The compound described by V2O5 crystallizes in the orthorhombic Pbam space group. V(1) is bonded in a 5-coordinate geometry to one O(3), two equivalent O(1), and two equivalent O(2) atoms. There are three inequivalent O sites. In the first O site, O(2) is bonded in a distorted single-bond geometry to two equivalent V(1) atoms. In the second O site, O(1) is bonded in a bent 120 degrees geometry to two equivalent V(1) atoms. In the third O site, O(3) is bonded in a linear geometry to two equivalent V(1) atoms. is represented by the CIF card [CIF]
data_V2O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.325
_cell_length_b   5.721
_cell_length_c   10.713
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   203.799
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.000  0.704  0.372  1.0
  V  V1  1  0.000  0.296  0.628  1.0
  V  V2  1  0.000  0.204  0.128  1.0
  V  V3  1  0.000  0.796  0.872  1.0
  O  O4  1  0.500  0.819  0.402  1.0
  O  O5  1  0.500  0.181  0.598  1.0
  O  O6  1  0.500  0.319  0.098  1.0
  O  O7  1  0.500  0.681  0.902  1.0
  O  O8  1  0.000  0.031  0.252  1.0
  O  O9  1  0.000  0.969  0.748  1.0
  O  O10  1  0.000  0.531  0.248  1.0
  O  O11  1  0.000  0.469  0.752  1.0
  O  O12  1  0.000  0.500  0.500  1.0
  O  O13  1  0.000  0.000  0.000  1.0
[/CIF]
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The compound described by V2O5 crystallizes in the orthorhombic Pbam space group. V(1) is bonded in a 5-coordinate geometry to one O(3), two equivalent O(1), and two equivalent O(2) atoms. There are three inequivalent O sites. In the first O site, O(2) is bonded in a distorted single-bond geometry to two equivalent V(1) atoms. In the second O site, O(1) is bonded in a bent 120 degrees geometry to two equivalent V(1) atoms. In the third O site, O(3) is bonded in a linear geometry to two equivalent V(1) atoms. is represented by the CIF card [CIF]
data_V2O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.325
_cell_length_b   5.721
_cell_length_c   10.713
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   203.799
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.000  0.704  0.372  1.0
  V  V1  1  0.000  0.296  0.628  1.0
  V  V2  1  0.000  0.204  0.128  1.0
  V  V3  1  0.000  0.796  0.872  1.0
  O  O4  1  0.500  0.819  0.402  1.0
  O  O5  1  0.500  0.181  0.598  1.0
  O  O6  1  0.500  0.319  0.098  1.0
  O  O7  1  0.500  0.681  0.902  1.0
  O  O8  1  0.000  0.031  0.252  1.0
  O  O9  1  0.000  0.969  0.748  1.0
  O  O10  1  0.000  0.531  0.248  1.0
  O  O11  1  0.000  0.469  0.752  1.0
  O  O12  1  0.000  0.500  0.500  1.0
  O  O13  1  0.000  0.000  0.000  1.0
[/CIF]
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