The crystal structure described by Tb2CdS4 crystallizes in the tetragonal I-42d space group. Tb(1) is bonded in a 8-coordinate geometry to eight equivalent S(1) atoms. Cd(1) is bonded in a distorted square co-planar geometry to four equivalent S(1) atoms. S(1) is bonded in a 5-coordinate geometry to four equivalent Tb(1) and one Cd(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Tb2CdS4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.307
_cell_length_b   7.307
_cell_length_c   7.307
_cell_angle_alpha   110.442
_cell_angle_beta   110.442
_cell_angle_gamma   107.547
_symmetry_Int_Tables_number   1
_cell_volume   300.063
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tb  Tb0  1  0.735  0.125  0.110  1.0
  Tb  Tb1  1  0.375  0.265  0.390  1.0
  Tb  Tb2  1  0.015  0.625  0.890  1.0
  Tb  Tb3  1  0.875  0.985  0.610  1.0
  Cd  Cd4  1  0.500  0.500  0.000  1.0
  Cd  Cd5  1  0.250  0.750  0.500  1.0
  S  S6  1  0.250  0.989  0.874  1.0
  S  S7  1  0.500  0.874  0.239  1.0
  S  S8  1  0.011  0.885  0.261  1.0
  S  S9  1  0.624  0.750  0.739  1.0
  S  S10  1  0.126  0.365  0.626  1.0
  S  S11  1  0.635  0.261  0.761  1.0
  S  S12  1  0.115  0.376  0.126  1.0
  S  S13  1  0.739  0.500  0.374  1.0
[/CIF]
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The crystal structure described by Tb2CdS4 crystallizes in the tetragonal I-42d space group. Tb(1) is bonded in a 8-coordinate geometry to eight equivalent S(1) atoms. Cd(1) is bonded in a distorted square co-planar geometry to four equivalent S(1) atoms. S(1) is bonded in a 5-coordinate geometry to four equivalent Tb(1) and one Cd(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Tb2CdS4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.307
_cell_length_b   7.307
_cell_length_c   7.307
_cell_angle_alpha   110.442
_cell_angle_beta   110.442
_cell_angle_gamma   107.547
_symmetry_Int_Tables_number   1
_cell_volume   300.063
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tb  Tb0  1  0.735  0.125  0.110  1.0
  Tb  Tb1  1  0.375  0.265  0.390  1.0
  Tb  Tb2  1  0.015  0.625  0.890  1.0
  Tb  Tb3  1  0.875  0.985  0.610  1.0
  Cd  Cd4  1  0.500  0.500  0.000  1.0
  Cd  Cd5  1  0.250  0.750  0.500  1.0
  S  S6  1  0.250  0.989  0.874  1.0
  S  S7  1  0.500  0.874  0.239  1.0
  S  S8  1  0.011  0.885  0.261  1.0
  S  S9  1  0.624  0.750  0.739  1.0
  S  S10  1  0.126  0.365  0.626  1.0
  S  S11  1  0.635  0.261  0.761  1.0
  S  S12  1  0.115  0.376  0.126  1.0
  S  S13  1  0.739  0.500  0.374  1.0
[/CIF]
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