The structure described by InBi3 crystallizes in the orthorhombic C222 space group. In(1) is bonded in a 6-coordinate geometry to two equivalent In(1) and four equivalent Bi(2) atoms. There are two inequivalent Bi sites. In the first Bi site, Bi(1) is bonded to two equivalent Bi(1) and four equivalent Bi(2) atoms to form distorted corner-sharing BiBi6 pentagonal pyramids. In the second Bi site, Bi(2) is bonded in a 6-coordinate geometry to two equivalent In(1), two equivalent Bi(1), and two equivalent Bi(2) atoms. is represented by the CIF card [CIF]
data_InBi3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.721
_cell_length_b   4.721
_cell_length_c   8.678
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   138.838
_symmetry_Int_Tables_number   1
_cell_volume   127.287
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.500  0.500  0.000  1.0
  Bi  Bi1  1  0.000  0.000  0.500  1.0
  Bi  Bi2  1  0.000  0.500  0.761  1.0
  Bi  Bi3  1  0.500  0.000  0.239  1.0
[/CIF]
.
The structure described by InBi3 crystallizes in the orthorhombic C222 space group. In(1) is bonded in a 6-coordinate geometry to two equivalent In(1) and four equivalent Bi(2) atoms. There are two inequivalent Bi sites. In the first Bi site, Bi(1) is bonded to two equivalent Bi(1) and four equivalent Bi(2) atoms to form distorted corner-sharing BiBi6 pentagonal pyramids. In the second Bi site, Bi(2) is bonded in a 6-coordinate geometry to two equivalent In(1), two equivalent Bi(1), and two equivalent Bi(2) atoms. is represented by the CIF card [CIF]
data_InBi3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.721
_cell_length_b   4.721
_cell_length_c   8.678
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   138.838
_symmetry_Int_Tables_number   1
_cell_volume   127.287
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.500  0.500  0.000  1.0
  Bi  Bi1  1  0.000  0.000  0.500  1.0
  Bi  Bi2  1  0.000  0.500  0.761  1.0
  Bi  Bi3  1  0.500  0.000  0.239  1.0
[/CIF]
.