The structure described by LaSbO4 crystallizes in the monoclinic P2_1/c space group. La(1) is bonded in a 6-coordinate geometry to one O(1), one O(3), two equivalent O(2), and two equivalent O(4) atoms. Sb(1) is bonded to one O(2), one O(4), two equivalent O(1), and two equivalent O(3) atoms to form edge-sharing SbO6 octahedra. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one La(1) and two equivalent Sb(1) atoms. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent La(1) and one Sb(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one La(1) and two equivalent Sb(1) atoms. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to two equivalent La(1) and one Sb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LaSbO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.086
_cell_length_b   5.411
_cell_length_c   13.623
_cell_angle_alpha   70.736
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   353.904
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.803  0.655  0.336  1.0
  La  La1  1  0.697  0.655  0.836  1.0
  La  La2  1  0.197  0.345  0.664  1.0
  La  La3  1  0.303  0.345  0.164  1.0
  Sb  Sb4  1  0.751  0.918  0.069  1.0
  Sb  Sb5  1  0.749  0.918  0.569  1.0
  Sb  Sb6  1  0.249  0.082  0.931  1.0
  Sb  Sb7  1  0.251  0.082  0.431  1.0
  O  O8  1  0.436  0.756  0.027  1.0
  O  O9  1  0.064  0.756  0.527  1.0
  O  O10  1  0.564  0.244  0.973  1.0
  O  O11  1  0.936  0.244  0.473  1.0
  O  O12  1  0.602  0.992  0.187  1.0
  O  O13  1  0.898  0.992  0.687  1.0
  O  O14  1  0.398  0.008  0.813  1.0
  O  O15  1  0.102  0.008  0.313  1.0
  O  O16  1  0.072  0.136  0.056  1.0
  O  O17  1  0.428  0.136  0.556  1.0
  O  O18  1  0.928  0.864  0.944  1.0
  O  O19  1  0.572  0.864  0.444  1.0
  O  O20  1  0.876  0.586  0.167  1.0
  O  O21  1  0.624  0.586  0.667  1.0
  O  O22  1  0.124  0.414  0.833  1.0
  O  O23  1  0.376  0.414  0.333  1.0
[/CIF]
.
The structure described by LaSbO4 crystallizes in the monoclinic P2_1/c space group. La(1) is bonded in a 6-coordinate geometry to one O(1), one O(3), two equivalent O(2), and two equivalent O(4) atoms. Sb(1) is bonded to one O(2), one O(4), two equivalent O(1), and two equivalent O(3) atoms to form edge-sharing SbO6 octahedra. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one La(1) and two equivalent Sb(1) atoms. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent La(1) and one Sb(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one La(1) and two equivalent Sb(1) atoms. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to two equivalent La(1) and one Sb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LaSbO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.086
_cell_length_b   5.411
_cell_length_c   13.623
_cell_angle_alpha   70.736
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   353.904
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.803  0.655  0.336  1.0
  La  La1  1  0.697  0.655  0.836  1.0
  La  La2  1  0.197  0.345  0.664  1.0
  La  La3  1  0.303  0.345  0.164  1.0
  Sb  Sb4  1  0.751  0.918  0.069  1.0
  Sb  Sb5  1  0.749  0.918  0.569  1.0
  Sb  Sb6  1  0.249  0.082  0.931  1.0
  Sb  Sb7  1  0.251  0.082  0.431  1.0
  O  O8  1  0.436  0.756  0.027  1.0
  O  O9  1  0.064  0.756  0.527  1.0
  O  O10  1  0.564  0.244  0.973  1.0
  O  O11  1  0.936  0.244  0.473  1.0
  O  O12  1  0.602  0.992  0.187  1.0
  O  O13  1  0.898  0.992  0.687  1.0
  O  O14  1  0.398  0.008  0.813  1.0
  O  O15  1  0.102  0.008  0.313  1.0
  O  O16  1  0.072  0.136  0.056  1.0
  O  O17  1  0.428  0.136  0.556  1.0
  O  O18  1  0.928  0.864  0.944  1.0
  O  O19  1  0.572  0.864  0.444  1.0
  O  O20  1  0.876  0.586  0.167  1.0
  O  O21  1  0.624  0.586  0.667  1.0
  O  O22  1  0.124  0.414  0.833  1.0
  O  O23  1  0.376  0.414  0.333  1.0
[/CIF]
.