The crystal structure described by HgN6 is Indium-like structured and crystallizes in the orthorhombic Pca2_1 space group. The structure is zero-dimensional and consists of four HgN6 clusters. Hg(1) is bonded in a linear geometry to one N(1) and one N(4) atom. There are six inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Hg(1) and one N(2) atom. In the second N site, N(2) is bonded in a linear geometry to one N(1) and one N(3) atom. In the third N site, N(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to one Hg(1) and one N(5) atom. In the fifth N site, N(5) is bonded in a linear geometry to one N(4) and one N(6) atom. In the sixth N site, N(6) is bonded in a single-bond geometry to one N(5) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_HgN6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.427
_cell_length_b   6.765
_cell_length_c   11.052
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   480.538
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Hg  Hg0  1  0.240  0.936  0.530  1.0
  Hg  Hg1  1  0.760  0.436  0.470  1.0
  Hg  Hg2  1  0.240  0.436  0.970  1.0
  Hg  Hg3  1  0.760  0.936  0.030  1.0
  N  N4  1  0.965  0.077  0.580  1.0
  N  N5  1  0.035  0.577  0.420  1.0
  N  N6  1  0.965  0.577  0.920  1.0
  N  N7  1  0.035  0.077  0.080  1.0
  N  N8  1  0.900  0.070  0.684  1.0
  N  N9  1  0.100  0.570  0.316  1.0
  N  N10  1  0.900  0.570  0.816  1.0
  N  N11  1  0.100  0.070  0.184  1.0
  N  N12  1  0.822  0.074  0.778  1.0
  N  N13  1  0.178  0.574  0.222  1.0
  N  N14  1  0.822  0.574  0.722  1.0
  N  N15  1  0.178  0.074  0.278  1.0
  N  N16  1  0.517  0.814  0.463  1.0
  N  N17  1  0.483  0.314  0.537  1.0
  N  N18  1  0.517  0.314  0.037  1.0
  N  N19  1  0.483  0.814  0.963  1.0
  N  N20  1  0.599  0.915  0.385  1.0
  N  N21  1  0.401  0.415  0.615  1.0
  N  N22  1  0.599  0.415  0.115  1.0
  N  N23  1  0.401  0.915  0.885  1.0
  N  N24  1  0.688  0.003  0.311  1.0
  N  N25  1  0.312  0.503  0.689  1.0
  N  N26  1  0.688  0.503  0.189  1.0
  N  N27  1  0.312  0.003  0.811  1.0
[/CIF]
.
The crystal structure described by HgN6 is Indium-like structured and crystallizes in the orthorhombic Pca2_1 space group. The structure is zero-dimensional and consists of four HgN6 clusters. Hg(1) is bonded in a linear geometry to one N(1) and one N(4) atom. There are six inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Hg(1) and one N(2) atom. In the second N site, N(2) is bonded in a linear geometry to one N(1) and one N(3) atom. In the third N site, N(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to one Hg(1) and one N(5) atom. In the fifth N site, N(5) is bonded in a linear geometry to one N(4) and one N(6) atom. In the sixth N site, N(6) is bonded in a single-bond geometry to one N(5) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_HgN6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.427
_cell_length_b   6.765
_cell_length_c   11.052
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   480.538
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Hg  Hg0  1  0.240  0.936  0.530  1.0
  Hg  Hg1  1  0.760  0.436  0.470  1.0
  Hg  Hg2  1  0.240  0.436  0.970  1.0
  Hg  Hg3  1  0.760  0.936  0.030  1.0
  N  N4  1  0.965  0.077  0.580  1.0
  N  N5  1  0.035  0.577  0.420  1.0
  N  N6  1  0.965  0.577  0.920  1.0
  N  N7  1  0.035  0.077  0.080  1.0
  N  N8  1  0.900  0.070  0.684  1.0
  N  N9  1  0.100  0.570  0.316  1.0
  N  N10  1  0.900  0.570  0.816  1.0
  N  N11  1  0.100  0.070  0.184  1.0
  N  N12  1  0.822  0.074  0.778  1.0
  N  N13  1  0.178  0.574  0.222  1.0
  N  N14  1  0.822  0.574  0.722  1.0
  N  N15  1  0.178  0.074  0.278  1.0
  N  N16  1  0.517  0.814  0.463  1.0
  N  N17  1  0.483  0.314  0.537  1.0
  N  N18  1  0.517  0.314  0.037  1.0
  N  N19  1  0.483  0.814  0.963  1.0
  N  N20  1  0.599  0.915  0.385  1.0
  N  N21  1  0.401  0.415  0.615  1.0
  N  N22  1  0.599  0.415  0.115  1.0
  N  N23  1  0.401  0.915  0.885  1.0
  N  N24  1  0.688  0.003  0.311  1.0
  N  N25  1  0.312  0.503  0.689  1.0
  N  N26  1  0.688  0.503  0.189  1.0
  N  N27  1  0.312  0.003  0.811  1.0
[/CIF]
.