The structure described by NaBa(PO2NH)3 crystallizes in the monoclinic C2/m space group. Na(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms. Ba(1) is bonded in a 9-coordinate geometry to one N(2), two equivalent O(1), two equivalent O(3), and four equivalent O(2) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded to one N(1), one N(2), one O(1), and one O(2) atom to form corner-sharing PN2O2 tetrahedra. In the second P site, P(2) is bonded to two equivalent N(1), one O(3), and one O(4) atom to form corner-sharing PN2O2 tetrahedra. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one P(1), one P(2), and one H(2) atom. In the second N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one Ba(1), two equivalent P(1), and one H(1) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Na(1), one Ba(1), and one P(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Na(1), two equivalent Ba(1), and one P(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Ba(1) and one P(2) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to two equivalent Na(1) and one P(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_BaNaP3H3(NO2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.579
_cell_length_b   7.579
_cell_length_c   7.996
_cell_angle_alpha   71.873
_cell_angle_beta   71.873
_cell_angle_gamma   87.718
_symmetry_Int_Tables_number   1
_cell_volume   413.994
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.569  0.569  0.697  1.0
  Ba  Ba1  1  0.431  0.431  0.303  1.0
  Na  Na2  1  0.818  0.182  0.500  1.0
  Na  Na3  1  0.182  0.818  0.500  1.0
  P  P4  1  0.657  0.939  0.235  1.0
  P  P5  1  0.061  0.343  0.765  1.0
  P  P6  1  0.343  0.061  0.765  1.0
  P  P7  1  0.939  0.657  0.235  1.0
  P  P8  1  0.800  0.800  0.913  1.0
  P  P9  1  0.200  0.200  0.087  1.0
  H  H10  1  0.936  0.936  0.293  1.0
  H  H11  1  0.064  0.064  0.707  1.0
  H  H12  1  0.741  0.102  0.918  1.0
  H  H13  1  0.898  0.259  0.082  1.0
  H  H14  1  0.259  0.898  0.082  1.0
  H  H15  1  0.102  0.741  0.918  1.0
  N  N16  1  0.713  0.968  0.007  1.0
  N  N17  1  0.032  0.287  0.993  1.0
  N  N18  1  0.287  0.032  0.993  1.0
  N  N19  1  0.968  0.713  0.007  1.0
  N  N20  1  0.837  0.837  0.306  1.0
  N  N21  1  0.163  0.163  0.694  1.0
  O  O22  1  0.648  0.129  0.261  1.0
  O  O23  1  0.871  0.352  0.739  1.0
  O  O24  1  0.352  0.871  0.739  1.0
  O  O25  1  0.129  0.648  0.261  1.0
  O  O26  1  0.494  0.795  0.339  1.0
  O  O27  1  0.205  0.506  0.661  1.0
  O  O28  1  0.506  0.205  0.661  1.0
  O  O29  1  0.795  0.494  0.339  1.0
  O  O30  1  0.648  0.648  0.976  1.0
  O  O31  1  0.352  0.352  0.024  1.0
  O  O32  1  0.888  0.888  0.705  1.0
  O  O33  1  0.112  0.112  0.295  1.0
[/CIF]
.
The structure described by NaBa(PO2NH)3 crystallizes in the monoclinic C2/m space group. Na(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms. Ba(1) is bonded in a 9-coordinate geometry to one N(2), two equivalent O(1), two equivalent O(3), and four equivalent O(2) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded to one N(1), one N(2), one O(1), and one O(2) atom to form corner-sharing PN2O2 tetrahedra. In the second P site, P(2) is bonded to two equivalent N(1), one O(3), and one O(4) atom to form corner-sharing PN2O2 tetrahedra. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one P(1), one P(2), and one H(2) atom. In the second N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one Ba(1), two equivalent P(1), and one H(1) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Na(1), one Ba(1), and one P(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Na(1), two equivalent Ba(1), and one P(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Ba(1) and one P(2) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to two equivalent Na(1) and one P(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_BaNaP3H3(NO2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.579
_cell_length_b   7.579
_cell_length_c   7.996
_cell_angle_alpha   71.873
_cell_angle_beta   71.873
_cell_angle_gamma   87.718
_symmetry_Int_Tables_number   1
_cell_volume   413.994
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.569  0.569  0.697  1.0
  Ba  Ba1  1  0.431  0.431  0.303  1.0
  Na  Na2  1  0.818  0.182  0.500  1.0
  Na  Na3  1  0.182  0.818  0.500  1.0
  P  P4  1  0.657  0.939  0.235  1.0
  P  P5  1  0.061  0.343  0.765  1.0
  P  P6  1  0.343  0.061  0.765  1.0
  P  P7  1  0.939  0.657  0.235  1.0
  P  P8  1  0.800  0.800  0.913  1.0
  P  P9  1  0.200  0.200  0.087  1.0
  H  H10  1  0.936  0.936  0.293  1.0
  H  H11  1  0.064  0.064  0.707  1.0
  H  H12  1  0.741  0.102  0.918  1.0
  H  H13  1  0.898  0.259  0.082  1.0
  H  H14  1  0.259  0.898  0.082  1.0
  H  H15  1  0.102  0.741  0.918  1.0
  N  N16  1  0.713  0.968  0.007  1.0
  N  N17  1  0.032  0.287  0.993  1.0
  N  N18  1  0.287  0.032  0.993  1.0
  N  N19  1  0.968  0.713  0.007  1.0
  N  N20  1  0.837  0.837  0.306  1.0
  N  N21  1  0.163  0.163  0.694  1.0
  O  O22  1  0.648  0.129  0.261  1.0
  O  O23  1  0.871  0.352  0.739  1.0
  O  O24  1  0.352  0.871  0.739  1.0
  O  O25  1  0.129  0.648  0.261  1.0
  O  O26  1  0.494  0.795  0.339  1.0
  O  O27  1  0.205  0.506  0.661  1.0
  O  O28  1  0.506  0.205  0.661  1.0
  O  O29  1  0.795  0.494  0.339  1.0
  O  O30  1  0.648  0.648  0.976  1.0
  O  O31  1  0.352  0.352  0.024  1.0
  O  O32  1  0.888  0.888  0.705  1.0
  O  O33  1  0.112  0.112  0.295  1.0
[/CIF]
.