The material structure described by Rb2LiPu(OCl2)2 crystallizes in the triclinic P1 space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 6-coordinate geometry to one O(1), one Cl(1), one Cl(2), one Cl(4), and two equivalent Cl(3) atoms. In the second Rb site, Rb(2) is bonded in a 8-coordinate geometry to two equivalent Cl(1), two equivalent Cl(2), two equivalent Cl(3), and two equivalent Cl(4) atoms. Li(1) is bonded in a distorted tetrahedral geometry to one O(1), one O(2), one Cl(1), and one Cl(4) atom. Pu(1) is bonded in a distorted linear geometry to one O(1), one O(2), one Cl(2), one Cl(3), and one Cl(4) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Rb(1), one Li(1), and one Pu(1) atom. In the second O site, O(2) is bonded in a water-like geometry to one Li(1) and one Pu(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 1-coordinate geometry to one Rb(1), two equivalent Rb(2), and one Li(1) atom. In the second Cl site, Cl(2) is bonded in a 4-coordinate geometry to one Rb(1), two equivalent Rb(2), and one Pu(1) atom. In the third Cl site, Cl(3) is bonded to two equivalent Rb(1), two equivalent Rb(2), and one Pu(1) atom to form distorted corner-sharing ClRb4Pu trigonal bipyramids. In the fourth Cl site, Cl(4) is bonded in a 4-coordinate geometry to one Rb(1), two equivalent Rb(2), one Li(1), and one Pu(1) atom. is represented by the CIF card [CIF]
data_Rb2LiPu(Cl2O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.013
_cell_length_b   7.253
_cell_length_c   7.321
_cell_angle_alpha   62.453
_cell_angle_beta   93.756
_cell_angle_gamma   90.232
_symmetry_Int_Tables_number   1
_cell_volume   282.362
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.771  0.894  0.772  1.0
  Rb  Rb1  1  0.237  0.176  0.106  1.0
  Li  Li2  1  0.981  0.573  0.390  1.0
  Pu  Pu3  1  0.485  0.498  0.491  1.0
  Cl  Cl4  1  0.726  0.861  0.321  1.0
  Cl  Cl5  1  0.710  0.390  0.865  1.0
  Cl  Cl6  1  0.263  0.134  0.620  1.0
  Cl  Cl7  1  0.220  0.629  0.120  1.0
  O  O8  1  0.723  0.387  0.425  1.0
  O  O9  1  0.248  0.608  0.557  1.0
[/CIF]
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The material structure described by Rb2LiPu(OCl2)2 crystallizes in the triclinic P1 space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 6-coordinate geometry to one O(1), one Cl(1), one Cl(2), one Cl(4), and two equivalent Cl(3) atoms. In the second Rb site, Rb(2) is bonded in a 8-coordinate geometry to two equivalent Cl(1), two equivalent Cl(2), two equivalent Cl(3), and two equivalent Cl(4) atoms. Li(1) is bonded in a distorted tetrahedral geometry to one O(1), one O(2), one Cl(1), and one Cl(4) atom. Pu(1) is bonded in a distorted linear geometry to one O(1), one O(2), one Cl(2), one Cl(3), and one Cl(4) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Rb(1), one Li(1), and one Pu(1) atom. In the second O site, O(2) is bonded in a water-like geometry to one Li(1) and one Pu(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 1-coordinate geometry to one Rb(1), two equivalent Rb(2), and one Li(1) atom. In the second Cl site, Cl(2) is bonded in a 4-coordinate geometry to one Rb(1), two equivalent Rb(2), and one Pu(1) atom. In the third Cl site, Cl(3) is bonded to two equivalent Rb(1), two equivalent Rb(2), and one Pu(1) atom to form distorted corner-sharing ClRb4Pu trigonal bipyramids. In the fourth Cl site, Cl(4) is bonded in a 4-coordinate geometry to one Rb(1), two equivalent Rb(2), one Li(1), and one Pu(1) atom. is represented by the CIF card [CIF]
data_Rb2LiPu(Cl2O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.013
_cell_length_b   7.253
_cell_length_c   7.321
_cell_angle_alpha   62.453
_cell_angle_beta   93.756
_cell_angle_gamma   90.232
_symmetry_Int_Tables_number   1
_cell_volume   282.362
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.771  0.894  0.772  1.0
  Rb  Rb1  1  0.237  0.176  0.106  1.0
  Li  Li2  1  0.981  0.573  0.390  1.0
  Pu  Pu3  1  0.485  0.498  0.491  1.0
  Cl  Cl4  1  0.726  0.861  0.321  1.0
  Cl  Cl5  1  0.710  0.390  0.865  1.0
  Cl  Cl6  1  0.263  0.134  0.620  1.0
  Cl  Cl7  1  0.220  0.629  0.120  1.0
  O  O8  1  0.723  0.387  0.425  1.0
  O  O9  1  0.248  0.608  0.557  1.0
[/CIF]
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