The crystal structure described by PdSO4 crystallizes in the monoclinic C2/c space group. Pd(1) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent O(2) atoms. S(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Pd(1) and one S(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Pd(1) and one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_PdSO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.913
_cell_length_b   4.913
_cell_length_c   7.778
_cell_angle_alpha   81.865
_cell_angle_beta   81.865
_cell_angle_gamma   80.671
_symmetry_Int_Tables_number   1
_cell_volume   182.045
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pd  Pd0  1  0.000  0.500  0.500  1.0
  Pd  Pd1  1  0.500  0.000  0.000  1.0
  S  S2  1  0.074  0.926  0.750  1.0
  S  S3  1  0.926  0.074  0.250  1.0
  O  O4  1  0.776  0.884  0.790  1.0
  O  O5  1  0.116  0.224  0.710  1.0
  O  O6  1  0.224  0.116  0.210  1.0
  O  O7  1  0.884  0.776  0.290  1.0
  O  O8  1  0.808  0.223  0.405  1.0
  O  O9  1  0.777  0.192  0.095  1.0
  O  O10  1  0.192  0.777  0.595  1.0
  O  O11  1  0.223  0.808  0.905  1.0
[/CIF]
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The crystal structure described by PdSO4 crystallizes in the monoclinic C2/c space group. Pd(1) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent O(2) atoms. S(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Pd(1) and one S(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Pd(1) and one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_PdSO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.913
_cell_length_b   4.913
_cell_length_c   7.778
_cell_angle_alpha   81.865
_cell_angle_beta   81.865
_cell_angle_gamma   80.671
_symmetry_Int_Tables_number   1
_cell_volume   182.045
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pd  Pd0  1  0.000  0.500  0.500  1.0
  Pd  Pd1  1  0.500  0.000  0.000  1.0
  S  S2  1  0.074  0.926  0.750  1.0
  S  S3  1  0.926  0.074  0.250  1.0
  O  O4  1  0.776  0.884  0.790  1.0
  O  O5  1  0.116  0.224  0.710  1.0
  O  O6  1  0.224  0.116  0.210  1.0
  O  O7  1  0.884  0.776  0.290  1.0
  O  O8  1  0.808  0.223  0.405  1.0
  O  O9  1  0.777  0.192  0.095  1.0
  O  O10  1  0.192  0.777  0.595  1.0
  O  O11  1  0.223  0.808  0.905  1.0
[/CIF]
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