The crystal structure described by WGeO4 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent W sites. In the first W site, W(1) is bonded to one O(1), one O(2), one O(5), one O(8), and two equivalent O(4) atoms to form a mixture of distorted corner and edge-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 13-42°. In the second W site, W(2) is bonded to one O(1), one O(2), one O(6), one O(7), and two equivalent O(3) atoms to form a mixture of distorted corner and edge-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 13-42°. There are two inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a distorted T-shaped geometry to one O(6), one O(7), and one O(8) atom. In the second Ge site, Ge(2) is bonded in a distorted T-shaped geometry to one O(2), one O(4), and one O(5) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to one W(1) and one W(2) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one W(1), one W(2), and one Ge(2) atom. In the third O site, O(3) is bonded in a water-like geometry to two equivalent W(2) atoms. In the fourth O site, O(4) is bonded in a trigonal non-coplanar geometry to two equivalent W(1) and one Ge(2) atom. In the fifth O site, O(5) is bonded in a water-like geometry to one W(1) and one Ge(2) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one W(2) and one Ge(1) atom. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one W(2) and one Ge(1) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one W(1) and one Ge(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_GeWO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.121
_cell_length_b   7.676
_cell_length_c   14.787
_cell_angle_alpha   58.894
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   692.008
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ge  Ge0  1  0.037  0.599  0.810  1.0
  Ge  Ge1  1  0.242  0.977  0.869  1.0
  Ge  Ge2  1  0.742  0.023  0.631  1.0
  Ge  Ge3  1  0.537  0.401  0.690  1.0
  Ge  Ge4  1  0.463  0.599  0.310  1.0
  Ge  Ge5  1  0.258  0.977  0.369  1.0
  Ge  Ge6  1  0.758  0.023  0.131  1.0
  Ge  Ge7  1  0.963  0.401  0.190  1.0
  W  W8  1  0.827  0.997  0.922  1.0
  W  W9  1  0.553  0.435  0.918  1.0
  W  W10  1  0.053  0.565  0.582  1.0
  W  W11  1  0.327  0.003  0.578  1.0
  W  W12  1  0.673  0.997  0.422  1.0
  W  W13  1  0.947  0.435  0.418  1.0
  W  W14  1  0.447  0.565  0.082  1.0
  W  W15  1  0.173  0.003  0.078  1.0
  O  O16  1  0.638  0.812  0.979  1.0
  O  O17  1  0.724  0.194  0.973  1.0
  O  O18  1  0.375  0.604  0.934  1.0
  O  O19  1  0.081  0.134  0.918  1.0
  O  O20  1  0.989  0.861  0.877  1.0
  O  O21  1  0.729  0.619  0.839  1.0
  O  O22  1  0.443  0.410  0.811  1.0
  O  O23  1  0.718  0.178  0.795  1.0
  O  O24  1  0.218  0.822  0.705  1.0
  O  O25  1  0.943  0.590  0.689  1.0
  O  O26  1  0.229  0.381  0.661  1.0
  O  O27  1  0.489  0.139  0.623  1.0
  O  O28  1  0.581  0.866  0.582  1.0
  O  O29  1  0.224  0.806  0.527  1.0
  O  O30  1  0.875  0.396  0.566  1.0
  O  O31  1  0.138  0.188  0.521  1.0
  O  O32  1  0.862  0.812  0.479  1.0
  O  O33  1  0.125  0.604  0.434  1.0
  O  O34  1  0.776  0.194  0.473  1.0
  O  O35  1  0.419  0.134  0.418  1.0
  O  O36  1  0.511  0.861  0.377  1.0
  O  O37  1  0.771  0.619  0.339  1.0
  O  O38  1  0.057  0.410  0.311  1.0
  O  O39  1  0.782  0.178  0.295  1.0
  O  O40  1  0.282  0.822  0.205  1.0
  O  O41  1  0.557  0.590  0.189  1.0
  O  O42  1  0.271  0.381  0.161  1.0
  O  O43  1  0.011  0.139  0.123  1.0
  O  O44  1  0.919  0.866  0.082  1.0
  O  O45  1  0.625  0.396  0.066  1.0
  O  O46  1  0.276  0.806  0.027  1.0
  O  O47  1  0.362  0.188  0.021  1.0
[/CIF]
.
The crystal structure described by WGeO4 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent W sites. In the first W site, W(1) is bonded to one O(1), one O(2), one O(5), one O(8), and two equivalent O(4) atoms to form a mixture of distorted corner and edge-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 13-42°. In the second W site, W(2) is bonded to one O(1), one O(2), one O(6), one O(7), and two equivalent O(3) atoms to form a mixture of distorted corner and edge-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 13-42°. There are two inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a distorted T-shaped geometry to one O(6), one O(7), and one O(8) atom. In the second Ge site, Ge(2) is bonded in a distorted T-shaped geometry to one O(2), one O(4), and one O(5) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to one W(1) and one W(2) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one W(1), one W(2), and one Ge(2) atom. In the third O site, O(3) is bonded in a water-like geometry to two equivalent W(2) atoms. In the fourth O site, O(4) is bonded in a trigonal non-coplanar geometry to two equivalent W(1) and one Ge(2) atom. In the fifth O site, O(5) is bonded in a water-like geometry to one W(1) and one Ge(2) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one W(2) and one Ge(1) atom. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one W(2) and one Ge(1) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one W(1) and one Ge(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_GeWO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.121
_cell_length_b   7.676
_cell_length_c   14.787
_cell_angle_alpha   58.894
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   692.008
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ge  Ge0  1  0.037  0.599  0.810  1.0
  Ge  Ge1  1  0.242  0.977  0.869  1.0
  Ge  Ge2  1  0.742  0.023  0.631  1.0
  Ge  Ge3  1  0.537  0.401  0.690  1.0
  Ge  Ge4  1  0.463  0.599  0.310  1.0
  Ge  Ge5  1  0.258  0.977  0.369  1.0
  Ge  Ge6  1  0.758  0.023  0.131  1.0
  Ge  Ge7  1  0.963  0.401  0.190  1.0
  W  W8  1  0.827  0.997  0.922  1.0
  W  W9  1  0.553  0.435  0.918  1.0
  W  W10  1  0.053  0.565  0.582  1.0
  W  W11  1  0.327  0.003  0.578  1.0
  W  W12  1  0.673  0.997  0.422  1.0
  W  W13  1  0.947  0.435  0.418  1.0
  W  W14  1  0.447  0.565  0.082  1.0
  W  W15  1  0.173  0.003  0.078  1.0
  O  O16  1  0.638  0.812  0.979  1.0
  O  O17  1  0.724  0.194  0.973  1.0
  O  O18  1  0.375  0.604  0.934  1.0
  O  O19  1  0.081  0.134  0.918  1.0
  O  O20  1  0.989  0.861  0.877  1.0
  O  O21  1  0.729  0.619  0.839  1.0
  O  O22  1  0.443  0.410  0.811  1.0
  O  O23  1  0.718  0.178  0.795  1.0
  O  O24  1  0.218  0.822  0.705  1.0
  O  O25  1  0.943  0.590  0.689  1.0
  O  O26  1  0.229  0.381  0.661  1.0
  O  O27  1  0.489  0.139  0.623  1.0
  O  O28  1  0.581  0.866  0.582  1.0
  O  O29  1  0.224  0.806  0.527  1.0
  O  O30  1  0.875  0.396  0.566  1.0
  O  O31  1  0.138  0.188  0.521  1.0
  O  O32  1  0.862  0.812  0.479  1.0
  O  O33  1  0.125  0.604  0.434  1.0
  O  O34  1  0.776  0.194  0.473  1.0
  O  O35  1  0.419  0.134  0.418  1.0
  O  O36  1  0.511  0.861  0.377  1.0
  O  O37  1  0.771  0.619  0.339  1.0
  O  O38  1  0.057  0.410  0.311  1.0
  O  O39  1  0.782  0.178  0.295  1.0
  O  O40  1  0.282  0.822  0.205  1.0
  O  O41  1  0.557  0.590  0.189  1.0
  O  O42  1  0.271  0.381  0.161  1.0
  O  O43  1  0.011  0.139  0.123  1.0
  O  O44  1  0.919  0.866  0.082  1.0
  O  O45  1  0.625  0.396  0.066  1.0
  O  O46  1  0.276  0.806  0.027  1.0
  O  O47  1  0.362  0.188  0.021  1.0
[/CIF]
.