The material structure described by Ba10Pr5Ir(Ru2O15)2 is (Cubic) Perovskite-derived structured and crystallizes in the monoclinic C2/m space group. There are five inequivalent Ba sites. In the first Ba site, Ba(1) is bonded to one O(8), one O(9), two equivalent O(1), two equivalent O(10), two equivalent O(5), and four equivalent O(4) atoms to form BaO12 cuboctahedra that share corners with three equivalent Ba(2)O12 cuboctahedra, corners with three equivalent Ba(5)O12 cuboctahedra, corners with six equivalent Ba(1)O12 cuboctahedra, faces with three equivalent Ba(4)O12 cuboctahedra, faces with three equivalent Ba(5)O12 cuboctahedra,  a faceface with one Pr(1)O6 octahedra,  a faceface with one Ir(1)O6 octahedra, faces with three equivalent Pr(3)O6 octahedra, and faces with three equivalent Ru(1)O6 octahedra. In the second Ba site, Ba(2) is bonded to one O(7), one O(8), two equivalent O(1), two equivalent O(2), two equivalent O(6), and four equivalent O(3) atoms to form BaO12 cuboctahedra that share corners with three equivalent Ba(1)O12 cuboctahedra, corners with three equivalent Ba(3)O12 cuboctahedra, corners with six equivalent Ba(2)O12 cuboctahedra, faces with three equivalent Ba(3)O12 cuboctahedra, faces with three equivalent Ba(4)O12 cuboctahedra,  a faceface with one Pr(2)O6 octahedra,  a faceface with one Ru(1)O6 octahedra, faces with three equivalent Pr(1)O6 octahedra, and faces with three equivalent Ru(2)O6 octahedra. In the third Ba site, Ba(3) is bonded to one O(6), two equivalent O(3), three equivalent O(7), and six equivalent O(2) atoms to form BaO12 cuboctahedra that share corners with three equivalent Ba(2)O12 cuboctahedra, corners with three equivalent Ba(4)O12 cuboctahedra, corners with six equivalent Ba(3)O12 cuboctahedra, faces with three equivalent Ba(2)O12 cuboctahedra, faces with three equivalent Ba(3)O12 cuboctahedra,  a faceface with one Pr(1)O6 octahedra, faces with three equivalent Pr(2)O6 octahedra, and faces with four equivalent Ru(2)O6 octahedra. In the fourth Ba site, Ba(4) is bonded to one O(10), one O(6), two equivalent O(3), two equivalent O(4), two equivalent O(8), and four equivalent O(1) atoms to form BaO12 cuboctahedra that share corners with three equivalent Ba(3)O12 cuboctahedra, corners with three equivalent Ba(5)O12 cuboctahedra, corners with six equivalent Ba(4)O12 cuboctahedra, faces with three equivalent Ba(1)O12 cuboctahedra, faces with three equivalent Ba(2)O12 cuboctahedra,  a faceface with one Pr(3)O6 octahedra,  a faceface with one Ru(2)O6 octahedra, faces with three equivalent Pr(1)O6 octahedra, and faces with three equivalent Ru(1)O6 octahedra. In the fifth Ba site, Ba(5) is bonded to one O(10), two equivalent O(4), three equivalent O(9), and six equivalent O(5) atoms to form BaO12 cuboctahedra that share corners with three equivalent Ba(1)O12 cuboctahedra, corners with three equivalent Ba(4)O12 cuboctahedra, corners with six equivalent Ba(5)O12 cuboctahedra, faces with three equivalent Ba(1)O12 cuboctahedra, faces with three equivalent Ba(5)O12 cuboctahedra,  a faceface with one Ru(1)O6 octahedra, faces with three equivalent Ir(1)O6 octahedra, and faces with four equivalent Pr(3)O6 octahedra. There are three inequivalent Pr sites. In the first Pr site, Pr(1) is bonded to one O(6), one O(8), two equivalent O(1), and two equivalent O(3) atoms to form PrO6 octahedra that share corners with three equivalent Ru(1)O6 octahedra, corners with three equivalent Ru(2)O6 octahedra,  a faceface with one Ba(1)O12 cuboctahedra,  a faceface with one Ba(3)O12 cuboctahedra, faces with three equivalent Ba(2)O12 cuboctahedra, and faces with three equivalent Ba(4)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the second Pr site, Pr(2) is bonded to two equivalent O(7) and four equivalent O(2) atoms to form PrO6 octahedra that share corners with six equivalent Ru(2)O6 octahedra, faces with two equivalent Ba(2)O12 cuboctahedra, and faces with six equivalent Ba(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the third Pr site, Pr(3) is bonded to one O(10), one O(9), two equivalent O(4), and two equivalent O(5) atoms to form PrO6 octahedra that share corners with three equivalent Ru(1)O6 octahedra, corners with three equivalent Ir(1)O6 octahedra,  a faceface with one Ba(4)O12 cuboctahedra, faces with three equivalent Ba(1)O12 cuboctahedra, and faces with four equivalent Ba(5)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. There are two inequivalent Ru sites. In the first Ru site, Ru(1) is bonded to one O(10), one O(8), two equivalent O(1), and two equivalent O(4) atoms to form RuO6 octahedra that share corners with three equivalent Pr(1)O6 octahedra, corners with three equivalent Pr(3)O6 octahedra,  a faceface with one Ba(2)O12 cuboctahedra,  a faceface with one Ba(5)O12 cuboctahedra, faces with three equivalent Ba(1)O12 cuboctahedra, and faces with three equivalent Ba(4)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the second Ru site, Ru(2) is bonded to one O(6), one O(7), two equivalent O(2), and two equivalent O(3) atoms to form RuO6 octahedra that share corners with three equivalent Pr(1)O6 octahedra, corners with three equivalent Pr(2)O6 octahedra,  a faceface with one Ba(4)O12 cuboctahedra, faces with three equivalent Ba(2)O12 cuboctahedra, and faces with four equivalent Ba(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. Ir(1) is bonded to two equivalent O(9) and four equivalent O(5) atoms to form IrO6 octahedra that share corners with six equivalent Pr(3)O6 octahedra, faces with two equivalent Ba(1)O12 cuboctahedra, and faces with six equivalent Ba(5)O12 cuboctahedra. The corner-sharing octahedral tilt angles are 1°. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to one Ba(1), one Ba(2), two equivalent Ba(4), one Pr(1), and one Ru(1) atom. In the second O site, O(2) is bonded in a distorted linear geometry to one Ba(2), three equivalent Ba(3), one Pr(2), and one Ru(2) atom. In the third O site, O(3) is bonded in a distorted linear geometry to one Ba(3), one Ba(4), two equivalent Ba(2), one Pr(1), and one Ru(2) atom. In the fourth O site, O(4) is bonded in a distorted linear geometry to one Ba(4), one Ba(5), two equivalent Ba(1), one Pr(3), and one Ru(1) atom. In the fifth O site, O(5) is bonded in a distorted linear geometry to one Ba(1), three equivalent Ba(5), one Pr(3), and one Ir(1) atom. In the sixth O site, O(6) is bonded in a distorted linear geometry to one Ba(3), one Ba(4), two equivalent Ba(2), one Pr(1), and one Ru(2) atom. In the seventh O site, O(7) is bonded in a distorted linear geometry to one Ba(2), three equivalent Ba(3), one Pr(2), and one Ru(2) atom. In the eighth O site, O(8) is bonded in a distorted linear geometry to one Ba(1), one Ba(2), two equivalent Ba(4), one Pr(1), and one Ru(1) atom. In the ninth O site, O(9) is bonded in a distorted linear geometry to one Ba(1), three equivalent Ba(5), one Pr(3), and one Ir(1) atom. In the tenth O site, O(10) is bonded in a distorted linear geometry to one Ba(4), one Ba(5), two equivalent Ba(1), one Pr(3), and one Ru(1) atom. is represented by the CIF card [CIF]
data_Ba10Pr5Ir(Ru2O15)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.100
_cell_length_b   25.241
_cell_length_c   6.100
_cell_angle_alpha   83.231
_cell_angle_beta   120.349
_cell_angle_gamma   96.769
_symmetry_Int_Tables_number   1
_cell_volume   803.045
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.248  0.252  0.752  1.0
  Ba  Ba1  1  0.648  0.451  0.352  1.0
  Ba  Ba2  1  0.048  0.651  0.952  1.0
  Ba  Ba3  1  0.448  0.851  0.552  1.0
  Ba  Ba4  1  0.848  0.050  0.152  1.0
  Ba  Ba5  1  0.952  0.349  0.048  1.0
  Ba  Ba6  1  0.352  0.549  0.648  1.0
  Ba  Ba7  1  0.752  0.749  0.248  1.0
  Ba  Ba8  1  0.152  0.948  0.848  1.0
  Ba  Ba9  1  0.552  0.150  0.448  1.0
  Pr  Pr10  1  0.300  0.400  0.700  1.0
  Pr  Pr11  1  0.700  0.600  0.300  1.0
  Pr  Pr12  1  0.100  0.800  0.900  1.0
  Pr  Pr13  1  0.500  0.000  0.500  1.0
  Pr  Pr14  1  0.900  0.200  0.100  1.0
  Ir  Ir15  1  0.200  0.100  0.800  1.0
  Ru  Ru16  1  0.600  0.300  0.400  1.0
  Ru  Ru17  1  0.000  0.500  1.000  1.0
  Ru  Ru18  1  0.400  0.700  0.600  1.0
  Ru  Ru19  1  0.800  0.900  0.200  1.0
  O  O20  1  0.459  0.345  0.078  1.0
  O  O21  1  0.859  0.546  0.678  1.0
  O  O22  1  0.260  0.746  0.278  1.0
  O  O23  1  0.660  0.946  0.878  1.0
  O  O24  1  0.060  0.145  0.478  1.0
  O  O25  1  0.922  0.345  0.541  1.0
  O  O26  1  0.322  0.546  0.141  1.0
  O  O27  1  0.722  0.746  0.740  1.0
  O  O28  1  0.122  0.946  0.340  1.0
  O  O29  1  0.522  0.145  0.940  1.0
  O  O30  1  0.740  0.254  0.722  1.0
  O  O31  1  0.140  0.454  0.322  1.0
  O  O32  1  0.541  0.654  0.922  1.0
  O  O33  1  0.941  0.855  0.522  1.0
  O  O34  1  0.340  0.055  0.122  1.0
  O  O35  1  0.278  0.254  0.260  1.0
  O  O36  1  0.678  0.454  0.860  1.0
  O  O37  1  0.078  0.654  0.459  1.0
  O  O38  1  0.478  0.855  0.059  1.0
  O  O39  1  0.878  0.055  0.660  1.0
  O  O40  1  0.138  0.454  0.862  1.0
  O  O41  1  0.538  0.654  0.462  1.0
  O  O42  1  0.938  0.855  0.062  1.0
  O  O43  1  0.338  0.055  0.662  1.0
  O  O44  1  0.738  0.254  0.262  1.0
  O  O45  1  0.062  0.145  0.938  1.0
  O  O46  1  0.462  0.345  0.538  1.0
  O  O47  1  0.862  0.546  0.138  1.0
  O  O48  1  0.262  0.746  0.738  1.0
  O  O49  1  0.662  0.946  0.338  1.0
[/CIF]
.
The material structure described by Ba10Pr5Ir(Ru2O15)2 is (Cubic) Perovskite-derived structured and crystallizes in the monoclinic C2/m space group. There are five inequivalent Ba sites. In the first Ba site, Ba(1) is bonded to one O(8), one O(9), two equivalent O(1), two equivalent O(10), two equivalent O(5), and four equivalent O(4) atoms to form BaO12 cuboctahedra that share corners with three equivalent Ba(2)O12 cuboctahedra, corners with three equivalent Ba(5)O12 cuboctahedra, corners with six equivalent Ba(1)O12 cuboctahedra, faces with three equivalent Ba(4)O12 cuboctahedra, faces with three equivalent Ba(5)O12 cuboctahedra,  a faceface with one Pr(1)O6 octahedra,  a faceface with one Ir(1)O6 octahedra, faces with three equivalent Pr(3)O6 octahedra, and faces with three equivalent Ru(1)O6 octahedra. In the second Ba site, Ba(2) is bonded to one O(7), one O(8), two equivalent O(1), two equivalent O(2), two equivalent O(6), and four equivalent O(3) atoms to form BaO12 cuboctahedra that share corners with three equivalent Ba(1)O12 cuboctahedra, corners with three equivalent Ba(3)O12 cuboctahedra, corners with six equivalent Ba(2)O12 cuboctahedra, faces with three equivalent Ba(3)O12 cuboctahedra, faces with three equivalent Ba(4)O12 cuboctahedra,  a faceface with one Pr(2)O6 octahedra,  a faceface with one Ru(1)O6 octahedra, faces with three equivalent Pr(1)O6 octahedra, and faces with three equivalent Ru(2)O6 octahedra. In the third Ba site, Ba(3) is bonded to one O(6), two equivalent O(3), three equivalent O(7), and six equivalent O(2) atoms to form BaO12 cuboctahedra that share corners with three equivalent Ba(2)O12 cuboctahedra, corners with three equivalent Ba(4)O12 cuboctahedra, corners with six equivalent Ba(3)O12 cuboctahedra, faces with three equivalent Ba(2)O12 cuboctahedra, faces with three equivalent Ba(3)O12 cuboctahedra,  a faceface with one Pr(1)O6 octahedra, faces with three equivalent Pr(2)O6 octahedra, and faces with four equivalent Ru(2)O6 octahedra. In the fourth Ba site, Ba(4) is bonded to one O(10), one O(6), two equivalent O(3), two equivalent O(4), two equivalent O(8), and four equivalent O(1) atoms to form BaO12 cuboctahedra that share corners with three equivalent Ba(3)O12 cuboctahedra, corners with three equivalent Ba(5)O12 cuboctahedra, corners with six equivalent Ba(4)O12 cuboctahedra, faces with three equivalent Ba(1)O12 cuboctahedra, faces with three equivalent Ba(2)O12 cuboctahedra,  a faceface with one Pr(3)O6 octahedra,  a faceface with one Ru(2)O6 octahedra, faces with three equivalent Pr(1)O6 octahedra, and faces with three equivalent Ru(1)O6 octahedra. In the fifth Ba site, Ba(5) is bonded to one O(10), two equivalent O(4), three equivalent O(9), and six equivalent O(5) atoms to form BaO12 cuboctahedra that share corners with three equivalent Ba(1)O12 cuboctahedra, corners with three equivalent Ba(4)O12 cuboctahedra, corners with six equivalent Ba(5)O12 cuboctahedra, faces with three equivalent Ba(1)O12 cuboctahedra, faces with three equivalent Ba(5)O12 cuboctahedra,  a faceface with one Ru(1)O6 octahedra, faces with three equivalent Ir(1)O6 octahedra, and faces with four equivalent Pr(3)O6 octahedra. There are three inequivalent Pr sites. In the first Pr site, Pr(1) is bonded to one O(6), one O(8), two equivalent O(1), and two equivalent O(3) atoms to form PrO6 octahedra that share corners with three equivalent Ru(1)O6 octahedra, corners with three equivalent Ru(2)O6 octahedra,  a faceface with one Ba(1)O12 cuboctahedra,  a faceface with one Ba(3)O12 cuboctahedra, faces with three equivalent Ba(2)O12 cuboctahedra, and faces with three equivalent Ba(4)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the second Pr site, Pr(2) is bonded to two equivalent O(7) and four equivalent O(2) atoms to form PrO6 octahedra that share corners with six equivalent Ru(2)O6 octahedra, faces with two equivalent Ba(2)O12 cuboctahedra, and faces with six equivalent Ba(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the third Pr site, Pr(3) is bonded to one O(10), one O(9), two equivalent O(4), and two equivalent O(5) atoms to form PrO6 octahedra that share corners with three equivalent Ru(1)O6 octahedra, corners with three equivalent Ir(1)O6 octahedra,  a faceface with one Ba(4)O12 cuboctahedra, faces with three equivalent Ba(1)O12 cuboctahedra, and faces with four equivalent Ba(5)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. There are two inequivalent Ru sites. In the first Ru site, Ru(1) is bonded to one O(10), one O(8), two equivalent O(1), and two equivalent O(4) atoms to form RuO6 octahedra that share corners with three equivalent Pr(1)O6 octahedra, corners with three equivalent Pr(3)O6 octahedra,  a faceface with one Ba(2)O12 cuboctahedra,  a faceface with one Ba(5)O12 cuboctahedra, faces with three equivalent Ba(1)O12 cuboctahedra, and faces with three equivalent Ba(4)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the second Ru site, Ru(2) is bonded to one O(6), one O(7), two equivalent O(2), and two equivalent O(3) atoms to form RuO6 octahedra that share corners with three equivalent Pr(1)O6 octahedra, corners with three equivalent Pr(2)O6 octahedra,  a faceface with one Ba(4)O12 cuboctahedra, faces with three equivalent Ba(2)O12 cuboctahedra, and faces with four equivalent Ba(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. Ir(1) is bonded to two equivalent O(9) and four equivalent O(5) atoms to form IrO6 octahedra that share corners with six equivalent Pr(3)O6 octahedra, faces with two equivalent Ba(1)O12 cuboctahedra, and faces with six equivalent Ba(5)O12 cuboctahedra. The corner-sharing octahedral tilt angles are 1°. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to one Ba(1), one Ba(2), two equivalent Ba(4), one Pr(1), and one Ru(1) atom. In the second O site, O(2) is bonded in a distorted linear geometry to one Ba(2), three equivalent Ba(3), one Pr(2), and one Ru(2) atom. In the third O site, O(3) is bonded in a distorted linear geometry to one Ba(3), one Ba(4), two equivalent Ba(2), one Pr(1), and one Ru(2) atom. In the fourth O site, O(4) is bonded in a distorted linear geometry to one Ba(4), one Ba(5), two equivalent Ba(1), one Pr(3), and one Ru(1) atom. In the fifth O site, O(5) is bonded in a distorted linear geometry to one Ba(1), three equivalent Ba(5), one Pr(3), and one Ir(1) atom. In the sixth O site, O(6) is bonded in a distorted linear geometry to one Ba(3), one Ba(4), two equivalent Ba(2), one Pr(1), and one Ru(2) atom. In the seventh O site, O(7) is bonded in a distorted linear geometry to one Ba(2), three equivalent Ba(3), one Pr(2), and one Ru(2) atom. In the eighth O site, O(8) is bonded in a distorted linear geometry to one Ba(1), one Ba(2), two equivalent Ba(4), one Pr(1), and one Ru(1) atom. In the ninth O site, O(9) is bonded in a distorted linear geometry to one Ba(1), three equivalent Ba(5), one Pr(3), and one Ir(1) atom. In the tenth O site, O(10) is bonded in a distorted linear geometry to one Ba(4), one Ba(5), two equivalent Ba(1), one Pr(3), and one Ru(1) atom. is represented by the CIF card [CIF]
data_Ba10Pr5Ir(Ru2O15)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.100
_cell_length_b   25.241
_cell_length_c   6.100
_cell_angle_alpha   83.231
_cell_angle_beta   120.349
_cell_angle_gamma   96.769
_symmetry_Int_Tables_number   1
_cell_volume   803.045
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.248  0.252  0.752  1.0
  Ba  Ba1  1  0.648  0.451  0.352  1.0
  Ba  Ba2  1  0.048  0.651  0.952  1.0
  Ba  Ba3  1  0.448  0.851  0.552  1.0
  Ba  Ba4  1  0.848  0.050  0.152  1.0
  Ba  Ba5  1  0.952  0.349  0.048  1.0
  Ba  Ba6  1  0.352  0.549  0.648  1.0
  Ba  Ba7  1  0.752  0.749  0.248  1.0
  Ba  Ba8  1  0.152  0.948  0.848  1.0
  Ba  Ba9  1  0.552  0.150  0.448  1.0
  Pr  Pr10  1  0.300  0.400  0.700  1.0
  Pr  Pr11  1  0.700  0.600  0.300  1.0
  Pr  Pr12  1  0.100  0.800  0.900  1.0
  Pr  Pr13  1  0.500  0.000  0.500  1.0
  Pr  Pr14  1  0.900  0.200  0.100  1.0
  Ir  Ir15  1  0.200  0.100  0.800  1.0
  Ru  Ru16  1  0.600  0.300  0.400  1.0
  Ru  Ru17  1  0.000  0.500  1.000  1.0
  Ru  Ru18  1  0.400  0.700  0.600  1.0
  Ru  Ru19  1  0.800  0.900  0.200  1.0
  O  O20  1  0.459  0.345  0.078  1.0
  O  O21  1  0.859  0.546  0.678  1.0
  O  O22  1  0.260  0.746  0.278  1.0
  O  O23  1  0.660  0.946  0.878  1.0
  O  O24  1  0.060  0.145  0.478  1.0
  O  O25  1  0.922  0.345  0.541  1.0
  O  O26  1  0.322  0.546  0.141  1.0
  O  O27  1  0.722  0.746  0.740  1.0
  O  O28  1  0.122  0.946  0.340  1.0
  O  O29  1  0.522  0.145  0.940  1.0
  O  O30  1  0.740  0.254  0.722  1.0
  O  O31  1  0.140  0.454  0.322  1.0
  O  O32  1  0.541  0.654  0.922  1.0
  O  O33  1  0.941  0.855  0.522  1.0
  O  O34  1  0.340  0.055  0.122  1.0
  O  O35  1  0.278  0.254  0.260  1.0
  O  O36  1  0.678  0.454  0.860  1.0
  O  O37  1  0.078  0.654  0.459  1.0
  O  O38  1  0.478  0.855  0.059  1.0
  O  O39  1  0.878  0.055  0.660  1.0
  O  O40  1  0.138  0.454  0.862  1.0
  O  O41  1  0.538  0.654  0.462  1.0
  O  O42  1  0.938  0.855  0.062  1.0
  O  O43  1  0.338  0.055  0.662  1.0
  O  O44  1  0.738  0.254  0.262  1.0
  O  O45  1  0.062  0.145  0.938  1.0
  O  O46  1  0.462  0.345  0.538  1.0
  O  O47  1  0.862  0.546  0.138  1.0
  O  O48  1  0.262  0.746  0.738  1.0
  O  O49  1  0.662  0.946  0.338  1.0
[/CIF]
.