The crystal structure described by CsMg6W crystallizes in the orthorhombic Amm2 space group. Cs(1) is bonded to two equivalent Mg(3), two equivalent Mg(4), four equivalent Mg(1), and four equivalent Mg(2) atoms to form CsMg12 cuboctahedra that share corners with four equivalent Cs(1)Mg12 cuboctahedra, edges with eight equivalent Mg(1)Cs2Mg8W2 cuboctahedra, faces with two equivalent Cs(1)Mg12 cuboctahedra, and faces with four equivalent Mg(1)Cs2Mg8W2 cuboctahedra. There are four inequivalent Mg sites. In the first Mg site, Mg(1) is bonded to two equivalent Cs(1), two equivalent Mg(3), two equivalent Mg(4), four equivalent Mg(2), and two equivalent W(1) atoms to form MgCs2Mg8W2 cuboctahedra that share corners with twelve equivalent Mg(1)Cs2Mg8W2 cuboctahedra, edges with four equivalent Cs(1)Mg12 cuboctahedra, faces with two equivalent Cs(1)Mg12 cuboctahedra, and faces with six equivalent Mg(1)Cs2Mg8W2 cuboctahedra. In the second Mg site, Mg(2) is bonded in a distorted L-shaped geometry to two equivalent Cs(1), four equivalent Mg(1), and two equivalent W(1) atoms. In the third Mg site, Mg(3) is bonded in a distorted L-shaped geometry to two equivalent Cs(1), four equivalent Mg(1), and two equivalent W(1) atoms. In the fourth Mg site, Mg(4) is bonded in a distorted L-shaped geometry to two equivalent Cs(1), four equivalent Mg(1), and two equivalent W(1) atoms. W(1) is bonded in a 8-coordinate geometry to two equivalent Mg(3), two equivalent Mg(4), four equivalent Mg(1), and four equivalent Mg(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_CsMg6W
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.198
_cell_length_b   6.969
_cell_length_c   6.969
_cell_angle_alpha   90.455
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   203.893
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.500  0.123  0.123  1.0
  Mg  Mg1  1  0.500  0.624  0.136  1.0
  Mg  Mg2  1  0.500  0.136  0.624  1.0
  Mg  Mg3  1  1.000  0.828  0.422  1.0
  Mg  Mg4  1  1.000  0.422  0.828  1.0
  Mg  Mg5  1  0.000  0.421  0.421  1.0
  Mg  Mg6  1  1.000  0.825  0.825  1.0
  W  W7  1  0.500  0.620  0.620  1.0
[/CIF]
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The crystal structure described by CsMg6W crystallizes in the orthorhombic Amm2 space group. Cs(1) is bonded to two equivalent Mg(3), two equivalent Mg(4), four equivalent Mg(1), and four equivalent Mg(2) atoms to form CsMg12 cuboctahedra that share corners with four equivalent Cs(1)Mg12 cuboctahedra, edges with eight equivalent Mg(1)Cs2Mg8W2 cuboctahedra, faces with two equivalent Cs(1)Mg12 cuboctahedra, and faces with four equivalent Mg(1)Cs2Mg8W2 cuboctahedra. There are four inequivalent Mg sites. In the first Mg site, Mg(1) is bonded to two equivalent Cs(1), two equivalent Mg(3), two equivalent Mg(4), four equivalent Mg(2), and two equivalent W(1) atoms to form MgCs2Mg8W2 cuboctahedra that share corners with twelve equivalent Mg(1)Cs2Mg8W2 cuboctahedra, edges with four equivalent Cs(1)Mg12 cuboctahedra, faces with two equivalent Cs(1)Mg12 cuboctahedra, and faces with six equivalent Mg(1)Cs2Mg8W2 cuboctahedra. In the second Mg site, Mg(2) is bonded in a distorted L-shaped geometry to two equivalent Cs(1), four equivalent Mg(1), and two equivalent W(1) atoms. In the third Mg site, Mg(3) is bonded in a distorted L-shaped geometry to two equivalent Cs(1), four equivalent Mg(1), and two equivalent W(1) atoms. In the fourth Mg site, Mg(4) is bonded in a distorted L-shaped geometry to two equivalent Cs(1), four equivalent Mg(1), and two equivalent W(1) atoms. W(1) is bonded in a 8-coordinate geometry to two equivalent Mg(3), two equivalent Mg(4), four equivalent Mg(1), and four equivalent Mg(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_CsMg6W
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.198
_cell_length_b   6.969
_cell_length_c   6.969
_cell_angle_alpha   90.455
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   203.893
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.500  0.123  0.123  1.0
  Mg  Mg1  1  0.500  0.624  0.136  1.0
  Mg  Mg2  1  0.500  0.136  0.624  1.0
  Mg  Mg3  1  1.000  0.828  0.422  1.0
  Mg  Mg4  1  1.000  0.422  0.828  1.0
  Mg  Mg5  1  0.000  0.421  0.421  1.0
  Mg  Mg6  1  1.000  0.825  0.825  1.0
  W  W7  1  0.500  0.620  0.620  1.0
[/CIF]
.