The structure described by Zn2SO6 crystallizes in the orthorhombic P2_12_12_1 space group. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 4-coordinate geometry to one O(2), one O(6), and two equivalent O(5) atoms. In the second Zn site, Zn(2) is bonded to one O(3), one O(4), two equivalent O(1), and two equivalent O(6) atoms to form ZnO6 octahedra that share corners with four equivalent S(1)O4 tetrahedra and edges with two equivalent Zn(2)O6 octahedra. S(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form SO4 tetrahedra that share corners with four equivalent Zn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-48°. There are six inequivalent O sites. In the first O site, O(6) is bonded in a trigonal non-coplanar geometry to one Zn(1) and two equivalent Zn(2) atoms. In the second O site, O(1) is bonded in a 3-coordinate geometry to two equivalent Zn(2) and one S(1) atom. In the third O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one S(1) atom. In the fourth O site, O(3) is bonded in a 2-coordinate geometry to one Zn(2) and one S(1) atom. In the fifth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one S(1) atom. In the sixth O site, O(5) is bonded in a bent 120 degrees geometry to two equivalent Zn(1) atoms. is represented by the CIF file [CIF]
data_Zn2SO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.908
_cell_length_b   6.417
_cell_length_c   14.292
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   450.132
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.663  0.128  0.059  1.0
  Zn  Zn1  1  0.837  0.872  0.559  1.0
  Zn  Zn2  1  0.337  0.628  0.441  1.0
  Zn  Zn3  1  0.163  0.372  0.941  1.0
  Zn  Zn4  1  0.500  0.359  0.253  1.0
  Zn  Zn5  1  1.000  0.641  0.753  1.0
  Zn  Zn6  1  0.500  0.859  0.247  1.0
  Zn  Zn7  1  0.000  0.141  0.747  1.0
  S  S8  1  0.012  0.109  0.368  1.0
  S  S9  1  0.488  0.891  0.868  1.0
  S  S10  1  0.988  0.609  0.132  1.0
  S  S11  1  0.512  0.391  0.632  1.0
  O  O12  1  0.262  0.608  0.180  1.0
  O  O13  1  0.238  0.392  0.680  1.0
  O  O14  1  0.738  0.108  0.320  1.0
  O  O15  1  0.762  0.892  0.820  1.0
  O  O16  1  0.032  0.606  0.030  1.0
  O  O17  1  0.468  0.394  0.530  1.0
  O  O18  1  0.968  0.106  0.470  1.0
  O  O19  1  0.532  0.894  0.970  1.0
  O  O20  1  0.336  0.082  0.838  1.0
  O  O21  1  0.164  0.918  0.338  1.0
  O  O22  1  0.664  0.582  0.662  1.0
  O  O23  1  0.836  0.418  0.162  1.0
  O  O24  1  0.163  0.300  0.343  1.0
  O  O25  1  0.337  0.700  0.843  1.0
  O  O26  1  0.837  0.800  0.157  1.0
  O  O27  1  0.663  0.200  0.657  1.0
  O  O28  1  0.043  0.140  0.025  1.0
  O  O29  1  0.457  0.860  0.525  1.0
  O  O30  1  0.957  0.640  0.475  1.0
  O  O31  1  0.543  0.360  0.975  1.0
  O  O32  1  0.441  0.114  0.168  1.0
  O  O33  1  0.059  0.886  0.668  1.0
  O  O34  1  0.559  0.614  0.332  1.0
  O  O35  1  0.941  0.386  0.832  1.0
[/CIF]
.
The structure described by Zn2SO6 crystallizes in the orthorhombic P2_12_12_1 space group. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 4-coordinate geometry to one O(2), one O(6), and two equivalent O(5) atoms. In the second Zn site, Zn(2) is bonded to one O(3), one O(4), two equivalent O(1), and two equivalent O(6) atoms to form ZnO6 octahedra that share corners with four equivalent S(1)O4 tetrahedra and edges with two equivalent Zn(2)O6 octahedra. S(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form SO4 tetrahedra that share corners with four equivalent Zn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-48°. There are six inequivalent O sites. In the first O site, O(6) is bonded in a trigonal non-coplanar geometry to one Zn(1) and two equivalent Zn(2) atoms. In the second O site, O(1) is bonded in a 3-coordinate geometry to two equivalent Zn(2) and one S(1) atom. In the third O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one S(1) atom. In the fourth O site, O(3) is bonded in a 2-coordinate geometry to one Zn(2) and one S(1) atom. In the fifth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one S(1) atom. In the sixth O site, O(5) is bonded in a bent 120 degrees geometry to two equivalent Zn(1) atoms. is represented by the CIF file [CIF]
data_Zn2SO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.908
_cell_length_b   6.417
_cell_length_c   14.292
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   450.132
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.663  0.128  0.059  1.0
  Zn  Zn1  1  0.837  0.872  0.559  1.0
  Zn  Zn2  1  0.337  0.628  0.441  1.0
  Zn  Zn3  1  0.163  0.372  0.941  1.0
  Zn  Zn4  1  0.500  0.359  0.253  1.0
  Zn  Zn5  1  1.000  0.641  0.753  1.0
  Zn  Zn6  1  0.500  0.859  0.247  1.0
  Zn  Zn7  1  0.000  0.141  0.747  1.0
  S  S8  1  0.012  0.109  0.368  1.0
  S  S9  1  0.488  0.891  0.868  1.0
  S  S10  1  0.988  0.609  0.132  1.0
  S  S11  1  0.512  0.391  0.632  1.0
  O  O12  1  0.262  0.608  0.180  1.0
  O  O13  1  0.238  0.392  0.680  1.0
  O  O14  1  0.738  0.108  0.320  1.0
  O  O15  1  0.762  0.892  0.820  1.0
  O  O16  1  0.032  0.606  0.030  1.0
  O  O17  1  0.468  0.394  0.530  1.0
  O  O18  1  0.968  0.106  0.470  1.0
  O  O19  1  0.532  0.894  0.970  1.0
  O  O20  1  0.336  0.082  0.838  1.0
  O  O21  1  0.164  0.918  0.338  1.0
  O  O22  1  0.664  0.582  0.662  1.0
  O  O23  1  0.836  0.418  0.162  1.0
  O  O24  1  0.163  0.300  0.343  1.0
  O  O25  1  0.337  0.700  0.843  1.0
  O  O26  1  0.837  0.800  0.157  1.0
  O  O27  1  0.663  0.200  0.657  1.0
  O  O28  1  0.043  0.140  0.025  1.0
  O  O29  1  0.457  0.860  0.525  1.0
  O  O30  1  0.957  0.640  0.475  1.0
  O  O31  1  0.543  0.360  0.975  1.0
  O  O32  1  0.441  0.114  0.168  1.0
  O  O33  1  0.059  0.886  0.668  1.0
  O  O34  1  0.559  0.614  0.332  1.0
  O  O35  1  0.941  0.386  0.832  1.0
[/CIF]
.