The crystal structure described by LiV(OF)2 crystallizes in the monoclinic P2_1 space group. Li(1) is bonded to one O(2), two equivalent F(1), and three equivalent F(2) atoms to form distorted edge-sharing LiOF5 octahedra. V(1) is bonded in a 5-coordinate geometry to one O(2), two equivalent O(1), one F(1), and one F(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to two equivalent V(1) atoms. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Li(1) and one V(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to two equivalent Li(1) and one V(1) atom. In the second F site, F(2) is bonded in a 4-coordinate geometry to three equivalent Li(1) and one V(1) atom. is represented by the CIF file [CIF]
data_LiV(OF)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.150
_cell_length_b   3.477
_cell_length_c   6.570
_cell_angle_alpha   90.000
_cell_angle_beta   111.633
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   130.614
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.330  0.242  0.801  1.0
  Li  Li1  1  0.670  0.742  0.199  1.0
  V  V2  1  0.152  0.240  0.234  1.0
  V  V3  1  0.848  0.740  0.766  1.0
  O  O4  1  0.097  0.740  0.151  1.0
  O  O5  1  0.308  0.240  0.490  1.0
  O  O6  1  0.692  0.740  0.510  1.0
  O  O7  1  0.903  0.240  0.849  1.0
  F  F8  1  0.146  0.740  0.747  1.0
  F  F9  1  0.609  0.740  0.885  1.0
  F  F10  1  0.391  0.240  0.115  1.0
  F  F11  1  0.854  0.240  0.253  1.0
[/CIF]
.
The crystal structure described by LiV(OF)2 crystallizes in the monoclinic P2_1 space group. Li(1) is bonded to one O(2), two equivalent F(1), and three equivalent F(2) atoms to form distorted edge-sharing LiOF5 octahedra. V(1) is bonded in a 5-coordinate geometry to one O(2), two equivalent O(1), one F(1), and one F(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to two equivalent V(1) atoms. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Li(1) and one V(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to two equivalent Li(1) and one V(1) atom. In the second F site, F(2) is bonded in a 4-coordinate geometry to three equivalent Li(1) and one V(1) atom. is represented by the CIF file [CIF]
data_LiV(OF)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.150
_cell_length_b   3.477
_cell_length_c   6.570
_cell_angle_alpha   90.000
_cell_angle_beta   111.633
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   130.614
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.330  0.242  0.801  1.0
  Li  Li1  1  0.670  0.742  0.199  1.0
  V  V2  1  0.152  0.240  0.234  1.0
  V  V3  1  0.848  0.740  0.766  1.0
  O  O4  1  0.097  0.740  0.151  1.0
  O  O5  1  0.308  0.240  0.490  1.0
  O  O6  1  0.692  0.740  0.510  1.0
  O  O7  1  0.903  0.240  0.849  1.0
  F  F8  1  0.146  0.740  0.747  1.0
  F  F9  1  0.609  0.740  0.885  1.0
  F  F10  1  0.391  0.240  0.115  1.0
  F  F11  1  0.854  0.240  0.253  1.0
[/CIF]
.