The material described by MgP2(H2O3)4(H2O)4H2O2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four water molecules, two water molecules, and one MgP2(H2O3)4 cluster. In the MgP2(H2O3)4 cluster, Mg(1) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(8) atoms to form MgO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra. P(1) is bonded to one O(5), one O(6), one O(8), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Mg(1)O6 octahedra. The corner-sharing octahedral tilt angles are 47°. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(2) atom. In the second H site, H(3) is bonded in a single-bond geometry to one O(2) atom. In the third H site, H(4) is bonded in a distorted single-bond geometry to one O(4) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one O(4) atom. There are six inequivalent O sites. In the first O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Mg(1) and one P(1) atom. In the second O site, O(9) is bonded in a single-bond geometry to one P(1) atom. In the third O site, O(2) is bonded in a 3-coordinate geometry to one Mg(1), one H(1), and one H(3) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Mg(1), one H(4), and one H(6) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one P(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one P(1) atom. is represented by the CIF card [CIF]
data_MgP2(HO)18
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.876
_cell_length_b   7.030
_cell_length_c   10.606
_cell_angle_alpha   71.498
_cell_angle_beta   75.218
_cell_angle_gamma   71.321
_symmetry_Int_Tables_number   1
_cell_volume   387.815
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.000  0.500  0.500  1.0
  P  P1  1  0.675  0.428  0.818  1.0
  P  P2  1  0.325  0.572  0.182  1.0
  H  H3  1  0.619  0.513  0.376  1.0
  H  H4  1  0.381  0.487  0.624  1.0
  H  H5  1  0.757  0.142  0.172  1.0
  H  H6  1  0.243  0.858  0.828  1.0
  H  H7  1  0.118  0.530  0.715  1.0
  H  H8  1  0.882  0.470  0.285  1.0
  H  H9  1  0.220  0.094  0.601  1.0
  H  H10  1  0.780  0.906  0.399  1.0
  H  H11  1  0.559  0.021  0.252  1.0
  H  H12  1  0.441  0.979  0.748  1.0
  H  H13  1  0.215  0.117  0.444  1.0
  H  H14  1  0.785  0.883  0.556  1.0
  H  H15  1  0.751  0.134  0.674  1.0
  H  H16  1  0.249  0.866  0.326  1.0
  H  H17  1  0.180  0.084  0.227  1.0
  H  H18  1  0.820  0.916  0.773  1.0
  H  H19  1  0.338  0.210  0.978  1.0
  H  H20  1  0.662  0.790  0.022  1.0
  O  O21  1  0.736  0.012  0.239  1.0
  O  O22  1  0.264  0.988  0.761  1.0
  O  O23  1  0.207  0.528  0.622  1.0
  O  O24  1  0.793  0.472  0.378  1.0
  O  O25  1  0.833  0.793  0.974  1.0
  O  O26  1  0.167  0.207  0.026  1.0
  O  O27  1  0.200  0.194  0.511  1.0
  O  O28  1  0.800  0.806  0.489  1.0
  O  O29  1  0.860  0.519  0.846  1.0
  O  O30  1  0.140  0.481  0.154  1.0
  O  O31  1  0.647  0.223  0.923  1.0
  O  O32  1  0.353  0.777  0.077  1.0
  O  O33  1  0.258  0.011  0.307  1.0
  O  O34  1  0.742  0.989  0.693  1.0
  O  O35  1  0.739  0.402  0.673  1.0
  O  O36  1  0.261  0.598  0.327  1.0
  O  O37  1  0.413  0.571  0.841  1.0
  O  O38  1  0.587  0.429  0.159  1.0
[/CIF]
.
The material described by MgP2(H2O3)4(H2O)4H2O2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four water molecules, two water molecules, and one MgP2(H2O3)4 cluster. In the MgP2(H2O3)4 cluster, Mg(1) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(8) atoms to form MgO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra. P(1) is bonded to one O(5), one O(6), one O(8), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Mg(1)O6 octahedra. The corner-sharing octahedral tilt angles are 47°. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(2) atom. In the second H site, H(3) is bonded in a single-bond geometry to one O(2) atom. In the third H site, H(4) is bonded in a distorted single-bond geometry to one O(4) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one O(4) atom. There are six inequivalent O sites. In the first O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Mg(1) and one P(1) atom. In the second O site, O(9) is bonded in a single-bond geometry to one P(1) atom. In the third O site, O(2) is bonded in a 3-coordinate geometry to one Mg(1), one H(1), and one H(3) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Mg(1), one H(4), and one H(6) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one P(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one P(1) atom. is represented by the CIF card [CIF]
data_MgP2(HO)18
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.876
_cell_length_b   7.030
_cell_length_c   10.606
_cell_angle_alpha   71.498
_cell_angle_beta   75.218
_cell_angle_gamma   71.321
_symmetry_Int_Tables_number   1
_cell_volume   387.815
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.000  0.500  0.500  1.0
  P  P1  1  0.675  0.428  0.818  1.0
  P  P2  1  0.325  0.572  0.182  1.0
  H  H3  1  0.619  0.513  0.376  1.0
  H  H4  1  0.381  0.487  0.624  1.0
  H  H5  1  0.757  0.142  0.172  1.0
  H  H6  1  0.243  0.858  0.828  1.0
  H  H7  1  0.118  0.530  0.715  1.0
  H  H8  1  0.882  0.470  0.285  1.0
  H  H9  1  0.220  0.094  0.601  1.0
  H  H10  1  0.780  0.906  0.399  1.0
  H  H11  1  0.559  0.021  0.252  1.0
  H  H12  1  0.441  0.979  0.748  1.0
  H  H13  1  0.215  0.117  0.444  1.0
  H  H14  1  0.785  0.883  0.556  1.0
  H  H15  1  0.751  0.134  0.674  1.0
  H  H16  1  0.249  0.866  0.326  1.0
  H  H17  1  0.180  0.084  0.227  1.0
  H  H18  1  0.820  0.916  0.773  1.0
  H  H19  1  0.338  0.210  0.978  1.0
  H  H20  1  0.662  0.790  0.022  1.0
  O  O21  1  0.736  0.012  0.239  1.0
  O  O22  1  0.264  0.988  0.761  1.0
  O  O23  1  0.207  0.528  0.622  1.0
  O  O24  1  0.793  0.472  0.378  1.0
  O  O25  1  0.833  0.793  0.974  1.0
  O  O26  1  0.167  0.207  0.026  1.0
  O  O27  1  0.200  0.194  0.511  1.0
  O  O28  1  0.800  0.806  0.489  1.0
  O  O29  1  0.860  0.519  0.846  1.0
  O  O30  1  0.140  0.481  0.154  1.0
  O  O31  1  0.647  0.223  0.923  1.0
  O  O32  1  0.353  0.777  0.077  1.0
  O  O33  1  0.258  0.011  0.307  1.0
  O  O34  1  0.742  0.989  0.693  1.0
  O  O35  1  0.739  0.402  0.673  1.0
  O  O36  1  0.261  0.598  0.327  1.0
  O  O37  1  0.413  0.571  0.841  1.0
  O  O38  1  0.587  0.429  0.159  1.0
[/CIF]
.