The crystal structure described by Ni(N3H2)2(H2O)4 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of eight water molecules and two Ni(N3H2)2 clusters. In each Ni(N3H2)2 cluster, Ni(1) is bonded in a distorted octahedral geometry to two equivalent N(2) and four equivalent N(1) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Ni(1) and one H(3) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Ni(1) atom. H(3) is bonded in a single-bond geometry to one N(1) atom. is represented by the CIF file [CIF]
data_NiH12(N3O2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.185
_cell_length_b   7.185
_cell_length_c   6.784
_cell_angle_alpha   67.876
_cell_angle_beta   67.876
_cell_angle_gamma   47.023
_symmetry_Int_Tables_number   1
_cell_volume   233.644
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni0  1  0.000  0.000  0.000  1.0
  H  H1  1  0.434  0.703  0.280  1.0
  H  H2  1  0.297  0.566  0.720  1.0
  H  H3  1  0.566  0.297  0.720  1.0
  H  H4  1  0.703  0.434  0.280  1.0
  H  H5  1  0.143  0.411  0.190  1.0
  H  H6  1  0.589  0.857  0.810  1.0
  H  H7  1  0.857  0.589  0.810  1.0
  H  H8  1  0.411  0.143  0.190  1.0
  H  H9  1  0.056  0.698  0.401  1.0
  H  H10  1  0.302  0.944  0.599  1.0
  H  H11  1  0.944  0.302  0.599  1.0
  H  H12  1  0.698  0.056  0.401  1.0
  N  N13  1  0.155  0.931  0.680  1.0
  N  N14  1  0.865  0.865  0.058  1.0
  N  N15  1  0.135  0.135  0.942  1.0
  N  N16  1  0.845  0.069  0.320  1.0
  N  N17  1  0.069  0.845  0.320  1.0
  N  N18  1  0.931  0.155  0.680  1.0
  O  O19  1  0.272  0.272  0.284  1.0
  O  O20  1  0.615  0.615  0.281  1.0
  O  O21  1  0.385  0.385  0.719  1.0
  O  O22  1  0.728  0.728  0.716  1.0
[/CIF]
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The crystal structure described by Ni(N3H2)2(H2O)4 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of eight water molecules and two Ni(N3H2)2 clusters. In each Ni(N3H2)2 cluster, Ni(1) is bonded in a distorted octahedral geometry to two equivalent N(2) and four equivalent N(1) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Ni(1) and one H(3) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Ni(1) atom. H(3) is bonded in a single-bond geometry to one N(1) atom. is represented by the CIF file [CIF]
data_NiH12(N3O2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.185
_cell_length_b   7.185
_cell_length_c   6.784
_cell_angle_alpha   67.876
_cell_angle_beta   67.876
_cell_angle_gamma   47.023
_symmetry_Int_Tables_number   1
_cell_volume   233.644
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni0  1  0.000  0.000  0.000  1.0
  H  H1  1  0.434  0.703  0.280  1.0
  H  H2  1  0.297  0.566  0.720  1.0
  H  H3  1  0.566  0.297  0.720  1.0
  H  H4  1  0.703  0.434  0.280  1.0
  H  H5  1  0.143  0.411  0.190  1.0
  H  H6  1  0.589  0.857  0.810  1.0
  H  H7  1  0.857  0.589  0.810  1.0
  H  H8  1  0.411  0.143  0.190  1.0
  H  H9  1  0.056  0.698  0.401  1.0
  H  H10  1  0.302  0.944  0.599  1.0
  H  H11  1  0.944  0.302  0.599  1.0
  H  H12  1  0.698  0.056  0.401  1.0
  N  N13  1  0.155  0.931  0.680  1.0
  N  N14  1  0.865  0.865  0.058  1.0
  N  N15  1  0.135  0.135  0.942  1.0
  N  N16  1  0.845  0.069  0.320  1.0
  N  N17  1  0.069  0.845  0.320  1.0
  N  N18  1  0.931  0.155  0.680  1.0
  O  O19  1  0.272  0.272  0.284  1.0
  O  O20  1  0.615  0.615  0.281  1.0
  O  O21  1  0.385  0.385  0.719  1.0
  O  O22  1  0.728  0.728  0.716  1.0
[/CIF]
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