The crystal structure described by CdC2(NS)2 crystallizes in the monoclinic P2_1/c space group. Cd(1) is bonded to one N(1), one N(2), two equivalent S(1), and two equivalent S(2) atoms to form a mixture of distorted edge and corner-sharing CdS4N2 octahedra. The corner-sharing octahedral tilt angles are 53°. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one N(1) and one S(1) atom. In the second C site, C(2) is bonded in a distorted linear geometry to one N(2) and one S(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 150 degrees geometry to one Cd(1) and one C(1) atom. In the second N site, N(2) is bonded in a linear geometry to one Cd(1) and one C(2) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted T-shaped geometry to two equivalent Cd(1) and one C(1) atom. In the second S site, S(2) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Cd(1) and one C(2) atom. is represented by the CIF card [CIF]
data_CdC2(SN)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.533
_cell_length_b   5.905
_cell_length_c   7.805
_cell_angle_alpha   66.206
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   570.734
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.869  0.175  0.884  1.0
  Cd  Cd1  1  0.369  0.825  0.616  1.0
  Cd  Cd2  1  0.131  0.825  0.116  1.0
  Cd  Cd3  1  0.631  0.175  0.384  1.0
  C  C4  1  0.986  0.724  0.779  1.0
  C  C5  1  0.486  0.276  0.721  1.0
  C  C6  1  0.014  0.276  0.221  1.0
  C  C7  1  0.514  0.724  0.279  1.0
  C  C8  1  0.754  0.623  0.986  1.0
  C  C9  1  0.254  0.377  0.514  1.0
  C  C10  1  0.246  0.377  0.014  1.0
  C  C11  1  0.746  0.623  0.486  1.0
  S  S12  1  0.033  0.989  0.763  1.0
  S  S13  1  0.533  0.011  0.737  1.0
  S  S14  1  0.967  0.011  0.237  1.0
  S  S15  1  0.467  0.989  0.263  1.0
  S  S16  1  0.707  0.357  0.006  1.0
  S  S17  1  0.207  0.643  0.494  1.0
  S  S18  1  0.293  0.643  0.994  1.0
  S  S19  1  0.793  0.357  0.506  1.0
  N  N20  1  0.953  0.537  0.786  1.0
  N  N21  1  0.453  0.463  0.714  1.0
  N  N22  1  0.047  0.463  0.214  1.0
  N  N23  1  0.547  0.537  0.286  1.0
  N  N24  1  0.787  0.816  0.970  1.0
  N  N25  1  0.287  0.184  0.530  1.0
  N  N26  1  0.213  0.184  0.030  1.0
  N  N27  1  0.713  0.816  0.470  1.0
[/CIF]
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The crystal structure described by CdC2(NS)2 crystallizes in the monoclinic P2_1/c space group. Cd(1) is bonded to one N(1), one N(2), two equivalent S(1), and two equivalent S(2) atoms to form a mixture of distorted edge and corner-sharing CdS4N2 octahedra. The corner-sharing octahedral tilt angles are 53°. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one N(1) and one S(1) atom. In the second C site, C(2) is bonded in a distorted linear geometry to one N(2) and one S(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 150 degrees geometry to one Cd(1) and one C(1) atom. In the second N site, N(2) is bonded in a linear geometry to one Cd(1) and one C(2) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted T-shaped geometry to two equivalent Cd(1) and one C(1) atom. In the second S site, S(2) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Cd(1) and one C(2) atom. is represented by the CIF card [CIF]
data_CdC2(SN)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.533
_cell_length_b   5.905
_cell_length_c   7.805
_cell_angle_alpha   66.206
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   570.734
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.869  0.175  0.884  1.0
  Cd  Cd1  1  0.369  0.825  0.616  1.0
  Cd  Cd2  1  0.131  0.825  0.116  1.0
  Cd  Cd3  1  0.631  0.175  0.384  1.0
  C  C4  1  0.986  0.724  0.779  1.0
  C  C5  1  0.486  0.276  0.721  1.0
  C  C6  1  0.014  0.276  0.221  1.0
  C  C7  1  0.514  0.724  0.279  1.0
  C  C8  1  0.754  0.623  0.986  1.0
  C  C9  1  0.254  0.377  0.514  1.0
  C  C10  1  0.246  0.377  0.014  1.0
  C  C11  1  0.746  0.623  0.486  1.0
  S  S12  1  0.033  0.989  0.763  1.0
  S  S13  1  0.533  0.011  0.737  1.0
  S  S14  1  0.967  0.011  0.237  1.0
  S  S15  1  0.467  0.989  0.263  1.0
  S  S16  1  0.707  0.357  0.006  1.0
  S  S17  1  0.207  0.643  0.494  1.0
  S  S18  1  0.293  0.643  0.994  1.0
  S  S19  1  0.793  0.357  0.506  1.0
  N  N20  1  0.953  0.537  0.786  1.0
  N  N21  1  0.453  0.463  0.714  1.0
  N  N22  1  0.047  0.463  0.214  1.0
  N  N23  1  0.547  0.537  0.286  1.0
  N  N24  1  0.787  0.816  0.970  1.0
  N  N25  1  0.287  0.184  0.530  1.0
  N  N26  1  0.213  0.184  0.030  1.0
  N  N27  1  0.713  0.816  0.470  1.0
[/CIF]
.