The structure described by Hg7InS6Cl5 crystallizes in the triclinic P-1 space group. There are eight inequivalent Hg sites. In the first Hg site, Hg(1) is bonded in a linear geometry to two equivalent S(4) atoms. In the second Hg site, Hg(2) is bonded in a linear geometry to one S(4) and one S(6) atom. In the third Hg site, Hg(3) is bonded in a distorted T-shaped geometry to one S(2), one S(3), and one Cl(1) atom. In the fourth Hg site, Hg(4) is bonded in a linear geometry to one S(5) and one S(6) atom. In the fifth Hg site, Hg(5) is bonded in a distorted T-shaped geometry to one S(1), one S(3), and one S(4) atom. In the sixth Hg site, Hg(6) is bonded in a T-shaped geometry to one S(1), one S(3), and one Cl(1) atom. In the seventh Hg site, Hg(7) is bonded in a 3-coordinate geometry to one S(1), one S(2), and one S(5) atom. In the eighth Hg site, Hg(8) is bonded in a linear geometry to two equivalent S(2) atoms. In(1) is bonded in an octahedral geometry to one S(5), one S(6), one Cl(2), one Cl(3), one Cl(4), and one Cl(5) atom. There are six inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to one Hg(5), one Hg(6), and one Hg(7) atom. In the second S site, S(2) is bonded in a distorted trigonal non-coplanar geometry to one Hg(3), one Hg(7), and one Hg(8) atom. In the third S site, S(3) is bonded in a trigonal non-coplanar geometry to one Hg(3), one Hg(5), and one Hg(6) atom. In the fourth S site, S(4) is bonded in a trigonal non-coplanar geometry to one Hg(1), one Hg(2), and one Hg(5) atom. In the fifth S site, S(5) is bonded in a trigonal non-coplanar geometry to one Hg(4), one Hg(7), and one In(1) atom. In the sixth S site, S(6) is bonded in a distorted trigonal non-coplanar geometry to one Hg(2), one Hg(4), and one In(1) atom. There are five inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted bent 120 degrees geometry to one Hg(3) and one Hg(6) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one In(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one In(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one In(1) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one In(1) atom. is represented by the CIF file [CIF]
data_InHg7S6Cl5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.589
_cell_length_b   10.777
_cell_length_c   14.088
_cell_angle_alpha   109.696
_cell_angle_beta   105.458
_cell_angle_gamma   92.855
_symmetry_Int_Tables_number   1
_cell_volume   1033.087
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.886  0.139  0.323  1.0
  In  In1  1  0.114  0.861  0.677  1.0
  Hg  Hg2  1  0.000  0.000  0.000  1.0
  Hg  Hg3  1  0.373  0.957  0.227  1.0
  Hg  Hg4  1  0.627  0.043  0.773  1.0
  Hg  Hg5  1  0.624  0.544  0.773  1.0
  Hg  Hg6  1  0.376  0.456  0.227  1.0
  Hg  Hg7  1  0.719  0.881  0.435  1.0
  Hg  Hg8  1  0.281  0.119  0.565  1.0
  Hg  Hg9  1  0.308  0.703  0.938  1.0
  Hg  Hg10  1  0.692  0.297  0.062  1.0
  Hg  Hg11  1  0.216  0.362  0.940  1.0
  Hg  Hg12  1  0.784  0.638  0.060  1.0
  Hg  Hg13  1  0.017  0.386  0.660  1.0
  Hg  Hg14  1  0.983  0.614  0.340  1.0
  Hg  Hg15  1  0.500  0.500  0.500  1.0
  S  S16  1  0.045  0.495  0.850  1.0
  S  S17  1  0.955  0.505  0.150  1.0
  S  S18  1  0.637  0.381  0.610  1.0
  S  S19  1  0.363  0.619  0.390  1.0
  S  S20  1  0.628  0.729  0.929  1.0
  S  S21  1  0.372  0.271  0.071  1.0
  S  S22  1  0.135  0.835  0.063  1.0
  S  S23  1  0.865  0.165  0.937  1.0
  S  S24  1  0.872  0.716  0.490  1.0
  S  S25  1  0.128  0.284  0.510  1.0
  S  S26  1  0.606  0.069  0.395  1.0
  S  S27  1  0.394  0.931  0.605  1.0
  Cl  Cl28  1  0.489  0.323  0.832  1.0
  Cl  Cl29  1  0.511  0.677  0.168  1.0
  Cl  Cl30  1  0.681  0.030  0.137  1.0
  Cl  Cl31  1  0.319  0.970  0.863  1.0
  Cl  Cl32  1  0.138  0.205  0.253  1.0
  Cl  Cl33  1  0.862  0.795  0.747  1.0
  Cl  Cl34  1  0.024  0.927  0.327  1.0
  Cl  Cl35  1  0.976  0.073  0.673  1.0
  Cl  Cl36  1  0.751  0.357  0.336  1.0
  Cl  Cl37  1  0.249  0.643  0.664  1.0
[/CIF]
.
The structure described by Hg7InS6Cl5 crystallizes in the triclinic P-1 space group. There are eight inequivalent Hg sites. In the first Hg site, Hg(1) is bonded in a linear geometry to two equivalent S(4) atoms. In the second Hg site, Hg(2) is bonded in a linear geometry to one S(4) and one S(6) atom. In the third Hg site, Hg(3) is bonded in a distorted T-shaped geometry to one S(2), one S(3), and one Cl(1) atom. In the fourth Hg site, Hg(4) is bonded in a linear geometry to one S(5) and one S(6) atom. In the fifth Hg site, Hg(5) is bonded in a distorted T-shaped geometry to one S(1), one S(3), and one S(4) atom. In the sixth Hg site, Hg(6) is bonded in a T-shaped geometry to one S(1), one S(3), and one Cl(1) atom. In the seventh Hg site, Hg(7) is bonded in a 3-coordinate geometry to one S(1), one S(2), and one S(5) atom. In the eighth Hg site, Hg(8) is bonded in a linear geometry to two equivalent S(2) atoms. In(1) is bonded in an octahedral geometry to one S(5), one S(6), one Cl(2), one Cl(3), one Cl(4), and one Cl(5) atom. There are six inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to one Hg(5), one Hg(6), and one Hg(7) atom. In the second S site, S(2) is bonded in a distorted trigonal non-coplanar geometry to one Hg(3), one Hg(7), and one Hg(8) atom. In the third S site, S(3) is bonded in a trigonal non-coplanar geometry to one Hg(3), one Hg(5), and one Hg(6) atom. In the fourth S site, S(4) is bonded in a trigonal non-coplanar geometry to one Hg(1), one Hg(2), and one Hg(5) atom. In the fifth S site, S(5) is bonded in a trigonal non-coplanar geometry to one Hg(4), one Hg(7), and one In(1) atom. In the sixth S site, S(6) is bonded in a distorted trigonal non-coplanar geometry to one Hg(2), one Hg(4), and one In(1) atom. There are five inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted bent 120 degrees geometry to one Hg(3) and one Hg(6) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one In(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one In(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one In(1) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one In(1) atom. is represented by the CIF file [CIF]
data_InHg7S6Cl5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.589
_cell_length_b   10.777
_cell_length_c   14.088
_cell_angle_alpha   109.696
_cell_angle_beta   105.458
_cell_angle_gamma   92.855
_symmetry_Int_Tables_number   1
_cell_volume   1033.087
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.886  0.139  0.323  1.0
  In  In1  1  0.114  0.861  0.677  1.0
  Hg  Hg2  1  0.000  0.000  0.000  1.0
  Hg  Hg3  1  0.373  0.957  0.227  1.0
  Hg  Hg4  1  0.627  0.043  0.773  1.0
  Hg  Hg5  1  0.624  0.544  0.773  1.0
  Hg  Hg6  1  0.376  0.456  0.227  1.0
  Hg  Hg7  1  0.719  0.881  0.435  1.0
  Hg  Hg8  1  0.281  0.119  0.565  1.0
  Hg  Hg9  1  0.308  0.703  0.938  1.0
  Hg  Hg10  1  0.692  0.297  0.062  1.0
  Hg  Hg11  1  0.216  0.362  0.940  1.0
  Hg  Hg12  1  0.784  0.638  0.060  1.0
  Hg  Hg13  1  0.017  0.386  0.660  1.0
  Hg  Hg14  1  0.983  0.614  0.340  1.0
  Hg  Hg15  1  0.500  0.500  0.500  1.0
  S  S16  1  0.045  0.495  0.850  1.0
  S  S17  1  0.955  0.505  0.150  1.0
  S  S18  1  0.637  0.381  0.610  1.0
  S  S19  1  0.363  0.619  0.390  1.0
  S  S20  1  0.628  0.729  0.929  1.0
  S  S21  1  0.372  0.271  0.071  1.0
  S  S22  1  0.135  0.835  0.063  1.0
  S  S23  1  0.865  0.165  0.937  1.0
  S  S24  1  0.872  0.716  0.490  1.0
  S  S25  1  0.128  0.284  0.510  1.0
  S  S26  1  0.606  0.069  0.395  1.0
  S  S27  1  0.394  0.931  0.605  1.0
  Cl  Cl28  1  0.489  0.323  0.832  1.0
  Cl  Cl29  1  0.511  0.677  0.168  1.0
  Cl  Cl30  1  0.681  0.030  0.137  1.0
  Cl  Cl31  1  0.319  0.970  0.863  1.0
  Cl  Cl32  1  0.138  0.205  0.253  1.0
  Cl  Cl33  1  0.862  0.795  0.747  1.0
  Cl  Cl34  1  0.024  0.927  0.327  1.0
  Cl  Cl35  1  0.976  0.073  0.673  1.0
  Cl  Cl36  1  0.751  0.357  0.336  1.0
  Cl  Cl37  1  0.249  0.643  0.664  1.0
[/CIF]
.