The compound described by AgAsBr4 is trigonal omega-derived structured and crystallizes in the orthorhombic Imma space group. Ag(1) is bonded to two equivalent Br(2) and four equivalent Br(1) atoms to form AgBr6 octahedra that share edges with two equivalent Ag(1)Br6 octahedra and edges with four equivalent As(1)Br6 octahedra. As(1) is bonded to two equivalent Br(1) and four equivalent Br(2) atoms to form AsBr6 octahedra that share edges with two equivalent As(1)Br6 octahedra and edges with four equivalent Ag(1)Br6 octahedra. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in a distorted T-shaped geometry to two equivalent Ag(1) and one As(1) atom. In the second Br site, Br(2) is bonded in a distorted T-shaped geometry to one Ag(1) and two equivalent As(1) atoms. is represented by the CIF file [CIF]
data_AgAsBr4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.366
_cell_length_b   7.803
_cell_length_c   8.366
_cell_angle_alpha   62.202
_cell_angle_beta   58.688
_cell_angle_gamma   62.202
_symmetry_Int_Tables_number   1
_cell_volume   394.156
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.000  0.000  0.500  1.0
  Ag  Ag1  1  0.500  0.000  0.000  1.0
  As  As2  1  0.000  0.000  0.000  1.0
  As  As3  1  0.000  0.500  0.000  1.0
  Br  Br4  1  0.216  0.279  0.216  1.0
  Br  Br5  1  0.216  0.788  0.216  1.0
  Br  Br6  1  0.225  0.256  0.764  1.0
  Br  Br7  1  0.764  0.256  0.225  1.0
  Br  Br8  1  0.236  0.744  0.775  1.0
  Br  Br9  1  0.784  0.212  0.784  1.0
  Br  Br10  1  0.775  0.744  0.236  1.0
  Br  Br11  1  0.784  0.721  0.784  1.0
[/CIF]
.
The compound described by AgAsBr4 is trigonal omega-derived structured and crystallizes in the orthorhombic Imma space group. Ag(1) is bonded to two equivalent Br(2) and four equivalent Br(1) atoms to form AgBr6 octahedra that share edges with two equivalent Ag(1)Br6 octahedra and edges with four equivalent As(1)Br6 octahedra. As(1) is bonded to two equivalent Br(1) and four equivalent Br(2) atoms to form AsBr6 octahedra that share edges with two equivalent As(1)Br6 octahedra and edges with four equivalent Ag(1)Br6 octahedra. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in a distorted T-shaped geometry to two equivalent Ag(1) and one As(1) atom. In the second Br site, Br(2) is bonded in a distorted T-shaped geometry to one Ag(1) and two equivalent As(1) atoms. is represented by the CIF file [CIF]
data_AgAsBr4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.366
_cell_length_b   7.803
_cell_length_c   8.366
_cell_angle_alpha   62.202
_cell_angle_beta   58.688
_cell_angle_gamma   62.202
_symmetry_Int_Tables_number   1
_cell_volume   394.156
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.000  0.000  0.500  1.0
  Ag  Ag1  1  0.500  0.000  0.000  1.0
  As  As2  1  0.000  0.000  0.000  1.0
  As  As3  1  0.000  0.500  0.000  1.0
  Br  Br4  1  0.216  0.279  0.216  1.0
  Br  Br5  1  0.216  0.788  0.216  1.0
  Br  Br6  1  0.225  0.256  0.764  1.0
  Br  Br7  1  0.764  0.256  0.225  1.0
  Br  Br8  1  0.236  0.744  0.775  1.0
  Br  Br9  1  0.784  0.212  0.784  1.0
  Br  Br10  1  0.775  0.744  0.236  1.0
  Br  Br11  1  0.784  0.721  0.784  1.0
[/CIF]
.