The crystal structure described by LaCrSbO6 crystallizes in the triclinic P1 space group. La(1) is bonded in a 12-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms. Cr(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form CrO6 octahedra that share corners with six equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-23°. Sb(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form SbO6 octahedra that share corners with six equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-23°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to two equivalent La(1), one Cr(1), and one Sb(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to two equivalent La(1), one Cr(1), and one Sb(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to two equivalent La(1), one Cr(1), and one Sb(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to two equivalent La(1), one Cr(1), and one Sb(1) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to two equivalent La(1), one Cr(1), and one Sb(1) atom. In the sixth O site, O(6) is bonded in a 2-coordinate geometry to two equivalent La(1), one Cr(1), and one Sb(1) atom. is represented by the CIF file [CIF]
data_LaCrSbO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.477
_cell_length_b   5.485
_cell_length_c   5.514
_cell_angle_alpha   90.203
_cell_angle_beta   119.459
_cell_angle_gamma   119.794
_symmetry_Int_Tables_number   1
_cell_volume   118.240
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.500  0.742  0.759  1.0
  Cr  Cr1  1  0.995  0.488  0.004  1.0
  Sb  Sb2  1  0.001  0.991  0.505  1.0
  O  O3  1  0.503  0.746  0.328  1.0
  O  O4  1  0.923  0.700  0.204  1.0
  O  O5  1  0.079  0.297  0.783  1.0
  O  O6  1  0.934  0.199  0.200  1.0
  O  O7  1  0.066  0.767  0.788  1.0
  O  O8  1  0.500  0.229  0.690  1.0
[/CIF]
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The crystal structure described by LaCrSbO6 crystallizes in the triclinic P1 space group. La(1) is bonded in a 12-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms. Cr(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form CrO6 octahedra that share corners with six equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-23°. Sb(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form SbO6 octahedra that share corners with six equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-23°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to two equivalent La(1), one Cr(1), and one Sb(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to two equivalent La(1), one Cr(1), and one Sb(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to two equivalent La(1), one Cr(1), and one Sb(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to two equivalent La(1), one Cr(1), and one Sb(1) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to two equivalent La(1), one Cr(1), and one Sb(1) atom. In the sixth O site, O(6) is bonded in a 2-coordinate geometry to two equivalent La(1), one Cr(1), and one Sb(1) atom. is represented by the CIF file [CIF]
data_LaCrSbO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.477
_cell_length_b   5.485
_cell_length_c   5.514
_cell_angle_alpha   90.203
_cell_angle_beta   119.459
_cell_angle_gamma   119.794
_symmetry_Int_Tables_number   1
_cell_volume   118.240
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.500  0.742  0.759  1.0
  Cr  Cr1  1  0.995  0.488  0.004  1.0
  Sb  Sb2  1  0.001  0.991  0.505  1.0
  O  O3  1  0.503  0.746  0.328  1.0
  O  O4  1  0.923  0.700  0.204  1.0
  O  O5  1  0.079  0.297  0.783  1.0
  O  O6  1  0.934  0.199  0.200  1.0
  O  O7  1  0.066  0.767  0.788  1.0
  O  O8  1  0.500  0.229  0.690  1.0
[/CIF]
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