The material structure described by LiVTeO5 crystallizes in the orthorhombic P2_12_12_1 space group. Li(1) is bonded in a 5-coordinate geometry to one O(2), one O(3), one O(4), and two equivalent O(5) atoms. V(1) is bonded to one O(1), one O(2), one O(3), one O(4), and one O(5) atom to form distorted VO5 trigonal bipyramids that share corners with three equivalent Te(1)O5 square pyramids and  an edgeedge with one Te(1)O5 square pyramid. Te(1) is bonded to one O(2), one O(3), one O(4), and two equivalent O(1) atoms to form distorted TeO5 square pyramids that share corners with two equivalent Te(1)O5 square pyramids, corners with three equivalent V(1)O5 trigonal bipyramids, and  an edgeedge with one V(1)O5 trigonal bipyramid. There are five inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one V(1) and two equivalent Te(1) atoms. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Li(1), one V(1), and one Te(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Li(1), one V(1), and one Te(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Li(1), one V(1), and one Te(1) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to two equivalent Li(1) and one V(1) atom. is represented by the CIF card [CIF]
data_LiVTeO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.221
_cell_length_b   8.481
_cell_length_c   9.658
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   427.631
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.037  0.879  0.976  1.0
  Li  Li1  1  0.537  0.621  0.024  1.0
  Li  Li2  1  0.463  0.121  0.476  1.0
  Li  Li3  1  0.963  0.379  0.524  1.0
  V  V4  1  0.543  0.978  0.148  1.0
  V  V5  1  0.043  0.522  0.852  1.0
  V  V6  1  0.957  0.022  0.648  1.0
  V  V7  1  0.457  0.478  0.352  1.0
  Te  Te8  1  0.462  0.183  0.853  1.0
  Te  Te9  1  0.962  0.317  0.147  1.0
  Te  Te10  1  0.038  0.817  0.353  1.0
  Te  Te11  1  0.538  0.683  0.647  1.0
  O  O12  1  0.688  0.176  0.081  1.0
  O  O13  1  0.188  0.324  0.919  1.0
  O  O14  1  0.812  0.824  0.581  1.0
  O  O15  1  0.312  0.676  0.419  1.0
  O  O16  1  0.845  0.995  0.812  1.0
  O  O17  1  0.345  0.505  0.188  1.0
  O  O18  1  0.655  0.005  0.312  1.0
  O  O19  1  0.155  0.495  0.688  1.0
  O  O20  1  0.286  0.100  0.691  1.0
  O  O21  1  0.786  0.400  0.309  1.0
  O  O22  1  0.214  0.900  0.191  1.0
  O  O23  1  0.714  0.600  0.809  1.0
  O  O24  1  0.337  0.024  0.970  1.0
  O  O25  1  0.837  0.476  0.030  1.0
  O  O26  1  0.163  0.976  0.470  1.0
  O  O27  1  0.663  0.524  0.530  1.0
  O  O28  1  0.715  0.824  0.089  1.0
  O  O29  1  0.215  0.676  0.911  1.0
  O  O30  1  0.785  0.176  0.589  1.0
  O  O31  1  0.285  0.324  0.411  1.0
[/CIF]
.
The material structure described by LiVTeO5 crystallizes in the orthorhombic P2_12_12_1 space group. Li(1) is bonded in a 5-coordinate geometry to one O(2), one O(3), one O(4), and two equivalent O(5) atoms. V(1) is bonded to one O(1), one O(2), one O(3), one O(4), and one O(5) atom to form distorted VO5 trigonal bipyramids that share corners with three equivalent Te(1)O5 square pyramids and  an edgeedge with one Te(1)O5 square pyramid. Te(1) is bonded to one O(2), one O(3), one O(4), and two equivalent O(1) atoms to form distorted TeO5 square pyramids that share corners with two equivalent Te(1)O5 square pyramids, corners with three equivalent V(1)O5 trigonal bipyramids, and  an edgeedge with one V(1)O5 trigonal bipyramid. There are five inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one V(1) and two equivalent Te(1) atoms. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Li(1), one V(1), and one Te(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Li(1), one V(1), and one Te(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Li(1), one V(1), and one Te(1) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to two equivalent Li(1) and one V(1) atom. is represented by the CIF card [CIF]
data_LiVTeO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.221
_cell_length_b   8.481
_cell_length_c   9.658
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   427.631
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.037  0.879  0.976  1.0
  Li  Li1  1  0.537  0.621  0.024  1.0
  Li  Li2  1  0.463  0.121  0.476  1.0
  Li  Li3  1  0.963  0.379  0.524  1.0
  V  V4  1  0.543  0.978  0.148  1.0
  V  V5  1  0.043  0.522  0.852  1.0
  V  V6  1  0.957  0.022  0.648  1.0
  V  V7  1  0.457  0.478  0.352  1.0
  Te  Te8  1  0.462  0.183  0.853  1.0
  Te  Te9  1  0.962  0.317  0.147  1.0
  Te  Te10  1  0.038  0.817  0.353  1.0
  Te  Te11  1  0.538  0.683  0.647  1.0
  O  O12  1  0.688  0.176  0.081  1.0
  O  O13  1  0.188  0.324  0.919  1.0
  O  O14  1  0.812  0.824  0.581  1.0
  O  O15  1  0.312  0.676  0.419  1.0
  O  O16  1  0.845  0.995  0.812  1.0
  O  O17  1  0.345  0.505  0.188  1.0
  O  O18  1  0.655  0.005  0.312  1.0
  O  O19  1  0.155  0.495  0.688  1.0
  O  O20  1  0.286  0.100  0.691  1.0
  O  O21  1  0.786  0.400  0.309  1.0
  O  O22  1  0.214  0.900  0.191  1.0
  O  O23  1  0.714  0.600  0.809  1.0
  O  O24  1  0.337  0.024  0.970  1.0
  O  O25  1  0.837  0.476  0.030  1.0
  O  O26  1  0.163  0.976  0.470  1.0
  O  O27  1  0.663  0.524  0.530  1.0
  O  O28  1  0.715  0.824  0.089  1.0
  O  O29  1  0.215  0.676  0.911  1.0
  O  O30  1  0.785  0.176  0.589  1.0
  O  O31  1  0.285  0.324  0.411  1.0
[/CIF]
.