The material described by VCoP crystallizes in the orthorhombic Pnma space group. V(1) is bonded in a 5-coordinate geometry to five equivalent P(1) atoms. Co(1) is bonded to four equivalent P(1) atoms to form a mixture of distorted edge and corner-sharing CoP4 tetrahedra. P(1) is bonded in a 9-coordinate geometry to five equivalent V(1) and four equivalent Co(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_VCoP
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.546
_cell_length_b   5.826
_cell_length_c   6.624
_cell_angle_alpha   89.997
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   136.835
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.750  0.474  0.327  1.0
  V  V1  1  0.750  0.974  0.173  1.0
  V  V2  1  0.250  0.526  0.673  1.0
  V  V3  1  0.250  0.026  0.827  1.0
  Co  Co4  1  0.750  0.359  0.938  1.0
  Co  Co5  1  0.750  0.859  0.562  1.0
  Co  Co6  1  0.250  0.641  0.062  1.0
  Co  Co7  1  0.250  0.141  0.438  1.0
  P  P8  1  0.750  0.733  0.876  1.0
  P  P9  1  0.750  0.233  0.624  1.0
  P  P10  1  0.250  0.267  0.124  1.0
  P  P11  1  0.250  0.767  0.376  1.0
[/CIF]
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The material described by VCoP crystallizes in the orthorhombic Pnma space group. V(1) is bonded in a 5-coordinate geometry to five equivalent P(1) atoms. Co(1) is bonded to four equivalent P(1) atoms to form a mixture of distorted edge and corner-sharing CoP4 tetrahedra. P(1) is bonded in a 9-coordinate geometry to five equivalent V(1) and four equivalent Co(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_VCoP
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.546
_cell_length_b   5.826
_cell_length_c   6.624
_cell_angle_alpha   89.997
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   136.835
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.750  0.474  0.327  1.0
  V  V1  1  0.750  0.974  0.173  1.0
  V  V2  1  0.250  0.526  0.673  1.0
  V  V3  1  0.250  0.026  0.827  1.0
  Co  Co4  1  0.750  0.359  0.938  1.0
  Co  Co5  1  0.750  0.859  0.562  1.0
  Co  Co6  1  0.250  0.641  0.062  1.0
  Co  Co7  1  0.250  0.141  0.438  1.0
  P  P8  1  0.750  0.733  0.876  1.0
  P  P9  1  0.750  0.233  0.624  1.0
  P  P10  1  0.250  0.267  0.124  1.0
  P  P11  1  0.250  0.767  0.376  1.0
[/CIF]
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