The structure described by AsF6(I)5 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight hydriodic acid atoms, four AsF6 clusters, and four I clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In each I cluster, there are two inequivalent I sites. In the first I site, I(1) is bonded in a 2-coordinate geometry to one I(2) atom. In the second I site, I(2) is bonded in a linear geometry to two equivalent I(1) atoms. is represented by the CIF file [CIF]
data_AsI5F6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.540
_cell_length_b   10.540
_cell_length_c   8.533
_cell_angle_alpha   71.778
_cell_angle_beta   71.778
_cell_angle_gamma   119.977
_symmetry_Int_Tables_number   1
_cell_volume   640.833
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.408  0.592  0.750  1.0
  As  As1  1  0.592  0.408  0.250  1.0
  I  I2  1  0.666  0.887  0.054  1.0
  I  I3  1  0.000  0.000  0.500  1.0
  I  I4  1  0.334  0.113  0.946  1.0
  I  I5  1  0.887  0.666  0.554  1.0
  I  I6  1  0.000  0.000  0.000  1.0
  I  I7  1  0.113  0.334  0.446  1.0
  I  I8  1  0.297  0.844  0.941  1.0
  I  I9  1  0.156  0.703  0.559  1.0
  I  I10  1  0.703  0.156  0.059  1.0
  I  I11  1  0.844  0.297  0.441  1.0
  F  F12  1  0.775  0.455  0.068  1.0
  F  F13  1  0.545  0.225  0.432  1.0
  F  F14  1  0.225  0.545  0.932  1.0
  F  F15  1  0.455  0.775  0.568  1.0
  F  F16  1  0.642  0.594  0.068  1.0
  F  F17  1  0.406  0.358  0.432  1.0
  F  F18  1  0.274  0.460  0.695  1.0
  F  F19  1  0.594  0.642  0.568  1.0
  F  F20  1  0.460  0.274  0.195  1.0
  F  F21  1  0.726  0.540  0.305  1.0
  F  F22  1  0.540  0.726  0.805  1.0
  F  F23  1  0.358  0.406  0.932  1.0
[/CIF]
.
The structure described by AsF6(I)5 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight hydriodic acid atoms, four AsF6 clusters, and four I clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In each I cluster, there are two inequivalent I sites. In the first I site, I(1) is bonded in a 2-coordinate geometry to one I(2) atom. In the second I site, I(2) is bonded in a linear geometry to two equivalent I(1) atoms. is represented by the CIF file [CIF]
data_AsI5F6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.540
_cell_length_b   10.540
_cell_length_c   8.533
_cell_angle_alpha   71.778
_cell_angle_beta   71.778
_cell_angle_gamma   119.977
_symmetry_Int_Tables_number   1
_cell_volume   640.833
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.408  0.592  0.750  1.0
  As  As1  1  0.592  0.408  0.250  1.0
  I  I2  1  0.666  0.887  0.054  1.0
  I  I3  1  0.000  0.000  0.500  1.0
  I  I4  1  0.334  0.113  0.946  1.0
  I  I5  1  0.887  0.666  0.554  1.0
  I  I6  1  0.000  0.000  0.000  1.0
  I  I7  1  0.113  0.334  0.446  1.0
  I  I8  1  0.297  0.844  0.941  1.0
  I  I9  1  0.156  0.703  0.559  1.0
  I  I10  1  0.703  0.156  0.059  1.0
  I  I11  1  0.844  0.297  0.441  1.0
  F  F12  1  0.775  0.455  0.068  1.0
  F  F13  1  0.545  0.225  0.432  1.0
  F  F14  1  0.225  0.545  0.932  1.0
  F  F15  1  0.455  0.775  0.568  1.0
  F  F16  1  0.642  0.594  0.068  1.0
  F  F17  1  0.406  0.358  0.432  1.0
  F  F18  1  0.274  0.460  0.695  1.0
  F  F19  1  0.594  0.642  0.568  1.0
  F  F20  1  0.460  0.274  0.195  1.0
  F  F21  1  0.726  0.540  0.305  1.0
  F  F22  1  0.540  0.726  0.805  1.0
  F  F23  1  0.358  0.406  0.932  1.0
[/CIF]
.