The material described by DyCoGa5 crystallizes in the tetragonal P4/mmm space group. Dy(1) is bonded to four equivalent Ga(1) and eight equivalent Ga(2) atoms to form DyGa12 cuboctahedra that share corners with four equivalent Dy(1)Ga12 cuboctahedra, faces with four equivalent Dy(1)Ga12 cuboctahedra, and faces with four equivalent Ga(1)Dy4Ga8 cuboctahedra. Co(1) is bonded in a body-centered cubic geometry to eight equivalent Ga(2) atoms. There are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded to four equivalent Dy(1) and eight equivalent Ga(2) atoms to form distorted GaDy4Ga8 cuboctahedra that share corners with four equivalent Ga(1)Dy4Ga8 cuboctahedra, faces with four equivalent Dy(1)Ga12 cuboctahedra, and faces with four equivalent Ga(1)Dy4Ga8 cuboctahedra. In the second Ga site, Ga(2) is bonded in a 11-coordinate geometry to two equivalent Dy(1), two equivalent Co(1), two equivalent Ga(1), and five equivalent Ga(2) atoms. is represented by the CIF file [CIF]
data_DyGa5Co
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.172
_cell_length_b   4.172
_cell_length_c   6.756
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   117.612
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  1  0.000  0.000  0.000  1.0
  Ga  Ga1  1  0.500  0.500  0.000  1.0
  Ga  Ga2  1  0.500  0.000  0.688  1.0
  Ga  Ga3  1  0.000  0.500  0.688  1.0
  Ga  Ga4  1  0.500  0.000  0.312  1.0
  Ga  Ga5  1  0.000  0.500  0.312  1.0
  Co  Co6  1  0.000  0.000  0.500  1.0
[/CIF]
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The material described by DyCoGa5 crystallizes in the tetragonal P4/mmm space group. Dy(1) is bonded to four equivalent Ga(1) and eight equivalent Ga(2) atoms to form DyGa12 cuboctahedra that share corners with four equivalent Dy(1)Ga12 cuboctahedra, faces with four equivalent Dy(1)Ga12 cuboctahedra, and faces with four equivalent Ga(1)Dy4Ga8 cuboctahedra. Co(1) is bonded in a body-centered cubic geometry to eight equivalent Ga(2) atoms. There are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded to four equivalent Dy(1) and eight equivalent Ga(2) atoms to form distorted GaDy4Ga8 cuboctahedra that share corners with four equivalent Ga(1)Dy4Ga8 cuboctahedra, faces with four equivalent Dy(1)Ga12 cuboctahedra, and faces with four equivalent Ga(1)Dy4Ga8 cuboctahedra. In the second Ga site, Ga(2) is bonded in a 11-coordinate geometry to two equivalent Dy(1), two equivalent Co(1), two equivalent Ga(1), and five equivalent Ga(2) atoms. is represented by the CIF file [CIF]
data_DyGa5Co
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.172
_cell_length_b   4.172
_cell_length_c   6.756
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   117.612
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  1  0.000  0.000  0.000  1.0
  Ga  Ga1  1  0.500  0.500  0.000  1.0
  Ga  Ga2  1  0.500  0.000  0.688  1.0
  Ga  Ga3  1  0.000  0.500  0.688  1.0
  Ga  Ga4  1  0.500  0.000  0.312  1.0
  Ga  Ga5  1  0.000  0.500  0.312  1.0
  Co  Co6  1  0.000  0.000  0.500  1.0
[/CIF]
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