The material described by Ag2PHO4 crystallizes in the trigonal P3_112 space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to two equivalent O(1) and two equivalent O(2) atoms. In the second Ag site, Ag(2) is bonded in a distorted linear geometry to two equivalent O(1) atoms. P(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. H(1) is bonded in a linear geometry to two equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Ag(1), one Ag(2), and one P(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Ag(1), one P(1), and one H(1) atom. is represented by the CIF card [CIF]
data_Ag2PHO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.283
_cell_length_b   6.283
_cell_length_c   9.090
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   310.719
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.152  0.076  0.000  1.0
  Ag  Ag1  1  0.924  0.076  0.333  1.0
  Ag  Ag2  1  0.924  0.848  0.667  1.0
  Ag  Ag3  1  0.596  0.798  0.000  1.0
  Ag  Ag4  1  0.202  0.798  0.333  1.0
  Ag  Ag5  1  0.202  0.404  0.667  1.0
  P  P6  1  0.975  0.487  0.000  1.0
  P  P7  1  0.513  0.487  0.333  1.0
  P  P8  1  0.513  0.025  0.667  1.0
  H  H9  1  0.641  0.281  0.167  1.0
  H  H10  1  0.719  0.359  0.500  1.0
  H  H11  1  0.641  0.359  0.833  1.0
  O  O12  1  0.137  0.406  0.916  1.0
  O  O13  1  0.594  0.731  0.250  1.0
  O  O14  1  0.269  0.863  0.583  1.0
  O  O15  1  0.137  0.731  0.084  1.0
  O  O16  1  0.594  0.863  0.750  1.0
  O  O17  1  0.269  0.406  0.417  1.0
  O  O18  1  0.807  0.272  0.107  1.0
  O  O19  1  0.728  0.535  0.440  1.0
  O  O20  1  0.465  0.193  0.774  1.0
  O  O21  1  0.807  0.535  0.893  1.0
  O  O22  1  0.728  0.193  0.560  1.0
  O  O23  1  0.465  0.272  0.226  1.0
[/CIF]
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The material described by Ag2PHO4 crystallizes in the trigonal P3_112 space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to two equivalent O(1) and two equivalent O(2) atoms. In the second Ag site, Ag(2) is bonded in a distorted linear geometry to two equivalent O(1) atoms. P(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. H(1) is bonded in a linear geometry to two equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Ag(1), one Ag(2), and one P(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Ag(1), one P(1), and one H(1) atom. is represented by the CIF card [CIF]
data_Ag2PHO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.283
_cell_length_b   6.283
_cell_length_c   9.090
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   310.719
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.152  0.076  0.000  1.0
  Ag  Ag1  1  0.924  0.076  0.333  1.0
  Ag  Ag2  1  0.924  0.848  0.667  1.0
  Ag  Ag3  1  0.596  0.798  0.000  1.0
  Ag  Ag4  1  0.202  0.798  0.333  1.0
  Ag  Ag5  1  0.202  0.404  0.667  1.0
  P  P6  1  0.975  0.487  0.000  1.0
  P  P7  1  0.513  0.487  0.333  1.0
  P  P8  1  0.513  0.025  0.667  1.0
  H  H9  1  0.641  0.281  0.167  1.0
  H  H10  1  0.719  0.359  0.500  1.0
  H  H11  1  0.641  0.359  0.833  1.0
  O  O12  1  0.137  0.406  0.916  1.0
  O  O13  1  0.594  0.731  0.250  1.0
  O  O14  1  0.269  0.863  0.583  1.0
  O  O15  1  0.137  0.731  0.084  1.0
  O  O16  1  0.594  0.863  0.750  1.0
  O  O17  1  0.269  0.406  0.417  1.0
  O  O18  1  0.807  0.272  0.107  1.0
  O  O19  1  0.728  0.535  0.440  1.0
  O  O20  1  0.465  0.193  0.774  1.0
  O  O21  1  0.807  0.535  0.893  1.0
  O  O22  1  0.728  0.193  0.560  1.0
  O  O23  1  0.465  0.272  0.226  1.0
[/CIF]
.