The material structure described by K3P2H(O3F)2 crystallizes in the monoclinic Cc space group. There are three inequivalent K sites. In the first K site, K(1) is bonded in a 12-coordinate geometry to two equivalent H(1), one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), two equivalent F(1), and two equivalent F(2) atoms. In the second K site, K(2) is bonded in a 10-coordinate geometry to one O(1), one O(2), one O(3), one O(6), two equivalent O(4), two equivalent O(5), one F(1), and one F(2) atom. In the third K site, K(3) is bonded in a 9-coordinate geometry to one O(3), one O(4), one O(5), two equivalent O(2), two equivalent O(6), one F(1), and one F(2) atom. There are two inequivalent P sites. In the first P site, P(1) is bonded in a tetrahedral geometry to one O(3), one O(4), one O(5), and one F(1) atom. In the second P site, P(2) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(6), and one F(2) atom. H(1) is bonded in a linear geometry to two equivalent K(1), one O(1), and one O(3) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one K(1), one K(2), one P(2), and one H(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one K(1), one K(2), two equivalent K(3), and one P(2) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one K(1), one K(2), one K(3), one P(1), and one H(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one K(1), one K(3), two equivalent K(2), and one P(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one K(1), one K(3), two equivalent K(2), and one P(1) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one K(1), one K(2), two equivalent K(3), and one P(2) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to one K(2), one K(3), two equivalent K(1), and one P(1) atom. In the second F site, F(2) is bonded in a distorted single-bond geometry to one K(2), one K(3), two equivalent K(1), and one P(2) atom. is represented by the CIF file [CIF]
data_K3P2H(O3F)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.172
_cell_length_b   7.172
_cell_length_c   9.448
_cell_angle_alpha   77.948
_cell_angle_beta   77.948
_cell_angle_gamma   111.353
_symmetry_Int_Tables_number   1
_cell_volume   420.417
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.140  0.851  0.254  1.0
  K  K1  1  0.463  0.721  0.563  1.0
  K  K2  1  0.277  0.538  0.940  1.0
  K  K3  1  0.721  0.463  0.063  1.0
  K  K4  1  0.538  0.277  0.440  1.0
  K  K5  1  0.851  0.140  0.754  1.0
  P  P6  1  0.675  0.907  0.183  1.0
  P  P7  1  0.907  0.675  0.683  1.0
  P  P8  1  0.098  0.323  0.321  1.0
  P  P9  1  0.323  0.098  0.821  1.0
  H  H10  1  0.005  0.001  0.501  1.0
  H  H11  1  0.001  0.005  0.001  1.0
  O  O12  1  0.113  0.934  0.946  1.0
  O  O13  1  0.440  0.993  0.741  1.0
  O  O14  1  0.076  0.882  0.559  1.0
  O  O15  1  0.003  0.551  0.768  1.0
  O  O16  1  0.721  0.699  0.771  1.0
  O  O17  1  0.699  0.721  0.271  1.0
  O  O18  1  0.302  0.283  0.728  1.0
  O  O19  1  0.283  0.302  0.228  1.0
  O  O20  1  0.993  0.440  0.241  1.0
  O  O21  1  0.934  0.113  0.446  1.0
  O  O22  1  0.551  0.003  0.268  1.0
  O  O23  1  0.882  0.076  0.059  1.0
  F  F24  1  0.532  0.811  0.076  1.0
  F  F25  1  0.195  0.465  0.427  1.0
  F  F26  1  0.811  0.532  0.576  1.0
  F  F27  1  0.465  0.195  0.927  1.0
[/CIF]
.
The material structure described by K3P2H(O3F)2 crystallizes in the monoclinic Cc space group. There are three inequivalent K sites. In the first K site, K(1) is bonded in a 12-coordinate geometry to two equivalent H(1), one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), two equivalent F(1), and two equivalent F(2) atoms. In the second K site, K(2) is bonded in a 10-coordinate geometry to one O(1), one O(2), one O(3), one O(6), two equivalent O(4), two equivalent O(5), one F(1), and one F(2) atom. In the third K site, K(3) is bonded in a 9-coordinate geometry to one O(3), one O(4), one O(5), two equivalent O(2), two equivalent O(6), one F(1), and one F(2) atom. There are two inequivalent P sites. In the first P site, P(1) is bonded in a tetrahedral geometry to one O(3), one O(4), one O(5), and one F(1) atom. In the second P site, P(2) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(6), and one F(2) atom. H(1) is bonded in a linear geometry to two equivalent K(1), one O(1), and one O(3) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one K(1), one K(2), one P(2), and one H(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one K(1), one K(2), two equivalent K(3), and one P(2) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one K(1), one K(2), one K(3), one P(1), and one H(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one K(1), one K(3), two equivalent K(2), and one P(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one K(1), one K(3), two equivalent K(2), and one P(1) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one K(1), one K(2), two equivalent K(3), and one P(2) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to one K(2), one K(3), two equivalent K(1), and one P(1) atom. In the second F site, F(2) is bonded in a distorted single-bond geometry to one K(2), one K(3), two equivalent K(1), and one P(2) atom. is represented by the CIF file [CIF]
data_K3P2H(O3F)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.172
_cell_length_b   7.172
_cell_length_c   9.448
_cell_angle_alpha   77.948
_cell_angle_beta   77.948
_cell_angle_gamma   111.353
_symmetry_Int_Tables_number   1
_cell_volume   420.417
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.140  0.851  0.254  1.0
  K  K1  1  0.463  0.721  0.563  1.0
  K  K2  1  0.277  0.538  0.940  1.0
  K  K3  1  0.721  0.463  0.063  1.0
  K  K4  1  0.538  0.277  0.440  1.0
  K  K5  1  0.851  0.140  0.754  1.0
  P  P6  1  0.675  0.907  0.183  1.0
  P  P7  1  0.907  0.675  0.683  1.0
  P  P8  1  0.098  0.323  0.321  1.0
  P  P9  1  0.323  0.098  0.821  1.0
  H  H10  1  0.005  0.001  0.501  1.0
  H  H11  1  0.001  0.005  0.001  1.0
  O  O12  1  0.113  0.934  0.946  1.0
  O  O13  1  0.440  0.993  0.741  1.0
  O  O14  1  0.076  0.882  0.559  1.0
  O  O15  1  0.003  0.551  0.768  1.0
  O  O16  1  0.721  0.699  0.771  1.0
  O  O17  1  0.699  0.721  0.271  1.0
  O  O18  1  0.302  0.283  0.728  1.0
  O  O19  1  0.283  0.302  0.228  1.0
  O  O20  1  0.993  0.440  0.241  1.0
  O  O21  1  0.934  0.113  0.446  1.0
  O  O22  1  0.551  0.003  0.268  1.0
  O  O23  1  0.882  0.076  0.059  1.0
  F  F24  1  0.532  0.811  0.076  1.0
  F  F25  1  0.195  0.465  0.427  1.0
  F  F26  1  0.811  0.532  0.576  1.0
  F  F27  1  0.465  0.195  0.927  1.0
[/CIF]
.