The material described by Rb2Mn(OCl2)2 crystallizes in the triclinic P-1 space group. Rb(1) is bonded in a 10-coordinate geometry to two equivalent O(1), four equivalent Cl(1), and four equivalent Cl(2) atoms. Mn(1) is bonded in a distorted octahedral geometry to two equivalent O(1), two equivalent Cl(1), and two equivalent Cl(2) atoms. O(1) is bonded in a single-bond geometry to two equivalent Rb(1) and one Mn(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 5-coordinate geometry to four equivalent Rb(1) and one Mn(1) atom. In the second Cl site, Cl(2) is bonded in a distorted single-bond geometry to four equivalent Rb(1) and one Mn(1) atom. is represented by the CIF file [CIF]
data_Rb2Mn(Cl2O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.958
_cell_length_b   6.822
_cell_length_c   6.859
_cell_angle_alpha   60.874
_cell_angle_beta   84.449
_cell_angle_gamma   86.777
_symmetry_Int_Tables_number   1
_cell_volume   242.370
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.243  0.135  0.172  1.0
  Rb  Rb1  1  0.757  0.865  0.828  1.0
  Mn  Mn2  1  0.000  0.500  0.500  1.0
  Cl  Cl3  1  0.788  0.359  0.852  1.0
  Cl  Cl4  1  0.212  0.641  0.148  1.0
  Cl  Cl5  1  0.237  0.178  0.647  1.0
  Cl  Cl6  1  0.763  0.822  0.353  1.0
  O  O7  1  0.829  0.358  0.421  1.0
  O  O8  1  0.171  0.642  0.579  1.0
[/CIF]
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The material described by Rb2Mn(OCl2)2 crystallizes in the triclinic P-1 space group. Rb(1) is bonded in a 10-coordinate geometry to two equivalent O(1), four equivalent Cl(1), and four equivalent Cl(2) atoms. Mn(1) is bonded in a distorted octahedral geometry to two equivalent O(1), two equivalent Cl(1), and two equivalent Cl(2) atoms. O(1) is bonded in a single-bond geometry to two equivalent Rb(1) and one Mn(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 5-coordinate geometry to four equivalent Rb(1) and one Mn(1) atom. In the second Cl site, Cl(2) is bonded in a distorted single-bond geometry to four equivalent Rb(1) and one Mn(1) atom. is represented by the CIF file [CIF]
data_Rb2Mn(Cl2O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.958
_cell_length_b   6.822
_cell_length_c   6.859
_cell_angle_alpha   60.874
_cell_angle_beta   84.449
_cell_angle_gamma   86.777
_symmetry_Int_Tables_number   1
_cell_volume   242.370
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.243  0.135  0.172  1.0
  Rb  Rb1  1  0.757  0.865  0.828  1.0
  Mn  Mn2  1  0.000  0.500  0.500  1.0
  Cl  Cl3  1  0.788  0.359  0.852  1.0
  Cl  Cl4  1  0.212  0.641  0.148  1.0
  Cl  Cl5  1  0.237  0.178  0.647  1.0
  Cl  Cl6  1  0.763  0.822  0.353  1.0
  O  O7  1  0.829  0.358  0.421  1.0
  O  O8  1  0.171  0.642  0.579  1.0
[/CIF]
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