The crystal structure described by Pt(NO)2NO2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two nitrous acid molecules and one Pt(NO)2 cluster. In the Pt(NO)2 cluster, Pt(1) is bonded in a rectangular see-saw-like geometry to one N(1), one N(2), and two equivalent O(1) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Pt(1) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one Pt(1) and one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to two equivalent Pt(1) atoms. In the second O site, O(2) is bonded in a single-bond geometry to one N(2) atom. is represented by the CIF file [CIF]
data_PtN3O4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.157
_cell_length_b   8.709
_cell_length_c   7.364
_cell_angle_alpha   81.261
_cell_angle_beta   135.358
_cell_angle_gamma   107.964
_symmetry_Int_Tables_number   1
_cell_volume   305.259
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pt  Pt0  1  0.751  0.644  0.093  1.0
  Pt  Pt1  1  0.249  0.356  0.907  1.0
  N  N2  1  0.790  0.856  0.064  1.0
  N  N3  1  0.210  0.144  0.936  1.0
  N  N4  1  0.140  0.672  0.275  1.0
  N  N5  1  0.860  0.328  0.725  1.0
  N  N6  1  0.694  0.851  0.485  1.0
  N  N7  1  0.306  0.149  0.515  1.0
  O  O8  1  0.635  0.408  0.054  1.0
  O  O9  1  0.365  0.592  0.946  1.0
  O  O10  1  0.251  0.778  0.231  1.0
  O  O11  1  0.749  0.222  0.769  1.0
  O  O12  1  0.829  0.765  0.645  1.0
  O  O13  1  0.171  0.235  0.355  1.0
  O  O14  1  0.742  0.987  0.436  1.0
  O  O15  1  0.258  0.013  0.564  1.0
[/CIF]
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The crystal structure described by Pt(NO)2NO2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two nitrous acid molecules and one Pt(NO)2 cluster. In the Pt(NO)2 cluster, Pt(1) is bonded in a rectangular see-saw-like geometry to one N(1), one N(2), and two equivalent O(1) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Pt(1) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one Pt(1) and one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to two equivalent Pt(1) atoms. In the second O site, O(2) is bonded in a single-bond geometry to one N(2) atom. is represented by the CIF file [CIF]
data_PtN3O4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.157
_cell_length_b   8.709
_cell_length_c   7.364
_cell_angle_alpha   81.261
_cell_angle_beta   135.358
_cell_angle_gamma   107.964
_symmetry_Int_Tables_number   1
_cell_volume   305.259
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pt  Pt0  1  0.751  0.644  0.093  1.0
  Pt  Pt1  1  0.249  0.356  0.907  1.0
  N  N2  1  0.790  0.856  0.064  1.0
  N  N3  1  0.210  0.144  0.936  1.0
  N  N4  1  0.140  0.672  0.275  1.0
  N  N5  1  0.860  0.328  0.725  1.0
  N  N6  1  0.694  0.851  0.485  1.0
  N  N7  1  0.306  0.149  0.515  1.0
  O  O8  1  0.635  0.408  0.054  1.0
  O  O9  1  0.365  0.592  0.946  1.0
  O  O10  1  0.251  0.778  0.231  1.0
  O  O11  1  0.749  0.222  0.769  1.0
  O  O12  1  0.829  0.765  0.645  1.0
  O  O13  1  0.171  0.235  0.355  1.0
  O  O14  1  0.742  0.987  0.436  1.0
  O  O15  1  0.258  0.013  0.564  1.0
[/CIF]
.