The material described by DyFeCo3Ga crystallizes in the monoclinic P2/m space group. Dy(1) is bonded in a 18-coordinate geometry to four equivalent Fe(1), four equivalent Co(2), six equivalent Co(1), and four equivalent Ga(1) atoms. Fe(1) is bonded to four equivalent Dy(1), two equivalent Co(2), four equivalent Co(1), and two equivalent Ga(1) atoms to form distorted FeDy4Ga2Co6 cuboctahedra that share corners with four equivalent Co(2)Dy4Ga2Fe2Co4 cuboctahedra, corners with four equivalent Ga(1)Dy4Fe2Co6 cuboctahedra, corners with eight equivalent Fe(1)Dy4Ga2Co6 cuboctahedra, edges with two equivalent Fe(1)Dy4Ga2Co6 cuboctahedra, edges with four equivalent Co(2)Dy4Ga2Fe2Co4 cuboctahedra, edges with four equivalent Ga(1)Dy4Fe2Co6 cuboctahedra, faces with two equivalent Fe(1)Dy4Ga2Co6 cuboctahedra, faces with four equivalent Co(2)Dy4Ga2Fe2Co4 cuboctahedra, and faces with four equivalent Ga(1)Dy4Fe2Co6 cuboctahedra. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a 9-coordinate geometry to three equivalent Dy(1), two equivalent Fe(1), two equivalent Co(2), and two equivalent Ga(1) atoms. In the second Co site, Co(2) is bonded to four equivalent Dy(1), two equivalent Fe(1), four equivalent Co(1), and two equivalent Ga(1) atoms to form distorted CoDy4Ga2Fe2Co4 cuboctahedra that share corners with four equivalent Fe(1)Dy4Ga2Co6 cuboctahedra, corners with four equivalent Ga(1)Dy4Fe2Co6 cuboctahedra, corners with eight equivalent Co(2)Dy4Ga2Fe2Co4 cuboctahedra, edges with two equivalent Co(2)Dy4Ga2Fe2Co4 cuboctahedra, edges with four equivalent Fe(1)Dy4Ga2Co6 cuboctahedra, edges with four equivalent Ga(1)Dy4Fe2Co6 cuboctahedra, faces with two equivalent Co(2)Dy4Ga2Fe2Co4 cuboctahedra, faces with four equivalent Fe(1)Dy4Ga2Co6 cuboctahedra, and faces with four equivalent Ga(1)Dy4Fe2Co6 cuboctahedra. Ga(1) is bonded to four equivalent Dy(1), two equivalent Fe(1), two equivalent Co(2), and four equivalent Co(1) atoms to form GaDy4Fe2Co6 cuboctahedra that share corners with four equivalent Fe(1)Dy4Ga2Co6 cuboctahedra, corners with four equivalent Co(2)Dy4Ga2Fe2Co4 cuboctahedra, corners with eight equivalent Ga(1)Dy4Fe2Co6 cuboctahedra, edges with two equivalent Ga(1)Dy4Fe2Co6 cuboctahedra, edges with four equivalent Fe(1)Dy4Ga2Co6 cuboctahedra, edges with four equivalent Co(2)Dy4Ga2Fe2Co4 cuboctahedra, faces with two equivalent Ga(1)Dy4Fe2Co6 cuboctahedra, faces with four equivalent Fe(1)Dy4Ga2Co6 cuboctahedra, and faces with four equivalent Co(2)Dy4Ga2Fe2Co4 cuboctahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_DyGaFeCo3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.009
_cell_length_b   5.079
_cell_length_c   4.918
_cell_angle_alpha   119.665
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   87.020
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  1  0.000  1.000  0.000  1.0
  Ga  Ga1  1  0.500  1.000  0.500  1.0
  Fe  Fe2  1  0.500  0.500  0.500  1.0
  Co  Co3  1  0.000  0.348  0.675  1.0
  Co  Co4  1  0.000  0.652  0.325  1.0
  Co  Co5  1  0.500  0.500  0.000  1.0
[/CIF]
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The material described by DyFeCo3Ga crystallizes in the monoclinic P2/m space group. Dy(1) is bonded in a 18-coordinate geometry to four equivalent Fe(1), four equivalent Co(2), six equivalent Co(1), and four equivalent Ga(1) atoms. Fe(1) is bonded to four equivalent Dy(1), two equivalent Co(2), four equivalent Co(1), and two equivalent Ga(1) atoms to form distorted FeDy4Ga2Co6 cuboctahedra that share corners with four equivalent Co(2)Dy4Ga2Fe2Co4 cuboctahedra, corners with four equivalent Ga(1)Dy4Fe2Co6 cuboctahedra, corners with eight equivalent Fe(1)Dy4Ga2Co6 cuboctahedra, edges with two equivalent Fe(1)Dy4Ga2Co6 cuboctahedra, edges with four equivalent Co(2)Dy4Ga2Fe2Co4 cuboctahedra, edges with four equivalent Ga(1)Dy4Fe2Co6 cuboctahedra, faces with two equivalent Fe(1)Dy4Ga2Co6 cuboctahedra, faces with four equivalent Co(2)Dy4Ga2Fe2Co4 cuboctahedra, and faces with four equivalent Ga(1)Dy4Fe2Co6 cuboctahedra. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a 9-coordinate geometry to three equivalent Dy(1), two equivalent Fe(1), two equivalent Co(2), and two equivalent Ga(1) atoms. In the second Co site, Co(2) is bonded to four equivalent Dy(1), two equivalent Fe(1), four equivalent Co(1), and two equivalent Ga(1) atoms to form distorted CoDy4Ga2Fe2Co4 cuboctahedra that share corners with four equivalent Fe(1)Dy4Ga2Co6 cuboctahedra, corners with four equivalent Ga(1)Dy4Fe2Co6 cuboctahedra, corners with eight equivalent Co(2)Dy4Ga2Fe2Co4 cuboctahedra, edges with two equivalent Co(2)Dy4Ga2Fe2Co4 cuboctahedra, edges with four equivalent Fe(1)Dy4Ga2Co6 cuboctahedra, edges with four equivalent Ga(1)Dy4Fe2Co6 cuboctahedra, faces with two equivalent Co(2)Dy4Ga2Fe2Co4 cuboctahedra, faces with four equivalent Fe(1)Dy4Ga2Co6 cuboctahedra, and faces with four equivalent Ga(1)Dy4Fe2Co6 cuboctahedra. Ga(1) is bonded to four equivalent Dy(1), two equivalent Fe(1), two equivalent Co(2), and four equivalent Co(1) atoms to form GaDy4Fe2Co6 cuboctahedra that share corners with four equivalent Fe(1)Dy4Ga2Co6 cuboctahedra, corners with four equivalent Co(2)Dy4Ga2Fe2Co4 cuboctahedra, corners with eight equivalent Ga(1)Dy4Fe2Co6 cuboctahedra, edges with two equivalent Ga(1)Dy4Fe2Co6 cuboctahedra, edges with four equivalent Fe(1)Dy4Ga2Co6 cuboctahedra, edges with four equivalent Co(2)Dy4Ga2Fe2Co4 cuboctahedra, faces with two equivalent Ga(1)Dy4Fe2Co6 cuboctahedra, faces with four equivalent Fe(1)Dy4Ga2Co6 cuboctahedra, and faces with four equivalent Co(2)Dy4Ga2Fe2Co4 cuboctahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_DyGaFeCo3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.009
_cell_length_b   5.079
_cell_length_c   4.918
_cell_angle_alpha   119.665
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   87.020
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  1  0.000  1.000  0.000  1.0
  Ga  Ga1  1  0.500  1.000  0.500  1.0
  Fe  Fe2  1  0.500  0.500  0.500  1.0
  Co  Co3  1  0.000  0.348  0.675  1.0
  Co  Co4  1  0.000  0.652  0.325  1.0
  Co  Co5  1  0.500  0.500  0.000  1.0
[/CIF]
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