The structure described by VRh2Sn is Heusler structured and crystallizes in the tetragonal I4/mmm space group. V(1) is bonded to eight equivalent Rh(1) and four equivalent Sn(1) atoms to form VSn4Rh8 cuboctahedra that share corners with four equivalent V(1)Sn4Rh8 cuboctahedra, corners with eight equivalent Sn(1)V4Rh8 cuboctahedra, edges with eight equivalent V(1)Sn4Rh8 cuboctahedra, faces with four equivalent V(1)Sn4Rh8 cuboctahedra, and faces with six equivalent Sn(1)V4Rh8 cuboctahedra. Rh(1) is bonded in a distorted body-centered cubic geometry to four equivalent V(1) and four equivalent Sn(1) atoms. Sn(1) is bonded to four equivalent V(1) and eight equivalent Rh(1) atoms to form SnV4Rh8 cuboctahedra that share corners with four equivalent Sn(1)V4Rh8 cuboctahedra, corners with eight equivalent V(1)Sn4Rh8 cuboctahedra, edges with eight equivalent Sn(1)V4Rh8 cuboctahedra, faces with four equivalent Sn(1)V4Rh8 cuboctahedra, and faces with six equivalent V(1)Sn4Rh8 cuboctahedra. is represented by the CIF card [CIF]
data_VSnRh2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.701
_cell_length_b   4.701
_cell_length_c   4.701
_cell_angle_alpha   128.229
_cell_angle_beta   128.229
_cell_angle_gamma   76.254
_symmetry_Int_Tables_number   1
_cell_volume   62.291
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.500  0.500  0.000  1.0
  Sn  Sn1  1  0.000  0.000  0.000  1.0
  Rh  Rh2  1  0.750  0.250  0.500  1.0
  Rh  Rh3  1  0.250  0.750  0.500  1.0
[/CIF]
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The structure described by VRh2Sn is Heusler structured and crystallizes in the tetragonal I4/mmm space group. V(1) is bonded to eight equivalent Rh(1) and four equivalent Sn(1) atoms to form VSn4Rh8 cuboctahedra that share corners with four equivalent V(1)Sn4Rh8 cuboctahedra, corners with eight equivalent Sn(1)V4Rh8 cuboctahedra, edges with eight equivalent V(1)Sn4Rh8 cuboctahedra, faces with four equivalent V(1)Sn4Rh8 cuboctahedra, and faces with six equivalent Sn(1)V4Rh8 cuboctahedra. Rh(1) is bonded in a distorted body-centered cubic geometry to four equivalent V(1) and four equivalent Sn(1) atoms. Sn(1) is bonded to four equivalent V(1) and eight equivalent Rh(1) atoms to form SnV4Rh8 cuboctahedra that share corners with four equivalent Sn(1)V4Rh8 cuboctahedra, corners with eight equivalent V(1)Sn4Rh8 cuboctahedra, edges with eight equivalent Sn(1)V4Rh8 cuboctahedra, faces with four equivalent Sn(1)V4Rh8 cuboctahedra, and faces with six equivalent V(1)Sn4Rh8 cuboctahedra. is represented by the CIF card [CIF]
data_VSnRh2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.701
_cell_length_b   4.701
_cell_length_c   4.701
_cell_angle_alpha   128.229
_cell_angle_beta   128.229
_cell_angle_gamma   76.254
_symmetry_Int_Tables_number   1
_cell_volume   62.291
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.500  0.500  0.000  1.0
  Sn  Sn1  1  0.000  0.000  0.000  1.0
  Rh  Rh2  1  0.750  0.250  0.500  1.0
  Rh  Rh3  1  0.250  0.750  0.500  1.0
[/CIF]
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