The crystal structure described by Al22Mo5 crystallizes in the monoclinic C2 space group. There are six inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 11-coordinate geometry to one Al(11); one Al(2); two equivalent Al(9); three Al(1,1); and four Al(8,8) atoms. In the second Mo site, Mo(2) is bonded to one Al(2), one Al(5), one Al(7), one Al(9), two equivalent Al(10), two equivalent Al(11), two equivalent Al(4), and two equivalent Al(6) atoms to form MoAl12 cuboctahedra that share  a cornercorner with one Mo(3)Al12 cuboctahedra,  a cornercorner with one Al(10)Al9Mo3 cuboctahedra, corners with four equivalent Mo(2)Al12 cuboctahedra, corners with five equivalent Al(7)Al9Mo3 cuboctahedra, edges with two equivalent Mo(2)Al12 cuboctahedra, edges with two equivalent Mo(3)Al12 cuboctahedra,  a faceface with one Al(7)Al9Mo3 cuboctahedra, and faces with three equivalent Al(10)Al9Mo3 cuboctahedra. In the third Mo site, Mo(2) is bonded to one Al(2), one Al(5), one Al(7), one Al(9), two equivalent Al(10), two equivalent Al(11), two equivalent Al(4), and two equivalent Al(6) atoms to form MoAl12 cuboctahedra that share  a cornercorner with one Mo(3)Al12 cuboctahedra,  a cornercorner with one Al(10)Al9Mo3 cuboctahedra, corners with four equivalent Mo(2)Al12 cuboctahedra, corners with five equivalent Al(7)Al9Mo3 cuboctahedra, edges with two equivalent Mo(2)Al12 cuboctahedra, edges with two equivalent Mo(3)Al12 cuboctahedra,  a faceface with one Al(7)Al9Mo3 cuboctahedra, and faces with three equivalent Al(10)Al9Mo3 cuboctahedra. In the fourth Mo site, Mo(1) is bonded in a 11-coordinate geometry to one Al(11); one Al(2); two equivalent Al(9); three Al(1,1); and four Al(8,8) atoms. In the fifth Mo site, Mo(3) is bonded to two equivalent Al(10), two equivalent Al(5), four equivalent Al(3), and four equivalent Al(7) atoms to form MoAl12 cuboctahedra that share corners with two equivalent Mo(2)Al12 cuboctahedra, corners with two equivalent Al(7)Al9Mo3 cuboctahedra, corners with four equivalent Mo(3)Al12 cuboctahedra, corners with eight equivalent Al(10)Al9Mo3 cuboctahedra, edges with two equivalent Mo(3)Al12 cuboctahedra, edges with four equivalent Mo(2)Al12 cuboctahedra, faces with two equivalent Al(10)Al9Mo3 cuboctahedra, and faces with six equivalent Al(7)Al9Mo3 cuboctahedra. In the sixth Mo site, Mo(3) is bonded to two equivalent Al(10), two equivalent Al(5), four equivalent Al(3), and four equivalent Al(7) atoms to form MoAl12 cuboctahedra that share corners with two equivalent Mo(2)Al12 cuboctahedra, corners with two equivalent Al(7)Al9Mo3 cuboctahedra, corners with four equivalent Mo(3)Al12 cuboctahedra, corners with eight equivalent Al(10)Al9Mo3 cuboctahedra, edges with two equivalent Mo(3)Al12 cuboctahedra, edges with four equivalent Mo(2)Al12 cuboctahedra, faces with two equivalent Al(10)Al9Mo3 cuboctahedra, and faces with six equivalent Al(7)Al9Mo3 cuboctahedra. There are twenty-two inequivalent Al sites. In the first Al site, Al(1) is bonded in a 3-coordinate geometry to three Mo(1,1) and one Al(11) atom. In the second Al site, Al(2) is bonded in a 2-coordinate geometry to one Mo(1), one Mo(2), and two equivalent Al(11) atoms. In the third Al site, Al(3) is bonded in a distorted bent 150 degrees geometry to two equivalent Mo(3), one Al(10), and three equivalent Al(7) atoms. In the fourth Al site, Al(4) is bonded in a 2-coordinate geometry to two equivalent Mo(2), one Al(10), one Al(9), and two equivalent Al(11) atoms. In the fifth Al site, Al(5) is bonded in a distorted bent 150 degrees geometry to one Mo(2), one Mo(3), two equivalent Al(10), and two equivalent Al(7) atoms. In the sixth Al site, Al(5) is bonded in a distorted bent 150 degrees geometry to one Mo(2), one Mo(3), two equivalent Al(10), and two equivalent Al(7) atoms. In the seventh Al site, Al(6) is bonded in a distorted bent 150 degrees geometry to two equivalent Mo(2), one Al(11), one Al(7), and two equivalent Al(10) atoms. In the eighth Al site, Al(7) is bonded to one Mo(2), two equivalent Mo(3), one Al(6), one Al(7), two equivalent Al(10), two equivalent Al(5), and three equivalent Al(3) atoms to form distorted AlAl9Mo3 cuboctahedra that share  a cornercorner with one Mo(3)Al12 cuboctahedra, corners with two equivalent Al(10)Al9Mo3 cuboctahedra, corners with five equivalent Mo(2)Al12 cuboctahedra, corners with eight equivalent Al(7)Al9Mo3 cuboctahedra, edges with two equivalent Al(10)Al9Mo3 cuboctahedra, edges with two equivalent Al(7)Al9Mo3 cuboctahedra,  a faceface with one Mo(2)Al12 cuboctahedra,  a faceface with one Al(7)Al9Mo3 cuboctahedra, faces with three equivalent Mo(3)Al12 cuboctahedra, and faces with three equivalent Al(10)Al9Mo3 cuboctahedra. In the ninth Al site, Al(8) is bonded in a 3-coordinate geometry to four Mo(1,1) atoms. In the tenth Al site, Al(9) is bonded in a 3-coordinate geometry to one Mo(2), two equivalent Mo(1), and two equivalent Al(11) atoms. In the eleventh Al site, Al(1) is bonded in a 3-coordinate geometry to three Mo(1,1); one Al(11); and two equivalent Al(9) atoms. In the twelfth Al site, Al(10) is bonded to one Mo(3), two equivalent Mo(2), one Al(11), one Al(3), one Al(4), two equivalent Al(5), two equivalent Al(6), and two equivalent Al(7) atoms to form distorted AlAl9Mo3 cuboctahedra that share  a cornercorner with one Mo(2)Al12 cuboctahedra, corners with two equivalent Al(7)Al9Mo3 cuboctahedra, corners with four equivalent Mo(3)Al12 cuboctahedra, corners with five equivalent Al(10)Al9Mo3 cuboctahedra, edges with two equivalent Al(10)Al9Mo3 cuboctahedra, edges with two equivalent Al(7)Al9Mo3 cuboctahedra,  a faceface with one Mo(3)Al12 cuboctahedra, faces with three equivalent Mo(2)Al12 cuboctahedra, and faces with three equivalent Al(7)Al9Mo3 cuboctahedra. In the thirteenth Al site, Al(10) is bonded to one Mo(3), two equivalent Mo(2), one Al(11), one Al(3), one Al(4), two equivalent Al(5), two equivalent Al(6), and two equivalent Al(7) atoms to form distorted AlAl9Mo3 cuboctahedra that share  a cornercorner with one Mo(2)Al12 cuboctahedra, corners with two equivalent Al(7)Al9Mo3 cuboctahedra, corners with four equivalent Mo(3)Al12 cuboctahedra, corners with five equivalent Al(10)Al9Mo3 cuboctahedra, edges with two equivalent Al(10)Al9Mo3 cuboctahedra, edges with two equivalent Al(7)Al9Mo3 cuboctahedra,  a faceface with one Mo(3)Al12 cuboctahedra, faces with three equivalent Mo(2)Al12 cuboctahedra, and faces with three equivalent Al(7)Al9Mo3 cuboctahedra. In the fourteenth Al site, Al(4) is bonded in a 2-coordinate geometry to two equivalent Mo(2), one Al(10), and two equivalent Al(11) atoms. In the fifteenth Al site, Al(7) is bonded to one Mo(2), two equivalent Mo(3), one Al(6), one Al(7), two equivalent Al(10), two equivalent Al(5), and three equivalent Al(3) atoms to form distorted AlAl9Mo3 cuboctahedra that share  a cornercorner with one Mo(3)Al12 cuboctahedra, corners with two equivalent Al(10)Al9Mo3 cuboctahedra, corners with five equivalent Mo(2)Al12 cuboctahedra, corners with eight equivalent Al(7)Al9Mo3 cuboctahedra, edges with two equivalent Al(10)Al9Mo3 cuboctahedra, edges with two equivalent Al(7)Al9Mo3 cuboctahedra,  a faceface with one Mo(2)Al12 cuboctahedra,  a faceface with one Al(7)Al9Mo3 cuboctahedra, faces with three equivalent Mo(3)Al12 cuboctahedra, and faces with three equivalent Al(10)Al9Mo3 cuboctahedra. In the sixteenth Al site, Al(3) is bonded in a distorted bent 150 degrees geometry to two equivalent Mo(3), one Al(10), and three equivalent Al(7) atoms. In the seventeenth Al site, Al(9) is bonded in a 11-coordinate geometry to one Mo(2), two equivalent Mo(1), one Al(4), one Al(8), two equivalent Al(1), two equivalent Al(11), and two equivalent Al(2) atoms. In the eighteenth Al site, Al(11) is bonded in a 12-coordinate geometry to one Mo(1), two equivalent Mo(2), one Al(1), one Al(10), one Al(6), two equivalent Al(2), two equivalent Al(4), and two equivalent Al(9) atoms. In the nineteenth Al site, Al(2) is bonded in a 2-coordinate geometry to one Mo(1), one Mo(2), two equivalent Al(11), and two equivalent Al(9) atoms. In the twentieth Al site, Al(11) is bonded in a 12-coordinate geometry to one Mo(1), two equivalent Mo(2), one Al(1), one Al(10), one Al(6), two equivalent Al(2), two equivalent Al(4), and two equivalent Al(9) atoms. In the twenty-first Al site, Al(8) is bonded in a 3-coordinate geometry to four Mo(1,1) and one Al(9) atom. In the twenty-second Al site, Al(6) is bonded in a distorted bent 150 degrees geometry to two equivalent Mo(2), one Al(11), one Al(7), and two equivalent Al(10) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Al22Mo5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.897
_cell_length_b   5.185
_cell_length_c   36.647
_cell_angle_alpha   88.195
_cell_angle_beta   86.171
_cell_angle_gamma   61.818
_symmetry_Int_Tables_number   1
_cell_volume   818.399
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  0.059  0.034  0.208  1.0
  Al  Al1  1  0.606  0.945  0.168  1.0
  Al  Al2  1  0.455  0.455  0.982  1.0
  Al  Al3  1  0.276  0.667  0.629  1.0
  Al  Al4  1  0.614  0.147  0.444  1.0
  Al  Al5  1  0.308  0.647  0.056  1.0
  Al  Al6  1  0.719  0.055  0.832  1.0
  Al  Al7  1  0.011  0.353  0.944  1.0
  Al  Al8  1  0.592  0.257  0.906  1.0
  Al  Al9  1  0.205  0.853  0.556  1.0
  Al  Al10  1  0.563  0.919  0.962  1.0
  Al  Al11  1  0.874  0.415  0.744  1.0
  Al  Al12  1  0.156  0.497  0.183  1.0
  Al  Al13  1  0.344  0.466  0.708  1.0
  Al  Al14  1  0.861  0.207  0.073  1.0
  Al  Al15  1  0.444  0.081  0.038  1.0
  Al  Al16  1  0.318  0.293  0.573  1.0
  Al  Al17  1  0.155  0.167  0.871  1.0
  Al  Al18  1  0.302  0.966  0.792  1.0
  Al  Al19  1  0.517  0.534  0.292  1.0
  Al  Al20  1  0.032  0.586  0.256  1.0
  Al  Al21  1  0.892  0.545  0.018  1.0
  Al  Al22  1  0.732  0.581  0.462  1.0
  Al  Al23  1  0.160  0.045  0.482  1.0
  Al  Al24  1  0.589  0.997  0.317  1.0
  Al  Al25  1  0.835  0.503  0.817  1.0
  Al  Al26  1  0.365  0.135  0.648  1.0
  Al  Al27  1  0.775  0.419  0.538  1.0
  Al  Al28  1  0.142  0.793  0.927  1.0
  Al  Al29  1  0.023  0.445  0.332  1.0
  Al  Al30  1  0.185  0.707  0.427  1.0
  Al  Al31  1  0.687  0.955  0.518  1.0
  Al  Al32  1  0.750  0.366  0.148  1.0
  Al  Al33  1  0.867  0.915  0.756  1.0
  Al  Al34  1  0.193  0.833  0.129  1.0
  Al  Al35  1  0.148  0.866  0.352  1.0
  Al  Al36  1  0.747  0.757  0.594  1.0
  Al  Al37  1  0.098  0.243  0.406  1.0
  Al  Al38  1  0.801  0.555  0.668  1.0
  Al  Al39  1  0.755  0.744  0.094  1.0
  Al  Al40  1  0.538  0.086  0.244  1.0
  Al  Al41  1  0.902  0.003  0.683  1.0
  Al  Al42  1  0.264  0.635  0.852  1.0
  Al  Al43  1  0.572  0.333  0.371  1.0
  Mo  Mo44  1  0.057  0.069  0.282  1.0
  Mo  Mo45  1  0.699  0.714  0.890  1.0
  Mo  Mo46  1  0.662  0.786  0.390  1.0
  Mo  Mo47  1  0.376  0.431  0.782  1.0
  Mo  Mo48  1  0.408  0.931  0.718  1.0
  Mo  Mo49  1  0.002  0.000  1.000  1.0
  Mo  Mo50  1  0.590  0.569  0.218  1.0
  Mo  Mo51  1  0.838  0.214  0.610  1.0
  Mo  Mo52  1  0.303  0.286  0.110  1.0
  Mo  Mo53  1  0.252  0.500  0.500  1.0
[/CIF]
.
The crystal structure described by Al22Mo5 crystallizes in the monoclinic C2 space group. There are six inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 11-coordinate geometry to one Al(11); one Al(2); two equivalent Al(9); three Al(1,1); and four Al(8,8) atoms. In the second Mo site, Mo(2) is bonded to one Al(2), one Al(5), one Al(7), one Al(9), two equivalent Al(10), two equivalent Al(11), two equivalent Al(4), and two equivalent Al(6) atoms to form MoAl12 cuboctahedra that share  a cornercorner with one Mo(3)Al12 cuboctahedra,  a cornercorner with one Al(10)Al9Mo3 cuboctahedra, corners with four equivalent Mo(2)Al12 cuboctahedra, corners with five equivalent Al(7)Al9Mo3 cuboctahedra, edges with two equivalent Mo(2)Al12 cuboctahedra, edges with two equivalent Mo(3)Al12 cuboctahedra,  a faceface with one Al(7)Al9Mo3 cuboctahedra, and faces with three equivalent Al(10)Al9Mo3 cuboctahedra. In the third Mo site, Mo(2) is bonded to one Al(2), one Al(5), one Al(7), one Al(9), two equivalent Al(10), two equivalent Al(11), two equivalent Al(4), and two equivalent Al(6) atoms to form MoAl12 cuboctahedra that share  a cornercorner with one Mo(3)Al12 cuboctahedra,  a cornercorner with one Al(10)Al9Mo3 cuboctahedra, corners with four equivalent Mo(2)Al12 cuboctahedra, corners with five equivalent Al(7)Al9Mo3 cuboctahedra, edges with two equivalent Mo(2)Al12 cuboctahedra, edges with two equivalent Mo(3)Al12 cuboctahedra,  a faceface with one Al(7)Al9Mo3 cuboctahedra, and faces with three equivalent Al(10)Al9Mo3 cuboctahedra. In the fourth Mo site, Mo(1) is bonded in a 11-coordinate geometry to one Al(11); one Al(2); two equivalent Al(9); three Al(1,1); and four Al(8,8) atoms. In the fifth Mo site, Mo(3) is bonded to two equivalent Al(10), two equivalent Al(5), four equivalent Al(3), and four equivalent Al(7) atoms to form MoAl12 cuboctahedra that share corners with two equivalent Mo(2)Al12 cuboctahedra, corners with two equivalent Al(7)Al9Mo3 cuboctahedra, corners with four equivalent Mo(3)Al12 cuboctahedra, corners with eight equivalent Al(10)Al9Mo3 cuboctahedra, edges with two equivalent Mo(3)Al12 cuboctahedra, edges with four equivalent Mo(2)Al12 cuboctahedra, faces with two equivalent Al(10)Al9Mo3 cuboctahedra, and faces with six equivalent Al(7)Al9Mo3 cuboctahedra. In the sixth Mo site, Mo(3) is bonded to two equivalent Al(10), two equivalent Al(5), four equivalent Al(3), and four equivalent Al(7) atoms to form MoAl12 cuboctahedra that share corners with two equivalent Mo(2)Al12 cuboctahedra, corners with two equivalent Al(7)Al9Mo3 cuboctahedra, corners with four equivalent Mo(3)Al12 cuboctahedra, corners with eight equivalent Al(10)Al9Mo3 cuboctahedra, edges with two equivalent Mo(3)Al12 cuboctahedra, edges with four equivalent Mo(2)Al12 cuboctahedra, faces with two equivalent Al(10)Al9Mo3 cuboctahedra, and faces with six equivalent Al(7)Al9Mo3 cuboctahedra. There are twenty-two inequivalent Al sites. In the first Al site, Al(1) is bonded in a 3-coordinate geometry to three Mo(1,1) and one Al(11) atom. In the second Al site, Al(2) is bonded in a 2-coordinate geometry to one Mo(1), one Mo(2), and two equivalent Al(11) atoms. In the third Al site, Al(3) is bonded in a distorted bent 150 degrees geometry to two equivalent Mo(3), one Al(10), and three equivalent Al(7) atoms. In the fourth Al site, Al(4) is bonded in a 2-coordinate geometry to two equivalent Mo(2), one Al(10), one Al(9), and two equivalent Al(11) atoms. In the fifth Al site, Al(5) is bonded in a distorted bent 150 degrees geometry to one Mo(2), one Mo(3), two equivalent Al(10), and two equivalent Al(7) atoms. In the sixth Al site, Al(5) is bonded in a distorted bent 150 degrees geometry to one Mo(2), one Mo(3), two equivalent Al(10), and two equivalent Al(7) atoms. In the seventh Al site, Al(6) is bonded in a distorted bent 150 degrees geometry to two equivalent Mo(2), one Al(11), one Al(7), and two equivalent Al(10) atoms. In the eighth Al site, Al(7) is bonded to one Mo(2), two equivalent Mo(3), one Al(6), one Al(7), two equivalent Al(10), two equivalent Al(5), and three equivalent Al(3) atoms to form distorted AlAl9Mo3 cuboctahedra that share  a cornercorner with one Mo(3)Al12 cuboctahedra, corners with two equivalent Al(10)Al9Mo3 cuboctahedra, corners with five equivalent Mo(2)Al12 cuboctahedra, corners with eight equivalent Al(7)Al9Mo3 cuboctahedra, edges with two equivalent Al(10)Al9Mo3 cuboctahedra, edges with two equivalent Al(7)Al9Mo3 cuboctahedra,  a faceface with one Mo(2)Al12 cuboctahedra,  a faceface with one Al(7)Al9Mo3 cuboctahedra, faces with three equivalent Mo(3)Al12 cuboctahedra, and faces with three equivalent Al(10)Al9Mo3 cuboctahedra. In the ninth Al site, Al(8) is bonded in a 3-coordinate geometry to four Mo(1,1) atoms. In the tenth Al site, Al(9) is bonded in a 3-coordinate geometry to one Mo(2), two equivalent Mo(1), and two equivalent Al(11) atoms. In the eleventh Al site, Al(1) is bonded in a 3-coordinate geometry to three Mo(1,1); one Al(11); and two equivalent Al(9) atoms. In the twelfth Al site, Al(10) is bonded to one Mo(3), two equivalent Mo(2), one Al(11), one Al(3), one Al(4), two equivalent Al(5), two equivalent Al(6), and two equivalent Al(7) atoms to form distorted AlAl9Mo3 cuboctahedra that share  a cornercorner with one Mo(2)Al12 cuboctahedra, corners with two equivalent Al(7)Al9Mo3 cuboctahedra, corners with four equivalent Mo(3)Al12 cuboctahedra, corners with five equivalent Al(10)Al9Mo3 cuboctahedra, edges with two equivalent Al(10)Al9Mo3 cuboctahedra, edges with two equivalent Al(7)Al9Mo3 cuboctahedra,  a faceface with one Mo(3)Al12 cuboctahedra, faces with three equivalent Mo(2)Al12 cuboctahedra, and faces with three equivalent Al(7)Al9Mo3 cuboctahedra. In the thirteenth Al site, Al(10) is bonded to one Mo(3), two equivalent Mo(2), one Al(11), one Al(3), one Al(4), two equivalent Al(5), two equivalent Al(6), and two equivalent Al(7) atoms to form distorted AlAl9Mo3 cuboctahedra that share  a cornercorner with one Mo(2)Al12 cuboctahedra, corners with two equivalent Al(7)Al9Mo3 cuboctahedra, corners with four equivalent Mo(3)Al12 cuboctahedra, corners with five equivalent Al(10)Al9Mo3 cuboctahedra, edges with two equivalent Al(10)Al9Mo3 cuboctahedra, edges with two equivalent Al(7)Al9Mo3 cuboctahedra,  a faceface with one Mo(3)Al12 cuboctahedra, faces with three equivalent Mo(2)Al12 cuboctahedra, and faces with three equivalent Al(7)Al9Mo3 cuboctahedra. In the fourteenth Al site, Al(4) is bonded in a 2-coordinate geometry to two equivalent Mo(2), one Al(10), and two equivalent Al(11) atoms. In the fifteenth Al site, Al(7) is bonded to one Mo(2), two equivalent Mo(3), one Al(6), one Al(7), two equivalent Al(10), two equivalent Al(5), and three equivalent Al(3) atoms to form distorted AlAl9Mo3 cuboctahedra that share  a cornercorner with one Mo(3)Al12 cuboctahedra, corners with two equivalent Al(10)Al9Mo3 cuboctahedra, corners with five equivalent Mo(2)Al12 cuboctahedra, corners with eight equivalent Al(7)Al9Mo3 cuboctahedra, edges with two equivalent Al(10)Al9Mo3 cuboctahedra, edges with two equivalent Al(7)Al9Mo3 cuboctahedra,  a faceface with one Mo(2)Al12 cuboctahedra,  a faceface with one Al(7)Al9Mo3 cuboctahedra, faces with three equivalent Mo(3)Al12 cuboctahedra, and faces with three equivalent Al(10)Al9Mo3 cuboctahedra. In the sixteenth Al site, Al(3) is bonded in a distorted bent 150 degrees geometry to two equivalent Mo(3), one Al(10), and three equivalent Al(7) atoms. In the seventeenth Al site, Al(9) is bonded in a 11-coordinate geometry to one Mo(2), two equivalent Mo(1), one Al(4), one Al(8), two equivalent Al(1), two equivalent Al(11), and two equivalent Al(2) atoms. In the eighteenth Al site, Al(11) is bonded in a 12-coordinate geometry to one Mo(1), two equivalent Mo(2), one Al(1), one Al(10), one Al(6), two equivalent Al(2), two equivalent Al(4), and two equivalent Al(9) atoms. In the nineteenth Al site, Al(2) is bonded in a 2-coordinate geometry to one Mo(1), one Mo(2), two equivalent Al(11), and two equivalent Al(9) atoms. In the twentieth Al site, Al(11) is bonded in a 12-coordinate geometry to one Mo(1), two equivalent Mo(2), one Al(1), one Al(10), one Al(6), two equivalent Al(2), two equivalent Al(4), and two equivalent Al(9) atoms. In the twenty-first Al site, Al(8) is bonded in a 3-coordinate geometry to four Mo(1,1) and one Al(9) atom. In the twenty-second Al site, Al(6) is bonded in a distorted bent 150 degrees geometry to two equivalent Mo(2), one Al(11), one Al(7), and two equivalent Al(10) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Al22Mo5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.897
_cell_length_b   5.185
_cell_length_c   36.647
_cell_angle_alpha   88.195
_cell_angle_beta   86.171
_cell_angle_gamma   61.818
_symmetry_Int_Tables_number   1
_cell_volume   818.399
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  0.059  0.034  0.208  1.0
  Al  Al1  1  0.606  0.945  0.168  1.0
  Al  Al2  1  0.455  0.455  0.982  1.0
  Al  Al3  1  0.276  0.667  0.629  1.0
  Al  Al4  1  0.614  0.147  0.444  1.0
  Al  Al5  1  0.308  0.647  0.056  1.0
  Al  Al6  1  0.719  0.055  0.832  1.0
  Al  Al7  1  0.011  0.353  0.944  1.0
  Al  Al8  1  0.592  0.257  0.906  1.0
  Al  Al9  1  0.205  0.853  0.556  1.0
  Al  Al10  1  0.563  0.919  0.962  1.0
  Al  Al11  1  0.874  0.415  0.744  1.0
  Al  Al12  1  0.156  0.497  0.183  1.0
  Al  Al13  1  0.344  0.466  0.708  1.0
  Al  Al14  1  0.861  0.207  0.073  1.0
  Al  Al15  1  0.444  0.081  0.038  1.0
  Al  Al16  1  0.318  0.293  0.573  1.0
  Al  Al17  1  0.155  0.167  0.871  1.0
  Al  Al18  1  0.302  0.966  0.792  1.0
  Al  Al19  1  0.517  0.534  0.292  1.0
  Al  Al20  1  0.032  0.586  0.256  1.0
  Al  Al21  1  0.892  0.545  0.018  1.0
  Al  Al22  1  0.732  0.581  0.462  1.0
  Al  Al23  1  0.160  0.045  0.482  1.0
  Al  Al24  1  0.589  0.997  0.317  1.0
  Al  Al25  1  0.835  0.503  0.817  1.0
  Al  Al26  1  0.365  0.135  0.648  1.0
  Al  Al27  1  0.775  0.419  0.538  1.0
  Al  Al28  1  0.142  0.793  0.927  1.0
  Al  Al29  1  0.023  0.445  0.332  1.0
  Al  Al30  1  0.185  0.707  0.427  1.0
  Al  Al31  1  0.687  0.955  0.518  1.0
  Al  Al32  1  0.750  0.366  0.148  1.0
  Al  Al33  1  0.867  0.915  0.756  1.0
  Al  Al34  1  0.193  0.833  0.129  1.0
  Al  Al35  1  0.148  0.866  0.352  1.0
  Al  Al36  1  0.747  0.757  0.594  1.0
  Al  Al37  1  0.098  0.243  0.406  1.0
  Al  Al38  1  0.801  0.555  0.668  1.0
  Al  Al39  1  0.755  0.744  0.094  1.0
  Al  Al40  1  0.538  0.086  0.244  1.0
  Al  Al41  1  0.902  0.003  0.683  1.0
  Al  Al42  1  0.264  0.635  0.852  1.0
  Al  Al43  1  0.572  0.333  0.371  1.0
  Mo  Mo44  1  0.057  0.069  0.282  1.0
  Mo  Mo45  1  0.699  0.714  0.890  1.0
  Mo  Mo46  1  0.662  0.786  0.390  1.0
  Mo  Mo47  1  0.376  0.431  0.782  1.0
  Mo  Mo48  1  0.408  0.931  0.718  1.0
  Mo  Mo49  1  0.002  0.000  1.000  1.0
  Mo  Mo50  1  0.590  0.569  0.218  1.0
  Mo  Mo51  1  0.838  0.214  0.610  1.0
  Mo  Mo52  1  0.303  0.286  0.110  1.0
  Mo  Mo53  1  0.252  0.500  0.500  1.0
[/CIF]
.