The compound described by NaHoO2 crystallizes in the tetragonal I4_1/amd space group. Na(1) is bonded to six O(1,1,1,1) atoms to form distorted NaO6 octahedra that share corners with two equivalent Ho(1)O6 octahedra, corners with four equivalent Na(1)O6 octahedra, edges with four equivalent Na(1)O6 octahedra, and edges with eight equivalent Ho(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-14°. Ho(1) is bonded to six O(1,1,1,1) atoms to form HoO6 octahedra that share corners with two equivalent Na(1)O6 octahedra, corners with four equivalent Ho(1)O6 octahedra, edges with four equivalent Ho(1)O6 octahedra, and edges with eight equivalent Na(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-14°. There are five inequivalent O sites. In the first O site, O(1) is bonded to three equivalent Na(1) and three equivalent Ho(1) atoms to form a mixture of distorted corner and edge-sharing ONa3Ho3 octahedra. The corner-sharing octahedral tilt angles range from 0-14°. In the second O site, O(1) is bonded to three equivalent Na(1) and three equivalent Ho(1) atoms to form a mixture of distorted corner and edge-sharing ONa3Ho3 octahedra. The corner-sharing octahedral tilt angles range from 0-14°. In the third O site, O(1) is bonded to three equivalent Na(1) and three equivalent Ho(1) atoms to form a mixture of distorted corner and edge-sharing ONa3Ho3 octahedra. The corner-sharing octahedral tilt angles range from 0-14°. In the fourth O site, O(1) is bonded to three equivalent Na(1) and three equivalent Ho(1) atoms to form a mixture of distorted corner and edge-sharing ONa3Ho3 octahedra. The corner-sharing octahedral tilt angles range from 0-14°. In the fifth O site, O(1) is bonded to three equivalent Na(1) and three equivalent Ho(1) atoms to form a mixture of distorted corner and edge-sharing ONa3Ho3 octahedra. The corner-sharing octahedral tilt angles range from 0-14°. is represented by the CIF file [CIF]
data_NaHoO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.011
_cell_length_b   6.011
_cell_length_c   6.011
_cell_angle_alpha   135.344
_cell_angle_beta   135.344
_cell_angle_gamma   64.996
_symmetry_Int_Tables_number   1
_cell_volume   105.752
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.000  0.000  0.000  1.0
  Na  Na1  1  0.750  0.250  0.500  1.0
  Ho  Ho2  1  0.500  0.500  0.000  1.0
  Ho  Ho3  1  0.250  0.750  0.500  1.0
  O  O4  1  0.473  0.973  0.500  1.0
  O  O5  1  0.277  0.277  0.000  1.0
  O  O6  1  0.723  0.723  0.000  1.0
  O  O7  1  0.027  0.527  0.500  1.0
[/CIF]
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The compound described by NaHoO2 crystallizes in the tetragonal I4_1/amd space group. Na(1) is bonded to six O(1,1,1,1) atoms to form distorted NaO6 octahedra that share corners with two equivalent Ho(1)O6 octahedra, corners with four equivalent Na(1)O6 octahedra, edges with four equivalent Na(1)O6 octahedra, and edges with eight equivalent Ho(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-14°. Ho(1) is bonded to six O(1,1,1,1) atoms to form HoO6 octahedra that share corners with two equivalent Na(1)O6 octahedra, corners with four equivalent Ho(1)O6 octahedra, edges with four equivalent Ho(1)O6 octahedra, and edges with eight equivalent Na(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-14°. There are five inequivalent O sites. In the first O site, O(1) is bonded to three equivalent Na(1) and three equivalent Ho(1) atoms to form a mixture of distorted corner and edge-sharing ONa3Ho3 octahedra. The corner-sharing octahedral tilt angles range from 0-14°. In the second O site, O(1) is bonded to three equivalent Na(1) and three equivalent Ho(1) atoms to form a mixture of distorted corner and edge-sharing ONa3Ho3 octahedra. The corner-sharing octahedral tilt angles range from 0-14°. In the third O site, O(1) is bonded to three equivalent Na(1) and three equivalent Ho(1) atoms to form a mixture of distorted corner and edge-sharing ONa3Ho3 octahedra. The corner-sharing octahedral tilt angles range from 0-14°. In the fourth O site, O(1) is bonded to three equivalent Na(1) and three equivalent Ho(1) atoms to form a mixture of distorted corner and edge-sharing ONa3Ho3 octahedra. The corner-sharing octahedral tilt angles range from 0-14°. In the fifth O site, O(1) is bonded to three equivalent Na(1) and three equivalent Ho(1) atoms to form a mixture of distorted corner and edge-sharing ONa3Ho3 octahedra. The corner-sharing octahedral tilt angles range from 0-14°. is represented by the CIF file [CIF]
data_NaHoO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.011
_cell_length_b   6.011
_cell_length_c   6.011
_cell_angle_alpha   135.344
_cell_angle_beta   135.344
_cell_angle_gamma   64.996
_symmetry_Int_Tables_number   1
_cell_volume   105.752
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.000  0.000  0.000  1.0
  Na  Na1  1  0.750  0.250  0.500  1.0
  Ho  Ho2  1  0.500  0.500  0.000  1.0
  Ho  Ho3  1  0.250  0.750  0.500  1.0
  O  O4  1  0.473  0.973  0.500  1.0
  O  O5  1  0.277  0.277  0.000  1.0
  O  O6  1  0.723  0.723  0.000  1.0
  O  O7  1  0.027  0.527  0.500  1.0
[/CIF]
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