The crystal structure described by Rb2PdC4N4O crystallizes in the orthorhombic Pnna space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 7-coordinate geometry to two equivalent N(2), four equivalent N(1), and one O(1) atom. In the second Rb site, Rb(2) is bonded in a 8-coordinate geometry to two equivalent N(1), four equivalent N(2), and two equivalent O(1) atoms. Pd(1) is bonded in a square co-planar geometry to two equivalent C(1) and two equivalent C(2) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one Pd(1) and one N(1) atom. In the second C site, C(2) is bonded in a distorted linear geometry to one Pd(1) and one N(2) atom. There are two inequivalent N sites. In the first N site, N(2) is bonded in a distorted single-bond geometry to one Rb(1), two equivalent Rb(2), and one C(2) atom. In the second N site, N(1) is bonded in a distorted single-bond geometry to one Rb(2), two equivalent Rb(1), and one C(1) atom. O(1) is bonded in a T-shaped geometry to one Rb(1) and two equivalent Rb(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Rb2PdC4N4O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.716
_cell_length_b   9.967
_cell_length_c   13.880
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1067.487
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.308  0.250  0.750  1.0
  Rb  Rb1  1  0.192  0.750  0.750  1.0
  Rb  Rb2  1  0.692  0.750  0.250  1.0
  Rb  Rb3  1  0.808  0.250  0.250  1.0
  Rb  Rb4  1  0.750  0.000  0.599  1.0
  Rb  Rb5  1  0.750  0.500  0.901  1.0
  Rb  Rb6  1  0.250  0.000  0.401  1.0
  Rb  Rb7  1  0.250  0.500  0.099  1.0
  Pd  Pd8  1  0.500  0.500  0.500  1.0
  Pd  Pd9  1  0.000  0.500  0.500  1.0
  Pd  Pd10  1  0.500  0.000  0.000  1.0
  Pd  Pd11  1  0.000  0.000  0.000  1.0
  C  C12  1  0.002  0.471  0.642  1.0
  C  C13  1  0.498  0.529  0.642  1.0
  C  C14  1  0.002  0.029  0.858  1.0
  C  C15  1  0.498  0.971  0.858  1.0
  C  C16  1  0.998  0.529  0.358  1.0
  C  C17  1  0.502  0.471  0.358  1.0
  C  C18  1  0.998  0.971  0.142  1.0
  C  C19  1  0.502  0.029  0.142  1.0
  C  C20  1  0.969  0.303  0.480  1.0
  C  C21  1  0.531  0.697  0.480  1.0
  C  C22  1  0.969  0.197  0.020  1.0
  C  C23  1  0.531  0.803  0.020  1.0
  C  C24  1  0.031  0.697  0.520  1.0
  C  C25  1  0.469  0.303  0.520  1.0
  C  C26  1  0.031  0.803  0.980  1.0
  C  C27  1  0.469  0.197  0.980  1.0
  N  N28  1  0.011  0.457  0.726  1.0
  N  N29  1  0.489  0.543  0.726  1.0
  N  N30  1  0.011  0.043  0.774  1.0
  N  N31  1  0.489  0.957  0.774  1.0
  N  N32  1  0.989  0.543  0.274  1.0
  N  N33  1  0.511  0.457  0.274  1.0
  N  N34  1  0.989  0.957  0.226  1.0
  N  N35  1  0.511  0.043  0.226  1.0
  N  N36  1  0.951  0.188  0.465  1.0
  N  N37  1  0.549  0.812  0.465  1.0
  N  N38  1  0.951  0.312  0.035  1.0
  N  N39  1  0.549  0.688  0.035  1.0
  N  N40  1  0.049  0.812  0.535  1.0
  N  N41  1  0.451  0.188  0.535  1.0
  N  N42  1  0.049  0.688  0.965  1.0
  N  N43  1  0.451  0.312  0.965  1.0
  O  O44  1  0.718  0.250  0.750  1.0
  O  O45  1  0.782  0.750  0.750  1.0
  O  O46  1  0.282  0.750  0.250  1.0
  O  O47  1  0.218  0.250  0.250  1.0
[/CIF]
.
The crystal structure described by Rb2PdC4N4O crystallizes in the orthorhombic Pnna space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 7-coordinate geometry to two equivalent N(2), four equivalent N(1), and one O(1) atom. In the second Rb site, Rb(2) is bonded in a 8-coordinate geometry to two equivalent N(1), four equivalent N(2), and two equivalent O(1) atoms. Pd(1) is bonded in a square co-planar geometry to two equivalent C(1) and two equivalent C(2) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one Pd(1) and one N(1) atom. In the second C site, C(2) is bonded in a distorted linear geometry to one Pd(1) and one N(2) atom. There are two inequivalent N sites. In the first N site, N(2) is bonded in a distorted single-bond geometry to one Rb(1), two equivalent Rb(2), and one C(2) atom. In the second N site, N(1) is bonded in a distorted single-bond geometry to one Rb(2), two equivalent Rb(1), and one C(1) atom. O(1) is bonded in a T-shaped geometry to one Rb(1) and two equivalent Rb(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Rb2PdC4N4O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.716
_cell_length_b   9.967
_cell_length_c   13.880
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1067.487
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.308  0.250  0.750  1.0
  Rb  Rb1  1  0.192  0.750  0.750  1.0
  Rb  Rb2  1  0.692  0.750  0.250  1.0
  Rb  Rb3  1  0.808  0.250  0.250  1.0
  Rb  Rb4  1  0.750  0.000  0.599  1.0
  Rb  Rb5  1  0.750  0.500  0.901  1.0
  Rb  Rb6  1  0.250  0.000  0.401  1.0
  Rb  Rb7  1  0.250  0.500  0.099  1.0
  Pd  Pd8  1  0.500  0.500  0.500  1.0
  Pd  Pd9  1  0.000  0.500  0.500  1.0
  Pd  Pd10  1  0.500  0.000  0.000  1.0
  Pd  Pd11  1  0.000  0.000  0.000  1.0
  C  C12  1  0.002  0.471  0.642  1.0
  C  C13  1  0.498  0.529  0.642  1.0
  C  C14  1  0.002  0.029  0.858  1.0
  C  C15  1  0.498  0.971  0.858  1.0
  C  C16  1  0.998  0.529  0.358  1.0
  C  C17  1  0.502  0.471  0.358  1.0
  C  C18  1  0.998  0.971  0.142  1.0
  C  C19  1  0.502  0.029  0.142  1.0
  C  C20  1  0.969  0.303  0.480  1.0
  C  C21  1  0.531  0.697  0.480  1.0
  C  C22  1  0.969  0.197  0.020  1.0
  C  C23  1  0.531  0.803  0.020  1.0
  C  C24  1  0.031  0.697  0.520  1.0
  C  C25  1  0.469  0.303  0.520  1.0
  C  C26  1  0.031  0.803  0.980  1.0
  C  C27  1  0.469  0.197  0.980  1.0
  N  N28  1  0.011  0.457  0.726  1.0
  N  N29  1  0.489  0.543  0.726  1.0
  N  N30  1  0.011  0.043  0.774  1.0
  N  N31  1  0.489  0.957  0.774  1.0
  N  N32  1  0.989  0.543  0.274  1.0
  N  N33  1  0.511  0.457  0.274  1.0
  N  N34  1  0.989  0.957  0.226  1.0
  N  N35  1  0.511  0.043  0.226  1.0
  N  N36  1  0.951  0.188  0.465  1.0
  N  N37  1  0.549  0.812  0.465  1.0
  N  N38  1  0.951  0.312  0.035  1.0
  N  N39  1  0.549  0.688  0.035  1.0
  N  N40  1  0.049  0.812  0.535  1.0
  N  N41  1  0.451  0.188  0.535  1.0
  N  N42  1  0.049  0.688  0.965  1.0
  N  N43  1  0.451  0.312  0.965  1.0
  O  O44  1  0.718  0.250  0.750  1.0
  O  O45  1  0.782  0.750  0.750  1.0
  O  O46  1  0.282  0.750  0.250  1.0
  O  O47  1  0.218  0.250  0.250  1.0
[/CIF]
.