The compound described by VPbO2 crystallizes in the tetragonal I4_1/a space group. V(1) is bonded in a distorted square co-planar geometry to four equivalent O(1) atoms. Pb(1) is bonded to six equivalent O(1) atoms to form edge-sharing PbO6 octahedra. O(1) is bonded to two equivalent V(1) and three equivalent Pb(1) atoms to form a mixture of distorted corner and edge-sharing OV2Pb3 square pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_VPbO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.576
_cell_length_b   7.576
_cell_length_c   7.576
_cell_angle_alpha   128.627
_cell_angle_beta   128.627
_cell_angle_gamma   75.612
_symmetry_Int_Tables_number   1
_cell_volume   258.170
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.375  0.125  0.250  1.0
  V  V1  1  0.875  0.125  0.750  1.0
  V  V2  1  0.875  0.125  0.250  1.0
  V  V3  1  0.875  0.625  0.750  1.0
  Pb  Pb4  1  0.875  0.625  0.250  1.0
  Pb  Pb5  1  0.375  0.625  0.750  1.0
  Pb  Pb6  1  0.375  0.625  0.250  1.0
  Pb  Pb7  1  0.375  0.125  0.750  1.0
  O  O8  1  0.163  0.354  0.208  1.0
  O  O9  1  0.146  0.955  0.792  1.0
  O  O10  1  0.104  0.396  0.691  1.0
  O  O11  1  0.587  0.896  0.292  1.0
  O  O12  1  0.705  0.413  0.309  1.0
  O  O13  1  0.604  0.295  0.708  1.0
  O  O14  1  0.646  0.854  0.809  1.0
  O  O15  1  0.045  0.837  0.191  1.0
[/CIF]
.
The compound described by VPbO2 crystallizes in the tetragonal I4_1/a space group. V(1) is bonded in a distorted square co-planar geometry to four equivalent O(1) atoms. Pb(1) is bonded to six equivalent O(1) atoms to form edge-sharing PbO6 octahedra. O(1) is bonded to two equivalent V(1) and three equivalent Pb(1) atoms to form a mixture of distorted corner and edge-sharing OV2Pb3 square pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_VPbO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.576
_cell_length_b   7.576
_cell_length_c   7.576
_cell_angle_alpha   128.627
_cell_angle_beta   128.627
_cell_angle_gamma   75.612
_symmetry_Int_Tables_number   1
_cell_volume   258.170
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.375  0.125  0.250  1.0
  V  V1  1  0.875  0.125  0.750  1.0
  V  V2  1  0.875  0.125  0.250  1.0
  V  V3  1  0.875  0.625  0.750  1.0
  Pb  Pb4  1  0.875  0.625  0.250  1.0
  Pb  Pb5  1  0.375  0.625  0.750  1.0
  Pb  Pb6  1  0.375  0.625  0.250  1.0
  Pb  Pb7  1  0.375  0.125  0.750  1.0
  O  O8  1  0.163  0.354  0.208  1.0
  O  O9  1  0.146  0.955  0.792  1.0
  O  O10  1  0.104  0.396  0.691  1.0
  O  O11  1  0.587  0.896  0.292  1.0
  O  O12  1  0.705  0.413  0.309  1.0
  O  O13  1  0.604  0.295  0.708  1.0
  O  O14  1  0.646  0.854  0.809  1.0
  O  O15  1  0.045  0.837  0.191  1.0
[/CIF]
.