The structure described by V2PbO2 crystallizes in the tetragonal I4_1/amd space group. V(1) is bonded in a single-bond geometry to two equivalent Pb(1) and one O(1) atom. Pb(1) is bonded in a 6-coordinate geometry to four equivalent V(1) and two equivalent O(1) atoms. O(1) is bonded in a distorted single-bond geometry to one V(1) and one Pb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_V2PbO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.606
_cell_length_b   8.606
_cell_length_c   8.606
_cell_angle_alpha   125.553
_cell_angle_beta   125.553
_cell_angle_gamma   80.623
_symmetry_Int_Tables_number   1
_cell_volume   406.867
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.573  0.336  0.763  1.0
  V  V1  1  0.573  0.810  0.237  1.0
  V  V2  1  0.560  0.823  0.737  1.0
  V  V3  1  0.177  0.440  0.263  1.0
  V  V4  1  0.177  0.914  0.737  1.0
  V  V5  1  0.086  0.823  0.263  1.0
  V  V6  1  0.190  0.427  0.763  1.0
  V  V7  1  0.664  0.427  0.237  1.0
  Pb  Pb8  1  0.875  0.125  0.250  1.0
  Pb  Pb9  1  0.875  0.625  0.750  1.0
  Pb  Pb10  1  0.375  0.125  0.250  1.0
  Pb  Pb11  1  0.875  0.125  0.750  1.0
  O  O12  1  0.695  0.530  0.835  1.0
  O  O13  1  0.695  0.859  0.165  1.0
  O  O14  1  0.609  0.945  0.665  1.0
  O  O15  1  0.055  0.391  0.335  1.0
  O  O16  1  0.055  0.720  0.665  1.0
  O  O17  1  0.280  0.945  0.335  1.0
  O  O18  1  0.141  0.305  0.835  1.0
  O  O19  1  0.470  0.305  0.165  1.0
[/CIF]
.
The structure described by V2PbO2 crystallizes in the tetragonal I4_1/amd space group. V(1) is bonded in a single-bond geometry to two equivalent Pb(1) and one O(1) atom. Pb(1) is bonded in a 6-coordinate geometry to four equivalent V(1) and two equivalent O(1) atoms. O(1) is bonded in a distorted single-bond geometry to one V(1) and one Pb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_V2PbO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.606
_cell_length_b   8.606
_cell_length_c   8.606
_cell_angle_alpha   125.553
_cell_angle_beta   125.553
_cell_angle_gamma   80.623
_symmetry_Int_Tables_number   1
_cell_volume   406.867
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.573  0.336  0.763  1.0
  V  V1  1  0.573  0.810  0.237  1.0
  V  V2  1  0.560  0.823  0.737  1.0
  V  V3  1  0.177  0.440  0.263  1.0
  V  V4  1  0.177  0.914  0.737  1.0
  V  V5  1  0.086  0.823  0.263  1.0
  V  V6  1  0.190  0.427  0.763  1.0
  V  V7  1  0.664  0.427  0.237  1.0
  Pb  Pb8  1  0.875  0.125  0.250  1.0
  Pb  Pb9  1  0.875  0.625  0.750  1.0
  Pb  Pb10  1  0.375  0.125  0.250  1.0
  Pb  Pb11  1  0.875  0.125  0.750  1.0
  O  O12  1  0.695  0.530  0.835  1.0
  O  O13  1  0.695  0.859  0.165  1.0
  O  O14  1  0.609  0.945  0.665  1.0
  O  O15  1  0.055  0.391  0.335  1.0
  O  O16  1  0.055  0.720  0.665  1.0
  O  O17  1  0.280  0.945  0.335  1.0
  O  O18  1  0.141  0.305  0.835  1.0
  O  O19  1  0.470  0.305  0.165  1.0
[/CIF]
.