The material described by AsF6SOF3 is Iron Boride structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four trifluoro(hydroxy)-lambda4-sulfane molecules and four AsF6 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to one F(1), one F(5), two equivalent F(2), and two equivalent F(6) atoms. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(6) is bonded in a single-bond geometry to one As(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_AsSOF9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.454
_cell_length_b   8.704
_cell_length_c   11.175
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   725.048
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.750  0.708  0.487  1.0
  As  As1  1  0.250  0.208  0.013  1.0
  As  As2  1  0.250  0.292  0.513  1.0
  As  As3  1  0.750  0.792  0.987  1.0
  S  S4  1  0.250  0.834  0.304  1.0
  S  S5  1  0.750  0.334  0.196  1.0
  S  S6  1  0.750  0.166  0.696  1.0
  S  S7  1  0.250  0.666  0.804  1.0
  O  O8  1  0.250  0.705  0.231  1.0
  O  O9  1  0.250  0.795  0.731  1.0
  O  O10  1  0.750  0.295  0.769  1.0
  O  O11  1  0.750  0.205  0.269  1.0
  F  F12  1  0.750  0.506  0.504  1.0
  F  F13  1  0.081  0.271  0.403  1.0
  F  F14  1  0.750  0.309  0.063  1.0
  F  F15  1  0.095  0.556  0.789  1.0
  F  F16  1  0.919  0.771  0.097  1.0
  F  F17  1  0.250  0.090  0.536  1.0
  F  F18  1  0.905  0.444  0.211  1.0
  F  F19  1  0.418  0.310  0.626  1.0
  F  F20  1  0.582  0.810  0.874  1.0
  F  F21  1  0.750  0.910  0.464  1.0
  F  F22  1  0.918  0.810  0.874  1.0
  F  F23  1  0.595  0.444  0.211  1.0
  F  F24  1  0.250  0.494  0.496  1.0
  F  F25  1  0.405  0.556  0.789  1.0
  F  F26  1  0.250  0.006  0.996  1.0
  F  F27  1  0.581  0.771  0.097  1.0
  F  F28  1  0.082  0.310  0.626  1.0
  F  F29  1  0.081  0.229  0.903  1.0
  F  F30  1  0.750  0.994  0.004  1.0
  F  F31  1  0.418  0.190  0.126  1.0
  F  F32  1  0.419  0.229  0.903  1.0
  F  F33  1  0.419  0.271  0.403  1.0
  F  F34  1  0.750  0.590  0.964  1.0
  F  F35  1  0.250  0.809  0.437  1.0
  F  F36  1  0.595  0.056  0.711  1.0
  F  F37  1  0.082  0.190  0.126  1.0
  F  F38  1  0.750  0.191  0.563  1.0
  F  F39  1  0.405  0.944  0.289  1.0
  F  F40  1  0.919  0.729  0.597  1.0
  F  F41  1  0.918  0.690  0.374  1.0
  F  F42  1  0.250  0.691  0.937  1.0
  F  F43  1  0.095  0.944  0.289  1.0
  F  F44  1  0.250  0.410  0.036  1.0
  F  F45  1  0.582  0.690  0.374  1.0
  F  F46  1  0.581  0.729  0.597  1.0
  F  F47  1  0.905  0.056  0.711  1.0
[/CIF]
.
The material described by AsF6SOF3 is Iron Boride structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four trifluoro(hydroxy)-lambda4-sulfane molecules and four AsF6 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to one F(1), one F(5), two equivalent F(2), and two equivalent F(6) atoms. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(6) is bonded in a single-bond geometry to one As(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_AsSOF9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.454
_cell_length_b   8.704
_cell_length_c   11.175
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   725.048
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.750  0.708  0.487  1.0
  As  As1  1  0.250  0.208  0.013  1.0
  As  As2  1  0.250  0.292  0.513  1.0
  As  As3  1  0.750  0.792  0.987  1.0
  S  S4  1  0.250  0.834  0.304  1.0
  S  S5  1  0.750  0.334  0.196  1.0
  S  S6  1  0.750  0.166  0.696  1.0
  S  S7  1  0.250  0.666  0.804  1.0
  O  O8  1  0.250  0.705  0.231  1.0
  O  O9  1  0.250  0.795  0.731  1.0
  O  O10  1  0.750  0.295  0.769  1.0
  O  O11  1  0.750  0.205  0.269  1.0
  F  F12  1  0.750  0.506  0.504  1.0
  F  F13  1  0.081  0.271  0.403  1.0
  F  F14  1  0.750  0.309  0.063  1.0
  F  F15  1  0.095  0.556  0.789  1.0
  F  F16  1  0.919  0.771  0.097  1.0
  F  F17  1  0.250  0.090  0.536  1.0
  F  F18  1  0.905  0.444  0.211  1.0
  F  F19  1  0.418  0.310  0.626  1.0
  F  F20  1  0.582  0.810  0.874  1.0
  F  F21  1  0.750  0.910  0.464  1.0
  F  F22  1  0.918  0.810  0.874  1.0
  F  F23  1  0.595  0.444  0.211  1.0
  F  F24  1  0.250  0.494  0.496  1.0
  F  F25  1  0.405  0.556  0.789  1.0
  F  F26  1  0.250  0.006  0.996  1.0
  F  F27  1  0.581  0.771  0.097  1.0
  F  F28  1  0.082  0.310  0.626  1.0
  F  F29  1  0.081  0.229  0.903  1.0
  F  F30  1  0.750  0.994  0.004  1.0
  F  F31  1  0.418  0.190  0.126  1.0
  F  F32  1  0.419  0.229  0.903  1.0
  F  F33  1  0.419  0.271  0.403  1.0
  F  F34  1  0.750  0.590  0.964  1.0
  F  F35  1  0.250  0.809  0.437  1.0
  F  F36  1  0.595  0.056  0.711  1.0
  F  F37  1  0.082  0.190  0.126  1.0
  F  F38  1  0.750  0.191  0.563  1.0
  F  F39  1  0.405  0.944  0.289  1.0
  F  F40  1  0.919  0.729  0.597  1.0
  F  F41  1  0.918  0.690  0.374  1.0
  F  F42  1  0.250  0.691  0.937  1.0
  F  F43  1  0.095  0.944  0.289  1.0
  F  F44  1  0.250  0.410  0.036  1.0
  F  F45  1  0.582  0.690  0.374  1.0
  F  F46  1  0.581  0.729  0.597  1.0
  F  F47  1  0.905  0.056  0.711  1.0
[/CIF]
.