The material described by (SbF5)4(F2)3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one hydrofluoric acid atom, one hydrogen fluoride hydrogen fluoride molecule, and two SbF5 clusters. In each SbF5 cluster, Sb(1) is bonded in a 4-coordinate geometry to one F(3), one F(4), one F(5), one F(6), and one F(7) atom. There are five inequivalent F sites. In the first F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(6) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(7) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sb2F13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.362
_cell_length_b   6.910
_cell_length_c   7.676
_cell_angle_alpha   116.516
_cell_angle_beta   94.873
_cell_angle_gamma   95.539
_symmetry_Int_Tables_number   1
_cell_volume   250.658
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.814  0.129  0.712  1.0
  Sb  Sb1  1  0.186  0.871  0.288  1.0
  F  F2  1  0.609  0.485  0.068  1.0
  F  F3  1  0.391  0.515  0.932  1.0
  F  F4  1  0.000  0.000  0.000  1.0
  F  F5  1  0.123  0.283  0.640  1.0
  F  F6  1  0.877  0.717  0.360  1.0
  F  F7  1  0.935  0.882  0.707  1.0
  F  F8  1  0.065  0.118  0.293  1.0
  F  F9  1  0.637  0.243  0.452  1.0
  F  F10  1  0.363  0.757  0.548  1.0
  F  F11  1  0.533  0.959  0.828  1.0
  F  F12  1  0.467  0.041  0.172  1.0
  F  F13  1  0.723  0.353  0.766  1.0
  F  F14  1  0.277  0.647  0.234  1.0
[/CIF]
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The material described by (SbF5)4(F2)3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one hydrofluoric acid atom, one hydrogen fluoride hydrogen fluoride molecule, and two SbF5 clusters. In each SbF5 cluster, Sb(1) is bonded in a 4-coordinate geometry to one F(3), one F(4), one F(5), one F(6), and one F(7) atom. There are five inequivalent F sites. In the first F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(6) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(7) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sb2F13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.362
_cell_length_b   6.910
_cell_length_c   7.676
_cell_angle_alpha   116.516
_cell_angle_beta   94.873
_cell_angle_gamma   95.539
_symmetry_Int_Tables_number   1
_cell_volume   250.658
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.814  0.129  0.712  1.0
  Sb  Sb1  1  0.186  0.871  0.288  1.0
  F  F2  1  0.609  0.485  0.068  1.0
  F  F3  1  0.391  0.515  0.932  1.0
  F  F4  1  0.000  0.000  0.000  1.0
  F  F5  1  0.123  0.283  0.640  1.0
  F  F6  1  0.877  0.717  0.360  1.0
  F  F7  1  0.935  0.882  0.707  1.0
  F  F8  1  0.065  0.118  0.293  1.0
  F  F9  1  0.637  0.243  0.452  1.0
  F  F10  1  0.363  0.757  0.548  1.0
  F  F11  1  0.533  0.959  0.828  1.0
  F  F12  1  0.467  0.041  0.172  1.0
  F  F13  1  0.723  0.353  0.766  1.0
  F  F14  1  0.277  0.647  0.234  1.0
[/CIF]
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