The material described by Sr(RhIn4)2 crystallizes in the orthorhombic Pbam space group. Sr(1) is bonded in a 13-coordinate geometry to one In(8), two equivalent In(1), two equivalent In(2), two equivalent In(4), two equivalent In(6), two equivalent In(7), and two equivalent In(9) atoms. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 9-coordinate geometry to one In(5), one In(7), one In(8), two equivalent In(4), two equivalent In(6), and two equivalent In(9) atoms. In the second Rh site, Rh(2) is bonded in a 9-coordinate geometry to one In(7), two equivalent In(1), two equivalent In(2), two equivalent In(3), and two equivalent In(5) atoms. There are nine inequivalent In sites. In the first In site, In(9) is bonded in a 12-coordinate geometry to two equivalent Sr(1), two equivalent Rh(1), one In(2), one In(4), two equivalent In(6), two equivalent In(7), and two equivalent In(8) atoms. In the second In site, In(1) is bonded in a 5-coordinate geometry to two equivalent Sr(1), two equivalent Rh(2), and one In(6) atom. In the third In site, In(2) is bonded in a 2-coordinate geometry to two equivalent Sr(1), two equivalent Rh(2), and one In(9) atom. In the fourth In site, In(3) is bonded in a 4-coordinate geometry to four equivalent Rh(2) atoms. In the fifth In site, In(4) is bonded in a 2-coordinate geometry to two equivalent Sr(1), two equivalent Rh(1), and one In(9) atom. In the sixth In site, In(5) is bonded in a 3-coordinate geometry to one Rh(1) and two equivalent Rh(2) atoms. In the seventh In site, In(6) is bonded in a 2-coordinate geometry to two equivalent Sr(1), two equivalent Rh(1), one In(1), and two equivalent In(9) atoms. In the eighth In site, In(7) is bonded in a distorted linear geometry to two equivalent Sr(1), one Rh(1), one Rh(2), and two equivalent In(9) atoms. In the ninth In site, In(8) is bonded in a distorted linear geometry to two equivalent Sr(1), two equivalent Rh(1), and four equivalent In(9) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sr(In4Rh)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.409
_cell_length_b   13.973
_cell_length_c   16.252
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1001.113
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.500  0.843  0.319  1.0
  Sr  Sr1  1  0.500  0.157  0.681  1.0
  Sr  Sr2  1  0.500  0.343  0.181  1.0
  Sr  Sr3  1  0.500  0.657  0.819  1.0
  In  In4  1  0.000  0.834  0.878  1.0
  In  In5  1  0.000  0.166  0.122  1.0
  In  In6  1  0.000  0.334  0.622  1.0
  In  In7  1  0.000  0.666  0.378  1.0
  In  In8  1  0.000  0.550  0.683  1.0
  In  In9  1  0.000  0.450  0.317  1.0
  In  In10  1  0.000  0.050  0.817  1.0
  In  In11  1  0.000  0.950  0.183  1.0
  In  In12  1  0.000  0.000  0.000  1.0
  In  In13  1  0.000  0.500  0.500  1.0
  In  In14  1  0.000  0.760  0.677  1.0
  In  In15  1  0.000  0.240  0.323  1.0
  In  In16  1  0.000  0.260  0.823  1.0
  In  In17  1  0.000  0.740  0.177  1.0
  In  In18  1  0.500  0.841  0.044  1.0
  In  In19  1  0.500  0.159  0.956  1.0
  In  In20  1  0.500  0.341  0.456  1.0
  In  In21  1  0.500  0.659  0.544  1.0
  In  In22  1  0.000  0.670  0.989  1.0
  In  In23  1  0.000  0.330  0.011  1.0
  In  In24  1  0.000  0.170  0.511  1.0
  In  In25  1  0.000  0.830  0.489  1.0
  In  In26  1  0.500  0.600  0.254  1.0
  In  In27  1  0.500  0.400  0.746  1.0
  In  In28  1  0.500  0.100  0.246  1.0
  In  In29  1  0.500  0.900  0.754  1.0
  In  In30  1  0.500  0.500  0.000  1.0
  In  In31  1  0.500  0.000  0.500  1.0
  In  In32  1  0.000  0.979  0.634  1.0
  In  In33  1  0.000  0.021  0.366  1.0
  In  In34  1  0.000  0.479  0.866  1.0
  In  In35  1  0.000  0.521  0.134  1.0
  Rh  Rh36  1  0.500  0.654  0.096  1.0
  Rh  Rh37  1  0.500  0.346  0.904  1.0
  Rh  Rh38  1  0.500  0.154  0.404  1.0
  Rh  Rh39  1  0.500  0.846  0.596  1.0
  Rh  Rh40  1  0.500  0.534  0.405  1.0
  Rh  Rh41  1  0.500  0.466  0.595  1.0
  Rh  Rh42  1  0.500  0.034  0.095  1.0
  Rh  Rh43  1  0.500  0.966  0.905  1.0
[/CIF]
.
The material described by Sr(RhIn4)2 crystallizes in the orthorhombic Pbam space group. Sr(1) is bonded in a 13-coordinate geometry to one In(8), two equivalent In(1), two equivalent In(2), two equivalent In(4), two equivalent In(6), two equivalent In(7), and two equivalent In(9) atoms. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 9-coordinate geometry to one In(5), one In(7), one In(8), two equivalent In(4), two equivalent In(6), and two equivalent In(9) atoms. In the second Rh site, Rh(2) is bonded in a 9-coordinate geometry to one In(7), two equivalent In(1), two equivalent In(2), two equivalent In(3), and two equivalent In(5) atoms. There are nine inequivalent In sites. In the first In site, In(9) is bonded in a 12-coordinate geometry to two equivalent Sr(1), two equivalent Rh(1), one In(2), one In(4), two equivalent In(6), two equivalent In(7), and two equivalent In(8) atoms. In the second In site, In(1) is bonded in a 5-coordinate geometry to two equivalent Sr(1), two equivalent Rh(2), and one In(6) atom. In the third In site, In(2) is bonded in a 2-coordinate geometry to two equivalent Sr(1), two equivalent Rh(2), and one In(9) atom. In the fourth In site, In(3) is bonded in a 4-coordinate geometry to four equivalent Rh(2) atoms. In the fifth In site, In(4) is bonded in a 2-coordinate geometry to two equivalent Sr(1), two equivalent Rh(1), and one In(9) atom. In the sixth In site, In(5) is bonded in a 3-coordinate geometry to one Rh(1) and two equivalent Rh(2) atoms. In the seventh In site, In(6) is bonded in a 2-coordinate geometry to two equivalent Sr(1), two equivalent Rh(1), one In(1), and two equivalent In(9) atoms. In the eighth In site, In(7) is bonded in a distorted linear geometry to two equivalent Sr(1), one Rh(1), one Rh(2), and two equivalent In(9) atoms. In the ninth In site, In(8) is bonded in a distorted linear geometry to two equivalent Sr(1), two equivalent Rh(1), and four equivalent In(9) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sr(In4Rh)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.409
_cell_length_b   13.973
_cell_length_c   16.252
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1001.113
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.500  0.843  0.319  1.0
  Sr  Sr1  1  0.500  0.157  0.681  1.0
  Sr  Sr2  1  0.500  0.343  0.181  1.0
  Sr  Sr3  1  0.500  0.657  0.819  1.0
  In  In4  1  0.000  0.834  0.878  1.0
  In  In5  1  0.000  0.166  0.122  1.0
  In  In6  1  0.000  0.334  0.622  1.0
  In  In7  1  0.000  0.666  0.378  1.0
  In  In8  1  0.000  0.550  0.683  1.0
  In  In9  1  0.000  0.450  0.317  1.0
  In  In10  1  0.000  0.050  0.817  1.0
  In  In11  1  0.000  0.950  0.183  1.0
  In  In12  1  0.000  0.000  0.000  1.0
  In  In13  1  0.000  0.500  0.500  1.0
  In  In14  1  0.000  0.760  0.677  1.0
  In  In15  1  0.000  0.240  0.323  1.0
  In  In16  1  0.000  0.260  0.823  1.0
  In  In17  1  0.000  0.740  0.177  1.0
  In  In18  1  0.500  0.841  0.044  1.0
  In  In19  1  0.500  0.159  0.956  1.0
  In  In20  1  0.500  0.341  0.456  1.0
  In  In21  1  0.500  0.659  0.544  1.0
  In  In22  1  0.000  0.670  0.989  1.0
  In  In23  1  0.000  0.330  0.011  1.0
  In  In24  1  0.000  0.170  0.511  1.0
  In  In25  1  0.000  0.830  0.489  1.0
  In  In26  1  0.500  0.600  0.254  1.0
  In  In27  1  0.500  0.400  0.746  1.0
  In  In28  1  0.500  0.100  0.246  1.0
  In  In29  1  0.500  0.900  0.754  1.0
  In  In30  1  0.500  0.500  0.000  1.0
  In  In31  1  0.500  0.000  0.500  1.0
  In  In32  1  0.000  0.979  0.634  1.0
  In  In33  1  0.000  0.021  0.366  1.0
  In  In34  1  0.000  0.479  0.866  1.0
  In  In35  1  0.000  0.521  0.134  1.0
  Rh  Rh36  1  0.500  0.654  0.096  1.0
  Rh  Rh37  1  0.500  0.346  0.904  1.0
  Rh  Rh38  1  0.500  0.154  0.404  1.0
  Rh  Rh39  1  0.500  0.846  0.596  1.0
  Rh  Rh40  1  0.500  0.534  0.405  1.0
  Rh  Rh41  1  0.500  0.466  0.595  1.0
  Rh  Rh42  1  0.500  0.034  0.095  1.0
  Rh  Rh43  1  0.500  0.966  0.905  1.0
[/CIF]
.