The crystal structure described by (CN2)2C2TeS4(NCl)2(NO)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four cyanamide molecules, four nitroxyl molecules, and two C2TeS4(NCl)2 clusters. In each C2TeS4(NCl)2 cluster, C(1) is bonded in a distorted linear geometry to one N(2) and one S(1) atom. N(2) is bonded in a single-bond geometry to one C(1) atom. Te(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent S(1) and two equivalent S(2) atoms. There are two inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one C(1) and one Te(1) atom. In the second S site, S(2) is bonded in a water-like geometry to one Te(1) and one Cl(1) atom. Cl(1) is bonded in a single-bond geometry to one S(2) atom. is represented by the CIF file [CIF]
data_TeC4S4N8(ClO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   14.461
_cell_length_b   7.920
_cell_length_c   12.126
_cell_angle_alpha   69.010
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1296.737
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.000  0.000  0.000  1.0
  Te  Te1  1  0.500  0.000  0.500  1.0
  C  C2  1  0.212  0.955  0.126  1.0
  C  C3  1  0.712  0.045  0.374  1.0
  C  C4  1  0.788  0.045  0.874  1.0
  C  C5  1  0.288  0.955  0.626  1.0
  C  C6  1  0.057  0.196  0.373  1.0
  C  C7  1  0.557  0.804  0.127  1.0
  C  C8  1  0.943  0.804  0.627  1.0
  C  C9  1  0.443  0.196  0.873  1.0
  S  S10  1  0.172  0.856  0.037  1.0
  S  S11  1  0.672  0.144  0.463  1.0
  S  S12  1  0.828  0.144  0.963  1.0
  S  S13  1  0.328  0.856  0.537  1.0
  S  S14  1  0.991  0.715  0.196  1.0
  S  S15  1  0.491  0.285  0.304  1.0
  S  S16  1  0.009  0.285  0.804  1.0
  S  S17  1  0.509  0.715  0.696  1.0
  N  N18  1  0.184  0.304  0.066  1.0
  N  N19  1  0.684  0.696  0.434  1.0
  N  N20  1  0.816  0.696  0.934  1.0
  N  N21  1  0.316  0.304  0.566  1.0
  N  N22  1  0.240  0.029  0.188  1.0
  N  N23  1  0.740  0.971  0.312  1.0
  N  N24  1  0.760  0.971  0.812  1.0
  N  N25  1  0.260  0.029  0.688  1.0
  N  N26  1  0.115  0.104  0.444  1.0
  N  N27  1  0.615  0.896  0.056  1.0
  N  N28  1  0.885  0.896  0.556  1.0
  N  N29  1  0.385  0.104  0.944  1.0
  N  N30  1  0.999  0.287  0.301  1.0
  N  N31  1  0.499  0.713  0.199  1.0
  N  N32  1  0.001  0.713  0.699  1.0
  N  N33  1  0.501  0.287  0.801  1.0
  Cl  Cl34  1  0.357  0.348  0.263  1.0
  Cl  Cl35  1  0.857  0.652  0.237  1.0
  Cl  Cl36  1  0.643  0.652  0.737  1.0
  Cl  Cl37  1  0.143  0.348  0.763  1.0
  O  O38  1  0.259  0.385  0.502  1.0
  O  O39  1  0.759  0.615  0.998  1.0
  O  O40  1  0.741  0.615  0.498  1.0
  O  O41  1  0.241  0.385  0.002  1.0
[/CIF]
.
The crystal structure described by (CN2)2C2TeS4(NCl)2(NO)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four cyanamide molecules, four nitroxyl molecules, and two C2TeS4(NCl)2 clusters. In each C2TeS4(NCl)2 cluster, C(1) is bonded in a distorted linear geometry to one N(2) and one S(1) atom. N(2) is bonded in a single-bond geometry to one C(1) atom. Te(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent S(1) and two equivalent S(2) atoms. There are two inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one C(1) and one Te(1) atom. In the second S site, S(2) is bonded in a water-like geometry to one Te(1) and one Cl(1) atom. Cl(1) is bonded in a single-bond geometry to one S(2) atom. is represented by the CIF file [CIF]
data_TeC4S4N8(ClO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   14.461
_cell_length_b   7.920
_cell_length_c   12.126
_cell_angle_alpha   69.010
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1296.737
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.000  0.000  0.000  1.0
  Te  Te1  1  0.500  0.000  0.500  1.0
  C  C2  1  0.212  0.955  0.126  1.0
  C  C3  1  0.712  0.045  0.374  1.0
  C  C4  1  0.788  0.045  0.874  1.0
  C  C5  1  0.288  0.955  0.626  1.0
  C  C6  1  0.057  0.196  0.373  1.0
  C  C7  1  0.557  0.804  0.127  1.0
  C  C8  1  0.943  0.804  0.627  1.0
  C  C9  1  0.443  0.196  0.873  1.0
  S  S10  1  0.172  0.856  0.037  1.0
  S  S11  1  0.672  0.144  0.463  1.0
  S  S12  1  0.828  0.144  0.963  1.0
  S  S13  1  0.328  0.856  0.537  1.0
  S  S14  1  0.991  0.715  0.196  1.0
  S  S15  1  0.491  0.285  0.304  1.0
  S  S16  1  0.009  0.285  0.804  1.0
  S  S17  1  0.509  0.715  0.696  1.0
  N  N18  1  0.184  0.304  0.066  1.0
  N  N19  1  0.684  0.696  0.434  1.0
  N  N20  1  0.816  0.696  0.934  1.0
  N  N21  1  0.316  0.304  0.566  1.0
  N  N22  1  0.240  0.029  0.188  1.0
  N  N23  1  0.740  0.971  0.312  1.0
  N  N24  1  0.760  0.971  0.812  1.0
  N  N25  1  0.260  0.029  0.688  1.0
  N  N26  1  0.115  0.104  0.444  1.0
  N  N27  1  0.615  0.896  0.056  1.0
  N  N28  1  0.885  0.896  0.556  1.0
  N  N29  1  0.385  0.104  0.944  1.0
  N  N30  1  0.999  0.287  0.301  1.0
  N  N31  1  0.499  0.713  0.199  1.0
  N  N32  1  0.001  0.713  0.699  1.0
  N  N33  1  0.501  0.287  0.801  1.0
  Cl  Cl34  1  0.357  0.348  0.263  1.0
  Cl  Cl35  1  0.857  0.652  0.237  1.0
  Cl  Cl36  1  0.643  0.652  0.737  1.0
  Cl  Cl37  1  0.143  0.348  0.763  1.0
  O  O38  1  0.259  0.385  0.502  1.0
  O  O39  1  0.759  0.615  0.998  1.0
  O  O40  1  0.741  0.615  0.498  1.0
  O  O41  1  0.241  0.385  0.002  1.0
[/CIF]
.