The material described by Ag(AuF4)2 crystallizes in the monoclinic P2_1/c space group. Au(1) is bonded in a rectangular see-saw-like geometry to one F(1), one F(2), one F(3), and one F(4) atom. Ag(1) is bonded in a distorted octahedral geometry to two equivalent F(2), two equivalent F(3), and two equivalent F(4) atoms. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Au(1) atom. In the second F site, F(2) is bonded in a bent 120 degrees geometry to one Au(1) and one Ag(1) atom. In the third F site, F(3) is bonded in a bent 120 degrees geometry to one Au(1) and one Ag(1) atom. In the fourth F site, F(4) is bonded in a bent 120 degrees geometry to one Au(1) and one Ag(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ag(AuF4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.976
_cell_length_b   5.175
_cell_length_c   7.207
_cell_angle_alpha   49.823
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   312.794
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.500  0.500  0.500  1.0
  Ag  Ag1  1  0.000  0.500  0.000  1.0
  Au  Au2  1  0.680  0.251  0.028  1.0
  Au  Au3  1  0.180  0.749  0.472  1.0
  Au  Au4  1  0.820  0.251  0.528  1.0
  Au  Au5  1  0.320  0.749  0.972  1.0
  F  F6  1  0.223  0.447  0.259  1.0
  F  F7  1  0.723  0.553  0.241  1.0
  F  F8  1  0.777  0.553  0.741  1.0
  F  F9  1  0.277  0.447  0.759  1.0
  F  F10  1  0.169  0.906  0.790  1.0
  F  F11  1  0.669  0.094  0.710  1.0
  F  F12  1  0.088  0.038  0.166  1.0
  F  F13  1  0.588  0.962  0.334  1.0
  F  F14  1  0.912  0.962  0.834  1.0
  F  F15  1  0.412  0.038  0.666  1.0
  F  F16  1  0.028  0.598  0.656  1.0
  F  F17  1  0.528  0.402  0.844  1.0
  F  F18  1  0.972  0.402  0.344  1.0
  F  F19  1  0.472  0.598  0.156  1.0
  F  F20  1  0.331  0.906  0.290  1.0
  F  F21  1  0.831  0.094  0.210  1.0
[/CIF]
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The material described by Ag(AuF4)2 crystallizes in the monoclinic P2_1/c space group. Au(1) is bonded in a rectangular see-saw-like geometry to one F(1), one F(2), one F(3), and one F(4) atom. Ag(1) is bonded in a distorted octahedral geometry to two equivalent F(2), two equivalent F(3), and two equivalent F(4) atoms. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Au(1) atom. In the second F site, F(2) is bonded in a bent 120 degrees geometry to one Au(1) and one Ag(1) atom. In the third F site, F(3) is bonded in a bent 120 degrees geometry to one Au(1) and one Ag(1) atom. In the fourth F site, F(4) is bonded in a bent 120 degrees geometry to one Au(1) and one Ag(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ag(AuF4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.976
_cell_length_b   5.175
_cell_length_c   7.207
_cell_angle_alpha   49.823
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   312.794
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.500  0.500  0.500  1.0
  Ag  Ag1  1  0.000  0.500  0.000  1.0
  Au  Au2  1  0.680  0.251  0.028  1.0
  Au  Au3  1  0.180  0.749  0.472  1.0
  Au  Au4  1  0.820  0.251  0.528  1.0
  Au  Au5  1  0.320  0.749  0.972  1.0
  F  F6  1  0.223  0.447  0.259  1.0
  F  F7  1  0.723  0.553  0.241  1.0
  F  F8  1  0.777  0.553  0.741  1.0
  F  F9  1  0.277  0.447  0.759  1.0
  F  F10  1  0.169  0.906  0.790  1.0
  F  F11  1  0.669  0.094  0.710  1.0
  F  F12  1  0.088  0.038  0.166  1.0
  F  F13  1  0.588  0.962  0.334  1.0
  F  F14  1  0.912  0.962  0.834  1.0
  F  F15  1  0.412  0.038  0.666  1.0
  F  F16  1  0.028  0.598  0.656  1.0
  F  F17  1  0.528  0.402  0.844  1.0
  F  F18  1  0.972  0.402  0.344  1.0
  F  F19  1  0.472  0.598  0.156  1.0
  F  F20  1  0.331  0.906  0.290  1.0
  F  F21  1  0.831  0.094  0.210  1.0
[/CIF]
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