The compound described by LiLa4CoO8 is (La,Ba)CuO4-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(20), one O(24), one O(27), one O(31), and one O(6) atom to form LiO6 octahedra that share corners with two equivalent Co(1)O6 octahedra and corners with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the second Li site, Li(2) is bonded to one O(19), one O(2), one O(23), one O(25), one O(29), and one O(8) atom to form LiO6 octahedra that share corners with two equivalent Co(1)O6 octahedra and corners with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the third Li site, Li(3) is bonded to one O(18), one O(22), one O(28), one O(3), one O(32), and one O(5) atom to form LiO6 octahedra that share corners with two equivalent Co(2)O6 octahedra and corners with two equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the fourth Li site, Li(4) is bonded to one O(17), one O(21), one O(26), one O(30), one O(4), and one O(7) atom to form LiO6 octahedra that share corners with two equivalent Co(3)O6 octahedra and corners with two equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. There are sixteen inequivalent La sites. In the first La site, La(1) is bonded in a 9-coordinate geometry to one O(13), one O(17), one O(21), one O(28), one O(32), one O(5), one O(7), and two equivalent O(9) atoms. In the second La site, La(2) is bonded in a 9-coordinate geometry to one O(14), one O(18), one O(22), one O(27), one O(31), one O(5), one O(6), and two equivalent O(10) atoms. In the third La site, La(3) is bonded in a 9-coordinate geometry to one O(15), one O(19), one O(23), one O(26), one O(30), one O(7), one O(8), and two equivalent O(11) atoms. In the fourth La site, La(4) is bonded in a 9-coordinate geometry to one O(16), one O(20), one O(24), one O(25), one O(29), one O(6), one O(8), and two equivalent O(12) atoms. In the fifth La site, La(5) is bonded in a 9-coordinate geometry to one O(1), one O(2), one O(20), one O(24), one O(25), one O(29), one O(9), and two equivalent O(13) atoms. In the sixth La site, La(6) is bonded in a 9-coordinate geometry to one O(10), one O(19), one O(2), one O(23), one O(26), one O(30), one O(4), and two equivalent O(14) atoms. In the seventh La site, La(7) is bonded in a 9-coordinate geometry to one O(1), one O(11), one O(18), one O(22), one O(27), one O(3), one O(31), and two equivalent O(15) atoms. In the eighth La site, La(8) is bonded in a 9-coordinate geometry to one O(12), one O(17), one O(21), one O(28), one O(3), one O(32), one O(4), and two equivalent O(16) atoms. In the ninth La site, La(9) is bonded in a 9-coordinate geometry to one O(13), one O(15), one O(20), one O(24), one O(27), one O(31), one O(7), and two equivalent O(1) atoms. In the tenth La site, La(10) is bonded in a 9-coordinate geometry to one O(13), one O(14), one O(19), one O(23), one O(25), one O(29), one O(5), and two equivalent O(2) atoms. In the eleventh La site, La(11) is bonded in a 9-coordinate geometry to one O(15), one O(16), one O(18), one O(22), one O(28), one O(32), one O(8), and two equivalent O(3) atoms. In the twelfth La site, La(12) is bonded in a 9-coordinate geometry to one O(14), one O(16), one O(17), one O(21), one O(26), one O(30), one O(6), and two equivalent O(4) atoms. In the thirteenth La site, La(13) is bonded in a 9-coordinate geometry to one O(10), one O(18), one O(2), one O(22), one O(28), one O(32), one O(9), and two equivalent O(5) atoms. In the fourteenth La site, La(14) is bonded in a 9-coordinate geometry to one O(10), one O(12), one O(20), one O(24), one O(27), one O(31), one O(4), and two equivalent O(6) atoms. In the fifteenth La site, La(15) is bonded in a 9-coordinate geometry to one O(1), one O(11), one O(17), one O(21), one O(26), one O(30), one O(9), and two equivalent O(7) atoms. In the sixteenth La site, La(16) is bonded in a 9-coordinate geometry to one O(11), one O(12), one O(19), one O(23), one O(25), one O(29), one O(3), and two equivalent O(8) atoms. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(12), one O(13), one O(20), one O(24), one O(25), and one O(29) atom to form CoO6 octahedra that share corners with two equivalent Li(1)O6 octahedra and corners with two equivalent Li(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the second Co site, Co(2) is bonded to one O(10), one O(15), one O(18), one O(22), one O(27), and one O(31) atom to form CoO6 octahedra that share corners with two equivalent Li(1)O6 octahedra and corners with two equivalent Li(3)O6 octahedra. The corner-sharing octahedral tilt angles are 1°. In the third Co site, Co(3) is bonded to one O(11), one O(14), one O(19), one O(23), one O(26), and one O(30) atom to form CoO6 octahedra that share corners with two equivalent Li(2)O6 octahedra and corners with two equivalent Li(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the fourth Co site, Co(4) is bonded to one O(16), one O(17), one O(21), one O(28), one O(32), and one O(9) atom to form CoO6 octahedra that share corners with two equivalent Li(3)O6 octahedra and corners with two equivalent Li(4)O6 octahedra. The corner-sharing octahedra are not tilted. There are thirty-two inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one La(15), one La(5), one La(7), and two equivalent La(9) atoms to form distorted OLiLa5 octahedra that share  a cornercorner with one O(17)LiLa4Co octahedra,  a cornercorner with one O(18)LiLa4Co octahedra,  a cornercorner with one O(20)LiLa4Co octahedra,  a cornercorner with one O(21)LiLa4Co octahedra,  a cornercorner with one O(22)LiLa4Co octahedra,  a cornercorner with one O(24)LiLa4Co octahedra,  a cornercorner with one O(25)LiLa4Co octahedra,  a cornercorner with one O(26)LiLa4Co octahedra,  a cornercorner with one O(27)LiLa4Co octahedra,  a cornercorner with one O(29)LiLa4Co octahedra,  a cornercorner with one O(30)LiLa4Co octahedra,  a cornercorner with one O(31)LiLa4Co octahedra,  a cornercorner with one O(2)LiLa5 octahedra,  a cornercorner with one O(3)LiLa5 octahedra,  a cornercorner with one O(6)LiLa5 octahedra, corners with two equivalent O(1)LiLa5 octahedra,  an edgeedge with one O(11)La5Co octahedra,  an edgeedge with one O(9)La5Co octahedra, edges with two equivalent O(13)La5Co octahedra, edges with two equivalent O(15)La5Co octahedra, edges with two equivalent O(7)LiLa5 octahedra,  a faceface with one O(20)LiLa4Co octahedra,  a faceface with one O(24)LiLa4Co octahedra,  a faceface with one O(27)LiLa4Co octahedra, and  a faceface with one O(31)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 1-51°. In the second O site, O(2) is bonded to one Li(2), one La(13), one La(5), one La(6), and two equivalent La(10) atoms to form distorted OLiLa5 octahedra that share  a cornercorner with one O(18)LiLa4Co octahedra,  a cornercorner with one O(19)LiLa4Co octahedra,  a cornercorner with one O(20)LiLa4Co octahedra,  a cornercorner with one O(22)LiLa4Co octahedra,  a cornercorner with one O(23)LiLa4Co octahedra,  a cornercorner with one O(24)LiLa4Co octahedra,  a cornercorner with one O(25)LiLa4Co octahedra,  a cornercorner with one O(26)LiLa4Co octahedra,  a cornercorner with one O(28)LiLa4Co octahedra,  a cornercorner with one O(29)LiLa4Co octahedra,  a cornercorner with one O(30)LiLa4Co octahedra,  a cornercorner with one O(32)LiLa4Co octahedra,  a cornercorner with one O(1)LiLa5 octahedra,  a cornercorner with one O(4)LiLa5 octahedra,  a cornercorner with one O(8)LiLa5 octahedra, corners with two equivalent O(2)LiLa5 octahedra,  an edgeedge with one O(10)La5Co octahedra,  an edgeedge with one O(9)La5Co octahedra, edges with two equivalent O(13)La5Co octahedra, edges with two equivalent O(14)La5Co octahedra, edges with two equivalent O(5)LiLa5 octahedra,  a faceface with one O(19)LiLa4Co octahedra,  a faceface with one O(23)LiLa4Co octahedra,  a faceface with one O(25)LiLa4Co octahedra, and  a faceface with one O(29)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-50°. In the third O site, O(3) is bonded to one Li(3), one La(16), one La(7), one La(8), and two equivalent La(11) atoms to form distorted OLiLa5 octahedra that share  a cornercorner with one O(17)LiLa4Co octahedra,  a cornercorner with one O(18)LiLa4Co octahedra,  a cornercorner with one O(19)LiLa4Co octahedra,  a cornercorner with one O(21)LiLa4Co octahedra,  a cornercorner with one O(22)LiLa4Co octahedra,  a cornercorner with one O(23)LiLa4Co octahedra,  a cornercorner with one O(25)LiLa4Co octahedra,  a cornercorner with one O(27)LiLa4Co octahedra,  a cornercorner with one O(28)LiLa4Co octahedra,  a cornercorner with one O(29)LiLa4Co octahedra,  a cornercorner with one O(31)LiLa4Co octahedra,  a cornercorner with one O(32)LiLa4Co octahedra,  a cornercorner with one O(1)LiLa5 octahedra,  a cornercorner with one O(4)LiLa5 octahedra,  a cornercorner with one O(5)LiLa5 octahedra, corners with two equivalent O(3)LiLa5 octahedra,  an edgeedge with one O(11)La5Co octahedra,  an edgeedge with one O(12)La5Co octahedra, edges with two equivalent O(15)La5Co octahedra, edges with two equivalent O(16)La5Co octahedra, edges with two equivalent O(8)LiLa5 octahedra,  a faceface with one O(18)LiLa4Co octahedra,  a faceface with one O(22)LiLa4Co octahedra,  a faceface with one O(28)LiLa4Co octahedra, and  a faceface with one O(32)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 1-51°. In the fourth O site, O(4) is bonded to one Li(4), one La(14), one La(6), one La(8), and two equivalent La(12) atoms to form distorted OLiLa5 octahedra that share  a cornercorner with one O(17)LiLa4Co octahedra,  a cornercorner with one O(19)LiLa4Co octahedra,  a cornercorner with one O(20)LiLa4Co octahedra,  a cornercorner with one O(21)LiLa4Co octahedra,  a cornercorner with one O(23)LiLa4Co octahedra,  a cornercorner with one O(24)LiLa4Co octahedra,  a cornercorner with one O(26)LiLa4Co octahedra,  a cornercorner with one O(27)LiLa4Co octahedra,  a cornercorner with one O(28)LiLa4Co octahedra,  a cornercorner with one O(30)LiLa4Co octahedra,  a cornercorner with one O(31)LiLa4Co octahedra,  a cornercorner with one O(32)LiLa4Co octahedra,  a cornercorner with one O(2)LiLa5 octahedra,  a cornercorner with one O(3)LiLa5 octahedra,  a cornercorner with one O(7)LiLa5 octahedra, corners with two equivalent O(4)LiLa5 octahedra,  an edgeedge with one O(10)La5Co octahedra,  an edgeedge with one O(12)La5Co octahedra, edges with two equivalent O(14)La5Co octahedra, edges with two equivalent O(16)La5Co octahedra, edges with two equivalent O(6)LiLa5 octahedra,  a faceface with one O(17)LiLa4Co octahedra,  a faceface with one O(21)LiLa4Co octahedra,  a faceface with one O(26)LiLa4Co octahedra, and  a faceface with one O(30)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-51°. In the fifth O site, O(5) is bonded to one Li(3), one La(1), one La(10), one La(2), and two equivalent La(13) atoms to form distorted OLiLa5 octahedra that share  a cornercorner with one O(17)LiLa4Co octahedra,  a cornercorner with one O(18)LiLa4Co octahedra,  a cornercorner with one O(19)LiLa4Co octahedra,  a cornercorner with one O(21)LiLa4Co octahedra,  a cornercorner with one O(22)LiLa4Co octahedra,  a cornercorner with one O(23)LiLa4Co octahedra,  a cornercorner with one O(25)LiLa4Co octahedra,  a cornercorner with one O(27)LiLa4Co octahedra,  a cornercorner with one O(28)LiLa4Co octahedra,  a cornercorner with one O(29)LiLa4Co octahedra,  a cornercorner with one O(31)LiLa4Co octahedra,  a cornercorner with one O(32)LiLa4Co octahedra,  a cornercorner with one O(3)LiLa5 octahedra,  a cornercorner with one O(6)LiLa5 octahedra,  a cornercorner with one O(7)LiLa5 octahedra, corners with two equivalent O(5)LiLa5 octahedra,  an edgeedge with one O(13)La5Co octahedra,  an edgeedge with one O(14)La5Co octahedra, edges with two equivalent O(10)La5Co octahedra, edges with two equivalent O(9)La5Co octahedra, edges with two equivalent O(2)LiLa5 octahedra,  a faceface with one O(18)LiLa4Co octahedra,  a faceface with one O(22)LiLa4Co octahedra,  a faceface with one O(28)LiLa4Co octahedra, and  a faceface with one O(32)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 1-51°. In the sixth O site, O(6) is bonded to one Li(1), one La(12), one La(2), one La(4), and two equivalent La(14) atoms to form distorted OLiLa5 octahedra that share  a cornercorner with one O(17)LiLa4Co octahedra,  a cornercorner with one O(18)LiLa4Co octahedra,  a cornercorner with one O(20)LiLa4Co octahedra,  a cornercorner with one O(21)LiLa4Co octahedra,  a cornercorner with one O(22)LiLa4Co octahedra,  a cornercorner with one O(24)LiLa4Co octahedra,  a cornercorner with one O(25)LiLa4Co octahedra,  a cornercorner with one O(26)LiLa4Co octahedra,  a cornercorner with one O(27)LiLa4Co octahedra,  a cornercorner with one O(29)LiLa4Co octahedra,  a cornercorner with one O(30)LiLa4Co octahedra,  a cornercorner with one O(31)LiLa4Co octahedra,  a cornercorner with one O(1)LiLa5 octahedra,  a cornercorner with one O(5)LiLa5 octahedra,  a cornercorner with one O(8)LiLa5 octahedra, corners with two equivalent O(6)LiLa5 octahedra,  an edgeedge with one O(14)La5Co octahedra,  an edgeedge with one O(16)La5Co octahedra, edges with two equivalent O(10)La5Co octahedra, edges with two equivalent O(12)La5Co octahedra, edges with two equivalent O(4)LiLa5 octahedra,  a faceface with one O(20)LiLa4Co octahedra,  a faceface with one O(24)LiLa4Co octahedra,  a faceface with one O(27)LiLa4Co octahedra, and  a faceface with one O(31)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 1-51°. In the seventh O site, O(7) is bonded to one Li(4), one La(1), one La(3), one La(9), and two equivalent La(15) atoms to form distorted OLiLa5 octahedra that share  a cornercorner with one O(17)LiLa4Co octahedra,  a cornercorner with one O(19)LiLa4Co octahedra,  a cornercorner with one O(20)LiLa4Co octahedra,  a cornercorner with one O(21)LiLa4Co octahedra,  a cornercorner with one O(23)LiLa4Co octahedra,  a cornercorner with one O(24)LiLa4Co octahedra,  a cornercorner with one O(26)LiLa4Co octahedra,  a cornercorner with one O(27)LiLa4Co octahedra,  a cornercorner with one O(28)LiLa4Co octahedra,  a cornercorner with one O(30)LiLa4Co octahedra,  a cornercorner with one O(31)LiLa4Co octahedra,  a cornercorner with one O(32)LiLa4Co octahedra,  a cornercorner with one O(4)LiLa5 octahedra,  a cornercorner with one O(5)LiLa5 octahedra,  a cornercorner with one O(8)LiLa5 octahedra, corners with two equivalent O(7)LiLa5 octahedra,  an edgeedge with one O(13)La5Co octahedra,  an edgeedge with one O(15)La5Co octahedra, edges with two equivalent O(11)La5Co octahedra, edges with two equivalent O(9)La5Co octahedra, edges with two equivalent O(1)LiLa5 octahedra,  a faceface with one O(17)LiLa4Co octahedra,  a faceface with one O(21)LiLa4Co octahedra,  a faceface with one O(26)LiLa4Co octahedra, and  a faceface with one O(30)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-50°. In the eighth O site, O(8) is bonded to one Li(2), one La(11), one La(3), one La(4), and two equivalent La(16) atoms to form distorted OLiLa5 octahedra that share  a cornercorner with one O(18)LiLa4Co octahedra,  a cornercorner with one O(19)LiLa4Co octahedra,  a cornercorner with one O(20)LiLa4Co octahedra,  a cornercorner with one O(22)LiLa4Co octahedra,  a cornercorner with one O(23)LiLa4Co octahedra,  a cornercorner with one O(24)LiLa4Co octahedra,  a cornercorner with one O(25)LiLa4Co octahedra,  a cornercorner with one O(26)LiLa4Co octahedra,  a cornercorner with one O(28)LiLa4Co octahedra,  a cornercorner with one O(29)LiLa4Co octahedra,  a cornercorner with one O(30)LiLa4Co octahedra,  a cornercorner with one O(32)LiLa4Co octahedra,  a cornercorner with one O(2)LiLa5 octahedra,  a cornercorner with one O(6)LiLa5 octahedra,  a cornercorner with one O(7)LiLa5 octahedra, corners with two equivalent O(8)LiLa5 octahedra,  an edgeedge with one O(15)La5Co octahedra,  an edgeedge with one O(16)La5Co octahedra, edges with two equivalent O(11)La5Co octahedra, edges with two equivalent O(12)La5Co octahedra, edges with two equivalent O(3)LiLa5 octahedra,  a faceface with one O(19)LiLa4Co octahedra,  a faceface with one O(23)LiLa4Co octahedra,  a faceface with one O(25)LiLa4Co octahedra, and  a faceface with one O(29)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-51°. In the ninth O site, O(9) is bonded to one La(13), one La(15), one La(5), two equivalent La(1), and one Co(4) atom to form distorted OLa5Co octahedra that share  a cornercorner with one O(10)La5Co octahedra,  a cornercorner with one O(11)La5Co octahedra,  a cornercorner with one O(16)La5Co octahedra,  a cornercorner with one O(17)LiLa4Co octahedra,  a cornercorner with one O(18)LiLa4Co octahedra,  a cornercorner with one O(20)LiLa4Co octahedra,  a cornercorner with one O(21)LiLa4Co octahedra,  a cornercorner with one O(22)LiLa4Co octahedra,  a cornercorner with one O(24)LiLa4Co octahedra,  a cornercorner with one O(25)LiLa4Co octahedra,  a cornercorner with one O(26)LiLa4Co octahedra,  a cornercorner with one O(28)LiLa4Co octahedra,  a cornercorner with one O(29)LiLa4Co octahedra,  a cornercorner with one O(30)LiLa4Co octahedra,  a cornercorner with one O(32)LiLa4Co octahedra, corners with two equivalent O(9)La5Co octahedra,  an edgeedge with one O(1)LiLa5 octahedra,  an edgeedge with one O(2)LiLa5 octahedra, edges with two equivalent O(13)La5Co octahedra, edges with two equivalent O(5)LiLa5 octahedra, edges with two equivalent O(7)LiLa5 octahedra,  a faceface with one O(17)LiLa4Co octahedra,  a faceface with one O(21)LiLa4Co octahedra,  a faceface with one O(28)LiLa4Co octahedra, and  a faceface with one O(32)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-50°. In the tenth O site, O(10) is bonded to one La(13), one La(14), one La(6), two equivalent La(2), and one Co(2) atom to form distorted OLa5Co octahedra that share  a cornercorner with one O(12)La5Co octahedra,  a cornercorner with one O(15)La5Co octahedra,  a cornercorner with one O(9)La5Co octahedra,  a cornercorner with one O(18)LiLa4Co octahedra,  a cornercorner with one O(19)LiLa4Co octahedra,  a cornercorner with one O(20)LiLa4Co octahedra,  a cornercorner with one O(22)LiLa4Co octahedra,  a cornercorner with one O(23)LiLa4Co octahedra,  a cornercorner with one O(24)LiLa4Co octahedra,  a cornercorner with one O(26)LiLa4Co octahedra,  a cornercorner with one O(27)LiLa4Co octahedra,  a cornercorner with one O(28)LiLa4Co octahedra,  a cornercorner with one O(30)LiLa4Co octahedra,  a cornercorner with one O(31)LiLa4Co octahedra,  a cornercorner with one O(32)LiLa4Co octahedra, corners with two equivalent O(10)La5Co octahedra,  an edgeedge with one O(2)LiLa5 octahedra,  an edgeedge with one O(4)LiLa5 octahedra, edges with two equivalent O(14)La5Co octahedra, edges with two equivalent O(5)LiLa5 octahedra, edges with two equivalent O(6)LiLa5 octahedra,  a faceface with one O(18)LiLa4Co octahedra,  a faceface with one O(22)LiLa4Co octahedra,  a faceface with one O(27)LiLa4Co octahedra, and  a faceface with one O(31)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-50°. In the eleventh O site, O(11) is bonded to one La(15), one La(16), one La(7), two equivalent La(3), and one Co(3) atom to form distorted OLa5Co octahedra that share  a cornercorner with one O(12)La5Co octahedra,  a cornercorner with one O(14)La5Co octahedra,  a cornercorner with one O(9)La5Co octahedra,  a cornercorner with one O(17)LiLa4Co octahedra,  a cornercorner with one O(18)LiLa4Co octahedra,  a cornercorner with one O(19)LiLa4Co octahedra,  a cornercorner with one O(21)LiLa4Co octahedra,  a cornercorner with one O(22)LiLa4Co octahedra,  a cornercorner with one O(23)LiLa4Co octahedra,  a cornercorner with one O(25)LiLa4Co octahedra,  a cornercorner with one O(26)LiLa4Co octahedra,  a cornercorner with one O(27)LiLa4Co octahedra,  a cornercorner with one O(29)LiLa4Co octahedra,  a cornercorner with one O(30)LiLa4Co octahedra,  a cornercorner with one O(31)LiLa4Co octahedra, corners with two equivalent O(11)La5Co octahedra,  an edgeedge with one O(1)LiLa5 octahedra,  an edgeedge with one O(3)LiLa5 octahedra, edges with two equivalent O(15)La5Co octahedra, edges with two equivalent O(7)LiLa5 octahedra, edges with two equivalent O(8)LiLa5 octahedra,  a faceface with one O(19)LiLa4Co octahedra,  a faceface with one O(23)LiLa4Co octahedra,  a faceface with one O(26)LiLa4Co octahedra, and  a faceface with one O(30)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-51°. In the twelfth O site, O(12) is bonded to one La(14), one La(16), one La(8), two equivalent La(4), and one Co(1) atom to form distorted OLa5Co octahedra that share  a cornercorner with one O(10)La5Co octahedra,  a cornercorner with one O(11)La5Co octahedra,  a cornercorner with one O(13)La5Co octahedra,  a cornercorner with one O(17)LiLa4Co octahedra,  a cornercorner with one O(19)LiLa4Co octahedra,  a cornercorner with one O(20)LiLa4Co octahedra,  a cornercorner with one O(21)LiLa4Co octahedra,  a cornercorner with one O(23)LiLa4Co octahedra,  a cornercorner with one O(24)LiLa4Co octahedra,  a cornercorner with one O(25)LiLa4Co octahedra,  a cornercorner with one O(27)LiLa4Co octahedra,  a cornercorner with one O(28)LiLa4Co octahedra,  a cornercorner with one O(29)LiLa4Co octahedra,  a cornercorner with one O(31)LiLa4Co octahedra,  a cornercorner with one O(32)LiLa4Co octahedra, corners with two equivalent O(12)La5Co octahedra,  an edgeedge with one O(3)LiLa5 octahedra,  an edgeedge with one O(4)LiLa5 octahedra, edges with two equivalent O(16)La5Co octahedra, edges with two equivalent O(6)LiLa5 octahedra, edges with two equivalent O(8)LiLa5 octahedra,  a faceface with one O(20)LiLa4Co octahedra,  a faceface with one O(24)LiLa4Co octahedra,  a faceface with one O(25)LiLa4Co octahedra, and  a faceface with one O(29)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-50°. In the thirteenth O site, O(13) is bonded to one La(1), one La(10), one La(9), two equivalent La(5), and one Co(1) atom to form distorted OLa5Co octahedra that share  a cornercorner with one O(12)La5Co octahedra,  a cornercorner with one O(14)La5Co octahedra,  a cornercorner with one O(15)La5Co octahedra,  a cornercorner with one O(17)LiLa4Co octahedra,  a cornercorner with one O(19)LiLa4Co octahedra,  a cornercorner with one O(20)LiLa4Co octahedra,  a cornercorner with one O(21)LiLa4Co octahedra,  a cornercorner with one O(23)LiLa4Co octahedra,  a cornercorner with one O(24)LiLa4Co octahedra,  a cornercorner with one O(25)LiLa4Co octahedra,  a cornercorner with one O(27)LiLa4Co octahedra,  a cornercorner with one O(28)LiLa4Co octahedra,  a cornercorner with one O(29)LiLa4Co octahedra,  a cornercorner with one O(31)LiLa4Co octahedra,  a cornercorner with one O(32)LiLa4Co octahedra, corners with two equivalent O(13)La5Co octahedra,  an edgeedge with one O(5)LiLa5 octahedra,  an edgeedge with one O(7)LiLa5 octahedra, edges with two equivalent O(9)La5Co octahedra, edges with two equivalent O(1)LiLa5 octahedra, edges with two equivalent O(2)LiLa5 octahedra,  a faceface with one O(20)LiLa4Co octahedra,  a faceface with one O(24)LiLa4Co octahedra,  a faceface with one O(25)LiLa4Co octahedra, and  a faceface with one O(29)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-50°. In the fourteenth O site, O(14) is bonded to one La(10), one La(12), one La(2), two equivalent La(6), and one Co(3) atom to form distorted OLa5Co octahedra that share  a cornercorner with one O(11)La5Co octahedra,  a cornercorner with one O(13)La5Co octahedra,  a cornercorner with one O(16)La5Co octahedra,  a cornercorner with one O(17)LiLa4Co octahedra,  a cornercorner with one O(18)LiLa4Co octahedra,  a cornercorner with one O(19)LiLa4Co octahedra,  a cornercorner with one O(21)LiLa4Co octahedra,  a cornercorner with one O(22)LiLa4Co octahedra,  a cornercorner with one O(23)LiLa4Co octahedra,  a cornercorner with one O(25)LiLa4Co octahedra,  a cornercorner with one O(26)LiLa4Co octahedra,  a cornercorner with one O(27)LiLa4Co octahedra,  a cornercorner with one O(29)LiLa4Co octahedra,  a cornercorner with one O(30)LiLa4Co octahedra,  a cornercorner with one O(31)LiLa4Co octahedra, corners with two equivalent O(14)La5Co octahedra,  an edgeedge with one O(5)LiLa5 octahedra,  an edgeedge with one O(6)LiLa5 octahedra, edges with two equivalent O(10)La5Co octahedra, edges with two equivalent O(2)LiLa5 octahedra, edges with two equivalent O(4)LiLa5 octahedra,  a faceface with one O(19)LiLa4Co octahedra,  a faceface with one O(23)LiLa4Co octahedra,  a faceface with one O(26)LiLa4Co octahedra, and  a faceface with one O(30)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-51°. In the fifteenth O site, O(15) is bonded to one La(11), one La(3), one La(9), two equivalent La(7), and one Co(2) atom to form distorted OLa5Co octahedra that share  a cornercorner with one O(10)La5Co octahedra,  a cornercorner with one O(13)La5Co octahedra,  a cornercorner with one O(16)La5Co octahedra,  a cornercorner with one O(18)LiLa4Co octahedra,  a cornercorner with one O(19)LiLa4Co octahedra,  a cornercorner with one O(20)LiLa4Co octahedra,  a cornercorner with one O(22)LiLa4Co octahedra,  a cornercorner with one O(23)LiLa4Co octahedra,  a cornercorner with one O(24)LiLa4Co octahedra,  a cornercorner with one O(26)LiLa4Co octahedra,  a cornercorner with one O(27)LiLa4Co octahedra,  a cornercorner with one O(28)LiLa4Co octahedra,  a cornercorner with one O(30)LiLa4Co octahedra,  a cornercorner with one O(31)LiLa4Co octahedra,  a cornercorner with one O(32)LiLa4Co octahedra, corners with two equivalent O(15)La5Co octahedra,  an edgeedge with one O(7)LiLa5 octahedra,  an edgeedge with one O(8)LiLa5 octahedra, edges with two equivalent O(11)La5Co octahedra, edges with two equivalent O(1)LiLa5 octahedra, edges with two equivalent O(3)LiLa5 octahedra,  a faceface with one O(18)LiLa4Co octahedra,  a faceface with one O(22)LiLa4Co octahedra,  a faceface with one O(27)LiLa4Co octahedra, and  a faceface with one O(31)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-50°. In the sixteenth O site, O(16) is bonded to one La(11), one La(12), one La(4), two equivalent La(8), and one Co(4) atom to form distorted OLa5Co octahedra that share  a cornercorner with one O(14)La5Co octahedra,  a cornercorner with one O(15)La5Co octahedra,  a cornercorner with one O(9)La5Co octahedra,  a cornercorner with one O(17)LiLa4Co octahedra,  a cornercorner with one O(18)LiLa4Co octahedra,  a cornercorner with one O(20)LiLa4Co octahedra,  a cornercorner with one O(21)LiLa4Co octahedra,  a cornercorner with one O(22)LiLa4Co octahedra,  a cornercorner with one O(24)LiLa4Co octahedra,  a cornercorner with one O(25)LiLa4Co octahedra,  a cornercorner with one O(26)LiLa4Co octahedra,  a cornercorner with one O(28)LiLa4Co octahedra,  a cornercorner with one O(29)LiLa4Co octahedra,  a cornercorner with one O(30)LiLa4Co octahedra,  a cornercorner with one O(32)LiLa4Co octahedra, corners with two equivalent O(16)La5Co octahedra,  an edgeedge with one O(6)LiLa5 octahedra,  an edgeedge with one O(8)LiLa5 octahedra, edges with two equivalent O(12)La5Co octahedra, edges with two equivalent O(3)LiLa5 octahedra, edges with two equivalent O(4)LiLa5 octahedra,  a faceface with one O(17)LiLa4Co octahedra,  a faceface with one O(21)LiLa4Co octahedra,  a faceface with one O(28)LiLa4Co octahedra, and  a faceface with one O(32)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-50°. In the seventeenth O site, O(17) is bonded to one Li(4), one La(1), one La(12), one La(15), one La(8), and one Co(4) atom to form distorted OLiLa4Co octahedra that share  a cornercorner with one O(11)La5Co octahedra,  a cornercorner with one O(12)La5Co octahedra,  a cornercorner with one O(13)La5Co octahedra,  a cornercorner with one O(14)La5Co octahedra,  a cornercorner with one O(16)La5Co octahedra,  a cornercorner with one O(9)La5Co octahedra,  a cornercorner with one O(26)LiLa4Co octahedra,  a cornercorner with one O(28)LiLa4Co octahedra,  a cornercorner with one O(1)LiLa5 octahedra,  a cornercorner with one O(3)LiLa5 octahedra,  a cornercorner with one O(4)LiLa5 octahedra,  a cornercorner with one O(5)LiLa5 octahedra,  a cornercorner with one O(6)LiLa5 octahedra,  a cornercorner with one O(7)LiLa5 octahedra,  an edgeedge with one O(26)LiLa4Co octahedra,  an edgeedge with one O(28)LiLa4Co octahedra,  a faceface with one O(16)La5Co octahedra,  a faceface with one O(9)La5Co octahedra,  a faceface with one O(30)LiLa4Co octahedra,  a faceface with one O(32)LiLa4Co octahedra,  a faceface with one O(4)LiLa5 octahedra,  a faceface with one O(7)LiLa5 octahedra, and faces with two equivalent O(21)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-51°. In the eighteenth O site, O(18) is bonded to one Li(3), one La(11), one La(13), one La(2), one La(7), and one Co(2) atom to form distorted OLiLa4Co octahedra that share  a cornercorner with one O(10)La5Co octahedra,  a cornercorner with one O(11)La5Co octahedra,  a cornercorner with one O(14)La5Co octahedra,  a cornercorner with one O(15)La5Co octahedra,  a cornercorner with one O(16)La5Co octahedra,  a cornercorner with one O(9)La5Co octahedra,  a cornercorner with one O(27)LiLa4Co octahedra,  a cornercorner with one O(28)LiLa4Co octahedra,  a cornercorner with one O(1)LiLa5 octahedra,  a cornercorner with one O(2)LiLa5 octahedra,  a cornercorner with one O(3)LiLa5 octahedra,  a cornercorner with one O(5)LiLa5 octahedra,  a cornercorner with one O(6)LiLa5 octahedra,  a cornercorner with one O(8)LiLa5 octahedra,  an edgeedge with one O(27)LiLa4Co octahedra,  an edgeedge with one O(28)LiLa4Co octahedra,  a faceface with one O(10)La5Co octahedra,  a faceface with one O(15)La5Co octahedra,  a faceface with one O(31)LiLa4Co octahedra,  a faceface with one O(32)LiLa4Co octahedra,  a faceface with one O(3)LiLa5 octahedra,  a faceface with one O(5)LiLa5 octahedra, and faces with two equivalent O(22)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-51°. In the nineteenth O site, O(19) is bonded to one Li(2), one La(10), one La(16), one La(3), one La(6), and one Co(3) atom to form distorted OLiLa4Co octahedra that share  a cornercorner with one O(10)La5Co octahedra,  a cornercorner with one O(11)La5Co octahedra,  a cornercorner with one O(12)La5Co octahedra,  a cornercorner with one O(13)La5Co octahedra,  a cornercorner with one O(14)La5Co octahedra,  a cornercorner with one O(15)La5Co octahedra,  a cornercorner with one O(25)LiLa4Co octahedra,  a cornercorner with one O(26)LiLa4Co octahedra,  a cornercorner with one O(2)LiLa5 octahedra,  a cornercorner with one O(3)LiLa5 octahedra,  a cornercorner with one O(4)LiLa5 octahedra,  a cornercorner with one O(5)LiLa5 octahedra,  a cornercorner with one O(7)LiLa5 octahedra,  a cornercorner with one O(8)LiLa5 octahedra,  an edgeedge with one O(25)LiLa4Co octahedra,  an edgeedge with one O(26)LiLa4Co octahedra,  a faceface with one O(11)La5Co octahedra,  a faceface with one O(14)La5Co octahedra,  a faceface with one O(29)LiLa4Co octahedra,  a faceface with one O(30)LiLa4Co octahedra,  a faceface with one O(2)LiLa5 octahedra,  a faceface with one O(8)LiLa5 octahedra, and faces with two equivalent O(23)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-51°. In the twentieth O site, O(20) is bonded to one Li(1), one La(14), one La(4), one La(5), one La(9), and one Co(1) atom to form distorted OLiLa4Co octahedra that share  a cornercorner with one O(10)La5Co octahedra,  a cornercorner with one O(12)La5Co octahedra,  a cornercorner with one O(13)La5Co octahedra,  a cornercorner with one O(15)La5Co octahedra,  a cornercorner with one O(16)La5Co octahedra,  a cornercorner with one O(9)La5Co octahedra,  a cornercorner with one O(25)LiLa4Co octahedra,  a cornercorner with one O(27)LiLa4Co octahedra,  a cornercorner with one O(1)LiLa5 octahedra,  a cornercorner with one O(2)LiLa5 octahedra,  a cornercorner with one O(4)LiLa5 octahedra,  a cornercorner with one O(6)LiLa5 octahedra,  a cornercorner with one O(7)LiLa5 octahedra,  a cornercorner with one O(8)LiLa5 octahedra,  an edgeedge with one O(25)LiLa4Co octahedra,  an edgeedge with one O(27)LiLa4Co octahedra,  a faceface with one O(12)La5Co octahedra,  a faceface with one O(13)La5Co octahedra,  a faceface with one O(29)LiLa4Co octahedra,  a faceface with one O(31)LiLa4Co octahedra,  a faceface with one O(1)LiLa5 octahedra,  a faceface with one O(6)LiLa5 octahedra, and faces with two equivalent O(24)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-51°. In the twenty-first O site, O(21) is bonded to one Li(4), one La(1), one La(12), one La(15), one La(8), and one Co(4) atom to form distorted OLiLa4Co octahedra that share  a cornercorner with one O(11)La5Co octahedra,  a cornercorner with one O(12)La5Co octahedra,  a cornercorner with one O(13)La5Co octahedra,  a cornercorner with one O(14)La5Co octahedra,  a cornercorner with one O(16)La5Co octahedra,  a cornercorner with one O(9)La5Co octahedra,  a cornercorner with one O(30)LiLa4Co octahedra,  a cornercorner with one O(32)LiLa4Co octahedra,  a cornercorner with one O(1)LiLa5 octahedra,  a cornercorner with one O(3)LiLa5 octahedra,  a cornercorner with one O(4)LiLa5 octahedra,  a cornercorner with one O(5)LiLa5 octahedra,  a cornercorner with one O(6)LiLa5 octahedra,  a cornercorner with one O(7)LiLa5 octahedra,  an edgeedge with one O(30)LiLa4Co octahedra,  an edgeedge with one O(32)LiLa4Co octahedra,  a faceface with one O(16)La5Co octahedra,  a faceface with one O(9)La5Co octahedra,  a faceface with one O(26)LiLa4Co octahedra,  a faceface with one O(28)LiLa4Co octahedra,  a faceface with one O(4)LiLa5 octahedra,  a faceface with one O(7)LiLa5 octahedra, and faces with two equivalent O(17)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-51°. In the twenty-second O site, O(22) is bonded to one Li(3), one La(11), one La(13), one La(2), one La(7), and one Co(2) atom to form distorted OLiLa4Co octahedra that share  a cornercorner with one O(10)La5Co octahedra,  a cornercorner with one O(11)La5Co octahedra,  a cornercorner with one O(14)La5Co octahedra,  a cornercorner with one O(15)La5Co octahedra,  a cornercorner with one O(16)La5Co octahedra,  a cornercorner with one O(9)La5Co octahedra,  a cornercorner with one O(31)LiLa4Co octahedra,  a cornercorner with one O(32)LiLa4Co octahedra,  a cornercorner with one O(1)LiLa5 octahedra,  a cornercorner with one O(2)LiLa5 octahedra,  a cornercorner with one O(3)LiLa5 octahedra,  a cornercorner with one O(5)LiLa5 octahedra,  a cornercorner with one O(6)LiLa5 octahedra,  a cornercorner with one O(8)LiLa5 octahedra,  an edgeedge with one O(31)LiLa4Co octahedra,  an edgeedge with one O(32)LiLa4Co octahedra,  a faceface with one O(10)La5Co octahedra,  a faceface with one O(15)La5Co octahedra,  a faceface with one O(27)LiLa4Co octahedra,  a faceface with one O(28)LiLa4Co octahedra,  a faceface with one O(3)LiLa5 octahedra,  a faceface with one O(5)LiLa5 octahedra, and faces with two equivalent O(18)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-51°. In the twenty-third O site, O(23) is bonded to one Li(2), one La(10), one La(16), one La(3), one La(6), and one Co(3) atom to form distorted OLiLa4Co octahedra that share  a cornercorner with one O(10)La5Co octahedra,  a cornercorner with one O(11)La5Co octahedra,  a cornercorner with one O(12)La5Co octahedra,  a cornercorner with one O(13)La5Co octahedra,  a cornercorner with one O(14)La5Co octahedra,  a cornercorner with one O(15)La5Co octahedra,  a cornercorner with one O(29)LiLa4Co octahedra,  a cornercorner with one O(30)LiLa4Co octahedra,  a cornercorner with one O(2)LiLa5 octahedra,  a cornercorner with one O(3)LiLa5 octahedra,  a cornercorner with one O(4)LiLa5 octahedra,  a cornercorner with one O(5)LiLa5 octahedra,  a cornercorner with one O(7)LiLa5 octahedra,  a cornercorner with one O(8)LiLa5 octahedra,  an edgeedge with one O(29)LiLa4Co octahedra,  an edgeedge with one O(30)LiLa4Co octahedra,  a faceface with one O(11)La5Co octahedra,  a faceface with one O(14)La5Co octahedra,  a faceface with one O(25)LiLa4Co octahedra,  a faceface with one O(26)LiLa4Co octahedra,  a faceface with one O(2)LiLa5 octahedra,  a faceface with one O(8)LiLa5 octahedra, and faces with two equivalent O(19)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-50°. In the twenty-fourth O site, O(24) is bonded to one Li(1), one La(14), one La(4), one La(5), one La(9), and one Co(1) atom to form distorted OLiLa4Co octahedra that share  a cornercorner with one O(10)La5Co octahedra,  a cornercorner with one O(12)La5Co octahedra,  a cornercorner with one O(13)La5Co octahedra,  a cornercorner with one O(15)La5Co octahedra,  a cornercorner with one O(16)La5Co octahedra,  a cornercorner with one O(9)La5Co octahedra,  a cornercorner with one O(29)LiLa4Co octahedra,  a cornercorner with one O(31)LiLa4Co octahedra,  a cornercorner with one O(1)LiLa5 octahedra,  a cornercorner with one O(2)LiLa5 octahedra,  a cornercorner with one O(4)LiLa5 octahedra,  a cornercorner with one O(6)LiLa5 octahedra,  a cornercorner with one O(7)LiLa5 octahedra,  a cornercorner with one O(8)LiLa5 octahedra,  an edgeedge with one O(29)LiLa4Co octahedra,  an edgeedge with one O(31)LiLa4Co octahedra,  a faceface with one O(12)La5Co octahedra,  a faceface with one O(13)La5Co octahedra,  a faceface with one O(25)LiLa4Co octahedra,  a faceface with one O(27)LiLa4Co octahedra,  a faceface with one O(1)LiLa5 octahedra,  a faceface with one O(6)LiLa5 octahedra, and faces with two equivalent O(20)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-50°. In the twenty-fifth O site, O(25) is bonded to one Li(2), one La(10), one La(16), one La(4), one La(5), and one Co(1) atom to form distorted OLiLa4Co octahedra that share  a cornercorner with one O(11)La5Co octahedra,  a cornercorner with one O(12)La5Co octahedra,  a cornercorner with one O(13)La5Co octahedra,  a cornercorner with one O(14)La5Co octahedra,  a cornercorner with one O(16)La5Co octahedra,  a cornercorner with one O(9)La5Co octahedra,  a cornercorner with one O(19)LiLa4Co octahedra,  a cornercorner with one O(20)LiLa4Co octahedra,  a cornercorner with one O(1)LiLa5 octahedra,  a cornercorner with one O(2)LiLa5 octahedra,  a cornercorner with one O(3)LiLa5 octahedra,  a cornercorner with one O(5)LiLa5 octahedra,  a cornercorner with one O(6)LiLa5 octahedra,  a cornercorner with one O(8)LiLa5 octahedra,  an edgeedge with one O(19)LiLa4Co octahedra,  an edgeedge with one O(20)LiLa4Co octahedra,  a faceface with one O(12)La5Co octahedra,  a faceface with one O(13)La5Co octahedra,  a faceface with one O(23)LiLa4Co octahedra,  a faceface with one O(24)LiLa4Co octahedra,  a faceface with one O(2)LiLa5 octahedra,  a faceface with one O(8)LiLa5 octahedra, and faces with two equivalent O(29)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-51°. In the twenty-sixth O site, O(26) is bonded to one Li(4), one La(12), one La(15), one La(3), one La(6), and one Co(3) atom to form distorted OLiLa4Co octahedra that share  a cornercorner with one O(10)La5Co octahedra,  a cornercorner with one O(11)La5Co octahedra,  a cornercorner with one O(14)La5Co octahedra,  a cornercorner with one O(15)La5Co octahedra,  a cornercorner with one O(16)La5Co octahedra,  a cornercorner with one O(9)La5Co octahedra,  a cornercorner with one O(17)LiLa4Co octahedra,  a cornercorner with one O(19)LiLa4Co octahedra,  a cornercorner with one O(1)LiLa5 octahedra,  a cornercorner with one O(2)LiLa5 octahedra,  a cornercorner with one O(4)LiLa5 octahedra,  a cornercorner with one O(6)LiLa5 octahedra,  a cornercorner with one O(7)LiLa5 octahedra,  a cornercorner with one O(8)LiLa5 octahedra,  an edgeedge with one O(17)LiLa4Co octahedra,  an edgeedge with one O(19)LiLa4Co octahedra,  a faceface with one O(11)La5Co octahedra,  a faceface with one O(14)La5Co octahedra,  a faceface with one O(21)LiLa4Co octahedra,  a faceface with one O(23)LiLa4Co octahedra,  a faceface with one O(4)LiLa5 octahedra,  a faceface with one O(7)LiLa5 octahedra, and faces with two equivalent O(30)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-51°. In the twenty-seventh O site, O(27) is bonded to one Li(1), one La(14), one La(2), one La(7), one La(9), and one Co(2) atom to form distorted OLiLa4Co octahedra that share  a cornercorner with one O(10)La5Co octahedra,  a cornercorner with one O(11)La5Co octahedra,  a cornercorner with one O(12)La5Co octahedra,  a cornercorner with one O(13)La5Co octahedra,  a cornercorner with one O(14)La5Co octahedra,  a cornercorner with one O(15)La5Co octahedra,  a cornercorner with one O(18)LiLa4Co octahedra,  a cornercorner with one O(20)LiLa4Co octahedra,  a cornercorner with one O(1)LiLa5 octahedra,  a cornercorner with one O(3)LiLa5 octahedra,  a cornercorner with one O(4)LiLa5 octahedra,  a cornercorner with one O(5)LiLa5 octahedra,  a cornercorner with one O(6)LiLa5 octahedra,  a cornercorner with one O(7)LiLa5 octahedra,  an edgeedge with one O(18)LiLa4Co octahedra,  an edgeedge with one O(20)LiLa4Co octahedra,  a faceface with one O(10)La5Co octahedra,  a faceface with one O(15)La5Co octahedra,  a faceface with one O(22)LiLa4Co octahedra,  a faceface with one O(24)LiLa4Co octahedra,  a faceface with one O(1)LiLa5 octahedra,  a faceface with one O(6)LiLa5 octahedra, and faces with two equivalent O(31)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-51°. In the twenty-eighth O site, O(28) is bonded to one Li(3), one La(1), one La(11), one La(13), one La(8), and one Co(4) atom to form distorted OLiLa4Co octahedra that share  a cornercorner with one O(10)La5Co octahedra,  a cornercorner with one O(12)La5Co octahedra,  a cornercorner with one O(13)La5Co octahedra,  a cornercorner with one O(15)La5Co octahedra,  a cornercorner with one O(16)La5Co octahedra,  a cornercorner with one O(9)La5Co octahedra,  a cornercorner with one O(17)LiLa4Co octahedra,  a cornercorner with one O(18)LiLa4Co octahedra,  a cornercorner with one O(2)LiLa5 octahedra,  a cornercorner with one O(3)LiLa5 octahedra,  a cornercorner with one O(4)LiLa5 octahedra,  a cornercorner with one O(5)LiLa5 octahedra,  a cornercorner with one O(7)LiLa5 octahedra,  a cornercorner with one O(8)LiLa5 octahedra,  an edgeedge with one O(17)LiLa4Co octahedra,  an edgeedge with one O(18)LiLa4Co octahedra,  a faceface with one O(16)La5Co octahedra,  a faceface with one O(9)La5Co octahedra,  a faceface with one O(21)LiLa4Co octahedra,  a faceface with one O(22)LiLa4Co octahedra,  a faceface with one O(3)LiLa5 octahedra,  a faceface with one O(5)LiLa5 octahedra, and faces with two equivalent O(32)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-51°. In the twenty-ninth O site, O(29) is bonded to one Li(2), one La(10), one La(16), one La(4), one La(5), and one Co(1) atom to form distorted OLiLa4Co octahedra that share  a cornercorner with one O(11)La5Co octahedra,  a cornercorner with one O(12)La5Co octahedra,  a cornercorner with one O(13)La5Co octahedra,  a cornercorner with one O(14)La5Co octahedra,  a cornercorner with one O(16)La5Co octahedra,  a cornercorner with one O(9)La5Co octahedra,  a cornercorner with one O(23)LiLa4Co octahedra,  a cornercorner with one O(24)LiLa4Co octahedra,  a cornercorner with one O(1)LiLa5 octahedra,  a cornercorner with one O(2)LiLa5 octahedra,  a cornercorner with one O(3)LiLa5 octahedra,  a cornercorner with one O(5)LiLa5 octahedra,  a cornercorner with one O(6)LiLa5 octahedra,  a cornercorner with one O(8)LiLa5 octahedra,  an edgeedge with one O(23)LiLa4Co octahedra,  an edgeedge with one O(24)LiLa4Co octahedra,  a faceface with one O(12)La5Co octahedra,  a faceface with one O(13)La5Co octahedra,  a faceface with one O(19)LiLa4Co octahedra,  a faceface with one O(20)LiLa4Co octahedra,  a faceface with one O(2)LiLa5 octahedra,  a faceface with one O(8)LiLa5 octahedra, and faces with two equivalent O(25)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-51°. In the thirtieth O site, O(30) is bonded to one Li(4), one La(12), one La(15), one La(3), one La(6), and one Co(3) atom to form distorted OLiLa4Co octahedra that share  a cornercorner with one O(10)La5Co octahedra,  a cornercorner with one O(11)La5Co octahedra,  a cornercorner with one O(14)La5Co octahedra,  a cornercorner with one O(15)La5Co octahedra,  a cornercorner with one O(16)La5Co octahedra,  a cornercorner with one O(9)La5Co octahedra,  a cornercorner with one O(21)LiLa4Co octahedra,  a cornercorner with one O(23)LiLa4Co octahedra,  a cornercorner with one O(1)LiLa5 octahedra,  a cornercorner with one O(2)LiLa5 octahedra,  a cornercorner with one O(4)LiLa5 octahedra,  a cornercorner with one O(6)LiLa5 octahedra,  a cornercorner with one O(7)LiLa5 octahedra,  a cornercorner with one O(8)LiLa5 octahedra,  an edgeedge with one O(21)LiLa4Co octahedra,  an edgeedge with one O(23)LiLa4Co octahedra,  a faceface with one O(11)La5Co octahedra,  a faceface with one O(14)La5Co octahedra,  a faceface with one O(17)LiLa4Co octahedra,  a faceface with one O(19)LiLa4Co octahedra,  a faceface with one O(4)LiLa5 octahedra,  a faceface with one O(7)LiLa5 octahedra, and faces with two equivalent O(26)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-50°. In the thirty-first O site, O(31) is bonded to one Li(1), one La(14), one La(2), one La(7), one La(9), and one Co(2) atom to form distorted OLiLa4Co octahedra that share  a cornercorner with one O(10)La5Co octahedra,  a cornercorner with one O(11)La5Co octahedra,  a cornercorner with one O(12)La5Co octahedra,  a cornercorner with one O(13)La5Co octahedra,  a cornercorner with one O(14)La5Co octahedra,  a cornercorner with one O(15)La5Co octahedra,  a cornercorner with one O(22)LiLa4Co octahedra,  a cornercorner with one O(24)LiLa4Co octahedra,  a cornercorner with one O(1)LiLa5 octahedra,  a cornercorner with one O(3)LiLa5 octahedra,  a cornercorner with one O(4)LiLa5 octahedra,  a cornercorner with one O(5)LiLa5 octahedra,  a cornercorner with one O(6)LiLa5 octahedra,  a cornercorner with one O(7)LiLa5 octahedra,  an edgeedge with one O(22)LiLa4Co octahedra,  an edgeedge with one O(24)LiLa4Co octahedra,  a faceface with one O(10)La5Co octahedra,  a faceface with one O(15)La5Co octahedra,  a faceface with one O(18)LiLa4Co octahedra,  a faceface with one O(20)LiLa4Co octahedra,  a faceface with one O(1)LiLa5 octahedra,  a faceface with one O(6)LiLa5 octahedra, and faces with two equivalent O(27)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-51°. In the thirty-second O site, O(32) is bonded to one Li(3), one La(1), one La(11), one La(13), one La(8), and one Co(4) atom to form distorted OLiLa4Co octahedra that share  a cornercorner with one O(10)La5Co octahedra,  a cornercorner with one O(12)La5Co octahedra,  a cornercorner with one O(13)La5Co octahedra,  a cornercorner with one O(15)La5Co octahedra,  a cornercorner with one O(16)La5Co octahedra,  a cornercorner with one O(9)La5Co octahedra,  a cornercorner with one O(21)LiLa4Co octahedra,  a cornercorner with one O(22)LiLa4Co octahedra,  a cornercorner with one O(2)LiLa5 octahedra,  a cornercorner with one O(3)LiLa5 octahedra,  a cornercorner with one O(4)LiLa5 octahedra,  a cornercorner with one O(5)LiLa5 octahedra,  a cornercorner with one O(7)LiLa5 octahedra,  a cornercorner with one O(8)LiLa5 octahedra,  an edgeedge with one O(21)LiLa4Co octahedra,  an edgeedge with one O(22)LiLa4Co octahedra,  a faceface with one O(16)La5Co octahedra,  a faceface with one O(9)La5Co octahedra,  a faceface with one O(17)LiLa4Co octahedra,  a faceface with one O(18)LiLa4Co octahedra,  a faceface with one O(3)LiLa5 octahedra,  a faceface with one O(5)LiLa5 octahedra, and faces with two equivalent O(28)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-51°. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiLa4CoO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.369
_cell_length_b   5.373
_cell_length_c   6.980
_cell_angle_alpha   89.859
_cell_angle_beta   67.431
_cell_angle_gamma   89.673
_symmetry_Int_Tables_number   1
_cell_volume   185.938
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  1.000  0.500  0.000  1.0
  La  La1  1  0.362  0.500  0.274  1.0
  La  La2  1  0.638  0.500  0.726  1.0
  La  La3  1  0.138  0.999  0.724  1.0
  La  La4  1  0.862  0.001  0.276  1.0
  Li  Li5  1  0.500  1.000  0.000  1.0
  O  O6  1  0.681  1.000  0.637  1.0
  O  O7  1  0.319  1.000  0.363  1.0
  O  O8  1  0.822  0.499  0.357  1.0
  O  O9  1  0.178  0.501  0.643  1.0
  O  O10  1  0.752  0.254  0.000  1.0
  O  O11  1  0.246  0.256  1.000  1.0
  O  O12  1  0.248  0.746  1.000  1.0
  O  O13  1  0.754  0.744  0.000  1.0
[/CIF]
.
The compound described by LiLa4CoO8 is (La,Ba)CuO4-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(20), one O(24), one O(27), one O(31), and one O(6) atom to form LiO6 octahedra that share corners with two equivalent Co(1)O6 octahedra and corners with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the second Li site, Li(2) is bonded to one O(19), one O(2), one O(23), one O(25), one O(29), and one O(8) atom to form LiO6 octahedra that share corners with two equivalent Co(1)O6 octahedra and corners with two equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the third Li site, Li(3) is bonded to one O(18), one O(22), one O(28), one O(3), one O(32), and one O(5) atom to form LiO6 octahedra that share corners with two equivalent Co(2)O6 octahedra and corners with two equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the fourth Li site, Li(4) is bonded to one O(17), one O(21), one O(26), one O(30), one O(4), and one O(7) atom to form LiO6 octahedra that share corners with two equivalent Co(3)O6 octahedra and corners with two equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. There are sixteen inequivalent La sites. In the first La site, La(1) is bonded in a 9-coordinate geometry to one O(13), one O(17), one O(21), one O(28), one O(32), one O(5), one O(7), and two equivalent O(9) atoms. In the second La site, La(2) is bonded in a 9-coordinate geometry to one O(14), one O(18), one O(22), one O(27), one O(31), one O(5), one O(6), and two equivalent O(10) atoms. In the third La site, La(3) is bonded in a 9-coordinate geometry to one O(15), one O(19), one O(23), one O(26), one O(30), one O(7), one O(8), and two equivalent O(11) atoms. In the fourth La site, La(4) is bonded in a 9-coordinate geometry to one O(16), one O(20), one O(24), one O(25), one O(29), one O(6), one O(8), and two equivalent O(12) atoms. In the fifth La site, La(5) is bonded in a 9-coordinate geometry to one O(1), one O(2), one O(20), one O(24), one O(25), one O(29), one O(9), and two equivalent O(13) atoms. In the sixth La site, La(6) is bonded in a 9-coordinate geometry to one O(10), one O(19), one O(2), one O(23), one O(26), one O(30), one O(4), and two equivalent O(14) atoms. In the seventh La site, La(7) is bonded in a 9-coordinate geometry to one O(1), one O(11), one O(18), one O(22), one O(27), one O(3), one O(31), and two equivalent O(15) atoms. In the eighth La site, La(8) is bonded in a 9-coordinate geometry to one O(12), one O(17), one O(21), one O(28), one O(3), one O(32), one O(4), and two equivalent O(16) atoms. In the ninth La site, La(9) is bonded in a 9-coordinate geometry to one O(13), one O(15), one O(20), one O(24), one O(27), one O(31), one O(7), and two equivalent O(1) atoms. In the tenth La site, La(10) is bonded in a 9-coordinate geometry to one O(13), one O(14), one O(19), one O(23), one O(25), one O(29), one O(5), and two equivalent O(2) atoms. In the eleventh La site, La(11) is bonded in a 9-coordinate geometry to one O(15), one O(16), one O(18), one O(22), one O(28), one O(32), one O(8), and two equivalent O(3) atoms. In the twelfth La site, La(12) is bonded in a 9-coordinate geometry to one O(14), one O(16), one O(17), one O(21), one O(26), one O(30), one O(6), and two equivalent O(4) atoms. In the thirteenth La site, La(13) is bonded in a 9-coordinate geometry to one O(10), one O(18), one O(2), one O(22), one O(28), one O(32), one O(9), and two equivalent O(5) atoms. In the fourteenth La site, La(14) is bonded in a 9-coordinate geometry to one O(10), one O(12), one O(20), one O(24), one O(27), one O(31), one O(4), and two equivalent O(6) atoms. In the fifteenth La site, La(15) is bonded in a 9-coordinate geometry to one O(1), one O(11), one O(17), one O(21), one O(26), one O(30), one O(9), and two equivalent O(7) atoms. In the sixteenth La site, La(16) is bonded in a 9-coordinate geometry to one O(11), one O(12), one O(19), one O(23), one O(25), one O(29), one O(3), and two equivalent O(8) atoms. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(12), one O(13), one O(20), one O(24), one O(25), and one O(29) atom to form CoO6 octahedra that share corners with two equivalent Li(1)O6 octahedra and corners with two equivalent Li(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the second Co site, Co(2) is bonded to one O(10), one O(15), one O(18), one O(22), one O(27), and one O(31) atom to form CoO6 octahedra that share corners with two equivalent Li(1)O6 octahedra and corners with two equivalent Li(3)O6 octahedra. The corner-sharing octahedral tilt angles are 1°. In the third Co site, Co(3) is bonded to one O(11), one O(14), one O(19), one O(23), one O(26), and one O(30) atom to form CoO6 octahedra that share corners with two equivalent Li(2)O6 octahedra and corners with two equivalent Li(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the fourth Co site, Co(4) is bonded to one O(16), one O(17), one O(21), one O(28), one O(32), and one O(9) atom to form CoO6 octahedra that share corners with two equivalent Li(3)O6 octahedra and corners with two equivalent Li(4)O6 octahedra. The corner-sharing octahedra are not tilted. There are thirty-two inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one La(15), one La(5), one La(7), and two equivalent La(9) atoms to form distorted OLiLa5 octahedra that share  a cornercorner with one O(17)LiLa4Co octahedra,  a cornercorner with one O(18)LiLa4Co octahedra,  a cornercorner with one O(20)LiLa4Co octahedra,  a cornercorner with one O(21)LiLa4Co octahedra,  a cornercorner with one O(22)LiLa4Co octahedra,  a cornercorner with one O(24)LiLa4Co octahedra,  a cornercorner with one O(25)LiLa4Co octahedra,  a cornercorner with one O(26)LiLa4Co octahedra,  a cornercorner with one O(27)LiLa4Co octahedra,  a cornercorner with one O(29)LiLa4Co octahedra,  a cornercorner with one O(30)LiLa4Co octahedra,  a cornercorner with one O(31)LiLa4Co octahedra,  a cornercorner with one O(2)LiLa5 octahedra,  a cornercorner with one O(3)LiLa5 octahedra,  a cornercorner with one O(6)LiLa5 octahedra, corners with two equivalent O(1)LiLa5 octahedra,  an edgeedge with one O(11)La5Co octahedra,  an edgeedge with one O(9)La5Co octahedra, edges with two equivalent O(13)La5Co octahedra, edges with two equivalent O(15)La5Co octahedra, edges with two equivalent O(7)LiLa5 octahedra,  a faceface with one O(20)LiLa4Co octahedra,  a faceface with one O(24)LiLa4Co octahedra,  a faceface with one O(27)LiLa4Co octahedra, and  a faceface with one O(31)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 1-51°. In the second O site, O(2) is bonded to one Li(2), one La(13), one La(5), one La(6), and two equivalent La(10) atoms to form distorted OLiLa5 octahedra that share  a cornercorner with one O(18)LiLa4Co octahedra,  a cornercorner with one O(19)LiLa4Co octahedra,  a cornercorner with one O(20)LiLa4Co octahedra,  a cornercorner with one O(22)LiLa4Co octahedra,  a cornercorner with one O(23)LiLa4Co octahedra,  a cornercorner with one O(24)LiLa4Co octahedra,  a cornercorner with one O(25)LiLa4Co octahedra,  a cornercorner with one O(26)LiLa4Co octahedra,  a cornercorner with one O(28)LiLa4Co octahedra,  a cornercorner with one O(29)LiLa4Co octahedra,  a cornercorner with one O(30)LiLa4Co octahedra,  a cornercorner with one O(32)LiLa4Co octahedra,  a cornercorner with one O(1)LiLa5 octahedra,  a cornercorner with one O(4)LiLa5 octahedra,  a cornercorner with one O(8)LiLa5 octahedra, corners with two equivalent O(2)LiLa5 octahedra,  an edgeedge with one O(10)La5Co octahedra,  an edgeedge with one O(9)La5Co octahedra, edges with two equivalent O(13)La5Co octahedra, edges with two equivalent O(14)La5Co octahedra, edges with two equivalent O(5)LiLa5 octahedra,  a faceface with one O(19)LiLa4Co octahedra,  a faceface with one O(23)LiLa4Co octahedra,  a faceface with one O(25)LiLa4Co octahedra, and  a faceface with one O(29)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-50°. In the third O site, O(3) is bonded to one Li(3), one La(16), one La(7), one La(8), and two equivalent La(11) atoms to form distorted OLiLa5 octahedra that share  a cornercorner with one O(17)LiLa4Co octahedra,  a cornercorner with one O(18)LiLa4Co octahedra,  a cornercorner with one O(19)LiLa4Co octahedra,  a cornercorner with one O(21)LiLa4Co octahedra,  a cornercorner with one O(22)LiLa4Co octahedra,  a cornercorner with one O(23)LiLa4Co octahedra,  a cornercorner with one O(25)LiLa4Co octahedra,  a cornercorner with one O(27)LiLa4Co octahedra,  a cornercorner with one O(28)LiLa4Co octahedra,  a cornercorner with one O(29)LiLa4Co octahedra,  a cornercorner with one O(31)LiLa4Co octahedra,  a cornercorner with one O(32)LiLa4Co octahedra,  a cornercorner with one O(1)LiLa5 octahedra,  a cornercorner with one O(4)LiLa5 octahedra,  a cornercorner with one O(5)LiLa5 octahedra, corners with two equivalent O(3)LiLa5 octahedra,  an edgeedge with one O(11)La5Co octahedra,  an edgeedge with one O(12)La5Co octahedra, edges with two equivalent O(15)La5Co octahedra, edges with two equivalent O(16)La5Co octahedra, edges with two equivalent O(8)LiLa5 octahedra,  a faceface with one O(18)LiLa4Co octahedra,  a faceface with one O(22)LiLa4Co octahedra,  a faceface with one O(28)LiLa4Co octahedra, and  a faceface with one O(32)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 1-51°. In the fourth O site, O(4) is bonded to one Li(4), one La(14), one La(6), one La(8), and two equivalent La(12) atoms to form distorted OLiLa5 octahedra that share  a cornercorner with one O(17)LiLa4Co octahedra,  a cornercorner with one O(19)LiLa4Co octahedra,  a cornercorner with one O(20)LiLa4Co octahedra,  a cornercorner with one O(21)LiLa4Co octahedra,  a cornercorner with one O(23)LiLa4Co octahedra,  a cornercorner with one O(24)LiLa4Co octahedra,  a cornercorner with one O(26)LiLa4Co octahedra,  a cornercorner with one O(27)LiLa4Co octahedra,  a cornercorner with one O(28)LiLa4Co octahedra,  a cornercorner with one O(30)LiLa4Co octahedra,  a cornercorner with one O(31)LiLa4Co octahedra,  a cornercorner with one O(32)LiLa4Co octahedra,  a cornercorner with one O(2)LiLa5 octahedra,  a cornercorner with one O(3)LiLa5 octahedra,  a cornercorner with one O(7)LiLa5 octahedra, corners with two equivalent O(4)LiLa5 octahedra,  an edgeedge with one O(10)La5Co octahedra,  an edgeedge with one O(12)La5Co octahedra, edges with two equivalent O(14)La5Co octahedra, edges with two equivalent O(16)La5Co octahedra, edges with two equivalent O(6)LiLa5 octahedra,  a faceface with one O(17)LiLa4Co octahedra,  a faceface with one O(21)LiLa4Co octahedra,  a faceface with one O(26)LiLa4Co octahedra, and  a faceface with one O(30)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-51°. In the fifth O site, O(5) is bonded to one Li(3), one La(1), one La(10), one La(2), and two equivalent La(13) atoms to form distorted OLiLa5 octahedra that share  a cornercorner with one O(17)LiLa4Co octahedra,  a cornercorner with one O(18)LiLa4Co octahedra,  a cornercorner with one O(19)LiLa4Co octahedra,  a cornercorner with one O(21)LiLa4Co octahedra,  a cornercorner with one O(22)LiLa4Co octahedra,  a cornercorner with one O(23)LiLa4Co octahedra,  a cornercorner with one O(25)LiLa4Co octahedra,  a cornercorner with one O(27)LiLa4Co octahedra,  a cornercorner with one O(28)LiLa4Co octahedra,  a cornercorner with one O(29)LiLa4Co octahedra,  a cornercorner with one O(31)LiLa4Co octahedra,  a cornercorner with one O(32)LiLa4Co octahedra,  a cornercorner with one O(3)LiLa5 octahedra,  a cornercorner with one O(6)LiLa5 octahedra,  a cornercorner with one O(7)LiLa5 octahedra, corners with two equivalent O(5)LiLa5 octahedra,  an edgeedge with one O(13)La5Co octahedra,  an edgeedge with one O(14)La5Co octahedra, edges with two equivalent O(10)La5Co octahedra, edges with two equivalent O(9)La5Co octahedra, edges with two equivalent O(2)LiLa5 octahedra,  a faceface with one O(18)LiLa4Co octahedra,  a faceface with one O(22)LiLa4Co octahedra,  a faceface with one O(28)LiLa4Co octahedra, and  a faceface with one O(32)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 1-51°. In the sixth O site, O(6) is bonded to one Li(1), one La(12), one La(2), one La(4), and two equivalent La(14) atoms to form distorted OLiLa5 octahedra that share  a cornercorner with one O(17)LiLa4Co octahedra,  a cornercorner with one O(18)LiLa4Co octahedra,  a cornercorner with one O(20)LiLa4Co octahedra,  a cornercorner with one O(21)LiLa4Co octahedra,  a cornercorner with one O(22)LiLa4Co octahedra,  a cornercorner with one O(24)LiLa4Co octahedra,  a cornercorner with one O(25)LiLa4Co octahedra,  a cornercorner with one O(26)LiLa4Co octahedra,  a cornercorner with one O(27)LiLa4Co octahedra,  a cornercorner with one O(29)LiLa4Co octahedra,  a cornercorner with one O(30)LiLa4Co octahedra,  a cornercorner with one O(31)LiLa4Co octahedra,  a cornercorner with one O(1)LiLa5 octahedra,  a cornercorner with one O(5)LiLa5 octahedra,  a cornercorner with one O(8)LiLa5 octahedra, corners with two equivalent O(6)LiLa5 octahedra,  an edgeedge with one O(14)La5Co octahedra,  an edgeedge with one O(16)La5Co octahedra, edges with two equivalent O(10)La5Co octahedra, edges with two equivalent O(12)La5Co octahedra, edges with two equivalent O(4)LiLa5 octahedra,  a faceface with one O(20)LiLa4Co octahedra,  a faceface with one O(24)LiLa4Co octahedra,  a faceface with one O(27)LiLa4Co octahedra, and  a faceface with one O(31)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 1-51°. In the seventh O site, O(7) is bonded to one Li(4), one La(1), one La(3), one La(9), and two equivalent La(15) atoms to form distorted OLiLa5 octahedra that share  a cornercorner with one O(17)LiLa4Co octahedra,  a cornercorner with one O(19)LiLa4Co octahedra,  a cornercorner with one O(20)LiLa4Co octahedra,  a cornercorner with one O(21)LiLa4Co octahedra,  a cornercorner with one O(23)LiLa4Co octahedra,  a cornercorner with one O(24)LiLa4Co octahedra,  a cornercorner with one O(26)LiLa4Co octahedra,  a cornercorner with one O(27)LiLa4Co octahedra,  a cornercorner with one O(28)LiLa4Co octahedra,  a cornercorner with one O(30)LiLa4Co octahedra,  a cornercorner with one O(31)LiLa4Co octahedra,  a cornercorner with one O(32)LiLa4Co octahedra,  a cornercorner with one O(4)LiLa5 octahedra,  a cornercorner with one O(5)LiLa5 octahedra,  a cornercorner with one O(8)LiLa5 octahedra, corners with two equivalent O(7)LiLa5 octahedra,  an edgeedge with one O(13)La5Co octahedra,  an edgeedge with one O(15)La5Co octahedra, edges with two equivalent O(11)La5Co octahedra, edges with two equivalent O(9)La5Co octahedra, edges with two equivalent O(1)LiLa5 octahedra,  a faceface with one O(17)LiLa4Co octahedra,  a faceface with one O(21)LiLa4Co octahedra,  a faceface with one O(26)LiLa4Co octahedra, and  a faceface with one O(30)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-50°. In the eighth O site, O(8) is bonded to one Li(2), one La(11), one La(3), one La(4), and two equivalent La(16) atoms to form distorted OLiLa5 octahedra that share  a cornercorner with one O(18)LiLa4Co octahedra,  a cornercorner with one O(19)LiLa4Co octahedra,  a cornercorner with one O(20)LiLa4Co octahedra,  a cornercorner with one O(22)LiLa4Co octahedra,  a cornercorner with one O(23)LiLa4Co octahedra,  a cornercorner with one O(24)LiLa4Co octahedra,  a cornercorner with one O(25)LiLa4Co octahedra,  a cornercorner with one O(26)LiLa4Co octahedra,  a cornercorner with one O(28)LiLa4Co octahedra,  a cornercorner with one O(29)LiLa4Co octahedra,  a cornercorner with one O(30)LiLa4Co octahedra,  a cornercorner with one O(32)LiLa4Co octahedra,  a cornercorner with one O(2)LiLa5 octahedra,  a cornercorner with one O(6)LiLa5 octahedra,  a cornercorner with one O(7)LiLa5 octahedra, corners with two equivalent O(8)LiLa5 octahedra,  an edgeedge with one O(15)La5Co octahedra,  an edgeedge with one O(16)La5Co octahedra, edges with two equivalent O(11)La5Co octahedra, edges with two equivalent O(12)La5Co octahedra, edges with two equivalent O(3)LiLa5 octahedra,  a faceface with one O(19)LiLa4Co octahedra,  a faceface with one O(23)LiLa4Co octahedra,  a faceface with one O(25)LiLa4Co octahedra, and  a faceface with one O(29)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-51°. In the ninth O site, O(9) is bonded to one La(13), one La(15), one La(5), two equivalent La(1), and one Co(4) atom to form distorted OLa5Co octahedra that share  a cornercorner with one O(10)La5Co octahedra,  a cornercorner with one O(11)La5Co octahedra,  a cornercorner with one O(16)La5Co octahedra,  a cornercorner with one O(17)LiLa4Co octahedra,  a cornercorner with one O(18)LiLa4Co octahedra,  a cornercorner with one O(20)LiLa4Co octahedra,  a cornercorner with one O(21)LiLa4Co octahedra,  a cornercorner with one O(22)LiLa4Co octahedra,  a cornercorner with one O(24)LiLa4Co octahedra,  a cornercorner with one O(25)LiLa4Co octahedra,  a cornercorner with one O(26)LiLa4Co octahedra,  a cornercorner with one O(28)LiLa4Co octahedra,  a cornercorner with one O(29)LiLa4Co octahedra,  a cornercorner with one O(30)LiLa4Co octahedra,  a cornercorner with one O(32)LiLa4Co octahedra, corners with two equivalent O(9)La5Co octahedra,  an edgeedge with one O(1)LiLa5 octahedra,  an edgeedge with one O(2)LiLa5 octahedra, edges with two equivalent O(13)La5Co octahedra, edges with two equivalent O(5)LiLa5 octahedra, edges with two equivalent O(7)LiLa5 octahedra,  a faceface with one O(17)LiLa4Co octahedra,  a faceface with one O(21)LiLa4Co octahedra,  a faceface with one O(28)LiLa4Co octahedra, and  a faceface with one O(32)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-50°. In the tenth O site, O(10) is bonded to one La(13), one La(14), one La(6), two equivalent La(2), and one Co(2) atom to form distorted OLa5Co octahedra that share  a cornercorner with one O(12)La5Co octahedra,  a cornercorner with one O(15)La5Co octahedra,  a cornercorner with one O(9)La5Co octahedra,  a cornercorner with one O(18)LiLa4Co octahedra,  a cornercorner with one O(19)LiLa4Co octahedra,  a cornercorner with one O(20)LiLa4Co octahedra,  a cornercorner with one O(22)LiLa4Co octahedra,  a cornercorner with one O(23)LiLa4Co octahedra,  a cornercorner with one O(24)LiLa4Co octahedra,  a cornercorner with one O(26)LiLa4Co octahedra,  a cornercorner with one O(27)LiLa4Co octahedra,  a cornercorner with one O(28)LiLa4Co octahedra,  a cornercorner with one O(30)LiLa4Co octahedra,  a cornercorner with one O(31)LiLa4Co octahedra,  a cornercorner with one O(32)LiLa4Co octahedra, corners with two equivalent O(10)La5Co octahedra,  an edgeedge with one O(2)LiLa5 octahedra,  an edgeedge with one O(4)LiLa5 octahedra, edges with two equivalent O(14)La5Co octahedra, edges with two equivalent O(5)LiLa5 octahedra, edges with two equivalent O(6)LiLa5 octahedra,  a faceface with one O(18)LiLa4Co octahedra,  a faceface with one O(22)LiLa4Co octahedra,  a faceface with one O(27)LiLa4Co octahedra, and  a faceface with one O(31)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-50°. In the eleventh O site, O(11) is bonded to one La(15), one La(16), one La(7), two equivalent La(3), and one Co(3) atom to form distorted OLa5Co octahedra that share  a cornercorner with one O(12)La5Co octahedra,  a cornercorner with one O(14)La5Co octahedra,  a cornercorner with one O(9)La5Co octahedra,  a cornercorner with one O(17)LiLa4Co octahedra,  a cornercorner with one O(18)LiLa4Co octahedra,  a cornercorner with one O(19)LiLa4Co octahedra,  a cornercorner with one O(21)LiLa4Co octahedra,  a cornercorner with one O(22)LiLa4Co octahedra,  a cornercorner with one O(23)LiLa4Co octahedra,  a cornercorner with one O(25)LiLa4Co octahedra,  a cornercorner with one O(26)LiLa4Co octahedra,  a cornercorner with one O(27)LiLa4Co octahedra,  a cornercorner with one O(29)LiLa4Co octahedra,  a cornercorner with one O(30)LiLa4Co octahedra,  a cornercorner with one O(31)LiLa4Co octahedra, corners with two equivalent O(11)La5Co octahedra,  an edgeedge with one O(1)LiLa5 octahedra,  an edgeedge with one O(3)LiLa5 octahedra, edges with two equivalent O(15)La5Co octahedra, edges with two equivalent O(7)LiLa5 octahedra, edges with two equivalent O(8)LiLa5 octahedra,  a faceface with one O(19)LiLa4Co octahedra,  a faceface with one O(23)LiLa4Co octahedra,  a faceface with one O(26)LiLa4Co octahedra, and  a faceface with one O(30)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-51°. In the twelfth O site, O(12) is bonded to one La(14), one La(16), one La(8), two equivalent La(4), and one Co(1) atom to form distorted OLa5Co octahedra that share  a cornercorner with one O(10)La5Co octahedra,  a cornercorner with one O(11)La5Co octahedra,  a cornercorner with one O(13)La5Co octahedra,  a cornercorner with one O(17)LiLa4Co octahedra,  a cornercorner with one O(19)LiLa4Co octahedra,  a cornercorner with one O(20)LiLa4Co octahedra,  a cornercorner with one O(21)LiLa4Co octahedra,  a cornercorner with one O(23)LiLa4Co octahedra,  a cornercorner with one O(24)LiLa4Co octahedra,  a cornercorner with one O(25)LiLa4Co octahedra,  a cornercorner with one O(27)LiLa4Co octahedra,  a cornercorner with one O(28)LiLa4Co octahedra,  a cornercorner with one O(29)LiLa4Co octahedra,  a cornercorner with one O(31)LiLa4Co octahedra,  a cornercorner with one O(32)LiLa4Co octahedra, corners with two equivalent O(12)La5Co octahedra,  an edgeedge with one O(3)LiLa5 octahedra,  an edgeedge with one O(4)LiLa5 octahedra, edges with two equivalent O(16)La5Co octahedra, edges with two equivalent O(6)LiLa5 octahedra, edges with two equivalent O(8)LiLa5 octahedra,  a faceface with one O(20)LiLa4Co octahedra,  a faceface with one O(24)LiLa4Co octahedra,  a faceface with one O(25)LiLa4Co octahedra, and  a faceface with one O(29)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-50°. In the thirteenth O site, O(13) is bonded to one La(1), one La(10), one La(9), two equivalent La(5), and one Co(1) atom to form distorted OLa5Co octahedra that share  a cornercorner with one O(12)La5Co octahedra,  a cornercorner with one O(14)La5Co octahedra,  a cornercorner with one O(15)La5Co octahedra,  a cornercorner with one O(17)LiLa4Co octahedra,  a cornercorner with one O(19)LiLa4Co octahedra,  a cornercorner with one O(20)LiLa4Co octahedra,  a cornercorner with one O(21)LiLa4Co octahedra,  a cornercorner with one O(23)LiLa4Co octahedra,  a cornercorner with one O(24)LiLa4Co octahedra,  a cornercorner with one O(25)LiLa4Co octahedra,  a cornercorner with one O(27)LiLa4Co octahedra,  a cornercorner with one O(28)LiLa4Co octahedra,  a cornercorner with one O(29)LiLa4Co octahedra,  a cornercorner with one O(31)LiLa4Co octahedra,  a cornercorner with one O(32)LiLa4Co octahedra, corners with two equivalent O(13)La5Co octahedra,  an edgeedge with one O(5)LiLa5 octahedra,  an edgeedge with one O(7)LiLa5 octahedra, edges with two equivalent O(9)La5Co octahedra, edges with two equivalent O(1)LiLa5 octahedra, edges with two equivalent O(2)LiLa5 octahedra,  a faceface with one O(20)LiLa4Co octahedra,  a faceface with one O(24)LiLa4Co octahedra,  a faceface with one O(25)LiLa4Co octahedra, and  a faceface with one O(29)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-50°. In the fourteenth O site, O(14) is bonded to one La(10), one La(12), one La(2), two equivalent La(6), and one Co(3) atom to form distorted OLa5Co octahedra that share  a cornercorner with one O(11)La5Co octahedra,  a cornercorner with one O(13)La5Co octahedra,  a cornercorner with one O(16)La5Co octahedra,  a cornercorner with one O(17)LiLa4Co octahedra,  a cornercorner with one O(18)LiLa4Co octahedra,  a cornercorner with one O(19)LiLa4Co octahedra,  a cornercorner with one O(21)LiLa4Co octahedra,  a cornercorner with one O(22)LiLa4Co octahedra,  a cornercorner with one O(23)LiLa4Co octahedra,  a cornercorner with one O(25)LiLa4Co octahedra,  a cornercorner with one O(26)LiLa4Co octahedra,  a cornercorner with one O(27)LiLa4Co octahedra,  a cornercorner with one O(29)LiLa4Co octahedra,  a cornercorner with one O(30)LiLa4Co octahedra,  a cornercorner with one O(31)LiLa4Co octahedra, corners with two equivalent O(14)La5Co octahedra,  an edgeedge with one O(5)LiLa5 octahedra,  an edgeedge with one O(6)LiLa5 octahedra, edges with two equivalent O(10)La5Co octahedra, edges with two equivalent O(2)LiLa5 octahedra, edges with two equivalent O(4)LiLa5 octahedra,  a faceface with one O(19)LiLa4Co octahedra,  a faceface with one O(23)LiLa4Co octahedra,  a faceface with one O(26)LiLa4Co octahedra, and  a faceface with one O(30)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-51°. In the fifteenth O site, O(15) is bonded to one La(11), one La(3), one La(9), two equivalent La(7), and one Co(2) atom to form distorted OLa5Co octahedra that share  a cornercorner with one O(10)La5Co octahedra,  a cornercorner with one O(13)La5Co octahedra,  a cornercorner with one O(16)La5Co octahedra,  a cornercorner with one O(18)LiLa4Co octahedra,  a cornercorner with one O(19)LiLa4Co octahedra,  a cornercorner with one O(20)LiLa4Co octahedra,  a cornercorner with one O(22)LiLa4Co octahedra,  a cornercorner with one O(23)LiLa4Co octahedra,  a cornercorner with one O(24)LiLa4Co octahedra,  a cornercorner with one O(26)LiLa4Co octahedra,  a cornercorner with one O(27)LiLa4Co octahedra,  a cornercorner with one O(28)LiLa4Co octahedra,  a cornercorner with one O(30)LiLa4Co octahedra,  a cornercorner with one O(31)LiLa4Co octahedra,  a cornercorner with one O(32)LiLa4Co octahedra, corners with two equivalent O(15)La5Co octahedra,  an edgeedge with one O(7)LiLa5 octahedra,  an edgeedge with one O(8)LiLa5 octahedra, edges with two equivalent O(11)La5Co octahedra, edges with two equivalent O(1)LiLa5 octahedra, edges with two equivalent O(3)LiLa5 octahedra,  a faceface with one O(18)LiLa4Co octahedra,  a faceface with one O(22)LiLa4Co octahedra,  a faceface with one O(27)LiLa4Co octahedra, and  a faceface with one O(31)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-50°. In the sixteenth O site, O(16) is bonded to one La(11), one La(12), one La(4), two equivalent La(8), and one Co(4) atom to form distorted OLa5Co octahedra that share  a cornercorner with one O(14)La5Co octahedra,  a cornercorner with one O(15)La5Co octahedra,  a cornercorner with one O(9)La5Co octahedra,  a cornercorner with one O(17)LiLa4Co octahedra,  a cornercorner with one O(18)LiLa4Co octahedra,  a cornercorner with one O(20)LiLa4Co octahedra,  a cornercorner with one O(21)LiLa4Co octahedra,  a cornercorner with one O(22)LiLa4Co octahedra,  a cornercorner with one O(24)LiLa4Co octahedra,  a cornercorner with one O(25)LiLa4Co octahedra,  a cornercorner with one O(26)LiLa4Co octahedra,  a cornercorner with one O(28)LiLa4Co octahedra,  a cornercorner with one O(29)LiLa4Co octahedra,  a cornercorner with one O(30)LiLa4Co octahedra,  a cornercorner with one O(32)LiLa4Co octahedra, corners with two equivalent O(16)La5Co octahedra,  an edgeedge with one O(6)LiLa5 octahedra,  an edgeedge with one O(8)LiLa5 octahedra, edges with two equivalent O(12)La5Co octahedra, edges with two equivalent O(3)LiLa5 octahedra, edges with two equivalent O(4)LiLa5 octahedra,  a faceface with one O(17)LiLa4Co octahedra,  a faceface with one O(21)LiLa4Co octahedra,  a faceface with one O(28)LiLa4Co octahedra, and  a faceface with one O(32)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-50°. In the seventeenth O site, O(17) is bonded to one Li(4), one La(1), one La(12), one La(15), one La(8), and one Co(4) atom to form distorted OLiLa4Co octahedra that share  a cornercorner with one O(11)La5Co octahedra,  a cornercorner with one O(12)La5Co octahedra,  a cornercorner with one O(13)La5Co octahedra,  a cornercorner with one O(14)La5Co octahedra,  a cornercorner with one O(16)La5Co octahedra,  a cornercorner with one O(9)La5Co octahedra,  a cornercorner with one O(26)LiLa4Co octahedra,  a cornercorner with one O(28)LiLa4Co octahedra,  a cornercorner with one O(1)LiLa5 octahedra,  a cornercorner with one O(3)LiLa5 octahedra,  a cornercorner with one O(4)LiLa5 octahedra,  a cornercorner with one O(5)LiLa5 octahedra,  a cornercorner with one O(6)LiLa5 octahedra,  a cornercorner with one O(7)LiLa5 octahedra,  an edgeedge with one O(26)LiLa4Co octahedra,  an edgeedge with one O(28)LiLa4Co octahedra,  a faceface with one O(16)La5Co octahedra,  a faceface with one O(9)La5Co octahedra,  a faceface with one O(30)LiLa4Co octahedra,  a faceface with one O(32)LiLa4Co octahedra,  a faceface with one O(4)LiLa5 octahedra,  a faceface with one O(7)LiLa5 octahedra, and faces with two equivalent O(21)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-51°. In the eighteenth O site, O(18) is bonded to one Li(3), one La(11), one La(13), one La(2), one La(7), and one Co(2) atom to form distorted OLiLa4Co octahedra that share  a cornercorner with one O(10)La5Co octahedra,  a cornercorner with one O(11)La5Co octahedra,  a cornercorner with one O(14)La5Co octahedra,  a cornercorner with one O(15)La5Co octahedra,  a cornercorner with one O(16)La5Co octahedra,  a cornercorner with one O(9)La5Co octahedra,  a cornercorner with one O(27)LiLa4Co octahedra,  a cornercorner with one O(28)LiLa4Co octahedra,  a cornercorner with one O(1)LiLa5 octahedra,  a cornercorner with one O(2)LiLa5 octahedra,  a cornercorner with one O(3)LiLa5 octahedra,  a cornercorner with one O(5)LiLa5 octahedra,  a cornercorner with one O(6)LiLa5 octahedra,  a cornercorner with one O(8)LiLa5 octahedra,  an edgeedge with one O(27)LiLa4Co octahedra,  an edgeedge with one O(28)LiLa4Co octahedra,  a faceface with one O(10)La5Co octahedra,  a faceface with one O(15)La5Co octahedra,  a faceface with one O(31)LiLa4Co octahedra,  a faceface with one O(32)LiLa4Co octahedra,  a faceface with one O(3)LiLa5 octahedra,  a faceface with one O(5)LiLa5 octahedra, and faces with two equivalent O(22)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-51°. In the nineteenth O site, O(19) is bonded to one Li(2), one La(10), one La(16), one La(3), one La(6), and one Co(3) atom to form distorted OLiLa4Co octahedra that share  a cornercorner with one O(10)La5Co octahedra,  a cornercorner with one O(11)La5Co octahedra,  a cornercorner with one O(12)La5Co octahedra,  a cornercorner with one O(13)La5Co octahedra,  a cornercorner with one O(14)La5Co octahedra,  a cornercorner with one O(15)La5Co octahedra,  a cornercorner with one O(25)LiLa4Co octahedra,  a cornercorner with one O(26)LiLa4Co octahedra,  a cornercorner with one O(2)LiLa5 octahedra,  a cornercorner with one O(3)LiLa5 octahedra,  a cornercorner with one O(4)LiLa5 octahedra,  a cornercorner with one O(5)LiLa5 octahedra,  a cornercorner with one O(7)LiLa5 octahedra,  a cornercorner with one O(8)LiLa5 octahedra,  an edgeedge with one O(25)LiLa4Co octahedra,  an edgeedge with one O(26)LiLa4Co octahedra,  a faceface with one O(11)La5Co octahedra,  a faceface with one O(14)La5Co octahedra,  a faceface with one O(29)LiLa4Co octahedra,  a faceface with one O(30)LiLa4Co octahedra,  a faceface with one O(2)LiLa5 octahedra,  a faceface with one O(8)LiLa5 octahedra, and faces with two equivalent O(23)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-51°. In the twentieth O site, O(20) is bonded to one Li(1), one La(14), one La(4), one La(5), one La(9), and one Co(1) atom to form distorted OLiLa4Co octahedra that share  a cornercorner with one O(10)La5Co octahedra,  a cornercorner with one O(12)La5Co octahedra,  a cornercorner with one O(13)La5Co octahedra,  a cornercorner with one O(15)La5Co octahedra,  a cornercorner with one O(16)La5Co octahedra,  a cornercorner with one O(9)La5Co octahedra,  a cornercorner with one O(25)LiLa4Co octahedra,  a cornercorner with one O(27)LiLa4Co octahedra,  a cornercorner with one O(1)LiLa5 octahedra,  a cornercorner with one O(2)LiLa5 octahedra,  a cornercorner with one O(4)LiLa5 octahedra,  a cornercorner with one O(6)LiLa5 octahedra,  a cornercorner with one O(7)LiLa5 octahedra,  a cornercorner with one O(8)LiLa5 octahedra,  an edgeedge with one O(25)LiLa4Co octahedra,  an edgeedge with one O(27)LiLa4Co octahedra,  a faceface with one O(12)La5Co octahedra,  a faceface with one O(13)La5Co octahedra,  a faceface with one O(29)LiLa4Co octahedra,  a faceface with one O(31)LiLa4Co octahedra,  a faceface with one O(1)LiLa5 octahedra,  a faceface with one O(6)LiLa5 octahedra, and faces with two equivalent O(24)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-51°. In the twenty-first O site, O(21) is bonded to one Li(4), one La(1), one La(12), one La(15), one La(8), and one Co(4) atom to form distorted OLiLa4Co octahedra that share  a cornercorner with one O(11)La5Co octahedra,  a cornercorner with one O(12)La5Co octahedra,  a cornercorner with one O(13)La5Co octahedra,  a cornercorner with one O(14)La5Co octahedra,  a cornercorner with one O(16)La5Co octahedra,  a cornercorner with one O(9)La5Co octahedra,  a cornercorner with one O(30)LiLa4Co octahedra,  a cornercorner with one O(32)LiLa4Co octahedra,  a cornercorner with one O(1)LiLa5 octahedra,  a cornercorner with one O(3)LiLa5 octahedra,  a cornercorner with one O(4)LiLa5 octahedra,  a cornercorner with one O(5)LiLa5 octahedra,  a cornercorner with one O(6)LiLa5 octahedra,  a cornercorner with one O(7)LiLa5 octahedra,  an edgeedge with one O(30)LiLa4Co octahedra,  an edgeedge with one O(32)LiLa4Co octahedra,  a faceface with one O(16)La5Co octahedra,  a faceface with one O(9)La5Co octahedra,  a faceface with one O(26)LiLa4Co octahedra,  a faceface with one O(28)LiLa4Co octahedra,  a faceface with one O(4)LiLa5 octahedra,  a faceface with one O(7)LiLa5 octahedra, and faces with two equivalent O(17)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-51°. In the twenty-second O site, O(22) is bonded to one Li(3), one La(11), one La(13), one La(2), one La(7), and one Co(2) atom to form distorted OLiLa4Co octahedra that share  a cornercorner with one O(10)La5Co octahedra,  a cornercorner with one O(11)La5Co octahedra,  a cornercorner with one O(14)La5Co octahedra,  a cornercorner with one O(15)La5Co octahedra,  a cornercorner with one O(16)La5Co octahedra,  a cornercorner with one O(9)La5Co octahedra,  a cornercorner with one O(31)LiLa4Co octahedra,  a cornercorner with one O(32)LiLa4Co octahedra,  a cornercorner with one O(1)LiLa5 octahedra,  a cornercorner with one O(2)LiLa5 octahedra,  a cornercorner with one O(3)LiLa5 octahedra,  a cornercorner with one O(5)LiLa5 octahedra,  a cornercorner with one O(6)LiLa5 octahedra,  a cornercorner with one O(8)LiLa5 octahedra,  an edgeedge with one O(31)LiLa4Co octahedra,  an edgeedge with one O(32)LiLa4Co octahedra,  a faceface with one O(10)La5Co octahedra,  a faceface with one O(15)La5Co octahedra,  a faceface with one O(27)LiLa4Co octahedra,  a faceface with one O(28)LiLa4Co octahedra,  a faceface with one O(3)LiLa5 octahedra,  a faceface with one O(5)LiLa5 octahedra, and faces with two equivalent O(18)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-51°. In the twenty-third O site, O(23) is bonded to one Li(2), one La(10), one La(16), one La(3), one La(6), and one Co(3) atom to form distorted OLiLa4Co octahedra that share  a cornercorner with one O(10)La5Co octahedra,  a cornercorner with one O(11)La5Co octahedra,  a cornercorner with one O(12)La5Co octahedra,  a cornercorner with one O(13)La5Co octahedra,  a cornercorner with one O(14)La5Co octahedra,  a cornercorner with one O(15)La5Co octahedra,  a cornercorner with one O(29)LiLa4Co octahedra,  a cornercorner with one O(30)LiLa4Co octahedra,  a cornercorner with one O(2)LiLa5 octahedra,  a cornercorner with one O(3)LiLa5 octahedra,  a cornercorner with one O(4)LiLa5 octahedra,  a cornercorner with one O(5)LiLa5 octahedra,  a cornercorner with one O(7)LiLa5 octahedra,  a cornercorner with one O(8)LiLa5 octahedra,  an edgeedge with one O(29)LiLa4Co octahedra,  an edgeedge with one O(30)LiLa4Co octahedra,  a faceface with one O(11)La5Co octahedra,  a faceface with one O(14)La5Co octahedra,  a faceface with one O(25)LiLa4Co octahedra,  a faceface with one O(26)LiLa4Co octahedra,  a faceface with one O(2)LiLa5 octahedra,  a faceface with one O(8)LiLa5 octahedra, and faces with two equivalent O(19)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-50°. In the twenty-fourth O site, O(24) is bonded to one Li(1), one La(14), one La(4), one La(5), one La(9), and one Co(1) atom to form distorted OLiLa4Co octahedra that share  a cornercorner with one O(10)La5Co octahedra,  a cornercorner with one O(12)La5Co octahedra,  a cornercorner with one O(13)La5Co octahedra,  a cornercorner with one O(15)La5Co octahedra,  a cornercorner with one O(16)La5Co octahedra,  a cornercorner with one O(9)La5Co octahedra,  a cornercorner with one O(29)LiLa4Co octahedra,  a cornercorner with one O(31)LiLa4Co octahedra,  a cornercorner with one O(1)LiLa5 octahedra,  a cornercorner with one O(2)LiLa5 octahedra,  a cornercorner with one O(4)LiLa5 octahedra,  a cornercorner with one O(6)LiLa5 octahedra,  a cornercorner with one O(7)LiLa5 octahedra,  a cornercorner with one O(8)LiLa5 octahedra,  an edgeedge with one O(29)LiLa4Co octahedra,  an edgeedge with one O(31)LiLa4Co octahedra,  a faceface with one O(12)La5Co octahedra,  a faceface with one O(13)La5Co octahedra,  a faceface with one O(25)LiLa4Co octahedra,  a faceface with one O(27)LiLa4Co octahedra,  a faceface with one O(1)LiLa5 octahedra,  a faceface with one O(6)LiLa5 octahedra, and faces with two equivalent O(20)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-50°. In the twenty-fifth O site, O(25) is bonded to one Li(2), one La(10), one La(16), one La(4), one La(5), and one Co(1) atom to form distorted OLiLa4Co octahedra that share  a cornercorner with one O(11)La5Co octahedra,  a cornercorner with one O(12)La5Co octahedra,  a cornercorner with one O(13)La5Co octahedra,  a cornercorner with one O(14)La5Co octahedra,  a cornercorner with one O(16)La5Co octahedra,  a cornercorner with one O(9)La5Co octahedra,  a cornercorner with one O(19)LiLa4Co octahedra,  a cornercorner with one O(20)LiLa4Co octahedra,  a cornercorner with one O(1)LiLa5 octahedra,  a cornercorner with one O(2)LiLa5 octahedra,  a cornercorner with one O(3)LiLa5 octahedra,  a cornercorner with one O(5)LiLa5 octahedra,  a cornercorner with one O(6)LiLa5 octahedra,  a cornercorner with one O(8)LiLa5 octahedra,  an edgeedge with one O(19)LiLa4Co octahedra,  an edgeedge with one O(20)LiLa4Co octahedra,  a faceface with one O(12)La5Co octahedra,  a faceface with one O(13)La5Co octahedra,  a faceface with one O(23)LiLa4Co octahedra,  a faceface with one O(24)LiLa4Co octahedra,  a faceface with one O(2)LiLa5 octahedra,  a faceface with one O(8)LiLa5 octahedra, and faces with two equivalent O(29)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-51°. In the twenty-sixth O site, O(26) is bonded to one Li(4), one La(12), one La(15), one La(3), one La(6), and one Co(3) atom to form distorted OLiLa4Co octahedra that share  a cornercorner with one O(10)La5Co octahedra,  a cornercorner with one O(11)La5Co octahedra,  a cornercorner with one O(14)La5Co octahedra,  a cornercorner with one O(15)La5Co octahedra,  a cornercorner with one O(16)La5Co octahedra,  a cornercorner with one O(9)La5Co octahedra,  a cornercorner with one O(17)LiLa4Co octahedra,  a cornercorner with one O(19)LiLa4Co octahedra,  a cornercorner with one O(1)LiLa5 octahedra,  a cornercorner with one O(2)LiLa5 octahedra,  a cornercorner with one O(4)LiLa5 octahedra,  a cornercorner with one O(6)LiLa5 octahedra,  a cornercorner with one O(7)LiLa5 octahedra,  a cornercorner with one O(8)LiLa5 octahedra,  an edgeedge with one O(17)LiLa4Co octahedra,  an edgeedge with one O(19)LiLa4Co octahedra,  a faceface with one O(11)La5Co octahedra,  a faceface with one O(14)La5Co octahedra,  a faceface with one O(21)LiLa4Co octahedra,  a faceface with one O(23)LiLa4Co octahedra,  a faceface with one O(4)LiLa5 octahedra,  a faceface with one O(7)LiLa5 octahedra, and faces with two equivalent O(30)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-51°. In the twenty-seventh O site, O(27) is bonded to one Li(1), one La(14), one La(2), one La(7), one La(9), and one Co(2) atom to form distorted OLiLa4Co octahedra that share  a cornercorner with one O(10)La5Co octahedra,  a cornercorner with one O(11)La5Co octahedra,  a cornercorner with one O(12)La5Co octahedra,  a cornercorner with one O(13)La5Co octahedra,  a cornercorner with one O(14)La5Co octahedra,  a cornercorner with one O(15)La5Co octahedra,  a cornercorner with one O(18)LiLa4Co octahedra,  a cornercorner with one O(20)LiLa4Co octahedra,  a cornercorner with one O(1)LiLa5 octahedra,  a cornercorner with one O(3)LiLa5 octahedra,  a cornercorner with one O(4)LiLa5 octahedra,  a cornercorner with one O(5)LiLa5 octahedra,  a cornercorner with one O(6)LiLa5 octahedra,  a cornercorner with one O(7)LiLa5 octahedra,  an edgeedge with one O(18)LiLa4Co octahedra,  an edgeedge with one O(20)LiLa4Co octahedra,  a faceface with one O(10)La5Co octahedra,  a faceface with one O(15)La5Co octahedra,  a faceface with one O(22)LiLa4Co octahedra,  a faceface with one O(24)LiLa4Co octahedra,  a faceface with one O(1)LiLa5 octahedra,  a faceface with one O(6)LiLa5 octahedra, and faces with two equivalent O(31)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-51°. In the twenty-eighth O site, O(28) is bonded to one Li(3), one La(1), one La(11), one La(13), one La(8), and one Co(4) atom to form distorted OLiLa4Co octahedra that share  a cornercorner with one O(10)La5Co octahedra,  a cornercorner with one O(12)La5Co octahedra,  a cornercorner with one O(13)La5Co octahedra,  a cornercorner with one O(15)La5Co octahedra,  a cornercorner with one O(16)La5Co octahedra,  a cornercorner with one O(9)La5Co octahedra,  a cornercorner with one O(17)LiLa4Co octahedra,  a cornercorner with one O(18)LiLa4Co octahedra,  a cornercorner with one O(2)LiLa5 octahedra,  a cornercorner with one O(3)LiLa5 octahedra,  a cornercorner with one O(4)LiLa5 octahedra,  a cornercorner with one O(5)LiLa5 octahedra,  a cornercorner with one O(7)LiLa5 octahedra,  a cornercorner with one O(8)LiLa5 octahedra,  an edgeedge with one O(17)LiLa4Co octahedra,  an edgeedge with one O(18)LiLa4Co octahedra,  a faceface with one O(16)La5Co octahedra,  a faceface with one O(9)La5Co octahedra,  a faceface with one O(21)LiLa4Co octahedra,  a faceface with one O(22)LiLa4Co octahedra,  a faceface with one O(3)LiLa5 octahedra,  a faceface with one O(5)LiLa5 octahedra, and faces with two equivalent O(32)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-51°. In the twenty-ninth O site, O(29) is bonded to one Li(2), one La(10), one La(16), one La(4), one La(5), and one Co(1) atom to form distorted OLiLa4Co octahedra that share  a cornercorner with one O(11)La5Co octahedra,  a cornercorner with one O(12)La5Co octahedra,  a cornercorner with one O(13)La5Co octahedra,  a cornercorner with one O(14)La5Co octahedra,  a cornercorner with one O(16)La5Co octahedra,  a cornercorner with one O(9)La5Co octahedra,  a cornercorner with one O(23)LiLa4Co octahedra,  a cornercorner with one O(24)LiLa4Co octahedra,  a cornercorner with one O(1)LiLa5 octahedra,  a cornercorner with one O(2)LiLa5 octahedra,  a cornercorner with one O(3)LiLa5 octahedra,  a cornercorner with one O(5)LiLa5 octahedra,  a cornercorner with one O(6)LiLa5 octahedra,  a cornercorner with one O(8)LiLa5 octahedra,  an edgeedge with one O(23)LiLa4Co octahedra,  an edgeedge with one O(24)LiLa4Co octahedra,  a faceface with one O(12)La5Co octahedra,  a faceface with one O(13)La5Co octahedra,  a faceface with one O(19)LiLa4Co octahedra,  a faceface with one O(20)LiLa4Co octahedra,  a faceface with one O(2)LiLa5 octahedra,  a faceface with one O(8)LiLa5 octahedra, and faces with two equivalent O(25)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-51°. In the thirtieth O site, O(30) is bonded to one Li(4), one La(12), one La(15), one La(3), one La(6), and one Co(3) atom to form distorted OLiLa4Co octahedra that share  a cornercorner with one O(10)La5Co octahedra,  a cornercorner with one O(11)La5Co octahedra,  a cornercorner with one O(14)La5Co octahedra,  a cornercorner with one O(15)La5Co octahedra,  a cornercorner with one O(16)La5Co octahedra,  a cornercorner with one O(9)La5Co octahedra,  a cornercorner with one O(21)LiLa4Co octahedra,  a cornercorner with one O(23)LiLa4Co octahedra,  a cornercorner with one O(1)LiLa5 octahedra,  a cornercorner with one O(2)LiLa5 octahedra,  a cornercorner with one O(4)LiLa5 octahedra,  a cornercorner with one O(6)LiLa5 octahedra,  a cornercorner with one O(7)LiLa5 octahedra,  a cornercorner with one O(8)LiLa5 octahedra,  an edgeedge with one O(21)LiLa4Co octahedra,  an edgeedge with one O(23)LiLa4Co octahedra,  a faceface with one O(11)La5Co octahedra,  a faceface with one O(14)La5Co octahedra,  a faceface with one O(17)LiLa4Co octahedra,  a faceface with one O(19)LiLa4Co octahedra,  a faceface with one O(4)LiLa5 octahedra,  a faceface with one O(7)LiLa5 octahedra, and faces with two equivalent O(26)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-50°. In the thirty-first O site, O(31) is bonded to one Li(1), one La(14), one La(2), one La(7), one La(9), and one Co(2) atom to form distorted OLiLa4Co octahedra that share  a cornercorner with one O(10)La5Co octahedra,  a cornercorner with one O(11)La5Co octahedra,  a cornercorner with one O(12)La5Co octahedra,  a cornercorner with one O(13)La5Co octahedra,  a cornercorner with one O(14)La5Co octahedra,  a cornercorner with one O(15)La5Co octahedra,  a cornercorner with one O(22)LiLa4Co octahedra,  a cornercorner with one O(24)LiLa4Co octahedra,  a cornercorner with one O(1)LiLa5 octahedra,  a cornercorner with one O(3)LiLa5 octahedra,  a cornercorner with one O(4)LiLa5 octahedra,  a cornercorner with one O(5)LiLa5 octahedra,  a cornercorner with one O(6)LiLa5 octahedra,  a cornercorner with one O(7)LiLa5 octahedra,  an edgeedge with one O(22)LiLa4Co octahedra,  an edgeedge with one O(24)LiLa4Co octahedra,  a faceface with one O(10)La5Co octahedra,  a faceface with one O(15)La5Co octahedra,  a faceface with one O(18)LiLa4Co octahedra,  a faceface with one O(20)LiLa4Co octahedra,  a faceface with one O(1)LiLa5 octahedra,  a faceface with one O(6)LiLa5 octahedra, and faces with two equivalent O(27)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-51°. In the thirty-second O site, O(32) is bonded to one Li(3), one La(1), one La(11), one La(13), one La(8), and one Co(4) atom to form distorted OLiLa4Co octahedra that share  a cornercorner with one O(10)La5Co octahedra,  a cornercorner with one O(12)La5Co octahedra,  a cornercorner with one O(13)La5Co octahedra,  a cornercorner with one O(15)La5Co octahedra,  a cornercorner with one O(16)La5Co octahedra,  a cornercorner with one O(9)La5Co octahedra,  a cornercorner with one O(21)LiLa4Co octahedra,  a cornercorner with one O(22)LiLa4Co octahedra,  a cornercorner with one O(2)LiLa5 octahedra,  a cornercorner with one O(3)LiLa5 octahedra,  a cornercorner with one O(4)LiLa5 octahedra,  a cornercorner with one O(5)LiLa5 octahedra,  a cornercorner with one O(7)LiLa5 octahedra,  a cornercorner with one O(8)LiLa5 octahedra,  an edgeedge with one O(21)LiLa4Co octahedra,  an edgeedge with one O(22)LiLa4Co octahedra,  a faceface with one O(16)La5Co octahedra,  a faceface with one O(9)La5Co octahedra,  a faceface with one O(17)LiLa4Co octahedra,  a faceface with one O(18)LiLa4Co octahedra,  a faceface with one O(3)LiLa5 octahedra,  a faceface with one O(5)LiLa5 octahedra, and faces with two equivalent O(28)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-51°. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiLa4CoO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.369
_cell_length_b   5.373
_cell_length_c   6.980
_cell_angle_alpha   89.859
_cell_angle_beta   67.431
_cell_angle_gamma   89.673
_symmetry_Int_Tables_number   1
_cell_volume   185.938
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  1.000  0.500  0.000  1.0
  La  La1  1  0.362  0.500  0.274  1.0
  La  La2  1  0.638  0.500  0.726  1.0
  La  La3  1  0.138  0.999  0.724  1.0
  La  La4  1  0.862  0.001  0.276  1.0
  Li  Li5  1  0.500  1.000  0.000  1.0
  O  O6  1  0.681  1.000  0.637  1.0
  O  O7  1  0.319  1.000  0.363  1.0
  O  O8  1  0.822  0.499  0.357  1.0
  O  O9  1  0.178  0.501  0.643  1.0
  O  O10  1  0.752  0.254  0.000  1.0
  O  O11  1  0.246  0.256  1.000  1.0
  O  O12  1  0.248  0.746  1.000  1.0
  O  O13  1  0.754  0.744  0.000  1.0
[/CIF]
.