The material structure described by Rb2LaAgCl6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic Fm-3m space group. Rb(1) is bonded to twelve equivalent Cl(1) atoms to form RbCl12 cuboctahedra that share corners with twelve equivalent Rb(1)Cl12 cuboctahedra, faces with six equivalent Rb(1)Cl12 cuboctahedra, faces with four equivalent La(1)Cl6 octahedra, and faces with four equivalent Ag(1)Cl6 octahedra. La(1) is bonded to six equivalent Cl(1) atoms to form LaCl6 octahedra that share corners with six equivalent Ag(1)Cl6 octahedra and faces with eight equivalent Rb(1)Cl12 cuboctahedra. The corner-sharing octahedra are not tilted. Ag(1) is bonded to six equivalent Cl(1) atoms to form AgCl6 octahedra that share corners with six equivalent La(1)Cl6 octahedra and faces with eight equivalent Rb(1)Cl12 cuboctahedra. The corner-sharing octahedra are not tilted. Cl(1) is bonded in a distorted linear geometry to four equivalent Rb(1), one La(1), and one Ag(1) atom. is represented by the CIF card [CIF]
data_Rb2LaAgCl6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.799
_cell_length_b   7.799
_cell_length_c   7.799
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   335.410
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.750  0.750  0.750  1.0
  Rb  Rb1  1  0.250  0.250  0.250  1.0
  La  La2  1  0.000  0.000  0.000  1.0
  Ag  Ag3  1  0.500  0.500  0.500  1.0
  Cl  Cl4  1  0.749  0.251  0.251  1.0
  Cl  Cl5  1  0.251  0.251  0.749  1.0
  Cl  Cl6  1  0.251  0.749  0.749  1.0
  Cl  Cl7  1  0.251  0.749  0.251  1.0
  Cl  Cl8  1  0.749  0.251  0.749  1.0
  Cl  Cl9  1  0.749  0.749  0.251  1.0
[/CIF]
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The material structure described by Rb2LaAgCl6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic Fm-3m space group. Rb(1) is bonded to twelve equivalent Cl(1) atoms to form RbCl12 cuboctahedra that share corners with twelve equivalent Rb(1)Cl12 cuboctahedra, faces with six equivalent Rb(1)Cl12 cuboctahedra, faces with four equivalent La(1)Cl6 octahedra, and faces with four equivalent Ag(1)Cl6 octahedra. La(1) is bonded to six equivalent Cl(1) atoms to form LaCl6 octahedra that share corners with six equivalent Ag(1)Cl6 octahedra and faces with eight equivalent Rb(1)Cl12 cuboctahedra. The corner-sharing octahedra are not tilted. Ag(1) is bonded to six equivalent Cl(1) atoms to form AgCl6 octahedra that share corners with six equivalent La(1)Cl6 octahedra and faces with eight equivalent Rb(1)Cl12 cuboctahedra. The corner-sharing octahedra are not tilted. Cl(1) is bonded in a distorted linear geometry to four equivalent Rb(1), one La(1), and one Ag(1) atom. is represented by the CIF card [CIF]
data_Rb2LaAgCl6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.799
_cell_length_b   7.799
_cell_length_c   7.799
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   335.410
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.750  0.750  0.750  1.0
  Rb  Rb1  1  0.250  0.250  0.250  1.0
  La  La2  1  0.000  0.000  0.000  1.0
  Ag  Ag3  1  0.500  0.500  0.500  1.0
  Cl  Cl4  1  0.749  0.251  0.251  1.0
  Cl  Cl5  1  0.251  0.251  0.749  1.0
  Cl  Cl6  1  0.251  0.749  0.749  1.0
  Cl  Cl7  1  0.251  0.749  0.251  1.0
  Cl  Cl8  1  0.749  0.251  0.749  1.0
  Cl  Cl9  1  0.749  0.749  0.251  1.0
[/CIF]
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