The crystal structure described by Li3SbO3 crystallizes in the cubic P2_13 space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded in a trigonal planar geometry to three equivalent O(1) atoms. In the second Li site, Li(2) is bonded in a distorted trigonal planar geometry to three equivalent O(1) atoms. In the third Li site, Li(3) is bonded in a trigonal non-coplanar geometry to three equivalent O(1) atoms. Sb(1) is bonded in a 3-coordinate geometry to three equivalent O(1) atoms. O(1) is bonded to one Li(1), one Li(2), one Li(3), and one Sb(1) atom to form corner-sharing OLi3Sb tetrahedra. is represented by the CIF file [CIF]
data_Li3SbO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.163
_cell_length_b   7.163
_cell_length_c   7.163
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   367.582
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.969  0.969  0.969  1.0
  Li  Li1  1  0.261  0.239  0.761  1.0
  Li  Li2  1  0.241  0.741  0.759  1.0
  Li  Li3  1  0.259  0.259  0.259  1.0
  Li  Li4  1  0.239  0.761  0.261  1.0
  Li  Li5  1  0.531  0.031  0.469  1.0
  Li  Li6  1  0.469  0.531  0.031  1.0
  Li  Li7  1  0.761  0.261  0.239  1.0
  Li  Li8  1  0.741  0.759  0.241  1.0
  Li  Li9  1  0.759  0.241  0.741  1.0
  Li  Li10  1  0.739  0.739  0.739  1.0
  Li  Li11  1  0.031  0.469  0.531  1.0
  Sb  Sb12  1  0.023  0.977  0.477  1.0
  Sb  Sb13  1  0.477  0.023  0.977  1.0
  Sb  Sb14  1  0.523  0.523  0.523  1.0
  Sb  Sb15  1  0.977  0.477  0.023  1.0
  O  O16  1  0.994  0.241  0.401  1.0
  O  O17  1  0.099  0.006  0.741  1.0
  O  O18  1  0.241  0.401  0.994  1.0
  O  O19  1  0.259  0.599  0.494  1.0
  O  O20  1  0.401  0.994  0.241  1.0
  O  O21  1  0.506  0.759  0.901  1.0
  O  O22  1  0.494  0.259  0.599  1.0
  O  O23  1  0.599  0.494  0.259  1.0
  O  O24  1  0.741  0.099  0.006  1.0
  O  O25  1  0.759  0.901  0.506  1.0
  O  O26  1  0.901  0.506  0.759  1.0
  O  O27  1  0.006  0.741  0.099  1.0
[/CIF]
.
The crystal structure described by Li3SbO3 crystallizes in the cubic P2_13 space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded in a trigonal planar geometry to three equivalent O(1) atoms. In the second Li site, Li(2) is bonded in a distorted trigonal planar geometry to three equivalent O(1) atoms. In the third Li site, Li(3) is bonded in a trigonal non-coplanar geometry to three equivalent O(1) atoms. Sb(1) is bonded in a 3-coordinate geometry to three equivalent O(1) atoms. O(1) is bonded to one Li(1), one Li(2), one Li(3), and one Sb(1) atom to form corner-sharing OLi3Sb tetrahedra. is represented by the CIF file [CIF]
data_Li3SbO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.163
_cell_length_b   7.163
_cell_length_c   7.163
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   367.582
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.969  0.969  0.969  1.0
  Li  Li1  1  0.261  0.239  0.761  1.0
  Li  Li2  1  0.241  0.741  0.759  1.0
  Li  Li3  1  0.259  0.259  0.259  1.0
  Li  Li4  1  0.239  0.761  0.261  1.0
  Li  Li5  1  0.531  0.031  0.469  1.0
  Li  Li6  1  0.469  0.531  0.031  1.0
  Li  Li7  1  0.761  0.261  0.239  1.0
  Li  Li8  1  0.741  0.759  0.241  1.0
  Li  Li9  1  0.759  0.241  0.741  1.0
  Li  Li10  1  0.739  0.739  0.739  1.0
  Li  Li11  1  0.031  0.469  0.531  1.0
  Sb  Sb12  1  0.023  0.977  0.477  1.0
  Sb  Sb13  1  0.477  0.023  0.977  1.0
  Sb  Sb14  1  0.523  0.523  0.523  1.0
  Sb  Sb15  1  0.977  0.477  0.023  1.0
  O  O16  1  0.994  0.241  0.401  1.0
  O  O17  1  0.099  0.006  0.741  1.0
  O  O18  1  0.241  0.401  0.994  1.0
  O  O19  1  0.259  0.599  0.494  1.0
  O  O20  1  0.401  0.994  0.241  1.0
  O  O21  1  0.506  0.759  0.901  1.0
  O  O22  1  0.494  0.259  0.599  1.0
  O  O23  1  0.599  0.494  0.259  1.0
  O  O24  1  0.741  0.099  0.006  1.0
  O  O25  1  0.759  0.901  0.506  1.0
  O  O26  1  0.901  0.506  0.759  1.0
  O  O27  1  0.006  0.741  0.099  1.0
[/CIF]
.