The crystal structure described by Li4Ti2V3Mn3O16 is Hausmannite-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(12), one O(15), and one O(3) atom to form LiO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent V(3)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra, and corners with three equivalent Ti(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-67°. In the second Li site, Li(2) is bonded to one O(14), one O(16), one O(5), and one O(9) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, corners with three equivalent Ti(2)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, and  an edgeedge with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-66°. In the third Li site, Li(3) is bonded to one O(1), one O(10), one O(4), and one O(6) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra, corners with three equivalent Ti(1)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, and  an edgeedge with one Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-69°. In the fourth Li site, Li(4) is bonded to one O(13), one O(2), one O(7), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, and corners with three equivalent Ti(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-68°. There are two inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form distorted TiO6 octahedra that share corners with two equivalent V(3)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra, corners with three equivalent Li(3)O4 tetrahedra, corners with three equivalent Li(4)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, and  an edgeedge with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-56°. In the second Ti site, Ti(2) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form distorted TiO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra, corners with three equivalent Li(2)O4 tetrahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, and  an edgeedge with one Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-57°. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form VO6 octahedra that share corners with two equivalent Ti(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Ti(1)O6 octahedra, edges with two equivalent V(2)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 47-50°. In the second V site, V(2) is bonded to one O(16), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form VO6 octahedra that share corners with two equivalent Ti(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Ti(1)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 49-52°. In the third V site, V(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form VO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Ti(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 44-45°. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form MnO6 octahedra that share corners with two equivalent Ti(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Ti(1)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 56-57°. In the second Mn site, Mn(2) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form distorted MnO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Ti(2)O6 octahedra, edges with two equivalent V(3)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 55-56°. In the third Mn site, Mn(3) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form distorted MnO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Ti(2)O6 octahedra, edges with two equivalent V(3)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 55-56°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one Ti(1), one V(3), and one Mn(2) atom. In the second O site, O(2) is bonded to one Li(4), one Ti(1), one V(1), and one V(2) atom to form distorted OLiTiV2 tetrahedra that share  a cornercorner with one O(7)LiTiMnV tetrahedra,  a cornercorner with one O(8)LiTiMnV tetrahedra, corners with two equivalent O(4)LiMnV2 tetrahedra,  an edgeedge with one O(7)LiTiMnV tetrahedra, and  an edgeedge with one O(8)LiTiMnV tetrahedra. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Li(1), one V(1), one V(2), and one Mn(1) atom. In the fourth O site, O(4) is bonded to one Li(3), one V(1), one V(2), and one Mn(1) atom to form OLiMnV2 tetrahedra that share corners with two equivalent O(7)LiTiMnV tetrahedra, corners with two equivalent O(8)LiTiMnV tetrahedra, and corners with two equivalent O(2)LiTiV2 tetrahedra. In the fifth O site, O(5) is bonded to one Li(2), one V(3), one Mn(2), and one Mn(3) atom to form corner-sharing OLiMn2V tetrahedra. In the sixth O site, O(6) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one Ti(1), one V(3), and one Mn(3) atom. In the seventh O site, O(7) is bonded to one Li(4), one Ti(1), one V(1), and one Mn(1) atom to form distorted OLiTiMnV tetrahedra that share  a cornercorner with one O(8)LiTiMnV tetrahedra,  a cornercorner with one O(2)LiTiV2 tetrahedra, corners with two equivalent O(4)LiMnV2 tetrahedra,  an edgeedge with one O(8)LiTiMnV tetrahedra, and  an edgeedge with one O(2)LiTiV2 tetrahedra. In the eighth O site, O(8) is bonded to one Li(4), one Ti(1), one V(2), and one Mn(1) atom to form distorted OLiTiMnV tetrahedra that share  a cornercorner with one O(7)LiTiMnV tetrahedra,  a cornercorner with one O(2)LiTiV2 tetrahedra, corners with two equivalent O(4)LiMnV2 tetrahedra,  an edgeedge with one O(7)LiTiMnV tetrahedra, and  an edgeedge with one O(2)LiTiV2 tetrahedra. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Li(2), one Ti(2), one V(1), and one V(2) atom. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one Li(3), one Ti(1), one Mn(2), and one Mn(3) atom. In the eleventh O site, O(11) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Ti(2), one V(3), and one Mn(2) atom. In the twelfth O site, O(12) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Ti(2), one V(3), and one Mn(3) atom. In the thirteenth O site, O(13) is bonded in a rectangular see-saw-like geometry to one Li(4), one V(3), one Mn(2), and one Mn(3) atom. In the fourteenth O site, O(14) is bonded in a rectangular see-saw-like geometry to one Li(2), one Ti(2), one V(1), and one Mn(1) atom. In the fifteenth O site, O(15) is bonded to one Li(1), one Ti(2), one Mn(2), and one Mn(3) atom to form corner-sharing OLiTiMn2 tetrahedra. In the sixteenth O site, O(16) is bonded in a rectangular see-saw-like geometry to one Li(2), one Ti(2), one V(2), and one Mn(1) atom. is represented by the CIF card [CIF]
data_Li4Ti2Mn3V3O16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.884
_cell_length_b   6.016
_cell_length_c   9.615
_cell_angle_alpha   92.802
_cell_angle_beta   89.668
_cell_angle_gamma   119.060
_symmetry_Int_Tables_number   1
_cell_volume   297.076
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.347  0.687  0.099  1.0
  Li  Li1  1  0.995  0.994  0.010  1.0
  Li  Li2  1  0.999  0.998  0.508  1.0
  Li  Li3  1  0.663  0.327  0.599  1.0
  Ti  Ti4  1  0.342  0.682  0.502  1.0
  Ti  Ti5  1  0.653  0.324  0.004  1.0
  Mn  Mn6  1  0.165  0.333  0.793  1.0
  Mn  Mn7  1  0.343  0.181  0.290  1.0
  Mn  Mn8  1  0.834  0.176  0.291  1.0
  V  V9  1  0.155  0.806  0.780  1.0
  V  V10  1  0.652  0.809  0.781  1.0
  V  V11  1  0.837  0.656  0.273  1.0
  O  O12  1  0.158  0.811  0.407  1.0
  O  O13  1  0.477  0.955  0.659  1.0
  O  O14  1  0.348  0.701  0.897  1.0
  O  O15  1  0.990  0.978  0.695  1.0
  O  O16  1  0.998  0.997  0.200  1.0
  O  O17  1  0.656  0.810  0.405  1.0
  O  O18  1  0.037  0.535  0.656  1.0
  O  O19  1  0.500  0.537  0.657  1.0
  O  O20  1  0.830  0.660  0.896  1.0
  O  O21  1  0.163  0.327  0.411  1.0
  O  O22  1  0.537  0.503  0.149  1.0
  O  O23  1  0.971  0.509  0.154  1.0
  O  O24  1  0.676  0.354  0.391  1.0
  O  O25  1  0.333  0.148  0.911  1.0
  O  O26  1  0.529  0.057  0.163  1.0
  O  O27  1  0.812  0.147  0.913  1.0
[/CIF]
.
The crystal structure described by Li4Ti2V3Mn3O16 is Hausmannite-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(12), one O(15), and one O(3) atom to form LiO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent V(3)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra, and corners with three equivalent Ti(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-67°. In the second Li site, Li(2) is bonded to one O(14), one O(16), one O(5), and one O(9) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, corners with three equivalent Ti(2)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, and  an edgeedge with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-66°. In the third Li site, Li(3) is bonded to one O(1), one O(10), one O(4), and one O(6) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra, corners with three equivalent Ti(1)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, and  an edgeedge with one Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-69°. In the fourth Li site, Li(4) is bonded to one O(13), one O(2), one O(7), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, and corners with three equivalent Ti(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-68°. There are two inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form distorted TiO6 octahedra that share corners with two equivalent V(3)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra, corners with three equivalent Li(3)O4 tetrahedra, corners with three equivalent Li(4)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, and  an edgeedge with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-56°. In the second Ti site, Ti(2) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form distorted TiO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra, corners with three equivalent Li(2)O4 tetrahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, and  an edgeedge with one Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-57°. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form VO6 octahedra that share corners with two equivalent Ti(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Ti(1)O6 octahedra, edges with two equivalent V(2)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 47-50°. In the second V site, V(2) is bonded to one O(16), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form VO6 octahedra that share corners with two equivalent Ti(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Ti(1)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 49-52°. In the third V site, V(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form VO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Ti(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 44-45°. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form MnO6 octahedra that share corners with two equivalent Ti(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Ti(1)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 56-57°. In the second Mn site, Mn(2) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form distorted MnO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Ti(2)O6 octahedra, edges with two equivalent V(3)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 55-56°. In the third Mn site, Mn(3) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form distorted MnO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Ti(2)O6 octahedra, edges with two equivalent V(3)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 55-56°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one Ti(1), one V(3), and one Mn(2) atom. In the second O site, O(2) is bonded to one Li(4), one Ti(1), one V(1), and one V(2) atom to form distorted OLiTiV2 tetrahedra that share  a cornercorner with one O(7)LiTiMnV tetrahedra,  a cornercorner with one O(8)LiTiMnV tetrahedra, corners with two equivalent O(4)LiMnV2 tetrahedra,  an edgeedge with one O(7)LiTiMnV tetrahedra, and  an edgeedge with one O(8)LiTiMnV tetrahedra. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Li(1), one V(1), one V(2), and one Mn(1) atom. In the fourth O site, O(4) is bonded to one Li(3), one V(1), one V(2), and one Mn(1) atom to form OLiMnV2 tetrahedra that share corners with two equivalent O(7)LiTiMnV tetrahedra, corners with two equivalent O(8)LiTiMnV tetrahedra, and corners with two equivalent O(2)LiTiV2 tetrahedra. In the fifth O site, O(5) is bonded to one Li(2), one V(3), one Mn(2), and one Mn(3) atom to form corner-sharing OLiMn2V tetrahedra. In the sixth O site, O(6) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one Ti(1), one V(3), and one Mn(3) atom. In the seventh O site, O(7) is bonded to one Li(4), one Ti(1), one V(1), and one Mn(1) atom to form distorted OLiTiMnV tetrahedra that share  a cornercorner with one O(8)LiTiMnV tetrahedra,  a cornercorner with one O(2)LiTiV2 tetrahedra, corners with two equivalent O(4)LiMnV2 tetrahedra,  an edgeedge with one O(8)LiTiMnV tetrahedra, and  an edgeedge with one O(2)LiTiV2 tetrahedra. In the eighth O site, O(8) is bonded to one Li(4), one Ti(1), one V(2), and one Mn(1) atom to form distorted OLiTiMnV tetrahedra that share  a cornercorner with one O(7)LiTiMnV tetrahedra,  a cornercorner with one O(2)LiTiV2 tetrahedra, corners with two equivalent O(4)LiMnV2 tetrahedra,  an edgeedge with one O(7)LiTiMnV tetrahedra, and  an edgeedge with one O(2)LiTiV2 tetrahedra. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Li(2), one Ti(2), one V(1), and one V(2) atom. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one Li(3), one Ti(1), one Mn(2), and one Mn(3) atom. In the eleventh O site, O(11) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Ti(2), one V(3), and one Mn(2) atom. In the twelfth O site, O(12) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Ti(2), one V(3), and one Mn(3) atom. In the thirteenth O site, O(13) is bonded in a rectangular see-saw-like geometry to one Li(4), one V(3), one Mn(2), and one Mn(3) atom. In the fourteenth O site, O(14) is bonded in a rectangular see-saw-like geometry to one Li(2), one Ti(2), one V(1), and one Mn(1) atom. In the fifteenth O site, O(15) is bonded to one Li(1), one Ti(2), one Mn(2), and one Mn(3) atom to form corner-sharing OLiTiMn2 tetrahedra. In the sixteenth O site, O(16) is bonded in a rectangular see-saw-like geometry to one Li(2), one Ti(2), one V(2), and one Mn(1) atom. is represented by the CIF card [CIF]
data_Li4Ti2Mn3V3O16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.884
_cell_length_b   6.016
_cell_length_c   9.615
_cell_angle_alpha   92.802
_cell_angle_beta   89.668
_cell_angle_gamma   119.060
_symmetry_Int_Tables_number   1
_cell_volume   297.076
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.347  0.687  0.099  1.0
  Li  Li1  1  0.995  0.994  0.010  1.0
  Li  Li2  1  0.999  0.998  0.508  1.0
  Li  Li3  1  0.663  0.327  0.599  1.0
  Ti  Ti4  1  0.342  0.682  0.502  1.0
  Ti  Ti5  1  0.653  0.324  0.004  1.0
  Mn  Mn6  1  0.165  0.333  0.793  1.0
  Mn  Mn7  1  0.343  0.181  0.290  1.0
  Mn  Mn8  1  0.834  0.176  0.291  1.0
  V  V9  1  0.155  0.806  0.780  1.0
  V  V10  1  0.652  0.809  0.781  1.0
  V  V11  1  0.837  0.656  0.273  1.0
  O  O12  1  0.158  0.811  0.407  1.0
  O  O13  1  0.477  0.955  0.659  1.0
  O  O14  1  0.348  0.701  0.897  1.0
  O  O15  1  0.990  0.978  0.695  1.0
  O  O16  1  0.998  0.997  0.200  1.0
  O  O17  1  0.656  0.810  0.405  1.0
  O  O18  1  0.037  0.535  0.656  1.0
  O  O19  1  0.500  0.537  0.657  1.0
  O  O20  1  0.830  0.660  0.896  1.0
  O  O21  1  0.163  0.327  0.411  1.0
  O  O22  1  0.537  0.503  0.149  1.0
  O  O23  1  0.971  0.509  0.154  1.0
  O  O24  1  0.676  0.354  0.391  1.0
  O  O25  1  0.333  0.148  0.911  1.0
  O  O26  1  0.529  0.057  0.163  1.0
  O  O27  1  0.812  0.147  0.913  1.0
[/CIF]
.