The compound described by PdN4(Pd(N2O)2)2(NO3)4 is Indium-derived structured and crystallizes in the tetragonal I-42m space group. The structure is zero-dimensional and consists of two azanide;palladium molecules, eight nitric acid molecules, and four Pd(N2O)2 clusters. In each Pd(N2O)2 cluster, Pd(2) is bonded in a square co-planar geometry to one N(1), one N(4), and two equivalent N(3) atoms. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Pd(2) and two equivalent O(1) atoms. In the second N site, N(3) is bonded in a single-bond geometry to one Pd(2) atom. In the third N site, N(4) is bonded in a single-bond geometry to one Pd(2) atom. O(1) is bonded in a single-bond geometry to one N(1) atom. is represented by the CIF card [CIF]
data_Pd3(NO)16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.169
_cell_length_b   12.169
_cell_length_c   12.169
_cell_angle_alpha   143.046
_cell_angle_beta   143.046
_cell_angle_gamma   53.257
_symmetry_Int_Tables_number   1
_cell_volume   647.253
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pd  Pd0  1  0.000  0.000  0.000  1.0
  Pd  Pd1  1  0.260  0.260  0.000  1.0
  Pd  Pd2  1  0.740  0.740  0.000  1.0
  N  N3  1  0.160  0.160  0.000  1.0
  N  N4  1  0.840  0.840  0.000  1.0
  N  N5  1  0.185  0.814  0.000  1.0
  N  N6  1  0.814  0.185  0.000  1.0
  N  N7  1  0.815  0.815  0.629  1.0
  N  N8  1  0.186  0.186  0.371  1.0
  N  N9  1  0.450  0.078  0.000  1.0
  N  N10  1  0.078  0.450  0.000  1.0
  N  N11  1  0.550  0.550  0.629  1.0
  N  N12  1  0.922  0.922  0.371  1.0
  N  N13  1  0.349  0.349  0.000  1.0
  N  N14  1  0.651  0.651  0.000  1.0
  N  N15  1  0.121  0.621  0.500  1.0
  N  N16  1  0.879  0.379  0.500  1.0
  N  N17  1  0.379  0.879  0.500  1.0
  N  N18  1  0.621  0.121  0.500  1.0
  O  O19  1  0.233  0.033  0.000  1.0
  O  O20  1  0.033  0.233  0.000  1.0
  O  O21  1  0.767  0.767  0.800  1.0
  O  O22  1  0.967  0.967  0.200  1.0
  O  O23  1  0.178  0.678  0.500  1.0
  O  O24  1  0.822  0.322  0.500  1.0
  O  O25  1  0.322  0.822  0.500  1.0
  O  O26  1  0.678  0.178  0.500  1.0
  O  O27  1  0.232  0.576  0.624  1.0
  O  O28  1  0.952  0.607  0.376  1.0
  O  O29  1  0.768  0.393  0.345  1.0
  O  O30  1  0.048  0.424  0.655  1.0
  O  O31  1  0.393  0.768  0.345  1.0
  O  O32  1  0.424  0.048  0.655  1.0
  O  O33  1  0.607  0.952  0.376  1.0
  O  O34  1  0.576  0.232  0.624  1.0
[/CIF]
.
The compound described by PdN4(Pd(N2O)2)2(NO3)4 is Indium-derived structured and crystallizes in the tetragonal I-42m space group. The structure is zero-dimensional and consists of two azanide;palladium molecules, eight nitric acid molecules, and four Pd(N2O)2 clusters. In each Pd(N2O)2 cluster, Pd(2) is bonded in a square co-planar geometry to one N(1), one N(4), and two equivalent N(3) atoms. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Pd(2) and two equivalent O(1) atoms. In the second N site, N(3) is bonded in a single-bond geometry to one Pd(2) atom. In the third N site, N(4) is bonded in a single-bond geometry to one Pd(2) atom. O(1) is bonded in a single-bond geometry to one N(1) atom. is represented by the CIF card [CIF]
data_Pd3(NO)16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.169
_cell_length_b   12.169
_cell_length_c   12.169
_cell_angle_alpha   143.046
_cell_angle_beta   143.046
_cell_angle_gamma   53.257
_symmetry_Int_Tables_number   1
_cell_volume   647.253
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pd  Pd0  1  0.000  0.000  0.000  1.0
  Pd  Pd1  1  0.260  0.260  0.000  1.0
  Pd  Pd2  1  0.740  0.740  0.000  1.0
  N  N3  1  0.160  0.160  0.000  1.0
  N  N4  1  0.840  0.840  0.000  1.0
  N  N5  1  0.185  0.814  0.000  1.0
  N  N6  1  0.814  0.185  0.000  1.0
  N  N7  1  0.815  0.815  0.629  1.0
  N  N8  1  0.186  0.186  0.371  1.0
  N  N9  1  0.450  0.078  0.000  1.0
  N  N10  1  0.078  0.450  0.000  1.0
  N  N11  1  0.550  0.550  0.629  1.0
  N  N12  1  0.922  0.922  0.371  1.0
  N  N13  1  0.349  0.349  0.000  1.0
  N  N14  1  0.651  0.651  0.000  1.0
  N  N15  1  0.121  0.621  0.500  1.0
  N  N16  1  0.879  0.379  0.500  1.0
  N  N17  1  0.379  0.879  0.500  1.0
  N  N18  1  0.621  0.121  0.500  1.0
  O  O19  1  0.233  0.033  0.000  1.0
  O  O20  1  0.033  0.233  0.000  1.0
  O  O21  1  0.767  0.767  0.800  1.0
  O  O22  1  0.967  0.967  0.200  1.0
  O  O23  1  0.178  0.678  0.500  1.0
  O  O24  1  0.822  0.322  0.500  1.0
  O  O25  1  0.322  0.822  0.500  1.0
  O  O26  1  0.678  0.178  0.500  1.0
  O  O27  1  0.232  0.576  0.624  1.0
  O  O28  1  0.952  0.607  0.376  1.0
  O  O29  1  0.768  0.393  0.345  1.0
  O  O30  1  0.048  0.424  0.655  1.0
  O  O31  1  0.393  0.768  0.345  1.0
  O  O32  1  0.424  0.048  0.655  1.0
  O  O33  1  0.607  0.952  0.376  1.0
  O  O34  1  0.576  0.232  0.624  1.0
[/CIF]
.