The material described by RbWO7 crystallizes in the triclinic P-1 space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 11-coordinate geometry to one O(1), one O(10), one O(11), one O(12), one O(13), one O(2), one O(5), one O(8), one O(9), and two equivalent O(7) atoms. In the second Rb site, Rb(2) is bonded in a 6-coordinate geometry to one O(10), one O(11), one O(14), one O(3), one O(4), one O(5), and one O(6) atom. There are two inequivalent W sites. In the first W site, W(1) is bonded in a distorted pentagonal bipyramidal geometry to one O(1), one O(10), one O(14), one O(3), one O(4), one O(6), and one O(8) atom. In the second W site, W(2) is bonded in a 7-coordinate geometry to one O(1), one O(12), one O(13), one O(2), one O(5), one O(7), and one O(9) atom. There are fourteen inequivalent O sites. In the first O site, O(13) is bonded in a 2-coordinate geometry to one Rb(1), one W(2), and one O(12) atom. In the second O site, O(14) is bonded in a 3-coordinate geometry to one Rb(2), one W(1), and one O(6) atom. In the third O site, O(1) is bonded in a bent 150 degrees geometry to one Rb(1), one W(1), and one W(2) atom. In the fourth O site, O(2) is bonded in a 3-coordinate geometry to one Rb(1), one W(2), and one O(9) atom. In the fifth O site, O(3) is bonded in a distorted trigonal planar geometry to one Rb(2), one W(1), and one O(8) atom. In the sixth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Rb(2) and one W(1) atom. In the seventh O site, O(5) is bonded in a 4-coordinate geometry to one Rb(1), one Rb(2), one W(2), and one O(11) atom. In the eighth O site, O(6) is bonded in a distorted T-shaped geometry to one Rb(2), one W(1), and one O(14) atom. In the ninth O site, O(7) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one W(2) atom. In the tenth O site, O(8) is bonded in a 3-coordinate geometry to one Rb(1), one W(1), and one O(3) atom. In the eleventh O site, O(9) is bonded in a 3-coordinate geometry to one Rb(1), one W(2), and one O(2) atom. In the twelfth O site, O(10) is bonded in a 3-coordinate geometry to one Rb(1), one Rb(2), and one W(1) atom. In the thirteenth O site, O(11) is bonded in a 3-coordinate geometry to one Rb(1), one Rb(2), and one O(5) atom. In the fourteenth O site, O(12) is bonded in a 3-coordinate geometry to one Rb(1), one W(2), and one O(13) atom. is represented by the CIF card [CIF]
data_RbWO7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.401
_cell_length_b   8.431
_cell_length_c   13.469
_cell_angle_alpha   104.126
_cell_angle_beta   89.748
_cell_angle_gamma   98.203
_symmetry_Int_Tables_number   1
_cell_volume   697.363
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.327  0.819  0.117  1.0
  Rb  Rb1  1  0.673  0.181  0.883  1.0
  Rb  Rb2  1  0.617  0.263  0.564  1.0
  Rb  Rb3  1  0.383  0.737  0.436  1.0
  W  W4  1  0.034  0.133  0.335  1.0
  W  W5  1  0.966  0.867  0.665  1.0
  W  W6  1  0.289  0.253  0.105  1.0
  W  W7  1  0.711  0.747  0.895  1.0
  O  O8  1  0.101  0.170  0.202  1.0
  O  O9  1  0.899  0.830  0.798  1.0
  O  O10  1  0.054  0.357  0.053  1.0
  O  O11  1  0.946  0.643  0.947  1.0
  O  O12  1  0.221  0.069  0.646  1.0
  O  O13  1  0.779  0.931  0.354  1.0
  O  O14  1  0.836  0.257  0.390  1.0
  O  O15  1  0.164  0.743  0.610  1.0
  O  O16  1  0.286  0.518  0.231  1.0
  O  O17  1  0.714  0.482  0.769  1.0
  O  O18  1  0.200  0.280  0.481  1.0
  O  O19  1  0.800  0.720  0.519  1.0
  O  O20  1  0.285  0.070  0.007  1.0
  O  O21  1  0.715  0.930  0.993  1.0
  O  O22  1  0.204  0.058  0.744  1.0
  O  O23  1  0.796  0.942  0.256  1.0
  O  O24  1  0.262  0.418  0.023  1.0
  O  O25  1  0.738  0.582  0.977  1.0
  O  O26  1  0.797  0.016  0.647  1.0
  O  O27  1  0.203  0.984  0.353  1.0
  O  O28  1  0.902  0.446  0.772  1.0
  O  O29  1  0.098  0.554  0.228  1.0
  O  O30  1  0.595  0.334  0.117  1.0
  O  O31  1  0.405  0.666  0.883  1.0
  O  O32  1  0.526  0.246  0.197  1.0
  O  O33  1  0.474  0.754  0.803  1.0
  O  O34  1  0.270  0.336  0.399  1.0
  O  O35  1  0.730  0.664  0.601  1.0
[/CIF]
.
The material described by RbWO7 crystallizes in the triclinic P-1 space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 11-coordinate geometry to one O(1), one O(10), one O(11), one O(12), one O(13), one O(2), one O(5), one O(8), one O(9), and two equivalent O(7) atoms. In the second Rb site, Rb(2) is bonded in a 6-coordinate geometry to one O(10), one O(11), one O(14), one O(3), one O(4), one O(5), and one O(6) atom. There are two inequivalent W sites. In the first W site, W(1) is bonded in a distorted pentagonal bipyramidal geometry to one O(1), one O(10), one O(14), one O(3), one O(4), one O(6), and one O(8) atom. In the second W site, W(2) is bonded in a 7-coordinate geometry to one O(1), one O(12), one O(13), one O(2), one O(5), one O(7), and one O(9) atom. There are fourteen inequivalent O sites. In the first O site, O(13) is bonded in a 2-coordinate geometry to one Rb(1), one W(2), and one O(12) atom. In the second O site, O(14) is bonded in a 3-coordinate geometry to one Rb(2), one W(1), and one O(6) atom. In the third O site, O(1) is bonded in a bent 150 degrees geometry to one Rb(1), one W(1), and one W(2) atom. In the fourth O site, O(2) is bonded in a 3-coordinate geometry to one Rb(1), one W(2), and one O(9) atom. In the fifth O site, O(3) is bonded in a distorted trigonal planar geometry to one Rb(2), one W(1), and one O(8) atom. In the sixth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Rb(2) and one W(1) atom. In the seventh O site, O(5) is bonded in a 4-coordinate geometry to one Rb(1), one Rb(2), one W(2), and one O(11) atom. In the eighth O site, O(6) is bonded in a distorted T-shaped geometry to one Rb(2), one W(1), and one O(14) atom. In the ninth O site, O(7) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one W(2) atom. In the tenth O site, O(8) is bonded in a 3-coordinate geometry to one Rb(1), one W(1), and one O(3) atom. In the eleventh O site, O(9) is bonded in a 3-coordinate geometry to one Rb(1), one W(2), and one O(2) atom. In the twelfth O site, O(10) is bonded in a 3-coordinate geometry to one Rb(1), one Rb(2), and one W(1) atom. In the thirteenth O site, O(11) is bonded in a 3-coordinate geometry to one Rb(1), one Rb(2), and one O(5) atom. In the fourteenth O site, O(12) is bonded in a 3-coordinate geometry to one Rb(1), one W(2), and one O(13) atom. is represented by the CIF card [CIF]
data_RbWO7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.401
_cell_length_b   8.431
_cell_length_c   13.469
_cell_angle_alpha   104.126
_cell_angle_beta   89.748
_cell_angle_gamma   98.203
_symmetry_Int_Tables_number   1
_cell_volume   697.363
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.327  0.819  0.117  1.0
  Rb  Rb1  1  0.673  0.181  0.883  1.0
  Rb  Rb2  1  0.617  0.263  0.564  1.0
  Rb  Rb3  1  0.383  0.737  0.436  1.0
  W  W4  1  0.034  0.133  0.335  1.0
  W  W5  1  0.966  0.867  0.665  1.0
  W  W6  1  0.289  0.253  0.105  1.0
  W  W7  1  0.711  0.747  0.895  1.0
  O  O8  1  0.101  0.170  0.202  1.0
  O  O9  1  0.899  0.830  0.798  1.0
  O  O10  1  0.054  0.357  0.053  1.0
  O  O11  1  0.946  0.643  0.947  1.0
  O  O12  1  0.221  0.069  0.646  1.0
  O  O13  1  0.779  0.931  0.354  1.0
  O  O14  1  0.836  0.257  0.390  1.0
  O  O15  1  0.164  0.743  0.610  1.0
  O  O16  1  0.286  0.518  0.231  1.0
  O  O17  1  0.714  0.482  0.769  1.0
  O  O18  1  0.200  0.280  0.481  1.0
  O  O19  1  0.800  0.720  0.519  1.0
  O  O20  1  0.285  0.070  0.007  1.0
  O  O21  1  0.715  0.930  0.993  1.0
  O  O22  1  0.204  0.058  0.744  1.0
  O  O23  1  0.796  0.942  0.256  1.0
  O  O24  1  0.262  0.418  0.023  1.0
  O  O25  1  0.738  0.582  0.977  1.0
  O  O26  1  0.797  0.016  0.647  1.0
  O  O27  1  0.203  0.984  0.353  1.0
  O  O28  1  0.902  0.446  0.772  1.0
  O  O29  1  0.098  0.554  0.228  1.0
  O  O30  1  0.595  0.334  0.117  1.0
  O  O31  1  0.405  0.666  0.883  1.0
  O  O32  1  0.526  0.246  0.197  1.0
  O  O33  1  0.474  0.754  0.803  1.0
  O  O34  1  0.270  0.336  0.399  1.0
  O  O35  1  0.730  0.664  0.601  1.0
[/CIF]
.