The structure described by LiB2SbO5 crystallizes in the monoclinic C2/c space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to two equivalent O(1) and two equivalent O(3) atoms to form distorted LiO4 trigonal pyramids that share corners with four equivalent Sb(1)O4 trigonal pyramids. In the second Li site, Li(2) is bonded in a 4-coordinate geometry to two equivalent O(4) and two equivalent O(5) atoms. There are two inequivalent B sites. In the first B site, B(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(5) atom. In the second B site, B(2) is bonded in a trigonal planar geometry to one O(3), one O(4), and one O(5) atom. Sb(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form SbO4 trigonal pyramids that share corners with two equivalent Li(1)O4 trigonal pyramids. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one B(1), and one Sb(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one B(1) and one Sb(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Li(1), one B(2), and one Sb(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Li(2), one B(2), and one Sb(1) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Li(2), one B(1), and one B(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiB2SbO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.450
_cell_length_b   7.450
_cell_length_c   10.148
_cell_angle_alpha   71.075
_cell_angle_beta   71.075
_cell_angle_gamma   93.397
_symmetry_Int_Tables_number   1
_cell_volume   495.354
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.864  0.136  0.250  1.0
  Li  Li1  1  0.378  0.622  0.250  1.0
  Li  Li2  1  0.622  0.378  0.750  1.0
  Li  Li3  1  0.136  0.864  0.750  1.0
  B  B4  1  0.797  0.745  0.395  1.0
  B  B5  1  0.736  0.378  0.489  1.0
  B  B6  1  0.745  0.797  0.895  1.0
  B  B7  1  0.378  0.736  0.989  1.0
  B  B8  1  0.622  0.264  0.011  1.0
  B  B9  1  0.255  0.203  0.105  1.0
  B  B10  1  0.264  0.622  0.511  1.0
  B  B11  1  0.203  0.255  0.605  1.0
  Sb  Sb12  1  0.940  0.592  0.138  1.0
  Sb  Sb13  1  0.592  0.940  0.638  1.0
  Sb  Sb14  1  0.408  0.060  0.362  1.0
  Sb  Sb15  1  0.060  0.408  0.862  1.0
  O  O16  1  0.791  0.904  0.432  1.0
  O  O17  1  0.855  0.772  0.244  1.0
  O  O18  1  0.904  0.791  0.932  1.0
  O  O19  1  0.804  0.355  0.356  1.0
  O  O20  1  0.345  0.776  0.374  1.0
  O  O21  1  0.772  0.855  0.744  1.0
  O  O22  1  0.558  0.737  0.009  1.0
  O  O23  1  0.263  0.442  0.491  1.0
  O  O24  1  0.355  0.804  0.856  1.0
  O  O25  1  0.776  0.345  0.874  1.0
  O  O26  1  0.224  0.655  0.126  1.0
  O  O27  1  0.645  0.196  0.144  1.0
  O  O28  1  0.737  0.558  0.509  1.0
  O  O29  1  0.442  0.263  0.991  1.0
  O  O30  1  0.228  0.145  0.256  1.0
  O  O31  1  0.655  0.224  0.626  1.0
  O  O32  1  0.196  0.645  0.644  1.0
  O  O33  1  0.096  0.209  0.068  1.0
  O  O34  1  0.145  0.228  0.756  1.0
  O  O35  1  0.209  0.096  0.568  1.0
[/CIF]
.
The structure described by LiB2SbO5 crystallizes in the monoclinic C2/c space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to two equivalent O(1) and two equivalent O(3) atoms to form distorted LiO4 trigonal pyramids that share corners with four equivalent Sb(1)O4 trigonal pyramids. In the second Li site, Li(2) is bonded in a 4-coordinate geometry to two equivalent O(4) and two equivalent O(5) atoms. There are two inequivalent B sites. In the first B site, B(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(5) atom. In the second B site, B(2) is bonded in a trigonal planar geometry to one O(3), one O(4), and one O(5) atom. Sb(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form SbO4 trigonal pyramids that share corners with two equivalent Li(1)O4 trigonal pyramids. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one B(1), and one Sb(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one B(1) and one Sb(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Li(1), one B(2), and one Sb(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Li(2), one B(2), and one Sb(1) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Li(2), one B(1), and one B(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiB2SbO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.450
_cell_length_b   7.450
_cell_length_c   10.148
_cell_angle_alpha   71.075
_cell_angle_beta   71.075
_cell_angle_gamma   93.397
_symmetry_Int_Tables_number   1
_cell_volume   495.354
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.864  0.136  0.250  1.0
  Li  Li1  1  0.378  0.622  0.250  1.0
  Li  Li2  1  0.622  0.378  0.750  1.0
  Li  Li3  1  0.136  0.864  0.750  1.0
  B  B4  1  0.797  0.745  0.395  1.0
  B  B5  1  0.736  0.378  0.489  1.0
  B  B6  1  0.745  0.797  0.895  1.0
  B  B7  1  0.378  0.736  0.989  1.0
  B  B8  1  0.622  0.264  0.011  1.0
  B  B9  1  0.255  0.203  0.105  1.0
  B  B10  1  0.264  0.622  0.511  1.0
  B  B11  1  0.203  0.255  0.605  1.0
  Sb  Sb12  1  0.940  0.592  0.138  1.0
  Sb  Sb13  1  0.592  0.940  0.638  1.0
  Sb  Sb14  1  0.408  0.060  0.362  1.0
  Sb  Sb15  1  0.060  0.408  0.862  1.0
  O  O16  1  0.791  0.904  0.432  1.0
  O  O17  1  0.855  0.772  0.244  1.0
  O  O18  1  0.904  0.791  0.932  1.0
  O  O19  1  0.804  0.355  0.356  1.0
  O  O20  1  0.345  0.776  0.374  1.0
  O  O21  1  0.772  0.855  0.744  1.0
  O  O22  1  0.558  0.737  0.009  1.0
  O  O23  1  0.263  0.442  0.491  1.0
  O  O24  1  0.355  0.804  0.856  1.0
  O  O25  1  0.776  0.345  0.874  1.0
  O  O26  1  0.224  0.655  0.126  1.0
  O  O27  1  0.645  0.196  0.144  1.0
  O  O28  1  0.737  0.558  0.509  1.0
  O  O29  1  0.442  0.263  0.991  1.0
  O  O30  1  0.228  0.145  0.256  1.0
  O  O31  1  0.655  0.224  0.626  1.0
  O  O32  1  0.196  0.645  0.644  1.0
  O  O33  1  0.096  0.209  0.068  1.0
  O  O34  1  0.145  0.228  0.756  1.0
  O  O35  1  0.209  0.096  0.568  1.0
[/CIF]
.