The crystal structure described by NaNH2 crystallizes in the orthorhombic Fddd space group. Na(1) is bonded in a 4-coordinate geometry to four equivalent N(1) atoms. N(1) is bonded in a water-like geometry to four equivalent Na(1) and two equivalent H(1) atoms. H(1) is bonded in a single-bond geometry to one N(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_NaH2N
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.780
_cell_length_b   6.401
_cell_length_c   5.959
_cell_angle_alpha   66.428
_cell_angle_beta   59.916
_cell_angle_gamma   53.657
_symmetry_Int_Tables_number   1
_cell_volume   178.271
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.397  0.397  0.103  1.0
  Na  Na1  1  0.853  0.853  0.147  1.0
  Na  Na2  1  0.103  0.103  0.397  1.0
  Na  Na3  1  0.147  0.147  0.853  1.0
  H  H4  1  0.537  0.819  0.031  1.0
  H  H5  1  0.819  0.537  0.612  1.0
  H  H6  1  0.713  0.431  0.219  1.0
  H  H7  1  0.431  0.713  0.638  1.0
  H  H8  1  0.031  0.612  0.537  1.0
  H  H9  1  0.612  0.031  0.819  1.0
  H  H10  1  0.219  0.638  0.713  1.0
  H  H11  1  0.638  0.219  0.431  1.0
  N  N12  1  0.491  0.009  0.009  1.0
  N  N13  1  0.009  0.491  0.491  1.0
  N  N14  1  0.759  0.241  0.241  1.0
  N  N15  1  0.241  0.759  0.759  1.0
[/CIF]
.
The crystal structure described by NaNH2 crystallizes in the orthorhombic Fddd space group. Na(1) is bonded in a 4-coordinate geometry to four equivalent N(1) atoms. N(1) is bonded in a water-like geometry to four equivalent Na(1) and two equivalent H(1) atoms. H(1) is bonded in a single-bond geometry to one N(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_NaH2N
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.780
_cell_length_b   6.401
_cell_length_c   5.959
_cell_angle_alpha   66.428
_cell_angle_beta   59.916
_cell_angle_gamma   53.657
_symmetry_Int_Tables_number   1
_cell_volume   178.271
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.397  0.397  0.103  1.0
  Na  Na1  1  0.853  0.853  0.147  1.0
  Na  Na2  1  0.103  0.103  0.397  1.0
  Na  Na3  1  0.147  0.147  0.853  1.0
  H  H4  1  0.537  0.819  0.031  1.0
  H  H5  1  0.819  0.537  0.612  1.0
  H  H6  1  0.713  0.431  0.219  1.0
  H  H7  1  0.431  0.713  0.638  1.0
  H  H8  1  0.031  0.612  0.537  1.0
  H  H9  1  0.612  0.031  0.819  1.0
  H  H10  1  0.219  0.638  0.713  1.0
  H  H11  1  0.638  0.219  0.431  1.0
  N  N12  1  0.491  0.009  0.009  1.0
  N  N13  1  0.009  0.491  0.491  1.0
  N  N14  1  0.759  0.241  0.241  1.0
  N  N15  1  0.241  0.759  0.759  1.0
[/CIF]
.