The structure described by Na2Au6In5 crystallizes in the cubic Pm-3 space group. Na(1) is bonded in a 15-coordinate geometry to one Na(1), six equivalent Au(1), four equivalent In(1), and four equivalent In(2) atoms. There are two inequivalent Au sites. In the first Au site, Au(1) is bonded in a 7-coordinate geometry to three equivalent Na(1), one In(2), one In(3), and two equivalent In(1) atoms. In the second Au site, Au(2) is bonded in a 6-coordinate geometry to two equivalent In(2) and four equivalent In(1) atoms. There are three inequivalent In sites. In the first In site, In(1) is bonded in a 6-coordinate geometry to three equivalent Na(1), three equivalent Au(1), and three equivalent Au(2) atoms. In the second In site, In(2) is bonded in a 4-coordinate geometry to four equivalent Na(1), two equivalent Au(1), and two equivalent Au(2) atoms. In the third In site, In(3) is bonded in a cuboctahedral geometry to twelve equivalent Au(1) atoms. is represented by the CIF card [CIF]
data_Na2In5Au6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.479
_cell_length_b   9.479
_cell_length_c   9.479
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   851.675
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.500  0.828  0.000  1.0
  Na  Na1  1  0.500  0.172  0.000  1.0
  Na  Na2  1  0.828  0.000  0.500  1.0
  Na  Na3  1  0.000  0.500  0.828  1.0
  Na  Na4  1  0.000  0.500  0.172  1.0
  Na  Na5  1  0.172  0.000  0.500  1.0
  In  In6  1  0.283  0.283  0.717  1.0
  In  In7  1  0.717  0.717  0.283  1.0
  In  In8  1  0.717  0.283  0.717  1.0
  In  In9  1  0.500  0.000  0.338  1.0
  In  In10  1  0.500  0.000  0.662  1.0
  In  In11  1  0.338  0.500  0.000  1.0
  In  In12  1  0.662  0.500  0.000  1.0
  In  In13  1  0.000  0.338  0.500  1.0
  In  In14  1  0.717  0.717  0.717  1.0
  In  In15  1  0.283  0.717  0.283  1.0
  In  In16  1  0.000  0.662  0.500  1.0
  In  In17  1  0.283  0.717  0.717  1.0
  In  In18  1  0.717  0.283  0.283  1.0
  In  In19  1  0.283  0.283  0.283  1.0
  In  In20  1  0.000  0.000  0.000  1.0
  Au  Au21  1  0.827  0.741  0.000  1.0
  Au  Au22  1  0.259  0.000  0.173  1.0
  Au  Au23  1  0.000  0.173  0.741  1.0
  Au  Au24  1  0.173  0.259  0.000  1.0
  Au  Au25  1  0.827  0.259  0.000  1.0
  Au  Au26  1  0.735  0.500  0.500  1.0
  Au  Au27  1  0.000  0.827  0.741  1.0
  Au  Au28  1  0.173  0.741  0.000  1.0
  Au  Au29  1  0.741  0.000  0.173  1.0
  Au  Au30  1  0.000  0.173  0.259  1.0
  Au  Au31  1  0.500  0.500  0.265  1.0
  Au  Au32  1  0.500  0.500  0.735  1.0
  Au  Au33  1  0.500  0.735  0.500  1.0
  Au  Au34  1  0.259  0.000  0.827  1.0
  Au  Au35  1  0.265  0.500  0.500  1.0
  Au  Au36  1  0.741  0.000  0.827  1.0
  Au  Au37  1  0.000  0.827  0.259  1.0
  Au  Au38  1  0.500  0.265  0.500  1.0
[/CIF]
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The structure described by Na2Au6In5 crystallizes in the cubic Pm-3 space group. Na(1) is bonded in a 15-coordinate geometry to one Na(1), six equivalent Au(1), four equivalent In(1), and four equivalent In(2) atoms. There are two inequivalent Au sites. In the first Au site, Au(1) is bonded in a 7-coordinate geometry to three equivalent Na(1), one In(2), one In(3), and two equivalent In(1) atoms. In the second Au site, Au(2) is bonded in a 6-coordinate geometry to two equivalent In(2) and four equivalent In(1) atoms. There are three inequivalent In sites. In the first In site, In(1) is bonded in a 6-coordinate geometry to three equivalent Na(1), three equivalent Au(1), and three equivalent Au(2) atoms. In the second In site, In(2) is bonded in a 4-coordinate geometry to four equivalent Na(1), two equivalent Au(1), and two equivalent Au(2) atoms. In the third In site, In(3) is bonded in a cuboctahedral geometry to twelve equivalent Au(1) atoms. is represented by the CIF card [CIF]
data_Na2In5Au6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.479
_cell_length_b   9.479
_cell_length_c   9.479
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   851.675
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.500  0.828  0.000  1.0
  Na  Na1  1  0.500  0.172  0.000  1.0
  Na  Na2  1  0.828  0.000  0.500  1.0
  Na  Na3  1  0.000  0.500  0.828  1.0
  Na  Na4  1  0.000  0.500  0.172  1.0
  Na  Na5  1  0.172  0.000  0.500  1.0
  In  In6  1  0.283  0.283  0.717  1.0
  In  In7  1  0.717  0.717  0.283  1.0
  In  In8  1  0.717  0.283  0.717  1.0
  In  In9  1  0.500  0.000  0.338  1.0
  In  In10  1  0.500  0.000  0.662  1.0
  In  In11  1  0.338  0.500  0.000  1.0
  In  In12  1  0.662  0.500  0.000  1.0
  In  In13  1  0.000  0.338  0.500  1.0
  In  In14  1  0.717  0.717  0.717  1.0
  In  In15  1  0.283  0.717  0.283  1.0
  In  In16  1  0.000  0.662  0.500  1.0
  In  In17  1  0.283  0.717  0.717  1.0
  In  In18  1  0.717  0.283  0.283  1.0
  In  In19  1  0.283  0.283  0.283  1.0
  In  In20  1  0.000  0.000  0.000  1.0
  Au  Au21  1  0.827  0.741  0.000  1.0
  Au  Au22  1  0.259  0.000  0.173  1.0
  Au  Au23  1  0.000  0.173  0.741  1.0
  Au  Au24  1  0.173  0.259  0.000  1.0
  Au  Au25  1  0.827  0.259  0.000  1.0
  Au  Au26  1  0.735  0.500  0.500  1.0
  Au  Au27  1  0.000  0.827  0.741  1.0
  Au  Au28  1  0.173  0.741  0.000  1.0
  Au  Au29  1  0.741  0.000  0.173  1.0
  Au  Au30  1  0.000  0.173  0.259  1.0
  Au  Au31  1  0.500  0.500  0.265  1.0
  Au  Au32  1  0.500  0.500  0.735  1.0
  Au  Au33  1  0.500  0.735  0.500  1.0
  Au  Au34  1  0.259  0.000  0.827  1.0
  Au  Au35  1  0.265  0.500  0.500  1.0
  Au  Au36  1  0.741  0.000  0.827  1.0
  Au  Au37  1  0.000  0.827  0.259  1.0
  Au  Au38  1  0.500  0.265  0.500  1.0
[/CIF]
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