The structure described by U2Ru2RhSi5 crystallizes in the monoclinic C2/c space group. U(1) is bonded in a 16-coordinate geometry to four equivalent Ru(1), two equivalent Rh(1), two equivalent Si(2), two equivalent Si(3), two equivalent Si(4), and four equivalent Si(1) atoms. Ru(1) is bonded in a 5-coordinate geometry to four equivalent U(1), one Si(1), one Si(3), one Si(4), and two equivalent Si(2) atoms. Rh(1) is bonded in a 6-coordinate geometry to four equivalent U(1), one Si(3), one Si(4), and four equivalent Si(1) atoms. There are four inequivalent Si sites. In the first Si site, Si(1) is bonded in a 9-coordinate geometry to four equivalent U(1), one Ru(1), two equivalent Rh(1), one Si(3), and one Si(4) atom. In the second Si site, Si(2) is bonded in a 4-coordinate geometry to four equivalent U(1) and four equivalent Ru(1) atoms. In the third Si site, Si(3) is bonded in a 3-coordinate geometry to four equivalent U(1), two equivalent Ru(1), one Rh(1), and two equivalent Si(1) atoms. In the fourth Si site, Si(4) is bonded in a 3-coordinate geometry to four equivalent U(1), two equivalent Ru(1), one Rh(1), and two equivalent Si(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_U2Si5Ru2Rh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.130
_cell_length_b   8.130
_cell_length_c   5.646
_cell_angle_alpha   70.801
_cell_angle_beta   70.801
_cell_angle_gamma   92.852
_symmetry_Int_Tables_number   1
_cell_volume   327.600
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  U  U0  1  0.866  0.592  0.767  1.0
  U  U1  1  0.408  0.134  0.733  1.0
  U  U2  1  0.134  0.408  0.233  1.0
  U  U3  1  0.592  0.866  0.267  1.0
  Si  Si4  1  0.061  0.266  0.835  1.0
  Si  Si5  1  0.734  0.939  0.665  1.0
  Si  Si6  1  0.939  0.734  0.165  1.0
  Si  Si7  1  0.266  0.061  0.335  1.0
  Si  Si8  1  0.514  0.486  0.750  1.0
  Si  Si9  1  0.486  0.514  0.250  1.0
  Si  Si10  1  0.207  0.793  0.750  1.0
  Si  Si11  1  0.793  0.207  0.250  1.0
  Si  Si12  1  0.777  0.223  0.750  1.0
  Si  Si13  1  0.223  0.777  0.250  1.0
  Ru  Ru14  1  0.254  0.541  0.634  1.0
  Ru  Ru15  1  0.459  0.746  0.866  1.0
  Ru  Ru16  1  0.746  0.459  0.366  1.0
  Ru  Ru17  1  0.541  0.254  0.134  1.0
  Rh  Rh18  1  1.000  0.000  0.750  1.0
  Rh  Rh19  1  0.000  1.000  0.250  1.0
[/CIF]
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The structure described by U2Ru2RhSi5 crystallizes in the monoclinic C2/c space group. U(1) is bonded in a 16-coordinate geometry to four equivalent Ru(1), two equivalent Rh(1), two equivalent Si(2), two equivalent Si(3), two equivalent Si(4), and four equivalent Si(1) atoms. Ru(1) is bonded in a 5-coordinate geometry to four equivalent U(1), one Si(1), one Si(3), one Si(4), and two equivalent Si(2) atoms. Rh(1) is bonded in a 6-coordinate geometry to four equivalent U(1), one Si(3), one Si(4), and four equivalent Si(1) atoms. There are four inequivalent Si sites. In the first Si site, Si(1) is bonded in a 9-coordinate geometry to four equivalent U(1), one Ru(1), two equivalent Rh(1), one Si(3), and one Si(4) atom. In the second Si site, Si(2) is bonded in a 4-coordinate geometry to four equivalent U(1) and four equivalent Ru(1) atoms. In the third Si site, Si(3) is bonded in a 3-coordinate geometry to four equivalent U(1), two equivalent Ru(1), one Rh(1), and two equivalent Si(1) atoms. In the fourth Si site, Si(4) is bonded in a 3-coordinate geometry to four equivalent U(1), two equivalent Ru(1), one Rh(1), and two equivalent Si(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_U2Si5Ru2Rh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.130
_cell_length_b   8.130
_cell_length_c   5.646
_cell_angle_alpha   70.801
_cell_angle_beta   70.801
_cell_angle_gamma   92.852
_symmetry_Int_Tables_number   1
_cell_volume   327.600
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  U  U0  1  0.866  0.592  0.767  1.0
  U  U1  1  0.408  0.134  0.733  1.0
  U  U2  1  0.134  0.408  0.233  1.0
  U  U3  1  0.592  0.866  0.267  1.0
  Si  Si4  1  0.061  0.266  0.835  1.0
  Si  Si5  1  0.734  0.939  0.665  1.0
  Si  Si6  1  0.939  0.734  0.165  1.0
  Si  Si7  1  0.266  0.061  0.335  1.0
  Si  Si8  1  0.514  0.486  0.750  1.0
  Si  Si9  1  0.486  0.514  0.250  1.0
  Si  Si10  1  0.207  0.793  0.750  1.0
  Si  Si11  1  0.793  0.207  0.250  1.0
  Si  Si12  1  0.777  0.223  0.750  1.0
  Si  Si13  1  0.223  0.777  0.250  1.0
  Ru  Ru14  1  0.254  0.541  0.634  1.0
  Ru  Ru15  1  0.459  0.746  0.866  1.0
  Ru  Ru16  1  0.746  0.459  0.366  1.0
  Ru  Ru17  1  0.541  0.254  0.134  1.0
  Rh  Rh18  1  1.000  0.000  0.750  1.0
  Rh  Rh19  1  0.000  1.000  0.250  1.0
[/CIF]
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