The material structure described by VF3 crystallizes in the triclinic P-1 space group. There are two inequivalent V sites. In the first V site, V(1) is bonded to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form corner-sharing VF6 octahedra. The corner-sharing octahedral tilt angles are 37°. In the second V site, V(2) is bonded to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form corner-sharing VF6 octahedra. The corner-sharing octahedral tilt angles are 37°. There are three inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to one V(1) and one V(2) atom. In the second F site, F(2) is bonded in a bent 150 degrees geometry to one V(1) and one V(2) atom. In the third F site, F(3) is bonded in a bent 150 degrees geometry to one V(1) and one V(2) atom. is represented by the CIF card [CIF]
data_VF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.407
_cell_length_b   7.367
_cell_length_c   5.344
_cell_angle_alpha   136.635
_cell_angle_beta   151.549
_cell_angle_gamma   34.191
_symmetry_Int_Tables_number   1
_cell_volume   99.160
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  1.000  0.500  0.000  1.0
  V  V1  1  0.000  1.000  1.000  1.0
  F  F2  1  0.505  0.370  0.634  1.0
  F  F3  1  0.120  0.250  0.239  1.0
  F  F4  1  0.128  0.130  0.632  1.0
  F  F5  1  0.495  0.630  0.366  1.0
  F  F6  1  0.880  0.750  0.761  1.0
  F  F7  1  0.872  0.870  0.368  1.0
[/CIF]
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The material structure described by VF3 crystallizes in the triclinic P-1 space group. There are two inequivalent V sites. In the first V site, V(1) is bonded to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form corner-sharing VF6 octahedra. The corner-sharing octahedral tilt angles are 37°. In the second V site, V(2) is bonded to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form corner-sharing VF6 octahedra. The corner-sharing octahedral tilt angles are 37°. There are three inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to one V(1) and one V(2) atom. In the second F site, F(2) is bonded in a bent 150 degrees geometry to one V(1) and one V(2) atom. In the third F site, F(3) is bonded in a bent 150 degrees geometry to one V(1) and one V(2) atom. is represented by the CIF card [CIF]
data_VF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.407
_cell_length_b   7.367
_cell_length_c   5.344
_cell_angle_alpha   136.635
_cell_angle_beta   151.549
_cell_angle_gamma   34.191
_symmetry_Int_Tables_number   1
_cell_volume   99.160
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  1.000  0.500  0.000  1.0
  V  V1  1  0.000  1.000  1.000  1.0
  F  F2  1  0.505  0.370  0.634  1.0
  F  F3  1  0.120  0.250  0.239  1.0
  F  F4  1  0.128  0.130  0.632  1.0
  F  F5  1  0.495  0.630  0.366  1.0
  F  F6  1  0.880  0.750  0.761  1.0
  F  F7  1  0.872  0.870  0.368  1.0
[/CIF]
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