The structure described by CsMoN3O11 crystallizes in the monoclinic C2 space group. There are two inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a distorted cuboctahedral geometry to two equivalent O(1), two equivalent O(10), two equivalent O(11), two equivalent O(3), two equivalent O(8), and two equivalent O(9) atoms. In the second Cs site, Cs(2) is bonded in a 12-coordinate geometry to two equivalent O(11), two equivalent O(2), two equivalent O(5), two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms. Mo(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(6), and one O(9) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(3), one O(4), and one O(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(6), one O(7), and one O(8) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one O(10), one O(11), and one O(9) atom. There are eleven inequivalent O sites. In the first O site, O(7) is bonded in a single-bond geometry to one Cs(2) and one N(2) atom. In the second O site, O(8) is bonded in a single-bond geometry to one Cs(1), one Cs(2), and one N(2) atom. In the third O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Cs(1), one Mo(1), and one N(3) atom. In the fourth O site, O(10) is bonded in a single-bond geometry to one Cs(1) and one N(3) atom. In the fifth O site, O(11) is bonded in a single-bond geometry to one Cs(1), one Cs(2), and one N(3) atom. In the sixth O site, O(1) is bonded in a single-bond geometry to one Cs(1) and one Mo(1) atom. In the seventh O site, O(2) is bonded in a single-bond geometry to one Cs(2) and one Mo(1) atom. In the eighth O site, O(3) is bonded in a 2-coordinate geometry to one Cs(1), one Mo(1), and one N(1) atom. In the ninth O site, O(4) is bonded in a distorted single-bond geometry to one Mo(1) and one N(1) atom. In the tenth O site, O(5) is bonded in a single-bond geometry to one Cs(2) and one N(1) atom. In the eleventh O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Cs(2), one Mo(1), and one N(2) atom. is represented by the CIF card [CIF]
data_CsMoN3O11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.683
_cell_length_b   7.683
_cell_length_c   9.977
_cell_angle_alpha   69.604
_cell_angle_beta   69.604
_cell_angle_gamma   65.255
_symmetry_Int_Tables_number   1
_cell_volume   486.908
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.999  0.001  0.000  1.0
  Cs  Cs1  1  0.608  0.392  0.500  1.0
  Mo  Mo2  1  0.693  0.701  0.786  1.0
  Mo  Mo3  1  0.299  0.307  0.214  1.0
  N  N4  1  0.077  0.682  0.716  1.0
  N  N5  1  0.318  0.923  0.284  1.0
  N  N6  1  0.791  0.862  0.454  1.0
  N  N7  1  0.138  0.209  0.546  1.0
  N  N8  1  0.785  0.523  0.083  1.0
  N  N9  1  0.477  0.215  0.917  1.0
  O  O10  1  0.474  0.835  0.875  1.0
  O  O11  1  0.165  0.526  0.125  1.0
  O  O12  1  0.646  0.541  0.735  1.0
  O  O13  1  0.459  0.354  0.265  1.0
  O  O14  1  0.927  0.785  0.800  1.0
  O  O15  1  0.215  0.073  0.200  1.0
  O  O16  1  0.036  0.571  0.671  1.0
  O  O17  1  0.429  0.964  0.329  1.0
  O  O18  1  0.239  0.696  0.684  1.0
  O  O19  1  0.304  0.761  0.316  1.0
  O  O20  1  0.721  0.899  0.592  1.0
  O  O21  1  0.101  0.279  0.408  1.0
  O  O22  1  0.822  0.698  0.442  1.0
  O  O23  1  0.302  0.178  0.558  1.0
  O  O24  1  0.816  0.004  0.355  1.0
  O  O25  1  0.996  0.184  0.645  1.0
  O  O26  1  0.788  0.485  0.960  1.0
  O  O27  1  0.515  0.212  0.040  1.0
  O  O28  1  0.714  0.695  0.094  1.0
  O  O29  1  0.305  0.286  0.906  1.0
  O  O30  1  0.855  0.377  0.174  1.0
  O  O31  1  0.623  0.145  0.826  1.0
[/CIF]
.
The structure described by CsMoN3O11 crystallizes in the monoclinic C2 space group. There are two inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a distorted cuboctahedral geometry to two equivalent O(1), two equivalent O(10), two equivalent O(11), two equivalent O(3), two equivalent O(8), and two equivalent O(9) atoms. In the second Cs site, Cs(2) is bonded in a 12-coordinate geometry to two equivalent O(11), two equivalent O(2), two equivalent O(5), two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms. Mo(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(6), and one O(9) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(3), one O(4), and one O(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(6), one O(7), and one O(8) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one O(10), one O(11), and one O(9) atom. There are eleven inequivalent O sites. In the first O site, O(7) is bonded in a single-bond geometry to one Cs(2) and one N(2) atom. In the second O site, O(8) is bonded in a single-bond geometry to one Cs(1), one Cs(2), and one N(2) atom. In the third O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Cs(1), one Mo(1), and one N(3) atom. In the fourth O site, O(10) is bonded in a single-bond geometry to one Cs(1) and one N(3) atom. In the fifth O site, O(11) is bonded in a single-bond geometry to one Cs(1), one Cs(2), and one N(3) atom. In the sixth O site, O(1) is bonded in a single-bond geometry to one Cs(1) and one Mo(1) atom. In the seventh O site, O(2) is bonded in a single-bond geometry to one Cs(2) and one Mo(1) atom. In the eighth O site, O(3) is bonded in a 2-coordinate geometry to one Cs(1), one Mo(1), and one N(1) atom. In the ninth O site, O(4) is bonded in a distorted single-bond geometry to one Mo(1) and one N(1) atom. In the tenth O site, O(5) is bonded in a single-bond geometry to one Cs(2) and one N(1) atom. In the eleventh O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Cs(2), one Mo(1), and one N(2) atom. is represented by the CIF card [CIF]
data_CsMoN3O11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.683
_cell_length_b   7.683
_cell_length_c   9.977
_cell_angle_alpha   69.604
_cell_angle_beta   69.604
_cell_angle_gamma   65.255
_symmetry_Int_Tables_number   1
_cell_volume   486.908
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.999  0.001  0.000  1.0
  Cs  Cs1  1  0.608  0.392  0.500  1.0
  Mo  Mo2  1  0.693  0.701  0.786  1.0
  Mo  Mo3  1  0.299  0.307  0.214  1.0
  N  N4  1  0.077  0.682  0.716  1.0
  N  N5  1  0.318  0.923  0.284  1.0
  N  N6  1  0.791  0.862  0.454  1.0
  N  N7  1  0.138  0.209  0.546  1.0
  N  N8  1  0.785  0.523  0.083  1.0
  N  N9  1  0.477  0.215  0.917  1.0
  O  O10  1  0.474  0.835  0.875  1.0
  O  O11  1  0.165  0.526  0.125  1.0
  O  O12  1  0.646  0.541  0.735  1.0
  O  O13  1  0.459  0.354  0.265  1.0
  O  O14  1  0.927  0.785  0.800  1.0
  O  O15  1  0.215  0.073  0.200  1.0
  O  O16  1  0.036  0.571  0.671  1.0
  O  O17  1  0.429  0.964  0.329  1.0
  O  O18  1  0.239  0.696  0.684  1.0
  O  O19  1  0.304  0.761  0.316  1.0
  O  O20  1  0.721  0.899  0.592  1.0
  O  O21  1  0.101  0.279  0.408  1.0
  O  O22  1  0.822  0.698  0.442  1.0
  O  O23  1  0.302  0.178  0.558  1.0
  O  O24  1  0.816  0.004  0.355  1.0
  O  O25  1  0.996  0.184  0.645  1.0
  O  O26  1  0.788  0.485  0.960  1.0
  O  O27  1  0.515  0.212  0.040  1.0
  O  O28  1  0.714  0.695  0.094  1.0
  O  O29  1  0.305  0.286  0.906  1.0
  O  O30  1  0.855  0.377  0.174  1.0
  O  O31  1  0.623  0.145  0.826  1.0
[/CIF]
.