The crystal structure described by (PuO4)2(NO3)4O2 is Cyanogen Chloride-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four nitric acid molecules, two water atoms, and two PuO4 clusters. In one of the PuO4 clusters, Pu(1) is bonded in a square co-planar geometry to four equivalent O(1,5) atoms. O(1,5) is bonded in a single-bond geometry to one Pu(1) atom. In one of the PuO4 clusters, Pu(2) is bonded in a square co-planar geometry to four equivalent O(6,10) atoms. O(6,10) is bonded in a single-bond geometry to one Pu(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_PuN2O11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.364
_cell_length_b   7.582
_cell_length_c   10.344
_cell_angle_alpha   82.794
_cell_angle_beta   77.726
_cell_angle_gamma   67.930
_symmetry_Int_Tables_number   1
_cell_volume   522.394
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pu  Pu0  1  0.500  0.500  0.500  1.0
  Pu  Pu1  1  0.500  0.000  0.000  1.0
  N  N2  1  0.828  0.117  0.390  1.0
  N  N3  1  0.172  0.883  0.610  1.0
  N  N4  1  0.752  0.235  0.044  1.0
  N  N5  1  0.248  0.765  0.956  1.0
  O  O6  1  0.585  0.425  0.656  1.0
  O  O7  1  0.415  0.575  0.344  1.0
  O  O8  1  0.655  0.122  0.442  1.0
  O  O9  1  0.345  0.878  0.558  1.0
  O  O10  1  0.960  0.970  0.346  1.0
  O  O11  1  0.040  0.030  0.654  1.0
  O  O12  1  0.860  0.272  0.383  1.0
  O  O13  1  0.140  0.728  0.617  1.0
  O  O14  1  0.676  0.622  0.452  1.0
  O  O15  1  0.324  0.378  0.548  1.0
  O  O16  1  0.665  0.793  0.077  1.0
  O  O17  1  0.335  0.207  0.923  1.0
  O  O18  1  0.781  0.157  0.936  1.0
  O  O19  1  0.219  0.843  0.064  1.0
  O  O20  1  0.854  0.326  0.059  1.0
  O  O21  1  0.146  0.674  0.941  1.0
  O  O22  1  0.614  0.216  0.135  1.0
  O  O23  1  0.386  0.784  0.865  1.0
  O  O24  1  0.657  0.931  0.840  1.0
  O  O25  1  0.343  0.069  0.160  1.0
  O  O26  1  0.065  0.528  0.232  1.0
  O  O27  1  0.935  0.472  0.768  1.0
[/CIF]
.
The crystal structure described by (PuO4)2(NO3)4O2 is Cyanogen Chloride-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four nitric acid molecules, two water atoms, and two PuO4 clusters. In one of the PuO4 clusters, Pu(1) is bonded in a square co-planar geometry to four equivalent O(1,5) atoms. O(1,5) is bonded in a single-bond geometry to one Pu(1) atom. In one of the PuO4 clusters, Pu(2) is bonded in a square co-planar geometry to four equivalent O(6,10) atoms. O(6,10) is bonded in a single-bond geometry to one Pu(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_PuN2O11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.364
_cell_length_b   7.582
_cell_length_c   10.344
_cell_angle_alpha   82.794
_cell_angle_beta   77.726
_cell_angle_gamma   67.930
_symmetry_Int_Tables_number   1
_cell_volume   522.394
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pu  Pu0  1  0.500  0.500  0.500  1.0
  Pu  Pu1  1  0.500  0.000  0.000  1.0
  N  N2  1  0.828  0.117  0.390  1.0
  N  N3  1  0.172  0.883  0.610  1.0
  N  N4  1  0.752  0.235  0.044  1.0
  N  N5  1  0.248  0.765  0.956  1.0
  O  O6  1  0.585  0.425  0.656  1.0
  O  O7  1  0.415  0.575  0.344  1.0
  O  O8  1  0.655  0.122  0.442  1.0
  O  O9  1  0.345  0.878  0.558  1.0
  O  O10  1  0.960  0.970  0.346  1.0
  O  O11  1  0.040  0.030  0.654  1.0
  O  O12  1  0.860  0.272  0.383  1.0
  O  O13  1  0.140  0.728  0.617  1.0
  O  O14  1  0.676  0.622  0.452  1.0
  O  O15  1  0.324  0.378  0.548  1.0
  O  O16  1  0.665  0.793  0.077  1.0
  O  O17  1  0.335  0.207  0.923  1.0
  O  O18  1  0.781  0.157  0.936  1.0
  O  O19  1  0.219  0.843  0.064  1.0
  O  O20  1  0.854  0.326  0.059  1.0
  O  O21  1  0.146  0.674  0.941  1.0
  O  O22  1  0.614  0.216  0.135  1.0
  O  O23  1  0.386  0.784  0.865  1.0
  O  O24  1  0.657  0.931  0.840  1.0
  O  O25  1  0.343  0.069  0.160  1.0
  O  O26  1  0.065  0.528  0.232  1.0
  O  O27  1  0.935  0.472  0.768  1.0
[/CIF]
.