The compound described by SbO4 is Upper Bainite-like structured and crystallizes in the orthorhombic Imma space group. The structure consists of eight water atoms inside a SbO3 framework. In the SbO3 framework, there are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles are 46°. In the second Sb site, Sb(2) is bonded to two equivalent O(3) and four equivalent O(1) atoms to form corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 45-46°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Sb(1) and one Sb(2) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to two equivalent Sb(1) atoms. In the third O site, O(3) is bonded in a bent 150 degrees geometry to two equivalent Sb(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_SbO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.378
_cell_length_b   7.378
_cell_length_c   7.378
_cell_angle_alpha   120.429
_cell_angle_beta   119.885
_cell_angle_gamma   89.729
_symmetry_Int_Tables_number   1
_cell_volume   283.275
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.000  0.000  0.500  1.0
  Sb  Sb1  1  0.000  0.500  0.000  1.0
  Sb  Sb2  1  0.000  0.000  0.000  1.0
  Sb  Sb3  1  0.500  0.000  0.500  1.0
  O  O4  1  0.927  0.675  0.851  1.0
  O  O5  1  0.324  0.075  0.649  1.0
  O  O6  1  0.926  0.676  0.250  1.0
  O  O7  1  0.322  0.072  0.250  1.0
  O  O8  1  0.927  0.075  0.251  1.0
  O  O9  1  0.324  0.675  0.249  1.0
  O  O10  1  0.073  0.325  0.149  1.0
  O  O11  1  0.676  0.925  0.351  1.0
  O  O12  1  0.074  0.324  0.750  1.0
  O  O13  1  0.678  0.928  0.750  1.0
  O  O14  1  0.073  0.925  0.749  1.0
  O  O15  1  0.676  0.325  0.751  1.0
  O  O16  1  0.377  0.627  0.750  1.0
  O  O17  1  0.623  0.373  0.250  1.0
  O  O18  1  0.500  0.500  0.500  1.0
  O  O19  1  0.500  0.000  0.000  1.0
[/CIF]
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The compound described by SbO4 is Upper Bainite-like structured and crystallizes in the orthorhombic Imma space group. The structure consists of eight water atoms inside a SbO3 framework. In the SbO3 framework, there are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles are 46°. In the second Sb site, Sb(2) is bonded to two equivalent O(3) and four equivalent O(1) atoms to form corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 45-46°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Sb(1) and one Sb(2) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to two equivalent Sb(1) atoms. In the third O site, O(3) is bonded in a bent 150 degrees geometry to two equivalent Sb(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_SbO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.378
_cell_length_b   7.378
_cell_length_c   7.378
_cell_angle_alpha   120.429
_cell_angle_beta   119.885
_cell_angle_gamma   89.729
_symmetry_Int_Tables_number   1
_cell_volume   283.275
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.000  0.000  0.500  1.0
  Sb  Sb1  1  0.000  0.500  0.000  1.0
  Sb  Sb2  1  0.000  0.000  0.000  1.0
  Sb  Sb3  1  0.500  0.000  0.500  1.0
  O  O4  1  0.927  0.675  0.851  1.0
  O  O5  1  0.324  0.075  0.649  1.0
  O  O6  1  0.926  0.676  0.250  1.0
  O  O7  1  0.322  0.072  0.250  1.0
  O  O8  1  0.927  0.075  0.251  1.0
  O  O9  1  0.324  0.675  0.249  1.0
  O  O10  1  0.073  0.325  0.149  1.0
  O  O11  1  0.676  0.925  0.351  1.0
  O  O12  1  0.074  0.324  0.750  1.0
  O  O13  1  0.678  0.928  0.750  1.0
  O  O14  1  0.073  0.925  0.749  1.0
  O  O15  1  0.676  0.325  0.751  1.0
  O  O16  1  0.377  0.627  0.750  1.0
  O  O17  1  0.623  0.373  0.250  1.0
  O  O18  1  0.500  0.500  0.500  1.0
  O  O19  1  0.500  0.000  0.000  1.0
[/CIF]
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