The material structure described by CrP4(CO)2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four CrP4(CO)2 clusters. Cr(1) is bonded in an octahedral geometry to two equivalent C(1), two equivalent P(1), and two equivalent P(2) atoms. C(1) is bonded in a linear geometry to one Cr(1) and one O(1) atom. There are two inequivalent P sites. In the first P site, P(1) is bonded in a single-bond geometry to one Cr(1) atom. In the second P site, P(2) is bonded in a single-bond geometry to one Cr(1) atom. O(1) is bonded in a single-bond geometry to one C(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CrP4(CO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.980
_cell_length_b   6.980
_cell_length_c   14.124
_cell_angle_alpha   83.671
_cell_angle_beta   83.671
_cell_angle_gamma   116.578
_symmetry_Int_Tables_number   1
_cell_volume   601.787
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.068  0.932  0.250  1.0
  Cr  Cr1  1  0.932  0.068  0.750  1.0
  P  P2  1  0.068  0.713  0.148  1.0
  P  P3  1  0.287  0.932  0.352  1.0
  P  P4  1  0.932  0.287  0.852  1.0
  P  P5  1  0.713  0.068  0.648  1.0
  P  P6  1  0.790  0.672  0.360  1.0
  P  P7  1  0.328  0.210  0.140  1.0
  P  P8  1  0.210  0.328  0.640  1.0
  P  P9  1  0.672  0.790  0.860  1.0
  C  C10  1  0.858  0.954  0.175  1.0
  C  C11  1  0.046  0.142  0.325  1.0
  C  C12  1  0.142  0.046  0.825  1.0
  C  C13  1  0.954  0.858  0.675  1.0
  O  O14  1  0.734  0.968  0.129  1.0
  O  O15  1  0.032  0.266  0.371  1.0
  O  O16  1  0.266  0.032  0.871  1.0
  O  O17  1  0.968  0.734  0.629  1.0
[/CIF]
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The material structure described by CrP4(CO)2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four CrP4(CO)2 clusters. Cr(1) is bonded in an octahedral geometry to two equivalent C(1), two equivalent P(1), and two equivalent P(2) atoms. C(1) is bonded in a linear geometry to one Cr(1) and one O(1) atom. There are two inequivalent P sites. In the first P site, P(1) is bonded in a single-bond geometry to one Cr(1) atom. In the second P site, P(2) is bonded in a single-bond geometry to one Cr(1) atom. O(1) is bonded in a single-bond geometry to one C(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CrP4(CO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.980
_cell_length_b   6.980
_cell_length_c   14.124
_cell_angle_alpha   83.671
_cell_angle_beta   83.671
_cell_angle_gamma   116.578
_symmetry_Int_Tables_number   1
_cell_volume   601.787
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.068  0.932  0.250  1.0
  Cr  Cr1  1  0.932  0.068  0.750  1.0
  P  P2  1  0.068  0.713  0.148  1.0
  P  P3  1  0.287  0.932  0.352  1.0
  P  P4  1  0.932  0.287  0.852  1.0
  P  P5  1  0.713  0.068  0.648  1.0
  P  P6  1  0.790  0.672  0.360  1.0
  P  P7  1  0.328  0.210  0.140  1.0
  P  P8  1  0.210  0.328  0.640  1.0
  P  P9  1  0.672  0.790  0.860  1.0
  C  C10  1  0.858  0.954  0.175  1.0
  C  C11  1  0.046  0.142  0.325  1.0
  C  C12  1  0.142  0.046  0.825  1.0
  C  C13  1  0.954  0.858  0.675  1.0
  O  O14  1  0.734  0.968  0.129  1.0
  O  O15  1  0.032  0.266  0.371  1.0
  O  O16  1  0.266  0.032  0.871  1.0
  O  O17  1  0.968  0.734  0.629  1.0
[/CIF]
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