The crystal structure described by MgNH8O3Br4N2H7NH3H2O is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one ammonia molecule, one azanium;azane molecule, one water molecule, and one MgNH8O3Br4 cluster. In the MgNH8O3Br4 cluster, Mg(1) is bonded in a tetrahedral geometry to one O(3), one Br(2), one Br(3), and one Br(4) atom. N(3) is bonded in a distorted water-like geometry to one H(10), one H(2), and one H(6) atom. There are eight inequivalent H sites. In the first H site, H(2) is bonded in a linear geometry to one N(3) and one O(3) atom. In the second H site, H(6) is bonded in a single-bond geometry to one N(3) atom. In the third H site, H(10) is bonded in a single-bond geometry to one N(3) atom. In the fourth H site, H(14) is bonded in a single-bond geometry to one O(2) atom. In the fifth H site, H(16) is bonded in a single-bond geometry to one O(4) and one Br(1) atom. In the sixth H site, H(18) is bonded in a single-bond geometry to one O(2) and one Br(1) atom. In the seventh H site, H(19) is bonded in a single-bond geometry to one O(3) and one Br(1) atom. In the eighth H site, H(20) is bonded in a single-bond geometry to one O(4) atom. There are three inequivalent O sites. In the first O site, O(4) is bonded in a distorted water-like geometry to one H(16) and one H(20) atom. In the second O site, O(2) is bonded in a water-like geometry to one H(14) and one H(18) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one Mg(1), one H(19), and one H(2) atom. There are four inequivalent Br sites. In the first Br site, Br(1) is bonded in a 3-coordinate geometry to one H(16), one H(18), and one H(19) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Mg(1) atom. In the third Br site, Br(3) is bonded in a single-bond geometry to one Mg(1) atom. In the fourth Br site, Br(4) is bonded in a distorted single-bond geometry to one Mg(1) atom. is represented by the CIF file [CIF]
data_MgH20Br4(NO)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.586
_cell_length_b   7.541
_cell_length_c   8.874
_cell_angle_alpha   87.133
_cell_angle_beta   116.112
_cell_angle_gamma   97.048
_symmetry_Int_Tables_number   1
_cell_volume   452.351
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.905  0.151  0.935  1.0
  H  H1  1  0.259  0.091  0.586  1.0
  H  H2  1  0.734  0.355  0.069  1.0
  H  H3  1  0.704  0.909  0.352  1.0
  H  H4  1  0.318  0.595  0.917  1.0
  H  H5  1  0.212  0.893  0.491  1.0
  H  H6  1  0.663  0.624  0.997  1.0
  H  H7  1  0.756  0.110  0.445  1.0
  H  H8  1  0.337  0.376  0.976  1.0
  H  H9  1  0.189  0.908  0.667  1.0
  H  H10  1  0.612  0.559  0.158  1.0
  H  H11  1  0.961  0.003  0.457  1.0
  H  H12  1  0.385  0.446  0.811  1.0
  H  H13  1  0.241  0.871  0.972  1.0
  H  H14  1  0.673  0.585  0.443  1.0
  H  H15  1  0.779  0.094  0.267  1.0
  H  H16  1  0.304  0.435  0.539  1.0
  H  H17  1  0.053  0.745  0.867  1.0
  H  H18  1  0.458  0.633  0.331  1.0
  H  H19  1  0.960  0.344  0.181  1.0
  H  H20  1  0.515  0.371  0.644  1.0
  Br  Br21  1  0.147  0.591  0.311  1.0
  Br  Br22  1  0.721  0.856  0.820  1.0
  Br  Br23  1  0.847  0.356  0.686  1.0
  Br  Br24  1  0.270  0.131  0.115  1.0
  N  N25  1  0.397  0.484  0.930  1.0
  N  N26  1  0.794  0.029  0.377  1.0
  N  N27  1  0.604  0.518  0.045  1.0
  N  N28  1  0.168  0.972  0.556  1.0
  O  O29  1  0.192  0.774  0.887  1.0
  O  O30  1  0.596  0.650  0.341  1.0
  O  O31  1  0.840  0.266  0.102  1.0
  O  O32  1  0.382  0.365  0.640  1.0
[/CIF]
.
The crystal structure described by MgNH8O3Br4N2H7NH3H2O is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one ammonia molecule, one azanium;azane molecule, one water molecule, and one MgNH8O3Br4 cluster. In the MgNH8O3Br4 cluster, Mg(1) is bonded in a tetrahedral geometry to one O(3), one Br(2), one Br(3), and one Br(4) atom. N(3) is bonded in a distorted water-like geometry to one H(10), one H(2), and one H(6) atom. There are eight inequivalent H sites. In the first H site, H(2) is bonded in a linear geometry to one N(3) and one O(3) atom. In the second H site, H(6) is bonded in a single-bond geometry to one N(3) atom. In the third H site, H(10) is bonded in a single-bond geometry to one N(3) atom. In the fourth H site, H(14) is bonded in a single-bond geometry to one O(2) atom. In the fifth H site, H(16) is bonded in a single-bond geometry to one O(4) and one Br(1) atom. In the sixth H site, H(18) is bonded in a single-bond geometry to one O(2) and one Br(1) atom. In the seventh H site, H(19) is bonded in a single-bond geometry to one O(3) and one Br(1) atom. In the eighth H site, H(20) is bonded in a single-bond geometry to one O(4) atom. There are three inequivalent O sites. In the first O site, O(4) is bonded in a distorted water-like geometry to one H(16) and one H(20) atom. In the second O site, O(2) is bonded in a water-like geometry to one H(14) and one H(18) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one Mg(1), one H(19), and one H(2) atom. There are four inequivalent Br sites. In the first Br site, Br(1) is bonded in a 3-coordinate geometry to one H(16), one H(18), and one H(19) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Mg(1) atom. In the third Br site, Br(3) is bonded in a single-bond geometry to one Mg(1) atom. In the fourth Br site, Br(4) is bonded in a distorted single-bond geometry to one Mg(1) atom. is represented by the CIF file [CIF]
data_MgH20Br4(NO)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.586
_cell_length_b   7.541
_cell_length_c   8.874
_cell_angle_alpha   87.133
_cell_angle_beta   116.112
_cell_angle_gamma   97.048
_symmetry_Int_Tables_number   1
_cell_volume   452.351
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.905  0.151  0.935  1.0
  H  H1  1  0.259  0.091  0.586  1.0
  H  H2  1  0.734  0.355  0.069  1.0
  H  H3  1  0.704  0.909  0.352  1.0
  H  H4  1  0.318  0.595  0.917  1.0
  H  H5  1  0.212  0.893  0.491  1.0
  H  H6  1  0.663  0.624  0.997  1.0
  H  H7  1  0.756  0.110  0.445  1.0
  H  H8  1  0.337  0.376  0.976  1.0
  H  H9  1  0.189  0.908  0.667  1.0
  H  H10  1  0.612  0.559  0.158  1.0
  H  H11  1  0.961  0.003  0.457  1.0
  H  H12  1  0.385  0.446  0.811  1.0
  H  H13  1  0.241  0.871  0.972  1.0
  H  H14  1  0.673  0.585  0.443  1.0
  H  H15  1  0.779  0.094  0.267  1.0
  H  H16  1  0.304  0.435  0.539  1.0
  H  H17  1  0.053  0.745  0.867  1.0
  H  H18  1  0.458  0.633  0.331  1.0
  H  H19  1  0.960  0.344  0.181  1.0
  H  H20  1  0.515  0.371  0.644  1.0
  Br  Br21  1  0.147  0.591  0.311  1.0
  Br  Br22  1  0.721  0.856  0.820  1.0
  Br  Br23  1  0.847  0.356  0.686  1.0
  Br  Br24  1  0.270  0.131  0.115  1.0
  N  N25  1  0.397  0.484  0.930  1.0
  N  N26  1  0.794  0.029  0.377  1.0
  N  N27  1  0.604  0.518  0.045  1.0
  N  N28  1  0.168  0.972  0.556  1.0
  O  O29  1  0.192  0.774  0.887  1.0
  O  O30  1  0.596  0.650  0.341  1.0
  O  O31  1  0.840  0.266  0.102  1.0
  O  O32  1  0.382  0.365  0.640  1.0
[/CIF]
.