The crystal structure described by WAgZn2O6 crystallizes in the triclinic P1 space group. W(1) is bonded in an octahedral geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. Ag(1) is bonded in a square co-planar geometry to one O(1), one O(2), one O(3), and one O(6) atom. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(3), one O(5), and one O(6) atom. In the second Zn site, Zn(2) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(3), one O(4), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded to one W(1), one Ag(1), one Zn(1), and one Zn(2) atom to form a mixture of distorted edge and corner-sharing OZn2AgW tetrahedra. In the second O site, O(2) is bonded to one W(1), one Ag(1), one Zn(1), and one Zn(2) atom to form a mixture of distorted edge and corner-sharing OZn2AgW tetrahedra. In the third O site, O(3) is bonded to one W(1), one Ag(1), one Zn(1), and one Zn(2) atom to form a mixture of edge and corner-sharing OZn2AgW tetrahedra. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one W(1) and one Zn(2) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one W(1) and one Zn(1) atom. In the sixth O site, O(6) is bonded to one W(1), one Ag(1), one Zn(1), and one Zn(2) atom to form a mixture of edge and corner-sharing OZn2AgW tetrahedra. is represented by the CIF card [CIF]
data_Zn2AgWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.885
_cell_length_b   6.019
_cell_length_c   7.496
_cell_angle_alpha   87.855
_cell_angle_beta   128.678
_cell_angle_gamma   129.348
_symmetry_Int_Tables_number   1
_cell_volume   128.908
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.067  0.556  0.244  1.0
  Zn  Zn1  1  0.922  0.402  0.752  1.0
  Ag  Ag2  1  0.994  0.980  0.498  1.0
  W  W3  1  0.995  0.980  0.998  1.0
  O  O4  1  0.237  0.022  0.352  1.0
  O  O5  1  0.752  0.939  0.644  1.0
  O  O6  1  0.254  0.442  0.142  1.0
  O  O7  1  0.438  0.747  0.837  1.0
  O  O8  1  0.555  0.216  0.162  1.0
  O  O9  1  0.736  0.519  0.854  1.0
[/CIF]
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The crystal structure described by WAgZn2O6 crystallizes in the triclinic P1 space group. W(1) is bonded in an octahedral geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. Ag(1) is bonded in a square co-planar geometry to one O(1), one O(2), one O(3), and one O(6) atom. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(3), one O(5), and one O(6) atom. In the second Zn site, Zn(2) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(3), one O(4), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded to one W(1), one Ag(1), one Zn(1), and one Zn(2) atom to form a mixture of distorted edge and corner-sharing OZn2AgW tetrahedra. In the second O site, O(2) is bonded to one W(1), one Ag(1), one Zn(1), and one Zn(2) atom to form a mixture of distorted edge and corner-sharing OZn2AgW tetrahedra. In the third O site, O(3) is bonded to one W(1), one Ag(1), one Zn(1), and one Zn(2) atom to form a mixture of edge and corner-sharing OZn2AgW tetrahedra. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one W(1) and one Zn(2) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one W(1) and one Zn(1) atom. In the sixth O site, O(6) is bonded to one W(1), one Ag(1), one Zn(1), and one Zn(2) atom to form a mixture of edge and corner-sharing OZn2AgW tetrahedra. is represented by the CIF card [CIF]
data_Zn2AgWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.885
_cell_length_b   6.019
_cell_length_c   7.496
_cell_angle_alpha   87.855
_cell_angle_beta   128.678
_cell_angle_gamma   129.348
_symmetry_Int_Tables_number   1
_cell_volume   128.908
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.067  0.556  0.244  1.0
  Zn  Zn1  1  0.922  0.402  0.752  1.0
  Ag  Ag2  1  0.994  0.980  0.498  1.0
  W  W3  1  0.995  0.980  0.998  1.0
  O  O4  1  0.237  0.022  0.352  1.0
  O  O5  1  0.752  0.939  0.644  1.0
  O  O6  1  0.254  0.442  0.142  1.0
  O  O7  1  0.438  0.747  0.837  1.0
  O  O8  1  0.555  0.216  0.162  1.0
  O  O9  1  0.736  0.519  0.854  1.0
[/CIF]
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