The compound described by Ho2N3 is Spinel-derived structured and crystallizes in the cubic Ia-3 space group. There are two inequivalent Ho sites. In the first Ho site, Ho(1) is bonded to six equivalent N(1) atoms to form a mixture of distorted edge and corner-sharing HoN6 octahedra. The corner-sharing octahedral tilt angles range from 56-58°. In the second Ho site, Ho(2) is bonded to six equivalent N(1) atoms to form a mixture of distorted edge and corner-sharing HoN6 octahedra. The corner-sharing octahedral tilt angles are 58°. N(1) is bonded to one Ho(2) and three equivalent Ho(1) atoms to form a mixture of edge and corner-sharing NHo4 tetrahedra. is represented by the CIF file [CIF]
data_Ho2N3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.450
_cell_length_b   9.450
_cell_length_c   9.450
_cell_angle_alpha   109.471
_cell_angle_beta   109.471
_cell_angle_gamma   109.471
_symmetry_Int_Tables_number   1
_cell_volume   649.556
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ho  Ho0  1  0.780  0.250  0.030  1.0
  Ho  Ho1  1  0.720  0.750  0.470  1.0
  Ho  Ho2  1  0.250  0.030  0.780  1.0
  Ho  Ho3  1  0.750  0.470  0.720  1.0
  Ho  Ho4  1  0.030  0.780  0.250  1.0
  Ho  Ho5  1  0.470  0.720  0.750  1.0
  Ho  Ho6  1  0.220  0.750  0.970  1.0
  Ho  Ho7  1  0.280  0.250  0.530  1.0
  Ho  Ho8  1  0.750  0.970  0.220  1.0
  Ho  Ho9  1  0.250  0.530  0.280  1.0
  Ho  Ho10  1  0.970  0.220  0.750  1.0
  Ho  Ho11  1  0.530  0.280  0.250  1.0
  Ho  Ho12  1  0.500  0.000  0.500  1.0
  Ho  Ho13  1  0.500  0.500  0.000  1.0
  Ho  Ho14  1  0.000  0.500  0.500  1.0
  Ho  Ho15  1  0.000  0.000  0.000  1.0
  N  N16  1  0.491  0.231  0.463  1.0
  N  N17  1  0.233  0.269  0.760  1.0
  N  N18  1  0.009  0.473  0.740  1.0
  N  N19  1  0.267  0.027  0.037  1.0
  N  N20  1  0.231  0.463  0.491  1.0
  N  N21  1  0.269  0.760  0.233  1.0
  N  N22  1  0.473  0.740  0.009  1.0
  N  N23  1  0.027  0.037  0.267  1.0
  N  N24  1  0.463  0.491  0.231  1.0
  N  N25  1  0.760  0.233  0.269  1.0
  N  N26  1  0.740  0.009  0.473  1.0
  N  N27  1  0.037  0.267  0.027  1.0
  N  N28  1  0.509  0.769  0.537  1.0
  N  N29  1  0.767  0.731  0.240  1.0
  N  N30  1  0.991  0.527  0.260  1.0
  N  N31  1  0.733  0.973  0.963  1.0
  N  N32  1  0.769  0.537  0.509  1.0
  N  N33  1  0.731  0.240  0.767  1.0
  N  N34  1  0.527  0.260  0.991  1.0
  N  N35  1  0.973  0.963  0.733  1.0
  N  N36  1  0.537  0.509  0.769  1.0
  N  N37  1  0.240  0.767  0.731  1.0
  N  N38  1  0.260  0.991  0.527  1.0
  N  N39  1  0.963  0.733  0.973  1.0
[/CIF]
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The compound described by Ho2N3 is Spinel-derived structured and crystallizes in the cubic Ia-3 space group. There are two inequivalent Ho sites. In the first Ho site, Ho(1) is bonded to six equivalent N(1) atoms to form a mixture of distorted edge and corner-sharing HoN6 octahedra. The corner-sharing octahedral tilt angles range from 56-58°. In the second Ho site, Ho(2) is bonded to six equivalent N(1) atoms to form a mixture of distorted edge and corner-sharing HoN6 octahedra. The corner-sharing octahedral tilt angles are 58°. N(1) is bonded to one Ho(2) and three equivalent Ho(1) atoms to form a mixture of edge and corner-sharing NHo4 tetrahedra. is represented by the CIF file [CIF]
data_Ho2N3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.450
_cell_length_b   9.450
_cell_length_c   9.450
_cell_angle_alpha   109.471
_cell_angle_beta   109.471
_cell_angle_gamma   109.471
_symmetry_Int_Tables_number   1
_cell_volume   649.556
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ho  Ho0  1  0.780  0.250  0.030  1.0
  Ho  Ho1  1  0.720  0.750  0.470  1.0
  Ho  Ho2  1  0.250  0.030  0.780  1.0
  Ho  Ho3  1  0.750  0.470  0.720  1.0
  Ho  Ho4  1  0.030  0.780  0.250  1.0
  Ho  Ho5  1  0.470  0.720  0.750  1.0
  Ho  Ho6  1  0.220  0.750  0.970  1.0
  Ho  Ho7  1  0.280  0.250  0.530  1.0
  Ho  Ho8  1  0.750  0.970  0.220  1.0
  Ho  Ho9  1  0.250  0.530  0.280  1.0
  Ho  Ho10  1  0.970  0.220  0.750  1.0
  Ho  Ho11  1  0.530  0.280  0.250  1.0
  Ho  Ho12  1  0.500  0.000  0.500  1.0
  Ho  Ho13  1  0.500  0.500  0.000  1.0
  Ho  Ho14  1  0.000  0.500  0.500  1.0
  Ho  Ho15  1  0.000  0.000  0.000  1.0
  N  N16  1  0.491  0.231  0.463  1.0
  N  N17  1  0.233  0.269  0.760  1.0
  N  N18  1  0.009  0.473  0.740  1.0
  N  N19  1  0.267  0.027  0.037  1.0
  N  N20  1  0.231  0.463  0.491  1.0
  N  N21  1  0.269  0.760  0.233  1.0
  N  N22  1  0.473  0.740  0.009  1.0
  N  N23  1  0.027  0.037  0.267  1.0
  N  N24  1  0.463  0.491  0.231  1.0
  N  N25  1  0.760  0.233  0.269  1.0
  N  N26  1  0.740  0.009  0.473  1.0
  N  N27  1  0.037  0.267  0.027  1.0
  N  N28  1  0.509  0.769  0.537  1.0
  N  N29  1  0.767  0.731  0.240  1.0
  N  N30  1  0.991  0.527  0.260  1.0
  N  N31  1  0.733  0.973  0.963  1.0
  N  N32  1  0.769  0.537  0.509  1.0
  N  N33  1  0.731  0.240  0.767  1.0
  N  N34  1  0.527  0.260  0.991  1.0
  N  N35  1  0.973  0.963  0.733  1.0
  N  N36  1  0.537  0.509  0.769  1.0
  N  N37  1  0.240  0.767  0.731  1.0
  N  N38  1  0.260  0.991  0.527  1.0
  N  N39  1  0.963  0.733  0.973  1.0
[/CIF]
.