The compound described by Sm2Ni2In crystallizes in the tetragonal P4/mbm space group. Sm(1) is bonded in a 10-coordinate geometry to six equivalent Ni(1) and four equivalent In(1) atoms. Ni(1) is bonded in a 9-coordinate geometry to six equivalent Sm(1), one Ni(1), and two equivalent In(1) atoms. In(1) is bonded to eight equivalent Sm(1) and four equivalent Ni(1) atoms to form a mixture of face and corner-sharing InSm8Ni4 cuboctahedra. is represented by the CIF file [CIF]
data_Sm2InNi2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.706
_cell_length_b   7.409
_cell_length_c   7.409
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   203.398
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sm  Sm0  1  0.500  0.177  0.677  1.0
  Sm  Sm1  1  0.500  0.823  0.323  1.0
  Sm  Sm2  1  0.500  0.323  0.177  1.0
  Sm  Sm3  1  0.500  0.677  0.823  1.0
  In  In4  1  0.000  0.500  0.500  1.0
  In  In5  1  0.000  0.000  0.000  1.0
  Ni  Ni6  1  0.000  0.618  0.118  1.0
  Ni  Ni7  1  0.000  0.382  0.882  1.0
  Ni  Ni8  1  0.000  0.882  0.618  1.0
  Ni  Ni9  1  0.000  0.118  0.382  1.0
[/CIF]
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The compound described by Sm2Ni2In crystallizes in the tetragonal P4/mbm space group. Sm(1) is bonded in a 10-coordinate geometry to six equivalent Ni(1) and four equivalent In(1) atoms. Ni(1) is bonded in a 9-coordinate geometry to six equivalent Sm(1), one Ni(1), and two equivalent In(1) atoms. In(1) is bonded to eight equivalent Sm(1) and four equivalent Ni(1) atoms to form a mixture of face and corner-sharing InSm8Ni4 cuboctahedra. is represented by the CIF file [CIF]
data_Sm2InNi2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.706
_cell_length_b   7.409
_cell_length_c   7.409
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   203.398
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sm  Sm0  1  0.500  0.177  0.677  1.0
  Sm  Sm1  1  0.500  0.823  0.323  1.0
  Sm  Sm2  1  0.500  0.323  0.177  1.0
  Sm  Sm3  1  0.500  0.677  0.823  1.0
  In  In4  1  0.000  0.500  0.500  1.0
  In  In5  1  0.000  0.000  0.000  1.0
  Ni  Ni6  1  0.000  0.618  0.118  1.0
  Ni  Ni7  1  0.000  0.382  0.882  1.0
  Ni  Ni8  1  0.000  0.882  0.618  1.0
  Ni  Ni9  1  0.000  0.118  0.382  1.0
[/CIF]
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