The structure described by V2Re2O11 crystallizes in the orthorhombic Cmc2_1 space group. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(4), one O(5), and two equivalent O(8) atoms to form VO4 tetrahedra that share corners with three equivalent Re(2)O6 octahedra and  a cornercorner with one Re(1)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 3-39°. In the second V site, V(2) is bonded to one O(1), one O(7), and two equivalent O(3) atoms to form VO4 tetrahedra that share  a cornercorner with one Re(2)O6 octahedra and corners with two equivalent Re(1)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 19°. There are two inequivalent Re sites. In the first Re site, Re(1) is bonded to one O(2), one O(4), one O(9), and two equivalent O(3) atoms to form ReO5 trigonal bipyramids that share  a cornercorner with one Re(2)O6 octahedra,  a cornercorner with one V(1)O4 tetrahedra, and corners with two equivalent V(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 28°. In the second Re site, Re(2) is bonded to one O(2), one O(5), one O(6), one O(7), and two equivalent O(8) atoms to form distorted ReO6 octahedra that share  a cornercorner with one V(2)O4 tetrahedra, corners with three equivalent V(1)O4 tetrahedra, and  a cornercorner with one Re(1)O5 trigonal bipyramid. There are nine inequivalent O sites. In the first O site, O(9) is bonded in a single-bond geometry to one Re(1) atom. In the second O site, O(1) is bonded in a single-bond geometry to one V(2) atom. In the third O site, O(2) is bonded in a bent 150 degrees geometry to one Re(1) and one Re(2) atom. In the fourth O site, O(3) is bonded in a bent 120 degrees geometry to one V(2) and one Re(1) atom. In the fifth O site, O(4) is bonded in a bent 120 degrees geometry to one V(1) and one Re(1) atom. In the sixth O site, O(5) is bonded in a distorted linear geometry to one V(1) and one Re(2) atom. In the seventh O site, O(6) is bonded in a single-bond geometry to one Re(2) atom. In the eighth O site, O(7) is bonded in a bent 150 degrees geometry to one V(2) and one Re(2) atom. In the ninth O site, O(8) is bonded in a bent 150 degrees geometry to one V(1) and one Re(2) atom. is represented by the CIF file [CIF]
data_V2Re2O11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.799
_cell_length_b   7.799
_cell_length_c   9.374
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   127.840
_symmetry_Int_Tables_number   1
_cell_volume   450.305
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.793  0.207  0.217  1.0
  V  V1  1  0.482  0.518  0.549  1.0
  V  V2  1  0.518  0.482  0.049  1.0
  V  V3  1  0.207  0.793  0.717  1.0
  Re  Re4  1  0.001  0.999  0.527  1.0
  Re  Re5  1  0.261  0.739  0.134  1.0
  Re  Re6  1  0.999  0.001  0.027  1.0
  Re  Re7  1  0.739  0.261  0.634  1.0
  O  O8  1  0.552  0.448  0.214  1.0
  O  O9  1  0.869  0.131  0.632  1.0
  O  O10  1  0.198  0.284  0.474  1.0
  O  O11  1  0.935  0.065  0.194  1.0
  O  O12  1  0.773  0.227  0.393  1.0
  O  O13  1  0.716  0.802  0.474  1.0
  O  O14  1  0.131  0.869  0.132  1.0
  O  O15  1  0.714  0.286  0.813  1.0
  O  O16  1  0.227  0.773  0.893  1.0
  O  O17  1  0.385  0.615  0.058  1.0
  O  O18  1  0.284  0.198  0.974  1.0
  O  O19  1  0.448  0.552  0.714  1.0
  O  O20  1  0.459  0.982  0.616  1.0
  O  O21  1  0.541  0.018  0.116  1.0
  O  O22  1  0.802  0.716  0.974  1.0
  O  O23  1  0.982  0.459  0.116  1.0
  O  O24  1  0.018  0.541  0.616  1.0
  O  O25  1  0.615  0.385  0.558  1.0
  O  O26  1  0.286  0.714  0.313  1.0
  O  O27  1  0.065  0.935  0.694  1.0
  O  O28  1  0.902  0.098  0.915  1.0
  O  O29  1  0.098  0.902  0.415  1.0
[/CIF]
.
The structure described by V2Re2O11 crystallizes in the orthorhombic Cmc2_1 space group. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(4), one O(5), and two equivalent O(8) atoms to form VO4 tetrahedra that share corners with three equivalent Re(2)O6 octahedra and  a cornercorner with one Re(1)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 3-39°. In the second V site, V(2) is bonded to one O(1), one O(7), and two equivalent O(3) atoms to form VO4 tetrahedra that share  a cornercorner with one Re(2)O6 octahedra and corners with two equivalent Re(1)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 19°. There are two inequivalent Re sites. In the first Re site, Re(1) is bonded to one O(2), one O(4), one O(9), and two equivalent O(3) atoms to form ReO5 trigonal bipyramids that share  a cornercorner with one Re(2)O6 octahedra,  a cornercorner with one V(1)O4 tetrahedra, and corners with two equivalent V(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 28°. In the second Re site, Re(2) is bonded to one O(2), one O(5), one O(6), one O(7), and two equivalent O(8) atoms to form distorted ReO6 octahedra that share  a cornercorner with one V(2)O4 tetrahedra, corners with three equivalent V(1)O4 tetrahedra, and  a cornercorner with one Re(1)O5 trigonal bipyramid. There are nine inequivalent O sites. In the first O site, O(9) is bonded in a single-bond geometry to one Re(1) atom. In the second O site, O(1) is bonded in a single-bond geometry to one V(2) atom. In the third O site, O(2) is bonded in a bent 150 degrees geometry to one Re(1) and one Re(2) atom. In the fourth O site, O(3) is bonded in a bent 120 degrees geometry to one V(2) and one Re(1) atom. In the fifth O site, O(4) is bonded in a bent 120 degrees geometry to one V(1) and one Re(1) atom. In the sixth O site, O(5) is bonded in a distorted linear geometry to one V(1) and one Re(2) atom. In the seventh O site, O(6) is bonded in a single-bond geometry to one Re(2) atom. In the eighth O site, O(7) is bonded in a bent 150 degrees geometry to one V(2) and one Re(2) atom. In the ninth O site, O(8) is bonded in a bent 150 degrees geometry to one V(1) and one Re(2) atom. is represented by the CIF file [CIF]
data_V2Re2O11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.799
_cell_length_b   7.799
_cell_length_c   9.374
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   127.840
_symmetry_Int_Tables_number   1
_cell_volume   450.305
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.793  0.207  0.217  1.0
  V  V1  1  0.482  0.518  0.549  1.0
  V  V2  1  0.518  0.482  0.049  1.0
  V  V3  1  0.207  0.793  0.717  1.0
  Re  Re4  1  0.001  0.999  0.527  1.0
  Re  Re5  1  0.261  0.739  0.134  1.0
  Re  Re6  1  0.999  0.001  0.027  1.0
  Re  Re7  1  0.739  0.261  0.634  1.0
  O  O8  1  0.552  0.448  0.214  1.0
  O  O9  1  0.869  0.131  0.632  1.0
  O  O10  1  0.198  0.284  0.474  1.0
  O  O11  1  0.935  0.065  0.194  1.0
  O  O12  1  0.773  0.227  0.393  1.0
  O  O13  1  0.716  0.802  0.474  1.0
  O  O14  1  0.131  0.869  0.132  1.0
  O  O15  1  0.714  0.286  0.813  1.0
  O  O16  1  0.227  0.773  0.893  1.0
  O  O17  1  0.385  0.615  0.058  1.0
  O  O18  1  0.284  0.198  0.974  1.0
  O  O19  1  0.448  0.552  0.714  1.0
  O  O20  1  0.459  0.982  0.616  1.0
  O  O21  1  0.541  0.018  0.116  1.0
  O  O22  1  0.802  0.716  0.974  1.0
  O  O23  1  0.982  0.459  0.116  1.0
  O  O24  1  0.018  0.541  0.616  1.0
  O  O25  1  0.615  0.385  0.558  1.0
  O  O26  1  0.286  0.714  0.313  1.0
  O  O27  1  0.065  0.935  0.694  1.0
  O  O28  1  0.902  0.098  0.915  1.0
  O  O29  1  0.098  0.902  0.415  1.0
[/CIF]
.