The compound described by Sr6Ti3FeO14 crystallizes in the orthorhombic Cmm2 space group. There are twelve inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 9-coordinate geometry to one O(1), one O(21), one O(22), two equivalent O(24), two equivalent O(5), and two equivalent O(6) atoms. In the second Sr site, Sr(2) is bonded in a 9-coordinate geometry to one O(2), one O(21), one O(23), two equivalent O(24), two equivalent O(5), and two equivalent O(6) atoms. In the third Sr site, Sr(3) is bonded in a 9-coordinate geometry to one O(3), two equivalent O(25), two equivalent O(26), two equivalent O(7), and two equivalent O(8) atoms. In the fourth Sr site, Sr(4) is bonded in a 9-coordinate geometry to one O(27), one O(28), one O(4), two equivalent O(25), two equivalent O(7), and two equivalent O(8) atoms. In the fifth Sr site, Sr(5) is bonded in a 9-coordinate geometry to one O(5), two equivalent O(1), two equivalent O(13), two equivalent O(14), and two equivalent O(2) atoms. In the sixth Sr site, Sr(6) is bonded in a 9-coordinate geometry to one O(15), one O(16), one O(6), two equivalent O(1), two equivalent O(13), and two equivalent O(2) atoms. In the seventh Sr site, Sr(7) is bonded in a 9-coordinate geometry to one O(17), one O(18), one O(7), two equivalent O(20), two equivalent O(3), and two equivalent O(4) atoms. In the eighth Sr site, Sr(8) is bonded in a 9-coordinate geometry to one O(17), one O(19), one O(8), two equivalent O(20), two equivalent O(3), and two equivalent O(4) atoms. In the ninth Sr site, Sr(9) is bonded to one O(17), one O(18), one O(21), one O(22), two equivalent O(10), two equivalent O(20), two equivalent O(24), and two equivalent O(9) atoms to form SrO12 cuboctahedra that share corners with two equivalent Sr(10)O12 cuboctahedra, corners with two equivalent Sr(9)O12 cuboctahedra,  a faceface with one Sr(9)O12 cuboctahedra, faces with three equivalent Sr(10)O12 cuboctahedra, faces with two equivalent Ti(1)O6 octahedra, faces with two equivalent Ti(2)O6 octahedra, faces with two equivalent Ti(3)O6 octahedra, and faces with two equivalent Ti(4)O6 octahedra. In the tenth Sr site, Sr(10) is bonded to one O(17), one O(19), one O(21), one O(23), two equivalent O(10), two equivalent O(20), two equivalent O(24), and two equivalent O(9) atoms to form SrO12 cuboctahedra that share corners with two equivalent Sr(10)O12 cuboctahedra, corners with two equivalent Sr(9)O12 cuboctahedra,  a faceface with one Sr(10)O12 cuboctahedra, faces with three equivalent Sr(9)O12 cuboctahedra, faces with two equivalent Ti(1)O6 octahedra, faces with two equivalent Ti(2)O6 octahedra, faces with two equivalent Ti(3)O6 octahedra, and faces with two equivalent Ti(4)O6 octahedra. In the eleventh Sr site, Sr(11) is bonded to two equivalent O(11), two equivalent O(12), two equivalent O(13), two equivalent O(14), two equivalent O(25), and two equivalent O(26) atoms to form SrO12 cuboctahedra that share corners with four equivalent Sr(12)O12 cuboctahedra, faces with two equivalent Sr(11)O12 cuboctahedra, faces with two equivalent Sr(12)O12 cuboctahedra, faces with two equivalent Ti(5)O6 octahedra, faces with two equivalent Ti(6)O6 octahedra, faces with two equivalent Fe(1)O6 octahedra, and faces with two equivalent Fe(2)O6 octahedra. In the twelfth Sr site, Sr(12) is bonded to one O(15), one O(16), one O(27), one O(28), two equivalent O(11), two equivalent O(12), two equivalent O(13), and two equivalent O(25) atoms to form SrO12 cuboctahedra that share corners with four equivalent Sr(11)O12 cuboctahedra, faces with two equivalent Sr(11)O12 cuboctahedra, faces with two equivalent Sr(12)O12 cuboctahedra, faces with two equivalent Ti(5)O6 octahedra, faces with two equivalent Ti(6)O6 octahedra, faces with two equivalent Fe(1)O6 octahedra, and faces with two equivalent Fe(2)O6 octahedra. There are six inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to one O(3), one O(9), two equivalent O(17), and two equivalent O(20) atoms to form TiO6 octahedra that share  a cornercorner with one Ti(3)O6 octahedra, corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra, faces with two equivalent Sr(10)O12 cuboctahedra, and faces with two equivalent Sr(9)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the second Ti site, Ti(2) is bonded to one O(10), one O(18), one O(19), one O(4), and two equivalent O(20) atoms to form TiO6 octahedra that share  a cornercorner with one Ti(4)O6 octahedra, corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra, faces with two equivalent Sr(10)O12 cuboctahedra, and faces with two equivalent Sr(9)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the third Ti site, Ti(3) is bonded to one O(5), one O(9), two equivalent O(21), and two equivalent O(24) atoms to form TiO6 octahedra that share  a cornercorner with one Ti(1)O6 octahedra, corners with two equivalent Ti(3)O6 octahedra, corners with two equivalent Ti(4)O6 octahedra, faces with two equivalent Sr(10)O12 cuboctahedra, and faces with two equivalent Sr(9)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the fourth Ti site, Ti(4) is bonded to one O(10), one O(22), one O(23), one O(6), and two equivalent O(24) atoms to form TiO6 octahedra that share  a cornercorner with one Ti(2)O6 octahedra, corners with two equivalent Ti(3)O6 octahedra, corners with two equivalent Ti(4)O6 octahedra, faces with two equivalent Sr(10)O12 cuboctahedra, and faces with two equivalent Sr(9)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the fifth Ti site, Ti(5) is bonded to one O(11), one O(26), one O(27), one O(7), and two equivalent O(25) atoms to form TiO6 octahedra that share  a cornercorner with one Ti(5)O6 octahedra,  a cornercorner with one Fe(1)O6 octahedra, corners with three equivalent Ti(6)O6 octahedra, faces with two equivalent Sr(11)O12 cuboctahedra, and faces with two equivalent Sr(12)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 1-2°. In the sixth Ti site, Ti(6) is bonded to one O(12), one O(26), one O(28), one O(8), and two equivalent O(25) atoms to form TiO6 octahedra that share  a cornercorner with one Ti(6)O6 octahedra,  a cornercorner with one Fe(2)O6 octahedra, corners with three equivalent Ti(5)O6 octahedra, faces with two equivalent Sr(11)O12 cuboctahedra, and faces with two equivalent Sr(12)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 1-2°. There are two inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to one O(1), one O(11), one O(14), one O(15), and two equivalent O(13) atoms to form FeO6 octahedra that share  a cornercorner with one Ti(5)O6 octahedra,  a cornercorner with one Fe(1)O6 octahedra, corners with three equivalent Fe(2)O6 octahedra, faces with two equivalent Sr(11)O12 cuboctahedra, and faces with two equivalent Sr(12)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 1-2°. In the second Fe site, Fe(2) is bonded to one O(12), one O(14), one O(16), one O(2), and two equivalent O(13) atoms to form FeO6 octahedra that share  a cornercorner with one Ti(6)O6 octahedra,  a cornercorner with one Fe(2)O6 octahedra, corners with three equivalent Fe(1)O6 octahedra, faces with two equivalent Sr(11)O12 cuboctahedra, and faces with two equivalent Sr(12)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 1-2°. There are twenty-eight inequivalent O sites. In the first O site, O(25) is bonded to one Sr(11), one Sr(12), one Sr(3), one Sr(4), one Ti(5), and one Ti(6) atom to form distorted OSr4Ti2 octahedra that share  a cornercorner with one O(15)Sr4Fe2 octahedra,  a cornercorner with one O(16)Sr4Fe2 octahedra,  a cornercorner with one O(3)Sr5Ti octahedra,  a cornercorner with one O(4)Sr5Ti octahedra, corners with two equivalent O(13)Sr4Fe2 octahedra, corners with two equivalent O(14)Sr4Fe2 octahedra, corners with two equivalent O(25)Sr4Ti2 octahedra, corners with two equivalent O(7)Sr5Ti octahedra, corners with two equivalent O(8)Sr5Ti octahedra,  an edgeedge with one O(13)Sr4Fe2 octahedra, edges with two equivalent O(25)Sr4Ti2 octahedra,  a faceface with one O(27)Sr4Ti2 octahedra,  a faceface with one O(28)Sr4Ti2 octahedra,  a faceface with one O(7)Sr5Ti octahedra,  a faceface with one O(8)Sr5Ti octahedra, and faces with two equivalent O(26)Sr4Ti2 octahedra. The corner-sharing octahedral tilt angles range from 0-61°. In the second O site, O(26) is bonded to two equivalent Sr(11), two equivalent Sr(3), one Ti(5), and one Ti(6) atom to form distorted OSr4Ti2 octahedra that share  a cornercorner with one O(27)Sr4Ti2 octahedra,  a cornercorner with one O(28)Sr4Ti2 octahedra, corners with two equivalent O(14)Sr4Fe2 octahedra, corners with two equivalent O(3)Sr5Ti octahedra, corners with two equivalent O(7)Sr5Ti octahedra, corners with two equivalent O(8)Sr5Ti octahedra, corners with four equivalent O(13)Sr4Fe2 octahedra,  an edgeedge with one O(14)Sr4Fe2 octahedra, edges with two equivalent O(26)Sr4Ti2 octahedra,  a faceface with one O(7)Sr5Ti octahedra,  a faceface with one O(8)Sr5Ti octahedra, and faces with four equivalent O(25)Sr4Ti2 octahedra. The corner-sharing octahedral tilt angles range from 0-62°. In the third O site, O(27) is bonded to two equivalent Sr(12), two equivalent Sr(4), and two equivalent Ti(5) atoms to form distorted OSr4Ti2 octahedra that share corners with two equivalent O(16)Sr4Fe2 octahedra, corners with two equivalent O(26)Sr4Ti2 octahedra, corners with two equivalent O(4)Sr5Ti octahedra, corners with four equivalent O(13)Sr4Fe2 octahedra, corners with four equivalent O(8)Sr5Ti octahedra,  an edgeedge with one O(15)Sr4Fe2 octahedra, edges with two equivalent O(28)Sr4Ti2 octahedra, faces with two equivalent O(7)Sr5Ti octahedra, and faces with four equivalent O(25)Sr4Ti2 octahedra. The corner-sharing octahedral tilt angles range from 2-61°. In the fourth O site, O(28) is bonded to two equivalent Sr(12), two equivalent Sr(4), and two equivalent Ti(6) atoms to form distorted OSr4Ti2 octahedra that share corners with two equivalent O(15)Sr4Fe2 octahedra, corners with two equivalent O(26)Sr4Ti2 octahedra, corners with two equivalent O(4)Sr5Ti octahedra, corners with four equivalent O(13)Sr4Fe2 octahedra, corners with four equivalent O(7)Sr5Ti octahedra,  an edgeedge with one O(16)Sr4Fe2 octahedra, edges with two equivalent O(27)Sr4Ti2 octahedra, faces with two equivalent O(8)Sr5Ti octahedra, and faces with four equivalent O(25)Sr4Ti2 octahedra. The corner-sharing octahedral tilt angles range from 0-59°. In the fifth O site, O(1) is bonded to one Sr(1), two equivalent Sr(5), two equivalent Sr(6), and one Fe(1) atom to form distorted OSr5Fe octahedra that share  a cornercorner with one O(21)Sr4Ti2 octahedra,  a cornercorner with one O(22)Sr4Ti2 octahedra, corners with two equivalent O(14)Sr4Fe2 octahedra, corners with two equivalent O(16)Sr4Fe2 octahedra, corners with two equivalent O(24)Sr4Ti2 octahedra, corners with two equivalent O(1)Sr5Fe octahedra, corners with two equivalent O(2)Sr5Fe octahedra, corners with four equivalent O(13)Sr4Fe2 octahedra,  an edgeedge with one O(1)Sr5Fe octahedra, edges with two equivalent O(5)Sr5Ti octahedra, edges with two equivalent O(6)Sr5Ti octahedra, edges with three equivalent O(2)Sr5Fe octahedra,  a faceface with one O(14)Sr4Fe2 octahedra,  a faceface with one O(15)Sr4Fe2 octahedra, and faces with two equivalent O(13)Sr4Fe2 octahedra. The corner-sharing octahedral tilt angles range from 9-56°. In the sixth O site, O(2) is bonded to one Sr(2), two equivalent Sr(5), two equivalent Sr(6), and one Fe(2) atom to form distorted OSr5Fe octahedra that share  a cornercorner with one O(21)Sr4Ti2 octahedra,  a cornercorner with one O(23)Sr4Ti2 octahedra, corners with two equivalent O(14)Sr4Fe2 octahedra, corners with two equivalent O(15)Sr4Fe2 octahedra, corners with two equivalent O(24)Sr4Ti2 octahedra, corners with two equivalent O(1)Sr5Fe octahedra, corners with two equivalent O(2)Sr5Fe octahedra, corners with four equivalent O(13)Sr4Fe2 octahedra,  an edgeedge with one O(2)Sr5Fe octahedra, edges with two equivalent O(5)Sr5Ti octahedra, edges with two equivalent O(6)Sr5Ti octahedra, edges with three equivalent O(1)Sr5Fe octahedra,  a faceface with one O(14)Sr4Fe2 octahedra,  a faceface with one O(16)Sr4Fe2 octahedra, and faces with two equivalent O(13)Sr4Fe2 octahedra. The corner-sharing octahedral tilt angles range from 10-55°. In the seventh O site, O(3) is bonded to one Sr(3), two equivalent Sr(7), two equivalent Sr(8), and one Ti(1) atom to form distorted OSr5Ti octahedra that share  a cornercorner with one O(9)Sr4Ti2 octahedra, corners with two equivalent O(18)Sr4Ti2 octahedra, corners with two equivalent O(19)Sr4Ti2 octahedra, corners with two equivalent O(25)Sr4Ti2 octahedra, corners with two equivalent O(26)Sr4Ti2 octahedra, corners with four equivalent O(20)Sr4Ti2 octahedra, corners with four equivalent O(4)Sr5Ti octahedra, edges with two equivalent O(3)Sr5Ti octahedra, edges with two equivalent O(4)Sr5Ti octahedra, edges with two equivalent O(7)Sr5Ti octahedra, edges with two equivalent O(8)Sr5Ti octahedra, faces with two equivalent O(17)Sr4Ti2 octahedra, and faces with two equivalent O(20)Sr4Ti2 octahedra. The corner-sharing octahedral tilt angles range from 0-55°. In the eighth O site, O(4) is bonded to one Sr(4), two equivalent Sr(7), two equivalent Sr(8), and one Ti(2) atom to form distorted OSr5Ti octahedra that share  a cornercorner with one O(10)Sr4Ti2 octahedra,  a cornercorner with one O(27)Sr4Ti2 octahedra,  a cornercorner with one O(28)Sr4Ti2 octahedra, corners with two equivalent O(25)Sr4Ti2 octahedra, corners with four equivalent O(17)Sr4Ti2 octahedra, corners with four equivalent O(20)Sr4Ti2 octahedra, corners with four equivalent O(3)Sr5Ti octahedra, edges with two equivalent O(3)Sr5Ti octahedra, edges with two equivalent O(4)Sr5Ti octahedra, edges with two equivalent O(7)Sr5Ti octahedra, edges with two equivalent O(8)Sr5Ti octahedra,  a faceface with one O(18)Sr4Ti2 octahedra,  a faceface with one O(19)Sr4Ti2 octahedra, and faces with two equivalent O(20)Sr4Ti2 octahedra. The corner-sharing octahedral tilt angles range from 0-55°. In the ninth O site, O(5) is bonded to one Sr(5), two equivalent Sr(1), two equivalent Sr(2), and one Ti(3) atom to form distorted OSr5Ti octahedra that share  a cornercorner with one O(9)Sr4Ti2 octahedra, corners with two equivalent O(13)Sr4Fe2 octahedra, corners with two equivalent O(14)Sr4Fe2 octahedra, corners with two equivalent O(22)Sr4Ti2 octahedra, corners with two equivalent O(23)Sr4Ti2 octahedra, corners with four equivalent O(24)Sr4Ti2 octahedra, corners with four equivalent O(6)Sr5Ti octahedra, edges with two equivalent O(1)Sr5Fe octahedra, edges with two equivalent O(2)Sr5Fe octahedra, edges with two equivalent O(5)Sr5Ti octahedra, edges with two equivalent O(6)Sr5Ti octahedra, faces with two equivalent O(21)Sr4Ti2 octahedra, and faces with two equivalent O(24)Sr4Ti2 octahedra. The corner-sharing octahedral tilt angles range from 0-56°. In the tenth O site, O(6) is bonded to one Sr(6), two equivalent Sr(1), two equivalent Sr(2), and one Ti(4) atom to form distorted OSr5Ti octahedra that share  a cornercorner with one O(15)Sr4Fe2 octahedra,  a cornercorner with one O(16)Sr4Fe2 octahedra,  a cornercorner with one O(10)Sr4Ti2 octahedra, corners with two equivalent O(13)Sr4Fe2 octahedra, corners with four equivalent O(21)Sr4Ti2 octahedra, corners with four equivalent O(24)Sr4Ti2 octahedra, corners with four equivalent O(5)Sr5Ti octahedra, edges with two equivalent O(1)Sr5Fe octahedra, edges with two equivalent O(2)Sr5Fe octahedra, edges with two equivalent O(5)Sr5Ti octahedra, edges with two equivalent O(6)Sr5Ti octahedra,  a faceface with one O(22)Sr4Ti2 octahedra,  a faceface with one O(23)Sr4Ti2 octahedra, and faces with two equivalent O(24)Sr4Ti2 octahedra. The corner-sharing octahedral tilt angles range from 0-56°. In the eleventh O site, O(7) is bonded to one Sr(7), two equivalent Sr(3), two equivalent Sr(4), and one Ti(5) atom to form distorted OSr5Ti octahedra that share  a cornercorner with one O(17)Sr4Ti2 octahedra,  a cornercorner with one O(18)Sr4Ti2 octahedra, corners with two equivalent O(20)Sr4Ti2 octahedra, corners with two equivalent O(26)Sr4Ti2 octahedra, corners with two equivalent O(28)Sr4Ti2 octahedra, corners with two equivalent O(7)Sr5Ti octahedra, corners with two equivalent O(8)Sr5Ti octahedra, corners with four equivalent O(25)Sr4Ti2 octahedra,  an edgeedge with one O(7)Sr5Ti octahedra, edges with two equivalent O(3)Sr5Ti octahedra, edges with two equivalent O(4)Sr5Ti octahedra, edges with three equivalent O(8)Sr5Ti octahedra,  a faceface with one O(26)Sr4Ti2 octahedra,  a faceface with one O(27)Sr4Ti2 octahedra, and faces with two equivalent O(25)Sr4Ti2 octahedra. The corner-sharing octahedral tilt angles range from 8-56°. In the twelfth O site, O(8) is bonded to one Sr(8), two equivalent Sr(3), two equivalent Sr(4), and one Ti(6) atom to form distorted OSr5Ti octahedra that share  a cornercorner with one O(17)Sr4Ti2 octahedra,  a cornercorner with one O(19)Sr4Ti2 octahedra, corners with two equivalent O(20)Sr4Ti2 octahedra, corners with two equivalent O(26)Sr4Ti2 octahedra, corners with two equivalent O(27)Sr4Ti2 octahedra, corners with two equivalent O(7)Sr5Ti octahedra, corners with two equivalent O(8)Sr5Ti octahedra, corners with four equivalent O(25)Sr4Ti2 octahedra,  an edgeedge with one O(8)Sr5Ti octahedra, edges with two equivalent O(3)Sr5Ti octahedra, edges with two equivalent O(4)Sr5Ti octahedra, edges with three equivalent O(7)Sr5Ti octahedra,  a faceface with one O(26)Sr4Ti2 octahedra,  a faceface with one O(28)Sr4Ti2 octahedra, and faces with two equivalent O(25)Sr4Ti2 octahedra. The corner-sharing octahedral tilt angles range from 8-55°. In the thirteenth O site, O(9) is bonded to two equivalent Sr(10), two equivalent Sr(9), one Ti(1), and one Ti(3) atom to form distorted OSr4Ti2 octahedra that share  a cornercorner with one O(3)Sr5Ti octahedra,  a cornercorner with one O(5)Sr5Ti octahedra, corners with two equivalent O(18)Sr4Ti2 octahedra, corners with two equivalent O(19)Sr4Ti2 octahedra, corners with two equivalent O(22)Sr4Ti2 octahedra, corners with two equivalent O(23)Sr4Ti2 octahedra, corners with four equivalent O(10)Sr4Ti2 octahedra, corners with four equivalent O(20)Sr4Ti2 octahedra, corners with four equivalent O(24)Sr4Ti2 octahedra, edges with two equivalent O(10)Sr4Ti2 octahedra, edges with two equivalent O(9)Sr4Ti2 octahedra, faces with two equivalent O(17)Sr4Ti2 octahedra, faces with two equivalent O(20)Sr4Ti2 octahedra, faces with two equivalent O(21)Sr4Ti2 octahedra, and faces with two equivalent O(24)Sr4Ti2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°. In the fourteenth O site, O(10) is bonded to two equivalent Sr(10), two equivalent Sr(9), one Ti(2), and one Ti(4) atom to form distorted OSr4Ti2 octahedra that share  a cornercorner with one O(4)Sr5Ti octahedra,  a cornercorner with one O(6)Sr5Ti octahedra, corners with four equivalent O(17)Sr4Ti2 octahedra, corners with four equivalent O(20)Sr4Ti2 octahedra, corners with four equivalent O(21)Sr4Ti2 octahedra, corners with four equivalent O(24)Sr4Ti2 octahedra, corners with four equivalent O(9)Sr4Ti2 octahedra, edges with two equivalent O(10)Sr4Ti2 octahedra, edges with two equivalent O(9)Sr4Ti2 octahedra,  a faceface with one O(18)Sr4Ti2 octahedra,  a faceface with one O(19)Sr4Ti2 octahedra,  a faceface with one O(22)Sr4Ti2 octahedra,  a faceface with one O(23)Sr4Ti2 octahedra, faces with two equivalent O(20)Sr4Ti2 octahedra, and faces with two equivalent O(24)Sr4Ti2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°. In the fifteenth O site, O(11) is bonded in a distorted linear geometry to two equivalent Sr(11), two equivalent Sr(12), one Ti(5), and one Fe(1) atom. In the sixteenth O site, O(12) is bonded in a distorted linear geometry to two equivalent Sr(11), two equivalent Sr(12), one Ti(6), and one Fe(2) atom. In the seventeenth O site, O(13) is bonded to one Sr(11), one Sr(12), one Sr(5), one Sr(6), one Fe(1), and one Fe(2) atom to form distorted OSr4Fe2 octahedra that share  a cornercorner with one O(27)Sr4Ti2 octahedra,  a cornercorner with one O(28)Sr4Ti2 octahedra,  a cornercorner with one O(5)Sr5Ti octahedra,  a cornercorner with one O(6)Sr5Ti octahedra, corners with two equivalent O(13)Sr4Fe2 octahedra, corners with two equivalent O(25)Sr4Ti2 octahedra, corners with two equivalent O(26)Sr4Ti2 octahedra, corners with two equivalent O(1)Sr5Fe octahedra, corners with two equivalent O(2)Sr5Fe octahedra,  an edgeedge with one O(25)Sr4Ti2 octahedra, edges with two equivalent O(13)Sr4Fe2 octahedra,  a faceface with one O(15)Sr4Fe2 octahedra,  a faceface with one O(16)Sr4Fe2 octahedra,  a faceface with one O(1)Sr5Fe octahedra,  a faceface with one O(2)Sr5Fe octahedra, and faces with two equivalent O(14)Sr4Fe2 octahedra. The corner-sharing octahedral tilt angles range from 2-62°. In the eighteenth O site, O(14) is bonded to two equivalent Sr(11), two equivalent Sr(5), one Fe(1), and one Fe(2) atom to form distorted OSr4Fe2 octahedra that share  a cornercorner with one O(15)Sr4Fe2 octahedra,  a cornercorner with one O(16)Sr4Fe2 octahedra, corners with two equivalent O(26)Sr4Ti2 octahedra, corners with two equivalent O(1)Sr5Fe octahedra, corners with two equivalent O(2)Sr5Fe octahedra, corners with two equivalent O(5)Sr5Ti octahedra, corners with four equivalent O(25)Sr4Ti2 octahedra,  an edgeedge with one O(26)Sr4Ti2 octahedra, edges with two equivalent O(14)Sr4Fe2 octahedra,  a faceface with one O(1)Sr5Fe octahedra,  a faceface with one O(2)Sr5Fe octahedra, and faces with four equivalent O(13)Sr4Fe2 octahedra. The corner-sharing octahedral tilt angles range from 2-61°. In the nineteenth O site, O(15) is bonded to two equivalent Sr(12), two equivalent Sr(6), and two equivalent Fe(1) atoms to form distorted OSr4Fe2 octahedra that share corners with two equivalent O(14)Sr4Fe2 octahedra, corners with two equivalent O(28)Sr4Ti2 octahedra, corners with two equivalent O(6)Sr5Ti octahedra, corners with four equivalent O(25)Sr4Ti2 octahedra, corners with four equivalent O(2)Sr5Fe octahedra,  an edgeedge with one O(27)Sr4Ti2 octahedra, edges with two equivalent O(16)Sr4Fe2 octahedra, faces with two equivalent O(1)Sr5Fe octahedra, and faces with four equivalent O(13)Sr4Fe2 octahedra. The corner-sharing octahedral tilt angles range from 2-60°. In the twentieth O site, O(16) is bonded to two equivalent Sr(12), two equivalent Sr(6), and two equivalent Fe(2) atoms to form distorted OSr4Fe2 octahedra that share corners with two equivalent O(14)Sr4Fe2 octahedra, corners with two equivalent O(27)Sr4Ti2 octahedra, corners with two equivalent O(6)Sr5Ti octahedra, corners with four equivalent O(25)Sr4Ti2 octahedra, corners with four equivalent O(1)Sr5Fe octahedra,  an edgeedge with one O(28)Sr4Ti2 octahedra, edges with two equivalent O(15)Sr4Fe2 octahedra, faces with two equivalent O(2)Sr5Fe octahedra, and faces with four equivalent O(13)Sr4Fe2 octahedra. The corner-sharing octahedral tilt angles range from 2-60°. In the twenty-first O site, O(17) is bonded to one Sr(10), one Sr(7), one Sr(8), one Sr(9), and two equivalent Ti(1) atoms to form distorted OSr4Ti2 octahedra that share  a cornercorner with one O(22)Sr4Ti2 octahedra,  a cornercorner with one O(23)Sr4Ti2 octahedra,  a cornercorner with one O(7)Sr5Ti octahedra,  a cornercorner with one O(8)Sr5Ti octahedra, corners with two equivalent O(17)Sr4Ti2 octahedra, corners with four equivalent O(10)Sr4Ti2 octahedra, corners with four equivalent O(24)Sr4Ti2 octahedra, corners with four equivalent O(4)Sr5Ti octahedra,  an edgeedge with one O(18)Sr4Ti2 octahedra,  an edgeedge with one O(19)Sr4Ti2 octahedra,  an edgeedge with one O(21)Sr4Ti2 octahedra, faces with two equivalent O(9)Sr4Ti2 octahedra, faces with two equivalent O(3)Sr5Ti octahedra, and faces with four equivalent O(20)Sr4Ti2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°. In the twenty-second O site, O(18) is bonded to two equivalent Sr(7), two equivalent Sr(9), and two equivalent Ti(2) atoms to form distorted OSr4Ti2 octahedra that share corners with two equivalent O(19)Sr4Ti2 octahedra, corners with two equivalent O(21)Sr4Ti2 octahedra, corners with two equivalent O(7)Sr5Ti octahedra, corners with four equivalent O(24)Sr4Ti2 octahedra, corners with four equivalent O(9)Sr4Ti2 octahedra, corners with four equivalent O(3)Sr5Ti octahedra,  an edgeedge with one O(22)Sr4Ti2 octahedra, edges with two equivalent O(17)Sr4Ti2 octahedra, faces with two equivalent O(10)Sr4Ti2 octahedra, faces with two equivalent O(4)Sr5Ti octahedra, and faces with four equivalent O(20)Sr4Ti2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°. In the twenty-third O site, O(19) is bonded to two equivalent Sr(10), two equivalent Sr(8), and two equivalent Ti(2) atoms to form distorted OSr4Ti2 octahedra that share corners with two equivalent O(18)Sr4Ti2 octahedra, corners with two equivalent O(21)Sr4Ti2 octahedra, corners with two equivalent O(8)Sr5Ti octahedra, corners with four equivalent O(24)Sr4Ti2 octahedra, corners with four equivalent O(9)Sr4Ti2 octahedra, corners with four equivalent O(3)Sr5Ti octahedra,  an edgeedge with one O(23)Sr4Ti2 octahedra, edges with two equivalent O(17)Sr4Ti2 octahedra, faces with two equivalent O(10)Sr4Ti2 octahedra, faces with two equivalent O(4)Sr5Ti octahedra, and faces with four equivalent O(20)Sr4Ti2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°. In the twenty-fourth O site, O(20) is bonded to one Sr(10), one Sr(7), one Sr(8), one Sr(9), one Ti(1), and one Ti(2) atom to form distorted OSr4Ti2 octahedra that share  a cornercorner with one O(22)Sr4Ti2 octahedra,  a cornercorner with one O(23)Sr4Ti2 octahedra,  a cornercorner with one O(7)Sr5Ti octahedra,  a cornercorner with one O(8)Sr5Ti octahedra, corners with two equivalent O(10)Sr4Ti2 octahedra, corners with two equivalent O(20)Sr4Ti2 octahedra, corners with two equivalent O(21)Sr4Ti2 octahedra, corners with two equivalent O(24)Sr4Ti2 octahedra, corners with two equivalent O(9)Sr4Ti2 octahedra, corners with two equivalent O(3)Sr5Ti octahedra, corners with two equivalent O(4)Sr5Ti octahedra,  an edgeedge with one O(24)Sr4Ti2 octahedra, edges with two equivalent O(20)Sr4Ti2 octahedra,  a faceface with one O(10)Sr4Ti2 octahedra,  a faceface with one O(18)Sr4Ti2 octahedra,  a faceface with one O(19)Sr4Ti2 octahedra,  a faceface with one O(9)Sr4Ti2 octahedra,  a faceface with one O(3)Sr5Ti octahedra,  a faceface with one O(4)Sr5Ti octahedra, and faces with two equivalent O(17)Sr4Ti2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°. In the twenty-fifth O site, O(21) is bonded to one Sr(1), one Sr(10), one Sr(2), one Sr(9), and two equivalent Ti(3) atoms to form distorted OSr4Ti2 octahedra that share  a cornercorner with one O(18)Sr4Ti2 octahedra,  a cornercorner with one O(19)Sr4Ti2 octahedra,  a cornercorner with one O(1)Sr5Fe octahedra,  a cornercorner with one O(2)Sr5Fe octahedra, corners with two equivalent O(21)Sr4Ti2 octahedra, corners with four equivalent O(10)Sr4Ti2 octahedra, corners with four equivalent O(20)Sr4Ti2 octahedra, corners with four equivalent O(6)Sr5Ti octahedra,  an edgeedge with one O(17)Sr4Ti2 octahedra,  an edgeedge with one O(22)Sr4Ti2 octahedra,  an edgeedge with one O(23)Sr4Ti2 octahedra, faces with two equivalent O(9)Sr4Ti2 octahedra, faces with two equivalent O(5)Sr5Ti octahedra, and faces with four equivalent O(24)Sr4Ti2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°. In the twenty-sixth O site, O(22) is bonded to two equivalent Sr(1), two equivalent Sr(9), and two equivalent Ti(4) atoms to form distorted OSr4Ti2 octahedra that share corners with two equivalent O(17)Sr4Ti2 octahedra, corners with two equivalent O(23)Sr4Ti2 octahedra, corners with two equivalent O(1)Sr5Fe octahedra, corners with four equivalent O(20)Sr4Ti2 octahedra, corners with four equivalent O(9)Sr4Ti2 octahedra, corners with four equivalent O(5)Sr5Ti octahedra,  an edgeedge with one O(18)Sr4Ti2 octahedra, edges with two equivalent O(21)Sr4Ti2 octahedra, faces with two equivalent O(10)Sr4Ti2 octahedra, faces with two equivalent O(6)Sr5Ti octahedra, and faces with four equivalent O(24)Sr4Ti2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°. In the twenty-seventh O site, O(23) is bonded to two equivalent Sr(10), two equivalent Sr(2), and two equivalent Ti(4) atoms to form distorted OSr4Ti2 octahedra that share corners with two equivalent O(17)Sr4Ti2 octahedra, corners with two equivalent O(22)Sr4Ti2 octahedra, corners with two equivalent O(2)Sr5Fe octahedra, corners with four equivalent O(20)Sr4Ti2 octahedra, corners with four equivalent O(9)Sr4Ti2 octahedra, corners with four equivalent O(5)Sr5Ti octahedra,  an edgeedge with one O(19)Sr4Ti2 octahedra, edges with two equivalent O(21)Sr4Ti2 octahedra, faces with two equivalent O(10)Sr4Ti2 octahedra, faces with two equivalent O(6)Sr5Ti octahedra, and faces with four equivalent O(24)Sr4Ti2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°. In the twenty-eighth O site, O(24) is bonded to one Sr(1), one Sr(10), one Sr(2), one Sr(9), one Ti(3), and one Ti(4) atom to form distorted OSr4Ti2 octahedra that share  a cornercorner with one O(18)Sr4Ti2 octahedra,  a cornercorner with one O(19)Sr4Ti2 octahedra,  a cornercorner with one O(1)Sr5Fe octahedra,  a cornercorner with one O(2)Sr5Fe octahedra, corners with two equivalent O(10)Sr4Ti2 octahedra, corners with two equivalent O(17)Sr4Ti2 octahedra, corners with two equivalent O(20)Sr4Ti2 octahedra, corners with two equivalent O(24)Sr4Ti2 octahedra, corners with two equivalent O(9)Sr4Ti2 octahedra, corners with two equivalent O(5)Sr5Ti octahedra, corners with two equivalent O(6)Sr5Ti octahedra,  an edgeedge with one O(20)Sr4Ti2 octahedra, edges with two equivalent O(24)Sr4Ti2 octahedra,  a faceface with one O(10)Sr4Ti2 octahedra,  a faceface with one O(22)Sr4Ti2 octahedra,  a faceface with one O(23)Sr4Ti2 octahedra,  a faceface with one O(9)Sr4Ti2 octahedra,  a faceface with one O(5)Sr5Ti octahedra,  a faceface with one O(6)Sr5Ti octahedra, and faces with two equivalent O(21)Sr4Ti2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°. is represented by the CIF card [CIF]
data_Sr6Ti3FeO14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.937
_cell_length_b   3.944
_cell_length_c   20.420
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.005
_symmetry_Int_Tables_number   1
_cell_volume   317.047
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.500  0.500  0.598  1.0
  O  O1  1  0.500  0.500  0.693  1.0
  O  O2  1  1.000  1.000  0.194  1.0
  O  O3  1  1.000  1.000  0.805  1.0
  O  O4  1  0.500  0.500  0.307  1.0
  O  O5  1  1.000  1.000  1.000  1.0
  O  O6  1  0.500  0.500  0.501  1.0
  O  O7  1  0.500  0.000  0.596  1.0
  O  O8  1  0.000  0.500  0.596  1.0
  O  O9  1  1.000  0.500  0.097  1.0
  O  O10  1  0.500  1.000  0.097  1.0
  O  O11  1  1.000  0.500  0.903  1.0
  O  O12  1  0.500  1.000  0.903  1.0
  O  O13  1  0.500  0.000  0.404  1.0
  O  O14  1  0.000  0.500  0.404  1.0
  Sr  Sr15  1  0.500  0.500  0.814  1.0
  Sr  Sr16  1  1.000  0.000  0.317  1.0
  Sr  Sr17  1  0.000  0.000  0.681  1.0
  Sr  Sr18  1  0.500  0.500  0.185  1.0
  Sr  Sr19  1  0.500  0.500  1.000  1.0
  Sr  Sr20  1  1.000  0.000  0.503  1.0
  Ti  Ti21  1  1.000  0.000  0.098  1.0
  Ti  Ti22  1  0.000  1.000  0.901  1.0
  Ti  Ti23  1  0.500  0.500  0.403  1.0
[/CIF]
.
The compound described by Sr6Ti3FeO14 crystallizes in the orthorhombic Cmm2 space group. There are twelve inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 9-coordinate geometry to one O(1), one O(21), one O(22), two equivalent O(24), two equivalent O(5), and two equivalent O(6) atoms. In the second Sr site, Sr(2) is bonded in a 9-coordinate geometry to one O(2), one O(21), one O(23), two equivalent O(24), two equivalent O(5), and two equivalent O(6) atoms. In the third Sr site, Sr(3) is bonded in a 9-coordinate geometry to one O(3), two equivalent O(25), two equivalent O(26), two equivalent O(7), and two equivalent O(8) atoms. In the fourth Sr site, Sr(4) is bonded in a 9-coordinate geometry to one O(27), one O(28), one O(4), two equivalent O(25), two equivalent O(7), and two equivalent O(8) atoms. In the fifth Sr site, Sr(5) is bonded in a 9-coordinate geometry to one O(5), two equivalent O(1), two equivalent O(13), two equivalent O(14), and two equivalent O(2) atoms. In the sixth Sr site, Sr(6) is bonded in a 9-coordinate geometry to one O(15), one O(16), one O(6), two equivalent O(1), two equivalent O(13), and two equivalent O(2) atoms. In the seventh Sr site, Sr(7) is bonded in a 9-coordinate geometry to one O(17), one O(18), one O(7), two equivalent O(20), two equivalent O(3), and two equivalent O(4) atoms. In the eighth Sr site, Sr(8) is bonded in a 9-coordinate geometry to one O(17), one O(19), one O(8), two equivalent O(20), two equivalent O(3), and two equivalent O(4) atoms. In the ninth Sr site, Sr(9) is bonded to one O(17), one O(18), one O(21), one O(22), two equivalent O(10), two equivalent O(20), two equivalent O(24), and two equivalent O(9) atoms to form SrO12 cuboctahedra that share corners with two equivalent Sr(10)O12 cuboctahedra, corners with two equivalent Sr(9)O12 cuboctahedra,  a faceface with one Sr(9)O12 cuboctahedra, faces with three equivalent Sr(10)O12 cuboctahedra, faces with two equivalent Ti(1)O6 octahedra, faces with two equivalent Ti(2)O6 octahedra, faces with two equivalent Ti(3)O6 octahedra, and faces with two equivalent Ti(4)O6 octahedra. In the tenth Sr site, Sr(10) is bonded to one O(17), one O(19), one O(21), one O(23), two equivalent O(10), two equivalent O(20), two equivalent O(24), and two equivalent O(9) atoms to form SrO12 cuboctahedra that share corners with two equivalent Sr(10)O12 cuboctahedra, corners with two equivalent Sr(9)O12 cuboctahedra,  a faceface with one Sr(10)O12 cuboctahedra, faces with three equivalent Sr(9)O12 cuboctahedra, faces with two equivalent Ti(1)O6 octahedra, faces with two equivalent Ti(2)O6 octahedra, faces with two equivalent Ti(3)O6 octahedra, and faces with two equivalent Ti(4)O6 octahedra. In the eleventh Sr site, Sr(11) is bonded to two equivalent O(11), two equivalent O(12), two equivalent O(13), two equivalent O(14), two equivalent O(25), and two equivalent O(26) atoms to form SrO12 cuboctahedra that share corners with four equivalent Sr(12)O12 cuboctahedra, faces with two equivalent Sr(11)O12 cuboctahedra, faces with two equivalent Sr(12)O12 cuboctahedra, faces with two equivalent Ti(5)O6 octahedra, faces with two equivalent Ti(6)O6 octahedra, faces with two equivalent Fe(1)O6 octahedra, and faces with two equivalent Fe(2)O6 octahedra. In the twelfth Sr site, Sr(12) is bonded to one O(15), one O(16), one O(27), one O(28), two equivalent O(11), two equivalent O(12), two equivalent O(13), and two equivalent O(25) atoms to form SrO12 cuboctahedra that share corners with four equivalent Sr(11)O12 cuboctahedra, faces with two equivalent Sr(11)O12 cuboctahedra, faces with two equivalent Sr(12)O12 cuboctahedra, faces with two equivalent Ti(5)O6 octahedra, faces with two equivalent Ti(6)O6 octahedra, faces with two equivalent Fe(1)O6 octahedra, and faces with two equivalent Fe(2)O6 octahedra. There are six inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to one O(3), one O(9), two equivalent O(17), and two equivalent O(20) atoms to form TiO6 octahedra that share  a cornercorner with one Ti(3)O6 octahedra, corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra, faces with two equivalent Sr(10)O12 cuboctahedra, and faces with two equivalent Sr(9)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the second Ti site, Ti(2) is bonded to one O(10), one O(18), one O(19), one O(4), and two equivalent O(20) atoms to form TiO6 octahedra that share  a cornercorner with one Ti(4)O6 octahedra, corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra, faces with two equivalent Sr(10)O12 cuboctahedra, and faces with two equivalent Sr(9)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the third Ti site, Ti(3) is bonded to one O(5), one O(9), two equivalent O(21), and two equivalent O(24) atoms to form TiO6 octahedra that share  a cornercorner with one Ti(1)O6 octahedra, corners with two equivalent Ti(3)O6 octahedra, corners with two equivalent Ti(4)O6 octahedra, faces with two equivalent Sr(10)O12 cuboctahedra, and faces with two equivalent Sr(9)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the fourth Ti site, Ti(4) is bonded to one O(10), one O(22), one O(23), one O(6), and two equivalent O(24) atoms to form TiO6 octahedra that share  a cornercorner with one Ti(2)O6 octahedra, corners with two equivalent Ti(3)O6 octahedra, corners with two equivalent Ti(4)O6 octahedra, faces with two equivalent Sr(10)O12 cuboctahedra, and faces with two equivalent Sr(9)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the fifth Ti site, Ti(5) is bonded to one O(11), one O(26), one O(27), one O(7), and two equivalent O(25) atoms to form TiO6 octahedra that share  a cornercorner with one Ti(5)O6 octahedra,  a cornercorner with one Fe(1)O6 octahedra, corners with three equivalent Ti(6)O6 octahedra, faces with two equivalent Sr(11)O12 cuboctahedra, and faces with two equivalent Sr(12)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 1-2°. In the sixth Ti site, Ti(6) is bonded to one O(12), one O(26), one O(28), one O(8), and two equivalent O(25) atoms to form TiO6 octahedra that share  a cornercorner with one Ti(6)O6 octahedra,  a cornercorner with one Fe(2)O6 octahedra, corners with three equivalent Ti(5)O6 octahedra, faces with two equivalent Sr(11)O12 cuboctahedra, and faces with two equivalent Sr(12)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 1-2°. There are two inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to one O(1), one O(11), one O(14), one O(15), and two equivalent O(13) atoms to form FeO6 octahedra that share  a cornercorner with one Ti(5)O6 octahedra,  a cornercorner with one Fe(1)O6 octahedra, corners with three equivalent Fe(2)O6 octahedra, faces with two equivalent Sr(11)O12 cuboctahedra, and faces with two equivalent Sr(12)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 1-2°. In the second Fe site, Fe(2) is bonded to one O(12), one O(14), one O(16), one O(2), and two equivalent O(13) atoms to form FeO6 octahedra that share  a cornercorner with one Ti(6)O6 octahedra,  a cornercorner with one Fe(2)O6 octahedra, corners with three equivalent Fe(1)O6 octahedra, faces with two equivalent Sr(11)O12 cuboctahedra, and faces with two equivalent Sr(12)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 1-2°. There are twenty-eight inequivalent O sites. In the first O site, O(25) is bonded to one Sr(11), one Sr(12), one Sr(3), one Sr(4), one Ti(5), and one Ti(6) atom to form distorted OSr4Ti2 octahedra that share  a cornercorner with one O(15)Sr4Fe2 octahedra,  a cornercorner with one O(16)Sr4Fe2 octahedra,  a cornercorner with one O(3)Sr5Ti octahedra,  a cornercorner with one O(4)Sr5Ti octahedra, corners with two equivalent O(13)Sr4Fe2 octahedra, corners with two equivalent O(14)Sr4Fe2 octahedra, corners with two equivalent O(25)Sr4Ti2 octahedra, corners with two equivalent O(7)Sr5Ti octahedra, corners with two equivalent O(8)Sr5Ti octahedra,  an edgeedge with one O(13)Sr4Fe2 octahedra, edges with two equivalent O(25)Sr4Ti2 octahedra,  a faceface with one O(27)Sr4Ti2 octahedra,  a faceface with one O(28)Sr4Ti2 octahedra,  a faceface with one O(7)Sr5Ti octahedra,  a faceface with one O(8)Sr5Ti octahedra, and faces with two equivalent O(26)Sr4Ti2 octahedra. The corner-sharing octahedral tilt angles range from 0-61°. In the second O site, O(26) is bonded to two equivalent Sr(11), two equivalent Sr(3), one Ti(5), and one Ti(6) atom to form distorted OSr4Ti2 octahedra that share  a cornercorner with one O(27)Sr4Ti2 octahedra,  a cornercorner with one O(28)Sr4Ti2 octahedra, corners with two equivalent O(14)Sr4Fe2 octahedra, corners with two equivalent O(3)Sr5Ti octahedra, corners with two equivalent O(7)Sr5Ti octahedra, corners with two equivalent O(8)Sr5Ti octahedra, corners with four equivalent O(13)Sr4Fe2 octahedra,  an edgeedge with one O(14)Sr4Fe2 octahedra, edges with two equivalent O(26)Sr4Ti2 octahedra,  a faceface with one O(7)Sr5Ti octahedra,  a faceface with one O(8)Sr5Ti octahedra, and faces with four equivalent O(25)Sr4Ti2 octahedra. The corner-sharing octahedral tilt angles range from 0-62°. In the third O site, O(27) is bonded to two equivalent Sr(12), two equivalent Sr(4), and two equivalent Ti(5) atoms to form distorted OSr4Ti2 octahedra that share corners with two equivalent O(16)Sr4Fe2 octahedra, corners with two equivalent O(26)Sr4Ti2 octahedra, corners with two equivalent O(4)Sr5Ti octahedra, corners with four equivalent O(13)Sr4Fe2 octahedra, corners with four equivalent O(8)Sr5Ti octahedra,  an edgeedge with one O(15)Sr4Fe2 octahedra, edges with two equivalent O(28)Sr4Ti2 octahedra, faces with two equivalent O(7)Sr5Ti octahedra, and faces with four equivalent O(25)Sr4Ti2 octahedra. The corner-sharing octahedral tilt angles range from 2-61°. In the fourth O site, O(28) is bonded to two equivalent Sr(12), two equivalent Sr(4), and two equivalent Ti(6) atoms to form distorted OSr4Ti2 octahedra that share corners with two equivalent O(15)Sr4Fe2 octahedra, corners with two equivalent O(26)Sr4Ti2 octahedra, corners with two equivalent O(4)Sr5Ti octahedra, corners with four equivalent O(13)Sr4Fe2 octahedra, corners with four equivalent O(7)Sr5Ti octahedra,  an edgeedge with one O(16)Sr4Fe2 octahedra, edges with two equivalent O(27)Sr4Ti2 octahedra, faces with two equivalent O(8)Sr5Ti octahedra, and faces with four equivalent O(25)Sr4Ti2 octahedra. The corner-sharing octahedral tilt angles range from 0-59°. In the fifth O site, O(1) is bonded to one Sr(1), two equivalent Sr(5), two equivalent Sr(6), and one Fe(1) atom to form distorted OSr5Fe octahedra that share  a cornercorner with one O(21)Sr4Ti2 octahedra,  a cornercorner with one O(22)Sr4Ti2 octahedra, corners with two equivalent O(14)Sr4Fe2 octahedra, corners with two equivalent O(16)Sr4Fe2 octahedra, corners with two equivalent O(24)Sr4Ti2 octahedra, corners with two equivalent O(1)Sr5Fe octahedra, corners with two equivalent O(2)Sr5Fe octahedra, corners with four equivalent O(13)Sr4Fe2 octahedra,  an edgeedge with one O(1)Sr5Fe octahedra, edges with two equivalent O(5)Sr5Ti octahedra, edges with two equivalent O(6)Sr5Ti octahedra, edges with three equivalent O(2)Sr5Fe octahedra,  a faceface with one O(14)Sr4Fe2 octahedra,  a faceface with one O(15)Sr4Fe2 octahedra, and faces with two equivalent O(13)Sr4Fe2 octahedra. The corner-sharing octahedral tilt angles range from 9-56°. In the sixth O site, O(2) is bonded to one Sr(2), two equivalent Sr(5), two equivalent Sr(6), and one Fe(2) atom to form distorted OSr5Fe octahedra that share  a cornercorner with one O(21)Sr4Ti2 octahedra,  a cornercorner with one O(23)Sr4Ti2 octahedra, corners with two equivalent O(14)Sr4Fe2 octahedra, corners with two equivalent O(15)Sr4Fe2 octahedra, corners with two equivalent O(24)Sr4Ti2 octahedra, corners with two equivalent O(1)Sr5Fe octahedra, corners with two equivalent O(2)Sr5Fe octahedra, corners with four equivalent O(13)Sr4Fe2 octahedra,  an edgeedge with one O(2)Sr5Fe octahedra, edges with two equivalent O(5)Sr5Ti octahedra, edges with two equivalent O(6)Sr5Ti octahedra, edges with three equivalent O(1)Sr5Fe octahedra,  a faceface with one O(14)Sr4Fe2 octahedra,  a faceface with one O(16)Sr4Fe2 octahedra, and faces with two equivalent O(13)Sr4Fe2 octahedra. The corner-sharing octahedral tilt angles range from 10-55°. In the seventh O site, O(3) is bonded to one Sr(3), two equivalent Sr(7), two equivalent Sr(8), and one Ti(1) atom to form distorted OSr5Ti octahedra that share  a cornercorner with one O(9)Sr4Ti2 octahedra, corners with two equivalent O(18)Sr4Ti2 octahedra, corners with two equivalent O(19)Sr4Ti2 octahedra, corners with two equivalent O(25)Sr4Ti2 octahedra, corners with two equivalent O(26)Sr4Ti2 octahedra, corners with four equivalent O(20)Sr4Ti2 octahedra, corners with four equivalent O(4)Sr5Ti octahedra, edges with two equivalent O(3)Sr5Ti octahedra, edges with two equivalent O(4)Sr5Ti octahedra, edges with two equivalent O(7)Sr5Ti octahedra, edges with two equivalent O(8)Sr5Ti octahedra, faces with two equivalent O(17)Sr4Ti2 octahedra, and faces with two equivalent O(20)Sr4Ti2 octahedra. The corner-sharing octahedral tilt angles range from 0-55°. In the eighth O site, O(4) is bonded to one Sr(4), two equivalent Sr(7), two equivalent Sr(8), and one Ti(2) atom to form distorted OSr5Ti octahedra that share  a cornercorner with one O(10)Sr4Ti2 octahedra,  a cornercorner with one O(27)Sr4Ti2 octahedra,  a cornercorner with one O(28)Sr4Ti2 octahedra, corners with two equivalent O(25)Sr4Ti2 octahedra, corners with four equivalent O(17)Sr4Ti2 octahedra, corners with four equivalent O(20)Sr4Ti2 octahedra, corners with four equivalent O(3)Sr5Ti octahedra, edges with two equivalent O(3)Sr5Ti octahedra, edges with two equivalent O(4)Sr5Ti octahedra, edges with two equivalent O(7)Sr5Ti octahedra, edges with two equivalent O(8)Sr5Ti octahedra,  a faceface with one O(18)Sr4Ti2 octahedra,  a faceface with one O(19)Sr4Ti2 octahedra, and faces with two equivalent O(20)Sr4Ti2 octahedra. The corner-sharing octahedral tilt angles range from 0-55°. In the ninth O site, O(5) is bonded to one Sr(5), two equivalent Sr(1), two equivalent Sr(2), and one Ti(3) atom to form distorted OSr5Ti octahedra that share  a cornercorner with one O(9)Sr4Ti2 octahedra, corners with two equivalent O(13)Sr4Fe2 octahedra, corners with two equivalent O(14)Sr4Fe2 octahedra, corners with two equivalent O(22)Sr4Ti2 octahedra, corners with two equivalent O(23)Sr4Ti2 octahedra, corners with four equivalent O(24)Sr4Ti2 octahedra, corners with four equivalent O(6)Sr5Ti octahedra, edges with two equivalent O(1)Sr5Fe octahedra, edges with two equivalent O(2)Sr5Fe octahedra, edges with two equivalent O(5)Sr5Ti octahedra, edges with two equivalent O(6)Sr5Ti octahedra, faces with two equivalent O(21)Sr4Ti2 octahedra, and faces with two equivalent O(24)Sr4Ti2 octahedra. The corner-sharing octahedral tilt angles range from 0-56°. In the tenth O site, O(6) is bonded to one Sr(6), two equivalent Sr(1), two equivalent Sr(2), and one Ti(4) atom to form distorted OSr5Ti octahedra that share  a cornercorner with one O(15)Sr4Fe2 octahedra,  a cornercorner with one O(16)Sr4Fe2 octahedra,  a cornercorner with one O(10)Sr4Ti2 octahedra, corners with two equivalent O(13)Sr4Fe2 octahedra, corners with four equivalent O(21)Sr4Ti2 octahedra, corners with four equivalent O(24)Sr4Ti2 octahedra, corners with four equivalent O(5)Sr5Ti octahedra, edges with two equivalent O(1)Sr5Fe octahedra, edges with two equivalent O(2)Sr5Fe octahedra, edges with two equivalent O(5)Sr5Ti octahedra, edges with two equivalent O(6)Sr5Ti octahedra,  a faceface with one O(22)Sr4Ti2 octahedra,  a faceface with one O(23)Sr4Ti2 octahedra, and faces with two equivalent O(24)Sr4Ti2 octahedra. The corner-sharing octahedral tilt angles range from 0-56°. In the eleventh O site, O(7) is bonded to one Sr(7), two equivalent Sr(3), two equivalent Sr(4), and one Ti(5) atom to form distorted OSr5Ti octahedra that share  a cornercorner with one O(17)Sr4Ti2 octahedra,  a cornercorner with one O(18)Sr4Ti2 octahedra, corners with two equivalent O(20)Sr4Ti2 octahedra, corners with two equivalent O(26)Sr4Ti2 octahedra, corners with two equivalent O(28)Sr4Ti2 octahedra, corners with two equivalent O(7)Sr5Ti octahedra, corners with two equivalent O(8)Sr5Ti octahedra, corners with four equivalent O(25)Sr4Ti2 octahedra,  an edgeedge with one O(7)Sr5Ti octahedra, edges with two equivalent O(3)Sr5Ti octahedra, edges with two equivalent O(4)Sr5Ti octahedra, edges with three equivalent O(8)Sr5Ti octahedra,  a faceface with one O(26)Sr4Ti2 octahedra,  a faceface with one O(27)Sr4Ti2 octahedra, and faces with two equivalent O(25)Sr4Ti2 octahedra. The corner-sharing octahedral tilt angles range from 8-56°. In the twelfth O site, O(8) is bonded to one Sr(8), two equivalent Sr(3), two equivalent Sr(4), and one Ti(6) atom to form distorted OSr5Ti octahedra that share  a cornercorner with one O(17)Sr4Ti2 octahedra,  a cornercorner with one O(19)Sr4Ti2 octahedra, corners with two equivalent O(20)Sr4Ti2 octahedra, corners with two equivalent O(26)Sr4Ti2 octahedra, corners with two equivalent O(27)Sr4Ti2 octahedra, corners with two equivalent O(7)Sr5Ti octahedra, corners with two equivalent O(8)Sr5Ti octahedra, corners with four equivalent O(25)Sr4Ti2 octahedra,  an edgeedge with one O(8)Sr5Ti octahedra, edges with two equivalent O(3)Sr5Ti octahedra, edges with two equivalent O(4)Sr5Ti octahedra, edges with three equivalent O(7)Sr5Ti octahedra,  a faceface with one O(26)Sr4Ti2 octahedra,  a faceface with one O(28)Sr4Ti2 octahedra, and faces with two equivalent O(25)Sr4Ti2 octahedra. The corner-sharing octahedral tilt angles range from 8-55°. In the thirteenth O site, O(9) is bonded to two equivalent Sr(10), two equivalent Sr(9), one Ti(1), and one Ti(3) atom to form distorted OSr4Ti2 octahedra that share  a cornercorner with one O(3)Sr5Ti octahedra,  a cornercorner with one O(5)Sr5Ti octahedra, corners with two equivalent O(18)Sr4Ti2 octahedra, corners with two equivalent O(19)Sr4Ti2 octahedra, corners with two equivalent O(22)Sr4Ti2 octahedra, corners with two equivalent O(23)Sr4Ti2 octahedra, corners with four equivalent O(10)Sr4Ti2 octahedra, corners with four equivalent O(20)Sr4Ti2 octahedra, corners with four equivalent O(24)Sr4Ti2 octahedra, edges with two equivalent O(10)Sr4Ti2 octahedra, edges with two equivalent O(9)Sr4Ti2 octahedra, faces with two equivalent O(17)Sr4Ti2 octahedra, faces with two equivalent O(20)Sr4Ti2 octahedra, faces with two equivalent O(21)Sr4Ti2 octahedra, and faces with two equivalent O(24)Sr4Ti2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°. In the fourteenth O site, O(10) is bonded to two equivalent Sr(10), two equivalent Sr(9), one Ti(2), and one Ti(4) atom to form distorted OSr4Ti2 octahedra that share  a cornercorner with one O(4)Sr5Ti octahedra,  a cornercorner with one O(6)Sr5Ti octahedra, corners with four equivalent O(17)Sr4Ti2 octahedra, corners with four equivalent O(20)Sr4Ti2 octahedra, corners with four equivalent O(21)Sr4Ti2 octahedra, corners with four equivalent O(24)Sr4Ti2 octahedra, corners with four equivalent O(9)Sr4Ti2 octahedra, edges with two equivalent O(10)Sr4Ti2 octahedra, edges with two equivalent O(9)Sr4Ti2 octahedra,  a faceface with one O(18)Sr4Ti2 octahedra,  a faceface with one O(19)Sr4Ti2 octahedra,  a faceface with one O(22)Sr4Ti2 octahedra,  a faceface with one O(23)Sr4Ti2 octahedra, faces with two equivalent O(20)Sr4Ti2 octahedra, and faces with two equivalent O(24)Sr4Ti2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°. In the fifteenth O site, O(11) is bonded in a distorted linear geometry to two equivalent Sr(11), two equivalent Sr(12), one Ti(5), and one Fe(1) atom. In the sixteenth O site, O(12) is bonded in a distorted linear geometry to two equivalent Sr(11), two equivalent Sr(12), one Ti(6), and one Fe(2) atom. In the seventeenth O site, O(13) is bonded to one Sr(11), one Sr(12), one Sr(5), one Sr(6), one Fe(1), and one Fe(2) atom to form distorted OSr4Fe2 octahedra that share  a cornercorner with one O(27)Sr4Ti2 octahedra,  a cornercorner with one O(28)Sr4Ti2 octahedra,  a cornercorner with one O(5)Sr5Ti octahedra,  a cornercorner with one O(6)Sr5Ti octahedra, corners with two equivalent O(13)Sr4Fe2 octahedra, corners with two equivalent O(25)Sr4Ti2 octahedra, corners with two equivalent O(26)Sr4Ti2 octahedra, corners with two equivalent O(1)Sr5Fe octahedra, corners with two equivalent O(2)Sr5Fe octahedra,  an edgeedge with one O(25)Sr4Ti2 octahedra, edges with two equivalent O(13)Sr4Fe2 octahedra,  a faceface with one O(15)Sr4Fe2 octahedra,  a faceface with one O(16)Sr4Fe2 octahedra,  a faceface with one O(1)Sr5Fe octahedra,  a faceface with one O(2)Sr5Fe octahedra, and faces with two equivalent O(14)Sr4Fe2 octahedra. The corner-sharing octahedral tilt angles range from 2-62°. In the eighteenth O site, O(14) is bonded to two equivalent Sr(11), two equivalent Sr(5), one Fe(1), and one Fe(2) atom to form distorted OSr4Fe2 octahedra that share  a cornercorner with one O(15)Sr4Fe2 octahedra,  a cornercorner with one O(16)Sr4Fe2 octahedra, corners with two equivalent O(26)Sr4Ti2 octahedra, corners with two equivalent O(1)Sr5Fe octahedra, corners with two equivalent O(2)Sr5Fe octahedra, corners with two equivalent O(5)Sr5Ti octahedra, corners with four equivalent O(25)Sr4Ti2 octahedra,  an edgeedge with one O(26)Sr4Ti2 octahedra, edges with two equivalent O(14)Sr4Fe2 octahedra,  a faceface with one O(1)Sr5Fe octahedra,  a faceface with one O(2)Sr5Fe octahedra, and faces with four equivalent O(13)Sr4Fe2 octahedra. The corner-sharing octahedral tilt angles range from 2-61°. In the nineteenth O site, O(15) is bonded to two equivalent Sr(12), two equivalent Sr(6), and two equivalent Fe(1) atoms to form distorted OSr4Fe2 octahedra that share corners with two equivalent O(14)Sr4Fe2 octahedra, corners with two equivalent O(28)Sr4Ti2 octahedra, corners with two equivalent O(6)Sr5Ti octahedra, corners with four equivalent O(25)Sr4Ti2 octahedra, corners with four equivalent O(2)Sr5Fe octahedra,  an edgeedge with one O(27)Sr4Ti2 octahedra, edges with two equivalent O(16)Sr4Fe2 octahedra, faces with two equivalent O(1)Sr5Fe octahedra, and faces with four equivalent O(13)Sr4Fe2 octahedra. The corner-sharing octahedral tilt angles range from 2-60°. In the twentieth O site, O(16) is bonded to two equivalent Sr(12), two equivalent Sr(6), and two equivalent Fe(2) atoms to form distorted OSr4Fe2 octahedra that share corners with two equivalent O(14)Sr4Fe2 octahedra, corners with two equivalent O(27)Sr4Ti2 octahedra, corners with two equivalent O(6)Sr5Ti octahedra, corners with four equivalent O(25)Sr4Ti2 octahedra, corners with four equivalent O(1)Sr5Fe octahedra,  an edgeedge with one O(28)Sr4Ti2 octahedra, edges with two equivalent O(15)Sr4Fe2 octahedra, faces with two equivalent O(2)Sr5Fe octahedra, and faces with four equivalent O(13)Sr4Fe2 octahedra. The corner-sharing octahedral tilt angles range from 2-60°. In the twenty-first O site, O(17) is bonded to one Sr(10), one Sr(7), one Sr(8), one Sr(9), and two equivalent Ti(1) atoms to form distorted OSr4Ti2 octahedra that share  a cornercorner with one O(22)Sr4Ti2 octahedra,  a cornercorner with one O(23)Sr4Ti2 octahedra,  a cornercorner with one O(7)Sr5Ti octahedra,  a cornercorner with one O(8)Sr5Ti octahedra, corners with two equivalent O(17)Sr4Ti2 octahedra, corners with four equivalent O(10)Sr4Ti2 octahedra, corners with four equivalent O(24)Sr4Ti2 octahedra, corners with four equivalent O(4)Sr5Ti octahedra,  an edgeedge with one O(18)Sr4Ti2 octahedra,  an edgeedge with one O(19)Sr4Ti2 octahedra,  an edgeedge with one O(21)Sr4Ti2 octahedra, faces with two equivalent O(9)Sr4Ti2 octahedra, faces with two equivalent O(3)Sr5Ti octahedra, and faces with four equivalent O(20)Sr4Ti2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°. In the twenty-second O site, O(18) is bonded to two equivalent Sr(7), two equivalent Sr(9), and two equivalent Ti(2) atoms to form distorted OSr4Ti2 octahedra that share corners with two equivalent O(19)Sr4Ti2 octahedra, corners with two equivalent O(21)Sr4Ti2 octahedra, corners with two equivalent O(7)Sr5Ti octahedra, corners with four equivalent O(24)Sr4Ti2 octahedra, corners with four equivalent O(9)Sr4Ti2 octahedra, corners with four equivalent O(3)Sr5Ti octahedra,  an edgeedge with one O(22)Sr4Ti2 octahedra, edges with two equivalent O(17)Sr4Ti2 octahedra, faces with two equivalent O(10)Sr4Ti2 octahedra, faces with two equivalent O(4)Sr5Ti octahedra, and faces with four equivalent O(20)Sr4Ti2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°. In the twenty-third O site, O(19) is bonded to two equivalent Sr(10), two equivalent Sr(8), and two equivalent Ti(2) atoms to form distorted OSr4Ti2 octahedra that share corners with two equivalent O(18)Sr4Ti2 octahedra, corners with two equivalent O(21)Sr4Ti2 octahedra, corners with two equivalent O(8)Sr5Ti octahedra, corners with four equivalent O(24)Sr4Ti2 octahedra, corners with four equivalent O(9)Sr4Ti2 octahedra, corners with four equivalent O(3)Sr5Ti octahedra,  an edgeedge with one O(23)Sr4Ti2 octahedra, edges with two equivalent O(17)Sr4Ti2 octahedra, faces with two equivalent O(10)Sr4Ti2 octahedra, faces with two equivalent O(4)Sr5Ti octahedra, and faces with four equivalent O(20)Sr4Ti2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°. In the twenty-fourth O site, O(20) is bonded to one Sr(10), one Sr(7), one Sr(8), one Sr(9), one Ti(1), and one Ti(2) atom to form distorted OSr4Ti2 octahedra that share  a cornercorner with one O(22)Sr4Ti2 octahedra,  a cornercorner with one O(23)Sr4Ti2 octahedra,  a cornercorner with one O(7)Sr5Ti octahedra,  a cornercorner with one O(8)Sr5Ti octahedra, corners with two equivalent O(10)Sr4Ti2 octahedra, corners with two equivalent O(20)Sr4Ti2 octahedra, corners with two equivalent O(21)Sr4Ti2 octahedra, corners with two equivalent O(24)Sr4Ti2 octahedra, corners with two equivalent O(9)Sr4Ti2 octahedra, corners with two equivalent O(3)Sr5Ti octahedra, corners with two equivalent O(4)Sr5Ti octahedra,  an edgeedge with one O(24)Sr4Ti2 octahedra, edges with two equivalent O(20)Sr4Ti2 octahedra,  a faceface with one O(10)Sr4Ti2 octahedra,  a faceface with one O(18)Sr4Ti2 octahedra,  a faceface with one O(19)Sr4Ti2 octahedra,  a faceface with one O(9)Sr4Ti2 octahedra,  a faceface with one O(3)Sr5Ti octahedra,  a faceface with one O(4)Sr5Ti octahedra, and faces with two equivalent O(17)Sr4Ti2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°. In the twenty-fifth O site, O(21) is bonded to one Sr(1), one Sr(10), one Sr(2), one Sr(9), and two equivalent Ti(3) atoms to form distorted OSr4Ti2 octahedra that share  a cornercorner with one O(18)Sr4Ti2 octahedra,  a cornercorner with one O(19)Sr4Ti2 octahedra,  a cornercorner with one O(1)Sr5Fe octahedra,  a cornercorner with one O(2)Sr5Fe octahedra, corners with two equivalent O(21)Sr4Ti2 octahedra, corners with four equivalent O(10)Sr4Ti2 octahedra, corners with four equivalent O(20)Sr4Ti2 octahedra, corners with four equivalent O(6)Sr5Ti octahedra,  an edgeedge with one O(17)Sr4Ti2 octahedra,  an edgeedge with one O(22)Sr4Ti2 octahedra,  an edgeedge with one O(23)Sr4Ti2 octahedra, faces with two equivalent O(9)Sr4Ti2 octahedra, faces with two equivalent O(5)Sr5Ti octahedra, and faces with four equivalent O(24)Sr4Ti2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°. In the twenty-sixth O site, O(22) is bonded to two equivalent Sr(1), two equivalent Sr(9), and two equivalent Ti(4) atoms to form distorted OSr4Ti2 octahedra that share corners with two equivalent O(17)Sr4Ti2 octahedra, corners with two equivalent O(23)Sr4Ti2 octahedra, corners with two equivalent O(1)Sr5Fe octahedra, corners with four equivalent O(20)Sr4Ti2 octahedra, corners with four equivalent O(9)Sr4Ti2 octahedra, corners with four equivalent O(5)Sr5Ti octahedra,  an edgeedge with one O(18)Sr4Ti2 octahedra, edges with two equivalent O(21)Sr4Ti2 octahedra, faces with two equivalent O(10)Sr4Ti2 octahedra, faces with two equivalent O(6)Sr5Ti octahedra, and faces with four equivalent O(24)Sr4Ti2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°. In the twenty-seventh O site, O(23) is bonded to two equivalent Sr(10), two equivalent Sr(2), and two equivalent Ti(4) atoms to form distorted OSr4Ti2 octahedra that share corners with two equivalent O(17)Sr4Ti2 octahedra, corners with two equivalent O(22)Sr4Ti2 octahedra, corners with two equivalent O(2)Sr5Fe octahedra, corners with four equivalent O(20)Sr4Ti2 octahedra, corners with four equivalent O(9)Sr4Ti2 octahedra, corners with four equivalent O(5)Sr5Ti octahedra,  an edgeedge with one O(19)Sr4Ti2 octahedra, edges with two equivalent O(21)Sr4Ti2 octahedra, faces with two equivalent O(10)Sr4Ti2 octahedra, faces with two equivalent O(6)Sr5Ti octahedra, and faces with four equivalent O(24)Sr4Ti2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°. In the twenty-eighth O site, O(24) is bonded to one Sr(1), one Sr(10), one Sr(2), one Sr(9), one Ti(3), and one Ti(4) atom to form distorted OSr4Ti2 octahedra that share  a cornercorner with one O(18)Sr4Ti2 octahedra,  a cornercorner with one O(19)Sr4Ti2 octahedra,  a cornercorner with one O(1)Sr5Fe octahedra,  a cornercorner with one O(2)Sr5Fe octahedra, corners with two equivalent O(10)Sr4Ti2 octahedra, corners with two equivalent O(17)Sr4Ti2 octahedra, corners with two equivalent O(20)Sr4Ti2 octahedra, corners with two equivalent O(24)Sr4Ti2 octahedra, corners with two equivalent O(9)Sr4Ti2 octahedra, corners with two equivalent O(5)Sr5Ti octahedra, corners with two equivalent O(6)Sr5Ti octahedra,  an edgeedge with one O(20)Sr4Ti2 octahedra, edges with two equivalent O(24)Sr4Ti2 octahedra,  a faceface with one O(10)Sr4Ti2 octahedra,  a faceface with one O(22)Sr4Ti2 octahedra,  a faceface with one O(23)Sr4Ti2 octahedra,  a faceface with one O(9)Sr4Ti2 octahedra,  a faceface with one O(5)Sr5Ti octahedra,  a faceface with one O(6)Sr5Ti octahedra, and faces with two equivalent O(21)Sr4Ti2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°. is represented by the CIF card [CIF]
data_Sr6Ti3FeO14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.937
_cell_length_b   3.944
_cell_length_c   20.420
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.005
_symmetry_Int_Tables_number   1
_cell_volume   317.047
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.500  0.500  0.598  1.0
  O  O1  1  0.500  0.500  0.693  1.0
  O  O2  1  1.000  1.000  0.194  1.0
  O  O3  1  1.000  1.000  0.805  1.0
  O  O4  1  0.500  0.500  0.307  1.0
  O  O5  1  1.000  1.000  1.000  1.0
  O  O6  1  0.500  0.500  0.501  1.0
  O  O7  1  0.500  0.000  0.596  1.0
  O  O8  1  0.000  0.500  0.596  1.0
  O  O9  1  1.000  0.500  0.097  1.0
  O  O10  1  0.500  1.000  0.097  1.0
  O  O11  1  1.000  0.500  0.903  1.0
  O  O12  1  0.500  1.000  0.903  1.0
  O  O13  1  0.500  0.000  0.404  1.0
  O  O14  1  0.000  0.500  0.404  1.0
  Sr  Sr15  1  0.500  0.500  0.814  1.0
  Sr  Sr16  1  1.000  0.000  0.317  1.0
  Sr  Sr17  1  0.000  0.000  0.681  1.0
  Sr  Sr18  1  0.500  0.500  0.185  1.0
  Sr  Sr19  1  0.500  0.500  1.000  1.0
  Sr  Sr20  1  1.000  0.000  0.503  1.0
  Ti  Ti21  1  1.000  0.000  0.098  1.0
  Ti  Ti22  1  0.000  1.000  0.901  1.0
  Ti  Ti23  1  0.500  0.500  0.403  1.0
[/CIF]
.