The material described by Dy2(MoO4)3 crystallizes in the monoclinic C2/c space group. Dy(1) is bonded in a 8-coordinate geometry to one O(2), one O(4), one O(5), one O(6), two equivalent O(1), and two equivalent O(3) atoms. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 5-coordinate geometry to one O(3), one O(5), one O(6), and two equivalent O(4) atoms. In the second Mo site, Mo(2) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. There are six inequivalent O sites. In the first O site, O(4) is bonded in a trigonal non-coplanar geometry to one Dy(1) and two equivalent Mo(1) atoms. In the second O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Dy(1) and one Mo(1) atom. In the third O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Dy(1) and one Mo(1) atom. In the fourth O site, O(1) is bonded in a trigonal planar geometry to two equivalent Dy(1) and one Mo(2) atom. In the fifth O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Dy(1) and one Mo(2) atom. In the sixth O site, O(3) is bonded in a distorted trigonal planar geometry to two equivalent Dy(1) and one Mo(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Dy2(MoO4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.921
_cell_length_b   6.921
_cell_length_c   11.425
_cell_angle_alpha   79.358
_cell_angle_beta   79.358
_cell_angle_gamma   112.460
_symmetry_Int_Tables_number   1
_cell_volume   476.971
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  1  0.544  0.788  0.909  1.0
  Dy  Dy1  1  0.456  0.212  0.091  1.0
  Dy  Dy2  1  0.212  0.456  0.591  1.0
  Dy  Dy3  1  0.788  0.544  0.409  1.0
  Mo  Mo4  1  0.746  0.962  0.551  1.0
  Mo  Mo5  1  0.254  0.038  0.449  1.0
  Mo  Mo6  1  0.038  0.254  0.949  1.0
  Mo  Mo7  1  0.962  0.746  0.051  1.0
  Mo  Mo8  1  0.631  0.369  0.750  1.0
  Mo  Mo9  1  0.369  0.631  0.250  1.0
  O  O10  1  0.576  0.158  0.892  1.0
  O  O11  1  0.424  0.842  0.108  1.0
  O  O12  1  0.842  0.424  0.608  1.0
  O  O13  1  0.158  0.576  0.392  1.0
  O  O14  1  0.376  0.293  0.717  1.0
  O  O15  1  0.624  0.707  0.283  1.0
  O  O16  1  0.707  0.624  0.783  1.0
  O  O17  1  0.293  0.376  0.217  1.0
  O  O18  1  0.584  0.684  0.538  1.0
  O  O19  1  0.416  0.316  0.462  1.0
  O  O20  1  0.316  0.416  0.962  1.0
  O  O21  1  0.684  0.584  0.038  1.0
  O  O22  1  0.898  0.975  0.923  1.0
  O  O23  1  0.102  0.025  0.077  1.0
  O  O24  1  0.025  0.102  0.577  1.0
  O  O25  1  0.975  0.898  0.423  1.0
  O  O26  1  0.595  0.950  0.701  1.0
  O  O27  1  0.405  0.050  0.299  1.0
  O  O28  1  0.050  0.405  0.799  1.0
  O  O29  1  0.950  0.595  0.201  1.0
  O  O30  1  0.268  0.832  0.559  1.0
  O  O31  1  0.732  0.168  0.441  1.0
  O  O32  1  0.168  0.732  0.941  1.0
  O  O33  1  0.832  0.268  0.059  1.0
[/CIF]
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The material described by Dy2(MoO4)3 crystallizes in the monoclinic C2/c space group. Dy(1) is bonded in a 8-coordinate geometry to one O(2), one O(4), one O(5), one O(6), two equivalent O(1), and two equivalent O(3) atoms. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 5-coordinate geometry to one O(3), one O(5), one O(6), and two equivalent O(4) atoms. In the second Mo site, Mo(2) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. There are six inequivalent O sites. In the first O site, O(4) is bonded in a trigonal non-coplanar geometry to one Dy(1) and two equivalent Mo(1) atoms. In the second O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Dy(1) and one Mo(1) atom. In the third O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Dy(1) and one Mo(1) atom. In the fourth O site, O(1) is bonded in a trigonal planar geometry to two equivalent Dy(1) and one Mo(2) atom. In the fifth O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Dy(1) and one Mo(2) atom. In the sixth O site, O(3) is bonded in a distorted trigonal planar geometry to two equivalent Dy(1) and one Mo(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Dy2(MoO4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.921
_cell_length_b   6.921
_cell_length_c   11.425
_cell_angle_alpha   79.358
_cell_angle_beta   79.358
_cell_angle_gamma   112.460
_symmetry_Int_Tables_number   1
_cell_volume   476.971
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  1  0.544  0.788  0.909  1.0
  Dy  Dy1  1  0.456  0.212  0.091  1.0
  Dy  Dy2  1  0.212  0.456  0.591  1.0
  Dy  Dy3  1  0.788  0.544  0.409  1.0
  Mo  Mo4  1  0.746  0.962  0.551  1.0
  Mo  Mo5  1  0.254  0.038  0.449  1.0
  Mo  Mo6  1  0.038  0.254  0.949  1.0
  Mo  Mo7  1  0.962  0.746  0.051  1.0
  Mo  Mo8  1  0.631  0.369  0.750  1.0
  Mo  Mo9  1  0.369  0.631  0.250  1.0
  O  O10  1  0.576  0.158  0.892  1.0
  O  O11  1  0.424  0.842  0.108  1.0
  O  O12  1  0.842  0.424  0.608  1.0
  O  O13  1  0.158  0.576  0.392  1.0
  O  O14  1  0.376  0.293  0.717  1.0
  O  O15  1  0.624  0.707  0.283  1.0
  O  O16  1  0.707  0.624  0.783  1.0
  O  O17  1  0.293  0.376  0.217  1.0
  O  O18  1  0.584  0.684  0.538  1.0
  O  O19  1  0.416  0.316  0.462  1.0
  O  O20  1  0.316  0.416  0.962  1.0
  O  O21  1  0.684  0.584  0.038  1.0
  O  O22  1  0.898  0.975  0.923  1.0
  O  O23  1  0.102  0.025  0.077  1.0
  O  O24  1  0.025  0.102  0.577  1.0
  O  O25  1  0.975  0.898  0.423  1.0
  O  O26  1  0.595  0.950  0.701  1.0
  O  O27  1  0.405  0.050  0.299  1.0
  O  O28  1  0.050  0.405  0.799  1.0
  O  O29  1  0.950  0.595  0.201  1.0
  O  O30  1  0.268  0.832  0.559  1.0
  O  O31  1  0.732  0.168  0.441  1.0
  O  O32  1  0.168  0.732  0.941  1.0
  O  O33  1  0.832  0.268  0.059  1.0
[/CIF]
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