The compound described by B5Bi is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two B5Bi clusters. There are ten inequivalent B sites. In the first B site, B(1) is bonded in a 2-coordinate geometry to one B(2), one B(5), one B(6), and one Bi(2) atom. In the second B site, B(2) is bonded in a 4-coordinate geometry to one B(1), one B(6), one B(7), and one Bi(1) atom. In the third B site, B(3) is bonded in a 4-coordinate geometry to one B(4), one B(7), one B(8), and one Bi(1) atom. In the fourth B site, B(4) is bonded in a 4-coordinate geometry to one B(3), one B(8), one B(9), and one Bi(2) atom. In the fifth B site, B(5) is bonded in a 5-coordinate geometry to one B(1), one B(10), one B(6), one B(9), and one Bi(2) atom. In the sixth B site, B(6) is bonded in a 5-coordinate geometry to one B(1), one B(10), one B(2), one B(5), and one B(7) atom. In the seventh B site, B(7) is bonded in a 5-coordinate geometry to one B(10), one B(2), one B(3), one B(6), and one B(8) atom. In the eighth B site, B(8) is bonded in a 5-coordinate geometry to one B(10), one B(3), one B(4), one B(7), and one B(9) atom. In the ninth B site, B(9) is bonded in a 5-coordinate geometry to one B(10), one B(4), one B(5), one B(8), and one Bi(2) atom. In the tenth B site, B(10) is bonded in a 2-coordinate geometry to one B(5), one B(6), one B(7), one B(8), and one B(9) atom. There are two inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a 2-coordinate geometry to one B(2) and one B(3) atom. In the second Bi site, Bi(2) is bonded in a 4-coordinate geometry to one B(1), one B(4), one B(5), and one B(9) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_BiB5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.680
_cell_length_b   11.729
_cell_length_c   14.956
_cell_angle_alpha   93.054
_cell_angle_beta   108.531
_cell_angle_gamma   93.708
_symmetry_Int_Tables_number   1
_cell_volume   1767.167
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.642  0.877  0.102  1.0
  Bi  Bi1  1  0.358  0.123  0.898  1.0
  Bi  Bi2  1  0.570  0.916  0.394  1.0
  Bi  Bi3  1  0.430  0.084  0.606  1.0
  B  B4  1  0.752  0.004  0.351  1.0
  B  B5  1  0.248  0.996  0.649  1.0
  B  B6  1  0.777  0.964  0.250  1.0
  B  B7  1  0.223  0.036  0.750  1.0
  B  B8  1  0.669  0.751  0.224  1.0
  B  B9  1  0.331  0.249  0.776  1.0
  B  B10  1  0.620  0.744  0.318  1.0
  B  B11  1  0.380  0.256  0.682  1.0
  B  B12  1  0.816  0.916  0.438  1.0
  B  B13  1  0.184  0.084  0.562  1.0
  B  B14  1  0.886  0.938  0.353  1.0
  B  B15  1  0.114  0.062  0.647  1.0
  B  B16  1  0.819  0.828  0.272  1.0
  B  B17  1  0.181  0.172  0.728  1.0
  B  B18  1  0.774  0.717  0.325  1.0
  B  B19  1  0.226  0.283  0.675  1.0
  B  B20  1  0.746  0.782  0.420  1.0
  B  B21  1  0.254  0.218  0.580  1.0
  B  B22  1  0.889  0.812  0.399  1.0
  B  B23  1  0.111  0.188  0.601  1.0
[/CIF]
.
The compound described by B5Bi is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two B5Bi clusters. There are ten inequivalent B sites. In the first B site, B(1) is bonded in a 2-coordinate geometry to one B(2), one B(5), one B(6), and one Bi(2) atom. In the second B site, B(2) is bonded in a 4-coordinate geometry to one B(1), one B(6), one B(7), and one Bi(1) atom. In the third B site, B(3) is bonded in a 4-coordinate geometry to one B(4), one B(7), one B(8), and one Bi(1) atom. In the fourth B site, B(4) is bonded in a 4-coordinate geometry to one B(3), one B(8), one B(9), and one Bi(2) atom. In the fifth B site, B(5) is bonded in a 5-coordinate geometry to one B(1), one B(10), one B(6), one B(9), and one Bi(2) atom. In the sixth B site, B(6) is bonded in a 5-coordinate geometry to one B(1), one B(10), one B(2), one B(5), and one B(7) atom. In the seventh B site, B(7) is bonded in a 5-coordinate geometry to one B(10), one B(2), one B(3), one B(6), and one B(8) atom. In the eighth B site, B(8) is bonded in a 5-coordinate geometry to one B(10), one B(3), one B(4), one B(7), and one B(9) atom. In the ninth B site, B(9) is bonded in a 5-coordinate geometry to one B(10), one B(4), one B(5), one B(8), and one Bi(2) atom. In the tenth B site, B(10) is bonded in a 2-coordinate geometry to one B(5), one B(6), one B(7), one B(8), and one B(9) atom. There are two inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a 2-coordinate geometry to one B(2) and one B(3) atom. In the second Bi site, Bi(2) is bonded in a 4-coordinate geometry to one B(1), one B(4), one B(5), and one B(9) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_BiB5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.680
_cell_length_b   11.729
_cell_length_c   14.956
_cell_angle_alpha   93.054
_cell_angle_beta   108.531
_cell_angle_gamma   93.708
_symmetry_Int_Tables_number   1
_cell_volume   1767.167
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.642  0.877  0.102  1.0
  Bi  Bi1  1  0.358  0.123  0.898  1.0
  Bi  Bi2  1  0.570  0.916  0.394  1.0
  Bi  Bi3  1  0.430  0.084  0.606  1.0
  B  B4  1  0.752  0.004  0.351  1.0
  B  B5  1  0.248  0.996  0.649  1.0
  B  B6  1  0.777  0.964  0.250  1.0
  B  B7  1  0.223  0.036  0.750  1.0
  B  B8  1  0.669  0.751  0.224  1.0
  B  B9  1  0.331  0.249  0.776  1.0
  B  B10  1  0.620  0.744  0.318  1.0
  B  B11  1  0.380  0.256  0.682  1.0
  B  B12  1  0.816  0.916  0.438  1.0
  B  B13  1  0.184  0.084  0.562  1.0
  B  B14  1  0.886  0.938  0.353  1.0
  B  B15  1  0.114  0.062  0.647  1.0
  B  B16  1  0.819  0.828  0.272  1.0
  B  B17  1  0.181  0.172  0.728  1.0
  B  B18  1  0.774  0.717  0.325  1.0
  B  B19  1  0.226  0.283  0.675  1.0
  B  B20  1  0.746  0.782  0.420  1.0
  B  B21  1  0.254  0.218  0.580  1.0
  B  B22  1  0.889  0.812  0.399  1.0
  B  B23  1  0.111  0.188  0.601  1.0
[/CIF]
.