The crystal structure described by Li4Mn3P3O12F crystallizes in the cubic P-43n space group. Li(1) is bonded to three equivalent O(1) and one F(1) atom to form LiO3F tetrahedra that share corners with three equivalent Li(1)O3F tetrahedra, corners with three equivalent Mn(1)O4 tetrahedra, and corners with three equivalent P(1)O4 tetrahedra. Mn(1) is bonded to four equivalent O(1) atoms to form MnO4 tetrahedra that share corners with four equivalent Li(1)O3F tetrahedra and corners with four equivalent P(1)O4 tetrahedra. P(1) is bonded to four equivalent O(1) atoms to form PO4 tetrahedra that share corners with four equivalent Li(1)O3F tetrahedra and corners with four equivalent Mn(1)O4 tetrahedra. O(1) is bonded in a distorted trigonal planar geometry to one Li(1), one Mn(1), and one P(1) atom. F(1) is bonded in a tetrahedral geometry to four equivalent Li(1) atoms. is represented by the CIF file [CIF]
data_Li4Mn3P3O12F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.505
_cell_length_b   8.505
_cell_length_c   8.505
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   615.177
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.142  0.142  0.142  1.0
  Li  Li1  1  0.142  0.858  0.858  1.0
  Li  Li2  1  0.358  0.358  0.642  1.0
  Li  Li3  1  0.358  0.642  0.358  1.0
  Li  Li4  1  0.642  0.358  0.358  1.0
  Li  Li5  1  0.642  0.642  0.642  1.0
  Li  Li6  1  0.858  0.142  0.858  1.0
  Li  Li7  1  0.858  0.858  0.142  1.0
  Mn  Mn8  1  0.000  0.500  0.250  1.0
  Mn  Mn9  1  0.000  0.500  0.750  1.0
  Mn  Mn10  1  0.250  0.000  0.500  1.0
  Mn  Mn11  1  0.500  0.250  0.000  1.0
  Mn  Mn12  1  0.500  0.750  0.000  1.0
  Mn  Mn13  1  0.750  0.000  0.500  1.0
  P  P14  1  0.000  0.250  0.500  1.0
  P  P15  1  0.000  0.750  0.500  1.0
  P  P16  1  0.250  0.500  0.000  1.0
  P  P17  1  0.500  0.000  0.250  1.0
  P  P18  1  0.500  0.000  0.750  1.0
  P  P19  1  0.750  0.500  0.000  1.0
  O  O20  1  0.118  0.351  0.597  1.0
  O  O21  1  0.118  0.649  0.403  1.0
  O  O22  1  0.097  0.149  0.382  1.0
  O  O23  1  0.097  0.851  0.618  1.0
  O  O24  1  0.149  0.382  0.097  1.0
  O  O25  1  0.149  0.618  0.903  1.0
  O  O26  1  0.351  0.403  0.882  1.0
  O  O27  1  0.351  0.597  0.118  1.0
  O  O28  1  0.403  0.118  0.649  1.0
  O  O29  1  0.403  0.882  0.351  1.0
  O  O30  1  0.382  0.097  0.149  1.0
  O  O31  1  0.382  0.903  0.851  1.0
  O  O32  1  0.618  0.097  0.851  1.0
  O  O33  1  0.618  0.903  0.149  1.0
  O  O34  1  0.597  0.882  0.649  1.0
  O  O35  1  0.597  0.118  0.351  1.0
  O  O36  1  0.649  0.597  0.882  1.0
  O  O37  1  0.649  0.403  0.118  1.0
  O  O38  1  0.851  0.382  0.903  1.0
  O  O39  1  0.851  0.618  0.097  1.0
  O  O40  1  0.903  0.149  0.618  1.0
  O  O41  1  0.903  0.851  0.382  1.0
  O  O42  1  0.882  0.351  0.403  1.0
  O  O43  1  0.882  0.649  0.597  1.0
  F  F44  1  0.000  0.000  0.000  1.0
  F  F45  1  0.500  0.500  0.500  1.0
[/CIF]
.
The crystal structure described by Li4Mn3P3O12F crystallizes in the cubic P-43n space group. Li(1) is bonded to three equivalent O(1) and one F(1) atom to form LiO3F tetrahedra that share corners with three equivalent Li(1)O3F tetrahedra, corners with three equivalent Mn(1)O4 tetrahedra, and corners with three equivalent P(1)O4 tetrahedra. Mn(1) is bonded to four equivalent O(1) atoms to form MnO4 tetrahedra that share corners with four equivalent Li(1)O3F tetrahedra and corners with four equivalent P(1)O4 tetrahedra. P(1) is bonded to four equivalent O(1) atoms to form PO4 tetrahedra that share corners with four equivalent Li(1)O3F tetrahedra and corners with four equivalent Mn(1)O4 tetrahedra. O(1) is bonded in a distorted trigonal planar geometry to one Li(1), one Mn(1), and one P(1) atom. F(1) is bonded in a tetrahedral geometry to four equivalent Li(1) atoms. is represented by the CIF file [CIF]
data_Li4Mn3P3O12F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.505
_cell_length_b   8.505
_cell_length_c   8.505
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   615.177
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.142  0.142  0.142  1.0
  Li  Li1  1  0.142  0.858  0.858  1.0
  Li  Li2  1  0.358  0.358  0.642  1.0
  Li  Li3  1  0.358  0.642  0.358  1.0
  Li  Li4  1  0.642  0.358  0.358  1.0
  Li  Li5  1  0.642  0.642  0.642  1.0
  Li  Li6  1  0.858  0.142  0.858  1.0
  Li  Li7  1  0.858  0.858  0.142  1.0
  Mn  Mn8  1  0.000  0.500  0.250  1.0
  Mn  Mn9  1  0.000  0.500  0.750  1.0
  Mn  Mn10  1  0.250  0.000  0.500  1.0
  Mn  Mn11  1  0.500  0.250  0.000  1.0
  Mn  Mn12  1  0.500  0.750  0.000  1.0
  Mn  Mn13  1  0.750  0.000  0.500  1.0
  P  P14  1  0.000  0.250  0.500  1.0
  P  P15  1  0.000  0.750  0.500  1.0
  P  P16  1  0.250  0.500  0.000  1.0
  P  P17  1  0.500  0.000  0.250  1.0
  P  P18  1  0.500  0.000  0.750  1.0
  P  P19  1  0.750  0.500  0.000  1.0
  O  O20  1  0.118  0.351  0.597  1.0
  O  O21  1  0.118  0.649  0.403  1.0
  O  O22  1  0.097  0.149  0.382  1.0
  O  O23  1  0.097  0.851  0.618  1.0
  O  O24  1  0.149  0.382  0.097  1.0
  O  O25  1  0.149  0.618  0.903  1.0
  O  O26  1  0.351  0.403  0.882  1.0
  O  O27  1  0.351  0.597  0.118  1.0
  O  O28  1  0.403  0.118  0.649  1.0
  O  O29  1  0.403  0.882  0.351  1.0
  O  O30  1  0.382  0.097  0.149  1.0
  O  O31  1  0.382  0.903  0.851  1.0
  O  O32  1  0.618  0.097  0.851  1.0
  O  O33  1  0.618  0.903  0.149  1.0
  O  O34  1  0.597  0.882  0.649  1.0
  O  O35  1  0.597  0.118  0.351  1.0
  O  O36  1  0.649  0.597  0.882  1.0
  O  O37  1  0.649  0.403  0.118  1.0
  O  O38  1  0.851  0.382  0.903  1.0
  O  O39  1  0.851  0.618  0.097  1.0
  O  O40  1  0.903  0.149  0.618  1.0
  O  O41  1  0.903  0.851  0.382  1.0
  O  O42  1  0.882  0.351  0.403  1.0
  O  O43  1  0.882  0.649  0.597  1.0
  F  F44  1  0.000  0.000  0.000  1.0
  F  F45  1  0.500  0.500  0.500  1.0
[/CIF]
.