The structure described by Cd(Ge2S5)2(C4N)2 crystallizes in the tetragonal I-4 space group. The structure consists of four tetramethylammonium molecules inside a Cd(Ge2S5)2 framework. In the Cd(Ge2S5)2 framework, Cd(1) is bonded to four equivalent S(2) atoms to form CdS4 tetrahedra that share corners with four equivalent Ge(1)S4 tetrahedra. Ge(1) is bonded to one S(2), one S(3), and two equivalent S(1) atoms to form GeS4 tetrahedra that share  a cornercorner with one Cd(1)S4 tetrahedra and corners with three equivalent Ge(1)S4 tetrahedra. There are three inequivalent S sites. In the first S site, S(3) is bonded in a water-like geometry to two equivalent Ge(1) atoms. In the second S site, S(1) is bonded in a water-like geometry to two equivalent Ge(1) atoms. In the third S site, S(2) is bonded in a water-like geometry to one Cd(1) and one Ge(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CdGe4C8(S5N)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.512
_cell_length_b   8.512
_cell_length_c   9.444
_cell_angle_alpha   116.785
_cell_angle_beta   116.785
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   527.274
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.250  0.750  0.500  1.0
  Ge  Ge1  1  0.402  0.482  0.168  1.0
  Ge  Ge2  1  0.765  0.685  0.168  1.0
  Ge  Ge3  1  0.315  0.598  0.832  1.0
  Ge  Ge4  1  0.518  0.235  0.832  1.0
  C  C5  1  0.987  0.071  0.885  1.0
  C  C6  1  0.898  0.814  0.885  1.0
  C  C7  1  0.186  0.013  0.115  1.0
  C  C8  1  0.929  0.102  0.115  1.0
  C  C9  1  0.594  0.146  0.468  1.0
  C  C10  1  0.873  0.322  0.468  1.0
  C  C11  1  0.678  0.406  0.532  1.0
  C  C12  1  0.854  0.127  0.532  1.0
  S  S13  1  0.410  0.200  0.995  1.0
  S  S14  1  0.585  0.796  0.995  1.0
  S  S15  1  0.204  0.590  0.005  1.0
  S  S16  1  0.800  0.415  0.005  1.0
  S  S17  1  0.288  0.428  0.314  1.0
  S  S18  1  0.027  0.887  0.314  1.0
  S  S19  1  0.113  0.712  0.686  1.0
  S  S20  1  0.572  0.973  0.686  1.0
  S  S21  1  0.682  0.682  0.363  1.0
  S  S22  1  0.318  0.318  0.637  1.0
  N  N23  1  0.000  0.000  0.000  1.0
  N  N24  1  0.750  0.250  0.500  1.0
[/CIF]
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The structure described by Cd(Ge2S5)2(C4N)2 crystallizes in the tetragonal I-4 space group. The structure consists of four tetramethylammonium molecules inside a Cd(Ge2S5)2 framework. In the Cd(Ge2S5)2 framework, Cd(1) is bonded to four equivalent S(2) atoms to form CdS4 tetrahedra that share corners with four equivalent Ge(1)S4 tetrahedra. Ge(1) is bonded to one S(2), one S(3), and two equivalent S(1) atoms to form GeS4 tetrahedra that share  a cornercorner with one Cd(1)S4 tetrahedra and corners with three equivalent Ge(1)S4 tetrahedra. There are three inequivalent S sites. In the first S site, S(3) is bonded in a water-like geometry to two equivalent Ge(1) atoms. In the second S site, S(1) is bonded in a water-like geometry to two equivalent Ge(1) atoms. In the third S site, S(2) is bonded in a water-like geometry to one Cd(1) and one Ge(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CdGe4C8(S5N)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.512
_cell_length_b   8.512
_cell_length_c   9.444
_cell_angle_alpha   116.785
_cell_angle_beta   116.785
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   527.274
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.250  0.750  0.500  1.0
  Ge  Ge1  1  0.402  0.482  0.168  1.0
  Ge  Ge2  1  0.765  0.685  0.168  1.0
  Ge  Ge3  1  0.315  0.598  0.832  1.0
  Ge  Ge4  1  0.518  0.235  0.832  1.0
  C  C5  1  0.987  0.071  0.885  1.0
  C  C6  1  0.898  0.814  0.885  1.0
  C  C7  1  0.186  0.013  0.115  1.0
  C  C8  1  0.929  0.102  0.115  1.0
  C  C9  1  0.594  0.146  0.468  1.0
  C  C10  1  0.873  0.322  0.468  1.0
  C  C11  1  0.678  0.406  0.532  1.0
  C  C12  1  0.854  0.127  0.532  1.0
  S  S13  1  0.410  0.200  0.995  1.0
  S  S14  1  0.585  0.796  0.995  1.0
  S  S15  1  0.204  0.590  0.005  1.0
  S  S16  1  0.800  0.415  0.005  1.0
  S  S17  1  0.288  0.428  0.314  1.0
  S  S18  1  0.027  0.887  0.314  1.0
  S  S19  1  0.113  0.712  0.686  1.0
  S  S20  1  0.572  0.973  0.686  1.0
  S  S21  1  0.682  0.682  0.363  1.0
  S  S22  1  0.318  0.318  0.637  1.0
  N  N23  1  0.000  0.000  0.000  1.0
  N  N24  1  0.750  0.250  0.500  1.0
[/CIF]
.