The material structure described by N2Se3(AsF6)2 is Indium-derived structured and crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of eight AsF6 clusters and four N2Se3 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. There are three inequivalent F sites. In the first F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In each N2Se3 cluster, N(1,2) is bonded in a bent 120 degrees geometry to one Se(1,2) and one Se(3) atom. There are two inequivalent Se sites. In the first Se site, Se(1,2) is bonded in a single-bond geometry to one N(1,2) atom. In the second Se site, Se(3) is bonded in a water-like geometry to two equivalent N(1,2) atoms. is represented by the CIF file [CIF]
data_As2Se3(NF6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.905
_cell_length_b   7.905
_cell_length_c   11.180
_cell_angle_alpha   88.864
_cell_angle_beta   88.864
_cell_angle_gamma   68.171
_symmetry_Int_Tables_number   1
_cell_volume   648.340
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.093  0.907  0.500  1.0
  As  As1  1  0.098  0.902  0.000  1.0
  As  As2  1  0.482  0.248  0.249  1.0
  As  As3  1  0.752  0.518  0.751  1.0
  Se  Se4  1  0.942  0.479  0.357  1.0
  Se  Se5  1  0.521  0.058  0.643  1.0
  Se  Se6  1  0.949  0.479  0.142  1.0
  Se  Se7  1  0.521  0.051  0.858  1.0
  Se  Se8  1  0.572  0.707  0.247  1.0
  Se  Se9  1  0.293  0.428  0.753  1.0
  N  N10  1  0.724  0.620  0.125  1.0
  N  N11  1  0.380  0.276  0.875  1.0
  N  N12  1  0.716  0.620  0.371  1.0
  N  N13  1  0.380  0.284  0.629  1.0
  F  F14  1  0.306  0.836  0.421  1.0
  F  F15  1  0.164  0.694  0.579  1.0
  F  F16  1  0.882  0.979  0.579  1.0
  F  F17  1  0.021  0.118  0.421  1.0
  F  F18  1  0.188  0.999  0.612  1.0
  F  F19  1  0.001  0.812  0.388  1.0
  F  F20  1  0.182  0.980  0.871  1.0
  F  F21  1  0.020  0.818  0.129  1.0
  F  F22  1  0.880  0.966  0.935  1.0
  F  F23  1  0.034  0.120  0.065  1.0
  F  F24  1  0.319  0.838  0.064  1.0
  F  F25  1  0.162  0.681  0.936  1.0
  F  F26  1  0.409  0.416  0.361  1.0
  F  F27  1  0.584  0.591  0.639  1.0
  F  F28  1  0.546  0.078  0.138  1.0
  F  F29  1  0.922  0.454  0.862  1.0
  F  F30  1  0.415  0.421  0.137  1.0
  F  F31  1  0.579  0.585  0.863  1.0
  F  F32  1  0.254  0.246  0.249  1.0
  F  F33  1  0.754  0.746  0.751  1.0
  F  F34  1  0.541  0.074  0.361  1.0
  F  F35  1  0.926  0.459  0.639  1.0
  F  F36  1  0.703  0.254  0.249  1.0
  F  F37  1  0.746  0.297  0.751  1.0
[/CIF]
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The material structure described by N2Se3(AsF6)2 is Indium-derived structured and crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of eight AsF6 clusters and four N2Se3 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. There are three inequivalent F sites. In the first F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In each N2Se3 cluster, N(1,2) is bonded in a bent 120 degrees geometry to one Se(1,2) and one Se(3) atom. There are two inequivalent Se sites. In the first Se site, Se(1,2) is bonded in a single-bond geometry to one N(1,2) atom. In the second Se site, Se(3) is bonded in a water-like geometry to two equivalent N(1,2) atoms. is represented by the CIF file [CIF]
data_As2Se3(NF6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.905
_cell_length_b   7.905
_cell_length_c   11.180
_cell_angle_alpha   88.864
_cell_angle_beta   88.864
_cell_angle_gamma   68.171
_symmetry_Int_Tables_number   1
_cell_volume   648.340
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.093  0.907  0.500  1.0
  As  As1  1  0.098  0.902  0.000  1.0
  As  As2  1  0.482  0.248  0.249  1.0
  As  As3  1  0.752  0.518  0.751  1.0
  Se  Se4  1  0.942  0.479  0.357  1.0
  Se  Se5  1  0.521  0.058  0.643  1.0
  Se  Se6  1  0.949  0.479  0.142  1.0
  Se  Se7  1  0.521  0.051  0.858  1.0
  Se  Se8  1  0.572  0.707  0.247  1.0
  Se  Se9  1  0.293  0.428  0.753  1.0
  N  N10  1  0.724  0.620  0.125  1.0
  N  N11  1  0.380  0.276  0.875  1.0
  N  N12  1  0.716  0.620  0.371  1.0
  N  N13  1  0.380  0.284  0.629  1.0
  F  F14  1  0.306  0.836  0.421  1.0
  F  F15  1  0.164  0.694  0.579  1.0
  F  F16  1  0.882  0.979  0.579  1.0
  F  F17  1  0.021  0.118  0.421  1.0
  F  F18  1  0.188  0.999  0.612  1.0
  F  F19  1  0.001  0.812  0.388  1.0
  F  F20  1  0.182  0.980  0.871  1.0
  F  F21  1  0.020  0.818  0.129  1.0
  F  F22  1  0.880  0.966  0.935  1.0
  F  F23  1  0.034  0.120  0.065  1.0
  F  F24  1  0.319  0.838  0.064  1.0
  F  F25  1  0.162  0.681  0.936  1.0
  F  F26  1  0.409  0.416  0.361  1.0
  F  F27  1  0.584  0.591  0.639  1.0
  F  F28  1  0.546  0.078  0.138  1.0
  F  F29  1  0.922  0.454  0.862  1.0
  F  F30  1  0.415  0.421  0.137  1.0
  F  F31  1  0.579  0.585  0.863  1.0
  F  F32  1  0.254  0.246  0.249  1.0
  F  F33  1  0.754  0.746  0.751  1.0
  F  F34  1  0.541  0.074  0.361  1.0
  F  F35  1  0.926  0.459  0.639  1.0
  F  F36  1  0.703  0.254  0.249  1.0
  F  F37  1  0.746  0.297  0.751  1.0
[/CIF]
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