The material described by RbClO4 crystallizes in the triclinic P1 space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 12-coordinate geometry to one O(1), one O(2), one O(3), one O(4), two equivalent O(5), two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms. In the second Rb site, Rb(2) is bonded in a 12-coordinate geometry to one O(5), one O(6), one O(7), one O(8), two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted L-shaped geometry to one Rb(1), two equivalent Rb(2), and one Cl(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Rb(1), two equivalent Rb(2), and one Cl(1) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Rb(1), two equivalent Rb(2), and one Cl(1) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to one Rb(1), two equivalent Rb(2), and one Cl(1) atom. In the fifth O site, O(5) is bonded in a distorted L-shaped geometry to one Rb(2), two equivalent Rb(1), and one Cl(2) atom. In the sixth O site, O(6) is bonded in a distorted L-shaped geometry to one Rb(2), two equivalent Rb(1), and one Cl(2) atom. In the seventh O site, O(7) is bonded in a distorted L-shaped geometry to one Rb(2), two equivalent Rb(1), and one Cl(2) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one Rb(2), two equivalent Rb(1), and one Cl(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. In the second Cl site, Cl(2) is bonded in a tetrahedral geometry to one O(5), one O(6), one O(7), and one O(8) atom. is represented by the CIF card [CIF]
data_RbClO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.022
_cell_length_b   5.038
_cell_length_c   5.560
_cell_angle_alpha   90.116
_cell_angle_beta   90.031
_cell_angle_gamma   90.030
_symmetry_Int_Tables_number   1
_cell_volume   140.671
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.003  0.000  0.499  1.0
  Rb  Rb1  1  0.492  0.507  0.001  1.0
  Cl  Cl2  1  0.998  0.002  0.998  1.0
  Cl  Cl3  1  0.502  0.501  0.500  1.0
  O  O4  1  0.746  0.002  0.868  1.0
  O  O5  1  0.251  0.002  0.871  1.0
  O  O6  1  0.998  0.751  0.127  1.0
  O  O7  1  0.998  0.253  0.129  1.0
  O  O8  1  0.504  0.251  0.367  1.0
  O  O9  1  0.248  0.498  0.626  1.0
  O  O10  1  0.751  0.500  0.634  1.0
  O  O11  1  0.503  0.754  0.375  1.0
[/CIF]
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The material described by RbClO4 crystallizes in the triclinic P1 space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 12-coordinate geometry to one O(1), one O(2), one O(3), one O(4), two equivalent O(5), two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms. In the second Rb site, Rb(2) is bonded in a 12-coordinate geometry to one O(5), one O(6), one O(7), one O(8), two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted L-shaped geometry to one Rb(1), two equivalent Rb(2), and one Cl(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Rb(1), two equivalent Rb(2), and one Cl(1) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Rb(1), two equivalent Rb(2), and one Cl(1) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to one Rb(1), two equivalent Rb(2), and one Cl(1) atom. In the fifth O site, O(5) is bonded in a distorted L-shaped geometry to one Rb(2), two equivalent Rb(1), and one Cl(2) atom. In the sixth O site, O(6) is bonded in a distorted L-shaped geometry to one Rb(2), two equivalent Rb(1), and one Cl(2) atom. In the seventh O site, O(7) is bonded in a distorted L-shaped geometry to one Rb(2), two equivalent Rb(1), and one Cl(2) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one Rb(2), two equivalent Rb(1), and one Cl(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. In the second Cl site, Cl(2) is bonded in a tetrahedral geometry to one O(5), one O(6), one O(7), and one O(8) atom. is represented by the CIF card [CIF]
data_RbClO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.022
_cell_length_b   5.038
_cell_length_c   5.560
_cell_angle_alpha   90.116
_cell_angle_beta   90.031
_cell_angle_gamma   90.030
_symmetry_Int_Tables_number   1
_cell_volume   140.671
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.003  0.000  0.499  1.0
  Rb  Rb1  1  0.492  0.507  0.001  1.0
  Cl  Cl2  1  0.998  0.002  0.998  1.0
  Cl  Cl3  1  0.502  0.501  0.500  1.0
  O  O4  1  0.746  0.002  0.868  1.0
  O  O5  1  0.251  0.002  0.871  1.0
  O  O6  1  0.998  0.751  0.127  1.0
  O  O7  1  0.998  0.253  0.129  1.0
  O  O8  1  0.504  0.251  0.367  1.0
  O  O9  1  0.248  0.498  0.626  1.0
  O  O10  1  0.751  0.500  0.634  1.0
  O  O11  1  0.503  0.754  0.375  1.0
[/CIF]
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