The structure described by KZnH4O2Br3 crystallizes in the monoclinic P2_1/c space group. K(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), one Br(3), two equivalent Br(2), and three equivalent Br(1) atoms. Zn(1) is bonded in a tetrahedral geometry to one O(1), one Br(1), one Br(2), and one Br(3) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one K(1), one Zn(1), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one K(1), one H(3), and one H(4) atom. There are three inequivalent Br sites. In the first Br site, Br(3) is bonded in a distorted L-shaped geometry to one K(1) and one Zn(1) atom. In the second Br site, Br(1) is bonded in a 4-coordinate geometry to three equivalent K(1) and one Zn(1) atom. In the third Br site, Br(2) is bonded in a distorted single-bond geometry to two equivalent K(1) and one Zn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_KZnH4Br3O2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.681
_cell_length_b   6.813
_cell_length_c   11.250
_cell_angle_alpha   63.297
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   868.245
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.831  0.279  0.992  1.0
  K  K1  1  0.331  0.721  0.508  1.0
  K  K2  1  0.169  0.721  0.008  1.0
  K  K3  1  0.669  0.279  0.492  1.0
  Zn  Zn4  1  0.928  0.000  0.740  1.0
  Zn  Zn5  1  0.428  1.000  0.760  1.0
  Zn  Zn6  1  0.072  1.000  0.260  1.0
  Zn  Zn7  1  0.572  0.000  0.240  1.0
  H  H8  1  0.262  0.218  0.797  1.0
  H  H9  1  0.762  0.782  0.703  1.0
  H  H10  1  0.738  0.782  0.203  1.0
  H  H11  1  0.238  0.218  0.297  1.0
  H  H12  1  0.329  0.107  0.934  1.0
  H  H13  1  0.829  0.893  0.566  1.0
  H  H14  1  0.671  0.893  0.066  1.0
  H  H15  1  0.171  0.107  0.434  1.0
  H  H16  1  0.138  0.499  0.715  1.0
  H  H17  1  0.638  0.501  0.785  1.0
  H  H18  1  0.862  0.501  0.285  1.0
  H  H19  1  0.362  0.499  0.215  1.0
  H  H20  1  0.138  0.340  0.650  1.0
  H  H21  1  0.638  0.660  0.850  1.0
  H  H22  1  0.862  0.660  0.350  1.0
  H  H23  1  0.362  0.340  0.150  1.0
  Br  Br24  1  0.399  0.226  0.526  1.0
  Br  Br25  1  0.899  0.774  0.974  1.0
  Br  Br26  1  0.601  0.774  0.474  1.0
  Br  Br27  1  0.101  0.226  0.026  1.0
  Br  Br28  1  0.394  0.618  0.830  1.0
  Br  Br29  1  0.894  0.382  0.670  1.0
  Br  Br30  1  0.606  0.382  0.170  1.0
  Br  Br31  1  0.106  0.618  0.330  1.0
  Br  Br32  1  0.100  0.928  0.675  1.0
  Br  Br33  1  0.600  0.072  0.825  1.0
  Br  Br34  1  0.900  0.072  0.325  1.0
  Br  Br35  1  0.400  0.928  0.175  1.0
  O  O36  1  0.806  0.914  0.644  1.0
  O  O37  1  0.306  0.086  0.856  1.0
  O  O38  1  0.194  0.086  0.356  1.0
  O  O39  1  0.694  0.914  0.144  1.0
  O  O40  1  0.685  0.587  0.814  1.0
  O  O41  1  0.185  0.413  0.686  1.0
  O  O42  1  0.315  0.413  0.186  1.0
  O  O43  1  0.815  0.587  0.314  1.0
[/CIF]
.
The structure described by KZnH4O2Br3 crystallizes in the monoclinic P2_1/c space group. K(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), one Br(3), two equivalent Br(2), and three equivalent Br(1) atoms. Zn(1) is bonded in a tetrahedral geometry to one O(1), one Br(1), one Br(2), and one Br(3) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one K(1), one Zn(1), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one K(1), one H(3), and one H(4) atom. There are three inequivalent Br sites. In the first Br site, Br(3) is bonded in a distorted L-shaped geometry to one K(1) and one Zn(1) atom. In the second Br site, Br(1) is bonded in a 4-coordinate geometry to three equivalent K(1) and one Zn(1) atom. In the third Br site, Br(2) is bonded in a distorted single-bond geometry to two equivalent K(1) and one Zn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_KZnH4Br3O2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.681
_cell_length_b   6.813
_cell_length_c   11.250
_cell_angle_alpha   63.297
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   868.245
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.831  0.279  0.992  1.0
  K  K1  1  0.331  0.721  0.508  1.0
  K  K2  1  0.169  0.721  0.008  1.0
  K  K3  1  0.669  0.279  0.492  1.0
  Zn  Zn4  1  0.928  0.000  0.740  1.0
  Zn  Zn5  1  0.428  1.000  0.760  1.0
  Zn  Zn6  1  0.072  1.000  0.260  1.0
  Zn  Zn7  1  0.572  0.000  0.240  1.0
  H  H8  1  0.262  0.218  0.797  1.0
  H  H9  1  0.762  0.782  0.703  1.0
  H  H10  1  0.738  0.782  0.203  1.0
  H  H11  1  0.238  0.218  0.297  1.0
  H  H12  1  0.329  0.107  0.934  1.0
  H  H13  1  0.829  0.893  0.566  1.0
  H  H14  1  0.671  0.893  0.066  1.0
  H  H15  1  0.171  0.107  0.434  1.0
  H  H16  1  0.138  0.499  0.715  1.0
  H  H17  1  0.638  0.501  0.785  1.0
  H  H18  1  0.862  0.501  0.285  1.0
  H  H19  1  0.362  0.499  0.215  1.0
  H  H20  1  0.138  0.340  0.650  1.0
  H  H21  1  0.638  0.660  0.850  1.0
  H  H22  1  0.862  0.660  0.350  1.0
  H  H23  1  0.362  0.340  0.150  1.0
  Br  Br24  1  0.399  0.226  0.526  1.0
  Br  Br25  1  0.899  0.774  0.974  1.0
  Br  Br26  1  0.601  0.774  0.474  1.0
  Br  Br27  1  0.101  0.226  0.026  1.0
  Br  Br28  1  0.394  0.618  0.830  1.0
  Br  Br29  1  0.894  0.382  0.670  1.0
  Br  Br30  1  0.606  0.382  0.170  1.0
  Br  Br31  1  0.106  0.618  0.330  1.0
  Br  Br32  1  0.100  0.928  0.675  1.0
  Br  Br33  1  0.600  0.072  0.825  1.0
  Br  Br34  1  0.900  0.072  0.325  1.0
  Br  Br35  1  0.400  0.928  0.175  1.0
  O  O36  1  0.806  0.914  0.644  1.0
  O  O37  1  0.306  0.086  0.856  1.0
  O  O38  1  0.194  0.086  0.356  1.0
  O  O39  1  0.694  0.914  0.144  1.0
  O  O40  1  0.685  0.587  0.814  1.0
  O  O41  1  0.185  0.413  0.686  1.0
  O  O42  1  0.315  0.413  0.186  1.0
  O  O43  1  0.815  0.587  0.314  1.0
[/CIF]
.