The crystal structure described by Mn(CoN)3 crystallizes in the monoclinic P2_1/m space group. Mn(1) is bonded in a distorted trigonal planar geometry to one N(1), one N(2), and one N(3) atom. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded in a distorted square co-planar geometry to one N(2), one N(3), and two equivalent N(1) atoms. In the second Co site, Co(2) is bonded in a distorted square co-planar geometry to one N(1), one N(3), and two equivalent N(2) atoms. In the third Co site, Co(3) is bonded to one N(1), one N(2), and three equivalent N(3) atoms to form a mixture of distorted corner and edge-sharing CoN5 square pyramids. There are three inequivalent N sites. In the first N site, N(1) is bonded to one Mn(1), one Co(2), one Co(3), and two equivalent Co(1) atoms to form distorted NMnCo4 square pyramids that share  a cornercorner with one N(3)MnCo5 octahedra, corners with two equivalent N(1)MnCo4 square pyramids, corners with two equivalent N(2)MnCo4 trigonal bipyramids, edges with three equivalent N(3)MnCo5 octahedra, and edges with two equivalent N(2)MnCo4 trigonal bipyramids. The corner-sharing octahedral tilt angles are 30°. In the second N site, N(2) is bonded to one Mn(1), one Co(1), one Co(3), and two equivalent Co(2) atoms to form NMnCo4 trigonal bipyramids that share corners with three equivalent N(3)MnCo5 octahedra, corners with two equivalent N(1)MnCo4 square pyramids, corners with two equivalent N(2)MnCo4 trigonal bipyramids, edges with two equivalent N(3)MnCo5 octahedra, and edges with two equivalent N(1)MnCo4 square pyramids. The corner-sharing octahedral tilt angles range from 5-41°. In the third N site, N(3) is bonded to one Mn(1), one Co(1), one Co(2), and three equivalent Co(3) atoms to form distorted NMnCo5 octahedra that share corners with two equivalent N(3)MnCo5 octahedra,  a cornercorner with one N(1)MnCo4 square pyramid, corners with three equivalent N(2)MnCo4 trigonal bipyramids, edges with two equivalent N(3)MnCo5 octahedra, edges with three equivalent N(1)MnCo4 square pyramids, and edges with two equivalent N(2)MnCo4 trigonal bipyramids. The corner-sharing octahedral tilt angles are 14°. is represented by the CIF card [CIF]
data_Mn(CoN)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.814
_cell_length_b   5.996
_cell_length_c   3.794
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.123
_symmetry_Int_Tables_number   1
_cell_volume   134.054
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.664  0.280  0.750  1.0
  Mn  Mn1  1  0.336  0.720  0.250  1.0
  Co  Co2  1  0.877  0.702  0.250  1.0
  Co  Co3  1  0.829  0.116  0.250  1.0
  Co  Co4  1  0.379  0.295  0.250  1.0
  Co  Co5  1  0.123  0.298  0.750  1.0
  Co  Co6  1  0.171  0.884  0.750  1.0
  Co  Co7  1  0.621  0.705  0.750  1.0
  N  N8  1  0.870  0.611  0.750  1.0
  N  N9  1  0.786  0.072  0.750  1.0
  N  N10  1  0.393  0.266  0.750  1.0
  N  N11  1  0.130  0.389  0.250  1.0
  N  N12  1  0.214  0.928  0.250  1.0
  N  N13  1  0.607  0.734  0.250  1.0
[/CIF]
.
The crystal structure described by Mn(CoN)3 crystallizes in the monoclinic P2_1/m space group. Mn(1) is bonded in a distorted trigonal planar geometry to one N(1), one N(2), and one N(3) atom. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded in a distorted square co-planar geometry to one N(2), one N(3), and two equivalent N(1) atoms. In the second Co site, Co(2) is bonded in a distorted square co-planar geometry to one N(1), one N(3), and two equivalent N(2) atoms. In the third Co site, Co(3) is bonded to one N(1), one N(2), and three equivalent N(3) atoms to form a mixture of distorted corner and edge-sharing CoN5 square pyramids. There are three inequivalent N sites. In the first N site, N(1) is bonded to one Mn(1), one Co(2), one Co(3), and two equivalent Co(1) atoms to form distorted NMnCo4 square pyramids that share  a cornercorner with one N(3)MnCo5 octahedra, corners with two equivalent N(1)MnCo4 square pyramids, corners with two equivalent N(2)MnCo4 trigonal bipyramids, edges with three equivalent N(3)MnCo5 octahedra, and edges with two equivalent N(2)MnCo4 trigonal bipyramids. The corner-sharing octahedral tilt angles are 30°. In the second N site, N(2) is bonded to one Mn(1), one Co(1), one Co(3), and two equivalent Co(2) atoms to form NMnCo4 trigonal bipyramids that share corners with three equivalent N(3)MnCo5 octahedra, corners with two equivalent N(1)MnCo4 square pyramids, corners with two equivalent N(2)MnCo4 trigonal bipyramids, edges with two equivalent N(3)MnCo5 octahedra, and edges with two equivalent N(1)MnCo4 square pyramids. The corner-sharing octahedral tilt angles range from 5-41°. In the third N site, N(3) is bonded to one Mn(1), one Co(1), one Co(2), and three equivalent Co(3) atoms to form distorted NMnCo5 octahedra that share corners with two equivalent N(3)MnCo5 octahedra,  a cornercorner with one N(1)MnCo4 square pyramid, corners with three equivalent N(2)MnCo4 trigonal bipyramids, edges with two equivalent N(3)MnCo5 octahedra, edges with three equivalent N(1)MnCo4 square pyramids, and edges with two equivalent N(2)MnCo4 trigonal bipyramids. The corner-sharing octahedral tilt angles are 14°. is represented by the CIF card [CIF]
data_Mn(CoN)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.814
_cell_length_b   5.996
_cell_length_c   3.794
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.123
_symmetry_Int_Tables_number   1
_cell_volume   134.054
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.664  0.280  0.750  1.0
  Mn  Mn1  1  0.336  0.720  0.250  1.0
  Co  Co2  1  0.877  0.702  0.250  1.0
  Co  Co3  1  0.829  0.116  0.250  1.0
  Co  Co4  1  0.379  0.295  0.250  1.0
  Co  Co5  1  0.123  0.298  0.750  1.0
  Co  Co6  1  0.171  0.884  0.750  1.0
  Co  Co7  1  0.621  0.705  0.750  1.0
  N  N8  1  0.870  0.611  0.750  1.0
  N  N9  1  0.786  0.072  0.750  1.0
  N  N10  1  0.393  0.266  0.750  1.0
  N  N11  1  0.130  0.389  0.250  1.0
  N  N12  1  0.214  0.928  0.250  1.0
  N  N13  1  0.607  0.734  0.250  1.0
[/CIF]
.