The crystal structure described by Mo2AsP3 crystallizes in the monoclinic Cm space group. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 7-coordinate geometry to one As(1), two equivalent P(1), two equivalent P(2), and two equivalent P(3) atoms. In the second Mo site, Mo(2) is bonded in a 7-coordinate geometry to two equivalent As(1), one P(1), two equivalent P(2), and two equivalent P(3) atoms. As(1) is bonded in a distorted rectangular see-saw-like geometry to one Mo(1), two equivalent Mo(2), and one P(2) atom. There are three inequivalent P sites. In the first P site, P(1) is bonded in a distorted rectangular see-saw-like geometry to one Mo(2), two equivalent Mo(1), and one P(3) atom. In the second P site, P(2) is bonded in a 5-coordinate geometry to two equivalent Mo(1), two equivalent Mo(2), and one As(1) atom. In the third P site, P(3) is bonded in a 5-coordinate geometry to two equivalent Mo(1), two equivalent Mo(2), and one P(1) atom. is represented by the CIF file [CIF]
data_Mo2AsP3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.932
_cell_length_b   5.932
_cell_length_c   5.097
_cell_angle_alpha   89.202
_cell_angle_beta   89.202
_cell_angle_gamma   31.108
_symmetry_Int_Tables_number   1
_cell_volume   92.656
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.091  0.091  0.498  1.0
  Mo  Mo1  1  0.910  0.910  0.008  1.0
  As  As2  1  0.296  0.296  0.700  1.0
  P  P3  1  0.700  0.700  0.197  1.0
  P  P4  1  0.434  0.434  0.373  1.0
  P  P5  1  0.569  0.569  0.882  1.0
[/CIF]
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The crystal structure described by Mo2AsP3 crystallizes in the monoclinic Cm space group. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 7-coordinate geometry to one As(1), two equivalent P(1), two equivalent P(2), and two equivalent P(3) atoms. In the second Mo site, Mo(2) is bonded in a 7-coordinate geometry to two equivalent As(1), one P(1), two equivalent P(2), and two equivalent P(3) atoms. As(1) is bonded in a distorted rectangular see-saw-like geometry to one Mo(1), two equivalent Mo(2), and one P(2) atom. There are three inequivalent P sites. In the first P site, P(1) is bonded in a distorted rectangular see-saw-like geometry to one Mo(2), two equivalent Mo(1), and one P(3) atom. In the second P site, P(2) is bonded in a 5-coordinate geometry to two equivalent Mo(1), two equivalent Mo(2), and one As(1) atom. In the third P site, P(3) is bonded in a 5-coordinate geometry to two equivalent Mo(1), two equivalent Mo(2), and one P(1) atom. is represented by the CIF file [CIF]
data_Mo2AsP3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.932
_cell_length_b   5.932
_cell_length_c   5.097
_cell_angle_alpha   89.202
_cell_angle_beta   89.202
_cell_angle_gamma   31.108
_symmetry_Int_Tables_number   1
_cell_volume   92.656
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.091  0.091  0.498  1.0
  Mo  Mo1  1  0.910  0.910  0.008  1.0
  As  As2  1  0.296  0.296  0.700  1.0
  P  P3  1  0.700  0.700  0.197  1.0
  P  P4  1  0.434  0.434  0.373  1.0
  P  P5  1  0.569  0.569  0.882  1.0
[/CIF]
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