The crystal structure described by (CN5H4)2Cl2 is Indium-derived structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of four hydrochloric acid atoms and four CN5H4 clusters. In each CN5H4 cluster, C(1) is bonded in a trigonal planar geometry to one N(1), one N(4), and one N(5) atom. There are five inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one C(1) and one N(2) atom. In the second N site, N(2) is bonded in a linear geometry to one N(1) and one N(3) atom. In the third N site, N(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(1), one H(1), and one H(2) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one C(1), one H(3), and one H(4) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(5) atom. is represented by the CIF file [CIF]
data_H4CN5Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.024
_cell_length_b   6.024
_cell_length_c   9.820
_cell_angle_alpha   88.812
_cell_angle_beta   88.812
_cell_angle_gamma   129.134
_symmetry_Int_Tables_number   1
_cell_volume   276.115
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.054  0.318  0.946  1.0
  H  H1  1  0.318  0.054  0.446  1.0
  H  H2  1  0.080  0.513  0.087  1.0
  H  H3  1  0.513  0.080  0.587  1.0
  H  H4  1  0.513  0.804  0.197  1.0
  H  H5  1  0.804  0.513  0.697  1.0
  H  H6  1  0.761  0.734  0.179  1.0
  H  H7  1  0.734  0.761  0.679  1.0
  C  C8  1  0.410  0.509  0.060  1.0
  C  C9  1  0.509  0.410  0.560  1.0
  N  N10  1  0.522  0.394  0.994  1.0
  N  N11  1  0.394  0.522  0.494  1.0
  N  N12  1  0.347  0.165  0.936  1.0
  N  N13  1  0.165  0.347  0.436  1.0
  N  N14  1  0.213  0.957  0.879  1.0
  N  N15  1  0.957  0.213  0.379  1.0
  N  N16  1  0.154  0.425  0.033  1.0
  N  N17  1  0.425  0.154  0.533  1.0
  N  N18  1  0.579  0.703  0.149  1.0
  N  N19  1  0.703  0.579  0.649  1.0
  Cl  Cl20  1  0.157  0.842  0.250  1.0
  Cl  Cl21  1  0.842  0.157  0.750  1.0
[/CIF]
.
The crystal structure described by (CN5H4)2Cl2 is Indium-derived structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of four hydrochloric acid atoms and four CN5H4 clusters. In each CN5H4 cluster, C(1) is bonded in a trigonal planar geometry to one N(1), one N(4), and one N(5) atom. There are five inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one C(1) and one N(2) atom. In the second N site, N(2) is bonded in a linear geometry to one N(1) and one N(3) atom. In the third N site, N(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(1), one H(1), and one H(2) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one C(1), one H(3), and one H(4) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(5) atom. is represented by the CIF file [CIF]
data_H4CN5Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.024
_cell_length_b   6.024
_cell_length_c   9.820
_cell_angle_alpha   88.812
_cell_angle_beta   88.812
_cell_angle_gamma   129.134
_symmetry_Int_Tables_number   1
_cell_volume   276.115
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.054  0.318  0.946  1.0
  H  H1  1  0.318  0.054  0.446  1.0
  H  H2  1  0.080  0.513  0.087  1.0
  H  H3  1  0.513  0.080  0.587  1.0
  H  H4  1  0.513  0.804  0.197  1.0
  H  H5  1  0.804  0.513  0.697  1.0
  H  H6  1  0.761  0.734  0.179  1.0
  H  H7  1  0.734  0.761  0.679  1.0
  C  C8  1  0.410  0.509  0.060  1.0
  C  C9  1  0.509  0.410  0.560  1.0
  N  N10  1  0.522  0.394  0.994  1.0
  N  N11  1  0.394  0.522  0.494  1.0
  N  N12  1  0.347  0.165  0.936  1.0
  N  N13  1  0.165  0.347  0.436  1.0
  N  N14  1  0.213  0.957  0.879  1.0
  N  N15  1  0.957  0.213  0.379  1.0
  N  N16  1  0.154  0.425  0.033  1.0
  N  N17  1  0.425  0.154  0.533  1.0
  N  N18  1  0.579  0.703  0.149  1.0
  N  N19  1  0.703  0.579  0.649  1.0
  Cl  Cl20  1  0.157  0.842  0.250  1.0
  Cl  Cl21  1  0.842  0.157  0.750  1.0
[/CIF]
.