The compound described by CdGa(AgS2)2 is Stannite-like structured and crystallizes in the orthorhombic Pmn2_1 space group. Ag(1) is bonded to one S(1), one S(3), and two equivalent S(2) atoms to form AgS4 tetrahedra that share corners with four equivalent Ag(1)S4 tetrahedra, corners with four equivalent Cd(1)S4 tetrahedra, and corners with four equivalent Ga(1)S4 tetrahedra. Cd(1) is bonded to one S(1), one S(3), and two equivalent S(2) atoms to form CdS4 tetrahedra that share corners with four equivalent Ga(1)S4 tetrahedra and corners with eight equivalent Ag(1)S4 tetrahedra. Ga(1) is bonded to one S(1), one S(3), and two equivalent S(2) atoms to form GaS4 tetrahedra that share corners with four equivalent Cd(1)S4 tetrahedra and corners with eight equivalent Ag(1)S4 tetrahedra. There are three inequivalent S sites. In the first S site, S(1) is bonded to two equivalent Ag(1), one Cd(1), and one Ga(1) atom to form corner-sharing SCdGaAg2 tetrahedra. In the second S site, S(2) is bonded to two equivalent Ag(1), one Cd(1), and one Ga(1) atom to form corner-sharing SCdGaAg2 tetrahedra. In the third S site, S(3) is bonded to two equivalent Ag(1), one Cd(1), and one Ga(1) atom to form corner-sharing SCdGaAg2 tetrahedra. is represented by the CIF file [CIF]
data_CdGa(AgS2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.751
_cell_length_b   7.124
_cell_length_c   7.819
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   376.065
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.507  0.349  0.000  1.0
  Cd  Cd1  1  0.007  0.651  0.500  1.0
  Ga  Ga2  1  1.000  0.671  0.000  1.0
  Ga  Ga3  1  0.500  0.329  0.500  1.0
  Ag  Ag4  1  0.514  0.825  0.750  1.0
  Ag  Ag5  1  0.014  0.175  0.750  1.0
  Ag  Ag6  1  0.014  0.175  0.250  1.0
  Ag  Ag7  1  0.514  0.825  0.250  1.0
  S  S8  1  0.890  0.363  0.000  1.0
  S  S9  1  0.390  0.637  0.500  1.0
  S  S10  1  0.891  0.832  0.764  1.0
  S  S11  1  0.391  0.168  0.736  1.0
  S  S12  1  0.391  0.168  0.264  1.0
  S  S13  1  0.891  0.832  0.236  1.0
  S  S14  1  0.346  0.675  0.000  1.0
  S  S15  1  0.846  0.325  0.500  1.0
[/CIF]
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The compound described by CdGa(AgS2)2 is Stannite-like structured and crystallizes in the orthorhombic Pmn2_1 space group. Ag(1) is bonded to one S(1), one S(3), and two equivalent S(2) atoms to form AgS4 tetrahedra that share corners with four equivalent Ag(1)S4 tetrahedra, corners with four equivalent Cd(1)S4 tetrahedra, and corners with four equivalent Ga(1)S4 tetrahedra. Cd(1) is bonded to one S(1), one S(3), and two equivalent S(2) atoms to form CdS4 tetrahedra that share corners with four equivalent Ga(1)S4 tetrahedra and corners with eight equivalent Ag(1)S4 tetrahedra. Ga(1) is bonded to one S(1), one S(3), and two equivalent S(2) atoms to form GaS4 tetrahedra that share corners with four equivalent Cd(1)S4 tetrahedra and corners with eight equivalent Ag(1)S4 tetrahedra. There are three inequivalent S sites. In the first S site, S(1) is bonded to two equivalent Ag(1), one Cd(1), and one Ga(1) atom to form corner-sharing SCdGaAg2 tetrahedra. In the second S site, S(2) is bonded to two equivalent Ag(1), one Cd(1), and one Ga(1) atom to form corner-sharing SCdGaAg2 tetrahedra. In the third S site, S(3) is bonded to two equivalent Ag(1), one Cd(1), and one Ga(1) atom to form corner-sharing SCdGaAg2 tetrahedra. is represented by the CIF file [CIF]
data_CdGa(AgS2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.751
_cell_length_b   7.124
_cell_length_c   7.819
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   376.065
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.507  0.349  0.000  1.0
  Cd  Cd1  1  0.007  0.651  0.500  1.0
  Ga  Ga2  1  1.000  0.671  0.000  1.0
  Ga  Ga3  1  0.500  0.329  0.500  1.0
  Ag  Ag4  1  0.514  0.825  0.750  1.0
  Ag  Ag5  1  0.014  0.175  0.750  1.0
  Ag  Ag6  1  0.014  0.175  0.250  1.0
  Ag  Ag7  1  0.514  0.825  0.250  1.0
  S  S8  1  0.890  0.363  0.000  1.0
  S  S9  1  0.390  0.637  0.500  1.0
  S  S10  1  0.891  0.832  0.764  1.0
  S  S11  1  0.391  0.168  0.736  1.0
  S  S12  1  0.391  0.168  0.264  1.0
  S  S13  1  0.891  0.832  0.236  1.0
  S  S14  1  0.346  0.675  0.000  1.0
  S  S15  1  0.846  0.325  0.500  1.0
[/CIF]
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