The compound described by AuCS2Cl3 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight AuCS2Cl3 clusters. Au(1) is bonded in a distorted rectangular see-saw-like geometry to one S(1), one S(2), one Cl(1), and one Cl(3) atom. C(1) is bonded in a trigonal planar geometry to one S(1), one S(2), and one Cl(2) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in an L-shaped geometry to one Au(1) and one C(1) atom. In the second S site, S(2) is bonded in an L-shaped geometry to one Au(1) and one C(1) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Au(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one C(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Au(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_AuCS2Cl3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.433
_cell_length_b   9.433
_cell_length_c   11.620
_cell_angle_alpha   65.702
_cell_angle_beta   65.702
_cell_angle_gamma   69.194
_symmetry_Int_Tables_number   1
_cell_volume   837.122
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Au  Au0  1  0.046  0.291  0.462  1.0
  Au  Au1  1  0.954  0.709  0.538  1.0
  Au  Au2  1  0.291  0.046  0.962  1.0
  Au  Au3  1  0.709  0.954  0.038  1.0
  C  C4  1  0.752  0.298  0.451  1.0
  C  C5  1  0.248  0.702  0.549  1.0
  C  C6  1  0.702  0.248  0.049  1.0
  C  C7  1  0.298  0.752  0.951  1.0
  S  S8  1  0.137  0.567  0.660  1.0
  S  S9  1  0.567  0.137  0.160  1.0
  S  S10  1  0.839  0.167  0.931  1.0
  S  S11  1  0.833  0.161  0.569  1.0
  S  S12  1  0.863  0.433  0.340  1.0
  S  S13  1  0.433  0.863  0.840  1.0
  S  S14  1  0.167  0.839  0.431  1.0
  S  S15  1  0.161  0.833  0.069  1.0
  Cl  Cl16  1  0.767  0.550  0.669  1.0
  Cl  Cl17  1  0.698  0.425  0.055  1.0
  Cl  Cl18  1  0.450  0.233  0.831  1.0
  Cl  Cl19  1  0.804  0.876  0.395  1.0
  Cl  Cl20  1  0.233  0.450  0.331  1.0
  Cl  Cl21  1  0.425  0.698  0.555  1.0
  Cl  Cl22  1  0.124  0.196  0.105  1.0
  Cl  Cl23  1  0.575  0.302  0.445  1.0
  Cl  Cl24  1  0.550  0.767  0.169  1.0
  Cl  Cl25  1  0.876  0.804  0.895  1.0
  Cl  Cl26  1  0.196  0.124  0.605  1.0
  Cl  Cl27  1  0.302  0.575  0.945  1.0
[/CIF]
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The compound described by AuCS2Cl3 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight AuCS2Cl3 clusters. Au(1) is bonded in a distorted rectangular see-saw-like geometry to one S(1), one S(2), one Cl(1), and one Cl(3) atom. C(1) is bonded in a trigonal planar geometry to one S(1), one S(2), and one Cl(2) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in an L-shaped geometry to one Au(1) and one C(1) atom. In the second S site, S(2) is bonded in an L-shaped geometry to one Au(1) and one C(1) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Au(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one C(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Au(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_AuCS2Cl3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.433
_cell_length_b   9.433
_cell_length_c   11.620
_cell_angle_alpha   65.702
_cell_angle_beta   65.702
_cell_angle_gamma   69.194
_symmetry_Int_Tables_number   1
_cell_volume   837.122
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Au  Au0  1  0.046  0.291  0.462  1.0
  Au  Au1  1  0.954  0.709  0.538  1.0
  Au  Au2  1  0.291  0.046  0.962  1.0
  Au  Au3  1  0.709  0.954  0.038  1.0
  C  C4  1  0.752  0.298  0.451  1.0
  C  C5  1  0.248  0.702  0.549  1.0
  C  C6  1  0.702  0.248  0.049  1.0
  C  C7  1  0.298  0.752  0.951  1.0
  S  S8  1  0.137  0.567  0.660  1.0
  S  S9  1  0.567  0.137  0.160  1.0
  S  S10  1  0.839  0.167  0.931  1.0
  S  S11  1  0.833  0.161  0.569  1.0
  S  S12  1  0.863  0.433  0.340  1.0
  S  S13  1  0.433  0.863  0.840  1.0
  S  S14  1  0.167  0.839  0.431  1.0
  S  S15  1  0.161  0.833  0.069  1.0
  Cl  Cl16  1  0.767  0.550  0.669  1.0
  Cl  Cl17  1  0.698  0.425  0.055  1.0
  Cl  Cl18  1  0.450  0.233  0.831  1.0
  Cl  Cl19  1  0.804  0.876  0.395  1.0
  Cl  Cl20  1  0.233  0.450  0.331  1.0
  Cl  Cl21  1  0.425  0.698  0.555  1.0
  Cl  Cl22  1  0.124  0.196  0.105  1.0
  Cl  Cl23  1  0.575  0.302  0.445  1.0
  Cl  Cl24  1  0.550  0.767  0.169  1.0
  Cl  Cl25  1  0.876  0.804  0.895  1.0
  Cl  Cl26  1  0.196  0.124  0.605  1.0
  Cl  Cl27  1  0.302  0.575  0.945  1.0
[/CIF]
.