The compound described by RbAuS crystallizes in the orthorhombic Cmcm space group. Rb(1) is bonded in a 11-coordinate geometry to six equivalent Au(1) and five equivalent S(1) atoms. Au(1) is bonded in a 4-coordinate geometry to six equivalent Rb(1) and two equivalent S(1) atoms. S(1) is bonded to five equivalent Rb(1) and two equivalent Au(1) atoms to form a mixture of distorted corner and edge-sharing SRb5Au2 pentagonal bipyramids. is represented by the CIF file [CIF]
data_RbAuS
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.262
_cell_length_b   5.262
_cell_length_c   6.711
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   101.740
_symmetry_Int_Tables_number   1
_cell_volume   181.943
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.624  0.376  0.250  1.0
  Rb  Rb1  1  0.376  0.624  0.750  1.0
  Au  Au2  1  0.000  0.000  0.000  1.0
  Au  Au3  1  0.000  0.000  0.500  1.0
  S  S4  1  0.196  0.804  0.250  1.0
  S  S5  1  0.804  0.196  0.750  1.0
[/CIF]
.
The compound described by RbAuS crystallizes in the orthorhombic Cmcm space group. Rb(1) is bonded in a 11-coordinate geometry to six equivalent Au(1) and five equivalent S(1) atoms. Au(1) is bonded in a 4-coordinate geometry to six equivalent Rb(1) and two equivalent S(1) atoms. S(1) is bonded to five equivalent Rb(1) and two equivalent Au(1) atoms to form a mixture of distorted corner and edge-sharing SRb5Au2 pentagonal bipyramids. is represented by the CIF file [CIF]
data_RbAuS
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.262
_cell_length_b   5.262
_cell_length_c   6.711
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   101.740
_symmetry_Int_Tables_number   1
_cell_volume   181.943
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.624  0.376  0.250  1.0
  Rb  Rb1  1  0.376  0.624  0.750  1.0
  Au  Au2  1  0.000  0.000  0.000  1.0
  Au  Au3  1  0.000  0.000  0.500  1.0
  S  S4  1  0.196  0.804  0.250  1.0
  S  S5  1  0.804  0.196  0.750  1.0
[/CIF]
.