The structure described by C(NH2)3BF4 is Tetraauricupride structured and crystallizes in the trigonal R3m space group. The structure is zero-dimensional and consists of three guanidinium molecules and three BF4 clusters. In each BF4 cluster, B(1) is bonded in a tetrahedral geometry to one F(2) and three equivalent F(1) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one B(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one B(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_BH6CN3F4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.376
_cell_length_b   5.376
_cell_length_c   5.376
_cell_angle_alpha   87.841
_cell_angle_beta   87.841
_cell_angle_gamma   87.841
_symmetry_Int_Tables_number   1
_cell_volume   155.077
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.586  0.586  0.586  1.0
  H  H1  1  0.252  0.018  0.704  1.0
  H  H2  1  0.252  0.704  0.018  1.0
  H  H3  1  0.704  0.252  0.018  1.0
  H  H4  1  0.018  0.252  0.704  1.0
  H  H5  1  0.018  0.704  0.252  1.0
  H  H6  1  0.704  0.018  0.252  1.0
  C  C7  1  0.985  0.985  0.985  1.0
  N  N8  1  0.778  0.088  0.088  1.0
  N  N9  1  0.088  0.778  0.088  1.0
  N  N10  1  0.088  0.088  0.778  1.0
  F  F11  1  0.845  0.534  0.534  1.0
  F  F12  1  0.534  0.845  0.534  1.0
  F  F13  1  0.534  0.534  0.845  1.0
  F  F14  1  0.441  0.441  0.441  1.0
[/CIF]
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The structure described by C(NH2)3BF4 is Tetraauricupride structured and crystallizes in the trigonal R3m space group. The structure is zero-dimensional and consists of three guanidinium molecules and three BF4 clusters. In each BF4 cluster, B(1) is bonded in a tetrahedral geometry to one F(2) and three equivalent F(1) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one B(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one B(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_BH6CN3F4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.376
_cell_length_b   5.376
_cell_length_c   5.376
_cell_angle_alpha   87.841
_cell_angle_beta   87.841
_cell_angle_gamma   87.841
_symmetry_Int_Tables_number   1
_cell_volume   155.077
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.586  0.586  0.586  1.0
  H  H1  1  0.252  0.018  0.704  1.0
  H  H2  1  0.252  0.704  0.018  1.0
  H  H3  1  0.704  0.252  0.018  1.0
  H  H4  1  0.018  0.252  0.704  1.0
  H  H5  1  0.018  0.704  0.252  1.0
  H  H6  1  0.704  0.018  0.252  1.0
  C  C7  1  0.985  0.985  0.985  1.0
  N  N8  1  0.778  0.088  0.088  1.0
  N  N9  1  0.088  0.778  0.088  1.0
  N  N10  1  0.088  0.088  0.778  1.0
  F  F11  1  0.845  0.534  0.534  1.0
  F  F12  1  0.534  0.845  0.534  1.0
  F  F13  1  0.534  0.534  0.845  1.0
  F  F14  1  0.441  0.441  0.441  1.0
[/CIF]
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