The structure described by Co(IO3)2 crystallizes in the orthorhombic P2_12_12_1 space group. Co(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Co(1) and one I(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Co(1), one I(1), and one I(2) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Co(1) and two equivalent I(2) atoms. In the fourth O site, O(4) is bonded in a water-like geometry to one Co(1) and one I(1) atom. In the fifth O site, O(5) is bonded in a distorted water-like geometry to one Co(1), one I(1), and one I(2) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Co(1) and two equivalent I(1) atoms. There are two inequivalent I sites. In the first I site, I(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(4), one O(5), and two equivalent O(6) atoms. In the second I site, I(2) is bonded in a 3-coordinate geometry to one O(2), one O(5), and two equivalent O(3) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Co(IO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.372
_cell_length_b   5.659
_cell_length_c   17.746
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   539.483
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.723  0.172  0.100  1.0
  Co  Co1  1  0.223  0.328  0.900  1.0
  Co  Co2  1  0.277  0.672  0.400  1.0
  Co  Co3  1  0.777  0.828  0.600  1.0
  I  I4  1  0.977  0.140  0.425  1.0
  I  I5  1  0.257  0.219  0.206  1.0
  I  I6  1  0.757  0.281  0.794  1.0
  I  I7  1  0.477  0.360  0.575  1.0
  I  I8  1  0.023  0.640  0.075  1.0
  I  I9  1  0.743  0.719  0.294  1.0
  I  I10  1  0.243  0.781  0.706  1.0
  I  I11  1  0.523  0.860  0.925  1.0
  O  O12  1  0.102  0.002  0.336  1.0
  O  O13  1  0.029  0.022  0.158  1.0
  O  O14  1  0.521  0.012  0.204  1.0
  O  O15  1  0.419  0.118  0.980  1.0
  O  O16  1  0.893  0.131  0.878  1.0
  O  O17  1  0.746  0.166  0.549  1.0
  O  O18  1  0.246  0.334  0.451  1.0
  O  O19  1  0.393  0.369  0.122  1.0
  O  O20  1  0.919  0.382  0.020  1.0
  O  O21  1  0.021  0.488  0.796  1.0
  O  O22  1  0.529  0.478  0.842  1.0
  O  O23  1  0.602  0.498  0.664  1.0
  O  O24  1  0.898  0.502  0.164  1.0
  O  O25  1  0.971  0.522  0.342  1.0
  O  O26  1  0.479  0.512  0.296  1.0
  O  O27  1  0.581  0.618  0.520  1.0
  O  O28  1  0.107  0.631  0.622  1.0
  O  O29  1  0.254  0.666  0.951  1.0
  O  O30  1  0.754  0.834  0.049  1.0
  O  O31  1  0.607  0.869  0.378  1.0
  O  O32  1  0.081  0.882  0.480  1.0
  O  O33  1  0.979  0.988  0.704  1.0
  O  O34  1  0.471  0.978  0.658  1.0
  O  O35  1  0.398  0.998  0.836  1.0
[/CIF]
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The structure described by Co(IO3)2 crystallizes in the orthorhombic P2_12_12_1 space group. Co(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Co(1) and one I(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Co(1), one I(1), and one I(2) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Co(1) and two equivalent I(2) atoms. In the fourth O site, O(4) is bonded in a water-like geometry to one Co(1) and one I(1) atom. In the fifth O site, O(5) is bonded in a distorted water-like geometry to one Co(1), one I(1), and one I(2) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Co(1) and two equivalent I(1) atoms. There are two inequivalent I sites. In the first I site, I(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(4), one O(5), and two equivalent O(6) atoms. In the second I site, I(2) is bonded in a 3-coordinate geometry to one O(2), one O(5), and two equivalent O(3) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Co(IO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.372
_cell_length_b   5.659
_cell_length_c   17.746
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   539.483
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.723  0.172  0.100  1.0
  Co  Co1  1  0.223  0.328  0.900  1.0
  Co  Co2  1  0.277  0.672  0.400  1.0
  Co  Co3  1  0.777  0.828  0.600  1.0
  I  I4  1  0.977  0.140  0.425  1.0
  I  I5  1  0.257  0.219  0.206  1.0
  I  I6  1  0.757  0.281  0.794  1.0
  I  I7  1  0.477  0.360  0.575  1.0
  I  I8  1  0.023  0.640  0.075  1.0
  I  I9  1  0.743  0.719  0.294  1.0
  I  I10  1  0.243  0.781  0.706  1.0
  I  I11  1  0.523  0.860  0.925  1.0
  O  O12  1  0.102  0.002  0.336  1.0
  O  O13  1  0.029  0.022  0.158  1.0
  O  O14  1  0.521  0.012  0.204  1.0
  O  O15  1  0.419  0.118  0.980  1.0
  O  O16  1  0.893  0.131  0.878  1.0
  O  O17  1  0.746  0.166  0.549  1.0
  O  O18  1  0.246  0.334  0.451  1.0
  O  O19  1  0.393  0.369  0.122  1.0
  O  O20  1  0.919  0.382  0.020  1.0
  O  O21  1  0.021  0.488  0.796  1.0
  O  O22  1  0.529  0.478  0.842  1.0
  O  O23  1  0.602  0.498  0.664  1.0
  O  O24  1  0.898  0.502  0.164  1.0
  O  O25  1  0.971  0.522  0.342  1.0
  O  O26  1  0.479  0.512  0.296  1.0
  O  O27  1  0.581  0.618  0.520  1.0
  O  O28  1  0.107  0.631  0.622  1.0
  O  O29  1  0.254  0.666  0.951  1.0
  O  O30  1  0.754  0.834  0.049  1.0
  O  O31  1  0.607  0.869  0.378  1.0
  O  O32  1  0.081  0.882  0.480  1.0
  O  O33  1  0.979  0.988  0.704  1.0
  O  O34  1  0.471  0.978  0.658  1.0
  O  O35  1  0.398  0.998  0.836  1.0
[/CIF]
.