The material described by N2(SO3F)2 is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four ammonia atoms and four SO3F clusters. In each SO3F cluster, S(1) is bonded in a tetrahedral geometry to one O(1), two equivalent O(2), and one F(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. F(1) is bonded in a single-bond geometry to one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SNO3F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.215
_cell_length_b   9.351
_cell_length_c   7.858
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   456.639
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.750  0.918  0.807  1.0
  S  S1  1  0.250  0.082  0.193  1.0
  S  S2  1  0.250  0.582  0.307  1.0
  S  S3  1  0.750  0.418  0.693  1.0
  N  N4  1  0.750  0.824  0.336  1.0
  N  N5  1  0.250  0.176  0.664  1.0
  N  N6  1  0.250  0.676  0.836  1.0
  N  N7  1  0.750  0.324  0.164  1.0
  O  O8  1  0.750  0.811  0.941  1.0
  O  O9  1  0.250  0.189  0.059  1.0
  O  O10  1  0.250  0.689  0.441  1.0
  O  O11  1  0.750  0.311  0.559  1.0
  O  O12  1  0.946  0.919  0.705  1.0
  O  O13  1  0.054  0.081  0.295  1.0
  O  O14  1  0.054  0.581  0.205  1.0
  O  O15  1  0.446  0.081  0.295  1.0
  O  O16  1  0.946  0.419  0.795  1.0
  O  O17  1  0.554  0.919  0.705  1.0
  O  O18  1  0.554  0.419  0.795  1.0
  O  O19  1  0.446  0.581  0.205  1.0
  F  F20  1  0.750  0.568  0.596  1.0
  F  F21  1  0.250  0.432  0.404  1.0
  F  F22  1  0.250  0.932  0.096  1.0
  F  F23  1  0.750  0.068  0.904  1.0
[/CIF]
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The material described by N2(SO3F)2 is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four ammonia atoms and four SO3F clusters. In each SO3F cluster, S(1) is bonded in a tetrahedral geometry to one O(1), two equivalent O(2), and one F(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. F(1) is bonded in a single-bond geometry to one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SNO3F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.215
_cell_length_b   9.351
_cell_length_c   7.858
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   456.639
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.750  0.918  0.807  1.0
  S  S1  1  0.250  0.082  0.193  1.0
  S  S2  1  0.250  0.582  0.307  1.0
  S  S3  1  0.750  0.418  0.693  1.0
  N  N4  1  0.750  0.824  0.336  1.0
  N  N5  1  0.250  0.176  0.664  1.0
  N  N6  1  0.250  0.676  0.836  1.0
  N  N7  1  0.750  0.324  0.164  1.0
  O  O8  1  0.750  0.811  0.941  1.0
  O  O9  1  0.250  0.189  0.059  1.0
  O  O10  1  0.250  0.689  0.441  1.0
  O  O11  1  0.750  0.311  0.559  1.0
  O  O12  1  0.946  0.919  0.705  1.0
  O  O13  1  0.054  0.081  0.295  1.0
  O  O14  1  0.054  0.581  0.205  1.0
  O  O15  1  0.446  0.081  0.295  1.0
  O  O16  1  0.946  0.419  0.795  1.0
  O  O17  1  0.554  0.919  0.705  1.0
  O  O18  1  0.554  0.419  0.795  1.0
  O  O19  1  0.446  0.581  0.205  1.0
  F  F20  1  0.750  0.568  0.596  1.0
  F  F21  1  0.250  0.432  0.404  1.0
  F  F22  1  0.250  0.932  0.096  1.0
  F  F23  1  0.750  0.068  0.904  1.0
[/CIF]
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