The structure described by Pr32Rh19In3 crystallizes in the orthorhombic Amm2 space group. There are thirteen inequivalent Pr sites. In the first Pr site, Pr(1) is bonded in a 6-coordinate geometry to one Rh(1), one Rh(2), two equivalent Rh(6), and two equivalent Rh(9) atoms. In the second Pr site, Pr(2) is bonded in a 6-coordinate geometry to one Rh(4), one Rh(5), one Rh(8), two equivalent Rh(3), and one In(2) atom. In the third Pr site, Pr(3) is bonded in a 6-coordinate geometry to one Rh(8), one Rh(9), two equivalent Rh(3), and two equivalent Rh(7) atoms. In the fourth Pr site, Pr(4) is bonded in a 6-coordinate geometry to one Rh(9), two equivalent Rh(3), two equivalent Rh(7), and one In(2) atom. In the fifth Pr site, Pr(5) is bonded in a 6-coordinate geometry to one Rh(9), two equivalent Rh(2), two equivalent Rh(7), and one In(2) atom. In the sixth Pr site, Pr(6) is bonded in a 6-coordinate geometry to one Rh(8), one Rh(9), two equivalent Rh(1), and two equivalent Rh(7) atoms. In the seventh Pr site, Pr(7) is bonded in a 6-coordinate geometry to one Rh(2), one Rh(3), one Rh(6), one Rh(7), one Rh(9), and one In(1) atom. In the eighth Pr site, Pr(8) is bonded in a 6-coordinate geometry to one Rh(1), one Rh(3), one Rh(6), one Rh(7), one Rh(9), and one In(1) atom. In the ninth Pr site, Pr(9) is bonded in a 6-coordinate geometry to one Rh(2), one Rh(3), one Rh(4), one Rh(7), one In(1), and one In(2) atom. In the tenth Pr site, Pr(10) is bonded in a 6-coordinate geometry to one Rh(1), one Rh(3), one Rh(5), one Rh(7), one Rh(8), and one In(1) atom. In the eleventh Pr site, Pr(11) is bonded to two equivalent Rh(1) and two equivalent Rh(6) atoms to form distorted edge-sharing PrRh4 trigonal pyramids. In the twelfth Pr site, Pr(12) is bonded to two equivalent Rh(2) and two equivalent Rh(6) atoms to form distorted PrRh4 trigonal pyramids that share corners with two equivalent In(2)Pr10Rh2 cuboctahedra and  an edgeedge with one Pr(11)Rh4 trigonal pyramid. In the thirteenth Pr site, Pr(13) is bonded to one Rh(4), one Rh(5), and two equivalent Rh(3) atoms to form distorted edge-sharing PrRh4 trigonal pyramids. There are nine inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 8-coordinate geometry to one Pr(1), one Pr(11), two equivalent Pr(10), two equivalent Pr(6), and two equivalent Pr(8) atoms. In the second Rh site, Rh(2) is bonded in a 6-coordinate geometry to one Pr(1), one Pr(12), two equivalent Pr(5), two equivalent Pr(7), two equivalent Pr(9), and one In(2) atom. In the third Rh site, Rh(3) is bonded in a 8-coordinate geometry to one Pr(10), one Pr(13), one Pr(2), one Pr(3), one Pr(4), one Pr(7), one Pr(8), and one Pr(9) atom. In the fourth Rh site, Rh(4) is bonded in a 6-coordinate geometry to two equivalent Pr(13), two equivalent Pr(2), and four equivalent Pr(9) atoms. In the fifth Rh site, Rh(5) is bonded in a 8-coordinate geometry to two equivalent Pr(13), two equivalent Pr(2), and four equivalent Pr(10) atoms. In the sixth Rh site, Rh(6) is bonded in a 8-coordinate geometry to one Pr(11), one Pr(12), two equivalent Pr(1), two equivalent Pr(7), and two equivalent Pr(8) atoms. In the seventh Rh site, Rh(7) is bonded in a 8-coordinate geometry to one Pr(10), one Pr(3), one Pr(4), one Pr(5), one Pr(6), one Pr(7), one Pr(8), one Pr(9), and one In(1) atom. In the eighth Rh site, Rh(8) is bonded in a 10-coordinate geometry to two equivalent Pr(2), two equivalent Pr(3), two equivalent Pr(6), and four equivalent Pr(10) atoms. In the ninth Rh site, Rh(9) is bonded in a 10-coordinate geometry to one Pr(3), one Pr(4), one Pr(5), one Pr(6), two equivalent Pr(1), two equivalent Pr(7), and two equivalent Pr(8) atoms. There are two inequivalent In sites. In the first In site, In(1) is bonded in a distorted body-centered cubic geometry to two equivalent Pr(10), two equivalent Pr(7), two equivalent Pr(8), two equivalent Pr(9), and two equivalent Rh(7) atoms. In the second In site, In(2) is bonded to two equivalent Pr(2), two equivalent Pr(4), two equivalent Pr(5), four equivalent Pr(9), and two equivalent Rh(2) atoms to form distorted InPr10Rh2 cuboctahedra that share corners with two equivalent Pr(12)Rh4 trigonal pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_Pr32In3Rh19
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.880
_cell_length_b   11.880
_cell_length_c   10.031
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.788
_symmetry_Int_Tables_number   1
_cell_volume   1415.600
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pr  Pr0  1  0.498  0.498  0.809  1.0
  Pr  Pr1  1  0.994  0.994  0.803  1.0
  Pr  Pr2  1  0.498  0.498  0.191  1.0
  Pr  Pr3  1  0.994  0.994  0.197  1.0
  Pr  Pr4  1  0.721  0.069  0.000  1.0
  Pr  Pr5  1  0.303  0.912  0.000  1.0
  Pr  Pr6  1  0.216  0.443  0.000  1.0
  Pr  Pr7  1  0.784  0.577  0.000  1.0
  Pr  Pr8  1  0.443  0.216  0.000  1.0
  Pr  Pr9  1  0.577  0.784  0.000  1.0
  Pr  Pr10  1  0.069  0.721  0.000  1.0
  Pr  Pr11  1  0.912  0.303  0.000  1.0
  Pr  Pr12  1  0.585  0.203  0.693  1.0
  Pr  Pr13  1  0.416  0.791  0.694  1.0
  Pr  Pr14  1  0.082  0.294  0.698  1.0
  Pr  Pr15  1  0.914  0.704  0.693  1.0
  Pr  Pr16  1  0.294  0.082  0.698  1.0
  Pr  Pr17  1  0.704  0.914  0.693  1.0
  Pr  Pr18  1  0.203  0.585  0.693  1.0
  Pr  Pr19  1  0.791  0.416  0.694  1.0
  Pr  Pr20  1  0.416  0.791  0.306  1.0
  Pr  Pr21  1  0.585  0.203  0.307  1.0
  Pr  Pr22  1  0.914  0.704  0.307  1.0
  Pr  Pr23  1  0.082  0.294  0.302  1.0
  Pr  Pr24  1  0.704  0.914  0.307  1.0
  Pr  Pr25  1  0.294  0.082  0.302  1.0
  Pr  Pr26  1  0.791  0.416  0.306  1.0
  Pr  Pr27  1  0.203  0.585  0.307  1.0
  Pr  Pr28  1  0.634  0.634  0.500  1.0
  Pr  Pr29  1  0.358  0.358  0.500  1.0
  Pr  Pr30  1  0.137  0.861  0.500  1.0
  Pr  Pr31  1  0.861  0.137  0.500  1.0
  In  In32  1  0.497  0.997  0.500  1.0
  In  In33  1  0.998  0.497  0.500  1.0
  In  In34  1  0.166  0.166  0.000  1.0
  Rh  Rh35  1  0.672  0.672  0.772  1.0
  Rh  Rh36  1  0.321  0.321  0.783  1.0
  Rh  Rh37  1  0.176  0.828  0.774  1.0
  Rh  Rh38  1  0.828  0.176  0.774  1.0
  Rh  Rh39  1  0.321  0.321  0.217  1.0
  Rh  Rh40  1  0.672  0.672  0.228  1.0
  Rh  Rh41  1  0.828  0.176  0.226  1.0
  Rh  Rh42  1  0.176  0.828  0.226  1.0
  Rh  Rh43  1  0.111  0.111  0.500  1.0
  Rh  Rh44  1  0.891  0.891  0.500  1.0
  Rh  Rh45  1  0.604  0.389  0.500  1.0
  Rh  Rh46  1  0.389  0.604  0.500  1.0
  Rh  Rh47  1  0.506  0.998  0.843  1.0
  Rh  Rh48  1  0.998  0.506  0.843  1.0
  Rh  Rh49  1  0.506  0.998  0.157  1.0
  Rh  Rh50  1  0.998  0.506  0.157  1.0
  Rh  Rh51  1  0.855  0.855  0.000  1.0
  Rh  Rh52  1  0.652  0.358  0.000  1.0
  Rh  Rh53  1  0.358  0.652  0.000  1.0
[/CIF]
.
The structure described by Pr32Rh19In3 crystallizes in the orthorhombic Amm2 space group. There are thirteen inequivalent Pr sites. In the first Pr site, Pr(1) is bonded in a 6-coordinate geometry to one Rh(1), one Rh(2), two equivalent Rh(6), and two equivalent Rh(9) atoms. In the second Pr site, Pr(2) is bonded in a 6-coordinate geometry to one Rh(4), one Rh(5), one Rh(8), two equivalent Rh(3), and one In(2) atom. In the third Pr site, Pr(3) is bonded in a 6-coordinate geometry to one Rh(8), one Rh(9), two equivalent Rh(3), and two equivalent Rh(7) atoms. In the fourth Pr site, Pr(4) is bonded in a 6-coordinate geometry to one Rh(9), two equivalent Rh(3), two equivalent Rh(7), and one In(2) atom. In the fifth Pr site, Pr(5) is bonded in a 6-coordinate geometry to one Rh(9), two equivalent Rh(2), two equivalent Rh(7), and one In(2) atom. In the sixth Pr site, Pr(6) is bonded in a 6-coordinate geometry to one Rh(8), one Rh(9), two equivalent Rh(1), and two equivalent Rh(7) atoms. In the seventh Pr site, Pr(7) is bonded in a 6-coordinate geometry to one Rh(2), one Rh(3), one Rh(6), one Rh(7), one Rh(9), and one In(1) atom. In the eighth Pr site, Pr(8) is bonded in a 6-coordinate geometry to one Rh(1), one Rh(3), one Rh(6), one Rh(7), one Rh(9), and one In(1) atom. In the ninth Pr site, Pr(9) is bonded in a 6-coordinate geometry to one Rh(2), one Rh(3), one Rh(4), one Rh(7), one In(1), and one In(2) atom. In the tenth Pr site, Pr(10) is bonded in a 6-coordinate geometry to one Rh(1), one Rh(3), one Rh(5), one Rh(7), one Rh(8), and one In(1) atom. In the eleventh Pr site, Pr(11) is bonded to two equivalent Rh(1) and two equivalent Rh(6) atoms to form distorted edge-sharing PrRh4 trigonal pyramids. In the twelfth Pr site, Pr(12) is bonded to two equivalent Rh(2) and two equivalent Rh(6) atoms to form distorted PrRh4 trigonal pyramids that share corners with two equivalent In(2)Pr10Rh2 cuboctahedra and  an edgeedge with one Pr(11)Rh4 trigonal pyramid. In the thirteenth Pr site, Pr(13) is bonded to one Rh(4), one Rh(5), and two equivalent Rh(3) atoms to form distorted edge-sharing PrRh4 trigonal pyramids. There are nine inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 8-coordinate geometry to one Pr(1), one Pr(11), two equivalent Pr(10), two equivalent Pr(6), and two equivalent Pr(8) atoms. In the second Rh site, Rh(2) is bonded in a 6-coordinate geometry to one Pr(1), one Pr(12), two equivalent Pr(5), two equivalent Pr(7), two equivalent Pr(9), and one In(2) atom. In the third Rh site, Rh(3) is bonded in a 8-coordinate geometry to one Pr(10), one Pr(13), one Pr(2), one Pr(3), one Pr(4), one Pr(7), one Pr(8), and one Pr(9) atom. In the fourth Rh site, Rh(4) is bonded in a 6-coordinate geometry to two equivalent Pr(13), two equivalent Pr(2), and four equivalent Pr(9) atoms. In the fifth Rh site, Rh(5) is bonded in a 8-coordinate geometry to two equivalent Pr(13), two equivalent Pr(2), and four equivalent Pr(10) atoms. In the sixth Rh site, Rh(6) is bonded in a 8-coordinate geometry to one Pr(11), one Pr(12), two equivalent Pr(1), two equivalent Pr(7), and two equivalent Pr(8) atoms. In the seventh Rh site, Rh(7) is bonded in a 8-coordinate geometry to one Pr(10), one Pr(3), one Pr(4), one Pr(5), one Pr(6), one Pr(7), one Pr(8), one Pr(9), and one In(1) atom. In the eighth Rh site, Rh(8) is bonded in a 10-coordinate geometry to two equivalent Pr(2), two equivalent Pr(3), two equivalent Pr(6), and four equivalent Pr(10) atoms. In the ninth Rh site, Rh(9) is bonded in a 10-coordinate geometry to one Pr(3), one Pr(4), one Pr(5), one Pr(6), two equivalent Pr(1), two equivalent Pr(7), and two equivalent Pr(8) atoms. There are two inequivalent In sites. In the first In site, In(1) is bonded in a distorted body-centered cubic geometry to two equivalent Pr(10), two equivalent Pr(7), two equivalent Pr(8), two equivalent Pr(9), and two equivalent Rh(7) atoms. In the second In site, In(2) is bonded to two equivalent Pr(2), two equivalent Pr(4), two equivalent Pr(5), four equivalent Pr(9), and two equivalent Rh(2) atoms to form distorted InPr10Rh2 cuboctahedra that share corners with two equivalent Pr(12)Rh4 trigonal pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_Pr32In3Rh19
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.880
_cell_length_b   11.880
_cell_length_c   10.031
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.788
_symmetry_Int_Tables_number   1
_cell_volume   1415.600
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pr  Pr0  1  0.498  0.498  0.809  1.0
  Pr  Pr1  1  0.994  0.994  0.803  1.0
  Pr  Pr2  1  0.498  0.498  0.191  1.0
  Pr  Pr3  1  0.994  0.994  0.197  1.0
  Pr  Pr4  1  0.721  0.069  0.000  1.0
  Pr  Pr5  1  0.303  0.912  0.000  1.0
  Pr  Pr6  1  0.216  0.443  0.000  1.0
  Pr  Pr7  1  0.784  0.577  0.000  1.0
  Pr  Pr8  1  0.443  0.216  0.000  1.0
  Pr  Pr9  1  0.577  0.784  0.000  1.0
  Pr  Pr10  1  0.069  0.721  0.000  1.0
  Pr  Pr11  1  0.912  0.303  0.000  1.0
  Pr  Pr12  1  0.585  0.203  0.693  1.0
  Pr  Pr13  1  0.416  0.791  0.694  1.0
  Pr  Pr14  1  0.082  0.294  0.698  1.0
  Pr  Pr15  1  0.914  0.704  0.693  1.0
  Pr  Pr16  1  0.294  0.082  0.698  1.0
  Pr  Pr17  1  0.704  0.914  0.693  1.0
  Pr  Pr18  1  0.203  0.585  0.693  1.0
  Pr  Pr19  1  0.791  0.416  0.694  1.0
  Pr  Pr20  1  0.416  0.791  0.306  1.0
  Pr  Pr21  1  0.585  0.203  0.307  1.0
  Pr  Pr22  1  0.914  0.704  0.307  1.0
  Pr  Pr23  1  0.082  0.294  0.302  1.0
  Pr  Pr24  1  0.704  0.914  0.307  1.0
  Pr  Pr25  1  0.294  0.082  0.302  1.0
  Pr  Pr26  1  0.791  0.416  0.306  1.0
  Pr  Pr27  1  0.203  0.585  0.307  1.0
  Pr  Pr28  1  0.634  0.634  0.500  1.0
  Pr  Pr29  1  0.358  0.358  0.500  1.0
  Pr  Pr30  1  0.137  0.861  0.500  1.0
  Pr  Pr31  1  0.861  0.137  0.500  1.0
  In  In32  1  0.497  0.997  0.500  1.0
  In  In33  1  0.998  0.497  0.500  1.0
  In  In34  1  0.166  0.166  0.000  1.0
  Rh  Rh35  1  0.672  0.672  0.772  1.0
  Rh  Rh36  1  0.321  0.321  0.783  1.0
  Rh  Rh37  1  0.176  0.828  0.774  1.0
  Rh  Rh38  1  0.828  0.176  0.774  1.0
  Rh  Rh39  1  0.321  0.321  0.217  1.0
  Rh  Rh40  1  0.672  0.672  0.228  1.0
  Rh  Rh41  1  0.828  0.176  0.226  1.0
  Rh  Rh42  1  0.176  0.828  0.226  1.0
  Rh  Rh43  1  0.111  0.111  0.500  1.0
  Rh  Rh44  1  0.891  0.891  0.500  1.0
  Rh  Rh45  1  0.604  0.389  0.500  1.0
  Rh  Rh46  1  0.389  0.604  0.500  1.0
  Rh  Rh47  1  0.506  0.998  0.843  1.0
  Rh  Rh48  1  0.998  0.506  0.843  1.0
  Rh  Rh49  1  0.506  0.998  0.157  1.0
  Rh  Rh50  1  0.998  0.506  0.157  1.0
  Rh  Rh51  1  0.855  0.855  0.000  1.0
  Rh  Rh52  1  0.652  0.358  0.000  1.0
  Rh  Rh53  1  0.358  0.652  0.000  1.0
[/CIF]
.