The compound described by DyO9I crystallizes in the monoclinic P2_1/c space group. Dy(1) is bonded in a 7-coordinate geometry to one O(2), one O(3), one O(4), one O(5), one O(8), and two equivalent O(1) atoms. There are nine inequivalent O sites. In the first O site, O(7) is bonded in a distorted single-bond geometry to one O(3) and one I(1) atom. In the second O site, O(8) is bonded in a distorted trigonal planar geometry to one Dy(1), one O(5), and one I(1) atom. In the third O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent Dy(1) and one I(1) atom. In the fourth O site, O(9) is bonded in a water-like geometry to one O(6) and one I(1) atom. In the fifth O site, O(2) is bonded in a water-like geometry to one Dy(1) and one I(1) atom. In the sixth O site, O(3) is bonded in a bent 120 degrees geometry to one Dy(1) and one O(7) atom. In the seventh O site, O(4) is bonded in an L-shaped geometry to one Dy(1) and one I(1) atom. In the eighth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Dy(1) and one O(8) atom. In the ninth O site, O(6) is bonded in a single-bond geometry to one O(9) atom. I(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(4), one O(7), one O(8), and one O(9) atom. is represented by the CIF file [CIF]
data_DyIO9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.506
_cell_length_b   7.974
_cell_length_c   12.031
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   94.577
_symmetry_Int_Tables_number   1
_cell_volume   717.766
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  1  0.001  0.817  0.420  1.0
  Dy  Dy1  1  0.999  0.183  0.580  1.0
  Dy  Dy2  1  0.499  0.683  0.920  1.0
  Dy  Dy3  1  0.501  0.317  0.080  1.0
  I  I4  1  0.749  0.746  0.193  1.0
  I  I5  1  0.251  0.254  0.807  1.0
  I  I6  1  0.751  0.754  0.693  1.0
  I  I7  1  0.249  0.246  0.307  1.0
  O  O8  1  0.640  0.573  0.063  1.0
  O  O9  1  0.360  0.427  0.937  1.0
  O  O10  1  0.860  0.927  0.563  1.0
  O  O11  1  0.140  0.073  0.437  1.0
  O  O12  1  0.646  0.574  0.783  1.0
  O  O13  1  0.354  0.426  0.217  1.0
  O  O14  1  0.854  0.926  0.283  1.0
  O  O15  1  0.146  0.074  0.717  1.0
  O  O16  1  0.294  0.769  0.286  1.0
  O  O17  1  0.706  0.231  0.714  1.0
  O  O18  1  0.206  0.731  0.786  1.0
  O  O19  1  0.794  0.269  0.214  1.0
  O  O20  1  0.873  0.598  0.273  1.0
  O  O21  1  0.127  0.402  0.727  1.0
  O  O22  1  0.627  0.902  0.773  1.0
  O  O23  1  0.373  0.098  0.227  1.0
  O  O24  1  0.151  0.583  0.483  1.0
  O  O25  1  0.849  0.417  0.517  1.0
  O  O26  1  0.349  0.917  0.983  1.0
  O  O27  1  0.651  0.083  0.017  1.0
  O  O28  1  0.397  0.837  0.576  1.0
  O  O29  1  0.603  0.163  0.424  1.0
  O  O30  1  0.103  0.663  0.076  1.0
  O  O31  1  0.897  0.337  0.924  1.0
  O  O32  1  0.055  0.751  0.825  1.0
  O  O33  1  0.945  0.249  0.175  1.0
  O  O34  1  0.445  0.749  0.325  1.0
  O  O35  1  0.555  0.251  0.675  1.0
  O  O36  1  0.869  0.580  0.532  1.0
  O  O37  1  0.131  0.420  0.468  1.0
  O  O38  1  0.631  0.920  0.032  1.0
  O  O39  1  0.369  0.080  0.968  1.0
  O  O40  1  0.005  0.783  0.065  1.0
  O  O41  1  0.995  0.217  0.935  1.0
  O  O42  1  0.495  0.717  0.565  1.0
  O  O43  1  0.505  0.283  0.435  1.0
[/CIF]
.
The compound described by DyO9I crystallizes in the monoclinic P2_1/c space group. Dy(1) is bonded in a 7-coordinate geometry to one O(2), one O(3), one O(4), one O(5), one O(8), and two equivalent O(1) atoms. There are nine inequivalent O sites. In the first O site, O(7) is bonded in a distorted single-bond geometry to one O(3) and one I(1) atom. In the second O site, O(8) is bonded in a distorted trigonal planar geometry to one Dy(1), one O(5), and one I(1) atom. In the third O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent Dy(1) and one I(1) atom. In the fourth O site, O(9) is bonded in a water-like geometry to one O(6) and one I(1) atom. In the fifth O site, O(2) is bonded in a water-like geometry to one Dy(1) and one I(1) atom. In the sixth O site, O(3) is bonded in a bent 120 degrees geometry to one Dy(1) and one O(7) atom. In the seventh O site, O(4) is bonded in an L-shaped geometry to one Dy(1) and one I(1) atom. In the eighth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Dy(1) and one O(8) atom. In the ninth O site, O(6) is bonded in a single-bond geometry to one O(9) atom. I(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(4), one O(7), one O(8), and one O(9) atom. is represented by the CIF file [CIF]
data_DyIO9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.506
_cell_length_b   7.974
_cell_length_c   12.031
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   94.577
_symmetry_Int_Tables_number   1
_cell_volume   717.766
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  1  0.001  0.817  0.420  1.0
  Dy  Dy1  1  0.999  0.183  0.580  1.0
  Dy  Dy2  1  0.499  0.683  0.920  1.0
  Dy  Dy3  1  0.501  0.317  0.080  1.0
  I  I4  1  0.749  0.746  0.193  1.0
  I  I5  1  0.251  0.254  0.807  1.0
  I  I6  1  0.751  0.754  0.693  1.0
  I  I7  1  0.249  0.246  0.307  1.0
  O  O8  1  0.640  0.573  0.063  1.0
  O  O9  1  0.360  0.427  0.937  1.0
  O  O10  1  0.860  0.927  0.563  1.0
  O  O11  1  0.140  0.073  0.437  1.0
  O  O12  1  0.646  0.574  0.783  1.0
  O  O13  1  0.354  0.426  0.217  1.0
  O  O14  1  0.854  0.926  0.283  1.0
  O  O15  1  0.146  0.074  0.717  1.0
  O  O16  1  0.294  0.769  0.286  1.0
  O  O17  1  0.706  0.231  0.714  1.0
  O  O18  1  0.206  0.731  0.786  1.0
  O  O19  1  0.794  0.269  0.214  1.0
  O  O20  1  0.873  0.598  0.273  1.0
  O  O21  1  0.127  0.402  0.727  1.0
  O  O22  1  0.627  0.902  0.773  1.0
  O  O23  1  0.373  0.098  0.227  1.0
  O  O24  1  0.151  0.583  0.483  1.0
  O  O25  1  0.849  0.417  0.517  1.0
  O  O26  1  0.349  0.917  0.983  1.0
  O  O27  1  0.651  0.083  0.017  1.0
  O  O28  1  0.397  0.837  0.576  1.0
  O  O29  1  0.603  0.163  0.424  1.0
  O  O30  1  0.103  0.663  0.076  1.0
  O  O31  1  0.897  0.337  0.924  1.0
  O  O32  1  0.055  0.751  0.825  1.0
  O  O33  1  0.945  0.249  0.175  1.0
  O  O34  1  0.445  0.749  0.325  1.0
  O  O35  1  0.555  0.251  0.675  1.0
  O  O36  1  0.869  0.580  0.532  1.0
  O  O37  1  0.131  0.420  0.468  1.0
  O  O38  1  0.631  0.920  0.032  1.0
  O  O39  1  0.369  0.080  0.968  1.0
  O  O40  1  0.005  0.783  0.065  1.0
  O  O41  1  0.995  0.217  0.935  1.0
  O  O42  1  0.495  0.717  0.565  1.0
  O  O43  1  0.505  0.283  0.435  1.0
[/CIF]
.