The material described by PtCOI2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four PtCOI2 clusters. Pt(1) is bonded in a rectangular see-saw-like geometry to one C(1), one I(1), and two equivalent I(2) atoms. C(1) is bonded in a linear geometry to one Pt(1) and one O(1) atom. O(1) is bonded in a single-bond geometry to one C(1) atom. There are two inequivalent I sites. In the first I site, I(1) is bonded in a single-bond geometry to one Pt(1) atom. In the second I site, I(2) is bonded in an L-shaped geometry to two equivalent Pt(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_PtCI2O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.365
_cell_length_b   7.365
_cell_length_c   13.735
_cell_angle_alpha   72.610
_cell_angle_beta   72.610
_cell_angle_gamma   81.222
_symmetry_Int_Tables_number   1
_cell_volume   676.883
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pt  Pt0  1  0.745  0.907  0.079  1.0
  Pt  Pt1  1  0.255  0.093  0.921  1.0
  Pt  Pt2  1  0.093  0.255  0.421  1.0
  Pt  Pt3  1  0.907  0.745  0.579  1.0
  C  C4  1  0.282  0.404  0.412  1.0
  C  C5  1  0.596  0.718  0.088  1.0
  C  C6  1  0.404  0.282  0.912  1.0
  C  C7  1  0.718  0.596  0.588  1.0
  I  I8  1  0.969  0.535  0.279  1.0
  I  I9  1  0.822  0.044  0.429  1.0
  I  I10  1  0.465  0.031  0.221  1.0
  I  I11  1  0.956  0.178  0.071  1.0
  I  I12  1  0.031  0.465  0.721  1.0
  I  I13  1  0.535  0.969  0.779  1.0
  I  I14  1  0.044  0.822  0.929  1.0
  I  I15  1  0.178  0.956  0.571  1.0
  O  O16  1  0.497  0.400  0.906  1.0
  O  O17  1  0.600  0.503  0.594  1.0
  O  O18  1  0.503  0.600  0.094  1.0
  O  O19  1  0.400  0.497  0.406  1.0
[/CIF]
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The material described by PtCOI2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four PtCOI2 clusters. Pt(1) is bonded in a rectangular see-saw-like geometry to one C(1), one I(1), and two equivalent I(2) atoms. C(1) is bonded in a linear geometry to one Pt(1) and one O(1) atom. O(1) is bonded in a single-bond geometry to one C(1) atom. There are two inequivalent I sites. In the first I site, I(1) is bonded in a single-bond geometry to one Pt(1) atom. In the second I site, I(2) is bonded in an L-shaped geometry to two equivalent Pt(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_PtCI2O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.365
_cell_length_b   7.365
_cell_length_c   13.735
_cell_angle_alpha   72.610
_cell_angle_beta   72.610
_cell_angle_gamma   81.222
_symmetry_Int_Tables_number   1
_cell_volume   676.883
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pt  Pt0  1  0.745  0.907  0.079  1.0
  Pt  Pt1  1  0.255  0.093  0.921  1.0
  Pt  Pt2  1  0.093  0.255  0.421  1.0
  Pt  Pt3  1  0.907  0.745  0.579  1.0
  C  C4  1  0.282  0.404  0.412  1.0
  C  C5  1  0.596  0.718  0.088  1.0
  C  C6  1  0.404  0.282  0.912  1.0
  C  C7  1  0.718  0.596  0.588  1.0
  I  I8  1  0.969  0.535  0.279  1.0
  I  I9  1  0.822  0.044  0.429  1.0
  I  I10  1  0.465  0.031  0.221  1.0
  I  I11  1  0.956  0.178  0.071  1.0
  I  I12  1  0.031  0.465  0.721  1.0
  I  I13  1  0.535  0.969  0.779  1.0
  I  I14  1  0.044  0.822  0.929  1.0
  I  I15  1  0.178  0.956  0.571  1.0
  O  O16  1  0.497  0.400  0.906  1.0
  O  O17  1  0.600  0.503  0.594  1.0
  O  O18  1  0.503  0.600  0.094  1.0
  O  O19  1  0.400  0.497  0.406  1.0
[/CIF]
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