The material structure described by CsCo(CN)6(N(CH3)4)2 crystallizes in the monoclinic C2/m space group. The structure consists of four tetramethylammonium molecules inside a CsCo(CN)6 framework. In the CsCo(CN)6 framework, Cs(1) is bonded in an octahedral geometry to two equivalent N(1) and four equivalent N(2) atoms. Co(1) is bonded in an octahedral geometry to two equivalent C(1) and four equivalent C(2) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Co(1) and one N(1) atom. In the second C site, C(2) is bonded in a linear geometry to one Co(1) and one N(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Cs(1) and one C(1) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Cs(1) and one C(2) atom. is represented by the CIF card [CIF]
data_CsCoH24(C7N4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.527
_cell_length_b   9.527
_cell_length_c   9.538
_cell_angle_alpha   60.577
_cell_angle_beta   60.577
_cell_angle_gamma   60.156
_symmetry_Int_Tables_number   1
_cell_volume   618.185
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.500  0.500  0.500  1.0
  Co  Co1  1  0.000  0.000  0.000  1.0
  H  H2  1  0.244  0.244  0.480  1.0
  H  H3  1  0.756  0.756  0.520  1.0
  H  H4  1  0.251  0.440  0.304  1.0
  H  H5  1  0.560  0.749  0.696  1.0
  H  H6  1  0.749  0.560  0.696  1.0
  H  H7  1  0.440  0.251  0.304  1.0
  H  H8  1  0.285  0.285  0.004  1.0
  H  H9  1  0.715  0.715  0.996  1.0
  H  H10  1  0.275  0.464  0.032  1.0
  H  H11  1  0.536  0.725  0.968  1.0
  H  H12  1  0.725  0.536  0.968  1.0
  H  H13  1  0.464  0.275  0.032  1.0
  H  H14  1  0.005  0.260  0.440  1.0
  H  H15  1  0.740  0.995  0.560  1.0
  H  H16  1  0.995  0.740  0.560  1.0
  H  H17  1  0.260  0.005  0.440  1.0
  H  H18  1  0.024  0.278  0.234  1.0
  H  H19  1  0.722  0.976  0.766  1.0
  H  H20  1  0.976  0.722  0.766  1.0
  H  H21  1  0.278  0.024  0.234  1.0
  H  H22  1  0.016  0.455  0.264  1.0
  H  H23  1  0.545  0.984  0.736  1.0
  H  H24  1  0.984  0.545  0.736  1.0
  H  H25  1  0.455  0.016  0.264  1.0
  C  C26  1  0.139  0.139  0.872  1.0
  C  C27  1  0.861  0.861  0.128  1.0
  C  C28  1  0.864  0.144  0.857  1.0
  C  C29  1  0.856  0.136  0.143  1.0
  C  C30  1  0.136  0.856  0.143  1.0
  C  C31  1  0.144  0.864  0.857  1.0
  C  C32  1  0.300  0.300  0.343  1.0
  C  C33  1  0.700  0.700  0.657  1.0
  C  C34  1  0.324  0.324  0.066  1.0
  C  C35  1  0.676  0.676  0.934  1.0
  C  C36  1  0.059  0.316  0.302  1.0
  C  C37  1  0.684  0.941  0.698  1.0
  C  C38  1  0.941  0.684  0.698  1.0
  C  C39  1  0.316  0.059  0.302  1.0
  N  N40  1  0.225  0.225  0.791  1.0
  N  N41  1  0.775  0.775  0.209  1.0
  N  N42  1  0.778  0.234  0.768  1.0
  N  N43  1  0.766  0.222  0.232  1.0
  N  N44  1  0.222  0.766  0.232  1.0
  N  N45  1  0.234  0.778  0.768  1.0
  N  N46  1  0.249  0.249  0.254  1.0
  N  N47  1  0.751  0.751  0.746  1.0
[/CIF]
.
The material structure described by CsCo(CN)6(N(CH3)4)2 crystallizes in the monoclinic C2/m space group. The structure consists of four tetramethylammonium molecules inside a CsCo(CN)6 framework. In the CsCo(CN)6 framework, Cs(1) is bonded in an octahedral geometry to two equivalent N(1) and four equivalent N(2) atoms. Co(1) is bonded in an octahedral geometry to two equivalent C(1) and four equivalent C(2) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Co(1) and one N(1) atom. In the second C site, C(2) is bonded in a linear geometry to one Co(1) and one N(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Cs(1) and one C(1) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Cs(1) and one C(2) atom. is represented by the CIF card [CIF]
data_CsCoH24(C7N4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.527
_cell_length_b   9.527
_cell_length_c   9.538
_cell_angle_alpha   60.577
_cell_angle_beta   60.577
_cell_angle_gamma   60.156
_symmetry_Int_Tables_number   1
_cell_volume   618.185
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.500  0.500  0.500  1.0
  Co  Co1  1  0.000  0.000  0.000  1.0
  H  H2  1  0.244  0.244  0.480  1.0
  H  H3  1  0.756  0.756  0.520  1.0
  H  H4  1  0.251  0.440  0.304  1.0
  H  H5  1  0.560  0.749  0.696  1.0
  H  H6  1  0.749  0.560  0.696  1.0
  H  H7  1  0.440  0.251  0.304  1.0
  H  H8  1  0.285  0.285  0.004  1.0
  H  H9  1  0.715  0.715  0.996  1.0
  H  H10  1  0.275  0.464  0.032  1.0
  H  H11  1  0.536  0.725  0.968  1.0
  H  H12  1  0.725  0.536  0.968  1.0
  H  H13  1  0.464  0.275  0.032  1.0
  H  H14  1  0.005  0.260  0.440  1.0
  H  H15  1  0.740  0.995  0.560  1.0
  H  H16  1  0.995  0.740  0.560  1.0
  H  H17  1  0.260  0.005  0.440  1.0
  H  H18  1  0.024  0.278  0.234  1.0
  H  H19  1  0.722  0.976  0.766  1.0
  H  H20  1  0.976  0.722  0.766  1.0
  H  H21  1  0.278  0.024  0.234  1.0
  H  H22  1  0.016  0.455  0.264  1.0
  H  H23  1  0.545  0.984  0.736  1.0
  H  H24  1  0.984  0.545  0.736  1.0
  H  H25  1  0.455  0.016  0.264  1.0
  C  C26  1  0.139  0.139  0.872  1.0
  C  C27  1  0.861  0.861  0.128  1.0
  C  C28  1  0.864  0.144  0.857  1.0
  C  C29  1  0.856  0.136  0.143  1.0
  C  C30  1  0.136  0.856  0.143  1.0
  C  C31  1  0.144  0.864  0.857  1.0
  C  C32  1  0.300  0.300  0.343  1.0
  C  C33  1  0.700  0.700  0.657  1.0
  C  C34  1  0.324  0.324  0.066  1.0
  C  C35  1  0.676  0.676  0.934  1.0
  C  C36  1  0.059  0.316  0.302  1.0
  C  C37  1  0.684  0.941  0.698  1.0
  C  C38  1  0.941  0.684  0.698  1.0
  C  C39  1  0.316  0.059  0.302  1.0
  N  N40  1  0.225  0.225  0.791  1.0
  N  N41  1  0.775  0.775  0.209  1.0
  N  N42  1  0.778  0.234  0.768  1.0
  N  N43  1  0.766  0.222  0.232  1.0
  N  N44  1  0.222  0.766  0.232  1.0
  N  N45  1  0.234  0.778  0.768  1.0
  N  N46  1  0.249  0.249  0.254  1.0
  N  N47  1  0.751  0.751  0.746  1.0
[/CIF]
.