The crystal structure described by CdS2(NO7)2 is Hg_xSn structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two CdS2(NO7)2 clusters. Cd(1) is bonded in a linear geometry to two equivalent O(7) atoms. N(1) is bonded in a bent 120 degrees geometry to one O(5) and one O(6) atom. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are seven inequivalent O sites. In the first O site, O(7) is bonded in a water-like geometry to one Cd(1) and one O(3) atom. In the second O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the fourth O site, O(3) is bonded in a distorted single-bond geometry to one S(1) and one O(7) atom. In the fifth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one S(1) and one O(5) atom. In the sixth O site, O(5) is bonded in a 2-coordinate geometry to one N(1) and one O(4) atom. In the seventh O site, O(6) is bonded in a single-bond geometry to one N(1) atom. is represented by the CIF card [CIF]
data_CdS2(NO7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.903
_cell_length_b   8.102
_cell_length_c   13.535
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   88.586
_symmetry_Int_Tables_number   1
_cell_volume   647.110
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.000  0.500  0.500  1.0
  Cd  Cd1  1  0.000  0.000  0.000  1.0
  S  S2  1  0.756  0.885  0.368  1.0
  S  S3  1  0.244  0.615  0.868  1.0
  S  S4  1  0.244  0.115  0.632  1.0
  S  S5  1  0.756  0.385  0.132  1.0
  N  N6  1  0.216  0.679  0.232  1.0
  N  N7  1  0.784  0.821  0.732  1.0
  N  N8  1  0.784  0.321  0.768  1.0
  N  N9  1  0.216  0.179  0.268  1.0
  O  O10  1  0.657  0.826  0.279  1.0
  O  O11  1  0.343  0.674  0.779  1.0
  O  O12  1  0.343  0.174  0.721  1.0
  O  O13  1  0.657  0.326  0.221  1.0
  O  O14  1  0.724  0.049  0.406  1.0
  O  O15  1  0.276  0.451  0.906  1.0
  O  O16  1  0.276  0.951  0.594  1.0
  O  O17  1  0.724  0.549  0.094  1.0
  O  O18  1  0.707  0.767  0.461  1.0
  O  O19  1  0.293  0.733  0.961  1.0
  O  O20  1  0.293  0.233  0.539  1.0
  O  O21  1  0.707  0.267  0.039  1.0
  O  O22  1  0.041  0.876  0.359  1.0
  O  O23  1  0.959  0.624  0.859  1.0
  O  O24  1  0.959  0.124  0.641  1.0
  O  O25  1  0.041  0.376  0.141  1.0
  O  O26  1  0.131  0.711  0.343  1.0
  O  O27  1  0.869  0.789  0.843  1.0
  O  O28  1  0.869  0.289  0.657  1.0
  O  O29  1  0.131  0.211  0.157  1.0
  O  O30  1  0.177  0.288  0.321  1.0
  O  O31  1  0.823  0.212  0.821  1.0
  O  O32  1  0.823  0.712  0.679  1.0
  O  O33  1  0.177  0.788  0.179  1.0
  O  O34  1  0.292  0.410  0.568  1.0
  O  O35  1  0.708  0.090  0.068  1.0
  O  O36  1  0.708  0.590  0.432  1.0
  O  O37  1  0.292  0.910  0.932  1.0
[/CIF]
.
The crystal structure described by CdS2(NO7)2 is Hg_xSn structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two CdS2(NO7)2 clusters. Cd(1) is bonded in a linear geometry to two equivalent O(7) atoms. N(1) is bonded in a bent 120 degrees geometry to one O(5) and one O(6) atom. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are seven inequivalent O sites. In the first O site, O(7) is bonded in a water-like geometry to one Cd(1) and one O(3) atom. In the second O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the fourth O site, O(3) is bonded in a distorted single-bond geometry to one S(1) and one O(7) atom. In the fifth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one S(1) and one O(5) atom. In the sixth O site, O(5) is bonded in a 2-coordinate geometry to one N(1) and one O(4) atom. In the seventh O site, O(6) is bonded in a single-bond geometry to one N(1) atom. is represented by the CIF card [CIF]
data_CdS2(NO7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.903
_cell_length_b   8.102
_cell_length_c   13.535
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   88.586
_symmetry_Int_Tables_number   1
_cell_volume   647.110
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.000  0.500  0.500  1.0
  Cd  Cd1  1  0.000  0.000  0.000  1.0
  S  S2  1  0.756  0.885  0.368  1.0
  S  S3  1  0.244  0.615  0.868  1.0
  S  S4  1  0.244  0.115  0.632  1.0
  S  S5  1  0.756  0.385  0.132  1.0
  N  N6  1  0.216  0.679  0.232  1.0
  N  N7  1  0.784  0.821  0.732  1.0
  N  N8  1  0.784  0.321  0.768  1.0
  N  N9  1  0.216  0.179  0.268  1.0
  O  O10  1  0.657  0.826  0.279  1.0
  O  O11  1  0.343  0.674  0.779  1.0
  O  O12  1  0.343  0.174  0.721  1.0
  O  O13  1  0.657  0.326  0.221  1.0
  O  O14  1  0.724  0.049  0.406  1.0
  O  O15  1  0.276  0.451  0.906  1.0
  O  O16  1  0.276  0.951  0.594  1.0
  O  O17  1  0.724  0.549  0.094  1.0
  O  O18  1  0.707  0.767  0.461  1.0
  O  O19  1  0.293  0.733  0.961  1.0
  O  O20  1  0.293  0.233  0.539  1.0
  O  O21  1  0.707  0.267  0.039  1.0
  O  O22  1  0.041  0.876  0.359  1.0
  O  O23  1  0.959  0.624  0.859  1.0
  O  O24  1  0.959  0.124  0.641  1.0
  O  O25  1  0.041  0.376  0.141  1.0
  O  O26  1  0.131  0.711  0.343  1.0
  O  O27  1  0.869  0.789  0.843  1.0
  O  O28  1  0.869  0.289  0.657  1.0
  O  O29  1  0.131  0.211  0.157  1.0
  O  O30  1  0.177  0.288  0.321  1.0
  O  O31  1  0.823  0.212  0.821  1.0
  O  O32  1  0.823  0.712  0.679  1.0
  O  O33  1  0.177  0.788  0.179  1.0
  O  O34  1  0.292  0.410  0.568  1.0
  O  O35  1  0.708  0.090  0.068  1.0
  O  O36  1  0.708  0.590  0.432  1.0
  O  O37  1  0.292  0.910  0.932  1.0
[/CIF]
.