The structure described by Zn(MoO2)4 crystallizes in the trigonal R-3m space group. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form MoO6 octahedra that share edges with two equivalent Mo(2)O6 octahedra, edges with two equivalent Zn(1)O6 octahedra, and edges with four equivalent Mo(1)O6 octahedra. In the second Mo site, Mo(2) is bonded to six equivalent O(1) atoms to form MoO6 octahedra that share corners with six equivalent Zn(1)O6 octahedra and edges with six equivalent Mo(1)O6 octahedra. The corner-sharing octahedral tilt angles are 9°. Zn(1) is bonded to six equivalent O(1) atoms to form ZnO6 octahedra that share corners with six equivalent Mo(2)O6 octahedra and edges with six equivalent Mo(1)O6 octahedra. The corner-sharing octahedral tilt angles are 9°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Mo(2), two equivalent Mo(1), and one Zn(1) atom. In the second O site, O(2) is bonded in a trigonal non-coplanar geometry to three equivalent Mo(1) atoms. is represented by the CIF card [CIF]
data_Zn(MoO2)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.183
_cell_length_b   6.183
_cell_length_c   6.183
_cell_angle_alpha   62.921
_cell_angle_beta   62.921
_cell_angle_gamma   62.921
_symmetry_Int_Tables_number   1
_cell_volume   177.951
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.500  0.500  0.500  1.0
  Mo  Mo1  1  0.000  0.500  0.500  1.0
  Mo  Mo2  1  0.500  0.000  0.500  1.0
  Mo  Mo3  1  0.500  0.500  0.000  1.0
  Mo  Mo4  1  0.000  0.000  0.000  1.0
  O  O5  1  0.276  0.752  0.752  1.0
  O  O6  1  0.248  0.248  0.724  1.0
  O  O7  1  0.724  0.248  0.248  1.0
  O  O8  1  0.248  0.724  0.248  1.0
  O  O9  1  0.271  0.271  0.271  1.0
  O  O10  1  0.729  0.729  0.729  1.0
  O  O11  1  0.752  0.276  0.752  1.0
  O  O12  1  0.752  0.752  0.276  1.0
[/CIF]
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The structure described by Zn(MoO2)4 crystallizes in the trigonal R-3m space group. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form MoO6 octahedra that share edges with two equivalent Mo(2)O6 octahedra, edges with two equivalent Zn(1)O6 octahedra, and edges with four equivalent Mo(1)O6 octahedra. In the second Mo site, Mo(2) is bonded to six equivalent O(1) atoms to form MoO6 octahedra that share corners with six equivalent Zn(1)O6 octahedra and edges with six equivalent Mo(1)O6 octahedra. The corner-sharing octahedral tilt angles are 9°. Zn(1) is bonded to six equivalent O(1) atoms to form ZnO6 octahedra that share corners with six equivalent Mo(2)O6 octahedra and edges with six equivalent Mo(1)O6 octahedra. The corner-sharing octahedral tilt angles are 9°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Mo(2), two equivalent Mo(1), and one Zn(1) atom. In the second O site, O(2) is bonded in a trigonal non-coplanar geometry to three equivalent Mo(1) atoms. is represented by the CIF card [CIF]
data_Zn(MoO2)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.183
_cell_length_b   6.183
_cell_length_c   6.183
_cell_angle_alpha   62.921
_cell_angle_beta   62.921
_cell_angle_gamma   62.921
_symmetry_Int_Tables_number   1
_cell_volume   177.951
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.500  0.500  0.500  1.0
  Mo  Mo1  1  0.000  0.500  0.500  1.0
  Mo  Mo2  1  0.500  0.000  0.500  1.0
  Mo  Mo3  1  0.500  0.500  0.000  1.0
  Mo  Mo4  1  0.000  0.000  0.000  1.0
  O  O5  1  0.276  0.752  0.752  1.0
  O  O6  1  0.248  0.248  0.724  1.0
  O  O7  1  0.724  0.248  0.248  1.0
  O  O8  1  0.248  0.724  0.248  1.0
  O  O9  1  0.271  0.271  0.271  1.0
  O  O10  1  0.729  0.729  0.729  1.0
  O  O11  1  0.752  0.276  0.752  1.0
  O  O12  1  0.752  0.752  0.276  1.0
[/CIF]
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