The crystal structure described by Zn8B4H3O15F crystallizes in the triclinic P1 space group. There are eight inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(12), one O(15), one O(8), and one O(9) atom to form ZnO4 tetrahedra that share  a cornercorner with one Zn(6)O3F tetrahedra,  a cornercorner with one Zn(5)O4 tetrahedra, and corners with two equivalent Zn(4)O4 tetrahedra. In the second Zn site, Zn(2) is bonded to one O(10), one O(11), one O(7), and one F(1) atom to form ZnO3F tetrahedra that share  a cornercorner with one Zn(6)O3F tetrahedra,  a cornercorner with one Zn(5)O4 tetrahedra, and corners with two equivalent Zn(3)O4 tetrahedra. In the third Zn site, Zn(3) is bonded to one O(10), one O(11), one O(13), and one O(6) atom to form ZnO4 tetrahedra that share  a cornercorner with one Zn(7)O4 tetrahedra,  a cornercorner with one Zn(8)O4 tetrahedra, and corners with two equivalent Zn(2)O3F tetrahedra. In the fourth Zn site, Zn(4) is bonded to one O(12), one O(14), one O(5), and one O(9) atom to form corner-sharing ZnO4 tetrahedra. In the fifth Zn site, Zn(5) is bonded to one O(15), one O(2), one O(3), and one O(7) atom to form ZnO4 tetrahedra that share  a cornercorner with one Zn(2)O3F tetrahedra,  a cornercorner with one Zn(1)O4 tetrahedra, and corners with two equivalent Zn(8)O4 tetrahedra. In the sixth Zn site, Zn(6) is bonded to one O(1), one O(4), one O(8), and one F(1) atom to form ZnO3F tetrahedra that share  a cornercorner with one Zn(2)O3F tetrahedra,  a cornercorner with one Zn(1)O4 tetrahedra, and corners with two equivalent Zn(7)O4 tetrahedra. In the seventh Zn site, Zn(7) is bonded to one O(1), one O(13), one O(4), and one O(5) atom to form ZnO4 tetrahedra that share  a cornercorner with one Zn(3)O4 tetrahedra,  a cornercorner with one Zn(4)O4 tetrahedra, and corners with two equivalent Zn(6)O3F tetrahedra. In the eighth Zn site, Zn(8) is bonded to one O(14), one O(2), one O(3), and one O(6) atom to form corner-sharing ZnO4 tetrahedra. There are four inequivalent B sites. In the first B site, B(1) is bonded in a trigonal planar geometry to one O(11), one O(3), and one O(7) atom. In the second B site, B(2) is bonded in a trigonal planar geometry to one O(12), one O(4), and one O(8) atom. In the third B site, B(3) is bonded in a trigonal planar geometry to one O(1), one O(5), and one O(9) atom. In the fourth B site, B(4) is bonded in a trigonal planar geometry to one O(10), one O(2), and one O(6) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(13) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(14) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(15) atom. There are fifteen inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Zn(6), one Zn(7), and one B(3) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Zn(5), one Zn(8), and one B(4) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Zn(5), one Zn(8), and one B(1) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Zn(6), one Zn(7), and one B(2) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one Zn(4), one Zn(7), and one B(3) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one Zn(3), one Zn(8), and one B(4) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to one Zn(2), one Zn(5), and one B(1) atom. In the eighth O site, O(8) is bonded in a trigonal planar geometry to one Zn(1), one Zn(6), and one B(2) atom. In the ninth O site, O(9) is bonded in a distorted trigonal non-coplanar geometry to one Zn(1), one Zn(4), and one B(3) atom. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one Zn(2), one Zn(3), and one B(4) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal non-coplanar geometry to one Zn(2), one Zn(3), and one B(1) atom. In the twelfth O site, O(12) is bonded in a distorted trigonal non-coplanar geometry to one Zn(1), one Zn(4), and one B(2) atom. In the thirteenth O site, O(13) is bonded in a distorted trigonal non-coplanar geometry to one Zn(3), one Zn(7), and one H(1) atom. In the fourteenth O site, O(14) is bonded in a distorted trigonal non-coplanar geometry to one Zn(4), one Zn(8), and one H(2) atom. In the fifteenth O site, O(15) is bonded in a distorted trigonal non-coplanar geometry to one Zn(1), one Zn(5), and one H(3) atom. F(1) is bonded in a bent 120 degrees geometry to one Zn(2) and one Zn(6) atom. is represented by the CIF card [CIF]
data_Zn8B4H3O15F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.994
_cell_length_b   8.339
_cell_length_c   9.747
_cell_angle_alpha   101.168
_cell_angle_beta   90.213
_cell_angle_gamma   90.014
_symmetry_Int_Tables_number   1
_cell_volume   398.257
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.517  0.224  0.848  1.0
  Zn  Zn1  1  0.518  0.719  0.343  1.0
  Zn  Zn2  1  0.018  0.778  0.152  1.0
  Zn  Zn3  1  0.017  0.277  0.650  1.0
  Zn  Zn4  1  0.501  0.349  0.204  1.0
  Zn  Zn5  1  0.501  0.849  0.711  1.0
  Zn  Zn6  1  0.002  0.649  0.796  1.0
  Zn  Zn7  1  0.001  0.150  0.297  1.0
  B  B8  1  0.005  0.517  0.306  1.0
  B  B9  1  0.003  0.017  0.805  1.0
  B  B10  1  0.504  0.484  0.694  1.0
  B  B11  1  0.504  0.984  0.194  1.0
  H  H12  1  0.173  0.529  0.993  1.0
  H  H13  1  0.179  0.028  0.493  1.0
  H  H14  1  0.674  0.471  0.007  1.0
  O  O15  1  0.641  0.631  0.712  1.0
  O  O16  1  0.640  0.131  0.213  1.0
  O  O17  1  0.139  0.369  0.284  1.0
  O  O18  1  0.136  0.869  0.785  1.0
  O  O19  1  0.228  0.482  0.679  1.0
  O  O20  1  0.228  0.981  0.177  1.0
  O  O21  1  0.729  0.518  0.324  1.0
  O  O22  1  0.727  0.020  0.821  1.0
  O  O23  1  0.641  0.340  0.696  1.0
  O  O24  1  0.639  0.840  0.197  1.0
  O  O25  1  0.138  0.662  0.306  1.0
  O  O26  1  0.139  0.162  0.806  1.0
  O  O27  1  0.015  0.598  0.987  1.0
  O  O28  1  0.034  0.105  0.485  1.0
  O  O29  1  0.516  0.403  0.014  1.0
  F  F30  1  0.494  0.888  0.515  1.0
[/CIF]
.
The crystal structure described by Zn8B4H3O15F crystallizes in the triclinic P1 space group. There are eight inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(12), one O(15), one O(8), and one O(9) atom to form ZnO4 tetrahedra that share  a cornercorner with one Zn(6)O3F tetrahedra,  a cornercorner with one Zn(5)O4 tetrahedra, and corners with two equivalent Zn(4)O4 tetrahedra. In the second Zn site, Zn(2) is bonded to one O(10), one O(11), one O(7), and one F(1) atom to form ZnO3F tetrahedra that share  a cornercorner with one Zn(6)O3F tetrahedra,  a cornercorner with one Zn(5)O4 tetrahedra, and corners with two equivalent Zn(3)O4 tetrahedra. In the third Zn site, Zn(3) is bonded to one O(10), one O(11), one O(13), and one O(6) atom to form ZnO4 tetrahedra that share  a cornercorner with one Zn(7)O4 tetrahedra,  a cornercorner with one Zn(8)O4 tetrahedra, and corners with two equivalent Zn(2)O3F tetrahedra. In the fourth Zn site, Zn(4) is bonded to one O(12), one O(14), one O(5), and one O(9) atom to form corner-sharing ZnO4 tetrahedra. In the fifth Zn site, Zn(5) is bonded to one O(15), one O(2), one O(3), and one O(7) atom to form ZnO4 tetrahedra that share  a cornercorner with one Zn(2)O3F tetrahedra,  a cornercorner with one Zn(1)O4 tetrahedra, and corners with two equivalent Zn(8)O4 tetrahedra. In the sixth Zn site, Zn(6) is bonded to one O(1), one O(4), one O(8), and one F(1) atom to form ZnO3F tetrahedra that share  a cornercorner with one Zn(2)O3F tetrahedra,  a cornercorner with one Zn(1)O4 tetrahedra, and corners with two equivalent Zn(7)O4 tetrahedra. In the seventh Zn site, Zn(7) is bonded to one O(1), one O(13), one O(4), and one O(5) atom to form ZnO4 tetrahedra that share  a cornercorner with one Zn(3)O4 tetrahedra,  a cornercorner with one Zn(4)O4 tetrahedra, and corners with two equivalent Zn(6)O3F tetrahedra. In the eighth Zn site, Zn(8) is bonded to one O(14), one O(2), one O(3), and one O(6) atom to form corner-sharing ZnO4 tetrahedra. There are four inequivalent B sites. In the first B site, B(1) is bonded in a trigonal planar geometry to one O(11), one O(3), and one O(7) atom. In the second B site, B(2) is bonded in a trigonal planar geometry to one O(12), one O(4), and one O(8) atom. In the third B site, B(3) is bonded in a trigonal planar geometry to one O(1), one O(5), and one O(9) atom. In the fourth B site, B(4) is bonded in a trigonal planar geometry to one O(10), one O(2), and one O(6) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(13) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(14) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(15) atom. There are fifteen inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Zn(6), one Zn(7), and one B(3) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Zn(5), one Zn(8), and one B(4) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Zn(5), one Zn(8), and one B(1) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Zn(6), one Zn(7), and one B(2) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one Zn(4), one Zn(7), and one B(3) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one Zn(3), one Zn(8), and one B(4) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to one Zn(2), one Zn(5), and one B(1) atom. In the eighth O site, O(8) is bonded in a trigonal planar geometry to one Zn(1), one Zn(6), and one B(2) atom. In the ninth O site, O(9) is bonded in a distorted trigonal non-coplanar geometry to one Zn(1), one Zn(4), and one B(3) atom. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one Zn(2), one Zn(3), and one B(4) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal non-coplanar geometry to one Zn(2), one Zn(3), and one B(1) atom. In the twelfth O site, O(12) is bonded in a distorted trigonal non-coplanar geometry to one Zn(1), one Zn(4), and one B(2) atom. In the thirteenth O site, O(13) is bonded in a distorted trigonal non-coplanar geometry to one Zn(3), one Zn(7), and one H(1) atom. In the fourteenth O site, O(14) is bonded in a distorted trigonal non-coplanar geometry to one Zn(4), one Zn(8), and one H(2) atom. In the fifteenth O site, O(15) is bonded in a distorted trigonal non-coplanar geometry to one Zn(1), one Zn(5), and one H(3) atom. F(1) is bonded in a bent 120 degrees geometry to one Zn(2) and one Zn(6) atom. is represented by the CIF card [CIF]
data_Zn8B4H3O15F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.994
_cell_length_b   8.339
_cell_length_c   9.747
_cell_angle_alpha   101.168
_cell_angle_beta   90.213
_cell_angle_gamma   90.014
_symmetry_Int_Tables_number   1
_cell_volume   398.257
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.517  0.224  0.848  1.0
  Zn  Zn1  1  0.518  0.719  0.343  1.0
  Zn  Zn2  1  0.018  0.778  0.152  1.0
  Zn  Zn3  1  0.017  0.277  0.650  1.0
  Zn  Zn4  1  0.501  0.349  0.204  1.0
  Zn  Zn5  1  0.501  0.849  0.711  1.0
  Zn  Zn6  1  0.002  0.649  0.796  1.0
  Zn  Zn7  1  0.001  0.150  0.297  1.0
  B  B8  1  0.005  0.517  0.306  1.0
  B  B9  1  0.003  0.017  0.805  1.0
  B  B10  1  0.504  0.484  0.694  1.0
  B  B11  1  0.504  0.984  0.194  1.0
  H  H12  1  0.173  0.529  0.993  1.0
  H  H13  1  0.179  0.028  0.493  1.0
  H  H14  1  0.674  0.471  0.007  1.0
  O  O15  1  0.641  0.631  0.712  1.0
  O  O16  1  0.640  0.131  0.213  1.0
  O  O17  1  0.139  0.369  0.284  1.0
  O  O18  1  0.136  0.869  0.785  1.0
  O  O19  1  0.228  0.482  0.679  1.0
  O  O20  1  0.228  0.981  0.177  1.0
  O  O21  1  0.729  0.518  0.324  1.0
  O  O22  1  0.727  0.020  0.821  1.0
  O  O23  1  0.641  0.340  0.696  1.0
  O  O24  1  0.639  0.840  0.197  1.0
  O  O25  1  0.138  0.662  0.306  1.0
  O  O26  1  0.139  0.162  0.806  1.0
  O  O27  1  0.015  0.598  0.987  1.0
  O  O28  1  0.034  0.105  0.485  1.0
  O  O29  1  0.516  0.403  0.014  1.0
  F  F30  1  0.494  0.888  0.515  1.0
[/CIF]
.