The material described by NaLaGeP2SO12 crystallizes in the monoclinic Cc space group. Na(1) is bonded in a 5-coordinate geometry to one O(11), one O(12), one O(7), one O(8), and one O(9) atom. La(1) is bonded to one O(10), one O(11), one O(12), one O(4), one O(5), and one O(6) atom to form LaO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and corners with two equivalent S(1)O4 tetrahedra. Ge(1) is bonded to one O(1), one O(3), one O(7), one O(8), and one O(9) atom to form GeO5 trigonal bipyramids that share  a cornercorner with one S(1)O4 tetrahedra, corners with two equivalent P(1)O4 tetrahedra, and corners with two equivalent P(2)O4 tetrahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(10), one O(4), and one O(7) atom to form PO4 tetrahedra that share corners with two equivalent La(1)O6 octahedra and corners with two equivalent Ge(1)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 20-29°. In the second P site, P(2) is bonded to one O(12), one O(3), one O(5), and one O(8) atom to form PO4 tetrahedra that share corners with two equivalent La(1)O6 octahedra and corners with two equivalent Ge(1)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 14-27°. S(1) is bonded to one O(11), one O(2), one O(6), and one O(9) atom to form SO4 tetrahedra that share corners with two equivalent La(1)O6 octahedra and  a cornercorner with one Ge(1)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 27-42°. There are twelve inequivalent O sites. In the first O site, O(6) is bonded in a bent 150 degrees geometry to one La(1) and one S(1) atom. In the second O site, O(7) is bonded in a 3-coordinate geometry to one Na(1), one Ge(1), and one P(1) atom. In the third O site, O(8) is bonded in a 3-coordinate geometry to one Na(1), one Ge(1), and one P(2) atom. In the fourth O site, O(9) is bonded in a 3-coordinate geometry to one Na(1), one Ge(1), and one S(1) atom. In the fifth O site, O(10) is bonded in a bent 150 degrees geometry to one La(1) and one P(1) atom. In the sixth O site, O(11) is bonded in a 3-coordinate geometry to one Na(1), one La(1), and one S(1) atom. In the seventh O site, O(12) is bonded in a 3-coordinate geometry to one Na(1), one La(1), and one P(2) atom. In the eighth O site, O(1) is bonded in a bent 150 degrees geometry to one Ge(1) and one P(1) atom. In the ninth O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the tenth O site, O(3) is bonded in a bent 150 degrees geometry to one Ge(1) and one P(2) atom. In the eleventh O site, O(4) is bonded in a bent 150 degrees geometry to one La(1) and one P(1) atom. In the twelfth O site, O(5) is bonded in a distorted linear geometry to one La(1) and one P(2) atom. is represented by the CIF file [CIF]
data_NaLaGeP2SO12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.788
_cell_length_b   8.973
_cell_length_c   9.249
_cell_angle_alpha   117.016
_cell_angle_beta   118.362
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   549.652
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ge  Ge0  1  0.368  0.073  0.750  1.0
  Ge  Ge1  1  0.882  0.573  0.750  1.0
  La  La2  1  0.651  0.916  0.286  1.0
  La  La3  1  0.135  0.416  0.286  1.0
  Na  Na4  1  0.486  0.481  0.953  1.0
  Na  Na5  1  0.966  0.981  0.953  1.0
  O  O6  1  0.158  0.923  0.677  1.0
  O  O7  1  0.247  0.904  0.353  1.0
  O  O8  1  0.522  0.928  0.780  1.0
  O  O9  1  0.758  0.428  0.780  1.0
  O  O10  1  0.606  0.404  0.353  1.0
  O  O11  1  0.020  0.423  0.677  1.0
  O  O12  1  0.910  0.097  0.419  1.0
  O  O13  1  0.692  0.095  0.586  1.0
  O  O14  1  0.491  0.085  0.170  1.0
  O  O15  1  0.179  0.585  0.170  1.0
  O  O16  1  0.394  0.595  0.586  1.0
  O  O17  1  0.009  0.597  0.419  1.0
  O  O18  1  0.227  0.233  0.717  1.0
  O  O19  1  0.534  0.228  0.761  1.0
  O  O20  1  0.479  0.242  0.013  1.0
  O  O21  1  0.034  0.742  0.013  1.0
  O  O22  1  0.726  0.728  0.761  1.0
  O  O23  1  0.989  0.733  0.717  1.0
  O  O24  1  0.813  0.786  0.445  1.0
  O  O25  1  0.349  0.751  0.131  1.0
  O  O26  1  0.584  0.756  0.953  1.0
  O  O27  1  0.869  0.256  0.953  1.0
  O  O28  1  0.282  0.251  0.131  1.0
  O  O29  1  0.132  0.286  0.445  1.0
  P  P30  1  0.991  0.758  0.559  1.0
  P  P31  1  0.549  0.745  0.769  1.0
  P  P32  1  0.720  0.245  0.769  1.0
  P  P33  1  0.068  0.258  0.559  1.0
  S  S34  1  0.211  0.749  0.179  1.0
  S  S35  1  0.467  0.249  0.179  1.0
[/CIF]
.
The material described by NaLaGeP2SO12 crystallizes in the monoclinic Cc space group. Na(1) is bonded in a 5-coordinate geometry to one O(11), one O(12), one O(7), one O(8), and one O(9) atom. La(1) is bonded to one O(10), one O(11), one O(12), one O(4), one O(5), and one O(6) atom to form LaO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and corners with two equivalent S(1)O4 tetrahedra. Ge(1) is bonded to one O(1), one O(3), one O(7), one O(8), and one O(9) atom to form GeO5 trigonal bipyramids that share  a cornercorner with one S(1)O4 tetrahedra, corners with two equivalent P(1)O4 tetrahedra, and corners with two equivalent P(2)O4 tetrahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(10), one O(4), and one O(7) atom to form PO4 tetrahedra that share corners with two equivalent La(1)O6 octahedra and corners with two equivalent Ge(1)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 20-29°. In the second P site, P(2) is bonded to one O(12), one O(3), one O(5), and one O(8) atom to form PO4 tetrahedra that share corners with two equivalent La(1)O6 octahedra and corners with two equivalent Ge(1)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 14-27°. S(1) is bonded to one O(11), one O(2), one O(6), and one O(9) atom to form SO4 tetrahedra that share corners with two equivalent La(1)O6 octahedra and  a cornercorner with one Ge(1)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 27-42°. There are twelve inequivalent O sites. In the first O site, O(6) is bonded in a bent 150 degrees geometry to one La(1) and one S(1) atom. In the second O site, O(7) is bonded in a 3-coordinate geometry to one Na(1), one Ge(1), and one P(1) atom. In the third O site, O(8) is bonded in a 3-coordinate geometry to one Na(1), one Ge(1), and one P(2) atom. In the fourth O site, O(9) is bonded in a 3-coordinate geometry to one Na(1), one Ge(1), and one S(1) atom. In the fifth O site, O(10) is bonded in a bent 150 degrees geometry to one La(1) and one P(1) atom. In the sixth O site, O(11) is bonded in a 3-coordinate geometry to one Na(1), one La(1), and one S(1) atom. In the seventh O site, O(12) is bonded in a 3-coordinate geometry to one Na(1), one La(1), and one P(2) atom. In the eighth O site, O(1) is bonded in a bent 150 degrees geometry to one Ge(1) and one P(1) atom. In the ninth O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the tenth O site, O(3) is bonded in a bent 150 degrees geometry to one Ge(1) and one P(2) atom. In the eleventh O site, O(4) is bonded in a bent 150 degrees geometry to one La(1) and one P(1) atom. In the twelfth O site, O(5) is bonded in a distorted linear geometry to one La(1) and one P(2) atom. is represented by the CIF file [CIF]
data_NaLaGeP2SO12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.788
_cell_length_b   8.973
_cell_length_c   9.249
_cell_angle_alpha   117.016
_cell_angle_beta   118.362
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   549.652
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ge  Ge0  1  0.368  0.073  0.750  1.0
  Ge  Ge1  1  0.882  0.573  0.750  1.0
  La  La2  1  0.651  0.916  0.286  1.0
  La  La3  1  0.135  0.416  0.286  1.0
  Na  Na4  1  0.486  0.481  0.953  1.0
  Na  Na5  1  0.966  0.981  0.953  1.0
  O  O6  1  0.158  0.923  0.677  1.0
  O  O7  1  0.247  0.904  0.353  1.0
  O  O8  1  0.522  0.928  0.780  1.0
  O  O9  1  0.758  0.428  0.780  1.0
  O  O10  1  0.606  0.404  0.353  1.0
  O  O11  1  0.020  0.423  0.677  1.0
  O  O12  1  0.910  0.097  0.419  1.0
  O  O13  1  0.692  0.095  0.586  1.0
  O  O14  1  0.491  0.085  0.170  1.0
  O  O15  1  0.179  0.585  0.170  1.0
  O  O16  1  0.394  0.595  0.586  1.0
  O  O17  1  0.009  0.597  0.419  1.0
  O  O18  1  0.227  0.233  0.717  1.0
  O  O19  1  0.534  0.228  0.761  1.0
  O  O20  1  0.479  0.242  0.013  1.0
  O  O21  1  0.034  0.742  0.013  1.0
  O  O22  1  0.726  0.728  0.761  1.0
  O  O23  1  0.989  0.733  0.717  1.0
  O  O24  1  0.813  0.786  0.445  1.0
  O  O25  1  0.349  0.751  0.131  1.0
  O  O26  1  0.584  0.756  0.953  1.0
  O  O27  1  0.869  0.256  0.953  1.0
  O  O28  1  0.282  0.251  0.131  1.0
  O  O29  1  0.132  0.286  0.445  1.0
  P  P30  1  0.991  0.758  0.559  1.0
  P  P31  1  0.549  0.745  0.769  1.0
  P  P32  1  0.720  0.245  0.769  1.0
  P  P33  1  0.068  0.258  0.559  1.0
  S  S34  1  0.211  0.749  0.179  1.0
  S  S35  1  0.467  0.249  0.179  1.0
[/CIF]
.