The material described by KAgCO3 crystallizes in the orthorhombic Ibca space group. K(1) is bonded in a 9-coordinate geometry to four equivalent O(2) and five equivalent O(1) atoms. Ag(1) is bonded in a linear geometry to two equivalent O(2) atoms. C(1) is bonded in a trigonal planar geometry to one O(1) and two equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to five equivalent K(1) and one C(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to two equivalent K(1), one Ag(1), and one C(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_KAgCO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.195
_cell_length_b   11.195
_cell_length_c   11.195
_cell_angle_alpha   149.676
_cell_angle_beta   148.543
_cell_angle_gamma   44.257
_symmetry_Int_Tables_number   1
_cell_volume   368.611
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.430  0.180  0.250  1.0
  K  K1  1  0.070  0.320  0.750  1.0
  K  K2  1  0.570  0.820  0.750  1.0
  K  K3  1  0.930  0.680  0.250  1.0
  Ag  Ag4  1  0.365  0.250  0.615  1.0
  Ag  Ag5  1  0.135  0.750  0.885  1.0
  Ag  Ag6  1  0.635  0.750  0.385  1.0
  Ag  Ag7  1  0.865  0.250  0.115  1.0
  C  C8  1  0.123  0.873  0.250  1.0
  C  C9  1  0.377  0.627  0.750  1.0
  C  C10  1  0.877  0.127  0.750  1.0
  C  C11  1  0.623  0.373  0.250  1.0
  O  O12  1  0.061  0.811  0.250  1.0
  O  O13  1  0.439  0.689  0.750  1.0
  O  O14  1  0.939  0.189  0.750  1.0
  O  O15  1  0.561  0.311  0.250  1.0
  O  O16  1  0.287  0.042  0.523  1.0
  O  O17  1  0.213  0.736  0.755  1.0
  O  O18  1  0.481  0.458  0.745  1.0
  O  O19  1  0.019  0.764  0.977  1.0
  O  O20  1  0.713  0.958  0.477  1.0
  O  O21  1  0.787  0.264  0.245  1.0
  O  O22  1  0.519  0.542  0.255  1.0
  O  O23  1  0.981  0.236  0.023  1.0
[/CIF]
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The material described by KAgCO3 crystallizes in the orthorhombic Ibca space group. K(1) is bonded in a 9-coordinate geometry to four equivalent O(2) and five equivalent O(1) atoms. Ag(1) is bonded in a linear geometry to two equivalent O(2) atoms. C(1) is bonded in a trigonal planar geometry to one O(1) and two equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to five equivalent K(1) and one C(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to two equivalent K(1), one Ag(1), and one C(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_KAgCO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.195
_cell_length_b   11.195
_cell_length_c   11.195
_cell_angle_alpha   149.676
_cell_angle_beta   148.543
_cell_angle_gamma   44.257
_symmetry_Int_Tables_number   1
_cell_volume   368.611
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.430  0.180  0.250  1.0
  K  K1  1  0.070  0.320  0.750  1.0
  K  K2  1  0.570  0.820  0.750  1.0
  K  K3  1  0.930  0.680  0.250  1.0
  Ag  Ag4  1  0.365  0.250  0.615  1.0
  Ag  Ag5  1  0.135  0.750  0.885  1.0
  Ag  Ag6  1  0.635  0.750  0.385  1.0
  Ag  Ag7  1  0.865  0.250  0.115  1.0
  C  C8  1  0.123  0.873  0.250  1.0
  C  C9  1  0.377  0.627  0.750  1.0
  C  C10  1  0.877  0.127  0.750  1.0
  C  C11  1  0.623  0.373  0.250  1.0
  O  O12  1  0.061  0.811  0.250  1.0
  O  O13  1  0.439  0.689  0.750  1.0
  O  O14  1  0.939  0.189  0.750  1.0
  O  O15  1  0.561  0.311  0.250  1.0
  O  O16  1  0.287  0.042  0.523  1.0
  O  O17  1  0.213  0.736  0.755  1.0
  O  O18  1  0.481  0.458  0.745  1.0
  O  O19  1  0.019  0.764  0.977  1.0
  O  O20  1  0.713  0.958  0.477  1.0
  O  O21  1  0.787  0.264  0.245  1.0
  O  O22  1  0.519  0.542  0.255  1.0
  O  O23  1  0.981  0.236  0.023  1.0
[/CIF]
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