The material described by BiSbO4 crystallizes in the monoclinic C2/c space group. Bi(1) is bonded in a 4-coordinate geometry to four equivalent O(1) atoms. Sb(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles are 46°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent Bi(1) and one Sb(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to two equivalent Sb(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_BiSbO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.920
_cell_length_b   5.491
_cell_length_c   6.496
_cell_angle_alpha   104.155
_cell_angle_beta   112.253
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   156.649
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.758  0.250  0.500  1.0
  Bi  Bi1  1  0.242  0.750  0.500  1.0
  Sb  Sb2  1  0.000  0.000  0.000  1.0
  Sb  Sb3  1  0.500  0.500  0.000  1.0
  O  O4  1  0.811  0.538  0.308  1.0
  O  O5  1  0.003  0.962  0.692  1.0
  O  O6  1  0.189  0.462  0.692  1.0
  O  O7  1  0.997  0.038  0.308  1.0
  O  O8  1  0.356  0.821  0.126  1.0
  O  O9  1  0.730  0.679  0.874  1.0
  O  O10  1  0.644  0.179  0.874  1.0
  O  O11  1  0.270  0.321  0.126  1.0
[/CIF]
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The material described by BiSbO4 crystallizes in the monoclinic C2/c space group. Bi(1) is bonded in a 4-coordinate geometry to four equivalent O(1) atoms. Sb(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles are 46°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent Bi(1) and one Sb(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to two equivalent Sb(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_BiSbO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.920
_cell_length_b   5.491
_cell_length_c   6.496
_cell_angle_alpha   104.155
_cell_angle_beta   112.253
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   156.649
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.758  0.250  0.500  1.0
  Bi  Bi1  1  0.242  0.750  0.500  1.0
  Sb  Sb2  1  0.000  0.000  0.000  1.0
  Sb  Sb3  1  0.500  0.500  0.000  1.0
  O  O4  1  0.811  0.538  0.308  1.0
  O  O5  1  0.003  0.962  0.692  1.0
  O  O6  1  0.189  0.462  0.692  1.0
  O  O7  1  0.997  0.038  0.308  1.0
  O  O8  1  0.356  0.821  0.126  1.0
  O  O9  1  0.730  0.679  0.874  1.0
  O  O10  1  0.644  0.179  0.874  1.0
  O  O11  1  0.270  0.321  0.126  1.0
[/CIF]
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