The material structure described by (VO2)4Zn is beta Vanadium nitride-derived structured and crystallizes in the monoclinic Cm space group. The structure consists of two 7440-66-6 atoms inside a VO2 framework. In the VO2 framework, there are four inequivalent V sites. In the first V site, V(1) is bonded to one O(2), one O(7), two equivalent O(4), and two equivalent O(5) atoms to form a mixture of corner and edge-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 47-49°. In the second V site, V(2) is bonded to one O(4), one O(8), two equivalent O(3), and two equivalent O(6) atoms to form a mixture of corner and edge-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 47-49°. In the third V site, V(3) is bonded to one O(1), one O(6), two equivalent O(2), and two equivalent O(8) atoms to form a mixture of corner and edge-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 47-49°. In the fourth V site, V(4) is bonded to one O(3), one O(5), two equivalent O(1), and two equivalent O(7) atoms to form a mixture of corner and edge-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 47-49°. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one V(3) and two equivalent V(4) atoms. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one V(1) and two equivalent V(3) atoms. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one V(4) and two equivalent V(2) atoms. In the fourth O site, O(4) is bonded in a distorted T-shaped geometry to one V(2) and two equivalent V(1) atoms. In the fifth O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one V(4) and two equivalent V(1) atoms. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one V(3) and two equivalent V(2) atoms. In the seventh O site, O(7) is bonded in a distorted T-shaped geometry to one V(1) and two equivalent V(4) atoms. In the eighth O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to one V(2) and two equivalent V(3) atoms. is represented by the CIF file [CIF]
data_V4ZnO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.332
_cell_length_b   7.332
_cell_length_c   9.974
_cell_angle_alpha   48.537
_cell_angle_beta   48.537
_cell_angle_gamma   22.599
_symmetry_Int_Tables_number   1
_cell_volume   151.981
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.370  0.370  0.439  1.0
  V  V1  1  0.851  0.851  0.785  1.0
  V  V2  1  0.177  0.177  0.153  1.0
  V  V3  1  0.656  0.656  0.499  1.0
  Zn  Zn4  1  0.552  0.552  0.932  1.0
  O  O5  1  0.161  0.161  0.360  1.0
  O  O6  1  0.552  0.552  0.248  1.0
  O  O7  1  0.474  0.474  0.691  1.0
  O  O8  1  0.866  0.866  0.577  1.0
  O  O9  1  0.849  0.849  0.330  1.0
  O  O10  1  0.221  0.221  0.909  1.0
  O  O11  1  0.176  0.176  0.615  1.0
  O  O12  1  0.799  0.799  0.032  1.0
[/CIF]
.
The material structure described by (VO2)4Zn is beta Vanadium nitride-derived structured and crystallizes in the monoclinic Cm space group. The structure consists of two 7440-66-6 atoms inside a VO2 framework. In the VO2 framework, there are four inequivalent V sites. In the first V site, V(1) is bonded to one O(2), one O(7), two equivalent O(4), and two equivalent O(5) atoms to form a mixture of corner and edge-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 47-49°. In the second V site, V(2) is bonded to one O(4), one O(8), two equivalent O(3), and two equivalent O(6) atoms to form a mixture of corner and edge-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 47-49°. In the third V site, V(3) is bonded to one O(1), one O(6), two equivalent O(2), and two equivalent O(8) atoms to form a mixture of corner and edge-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 47-49°. In the fourth V site, V(4) is bonded to one O(3), one O(5), two equivalent O(1), and two equivalent O(7) atoms to form a mixture of corner and edge-sharing VO6 octahedra. The corner-sharing octahedral tilt angles range from 47-49°. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one V(3) and two equivalent V(4) atoms. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one V(1) and two equivalent V(3) atoms. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one V(4) and two equivalent V(2) atoms. In the fourth O site, O(4) is bonded in a distorted T-shaped geometry to one V(2) and two equivalent V(1) atoms. In the fifth O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one V(4) and two equivalent V(1) atoms. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one V(3) and two equivalent V(2) atoms. In the seventh O site, O(7) is bonded in a distorted T-shaped geometry to one V(1) and two equivalent V(4) atoms. In the eighth O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to one V(2) and two equivalent V(3) atoms. is represented by the CIF file [CIF]
data_V4ZnO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.332
_cell_length_b   7.332
_cell_length_c   9.974
_cell_angle_alpha   48.537
_cell_angle_beta   48.537
_cell_angle_gamma   22.599
_symmetry_Int_Tables_number   1
_cell_volume   151.981
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.370  0.370  0.439  1.0
  V  V1  1  0.851  0.851  0.785  1.0
  V  V2  1  0.177  0.177  0.153  1.0
  V  V3  1  0.656  0.656  0.499  1.0
  Zn  Zn4  1  0.552  0.552  0.932  1.0
  O  O5  1  0.161  0.161  0.360  1.0
  O  O6  1  0.552  0.552  0.248  1.0
  O  O7  1  0.474  0.474  0.691  1.0
  O  O8  1  0.866  0.866  0.577  1.0
  O  O9  1  0.849  0.849  0.330  1.0
  O  O10  1  0.221  0.221  0.909  1.0
  O  O11  1  0.176  0.176  0.615  1.0
  O  O12  1  0.799  0.799  0.032  1.0
[/CIF]
.