The material structure described by NaSb3F10 crystallizes in the hexagonal P6_3 space group. Na(1) is bonded in an octahedral geometry to three equivalent F(2) and three equivalent F(3) atoms. Sb(1) is bonded in a 5-coordinate geometry to one F(1), one F(2), one F(3), and two equivalent F(4) atoms. There are four inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to three equivalent Sb(1) atoms. In the second F site, F(2) is bonded in a bent 120 degrees geometry to one Na(1) and one Sb(1) atom. In the third F site, F(3) is bonded in a distorted bent 150 degrees geometry to one Na(1) and one Sb(1) atom. In the fourth F site, F(4) is bonded in a distorted bent 150 degrees geometry to two equivalent Sb(1) atoms. is represented by the CIF card [CIF]
data_NaSb3F10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.154
_cell_length_b   8.154
_cell_length_c   7.548
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.003
_symmetry_Int_Tables_number   1
_cell_volume   434.626
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.667  0.333  0.665  1.0
  Na  Na1  1  0.333  0.667  0.165  1.0
  Sb  Sb2  1  0.122  0.782  0.748  1.0
  Sb  Sb3  1  0.339  0.122  0.248  1.0
  Sb  Sb4  1  0.782  0.661  0.248  1.0
  Sb  Sb5  1  0.218  0.339  0.748  1.0
  Sb  Sb6  1  0.661  0.878  0.748  1.0
  Sb  Sb7  1  0.878  0.218  0.248  1.0
  F  F8  1  0.333  0.667  0.739  1.0
  F  F9  1  0.667  0.333  0.239  1.0
  F  F10  1  0.965  0.505  0.783  1.0
  F  F11  1  0.459  0.965  0.283  1.0
  F  F12  1  0.505  0.541  0.283  1.0
  F  F13  1  0.495  0.459  0.783  1.0
  F  F14  1  0.541  0.035  0.783  1.0
  F  F15  1  0.035  0.495  0.283  1.0
  F  F16  1  0.201  0.395  0.996  1.0
  F  F17  1  0.807  0.201  0.496  1.0
  F  F18  1  0.395  0.193  0.496  1.0
  F  F19  1  0.605  0.807  0.996  1.0
  F  F20  1  0.193  0.799  0.996  1.0
  F  F21  1  0.799  0.605  0.496  1.0
  F  F22  1  0.112  0.224  0.340  1.0
  F  F23  1  0.888  0.112  0.840  1.0
  F  F24  1  0.224  0.112  0.840  1.0
  F  F25  1  0.776  0.888  0.340  1.0
  F  F26  1  0.112  0.888  0.340  1.0
  F  F27  1  0.888  0.776  0.840  1.0
[/CIF]
.
The material structure described by NaSb3F10 crystallizes in the hexagonal P6_3 space group. Na(1) is bonded in an octahedral geometry to three equivalent F(2) and three equivalent F(3) atoms. Sb(1) is bonded in a 5-coordinate geometry to one F(1), one F(2), one F(3), and two equivalent F(4) atoms. There are four inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to three equivalent Sb(1) atoms. In the second F site, F(2) is bonded in a bent 120 degrees geometry to one Na(1) and one Sb(1) atom. In the third F site, F(3) is bonded in a distorted bent 150 degrees geometry to one Na(1) and one Sb(1) atom. In the fourth F site, F(4) is bonded in a distorted bent 150 degrees geometry to two equivalent Sb(1) atoms. is represented by the CIF card [CIF]
data_NaSb3F10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.154
_cell_length_b   8.154
_cell_length_c   7.548
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.003
_symmetry_Int_Tables_number   1
_cell_volume   434.626
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.667  0.333  0.665  1.0
  Na  Na1  1  0.333  0.667  0.165  1.0
  Sb  Sb2  1  0.122  0.782  0.748  1.0
  Sb  Sb3  1  0.339  0.122  0.248  1.0
  Sb  Sb4  1  0.782  0.661  0.248  1.0
  Sb  Sb5  1  0.218  0.339  0.748  1.0
  Sb  Sb6  1  0.661  0.878  0.748  1.0
  Sb  Sb7  1  0.878  0.218  0.248  1.0
  F  F8  1  0.333  0.667  0.739  1.0
  F  F9  1  0.667  0.333  0.239  1.0
  F  F10  1  0.965  0.505  0.783  1.0
  F  F11  1  0.459  0.965  0.283  1.0
  F  F12  1  0.505  0.541  0.283  1.0
  F  F13  1  0.495  0.459  0.783  1.0
  F  F14  1  0.541  0.035  0.783  1.0
  F  F15  1  0.035  0.495  0.283  1.0
  F  F16  1  0.201  0.395  0.996  1.0
  F  F17  1  0.807  0.201  0.496  1.0
  F  F18  1  0.395  0.193  0.496  1.0
  F  F19  1  0.605  0.807  0.996  1.0
  F  F20  1  0.193  0.799  0.996  1.0
  F  F21  1  0.799  0.605  0.496  1.0
  F  F22  1  0.112  0.224  0.340  1.0
  F  F23  1  0.888  0.112  0.840  1.0
  F  F24  1  0.224  0.112  0.840  1.0
  F  F25  1  0.776  0.888  0.340  1.0
  F  F26  1  0.112  0.888  0.340  1.0
  F  F27  1  0.888  0.776  0.840  1.0
[/CIF]
.