The material structure described by Bi2O2CO3 crystallizes in the orthorhombic Fmm2 space group. C(1) is bonded in a trigonal planar geometry to one O(1) and two equivalent O(2) atoms. Bi(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), and four equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one C(1) and two equivalent Bi(1) atoms. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) and one Bi(1) atom. In the third O site, O(3) is bonded to four equivalent Bi(1) atoms to form a mixture of corner and edge-sharing OBi4 tetrahedra. is represented by the CIF card [CIF]
data_Bi2CO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.543
_cell_length_b   7.526
_cell_length_c   3.881
_cell_angle_alpha   75.314
_cell_angle_beta   74.838
_cell_angle_gamma   29.848
_symmetry_Int_Tables_number   1
_cell_volume   105.667
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.166  0.157  0.843  1.0
  Bi  Bi1  1  0.843  0.834  0.166  1.0
  C  C2  1  0.548  0.452  0.548  1.0
  O  O3  1  0.781  0.219  0.781  1.0
  O  O4  1  0.356  0.482  0.518  1.0
  O  O5  1  0.753  0.747  0.753  1.0
  O  O6  1  0.518  0.644  0.356  1.0
  O  O7  1  0.253  0.247  0.253  1.0
[/CIF]
.
The material structure described by Bi2O2CO3 crystallizes in the orthorhombic Fmm2 space group. C(1) is bonded in a trigonal planar geometry to one O(1) and two equivalent O(2) atoms. Bi(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), and four equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one C(1) and two equivalent Bi(1) atoms. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) and one Bi(1) atom. In the third O site, O(3) is bonded to four equivalent Bi(1) atoms to form a mixture of corner and edge-sharing OBi4 tetrahedra. is represented by the CIF card [CIF]
data_Bi2CO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.543
_cell_length_b   7.526
_cell_length_c   3.881
_cell_angle_alpha   75.314
_cell_angle_beta   74.838
_cell_angle_gamma   29.848
_symmetry_Int_Tables_number   1
_cell_volume   105.667
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.166  0.157  0.843  1.0
  Bi  Bi1  1  0.843  0.834  0.166  1.0
  C  C2  1  0.548  0.452  0.548  1.0
  O  O3  1  0.781  0.219  0.781  1.0
  O  O4  1  0.356  0.482  0.518  1.0
  O  O5  1  0.753  0.747  0.753  1.0
  O  O6  1  0.518  0.644  0.356  1.0
  O  O7  1  0.253  0.247  0.253  1.0
[/CIF]
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