The material structure described by WIrN5O4Cl is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four WIrN5O4Cl clusters. W(1) is bonded in a 5-coordinate geometry to one O(1), one O(3), two equivalent O(2), and one Cl(1) atom. Ir(1) is bonded in a distorted trigonal non-coplanar geometry to one N(3), two equivalent N(1), and one Cl(1) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Ir(1) atom. In the second N site, N(2) is bonded in a single-bond geometry to one O(2) atom. In the third N site, N(3) is bonded in a single-bond geometry to one Ir(1) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one W(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one W(1) and one N(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one W(1) atom. Cl(1) is bonded in a bent 120 degrees geometry to one W(1) and one Ir(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_IrWN5ClO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.995
_cell_length_b   9.214
_cell_length_c   12.274
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1017.245
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ir  Ir0  1  0.250  0.376  0.648  1.0
  Ir  Ir1  1  0.250  0.124  0.148  1.0
  Ir  Ir2  1  0.750  0.624  0.352  1.0
  Ir  Ir3  1  0.750  0.876  0.852  1.0
  W  W4  1  0.250  0.818  0.544  1.0
  W  W5  1  0.250  0.682  0.044  1.0
  W  W6  1  0.750  0.182  0.456  1.0
  W  W7  1  0.750  0.318  0.956  1.0
  N  N8  1  0.090  0.282  0.608  1.0
  N  N9  1  0.410  0.218  0.108  1.0
  N  N10  1  0.590  0.718  0.392  1.0
  N  N11  1  0.910  0.782  0.892  1.0
  N  N12  1  0.910  0.718  0.392  1.0
  N  N13  1  0.590  0.782  0.892  1.0
  N  N14  1  0.410  0.282  0.608  1.0
  N  N15  1  0.090  0.218  0.108  1.0
  N  N16  1  0.053  0.594  0.697  1.0
  N  N17  1  0.447  0.906  0.197  1.0
  N  N18  1  0.553  0.406  0.303  1.0
  N  N19  1  0.947  0.094  0.803  1.0
  N  N20  1  0.947  0.406  0.303  1.0
  N  N21  1  0.553  0.094  0.803  1.0
  N  N22  1  0.447  0.594  0.697  1.0
  N  N23  1  0.053  0.906  0.197  1.0
  N  N24  1  0.250  0.393  0.791  1.0
  N  N25  1  0.250  0.107  0.291  1.0
  N  N26  1  0.750  0.607  0.209  1.0
  N  N27  1  0.750  0.893  0.709  1.0
  Cl  Cl28  1  0.250  0.552  0.490  1.0
  Cl  Cl29  1  0.250  0.948  0.990  1.0
  Cl  Cl30  1  0.750  0.448  0.510  1.0
  Cl  Cl31  1  0.750  0.052  0.010  1.0
  O  O32  1  0.250  0.977  0.622  1.0
  O  O33  1  0.250  0.523  0.122  1.0
  O  O34  1  0.750  0.023  0.378  1.0
  O  O35  1  0.750  0.477  0.878  1.0
  O  O36  1  0.083  0.716  0.673  1.0
  O  O37  1  0.417  0.784  0.173  1.0
  O  O38  1  0.583  0.284  0.327  1.0
  O  O39  1  0.917  0.216  0.827  1.0
  O  O40  1  0.917  0.284  0.327  1.0
  O  O41  1  0.583  0.216  0.827  1.0
  O  O42  1  0.417  0.716  0.673  1.0
  O  O43  1  0.083  0.784  0.173  1.0
  O  O44  1  0.250  0.865  0.406  1.0
  O  O45  1  0.250  0.635  0.906  1.0
  O  O46  1  0.750  0.135  0.594  1.0
  O  O47  1  0.750  0.365  0.094  1.0
[/CIF]
.
The material structure described by WIrN5O4Cl is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four WIrN5O4Cl clusters. W(1) is bonded in a 5-coordinate geometry to one O(1), one O(3), two equivalent O(2), and one Cl(1) atom. Ir(1) is bonded in a distorted trigonal non-coplanar geometry to one N(3), two equivalent N(1), and one Cl(1) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Ir(1) atom. In the second N site, N(2) is bonded in a single-bond geometry to one O(2) atom. In the third N site, N(3) is bonded in a single-bond geometry to one Ir(1) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one W(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one W(1) and one N(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one W(1) atom. Cl(1) is bonded in a bent 120 degrees geometry to one W(1) and one Ir(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_IrWN5ClO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.995
_cell_length_b   9.214
_cell_length_c   12.274
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1017.245
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ir  Ir0  1  0.250  0.376  0.648  1.0
  Ir  Ir1  1  0.250  0.124  0.148  1.0
  Ir  Ir2  1  0.750  0.624  0.352  1.0
  Ir  Ir3  1  0.750  0.876  0.852  1.0
  W  W4  1  0.250  0.818  0.544  1.0
  W  W5  1  0.250  0.682  0.044  1.0
  W  W6  1  0.750  0.182  0.456  1.0
  W  W7  1  0.750  0.318  0.956  1.0
  N  N8  1  0.090  0.282  0.608  1.0
  N  N9  1  0.410  0.218  0.108  1.0
  N  N10  1  0.590  0.718  0.392  1.0
  N  N11  1  0.910  0.782  0.892  1.0
  N  N12  1  0.910  0.718  0.392  1.0
  N  N13  1  0.590  0.782  0.892  1.0
  N  N14  1  0.410  0.282  0.608  1.0
  N  N15  1  0.090  0.218  0.108  1.0
  N  N16  1  0.053  0.594  0.697  1.0
  N  N17  1  0.447  0.906  0.197  1.0
  N  N18  1  0.553  0.406  0.303  1.0
  N  N19  1  0.947  0.094  0.803  1.0
  N  N20  1  0.947  0.406  0.303  1.0
  N  N21  1  0.553  0.094  0.803  1.0
  N  N22  1  0.447  0.594  0.697  1.0
  N  N23  1  0.053  0.906  0.197  1.0
  N  N24  1  0.250  0.393  0.791  1.0
  N  N25  1  0.250  0.107  0.291  1.0
  N  N26  1  0.750  0.607  0.209  1.0
  N  N27  1  0.750  0.893  0.709  1.0
  Cl  Cl28  1  0.250  0.552  0.490  1.0
  Cl  Cl29  1  0.250  0.948  0.990  1.0
  Cl  Cl30  1  0.750  0.448  0.510  1.0
  Cl  Cl31  1  0.750  0.052  0.010  1.0
  O  O32  1  0.250  0.977  0.622  1.0
  O  O33  1  0.250  0.523  0.122  1.0
  O  O34  1  0.750  0.023  0.378  1.0
  O  O35  1  0.750  0.477  0.878  1.0
  O  O36  1  0.083  0.716  0.673  1.0
  O  O37  1  0.417  0.784  0.173  1.0
  O  O38  1  0.583  0.284  0.327  1.0
  O  O39  1  0.917  0.216  0.827  1.0
  O  O40  1  0.917  0.284  0.327  1.0
  O  O41  1  0.583  0.216  0.827  1.0
  O  O42  1  0.417  0.716  0.673  1.0
  O  O43  1  0.083  0.784  0.173  1.0
  O  O44  1  0.250  0.865  0.406  1.0
  O  O45  1  0.250  0.635  0.906  1.0
  O  O46  1  0.750  0.135  0.594  1.0
  O  O47  1  0.750  0.365  0.094  1.0
[/CIF]
.