The structure described by KLiMnS2 crystallizes in the tetragonal I-4m2 space group. K(1) is bonded in a body-centered cubic geometry to eight equivalent S(1) atoms. Li(1) is bonded to four equivalent S(1) atoms to form distorted LiS4 tetrahedra that share corners with four equivalent Li(1)S4 tetrahedra and edges with four equivalent Mn(1)S4 tetrahedra. Mn(1) is bonded to four equivalent S(1) atoms to form distorted MnS4 tetrahedra that share corners with four equivalent Mn(1)S4 tetrahedra and edges with four equivalent Li(1)S4 tetrahedra. S(1) is bonded in a 8-coordinate geometry to four equivalent K(1), two equivalent Li(1), and two equivalent Mn(1) atoms. is represented by the CIF file [CIF]
data_KLiMnS2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.240
_cell_length_b   7.240
_cell_length_c   7.240
_cell_angle_alpha   147.411
_cell_angle_beta   147.411
_cell_angle_gamma   46.756
_symmetry_Int_Tables_number   1
_cell_volume   109.687
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.000  0.000  0.000  1.0
  Li  Li1  1  0.750  0.250  0.500  1.0
  Mn  Mn2  1  0.250  0.750  0.500  1.0
  S  S3  1  0.649  0.649  0.000  1.0
  S  S4  1  0.351  0.351  0.000  1.0
[/CIF]
.
The structure described by KLiMnS2 crystallizes in the tetragonal I-4m2 space group. K(1) is bonded in a body-centered cubic geometry to eight equivalent S(1) atoms. Li(1) is bonded to four equivalent S(1) atoms to form distorted LiS4 tetrahedra that share corners with four equivalent Li(1)S4 tetrahedra and edges with four equivalent Mn(1)S4 tetrahedra. Mn(1) is bonded to four equivalent S(1) atoms to form distorted MnS4 tetrahedra that share corners with four equivalent Mn(1)S4 tetrahedra and edges with four equivalent Li(1)S4 tetrahedra. S(1) is bonded in a 8-coordinate geometry to four equivalent K(1), two equivalent Li(1), and two equivalent Mn(1) atoms. is represented by the CIF file [CIF]
data_KLiMnS2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.240
_cell_length_b   7.240
_cell_length_c   7.240
_cell_angle_alpha   147.411
_cell_angle_beta   147.411
_cell_angle_gamma   46.756
_symmetry_Int_Tables_number   1
_cell_volume   109.687
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.000  0.000  0.000  1.0
  Li  Li1  1  0.750  0.250  0.500  1.0
  Mn  Mn2  1  0.250  0.750  0.500  1.0
  S  S3  1  0.649  0.649  0.000  1.0
  S  S4  1  0.351  0.351  0.000  1.0
[/CIF]
.