The structure described by CdSn2H12(OF)6 crystallizes in the triclinic P-1 space group. Cd(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. Sn(1) is bonded in a distorted T-shaped geometry to one F(1), one F(2), and one F(3) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one O(2) and one F(1) atom. In the second H site, H(2) is bonded in a distorted single-bond geometry to one O(1) and one F(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(1) and one F(2) atom. In the fourth H site, H(4) is bonded in a distorted single-bond geometry to one O(2) and one F(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(3) and one F(2) atom. In the sixth H site, H(6) is bonded in a distorted single-bond geometry to one O(3) and one F(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Cd(1), one H(2), and one H(3) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Cd(1), one H(1), and one H(4) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one Cd(1), one H(5), and one H(6) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a 3-coordinate geometry to one Sn(1), one H(1), and one H(2) atom. In the second F site, F(2) is bonded in a 3-coordinate geometry to one Sn(1), one H(3), and one H(5) atom. In the third F site, F(3) is bonded in a 3-coordinate geometry to one Sn(1), one H(4), and one H(6) atom. is represented by the CIF file [CIF]
data_CdSn2H12(OF)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.711
_cell_length_b   7.038
_cell_length_c   7.064
_cell_angle_alpha   78.007
_cell_angle_beta   79.177
_cell_angle_gamma   70.344
_symmetry_Int_Tables_number   1
_cell_volume   304.814
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.000  0.000  0.000  1.0
  Sn  Sn1  1  0.655  0.665  0.622  1.0
  Sn  Sn2  1  0.345  0.335  0.378  1.0
  H  H3  1  0.637  0.898  0.197  1.0
  H  H4  1  0.270  0.899  0.297  1.0
  H  H5  1  0.094  0.785  0.382  1.0
  H  H6  1  0.738  0.732  0.054  1.0
  H  H7  1  0.131  0.709  0.732  1.0
  H  H8  1  0.264  0.615  0.915  1.0
  H  H9  1  0.736  0.385  0.085  1.0
  H  H10  1  0.869  0.291  0.268  1.0
  H  H11  1  0.262  0.268  0.946  1.0
  H  H12  1  0.906  0.215  0.618  1.0
  H  H13  1  0.730  0.101  0.703  1.0
  H  H14  1  0.363  0.102  0.803  1.0
  O  O15  1  0.188  0.820  0.263  1.0
  O  O16  1  0.773  0.809  0.139  1.0
  O  O17  1  0.223  0.738  0.812  1.0
  O  O18  1  0.777  0.262  0.188  1.0
  O  O19  1  0.227  0.191  0.861  1.0
  O  O20  1  0.812  0.180  0.737  1.0
  F  F21  1  0.577  0.973  0.678  1.0
  F  F22  1  0.976  0.686  0.586  1.0
  F  F23  1  0.684  0.591  0.924  1.0
  F  F24  1  0.316  0.409  0.076  1.0
  F  F25  1  0.024  0.314  0.414  1.0
  F  F26  1  0.423  0.027  0.322  1.0
[/CIF]
.
The structure described by CdSn2H12(OF)6 crystallizes in the triclinic P-1 space group. Cd(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. Sn(1) is bonded in a distorted T-shaped geometry to one F(1), one F(2), and one F(3) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one O(2) and one F(1) atom. In the second H site, H(2) is bonded in a distorted single-bond geometry to one O(1) and one F(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(1) and one F(2) atom. In the fourth H site, H(4) is bonded in a distorted single-bond geometry to one O(2) and one F(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(3) and one F(2) atom. In the sixth H site, H(6) is bonded in a distorted single-bond geometry to one O(3) and one F(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Cd(1), one H(2), and one H(3) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Cd(1), one H(1), and one H(4) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one Cd(1), one H(5), and one H(6) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a 3-coordinate geometry to one Sn(1), one H(1), and one H(2) atom. In the second F site, F(2) is bonded in a 3-coordinate geometry to one Sn(1), one H(3), and one H(5) atom. In the third F site, F(3) is bonded in a 3-coordinate geometry to one Sn(1), one H(4), and one H(6) atom. is represented by the CIF file [CIF]
data_CdSn2H12(OF)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.711
_cell_length_b   7.038
_cell_length_c   7.064
_cell_angle_alpha   78.007
_cell_angle_beta   79.177
_cell_angle_gamma   70.344
_symmetry_Int_Tables_number   1
_cell_volume   304.814
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.000  0.000  0.000  1.0
  Sn  Sn1  1  0.655  0.665  0.622  1.0
  Sn  Sn2  1  0.345  0.335  0.378  1.0
  H  H3  1  0.637  0.898  0.197  1.0
  H  H4  1  0.270  0.899  0.297  1.0
  H  H5  1  0.094  0.785  0.382  1.0
  H  H6  1  0.738  0.732  0.054  1.0
  H  H7  1  0.131  0.709  0.732  1.0
  H  H8  1  0.264  0.615  0.915  1.0
  H  H9  1  0.736  0.385  0.085  1.0
  H  H10  1  0.869  0.291  0.268  1.0
  H  H11  1  0.262  0.268  0.946  1.0
  H  H12  1  0.906  0.215  0.618  1.0
  H  H13  1  0.730  0.101  0.703  1.0
  H  H14  1  0.363  0.102  0.803  1.0
  O  O15  1  0.188  0.820  0.263  1.0
  O  O16  1  0.773  0.809  0.139  1.0
  O  O17  1  0.223  0.738  0.812  1.0
  O  O18  1  0.777  0.262  0.188  1.0
  O  O19  1  0.227  0.191  0.861  1.0
  O  O20  1  0.812  0.180  0.737  1.0
  F  F21  1  0.577  0.973  0.678  1.0
  F  F22  1  0.976  0.686  0.586  1.0
  F  F23  1  0.684  0.591  0.924  1.0
  F  F24  1  0.316  0.409  0.076  1.0
  F  F25  1  0.024  0.314  0.414  1.0
  F  F26  1  0.423  0.027  0.322  1.0
[/CIF]
.