The compound described by Li4Mn(TeO4)3 is Ilmenite-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded in a 5-coordinate geometry to one O(2), one O(4), one O(5), one O(7), and one O(8) atom. In the second Li site, Li(2) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(11), one O(3), one O(6), and one O(9) atom. In the third Li site, Li(3) is bonded to one O(1), one O(11), one O(12), one O(3), one O(5), and one O(6) atom to form distorted LiO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent Te(3)O6 octahedra,  an edgeedge with one Te(1)O6 octahedra, edges with two equivalent Te(2)O6 octahedra, and  a faceface with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-64°. In the fourth Li site, Li(4) is bonded in a 6-coordinate geometry to one O(10), one O(2), one O(4), one O(7), one O(8), and one O(9) atom. Mn(1) is bonded to one O(1), one O(11), one O(5), one O(6), one O(8), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra, corners with two equivalent Te(1)O6 octahedra, corners with four equivalent Te(2)O6 octahedra, and  a faceface with one Li(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 35-64°. There are three inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(1), one O(10), one O(12), one O(2), one O(7), and one O(8) atom to form TeO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with four equivalent Te(3)O6 octahedra, and  an edgeedge with one Li(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-43°. In the second Te site, Te(2) is bonded to one O(11), one O(3), one O(4), one O(5), one O(6), and one O(9) atom to form TeO6 octahedra that share corners with two equivalent Te(3)O6 octahedra, corners with four equivalent Mn(1)O6 octahedra, and edges with two equivalent Li(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 35-43°. In the third Te site, Te(3) is bonded to one O(10), one O(12), one O(2), one O(3), one O(4), and one O(7) atom to form TeO6 octahedra that share corners with two equivalent Li(3)O6 octahedra, corners with two equivalent Te(2)O6 octahedra, and corners with four equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-59°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted see-saw-like geometry to one Li(2), one Li(3), one Mn(1), and one Te(1) atom. In the second O site, O(2) is bonded to one Li(1), one Li(4), one Te(1), and one Te(3) atom to form distorted OLi2Te2 trigonal pyramids that share  a cornercorner with one O(9)Li2MnTe tetrahedra, corners with three equivalent O(8)Li2MnTe tetrahedra,  a cornercorner with one O(4)Li2Te2 trigonal pyramid, edges with two equivalent O(7)Li2Te2 tetrahedra, and  an edgeedge with one O(4)Li2Te2 trigonal pyramid. In the third O site, O(3) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one Li(3), one Te(2), and one Te(3) atom. In the fourth O site, O(4) is bonded to one Li(1), one Li(4), one Te(2), and one Te(3) atom to form distorted OLi2Te2 trigonal pyramids that share corners with two equivalent O(8)Li2MnTe tetrahedra, corners with three equivalent O(7)Li2Te2 tetrahedra,  a cornercorner with one O(2)Li2Te2 trigonal pyramid,  an edgeedge with one O(9)Li2MnTe tetrahedra, and  an edgeedge with one O(2)Li2Te2 trigonal pyramid. In the fifth O site, O(5) is bonded in a distorted see-saw-like geometry to one Li(1), one Li(3), one Mn(1), and one Te(2) atom. In the sixth O site, O(6) is bonded in a distorted see-saw-like geometry to one Li(2), one Li(3), one Mn(1), and one Te(2) atom. In the seventh O site, O(7) is bonded to one Li(1), one Li(4), one Te(1), and one Te(3) atom to form distorted OLi2Te2 tetrahedra that share  a cornercorner with one O(8)Li2MnTe tetrahedra,  a cornercorner with one O(9)Li2MnTe tetrahedra, corners with three equivalent O(4)Li2Te2 trigonal pyramids,  an edgeedge with one O(8)Li2MnTe tetrahedra, and edges with two equivalent O(2)Li2Te2 trigonal pyramids. In the eighth O site, O(8) is bonded to one Li(1), one Li(4), one Mn(1), and one Te(1) atom to form distorted OLi2MnTe tetrahedra that share  a cornercorner with one O(7)Li2Te2 tetrahedra, corners with two equivalent O(9)Li2MnTe tetrahedra, corners with two equivalent O(4)Li2Te2 trigonal pyramids, corners with three equivalent O(2)Li2Te2 trigonal pyramids, and  an edgeedge with one O(7)Li2Te2 tetrahedra. In the ninth O site, O(9) is bonded to one Li(2), one Li(4), one Mn(1), and one Te(2) atom to form OLi2MnTe tetrahedra that share  a cornercorner with one O(7)Li2Te2 tetrahedra, corners with two equivalent O(8)Li2MnTe tetrahedra,  a cornercorner with one O(2)Li2Te2 trigonal pyramid, and  an edgeedge with one O(4)Li2Te2 trigonal pyramid. In the tenth O site, O(10) is bonded in a 4-coordinate geometry to one Li(2), one Li(4), one Te(1), and one Te(3) atom. In the eleventh O site, O(11) is bonded in a distorted see-saw-like geometry to one Li(2), one Li(3), one Mn(1), and one Te(2) atom. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to one Li(3), one Te(1), and one Te(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li4Mn(TeO4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.200
_cell_length_b   5.486
_cell_length_c   7.640
_cell_angle_alpha   85.862
_cell_angle_beta   89.737
_cell_angle_gamma   89.844
_symmetry_Int_Tables_number   1
_cell_volume   217.397
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.993  0.509  0.224  1.0
  Li  Li1  1  0.504  0.987  0.771  1.0
  Li  Li2  1  0.006  0.520  0.772  1.0
  Li  Li3  1  0.498  0.982  0.225  1.0
  Mn  Mn4  1  0.002  0.938  0.964  1.0
  Te  Te5  1  0.002  0.923  0.462  1.0
  Te  Te6  1  0.498  0.424  0.962  1.0
  Te  Te7  1  0.500  0.421  0.464  1.0
  O  O8  1  0.873  0.900  0.691  1.0
  O  O9  1  0.804  0.226  0.380  1.0
  O  O10  1  0.639  0.404  0.699  1.0
  O  O11  1  0.365  0.396  0.221  1.0
  O  O12  1  0.805  0.596  0.006  1.0
  O  O13  1  0.310  0.715  0.895  1.0
  O  O14  1  0.692  0.717  0.379  1.0
  O  O15  1  0.126  0.892  0.233  1.0
  O  O16  1  0.665  0.114  0.009  1.0
  O  O17  1  0.328  0.096  0.524  1.0
  O  O18  1  0.208  0.243  0.889  1.0
  O  O19  1  0.182  0.591  0.528  1.0
[/CIF]
.
The compound described by Li4Mn(TeO4)3 is Ilmenite-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded in a 5-coordinate geometry to one O(2), one O(4), one O(5), one O(7), and one O(8) atom. In the second Li site, Li(2) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(11), one O(3), one O(6), and one O(9) atom. In the third Li site, Li(3) is bonded to one O(1), one O(11), one O(12), one O(3), one O(5), and one O(6) atom to form distorted LiO6 octahedra that share  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent Te(3)O6 octahedra,  an edgeedge with one Te(1)O6 octahedra, edges with two equivalent Te(2)O6 octahedra, and  a faceface with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-64°. In the fourth Li site, Li(4) is bonded in a 6-coordinate geometry to one O(10), one O(2), one O(4), one O(7), one O(8), and one O(9) atom. Mn(1) is bonded to one O(1), one O(11), one O(5), one O(6), one O(8), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra, corners with two equivalent Te(1)O6 octahedra, corners with four equivalent Te(2)O6 octahedra, and  a faceface with one Li(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 35-64°. There are three inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(1), one O(10), one O(12), one O(2), one O(7), and one O(8) atom to form TeO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with four equivalent Te(3)O6 octahedra, and  an edgeedge with one Li(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-43°. In the second Te site, Te(2) is bonded to one O(11), one O(3), one O(4), one O(5), one O(6), and one O(9) atom to form TeO6 octahedra that share corners with two equivalent Te(3)O6 octahedra, corners with four equivalent Mn(1)O6 octahedra, and edges with two equivalent Li(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 35-43°. In the third Te site, Te(3) is bonded to one O(10), one O(12), one O(2), one O(3), one O(4), and one O(7) atom to form TeO6 octahedra that share corners with two equivalent Li(3)O6 octahedra, corners with two equivalent Te(2)O6 octahedra, and corners with four equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-59°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted see-saw-like geometry to one Li(2), one Li(3), one Mn(1), and one Te(1) atom. In the second O site, O(2) is bonded to one Li(1), one Li(4), one Te(1), and one Te(3) atom to form distorted OLi2Te2 trigonal pyramids that share  a cornercorner with one O(9)Li2MnTe tetrahedra, corners with three equivalent O(8)Li2MnTe tetrahedra,  a cornercorner with one O(4)Li2Te2 trigonal pyramid, edges with two equivalent O(7)Li2Te2 tetrahedra, and  an edgeedge with one O(4)Li2Te2 trigonal pyramid. In the third O site, O(3) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one Li(3), one Te(2), and one Te(3) atom. In the fourth O site, O(4) is bonded to one Li(1), one Li(4), one Te(2), and one Te(3) atom to form distorted OLi2Te2 trigonal pyramids that share corners with two equivalent O(8)Li2MnTe tetrahedra, corners with three equivalent O(7)Li2Te2 tetrahedra,  a cornercorner with one O(2)Li2Te2 trigonal pyramid,  an edgeedge with one O(9)Li2MnTe tetrahedra, and  an edgeedge with one O(2)Li2Te2 trigonal pyramid. In the fifth O site, O(5) is bonded in a distorted see-saw-like geometry to one Li(1), one Li(3), one Mn(1), and one Te(2) atom. In the sixth O site, O(6) is bonded in a distorted see-saw-like geometry to one Li(2), one Li(3), one Mn(1), and one Te(2) atom. In the seventh O site, O(7) is bonded to one Li(1), one Li(4), one Te(1), and one Te(3) atom to form distorted OLi2Te2 tetrahedra that share  a cornercorner with one O(8)Li2MnTe tetrahedra,  a cornercorner with one O(9)Li2MnTe tetrahedra, corners with three equivalent O(4)Li2Te2 trigonal pyramids,  an edgeedge with one O(8)Li2MnTe tetrahedra, and edges with two equivalent O(2)Li2Te2 trigonal pyramids. In the eighth O site, O(8) is bonded to one Li(1), one Li(4), one Mn(1), and one Te(1) atom to form distorted OLi2MnTe tetrahedra that share  a cornercorner with one O(7)Li2Te2 tetrahedra, corners with two equivalent O(9)Li2MnTe tetrahedra, corners with two equivalent O(4)Li2Te2 trigonal pyramids, corners with three equivalent O(2)Li2Te2 trigonal pyramids, and  an edgeedge with one O(7)Li2Te2 tetrahedra. In the ninth O site, O(9) is bonded to one Li(2), one Li(4), one Mn(1), and one Te(2) atom to form OLi2MnTe tetrahedra that share  a cornercorner with one O(7)Li2Te2 tetrahedra, corners with two equivalent O(8)Li2MnTe tetrahedra,  a cornercorner with one O(2)Li2Te2 trigonal pyramid, and  an edgeedge with one O(4)Li2Te2 trigonal pyramid. In the tenth O site, O(10) is bonded in a 4-coordinate geometry to one Li(2), one Li(4), one Te(1), and one Te(3) atom. In the eleventh O site, O(11) is bonded in a distorted see-saw-like geometry to one Li(2), one Li(3), one Mn(1), and one Te(2) atom. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to one Li(3), one Te(1), and one Te(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li4Mn(TeO4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.200
_cell_length_b   5.486
_cell_length_c   7.640
_cell_angle_alpha   85.862
_cell_angle_beta   89.737
_cell_angle_gamma   89.844
_symmetry_Int_Tables_number   1
_cell_volume   217.397
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.993  0.509  0.224  1.0
  Li  Li1  1  0.504  0.987  0.771  1.0
  Li  Li2  1  0.006  0.520  0.772  1.0
  Li  Li3  1  0.498  0.982  0.225  1.0
  Mn  Mn4  1  0.002  0.938  0.964  1.0
  Te  Te5  1  0.002  0.923  0.462  1.0
  Te  Te6  1  0.498  0.424  0.962  1.0
  Te  Te7  1  0.500  0.421  0.464  1.0
  O  O8  1  0.873  0.900  0.691  1.0
  O  O9  1  0.804  0.226  0.380  1.0
  O  O10  1  0.639  0.404  0.699  1.0
  O  O11  1  0.365  0.396  0.221  1.0
  O  O12  1  0.805  0.596  0.006  1.0
  O  O13  1  0.310  0.715  0.895  1.0
  O  O14  1  0.692  0.717  0.379  1.0
  O  O15  1  0.126  0.892  0.233  1.0
  O  O16  1  0.665  0.114  0.009  1.0
  O  O17  1  0.328  0.096  0.524  1.0
  O  O18  1  0.208  0.243  0.889  1.0
  O  O19  1  0.182  0.591  0.528  1.0
[/CIF]
.