The material described by Li3V(PO4)2LiMnPO4 crystallizes in the triclinic P-1 space group. The structure consists of two LiMnPO4 clusters inside a Li3V(PO4)2 framework. In each LiMnPO4 cluster, Li(2) is bonded in a distorted single-bond geometry to one P(1), one O(3), and one O(5) atom. Mn(1) is bonded in a 2-coordinate geometry to one P(1) and one O(11) atom. P(1) is bonded in a 5-coordinate geometry to one Li(2), one Mn(1), one O(12), one O(3), and one O(5) atom. There are four inequivalent O sites. In the first O site, O(3) is bonded in a distorted L-shaped geometry to one Li(2) and one P(1) atom. In the second O site, O(5) is bonded in a 2-coordinate geometry to one Li(2) and one P(1) atom. In the third O site, O(11) is bonded in a single-bond geometry to one Mn(1) atom. In the fourth O site, O(12) is bonded in a 1-coordinate geometry to one P(1) atom. In the Li3V(PO4)2 framework, there are three inequivalent Li sites. In the first Li site, Li(1) is bonded in a 5-coordinate geometry to one V(1), one P(3), one O(1), one O(10), and one O(2) atom. In the second Li site, Li(3) is bonded in a 3-coordinate geometry to one V(1), one P(2), one O(1), and one O(6) atom. In the third Li site, Li(4) is bonded in a distorted single-bond geometry to one O(6), one O(7), and one O(8) atom. V(1) is bonded in a 3-coordinate geometry to one Li(1), one Li(3), one O(1), one O(2), and one O(9) atom. There are two inequivalent P sites. In the first P site, P(2) is bonded in a distorted trigonal non-coplanar geometry to one Li(3), one O(4), and one O(6) atom. In the second P site, P(3) is bonded in a 5-coordinate geometry to one Li(1), one O(10), one O(7), one O(8), and one O(9) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Li(1), one Li(3), one V(1), and one O(10) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Li(1), one V(1), and one O(4) atom. In the third O site, O(4) is bonded in a distorted bent 120 degrees geometry to one P(2) and one O(2) atom. In the fourth O site, O(6) is bonded in a 3-coordinate geometry to one Li(3), one Li(4), and one P(2) atom. In the fifth O site, O(7) is bonded in a distorted trigonal non-coplanar geometry to one Li(4), one P(3), and one O(7) atom. In the sixth O site, O(8) is bonded in a 3-coordinate geometry to one Li(4), one P(3), and one O(9) atom. In the seventh O site, O(9) is bonded in a bent 150 degrees geometry to one V(1), one P(3), and one O(8) atom. In the eighth O site, O(10) is bonded in a distorted single-bond geometry to one Li(1), one P(3), and one O(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li4MnV(PO4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.415
_cell_length_b   8.437
_cell_length_c   9.301
_cell_angle_alpha   116.728
_cell_angle_beta   90.373
_cell_angle_gamma   119.403
_symmetry_Int_Tables_number   1
_cell_volume   491.415
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.736  0.533  0.135  1.0
  Li  Li1  1  0.057  0.169  0.097  1.0
  Li  Li2  1  0.341  0.781  0.147  1.0
  Li  Li3  1  0.202  0.850  0.409  1.0
  Li  Li4  1  0.798  0.150  0.591  1.0
  Li  Li5  1  0.659  0.219  0.853  1.0
  Li  Li6  1  0.943  0.831  0.903  1.0
  Li  Li7  1  0.264  0.467  0.865  1.0
  Mn  Mn8  1  0.850  0.589  0.562  1.0
  Mn  Mn9  1  0.150  0.411  0.438  1.0
  V  V10  1  0.352  0.621  0.035  1.0
  V  V11  1  0.648  0.379  0.965  1.0
  P  P12  1  0.051  0.293  0.246  1.0
  P  P13  1  0.453  0.014  0.246  1.0
  P  P14  1  0.745  0.715  0.238  1.0
  P  P15  1  0.255  0.285  0.762  1.0
  P  P16  1  0.547  0.986  0.754  1.0
  P  P17  1  0.949  0.707  0.754  1.0
  O  O18  1  0.850  0.424  0.107  1.0
  O  O19  1  0.497  0.302  0.179  1.0
  O  O20  1  0.168  0.314  0.183  1.0
  O  O21  1  0.446  0.105  0.101  1.0
  O  O22  1  0.790  0.056  0.101  1.0
  O  O23  1  0.249  0.890  0.268  1.0
  O  O24  1  0.033  0.972  0.412  1.0
  O  O25  1  0.602  0.803  0.407  1.0
  O  O26  1  0.528  0.660  0.177  1.0
  O  O27  1  0.866  0.614  0.245  1.0
  O  O28  1  0.792  0.564  0.409  1.0
  O  O29  1  0.148  0.491  0.254  1.0
  O  O30  1  0.852  0.509  0.746  1.0
  O  O31  1  0.208  0.436  0.591  1.0
  O  O32  1  0.134  0.386  0.755  1.0
  O  O33  1  0.472  0.340  0.823  1.0
  O  O34  1  0.398  0.197  0.593  1.0
  O  O35  1  0.967  0.028  0.588  1.0
  O  O36  1  0.751  0.110  0.732  1.0
  O  O37  1  0.210  0.944  0.899  1.0
  O  O38  1  0.554  0.895  0.899  1.0
  O  O39  1  0.832  0.686  0.817  1.0
  O  O40  1  0.503  0.698  0.821  1.0
  O  O41  1  0.150  0.576  0.893  1.0
[/CIF]
.
The material described by Li3V(PO4)2LiMnPO4 crystallizes in the triclinic P-1 space group. The structure consists of two LiMnPO4 clusters inside a Li3V(PO4)2 framework. In each LiMnPO4 cluster, Li(2) is bonded in a distorted single-bond geometry to one P(1), one O(3), and one O(5) atom. Mn(1) is bonded in a 2-coordinate geometry to one P(1) and one O(11) atom. P(1) is bonded in a 5-coordinate geometry to one Li(2), one Mn(1), one O(12), one O(3), and one O(5) atom. There are four inequivalent O sites. In the first O site, O(3) is bonded in a distorted L-shaped geometry to one Li(2) and one P(1) atom. In the second O site, O(5) is bonded in a 2-coordinate geometry to one Li(2) and one P(1) atom. In the third O site, O(11) is bonded in a single-bond geometry to one Mn(1) atom. In the fourth O site, O(12) is bonded in a 1-coordinate geometry to one P(1) atom. In the Li3V(PO4)2 framework, there are three inequivalent Li sites. In the first Li site, Li(1) is bonded in a 5-coordinate geometry to one V(1), one P(3), one O(1), one O(10), and one O(2) atom. In the second Li site, Li(3) is bonded in a 3-coordinate geometry to one V(1), one P(2), one O(1), and one O(6) atom. In the third Li site, Li(4) is bonded in a distorted single-bond geometry to one O(6), one O(7), and one O(8) atom. V(1) is bonded in a 3-coordinate geometry to one Li(1), one Li(3), one O(1), one O(2), and one O(9) atom. There are two inequivalent P sites. In the first P site, P(2) is bonded in a distorted trigonal non-coplanar geometry to one Li(3), one O(4), and one O(6) atom. In the second P site, P(3) is bonded in a 5-coordinate geometry to one Li(1), one O(10), one O(7), one O(8), and one O(9) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Li(1), one Li(3), one V(1), and one O(10) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Li(1), one V(1), and one O(4) atom. In the third O site, O(4) is bonded in a distorted bent 120 degrees geometry to one P(2) and one O(2) atom. In the fourth O site, O(6) is bonded in a 3-coordinate geometry to one Li(3), one Li(4), and one P(2) atom. In the fifth O site, O(7) is bonded in a distorted trigonal non-coplanar geometry to one Li(4), one P(3), and one O(7) atom. In the sixth O site, O(8) is bonded in a 3-coordinate geometry to one Li(4), one P(3), and one O(9) atom. In the seventh O site, O(9) is bonded in a bent 150 degrees geometry to one V(1), one P(3), and one O(8) atom. In the eighth O site, O(10) is bonded in a distorted single-bond geometry to one Li(1), one P(3), and one O(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li4MnV(PO4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.415
_cell_length_b   8.437
_cell_length_c   9.301
_cell_angle_alpha   116.728
_cell_angle_beta   90.373
_cell_angle_gamma   119.403
_symmetry_Int_Tables_number   1
_cell_volume   491.415
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.736  0.533  0.135  1.0
  Li  Li1  1  0.057  0.169  0.097  1.0
  Li  Li2  1  0.341  0.781  0.147  1.0
  Li  Li3  1  0.202  0.850  0.409  1.0
  Li  Li4  1  0.798  0.150  0.591  1.0
  Li  Li5  1  0.659  0.219  0.853  1.0
  Li  Li6  1  0.943  0.831  0.903  1.0
  Li  Li7  1  0.264  0.467  0.865  1.0
  Mn  Mn8  1  0.850  0.589  0.562  1.0
  Mn  Mn9  1  0.150  0.411  0.438  1.0
  V  V10  1  0.352  0.621  0.035  1.0
  V  V11  1  0.648  0.379  0.965  1.0
  P  P12  1  0.051  0.293  0.246  1.0
  P  P13  1  0.453  0.014  0.246  1.0
  P  P14  1  0.745  0.715  0.238  1.0
  P  P15  1  0.255  0.285  0.762  1.0
  P  P16  1  0.547  0.986  0.754  1.0
  P  P17  1  0.949  0.707  0.754  1.0
  O  O18  1  0.850  0.424  0.107  1.0
  O  O19  1  0.497  0.302  0.179  1.0
  O  O20  1  0.168  0.314  0.183  1.0
  O  O21  1  0.446  0.105  0.101  1.0
  O  O22  1  0.790  0.056  0.101  1.0
  O  O23  1  0.249  0.890  0.268  1.0
  O  O24  1  0.033  0.972  0.412  1.0
  O  O25  1  0.602  0.803  0.407  1.0
  O  O26  1  0.528  0.660  0.177  1.0
  O  O27  1  0.866  0.614  0.245  1.0
  O  O28  1  0.792  0.564  0.409  1.0
  O  O29  1  0.148  0.491  0.254  1.0
  O  O30  1  0.852  0.509  0.746  1.0
  O  O31  1  0.208  0.436  0.591  1.0
  O  O32  1  0.134  0.386  0.755  1.0
  O  O33  1  0.472  0.340  0.823  1.0
  O  O34  1  0.398  0.197  0.593  1.0
  O  O35  1  0.967  0.028  0.588  1.0
  O  O36  1  0.751  0.110  0.732  1.0
  O  O37  1  0.210  0.944  0.899  1.0
  O  O38  1  0.554  0.895  0.899  1.0
  O  O39  1  0.832  0.686  0.817  1.0
  O  O40  1  0.503  0.698  0.821  1.0
  O  O41  1  0.150  0.576  0.893  1.0
[/CIF]
.