The material described by CrP4 is Sylvanite-derived structured and crystallizes in the monoclinic C2/c space group. Cr(1) is bonded to two equivalent P(1) and four equivalent P(2) atoms to form edge-sharing CrP6 octahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded in a distorted rectangular see-saw-like geometry to one Cr(1), one P(2), and two equivalent P(1) atoms. In the second P site, P(2) is bonded in a 4-coordinate geometry to two equivalent Cr(1), one P(1), and one P(2) atom. is represented by the CIF card [CIF]
data_CrP4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.174
_cell_length_b   5.725
_cell_length_c   5.941
_cell_angle_alpha   81.174
_cell_angle_beta   64.186
_cell_angle_gamma   69.381
_symmetry_Int_Tables_number   1
_cell_volume   148.270
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.061  0.250  0.878  1.0
  Cr  Cr1  1  0.939  0.750  0.122  1.0
  P  P2  1  0.494  0.310  0.560  1.0
  P  P3  1  0.946  0.190  0.560  1.0
  P  P4  1  0.184  0.323  0.177  1.0
  P  P5  1  0.639  0.178  0.177  1.0
  P  P6  1  0.816  0.677  0.823  1.0
  P  P7  1  0.361  0.822  0.823  1.0
  P  P8  1  0.054  0.810  0.440  1.0
  P  P9  1  0.506  0.690  0.440  1.0
[/CIF]
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The material described by CrP4 is Sylvanite-derived structured and crystallizes in the monoclinic C2/c space group. Cr(1) is bonded to two equivalent P(1) and four equivalent P(2) atoms to form edge-sharing CrP6 octahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded in a distorted rectangular see-saw-like geometry to one Cr(1), one P(2), and two equivalent P(1) atoms. In the second P site, P(2) is bonded in a 4-coordinate geometry to two equivalent Cr(1), one P(1), and one P(2) atom. is represented by the CIF card [CIF]
data_CrP4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.174
_cell_length_b   5.725
_cell_length_c   5.941
_cell_angle_alpha   81.174
_cell_angle_beta   64.186
_cell_angle_gamma   69.381
_symmetry_Int_Tables_number   1
_cell_volume   148.270
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.061  0.250  0.878  1.0
  Cr  Cr1  1  0.939  0.750  0.122  1.0
  P  P2  1  0.494  0.310  0.560  1.0
  P  P3  1  0.946  0.190  0.560  1.0
  P  P4  1  0.184  0.323  0.177  1.0
  P  P5  1  0.639  0.178  0.177  1.0
  P  P6  1  0.816  0.677  0.823  1.0
  P  P7  1  0.361  0.822  0.823  1.0
  P  P8  1  0.054  0.810  0.440  1.0
  P  P9  1  0.506  0.690  0.440  1.0
[/CIF]
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