The structure described by Li4V2Mn3Sb3O16 is Hausmannite-derived structured and crystallizes in the monoclinic Cm space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(12), one O(3), and two equivalent O(9) atoms to form LiO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent Sb(1)O6 octahedra, corners with two equivalent Sb(2)O6 octahedra, corners with three equivalent V(2)O6 octahedra, and corners with four equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-67°. In the second Li site, Li(2) is bonded in a distorted rectangular see-saw-like geometry to one O(5), one O(7), and two equivalent O(11) atoms. In the third Li site, Li(3) is bonded to one O(4), one O(8), and two equivalent O(1) atoms to form distorted LiO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent Sb(1)O6 octahedra, corners with three equivalent V(1)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-68°. In the fourth Li site, Li(4) is bonded to one O(10), one O(2), and two equivalent O(6) atoms to form LiO4 tetrahedra that share  a cornercorner with one Sb(2)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with three equivalent V(1)O6 octahedra, and corners with four equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 58-64°. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(2), one O(8), two equivalent O(1), and two equivalent O(6) atoms to form distorted VO6 octahedra that share corners with two equivalent Sb(2)O6 octahedra, corners with four equivalent Mn(2)O6 octahedra, corners with three equivalent Li(3)O4 tetrahedra, corners with three equivalent Li(4)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-53°. In the second V site, V(2) is bonded to one O(12), one O(7), two equivalent O(11), and two equivalent O(9) atoms to form distorted VO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with four equivalent Sb(1)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra,  an edgeedge with one Sb(2)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-52°. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(3), one O(4), two equivalent O(11), and two equivalent O(6) atoms to form MnO6 octahedra that share corners with two equivalent V(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra, and edges with four equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles are 51°. In the second Mn site, Mn(2) is bonded to one O(1), one O(10), one O(12), one O(5), one O(8), and one O(9) atom to form distorted MnO6 octahedra that share corners with two equivalent V(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Sb(2)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 53°. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(11), one O(2), one O(3), one O(4), one O(6), and one O(7) atom to form SbO6 octahedra that share corners with two equivalent V(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-52°. In the second Sb site, Sb(2) is bonded to one O(10), one O(5), two equivalent O(1), and two equivalent O(9) atoms to form SbO6 octahedra that share corners with two equivalent V(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra, edges with four equivalent Mn(2)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 49°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one V(1), one Mn(2), and one Sb(2) atom. In the second O site, O(2) is bonded to one Li(4), one V(1), and two equivalent Sb(1) atoms to form distorted OLiVSb2 trigonal pyramids that share  a cornercorner with one O(10)LiMn2Sb tetrahedra, corners with two equivalent O(4)LiMnSb2 tetrahedra, corners with two equivalent O(6)LiMnVSb tetrahedra, and edges with two equivalent O(6)LiMnVSb tetrahedra. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Li(1), one Mn(1), and two equivalent Sb(1) atoms. In the fourth O site, O(4) is bonded to one Li(3), one Mn(1), and two equivalent Sb(1) atoms to form distorted OLiMnSb2 tetrahedra that share corners with four equivalent O(6)LiMnVSb tetrahedra and corners with two equivalent O(2)LiVSb2 trigonal pyramids. In the fifth O site, O(5) is bonded to one Li(2), two equivalent Mn(2), and one Sb(2) atom to form OLiMn2Sb tetrahedra that share corners with two equivalent O(12)LiMn2V tetrahedra and corners with three equivalent O(10)LiMn2Sb tetrahedra. In the sixth O site, O(6) is bonded to one Li(4), one V(1), one Mn(1), and one Sb(1) atom to form distorted OLiMnVSb tetrahedra that share  a cornercorner with one O(10)LiMn2Sb tetrahedra,  a cornercorner with one O(6)LiMnVSb tetrahedra, corners with two equivalent O(4)LiMnSb2 tetrahedra,  a cornercorner with one O(2)LiVSb2 trigonal pyramid,  an edgeedge with one O(6)LiMnVSb tetrahedra, and  an edgeedge with one O(2)LiVSb2 trigonal pyramid. In the seventh O site, O(7) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one V(2), and two equivalent Sb(1) atoms. In the eighth O site, O(8) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one V(1), and two equivalent Mn(2) atoms. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Li(1), one V(2), one Mn(2), and one Sb(2) atom. In the tenth O site, O(10) is bonded to one Li(4), two equivalent Mn(2), and one Sb(2) atom to form distorted OLiMn2Sb tetrahedra that share corners with two equivalent O(6)LiMnVSb tetrahedra, corners with three equivalent O(5)LiMn2Sb tetrahedra,  a cornercorner with one O(2)LiVSb2 trigonal pyramid, and  an edgeedge with one O(12)LiMn2V tetrahedra. In the eleventh O site, O(11) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(2), one Mn(1), and one Sb(1) atom. In the twelfth O site, O(12) is bonded to one Li(1), one V(2), and two equivalent Mn(2) atoms to form a mixture of distorted corner and edge-sharing OLiMn2V tetrahedra. is represented by the CIF card [CIF]
data_Li4Mn3V2Sb3O16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.233
_cell_length_b   6.121
_cell_length_c   9.760
_cell_angle_alpha   90.045
_cell_angle_beta   91.838
_cell_angle_gamma   119.419
_symmetry_Int_Tables_number   1
_cell_volume   324.098
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.324  0.662  0.886  1.0
  Li  Li1  1  0.978  0.989  0.986  1.0
  Li  Li2  1  0.988  0.994  0.503  1.0
  Li  Li3  1  0.644  0.322  0.402  1.0
  Mn  Mn4  1  0.664  0.832  0.213  1.0
  Mn  Mn5  1  0.830  0.663  0.709  1.0
  Mn  Mn6  1  0.830  0.168  0.709  1.0
  V  V7  1  0.351  0.676  0.497  1.0
  V  V8  1  0.704  0.352  0.973  1.0
  Sb  Sb9  1  0.168  0.830  0.215  1.0
  Sb  Sb10  1  0.168  0.338  0.215  1.0
  Sb  Sb11  1  0.346  0.173  0.716  1.0
  O  O12  1  0.191  0.848  0.595  1.0
  O  O13  1  0.031  0.516  0.339  1.0
  O  O14  1  0.317  0.658  0.100  1.0
  O  O15  1  0.014  0.007  0.318  1.0
  O  O16  1  0.010  0.005  0.801  1.0
  O  O17  1  0.191  0.342  0.595  1.0
  O  O18  1  0.463  0.953  0.346  1.0
  O  O19  1  0.463  0.511  0.346  1.0
  O  O20  1  0.316  0.158  0.106  1.0
  O  O21  1  0.671  0.835  0.594  1.0
  O  O22  1  0.509  0.470  0.850  1.0
  O  O23  1  0.509  0.040  0.850  1.0
  O  O24  1  0.662  0.331  0.607  1.0
  O  O25  1  0.855  0.678  0.095  1.0
  O  O26  1  0.947  0.474  0.846  1.0
  O  O27  1  0.855  0.177  0.095  1.0
[/CIF]
.
The structure described by Li4V2Mn3Sb3O16 is Hausmannite-derived structured and crystallizes in the monoclinic Cm space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(12), one O(3), and two equivalent O(9) atoms to form LiO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent Sb(1)O6 octahedra, corners with two equivalent Sb(2)O6 octahedra, corners with three equivalent V(2)O6 octahedra, and corners with four equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-67°. In the second Li site, Li(2) is bonded in a distorted rectangular see-saw-like geometry to one O(5), one O(7), and two equivalent O(11) atoms. In the third Li site, Li(3) is bonded to one O(4), one O(8), and two equivalent O(1) atoms to form distorted LiO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent Sb(1)O6 octahedra, corners with three equivalent V(1)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-68°. In the fourth Li site, Li(4) is bonded to one O(10), one O(2), and two equivalent O(6) atoms to form LiO4 tetrahedra that share  a cornercorner with one Sb(2)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with three equivalent V(1)O6 octahedra, and corners with four equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 58-64°. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(2), one O(8), two equivalent O(1), and two equivalent O(6) atoms to form distorted VO6 octahedra that share corners with two equivalent Sb(2)O6 octahedra, corners with four equivalent Mn(2)O6 octahedra, corners with three equivalent Li(3)O4 tetrahedra, corners with three equivalent Li(4)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-53°. In the second V site, V(2) is bonded to one O(12), one O(7), two equivalent O(11), and two equivalent O(9) atoms to form distorted VO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with four equivalent Sb(1)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra,  an edgeedge with one Sb(2)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-52°. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(3), one O(4), two equivalent O(11), and two equivalent O(6) atoms to form MnO6 octahedra that share corners with two equivalent V(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra, and edges with four equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles are 51°. In the second Mn site, Mn(2) is bonded to one O(1), one O(10), one O(12), one O(5), one O(8), and one O(9) atom to form distorted MnO6 octahedra that share corners with two equivalent V(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Sb(2)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 53°. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(11), one O(2), one O(3), one O(4), one O(6), and one O(7) atom to form SbO6 octahedra that share corners with two equivalent V(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-52°. In the second Sb site, Sb(2) is bonded to one O(10), one O(5), two equivalent O(1), and two equivalent O(9) atoms to form SbO6 octahedra that share corners with two equivalent V(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra, edges with four equivalent Mn(2)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 49°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one V(1), one Mn(2), and one Sb(2) atom. In the second O site, O(2) is bonded to one Li(4), one V(1), and two equivalent Sb(1) atoms to form distorted OLiVSb2 trigonal pyramids that share  a cornercorner with one O(10)LiMn2Sb tetrahedra, corners with two equivalent O(4)LiMnSb2 tetrahedra, corners with two equivalent O(6)LiMnVSb tetrahedra, and edges with two equivalent O(6)LiMnVSb tetrahedra. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Li(1), one Mn(1), and two equivalent Sb(1) atoms. In the fourth O site, O(4) is bonded to one Li(3), one Mn(1), and two equivalent Sb(1) atoms to form distorted OLiMnSb2 tetrahedra that share corners with four equivalent O(6)LiMnVSb tetrahedra and corners with two equivalent O(2)LiVSb2 trigonal pyramids. In the fifth O site, O(5) is bonded to one Li(2), two equivalent Mn(2), and one Sb(2) atom to form OLiMn2Sb tetrahedra that share corners with two equivalent O(12)LiMn2V tetrahedra and corners with three equivalent O(10)LiMn2Sb tetrahedra. In the sixth O site, O(6) is bonded to one Li(4), one V(1), one Mn(1), and one Sb(1) atom to form distorted OLiMnVSb tetrahedra that share  a cornercorner with one O(10)LiMn2Sb tetrahedra,  a cornercorner with one O(6)LiMnVSb tetrahedra, corners with two equivalent O(4)LiMnSb2 tetrahedra,  a cornercorner with one O(2)LiVSb2 trigonal pyramid,  an edgeedge with one O(6)LiMnVSb tetrahedra, and  an edgeedge with one O(2)LiVSb2 trigonal pyramid. In the seventh O site, O(7) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one V(2), and two equivalent Sb(1) atoms. In the eighth O site, O(8) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one V(1), and two equivalent Mn(2) atoms. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Li(1), one V(2), one Mn(2), and one Sb(2) atom. In the tenth O site, O(10) is bonded to one Li(4), two equivalent Mn(2), and one Sb(2) atom to form distorted OLiMn2Sb tetrahedra that share corners with two equivalent O(6)LiMnVSb tetrahedra, corners with three equivalent O(5)LiMn2Sb tetrahedra,  a cornercorner with one O(2)LiVSb2 trigonal pyramid, and  an edgeedge with one O(12)LiMn2V tetrahedra. In the eleventh O site, O(11) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(2), one Mn(1), and one Sb(1) atom. In the twelfth O site, O(12) is bonded to one Li(1), one V(2), and two equivalent Mn(2) atoms to form a mixture of distorted corner and edge-sharing OLiMn2V tetrahedra. is represented by the CIF card [CIF]
data_Li4Mn3V2Sb3O16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.233
_cell_length_b   6.121
_cell_length_c   9.760
_cell_angle_alpha   90.045
_cell_angle_beta   91.838
_cell_angle_gamma   119.419
_symmetry_Int_Tables_number   1
_cell_volume   324.098
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.324  0.662  0.886  1.0
  Li  Li1  1  0.978  0.989  0.986  1.0
  Li  Li2  1  0.988  0.994  0.503  1.0
  Li  Li3  1  0.644  0.322  0.402  1.0
  Mn  Mn4  1  0.664  0.832  0.213  1.0
  Mn  Mn5  1  0.830  0.663  0.709  1.0
  Mn  Mn6  1  0.830  0.168  0.709  1.0
  V  V7  1  0.351  0.676  0.497  1.0
  V  V8  1  0.704  0.352  0.973  1.0
  Sb  Sb9  1  0.168  0.830  0.215  1.0
  Sb  Sb10  1  0.168  0.338  0.215  1.0
  Sb  Sb11  1  0.346  0.173  0.716  1.0
  O  O12  1  0.191  0.848  0.595  1.0
  O  O13  1  0.031  0.516  0.339  1.0
  O  O14  1  0.317  0.658  0.100  1.0
  O  O15  1  0.014  0.007  0.318  1.0
  O  O16  1  0.010  0.005  0.801  1.0
  O  O17  1  0.191  0.342  0.595  1.0
  O  O18  1  0.463  0.953  0.346  1.0
  O  O19  1  0.463  0.511  0.346  1.0
  O  O20  1  0.316  0.158  0.106  1.0
  O  O21  1  0.671  0.835  0.594  1.0
  O  O22  1  0.509  0.470  0.850  1.0
  O  O23  1  0.509  0.040  0.850  1.0
  O  O24  1  0.662  0.331  0.607  1.0
  O  O25  1  0.855  0.678  0.095  1.0
  O  O26  1  0.947  0.474  0.846  1.0
  O  O27  1  0.855  0.177  0.095  1.0
[/CIF]
.