The material described by Ni(AuF4)2 crystallizes in the monoclinic P2_1/c space group. Ni(1) is bonded in an octahedral geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. Au(1) is bonded in a rectangular see-saw-like geometry to one F(1), one F(2), one F(3), and one F(4) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a distorted bent 150 degrees geometry to one Ni(1) and one Au(1) atom. In the second F site, F(2) is bonded in a bent 150 degrees geometry to one Ni(1) and one Au(1) atom. In the third F site, F(3) is bonded in a bent 120 degrees geometry to one Ni(1) and one Au(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Au(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ni(AuF4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.448
_cell_length_b   5.447
_cell_length_c   10.680
_cell_angle_alpha   70.575
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   298.903
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni0  1  0.500  0.500  0.000  1.0
  Ni  Ni1  1  0.000  0.500  0.500  1.0
  Au  Au2  1  0.708  0.866  0.665  1.0
  Au  Au3  1  0.208  0.134  0.835  1.0
  Au  Au4  1  0.292  0.134  0.335  1.0
  Au  Au5  1  0.792  0.866  0.165  1.0
  F  F6  1  0.598  0.562  0.812  1.0
  F  F7  1  0.098  0.438  0.688  1.0
  F  F8  1  0.402  0.438  0.188  1.0
  F  F9  1  0.902  0.562  0.312  1.0
  F  F10  1  0.686  0.173  0.019  1.0
  F  F11  1  0.186  0.827  0.481  1.0
  F  F12  1  0.798  0.660  0.044  1.0
  F  F13  1  0.298  0.340  0.456  1.0
  F  F14  1  0.202  0.340  0.956  1.0
  F  F15  1  0.702  0.660  0.544  1.0
  F  F16  1  0.794  0.067  0.282  1.0
  F  F17  1  0.294  0.933  0.218  1.0
  F  F18  1  0.206  0.933  0.718  1.0
  F  F19  1  0.706  0.067  0.782  1.0
  F  F20  1  0.814  0.173  0.519  1.0
  F  F21  1  0.314  0.827  0.981  1.0
[/CIF]
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The material described by Ni(AuF4)2 crystallizes in the monoclinic P2_1/c space group. Ni(1) is bonded in an octahedral geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. Au(1) is bonded in a rectangular see-saw-like geometry to one F(1), one F(2), one F(3), and one F(4) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a distorted bent 150 degrees geometry to one Ni(1) and one Au(1) atom. In the second F site, F(2) is bonded in a bent 150 degrees geometry to one Ni(1) and one Au(1) atom. In the third F site, F(3) is bonded in a bent 120 degrees geometry to one Ni(1) and one Au(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Au(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ni(AuF4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.448
_cell_length_b   5.447
_cell_length_c   10.680
_cell_angle_alpha   70.575
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   298.903
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni0  1  0.500  0.500  0.000  1.0
  Ni  Ni1  1  0.000  0.500  0.500  1.0
  Au  Au2  1  0.708  0.866  0.665  1.0
  Au  Au3  1  0.208  0.134  0.835  1.0
  Au  Au4  1  0.292  0.134  0.335  1.0
  Au  Au5  1  0.792  0.866  0.165  1.0
  F  F6  1  0.598  0.562  0.812  1.0
  F  F7  1  0.098  0.438  0.688  1.0
  F  F8  1  0.402  0.438  0.188  1.0
  F  F9  1  0.902  0.562  0.312  1.0
  F  F10  1  0.686  0.173  0.019  1.0
  F  F11  1  0.186  0.827  0.481  1.0
  F  F12  1  0.798  0.660  0.044  1.0
  F  F13  1  0.298  0.340  0.456  1.0
  F  F14  1  0.202  0.340  0.956  1.0
  F  F15  1  0.702  0.660  0.544  1.0
  F  F16  1  0.794  0.067  0.282  1.0
  F  F17  1  0.294  0.933  0.218  1.0
  F  F18  1  0.206  0.933  0.718  1.0
  F  F19  1  0.706  0.067  0.782  1.0
  F  F20  1  0.814  0.173  0.519  1.0
  F  F21  1  0.314  0.827  0.981  1.0
[/CIF]
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