The crystal structure described by KGd(MoO4)2 crystallizes in the triclinic P-1 space group. K(1) is bonded in a 8-coordinate geometry to one O(4), one O(5), two equivalent O(1), two equivalent O(7), and two equivalent O(8) atoms. Gd(1) is bonded in a 7-coordinate geometry to one O(3), one O(4), one O(5), two equivalent O(2), and two equivalent O(6) atoms. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 2-coordinate geometry to one O(1), one O(2), one O(3), one O(4), and one O(6) atom. In the second Mo site, Mo(2) is bonded in a 1-coordinate geometry to one O(1), one O(5), one O(6), one O(7), and one O(8) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to two equivalent K(1), one Mo(1), and one Mo(2) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Gd(1) and one Mo(1) atom. In the third O site, O(3) is bonded in an L-shaped geometry to one Gd(1) and one Mo(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one K(1), one Gd(1), and one Mo(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one K(1), one Gd(1), and one Mo(2) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to two equivalent Gd(1), one Mo(1), and one Mo(2) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to two equivalent K(1) and one Mo(2) atom. In the eighth O site, O(8) is bonded in a distorted water-like geometry to two equivalent K(1) and one Mo(2) atom. is represented by the CIF card [CIF]
data_KGd(MoO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.371
_cell_length_b   7.044
_cell_length_c   10.845
_cell_angle_alpha   75.610
_cell_angle_beta   76.842
_cell_angle_gamma   67.581
_symmetry_Int_Tables_number   1
_cell_volume   363.371
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.810  0.695  0.557  1.0
  K  K1  1  0.190  0.305  0.443  1.0
  Gd  Gd2  1  0.693  0.815  0.938  1.0
  Gd  Gd3  1  0.307  0.185  0.062  1.0
  Mo  Mo4  1  0.043  0.429  0.830  1.0
  Mo  Mo5  1  0.957  0.571  0.170  1.0
  Mo  Mo6  1  0.425  0.061  0.717  1.0
  Mo  Mo7  1  0.575  0.939  0.283  1.0
  O  O8  1  0.236  0.414  0.681  1.0
  O  O9  1  0.764  0.586  0.319  1.0
  O  O10  1  0.727  0.187  0.915  1.0
  O  O11  1  0.273  0.813  0.085  1.0
  O  O12  1  0.287  0.484  0.932  1.0
  O  O13  1  0.713  0.516  0.068  1.0
  O  O14  1  0.943  0.642  0.808  1.0
  O  O15  1  0.057  0.358  0.192  1.0
  O  O16  1  0.574  0.875  0.750  1.0
  O  O17  1  0.426  0.125  0.249  1.0
  O  O18  1  0.174  0.059  0.872  1.0
  O  O19  1  0.826  0.941  0.128  1.0
  O  O20  1  0.709  0.305  0.654  1.0
  O  O21  1  0.291  0.695  0.346  1.0
  O  O22  1  0.252  1.000  0.597  1.0
  O  O23  1  0.748  0.000  0.403  1.0
[/CIF]
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The crystal structure described by KGd(MoO4)2 crystallizes in the triclinic P-1 space group. K(1) is bonded in a 8-coordinate geometry to one O(4), one O(5), two equivalent O(1), two equivalent O(7), and two equivalent O(8) atoms. Gd(1) is bonded in a 7-coordinate geometry to one O(3), one O(4), one O(5), two equivalent O(2), and two equivalent O(6) atoms. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 2-coordinate geometry to one O(1), one O(2), one O(3), one O(4), and one O(6) atom. In the second Mo site, Mo(2) is bonded in a 1-coordinate geometry to one O(1), one O(5), one O(6), one O(7), and one O(8) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to two equivalent K(1), one Mo(1), and one Mo(2) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Gd(1) and one Mo(1) atom. In the third O site, O(3) is bonded in an L-shaped geometry to one Gd(1) and one Mo(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one K(1), one Gd(1), and one Mo(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one K(1), one Gd(1), and one Mo(2) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to two equivalent Gd(1), one Mo(1), and one Mo(2) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to two equivalent K(1) and one Mo(2) atom. In the eighth O site, O(8) is bonded in a distorted water-like geometry to two equivalent K(1) and one Mo(2) atom. is represented by the CIF card [CIF]
data_KGd(MoO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.371
_cell_length_b   7.044
_cell_length_c   10.845
_cell_angle_alpha   75.610
_cell_angle_beta   76.842
_cell_angle_gamma   67.581
_symmetry_Int_Tables_number   1
_cell_volume   363.371
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.810  0.695  0.557  1.0
  K  K1  1  0.190  0.305  0.443  1.0
  Gd  Gd2  1  0.693  0.815  0.938  1.0
  Gd  Gd3  1  0.307  0.185  0.062  1.0
  Mo  Mo4  1  0.043  0.429  0.830  1.0
  Mo  Mo5  1  0.957  0.571  0.170  1.0
  Mo  Mo6  1  0.425  0.061  0.717  1.0
  Mo  Mo7  1  0.575  0.939  0.283  1.0
  O  O8  1  0.236  0.414  0.681  1.0
  O  O9  1  0.764  0.586  0.319  1.0
  O  O10  1  0.727  0.187  0.915  1.0
  O  O11  1  0.273  0.813  0.085  1.0
  O  O12  1  0.287  0.484  0.932  1.0
  O  O13  1  0.713  0.516  0.068  1.0
  O  O14  1  0.943  0.642  0.808  1.0
  O  O15  1  0.057  0.358  0.192  1.0
  O  O16  1  0.574  0.875  0.750  1.0
  O  O17  1  0.426  0.125  0.249  1.0
  O  O18  1  0.174  0.059  0.872  1.0
  O  O19  1  0.826  0.941  0.128  1.0
  O  O20  1  0.709  0.305  0.654  1.0
  O  O21  1  0.291  0.695  0.346  1.0
  O  O22  1  0.252  1.000  0.597  1.0
  O  O23  1  0.748  0.000  0.403  1.0
[/CIF]
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