The compound described by KMnCl crystallizes in the orthorhombic Imma space group. K(1) is bonded in a square co-planar geometry to four equivalent Cl(1) atoms. Mn(1) is bonded in a linear geometry to two equivalent Cl(1) atoms. Cl(1) is bonded to four equivalent K(1) and two equivalent Mn(1) atoms to form a mixture of corner and edge-sharing ClK4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. is represented by the CIF file [CIF]
data_KMnCl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.336
_cell_length_b   4.336
_cell_length_c   5.505
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   89.840
_symmetry_Int_Tables_number   1
_cell_volume   103.498
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cl  Cl0  1  0.500  0.500  0.500  1.0
  K  K1  1  0.000  0.000  0.500  1.0
  Mn  Mn2  1  0.500  0.500  1.000  1.0
[/CIF]
.
The compound described by KMnCl crystallizes in the orthorhombic Imma space group. K(1) is bonded in a square co-planar geometry to four equivalent Cl(1) atoms. Mn(1) is bonded in a linear geometry to two equivalent Cl(1) atoms. Cl(1) is bonded to four equivalent K(1) and two equivalent Mn(1) atoms to form a mixture of corner and edge-sharing ClK4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. is represented by the CIF file [CIF]
data_KMnCl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.336
_cell_length_b   4.336
_cell_length_c   5.505
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   89.840
_symmetry_Int_Tables_number   1
_cell_volume   103.498
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cl  Cl0  1  0.500  0.500  0.500  1.0
  K  K1  1  0.000  0.000  0.500  1.0
  Mn  Mn2  1  0.500  0.500  1.000  1.0
[/CIF]
.