The compound described by Li14P2O3N6 crystallizes in the trigonal P-3 space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded to four equivalent N(1) atoms to form distorted LiN4 tetrahedra that share corners with two equivalent Li(3)N3O tetrahedra, corners with two equivalent P(1)N3O tetrahedra, corners with four equivalent Li(2)NO3 tetrahedra, corners with six equivalent Li(1)N4 tetrahedra,  an edgeedge with one Li(3)N3O tetrahedra,  an edgeedge with one P(1)N3O tetrahedra, and edges with three equivalent Li(1)N4 tetrahedra. In the second Li site, Li(2) is bonded to one N(1), one O(2), and two equivalent O(1) atoms to form LiNO3 tetrahedra that share  a cornercorner with one Li(3)N3O tetrahedra,  a cornercorner with one P(1)N3O tetrahedra, corners with four equivalent Li(1)N4 tetrahedra, corners with nine equivalent Li(2)NO3 tetrahedra,  an edgeedge with one Li(3)N3O tetrahedra,  an edgeedge with one P(1)N3O tetrahedra, and edges with three equivalent Li(2)NO3 tetrahedra. In the third Li site, Li(3) is bonded to three equivalent N(1) and one O(2) atom to form LiN3O tetrahedra that share  a cornercorner with one Li(3)N3O tetrahedra, corners with three equivalent Li(2)NO3 tetrahedra, corners with three equivalent P(1)N3O tetrahedra, corners with six equivalent Li(1)N4 tetrahedra, edges with three equivalent Li(1)N4 tetrahedra, and edges with three equivalent Li(2)NO3 tetrahedra. P(1) is bonded to three equivalent N(1) and one O(1) atom to form PN3O tetrahedra that share corners with three equivalent Li(3)N3O tetrahedra, corners with three equivalent Li(2)NO3 tetrahedra, corners with six equivalent Li(1)N4 tetrahedra, edges with three equivalent Li(1)N4 tetrahedra, and edges with three equivalent Li(2)NO3 tetrahedra. N(1) is bonded in a 7-coordinate geometry to one Li(2), one Li(3), four equivalent Li(1), and one P(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded to six equivalent Li(2) and one P(1) atom to form distorted edge-sharing OLi6P hexagonal pyramids. In the second O site, O(2) is bonded in a body-centered cubic geometry to two equivalent Li(3) and six equivalent Li(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li14P2(N2O)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.699
_cell_length_b   5.699
_cell_length_c   8.072
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   227.016
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.378  0.083  0.091  1.0
  Li  Li1  1  0.704  0.622  0.091  1.0
  Li  Li2  1  0.917  0.296  0.091  1.0
  Li  Li3  1  0.622  0.917  0.909  1.0
  Li  Li4  1  0.296  0.378  0.909  1.0
  Li  Li5  1  0.083  0.704  0.909  1.0
  Li  Li6  1  0.043  0.353  0.589  1.0
  Li  Li7  1  0.310  0.957  0.589  1.0
  Li  Li8  1  0.647  0.690  0.589  1.0
  Li  Li9  1  0.957  0.647  0.411  1.0
  Li  Li10  1  0.690  0.043  0.411  1.0
  Li  Li11  1  0.353  0.310  0.411  1.0
  Li  Li12  1  0.000  0.000  0.250  1.0
  Li  Li13  1  0.000  0.000  0.750  1.0
  P  P14  1  0.667  0.333  0.774  1.0
  P  P15  1  0.333  0.667  0.226  1.0
  N  N16  1  0.377  0.071  0.826  1.0
  N  N17  1  0.694  0.623  0.826  1.0
  N  N18  1  0.929  0.306  0.826  1.0
  N  N19  1  0.623  0.929  0.174  1.0
  N  N20  1  0.306  0.377  0.174  1.0
  N  N21  1  0.071  0.694  0.174  1.0
  O  O22  1  0.667  0.333  0.554  1.0
  O  O23  1  0.333  0.667  0.446  1.0
  O  O24  1  0.000  0.000  0.500  1.0
[/CIF]
.
The compound described by Li14P2O3N6 crystallizes in the trigonal P-3 space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded to four equivalent N(1) atoms to form distorted LiN4 tetrahedra that share corners with two equivalent Li(3)N3O tetrahedra, corners with two equivalent P(1)N3O tetrahedra, corners with four equivalent Li(2)NO3 tetrahedra, corners with six equivalent Li(1)N4 tetrahedra,  an edgeedge with one Li(3)N3O tetrahedra,  an edgeedge with one P(1)N3O tetrahedra, and edges with three equivalent Li(1)N4 tetrahedra. In the second Li site, Li(2) is bonded to one N(1), one O(2), and two equivalent O(1) atoms to form LiNO3 tetrahedra that share  a cornercorner with one Li(3)N3O tetrahedra,  a cornercorner with one P(1)N3O tetrahedra, corners with four equivalent Li(1)N4 tetrahedra, corners with nine equivalent Li(2)NO3 tetrahedra,  an edgeedge with one Li(3)N3O tetrahedra,  an edgeedge with one P(1)N3O tetrahedra, and edges with three equivalent Li(2)NO3 tetrahedra. In the third Li site, Li(3) is bonded to three equivalent N(1) and one O(2) atom to form LiN3O tetrahedra that share  a cornercorner with one Li(3)N3O tetrahedra, corners with three equivalent Li(2)NO3 tetrahedra, corners with three equivalent P(1)N3O tetrahedra, corners with six equivalent Li(1)N4 tetrahedra, edges with three equivalent Li(1)N4 tetrahedra, and edges with three equivalent Li(2)NO3 tetrahedra. P(1) is bonded to three equivalent N(1) and one O(1) atom to form PN3O tetrahedra that share corners with three equivalent Li(3)N3O tetrahedra, corners with three equivalent Li(2)NO3 tetrahedra, corners with six equivalent Li(1)N4 tetrahedra, edges with three equivalent Li(1)N4 tetrahedra, and edges with three equivalent Li(2)NO3 tetrahedra. N(1) is bonded in a 7-coordinate geometry to one Li(2), one Li(3), four equivalent Li(1), and one P(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded to six equivalent Li(2) and one P(1) atom to form distorted edge-sharing OLi6P hexagonal pyramids. In the second O site, O(2) is bonded in a body-centered cubic geometry to two equivalent Li(3) and six equivalent Li(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li14P2(N2O)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.699
_cell_length_b   5.699
_cell_length_c   8.072
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   227.016
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.378  0.083  0.091  1.0
  Li  Li1  1  0.704  0.622  0.091  1.0
  Li  Li2  1  0.917  0.296  0.091  1.0
  Li  Li3  1  0.622  0.917  0.909  1.0
  Li  Li4  1  0.296  0.378  0.909  1.0
  Li  Li5  1  0.083  0.704  0.909  1.0
  Li  Li6  1  0.043  0.353  0.589  1.0
  Li  Li7  1  0.310  0.957  0.589  1.0
  Li  Li8  1  0.647  0.690  0.589  1.0
  Li  Li9  1  0.957  0.647  0.411  1.0
  Li  Li10  1  0.690  0.043  0.411  1.0
  Li  Li11  1  0.353  0.310  0.411  1.0
  Li  Li12  1  0.000  0.000  0.250  1.0
  Li  Li13  1  0.000  0.000  0.750  1.0
  P  P14  1  0.667  0.333  0.774  1.0
  P  P15  1  0.333  0.667  0.226  1.0
  N  N16  1  0.377  0.071  0.826  1.0
  N  N17  1  0.694  0.623  0.826  1.0
  N  N18  1  0.929  0.306  0.826  1.0
  N  N19  1  0.623  0.929  0.174  1.0
  N  N20  1  0.306  0.377  0.174  1.0
  N  N21  1  0.071  0.694  0.174  1.0
  O  O22  1  0.667  0.333  0.554  1.0
  O  O23  1  0.333  0.667  0.446  1.0
  O  O24  1  0.000  0.000  0.500  1.0
[/CIF]
.