The compound described by BiO2 is Hydrophilite-like structured and crystallizes in the tetragonal P4_2/mnm space group. Bi(1) is bonded to six equivalent O(1) atoms to form a mixture of edge and corner-sharing BiO6 octahedra. The corner-sharing octahedral tilt angles are 52°. O(1) is bonded in a trigonal planar geometry to three equivalent Bi(1) atoms. is represented by the CIF card [CIF]
data_BiO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.533
_cell_length_b   5.113
_cell_length_c   5.113
_cell_angle_alpha   89.994
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   92.363
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.000  0.500  1.000  1.0
  Bi  Bi1  1  0.500  0.000  0.500  1.0
  O  O2  1  0.500  0.308  0.808  1.0
  O  O3  1  1.000  0.193  0.307  1.0
  O  O4  1  0.000  0.807  0.693  1.0
  O  O5  1  0.500  0.692  0.192  1.0
[/CIF]
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The compound described by BiO2 is Hydrophilite-like structured and crystallizes in the tetragonal P4_2/mnm space group. Bi(1) is bonded to six equivalent O(1) atoms to form a mixture of edge and corner-sharing BiO6 octahedra. The corner-sharing octahedral tilt angles are 52°. O(1) is bonded in a trigonal planar geometry to three equivalent Bi(1) atoms. is represented by the CIF card [CIF]
data_BiO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.533
_cell_length_b   5.113
_cell_length_c   5.113
_cell_angle_alpha   89.994
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   92.363
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.000  0.500  1.000  1.0
  Bi  Bi1  1  0.500  0.000  0.500  1.0
  O  O2  1  0.500  0.308  0.808  1.0
  O  O3  1  1.000  0.193  0.307  1.0
  O  O4  1  0.000  0.807  0.693  1.0
  O  O5  1  0.500  0.692  0.192  1.0
[/CIF]
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