The crystal structure described by TlGeCl3 is (Cubic) Perovskite structured and crystallizes in the monoclinic Cm space group. The structure consists of two 7440-28-0 atoms inside a GeCl3 framework. In the GeCl3 framework, Ge(1) is bonded to two equivalent Cl(2) and four equivalent Cl(1) atoms to form corner-sharing GeCl6 octahedra. The corner-sharing octahedral tilt angles range from 4-7°. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a linear geometry to two equivalent Ge(1) atoms. In the second Cl site, Cl(2) is bonded in a linear geometry to two equivalent Ge(1) atoms. is represented by the CIF file [CIF]
data_TlGeCl3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.328
_cell_length_b   5.328
_cell_length_c   5.322
_cell_angle_alpha   89.226
_cell_angle_beta   89.226
_cell_angle_gamma   89.162
_symmetry_Int_Tables_number   1
_cell_volume   151.039
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.989  0.989  0.009  1.0
  Ge  Ge1  1  0.481  0.481  0.467  1.0
  Cl  Cl2  1  0.497  0.020  0.477  1.0
  Cl  Cl3  1  0.503  0.503  0.006  1.0
  Cl  Cl4  1  0.020  0.497  0.477  1.0
[/CIF]
.
The crystal structure described by TlGeCl3 is (Cubic) Perovskite structured and crystallizes in the monoclinic Cm space group. The structure consists of two 7440-28-0 atoms inside a GeCl3 framework. In the GeCl3 framework, Ge(1) is bonded to two equivalent Cl(2) and four equivalent Cl(1) atoms to form corner-sharing GeCl6 octahedra. The corner-sharing octahedral tilt angles range from 4-7°. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a linear geometry to two equivalent Ge(1) atoms. In the second Cl site, Cl(2) is bonded in a linear geometry to two equivalent Ge(1) atoms. is represented by the CIF file [CIF]
data_TlGeCl3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.328
_cell_length_b   5.328
_cell_length_c   5.322
_cell_angle_alpha   89.226
_cell_angle_beta   89.226
_cell_angle_gamma   89.162
_symmetry_Int_Tables_number   1
_cell_volume   151.039
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.989  0.989  0.009  1.0
  Ge  Ge1  1  0.481  0.481  0.467  1.0
  Cl  Cl2  1  0.497  0.020  0.477  1.0
  Cl  Cl3  1  0.503  0.503  0.006  1.0
  Cl  Cl4  1  0.020  0.497  0.477  1.0
[/CIF]
.