The material described by MnC3PNH15(OCl)3 is Indium-like structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of two MnC3PNH15(OCl)3 clusters. Mn(1) is bonded to one O(1), one O(2), one O(3), one Cl(1), one Cl(2), and one Cl(3) atom to form MnCl3O3 octahedra that share  a cornercorner with one P(1)C3O tetrahedra. There are three inequivalent C sites. In the first C site, C(1) is bonded to one P(1), one N(1), one H(14), and one H(15) atom to form distorted corner-sharing CPH2N tetrahedra. In the second C site, C(2) is bonded to one P(1), one H(10), one H(8), and one H(9) atom to form distorted CPH3 tetrahedra that share  a cornercorner with one C(1)PH2N tetrahedra and  a cornercorner with one C(3)PH3 tetrahedra. In the third C site, C(3) is bonded to one P(1), one H(11), one H(12), and one H(13) atom to form distorted CPH3 tetrahedra that share  a cornercorner with one C(1)PH2N tetrahedra and  a cornercorner with one C(2)PH3 tetrahedra. P(1) is bonded to one C(1), one C(2), one C(3), and one O(1) atom to form distorted PC3O tetrahedra that share  a cornercorner with one Mn(1)Cl3O3 octahedra and  a cornercorner with one N(1)H3C tetrahedra. The corner-sharing octahedral tilt angles are 39°. N(1) is bonded to one C(1), one H(1), one H(2), and one H(3) atom to form distorted NH3C tetrahedra that share  a cornercorner with one P(1)C3O tetrahedra. There are fifteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(2) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(3) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(2) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(2) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(2) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(3) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(3) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(3) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(1) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(1) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Mn(1) and one P(1) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Mn(1), one H(4), and one H(5) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one Mn(1), one H(6), and one H(7) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Mn(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Mn(1) atom. In the third Cl site, Cl(3) is bonded in a distorted single-bond geometry to one Mn(1) atom. is represented by the CIF file [CIF]
data_MnPH15C3N(ClO)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.543
_cell_length_b   8.746
_cell_length_c   11.091
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   99.663
_symmetry_Int_Tables_number   1
_cell_volume   625.630
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.007  0.866  0.999  1.0
  Mn  Mn1  1  0.993  0.134  0.499  1.0
  P  P2  1  0.270  0.246  0.001  1.0
  P  P3  1  0.730  0.754  0.501  1.0
  H  H4  1  0.023  0.471  0.124  1.0
  H  H5  1  0.977  0.529  0.624  1.0
  H  H6  1  0.121  0.458  0.265  1.0
  H  H7  1  0.879  0.542  0.765  1.0
  H  H8  1  0.998  0.299  0.200  1.0
  H  H9  1  0.002  0.701  0.700  1.0
  H  H10  1  0.636  0.880  0.862  1.0
  H  H11  1  0.364  0.120  0.362  1.0
  H  H12  1  0.804  0.002  0.799  1.0
  H  H13  1  0.196  0.998  0.299  1.0
  H  H14  1  0.609  0.856  0.125  1.0
  H  H15  1  0.391  0.144  0.625  1.0
  H  H16  1  0.770  0.987  0.185  1.0
  H  H17  1  0.230  0.013  0.685  1.0
  H  H18  1  0.219  0.298  0.792  1.0
  H  H19  1  0.781  0.702  0.292  1.0
  H  H20  1  0.376  0.458  0.869  1.0
  H  H21  1  0.624  0.542  0.369  1.0
  H  H22  1  0.101  0.423  0.889  1.0
  H  H23  1  0.899  0.577  0.389  1.0
  H  H24  1  0.546  0.117  0.064  1.0
  H  H25  1  0.454  0.883  0.564  1.0
  H  H26  1  0.636  0.297  0.985  1.0
  H  H27  1  0.364  0.703  0.485  1.0
  H  H28  1  0.525  0.126  0.904  1.0
  H  H29  1  0.475  0.874  0.404  1.0
  H  H30  1  0.382  0.324  0.203  1.0
  H  H31  1  0.618  0.676  0.703  1.0
  H  H32  1  0.393  0.489  0.106  1.0
  H  H33  1  0.607  0.511  0.606  1.0
  C  C34  1  0.300  0.377  0.132  1.0
  C  C35  1  0.700  0.623  0.632  1.0
  C  C36  1  0.238  0.368  0.874  1.0
  C  C37  1  0.762  0.632  0.374  1.0
  C  C38  1  0.519  0.191  0.988  1.0
  C  C39  1  0.481  0.809  0.488  1.0
  N  N40  1  0.098  0.403  0.182  1.0
  N  N41  1  0.902  0.597  0.682  1.0
  Cl  Cl42  1  0.252  0.812  0.165  1.0
  Cl  Cl43  1  0.748  0.188  0.665  1.0
  Cl  Cl44  1  0.834  0.577  0.983  1.0
  Cl  Cl45  1  0.166  0.423  0.483  1.0
  Cl  Cl46  1  0.259  0.839  0.820  1.0
  Cl  Cl47  1  0.741  0.161  0.320  1.0
  O  O48  1  0.090  0.116  0.021  1.0
  O  O49  1  0.910  0.884  0.521  1.0
  O  O50  1  0.786  0.906  0.847  1.0
  O  O51  1  0.214  0.094  0.347  1.0
  O  O52  1  0.759  0.897  0.130  1.0
  O  O53  1  0.241  0.103  0.630  1.0
[/CIF]
.
The material described by MnC3PNH15(OCl)3 is Indium-like structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of two MnC3PNH15(OCl)3 clusters. Mn(1) is bonded to one O(1), one O(2), one O(3), one Cl(1), one Cl(2), and one Cl(3) atom to form MnCl3O3 octahedra that share  a cornercorner with one P(1)C3O tetrahedra. There are three inequivalent C sites. In the first C site, C(1) is bonded to one P(1), one N(1), one H(14), and one H(15) atom to form distorted corner-sharing CPH2N tetrahedra. In the second C site, C(2) is bonded to one P(1), one H(10), one H(8), and one H(9) atom to form distorted CPH3 tetrahedra that share  a cornercorner with one C(1)PH2N tetrahedra and  a cornercorner with one C(3)PH3 tetrahedra. In the third C site, C(3) is bonded to one P(1), one H(11), one H(12), and one H(13) atom to form distorted CPH3 tetrahedra that share  a cornercorner with one C(1)PH2N tetrahedra and  a cornercorner with one C(2)PH3 tetrahedra. P(1) is bonded to one C(1), one C(2), one C(3), and one O(1) atom to form distorted PC3O tetrahedra that share  a cornercorner with one Mn(1)Cl3O3 octahedra and  a cornercorner with one N(1)H3C tetrahedra. The corner-sharing octahedral tilt angles are 39°. N(1) is bonded to one C(1), one H(1), one H(2), and one H(3) atom to form distorted NH3C tetrahedra that share  a cornercorner with one P(1)C3O tetrahedra. There are fifteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(2) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(3) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(2) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(2) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(2) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(3) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(3) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(3) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(1) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(1) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Mn(1) and one P(1) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Mn(1), one H(4), and one H(5) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one Mn(1), one H(6), and one H(7) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Mn(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Mn(1) atom. In the third Cl site, Cl(3) is bonded in a distorted single-bond geometry to one Mn(1) atom. is represented by the CIF file [CIF]
data_MnPH15C3N(ClO)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.543
_cell_length_b   8.746
_cell_length_c   11.091
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   99.663
_symmetry_Int_Tables_number   1
_cell_volume   625.630
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.007  0.866  0.999  1.0
  Mn  Mn1  1  0.993  0.134  0.499  1.0
  P  P2  1  0.270  0.246  0.001  1.0
  P  P3  1  0.730  0.754  0.501  1.0
  H  H4  1  0.023  0.471  0.124  1.0
  H  H5  1  0.977  0.529  0.624  1.0
  H  H6  1  0.121  0.458  0.265  1.0
  H  H7  1  0.879  0.542  0.765  1.0
  H  H8  1  0.998  0.299  0.200  1.0
  H  H9  1  0.002  0.701  0.700  1.0
  H  H10  1  0.636  0.880  0.862  1.0
  H  H11  1  0.364  0.120  0.362  1.0
  H  H12  1  0.804  0.002  0.799  1.0
  H  H13  1  0.196  0.998  0.299  1.0
  H  H14  1  0.609  0.856  0.125  1.0
  H  H15  1  0.391  0.144  0.625  1.0
  H  H16  1  0.770  0.987  0.185  1.0
  H  H17  1  0.230  0.013  0.685  1.0
  H  H18  1  0.219  0.298  0.792  1.0
  H  H19  1  0.781  0.702  0.292  1.0
  H  H20  1  0.376  0.458  0.869  1.0
  H  H21  1  0.624  0.542  0.369  1.0
  H  H22  1  0.101  0.423  0.889  1.0
  H  H23  1  0.899  0.577  0.389  1.0
  H  H24  1  0.546  0.117  0.064  1.0
  H  H25  1  0.454  0.883  0.564  1.0
  H  H26  1  0.636  0.297  0.985  1.0
  H  H27  1  0.364  0.703  0.485  1.0
  H  H28  1  0.525  0.126  0.904  1.0
  H  H29  1  0.475  0.874  0.404  1.0
  H  H30  1  0.382  0.324  0.203  1.0
  H  H31  1  0.618  0.676  0.703  1.0
  H  H32  1  0.393  0.489  0.106  1.0
  H  H33  1  0.607  0.511  0.606  1.0
  C  C34  1  0.300  0.377  0.132  1.0
  C  C35  1  0.700  0.623  0.632  1.0
  C  C36  1  0.238  0.368  0.874  1.0
  C  C37  1  0.762  0.632  0.374  1.0
  C  C38  1  0.519  0.191  0.988  1.0
  C  C39  1  0.481  0.809  0.488  1.0
  N  N40  1  0.098  0.403  0.182  1.0
  N  N41  1  0.902  0.597  0.682  1.0
  Cl  Cl42  1  0.252  0.812  0.165  1.0
  Cl  Cl43  1  0.748  0.188  0.665  1.0
  Cl  Cl44  1  0.834  0.577  0.983  1.0
  Cl  Cl45  1  0.166  0.423  0.483  1.0
  Cl  Cl46  1  0.259  0.839  0.820  1.0
  Cl  Cl47  1  0.741  0.161  0.320  1.0
  O  O48  1  0.090  0.116  0.021  1.0
  O  O49  1  0.910  0.884  0.521  1.0
  O  O50  1  0.786  0.906  0.847  1.0
  O  O51  1  0.214  0.094  0.347  1.0
  O  O52  1  0.759  0.897  0.130  1.0
  O  O53  1  0.241  0.103  0.630  1.0
[/CIF]
.