The material structure described by Ag4Te(O3Cl)2 crystallizes in the cubic P2_13 space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to three equivalent O(2) and one Cl(1) atom. In the second Ag site, Ag(2) is bonded in a distorted water-like geometry to two equivalent Te(1), one O(1), and one O(2) atom. Te(1) is bonded in a 6-coordinate geometry to six equivalent Ag(2) atoms. There are two inequivalent O sites. In the first O site, O(2) is bonded in a 3-coordinate geometry to one Ag(1), one Ag(2), and one Cl(2) atom. In the second O site, O(1) is bonded in a bent 120 degrees geometry to one Ag(2) and one Cl(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted tetrahedral geometry to one Ag(1) and three equivalent O(1) atoms. In the second Cl site, Cl(2) is bonded in a trigonal non-coplanar geometry to three equivalent O(2) atoms. is represented by the CIF file [CIF]
data_Ag4Te(ClO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.734
_cell_length_b   9.734
_cell_length_c   9.734
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   922.376
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.001  0.501  0.999  1.0
  Ag  Ag1  1  0.501  0.999  0.001  1.0
  Ag  Ag2  1  0.999  0.001  0.501  1.0
  Ag  Ag3  1  0.499  0.499  0.499  1.0
  Ag  Ag4  1  0.750  0.492  0.142  1.0
  Ag  Ag5  1  0.858  0.250  0.008  1.0
  Ag  Ag6  1  0.992  0.358  0.250  1.0
  Ag  Ag7  1  0.250  0.008  0.858  1.0
  Ag  Ag8  1  0.358  0.250  0.992  1.0
  Ag  Ag9  1  0.492  0.142  0.750  1.0
  Ag  Ag10  1  0.250  0.992  0.358  1.0
  Ag  Ag11  1  0.142  0.750  0.492  1.0
  Ag  Ag12  1  0.008  0.858  0.250  1.0
  Ag  Ag13  1  0.750  0.508  0.642  1.0
  Ag  Ag14  1  0.642  0.750  0.508  1.0
  Ag  Ag15  1  0.508  0.642  0.750  1.0
  Te  Te16  1  0.401  0.901  0.599  1.0
  Te  Te17  1  0.901  0.599  0.401  1.0
  Te  Te18  1  0.599  0.401  0.901  1.0
  Te  Te19  1  0.099  0.099  0.099  1.0
  Cl  Cl20  1  0.168  0.668  0.832  1.0
  Cl  Cl21  1  0.668  0.832  0.168  1.0
  Cl  Cl22  1  0.832  0.168  0.668  1.0
  Cl  Cl23  1  0.332  0.332  0.332  1.0
  Cl  Cl24  1  0.686  0.186  0.314  1.0
  Cl  Cl25  1  0.186  0.314  0.686  1.0
  Cl  Cl26  1  0.314  0.686  0.186  1.0
  Cl  Cl27  1  0.814  0.814  0.814  1.0
  O  O28  1  0.178  0.610  0.689  1.0
  O  O29  1  0.311  0.678  0.890  1.0
  O  O30  1  0.110  0.811  0.822  1.0
  O  O31  1  0.678  0.890  0.311  1.0
  O  O32  1  0.811  0.822  0.110  1.0
  O  O33  1  0.610  0.689  0.178  1.0
  O  O34  1  0.822  0.110  0.811  1.0
  O  O35  1  0.689  0.178  0.610  1.0
  O  O36  1  0.890  0.311  0.678  1.0
  O  O37  1  0.322  0.390  0.189  1.0
  O  O38  1  0.189  0.322  0.390  1.0
  O  O39  1  0.390  0.189  0.322  1.0
  O  O40  1  0.838  0.170  0.347  1.0
  O  O41  1  0.653  0.338  0.330  1.0
  O  O42  1  0.670  0.153  0.162  1.0
  O  O43  1  0.338  0.330  0.653  1.0
  O  O44  1  0.153  0.162  0.670  1.0
  O  O45  1  0.170  0.347  0.838  1.0
  O  O46  1  0.162  0.670  0.153  1.0
  O  O47  1  0.347  0.838  0.170  1.0
  O  O48  1  0.330  0.653  0.338  1.0
  O  O49  1  0.662  0.830  0.847  1.0
  O  O50  1  0.847  0.662  0.830  1.0
  O  O51  1  0.830  0.847  0.662  1.0
[/CIF]
.
The material structure described by Ag4Te(O3Cl)2 crystallizes in the cubic P2_13 space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to three equivalent O(2) and one Cl(1) atom. In the second Ag site, Ag(2) is bonded in a distorted water-like geometry to two equivalent Te(1), one O(1), and one O(2) atom. Te(1) is bonded in a 6-coordinate geometry to six equivalent Ag(2) atoms. There are two inequivalent O sites. In the first O site, O(2) is bonded in a 3-coordinate geometry to one Ag(1), one Ag(2), and one Cl(2) atom. In the second O site, O(1) is bonded in a bent 120 degrees geometry to one Ag(2) and one Cl(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted tetrahedral geometry to one Ag(1) and three equivalent O(1) atoms. In the second Cl site, Cl(2) is bonded in a trigonal non-coplanar geometry to three equivalent O(2) atoms. is represented by the CIF file [CIF]
data_Ag4Te(ClO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.734
_cell_length_b   9.734
_cell_length_c   9.734
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   922.376
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.001  0.501  0.999  1.0
  Ag  Ag1  1  0.501  0.999  0.001  1.0
  Ag  Ag2  1  0.999  0.001  0.501  1.0
  Ag  Ag3  1  0.499  0.499  0.499  1.0
  Ag  Ag4  1  0.750  0.492  0.142  1.0
  Ag  Ag5  1  0.858  0.250  0.008  1.0
  Ag  Ag6  1  0.992  0.358  0.250  1.0
  Ag  Ag7  1  0.250  0.008  0.858  1.0
  Ag  Ag8  1  0.358  0.250  0.992  1.0
  Ag  Ag9  1  0.492  0.142  0.750  1.0
  Ag  Ag10  1  0.250  0.992  0.358  1.0
  Ag  Ag11  1  0.142  0.750  0.492  1.0
  Ag  Ag12  1  0.008  0.858  0.250  1.0
  Ag  Ag13  1  0.750  0.508  0.642  1.0
  Ag  Ag14  1  0.642  0.750  0.508  1.0
  Ag  Ag15  1  0.508  0.642  0.750  1.0
  Te  Te16  1  0.401  0.901  0.599  1.0
  Te  Te17  1  0.901  0.599  0.401  1.0
  Te  Te18  1  0.599  0.401  0.901  1.0
  Te  Te19  1  0.099  0.099  0.099  1.0
  Cl  Cl20  1  0.168  0.668  0.832  1.0
  Cl  Cl21  1  0.668  0.832  0.168  1.0
  Cl  Cl22  1  0.832  0.168  0.668  1.0
  Cl  Cl23  1  0.332  0.332  0.332  1.0
  Cl  Cl24  1  0.686  0.186  0.314  1.0
  Cl  Cl25  1  0.186  0.314  0.686  1.0
  Cl  Cl26  1  0.314  0.686  0.186  1.0
  Cl  Cl27  1  0.814  0.814  0.814  1.0
  O  O28  1  0.178  0.610  0.689  1.0
  O  O29  1  0.311  0.678  0.890  1.0
  O  O30  1  0.110  0.811  0.822  1.0
  O  O31  1  0.678  0.890  0.311  1.0
  O  O32  1  0.811  0.822  0.110  1.0
  O  O33  1  0.610  0.689  0.178  1.0
  O  O34  1  0.822  0.110  0.811  1.0
  O  O35  1  0.689  0.178  0.610  1.0
  O  O36  1  0.890  0.311  0.678  1.0
  O  O37  1  0.322  0.390  0.189  1.0
  O  O38  1  0.189  0.322  0.390  1.0
  O  O39  1  0.390  0.189  0.322  1.0
  O  O40  1  0.838  0.170  0.347  1.0
  O  O41  1  0.653  0.338  0.330  1.0
  O  O42  1  0.670  0.153  0.162  1.0
  O  O43  1  0.338  0.330  0.653  1.0
  O  O44  1  0.153  0.162  0.670  1.0
  O  O45  1  0.170  0.347  0.838  1.0
  O  O46  1  0.162  0.670  0.153  1.0
  O  O47  1  0.347  0.838  0.170  1.0
  O  O48  1  0.330  0.653  0.338  1.0
  O  O49  1  0.662  0.830  0.847  1.0
  O  O50  1  0.847  0.662  0.830  1.0
  O  O51  1  0.830  0.847  0.662  1.0
[/CIF]
.