The material described by (AgC8(NS)4)2Cl2 is Indium-derived structured and crystallizes in the tetragonal I-4 space group. The structure is zero-dimensional and consists of two hydrochloric acid atoms and two AgC8(NS)4 clusters. In each AgC8(NS)4 cluster, Ag(1) is bonded in a distorted tetrahedral geometry to four equivalent S(1) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(2) and one N(1) atom. In the second C site, C(2) is bonded in a bent 150 degrees geometry to one C(1) and one S(1) atom. N(1) is bonded in a single-bond geometry to one C(1) atom. S(1) is bonded in an L-shaped geometry to one Ag(1) and one C(2) atom. is represented by the CIF file [CIF]
data_AgC8S4N4Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.111
_cell_length_b   9.986
_cell_length_c   9.986
_cell_angle_alpha   86.245
_cell_angle_beta   75.172
_cell_angle_gamma   75.172
_symmetry_Int_Tables_number   1
_cell_volume   476.373
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.000  0.000  0.000  1.0
  C  C1  1  0.548  0.322  0.194  1.0
  C  C2  1  0.064  0.678  0.806  1.0
  C  C3  1  0.130  0.806  0.322  1.0
  C  C4  1  0.258  0.194  0.678  1.0
  C  C5  1  0.571  0.310  0.060  1.0
  C  C6  1  0.941  0.690  0.940  1.0
  C  C7  1  0.119  0.940  0.310  1.0
  C  C8  1  0.369  0.060  0.690  1.0
  S  S9  1  0.684  0.239  0.914  1.0
  S  S10  1  0.837  0.761  0.086  1.0
  S  S11  1  0.077  0.086  0.239  1.0
  S  S12  1  0.402  0.914  0.761  1.0
  N  N13  1  0.559  0.314  0.313  1.0
  N  N14  1  0.186  0.686  0.687  1.0
  N  N15  1  0.127  0.687  0.314  1.0
  N  N16  1  0.128  0.313  0.686  1.0
  Cl  Cl17  1  0.250  0.500  0.500  1.0
[/CIF]
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The material described by (AgC8(NS)4)2Cl2 is Indium-derived structured and crystallizes in the tetragonal I-4 space group. The structure is zero-dimensional and consists of two hydrochloric acid atoms and two AgC8(NS)4 clusters. In each AgC8(NS)4 cluster, Ag(1) is bonded in a distorted tetrahedral geometry to four equivalent S(1) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(2) and one N(1) atom. In the second C site, C(2) is bonded in a bent 150 degrees geometry to one C(1) and one S(1) atom. N(1) is bonded in a single-bond geometry to one C(1) atom. S(1) is bonded in an L-shaped geometry to one Ag(1) and one C(2) atom. is represented by the CIF file [CIF]
data_AgC8S4N4Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.111
_cell_length_b   9.986
_cell_length_c   9.986
_cell_angle_alpha   86.245
_cell_angle_beta   75.172
_cell_angle_gamma   75.172
_symmetry_Int_Tables_number   1
_cell_volume   476.373
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.000  0.000  0.000  1.0
  C  C1  1  0.548  0.322  0.194  1.0
  C  C2  1  0.064  0.678  0.806  1.0
  C  C3  1  0.130  0.806  0.322  1.0
  C  C4  1  0.258  0.194  0.678  1.0
  C  C5  1  0.571  0.310  0.060  1.0
  C  C6  1  0.941  0.690  0.940  1.0
  C  C7  1  0.119  0.940  0.310  1.0
  C  C8  1  0.369  0.060  0.690  1.0
  S  S9  1  0.684  0.239  0.914  1.0
  S  S10  1  0.837  0.761  0.086  1.0
  S  S11  1  0.077  0.086  0.239  1.0
  S  S12  1  0.402  0.914  0.761  1.0
  N  N13  1  0.559  0.314  0.313  1.0
  N  N14  1  0.186  0.686  0.687  1.0
  N  N15  1  0.127  0.687  0.314  1.0
  N  N16  1  0.128  0.313  0.686  1.0
  Cl  Cl17  1  0.250  0.500  0.500  1.0
[/CIF]
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