The material structure described by Co3Cu3(TeO8)2 is beta Vanadium nitride-derived structured and crystallizes in the triclinic P1 space group. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form CoO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  an edgeedge with one Te(1)O6 octahedra, edges with two equivalent Cu(1)O6 octahedra, and edges with two equivalent Cu(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-51°. In the second Co site, Co(2) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form CoO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, and edges with two equivalent Cu(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-52°. In the third Co site, Co(3) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form CoO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Cu(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-52°. There are three inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form CuO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  an edgeedge with one Te(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Cu(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-54°. In the second Cu site, Cu(2) is bonded to one O(16), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form distorted CuO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  an edgeedge with one Te(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Cu(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-55°. In the third Cu site, Cu(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form CuO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-55°. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form TeO6 octahedra that share corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, corners with two equivalent Cu(3)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Cu(1)O6 octahedra, and  an edgeedge with one Cu(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-55°. In the second Te site, Te(2) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form TeO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Cu(1)O6 octahedra, corners with two equivalent Cu(2)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, and  an edgeedge with one Cu(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-55°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Co(2), one Cu(3), and one Te(1) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Cu(1), one Cu(2), and one Te(1) atom. In the third O site, O(3) is bonded in a trigonal non-coplanar geometry to one Co(1), one Cu(1), and one Cu(2) atom. In the fourth O site, O(4) is bonded in a trigonal non-coplanar geometry to one Co(1), one Cu(1), and one Cu(2) atom. In the fifth O site, O(5) is bonded in a trigonal non-coplanar geometry to one Co(2), one Co(3), and one Cu(3) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one Co(3), one Cu(3), and one Te(1) atom. In the seventh O site, O(7) is bonded in a distorted T-shaped geometry to one Co(1), one Cu(1), and one Te(1) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Co(1), one Cu(2), and one Te(1) atom. In the ninth O site, O(9) is bonded in a trigonal planar geometry to one Cu(1), one Cu(2), and one Te(2) atom. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one Co(2), one Co(3), and one Te(1) atom. In the eleventh O site, O(11) is bonded in a distorted T-shaped geometry to one Co(2), one Cu(3), and one Te(2) atom. In the twelfth O site, O(12) is bonded in a distorted trigonal non-coplanar geometry to one Co(3), one Cu(3), and one Te(2) atom. In the thirteenth O site, O(13) is bonded in a distorted trigonal non-coplanar geometry to one Co(2), one Co(3), and one Cu(3) atom. In the fourteenth O site, O(14) is bonded in a distorted trigonal planar geometry to one Co(1), one Cu(1), and one Te(2) atom. In the fifteenth O site, O(15) is bonded in a distorted T-shaped geometry to one Co(2), one Co(3), and one Te(2) atom. In the sixteenth O site, O(16) is bonded in a distorted T-shaped geometry to one Co(1), one Cu(2), and one Te(2) atom. is represented by the CIF file [CIF]
data_Co3Cu3(TeO8)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.737
_cell_length_b   5.826
_cell_length_c   9.204
_cell_angle_alpha   92.665
_cell_angle_beta   90.047
_cell_angle_gamma   118.985
_symmetry_Int_Tables_number   1
_cell_volume   268.679
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.830  0.658  0.786  1.0
  Co  Co1  1  0.660  0.831  0.287  1.0
  Co  Co2  1  0.166  0.826  0.290  1.0
  Cu  Cu3  1  0.826  0.160  0.788  1.0
  Cu  Cu4  1  0.329  0.163  0.788  1.0
  Cu  Cu5  1  0.167  0.333  0.287  1.0
  Te  Te6  1  0.676  0.349  0.512  1.0
  Te  Te7  1  0.335  0.659  0.011  1.0
  O  O8  1  0.829  0.163  0.409  1.0
  O  O9  1  0.513  0.046  0.651  1.0
  O  O10  1  0.668  0.348  0.879  1.0
  O  O11  1  0.991  0.977  0.696  1.0
  O  O12  1  0.991  0.985  0.195  1.0
  O  O13  1  0.327  0.167  0.403  1.0
  O  O14  1  0.978  0.504  0.656  1.0
  O  O15  1  0.541  0.526  0.647  1.0
  O  O16  1  0.157  0.310  0.909  1.0
  O  O17  1  0.842  0.677  0.398  1.0
  O  O18  1  0.501  0.528  0.156  1.0
  O  O19  1  0.037  0.518  0.160  1.0
  O  O20  1  0.341  0.676  0.385  1.0
  O  O21  1  0.661  0.823  0.908  1.0
  O  O22  1  0.480  0.960  0.168  1.0
  O  O23  1  0.154  0.812  0.915  1.0
[/CIF]
.
The material structure described by Co3Cu3(TeO8)2 is beta Vanadium nitride-derived structured and crystallizes in the triclinic P1 space group. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form CoO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  an edgeedge with one Te(1)O6 octahedra, edges with two equivalent Cu(1)O6 octahedra, and edges with two equivalent Cu(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-51°. In the second Co site, Co(2) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form CoO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, and edges with two equivalent Cu(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-52°. In the third Co site, Co(3) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form CoO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Cu(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-52°. There are three inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form CuO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  an edgeedge with one Te(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Cu(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-54°. In the second Cu site, Cu(2) is bonded to one O(16), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form distorted CuO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  an edgeedge with one Te(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Cu(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-55°. In the third Cu site, Cu(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form CuO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-55°. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form TeO6 octahedra that share corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, corners with two equivalent Cu(3)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Cu(1)O6 octahedra, and  an edgeedge with one Cu(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-55°. In the second Te site, Te(2) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form TeO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Cu(1)O6 octahedra, corners with two equivalent Cu(2)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, and  an edgeedge with one Cu(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-55°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Co(2), one Cu(3), and one Te(1) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Cu(1), one Cu(2), and one Te(1) atom. In the third O site, O(3) is bonded in a trigonal non-coplanar geometry to one Co(1), one Cu(1), and one Cu(2) atom. In the fourth O site, O(4) is bonded in a trigonal non-coplanar geometry to one Co(1), one Cu(1), and one Cu(2) atom. In the fifth O site, O(5) is bonded in a trigonal non-coplanar geometry to one Co(2), one Co(3), and one Cu(3) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one Co(3), one Cu(3), and one Te(1) atom. In the seventh O site, O(7) is bonded in a distorted T-shaped geometry to one Co(1), one Cu(1), and one Te(1) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Co(1), one Cu(2), and one Te(1) atom. In the ninth O site, O(9) is bonded in a trigonal planar geometry to one Cu(1), one Cu(2), and one Te(2) atom. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one Co(2), one Co(3), and one Te(1) atom. In the eleventh O site, O(11) is bonded in a distorted T-shaped geometry to one Co(2), one Cu(3), and one Te(2) atom. In the twelfth O site, O(12) is bonded in a distorted trigonal non-coplanar geometry to one Co(3), one Cu(3), and one Te(2) atom. In the thirteenth O site, O(13) is bonded in a distorted trigonal non-coplanar geometry to one Co(2), one Co(3), and one Cu(3) atom. In the fourteenth O site, O(14) is bonded in a distorted trigonal planar geometry to one Co(1), one Cu(1), and one Te(2) atom. In the fifteenth O site, O(15) is bonded in a distorted T-shaped geometry to one Co(2), one Co(3), and one Te(2) atom. In the sixteenth O site, O(16) is bonded in a distorted T-shaped geometry to one Co(1), one Cu(2), and one Te(2) atom. is represented by the CIF file [CIF]
data_Co3Cu3(TeO8)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.737
_cell_length_b   5.826
_cell_length_c   9.204
_cell_angle_alpha   92.665
_cell_angle_beta   90.047
_cell_angle_gamma   118.985
_symmetry_Int_Tables_number   1
_cell_volume   268.679
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.830  0.658  0.786  1.0
  Co  Co1  1  0.660  0.831  0.287  1.0
  Co  Co2  1  0.166  0.826  0.290  1.0
  Cu  Cu3  1  0.826  0.160  0.788  1.0
  Cu  Cu4  1  0.329  0.163  0.788  1.0
  Cu  Cu5  1  0.167  0.333  0.287  1.0
  Te  Te6  1  0.676  0.349  0.512  1.0
  Te  Te7  1  0.335  0.659  0.011  1.0
  O  O8  1  0.829  0.163  0.409  1.0
  O  O9  1  0.513  0.046  0.651  1.0
  O  O10  1  0.668  0.348  0.879  1.0
  O  O11  1  0.991  0.977  0.696  1.0
  O  O12  1  0.991  0.985  0.195  1.0
  O  O13  1  0.327  0.167  0.403  1.0
  O  O14  1  0.978  0.504  0.656  1.0
  O  O15  1  0.541  0.526  0.647  1.0
  O  O16  1  0.157  0.310  0.909  1.0
  O  O17  1  0.842  0.677  0.398  1.0
  O  O18  1  0.501  0.528  0.156  1.0
  O  O19  1  0.037  0.518  0.160  1.0
  O  O20  1  0.341  0.676  0.385  1.0
  O  O21  1  0.661  0.823  0.908  1.0
  O  O22  1  0.480  0.960  0.168  1.0
  O  O23  1  0.154  0.812  0.915  1.0
[/CIF]
.