The compound described by K3BS3 crystallizes in the monoclinic P2_1/c space group. There are three inequivalent K sites. In the first K site, K(1) is bonded in a 6-coordinate geometry to one S(2), one S(3), and four equivalent S(1) atoms. In the second K site, K(2) is bonded in a 7-coordinate geometry to one B(1), two equivalent S(1), two equivalent S(2), and two equivalent S(3) atoms. In the third K site, K(3) is bonded in a 7-coordinate geometry to one B(1), one S(1), two equivalent S(2), and three equivalent S(3) atoms. B(1) is bonded in a distorted trigonal planar geometry to one K(2), one K(3), one S(1), one S(2), and one S(3) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a 1-coordinate geometry to one K(3), two equivalent K(2), four equivalent K(1), and one B(1) atom. In the second S site, S(2) is bonded in a 1-coordinate geometry to one K(1), two equivalent K(2), two equivalent K(3), and one B(1) atom. In the third S site, S(3) is bonded in a distorted single-bond geometry to one K(1), two equivalent K(2), three equivalent K(3), and one B(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_K3BS3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.217
_cell_length_b   10.187
_cell_length_c   12.625
_cell_angle_alpha   67.997
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   741.384
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.726  0.468  0.408  1.0
  K  K1  1  0.226  0.532  0.092  1.0
  K  K2  1  0.274  0.532  0.592  1.0
  K  K3  1  0.774  0.468  0.908  1.0
  K  K4  1  0.833  0.764  0.111  1.0
  K  K5  1  0.333  0.236  0.389  1.0
  K  K6  1  0.167  0.236  0.889  1.0
  K  K7  1  0.667  0.764  0.611  1.0
  K  K8  1  0.557  0.100  0.150  1.0
  K  K9  1  0.057  0.900  0.350  1.0
  K  K10  1  0.443  0.900  0.850  1.0
  K  K11  1  0.943  0.100  0.650  1.0
  B  B12  1  0.872  0.269  0.240  1.0
  B  B13  1  0.372  0.731  0.260  1.0
  B  B14  1  0.128  0.731  0.760  1.0
  B  B15  1  0.628  0.269  0.740  1.0
  S  S16  1  0.703  0.423  0.168  1.0
  S  S17  1  0.203  0.577  0.332  1.0
  S  S18  1  0.297  0.577  0.832  1.0
  S  S19  1  0.797  0.423  0.668  1.0
  S  S20  1  0.829  0.162  0.392  1.0
  S  S21  1  0.329  0.838  0.108  1.0
  S  S22  1  0.171  0.838  0.608  1.0
  S  S23  1  0.671  0.162  0.892  1.0
  S  S24  1  0.424  0.213  0.660  1.0
  S  S25  1  0.924  0.787  0.840  1.0
  S  S26  1  0.576  0.787  0.340  1.0
  S  S27  1  0.076  0.213  0.160  1.0
[/CIF]
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The compound described by K3BS3 crystallizes in the monoclinic P2_1/c space group. There are three inequivalent K sites. In the first K site, K(1) is bonded in a 6-coordinate geometry to one S(2), one S(3), and four equivalent S(1) atoms. In the second K site, K(2) is bonded in a 7-coordinate geometry to one B(1), two equivalent S(1), two equivalent S(2), and two equivalent S(3) atoms. In the third K site, K(3) is bonded in a 7-coordinate geometry to one B(1), one S(1), two equivalent S(2), and three equivalent S(3) atoms. B(1) is bonded in a distorted trigonal planar geometry to one K(2), one K(3), one S(1), one S(2), and one S(3) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a 1-coordinate geometry to one K(3), two equivalent K(2), four equivalent K(1), and one B(1) atom. In the second S site, S(2) is bonded in a 1-coordinate geometry to one K(1), two equivalent K(2), two equivalent K(3), and one B(1) atom. In the third S site, S(3) is bonded in a distorted single-bond geometry to one K(1), two equivalent K(2), three equivalent K(3), and one B(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_K3BS3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.217
_cell_length_b   10.187
_cell_length_c   12.625
_cell_angle_alpha   67.997
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   741.384
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.726  0.468  0.408  1.0
  K  K1  1  0.226  0.532  0.092  1.0
  K  K2  1  0.274  0.532  0.592  1.0
  K  K3  1  0.774  0.468  0.908  1.0
  K  K4  1  0.833  0.764  0.111  1.0
  K  K5  1  0.333  0.236  0.389  1.0
  K  K6  1  0.167  0.236  0.889  1.0
  K  K7  1  0.667  0.764  0.611  1.0
  K  K8  1  0.557  0.100  0.150  1.0
  K  K9  1  0.057  0.900  0.350  1.0
  K  K10  1  0.443  0.900  0.850  1.0
  K  K11  1  0.943  0.100  0.650  1.0
  B  B12  1  0.872  0.269  0.240  1.0
  B  B13  1  0.372  0.731  0.260  1.0
  B  B14  1  0.128  0.731  0.760  1.0
  B  B15  1  0.628  0.269  0.740  1.0
  S  S16  1  0.703  0.423  0.168  1.0
  S  S17  1  0.203  0.577  0.332  1.0
  S  S18  1  0.297  0.577  0.832  1.0
  S  S19  1  0.797  0.423  0.668  1.0
  S  S20  1  0.829  0.162  0.392  1.0
  S  S21  1  0.329  0.838  0.108  1.0
  S  S22  1  0.171  0.838  0.608  1.0
  S  S23  1  0.671  0.162  0.892  1.0
  S  S24  1  0.424  0.213  0.660  1.0
  S  S25  1  0.924  0.787  0.840  1.0
  S  S26  1  0.576  0.787  0.340  1.0
  S  S27  1  0.076  0.213  0.160  1.0
[/CIF]
.