The structure described by Rb6Na4Tl13 crystallizes in the cubic Im-3 space group. Rb(1) is bonded in a 6-coordinate geometry to eight equivalent Tl(1) atoms. Na(1) is bonded in a distorted hexagonal planar geometry to six equivalent Tl(1) atoms. There are two inequivalent Tl sites. In the first Tl site, Tl(2) is bonded in a cuboctahedral geometry to twelve equivalent Tl(1) atoms. In the second Tl site, Tl(1) is bonded in a 12-coordinate geometry to four equivalent Rb(1), two equivalent Na(1), one Tl(2), and five equivalent Tl(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Rb6Na4Tl13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.165
_cell_length_b   10.165
_cell_length_c   10.165
_cell_angle_alpha   109.471
_cell_angle_beta   109.471
_cell_angle_gamma   109.471
_symmetry_Int_Tables_number   1
_cell_volume   808.444
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.829  0.329  0.500  1.0
  Rb  Rb1  1  0.171  0.671  0.500  1.0
  Rb  Rb2  1  0.329  0.500  0.829  1.0
  Rb  Rb3  1  0.671  0.500  0.171  1.0
  Rb  Rb4  1  0.500  0.829  0.329  1.0
  Rb  Rb5  1  0.500  0.171  0.671  1.0
  Na  Na6  1  0.500  0.500  0.500  1.0
  Na  Na7  1  0.500  0.000  0.000  1.0
  Na  Na8  1  0.000  0.500  0.000  1.0
  Na  Na9  1  0.000  0.000  0.500  1.0
  Tl  Tl10  1  0.859  0.762  0.621  1.0
  Tl  Tl11  1  0.141  0.238  0.379  1.0
  Tl  Tl12  1  0.141  0.762  0.903  1.0
  Tl  Tl13  1  0.859  0.238  0.097  1.0
  Tl  Tl14  1  0.762  0.621  0.859  1.0
  Tl  Tl15  1  0.238  0.379  0.141  1.0
  Tl  Tl16  1  0.762  0.903  0.141  1.0
  Tl  Tl17  1  0.238  0.097  0.859  1.0
  Tl  Tl18  1  0.621  0.859  0.762  1.0
  Tl  Tl19  1  0.379  0.141  0.238  1.0
  Tl  Tl20  1  0.097  0.859  0.238  1.0
  Tl  Tl21  1  0.903  0.141  0.762  1.0
  Tl  Tl22  1  0.000  0.000  0.000  1.0
[/CIF]
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The structure described by Rb6Na4Tl13 crystallizes in the cubic Im-3 space group. Rb(1) is bonded in a 6-coordinate geometry to eight equivalent Tl(1) atoms. Na(1) is bonded in a distorted hexagonal planar geometry to six equivalent Tl(1) atoms. There are two inequivalent Tl sites. In the first Tl site, Tl(2) is bonded in a cuboctahedral geometry to twelve equivalent Tl(1) atoms. In the second Tl site, Tl(1) is bonded in a 12-coordinate geometry to four equivalent Rb(1), two equivalent Na(1), one Tl(2), and five equivalent Tl(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Rb6Na4Tl13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.165
_cell_length_b   10.165
_cell_length_c   10.165
_cell_angle_alpha   109.471
_cell_angle_beta   109.471
_cell_angle_gamma   109.471
_symmetry_Int_Tables_number   1
_cell_volume   808.444
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.829  0.329  0.500  1.0
  Rb  Rb1  1  0.171  0.671  0.500  1.0
  Rb  Rb2  1  0.329  0.500  0.829  1.0
  Rb  Rb3  1  0.671  0.500  0.171  1.0
  Rb  Rb4  1  0.500  0.829  0.329  1.0
  Rb  Rb5  1  0.500  0.171  0.671  1.0
  Na  Na6  1  0.500  0.500  0.500  1.0
  Na  Na7  1  0.500  0.000  0.000  1.0
  Na  Na8  1  0.000  0.500  0.000  1.0
  Na  Na9  1  0.000  0.000  0.500  1.0
  Tl  Tl10  1  0.859  0.762  0.621  1.0
  Tl  Tl11  1  0.141  0.238  0.379  1.0
  Tl  Tl12  1  0.141  0.762  0.903  1.0
  Tl  Tl13  1  0.859  0.238  0.097  1.0
  Tl  Tl14  1  0.762  0.621  0.859  1.0
  Tl  Tl15  1  0.238  0.379  0.141  1.0
  Tl  Tl16  1  0.762  0.903  0.141  1.0
  Tl  Tl17  1  0.238  0.097  0.859  1.0
  Tl  Tl18  1  0.621  0.859  0.762  1.0
  Tl  Tl19  1  0.379  0.141  0.238  1.0
  Tl  Tl20  1  0.097  0.859  0.238  1.0
  Tl  Tl21  1  0.903  0.141  0.762  1.0
  Tl  Tl22  1  0.000  0.000  0.000  1.0
[/CIF]
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