The compound described by NiC2(N3S)2 is Indium-like structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of two NiC2(N3S)2 clusters. Ni(1) is bonded in an octahedral geometry to two equivalent N(2) and four equivalent N(1) atoms. C(1) is bonded in a distorted linear geometry to one N(2) and one S(1) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Ni(1) atom. In the second N site, N(2) is bonded in a linear geometry to one Ni(1) and one C(1) atom. S(1) is bonded in a single-bond geometry to one C(1) atom. is represented by the CIF file [CIF]
data_NiC2(SN3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.723
_cell_length_b   6.723
_cell_length_c   5.477
_cell_angle_alpha   76.385
_cell_angle_beta   76.385
_cell_angle_gamma   72.029
_symmetry_Int_Tables_number   1
_cell_volume   225.312
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni0  1  0.000  0.000  0.000  1.0
  C  C1  1  0.235  0.235  0.547  1.0
  C  C2  1  0.765  0.765  0.453  1.0
  S  S3  1  0.360  0.360  0.308  1.0
  S  S4  1  0.640  0.640  0.692  1.0
  N  N5  1  0.903  0.248  0.156  1.0
  N  N6  1  0.248  0.903  0.156  1.0
  N  N7  1  0.097  0.752  0.844  1.0
  N  N8  1  0.752  0.097  0.844  1.0
  N  N9  1  0.142  0.142  0.726  1.0
  N  N10  1  0.858  0.858  0.274  1.0
[/CIF]
.
The compound described by NiC2(N3S)2 is Indium-like structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of two NiC2(N3S)2 clusters. Ni(1) is bonded in an octahedral geometry to two equivalent N(2) and four equivalent N(1) atoms. C(1) is bonded in a distorted linear geometry to one N(2) and one S(1) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Ni(1) atom. In the second N site, N(2) is bonded in a linear geometry to one Ni(1) and one C(1) atom. S(1) is bonded in a single-bond geometry to one C(1) atom. is represented by the CIF file [CIF]
data_NiC2(SN3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.723
_cell_length_b   6.723
_cell_length_c   5.477
_cell_angle_alpha   76.385
_cell_angle_beta   76.385
_cell_angle_gamma   72.029
_symmetry_Int_Tables_number   1
_cell_volume   225.312
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni0  1  0.000  0.000  0.000  1.0
  C  C1  1  0.235  0.235  0.547  1.0
  C  C2  1  0.765  0.765  0.453  1.0
  S  S3  1  0.360  0.360  0.308  1.0
  S  S4  1  0.640  0.640  0.692  1.0
  N  N5  1  0.903  0.248  0.156  1.0
  N  N6  1  0.248  0.903  0.156  1.0
  N  N7  1  0.097  0.752  0.844  1.0
  N  N8  1  0.752  0.097  0.844  1.0
  N  N9  1  0.142  0.142  0.726  1.0
  N  N10  1  0.858  0.858  0.274  1.0
[/CIF]
.