The compound described by Ag2GeO3 crystallizes in the orthorhombic P2_12_12_1 space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted see-saw-like geometry to one O(1), one O(2), and two equivalent O(3) atoms. In the second Ag site, Ag(2) is bonded in a distorted rectangular see-saw-like geometry to one O(2), one O(3), and two equivalent O(1) atoms. Ge(1) is bonded to one O(1), one O(3), and two equivalent O(2) atoms to form corner-sharing GeO4 tetrahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded to one Ag(1), two equivalent Ag(2), and one Ge(1) atom to form a mixture of corner and edge-sharing OAg3Ge tetrahedra. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Ag(1), one Ag(2), and two equivalent Ge(1) atoms. In the third O site, O(3) is bonded to one Ag(2), two equivalent Ag(1), and one Ge(1) atom to form a mixture of distorted corner and edge-sharing OAg3Ge tetrahedra. is represented by the CIF card [CIF]
data_Ag2GeO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.670
_cell_length_b   6.978
_cell_length_c   10.538
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   343.458
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.590  0.628  0.625  1.0
  Ag  Ag1  1  0.910  0.372  0.125  1.0
  Ag  Ag2  1  0.090  0.872  0.375  1.0
  Ag  Ag3  1  0.410  0.128  0.875  1.0
  Ag  Ag4  1  0.981  0.393  0.774  1.0
  Ag  Ag5  1  0.519  0.607  0.274  1.0
  Ag  Ag6  1  0.481  0.107  0.226  1.0
  Ag  Ag7  1  0.019  0.893  0.726  1.0
  Ge  Ge8  1  0.523  0.130  0.564  1.0
  Ge  Ge9  1  0.977  0.870  0.064  1.0
  Ge  Ge10  1  0.023  0.370  0.436  1.0
  Ge  Ge11  1  0.477  0.630  0.936  1.0
  O  O12  1  0.698  0.141  0.711  1.0
  O  O13  1  0.802  0.859  0.211  1.0
  O  O14  1  0.198  0.359  0.289  1.0
  O  O15  1  0.302  0.641  0.789  1.0
  O  O16  1  0.277  0.328  0.560  1.0
  O  O17  1  0.223  0.672  0.060  1.0
  O  O18  1  0.777  0.172  0.440  1.0
  O  O19  1  0.723  0.828  0.940  1.0
  O  O20  1  0.647  0.414  0.961  1.0
  O  O21  1  0.853  0.586  0.461  1.0
  O  O22  1  0.147  0.086  0.039  1.0
  O  O23  1  0.353  0.914  0.539  1.0
[/CIF]
.
The compound described by Ag2GeO3 crystallizes in the orthorhombic P2_12_12_1 space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted see-saw-like geometry to one O(1), one O(2), and two equivalent O(3) atoms. In the second Ag site, Ag(2) is bonded in a distorted rectangular see-saw-like geometry to one O(2), one O(3), and two equivalent O(1) atoms. Ge(1) is bonded to one O(1), one O(3), and two equivalent O(2) atoms to form corner-sharing GeO4 tetrahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded to one Ag(1), two equivalent Ag(2), and one Ge(1) atom to form a mixture of corner and edge-sharing OAg3Ge tetrahedra. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Ag(1), one Ag(2), and two equivalent Ge(1) atoms. In the third O site, O(3) is bonded to one Ag(2), two equivalent Ag(1), and one Ge(1) atom to form a mixture of distorted corner and edge-sharing OAg3Ge tetrahedra. is represented by the CIF card [CIF]
data_Ag2GeO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.670
_cell_length_b   6.978
_cell_length_c   10.538
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   343.458
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.590  0.628  0.625  1.0
  Ag  Ag1  1  0.910  0.372  0.125  1.0
  Ag  Ag2  1  0.090  0.872  0.375  1.0
  Ag  Ag3  1  0.410  0.128  0.875  1.0
  Ag  Ag4  1  0.981  0.393  0.774  1.0
  Ag  Ag5  1  0.519  0.607  0.274  1.0
  Ag  Ag6  1  0.481  0.107  0.226  1.0
  Ag  Ag7  1  0.019  0.893  0.726  1.0
  Ge  Ge8  1  0.523  0.130  0.564  1.0
  Ge  Ge9  1  0.977  0.870  0.064  1.0
  Ge  Ge10  1  0.023  0.370  0.436  1.0
  Ge  Ge11  1  0.477  0.630  0.936  1.0
  O  O12  1  0.698  0.141  0.711  1.0
  O  O13  1  0.802  0.859  0.211  1.0
  O  O14  1  0.198  0.359  0.289  1.0
  O  O15  1  0.302  0.641  0.789  1.0
  O  O16  1  0.277  0.328  0.560  1.0
  O  O17  1  0.223  0.672  0.060  1.0
  O  O18  1  0.777  0.172  0.440  1.0
  O  O19  1  0.723  0.828  0.940  1.0
  O  O20  1  0.647  0.414  0.961  1.0
  O  O21  1  0.853  0.586  0.461  1.0
  O  O22  1  0.147  0.086  0.039  1.0
  O  O23  1  0.353  0.914  0.539  1.0
[/CIF]
.