The material described by ErPrMn4Co13 crystallizes in the monoclinic Cm space group. Er(1) is bonded in a 19-coordinate geometry to one Mn(1), two equivalent Mn(3), one Co(5), one Co(8), two equivalent Co(1), two equivalent Co(2), two equivalent Co(3), two equivalent Co(4), two equivalent Co(7), and four equivalent Co(6) atoms. Pr(1) is bonded in a 16-coordinate geometry to one Mn(2), one Co(7), one Co(8), two equivalent Co(1), two equivalent Co(2), two equivalent Co(3), two equivalent Co(5), two equivalent Co(6), and four equivalent Co(4) atoms. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a 14-coordinate geometry to one Er(1), one Mn(2), two equivalent Mn(3), one Co(7), one Co(8), two equivalent Co(1), two equivalent Co(2), two equivalent Co(3), and two equivalent Co(6) atoms. In the second Mn site, Mn(2) is bonded in a 14-coordinate geometry to one Pr(1), one Mn(1), two equivalent Mn(3), one Co(5), one Co(8), two equivalent Co(1), two equivalent Co(2), two equivalent Co(3), and two equivalent Co(4) atoms. In the third Mn site, Mn(3) is bonded in a 8-coordinate geometry to one Er(1), one Mn(1), one Mn(2), one Co(1), one Co(2), one Co(4), one Co(5), one Co(6), one Co(7), and two equivalent Co(3) atoms. There are eight inequivalent Co sites. In the first Co site, Co(1) is bonded in a 12-coordinate geometry to one Er(1), one Pr(1), one Mn(1), one Mn(2), one Mn(3), one Co(1), one Co(3), one Co(6), one Co(7), one Co(8), and two equivalent Co(4) atoms. In the second Co site, Co(2) is bonded in a 12-coordinate geometry to one Er(1), one Pr(1), one Mn(1), one Mn(2), one Mn(3), one Co(2), one Co(3), one Co(4), one Co(5), one Co(8), and two equivalent Co(6) atoms. In the third Co site, Co(3) is bonded in a 12-coordinate geometry to one Er(1), one Pr(1), one Mn(1), one Mn(2), two equivalent Mn(3), one Co(1), one Co(2), one Co(4), one Co(5), one Co(6), and one Co(7) atom. In the fourth Co site, Co(4) is bonded to one Er(1), two equivalent Pr(1), one Mn(2), one Mn(3), one Co(2), one Co(3), one Co(6), one Co(7), one Co(8), and two equivalent Co(1) atoms to form distorted CoPr2ErMn2Co7 cuboctahedra that share corners with two equivalent Co(4)Pr2ErMn2Co7 cuboctahedra, corners with three equivalent Co(7)PrEr2Mn3Co6 cuboctahedra, corners with five equivalent Co(6)PrEr2Mn2Co7 cuboctahedra,  an edgeedge with one Co(6)PrEr2Mn2Co7 cuboctahedra, edges with two equivalent Co(4)Pr2ErMn2Co7 cuboctahedra, edges with two equivalent Co(5)Pr2ErMn3Co6 cuboctahedra,  a faceface with one Co(7)PrEr2Mn3Co6 cuboctahedra, faces with two equivalent Co(4)Pr2ErMn2Co7 cuboctahedra, faces with two equivalent Co(5)Pr2ErMn3Co6 cuboctahedra, and faces with two equivalent Co(6)PrEr2Mn2Co7 cuboctahedra. In the fifth Co site, Co(5) is bonded to one Er(1), two equivalent Pr(1), one Mn(2), two equivalent Mn(3), two equivalent Co(2), two equivalent Co(3), and two equivalent Co(6) atoms to form distorted CoPr2ErMn3Co6 cuboctahedra that share corners with two equivalent Co(5)Pr2ErMn3Co6 cuboctahedra, corners with two equivalent Co(7)PrEr2Mn3Co6 cuboctahedra, corners with six equivalent Co(6)PrEr2Mn2Co7 cuboctahedra,  an edgeedge with one Co(7)PrEr2Mn3Co6 cuboctahedra, edges with four equivalent Co(4)Pr2ErMn2Co7 cuboctahedra,  a faceface with one Co(7)PrEr2Mn3Co6 cuboctahedra, faces with two equivalent Co(6)PrEr2Mn2Co7 cuboctahedra, and faces with four equivalent Co(4)Pr2ErMn2Co7 cuboctahedra. In the sixth Co site, Co(6) is bonded to two equivalent Er(1), one Pr(1), one Mn(1), one Mn(3), one Co(1), one Co(3), one Co(4), one Co(5), one Co(8), and two equivalent Co(2) atoms to form distorted CoPrEr2Mn2Co7 cuboctahedra that share corners with two equivalent Co(6)PrEr2Mn2Co7 cuboctahedra, corners with three equivalent Co(5)Pr2ErMn3Co6 cuboctahedra, corners with five equivalent Co(4)Pr2ErMn2Co7 cuboctahedra,  an edgeedge with one Co(4)Pr2ErMn2Co7 cuboctahedra, edges with two equivalent Co(6)PrEr2Mn2Co7 cuboctahedra, edges with two equivalent Co(7)PrEr2Mn3Co6 cuboctahedra,  a faceface with one Co(5)Pr2ErMn3Co6 cuboctahedra, faces with two equivalent Co(4)Pr2ErMn2Co7 cuboctahedra, faces with two equivalent Co(6)PrEr2Mn2Co7 cuboctahedra, and faces with two equivalent Co(7)PrEr2Mn3Co6 cuboctahedra. In the seventh Co site, Co(7) is bonded to two equivalent Er(1), one Pr(1), one Mn(1), two equivalent Mn(3), two equivalent Co(1), two equivalent Co(3), and two equivalent Co(4) atoms to form distorted CoPrEr2Mn3Co6 cuboctahedra that share corners with two equivalent Co(5)Pr2ErMn3Co6 cuboctahedra, corners with two equivalent Co(7)PrEr2Mn3Co6 cuboctahedra, corners with six equivalent Co(4)Pr2ErMn2Co7 cuboctahedra,  an edgeedge with one Co(5)Pr2ErMn3Co6 cuboctahedra, edges with four equivalent Co(6)PrEr2Mn2Co7 cuboctahedra,  a faceface with one Co(5)Pr2ErMn3Co6 cuboctahedra, faces with two equivalent Co(4)Pr2ErMn2Co7 cuboctahedra, and faces with four equivalent Co(6)PrEr2Mn2Co7 cuboctahedra. In the eighth Co site, Co(8) is bonded in a 12-coordinate geometry to one Er(1), one Pr(1), one Mn(1), one Mn(2), two equivalent Co(1), two equivalent Co(2), two equivalent Co(4), and two equivalent Co(6) atoms. is represented by the CIF card [CIF]
data_PrErMn4Co13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.344
_cell_length_b   6.384
_cell_length_c   6.384
_cell_angle_alpha   83.066
_cell_angle_beta   82.606
_cell_angle_gamma   82.606
_symmetry_Int_Tables_number   1
_cell_volume   252.870
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pr  Pr0  1  0.345  0.349  0.349  1.0
  Er  Er1  1  0.658  0.654  0.654  1.0
  Mn  Mn2  1  0.892  0.899  0.899  1.0
  Mn  Mn3  1  0.106  0.099  0.099  1.0
  Mn  Mn4  1  0.998  0.998  0.500  1.0
  Mn  Mn5  1  0.998  0.500  0.998  1.0
  Co  Co6  1  0.289  0.714  0.998  1.0
  Co  Co7  1  0.711  0.999  0.286  1.0
  Co  Co8  1  0.999  0.284  0.716  1.0
  Co  Co9  1  0.289  0.998  0.714  1.0
  Co  Co10  1  0.999  0.716  0.284  1.0
  Co  Co11  1  0.711  0.286  0.999  1.0
  Co  Co12  1  0.348  0.348  0.845  1.0
  Co  Co13  1  0.348  0.845  0.348  1.0
  Co  Co14  1  0.844  0.345  0.345  1.0
  Co  Co15  1  0.655  0.655  0.154  1.0
  Co  Co16  1  0.655  0.154  0.655  1.0
  Co  Co17  1  0.155  0.658  0.658  1.0
  Co  Co18  1  0.501  0.998  0.998  1.0
[/CIF]
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The material described by ErPrMn4Co13 crystallizes in the monoclinic Cm space group. Er(1) is bonded in a 19-coordinate geometry to one Mn(1), two equivalent Mn(3), one Co(5), one Co(8), two equivalent Co(1), two equivalent Co(2), two equivalent Co(3), two equivalent Co(4), two equivalent Co(7), and four equivalent Co(6) atoms. Pr(1) is bonded in a 16-coordinate geometry to one Mn(2), one Co(7), one Co(8), two equivalent Co(1), two equivalent Co(2), two equivalent Co(3), two equivalent Co(5), two equivalent Co(6), and four equivalent Co(4) atoms. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a 14-coordinate geometry to one Er(1), one Mn(2), two equivalent Mn(3), one Co(7), one Co(8), two equivalent Co(1), two equivalent Co(2), two equivalent Co(3), and two equivalent Co(6) atoms. In the second Mn site, Mn(2) is bonded in a 14-coordinate geometry to one Pr(1), one Mn(1), two equivalent Mn(3), one Co(5), one Co(8), two equivalent Co(1), two equivalent Co(2), two equivalent Co(3), and two equivalent Co(4) atoms. In the third Mn site, Mn(3) is bonded in a 8-coordinate geometry to one Er(1), one Mn(1), one Mn(2), one Co(1), one Co(2), one Co(4), one Co(5), one Co(6), one Co(7), and two equivalent Co(3) atoms. There are eight inequivalent Co sites. In the first Co site, Co(1) is bonded in a 12-coordinate geometry to one Er(1), one Pr(1), one Mn(1), one Mn(2), one Mn(3), one Co(1), one Co(3), one Co(6), one Co(7), one Co(8), and two equivalent Co(4) atoms. In the second Co site, Co(2) is bonded in a 12-coordinate geometry to one Er(1), one Pr(1), one Mn(1), one Mn(2), one Mn(3), one Co(2), one Co(3), one Co(4), one Co(5), one Co(8), and two equivalent Co(6) atoms. In the third Co site, Co(3) is bonded in a 12-coordinate geometry to one Er(1), one Pr(1), one Mn(1), one Mn(2), two equivalent Mn(3), one Co(1), one Co(2), one Co(4), one Co(5), one Co(6), and one Co(7) atom. In the fourth Co site, Co(4) is bonded to one Er(1), two equivalent Pr(1), one Mn(2), one Mn(3), one Co(2), one Co(3), one Co(6), one Co(7), one Co(8), and two equivalent Co(1) atoms to form distorted CoPr2ErMn2Co7 cuboctahedra that share corners with two equivalent Co(4)Pr2ErMn2Co7 cuboctahedra, corners with three equivalent Co(7)PrEr2Mn3Co6 cuboctahedra, corners with five equivalent Co(6)PrEr2Mn2Co7 cuboctahedra,  an edgeedge with one Co(6)PrEr2Mn2Co7 cuboctahedra, edges with two equivalent Co(4)Pr2ErMn2Co7 cuboctahedra, edges with two equivalent Co(5)Pr2ErMn3Co6 cuboctahedra,  a faceface with one Co(7)PrEr2Mn3Co6 cuboctahedra, faces with two equivalent Co(4)Pr2ErMn2Co7 cuboctahedra, faces with two equivalent Co(5)Pr2ErMn3Co6 cuboctahedra, and faces with two equivalent Co(6)PrEr2Mn2Co7 cuboctahedra. In the fifth Co site, Co(5) is bonded to one Er(1), two equivalent Pr(1), one Mn(2), two equivalent Mn(3), two equivalent Co(2), two equivalent Co(3), and two equivalent Co(6) atoms to form distorted CoPr2ErMn3Co6 cuboctahedra that share corners with two equivalent Co(5)Pr2ErMn3Co6 cuboctahedra, corners with two equivalent Co(7)PrEr2Mn3Co6 cuboctahedra, corners with six equivalent Co(6)PrEr2Mn2Co7 cuboctahedra,  an edgeedge with one Co(7)PrEr2Mn3Co6 cuboctahedra, edges with four equivalent Co(4)Pr2ErMn2Co7 cuboctahedra,  a faceface with one Co(7)PrEr2Mn3Co6 cuboctahedra, faces with two equivalent Co(6)PrEr2Mn2Co7 cuboctahedra, and faces with four equivalent Co(4)Pr2ErMn2Co7 cuboctahedra. In the sixth Co site, Co(6) is bonded to two equivalent Er(1), one Pr(1), one Mn(1), one Mn(3), one Co(1), one Co(3), one Co(4), one Co(5), one Co(8), and two equivalent Co(2) atoms to form distorted CoPrEr2Mn2Co7 cuboctahedra that share corners with two equivalent Co(6)PrEr2Mn2Co7 cuboctahedra, corners with three equivalent Co(5)Pr2ErMn3Co6 cuboctahedra, corners with five equivalent Co(4)Pr2ErMn2Co7 cuboctahedra,  an edgeedge with one Co(4)Pr2ErMn2Co7 cuboctahedra, edges with two equivalent Co(6)PrEr2Mn2Co7 cuboctahedra, edges with two equivalent Co(7)PrEr2Mn3Co6 cuboctahedra,  a faceface with one Co(5)Pr2ErMn3Co6 cuboctahedra, faces with two equivalent Co(4)Pr2ErMn2Co7 cuboctahedra, faces with two equivalent Co(6)PrEr2Mn2Co7 cuboctahedra, and faces with two equivalent Co(7)PrEr2Mn3Co6 cuboctahedra. In the seventh Co site, Co(7) is bonded to two equivalent Er(1), one Pr(1), one Mn(1), two equivalent Mn(3), two equivalent Co(1), two equivalent Co(3), and two equivalent Co(4) atoms to form distorted CoPrEr2Mn3Co6 cuboctahedra that share corners with two equivalent Co(5)Pr2ErMn3Co6 cuboctahedra, corners with two equivalent Co(7)PrEr2Mn3Co6 cuboctahedra, corners with six equivalent Co(4)Pr2ErMn2Co7 cuboctahedra,  an edgeedge with one Co(5)Pr2ErMn3Co6 cuboctahedra, edges with four equivalent Co(6)PrEr2Mn2Co7 cuboctahedra,  a faceface with one Co(5)Pr2ErMn3Co6 cuboctahedra, faces with two equivalent Co(4)Pr2ErMn2Co7 cuboctahedra, and faces with four equivalent Co(6)PrEr2Mn2Co7 cuboctahedra. In the eighth Co site, Co(8) is bonded in a 12-coordinate geometry to one Er(1), one Pr(1), one Mn(1), one Mn(2), two equivalent Co(1), two equivalent Co(2), two equivalent Co(4), and two equivalent Co(6) atoms. is represented by the CIF card [CIF]
data_PrErMn4Co13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.344
_cell_length_b   6.384
_cell_length_c   6.384
_cell_angle_alpha   83.066
_cell_angle_beta   82.606
_cell_angle_gamma   82.606
_symmetry_Int_Tables_number   1
_cell_volume   252.870
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pr  Pr0  1  0.345  0.349  0.349  1.0
  Er  Er1  1  0.658  0.654  0.654  1.0
  Mn  Mn2  1  0.892  0.899  0.899  1.0
  Mn  Mn3  1  0.106  0.099  0.099  1.0
  Mn  Mn4  1  0.998  0.998  0.500  1.0
  Mn  Mn5  1  0.998  0.500  0.998  1.0
  Co  Co6  1  0.289  0.714  0.998  1.0
  Co  Co7  1  0.711  0.999  0.286  1.0
  Co  Co8  1  0.999  0.284  0.716  1.0
  Co  Co9  1  0.289  0.998  0.714  1.0
  Co  Co10  1  0.999  0.716  0.284  1.0
  Co  Co11  1  0.711  0.286  0.999  1.0
  Co  Co12  1  0.348  0.348  0.845  1.0
  Co  Co13  1  0.348  0.845  0.348  1.0
  Co  Co14  1  0.844  0.345  0.345  1.0
  Co  Co15  1  0.655  0.655  0.154  1.0
  Co  Co16  1  0.655  0.154  0.655  1.0
  Co  Co17  1  0.155  0.658  0.658  1.0
  Co  Co18  1  0.501  0.998  0.998  1.0
[/CIF]
.