The material structure described by B2AsCl2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two B2AsCl2 clusters. There are four inequivalent B sites. In the first B site, B(1) is bonded in a distorted single-bond geometry to one As(2) and one Cl(2) atom. In the second B site, B(2) is bonded in a distorted single-bond geometry to one As(1), one As(2), and one Cl(1) atom. In the third B site, B(3) is bonded in a distorted single-bond geometry to one As(1), one As(2), and one Cl(3) atom. In the fourth B site, B(4) is bonded in a distorted single-bond geometry to one As(1) and one Cl(4) atom. There are two inequivalent As sites. In the first As site, As(1) is bonded in a 4-coordinate geometry to one B(2), one B(3), one B(4), and one As(2) atom. In the second As site, As(2) is bonded in a 4-coordinate geometry to one B(1), one B(2), one B(3), and one As(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one B(2) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one B(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one B(3) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one B(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_B2AsCl2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.397
_cell_length_b   7.665
_cell_length_c   11.458
_cell_angle_alpha   99.411
_cell_angle_beta   100.302
_cell_angle_gamma   117.121
_symmetry_Int_Tables_number   1
_cell_volume   546.166
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.157  0.776  0.710  1.0
  B  B1  1  0.843  0.224  0.290  1.0
  B  B2  1  0.106  0.732  0.849  1.0
  B  B3  1  0.894  0.268  0.151  1.0
  B  B4  1  0.902  0.730  0.641  1.0
  B  B5  1  0.098  0.270  0.359  1.0
  B  B6  1  0.060  0.907  0.786  1.0
  B  B7  1  0.940  0.093  0.214  1.0
  As  As8  1  0.776  0.661  0.796  1.0
  As  As9  1  0.224  0.339  0.204  1.0
  As  As10  1  0.917  0.470  0.686  1.0
  As  As11  1  0.083  0.530  0.314  1.0
  Cl  Cl12  1  0.742  0.253  0.010  1.0
  Cl  Cl13  1  0.258  0.747  0.990  1.0
  Cl  Cl14  1  0.613  0.144  0.340  1.0
  Cl  Cl15  1  0.387  0.856  0.660  1.0
  Cl  Cl16  1  0.779  0.742  0.499  1.0
  Cl  Cl17  1  0.221  0.258  0.501  1.0
  Cl  Cl18  1  0.156  0.170  0.844  1.0
  Cl  Cl19  1  0.844  0.830  0.156  1.0
[/CIF]
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The material structure described by B2AsCl2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two B2AsCl2 clusters. There are four inequivalent B sites. In the first B site, B(1) is bonded in a distorted single-bond geometry to one As(2) and one Cl(2) atom. In the second B site, B(2) is bonded in a distorted single-bond geometry to one As(1), one As(2), and one Cl(1) atom. In the third B site, B(3) is bonded in a distorted single-bond geometry to one As(1), one As(2), and one Cl(3) atom. In the fourth B site, B(4) is bonded in a distorted single-bond geometry to one As(1) and one Cl(4) atom. There are two inequivalent As sites. In the first As site, As(1) is bonded in a 4-coordinate geometry to one B(2), one B(3), one B(4), and one As(2) atom. In the second As site, As(2) is bonded in a 4-coordinate geometry to one B(1), one B(2), one B(3), and one As(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one B(2) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one B(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one B(3) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one B(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_B2AsCl2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.397
_cell_length_b   7.665
_cell_length_c   11.458
_cell_angle_alpha   99.411
_cell_angle_beta   100.302
_cell_angle_gamma   117.121
_symmetry_Int_Tables_number   1
_cell_volume   546.166
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.157  0.776  0.710  1.0
  B  B1  1  0.843  0.224  0.290  1.0
  B  B2  1  0.106  0.732  0.849  1.0
  B  B3  1  0.894  0.268  0.151  1.0
  B  B4  1  0.902  0.730  0.641  1.0
  B  B5  1  0.098  0.270  0.359  1.0
  B  B6  1  0.060  0.907  0.786  1.0
  B  B7  1  0.940  0.093  0.214  1.0
  As  As8  1  0.776  0.661  0.796  1.0
  As  As9  1  0.224  0.339  0.204  1.0
  As  As10  1  0.917  0.470  0.686  1.0
  As  As11  1  0.083  0.530  0.314  1.0
  Cl  Cl12  1  0.742  0.253  0.010  1.0
  Cl  Cl13  1  0.258  0.747  0.990  1.0
  Cl  Cl14  1  0.613  0.144  0.340  1.0
  Cl  Cl15  1  0.387  0.856  0.660  1.0
  Cl  Cl16  1  0.779  0.742  0.499  1.0
  Cl  Cl17  1  0.221  0.258  0.501  1.0
  Cl  Cl18  1  0.156  0.170  0.844  1.0
  Cl  Cl19  1  0.844  0.830  0.156  1.0
[/CIF]
.