The material described by U2S5 crystallizes in the orthorhombic Pbcn space group. U(1) is bonded in a 10-coordinate geometry to two equivalent S(3), four equivalent S(1), and four equivalent S(2) atoms. There are three inequivalent S sites. In the first S site, S(1) is bonded to four equivalent U(1) atoms to form a mixture of distorted corner and edge-sharing SU4 tetrahedra. In the second S site, S(2) is bonded in a 5-coordinate geometry to four equivalent U(1) and one S(2) atom. In the third S site, S(3) is bonded to four equivalent U(1) atoms to form a mixture of distorted corner and edge-sharing SU4 trigonal pyramids. is represented by the CIF file [CIF]
data_U2S5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.548
_cell_length_b   7.469
_cell_length_c   9.933
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.001
_symmetry_Int_Tables_number   1
_cell_volume   559.961
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  U  U0  1  0.229  0.017  0.853  1.0
  U  U1  1  0.271  0.517  0.647  1.0
  U  U2  1  0.729  0.983  0.647  1.0
  U  U3  1  0.771  0.483  0.853  1.0
  U  U4  1  0.771  0.983  0.147  1.0
  U  U5  1  0.729  0.483  0.353  1.0
  U  U6  1  0.271  0.017  0.353  1.0
  U  U7  1  0.229  0.517  0.147  1.0
  S  S8  1  0.364  0.387  0.393  1.0
  S  S9  1  0.136  0.887  0.107  1.0
  S  S10  1  0.864  0.613  0.107  1.0
  S  S11  1  0.636  0.113  0.393  1.0
  S  S12  1  0.636  0.613  0.607  1.0
  S  S13  1  0.864  0.113  0.893  1.0
  S  S14  1  0.136  0.387  0.893  1.0
  S  S15  1  0.364  0.887  0.607  1.0
  S  S16  1  0.899  0.849  0.400  1.0
  S  S17  1  0.601  0.349  0.100  1.0
  S  S18  1  0.399  0.151  0.100  1.0
  S  S19  1  0.101  0.651  0.400  1.0
  S  S20  1  0.101  0.151  0.600  1.0
  S  S21  1  0.399  0.651  0.900  1.0
  S  S22  1  0.601  0.849  0.900  1.0
  S  S23  1  0.899  0.349  0.600  1.0
  S  S24  1  1.000  0.250  0.249  1.0
  S  S25  1  0.500  0.750  0.251  1.0
  S  S26  1  1.000  0.750  0.751  1.0
  S  S27  1  0.500  0.250  0.749  1.0
[/CIF]
.
The material described by U2S5 crystallizes in the orthorhombic Pbcn space group. U(1) is bonded in a 10-coordinate geometry to two equivalent S(3), four equivalent S(1), and four equivalent S(2) atoms. There are three inequivalent S sites. In the first S site, S(1) is bonded to four equivalent U(1) atoms to form a mixture of distorted corner and edge-sharing SU4 tetrahedra. In the second S site, S(2) is bonded in a 5-coordinate geometry to four equivalent U(1) and one S(2) atom. In the third S site, S(3) is bonded to four equivalent U(1) atoms to form a mixture of distorted corner and edge-sharing SU4 trigonal pyramids. is represented by the CIF file [CIF]
data_U2S5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.548
_cell_length_b   7.469
_cell_length_c   9.933
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.001
_symmetry_Int_Tables_number   1
_cell_volume   559.961
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  U  U0  1  0.229  0.017  0.853  1.0
  U  U1  1  0.271  0.517  0.647  1.0
  U  U2  1  0.729  0.983  0.647  1.0
  U  U3  1  0.771  0.483  0.853  1.0
  U  U4  1  0.771  0.983  0.147  1.0
  U  U5  1  0.729  0.483  0.353  1.0
  U  U6  1  0.271  0.017  0.353  1.0
  U  U7  1  0.229  0.517  0.147  1.0
  S  S8  1  0.364  0.387  0.393  1.0
  S  S9  1  0.136  0.887  0.107  1.0
  S  S10  1  0.864  0.613  0.107  1.0
  S  S11  1  0.636  0.113  0.393  1.0
  S  S12  1  0.636  0.613  0.607  1.0
  S  S13  1  0.864  0.113  0.893  1.0
  S  S14  1  0.136  0.387  0.893  1.0
  S  S15  1  0.364  0.887  0.607  1.0
  S  S16  1  0.899  0.849  0.400  1.0
  S  S17  1  0.601  0.349  0.100  1.0
  S  S18  1  0.399  0.151  0.100  1.0
  S  S19  1  0.101  0.651  0.400  1.0
  S  S20  1  0.101  0.151  0.600  1.0
  S  S21  1  0.399  0.651  0.900  1.0
  S  S22  1  0.601  0.849  0.900  1.0
  S  S23  1  0.899  0.349  0.600  1.0
  S  S24  1  1.000  0.250  0.249  1.0
  S  S25  1  0.500  0.750  0.251  1.0
  S  S26  1  1.000  0.750  0.751  1.0
  S  S27  1  0.500  0.250  0.749  1.0
[/CIF]
.