The material described by LiCo(PO3)4 crystallizes in the monoclinic P2_1 space group. Li(1) is bonded in a water-like geometry to one O(10) and one O(11) atom. Co(1) is bonded to one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(10), one O(7), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra, and  a cornercorner with one P(4)O4 tetrahedra. The corner-sharing octahedral tilt angles are 42°. In the second P site, P(2) is bonded to one O(12), one O(3), one O(4), and one O(9) atom to form PO4 tetrahedra that share corners with two equivalent Co(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 43-51°. In the third P site, P(3) is bonded to one O(12), one O(2), one O(6), and one O(8) atom to form PO4 tetrahedra that share corners with two equivalent Co(1)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra, and  a cornercorner with one P(4)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 42-55°. In the fourth P site, P(4) is bonded to one O(1), one O(11), one O(2), and one O(5) atom to form PO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 41°. There are twelve inequivalent O sites. In the first O site, O(12) is bonded in a bent 150 degrees geometry to one P(2) and one P(3) atom. In the second O site, O(1) is bonded in a bent 150 degrees geometry to one P(1) and one P(4) atom. In the third O site, O(2) is bonded in a bent 120 degrees geometry to one P(3) and one P(4) atom. In the fourth O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one P(2) atom. In the fifth O site, O(4) is bonded in a bent 120 degrees geometry to one Co(1) and one P(2) atom. In the sixth O site, O(5) is bonded in a bent 150 degrees geometry to one Co(1) and one P(4) atom. In the seventh O site, O(6) is bonded in a bent 120 degrees geometry to one Co(1) and one P(3) atom. In the eighth O site, O(7) is bonded in a bent 150 degrees geometry to one Co(1) and one P(1) atom. In the ninth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one P(3) atom. In the tenth O site, O(9) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the eleventh O site, O(10) is bonded in a bent 150 degrees geometry to one Li(1) and one P(1) atom. In the twelfth O site, O(11) is bonded in a bent 150 degrees geometry to one Li(1) and one P(4) atom. is represented by the CIF card [CIF]
data_LiCo(PO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.691
_cell_length_b   5.200
_cell_length_c   7.108
_cell_angle_alpha   82.595
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   501.816
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.007  0.378  0.137  1.0
  Li  Li1  1  0.507  0.622  0.863  1.0
  Co  Co2  1  0.237  0.483  0.506  1.0
  Co  Co3  1  0.737  0.517  0.494  1.0
  P  P4  1  0.322  0.778  0.114  1.0
  P  P5  1  0.877  0.003  0.537  1.0
  P  P6  1  0.098  0.971  0.541  1.0
  P  P7  1  0.598  0.029  0.459  1.0
  P  P8  1  0.169  0.140  0.897  1.0
  P  P9  1  0.377  0.997  0.463  1.0
  P  P10  1  0.669  0.860  0.103  1.0
  P  P11  1  0.822  0.222  0.886  1.0
  O  O12  1  0.760  0.045  0.044  1.0
  O  O13  1  0.105  0.966  0.768  1.0
  O  O14  1  0.818  0.217  0.430  1.0
  O  O15  1  0.363  0.270  0.507  1.0
  O  O16  1  0.711  0.627  0.230  1.0
  O  O17  1  0.607  0.302  0.507  1.0
  O  O18  1  0.318  0.783  0.570  1.0
  O  O19  1  0.252  0.606  0.240  1.0
  O  O20  1  0.165  0.174  0.443  1.0
  O  O21  1  0.665  0.826  0.557  1.0
  O  O22  1  0.368  0.991  0.237  1.0
  O  O23  1  0.400  0.652  0.015  1.0
  O  O24  1  0.868  0.009  0.763  1.0
  O  O25  1  0.107  0.698  0.493  1.0
  O  O26  1  0.211  0.373  0.770  1.0
  O  O27  1  0.900  0.348  0.985  1.0
  O  O28  1  0.863  0.730  0.493  1.0
  O  O29  1  0.605  0.034  0.232  1.0
  O  O30  1  0.110  0.187  0.061  1.0
  O  O31  1  0.752  0.394  0.760  1.0
  O  O32  1  0.260  0.955  0.956  1.0
  O  O33  1  0.490  0.917  0.509  1.0
  O  O34  1  0.990  0.083  0.491  1.0
  O  O35  1  0.610  0.813  0.939  1.0
[/CIF]
.
The material described by LiCo(PO3)4 crystallizes in the monoclinic P2_1 space group. Li(1) is bonded in a water-like geometry to one O(10) and one O(11) atom. Co(1) is bonded to one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(10), one O(7), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra, and  a cornercorner with one P(4)O4 tetrahedra. The corner-sharing octahedral tilt angles are 42°. In the second P site, P(2) is bonded to one O(12), one O(3), one O(4), and one O(9) atom to form PO4 tetrahedra that share corners with two equivalent Co(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 43-51°. In the third P site, P(3) is bonded to one O(12), one O(2), one O(6), and one O(8) atom to form PO4 tetrahedra that share corners with two equivalent Co(1)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra, and  a cornercorner with one P(4)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 42-55°. In the fourth P site, P(4) is bonded to one O(1), one O(11), one O(2), and one O(5) atom to form PO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 41°. There are twelve inequivalent O sites. In the first O site, O(12) is bonded in a bent 150 degrees geometry to one P(2) and one P(3) atom. In the second O site, O(1) is bonded in a bent 150 degrees geometry to one P(1) and one P(4) atom. In the third O site, O(2) is bonded in a bent 120 degrees geometry to one P(3) and one P(4) atom. In the fourth O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one P(2) atom. In the fifth O site, O(4) is bonded in a bent 120 degrees geometry to one Co(1) and one P(2) atom. In the sixth O site, O(5) is bonded in a bent 150 degrees geometry to one Co(1) and one P(4) atom. In the seventh O site, O(6) is bonded in a bent 120 degrees geometry to one Co(1) and one P(3) atom. In the eighth O site, O(7) is bonded in a bent 150 degrees geometry to one Co(1) and one P(1) atom. In the ninth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one P(3) atom. In the tenth O site, O(9) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the eleventh O site, O(10) is bonded in a bent 150 degrees geometry to one Li(1) and one P(1) atom. In the twelfth O site, O(11) is bonded in a bent 150 degrees geometry to one Li(1) and one P(4) atom. is represented by the CIF card [CIF]
data_LiCo(PO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.691
_cell_length_b   5.200
_cell_length_c   7.108
_cell_angle_alpha   82.595
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   501.816
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.007  0.378  0.137  1.0
  Li  Li1  1  0.507  0.622  0.863  1.0
  Co  Co2  1  0.237  0.483  0.506  1.0
  Co  Co3  1  0.737  0.517  0.494  1.0
  P  P4  1  0.322  0.778  0.114  1.0
  P  P5  1  0.877  0.003  0.537  1.0
  P  P6  1  0.098  0.971  0.541  1.0
  P  P7  1  0.598  0.029  0.459  1.0
  P  P8  1  0.169  0.140  0.897  1.0
  P  P9  1  0.377  0.997  0.463  1.0
  P  P10  1  0.669  0.860  0.103  1.0
  P  P11  1  0.822  0.222  0.886  1.0
  O  O12  1  0.760  0.045  0.044  1.0
  O  O13  1  0.105  0.966  0.768  1.0
  O  O14  1  0.818  0.217  0.430  1.0
  O  O15  1  0.363  0.270  0.507  1.0
  O  O16  1  0.711  0.627  0.230  1.0
  O  O17  1  0.607  0.302  0.507  1.0
  O  O18  1  0.318  0.783  0.570  1.0
  O  O19  1  0.252  0.606  0.240  1.0
  O  O20  1  0.165  0.174  0.443  1.0
  O  O21  1  0.665  0.826  0.557  1.0
  O  O22  1  0.368  0.991  0.237  1.0
  O  O23  1  0.400  0.652  0.015  1.0
  O  O24  1  0.868  0.009  0.763  1.0
  O  O25  1  0.107  0.698  0.493  1.0
  O  O26  1  0.211  0.373  0.770  1.0
  O  O27  1  0.900  0.348  0.985  1.0
  O  O28  1  0.863  0.730  0.493  1.0
  O  O29  1  0.605  0.034  0.232  1.0
  O  O30  1  0.110  0.187  0.061  1.0
  O  O31  1  0.752  0.394  0.760  1.0
  O  O32  1  0.260  0.955  0.956  1.0
  O  O33  1  0.490  0.917  0.509  1.0
  O  O34  1  0.990  0.083  0.491  1.0
  O  O35  1  0.610  0.813  0.939  1.0
[/CIF]
.