The compound described by WGeO4 crystallizes in the orthorhombic Pnna space group. W(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles are 32°. Ge(1) is bonded in a rectangular see-saw-like geometry to four equivalent O(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one W(1) and two equivalent Ge(1) atoms. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent W(1) atoms. is represented by the CIF file [CIF]
data_GeWO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.055
_cell_length_b   5.585
_cell_length_c   11.703
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   330.417
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ge  Ge0  1  0.170  0.250  0.000  1.0
  Ge  Ge1  1  0.330  0.250  0.500  1.0
  Ge  Ge2  1  0.830  0.750  0.000  1.0
  Ge  Ge3  1  0.670  0.750  0.500  1.0
  W  W4  1  0.750  0.141  0.250  1.0
  W  W5  1  0.750  0.359  0.750  1.0
  W  W6  1  0.250  0.641  0.250  1.0
  W  W7  1  0.250  0.859  0.750  1.0
  O  O8  1  0.900  0.101  0.099  1.0
  O  O9  1  0.600  0.101  0.401  1.0
  O  O10  1  0.499  0.130  0.796  1.0
  O  O11  1  0.001  0.130  0.704  1.0
  O  O12  1  0.499  0.370  0.204  1.0
  O  O13  1  0.001  0.370  0.296  1.0
  O  O14  1  0.600  0.399  0.599  1.0
  O  O15  1  0.900  0.399  0.901  1.0
  O  O16  1  0.100  0.601  0.099  1.0
  O  O17  1  0.400  0.601  0.401  1.0
  O  O18  1  0.999  0.630  0.704  1.0
  O  O19  1  0.501  0.630  0.796  1.0
  O  O20  1  0.501  0.870  0.204  1.0
  O  O21  1  0.999  0.870  0.296  1.0
  O  O22  1  0.400  0.899  0.599  1.0
  O  O23  1  0.100  0.899  0.901  1.0
[/CIF]
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The compound described by WGeO4 crystallizes in the orthorhombic Pnna space group. W(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles are 32°. Ge(1) is bonded in a rectangular see-saw-like geometry to four equivalent O(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one W(1) and two equivalent Ge(1) atoms. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent W(1) atoms. is represented by the CIF file [CIF]
data_GeWO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.055
_cell_length_b   5.585
_cell_length_c   11.703
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   330.417
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ge  Ge0  1  0.170  0.250  0.000  1.0
  Ge  Ge1  1  0.330  0.250  0.500  1.0
  Ge  Ge2  1  0.830  0.750  0.000  1.0
  Ge  Ge3  1  0.670  0.750  0.500  1.0
  W  W4  1  0.750  0.141  0.250  1.0
  W  W5  1  0.750  0.359  0.750  1.0
  W  W6  1  0.250  0.641  0.250  1.0
  W  W7  1  0.250  0.859  0.750  1.0
  O  O8  1  0.900  0.101  0.099  1.0
  O  O9  1  0.600  0.101  0.401  1.0
  O  O10  1  0.499  0.130  0.796  1.0
  O  O11  1  0.001  0.130  0.704  1.0
  O  O12  1  0.499  0.370  0.204  1.0
  O  O13  1  0.001  0.370  0.296  1.0
  O  O14  1  0.600  0.399  0.599  1.0
  O  O15  1  0.900  0.399  0.901  1.0
  O  O16  1  0.100  0.601  0.099  1.0
  O  O17  1  0.400  0.601  0.401  1.0
  O  O18  1  0.999  0.630  0.704  1.0
  O  O19  1  0.501  0.630  0.796  1.0
  O  O20  1  0.501  0.870  0.204  1.0
  O  O21  1  0.999  0.870  0.296  1.0
  O  O22  1  0.400  0.899  0.599  1.0
  O  O23  1  0.100  0.899  0.901  1.0
[/CIF]
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