The compound described by Pr2Rh3Ge5 crystallizes in the orthorhombic Ibam space group. Pr(1) is bonded in a 17-coordinate geometry to two equivalent Rh(2), five equivalent Rh(1), two equivalent Ge(1), four equivalent Ge(2), and four equivalent Ge(3) atoms. There are two inequivalent Rh sites. In the first Rh site, Rh(2) is bonded in a 6-coordinate geometry to four equivalent Pr(1), two equivalent Ge(2), and four equivalent Ge(3) atoms. In the second Rh site, Rh(1) is bonded in a 5-coordinate geometry to five equivalent Pr(1), one Ge(3), two equivalent Ge(1), and two equivalent Ge(2) atoms. There are three inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 8-coordinate geometry to four equivalent Pr(1) and four equivalent Rh(1) atoms. In the second Ge site, Ge(2) is bonded in a 9-coordinate geometry to four equivalent Pr(1), one Rh(2), two equivalent Rh(1), and two equivalent Ge(3) atoms. In the third Ge site, Ge(3) is bonded in a 9-coordinate geometry to four equivalent Pr(1), one Rh(1), two equivalent Rh(2), and two equivalent Ge(2) atoms. is represented by the CIF card [CIF]
data_Pr2Ge5Rh3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.434
_cell_length_b   8.434
_cell_length_c   8.433
_cell_angle_alpha   137.768
_cell_angle_beta   106.333
_cell_angle_gamma   88.759
_symmetry_Int_Tables_number   1
_cell_volume   370.432
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pr  Pr0  1  0.864  0.632  0.231  1.0
  Pr  Pr1  1  0.136  0.368  0.769  1.0
  Pr  Pr2  1  0.599  0.868  0.731  1.0
  Pr  Pr3  1  0.401  0.132  0.269  1.0
  Ge  Ge4  1  0.500  0.750  0.250  1.0
  Ge  Ge5  1  0.500  0.250  0.750  1.0
  Ge  Ge6  1  0.224  0.974  0.750  1.0
  Ge  Ge7  1  0.776  0.526  0.750  1.0
  Ge  Ge8  1  0.776  0.026  0.250  1.0
  Ge  Ge9  1  0.224  0.474  0.250  1.0
  Ge  Ge10  1  0.057  0.899  0.158  1.0
  Ge  Ge11  1  0.943  0.101  0.842  1.0
  Ge  Ge12  1  0.258  0.601  0.658  1.0
  Ge  Ge13  1  0.742  0.399  0.342  1.0
  Rh  Rh14  1  0.253  0.860  0.393  1.0
  Rh  Rh15  1  0.747  0.140  0.607  1.0
  Rh  Rh16  1  0.533  0.640  0.893  1.0
  Rh  Rh17  1  0.467  0.360  0.107  1.0
  Rh  Rh18  1  0.000  0.750  0.750  1.0
  Rh  Rh19  1  1.000  0.250  0.250  1.0
[/CIF]
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The compound described by Pr2Rh3Ge5 crystallizes in the orthorhombic Ibam space group. Pr(1) is bonded in a 17-coordinate geometry to two equivalent Rh(2), five equivalent Rh(1), two equivalent Ge(1), four equivalent Ge(2), and four equivalent Ge(3) atoms. There are two inequivalent Rh sites. In the first Rh site, Rh(2) is bonded in a 6-coordinate geometry to four equivalent Pr(1), two equivalent Ge(2), and four equivalent Ge(3) atoms. In the second Rh site, Rh(1) is bonded in a 5-coordinate geometry to five equivalent Pr(1), one Ge(3), two equivalent Ge(1), and two equivalent Ge(2) atoms. There are three inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 8-coordinate geometry to four equivalent Pr(1) and four equivalent Rh(1) atoms. In the second Ge site, Ge(2) is bonded in a 9-coordinate geometry to four equivalent Pr(1), one Rh(2), two equivalent Rh(1), and two equivalent Ge(3) atoms. In the third Ge site, Ge(3) is bonded in a 9-coordinate geometry to four equivalent Pr(1), one Rh(1), two equivalent Rh(2), and two equivalent Ge(2) atoms. is represented by the CIF card [CIF]
data_Pr2Ge5Rh3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.434
_cell_length_b   8.434
_cell_length_c   8.433
_cell_angle_alpha   137.768
_cell_angle_beta   106.333
_cell_angle_gamma   88.759
_symmetry_Int_Tables_number   1
_cell_volume   370.432
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pr  Pr0  1  0.864  0.632  0.231  1.0
  Pr  Pr1  1  0.136  0.368  0.769  1.0
  Pr  Pr2  1  0.599  0.868  0.731  1.0
  Pr  Pr3  1  0.401  0.132  0.269  1.0
  Ge  Ge4  1  0.500  0.750  0.250  1.0
  Ge  Ge5  1  0.500  0.250  0.750  1.0
  Ge  Ge6  1  0.224  0.974  0.750  1.0
  Ge  Ge7  1  0.776  0.526  0.750  1.0
  Ge  Ge8  1  0.776  0.026  0.250  1.0
  Ge  Ge9  1  0.224  0.474  0.250  1.0
  Ge  Ge10  1  0.057  0.899  0.158  1.0
  Ge  Ge11  1  0.943  0.101  0.842  1.0
  Ge  Ge12  1  0.258  0.601  0.658  1.0
  Ge  Ge13  1  0.742  0.399  0.342  1.0
  Rh  Rh14  1  0.253  0.860  0.393  1.0
  Rh  Rh15  1  0.747  0.140  0.607  1.0
  Rh  Rh16  1  0.533  0.640  0.893  1.0
  Rh  Rh17  1  0.467  0.360  0.107  1.0
  Rh  Rh18  1  0.000  0.750  0.750  1.0
  Rh  Rh19  1  1.000  0.250  0.250  1.0
[/CIF]
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