The crystal structure described by KMgIn(MoO4)3 crystallizes in the monoclinic C2 space group. K(1) is bonded in a distorted hexagonal planar geometry to one O(1), one O(12), one O(3), one O(4), one O(7), and one O(8) atom. Mg(1) is bonded to one O(1), one O(10), one O(11), one O(12), one O(2), and one O(3) atom to form MgO6 octahedra that share  a cornercorner with one Mo(1)O4 tetrahedra,  a cornercorner with one Mo(3)O4 tetrahedra, corners with two equivalent Mo(2)O4 tetrahedra, and corners with two equivalent Mo(4)O4 tetrahedra. There are four inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to two equivalent O(1) and two equivalent O(5) atoms to form MoO4 tetrahedra that share corners with two equivalent Mg(1)O6 octahedra and corners with two equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 26-31°. In the second Mo site, Mo(2) is bonded to one O(12), one O(3), one O(6), and one O(9) atom to form MoO4 tetrahedra that share corners with two equivalent Mg(1)O6 octahedra and corners with two equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 25-31°. In the third Mo site, Mo(3) is bonded to two equivalent O(2) and two equivalent O(7) atoms to form MoO4 tetrahedra that share corners with two equivalent Mg(1)O6 octahedra and corners with two equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 24-34°. In the fourth Mo site, Mo(4) is bonded to one O(10), one O(11), one O(4), and one O(8) atom to form MoO4 tetrahedra that share corners with two equivalent Mg(1)O6 octahedra and corners with two equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 23-35°. In(1) is bonded to one O(4), one O(5), one O(6), one O(7), one O(8), and one O(9) atom to form InO6 octahedra that share  a cornercorner with one Mo(1)O4 tetrahedra,  a cornercorner with one Mo(3)O4 tetrahedra, corners with two equivalent Mo(2)O4 tetrahedra, and corners with two equivalent Mo(4)O4 tetrahedra. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one K(1), one Mg(1), and one Mo(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Mg(1) and one Mo(3) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one K(1), one Mg(1), and one Mo(2) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one K(1), one Mo(4), and one In(1) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Mo(1) and one In(1) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one Mo(2) and one In(1) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one K(1), one Mo(3), and one In(1) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one K(1), one Mo(4), and one In(1) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one Mo(2) and one In(1) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one Mg(1) and one Mo(4) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to one Mg(1) and one Mo(4) atom. In the twelfth O site, O(12) is bonded in a distorted bent 150 degrees geometry to one K(1), one Mg(1), and one Mo(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_KMgIn(MoO4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.675
_cell_length_b   9.675
_cell_length_c   9.991
_cell_angle_alpha   61.106
_cell_angle_beta   61.106
_cell_angle_gamma   59.932
_symmetry_Int_Tables_number   1
_cell_volume   671.751
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.881  0.624  0.245  1.0
  K  K1  1  0.376  0.119  0.755  1.0
  Mg  Mg2  1  0.244  0.968  0.182  1.0
  Mg  Mg3  1  0.032  0.756  0.818  1.0
  In  In4  1  0.745  0.468  0.680  1.0
  In  In5  1  0.532  0.255  0.320  1.0
  Mo  Mo6  1  0.929  0.071  0.000  1.0
  Mo  Mo7  1  0.637  0.650  0.003  1.0
  Mo  Mo8  1  0.859  0.141  0.500  1.0
  Mo  Mo9  1  0.419  0.864  0.499  1.0
  Mo  Mo10  1  0.136  0.581  0.501  1.0
  Mo  Mo11  1  0.350  0.363  0.997  1.0
  O  O12  1  0.957  0.887  0.975  1.0
  O  O13  1  0.891  0.966  0.674  1.0
  O  O14  1  0.817  0.679  0.977  1.0
  O  O15  1  0.958  0.549  0.517  1.0
  O  O16  1  0.896  0.250  0.823  1.0
  O  O17  1  0.664  0.617  0.827  1.0
  O  O18  1  0.829  0.333  0.518  1.0
  O  O19  1  0.609  0.680  0.519  1.0
  O  O20  1  0.530  0.389  0.820  1.0
  O  O21  1  0.389  0.899  0.323  1.0
  O  O22  1  0.243  0.834  0.670  1.0
  O  O23  1  0.667  0.171  0.482  1.0
  O  O24  1  0.611  0.470  0.180  1.0
  O  O25  1  0.167  0.544  0.971  1.0
  O  O26  1  0.456  0.833  0.029  1.0
  O  O27  1  0.750  0.104  0.177  1.0
  O  O28  1  0.320  0.391  0.481  1.0
  O  O29  1  0.101  0.611  0.677  1.0
  O  O30  1  0.451  0.042  0.483  1.0
  O  O31  1  0.166  0.757  0.330  1.0
  O  O32  1  0.383  0.336  0.173  1.0
  O  O33  1  0.321  0.183  0.023  1.0
  O  O34  1  0.034  0.109  0.326  1.0
  O  O35  1  0.113  0.043  0.025  1.0
[/CIF]
.
The crystal structure described by KMgIn(MoO4)3 crystallizes in the monoclinic C2 space group. K(1) is bonded in a distorted hexagonal planar geometry to one O(1), one O(12), one O(3), one O(4), one O(7), and one O(8) atom. Mg(1) is bonded to one O(1), one O(10), one O(11), one O(12), one O(2), and one O(3) atom to form MgO6 octahedra that share  a cornercorner with one Mo(1)O4 tetrahedra,  a cornercorner with one Mo(3)O4 tetrahedra, corners with two equivalent Mo(2)O4 tetrahedra, and corners with two equivalent Mo(4)O4 tetrahedra. There are four inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to two equivalent O(1) and two equivalent O(5) atoms to form MoO4 tetrahedra that share corners with two equivalent Mg(1)O6 octahedra and corners with two equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 26-31°. In the second Mo site, Mo(2) is bonded to one O(12), one O(3), one O(6), and one O(9) atom to form MoO4 tetrahedra that share corners with two equivalent Mg(1)O6 octahedra and corners with two equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 25-31°. In the third Mo site, Mo(3) is bonded to two equivalent O(2) and two equivalent O(7) atoms to form MoO4 tetrahedra that share corners with two equivalent Mg(1)O6 octahedra and corners with two equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 24-34°. In the fourth Mo site, Mo(4) is bonded to one O(10), one O(11), one O(4), and one O(8) atom to form MoO4 tetrahedra that share corners with two equivalent Mg(1)O6 octahedra and corners with two equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 23-35°. In(1) is bonded to one O(4), one O(5), one O(6), one O(7), one O(8), and one O(9) atom to form InO6 octahedra that share  a cornercorner with one Mo(1)O4 tetrahedra,  a cornercorner with one Mo(3)O4 tetrahedra, corners with two equivalent Mo(2)O4 tetrahedra, and corners with two equivalent Mo(4)O4 tetrahedra. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one K(1), one Mg(1), and one Mo(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Mg(1) and one Mo(3) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one K(1), one Mg(1), and one Mo(2) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one K(1), one Mo(4), and one In(1) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Mo(1) and one In(1) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one Mo(2) and one In(1) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one K(1), one Mo(3), and one In(1) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one K(1), one Mo(4), and one In(1) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one Mo(2) and one In(1) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one Mg(1) and one Mo(4) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to one Mg(1) and one Mo(4) atom. In the twelfth O site, O(12) is bonded in a distorted bent 150 degrees geometry to one K(1), one Mg(1), and one Mo(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_KMgIn(MoO4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.675
_cell_length_b   9.675
_cell_length_c   9.991
_cell_angle_alpha   61.106
_cell_angle_beta   61.106
_cell_angle_gamma   59.932
_symmetry_Int_Tables_number   1
_cell_volume   671.751
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.881  0.624  0.245  1.0
  K  K1  1  0.376  0.119  0.755  1.0
  Mg  Mg2  1  0.244  0.968  0.182  1.0
  Mg  Mg3  1  0.032  0.756  0.818  1.0
  In  In4  1  0.745  0.468  0.680  1.0
  In  In5  1  0.532  0.255  0.320  1.0
  Mo  Mo6  1  0.929  0.071  0.000  1.0
  Mo  Mo7  1  0.637  0.650  0.003  1.0
  Mo  Mo8  1  0.859  0.141  0.500  1.0
  Mo  Mo9  1  0.419  0.864  0.499  1.0
  Mo  Mo10  1  0.136  0.581  0.501  1.0
  Mo  Mo11  1  0.350  0.363  0.997  1.0
  O  O12  1  0.957  0.887  0.975  1.0
  O  O13  1  0.891  0.966  0.674  1.0
  O  O14  1  0.817  0.679  0.977  1.0
  O  O15  1  0.958  0.549  0.517  1.0
  O  O16  1  0.896  0.250  0.823  1.0
  O  O17  1  0.664  0.617  0.827  1.0
  O  O18  1  0.829  0.333  0.518  1.0
  O  O19  1  0.609  0.680  0.519  1.0
  O  O20  1  0.530  0.389  0.820  1.0
  O  O21  1  0.389  0.899  0.323  1.0
  O  O22  1  0.243  0.834  0.670  1.0
  O  O23  1  0.667  0.171  0.482  1.0
  O  O24  1  0.611  0.470  0.180  1.0
  O  O25  1  0.167  0.544  0.971  1.0
  O  O26  1  0.456  0.833  0.029  1.0
  O  O27  1  0.750  0.104  0.177  1.0
  O  O28  1  0.320  0.391  0.481  1.0
  O  O29  1  0.101  0.611  0.677  1.0
  O  O30  1  0.451  0.042  0.483  1.0
  O  O31  1  0.166  0.757  0.330  1.0
  O  O32  1  0.383  0.336  0.173  1.0
  O  O33  1  0.321  0.183  0.023  1.0
  O  O34  1  0.034  0.109  0.326  1.0
  O  O35  1  0.113  0.043  0.025  1.0
[/CIF]
.