The material described by Li3Al3P3H2O14F crystallizes in the triclinic P1 space group. There are six inequivalent Li sites. In the first Li site, Li(1) is bonded in a 5-coordinate geometry to one O(20), one O(3), one O(7), one O(8), and one F(2) atom. In the second Li site, Li(2) is bonded in a 6-coordinate geometry to one O(10), one O(13), one O(2), one O(23), one O(6), and one F(1) atom. In the third Li site, Li(3) is bonded in a 5-coordinate geometry to one O(11), one O(15), one O(18), one O(26), and one O(4) atom. In the fourth Li site, Li(4) is bonded in a 7-coordinate geometry to one H(3), one O(12), one O(16), one O(2), one O(23), one O(27), and one O(9) atom. In the fifth Li site, Li(5) is bonded in a 5-coordinate geometry to one O(14), one O(17), one O(21), one O(26), and one O(4) atom. In the sixth Li site, Li(6) is bonded in a 7-coordinate geometry to one H(2), one O(19), one O(20), one O(22), one O(24), one O(25), and one O(7) atom. There are six inequivalent Al sites. In the first Al site, Al(1) is bonded to one O(16), one O(2), one O(20), one O(22), one O(3), and one F(1) atom to form AlO5F octahedra that share  a cornercorner with one Al(4)O5F octahedra,  a cornercorner with one Al(6)O5F octahedra, corners with two equivalent P(1)O4 tetrahedra, and corners with two equivalent P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 41-46°. In the second Al site, Al(2) is bonded to one O(12), one O(15), one O(21), one O(23), one O(4), and one O(6) atom to form AlO6 octahedra that share  a cornercorner with one Al(4)O5F octahedra,  a cornercorner with one Al(5)O6 octahedra, corners with two equivalent P(3)O4 tetrahedra, and corners with two equivalent P(4)O4 tetrahedra. The corner-sharing octahedral tilt angles are 47°. In the third Al site, Al(3) is bonded to one O(11), one O(17), one O(25), one O(26), one O(7), and one F(2) atom to form AlO5F octahedra that share  a cornercorner with one Al(6)O5F octahedra,  a cornercorner with one Al(5)O6 octahedra, corners with two equivalent P(5)O4 tetrahedra, and corners with two equivalent P(6)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 41-46°. In the fourth Al site, Al(4) is bonded to one O(10), one O(12), one O(13), one O(27), one O(9), and one F(1) atom to form AlO5F octahedra that share  a cornercorner with one Al(1)O5F octahedra,  a cornercorner with one Al(2)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one P(4)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 41-47°. In the fifth Al site, Al(5) is bonded to one O(1), one O(14), one O(15), one O(17), one O(18), and one O(28) atom to form AlO6 octahedra that share  a cornercorner with one Al(3)O5F octahedra,  a cornercorner with one Al(2)O6 octahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, and  a cornercorner with one P(6)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 46-47°. In the sixth Al site, Al(6) is bonded to one O(19), one O(22), one O(24), one O(5), one O(8), and one F(2) atom to form AlO5F octahedra that share  a cornercorner with one Al(1)O5F octahedra,  a cornercorner with one Al(3)O5F octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, and  a cornercorner with one P(6)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 41-46°. There are six inequivalent P sites. In the first P site, P(1) is bonded to one O(16), one O(2), one O(5), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Al(4)O5F octahedra,  a cornercorner with one Al(6)O5F octahedra, and corners with two equivalent Al(1)O5F octahedra. The corner-sharing octahedral tilt angles range from 34-51°. In the second P site, P(2) is bonded to one O(20), one O(27), one O(3), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Al(4)O5F octahedra,  a cornercorner with one Al(6)O5F octahedra, and corners with two equivalent Al(1)O5F octahedra. The corner-sharing octahedral tilt angles range from 31-50°. In the third P site, P(3) is bonded to one O(10), one O(14), one O(21), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one Al(4)O5F octahedra,  a cornercorner with one Al(5)O6 octahedra, and corners with two equivalent Al(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 35-52°. In the fourth P site, P(4) is bonded to one O(13), one O(23), one O(28), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one Al(4)O5F octahedra,  a cornercorner with one Al(5)O6 octahedra, and corners with two equivalent Al(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 35-52°. In the fifth P site, P(5) is bonded to one O(1), one O(19), one O(25), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Al(6)O5F octahedra,  a cornercorner with one Al(5)O6 octahedra, and corners with two equivalent Al(3)O5F octahedra. The corner-sharing octahedral tilt angles range from 34-52°. In the sixth P site, P(6) is bonded to one O(11), one O(18), one O(24), and one O(26) atom to form PO4 tetrahedra that share  a cornercorner with one Al(6)O5F octahedra,  a cornercorner with one Al(5)O6 octahedra, and corners with two equivalent Al(3)O5F octahedra. The corner-sharing octahedral tilt angles range from 32-50°. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(15) atom. In the second H site, H(2) is bonded in a single-bond geometry to one Li(6) and one O(22) atom. In the third H site, H(3) is bonded in a single-bond geometry to one Li(4) and one O(12) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(17) atom. There are twenty-eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Al(5) and one P(5) atom. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one Li(2), one Li(4), one Al(1), and one P(1) atom. In the third O site, O(3) is bonded in a T-shaped geometry to one Li(1), one Al(1), and one P(2) atom. In the fourth O site, O(4) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one Li(5), one Al(2), and one P(3) atom. In the fifth O site, O(5) is bonded in a 2-coordinate geometry to one Al(6) and one P(1) atom. In the sixth O site, O(6) is bonded in a distorted T-shaped geometry to one Li(2), one Al(2), and one P(4) atom. In the seventh O site, O(7) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(6), one Al(3), and one P(5) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Li(1), one Al(6), and one P(2) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Li(4), one Al(4), and one P(1) atom. In the tenth O site, O(10) is bonded in a 2-coordinate geometry to one Li(2), one Al(4), and one P(3) atom. In the eleventh O site, O(11) is bonded in a T-shaped geometry to one Li(3), one Al(3), and one P(6) atom. In the twelfth O site, O(12) is bonded in a distorted single-bond geometry to one Li(4), one Al(2), one Al(4), and one H(3) atom. In the thirteenth O site, O(13) is bonded in a distorted trigonal planar geometry to one Li(2), one Al(4), and one P(4) atom. In the fourteenth O site, O(14) is bonded in a 3-coordinate geometry to one Li(5), one Al(5), and one P(3) atom. In the fifteenth O site, O(15) is bonded in a distorted single-bond geometry to one Li(3), one Al(2), one Al(5), and one H(1) atom. In the sixteenth O site, O(16) is bonded in a T-shaped geometry to one Li(4), one Al(1), and one P(1) atom. In the seventeenth O site, O(17) is bonded in a distorted single-bond geometry to one Li(5), one Al(3), one Al(5), and one H(4) atom. In the eighteenth O site, O(18) is bonded in a 3-coordinate geometry to one Li(3), one Al(5), and one P(6) atom. In the nineteenth O site, O(19) is bonded in a 3-coordinate geometry to one Li(6), one Al(6), and one P(5) atom. In the twentieth O site, O(20) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Li(6), one Al(1), and one P(2) atom. In the twenty-first O site, O(21) is bonded in a T-shaped geometry to one Li(5), one Al(2), and one P(3) atom. In the twenty-second O site, O(22) is bonded in a distorted single-bond geometry to one Li(6), one Al(1), one Al(6), and one H(2) atom. In the twenty-third O site, O(23) is bonded in a 4-coordinate geometry to one Li(2), one Li(4), one Al(2), and one P(4) atom. In the twenty-fourth O site, O(24) is bonded in a 3-coordinate geometry to one Li(6), one Al(6), and one P(6) atom. In the twenty-fifth O site, O(25) is bonded in a T-shaped geometry to one Li(6), one Al(3), and one P(5) atom. In the twenty-sixth O site, O(26) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one Li(5), one Al(3), and one P(6) atom. In the twenty-seventh O site, O(27) is bonded in a 3-coordinate geometry to one Li(4), one Al(4), and one P(2) atom. In the twenty-eighth O site, O(28) is bonded in a 2-coordinate geometry to one Al(5) and one P(4) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal non-coplanar geometry to one Li(2), one Al(1), and one Al(4) atom. In the second F site, F(2) is bonded in a trigonal non-coplanar geometry to one Li(1), one Al(3), and one Al(6) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li3Al3P3H2O14F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.088
_cell_length_b   7.137
_cell_length_c   14.213
_cell_angle_alpha   90.620
_cell_angle_beta   93.246
_cell_angle_gamma   106.841
_symmetry_Int_Tables_number   1
_cell_volume   493.048
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.418  0.681  0.968  1.0
  Li  Li1  1  0.090  0.352  0.636  1.0
  Li  Li2  1  0.749  0.009  0.298  1.0
  Li  Li3  1  0.235  0.980  0.708  1.0
  Li  Li4  1  0.908  0.660  0.368  1.0
  Li  Li5  1  0.556  0.312  0.042  1.0
  Al  Al6  1  0.335  0.334  0.836  1.0
  Al  Al7  1  0.002  0.003  0.501  1.0
  Al  Al8  1  0.656  0.667  0.168  1.0
  Al  Al9  1  0.674  0.672  0.667  1.0
  Al  Al10  1  0.327  0.334  0.334  1.0
  Al  Al11  1  0.999  0.004  1.000  1.0
  P  P12  1  0.732  0.059  0.794  1.0
  P  P13  1  0.935  0.612  0.871  1.0
  P  P14  1  0.399  0.726  0.462  1.0
  P  P15  1  0.601  0.278  0.539  1.0
  P  P16  1  0.054  0.393  0.126  1.0
  P  P17  1  0.261  0.946  0.204  1.0
  H  H18  1  0.903  0.250  0.406  1.0
  H  H19  1  0.424  0.084  0.929  1.0
  H  H20  1  0.099  0.754  0.595  1.0
  H  H21  1  0.747  0.417  0.260  1.0
  O  O22  1  0.059  0.340  0.232  1.0
  O  O23  1  0.031  0.154  0.765  1.0
  O  O24  1  0.109  0.468  0.886  1.0
  O  O25  1  0.698  0.814  0.433  1.0
  O  O26  1  0.732  0.003  0.900  1.0
  O  O27  1  0.771  0.132  0.556  1.0
  O  O28  1  0.352  0.491  0.096  1.0
  O  O29  1  0.082  0.786  0.939  1.0
  O  O30  1  0.584  0.881  0.729  1.0
  O  O31  1  0.398  0.670  0.568  1.0
  O  O32  1  0.435  0.802  0.219  1.0
  O  O33  1  0.975  0.837  0.606  1.0
  O  O34  1  0.754  0.455  0.605  1.0
  O  O35  1  0.246  0.549  0.396  1.0
  O  O36  1  0.026  0.168  0.394  1.0
  O  O37  1  0.554  0.199  0.779  1.0
  O  O38  1  0.626  0.500  0.273  1.0
  O  O39  1  0.410  0.120  0.272  1.0
  O  O40  1  0.907  0.215  0.060  1.0
  O  O41  1  0.635  0.521  0.901  1.0
  O  O42  1  0.230  0.872  0.446  1.0
  O  O43  1  0.302  0.167  0.940  1.0
  O  O44  1  0.302  0.192  0.568  1.0
  O  O45  1  0.255  0.007  0.101  1.0
  O  O46  1  0.872  0.532  0.111  1.0
  O  O47  1  0.962  0.851  0.234  1.0
  O  O48  1  0.932  0.672  0.767  1.0
  O  O49  1  0.603  0.331  0.434  1.0
  F  F50  1  0.385  0.493  0.727  1.0
  F  F51  1  0.708  0.828  0.060  1.0
[/CIF]
.
The material described by Li3Al3P3H2O14F crystallizes in the triclinic P1 space group. There are six inequivalent Li sites. In the first Li site, Li(1) is bonded in a 5-coordinate geometry to one O(20), one O(3), one O(7), one O(8), and one F(2) atom. In the second Li site, Li(2) is bonded in a 6-coordinate geometry to one O(10), one O(13), one O(2), one O(23), one O(6), and one F(1) atom. In the third Li site, Li(3) is bonded in a 5-coordinate geometry to one O(11), one O(15), one O(18), one O(26), and one O(4) atom. In the fourth Li site, Li(4) is bonded in a 7-coordinate geometry to one H(3), one O(12), one O(16), one O(2), one O(23), one O(27), and one O(9) atom. In the fifth Li site, Li(5) is bonded in a 5-coordinate geometry to one O(14), one O(17), one O(21), one O(26), and one O(4) atom. In the sixth Li site, Li(6) is bonded in a 7-coordinate geometry to one H(2), one O(19), one O(20), one O(22), one O(24), one O(25), and one O(7) atom. There are six inequivalent Al sites. In the first Al site, Al(1) is bonded to one O(16), one O(2), one O(20), one O(22), one O(3), and one F(1) atom to form AlO5F octahedra that share  a cornercorner with one Al(4)O5F octahedra,  a cornercorner with one Al(6)O5F octahedra, corners with two equivalent P(1)O4 tetrahedra, and corners with two equivalent P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 41-46°. In the second Al site, Al(2) is bonded to one O(12), one O(15), one O(21), one O(23), one O(4), and one O(6) atom to form AlO6 octahedra that share  a cornercorner with one Al(4)O5F octahedra,  a cornercorner with one Al(5)O6 octahedra, corners with two equivalent P(3)O4 tetrahedra, and corners with two equivalent P(4)O4 tetrahedra. The corner-sharing octahedral tilt angles are 47°. In the third Al site, Al(3) is bonded to one O(11), one O(17), one O(25), one O(26), one O(7), and one F(2) atom to form AlO5F octahedra that share  a cornercorner with one Al(6)O5F octahedra,  a cornercorner with one Al(5)O6 octahedra, corners with two equivalent P(5)O4 tetrahedra, and corners with two equivalent P(6)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 41-46°. In the fourth Al site, Al(4) is bonded to one O(10), one O(12), one O(13), one O(27), one O(9), and one F(1) atom to form AlO5F octahedra that share  a cornercorner with one Al(1)O5F octahedra,  a cornercorner with one Al(2)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one P(4)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 41-47°. In the fifth Al site, Al(5) is bonded to one O(1), one O(14), one O(15), one O(17), one O(18), and one O(28) atom to form AlO6 octahedra that share  a cornercorner with one Al(3)O5F octahedra,  a cornercorner with one Al(2)O6 octahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, and  a cornercorner with one P(6)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 46-47°. In the sixth Al site, Al(6) is bonded to one O(19), one O(22), one O(24), one O(5), one O(8), and one F(2) atom to form AlO5F octahedra that share  a cornercorner with one Al(1)O5F octahedra,  a cornercorner with one Al(3)O5F octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, and  a cornercorner with one P(6)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 41-46°. There are six inequivalent P sites. In the first P site, P(1) is bonded to one O(16), one O(2), one O(5), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Al(4)O5F octahedra,  a cornercorner with one Al(6)O5F octahedra, and corners with two equivalent Al(1)O5F octahedra. The corner-sharing octahedral tilt angles range from 34-51°. In the second P site, P(2) is bonded to one O(20), one O(27), one O(3), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Al(4)O5F octahedra,  a cornercorner with one Al(6)O5F octahedra, and corners with two equivalent Al(1)O5F octahedra. The corner-sharing octahedral tilt angles range from 31-50°. In the third P site, P(3) is bonded to one O(10), one O(14), one O(21), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one Al(4)O5F octahedra,  a cornercorner with one Al(5)O6 octahedra, and corners with two equivalent Al(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 35-52°. In the fourth P site, P(4) is bonded to one O(13), one O(23), one O(28), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one Al(4)O5F octahedra,  a cornercorner with one Al(5)O6 octahedra, and corners with two equivalent Al(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 35-52°. In the fifth P site, P(5) is bonded to one O(1), one O(19), one O(25), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Al(6)O5F octahedra,  a cornercorner with one Al(5)O6 octahedra, and corners with two equivalent Al(3)O5F octahedra. The corner-sharing octahedral tilt angles range from 34-52°. In the sixth P site, P(6) is bonded to one O(11), one O(18), one O(24), and one O(26) atom to form PO4 tetrahedra that share  a cornercorner with one Al(6)O5F octahedra,  a cornercorner with one Al(5)O6 octahedra, and corners with two equivalent Al(3)O5F octahedra. The corner-sharing octahedral tilt angles range from 32-50°. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(15) atom. In the second H site, H(2) is bonded in a single-bond geometry to one Li(6) and one O(22) atom. In the third H site, H(3) is bonded in a single-bond geometry to one Li(4) and one O(12) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(17) atom. There are twenty-eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Al(5) and one P(5) atom. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one Li(2), one Li(4), one Al(1), and one P(1) atom. In the third O site, O(3) is bonded in a T-shaped geometry to one Li(1), one Al(1), and one P(2) atom. In the fourth O site, O(4) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one Li(5), one Al(2), and one P(3) atom. In the fifth O site, O(5) is bonded in a 2-coordinate geometry to one Al(6) and one P(1) atom. In the sixth O site, O(6) is bonded in a distorted T-shaped geometry to one Li(2), one Al(2), and one P(4) atom. In the seventh O site, O(7) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(6), one Al(3), and one P(5) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Li(1), one Al(6), and one P(2) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Li(4), one Al(4), and one P(1) atom. In the tenth O site, O(10) is bonded in a 2-coordinate geometry to one Li(2), one Al(4), and one P(3) atom. In the eleventh O site, O(11) is bonded in a T-shaped geometry to one Li(3), one Al(3), and one P(6) atom. In the twelfth O site, O(12) is bonded in a distorted single-bond geometry to one Li(4), one Al(2), one Al(4), and one H(3) atom. In the thirteenth O site, O(13) is bonded in a distorted trigonal planar geometry to one Li(2), one Al(4), and one P(4) atom. In the fourteenth O site, O(14) is bonded in a 3-coordinate geometry to one Li(5), one Al(5), and one P(3) atom. In the fifteenth O site, O(15) is bonded in a distorted single-bond geometry to one Li(3), one Al(2), one Al(5), and one H(1) atom. In the sixteenth O site, O(16) is bonded in a T-shaped geometry to one Li(4), one Al(1), and one P(1) atom. In the seventeenth O site, O(17) is bonded in a distorted single-bond geometry to one Li(5), one Al(3), one Al(5), and one H(4) atom. In the eighteenth O site, O(18) is bonded in a 3-coordinate geometry to one Li(3), one Al(5), and one P(6) atom. In the nineteenth O site, O(19) is bonded in a 3-coordinate geometry to one Li(6), one Al(6), and one P(5) atom. In the twentieth O site, O(20) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Li(6), one Al(1), and one P(2) atom. In the twenty-first O site, O(21) is bonded in a T-shaped geometry to one Li(5), one Al(2), and one P(3) atom. In the twenty-second O site, O(22) is bonded in a distorted single-bond geometry to one Li(6), one Al(1), one Al(6), and one H(2) atom. In the twenty-third O site, O(23) is bonded in a 4-coordinate geometry to one Li(2), one Li(4), one Al(2), and one P(4) atom. In the twenty-fourth O site, O(24) is bonded in a 3-coordinate geometry to one Li(6), one Al(6), and one P(6) atom. In the twenty-fifth O site, O(25) is bonded in a T-shaped geometry to one Li(6), one Al(3), and one P(5) atom. In the twenty-sixth O site, O(26) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one Li(5), one Al(3), and one P(6) atom. In the twenty-seventh O site, O(27) is bonded in a 3-coordinate geometry to one Li(4), one Al(4), and one P(2) atom. In the twenty-eighth O site, O(28) is bonded in a 2-coordinate geometry to one Al(5) and one P(4) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal non-coplanar geometry to one Li(2), one Al(1), and one Al(4) atom. In the second F site, F(2) is bonded in a trigonal non-coplanar geometry to one Li(1), one Al(3), and one Al(6) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li3Al3P3H2O14F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.088
_cell_length_b   7.137
_cell_length_c   14.213
_cell_angle_alpha   90.620
_cell_angle_beta   93.246
_cell_angle_gamma   106.841
_symmetry_Int_Tables_number   1
_cell_volume   493.048
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.418  0.681  0.968  1.0
  Li  Li1  1  0.090  0.352  0.636  1.0
  Li  Li2  1  0.749  0.009  0.298  1.0
  Li  Li3  1  0.235  0.980  0.708  1.0
  Li  Li4  1  0.908  0.660  0.368  1.0
  Li  Li5  1  0.556  0.312  0.042  1.0
  Al  Al6  1  0.335  0.334  0.836  1.0
  Al  Al7  1  0.002  0.003  0.501  1.0
  Al  Al8  1  0.656  0.667  0.168  1.0
  Al  Al9  1  0.674  0.672  0.667  1.0
  Al  Al10  1  0.327  0.334  0.334  1.0
  Al  Al11  1  0.999  0.004  1.000  1.0
  P  P12  1  0.732  0.059  0.794  1.0
  P  P13  1  0.935  0.612  0.871  1.0
  P  P14  1  0.399  0.726  0.462  1.0
  P  P15  1  0.601  0.278  0.539  1.0
  P  P16  1  0.054  0.393  0.126  1.0
  P  P17  1  0.261  0.946  0.204  1.0
  H  H18  1  0.903  0.250  0.406  1.0
  H  H19  1  0.424  0.084  0.929  1.0
  H  H20  1  0.099  0.754  0.595  1.0
  H  H21  1  0.747  0.417  0.260  1.0
  O  O22  1  0.059  0.340  0.232  1.0
  O  O23  1  0.031  0.154  0.765  1.0
  O  O24  1  0.109  0.468  0.886  1.0
  O  O25  1  0.698  0.814  0.433  1.0
  O  O26  1  0.732  0.003  0.900  1.0
  O  O27  1  0.771  0.132  0.556  1.0
  O  O28  1  0.352  0.491  0.096  1.0
  O  O29  1  0.082  0.786  0.939  1.0
  O  O30  1  0.584  0.881  0.729  1.0
  O  O31  1  0.398  0.670  0.568  1.0
  O  O32  1  0.435  0.802  0.219  1.0
  O  O33  1  0.975  0.837  0.606  1.0
  O  O34  1  0.754  0.455  0.605  1.0
  O  O35  1  0.246  0.549  0.396  1.0
  O  O36  1  0.026  0.168  0.394  1.0
  O  O37  1  0.554  0.199  0.779  1.0
  O  O38  1  0.626  0.500  0.273  1.0
  O  O39  1  0.410  0.120  0.272  1.0
  O  O40  1  0.907  0.215  0.060  1.0
  O  O41  1  0.635  0.521  0.901  1.0
  O  O42  1  0.230  0.872  0.446  1.0
  O  O43  1  0.302  0.167  0.940  1.0
  O  O44  1  0.302  0.192  0.568  1.0
  O  O45  1  0.255  0.007  0.101  1.0
  O  O46  1  0.872  0.532  0.111  1.0
  O  O47  1  0.962  0.851  0.234  1.0
  O  O48  1  0.932  0.672  0.767  1.0
  O  O49  1  0.603  0.331  0.434  1.0
  F  F50  1  0.385  0.493  0.727  1.0
  F  F51  1  0.708  0.828  0.060  1.0
[/CIF]
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