The crystal structure described by TiF6(CN3H6)2 is Indium-derived structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of four guanidinium molecules and two TiF6 clusters. In each TiF6 cluster, Ti(1) is bonded in an octahedral geometry to one F(1), one F(2), two equivalent F(3), and two equivalent F(4) atoms. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Ti(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Ti(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Ti(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Ti(1) atom. is represented by the CIF card [CIF]
data_TiH12C2(NF)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.479
_cell_length_b   7.479
_cell_length_c   6.310
_cell_angle_alpha   69.128
_cell_angle_beta   69.128
_cell_angle_gamma   59.711
_symmetry_Int_Tables_number   1
_cell_volume   277.892
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.934  0.934  0.581  1.0
  H  H1  1  0.949  0.627  0.308  1.0
  H  H2  1  0.627  0.949  0.308  1.0
  H  H3  1  0.941  0.393  0.323  1.0
  H  H4  1  0.393  0.941  0.323  1.0
  H  H5  1  0.629  0.394  0.331  1.0
  H  H6  1  0.394  0.629  0.331  1.0
  H  H7  1  0.234  0.468  0.863  1.0
  H  H8  1  0.468  0.234  0.863  1.0
  H  H9  1  0.918  0.469  0.856  1.0
  H  H10  1  0.469  0.918  0.856  1.0
  H  H11  1  0.924  0.234  0.850  1.0
  H  H12  1  0.234  0.924  0.850  1.0
  C  C13  1  0.207  0.207  0.864  1.0
  C  C14  1  0.659  0.659  0.305  1.0
  N  N15  1  0.868  0.555  0.298  1.0
  N  N16  1  0.555  0.868  0.298  1.0
  N  N17  1  0.555  0.555  0.310  1.0
  N  N18  1  0.307  0.307  0.877  1.0
  N  N19  1  1.000  0.310  0.862  1.0
  N  N20  1  0.310  1.000  0.862  1.0
  F  F21  1  0.775  0.775  0.756  1.0
  F  F22  1  0.092  0.092  0.403  1.0
  F  F23  1  0.738  0.100  0.383  1.0
  F  F24  1  0.100  0.738  0.383  1.0
  F  F25  1  0.772  0.129  0.780  1.0
  F  F26  1  0.129  0.772  0.780  1.0
[/CIF]
.
The crystal structure described by TiF6(CN3H6)2 is Indium-derived structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of four guanidinium molecules and two TiF6 clusters. In each TiF6 cluster, Ti(1) is bonded in an octahedral geometry to one F(1), one F(2), two equivalent F(3), and two equivalent F(4) atoms. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Ti(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Ti(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Ti(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Ti(1) atom. is represented by the CIF card [CIF]
data_TiH12C2(NF)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.479
_cell_length_b   7.479
_cell_length_c   6.310
_cell_angle_alpha   69.128
_cell_angle_beta   69.128
_cell_angle_gamma   59.711
_symmetry_Int_Tables_number   1
_cell_volume   277.892
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.934  0.934  0.581  1.0
  H  H1  1  0.949  0.627  0.308  1.0
  H  H2  1  0.627  0.949  0.308  1.0
  H  H3  1  0.941  0.393  0.323  1.0
  H  H4  1  0.393  0.941  0.323  1.0
  H  H5  1  0.629  0.394  0.331  1.0
  H  H6  1  0.394  0.629  0.331  1.0
  H  H7  1  0.234  0.468  0.863  1.0
  H  H8  1  0.468  0.234  0.863  1.0
  H  H9  1  0.918  0.469  0.856  1.0
  H  H10  1  0.469  0.918  0.856  1.0
  H  H11  1  0.924  0.234  0.850  1.0
  H  H12  1  0.234  0.924  0.850  1.0
  C  C13  1  0.207  0.207  0.864  1.0
  C  C14  1  0.659  0.659  0.305  1.0
  N  N15  1  0.868  0.555  0.298  1.0
  N  N16  1  0.555  0.868  0.298  1.0
  N  N17  1  0.555  0.555  0.310  1.0
  N  N18  1  0.307  0.307  0.877  1.0
  N  N19  1  1.000  0.310  0.862  1.0
  N  N20  1  0.310  1.000  0.862  1.0
  F  F21  1  0.775  0.775  0.756  1.0
  F  F22  1  0.092  0.092  0.403  1.0
  F  F23  1  0.738  0.100  0.383  1.0
  F  F24  1  0.100  0.738  0.383  1.0
  F  F25  1  0.772  0.129  0.780  1.0
  F  F26  1  0.129  0.772  0.780  1.0
[/CIF]
.