The material described by Re(CO)5Mn(CO)5 is alpha carbon monoxide-like structured and crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of four Mn(CO)5 clusters and four Re(CO)5 clusters. In each Mn(CO)5 cluster, Mn(1) is bonded in a square pyramidal geometry to one C(1), one C(3), one C(5), one C(7), and one C(9) atom. There are five inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Mn(1) and one O(3,9) atom. In the second C site, C(3) is bonded in a linear geometry to one Mn(1) and one O(1) atom. In the third C site, C(5) is bonded in a linear geometry to one Mn(1) and one O(3,9) atom. In the fourth C site, C(7) is bonded in a linear geometry to one Mn(1) and one O(5) atom. In the fifth C site, C(9) is bonded in a linear geometry to one Mn(1) and one O(7) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(3) atom. In the second O site, O(3,9) is bonded in a single-bond geometry to one C(1) atom. In the third O site, O(5) is bonded in a single-bond geometry to one C(7) atom. In the fourth O site, O(7) is bonded in a single-bond geometry to one C(9) atom. In each Re(CO)5 cluster, Re(1) is bonded in a square pyramidal geometry to one C(10), one C(2), one C(4), one C(6), and one C(8) atom. There are five inequivalent C sites. In the first C site, C(2) is bonded in a linear geometry to one Re(1) and one O(2,4,10) atom. In the second C site, C(4) is bonded in a linear geometry to one Re(1) and one O(2,4,10) atom. In the third C site, C(6) is bonded in a linear geometry to one Re(1) and one O(2,4,10) atom. In the fourth C site, C(8) is bonded in a linear geometry to one Re(1) and one O(6,8) atom. In the fifth C site, C(10) is bonded in a linear geometry to one Re(1) and one O(6,8) atom. There are two inequivalent O sites. In the first O site, O(6,8) is bonded in a single-bond geometry to one C(8) atom. In the second O site, O(2,4,10) is bonded in a single-bond geometry to one C(4) atom. is represented by the CIF file [CIF]
data_MnRe(CO)10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.816
_cell_length_b   9.816
_cell_length_c   14.834
_cell_angle_alpha   56.275
_cell_angle_beta   56.275
_cell_angle_gamma   43.620
_symmetry_Int_Tables_number   1
_cell_volume   790.353
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.304  0.837  0.027  1.0
  Mn  Mn1  1  0.163  0.696  0.973  1.0
  Re  Re2  1  0.697  0.163  0.473  1.0
  Re  Re3  1  0.837  0.303  0.527  1.0
  C  C4  1  0.397  0.918  0.051  1.0
  C  C5  1  0.082  0.603  0.949  1.0
  C  C6  1  0.598  0.078  0.448  1.0
  C  C7  1  0.922  0.402  0.552  1.0
  C  C8  1  0.269  0.023  0.887  1.0
  C  C9  1  0.977  0.731  0.113  1.0
  C  C10  1  0.732  0.962  0.624  1.0
  C  C11  1  0.038  0.268  0.376  1.0
  C  C12  1  0.567  0.636  0.962  1.0
  C  C13  1  0.364  0.433  0.038  1.0
  C  C14  1  0.413  0.379  0.543  1.0
  C  C15  1  0.621  0.587  0.457  1.0
  C  C16  1  0.312  0.642  0.165  1.0
  C  C17  1  0.358  0.688  0.835  1.0
  C  C18  1  0.687  0.373  0.325  1.0
  C  C19  1  0.627  0.313  0.675  1.0
  C  C20  1  0.031  0.023  0.094  1.0
  C  C21  1  0.977  0.969  0.906  1.0
  C  C22  1  0.989  0.964  0.401  1.0
  C  C23  1  0.036  0.011  0.599  1.0
  O  O24  1  0.248  0.141  0.799  1.0
  O  O25  1  0.859  0.752  0.201  1.0
  O  O26  1  0.755  0.845  0.711  1.0
  O  O27  1  0.155  0.245  0.289  1.0
  O  O28  1  0.458  0.969  0.064  1.0
  O  O29  1  0.031  0.542  0.936  1.0
  O  O30  1  0.537  0.026  0.434  1.0
  O  O31  1  0.974  0.463  0.566  1.0
  O  O32  1  0.311  0.524  0.252  1.0
  O  O33  1  0.476  0.689  0.748  1.0
  O  O34  1  0.688  0.490  0.238  1.0
  O  O35  1  0.510  0.312  0.762  1.0
  O  O36  1  0.863  0.135  0.139  1.0
  O  O37  1  0.865  0.137  0.861  1.0
  O  O38  1  0.156  0.851  0.356  1.0
  O  O39  1  0.149  0.844  0.644  1.0
  O  O40  1  0.732  0.509  0.922  1.0
  O  O41  1  0.491  0.268  0.078  1.0
  O  O42  1  0.249  0.505  0.582  1.0
  O  O43  1  0.495  0.751  0.418  1.0
[/CIF]
.
The material described by Re(CO)5Mn(CO)5 is alpha carbon monoxide-like structured and crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of four Mn(CO)5 clusters and four Re(CO)5 clusters. In each Mn(CO)5 cluster, Mn(1) is bonded in a square pyramidal geometry to one C(1), one C(3), one C(5), one C(7), and one C(9) atom. There are five inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Mn(1) and one O(3,9) atom. In the second C site, C(3) is bonded in a linear geometry to one Mn(1) and one O(1) atom. In the third C site, C(5) is bonded in a linear geometry to one Mn(1) and one O(3,9) atom. In the fourth C site, C(7) is bonded in a linear geometry to one Mn(1) and one O(5) atom. In the fifth C site, C(9) is bonded in a linear geometry to one Mn(1) and one O(7) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(3) atom. In the second O site, O(3,9) is bonded in a single-bond geometry to one C(1) atom. In the third O site, O(5) is bonded in a single-bond geometry to one C(7) atom. In the fourth O site, O(7) is bonded in a single-bond geometry to one C(9) atom. In each Re(CO)5 cluster, Re(1) is bonded in a square pyramidal geometry to one C(10), one C(2), one C(4), one C(6), and one C(8) atom. There are five inequivalent C sites. In the first C site, C(2) is bonded in a linear geometry to one Re(1) and one O(2,4,10) atom. In the second C site, C(4) is bonded in a linear geometry to one Re(1) and one O(2,4,10) atom. In the third C site, C(6) is bonded in a linear geometry to one Re(1) and one O(2,4,10) atom. In the fourth C site, C(8) is bonded in a linear geometry to one Re(1) and one O(6,8) atom. In the fifth C site, C(10) is bonded in a linear geometry to one Re(1) and one O(6,8) atom. There are two inequivalent O sites. In the first O site, O(6,8) is bonded in a single-bond geometry to one C(8) atom. In the second O site, O(2,4,10) is bonded in a single-bond geometry to one C(4) atom. is represented by the CIF file [CIF]
data_MnRe(CO)10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.816
_cell_length_b   9.816
_cell_length_c   14.834
_cell_angle_alpha   56.275
_cell_angle_beta   56.275
_cell_angle_gamma   43.620
_symmetry_Int_Tables_number   1
_cell_volume   790.353
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.304  0.837  0.027  1.0
  Mn  Mn1  1  0.163  0.696  0.973  1.0
  Re  Re2  1  0.697  0.163  0.473  1.0
  Re  Re3  1  0.837  0.303  0.527  1.0
  C  C4  1  0.397  0.918  0.051  1.0
  C  C5  1  0.082  0.603  0.949  1.0
  C  C6  1  0.598  0.078  0.448  1.0
  C  C7  1  0.922  0.402  0.552  1.0
  C  C8  1  0.269  0.023  0.887  1.0
  C  C9  1  0.977  0.731  0.113  1.0
  C  C10  1  0.732  0.962  0.624  1.0
  C  C11  1  0.038  0.268  0.376  1.0
  C  C12  1  0.567  0.636  0.962  1.0
  C  C13  1  0.364  0.433  0.038  1.0
  C  C14  1  0.413  0.379  0.543  1.0
  C  C15  1  0.621  0.587  0.457  1.0
  C  C16  1  0.312  0.642  0.165  1.0
  C  C17  1  0.358  0.688  0.835  1.0
  C  C18  1  0.687  0.373  0.325  1.0
  C  C19  1  0.627  0.313  0.675  1.0
  C  C20  1  0.031  0.023  0.094  1.0
  C  C21  1  0.977  0.969  0.906  1.0
  C  C22  1  0.989  0.964  0.401  1.0
  C  C23  1  0.036  0.011  0.599  1.0
  O  O24  1  0.248  0.141  0.799  1.0
  O  O25  1  0.859  0.752  0.201  1.0
  O  O26  1  0.755  0.845  0.711  1.0
  O  O27  1  0.155  0.245  0.289  1.0
  O  O28  1  0.458  0.969  0.064  1.0
  O  O29  1  0.031  0.542  0.936  1.0
  O  O30  1  0.537  0.026  0.434  1.0
  O  O31  1  0.974  0.463  0.566  1.0
  O  O32  1  0.311  0.524  0.252  1.0
  O  O33  1  0.476  0.689  0.748  1.0
  O  O34  1  0.688  0.490  0.238  1.0
  O  O35  1  0.510  0.312  0.762  1.0
  O  O36  1  0.863  0.135  0.139  1.0
  O  O37  1  0.865  0.137  0.861  1.0
  O  O38  1  0.156  0.851  0.356  1.0
  O  O39  1  0.149  0.844  0.644  1.0
  O  O40  1  0.732  0.509  0.922  1.0
  O  O41  1  0.491  0.268  0.078  1.0
  O  O42  1  0.249  0.505  0.582  1.0
  O  O43  1  0.495  0.751  0.418  1.0
[/CIF]
.