The crystal structure described by K(RhP)2 crystallizes in the tetragonal I4/mmm space group. K(1) is bonded in a body-centered cubic geometry to eight equivalent P(1) atoms. Rh(1) is bonded to four equivalent P(1) atoms to form a mixture of corner and edge-sharing RhP4 tetrahedra. P(1) is bonded in a 8-coordinate geometry to four equivalent K(1) and four equivalent Rh(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_K(PRh)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.900
_cell_length_b   3.900
_cell_length_c   7.132
_cell_angle_alpha   105.867
_cell_angle_beta   105.867
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   100.028
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.000  0.000  0.000  1.0
  P  P1  1  0.654  0.654  0.307  1.0
  P  P2  1  0.346  0.346  0.693  1.0
  Rh  Rh3  1  0.750  0.250  0.500  1.0
  Rh  Rh4  1  0.250  0.750  0.500  1.0
[/CIF]
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The crystal structure described by K(RhP)2 crystallizes in the tetragonal I4/mmm space group. K(1) is bonded in a body-centered cubic geometry to eight equivalent P(1) atoms. Rh(1) is bonded to four equivalent P(1) atoms to form a mixture of corner and edge-sharing RhP4 tetrahedra. P(1) is bonded in a 8-coordinate geometry to four equivalent K(1) and four equivalent Rh(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_K(PRh)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.900
_cell_length_b   3.900
_cell_length_c   7.132
_cell_angle_alpha   105.867
_cell_angle_beta   105.867
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   100.028
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.000  0.000  0.000  1.0
  P  P1  1  0.654  0.654  0.307  1.0
  P  P2  1  0.346  0.346  0.693  1.0
  Rh  Rh3  1  0.750  0.250  0.500  1.0
  Rh  Rh4  1  0.250  0.750  0.500  1.0
[/CIF]
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