The material structure described by Li(CoO2)2 is Spinel structured and crystallizes in the triclinic P1 space group. There are eight inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(26), one O(27), one O(4), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(10)O6 octahedra,  a cornercorner with one Co(12)O6 octahedra,  a cornercorner with one Co(13)O6 octahedra,  a cornercorner with one Co(14)O6 octahedra,  a cornercorner with one Co(15)O6 octahedra,  a cornercorner with one Co(16)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra, and  a cornercorner with one Co(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 58-63°. In the second Li site, Li(2) is bonded to one O(1), one O(14), one O(15), and one O(5) atom to form LiO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(10)O6 octahedra,  a cornercorner with one Co(13)O6 octahedra,  a cornercorner with one Co(14)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Co(7)O6 octahedra,  a cornercorner with one Co(8)O6 octahedra, and  a cornercorner with one Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-61°. In the third Li site, Li(3) is bonded to one O(12), one O(16), one O(2), and one O(3) atom to form LiO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(11)O6 octahedra,  a cornercorner with one Co(12)O6 octahedra,  a cornercorner with one Co(15)O6 octahedra,  a cornercorner with one Co(16)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Co(7)O6 octahedra, and  a cornercorner with one Co(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-62°. In the fourth Li site, Li(4) is bonded to one O(13), one O(22), one O(23), and one O(9) atom to form LiO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(10)O6 octahedra,  a cornercorner with one Co(11)O6 octahedra,  a cornercorner with one Co(12)O6 octahedra,  a cornercorner with one Co(13)O6 octahedra,  a cornercorner with one Co(15)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Co(7)O6 octahedra,  a cornercorner with one Co(8)O6 octahedra, and  a cornercorner with one Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 58-61°. In the fifth Li site, Li(5) is bonded to one O(10), one O(11), one O(20), and one O(24) atom to form LiO4 tetrahedra that share  a cornercorner with one Co(10)O6 octahedra,  a cornercorner with one Co(11)O6 octahedra,  a cornercorner with one Co(12)O6 octahedra,  a cornercorner with one Co(14)O6 octahedra,  a cornercorner with one Co(16)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Co(7)O6 octahedra,  a cornercorner with one Co(8)O6 octahedra, and  a cornercorner with one Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-61°. In the sixth Li site, Li(6) is bonded to one O(17), one O(21), one O(30), and one O(31) atom to form LiO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(10)O6 octahedra,  a cornercorner with one Co(11)O6 octahedra,  a cornercorner with one Co(12)O6 octahedra,  a cornercorner with one Co(13)O6 octahedra,  a cornercorner with one Co(14)O6 octahedra,  a cornercorner with one Co(15)O6 octahedra,  a cornercorner with one Co(16)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra, and  a cornercorner with one Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 58-62°. In the seventh Li site, Li(7) is bonded to one O(18), one O(19), one O(28), and one O(32) atom to form LiO4 tetrahedra that share  a cornercorner with one Co(10)O6 octahedra,  a cornercorner with one Co(11)O6 octahedra,  a cornercorner with one Co(12)O6 octahedra,  a cornercorner with one Co(13)O6 octahedra,  a cornercorner with one Co(14)O6 octahedra,  a cornercorner with one Co(15)O6 octahedra,  a cornercorner with one Co(16)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(7)O6 octahedra,  a cornercorner with one Co(8)O6 octahedra, and  a cornercorner with one Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 58-62°. In the eighth Li site, Li(8) is bonded to one O(25), one O(29), one O(6), and one O(7) atom to form LiO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(11)O6 octahedra,  a cornercorner with one Co(13)O6 octahedra,  a cornercorner with one Co(14)O6 octahedra,  a cornercorner with one Co(15)O6 octahedra,  a cornercorner with one Co(16)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(7)O6 octahedra, and  a cornercorner with one Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-61°. There are sixteen inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(2), one O(30), one O(4), one O(6), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Co(13)O6 octahedra,  an edgeedge with one Co(15)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, and  an edgeedge with one Co(6)O6 octahedra. In the second Co site, Co(2) is bonded to one O(10), one O(3), one O(31), one O(4), one O(5), and one O(6) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(14)O6 octahedra,  an edgeedge with one Co(16)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, and  an edgeedge with one Co(6)O6 octahedra. In the third Co site, Co(3) is bonded to one O(1), one O(13), one O(2), one O(28), one O(7), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(13)O6 octahedra,  an edgeedge with one Co(15)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra, and  an edgeedge with one Co(8)O6 octahedra. In the fourth Co site, Co(4) is bonded to one O(11), one O(3), one O(32), one O(5), one O(7), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Co(14)O6 octahedra,  an edgeedge with one Co(16)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra, and  an edgeedge with one Co(8)O6 octahedra. In the fifth Co site, Co(5) is bonded to one O(10), one O(12), one O(14), one O(17), one O(6), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(11)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra, and  an edgeedge with one Co(9)O6 octahedra. In the sixth Co site, Co(6) is bonded to one O(10), one O(15), one O(16), one O(21), one O(4), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(12)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, and  an edgeedge with one Co(8)O6 octahedra. In the seventh Co site, Co(7) is bonded to one O(11), one O(12), one O(13), one O(14), one O(18), and one O(7) atom to form CoO6 octahedra that share  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Co(11)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra, and  an edgeedge with one Co(9)O6 octahedra. In the eighth Co site, Co(8) is bonded to one O(11), one O(13), one O(15), one O(16), one O(19), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(12)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, and  an edgeedge with one Co(7)O6 octahedra. In the ninth Co site, Co(9) is bonded to one O(14), one O(17), one O(18), one O(20), one O(22), and one O(25) atom to form CoO6 octahedra that share  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(11)O6 octahedra,  an edgeedge with one Co(13)O6 octahedra,  an edgeedge with one Co(14)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, and  an edgeedge with one Co(7)O6 octahedra. In the tenth Co site, Co(10) is bonded to one O(15), one O(19), one O(20), one O(21), one O(22), and one O(26) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  an edgeedge with one Co(12)O6 octahedra,  an edgeedge with one Co(13)O6 octahedra,  an edgeedge with one Co(14)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra, and  an edgeedge with one Co(9)O6 octahedra. In the eleventh Co site, Co(11) is bonded to one O(12), one O(17), one O(18), one O(23), one O(24), and one O(29) atom to form CoO6 octahedra that share  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Co(12)O6 octahedra,  an edgeedge with one Co(15)O6 octahedra,  an edgeedge with one Co(16)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra, and  an edgeedge with one Co(9)O6 octahedra. In the twelfth Co site, Co(12) is bonded to one O(16), one O(19), one O(21), one O(23), one O(24), and one O(27) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(11)O6 octahedra,  an edgeedge with one Co(15)O6 octahedra,  an edgeedge with one Co(16)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, and  an edgeedge with one Co(8)O6 octahedra. In the thirteenth Co site, Co(13) is bonded to one O(1), one O(22), one O(25), one O(26), one O(28), and one O(30) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(14)O6 octahedra,  an edgeedge with one Co(15)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, and  an edgeedge with one Co(9)O6 octahedra. In the fourteenth Co site, Co(14) is bonded to one O(20), one O(25), one O(26), one O(31), one O(32), and one O(5) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(13)O6 octahedra,  an edgeedge with one Co(16)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra, and  an edgeedge with one Co(9)O6 octahedra. In the fifteenth Co site, Co(15) is bonded to one O(2), one O(23), one O(27), one O(28), one O(29), and one O(30) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(11)O6 octahedra,  an edgeedge with one Co(12)O6 octahedra,  an edgeedge with one Co(13)O6 octahedra,  an edgeedge with one Co(16)O6 octahedra, and  an edgeedge with one Co(3)O6 octahedra. In the sixteenth Co site, Co(16) is bonded to one O(24), one O(27), one O(29), one O(3), one O(31), and one O(32) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Co(11)O6 octahedra,  an edgeedge with one Co(12)O6 octahedra,  an edgeedge with one Co(14)O6 octahedra,  an edgeedge with one Co(15)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra, and  an edgeedge with one Co(4)O6 octahedra. There are thirty-two inequivalent O sites. In the first O site, O(1) is bonded to one Li(2), one Co(1), one Co(13), and one Co(3) atom to form a mixture of distorted corner and edge-sharing OLiCo3 trigonal pyramids. In the second O site, O(2) is bonded to one Li(3), one Co(1), one Co(15), and one Co(3) atom to form a mixture of distorted corner and edge-sharing OLiCo3 trigonal pyramids. In the third O site, O(3) is bonded to one Li(3), one Co(16), one Co(2), and one Co(4) atom to form a mixture of distorted corner and edge-sharing OLiCo3 trigonal pyramids. In the fourth O site, O(4) is bonded to one Li(1), one Co(1), one Co(2), and one Co(6) atom to form a mixture of distorted corner and edge-sharing OLiCo3 trigonal pyramids. In the fifth O site, O(5) is bonded to one Li(2), one Co(14), one Co(2), and one Co(4) atom to form a mixture of distorted corner and edge-sharing OLiCo3 trigonal pyramids. In the sixth O site, O(6) is bonded to one Li(8), one Co(1), one Co(2), and one Co(5) atom to form a mixture of distorted corner and edge-sharing OLiCo3 trigonal pyramids. In the seventh O site, O(7) is bonded to one Li(8), one Co(3), one Co(4), and one Co(7) atom to form a mixture of distorted corner and edge-sharing OLiCo3 trigonal pyramids. In the eighth O site, O(8) is bonded to one Li(1), one Co(3), one Co(4), and one Co(8) atom to form a mixture of distorted corner and edge-sharing OLiCo3 trigonal pyramids. In the ninth O site, O(9) is bonded to one Li(4), one Co(1), one Co(5), and one Co(6) atom to form a mixture of distorted corner and edge-sharing OLiCo3 trigonal pyramids. In the tenth O site, O(10) is bonded to one Li(5), one Co(2), one Co(5), and one Co(6) atom to form a mixture of distorted corner and edge-sharing OLiCo3 tetrahedra. In the eleventh O site, O(11) is bonded to one Li(5), one Co(4), one Co(7), and one Co(8) atom to form a mixture of distorted corner and edge-sharing OLiCo3 tetrahedra. In the twelfth O site, O(12) is bonded to one Li(3), one Co(11), one Co(5), and one Co(7) atom to form a mixture of distorted corner and edge-sharing OLiCo3 trigonal pyramids. In the thirteenth O site, O(13) is bonded to one Li(4), one Co(3), one Co(7), and one Co(8) atom to form a mixture of distorted corner and edge-sharing OLiCo3 trigonal pyramids. In the fourteenth O site, O(14) is bonded to one Li(2), one Co(5), one Co(7), and one Co(9) atom to form a mixture of distorted corner and edge-sharing OLiCo3 trigonal pyramids. In the fifteenth O site, O(15) is bonded to one Li(2), one Co(10), one Co(6), and one Co(8) atom to form a mixture of distorted corner and edge-sharing OLiCo3 trigonal pyramids. In the sixteenth O site, O(16) is bonded to one Li(3), one Co(12), one Co(6), and one Co(8) atom to form a mixture of distorted corner and edge-sharing OLiCo3 trigonal pyramids. In the seventeenth O site, O(17) is bonded to one Li(6), one Co(11), one Co(5), and one Co(9) atom to form a mixture of distorted corner and edge-sharing OLiCo3 tetrahedra. In the eighteenth O site, O(18) is bonded in a distorted rectangular see-saw-like geometry to one Li(7), one Co(11), one Co(7), and one Co(9) atom. In the nineteenth O site, O(19) is bonded to one Li(7), one Co(10), one Co(12), and one Co(8) atom to form a mixture of distorted corner and edge-sharing OLiCo3 trigonal pyramids. In the twentieth O site, O(20) is bonded to one Li(5), one Co(10), one Co(14), and one Co(9) atom to form a mixture of distorted corner and edge-sharing OLiCo3 tetrahedra. In the twenty-first O site, O(21) is bonded to one Li(6), one Co(10), one Co(12), and one Co(6) atom to form a mixture of distorted corner and edge-sharing OLiCo3 trigonal pyramids. In the twenty-second O site, O(22) is bonded to one Li(4), one Co(10), one Co(13), and one Co(9) atom to form a mixture of distorted corner and edge-sharing OLiCo3 trigonal pyramids. In the twenty-third O site, O(23) is bonded to one Li(4), one Co(11), one Co(12), and one Co(15) atom to form a mixture of distorted corner and edge-sharing OLiCo3 trigonal pyramids. In the twenty-fourth O site, O(24) is bonded to one Li(5), one Co(11), one Co(12), and one Co(16) atom to form a mixture of distorted corner and edge-sharing OLiCo3 trigonal pyramids. In the twenty-fifth O site, O(25) is bonded to one Li(8), one Co(13), one Co(14), and one Co(9) atom to form a mixture of distorted corner and edge-sharing OLiCo3 trigonal pyramids. In the twenty-sixth O site, O(26) is bonded to one Li(1), one Co(10), one Co(13), and one Co(14) atom to form a mixture of distorted corner and edge-sharing OLiCo3 trigonal pyramids. In the twenty-seventh O site, O(27) is bonded to one Li(1), one Co(12), one Co(15), and one Co(16) atom to form a mixture of distorted corner and edge-sharing OLiCo3 trigonal pyramids. In the twenty-eighth O site, O(28) is bonded to one Li(7), one Co(13), one Co(15), and one Co(3) atom to form a mixture of distorted corner and edge-sharing OLiCo3 trigonal pyramids. In the twenty-ninth O site, O(29) is bonded to one Li(8), one Co(11), one Co(15), and one Co(16) atom to form a mixture of distorted corner and edge-sharing OLiCo3 trigonal pyramids. In the thirtieth O site, O(30) is bonded in a distorted rectangular see-saw-like geometry to one Li(6), one Co(1), one Co(13), and one Co(15) atom. In the thirty-first O site, O(31) is bonded in a distorted rectangular see-saw-like geometry to one Li(6), one Co(14), one Co(16), and one Co(2) atom. In the thirty-second O site, O(32) is bonded to one Li(7), one Co(14), one Co(16), and one Co(4) atom to form a mixture of distorted corner and edge-sharing OLiCo3 trigonal pyramids. is represented by the CIF file [CIF]
data_Li(CoO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.699
_cell_length_b   5.700
_cell_length_c   5.701
_cell_angle_alpha   60.016
_cell_angle_beta   60.025
_cell_angle_gamma   60.087
_symmetry_Int_Tables_number   1
_cell_volume   131.086
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.375  0.375  0.375  1.0
  Co  Co1  1  0.375  0.375  0.875  1.0
  Co  Co2  1  0.874  0.375  0.375  1.0
  Co  Co3  1  0.376  0.875  0.375  1.0
  Li  Li4  1  0.002  1.000  0.998  1.0
  Li  Li5  1  0.748  0.751  0.751  1.0
  O  O6  1  0.166  0.608  0.614  1.0
  O  O7  1  0.609  0.167  0.612  1.0
  O  O8  1  0.584  0.141  0.136  1.0
  O  O9  1  0.141  0.583  0.138  1.0
  O  O10  1  0.141  0.138  0.582  1.0
  O  O11  1  0.141  0.139  0.137  1.0
  O  O12  1  0.609  0.613  0.167  1.0
  O  O13  1  0.609  0.611  0.614  1.0
[/CIF]
.
The material structure described by Li(CoO2)2 is Spinel structured and crystallizes in the triclinic P1 space group. There are eight inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(26), one O(27), one O(4), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(10)O6 octahedra,  a cornercorner with one Co(12)O6 octahedra,  a cornercorner with one Co(13)O6 octahedra,  a cornercorner with one Co(14)O6 octahedra,  a cornercorner with one Co(15)O6 octahedra,  a cornercorner with one Co(16)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra, and  a cornercorner with one Co(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 58-63°. In the second Li site, Li(2) is bonded to one O(1), one O(14), one O(15), and one O(5) atom to form LiO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(10)O6 octahedra,  a cornercorner with one Co(13)O6 octahedra,  a cornercorner with one Co(14)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Co(7)O6 octahedra,  a cornercorner with one Co(8)O6 octahedra, and  a cornercorner with one Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-61°. In the third Li site, Li(3) is bonded to one O(12), one O(16), one O(2), and one O(3) atom to form LiO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(11)O6 octahedra,  a cornercorner with one Co(12)O6 octahedra,  a cornercorner with one Co(15)O6 octahedra,  a cornercorner with one Co(16)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Co(7)O6 octahedra, and  a cornercorner with one Co(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-62°. In the fourth Li site, Li(4) is bonded to one O(13), one O(22), one O(23), and one O(9) atom to form LiO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(10)O6 octahedra,  a cornercorner with one Co(11)O6 octahedra,  a cornercorner with one Co(12)O6 octahedra,  a cornercorner with one Co(13)O6 octahedra,  a cornercorner with one Co(15)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Co(7)O6 octahedra,  a cornercorner with one Co(8)O6 octahedra, and  a cornercorner with one Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 58-61°. In the fifth Li site, Li(5) is bonded to one O(10), one O(11), one O(20), and one O(24) atom to form LiO4 tetrahedra that share  a cornercorner with one Co(10)O6 octahedra,  a cornercorner with one Co(11)O6 octahedra,  a cornercorner with one Co(12)O6 octahedra,  a cornercorner with one Co(14)O6 octahedra,  a cornercorner with one Co(16)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra,  a cornercorner with one Co(7)O6 octahedra,  a cornercorner with one Co(8)O6 octahedra, and  a cornercorner with one Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-61°. In the sixth Li site, Li(6) is bonded to one O(17), one O(21), one O(30), and one O(31) atom to form LiO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(10)O6 octahedra,  a cornercorner with one Co(11)O6 octahedra,  a cornercorner with one Co(12)O6 octahedra,  a cornercorner with one Co(13)O6 octahedra,  a cornercorner with one Co(14)O6 octahedra,  a cornercorner with one Co(15)O6 octahedra,  a cornercorner with one Co(16)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(6)O6 octahedra, and  a cornercorner with one Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 58-62°. In the seventh Li site, Li(7) is bonded to one O(18), one O(19), one O(28), and one O(32) atom to form LiO4 tetrahedra that share  a cornercorner with one Co(10)O6 octahedra,  a cornercorner with one Co(11)O6 octahedra,  a cornercorner with one Co(12)O6 octahedra,  a cornercorner with one Co(13)O6 octahedra,  a cornercorner with one Co(14)O6 octahedra,  a cornercorner with one Co(15)O6 octahedra,  a cornercorner with one Co(16)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(7)O6 octahedra,  a cornercorner with one Co(8)O6 octahedra, and  a cornercorner with one Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 58-62°. In the eighth Li site, Li(8) is bonded to one O(25), one O(29), one O(6), and one O(7) atom to form LiO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(11)O6 octahedra,  a cornercorner with one Co(13)O6 octahedra,  a cornercorner with one Co(14)O6 octahedra,  a cornercorner with one Co(15)O6 octahedra,  a cornercorner with one Co(16)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Co(7)O6 octahedra, and  a cornercorner with one Co(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-61°. There are sixteen inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(2), one O(30), one O(4), one O(6), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Co(13)O6 octahedra,  an edgeedge with one Co(15)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, and  an edgeedge with one Co(6)O6 octahedra. In the second Co site, Co(2) is bonded to one O(10), one O(3), one O(31), one O(4), one O(5), and one O(6) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(14)O6 octahedra,  an edgeedge with one Co(16)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, and  an edgeedge with one Co(6)O6 octahedra. In the third Co site, Co(3) is bonded to one O(1), one O(13), one O(2), one O(28), one O(7), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(13)O6 octahedra,  an edgeedge with one Co(15)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra, and  an edgeedge with one Co(8)O6 octahedra. In the fourth Co site, Co(4) is bonded to one O(11), one O(3), one O(32), one O(5), one O(7), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Co(14)O6 octahedra,  an edgeedge with one Co(16)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra, and  an edgeedge with one Co(8)O6 octahedra. In the fifth Co site, Co(5) is bonded to one O(10), one O(12), one O(14), one O(17), one O(6), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(11)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra, and  an edgeedge with one Co(9)O6 octahedra. In the sixth Co site, Co(6) is bonded to one O(10), one O(15), one O(16), one O(21), one O(4), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(12)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, and  an edgeedge with one Co(8)O6 octahedra. In the seventh Co site, Co(7) is bonded to one O(11), one O(12), one O(13), one O(14), one O(18), and one O(7) atom to form CoO6 octahedra that share  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Co(11)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra, and  an edgeedge with one Co(9)O6 octahedra. In the eighth Co site, Co(8) is bonded to one O(11), one O(13), one O(15), one O(16), one O(19), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(12)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, and  an edgeedge with one Co(7)O6 octahedra. In the ninth Co site, Co(9) is bonded to one O(14), one O(17), one O(18), one O(20), one O(22), and one O(25) atom to form CoO6 octahedra that share  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(11)O6 octahedra,  an edgeedge with one Co(13)O6 octahedra,  an edgeedge with one Co(14)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra, and  an edgeedge with one Co(7)O6 octahedra. In the tenth Co site, Co(10) is bonded to one O(15), one O(19), one O(20), one O(21), one O(22), and one O(26) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  an edgeedge with one Co(12)O6 octahedra,  an edgeedge with one Co(13)O6 octahedra,  an edgeedge with one Co(14)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra,  an edgeedge with one Co(8)O6 octahedra, and  an edgeedge with one Co(9)O6 octahedra. In the eleventh Co site, Co(11) is bonded to one O(12), one O(17), one O(18), one O(23), one O(24), and one O(29) atom to form CoO6 octahedra that share  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Co(12)O6 octahedra,  an edgeedge with one Co(15)O6 octahedra,  an edgeedge with one Co(16)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Co(7)O6 octahedra, and  an edgeedge with one Co(9)O6 octahedra. In the twelfth Co site, Co(12) is bonded to one O(16), one O(19), one O(21), one O(23), one O(24), and one O(27) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(11)O6 octahedra,  an edgeedge with one Co(15)O6 octahedra,  an edgeedge with one Co(16)O6 octahedra,  an edgeedge with one Co(6)O6 octahedra, and  an edgeedge with one Co(8)O6 octahedra. In the thirteenth Co site, Co(13) is bonded to one O(1), one O(22), one O(25), one O(26), one O(28), and one O(30) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(14)O6 octahedra,  an edgeedge with one Co(15)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, and  an edgeedge with one Co(9)O6 octahedra. In the fourteenth Co site, Co(14) is bonded to one O(20), one O(25), one O(26), one O(31), one O(32), and one O(5) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Co(10)O6 octahedra,  an edgeedge with one Co(13)O6 octahedra,  an edgeedge with one Co(16)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra, and  an edgeedge with one Co(9)O6 octahedra. In the fifteenth Co site, Co(15) is bonded to one O(2), one O(23), one O(27), one O(28), one O(29), and one O(30) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(11)O6 octahedra,  an edgeedge with one Co(12)O6 octahedra,  an edgeedge with one Co(13)O6 octahedra,  an edgeedge with one Co(16)O6 octahedra, and  an edgeedge with one Co(3)O6 octahedra. In the sixteenth Co site, Co(16) is bonded to one O(24), one O(27), one O(29), one O(3), one O(31), and one O(32) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra,  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra,  an edgeedge with one Co(11)O6 octahedra,  an edgeedge with one Co(12)O6 octahedra,  an edgeedge with one Co(14)O6 octahedra,  an edgeedge with one Co(15)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra, and  an edgeedge with one Co(4)O6 octahedra. There are thirty-two inequivalent O sites. In the first O site, O(1) is bonded to one Li(2), one Co(1), one Co(13), and one Co(3) atom to form a mixture of distorted corner and edge-sharing OLiCo3 trigonal pyramids. In the second O site, O(2) is bonded to one Li(3), one Co(1), one Co(15), and one Co(3) atom to form a mixture of distorted corner and edge-sharing OLiCo3 trigonal pyramids. In the third O site, O(3) is bonded to one Li(3), one Co(16), one Co(2), and one Co(4) atom to form a mixture of distorted corner and edge-sharing OLiCo3 trigonal pyramids. In the fourth O site, O(4) is bonded to one Li(1), one Co(1), one Co(2), and one Co(6) atom to form a mixture of distorted corner and edge-sharing OLiCo3 trigonal pyramids. In the fifth O site, O(5) is bonded to one Li(2), one Co(14), one Co(2), and one Co(4) atom to form a mixture of distorted corner and edge-sharing OLiCo3 trigonal pyramids. In the sixth O site, O(6) is bonded to one Li(8), one Co(1), one Co(2), and one Co(5) atom to form a mixture of distorted corner and edge-sharing OLiCo3 trigonal pyramids. In the seventh O site, O(7) is bonded to one Li(8), one Co(3), one Co(4), and one Co(7) atom to form a mixture of distorted corner and edge-sharing OLiCo3 trigonal pyramids. In the eighth O site, O(8) is bonded to one Li(1), one Co(3), one Co(4), and one Co(8) atom to form a mixture of distorted corner and edge-sharing OLiCo3 trigonal pyramids. In the ninth O site, O(9) is bonded to one Li(4), one Co(1), one Co(5), and one Co(6) atom to form a mixture of distorted corner and edge-sharing OLiCo3 trigonal pyramids. In the tenth O site, O(10) is bonded to one Li(5), one Co(2), one Co(5), and one Co(6) atom to form a mixture of distorted corner and edge-sharing OLiCo3 tetrahedra. In the eleventh O site, O(11) is bonded to one Li(5), one Co(4), one Co(7), and one Co(8) atom to form a mixture of distorted corner and edge-sharing OLiCo3 tetrahedra. In the twelfth O site, O(12) is bonded to one Li(3), one Co(11), one Co(5), and one Co(7) atom to form a mixture of distorted corner and edge-sharing OLiCo3 trigonal pyramids. In the thirteenth O site, O(13) is bonded to one Li(4), one Co(3), one Co(7), and one Co(8) atom to form a mixture of distorted corner and edge-sharing OLiCo3 trigonal pyramids. In the fourteenth O site, O(14) is bonded to one Li(2), one Co(5), one Co(7), and one Co(9) atom to form a mixture of distorted corner and edge-sharing OLiCo3 trigonal pyramids. In the fifteenth O site, O(15) is bonded to one Li(2), one Co(10), one Co(6), and one Co(8) atom to form a mixture of distorted corner and edge-sharing OLiCo3 trigonal pyramids. In the sixteenth O site, O(16) is bonded to one Li(3), one Co(12), one Co(6), and one Co(8) atom to form a mixture of distorted corner and edge-sharing OLiCo3 trigonal pyramids. In the seventeenth O site, O(17) is bonded to one Li(6), one Co(11), one Co(5), and one Co(9) atom to form a mixture of distorted corner and edge-sharing OLiCo3 tetrahedra. In the eighteenth O site, O(18) is bonded in a distorted rectangular see-saw-like geometry to one Li(7), one Co(11), one Co(7), and one Co(9) atom. In the nineteenth O site, O(19) is bonded to one Li(7), one Co(10), one Co(12), and one Co(8) atom to form a mixture of distorted corner and edge-sharing OLiCo3 trigonal pyramids. In the twentieth O site, O(20) is bonded to one Li(5), one Co(10), one Co(14), and one Co(9) atom to form a mixture of distorted corner and edge-sharing OLiCo3 tetrahedra. In the twenty-first O site, O(21) is bonded to one Li(6), one Co(10), one Co(12), and one Co(6) atom to form a mixture of distorted corner and edge-sharing OLiCo3 trigonal pyramids. In the twenty-second O site, O(22) is bonded to one Li(4), one Co(10), one Co(13), and one Co(9) atom to form a mixture of distorted corner and edge-sharing OLiCo3 trigonal pyramids. In the twenty-third O site, O(23) is bonded to one Li(4), one Co(11), one Co(12), and one Co(15) atom to form a mixture of distorted corner and edge-sharing OLiCo3 trigonal pyramids. In the twenty-fourth O site, O(24) is bonded to one Li(5), one Co(11), one Co(12), and one Co(16) atom to form a mixture of distorted corner and edge-sharing OLiCo3 trigonal pyramids. In the twenty-fifth O site, O(25) is bonded to one Li(8), one Co(13), one Co(14), and one Co(9) atom to form a mixture of distorted corner and edge-sharing OLiCo3 trigonal pyramids. In the twenty-sixth O site, O(26) is bonded to one Li(1), one Co(10), one Co(13), and one Co(14) atom to form a mixture of distorted corner and edge-sharing OLiCo3 trigonal pyramids. In the twenty-seventh O site, O(27) is bonded to one Li(1), one Co(12), one Co(15), and one Co(16) atom to form a mixture of distorted corner and edge-sharing OLiCo3 trigonal pyramids. In the twenty-eighth O site, O(28) is bonded to one Li(7), one Co(13), one Co(15), and one Co(3) atom to form a mixture of distorted corner and edge-sharing OLiCo3 trigonal pyramids. In the twenty-ninth O site, O(29) is bonded to one Li(8), one Co(11), one Co(15), and one Co(16) atom to form a mixture of distorted corner and edge-sharing OLiCo3 trigonal pyramids. In the thirtieth O site, O(30) is bonded in a distorted rectangular see-saw-like geometry to one Li(6), one Co(1), one Co(13), and one Co(15) atom. In the thirty-first O site, O(31) is bonded in a distorted rectangular see-saw-like geometry to one Li(6), one Co(14), one Co(16), and one Co(2) atom. In the thirty-second O site, O(32) is bonded to one Li(7), one Co(14), one Co(16), and one Co(4) atom to form a mixture of distorted corner and edge-sharing OLiCo3 trigonal pyramids. is represented by the CIF file [CIF]
data_Li(CoO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.699
_cell_length_b   5.700
_cell_length_c   5.701
_cell_angle_alpha   60.016
_cell_angle_beta   60.025
_cell_angle_gamma   60.087
_symmetry_Int_Tables_number   1
_cell_volume   131.086
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.375  0.375  0.375  1.0
  Co  Co1  1  0.375  0.375  0.875  1.0
  Co  Co2  1  0.874  0.375  0.375  1.0
  Co  Co3  1  0.376  0.875  0.375  1.0
  Li  Li4  1  0.002  1.000  0.998  1.0
  Li  Li5  1  0.748  0.751  0.751  1.0
  O  O6  1  0.166  0.608  0.614  1.0
  O  O7  1  0.609  0.167  0.612  1.0
  O  O8  1  0.584  0.141  0.136  1.0
  O  O9  1  0.141  0.583  0.138  1.0
  O  O10  1  0.141  0.138  0.582  1.0
  O  O11  1  0.141  0.139  0.137  1.0
  O  O12  1  0.609  0.613  0.167  1.0
  O  O13  1  0.609  0.611  0.614  1.0
[/CIF]
.