The material described by Li4Ni3Cu3(WO8)2 is Hausmannite-derived structured and crystallizes in the monoclinic Cm space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(12), one O(3), and two equivalent O(9) atoms to form LiO4 tetrahedra that share  a cornercorner with one Ni(1)O6 octahedra, corners with two equivalent Cu(1)O6 octahedra, corners with two equivalent Cu(2)O6 octahedra, corners with three equivalent W(2)O6 octahedra, and corners with four equivalent Ni(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-62°. In the second Li site, Li(2) is bonded to one O(5), one O(7), and two equivalent O(11) atoms to form distorted LiO4 tetrahedra that share  a cornercorner with one Cu(2)O6 octahedra, corners with two equivalent Ni(2)O6 octahedra, corners with three equivalent W(2)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra, and edges with two equivalent Cu(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 60-65°. In the third Li site, Li(3) is bonded to one O(4), one O(8), and two equivalent O(1) atoms to form distorted LiO4 tetrahedra that share  a cornercorner with one Ni(1)O6 octahedra, corners with two equivalent Cu(1)O6 octahedra, corners with three equivalent W(1)O6 octahedra,  an edgeedge with one Cu(2)O6 octahedra, and edges with two equivalent Ni(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 58-67°. In the fourth Li site, Li(4) is bonded to one O(10), one O(2), and two equivalent O(6) atoms to form LiO4 tetrahedra that share  a cornercorner with one Cu(2)O6 octahedra, corners with two equivalent Ni(1)O6 octahedra, corners with two equivalent Ni(2)O6 octahedra, corners with three equivalent W(1)O6 octahedra, and corners with four equivalent Cu(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-64°. There are two inequivalent W sites. In the first W site, W(1) is bonded to one O(2), one O(8), two equivalent O(1), and two equivalent O(6) atoms to form distorted WO6 octahedra that share corners with two equivalent Cu(2)O6 octahedra, corners with four equivalent Ni(2)O6 octahedra, corners with three equivalent Li(3)O4 tetrahedra, corners with three equivalent Li(4)O4 tetrahedra,  an edgeedge with one Ni(1)O6 octahedra, and edges with two equivalent Cu(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-59°. In the second W site, W(2) is bonded to one O(12), one O(7), two equivalent O(11), and two equivalent O(9) atoms to form WO6 octahedra that share corners with two equivalent Ni(1)O6 octahedra, corners with four equivalent Cu(1)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra, corners with three equivalent Li(2)O4 tetrahedra,  an edgeedge with one Cu(2)O6 octahedra, and edges with two equivalent Ni(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 37-55°. There are two inequivalent Ni sites. In the first Ni site, Ni(1) is bonded to one O(3), one O(4), two equivalent O(11), and two equivalent O(6) atoms to form NiO6 octahedra that share corners with two equivalent W(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one W(1)O6 octahedra, edges with four equivalent Cu(1)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 37°. In the second Ni site, Ni(2) is bonded to one O(1), one O(10), one O(12), one O(5), one O(8), and one O(9) atom to form NiO6 octahedra that share corners with two equivalent W(1)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one W(2)O6 octahedra, edges with two equivalent Ni(2)O6 octahedra, edges with two equivalent Cu(2)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 44-46°. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one O(11), one O(2), one O(3), one O(4), one O(6), and one O(7) atom to form distorted CuO6 octahedra that share corners with two equivalent W(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one W(1)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, edges with two equivalent Cu(1)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 55°. In the second Cu site, Cu(2) is bonded to one O(10), one O(5), two equivalent O(1), and two equivalent O(9) atoms to form CuO6 octahedra that share corners with two equivalent W(1)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one W(2)O6 octahedra, edges with four equivalent Ni(2)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 59°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(3), one W(1), one Ni(2), and one Cu(2) atom. In the second O site, O(2) is bonded to one Li(4), one W(1), and two equivalent Cu(1) atoms to form distorted OLiCu2W tetrahedra that share  a cornercorner with one O(10)LiCuNi2 tetrahedra, corners with two equivalent O(4)LiCu2Ni tetrahedra, and  an edgeedge with one O(3)LiCu2Ni tetrahedra. In the third O site, O(3) is bonded to one Li(1), one Ni(1), and two equivalent Cu(1) atoms to form distorted OLiCu2Ni tetrahedra that share corners with three equivalent O(4)LiCu2Ni tetrahedra, corners with two equivalent O(9)LiCuNiW trigonal pyramids, and  an edgeedge with one O(2)LiCu2W tetrahedra. In the fourth O site, O(4) is bonded to one Li(3), one Ni(1), and two equivalent Cu(1) atoms to form OLiCu2Ni tetrahedra that share corners with two equivalent O(2)LiCu2W tetrahedra and corners with three equivalent O(3)LiCu2Ni tetrahedra. In the fifth O site, O(5) is bonded to one Li(2), two equivalent Ni(2), and one Cu(2) atom to form OLiCuNi2 tetrahedra that share corners with three equivalent O(10)LiCuNi2 tetrahedra and corners with four equivalent O(9)LiCuNiW trigonal pyramids. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one Li(4), one W(1), one Ni(1), and one Cu(1) atom. In the seventh O site, O(7) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one W(2), and two equivalent Cu(1) atoms. In the eighth O site, O(8) is bonded in a rectangular see-saw-like geometry to one Li(3), one W(1), and two equivalent Ni(2) atoms. In the ninth O site, O(9) is bonded to one Li(1), one W(2), one Ni(2), and one Cu(2) atom to form distorted OLiCuNiW trigonal pyramids that share  a cornercorner with one O(3)LiCu2Ni tetrahedra, corners with two equivalent O(5)LiCuNi2 tetrahedra,  a cornercorner with one O(9)LiCuNiW trigonal pyramid,  an edgeedge with one O(10)LiCuNi2 tetrahedra, and  an edgeedge with one O(9)LiCuNiW trigonal pyramid. In the tenth O site, O(10) is bonded to one Li(4), two equivalent Ni(2), and one Cu(2) atom to form distorted OLiCuNi2 tetrahedra that share  a cornercorner with one O(2)LiCu2W tetrahedra, corners with three equivalent O(5)LiCuNi2 tetrahedra, and edges with two equivalent O(9)LiCuNiW trigonal pyramids. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one Li(2), one W(2), one Ni(1), and one Cu(1) atom. In the twelfth O site, O(12) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one W(2), and two equivalent Ni(2) atoms. is represented by the CIF file [CIF]
data_Li4Cu3Ni3(WO8)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.937
_cell_length_b   5.937
_cell_length_c   9.862
_cell_angle_alpha   86.677
_cell_angle_beta   86.677
_cell_angle_gamma   58.244
_symmetry_Int_Tables_number   1
_cell_volume   294.930
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.663  0.663  0.908  1.0
  Li  Li1  1  0.999  0.999  0.987  1.0
  Li  Li2  1  0.007  0.007  0.488  1.0
  Li  Li3  1  0.344  0.344  0.414  1.0
  Cu  Cu4  1  0.838  0.337  0.211  1.0
  Cu  Cu5  1  0.337  0.838  0.211  1.0
  Cu  Cu6  1  0.168  0.168  0.713  1.0
  Ni  Ni7  1  0.830  0.830  0.215  1.0
  Ni  Ni8  1  0.663  0.170  0.712  1.0
  Ni  Ni9  1  0.170  0.663  0.712  1.0
  W  W10  1  0.687  0.687  0.489  1.0
  W  W11  1  0.339  0.339  0.979  1.0
  O  O12  1  0.823  0.340  0.584  1.0
  O  O13  1  0.531  0.531  0.333  1.0
  O  O14  1  0.663  0.663  0.118  1.0
  O  O15  1  0.002  0.002  0.298  1.0
  O  O16  1  0.004  0.004  0.799  1.0
  O  O17  1  0.340  0.823  0.584  1.0
  O  O18  1  0.981  0.529  0.365  1.0
  O  O19  1  0.529  0.981  0.365  1.0
  O  O20  1  0.153  0.153  0.093  1.0
  O  O21  1  0.828  0.828  0.599  1.0
  O  O22  1  0.469  0.034  0.851  1.0
  O  O23  1  0.034  0.469  0.851  1.0
  O  O24  1  0.330  0.330  0.618  1.0
  O  O25  1  0.642  0.143  0.079  1.0
  O  O26  1  0.484  0.484  0.852  1.0
  O  O27  1  0.143  0.642  0.079  1.0
[/CIF]
.
The material described by Li4Ni3Cu3(WO8)2 is Hausmannite-derived structured and crystallizes in the monoclinic Cm space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(12), one O(3), and two equivalent O(9) atoms to form LiO4 tetrahedra that share  a cornercorner with one Ni(1)O6 octahedra, corners with two equivalent Cu(1)O6 octahedra, corners with two equivalent Cu(2)O6 octahedra, corners with three equivalent W(2)O6 octahedra, and corners with four equivalent Ni(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-62°. In the second Li site, Li(2) is bonded to one O(5), one O(7), and two equivalent O(11) atoms to form distorted LiO4 tetrahedra that share  a cornercorner with one Cu(2)O6 octahedra, corners with two equivalent Ni(2)O6 octahedra, corners with three equivalent W(2)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra, and edges with two equivalent Cu(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 60-65°. In the third Li site, Li(3) is bonded to one O(4), one O(8), and two equivalent O(1) atoms to form distorted LiO4 tetrahedra that share  a cornercorner with one Ni(1)O6 octahedra, corners with two equivalent Cu(1)O6 octahedra, corners with three equivalent W(1)O6 octahedra,  an edgeedge with one Cu(2)O6 octahedra, and edges with two equivalent Ni(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 58-67°. In the fourth Li site, Li(4) is bonded to one O(10), one O(2), and two equivalent O(6) atoms to form LiO4 tetrahedra that share  a cornercorner with one Cu(2)O6 octahedra, corners with two equivalent Ni(1)O6 octahedra, corners with two equivalent Ni(2)O6 octahedra, corners with three equivalent W(1)O6 octahedra, and corners with four equivalent Cu(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-64°. There are two inequivalent W sites. In the first W site, W(1) is bonded to one O(2), one O(8), two equivalent O(1), and two equivalent O(6) atoms to form distorted WO6 octahedra that share corners with two equivalent Cu(2)O6 octahedra, corners with four equivalent Ni(2)O6 octahedra, corners with three equivalent Li(3)O4 tetrahedra, corners with three equivalent Li(4)O4 tetrahedra,  an edgeedge with one Ni(1)O6 octahedra, and edges with two equivalent Cu(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-59°. In the second W site, W(2) is bonded to one O(12), one O(7), two equivalent O(11), and two equivalent O(9) atoms to form WO6 octahedra that share corners with two equivalent Ni(1)O6 octahedra, corners with four equivalent Cu(1)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra, corners with three equivalent Li(2)O4 tetrahedra,  an edgeedge with one Cu(2)O6 octahedra, and edges with two equivalent Ni(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 37-55°. There are two inequivalent Ni sites. In the first Ni site, Ni(1) is bonded to one O(3), one O(4), two equivalent O(11), and two equivalent O(6) atoms to form NiO6 octahedra that share corners with two equivalent W(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one W(1)O6 octahedra, edges with four equivalent Cu(1)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 37°. In the second Ni site, Ni(2) is bonded to one O(1), one O(10), one O(12), one O(5), one O(8), and one O(9) atom to form NiO6 octahedra that share corners with two equivalent W(1)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one W(2)O6 octahedra, edges with two equivalent Ni(2)O6 octahedra, edges with two equivalent Cu(2)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 44-46°. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one O(11), one O(2), one O(3), one O(4), one O(6), and one O(7) atom to form distorted CuO6 octahedra that share corners with two equivalent W(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one W(1)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, edges with two equivalent Cu(1)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 55°. In the second Cu site, Cu(2) is bonded to one O(10), one O(5), two equivalent O(1), and two equivalent O(9) atoms to form CuO6 octahedra that share corners with two equivalent W(1)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one W(2)O6 octahedra, edges with four equivalent Ni(2)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 59°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(3), one W(1), one Ni(2), and one Cu(2) atom. In the second O site, O(2) is bonded to one Li(4), one W(1), and two equivalent Cu(1) atoms to form distorted OLiCu2W tetrahedra that share  a cornercorner with one O(10)LiCuNi2 tetrahedra, corners with two equivalent O(4)LiCu2Ni tetrahedra, and  an edgeedge with one O(3)LiCu2Ni tetrahedra. In the third O site, O(3) is bonded to one Li(1), one Ni(1), and two equivalent Cu(1) atoms to form distorted OLiCu2Ni tetrahedra that share corners with three equivalent O(4)LiCu2Ni tetrahedra, corners with two equivalent O(9)LiCuNiW trigonal pyramids, and  an edgeedge with one O(2)LiCu2W tetrahedra. In the fourth O site, O(4) is bonded to one Li(3), one Ni(1), and two equivalent Cu(1) atoms to form OLiCu2Ni tetrahedra that share corners with two equivalent O(2)LiCu2W tetrahedra and corners with three equivalent O(3)LiCu2Ni tetrahedra. In the fifth O site, O(5) is bonded to one Li(2), two equivalent Ni(2), and one Cu(2) atom to form OLiCuNi2 tetrahedra that share corners with three equivalent O(10)LiCuNi2 tetrahedra and corners with four equivalent O(9)LiCuNiW trigonal pyramids. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one Li(4), one W(1), one Ni(1), and one Cu(1) atom. In the seventh O site, O(7) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one W(2), and two equivalent Cu(1) atoms. In the eighth O site, O(8) is bonded in a rectangular see-saw-like geometry to one Li(3), one W(1), and two equivalent Ni(2) atoms. In the ninth O site, O(9) is bonded to one Li(1), one W(2), one Ni(2), and one Cu(2) atom to form distorted OLiCuNiW trigonal pyramids that share  a cornercorner with one O(3)LiCu2Ni tetrahedra, corners with two equivalent O(5)LiCuNi2 tetrahedra,  a cornercorner with one O(9)LiCuNiW trigonal pyramid,  an edgeedge with one O(10)LiCuNi2 tetrahedra, and  an edgeedge with one O(9)LiCuNiW trigonal pyramid. In the tenth O site, O(10) is bonded to one Li(4), two equivalent Ni(2), and one Cu(2) atom to form distorted OLiCuNi2 tetrahedra that share  a cornercorner with one O(2)LiCu2W tetrahedra, corners with three equivalent O(5)LiCuNi2 tetrahedra, and edges with two equivalent O(9)LiCuNiW trigonal pyramids. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one Li(2), one W(2), one Ni(1), and one Cu(1) atom. In the twelfth O site, O(12) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one W(2), and two equivalent Ni(2) atoms. is represented by the CIF file [CIF]
data_Li4Cu3Ni3(WO8)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.937
_cell_length_b   5.937
_cell_length_c   9.862
_cell_angle_alpha   86.677
_cell_angle_beta   86.677
_cell_angle_gamma   58.244
_symmetry_Int_Tables_number   1
_cell_volume   294.930
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.663  0.663  0.908  1.0
  Li  Li1  1  0.999  0.999  0.987  1.0
  Li  Li2  1  0.007  0.007  0.488  1.0
  Li  Li3  1  0.344  0.344  0.414  1.0
  Cu  Cu4  1  0.838  0.337  0.211  1.0
  Cu  Cu5  1  0.337  0.838  0.211  1.0
  Cu  Cu6  1  0.168  0.168  0.713  1.0
  Ni  Ni7  1  0.830  0.830  0.215  1.0
  Ni  Ni8  1  0.663  0.170  0.712  1.0
  Ni  Ni9  1  0.170  0.663  0.712  1.0
  W  W10  1  0.687  0.687  0.489  1.0
  W  W11  1  0.339  0.339  0.979  1.0
  O  O12  1  0.823  0.340  0.584  1.0
  O  O13  1  0.531  0.531  0.333  1.0
  O  O14  1  0.663  0.663  0.118  1.0
  O  O15  1  0.002  0.002  0.298  1.0
  O  O16  1  0.004  0.004  0.799  1.0
  O  O17  1  0.340  0.823  0.584  1.0
  O  O18  1  0.981  0.529  0.365  1.0
  O  O19  1  0.529  0.981  0.365  1.0
  O  O20  1  0.153  0.153  0.093  1.0
  O  O21  1  0.828  0.828  0.599  1.0
  O  O22  1  0.469  0.034  0.851  1.0
  O  O23  1  0.034  0.469  0.851  1.0
  O  O24  1  0.330  0.330  0.618  1.0
  O  O25  1  0.642  0.143  0.079  1.0
  O  O26  1  0.484  0.484  0.852  1.0
  O  O27  1  0.143  0.642  0.079  1.0
[/CIF]
.