The crystal structure described by V2Cr2Fe crystallizes in the orthorhombic Fmm2 space group. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 8-coordinate geometry to two equivalent V(2), four equivalent V(1), and two equivalent Cr(2) atoms. In the second V site, V(2) is bonded in a 2-coordinate geometry to two equivalent V(1) and two equivalent Fe(1) atoms. There are two inequivalent Cr sites. In the first Cr site, Cr(1) is bonded in a 2-coordinate geometry to two equivalent Cr(2) and two equivalent Fe(1) atoms. In the second Cr site, Cr(2) is bonded in a distorted body-centered cubic geometry to two equivalent V(1), two equivalent Cr(1), and four equivalent Cr(2) atoms. Fe(1) is bonded in a 4-coordinate geometry to two equivalent V(2) and two equivalent Cr(1) atoms. is represented by the CIF card [CIF]
data_V2Cr2Fe
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.441
_cell_length_b   10.342
_cell_length_c   2.514
_cell_angle_alpha   85.294
_cell_angle_beta   80.820
_cell_angle_gamma   13.885
_symmetry_Int_Tables_number   1
_cell_volume   61.197
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.797  0.797  0.203  1.0
  V  V1  1  0.404  0.404  0.596  1.0
  Cr  Cr2  1  0.600  0.600  0.400  1.0
  Cr  Cr3  1  0.196  0.196  0.804  1.0
  Fe  Fe4  1  0.003  0.003  0.997  1.0
[/CIF]
.
The crystal structure described by V2Cr2Fe crystallizes in the orthorhombic Fmm2 space group. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 8-coordinate geometry to two equivalent V(2), four equivalent V(1), and two equivalent Cr(2) atoms. In the second V site, V(2) is bonded in a 2-coordinate geometry to two equivalent V(1) and two equivalent Fe(1) atoms. There are two inequivalent Cr sites. In the first Cr site, Cr(1) is bonded in a 2-coordinate geometry to two equivalent Cr(2) and two equivalent Fe(1) atoms. In the second Cr site, Cr(2) is bonded in a distorted body-centered cubic geometry to two equivalent V(1), two equivalent Cr(1), and four equivalent Cr(2) atoms. Fe(1) is bonded in a 4-coordinate geometry to two equivalent V(2) and two equivalent Cr(1) atoms. is represented by the CIF card [CIF]
data_V2Cr2Fe
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.441
_cell_length_b   10.342
_cell_length_c   2.514
_cell_angle_alpha   85.294
_cell_angle_beta   80.820
_cell_angle_gamma   13.885
_symmetry_Int_Tables_number   1
_cell_volume   61.197
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.797  0.797  0.203  1.0
  V  V1  1  0.404  0.404  0.596  1.0
  Cr  Cr2  1  0.600  0.600  0.400  1.0
  Cr  Cr3  1  0.196  0.196  0.804  1.0
  Fe  Fe4  1  0.003  0.003  0.997  1.0
[/CIF]
.