The crystal structure described by Sc5(RhIn2)2 crystallizes in the orthorhombic Pbam space group. There are three inequivalent Sc sites. In the first Sc site, Sc(1) is bonded in a 8-coordinate geometry to four equivalent In(1) and four equivalent In(2) atoms. In the second Sc site, Sc(2) is bonded in a 4-coordinate geometry to four equivalent Rh(1); two equivalent In(1); and four In(2,2) atoms. In the third Sc site, Sc(3) is bonded in a 2-coordinate geometry to two equivalent Rh(1), two equivalent In(2), and four equivalent In(1) atoms. Rh(1) is bonded in a 9-coordinate geometry to two equivalent Sc(3); four equivalent Sc(2); one In(1); and two In(2,2) atoms. There are three inequivalent In sites. In the first In site, In(1) is bonded in a 12-coordinate geometry to two equivalent Sc(1), two equivalent Sc(2), four equivalent Sc(3), one Rh(1), one In(2), and two equivalent In(1) atoms. In the second In site, In(2) is bonded in a 13-coordinate geometry to two equivalent Sc(1), two equivalent Sc(3), four equivalent Sc(2), two equivalent Rh(1), one In(1), and two equivalent In(2) atoms. In the third In site, In(2) is bonded in a 13-coordinate geometry to two equivalent Sc(1), two equivalent Sc(3), four equivalent Sc(2), two equivalent Rh(1), one In(1), and two equivalent In(2) atoms. is represented by the CIF card [CIF]
data_Sc5(In2Rh)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.318
_cell_length_b   7.709
_cell_length_c   17.645
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   451.317
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc0  1  0.000  0.000  0.000  1.0
  Sc  Sc1  1  0.000  0.500  0.500  1.0
  Sc  Sc2  1  0.000  0.745  0.779  1.0
  Sc  Sc3  1  0.000  0.255  0.221  1.0
  Sc  Sc4  1  0.000  0.245  0.721  1.0
  Sc  Sc5  1  0.000  0.755  0.279  1.0
  Sc  Sc6  1  0.000  0.875  0.586  1.0
  Sc  Sc7  1  0.000  0.125  0.414  1.0
  Sc  Sc8  1  0.000  0.375  0.914  1.0
  Sc  Sc9  1  0.000  0.625  0.086  1.0
  In  In10  1  0.500  0.797  0.433  1.0
  In  In11  1  0.500  0.203  0.567  1.0
  In  In12  1  0.500  0.297  0.067  1.0
  In  In13  1  0.500  0.703  0.933  1.0
  In  In14  1  0.500  0.931  0.150  1.0
  In  In15  1  0.500  0.069  0.850  1.0
  In  In16  1  0.500  0.431  0.350  1.0
  In  In17  1  0.500  0.569  0.650  1.0
  Rh  Rh18  1  0.500  0.964  0.694  1.0
  Rh  Rh19  1  0.500  0.036  0.306  1.0
  Rh  Rh20  1  0.500  0.464  0.806  1.0
  Rh  Rh21  1  0.500  0.536  0.194  1.0
[/CIF]
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The crystal structure described by Sc5(RhIn2)2 crystallizes in the orthorhombic Pbam space group. There are three inequivalent Sc sites. In the first Sc site, Sc(1) is bonded in a 8-coordinate geometry to four equivalent In(1) and four equivalent In(2) atoms. In the second Sc site, Sc(2) is bonded in a 4-coordinate geometry to four equivalent Rh(1); two equivalent In(1); and four In(2,2) atoms. In the third Sc site, Sc(3) is bonded in a 2-coordinate geometry to two equivalent Rh(1), two equivalent In(2), and four equivalent In(1) atoms. Rh(1) is bonded in a 9-coordinate geometry to two equivalent Sc(3); four equivalent Sc(2); one In(1); and two In(2,2) atoms. There are three inequivalent In sites. In the first In site, In(1) is bonded in a 12-coordinate geometry to two equivalent Sc(1), two equivalent Sc(2), four equivalent Sc(3), one Rh(1), one In(2), and two equivalent In(1) atoms. In the second In site, In(2) is bonded in a 13-coordinate geometry to two equivalent Sc(1), two equivalent Sc(3), four equivalent Sc(2), two equivalent Rh(1), one In(1), and two equivalent In(2) atoms. In the third In site, In(2) is bonded in a 13-coordinate geometry to two equivalent Sc(1), two equivalent Sc(3), four equivalent Sc(2), two equivalent Rh(1), one In(1), and two equivalent In(2) atoms. is represented by the CIF card [CIF]
data_Sc5(In2Rh)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.318
_cell_length_b   7.709
_cell_length_c   17.645
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   451.317
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc0  1  0.000  0.000  0.000  1.0
  Sc  Sc1  1  0.000  0.500  0.500  1.0
  Sc  Sc2  1  0.000  0.745  0.779  1.0
  Sc  Sc3  1  0.000  0.255  0.221  1.0
  Sc  Sc4  1  0.000  0.245  0.721  1.0
  Sc  Sc5  1  0.000  0.755  0.279  1.0
  Sc  Sc6  1  0.000  0.875  0.586  1.0
  Sc  Sc7  1  0.000  0.125  0.414  1.0
  Sc  Sc8  1  0.000  0.375  0.914  1.0
  Sc  Sc9  1  0.000  0.625  0.086  1.0
  In  In10  1  0.500  0.797  0.433  1.0
  In  In11  1  0.500  0.203  0.567  1.0
  In  In12  1  0.500  0.297  0.067  1.0
  In  In13  1  0.500  0.703  0.933  1.0
  In  In14  1  0.500  0.931  0.150  1.0
  In  In15  1  0.500  0.069  0.850  1.0
  In  In16  1  0.500  0.431  0.350  1.0
  In  In17  1  0.500  0.569  0.650  1.0
  Rh  Rh18  1  0.500  0.964  0.694  1.0
  Rh  Rh19  1  0.500  0.036  0.306  1.0
  Rh  Rh20  1  0.500  0.464  0.806  1.0
  Rh  Rh21  1  0.500  0.536  0.194  1.0
[/CIF]
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