The material structure described by SmCo2P2 crystallizes in the tetragonal I4/mmm space group. Sm(1) is bonded in a 16-coordinate geometry to eight equivalent Co(1) and eight equivalent P(1) atoms. Co(1) is bonded to four equivalent Sm(1) and four equivalent P(1) atoms to form a mixture of distorted corner, edge, and face-sharing CoSm4P4 tetrahedra. P(1) is bonded in a 4-coordinate geometry to four equivalent Sm(1) and four equivalent Co(1) atoms. is represented by the CIF card [CIF]
data_Sm(CoP)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.874
_cell_length_b   3.874
_cell_length_c   5.489
_cell_angle_alpha   110.664
_cell_angle_beta   110.664
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   71.378
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sm  Sm0  1  0.000  0.000  0.000  1.0
  Co  Co1  1  0.250  0.750  0.500  1.0
  Co  Co2  1  0.750  0.250  0.500  1.0
  P  P3  1  0.367  0.367  0.734  1.0
  P  P4  1  0.633  0.633  0.266  1.0
[/CIF]
.
The material structure described by SmCo2P2 crystallizes in the tetragonal I4/mmm space group. Sm(1) is bonded in a 16-coordinate geometry to eight equivalent Co(1) and eight equivalent P(1) atoms. Co(1) is bonded to four equivalent Sm(1) and four equivalent P(1) atoms to form a mixture of distorted corner, edge, and face-sharing CoSm4P4 tetrahedra. P(1) is bonded in a 4-coordinate geometry to four equivalent Sm(1) and four equivalent Co(1) atoms. is represented by the CIF card [CIF]
data_Sm(CoP)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.874
_cell_length_b   3.874
_cell_length_c   5.489
_cell_angle_alpha   110.664
_cell_angle_beta   110.664
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   71.378
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sm  Sm0  1  0.000  0.000  0.000  1.0
  Co  Co1  1  0.250  0.750  0.500  1.0
  Co  Co2  1  0.750  0.250  0.500  1.0
  P  P3  1  0.367  0.367  0.734  1.0
  P  P4  1  0.633  0.633  0.266  1.0
[/CIF]
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