The structure described by LiV2(CO3)4 crystallizes in the monoclinic Cc space group. Li(1) is bonded to one O(1), one O(10), one O(12), one O(5), one O(7), and one O(9) atom to form LiO6 octahedra that share corners with three equivalent V(1)O6 octahedra and corners with three equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-63°. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(10), one O(2), one O(4), one O(5), and one O(8) atom to form VO6 octahedra that share corners with three equivalent Li(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-61°. In the second V site, V(2) is bonded to one O(11), one O(12), one O(3), one O(6), one O(7), and one O(9) atom to form VO6 octahedra that share corners with three equivalent Li(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-63°. There are four inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one O(2), one O(3), and one O(7) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one O(1), one O(4), and one O(6) atom. In the third C site, C(3) is bonded in a trigonal planar geometry to one O(11), one O(12), and one O(5) atom. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one O(10), one O(8), and one O(9) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Li(1), one V(1), and one C(2) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one V(1) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one V(2) and one C(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one V(1) and one C(2) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Li(1), one V(1), and one C(3) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one V(2) and one C(2) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Li(1), one V(2), and one C(1) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one V(1) and one C(4) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one Li(1), one V(2), and one C(4) atom. In the tenth O site, O(10) is bonded in a trigonal planar geometry to one Li(1), one V(1), and one C(4) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one V(2) and one C(3) atom. In the twelfth O site, O(12) is bonded in a distorted trigonal planar geometry to one Li(1), one V(2), and one C(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiV2(CO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.504
_cell_length_b   7.504
_cell_length_c   8.730
_cell_angle_alpha   72.975
_cell_angle_beta   72.975
_cell_angle_gamma   106.130
_symmetry_Int_Tables_number   1
_cell_volume   412.323
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.251  0.998  0.999  1.0
  Li  Li1  1  0.998  0.251  0.499  1.0
  V  V2  1  0.750  0.996  1.000  1.0
  V  V3  1  0.505  0.250  0.500  1.0
  V  V4  1  0.996  0.750  0.500  1.0
  V  V5  1  0.250  0.505  0.000  1.0
  C  C6  1  0.451  0.564  0.246  1.0
  C  C7  1  0.048  0.436  0.757  1.0
  C  C8  1  0.940  0.547  0.259  1.0
  C  C9  1  0.436  0.048  0.257  1.0
  C  C10  1  0.060  0.953  0.739  1.0
  C  C11  1  0.564  0.451  0.746  1.0
  C  C12  1  0.953  0.060  0.239  1.0
  C  C13  1  0.547  0.940  0.759  1.0
  O  O14  1  0.493  0.032  0.106  1.0
  O  O15  1  0.601  0.716  0.106  1.0
  O  O16  1  0.479  0.510  0.387  1.0
  O  O17  1  0.032  0.493  0.606  1.0
  O  O18  1  0.894  0.279  0.888  1.0
  O  O19  1  0.019  0.719  0.269  1.0
  O  O20  1  0.527  0.204  0.276  1.0
  O  O21  1  0.286  0.474  0.235  1.0
  O  O22  1  0.790  0.981  0.222  1.0
  O  O23  1  0.192  0.119  0.605  1.0
  O  O24  1  0.716  0.601  0.606  1.0
  O  O25  1  0.003  0.956  0.895  1.0
  O  O26  1  0.993  0.535  0.110  1.0
  O  O27  1  0.812  0.387  0.401  1.0
  O  O28  1  0.279  0.894  0.388  1.0
  O  O29  1  0.719  0.019  0.769  1.0
  O  O30  1  0.204  0.527  0.776  1.0
  O  O31  1  0.981  0.790  0.722  1.0
  O  O32  1  0.474  0.286  0.735  1.0
  O  O33  1  0.119  0.192  0.105  1.0
  O  O34  1  0.956  0.003  0.395  1.0
  O  O35  1  0.535  0.993  0.610  1.0
  O  O36  1  0.387  0.812  0.901  1.0
  O  O37  1  0.510  0.479  0.887  1.0
[/CIF]
.
The structure described by LiV2(CO3)4 crystallizes in the monoclinic Cc space group. Li(1) is bonded to one O(1), one O(10), one O(12), one O(5), one O(7), and one O(9) atom to form LiO6 octahedra that share corners with three equivalent V(1)O6 octahedra and corners with three equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-63°. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(10), one O(2), one O(4), one O(5), and one O(8) atom to form VO6 octahedra that share corners with three equivalent Li(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-61°. In the second V site, V(2) is bonded to one O(11), one O(12), one O(3), one O(6), one O(7), and one O(9) atom to form VO6 octahedra that share corners with three equivalent Li(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-63°. There are four inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one O(2), one O(3), and one O(7) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one O(1), one O(4), and one O(6) atom. In the third C site, C(3) is bonded in a trigonal planar geometry to one O(11), one O(12), and one O(5) atom. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one O(10), one O(8), and one O(9) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Li(1), one V(1), and one C(2) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one V(1) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one V(2) and one C(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one V(1) and one C(2) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Li(1), one V(1), and one C(3) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one V(2) and one C(2) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Li(1), one V(2), and one C(1) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one V(1) and one C(4) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one Li(1), one V(2), and one C(4) atom. In the tenth O site, O(10) is bonded in a trigonal planar geometry to one Li(1), one V(1), and one C(4) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one V(2) and one C(3) atom. In the twelfth O site, O(12) is bonded in a distorted trigonal planar geometry to one Li(1), one V(2), and one C(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiV2(CO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.504
_cell_length_b   7.504
_cell_length_c   8.730
_cell_angle_alpha   72.975
_cell_angle_beta   72.975
_cell_angle_gamma   106.130
_symmetry_Int_Tables_number   1
_cell_volume   412.323
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.251  0.998  0.999  1.0
  Li  Li1  1  0.998  0.251  0.499  1.0
  V  V2  1  0.750  0.996  1.000  1.0
  V  V3  1  0.505  0.250  0.500  1.0
  V  V4  1  0.996  0.750  0.500  1.0
  V  V5  1  0.250  0.505  0.000  1.0
  C  C6  1  0.451  0.564  0.246  1.0
  C  C7  1  0.048  0.436  0.757  1.0
  C  C8  1  0.940  0.547  0.259  1.0
  C  C9  1  0.436  0.048  0.257  1.0
  C  C10  1  0.060  0.953  0.739  1.0
  C  C11  1  0.564  0.451  0.746  1.0
  C  C12  1  0.953  0.060  0.239  1.0
  C  C13  1  0.547  0.940  0.759  1.0
  O  O14  1  0.493  0.032  0.106  1.0
  O  O15  1  0.601  0.716  0.106  1.0
  O  O16  1  0.479  0.510  0.387  1.0
  O  O17  1  0.032  0.493  0.606  1.0
  O  O18  1  0.894  0.279  0.888  1.0
  O  O19  1  0.019  0.719  0.269  1.0
  O  O20  1  0.527  0.204  0.276  1.0
  O  O21  1  0.286  0.474  0.235  1.0
  O  O22  1  0.790  0.981  0.222  1.0
  O  O23  1  0.192  0.119  0.605  1.0
  O  O24  1  0.716  0.601  0.606  1.0
  O  O25  1  0.003  0.956  0.895  1.0
  O  O26  1  0.993  0.535  0.110  1.0
  O  O27  1  0.812  0.387  0.401  1.0
  O  O28  1  0.279  0.894  0.388  1.0
  O  O29  1  0.719  0.019  0.769  1.0
  O  O30  1  0.204  0.527  0.776  1.0
  O  O31  1  0.981  0.790  0.722  1.0
  O  O32  1  0.474  0.286  0.735  1.0
  O  O33  1  0.119  0.192  0.105  1.0
  O  O34  1  0.956  0.003  0.395  1.0
  O  O35  1  0.535  0.993  0.610  1.0
  O  O36  1  0.387  0.812  0.901  1.0
  O  O37  1  0.510  0.479  0.887  1.0
[/CIF]
.