The compound described by N2Se2S(AsF6)2 is Indium-derived structured and crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of eight AsF6 clusters and four N2Se2S clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. There are six inequivalent F sites. In the first F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(6) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In each N2Se2S cluster, there are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Se(1) and one S(1) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one Se(2) and one S(1) atom. There are two inequivalent Se sites. In the first Se site, Se(1) is bonded in a single-bond geometry to one N(1) atom. In the second Se site, Se(2) is bonded in a single-bond geometry to one N(2) atom. S(1) is bonded in a water-like geometry to one N(1) and one N(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_As2Se2S(NF6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.793
_cell_length_b   7.793
_cell_length_c   10.943
_cell_angle_alpha   87.085
_cell_angle_beta   87.085
_cell_angle_gamma   68.749
_symmetry_Int_Tables_number   1
_cell_volume   618.231
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.344  0.384  0.748  1.0
  As  As1  1  0.616  0.656  0.252  1.0
  As  As2  1  0.998  0.002  0.500  1.0
  As  As3  1  0.005  0.995  0.000  1.0
  Se  Se4  1  0.568  0.845  0.857  1.0
  Se  Se5  1  0.155  0.432  0.143  1.0
  Se  Se6  1  0.576  0.862  0.639  1.0
  Se  Se7  1  0.138  0.424  0.361  1.0
  S  S8  1  0.795  0.502  0.744  1.0
  S  S9  1  0.498  0.205  0.256  1.0
  N  N10  1  0.715  0.616  0.863  1.0
  N  N11  1  0.384  0.285  0.137  1.0
  N  N12  1  0.724  0.634  0.627  1.0
  N  N13  1  0.366  0.276  0.373  1.0
  F  F14  1  0.166  0.447  0.863  1.0
  F  F15  1  0.553  0.834  0.137  1.0
  F  F16  1  0.520  0.312  0.633  1.0
  F  F17  1  0.688  0.480  0.367  1.0
  F  F18  1  0.358  0.605  0.744  1.0
  F  F19  1  0.395  0.642  0.256  1.0
  F  F20  1  0.174  0.453  0.635  1.0
  F  F21  1  0.547  0.826  0.365  1.0
  F  F22  1  0.334  0.155  0.751  1.0
  F  F23  1  0.845  0.666  0.249  1.0
  F  F24  1  0.509  0.306  0.862  1.0
  F  F25  1  0.694  0.491  0.138  1.0
  F  F26  1  0.940  0.226  0.557  1.0
  F  F27  1  0.774  0.060  0.443  1.0
  F  F28  1  0.222  0.939  0.559  1.0
  F  F29  1  0.061  0.778  0.441  1.0
  F  F30  1  0.918  0.925  0.640  1.0
  F  F31  1  0.075  0.082  0.360  1.0
  F  F32  1  0.921  0.190  0.901  1.0
  F  F33  1  0.810  0.079  0.099  1.0
  F  F34  1  0.892  0.877  0.917  1.0
  F  F35  1  0.123  0.108  0.083  1.0
  F  F36  1  0.204  0.904  0.902  1.0
  F  F37  1  0.096  0.796  0.098  1.0
[/CIF]
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The compound described by N2Se2S(AsF6)2 is Indium-derived structured and crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of eight AsF6 clusters and four N2Se2S clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. There are six inequivalent F sites. In the first F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(6) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In each N2Se2S cluster, there are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Se(1) and one S(1) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one Se(2) and one S(1) atom. There are two inequivalent Se sites. In the first Se site, Se(1) is bonded in a single-bond geometry to one N(1) atom. In the second Se site, Se(2) is bonded in a single-bond geometry to one N(2) atom. S(1) is bonded in a water-like geometry to one N(1) and one N(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_As2Se2S(NF6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.793
_cell_length_b   7.793
_cell_length_c   10.943
_cell_angle_alpha   87.085
_cell_angle_beta   87.085
_cell_angle_gamma   68.749
_symmetry_Int_Tables_number   1
_cell_volume   618.231
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.344  0.384  0.748  1.0
  As  As1  1  0.616  0.656  0.252  1.0
  As  As2  1  0.998  0.002  0.500  1.0
  As  As3  1  0.005  0.995  0.000  1.0
  Se  Se4  1  0.568  0.845  0.857  1.0
  Se  Se5  1  0.155  0.432  0.143  1.0
  Se  Se6  1  0.576  0.862  0.639  1.0
  Se  Se7  1  0.138  0.424  0.361  1.0
  S  S8  1  0.795  0.502  0.744  1.0
  S  S9  1  0.498  0.205  0.256  1.0
  N  N10  1  0.715  0.616  0.863  1.0
  N  N11  1  0.384  0.285  0.137  1.0
  N  N12  1  0.724  0.634  0.627  1.0
  N  N13  1  0.366  0.276  0.373  1.0
  F  F14  1  0.166  0.447  0.863  1.0
  F  F15  1  0.553  0.834  0.137  1.0
  F  F16  1  0.520  0.312  0.633  1.0
  F  F17  1  0.688  0.480  0.367  1.0
  F  F18  1  0.358  0.605  0.744  1.0
  F  F19  1  0.395  0.642  0.256  1.0
  F  F20  1  0.174  0.453  0.635  1.0
  F  F21  1  0.547  0.826  0.365  1.0
  F  F22  1  0.334  0.155  0.751  1.0
  F  F23  1  0.845  0.666  0.249  1.0
  F  F24  1  0.509  0.306  0.862  1.0
  F  F25  1  0.694  0.491  0.138  1.0
  F  F26  1  0.940  0.226  0.557  1.0
  F  F27  1  0.774  0.060  0.443  1.0
  F  F28  1  0.222  0.939  0.559  1.0
  F  F29  1  0.061  0.778  0.441  1.0
  F  F30  1  0.918  0.925  0.640  1.0
  F  F31  1  0.075  0.082  0.360  1.0
  F  F32  1  0.921  0.190  0.901  1.0
  F  F33  1  0.810  0.079  0.099  1.0
  F  F34  1  0.892  0.877  0.917  1.0
  F  F35  1  0.123  0.108  0.083  1.0
  F  F36  1  0.204  0.904  0.902  1.0
  F  F37  1  0.096  0.796  0.098  1.0
[/CIF]
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