The structure described by KP(OF)2 crystallizes in the orthorhombic Pnma space group. K(1) is bonded in a 8-coordinate geometry to six equivalent O(1), one F(1), and one F(2) atom. P(1) is bonded in a tetrahedral geometry to two equivalent O(1), one F(1), and one F(2) atom. O(1) is bonded in a distorted single-bond geometry to three equivalent K(1) and one P(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to one K(1) and one P(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one K(1) and one P(1) atom. is represented by the CIF file [CIF]
data_KP(OF)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.162
_cell_length_b   7.535
_cell_length_c   7.893
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   366.494
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.250  0.144  0.151  1.0
  K  K1  1  0.750  0.644  0.349  1.0
  K  K2  1  0.250  0.356  0.651  1.0
  K  K3  1  0.750  0.856  0.849  1.0
  P  P4  1  0.250  0.808  0.592  1.0
  P  P5  1  0.750  0.192  0.408  1.0
  P  P6  1  0.750  0.308  0.908  1.0
  P  P7  1  0.250  0.692  0.092  1.0
  O  O8  1  0.040  0.715  0.598  1.0
  O  O9  1  0.960  0.285  0.402  1.0
  O  O10  1  0.540  0.285  0.402  1.0
  O  O11  1  0.460  0.715  0.598  1.0
  O  O12  1  0.460  0.785  0.098  1.0
  O  O13  1  0.960  0.215  0.902  1.0
  O  O14  1  0.040  0.785  0.098  1.0
  O  O15  1  0.540  0.215  0.902  1.0
  F  F16  1  0.750  0.438  0.065  1.0
  F  F17  1  0.750  0.043  0.267  1.0
  F  F18  1  0.750  0.457  0.767  1.0
  F  F19  1  0.750  0.062  0.565  1.0
  F  F20  1  0.250  0.957  0.733  1.0
  F  F21  1  0.250  0.543  0.233  1.0
  F  F22  1  0.250  0.938  0.435  1.0
  F  F23  1  0.250  0.562  0.935  1.0
[/CIF]
.
The structure described by KP(OF)2 crystallizes in the orthorhombic Pnma space group. K(1) is bonded in a 8-coordinate geometry to six equivalent O(1), one F(1), and one F(2) atom. P(1) is bonded in a tetrahedral geometry to two equivalent O(1), one F(1), and one F(2) atom. O(1) is bonded in a distorted single-bond geometry to three equivalent K(1) and one P(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to one K(1) and one P(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one K(1) and one P(1) atom. is represented by the CIF file [CIF]
data_KP(OF)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.162
_cell_length_b   7.535
_cell_length_c   7.893
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   366.494
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.250  0.144  0.151  1.0
  K  K1  1  0.750  0.644  0.349  1.0
  K  K2  1  0.250  0.356  0.651  1.0
  K  K3  1  0.750  0.856  0.849  1.0
  P  P4  1  0.250  0.808  0.592  1.0
  P  P5  1  0.750  0.192  0.408  1.0
  P  P6  1  0.750  0.308  0.908  1.0
  P  P7  1  0.250  0.692  0.092  1.0
  O  O8  1  0.040  0.715  0.598  1.0
  O  O9  1  0.960  0.285  0.402  1.0
  O  O10  1  0.540  0.285  0.402  1.0
  O  O11  1  0.460  0.715  0.598  1.0
  O  O12  1  0.460  0.785  0.098  1.0
  O  O13  1  0.960  0.215  0.902  1.0
  O  O14  1  0.040  0.785  0.098  1.0
  O  O15  1  0.540  0.215  0.902  1.0
  F  F16  1  0.750  0.438  0.065  1.0
  F  F17  1  0.750  0.043  0.267  1.0
  F  F18  1  0.750  0.457  0.767  1.0
  F  F19  1  0.750  0.062  0.565  1.0
  F  F20  1  0.250  0.957  0.733  1.0
  F  F21  1  0.250  0.543  0.233  1.0
  F  F22  1  0.250  0.938  0.435  1.0
  F  F23  1  0.250  0.562  0.935  1.0
[/CIF]
.