The material described by CoN4ClN2SnCl4 is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 7727-37-9 molecules, four tin tetrachloride molecules, and four CoN4Cl clusters. In each CoN4Cl cluster, Co(1) is bonded in a tetrahedral geometry to one N(1), one N(3), one N(5), and one N(6) atom. There are four inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Co(1) and one Cl(5) atom. In the second N site, N(3) is bonded in a single-bond geometry to one Co(1) atom. In the third N site, N(5) is bonded in a single-bond geometry to one Co(1) atom. In the fourth N site, N(6) is bonded in a single-bond geometry to one Co(1) atom. Cl(5) is bonded in a single-bond geometry to one N(1) atom. is represented by the CIF card [CIF]
data_CoSnN6Cl5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   23.718
_cell_length_b   8.290
_cell_length_c   8.859
_cell_angle_alpha   81.253
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1721.603
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.094  0.072  0.653  1.0
  Co  Co1  1  0.594  0.928  0.847  1.0
  Co  Co2  1  0.906  0.928  0.347  1.0
  Co  Co3  1  0.406  0.072  0.153  1.0
  Sn  Sn4  1  0.394  0.657  0.687  1.0
  Sn  Sn5  1  0.894  0.343  0.813  1.0
  Sn  Sn6  1  0.606  0.343  0.313  1.0
  Sn  Sn7  1  0.106  0.657  0.187  1.0
  N  N8  1  0.096  0.115  0.440  1.0
  N  N9  1  0.596  0.885  0.060  1.0
  N  N10  1  0.904  0.885  0.560  1.0
  N  N11  1  0.404  0.115  0.940  1.0
  N  N12  1  0.182  0.341  0.857  1.0
  N  N13  1  0.682  0.659  0.643  1.0
  N  N14  1  0.818  0.659  0.143  1.0
  N  N15  1  0.318  0.341  0.357  1.0
  N  N16  1  0.072  0.239  0.717  1.0
  N  N17  1  0.572  0.761  0.783  1.0
  N  N18  1  0.928  0.761  0.283  1.0
  N  N19  1  0.428  0.239  0.217  1.0
  N  N20  1  0.200  0.388  0.743  1.0
  N  N21  1  0.700  0.612  0.757  1.0
  N  N22  1  0.800  0.612  0.257  1.0
  N  N23  1  0.300  0.388  0.243  1.0
  N  N24  1  0.158  0.027  0.702  1.0
  N  N25  1  0.658  0.973  0.798  1.0
  N  N26  1  0.842  0.973  0.298  1.0
  N  N27  1  0.342  0.027  0.202  1.0
  N  N28  1  0.050  0.925  0.693  1.0
  N  N29  1  0.550  0.075  0.807  1.0
  N  N30  1  0.950  0.075  0.307  1.0
  N  N31  1  0.450  0.925  0.193  1.0
  Cl  Cl32  1  0.379  0.633  0.948  1.0
  Cl  Cl33  1  0.879  0.367  0.552  1.0
  Cl  Cl34  1  0.621  0.367  0.052  1.0
  Cl  Cl35  1  0.121  0.633  0.448  1.0
  Cl  Cl36  1  0.439  0.903  0.608  1.0
  Cl  Cl37  1  0.939  0.097  0.892  1.0
  Cl  Cl38  1  0.561  0.097  0.392  1.0
  Cl  Cl39  1  0.061  0.903  0.108  1.0
  Cl  Cl40  1  0.447  0.438  0.635  1.0
  Cl  Cl41  1  0.947  0.562  0.865  1.0
  Cl  Cl42  1  0.553  0.562  0.365  1.0
  Cl  Cl43  1  0.053  0.438  0.135  1.0
  Cl  Cl44  1  0.192  0.659  0.063  1.0
  Cl  Cl45  1  0.692  0.341  0.437  1.0
  Cl  Cl46  1  0.808  0.341  0.937  1.0
  Cl  Cl47  1  0.308  0.659  0.563  1.0
  Cl  Cl48  1  0.346  0.193  0.864  1.0
  Cl  Cl49  1  0.846  0.807  0.636  1.0
  Cl  Cl50  1  0.654  0.807  0.136  1.0
  Cl  Cl51  1  0.154  0.193  0.364  1.0
[/CIF]
.
The material described by CoN4ClN2SnCl4 is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 7727-37-9 molecules, four tin tetrachloride molecules, and four CoN4Cl clusters. In each CoN4Cl cluster, Co(1) is bonded in a tetrahedral geometry to one N(1), one N(3), one N(5), and one N(6) atom. There are four inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Co(1) and one Cl(5) atom. In the second N site, N(3) is bonded in a single-bond geometry to one Co(1) atom. In the third N site, N(5) is bonded in a single-bond geometry to one Co(1) atom. In the fourth N site, N(6) is bonded in a single-bond geometry to one Co(1) atom. Cl(5) is bonded in a single-bond geometry to one N(1) atom. is represented by the CIF card [CIF]
data_CoSnN6Cl5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   23.718
_cell_length_b   8.290
_cell_length_c   8.859
_cell_angle_alpha   81.253
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1721.603
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.094  0.072  0.653  1.0
  Co  Co1  1  0.594  0.928  0.847  1.0
  Co  Co2  1  0.906  0.928  0.347  1.0
  Co  Co3  1  0.406  0.072  0.153  1.0
  Sn  Sn4  1  0.394  0.657  0.687  1.0
  Sn  Sn5  1  0.894  0.343  0.813  1.0
  Sn  Sn6  1  0.606  0.343  0.313  1.0
  Sn  Sn7  1  0.106  0.657  0.187  1.0
  N  N8  1  0.096  0.115  0.440  1.0
  N  N9  1  0.596  0.885  0.060  1.0
  N  N10  1  0.904  0.885  0.560  1.0
  N  N11  1  0.404  0.115  0.940  1.0
  N  N12  1  0.182  0.341  0.857  1.0
  N  N13  1  0.682  0.659  0.643  1.0
  N  N14  1  0.818  0.659  0.143  1.0
  N  N15  1  0.318  0.341  0.357  1.0
  N  N16  1  0.072  0.239  0.717  1.0
  N  N17  1  0.572  0.761  0.783  1.0
  N  N18  1  0.928  0.761  0.283  1.0
  N  N19  1  0.428  0.239  0.217  1.0
  N  N20  1  0.200  0.388  0.743  1.0
  N  N21  1  0.700  0.612  0.757  1.0
  N  N22  1  0.800  0.612  0.257  1.0
  N  N23  1  0.300  0.388  0.243  1.0
  N  N24  1  0.158  0.027  0.702  1.0
  N  N25  1  0.658  0.973  0.798  1.0
  N  N26  1  0.842  0.973  0.298  1.0
  N  N27  1  0.342  0.027  0.202  1.0
  N  N28  1  0.050  0.925  0.693  1.0
  N  N29  1  0.550  0.075  0.807  1.0
  N  N30  1  0.950  0.075  0.307  1.0
  N  N31  1  0.450  0.925  0.193  1.0
  Cl  Cl32  1  0.379  0.633  0.948  1.0
  Cl  Cl33  1  0.879  0.367  0.552  1.0
  Cl  Cl34  1  0.621  0.367  0.052  1.0
  Cl  Cl35  1  0.121  0.633  0.448  1.0
  Cl  Cl36  1  0.439  0.903  0.608  1.0
  Cl  Cl37  1  0.939  0.097  0.892  1.0
  Cl  Cl38  1  0.561  0.097  0.392  1.0
  Cl  Cl39  1  0.061  0.903  0.108  1.0
  Cl  Cl40  1  0.447  0.438  0.635  1.0
  Cl  Cl41  1  0.947  0.562  0.865  1.0
  Cl  Cl42  1  0.553  0.562  0.365  1.0
  Cl  Cl43  1  0.053  0.438  0.135  1.0
  Cl  Cl44  1  0.192  0.659  0.063  1.0
  Cl  Cl45  1  0.692  0.341  0.437  1.0
  Cl  Cl46  1  0.808  0.341  0.937  1.0
  Cl  Cl47  1  0.308  0.659  0.563  1.0
  Cl  Cl48  1  0.346  0.193  0.864  1.0
  Cl  Cl49  1  0.846  0.807  0.636  1.0
  Cl  Cl50  1  0.654  0.807  0.136  1.0
  Cl  Cl51  1  0.154  0.193  0.364  1.0
[/CIF]
.