The material structure described by Li2Co(WO4)2 crystallizes in the triclinic P-1 space group. Li(1) is bonded in a 6-coordinate geometry to one O(2), one O(4), two equivalent O(1), and two equivalent O(3) atoms. W(1) is bonded to one O(1), one O(4), two equivalent O(2), and two equivalent O(3) atoms to form distorted WO6 octahedra that share corners with four equivalent Co(1)O6 octahedra and edges with two equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 41-55°. Co(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms to form CoO6 octahedra that share corners with eight equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 41-55°. There are four inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Li(1), one W(1), and one Co(1) atom to form distorted OLi2CoW trigonal pyramids that share  a cornercorner with one O(1)Li2CoW trigonal pyramid, corners with two equivalent O(2)LiCoW2 trigonal pyramids,  an edgeedge with one O(1)Li2CoW trigonal pyramid, and edges with two equivalent O(2)LiCoW2 trigonal pyramids. In the second O site, O(2) is bonded to one Li(1), two equivalent W(1), and one Co(1) atom to form distorted OLiCoW2 trigonal pyramids that share  a cornercorner with one O(2)LiCoW2 trigonal pyramid, corners with two equivalent O(1)Li2CoW trigonal pyramids,  an edgeedge with one O(2)LiCoW2 trigonal pyramid, and edges with two equivalent O(1)Li2CoW trigonal pyramids. In the third O site, O(3) is bonded in a 4-coordinate geometry to two equivalent Li(1) and two equivalent W(1) atoms. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Li(1), one W(1), and one Co(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li2Co(WO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.043
_cell_length_b   5.686
_cell_length_c   5.934
_cell_angle_alpha   70.841
_cell_angle_beta   88.739
_cell_angle_gamma   64.024
_symmetry_Int_Tables_number   1
_cell_volume   143.004
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.500  0.000  0.000  1.0
  Li  Li1  1  0.042  0.919  0.749  1.0
  Li  Li2  1  0.958  0.081  0.251  1.0
  O  O3  1  0.727  0.239  0.923  1.0
  O  O4  1  0.273  0.761  0.077  1.0
  O  O5  1  0.830  0.722  0.333  1.0
  O  O6  1  0.170  0.278  0.667  1.0
  O  O7  1  0.318  0.719  0.544  1.0
  O  O8  1  0.682  0.281  0.456  1.0
  O  O9  1  0.246  0.246  0.194  1.0
  O  O10  1  0.754  0.754  0.806  1.0
  W  W11  1  0.732  0.525  0.662  1.0
  W  W12  1  0.268  0.475  0.338  1.0
[/CIF]
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The material structure described by Li2Co(WO4)2 crystallizes in the triclinic P-1 space group. Li(1) is bonded in a 6-coordinate geometry to one O(2), one O(4), two equivalent O(1), and two equivalent O(3) atoms. W(1) is bonded to one O(1), one O(4), two equivalent O(2), and two equivalent O(3) atoms to form distorted WO6 octahedra that share corners with four equivalent Co(1)O6 octahedra and edges with two equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 41-55°. Co(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms to form CoO6 octahedra that share corners with eight equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 41-55°. There are four inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Li(1), one W(1), and one Co(1) atom to form distorted OLi2CoW trigonal pyramids that share  a cornercorner with one O(1)Li2CoW trigonal pyramid, corners with two equivalent O(2)LiCoW2 trigonal pyramids,  an edgeedge with one O(1)Li2CoW trigonal pyramid, and edges with two equivalent O(2)LiCoW2 trigonal pyramids. In the second O site, O(2) is bonded to one Li(1), two equivalent W(1), and one Co(1) atom to form distorted OLiCoW2 trigonal pyramids that share  a cornercorner with one O(2)LiCoW2 trigonal pyramid, corners with two equivalent O(1)Li2CoW trigonal pyramids,  an edgeedge with one O(2)LiCoW2 trigonal pyramid, and edges with two equivalent O(1)Li2CoW trigonal pyramids. In the third O site, O(3) is bonded in a 4-coordinate geometry to two equivalent Li(1) and two equivalent W(1) atoms. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Li(1), one W(1), and one Co(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li2Co(WO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.043
_cell_length_b   5.686
_cell_length_c   5.934
_cell_angle_alpha   70.841
_cell_angle_beta   88.739
_cell_angle_gamma   64.024
_symmetry_Int_Tables_number   1
_cell_volume   143.004
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.500  0.000  0.000  1.0
  Li  Li1  1  0.042  0.919  0.749  1.0
  Li  Li2  1  0.958  0.081  0.251  1.0
  O  O3  1  0.727  0.239  0.923  1.0
  O  O4  1  0.273  0.761  0.077  1.0
  O  O5  1  0.830  0.722  0.333  1.0
  O  O6  1  0.170  0.278  0.667  1.0
  O  O7  1  0.318  0.719  0.544  1.0
  O  O8  1  0.682  0.281  0.456  1.0
  O  O9  1  0.246  0.246  0.194  1.0
  O  O10  1  0.754  0.754  0.806  1.0
  W  W11  1  0.732  0.525  0.662  1.0
  W  W12  1  0.268  0.475  0.338  1.0
[/CIF]
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