The material described by Pd32Ga3Te9 crystallizes in the trigonal R3 space group. There are sixteen inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 3-coordinate geometry to one Pd(11), one Pd(3), one Pd(7), three equivalent Pd(16), one Ga(1), and two equivalent Te(3) atoms. In the second Pd site, Pd(2) is bonded in a 3-coordinate geometry to one Pd(12), one Pd(4), one Te(5), and two equivalent Te(4) atoms. In the third Pd site, Pd(3) is bonded in a 12-coordinate geometry to one Pd(1), one Pd(15), one Pd(5), one Pd(7), one Pd(9), three equivalent Pd(13), one Te(1), and three equivalent Te(3) atoms. In the fourth Pd site, Pd(4) is bonded in a 12-coordinate geometry to one Pd(10), one Pd(16), one Pd(2), one Pd(6), one Pd(8), three equivalent Pd(14), one Te(2), and three equivalent Te(4) atoms. In the fifth Pd site, Pd(5) is bonded in a 1-coordinate geometry to three equivalent Pd(16), three equivalent Pd(3), one Ga(3), and three equivalent Te(3) atoms. In the sixth Pd site, Pd(6) is bonded in a 1-coordinate geometry to three equivalent Pd(4), one Ga(2), and three equivalent Te(4) atoms. In the seventh Pd site, Pd(7) is bonded in a 13-coordinate geometry to three equivalent Pd(1), three equivalent Pd(13), three equivalent Pd(3), one Ga(2), and three equivalent Te(3) atoms. In the eighth Pd site, Pd(8) is bonded in a 1-coordinate geometry to three equivalent Pd(4), one Ga(3), and three equivalent Te(4) atoms. In the ninth Pd site, Pd(9) is bonded in a 11-coordinate geometry to one Pd(11), three equivalent Pd(13), three equivalent Pd(3), one Te(5), and three equivalent Te(3) atoms. In the tenth Pd site, Pd(10) is bonded in a 11-coordinate geometry to one Pd(12), three equivalent Pd(14), three equivalent Pd(4), one Ga(1), and three equivalent Te(4) atoms. In the eleventh Pd site, Pd(11) is bonded in a 11-coordinate geometry to one Pd(9), three equivalent Pd(1), three equivalent Pd(16), one Te(2), and three equivalent Te(3) atoms. In the twelfth Pd site, Pd(12) is bonded in a 11-coordinate geometry to one Pd(10), three equivalent Pd(15), three equivalent Pd(2), one Te(1), and three equivalent Te(4) atoms. In the thirteenth Pd site, Pd(13) is bonded in a 1-coordinate geometry to one Pd(7), one Pd(9), three equivalent Pd(3), one Ga(2), one Te(1), one Te(3), and one Te(5) atom. In the fourteenth Pd site, Pd(14) is bonded in a 2-coordinate geometry to one Pd(10), three equivalent Pd(16), three equivalent Pd(4), one Ga(1), one Ga(3), one Te(2), and one Te(4) atom. In the fifteenth Pd site, Pd(15) is bonded in a 1-coordinate geometry to one Pd(12), one Pd(3), one Ga(2), one Te(1), one Te(4), and one Te(5) atom. In the sixteenth Pd site, Pd(16) is bonded in a 13-coordinate geometry to one Pd(11), one Pd(4), one Pd(5), three equivalent Pd(1), three equivalent Pd(14), one Ga(1), one Ga(3), one Te(2), and one Te(3) atom. There are three inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a 10-coordinate geometry to one Pd(10), three equivalent Pd(1), three equivalent Pd(14), and three equivalent Pd(16) atoms. In the second Ga site, Ga(2) is bonded in a body-centered cubic geometry to one Pd(6), one Pd(7), three equivalent Pd(13), and three equivalent Pd(15) atoms. In the third Ga site, Ga(3) is bonded in a body-centered cubic geometry to one Pd(5), one Pd(8), three equivalent Pd(14), and three equivalent Pd(16) atoms. There are five inequivalent Te sites. In the first Te site, Te(1) is bonded in a distorted q6 geometry to one Pd(12), three equivalent Pd(13), three equivalent Pd(15), and three equivalent Pd(3) atoms. In the second Te site, Te(2) is bonded in a distorted q6 geometry to one Pd(11), three equivalent Pd(14), three equivalent Pd(16), and three equivalent Pd(4) atoms. In the third Te site, Te(3) is bonded in a 10-coordinate geometry to one Pd(11), one Pd(13), one Pd(16), one Pd(5), one Pd(7), one Pd(9), two equivalent Pd(1), and three equivalent Pd(3) atoms. In the fourth Te site, Te(4) is bonded in a 10-coordinate geometry to one Pd(10), one Pd(12), one Pd(14), one Pd(15), one Pd(6), one Pd(8), two equivalent Pd(2), and three equivalent Pd(4) atoms. In the fifth Te site, Te(5) is bonded in a 10-coordinate geometry to one Pd(9), three equivalent Pd(13), three equivalent Pd(15), and three equivalent Pd(2) atoms. is represented by the CIF card [CIF]
data_Ga3Te9Pd32
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   15.139
_cell_length_b   15.139
_cell_length_c   15.139
_cell_angle_alpha   29.486
_cell_angle_beta   29.486
_cell_angle_gamma   29.486
_symmetry_Int_Tables_number   1
_cell_volume   744.009
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.791  0.791  0.791  1.0
  Ga  Ga1  1  0.949  0.949  0.949  1.0
  Ga  Ga2  1  0.449  0.449  0.449  1.0
  Te  Te3  1  0.606  0.606  0.606  1.0
  Te  Te4  1  0.106  0.106  0.106  1.0
  Te  Te5  1  0.879  0.195  0.520  1.0
  Te  Te6  1  0.520  0.879  0.195  1.0
  Te  Te7  1  0.195  0.520  0.879  1.0
  Te  Te8  1  0.017  0.698  0.382  1.0
  Te  Te9  1  0.382  0.017  0.698  1.0
  Te  Te10  1  0.698  0.382  0.017  1.0
  Te  Te11  1  0.290  0.290  0.290  1.0
  Pd  Pd12  1  0.086  0.826  0.585  1.0
  Pd  Pd13  1  0.585  0.086  0.826  1.0
  Pd  Pd14  1  0.826  0.585  0.086  1.0
  Pd  Pd15  1  0.079  0.327  0.594  1.0
  Pd  Pd16  1  0.594  0.079  0.327  1.0
  Pd  Pd17  1  0.327  0.594  0.079  1.0
  Pd  Pd18  1  0.296  0.829  0.565  1.0
  Pd  Pd19  1  0.565  0.296  0.829  1.0
  Pd  Pd20  1  0.829  0.565  0.296  1.0
  Pd  Pd21  1  0.066  0.329  0.795  1.0
  Pd  Pd22  1  0.795  0.066  0.329  1.0
  Pd  Pd23  1  0.329  0.795  0.066  1.0
  Pd  Pd24  1  0.509  0.509  0.509  1.0
  Pd  Pd25  1  0.010  0.010  0.010  1.0
  Pd  Pd26  1  0.888  0.888  0.888  1.0
  Pd  Pd27  1  0.388  0.388  0.388  1.0
  Pd  Pd28  1  0.231  0.231  0.231  1.0
  Pd  Pd29  1  0.732  0.732  0.732  1.0
  Pd  Pd30  1  0.167  0.167  0.167  1.0
  Pd  Pd31  1  0.667  0.667  0.667  1.0
  Pd  Pd32  1  0.961  0.230  0.603  1.0
  Pd  Pd33  1  0.603  0.961  0.230  1.0
  Pd  Pd34  1  0.230  0.603  0.961  1.0
  Pd  Pd35  1  0.098  0.732  0.466  1.0
  Pd  Pd36  1  0.466  0.098  0.732  1.0
  Pd  Pd37  1  0.732  0.466  0.098  1.0
  Pd  Pd38  1  0.299  0.934  0.663  1.0
  Pd  Pd39  1  0.663  0.299  0.934  1.0
  Pd  Pd40  1  0.934  0.663  0.299  1.0
  Pd  Pd41  1  0.157  0.437  0.801  1.0
  Pd  Pd42  1  0.801  0.157  0.437  1.0
  Pd  Pd43  1  0.437  0.801  0.157  1.0
[/CIF]
.
The material described by Pd32Ga3Te9 crystallizes in the trigonal R3 space group. There are sixteen inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 3-coordinate geometry to one Pd(11), one Pd(3), one Pd(7), three equivalent Pd(16), one Ga(1), and two equivalent Te(3) atoms. In the second Pd site, Pd(2) is bonded in a 3-coordinate geometry to one Pd(12), one Pd(4), one Te(5), and two equivalent Te(4) atoms. In the third Pd site, Pd(3) is bonded in a 12-coordinate geometry to one Pd(1), one Pd(15), one Pd(5), one Pd(7), one Pd(9), three equivalent Pd(13), one Te(1), and three equivalent Te(3) atoms. In the fourth Pd site, Pd(4) is bonded in a 12-coordinate geometry to one Pd(10), one Pd(16), one Pd(2), one Pd(6), one Pd(8), three equivalent Pd(14), one Te(2), and three equivalent Te(4) atoms. In the fifth Pd site, Pd(5) is bonded in a 1-coordinate geometry to three equivalent Pd(16), three equivalent Pd(3), one Ga(3), and three equivalent Te(3) atoms. In the sixth Pd site, Pd(6) is bonded in a 1-coordinate geometry to three equivalent Pd(4), one Ga(2), and three equivalent Te(4) atoms. In the seventh Pd site, Pd(7) is bonded in a 13-coordinate geometry to three equivalent Pd(1), three equivalent Pd(13), three equivalent Pd(3), one Ga(2), and three equivalent Te(3) atoms. In the eighth Pd site, Pd(8) is bonded in a 1-coordinate geometry to three equivalent Pd(4), one Ga(3), and three equivalent Te(4) atoms. In the ninth Pd site, Pd(9) is bonded in a 11-coordinate geometry to one Pd(11), three equivalent Pd(13), three equivalent Pd(3), one Te(5), and three equivalent Te(3) atoms. In the tenth Pd site, Pd(10) is bonded in a 11-coordinate geometry to one Pd(12), three equivalent Pd(14), three equivalent Pd(4), one Ga(1), and three equivalent Te(4) atoms. In the eleventh Pd site, Pd(11) is bonded in a 11-coordinate geometry to one Pd(9), three equivalent Pd(1), three equivalent Pd(16), one Te(2), and three equivalent Te(3) atoms. In the twelfth Pd site, Pd(12) is bonded in a 11-coordinate geometry to one Pd(10), three equivalent Pd(15), three equivalent Pd(2), one Te(1), and three equivalent Te(4) atoms. In the thirteenth Pd site, Pd(13) is bonded in a 1-coordinate geometry to one Pd(7), one Pd(9), three equivalent Pd(3), one Ga(2), one Te(1), one Te(3), and one Te(5) atom. In the fourteenth Pd site, Pd(14) is bonded in a 2-coordinate geometry to one Pd(10), three equivalent Pd(16), three equivalent Pd(4), one Ga(1), one Ga(3), one Te(2), and one Te(4) atom. In the fifteenth Pd site, Pd(15) is bonded in a 1-coordinate geometry to one Pd(12), one Pd(3), one Ga(2), one Te(1), one Te(4), and one Te(5) atom. In the sixteenth Pd site, Pd(16) is bonded in a 13-coordinate geometry to one Pd(11), one Pd(4), one Pd(5), three equivalent Pd(1), three equivalent Pd(14), one Ga(1), one Ga(3), one Te(2), and one Te(3) atom. There are three inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a 10-coordinate geometry to one Pd(10), three equivalent Pd(1), three equivalent Pd(14), and three equivalent Pd(16) atoms. In the second Ga site, Ga(2) is bonded in a body-centered cubic geometry to one Pd(6), one Pd(7), three equivalent Pd(13), and three equivalent Pd(15) atoms. In the third Ga site, Ga(3) is bonded in a body-centered cubic geometry to one Pd(5), one Pd(8), three equivalent Pd(14), and three equivalent Pd(16) atoms. There are five inequivalent Te sites. In the first Te site, Te(1) is bonded in a distorted q6 geometry to one Pd(12), three equivalent Pd(13), three equivalent Pd(15), and three equivalent Pd(3) atoms. In the second Te site, Te(2) is bonded in a distorted q6 geometry to one Pd(11), three equivalent Pd(14), three equivalent Pd(16), and three equivalent Pd(4) atoms. In the third Te site, Te(3) is bonded in a 10-coordinate geometry to one Pd(11), one Pd(13), one Pd(16), one Pd(5), one Pd(7), one Pd(9), two equivalent Pd(1), and three equivalent Pd(3) atoms. In the fourth Te site, Te(4) is bonded in a 10-coordinate geometry to one Pd(10), one Pd(12), one Pd(14), one Pd(15), one Pd(6), one Pd(8), two equivalent Pd(2), and three equivalent Pd(4) atoms. In the fifth Te site, Te(5) is bonded in a 10-coordinate geometry to one Pd(9), three equivalent Pd(13), three equivalent Pd(15), and three equivalent Pd(2) atoms. is represented by the CIF card [CIF]
data_Ga3Te9Pd32
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   15.139
_cell_length_b   15.139
_cell_length_c   15.139
_cell_angle_alpha   29.486
_cell_angle_beta   29.486
_cell_angle_gamma   29.486
_symmetry_Int_Tables_number   1
_cell_volume   744.009
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.791  0.791  0.791  1.0
  Ga  Ga1  1  0.949  0.949  0.949  1.0
  Ga  Ga2  1  0.449  0.449  0.449  1.0
  Te  Te3  1  0.606  0.606  0.606  1.0
  Te  Te4  1  0.106  0.106  0.106  1.0
  Te  Te5  1  0.879  0.195  0.520  1.0
  Te  Te6  1  0.520  0.879  0.195  1.0
  Te  Te7  1  0.195  0.520  0.879  1.0
  Te  Te8  1  0.017  0.698  0.382  1.0
  Te  Te9  1  0.382  0.017  0.698  1.0
  Te  Te10  1  0.698  0.382  0.017  1.0
  Te  Te11  1  0.290  0.290  0.290  1.0
  Pd  Pd12  1  0.086  0.826  0.585  1.0
  Pd  Pd13  1  0.585  0.086  0.826  1.0
  Pd  Pd14  1  0.826  0.585  0.086  1.0
  Pd  Pd15  1  0.079  0.327  0.594  1.0
  Pd  Pd16  1  0.594  0.079  0.327  1.0
  Pd  Pd17  1  0.327  0.594  0.079  1.0
  Pd  Pd18  1  0.296  0.829  0.565  1.0
  Pd  Pd19  1  0.565  0.296  0.829  1.0
  Pd  Pd20  1  0.829  0.565  0.296  1.0
  Pd  Pd21  1  0.066  0.329  0.795  1.0
  Pd  Pd22  1  0.795  0.066  0.329  1.0
  Pd  Pd23  1  0.329  0.795  0.066  1.0
  Pd  Pd24  1  0.509  0.509  0.509  1.0
  Pd  Pd25  1  0.010  0.010  0.010  1.0
  Pd  Pd26  1  0.888  0.888  0.888  1.0
  Pd  Pd27  1  0.388  0.388  0.388  1.0
  Pd  Pd28  1  0.231  0.231  0.231  1.0
  Pd  Pd29  1  0.732  0.732  0.732  1.0
  Pd  Pd30  1  0.167  0.167  0.167  1.0
  Pd  Pd31  1  0.667  0.667  0.667  1.0
  Pd  Pd32  1  0.961  0.230  0.603  1.0
  Pd  Pd33  1  0.603  0.961  0.230  1.0
  Pd  Pd34  1  0.230  0.603  0.961  1.0
  Pd  Pd35  1  0.098  0.732  0.466  1.0
  Pd  Pd36  1  0.466  0.098  0.732  1.0
  Pd  Pd37  1  0.732  0.466  0.098  1.0
  Pd  Pd38  1  0.299  0.934  0.663  1.0
  Pd  Pd39  1  0.663  0.299  0.934  1.0
  Pd  Pd40  1  0.934  0.663  0.299  1.0
  Pd  Pd41  1  0.157  0.437  0.801  1.0
  Pd  Pd42  1  0.801  0.157  0.437  1.0
  Pd  Pd43  1  0.437  0.801  0.157  1.0
[/CIF]
.