The compound described by NdCo1 crystallizes in the monoclinic C2/m space group. There are three inequivalent Nd sites. In the first Nd site, Nd(1) is bonded in a 7-coordinate geometry to one Co(1) and six equivalent Co(2) atoms. In the second Nd site, Nd(2) is bonded in a 4-coordinate geometry to three equivalent Co(1) and six equivalent Co(2) atoms. In the third Nd site, Nd(3) is bonded in a distorted square co-planar geometry to four equivalent Co(2) atoms. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to two equivalent Nd(1), six equivalent Nd(2), and four equivalent Co(2) atoms to form edge-sharing CoNd8Co4 cuboctahedra. In the second Co site, Co(2) is bonded in a 9-coordinate geometry to one Nd(3), three equivalent Nd(1), three equivalent Nd(2), one Co(1), and one Co(2) atom. is represented by the CIF file [CIF]
data_NdCo
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.794
_cell_length_b   5.717
_cell_length_c   7.416
_cell_angle_alpha   89.282
_cell_angle_beta   90.000
_cell_angle_gamma   59.552
_symmetry_Int_Tables_number   1
_cell_volume   211.748
_cell_formula_units_Z   5
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Nd  Nd0  1  0.663  0.675  0.873  1.0
  Nd  Nd1  1  0.337  0.325  0.127  1.0
  Nd  Nd2  1  0.840  0.320  0.428  1.0
  Nd  Nd3  1  0.160  0.680  0.572  1.0
  Nd  Nd4  1  0.000  0.000  0.000  1.0
  Co  Co5  1  0.500  0.000  0.500  1.0
  Co  Co6  1  0.609  0.201  0.739  1.0
  Co  Co7  1  0.810  0.799  0.261  1.0
  Co  Co8  1  0.391  0.799  0.261  1.0
  Co  Co9  1  0.190  0.201  0.739  1.0
[/CIF]
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The compound described by NdCo1 crystallizes in the monoclinic C2/m space group. There are three inequivalent Nd sites. In the first Nd site, Nd(1) is bonded in a 7-coordinate geometry to one Co(1) and six equivalent Co(2) atoms. In the second Nd site, Nd(2) is bonded in a 4-coordinate geometry to three equivalent Co(1) and six equivalent Co(2) atoms. In the third Nd site, Nd(3) is bonded in a distorted square co-planar geometry to four equivalent Co(2) atoms. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to two equivalent Nd(1), six equivalent Nd(2), and four equivalent Co(2) atoms to form edge-sharing CoNd8Co4 cuboctahedra. In the second Co site, Co(2) is bonded in a 9-coordinate geometry to one Nd(3), three equivalent Nd(1), three equivalent Nd(2), one Co(1), and one Co(2) atom. is represented by the CIF file [CIF]
data_NdCo
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.794
_cell_length_b   5.717
_cell_length_c   7.416
_cell_angle_alpha   89.282
_cell_angle_beta   90.000
_cell_angle_gamma   59.552
_symmetry_Int_Tables_number   1
_cell_volume   211.748
_cell_formula_units_Z   5
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Nd  Nd0  1  0.663  0.675  0.873  1.0
  Nd  Nd1  1  0.337  0.325  0.127  1.0
  Nd  Nd2  1  0.840  0.320  0.428  1.0
  Nd  Nd3  1  0.160  0.680  0.572  1.0
  Nd  Nd4  1  0.000  0.000  0.000  1.0
  Co  Co5  1  0.500  0.000  0.500  1.0
  Co  Co6  1  0.609  0.201  0.739  1.0
  Co  Co7  1  0.810  0.799  0.261  1.0
  Co  Co8  1  0.391  0.799  0.261  1.0
  Co  Co9  1  0.190  0.201  0.739  1.0
[/CIF]
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