The material described by BaCdBi2 is Parent of FeAs superconductors-derived structured and crystallizes in the tetragonal I4/mmm space group. Ba(1) is bonded in a 8-coordinate geometry to four equivalent Bi(1) and four equivalent Bi(2) atoms. Cd(1) is bonded to four equivalent Bi(2) atoms to form a mixture of distorted corner and edge-sharing CdBi4 tetrahedra. There are two inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a distorted body-centered cubic geometry to four equivalent Ba(1) and four equivalent Bi(1) atoms. In the second Bi site, Bi(2) is bonded in a 8-coordinate geometry to four equivalent Ba(1) and four equivalent Cd(1) atoms. is represented by the CIF file [CIF]
data_BaCdBi2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.731
_cell_length_b   4.731
_cell_length_c   12.851
_cell_angle_alpha   100.608
_cell_angle_beta   100.608
_cell_angle_gamma   89.980
_symmetry_Int_Tables_number   1
_cell_volume   277.700
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.886  0.886  0.772  1.0
  Ba  Ba1  1  0.114  0.114  0.228  1.0
  Cd  Cd2  1  0.250  0.750  0.500  1.0
  Cd  Cd3  1  0.750  0.250  0.500  1.0
  Bi  Bi4  1  0.000  0.500  0.000  1.0
  Bi  Bi5  1  0.673  0.673  0.346  1.0
  Bi  Bi6  1  0.500  0.000  0.000  1.0
  Bi  Bi7  1  0.327  0.327  0.654  1.0
[/CIF]
.
The material described by BaCdBi2 is Parent of FeAs superconductors-derived structured and crystallizes in the tetragonal I4/mmm space group. Ba(1) is bonded in a 8-coordinate geometry to four equivalent Bi(1) and four equivalent Bi(2) atoms. Cd(1) is bonded to four equivalent Bi(2) atoms to form a mixture of distorted corner and edge-sharing CdBi4 tetrahedra. There are two inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a distorted body-centered cubic geometry to four equivalent Ba(1) and four equivalent Bi(1) atoms. In the second Bi site, Bi(2) is bonded in a 8-coordinate geometry to four equivalent Ba(1) and four equivalent Cd(1) atoms. is represented by the CIF file [CIF]
data_BaCdBi2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.731
_cell_length_b   4.731
_cell_length_c   12.851
_cell_angle_alpha   100.608
_cell_angle_beta   100.608
_cell_angle_gamma   89.980
_symmetry_Int_Tables_number   1
_cell_volume   277.700
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.886  0.886  0.772  1.0
  Ba  Ba1  1  0.114  0.114  0.228  1.0
  Cd  Cd2  1  0.250  0.750  0.500  1.0
  Cd  Cd3  1  0.750  0.250  0.500  1.0
  Bi  Bi4  1  0.000  0.500  0.000  1.0
  Bi  Bi5  1  0.673  0.673  0.346  1.0
  Bi  Bi6  1  0.500  0.000  0.000  1.0
  Bi  Bi7  1  0.327  0.327  0.654  1.0
[/CIF]
.