The structure described by ZrF8(CuO6)2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight copper;hexahydrate molecules and four ZrF8 clusters. In each ZrF8 cluster, Zr(1) is bonded in a 8-coordinate geometry to two equivalent F(1), two equivalent F(2), two equivalent F(3), and two equivalent F(4) atoms. There are four inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one Zr(1) atom. In the second F site, F(3) is bonded in a single-bond geometry to one Zr(1) atom. In the third F site, F(4) is bonded in a single-bond geometry to one Zr(1) atom. In the fourth F site, F(1) is bonded in a single-bond geometry to one Zr(1) atom. is represented by the CIF card [CIF]
data_ZrCu2(O3F2)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.612
_cell_length_b   8.612
_cell_length_c   9.985
_cell_angle_alpha   95.668
_cell_angle_beta   109.559
_cell_angle_gamma   119.822
_symmetry_Int_Tables_number   1
_cell_volume   572.622
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr0  1  0.998  0.248  0.750  1.0
  Zr  Zr1  1  0.002  0.752  0.250  1.0
  Cu  Cu2  1  0.653  0.590  0.757  1.0
  Cu  Cu3  1  0.333  0.896  0.743  1.0
  Cu  Cu4  1  0.347  0.410  0.243  1.0
  Cu  Cu5  1  0.667  0.104  0.257  1.0
  O  O6  1  0.773  0.677  0.638  1.0
  O  O7  1  0.539  0.136  0.862  1.0
  O  O8  1  0.227  0.323  0.362  1.0
  O  O9  1  0.461  0.864  0.138  1.0
  O  O10  1  0.549  0.516  0.888  1.0
  O  O11  1  0.128  0.660  0.612  1.0
  O  O12  1  0.451  0.484  0.112  1.0
  O  O13  1  0.872  0.340  0.388  1.0
  O  O14  1  0.562  0.357  0.643  1.0
  O  O15  1  0.215  0.920  0.857  1.0
  O  O16  1  0.438  0.643  0.357  1.0
  O  O17  1  0.785  0.080  0.143  1.0
  O  O18  1  0.714  0.820  0.856  1.0
  O  O19  1  0.464  0.859  0.644  1.0
  O  O20  1  0.286  0.180  0.144  1.0
  O  O21  1  0.536  0.141  0.356  1.0
  O  O22  1  0.989  0.685  0.879  1.0
  O  O23  1  0.305  0.110  0.621  1.0
  O  O24  1  0.011  0.315  0.121  1.0
  O  O25  1  0.695  0.890  0.379  1.0
  O  O26  1  0.385  0.563  0.599  1.0
  O  O27  1  0.465  0.787  0.901  1.0
  O  O28  1  0.615  0.437  0.401  1.0
  O  O29  1  0.535  0.213  0.099  1.0
  F  F30  1  0.714  0.125  0.573  1.0
  F  F31  1  0.052  0.141  0.927  1.0
  F  F32  1  0.286  0.875  0.427  1.0
  F  F33  1  0.948  0.859  0.073  1.0
  F  F34  1  0.239  0.505  0.919  1.0
  F  F35  1  0.086  0.320  0.581  1.0
  F  F36  1  0.761  0.495  0.081  1.0
  F  F37  1  0.914  0.680  0.419  1.0
  F  F38  1  0.831  0.257  0.864  1.0
  F  F39  1  0.893  0.967  0.636  1.0
  F  F40  1  0.169  0.743  0.136  1.0
  F  F41  1  0.107  0.033  0.364  1.0
  F  F42  1  0.953  0.481  0.711  1.0
  F  F43  1  0.270  0.241  0.789  1.0
  F  F44  1  0.047  0.519  0.289  1.0
  F  F45  1  0.730  0.759  0.211  1.0
[/CIF]
.
The structure described by ZrF8(CuO6)2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight copper;hexahydrate molecules and four ZrF8 clusters. In each ZrF8 cluster, Zr(1) is bonded in a 8-coordinate geometry to two equivalent F(1), two equivalent F(2), two equivalent F(3), and two equivalent F(4) atoms. There are four inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one Zr(1) atom. In the second F site, F(3) is bonded in a single-bond geometry to one Zr(1) atom. In the third F site, F(4) is bonded in a single-bond geometry to one Zr(1) atom. In the fourth F site, F(1) is bonded in a single-bond geometry to one Zr(1) atom. is represented by the CIF card [CIF]
data_ZrCu2(O3F2)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.612
_cell_length_b   8.612
_cell_length_c   9.985
_cell_angle_alpha   95.668
_cell_angle_beta   109.559
_cell_angle_gamma   119.822
_symmetry_Int_Tables_number   1
_cell_volume   572.622
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr0  1  0.998  0.248  0.750  1.0
  Zr  Zr1  1  0.002  0.752  0.250  1.0
  Cu  Cu2  1  0.653  0.590  0.757  1.0
  Cu  Cu3  1  0.333  0.896  0.743  1.0
  Cu  Cu4  1  0.347  0.410  0.243  1.0
  Cu  Cu5  1  0.667  0.104  0.257  1.0
  O  O6  1  0.773  0.677  0.638  1.0
  O  O7  1  0.539  0.136  0.862  1.0
  O  O8  1  0.227  0.323  0.362  1.0
  O  O9  1  0.461  0.864  0.138  1.0
  O  O10  1  0.549  0.516  0.888  1.0
  O  O11  1  0.128  0.660  0.612  1.0
  O  O12  1  0.451  0.484  0.112  1.0
  O  O13  1  0.872  0.340  0.388  1.0
  O  O14  1  0.562  0.357  0.643  1.0
  O  O15  1  0.215  0.920  0.857  1.0
  O  O16  1  0.438  0.643  0.357  1.0
  O  O17  1  0.785  0.080  0.143  1.0
  O  O18  1  0.714  0.820  0.856  1.0
  O  O19  1  0.464  0.859  0.644  1.0
  O  O20  1  0.286  0.180  0.144  1.0
  O  O21  1  0.536  0.141  0.356  1.0
  O  O22  1  0.989  0.685  0.879  1.0
  O  O23  1  0.305  0.110  0.621  1.0
  O  O24  1  0.011  0.315  0.121  1.0
  O  O25  1  0.695  0.890  0.379  1.0
  O  O26  1  0.385  0.563  0.599  1.0
  O  O27  1  0.465  0.787  0.901  1.0
  O  O28  1  0.615  0.437  0.401  1.0
  O  O29  1  0.535  0.213  0.099  1.0
  F  F30  1  0.714  0.125  0.573  1.0
  F  F31  1  0.052  0.141  0.927  1.0
  F  F32  1  0.286  0.875  0.427  1.0
  F  F33  1  0.948  0.859  0.073  1.0
  F  F34  1  0.239  0.505  0.919  1.0
  F  F35  1  0.086  0.320  0.581  1.0
  F  F36  1  0.761  0.495  0.081  1.0
  F  F37  1  0.914  0.680  0.419  1.0
  F  F38  1  0.831  0.257  0.864  1.0
  F  F39  1  0.893  0.967  0.636  1.0
  F  F40  1  0.169  0.743  0.136  1.0
  F  F41  1  0.107  0.033  0.364  1.0
  F  F42  1  0.953  0.481  0.711  1.0
  F  F43  1  0.270  0.241  0.789  1.0
  F  F44  1  0.047  0.519  0.289  1.0
  F  F45  1  0.730  0.759  0.211  1.0
[/CIF]
.