The material structure described by AsF6S2ClSCl2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two sulfanyl thiohypochlorite molecules, two sulfur dichloride molecules, and two AsF6 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. There are six inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one As(1) atom. is represented by the CIF file [CIF]
data_AsS3(ClF2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.632
_cell_length_b   7.935
_cell_length_c   10.032
_cell_angle_alpha   82.753
_cell_angle_beta   112.646
_cell_angle_gamma   114.971
_symmetry_Int_Tables_number   1
_cell_volume   507.796
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.793  0.744  0.752  1.0
  As  As1  1  0.207  0.256  0.248  1.0
  S  S2  1  0.548  0.240  0.029  1.0
  S  S3  1  0.334  0.832  0.073  1.0
  S  S4  1  0.083  0.299  0.603  1.0
  S  S5  1  0.917  0.701  0.397  1.0
  S  S6  1  0.452  0.760  0.971  1.0
  S  S7  1  0.666  0.168  0.927  1.0
  Cl  Cl8  1  0.193  0.724  0.532  1.0
  Cl  Cl9  1  0.484  0.831  0.291  1.0
  Cl  Cl10  1  0.807  0.276  0.468  1.0
  Cl  Cl11  1  0.084  0.320  0.798  1.0
  Cl  Cl12  1  0.516  0.169  0.709  1.0
  Cl  Cl13  1  0.916  0.680  0.202  1.0
  F  F14  1  0.707  0.875  0.608  1.0
  F  F15  1  0.535  0.605  0.735  1.0
  F  F16  1  0.051  0.884  0.771  1.0
  F  F17  1  0.220  0.405  0.369  1.0
  F  F18  1  0.465  0.395  0.265  1.0
  F  F19  1  0.949  0.116  0.229  1.0
  F  F20  1  0.780  0.595  0.631  1.0
  F  F21  1  0.878  0.613  0.896  1.0
  F  F22  1  0.193  0.107  0.127  1.0
  F  F23  1  0.122  0.387  0.104  1.0
  F  F24  1  0.293  0.125  0.392  1.0
  F  F25  1  0.807  0.893  0.873  1.0
[/CIF]
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The material structure described by AsF6S2ClSCl2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two sulfanyl thiohypochlorite molecules, two sulfur dichloride molecules, and two AsF6 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. There are six inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one As(1) atom. is represented by the CIF file [CIF]
data_AsS3(ClF2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.632
_cell_length_b   7.935
_cell_length_c   10.032
_cell_angle_alpha   82.753
_cell_angle_beta   112.646
_cell_angle_gamma   114.971
_symmetry_Int_Tables_number   1
_cell_volume   507.796
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.793  0.744  0.752  1.0
  As  As1  1  0.207  0.256  0.248  1.0
  S  S2  1  0.548  0.240  0.029  1.0
  S  S3  1  0.334  0.832  0.073  1.0
  S  S4  1  0.083  0.299  0.603  1.0
  S  S5  1  0.917  0.701  0.397  1.0
  S  S6  1  0.452  0.760  0.971  1.0
  S  S7  1  0.666  0.168  0.927  1.0
  Cl  Cl8  1  0.193  0.724  0.532  1.0
  Cl  Cl9  1  0.484  0.831  0.291  1.0
  Cl  Cl10  1  0.807  0.276  0.468  1.0
  Cl  Cl11  1  0.084  0.320  0.798  1.0
  Cl  Cl12  1  0.516  0.169  0.709  1.0
  Cl  Cl13  1  0.916  0.680  0.202  1.0
  F  F14  1  0.707  0.875  0.608  1.0
  F  F15  1  0.535  0.605  0.735  1.0
  F  F16  1  0.051  0.884  0.771  1.0
  F  F17  1  0.220  0.405  0.369  1.0
  F  F18  1  0.465  0.395  0.265  1.0
  F  F19  1  0.949  0.116  0.229  1.0
  F  F20  1  0.780  0.595  0.631  1.0
  F  F21  1  0.878  0.613  0.896  1.0
  F  F22  1  0.193  0.107  0.127  1.0
  F  F23  1  0.122  0.387  0.104  1.0
  F  F24  1  0.293  0.125  0.392  1.0
  F  F25  1  0.807  0.893  0.873  1.0
[/CIF]
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