The material structure described by Pr2Zn2(BiO4)3Bi crystallizes in the cubic Pn-3 space group. The structure consists of two 7440-69-9 atoms inside a Pr2Zn2(BiO4)3 framework. In the Pr2Zn2(BiO4)3 framework, Pr(1) is bonded to six equivalent O(1) atoms to form PrO6 octahedra that share corners with six equivalent Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 38°. Zn(1) is bonded to six equivalent O(1) atoms to form ZnO6 octahedra that share corners with six equivalent Pr(1)O6 octahedra. The corner-sharing octahedral tilt angles are 38°. Bi(2) is bonded in a square co-planar geometry to four equivalent O(1) atoms. O(1) is bonded in a distorted trigonal planar geometry to one Pr(1), one Zn(1), and one Bi(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_PrZn(BiO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.451
_cell_length_b   8.451
_cell_length_c   8.451
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   603.572
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pr  Pr0  1  0.750  0.750  0.750  1.0
  Pr  Pr1  1  0.750  0.250  0.250  1.0
  Pr  Pr2  1  0.250  0.750  0.250  1.0
  Pr  Pr3  1  0.250  0.250  0.750  1.0
  Zn  Zn4  1  0.250  0.250  0.250  1.0
  Zn  Zn5  1  0.250  0.750  0.750  1.0
  Zn  Zn6  1  0.750  0.250  0.750  1.0
  Zn  Zn7  1  0.750  0.750  0.250  1.0
  Bi  Bi8  1  0.500  0.500  0.500  1.0
  Bi  Bi9  1  0.000  0.000  0.000  1.0
  Bi  Bi10  1  0.000  0.000  0.500  1.0
  Bi  Bi11  1  0.000  0.500  0.000  1.0
  Bi  Bi12  1  0.500  0.000  0.000  1.0
  Bi  Bi13  1  0.500  0.500  0.000  1.0
  Bi  Bi14  1  0.500  0.000  0.500  1.0
  Bi  Bi15  1  0.000  0.500  0.500  1.0
  O  O16  1  0.199  0.320  0.485  1.0
  O  O17  1  0.199  0.680  0.515  1.0
  O  O18  1  0.801  0.320  0.515  1.0
  O  O19  1  0.801  0.680  0.485  1.0
  O  O20  1  0.320  0.485  0.199  1.0
  O  O21  1  0.680  0.515  0.199  1.0
  O  O22  1  0.320  0.515  0.801  1.0
  O  O23  1  0.680  0.485  0.801  1.0
  O  O24  1  0.485  0.199  0.320  1.0
  O  O25  1  0.515  0.199  0.680  1.0
  O  O26  1  0.515  0.801  0.320  1.0
  O  O27  1  0.485  0.801  0.680  1.0
  O  O28  1  0.301  0.180  0.015  1.0
  O  O29  1  0.301  0.820  0.985  1.0
  O  O30  1  0.699  0.180  0.985  1.0
  O  O31  1  0.699  0.820  0.015  1.0
  O  O32  1  0.180  0.015  0.301  1.0
  O  O33  1  0.820  0.985  0.301  1.0
  O  O34  1  0.180  0.985  0.699  1.0
  O  O35  1  0.820  0.015  0.699  1.0
  O  O36  1  0.015  0.301  0.180  1.0
  O  O37  1  0.985  0.301  0.820  1.0
  O  O38  1  0.985  0.699  0.180  1.0
  O  O39  1  0.015  0.699  0.820  1.0
[/CIF]
.
The material structure described by Pr2Zn2(BiO4)3Bi crystallizes in the cubic Pn-3 space group. The structure consists of two 7440-69-9 atoms inside a Pr2Zn2(BiO4)3 framework. In the Pr2Zn2(BiO4)3 framework, Pr(1) is bonded to six equivalent O(1) atoms to form PrO6 octahedra that share corners with six equivalent Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 38°. Zn(1) is bonded to six equivalent O(1) atoms to form ZnO6 octahedra that share corners with six equivalent Pr(1)O6 octahedra. The corner-sharing octahedral tilt angles are 38°. Bi(2) is bonded in a square co-planar geometry to four equivalent O(1) atoms. O(1) is bonded in a distorted trigonal planar geometry to one Pr(1), one Zn(1), and one Bi(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_PrZn(BiO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.451
_cell_length_b   8.451
_cell_length_c   8.451
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   603.572
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pr  Pr0  1  0.750  0.750  0.750  1.0
  Pr  Pr1  1  0.750  0.250  0.250  1.0
  Pr  Pr2  1  0.250  0.750  0.250  1.0
  Pr  Pr3  1  0.250  0.250  0.750  1.0
  Zn  Zn4  1  0.250  0.250  0.250  1.0
  Zn  Zn5  1  0.250  0.750  0.750  1.0
  Zn  Zn6  1  0.750  0.250  0.750  1.0
  Zn  Zn7  1  0.750  0.750  0.250  1.0
  Bi  Bi8  1  0.500  0.500  0.500  1.0
  Bi  Bi9  1  0.000  0.000  0.000  1.0
  Bi  Bi10  1  0.000  0.000  0.500  1.0
  Bi  Bi11  1  0.000  0.500  0.000  1.0
  Bi  Bi12  1  0.500  0.000  0.000  1.0
  Bi  Bi13  1  0.500  0.500  0.000  1.0
  Bi  Bi14  1  0.500  0.000  0.500  1.0
  Bi  Bi15  1  0.000  0.500  0.500  1.0
  O  O16  1  0.199  0.320  0.485  1.0
  O  O17  1  0.199  0.680  0.515  1.0
  O  O18  1  0.801  0.320  0.515  1.0
  O  O19  1  0.801  0.680  0.485  1.0
  O  O20  1  0.320  0.485  0.199  1.0
  O  O21  1  0.680  0.515  0.199  1.0
  O  O22  1  0.320  0.515  0.801  1.0
  O  O23  1  0.680  0.485  0.801  1.0
  O  O24  1  0.485  0.199  0.320  1.0
  O  O25  1  0.515  0.199  0.680  1.0
  O  O26  1  0.515  0.801  0.320  1.0
  O  O27  1  0.485  0.801  0.680  1.0
  O  O28  1  0.301  0.180  0.015  1.0
  O  O29  1  0.301  0.820  0.985  1.0
  O  O30  1  0.699  0.180  0.985  1.0
  O  O31  1  0.699  0.820  0.015  1.0
  O  O32  1  0.180  0.015  0.301  1.0
  O  O33  1  0.820  0.985  0.301  1.0
  O  O34  1  0.180  0.985  0.699  1.0
  O  O35  1  0.820  0.015  0.699  1.0
  O  O36  1  0.015  0.301  0.180  1.0
  O  O37  1  0.985  0.301  0.820  1.0
  O  O38  1  0.985  0.699  0.180  1.0
  O  O39  1  0.015  0.699  0.820  1.0
[/CIF]
.