The structure described by Rh3W is beta Cu3Ti-like structured and crystallizes in the hexagonal P6_3/mmc space group. W(1) is bonded to twelve equivalent Rh(1) atoms to form WRh12 cuboctahedra that share corners with six equivalent W(1)Rh12 cuboctahedra, corners with twelve equivalent Rh(1)Rh8W4 cuboctahedra, edges with eighteen equivalent Rh(1)Rh8W4 cuboctahedra, faces with eight equivalent W(1)Rh12 cuboctahedra, and faces with twelve equivalent Rh(1)Rh8W4 cuboctahedra. Rh(1) is bonded to four equivalent W(1) and eight equivalent Rh(1) atoms to form RhRh8W4 cuboctahedra that share corners with four equivalent W(1)Rh12 cuboctahedra, corners with fourteen equivalent Rh(1)Rh8W4 cuboctahedra, edges with six equivalent W(1)Rh12 cuboctahedra, edges with twelve equivalent Rh(1)Rh8W4 cuboctahedra, faces with four equivalent W(1)Rh12 cuboctahedra, and faces with sixteen equivalent Rh(1)Rh8W4 cuboctahedra. is represented by the CIF file [CIF]
data_Rh3W
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.477
_cell_length_b   5.477
_cell_length_c   4.344
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   112.840
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rh  Rh0  1  0.833  0.667  0.250  1.0
  Rh  Rh1  1  0.167  0.833  0.750  1.0
  Rh  Rh2  1  0.667  0.833  0.750  1.0
  Rh  Rh3  1  0.333  0.167  0.250  1.0
  Rh  Rh4  1  0.833  0.167  0.250  1.0
  Rh  Rh5  1  0.167  0.333  0.750  1.0
  W  W6  1  0.333  0.667  0.250  1.0
  W  W7  1  0.667  0.333  0.750  1.0
[/CIF]
.
The structure described by Rh3W is beta Cu3Ti-like structured and crystallizes in the hexagonal P6_3/mmc space group. W(1) is bonded to twelve equivalent Rh(1) atoms to form WRh12 cuboctahedra that share corners with six equivalent W(1)Rh12 cuboctahedra, corners with twelve equivalent Rh(1)Rh8W4 cuboctahedra, edges with eighteen equivalent Rh(1)Rh8W4 cuboctahedra, faces with eight equivalent W(1)Rh12 cuboctahedra, and faces with twelve equivalent Rh(1)Rh8W4 cuboctahedra. Rh(1) is bonded to four equivalent W(1) and eight equivalent Rh(1) atoms to form RhRh8W4 cuboctahedra that share corners with four equivalent W(1)Rh12 cuboctahedra, corners with fourteen equivalent Rh(1)Rh8W4 cuboctahedra, edges with six equivalent W(1)Rh12 cuboctahedra, edges with twelve equivalent Rh(1)Rh8W4 cuboctahedra, faces with four equivalent W(1)Rh12 cuboctahedra, and faces with sixteen equivalent Rh(1)Rh8W4 cuboctahedra. is represented by the CIF file [CIF]
data_Rh3W
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.477
_cell_length_b   5.477
_cell_length_c   4.344
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   112.840
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rh  Rh0  1  0.833  0.667  0.250  1.0
  Rh  Rh1  1  0.167  0.833  0.750  1.0
  Rh  Rh2  1  0.667  0.833  0.750  1.0
  Rh  Rh3  1  0.333  0.167  0.250  1.0
  Rh  Rh4  1  0.833  0.167  0.250  1.0
  Rh  Rh5  1  0.167  0.333  0.750  1.0
  W  W6  1  0.333  0.667  0.250  1.0
  W  W7  1  0.667  0.333  0.750  1.0
[/CIF]
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