The structure described by KGeBr3 is Potassium chlorate structured and crystallizes in the monoclinic P2_1/m space group. K(1) is bonded in a 7-coordinate geometry to one Br(2) and six equivalent Br(1) atoms. Ge(1) is bonded in a distorted T-shaped geometry to one Br(2) and two equivalent Br(1) atoms. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded to three equivalent K(1) and one Ge(1) atom to form a mixture of distorted edge and corner-sharing BrK3Ge tetrahedra. In the second Br site, Br(2) is bonded in a water-like geometry to one K(1) and one Ge(1) atom. is represented by the CIF file [CIF]
data_KGeBr3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.981
_cell_length_b   7.424
_cell_length_c   8.486
_cell_angle_alpha   90.000
_cell_angle_beta   114.548
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   342.765
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.864  0.250  0.193  1.0
  K  K1  1  0.136  0.750  0.807  1.0
  Ge  Ge2  1  0.559  0.250  0.611  1.0
  Ge  Ge3  1  0.441  0.750  0.389  1.0
  Br  Br4  1  0.645  0.998  0.824  1.0
  Br  Br5  1  0.355  0.498  0.176  1.0
  Br  Br6  1  0.022  0.750  0.385  1.0
  Br  Br7  1  0.978  0.250  0.615  1.0
  Br  Br8  1  0.355  0.002  0.176  1.0
  Br  Br9  1  0.645  0.502  0.824  1.0
[/CIF]
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The structure described by KGeBr3 is Potassium chlorate structured and crystallizes in the monoclinic P2_1/m space group. K(1) is bonded in a 7-coordinate geometry to one Br(2) and six equivalent Br(1) atoms. Ge(1) is bonded in a distorted T-shaped geometry to one Br(2) and two equivalent Br(1) atoms. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded to three equivalent K(1) and one Ge(1) atom to form a mixture of distorted edge and corner-sharing BrK3Ge tetrahedra. In the second Br site, Br(2) is bonded in a water-like geometry to one K(1) and one Ge(1) atom. is represented by the CIF file [CIF]
data_KGeBr3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.981
_cell_length_b   7.424
_cell_length_c   8.486
_cell_angle_alpha   90.000
_cell_angle_beta   114.548
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   342.765
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.864  0.250  0.193  1.0
  K  K1  1  0.136  0.750  0.807  1.0
  Ge  Ge2  1  0.559  0.250  0.611  1.0
  Ge  Ge3  1  0.441  0.750  0.389  1.0
  Br  Br4  1  0.645  0.998  0.824  1.0
  Br  Br5  1  0.355  0.498  0.176  1.0
  Br  Br6  1  0.022  0.750  0.385  1.0
  Br  Br7  1  0.978  0.250  0.615  1.0
  Br  Br8  1  0.355  0.002  0.176  1.0
  Br  Br9  1  0.645  0.502  0.824  1.0
[/CIF]
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