The material described by YV(TeO4)2 crystallizes in the orthorhombic Cmce space group. Y(1) is bonded in a 8-coordinate geometry to two equivalent O(2), two equivalent O(3), and four equivalent O(1) atoms. V(1) is bonded in a 6-coordinate geometry to two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a 3-coordinate geometry to one O(2) and two equivalent O(1) atoms. In the second Te site, Te(2) is bonded in a distorted T-shaped geometry to one O(3) and two equivalent O(4) atoms. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent Y(1) and one Te(1) atom. In the second O site, O(2) is bonded in a trigonal non-coplanar geometry to two equivalent Y(1) and one Te(1) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to two equivalent Y(1) and one Te(2) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one V(1) and one Te(2) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to two equivalent V(1) atoms. is represented by the CIF card [CIF]
data_YV(TeO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.522
_cell_length_b   5.522
_cell_length_c   21.626
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   95.909
_symmetry_Int_Tables_number   1
_cell_volume   655.940
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  1  0.751  0.751  0.000  1.0
  Y  Y1  1  0.249  0.249  0.000  1.0
  Y  Y2  1  0.749  0.749  0.500  1.0
  Y  Y3  1  0.251  0.251  0.500  1.0
  V  V4  1  0.755  0.745  0.750  1.0
  V  V5  1  0.255  0.245  0.750  1.0
  V  V6  1  0.245  0.255  0.250  1.0
  V  V7  1  0.745  0.755  0.250  1.0
  Te  Te8  1  0.311  0.689  0.889  1.0
  Te  Te9  1  0.689  0.311  0.111  1.0
  Te  Te10  1  0.822  0.178  0.866  1.0
  Te  Te11  1  0.178  0.822  0.134  1.0
  Te  Te12  1  0.322  0.678  0.634  1.0
  Te  Te13  1  0.678  0.322  0.366  1.0
  Te  Te14  1  0.811  0.189  0.611  1.0
  Te  Te15  1  0.189  0.811  0.389  1.0
  O  O16  1  0.047  0.560  0.940  1.0
  O  O17  1  0.440  0.953  0.940  1.0
  O  O18  1  0.953  0.440  0.060  1.0
  O  O19  1  0.560  0.047  0.060  1.0
  O  O20  1  0.516  0.484  0.932  1.0
  O  O21  1  0.484  0.516  0.068  1.0
  O  O22  1  0.935  0.065  0.942  1.0
  O  O23  1  0.065  0.935  0.058  1.0
  O  O24  1  0.759  0.844  0.836  1.0
  O  O25  1  0.156  0.241  0.836  1.0
  O  O26  1  0.241  0.156  0.164  1.0
  O  O27  1  0.844  0.759  0.164  1.0
  O  O28  1  0.435  0.565  0.558  1.0
  O  O29  1  0.565  0.435  0.442  1.0
  O  O30  1  0.656  0.741  0.664  1.0
  O  O31  1  0.259  0.344  0.664  1.0
  O  O32  1  0.344  0.259  0.336  1.0
  O  O33  1  0.741  0.656  0.336  1.0
  O  O34  1  0.547  0.060  0.560  1.0
  O  O35  1  0.940  0.453  0.560  1.0
  O  O36  1  0.453  0.940  0.440  1.0
  O  O37  1  0.060  0.547  0.440  1.0
  O  O38  1  0.016  0.984  0.568  1.0
  O  O39  1  0.984  0.016  0.432  1.0
  O  O40  1  0.471  0.529  0.766  1.0
  O  O41  1  0.529  0.471  0.234  1.0
  O  O42  1  0.457  0.043  0.750  1.0
  O  O43  1  0.957  0.543  0.750  1.0
  O  O44  1  0.543  0.957  0.250  1.0
  O  O45  1  0.043  0.457  0.250  1.0
  O  O46  1  0.971  0.029  0.734  1.0
  O  O47  1  0.029  0.971  0.266  1.0
[/CIF]
.
The material described by YV(TeO4)2 crystallizes in the orthorhombic Cmce space group. Y(1) is bonded in a 8-coordinate geometry to two equivalent O(2), two equivalent O(3), and four equivalent O(1) atoms. V(1) is bonded in a 6-coordinate geometry to two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a 3-coordinate geometry to one O(2) and two equivalent O(1) atoms. In the second Te site, Te(2) is bonded in a distorted T-shaped geometry to one O(3) and two equivalent O(4) atoms. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent Y(1) and one Te(1) atom. In the second O site, O(2) is bonded in a trigonal non-coplanar geometry to two equivalent Y(1) and one Te(1) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to two equivalent Y(1) and one Te(2) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one V(1) and one Te(2) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to two equivalent V(1) atoms. is represented by the CIF card [CIF]
data_YV(TeO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.522
_cell_length_b   5.522
_cell_length_c   21.626
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   95.909
_symmetry_Int_Tables_number   1
_cell_volume   655.940
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  1  0.751  0.751  0.000  1.0
  Y  Y1  1  0.249  0.249  0.000  1.0
  Y  Y2  1  0.749  0.749  0.500  1.0
  Y  Y3  1  0.251  0.251  0.500  1.0
  V  V4  1  0.755  0.745  0.750  1.0
  V  V5  1  0.255  0.245  0.750  1.0
  V  V6  1  0.245  0.255  0.250  1.0
  V  V7  1  0.745  0.755  0.250  1.0
  Te  Te8  1  0.311  0.689  0.889  1.0
  Te  Te9  1  0.689  0.311  0.111  1.0
  Te  Te10  1  0.822  0.178  0.866  1.0
  Te  Te11  1  0.178  0.822  0.134  1.0
  Te  Te12  1  0.322  0.678  0.634  1.0
  Te  Te13  1  0.678  0.322  0.366  1.0
  Te  Te14  1  0.811  0.189  0.611  1.0
  Te  Te15  1  0.189  0.811  0.389  1.0
  O  O16  1  0.047  0.560  0.940  1.0
  O  O17  1  0.440  0.953  0.940  1.0
  O  O18  1  0.953  0.440  0.060  1.0
  O  O19  1  0.560  0.047  0.060  1.0
  O  O20  1  0.516  0.484  0.932  1.0
  O  O21  1  0.484  0.516  0.068  1.0
  O  O22  1  0.935  0.065  0.942  1.0
  O  O23  1  0.065  0.935  0.058  1.0
  O  O24  1  0.759  0.844  0.836  1.0
  O  O25  1  0.156  0.241  0.836  1.0
  O  O26  1  0.241  0.156  0.164  1.0
  O  O27  1  0.844  0.759  0.164  1.0
  O  O28  1  0.435  0.565  0.558  1.0
  O  O29  1  0.565  0.435  0.442  1.0
  O  O30  1  0.656  0.741  0.664  1.0
  O  O31  1  0.259  0.344  0.664  1.0
  O  O32  1  0.344  0.259  0.336  1.0
  O  O33  1  0.741  0.656  0.336  1.0
  O  O34  1  0.547  0.060  0.560  1.0
  O  O35  1  0.940  0.453  0.560  1.0
  O  O36  1  0.453  0.940  0.440  1.0
  O  O37  1  0.060  0.547  0.440  1.0
  O  O38  1  0.016  0.984  0.568  1.0
  O  O39  1  0.984  0.016  0.432  1.0
  O  O40  1  0.471  0.529  0.766  1.0
  O  O41  1  0.529  0.471  0.234  1.0
  O  O42  1  0.457  0.043  0.750  1.0
  O  O43  1  0.957  0.543  0.750  1.0
  O  O44  1  0.543  0.957  0.250  1.0
  O  O45  1  0.043  0.457  0.250  1.0
  O  O46  1  0.971  0.029  0.734  1.0
  O  O47  1  0.029  0.971  0.266  1.0
[/CIF]
.