The material described by (Zn)12Ni4Si is Indium-derived structured and crystallizes in the cubic Fd-3m space group. The structure is zero-dimensional and consists of eight Ni4Si clusters and thirty-two zinc molecules. In each Ni4Si cluster, Ni(1) is bonded in a single-bond geometry to one Si(1) atom. Si(1) is bonded in a tetrahedral geometry to four equivalent Ni(1) atoms. is represented by the CIF file [CIF]
data_Zn12SiNi4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   22.623
_cell_length_b   22.623
_cell_length_c   22.623
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   8187.142
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.560  0.560  0.190  1.0
  Zn  Zn1  1  0.689  0.190  0.560  1.0
  Zn  Zn2  1  0.190  0.689  0.560  1.0
  Zn  Zn3  1  0.560  0.190  0.560  1.0
  Zn  Zn4  1  0.061  0.190  0.560  1.0
  Zn  Zn5  1  0.190  0.190  0.560  1.0
  Zn  Zn6  1  0.560  0.560  0.689  1.0
  Zn  Zn7  1  0.190  0.560  0.689  1.0
  Zn  Zn8  1  0.190  0.560  0.190  1.0
  Zn  Zn9  1  0.061  0.560  0.190  1.0
  Zn  Zn10  1  0.689  0.560  0.190  1.0
  Zn  Zn11  1  0.190  0.061  0.190  1.0
  Zn  Zn12  1  0.560  0.061  0.190  1.0
  Zn  Zn13  1  0.560  0.689  0.560  1.0
  Zn  Zn14  1  0.560  0.190  0.061  1.0
  Zn  Zn15  1  0.190  0.190  0.061  1.0
  Zn  Zn16  1  0.190  0.560  0.560  1.0
  Zn  Zn17  1  0.560  0.190  0.689  1.0
  Zn  Zn18  1  0.689  0.560  0.560  1.0
  Zn  Zn19  1  0.560  0.689  0.190  1.0
  Zn  Zn20  1  0.190  0.560  0.061  1.0
  Zn  Zn21  1  0.560  0.190  0.190  1.0
  Zn  Zn22  1  0.190  0.061  0.560  1.0
  Zn  Zn23  1  0.061  0.190  0.190  1.0
  Si  Si24  1  0.000  0.000  0.000  1.0
  Si  Si25  1  0.750  0.750  0.750  1.0
  Ni  Ni26  1  0.788  0.788  0.788  1.0
  Ni  Ni27  1  0.636  0.788  0.788  1.0
  Ni  Ni28  1  0.788  0.636  0.788  1.0
  Ni  Ni29  1  0.114  0.962  0.962  1.0
  Ni  Ni30  1  0.962  0.962  0.962  1.0
  Ni  Ni31  1  0.788  0.788  0.636  1.0
  Ni  Ni32  1  0.962  0.114  0.962  1.0
  Ni  Ni33  1  0.962  0.962  0.114  1.0
[/CIF]
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The material described by (Zn)12Ni4Si is Indium-derived structured and crystallizes in the cubic Fd-3m space group. The structure is zero-dimensional and consists of eight Ni4Si clusters and thirty-two zinc molecules. In each Ni4Si cluster, Ni(1) is bonded in a single-bond geometry to one Si(1) atom. Si(1) is bonded in a tetrahedral geometry to four equivalent Ni(1) atoms. is represented by the CIF file [CIF]
data_Zn12SiNi4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   22.623
_cell_length_b   22.623
_cell_length_c   22.623
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   8187.142
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.560  0.560  0.190  1.0
  Zn  Zn1  1  0.689  0.190  0.560  1.0
  Zn  Zn2  1  0.190  0.689  0.560  1.0
  Zn  Zn3  1  0.560  0.190  0.560  1.0
  Zn  Zn4  1  0.061  0.190  0.560  1.0
  Zn  Zn5  1  0.190  0.190  0.560  1.0
  Zn  Zn6  1  0.560  0.560  0.689  1.0
  Zn  Zn7  1  0.190  0.560  0.689  1.0
  Zn  Zn8  1  0.190  0.560  0.190  1.0
  Zn  Zn9  1  0.061  0.560  0.190  1.0
  Zn  Zn10  1  0.689  0.560  0.190  1.0
  Zn  Zn11  1  0.190  0.061  0.190  1.0
  Zn  Zn12  1  0.560  0.061  0.190  1.0
  Zn  Zn13  1  0.560  0.689  0.560  1.0
  Zn  Zn14  1  0.560  0.190  0.061  1.0
  Zn  Zn15  1  0.190  0.190  0.061  1.0
  Zn  Zn16  1  0.190  0.560  0.560  1.0
  Zn  Zn17  1  0.560  0.190  0.689  1.0
  Zn  Zn18  1  0.689  0.560  0.560  1.0
  Zn  Zn19  1  0.560  0.689  0.190  1.0
  Zn  Zn20  1  0.190  0.560  0.061  1.0
  Zn  Zn21  1  0.560  0.190  0.190  1.0
  Zn  Zn22  1  0.190  0.061  0.560  1.0
  Zn  Zn23  1  0.061  0.190  0.190  1.0
  Si  Si24  1  0.000  0.000  0.000  1.0
  Si  Si25  1  0.750  0.750  0.750  1.0
  Ni  Ni26  1  0.788  0.788  0.788  1.0
  Ni  Ni27  1  0.636  0.788  0.788  1.0
  Ni  Ni28  1  0.788  0.636  0.788  1.0
  Ni  Ni29  1  0.114  0.962  0.962  1.0
  Ni  Ni30  1  0.962  0.962  0.962  1.0
  Ni  Ni31  1  0.788  0.788  0.636  1.0
  Ni  Ni32  1  0.962  0.114  0.962  1.0
  Ni  Ni33  1  0.962  0.962  0.114  1.0
[/CIF]
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