The compound described by KMo2O2Cl7 crystallizes in the monoclinic C2/c space group. K(1) is bonded in a 10-coordinate geometry to two equivalent O(1), two equivalent Cl(1), two equivalent Cl(2), and four equivalent Cl(4) atoms. Mo(1) is bonded in a 6-coordinate geometry to one O(1), one Cl(2), one Cl(3), one Cl(4), and two equivalent Cl(1) atoms. O(1) is bonded in a distorted linear geometry to one K(1) and one Mo(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 3-coordinate geometry to one K(1) and two equivalent Mo(1) atoms. In the second Cl site, Cl(2) is bonded in a distorted water-like geometry to one K(1) and one Mo(1) atom. In the third Cl site, Cl(3) is bonded in an L-shaped geometry to two equivalent Mo(1) atoms. In the fourth Cl site, Cl(4) is bonded in a distorted trigonal non-coplanar geometry to two equivalent K(1) and one Mo(1) atom. is represented by the CIF file [CIF]
data_KMo2Cl7O2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.261
_cell_length_b   8.261
_cell_length_c   10.688
_cell_angle_alpha   77.108
_cell_angle_beta   77.108
_cell_angle_gamma   92.791
_symmetry_Int_Tables_number   1
_cell_volume   689.368
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.409  0.591  0.250  1.0
  K  K1  1  0.591  0.409  0.750  1.0
  Mo  Mo2  1  0.646  0.130  0.162  1.0
  Mo  Mo3  1  0.354  0.870  0.838  1.0
  Mo  Mo4  1  0.870  0.354  0.338  1.0
  Mo  Mo5  1  0.130  0.646  0.662  1.0
  Cl  Cl6  1  0.462  0.794  0.628  1.0
  Cl  Cl7  1  0.806  0.166  0.945  1.0
  Cl  Cl8  1  0.903  0.097  0.250  1.0
  Cl  Cl9  1  0.261  0.430  0.582  1.0
  Cl  Cl10  1  0.739  0.570  0.418  1.0
  Cl  Cl11  1  0.097  0.903  0.750  1.0
  Cl  Cl12  1  0.206  0.538  0.872  1.0
  Cl  Cl13  1  0.834  0.194  0.555  1.0
  Cl  Cl14  1  0.570  0.739  0.918  1.0
  Cl  Cl15  1  0.538  0.206  0.372  1.0
  Cl  Cl16  1  0.194  0.834  0.055  1.0
  Cl  Cl17  1  0.430  0.261  0.082  1.0
  Cl  Cl18  1  0.794  0.462  0.128  1.0
  Cl  Cl19  1  0.166  0.806  0.445  1.0
  O  O20  1  0.426  0.076  0.795  1.0
  O  O21  1  0.924  0.574  0.705  1.0
  O  O22  1  0.574  0.924  0.205  1.0
  O  O23  1  0.076  0.426  0.295  1.0
[/CIF]
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The compound described by KMo2O2Cl7 crystallizes in the monoclinic C2/c space group. K(1) is bonded in a 10-coordinate geometry to two equivalent O(1), two equivalent Cl(1), two equivalent Cl(2), and four equivalent Cl(4) atoms. Mo(1) is bonded in a 6-coordinate geometry to one O(1), one Cl(2), one Cl(3), one Cl(4), and two equivalent Cl(1) atoms. O(1) is bonded in a distorted linear geometry to one K(1) and one Mo(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 3-coordinate geometry to one K(1) and two equivalent Mo(1) atoms. In the second Cl site, Cl(2) is bonded in a distorted water-like geometry to one K(1) and one Mo(1) atom. In the third Cl site, Cl(3) is bonded in an L-shaped geometry to two equivalent Mo(1) atoms. In the fourth Cl site, Cl(4) is bonded in a distorted trigonal non-coplanar geometry to two equivalent K(1) and one Mo(1) atom. is represented by the CIF file [CIF]
data_KMo2Cl7O2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.261
_cell_length_b   8.261
_cell_length_c   10.688
_cell_angle_alpha   77.108
_cell_angle_beta   77.108
_cell_angle_gamma   92.791
_symmetry_Int_Tables_number   1
_cell_volume   689.368
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.409  0.591  0.250  1.0
  K  K1  1  0.591  0.409  0.750  1.0
  Mo  Mo2  1  0.646  0.130  0.162  1.0
  Mo  Mo3  1  0.354  0.870  0.838  1.0
  Mo  Mo4  1  0.870  0.354  0.338  1.0
  Mo  Mo5  1  0.130  0.646  0.662  1.0
  Cl  Cl6  1  0.462  0.794  0.628  1.0
  Cl  Cl7  1  0.806  0.166  0.945  1.0
  Cl  Cl8  1  0.903  0.097  0.250  1.0
  Cl  Cl9  1  0.261  0.430  0.582  1.0
  Cl  Cl10  1  0.739  0.570  0.418  1.0
  Cl  Cl11  1  0.097  0.903  0.750  1.0
  Cl  Cl12  1  0.206  0.538  0.872  1.0
  Cl  Cl13  1  0.834  0.194  0.555  1.0
  Cl  Cl14  1  0.570  0.739  0.918  1.0
  Cl  Cl15  1  0.538  0.206  0.372  1.0
  Cl  Cl16  1  0.194  0.834  0.055  1.0
  Cl  Cl17  1  0.430  0.261  0.082  1.0
  Cl  Cl18  1  0.794  0.462  0.128  1.0
  Cl  Cl19  1  0.166  0.806  0.445  1.0
  O  O20  1  0.426  0.076  0.795  1.0
  O  O21  1  0.924  0.574  0.705  1.0
  O  O22  1  0.574  0.924  0.205  1.0
  O  O23  1  0.076  0.426  0.295  1.0
[/CIF]
.