The material structure described by Mn12O5F19 is Hydrophilite-derived structured and crystallizes in the triclinic P1 space group. There are twelve inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one F(1), one F(12), one F(15), one F(16), and one F(6) atom to form MnOF5 octahedra that share corners with two equivalent Mn(9)O2F4 octahedra, corners with two equivalent Mn(7)OF5 octahedra, corners with four equivalent Mn(11)OF5 octahedra,  an edgeedge with one Mn(2)OF5 octahedra, and  an edgeedge with one Mn(5)OF5 octahedra. The corner-sharing octahedral tilt angles range from 43-54°. In the second Mn site, Mn(2) is bonded to one O(5), one F(1), one F(11), one F(16), one F(4), and one F(5) atom to form MnOF5 octahedra that share corners with two equivalent Mn(10)OF5 octahedra, corners with two equivalent Mn(11)OF5 octahedra, corners with four equivalent Mn(9)O2F4 octahedra,  an edgeedge with one Mn(3)O2F4 octahedra, and  an edgeedge with one Mn(1)OF5 octahedra. The corner-sharing octahedral tilt angles range from 45-59°. In the third Mn site, Mn(3) is bonded to one O(3), one O(5), one F(10), one F(17), one F(3), and one F(4) atom to form MnO2F4 octahedra that share corners with two equivalent Mn(8)F6 octahedra, corners with two equivalent Mn(9)O2F4 octahedra, corners with four equivalent Mn(10)OF5 octahedra,  an edgeedge with one Mn(2)OF5 octahedra, and  an edgeedge with one Mn(6)OF5 octahedra. The corner-sharing octahedral tilt angles range from 47-63°. In the fourth Mn site, Mn(4) is bonded to one O(2), one O(4), one F(18), one F(19), one F(2), and one F(8) atom to form MnO2F4 octahedra that share corners with two equivalent Mn(8)F6 octahedra, corners with two equivalent Mn(7)OF5 octahedra, corners with four equivalent Mn(12)O2F4 octahedra,  an edgeedge with one Mn(5)OF5 octahedra, and  an edgeedge with one Mn(6)OF5 octahedra. The corner-sharing octahedral tilt angles range from 44-59°. In the fifth Mn site, Mn(5) is bonded to one O(1), one F(13), one F(15), one F(19), one F(2), and one F(7) atom to form distorted MnOF5 octahedra that share corners with two equivalent Mn(12)O2F4 octahedra, corners with two equivalent Mn(11)OF5 octahedra, corners with four equivalent Mn(7)OF5 octahedra,  an edgeedge with one Mn(4)O2F4 octahedra, and  an edgeedge with one Mn(1)OF5 octahedra. The corner-sharing octahedral tilt angles range from 46-60°. In the sixth Mn site, Mn(6) is bonded to one O(2), one F(14), one F(17), one F(18), one F(3), and one F(9) atom to form MnOF5 octahedra that share corners with two equivalent Mn(12)O2F4 octahedra, corners with two equivalent Mn(10)OF5 octahedra, corners with four equivalent Mn(8)F6 octahedra,  an edgeedge with one Mn(3)O2F4 octahedra, and  an edgeedge with one Mn(4)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 48-63°. In the seventh Mn site, Mn(7) is bonded to one O(4), one F(13), one F(15), one F(2), one F(6), and one F(7) atom to form MnOF5 octahedra that share corners with two equivalent Mn(4)O2F4 octahedra, corners with two equivalent Mn(1)OF5 octahedra, corners with four equivalent Mn(5)OF5 octahedra,  an edgeedge with one Mn(12)O2F4 octahedra, and  an edgeedge with one Mn(11)OF5 octahedra. The corner-sharing octahedral tilt angles range from 43-59°. In the eighth Mn site, Mn(8) is bonded to one F(10), one F(14), one F(18), one F(3), one F(8), and one F(9) atom to form distorted MnF6 octahedra that share corners with two equivalent Mn(3)O2F4 octahedra, corners with two equivalent Mn(4)O2F4 octahedra, corners with four equivalent Mn(6)OF5 octahedra,  an edgeedge with one Mn(12)O2F4 octahedra, and  an edgeedge with one Mn(10)OF5 octahedra. The corner-sharing octahedral tilt angles range from 47-63°. In the ninth Mn site, Mn(9) is bonded to one O(3), one O(5), one F(1), one F(11), one F(12), and one F(5) atom to form MnO2F4 octahedra that share corners with two equivalent Mn(3)O2F4 octahedra, corners with two equivalent Mn(1)OF5 octahedra, corners with four equivalent Mn(2)OF5 octahedra,  an edgeedge with one Mn(10)OF5 octahedra, and  an edgeedge with one Mn(11)OF5 octahedra. The corner-sharing octahedral tilt angles range from 44-59°. In the tenth Mn site, Mn(10) is bonded to one O(3), one F(10), one F(11), one F(17), one F(4), and one F(9) atom to form MnOF5 octahedra that share corners with two equivalent Mn(2)OF5 octahedra, corners with two equivalent Mn(6)OF5 octahedra, corners with four equivalent Mn(3)O2F4 octahedra,  an edgeedge with one Mn(8)F6 octahedra, and  an edgeedge with one Mn(9)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 48-63°. In the eleventh Mn site, Mn(11) is bonded to one O(1), one F(12), one F(13), one F(16), one F(5), and one F(6) atom to form MnOF5 octahedra that share corners with two equivalent Mn(2)OF5 octahedra, corners with two equivalent Mn(5)OF5 octahedra, corners with four equivalent Mn(1)OF5 octahedra,  an edgeedge with one Mn(9)O2F4 octahedra, and  an edgeedge with one Mn(7)OF5 octahedra. The corner-sharing octahedral tilt angles range from 47-60°. In the twelfth Mn site, Mn(12) is bonded to one O(2), one O(4), one F(14), one F(19), one F(7), and one F(8) atom to form MnO2F4 octahedra that share corners with two equivalent Mn(5)OF5 octahedra, corners with two equivalent Mn(6)OF5 octahedra, corners with four equivalent Mn(4)O2F4 octahedra,  an edgeedge with one Mn(8)F6 octahedra, and  an edgeedge with one Mn(7)OF5 octahedra. The corner-sharing octahedral tilt angles range from 44-59°. There are five inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Mn(1), one Mn(11), and one Mn(5) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Mn(12), one Mn(4), and one Mn(6) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Mn(10), one Mn(3), and one Mn(9) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Mn(12), one Mn(4), and one Mn(7) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one Mn(2), one Mn(3), and one Mn(9) atom. There are nineteen inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(2), and one Mn(9) atom. In the second F site, F(2) is bonded in a trigonal planar geometry to one Mn(4), one Mn(5), and one Mn(7) atom. In the third F site, F(3) is bonded in a trigonal planar geometry to one Mn(3), one Mn(6), and one Mn(8) atom. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one Mn(10), one Mn(2), and one Mn(3) atom. In the fifth F site, F(5) is bonded in a trigonal planar geometry to one Mn(11), one Mn(2), and one Mn(9) atom. In the sixth F site, F(6) is bonded in a trigonal planar geometry to one Mn(1), one Mn(11), and one Mn(7) atom. In the seventh F site, F(7) is bonded in a distorted trigonal planar geometry to one Mn(12), one Mn(5), and one Mn(7) atom. In the eighth F site, F(8) is bonded in a trigonal planar geometry to one Mn(12), one Mn(4), and one Mn(8) atom. In the ninth F site, F(9) is bonded in a trigonal planar geometry to one Mn(10), one Mn(6), and one Mn(8) atom. In the tenth F site, F(10) is bonded in a trigonal planar geometry to one Mn(10), one Mn(3), and one Mn(8) atom. In the eleventh F site, F(11) is bonded in a distorted trigonal planar geometry to one Mn(10), one Mn(2), and one Mn(9) atom. In the twelfth F site, F(12) is bonded in a trigonal planar geometry to one Mn(1), one Mn(11), and one Mn(9) atom. In the thirteenth F site, F(13) is bonded in a trigonal planar geometry to one Mn(11), one Mn(5), and one Mn(7) atom. In the fourteenth F site, F(14) is bonded in a distorted trigonal planar geometry to one Mn(12), one Mn(6), and one Mn(8) atom. In the fifteenth F site, F(15) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(5), and one Mn(7) atom. In the sixteenth F site, F(16) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(11), and one Mn(2) atom. In the seventeenth F site, F(17) is bonded in a trigonal planar geometry to one Mn(10), one Mn(3), and one Mn(6) atom. In the eighteenth F site, F(18) is bonded in a trigonal planar geometry to one Mn(4), one Mn(6), and one Mn(8) atom. In the nineteenth F site, F(19) is bonded in a trigonal planar geometry to one Mn(12), one Mn(4), and one Mn(5) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mn12O5F19
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.810
_cell_length_b   5.812
_cell_length_c   16.109
_cell_angle_alpha   90.409
_cell_angle_beta   89.994
_cell_angle_gamma   92.271
_symmetry_Int_Tables_number   1
_cell_volume   449.999
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.015  0.854  0.581  1.0
  Mn  Mn1  1  0.991  0.149  0.751  1.0
  Mn  Mn2  1  0.011  0.827  0.906  1.0
  Mn  Mn3  1  0.994  0.846  0.252  1.0
  Mn  Mn4  1  0.014  0.169  0.425  1.0
  Mn  Mn5  1  0.016  0.158  0.090  1.0
  Mn  Mn6  1  0.521  0.664  0.406  1.0
  Mn  Mn7  1  0.485  0.672  0.083  1.0
  Mn  Mn8  1  0.505  0.672  0.761  1.0
  Mn  Mn9  1  0.505  0.351  0.916  1.0
  Mn  Mn10  1  0.482  0.338  0.582  1.0
  Mn  Mn11  1  0.499  0.340  0.248  1.0
  O  O12  1  0.222  0.102  0.534  1.0
  O  O13  1  0.224  0.105  0.202  1.0
  O  O14  1  0.290  0.623  0.862  1.0
  O  O15  1  0.722  0.611  0.295  1.0
  O  O16  1  0.789  0.875  0.806  1.0
  F  F17  1  0.238  0.888  0.690  1.0
  F  F18  1  0.210  0.877  0.361  1.0
  F  F19  1  0.221  0.887  0.018  1.0
  F  F20  1  0.244  0.120  0.856  1.0
  F  F21  1  0.273  0.404  0.698  1.0
  F  F22  1  0.263  0.609  0.522  1.0
  F  F23  1  0.276  0.382  0.355  1.0
  F  F24  1  0.242  0.606  0.191  1.0
  F  F25  1  0.267  0.388  0.026  1.0
  F  F26  1  0.747  0.610  0.979  1.0
  F  F27  1  0.738  0.385  0.806  1.0
  F  F28  1  0.731  0.625  0.640  1.0
  F  F29  1  0.719  0.392  0.473  1.0
  F  F30  1  0.705  0.376  0.138  1.0
  F  F31  1  0.767  0.882  0.479  1.0
  F  F32  1  0.763  0.115  0.640  1.0
  F  F33  1  0.779  0.106  0.972  1.0
  F  F34  1  0.774  0.885  0.143  1.0
  F  F35  1  0.756  0.108  0.313  1.0
[/CIF]
.
The material structure described by Mn12O5F19 is Hydrophilite-derived structured and crystallizes in the triclinic P1 space group. There are twelve inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one F(1), one F(12), one F(15), one F(16), and one F(6) atom to form MnOF5 octahedra that share corners with two equivalent Mn(9)O2F4 octahedra, corners with two equivalent Mn(7)OF5 octahedra, corners with four equivalent Mn(11)OF5 octahedra,  an edgeedge with one Mn(2)OF5 octahedra, and  an edgeedge with one Mn(5)OF5 octahedra. The corner-sharing octahedral tilt angles range from 43-54°. In the second Mn site, Mn(2) is bonded to one O(5), one F(1), one F(11), one F(16), one F(4), and one F(5) atom to form MnOF5 octahedra that share corners with two equivalent Mn(10)OF5 octahedra, corners with two equivalent Mn(11)OF5 octahedra, corners with four equivalent Mn(9)O2F4 octahedra,  an edgeedge with one Mn(3)O2F4 octahedra, and  an edgeedge with one Mn(1)OF5 octahedra. The corner-sharing octahedral tilt angles range from 45-59°. In the third Mn site, Mn(3) is bonded to one O(3), one O(5), one F(10), one F(17), one F(3), and one F(4) atom to form MnO2F4 octahedra that share corners with two equivalent Mn(8)F6 octahedra, corners with two equivalent Mn(9)O2F4 octahedra, corners with four equivalent Mn(10)OF5 octahedra,  an edgeedge with one Mn(2)OF5 octahedra, and  an edgeedge with one Mn(6)OF5 octahedra. The corner-sharing octahedral tilt angles range from 47-63°. In the fourth Mn site, Mn(4) is bonded to one O(2), one O(4), one F(18), one F(19), one F(2), and one F(8) atom to form MnO2F4 octahedra that share corners with two equivalent Mn(8)F6 octahedra, corners with two equivalent Mn(7)OF5 octahedra, corners with four equivalent Mn(12)O2F4 octahedra,  an edgeedge with one Mn(5)OF5 octahedra, and  an edgeedge with one Mn(6)OF5 octahedra. The corner-sharing octahedral tilt angles range from 44-59°. In the fifth Mn site, Mn(5) is bonded to one O(1), one F(13), one F(15), one F(19), one F(2), and one F(7) atom to form distorted MnOF5 octahedra that share corners with two equivalent Mn(12)O2F4 octahedra, corners with two equivalent Mn(11)OF5 octahedra, corners with four equivalent Mn(7)OF5 octahedra,  an edgeedge with one Mn(4)O2F4 octahedra, and  an edgeedge with one Mn(1)OF5 octahedra. The corner-sharing octahedral tilt angles range from 46-60°. In the sixth Mn site, Mn(6) is bonded to one O(2), one F(14), one F(17), one F(18), one F(3), and one F(9) atom to form MnOF5 octahedra that share corners with two equivalent Mn(12)O2F4 octahedra, corners with two equivalent Mn(10)OF5 octahedra, corners with four equivalent Mn(8)F6 octahedra,  an edgeedge with one Mn(3)O2F4 octahedra, and  an edgeedge with one Mn(4)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 48-63°. In the seventh Mn site, Mn(7) is bonded to one O(4), one F(13), one F(15), one F(2), one F(6), and one F(7) atom to form MnOF5 octahedra that share corners with two equivalent Mn(4)O2F4 octahedra, corners with two equivalent Mn(1)OF5 octahedra, corners with four equivalent Mn(5)OF5 octahedra,  an edgeedge with one Mn(12)O2F4 octahedra, and  an edgeedge with one Mn(11)OF5 octahedra. The corner-sharing octahedral tilt angles range from 43-59°. In the eighth Mn site, Mn(8) is bonded to one F(10), one F(14), one F(18), one F(3), one F(8), and one F(9) atom to form distorted MnF6 octahedra that share corners with two equivalent Mn(3)O2F4 octahedra, corners with two equivalent Mn(4)O2F4 octahedra, corners with four equivalent Mn(6)OF5 octahedra,  an edgeedge with one Mn(12)O2F4 octahedra, and  an edgeedge with one Mn(10)OF5 octahedra. The corner-sharing octahedral tilt angles range from 47-63°. In the ninth Mn site, Mn(9) is bonded to one O(3), one O(5), one F(1), one F(11), one F(12), and one F(5) atom to form MnO2F4 octahedra that share corners with two equivalent Mn(3)O2F4 octahedra, corners with two equivalent Mn(1)OF5 octahedra, corners with four equivalent Mn(2)OF5 octahedra,  an edgeedge with one Mn(10)OF5 octahedra, and  an edgeedge with one Mn(11)OF5 octahedra. The corner-sharing octahedral tilt angles range from 44-59°. In the tenth Mn site, Mn(10) is bonded to one O(3), one F(10), one F(11), one F(17), one F(4), and one F(9) atom to form MnOF5 octahedra that share corners with two equivalent Mn(2)OF5 octahedra, corners with two equivalent Mn(6)OF5 octahedra, corners with four equivalent Mn(3)O2F4 octahedra,  an edgeedge with one Mn(8)F6 octahedra, and  an edgeedge with one Mn(9)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 48-63°. In the eleventh Mn site, Mn(11) is bonded to one O(1), one F(12), one F(13), one F(16), one F(5), and one F(6) atom to form MnOF5 octahedra that share corners with two equivalent Mn(2)OF5 octahedra, corners with two equivalent Mn(5)OF5 octahedra, corners with four equivalent Mn(1)OF5 octahedra,  an edgeedge with one Mn(9)O2F4 octahedra, and  an edgeedge with one Mn(7)OF5 octahedra. The corner-sharing octahedral tilt angles range from 47-60°. In the twelfth Mn site, Mn(12) is bonded to one O(2), one O(4), one F(14), one F(19), one F(7), and one F(8) atom to form MnO2F4 octahedra that share corners with two equivalent Mn(5)OF5 octahedra, corners with two equivalent Mn(6)OF5 octahedra, corners with four equivalent Mn(4)O2F4 octahedra,  an edgeedge with one Mn(8)F6 octahedra, and  an edgeedge with one Mn(7)OF5 octahedra. The corner-sharing octahedral tilt angles range from 44-59°. There are five inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Mn(1), one Mn(11), and one Mn(5) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Mn(12), one Mn(4), and one Mn(6) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Mn(10), one Mn(3), and one Mn(9) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Mn(12), one Mn(4), and one Mn(7) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one Mn(2), one Mn(3), and one Mn(9) atom. There are nineteen inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(2), and one Mn(9) atom. In the second F site, F(2) is bonded in a trigonal planar geometry to one Mn(4), one Mn(5), and one Mn(7) atom. In the third F site, F(3) is bonded in a trigonal planar geometry to one Mn(3), one Mn(6), and one Mn(8) atom. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one Mn(10), one Mn(2), and one Mn(3) atom. In the fifth F site, F(5) is bonded in a trigonal planar geometry to one Mn(11), one Mn(2), and one Mn(9) atom. In the sixth F site, F(6) is bonded in a trigonal planar geometry to one Mn(1), one Mn(11), and one Mn(7) atom. In the seventh F site, F(7) is bonded in a distorted trigonal planar geometry to one Mn(12), one Mn(5), and one Mn(7) atom. In the eighth F site, F(8) is bonded in a trigonal planar geometry to one Mn(12), one Mn(4), and one Mn(8) atom. In the ninth F site, F(9) is bonded in a trigonal planar geometry to one Mn(10), one Mn(6), and one Mn(8) atom. In the tenth F site, F(10) is bonded in a trigonal planar geometry to one Mn(10), one Mn(3), and one Mn(8) atom. In the eleventh F site, F(11) is bonded in a distorted trigonal planar geometry to one Mn(10), one Mn(2), and one Mn(9) atom. In the twelfth F site, F(12) is bonded in a trigonal planar geometry to one Mn(1), one Mn(11), and one Mn(9) atom. In the thirteenth F site, F(13) is bonded in a trigonal planar geometry to one Mn(11), one Mn(5), and one Mn(7) atom. In the fourteenth F site, F(14) is bonded in a distorted trigonal planar geometry to one Mn(12), one Mn(6), and one Mn(8) atom. In the fifteenth F site, F(15) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(5), and one Mn(7) atom. In the sixteenth F site, F(16) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(11), and one Mn(2) atom. In the seventeenth F site, F(17) is bonded in a trigonal planar geometry to one Mn(10), one Mn(3), and one Mn(6) atom. In the eighteenth F site, F(18) is bonded in a trigonal planar geometry to one Mn(4), one Mn(6), and one Mn(8) atom. In the nineteenth F site, F(19) is bonded in a trigonal planar geometry to one Mn(12), one Mn(4), and one Mn(5) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mn12O5F19
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.810
_cell_length_b   5.812
_cell_length_c   16.109
_cell_angle_alpha   90.409
_cell_angle_beta   89.994
_cell_angle_gamma   92.271
_symmetry_Int_Tables_number   1
_cell_volume   449.999
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.015  0.854  0.581  1.0
  Mn  Mn1  1  0.991  0.149  0.751  1.0
  Mn  Mn2  1  0.011  0.827  0.906  1.0
  Mn  Mn3  1  0.994  0.846  0.252  1.0
  Mn  Mn4  1  0.014  0.169  0.425  1.0
  Mn  Mn5  1  0.016  0.158  0.090  1.0
  Mn  Mn6  1  0.521  0.664  0.406  1.0
  Mn  Mn7  1  0.485  0.672  0.083  1.0
  Mn  Mn8  1  0.505  0.672  0.761  1.0
  Mn  Mn9  1  0.505  0.351  0.916  1.0
  Mn  Mn10  1  0.482  0.338  0.582  1.0
  Mn  Mn11  1  0.499  0.340  0.248  1.0
  O  O12  1  0.222  0.102  0.534  1.0
  O  O13  1  0.224  0.105  0.202  1.0
  O  O14  1  0.290  0.623  0.862  1.0
  O  O15  1  0.722  0.611  0.295  1.0
  O  O16  1  0.789  0.875  0.806  1.0
  F  F17  1  0.238  0.888  0.690  1.0
  F  F18  1  0.210  0.877  0.361  1.0
  F  F19  1  0.221  0.887  0.018  1.0
  F  F20  1  0.244  0.120  0.856  1.0
  F  F21  1  0.273  0.404  0.698  1.0
  F  F22  1  0.263  0.609  0.522  1.0
  F  F23  1  0.276  0.382  0.355  1.0
  F  F24  1  0.242  0.606  0.191  1.0
  F  F25  1  0.267  0.388  0.026  1.0
  F  F26  1  0.747  0.610  0.979  1.0
  F  F27  1  0.738  0.385  0.806  1.0
  F  F28  1  0.731  0.625  0.640  1.0
  F  F29  1  0.719  0.392  0.473  1.0
  F  F30  1  0.705  0.376  0.138  1.0
  F  F31  1  0.767  0.882  0.479  1.0
  F  F32  1  0.763  0.115  0.640  1.0
  F  F33  1  0.779  0.106  0.972  1.0
  F  F34  1  0.774  0.885  0.143  1.0
  F  F35  1  0.756  0.108  0.313  1.0
[/CIF]
.