The structure described by Ru3BiH3(CO)9 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two Ru3BiH3(CO)9 clusters. There are three inequivalent Ru sites. In the first Ru site, Ru(1) is bonded in a 6-coordinate geometry to one C(1), one C(2), one C(3), one Bi(1), one H(1), and one H(2) atom. In the second Ru site, Ru(2) is bonded in a 6-coordinate geometry to one C(4), one C(5), one C(6), one Bi(1), one H(1), and one H(3) atom. In the third Ru site, Ru(3) is bonded in a 6-coordinate geometry to one C(7), one C(8), one C(9), one Bi(1), one H(2), and one H(3) atom. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one Ru(1) and one O(1,8) atom. In the second C site, C(2) is bonded in a linear geometry to one Ru(1) and one O(2) atom. In the third C site, C(3) is bonded in a linear geometry to one Ru(1) and one O(3,6,7) atom. In the fourth C site, C(4) is bonded in a linear geometry to one Ru(2) and one O(4) atom. In the fifth C site, C(5) is bonded in a linear geometry to one Ru(2) and one O(5) atom. In the sixth C site, C(6) is bonded in a linear geometry to one Ru(2) and one O(3,6,7) atom. In the seventh C site, C(7) is bonded in a linear geometry to one Ru(3) and one O(3,6,7) atom. In the eighth C site, C(8) is bonded in a distorted linear geometry to one Ru(3) and one O(1,8) atom. In the ninth C site, C(9) is bonded in a linear geometry to one Ru(3) and one O(9) atom. Bi(1) is bonded in a 3-coordinate geometry to one Ru(1), one Ru(2), and one Ru(3) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a bent 120 degrees geometry to one Ru(1) and one Ru(2) atom. In the second H site, H(2) is bonded in a water-like geometry to one Ru(1) and one Ru(3) atom. In the third H site, H(3) is bonded in a bent 120 degrees geometry to one Ru(2) and one Ru(3) atom. There are six inequivalent O sites. In the first O site, O(1,8) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(2) atom. In the third O site, O(3,6,7) is bonded in a single-bond geometry to one C(3) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(5) atom. In the sixth O site, O(9) is bonded in a single-bond geometry to one C(9) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_BiH3Ru3(CO)9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.324
_cell_length_b   9.378
_cell_length_c   12.686
_cell_angle_alpha   87.945
_cell_angle_beta   108.120
_cell_angle_gamma   111.227
_symmetry_Int_Tables_number   1
_cell_volume   874.019
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.493  0.215  0.597  1.0
  Bi  Bi1  1  0.507  0.785  0.403  1.0
  H  H2  1  0.507  0.145  0.859  1.0
  H  H3  1  0.493  0.855  0.141  1.0
  H  H4  1  0.343  0.314  0.795  1.0
  H  H5  1  0.657  0.686  0.205  1.0
  H  H6  1  0.662  0.406  0.853  1.0
  H  H7  1  0.338  0.594  0.147  1.0
  Ru  Ru8  1  0.298  0.120  0.749  1.0
  Ru  Ru9  1  0.702  0.880  0.251  1.0
  Ru  Ru10  1  0.709  0.241  0.821  1.0
  Ru  Ru11  1  0.291  0.759  0.179  1.0
  Ru  Ru12  1  0.509  0.453  0.735  1.0
  Ru  Ru13  1  0.491  0.547  0.265  1.0
  C  C14  1  0.213  0.093  0.876  1.0
  C  C15  1  0.787  0.907  0.124  1.0
  C  C16  1  0.080  0.110  0.638  1.0
  C  C17  1  0.920  0.890  0.362  1.0
  C  C18  1  0.265  0.913  0.713  1.0
  C  C19  1  0.735  0.087  0.287  1.0
  C  C20  1  0.726  0.050  0.792  1.0
  C  C21  1  0.274  0.950  0.208  1.0
  C  C22  1  0.828  0.272  0.981  1.0
  C  C23  1  0.172  0.728  0.019  1.0
  C  C24  1  0.917  0.357  0.778  1.0
  C  C25  1  0.083  0.643  0.222  1.0
  C  C26  1  0.699  0.600  0.690  1.0
  C  C27  1  0.301  0.400  0.310  1.0
  C  C28  1  0.506  0.580  0.850  1.0
  C  C29  1  0.494  0.420  0.150  1.0
  C  C30  1  0.321  0.484  0.615  1.0
  C  C31  1  0.679  0.516  0.385  1.0
  O  O32  1  0.153  0.076  0.949  1.0
  O  O33  1  0.847  0.924  0.051  1.0
  O  O34  1  0.945  0.107  0.573  1.0
  O  O35  1  0.055  0.893  0.427  1.0
  O  O36  1  0.246  0.786  0.693  1.0
  O  O37  1  0.754  0.214  0.307  1.0
  O  O38  1  0.737  0.933  0.777  1.0
  O  O39  1  0.263  0.067  0.223  1.0
  O  O40  1  0.907  0.290  0.076  1.0
  O  O41  1  0.093  0.710  0.924  1.0
  O  O42  1  0.043  0.431  0.754  1.0
  O  O43  1  0.957  0.569  0.246  1.0
  O  O44  1  0.815  0.692  0.665  1.0
  O  O45  1  0.185  0.308  0.335  1.0
  O  O46  1  0.495  0.654  0.917  1.0
  O  O47  1  0.505  0.346  0.083  1.0
  O  O48  1  0.206  0.503  0.543  1.0
  O  O49  1  0.794  0.497  0.457  1.0
[/CIF]
.
The structure described by Ru3BiH3(CO)9 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two Ru3BiH3(CO)9 clusters. There are three inequivalent Ru sites. In the first Ru site, Ru(1) is bonded in a 6-coordinate geometry to one C(1), one C(2), one C(3), one Bi(1), one H(1), and one H(2) atom. In the second Ru site, Ru(2) is bonded in a 6-coordinate geometry to one C(4), one C(5), one C(6), one Bi(1), one H(1), and one H(3) atom. In the third Ru site, Ru(3) is bonded in a 6-coordinate geometry to one C(7), one C(8), one C(9), one Bi(1), one H(2), and one H(3) atom. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one Ru(1) and one O(1,8) atom. In the second C site, C(2) is bonded in a linear geometry to one Ru(1) and one O(2) atom. In the third C site, C(3) is bonded in a linear geometry to one Ru(1) and one O(3,6,7) atom. In the fourth C site, C(4) is bonded in a linear geometry to one Ru(2) and one O(4) atom. In the fifth C site, C(5) is bonded in a linear geometry to one Ru(2) and one O(5) atom. In the sixth C site, C(6) is bonded in a linear geometry to one Ru(2) and one O(3,6,7) atom. In the seventh C site, C(7) is bonded in a linear geometry to one Ru(3) and one O(3,6,7) atom. In the eighth C site, C(8) is bonded in a distorted linear geometry to one Ru(3) and one O(1,8) atom. In the ninth C site, C(9) is bonded in a linear geometry to one Ru(3) and one O(9) atom. Bi(1) is bonded in a 3-coordinate geometry to one Ru(1), one Ru(2), and one Ru(3) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a bent 120 degrees geometry to one Ru(1) and one Ru(2) atom. In the second H site, H(2) is bonded in a water-like geometry to one Ru(1) and one Ru(3) atom. In the third H site, H(3) is bonded in a bent 120 degrees geometry to one Ru(2) and one Ru(3) atom. There are six inequivalent O sites. In the first O site, O(1,8) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(2) atom. In the third O site, O(3,6,7) is bonded in a single-bond geometry to one C(3) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(5) atom. In the sixth O site, O(9) is bonded in a single-bond geometry to one C(9) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_BiH3Ru3(CO)9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.324
_cell_length_b   9.378
_cell_length_c   12.686
_cell_angle_alpha   87.945
_cell_angle_beta   108.120
_cell_angle_gamma   111.227
_symmetry_Int_Tables_number   1
_cell_volume   874.019
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.493  0.215  0.597  1.0
  Bi  Bi1  1  0.507  0.785  0.403  1.0
  H  H2  1  0.507  0.145  0.859  1.0
  H  H3  1  0.493  0.855  0.141  1.0
  H  H4  1  0.343  0.314  0.795  1.0
  H  H5  1  0.657  0.686  0.205  1.0
  H  H6  1  0.662  0.406  0.853  1.0
  H  H7  1  0.338  0.594  0.147  1.0
  Ru  Ru8  1  0.298  0.120  0.749  1.0
  Ru  Ru9  1  0.702  0.880  0.251  1.0
  Ru  Ru10  1  0.709  0.241  0.821  1.0
  Ru  Ru11  1  0.291  0.759  0.179  1.0
  Ru  Ru12  1  0.509  0.453  0.735  1.0
  Ru  Ru13  1  0.491  0.547  0.265  1.0
  C  C14  1  0.213  0.093  0.876  1.0
  C  C15  1  0.787  0.907  0.124  1.0
  C  C16  1  0.080  0.110  0.638  1.0
  C  C17  1  0.920  0.890  0.362  1.0
  C  C18  1  0.265  0.913  0.713  1.0
  C  C19  1  0.735  0.087  0.287  1.0
  C  C20  1  0.726  0.050  0.792  1.0
  C  C21  1  0.274  0.950  0.208  1.0
  C  C22  1  0.828  0.272  0.981  1.0
  C  C23  1  0.172  0.728  0.019  1.0
  C  C24  1  0.917  0.357  0.778  1.0
  C  C25  1  0.083  0.643  0.222  1.0
  C  C26  1  0.699  0.600  0.690  1.0
  C  C27  1  0.301  0.400  0.310  1.0
  C  C28  1  0.506  0.580  0.850  1.0
  C  C29  1  0.494  0.420  0.150  1.0
  C  C30  1  0.321  0.484  0.615  1.0
  C  C31  1  0.679  0.516  0.385  1.0
  O  O32  1  0.153  0.076  0.949  1.0
  O  O33  1  0.847  0.924  0.051  1.0
  O  O34  1  0.945  0.107  0.573  1.0
  O  O35  1  0.055  0.893  0.427  1.0
  O  O36  1  0.246  0.786  0.693  1.0
  O  O37  1  0.754  0.214  0.307  1.0
  O  O38  1  0.737  0.933  0.777  1.0
  O  O39  1  0.263  0.067  0.223  1.0
  O  O40  1  0.907  0.290  0.076  1.0
  O  O41  1  0.093  0.710  0.924  1.0
  O  O42  1  0.043  0.431  0.754  1.0
  O  O43  1  0.957  0.569  0.246  1.0
  O  O44  1  0.815  0.692  0.665  1.0
  O  O45  1  0.185  0.308  0.335  1.0
  O  O46  1  0.495  0.654  0.917  1.0
  O  O47  1  0.505  0.346  0.083  1.0
  O  O48  1  0.206  0.503  0.543  1.0
  O  O49  1  0.794  0.497  0.457  1.0
[/CIF]
.