The material described by NaAgO2 crystallizes in the monoclinic C2/m space group. Na(1) is bonded to six equivalent O(1) atoms to form edge-sharing NaO6 octahedra. Ag(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. O(1) is bonded to three equivalent Na(1) and two equivalent Ag(1) atoms to form a mixture of distorted corner and edge-sharing ONa3Ag2 square pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_NaAgO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.513
_cell_length_b   3.513
_cell_length_c   6.336
_cell_angle_alpha   61.779
_cell_angle_beta   118.221
_cell_angle_gamma   129.673
_symmetry_Int_Tables_number   1
_cell_volume   51.303
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.500  0.500  0.500  1.0
  Ag  Ag1  1  0.000  0.000  0.000  1.0
  O  O2  1  0.328  0.672  0.756  1.0
  O  O3  1  0.672  0.328  0.244  1.0
[/CIF]
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The material described by NaAgO2 crystallizes in the monoclinic C2/m space group. Na(1) is bonded to six equivalent O(1) atoms to form edge-sharing NaO6 octahedra. Ag(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. O(1) is bonded to three equivalent Na(1) and two equivalent Ag(1) atoms to form a mixture of distorted corner and edge-sharing ONa3Ag2 square pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_NaAgO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.513
_cell_length_b   3.513
_cell_length_c   6.336
_cell_angle_alpha   61.779
_cell_angle_beta   118.221
_cell_angle_gamma   129.673
_symmetry_Int_Tables_number   1
_cell_volume   51.303
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.500  0.500  0.500  1.0
  Ag  Ag1  1  0.000  0.000  0.000  1.0
  O  O2  1  0.328  0.672  0.756  1.0
  O  O3  1  0.672  0.328  0.244  1.0
[/CIF]
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