The structure described by Li(O2Cl)2 is Indium-like structured and crystallizes in the tetragonal P4_2/mmc space group. The structure is zero-dimensional and consists of two Li(O2Cl)2 clusters. Li(1) is bonded in a distorted square co-planar geometry to four equivalent O(1) atoms. O(1) is bonded in an L-shaped geometry to one Li(1) and one Cl(1) atom. Cl(1) is bonded in a water-like geometry to two equivalent O(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li(ClO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.451
_cell_length_b   5.451
_cell_length_c   14.587
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   433.505
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.500  0.000  0.500  1.0
  Li  Li1  1  0.000  0.500  0.000  1.0
  Cl  Cl2  1  0.000  0.500  0.825  1.0
  Cl  Cl3  1  0.500  0.000  0.325  1.0
  Cl  Cl4  1  0.500  0.000  0.675  1.0
  Cl  Cl5  1  0.000  0.500  0.175  1.0
  O  O6  1  0.000  0.270  0.886  1.0
  O  O7  1  0.000  0.730  0.886  1.0
  O  O8  1  0.730  0.000  0.386  1.0
  O  O9  1  0.730  0.000  0.614  1.0
  O  O10  1  0.000  0.730  0.114  1.0
  O  O11  1  0.270  0.000  0.386  1.0
  O  O12  1  0.270  0.000  0.614  1.0
  O  O13  1  0.000  0.270  0.114  1.0
[/CIF]
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The structure described by Li(O2Cl)2 is Indium-like structured and crystallizes in the tetragonal P4_2/mmc space group. The structure is zero-dimensional and consists of two Li(O2Cl)2 clusters. Li(1) is bonded in a distorted square co-planar geometry to four equivalent O(1) atoms. O(1) is bonded in an L-shaped geometry to one Li(1) and one Cl(1) atom. Cl(1) is bonded in a water-like geometry to two equivalent O(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li(ClO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.451
_cell_length_b   5.451
_cell_length_c   14.587
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   433.505
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.500  0.000  0.500  1.0
  Li  Li1  1  0.000  0.500  0.000  1.0
  Cl  Cl2  1  0.000  0.500  0.825  1.0
  Cl  Cl3  1  0.500  0.000  0.325  1.0
  Cl  Cl4  1  0.500  0.000  0.675  1.0
  Cl  Cl5  1  0.000  0.500  0.175  1.0
  O  O6  1  0.000  0.270  0.886  1.0
  O  O7  1  0.000  0.730  0.886  1.0
  O  O8  1  0.730  0.000  0.386  1.0
  O  O9  1  0.730  0.000  0.614  1.0
  O  O10  1  0.000  0.730  0.114  1.0
  O  O11  1  0.270  0.000  0.386  1.0
  O  O12  1  0.270  0.000  0.614  1.0
  O  O13  1  0.000  0.270  0.114  1.0
[/CIF]
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