The structure described by VNCl5N2 is Indium-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of eight ammonia atoms and four VNCl5 clusters. In each VNCl5 cluster, V(1) is bonded in a trigonal bipyramidal geometry to one N(1), one Cl(1), one Cl(4), and two equivalent Cl(3) atoms. N(1) is bonded in a 2-coordinate geometry to one V(1) and one Cl(2) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(4) is bonded in a single-bond geometry to one V(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one V(1) atom. In the third Cl site, Cl(2) is bonded in a single-bond geometry to one N(1) atom. In the fourth Cl site, Cl(3) is bonded in a single-bond geometry to one V(1) atom. is represented by the CIF file [CIF]
data_VN3Cl5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.518
_cell_length_b   10.856
_cell_length_c   13.618
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1111.501
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.745  0.750  0.609  1.0
  V  V1  1  0.255  0.250  0.391  1.0
  V  V2  1  0.245  0.250  0.891  1.0
  V  V3  1  0.755  0.750  0.109  1.0
  N  N4  1  0.980  0.750  0.584  1.0
  N  N5  1  0.020  0.250  0.416  1.0
  N  N6  1  0.480  0.250  0.916  1.0
  N  N7  1  0.520  0.750  0.084  1.0
  N  N8  1  0.858  0.508  0.857  1.0
  N  N9  1  0.142  0.492  0.143  1.0
  N  N10  1  0.358  0.492  0.643  1.0
  N  N11  1  0.142  0.008  0.143  1.0
  N  N12  1  0.642  0.508  0.357  1.0
  N  N13  1  0.858  0.992  0.857  1.0
  N  N14  1  0.642  0.992  0.357  1.0
  N  N15  1  0.358  0.008  0.643  1.0
  Cl  Cl16  1  0.578  0.750  0.480  1.0
  Cl  Cl17  1  0.422  0.250  0.520  1.0
  Cl  Cl18  1  0.078  0.250  0.020  1.0
  Cl  Cl19  1  0.922  0.750  0.980  1.0
  Cl  Cl20  1  0.156  0.750  0.649  1.0
  Cl  Cl21  1  0.844  0.250  0.351  1.0
  Cl  Cl22  1  0.656  0.250  0.851  1.0
  Cl  Cl23  1  0.344  0.750  0.149  1.0
  Cl  Cl24  1  0.781  0.543  0.617  1.0
  Cl  Cl25  1  0.219  0.457  0.383  1.0
  Cl  Cl26  1  0.281  0.457  0.883  1.0
  Cl  Cl27  1  0.219  0.043  0.383  1.0
  Cl  Cl28  1  0.719  0.543  0.117  1.0
  Cl  Cl29  1  0.781  0.957  0.617  1.0
  Cl  Cl30  1  0.719  0.957  0.117  1.0
  Cl  Cl31  1  0.281  0.043  0.883  1.0
  Cl  Cl32  1  0.596  0.750  0.747  1.0
  Cl  Cl33  1  0.404  0.250  0.253  1.0
  Cl  Cl34  1  0.096  0.250  0.753  1.0
  Cl  Cl35  1  0.904  0.750  0.247  1.0
[/CIF]
.
The structure described by VNCl5N2 is Indium-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of eight ammonia atoms and four VNCl5 clusters. In each VNCl5 cluster, V(1) is bonded in a trigonal bipyramidal geometry to one N(1), one Cl(1), one Cl(4), and two equivalent Cl(3) atoms. N(1) is bonded in a 2-coordinate geometry to one V(1) and one Cl(2) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(4) is bonded in a single-bond geometry to one V(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one V(1) atom. In the third Cl site, Cl(2) is bonded in a single-bond geometry to one N(1) atom. In the fourth Cl site, Cl(3) is bonded in a single-bond geometry to one V(1) atom. is represented by the CIF file [CIF]
data_VN3Cl5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.518
_cell_length_b   10.856
_cell_length_c   13.618
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1111.501
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.745  0.750  0.609  1.0
  V  V1  1  0.255  0.250  0.391  1.0
  V  V2  1  0.245  0.250  0.891  1.0
  V  V3  1  0.755  0.750  0.109  1.0
  N  N4  1  0.980  0.750  0.584  1.0
  N  N5  1  0.020  0.250  0.416  1.0
  N  N6  1  0.480  0.250  0.916  1.0
  N  N7  1  0.520  0.750  0.084  1.0
  N  N8  1  0.858  0.508  0.857  1.0
  N  N9  1  0.142  0.492  0.143  1.0
  N  N10  1  0.358  0.492  0.643  1.0
  N  N11  1  0.142  0.008  0.143  1.0
  N  N12  1  0.642  0.508  0.357  1.0
  N  N13  1  0.858  0.992  0.857  1.0
  N  N14  1  0.642  0.992  0.357  1.0
  N  N15  1  0.358  0.008  0.643  1.0
  Cl  Cl16  1  0.578  0.750  0.480  1.0
  Cl  Cl17  1  0.422  0.250  0.520  1.0
  Cl  Cl18  1  0.078  0.250  0.020  1.0
  Cl  Cl19  1  0.922  0.750  0.980  1.0
  Cl  Cl20  1  0.156  0.750  0.649  1.0
  Cl  Cl21  1  0.844  0.250  0.351  1.0
  Cl  Cl22  1  0.656  0.250  0.851  1.0
  Cl  Cl23  1  0.344  0.750  0.149  1.0
  Cl  Cl24  1  0.781  0.543  0.617  1.0
  Cl  Cl25  1  0.219  0.457  0.383  1.0
  Cl  Cl26  1  0.281  0.457  0.883  1.0
  Cl  Cl27  1  0.219  0.043  0.383  1.0
  Cl  Cl28  1  0.719  0.543  0.117  1.0
  Cl  Cl29  1  0.781  0.957  0.617  1.0
  Cl  Cl30  1  0.719  0.957  0.117  1.0
  Cl  Cl31  1  0.281  0.043  0.883  1.0
  Cl  Cl32  1  0.596  0.750  0.747  1.0
  Cl  Cl33  1  0.404  0.250  0.253  1.0
  Cl  Cl34  1  0.096  0.250  0.753  1.0
  Cl  Cl35  1  0.904  0.750  0.247  1.0
[/CIF]
.