The material structure described by V3(O2F)2 is Hydrophilite-derived structured and crystallizes in the triclinic P1 space group. There are six inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(5), one O(6), one O(8), one F(3), and one F(4) atom to form a mixture of edge and corner-sharing VO4F2 octahedra. The corner-sharing octahedral tilt angles range from 46-53°. In the second V site, V(2) is bonded to one O(1), one O(4), one O(6), one O(7), one F(1), and one F(2) atom to form a mixture of edge and corner-sharing VO4F2 octahedra. The corner-sharing octahedral tilt angles range from 43-53°. In the third V site, V(3) is bonded to one O(2), one O(3), one O(5), one O(8), one F(1), and one F(2) atom to form a mixture of edge and corner-sharing VO4F2 octahedra. The corner-sharing octahedral tilt angles range from 42-54°. In the fourth V site, V(4) is bonded to one O(2), one O(5), one O(6), one O(7), one F(3), and one F(4) atom to form a mixture of edge and corner-sharing VO4F2 octahedra. The corner-sharing octahedral tilt angles range from 45-53°. In the fifth V site, V(5) is bonded to one O(2), one O(3), one O(4), one O(8), one F(1), and one F(3) atom to form a mixture of edge and corner-sharing VO4F2 octahedra. The corner-sharing octahedral tilt angles range from 42-58°. In the sixth V site, V(6) is bonded to one O(1), one O(3), one O(4), one O(7), one F(2), and one F(4) atom to form a mixture of edge and corner-sharing VO4F2 octahedra. The corner-sharing octahedral tilt angles range from 46-58°. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one V(1), one V(2), and one V(6) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one V(3), one V(4), and one V(5) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one V(3), one V(5), and one V(6) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one V(2), one V(5), and one V(6) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one V(1), one V(3), and one V(4) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one V(4) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to one V(2), one V(4), and one V(6) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to one V(1), one V(3), and one V(5) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one V(2), one V(3), and one V(5) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one V(2), one V(3), and one V(6) atom. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one V(1), one V(4), and one V(5) atom. In the fourth F site, F(4) is bonded in a trigonal planar geometry to one V(1), one V(4), and one V(6) atom. is represented by the CIF file [CIF]
data_V3(O2F)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.677
_cell_length_b   7.765
_cell_length_c   5.588
_cell_angle_alpha   94.196
_cell_angle_beta   89.680
_cell_angle_gamma   89.362
_symmetry_Int_Tables_number   1
_cell_volume   202.377
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.008  0.669  0.687  1.0
  V  V1  1  0.520  0.356  0.808  1.0
  V  V2  1  0.018  0.977  0.016  1.0
  V  V3  1  0.510  0.663  0.154  1.0
  V  V4  1  0.481  0.014  0.493  1.0
  V  V5  1  0.982  0.322  0.330  1.0
  O  O6  1  0.792  0.439  0.630  1.0
  O  O7  1  0.296  0.888  0.212  1.0
  O  O8  1  0.809  0.089  0.284  1.0
  O  O9  1  0.301  0.244  0.536  1.0
  O  O10  1  0.807  0.769  0.974  1.0
  O  O11  1  0.303  0.561  0.863  1.0
  O  O12  1  0.690  0.428  0.122  1.0
  O  O13  1  0.191  0.913  0.722  1.0
  F  F14  1  0.701  0.111  0.800  1.0
  F  F15  1  0.212  0.223  0.027  1.0
  F  F16  1  0.693  0.769  0.478  1.0
  F  F17  1  0.186  0.566  0.363  1.0
[/CIF]
.
The material structure described by V3(O2F)2 is Hydrophilite-derived structured and crystallizes in the triclinic P1 space group. There are six inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(5), one O(6), one O(8), one F(3), and one F(4) atom to form a mixture of edge and corner-sharing VO4F2 octahedra. The corner-sharing octahedral tilt angles range from 46-53°. In the second V site, V(2) is bonded to one O(1), one O(4), one O(6), one O(7), one F(1), and one F(2) atom to form a mixture of edge and corner-sharing VO4F2 octahedra. The corner-sharing octahedral tilt angles range from 43-53°. In the third V site, V(3) is bonded to one O(2), one O(3), one O(5), one O(8), one F(1), and one F(2) atom to form a mixture of edge and corner-sharing VO4F2 octahedra. The corner-sharing octahedral tilt angles range from 42-54°. In the fourth V site, V(4) is bonded to one O(2), one O(5), one O(6), one O(7), one F(3), and one F(4) atom to form a mixture of edge and corner-sharing VO4F2 octahedra. The corner-sharing octahedral tilt angles range from 45-53°. In the fifth V site, V(5) is bonded to one O(2), one O(3), one O(4), one O(8), one F(1), and one F(3) atom to form a mixture of edge and corner-sharing VO4F2 octahedra. The corner-sharing octahedral tilt angles range from 42-58°. In the sixth V site, V(6) is bonded to one O(1), one O(3), one O(4), one O(7), one F(2), and one F(4) atom to form a mixture of edge and corner-sharing VO4F2 octahedra. The corner-sharing octahedral tilt angles range from 46-58°. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one V(1), one V(2), and one V(6) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one V(3), one V(4), and one V(5) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one V(3), one V(5), and one V(6) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one V(2), one V(5), and one V(6) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one V(1), one V(3), and one V(4) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one V(4) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to one V(2), one V(4), and one V(6) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to one V(1), one V(3), and one V(5) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one V(2), one V(3), and one V(5) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one V(2), one V(3), and one V(6) atom. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one V(1), one V(4), and one V(5) atom. In the fourth F site, F(4) is bonded in a trigonal planar geometry to one V(1), one V(4), and one V(6) atom. is represented by the CIF file [CIF]
data_V3(O2F)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.677
_cell_length_b   7.765
_cell_length_c   5.588
_cell_angle_alpha   94.196
_cell_angle_beta   89.680
_cell_angle_gamma   89.362
_symmetry_Int_Tables_number   1
_cell_volume   202.377
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.008  0.669  0.687  1.0
  V  V1  1  0.520  0.356  0.808  1.0
  V  V2  1  0.018  0.977  0.016  1.0
  V  V3  1  0.510  0.663  0.154  1.0
  V  V4  1  0.481  0.014  0.493  1.0
  V  V5  1  0.982  0.322  0.330  1.0
  O  O6  1  0.792  0.439  0.630  1.0
  O  O7  1  0.296  0.888  0.212  1.0
  O  O8  1  0.809  0.089  0.284  1.0
  O  O9  1  0.301  0.244  0.536  1.0
  O  O10  1  0.807  0.769  0.974  1.0
  O  O11  1  0.303  0.561  0.863  1.0
  O  O12  1  0.690  0.428  0.122  1.0
  O  O13  1  0.191  0.913  0.722  1.0
  F  F14  1  0.701  0.111  0.800  1.0
  F  F15  1  0.212  0.223  0.027  1.0
  F  F16  1  0.693  0.769  0.478  1.0
  F  F17  1  0.186  0.566  0.363  1.0
[/CIF]
.