The material structure described by V3Ag2TeS6 crystallizes in the hexagonal P-62m space group. V(1) is bonded to two equivalent S(2) and four equivalent S(1) atoms to form distorted VS6 pentagonal pyramids that share corners with two equivalent Te(1)Ag6S2 hexagonal bipyramids and edges with six equivalent V(1)S6 pentagonal pyramids. Ag(1) is bonded in a distorted linear geometry to three equivalent Te(1) and two equivalent S(1) atoms. Te(1) is bonded to six equivalent Ag(1) and two equivalent S(2) atoms to form distorted TeAg6S2 hexagonal bipyramids that share corners with six equivalent V(1)S6 pentagonal pyramids and edges with six equivalent Te(1)Ag6S2 hexagonal bipyramids. There are two inequivalent S sites. In the first S site, S(1) is bonded in a rectangular see-saw-like geometry to three equivalent V(1) and one Ag(1) atom. In the second S site, S(2) is bonded in a rectangular see-saw-like geometry to three equivalent V(1) and one Te(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_V3Ag2TeS6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.537
_cell_length_b   5.537
_cell_length_c   8.033
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   213.289
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.659  0.659  0.500  1.0
  V  V1  1  0.341  1.000  0.500  1.0
  V  V2  1  0.000  0.341  0.500  1.0
  Ag  Ag3  1  0.667  0.333  1.000  1.0
  Ag  Ag4  1  0.333  0.667  1.000  1.0
  Te  Te5  1  0.000  0.000  1.000  1.0
  S  S6  1  0.333  0.667  0.683  1.0
  S  S7  1  0.333  0.667  0.317  1.0
  S  S8  1  0.667  0.333  0.683  1.0
  S  S9  1  0.667  0.333  0.317  1.0
  S  S10  1  1.000  1.000  0.672  1.0
  S  S11  1  1.000  1.000  0.328  1.0
[/CIF]
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The material structure described by V3Ag2TeS6 crystallizes in the hexagonal P-62m space group. V(1) is bonded to two equivalent S(2) and four equivalent S(1) atoms to form distorted VS6 pentagonal pyramids that share corners with two equivalent Te(1)Ag6S2 hexagonal bipyramids and edges with six equivalent V(1)S6 pentagonal pyramids. Ag(1) is bonded in a distorted linear geometry to three equivalent Te(1) and two equivalent S(1) atoms. Te(1) is bonded to six equivalent Ag(1) and two equivalent S(2) atoms to form distorted TeAg6S2 hexagonal bipyramids that share corners with six equivalent V(1)S6 pentagonal pyramids and edges with six equivalent Te(1)Ag6S2 hexagonal bipyramids. There are two inequivalent S sites. In the first S site, S(1) is bonded in a rectangular see-saw-like geometry to three equivalent V(1) and one Ag(1) atom. In the second S site, S(2) is bonded in a rectangular see-saw-like geometry to three equivalent V(1) and one Te(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_V3Ag2TeS6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.537
_cell_length_b   5.537
_cell_length_c   8.033
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   213.289
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.659  0.659  0.500  1.0
  V  V1  1  0.341  1.000  0.500  1.0
  V  V2  1  0.000  0.341  0.500  1.0
  Ag  Ag3  1  0.667  0.333  1.000  1.0
  Ag  Ag4  1  0.333  0.667  1.000  1.0
  Te  Te5  1  0.000  0.000  1.000  1.0
  S  S6  1  0.333  0.667  0.683  1.0
  S  S7  1  0.333  0.667  0.317  1.0
  S  S8  1  0.667  0.333  0.683  1.0
  S  S9  1  0.667  0.333  0.317  1.0
  S  S10  1  1.000  1.000  0.672  1.0
  S  S11  1  1.000  1.000  0.328  1.0
[/CIF]
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