The material described by Na5Ag(TeO14)2 crystallizes in the triclinic P-1 space group. There are three inequivalent Na sites. In the first Na site, Na(1) is bonded to two equivalent O(13), two equivalent O(2), two equivalent O(7), and two equivalent O(8) atoms to form distorted edge-sharing NaO8 hexagonal bipyramids. In the second Na site, Na(2) is bonded in a 7-coordinate geometry to one O(10), one O(11), one O(4), one O(5), and three equivalent O(9) atoms. In the third Na site, Na(3) is bonded to one O(10), one O(11), one O(12), one O(13), one O(6), and one O(7) atom to form distorted NaO6 trigonal bipyramids that share  a cornercorner with one Te(1)O5 square pyramid and  an edgeedge with one Na(1)O8 hexagonal bipyramid. Ag(1) is bonded in a distorted square co-planar geometry to two equivalent O(5) and two equivalent O(6) atoms. Te(1) is bonded to one O(1), one O(3), one O(4), one O(5), and one O(6) atom to form distorted TeO5 square pyramids that share  a cornercorner with one Na(3)O6 trigonal bipyramid. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Te(1) and one O(4) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Na(1) and one O(13) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Te(1) and one O(10) atom. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to one Na(2), one Te(1), and one O(1) atom. In the fifth O site, O(5) is bonded in a trigonal non-coplanar geometry to one Na(2), one Ag(1), and one Te(1) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one Na(3), one Ag(1), one Te(1), and one O(11) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Na(1), one Na(3), and one O(12) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Na(1) and one O(14) atom. In the ninth O site, O(9) is bonded in a distorted bent 120 degrees geometry to three equivalent Na(2) atoms. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Na(2), one Na(3), and one O(3) atom. In the eleventh O site, O(11) is bonded in a trigonal non-coplanar geometry to one Na(2), one Na(3), and one O(6) atom. In the twelfth O site, O(12) is bonded in an L-shaped geometry to one Na(3) and one O(7) atom. In the thirteenth O site, O(13) is bonded in a distorted T-shaped geometry to one Na(1), one Na(3), and one O(2) atom. In the fourteenth O site, O(14) is bonded in a single-bond geometry to one O(8) atom. is represented by the CIF card [CIF]
data_Na5Ag(TeO14)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.918
_cell_length_b   9.468
_cell_length_c   14.495
_cell_angle_alpha   96.598
_cell_angle_beta   100.711
_cell_angle_gamma   72.636
_symmetry_Int_Tables_number   1
_cell_volume   631.683
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.000  0.500  0.500  1.0
  Na  Na1  1  0.697  0.170  0.033  1.0
  Na  Na2  1  0.303  0.830  0.967  1.0
  Na  Na3  1  0.360  0.712  0.697  1.0
  Na  Na4  1  0.640  0.288  0.303  1.0
  Ag  Ag5  1  0.000  0.500  0.000  1.0
  Te  Te6  1  0.801  0.284  0.819  1.0
  Te  Te7  1  0.199  0.716  0.181  1.0
  O  O8  1  0.204  0.276  0.789  1.0
  O  O9  1  0.796  0.724  0.211  1.0
  O  O10  1  0.472  0.361  0.622  1.0
  O  O11  1  0.528  0.639  0.378  1.0
  O  O12  1  0.942  0.996  0.792  1.0
  O  O13  1  0.058  0.004  0.208  1.0
  O  O14  1  0.423  0.289  0.870  1.0
  O  O15  1  0.577  0.711  0.130  1.0
  O  O16  1  0.940  0.284  0.949  1.0
  O  O17  1  0.060  0.716  0.051  1.0
  O  O18  1  0.692  0.541  0.842  1.0
  O  O19  1  0.308  0.459  0.158  1.0
  O  O20  1  0.886  0.670  0.636  1.0
  O  O21  1  0.114  0.330  0.364  1.0
  O  O22  1  0.960  0.221  0.529  1.0
  O  O23  1  0.040  0.779  0.471  1.0
  O  O24  1  0.663  0.943  0.952  1.0
  O  O25  1  0.337  0.057  0.048  1.0
  O  O26  1  0.207  0.941  0.783  1.0
  O  O27  1  0.793  0.059  0.217  1.0
  O  O28  1  0.414  0.614  0.844  1.0
  O  O29  1  0.586  0.386  0.156  1.0
  O  O30  1  0.685  0.795  0.629  1.0
  O  O31  1  0.315  0.205  0.371  1.0
  O  O32  1  0.477  0.486  0.596  1.0
  O  O33  1  0.523  0.514  0.404  1.0
  O  O34  1  0.178  0.113  0.541  1.0
  O  O35  1  0.822  0.887  0.459  1.0
[/CIF]
.
The material described by Na5Ag(TeO14)2 crystallizes in the triclinic P-1 space group. There are three inequivalent Na sites. In the first Na site, Na(1) is bonded to two equivalent O(13), two equivalent O(2), two equivalent O(7), and two equivalent O(8) atoms to form distorted edge-sharing NaO8 hexagonal bipyramids. In the second Na site, Na(2) is bonded in a 7-coordinate geometry to one O(10), one O(11), one O(4), one O(5), and three equivalent O(9) atoms. In the third Na site, Na(3) is bonded to one O(10), one O(11), one O(12), one O(13), one O(6), and one O(7) atom to form distorted NaO6 trigonal bipyramids that share  a cornercorner with one Te(1)O5 square pyramid and  an edgeedge with one Na(1)O8 hexagonal bipyramid. Ag(1) is bonded in a distorted square co-planar geometry to two equivalent O(5) and two equivalent O(6) atoms. Te(1) is bonded to one O(1), one O(3), one O(4), one O(5), and one O(6) atom to form distorted TeO5 square pyramids that share  a cornercorner with one Na(3)O6 trigonal bipyramid. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Te(1) and one O(4) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Na(1) and one O(13) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Te(1) and one O(10) atom. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to one Na(2), one Te(1), and one O(1) atom. In the fifth O site, O(5) is bonded in a trigonal non-coplanar geometry to one Na(2), one Ag(1), and one Te(1) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one Na(3), one Ag(1), one Te(1), and one O(11) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Na(1), one Na(3), and one O(12) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Na(1) and one O(14) atom. In the ninth O site, O(9) is bonded in a distorted bent 120 degrees geometry to three equivalent Na(2) atoms. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Na(2), one Na(3), and one O(3) atom. In the eleventh O site, O(11) is bonded in a trigonal non-coplanar geometry to one Na(2), one Na(3), and one O(6) atom. In the twelfth O site, O(12) is bonded in an L-shaped geometry to one Na(3) and one O(7) atom. In the thirteenth O site, O(13) is bonded in a distorted T-shaped geometry to one Na(1), one Na(3), and one O(2) atom. In the fourteenth O site, O(14) is bonded in a single-bond geometry to one O(8) atom. is represented by the CIF card [CIF]
data_Na5Ag(TeO14)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.918
_cell_length_b   9.468
_cell_length_c   14.495
_cell_angle_alpha   96.598
_cell_angle_beta   100.711
_cell_angle_gamma   72.636
_symmetry_Int_Tables_number   1
_cell_volume   631.683
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.000  0.500  0.500  1.0
  Na  Na1  1  0.697  0.170  0.033  1.0
  Na  Na2  1  0.303  0.830  0.967  1.0
  Na  Na3  1  0.360  0.712  0.697  1.0
  Na  Na4  1  0.640  0.288  0.303  1.0
  Ag  Ag5  1  0.000  0.500  0.000  1.0
  Te  Te6  1  0.801  0.284  0.819  1.0
  Te  Te7  1  0.199  0.716  0.181  1.0
  O  O8  1  0.204  0.276  0.789  1.0
  O  O9  1  0.796  0.724  0.211  1.0
  O  O10  1  0.472  0.361  0.622  1.0
  O  O11  1  0.528  0.639  0.378  1.0
  O  O12  1  0.942  0.996  0.792  1.0
  O  O13  1  0.058  0.004  0.208  1.0
  O  O14  1  0.423  0.289  0.870  1.0
  O  O15  1  0.577  0.711  0.130  1.0
  O  O16  1  0.940  0.284  0.949  1.0
  O  O17  1  0.060  0.716  0.051  1.0
  O  O18  1  0.692  0.541  0.842  1.0
  O  O19  1  0.308  0.459  0.158  1.0
  O  O20  1  0.886  0.670  0.636  1.0
  O  O21  1  0.114  0.330  0.364  1.0
  O  O22  1  0.960  0.221  0.529  1.0
  O  O23  1  0.040  0.779  0.471  1.0
  O  O24  1  0.663  0.943  0.952  1.0
  O  O25  1  0.337  0.057  0.048  1.0
  O  O26  1  0.207  0.941  0.783  1.0
  O  O27  1  0.793  0.059  0.217  1.0
  O  O28  1  0.414  0.614  0.844  1.0
  O  O29  1  0.586  0.386  0.156  1.0
  O  O30  1  0.685  0.795  0.629  1.0
  O  O31  1  0.315  0.205  0.371  1.0
  O  O32  1  0.477  0.486  0.596  1.0
  O  O33  1  0.523  0.514  0.404  1.0
  O  O34  1  0.178  0.113  0.541  1.0
  O  O35  1  0.822  0.887  0.459  1.0
[/CIF]
.