The material described by Pb2MnWO6 is Pb(Zr_(1-x)Ti_x)O3-derived structured and crystallizes in the orthorhombic Pna2_1 space group. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share corners with six equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-20°. Mn(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form MnO6 octahedra that share corners with six equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-20°. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(4), and one O(5) atom. In the second Pb site, Pb(2) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(4), and one O(5) atom. There are six inequivalent O sites. In the first O site, O(5) is bonded in a 4-coordinate geometry to one W(1), one Mn(1), one Pb(1), and one Pb(2) atom. In the second O site, O(6) is bonded in a linear geometry to one W(1) and one Mn(1) atom. In the third O site, O(1) is bonded in a distorted see-saw-like geometry to one W(1), one Mn(1), one Pb(1), and one Pb(2) atom. In the fourth O site, O(2) is bonded in a distorted see-saw-like geometry to one W(1), one Mn(1), one Pb(1), and one Pb(2) atom. In the fifth O site, O(3) is bonded in a linear geometry to one W(1) and one Mn(1) atom. In the sixth O site, O(4) is bonded in a distorted rectangular see-saw-like geometry to one W(1), one Mn(1), one Pb(1), and one Pb(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_MnPb2WO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.907
_cell_length_b   8.176
_cell_length_c   11.848
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   572.204
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.259  0.120  0.118  1.0
  Mn  Mn1  1  0.741  0.620  0.882  1.0
  Mn  Mn2  1  0.759  0.620  0.382  1.0
  Mn  Mn3  1  0.241  0.120  0.618  1.0
  Pb  Pb4  1  0.793  0.377  0.148  1.0
  Pb  Pb5  1  0.207  0.877  0.852  1.0
  Pb  Pb6  1  0.293  0.877  0.352  1.0
  Pb  Pb7  1  0.707  0.377  0.648  1.0
  Pb  Pb8  1  0.797  0.865  0.145  1.0
  Pb  Pb9  1  0.203  0.365  0.855  1.0
  Pb  Pb10  1  0.297  0.365  0.355  1.0
  Pb  Pb11  1  0.703  0.865  0.645  1.0
  W  W12  1  0.251  0.618  0.118  1.0
  W  W13  1  0.749  0.118  0.882  1.0
  W  W14  1  0.751  0.118  0.382  1.0
  W  W15  1  0.249  0.618  0.618  1.0
  O  O16  1  0.966  0.624  0.230  1.0
  O  O17  1  0.034  0.124  0.770  1.0
  O  O18  1  0.466  0.124  0.270  1.0
  O  O19  1  0.534  0.624  0.730  1.0
  O  O20  1  0.445  0.612  0.254  1.0
  O  O21  1  0.555  0.112  0.746  1.0
  O  O22  1  0.945  0.112  0.246  1.0
  O  O23  1  0.055  0.612  0.754  1.0
  O  O24  1  0.492  0.613  0.017  1.0
  O  O25  1  0.508  0.113  0.983  1.0
  O  O26  1  0.992  0.113  0.483  1.0
  O  O27  1  0.008  0.613  0.517  1.0
  O  O28  1  0.231  0.857  0.139  1.0
  O  O29  1  0.769  0.357  0.861  1.0
  O  O30  1  0.731  0.357  0.361  1.0
  O  O31  1  0.269  0.857  0.639  1.0
  O  O32  1  0.211  0.381  0.139  1.0
  O  O33  1  0.789  0.881  0.861  1.0
  O  O34  1  0.711  0.881  0.361  1.0
  O  O35  1  0.289  0.381  0.639  1.0
  O  O36  1  0.022  0.623  0.003  1.0
  O  O37  1  0.978  0.123  0.997  1.0
  O  O38  1  0.522  0.123  0.497  1.0
  O  O39  1  0.478  0.623  0.503  1.0
[/CIF]
.
The material described by Pb2MnWO6 is Pb(Zr_(1-x)Ti_x)O3-derived structured and crystallizes in the orthorhombic Pna2_1 space group. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share corners with six equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-20°. Mn(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form MnO6 octahedra that share corners with six equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-20°. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(4), and one O(5) atom. In the second Pb site, Pb(2) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(4), and one O(5) atom. There are six inequivalent O sites. In the first O site, O(5) is bonded in a 4-coordinate geometry to one W(1), one Mn(1), one Pb(1), and one Pb(2) atom. In the second O site, O(6) is bonded in a linear geometry to one W(1) and one Mn(1) atom. In the third O site, O(1) is bonded in a distorted see-saw-like geometry to one W(1), one Mn(1), one Pb(1), and one Pb(2) atom. In the fourth O site, O(2) is bonded in a distorted see-saw-like geometry to one W(1), one Mn(1), one Pb(1), and one Pb(2) atom. In the fifth O site, O(3) is bonded in a linear geometry to one W(1) and one Mn(1) atom. In the sixth O site, O(4) is bonded in a distorted rectangular see-saw-like geometry to one W(1), one Mn(1), one Pb(1), and one Pb(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_MnPb2WO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.907
_cell_length_b   8.176
_cell_length_c   11.848
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   572.204
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.259  0.120  0.118  1.0
  Mn  Mn1  1  0.741  0.620  0.882  1.0
  Mn  Mn2  1  0.759  0.620  0.382  1.0
  Mn  Mn3  1  0.241  0.120  0.618  1.0
  Pb  Pb4  1  0.793  0.377  0.148  1.0
  Pb  Pb5  1  0.207  0.877  0.852  1.0
  Pb  Pb6  1  0.293  0.877  0.352  1.0
  Pb  Pb7  1  0.707  0.377  0.648  1.0
  Pb  Pb8  1  0.797  0.865  0.145  1.0
  Pb  Pb9  1  0.203  0.365  0.855  1.0
  Pb  Pb10  1  0.297  0.365  0.355  1.0
  Pb  Pb11  1  0.703  0.865  0.645  1.0
  W  W12  1  0.251  0.618  0.118  1.0
  W  W13  1  0.749  0.118  0.882  1.0
  W  W14  1  0.751  0.118  0.382  1.0
  W  W15  1  0.249  0.618  0.618  1.0
  O  O16  1  0.966  0.624  0.230  1.0
  O  O17  1  0.034  0.124  0.770  1.0
  O  O18  1  0.466  0.124  0.270  1.0
  O  O19  1  0.534  0.624  0.730  1.0
  O  O20  1  0.445  0.612  0.254  1.0
  O  O21  1  0.555  0.112  0.746  1.0
  O  O22  1  0.945  0.112  0.246  1.0
  O  O23  1  0.055  0.612  0.754  1.0
  O  O24  1  0.492  0.613  0.017  1.0
  O  O25  1  0.508  0.113  0.983  1.0
  O  O26  1  0.992  0.113  0.483  1.0
  O  O27  1  0.008  0.613  0.517  1.0
  O  O28  1  0.231  0.857  0.139  1.0
  O  O29  1  0.769  0.357  0.861  1.0
  O  O30  1  0.731  0.357  0.361  1.0
  O  O31  1  0.269  0.857  0.639  1.0
  O  O32  1  0.211  0.381  0.139  1.0
  O  O33  1  0.789  0.881  0.861  1.0
  O  O34  1  0.711  0.881  0.361  1.0
  O  O35  1  0.289  0.381  0.639  1.0
  O  O36  1  0.022  0.623  0.003  1.0
  O  O37  1  0.978  0.123  0.997  1.0
  O  O38  1  0.522  0.123  0.497  1.0
  O  O39  1  0.478  0.623  0.503  1.0
[/CIF]
.