0.333  1.0
  O  O13  1  0.195  0.805  0.833  1.0
  O  O14  1  0.195  0.805  0.167  1.0
  O  O15  1  0.305  0.305  0.667  1.0
  O  O16  1  0.805  0.195  0.167  1.0
  O  O17  1  0.805  0.195  0.833  1.0
[/CIF]
.
The material described by Rh2TeO6 is Hydrophilite-derived structured and crystallizes in the tetragonal P4_2/mnm space group. Rh(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form RhO6 octahedra that share corners with four equivalent Rh(1)O6 octahedra, corners with four equivalent Te(1)O6 octahedra,  an edgeedge with one Rh(1)O6 octahedra, and  an edgeedge with one Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-52°. Te(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form TeO6 octahedra that share corners with eight equivalent Rh(1)O6 octahedra and edges with two equivalent Rh(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-52°. There are two inequivalent O sites. In the first O site, O(2) is bonded in a trigonal planar geometry to two equivalent Rh(1) and one Te(1) atom. In the second O site, O(1) is bonded in a trigonal planar geometry to two equivalent Rh(1) and one Te(1) atom. is represented by the CIF file [CIF]
data_Te(RhO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.681
_cell_length_b   4.681
_cell_length_c   9.553
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   209.331
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.000  0.000  0.000  1.0
  Te  Te1  1  0.500  0.500  0.500  1.0
  Rh  Rh2  1  0.000  0.000  0.332  1.0
  Rh  Rh3  1  0.000  0.000  0.668  1.0
  Rh  Rh4  1  0.500  0.500  0.832  1.0
  Rh  Rh5  1  0.500  0.500  0.168  1.0
  O  O6  1  0.310  0.310  0.000  1.0
  O  O7  1  0.690  0.690  0.000  1.0
  O  O8  1  0.190  0.810  0.500  1.0
  O  O9  1  0.810  0.190  0.500  1.0
  O  O10  1  0.305  0.305  0.333  1.0
  O  O11  1  0.695  0.695  0.667  1.0
  O  O12  1  0.695  0.695  0.333  1.0
  O  O13  1  0.195  0.805  0.833  1.0
  O  O14  1  0.195  0.805  0.167  1.0
  O  O15  1  0.305  0.305  0.667  1.0
  O  O16  1  0.805  0.195  0.167  1.0
  O  O17  1  0.805  0.195  0.833  1.0
[/CIF]
.