The material structure described by N2SbF5 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight ammonia atoms and four SbF5 clusters. In each SbF5 cluster, Sb(1) is bonded in a distorted trigonal bipyramidal geometry to one F(1), two equivalent F(2), and two equivalent F(3) atoms. There are three inequivalent F sites. In the first F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the CIF card [CIF]
data_SbN2F5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.204
_cell_length_b   8.204
_cell_length_c   6.836
_cell_angle_alpha   89.712
_cell_angle_beta   89.712
_cell_angle_gamma   133.897
_symmetry_Int_Tables_number   1
_cell_volume   331.551
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.875  0.125  0.750  1.0
  Sb  Sb1  1  0.125  0.875  0.250  1.0
  N  N2  1  0.442  0.558  0.250  1.0
  N  N3  1  0.558  0.442  0.750  1.0
  N  N4  1  0.244  0.756  0.750  1.0
  N  N5  1  0.756  0.244  0.250  1.0
  F  F6  1  0.751  0.249  0.750  1.0
  F  F7  1  0.249  0.751  0.250  1.0
  F  F8  1  0.134  0.333  0.588  1.0
  F  F9  1  0.667  0.866  0.912  1.0
  F  F10  1  0.866  0.667  0.412  1.0
  F  F11  1  0.333  0.134  0.088  1.0
  F  F12  1  0.071  0.263  0.967  1.0
  F  F13  1  0.737  0.929  0.533  1.0
  F  F14  1  0.929  0.737  0.033  1.0
  F  F15  1  0.263  0.071  0.467  1.0
[/CIF]
.
The material structure described by N2SbF5 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight ammonia atoms and four SbF5 clusters. In each SbF5 cluster, Sb(1) is bonded in a distorted trigonal bipyramidal geometry to one F(1), two equivalent F(2), and two equivalent F(3) atoms. There are three inequivalent F sites. In the first F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the CIF card [CIF]
data_SbN2F5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.204
_cell_length_b   8.204
_cell_length_c   6.836
_cell_angle_alpha   89.712
_cell_angle_beta   89.712
_cell_angle_gamma   133.897
_symmetry_Int_Tables_number   1
_cell_volume   331.551
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.875  0.125  0.750  1.0
  Sb  Sb1  1  0.125  0.875  0.250  1.0
  N  N2  1  0.442  0.558  0.250  1.0
  N  N3  1  0.558  0.442  0.750  1.0
  N  N4  1  0.244  0.756  0.750  1.0
  N  N5  1  0.756  0.244  0.250  1.0
  F  F6  1  0.751  0.249  0.750  1.0
  F  F7  1  0.249  0.751  0.250  1.0
  F  F8  1  0.134  0.333  0.588  1.0
  F  F9  1  0.667  0.866  0.912  1.0
  F  F10  1  0.866  0.667  0.412  1.0
  F  F11  1  0.333  0.134  0.088  1.0
  F  F12  1  0.071  0.263  0.967  1.0
  F  F13  1  0.737  0.929  0.533  1.0
  F  F14  1  0.929  0.737  0.033  1.0
  F  F15  1  0.263  0.071  0.467  1.0
[/CIF]
.