The structure described by RhSbAs crystallizes in the monoclinic P2_1/c space group. Rh(1) is bonded to three equivalent Sb(1) and three equivalent As(1) atoms to form distorted RhSb3As3 octahedra that share corners with eight equivalent Rh(1)Sb3As3 octahedra, corners with three equivalent Sb(1)AsRh3 tetrahedra, corners with three equivalent As(1)SbRh3 tetrahedra, and edges with two equivalent Rh(1)Sb3As3 octahedra. The corner-sharing octahedral tilt angles range from 51-60°. Sb(1) is bonded to three equivalent Rh(1) and one As(1) atom to form SbAsRh3 tetrahedra that share corners with three equivalent Rh(1)Sb3As3 octahedra, corners with four equivalent Sb(1)AsRh3 tetrahedra, corners with nine equivalent As(1)SbRh3 tetrahedra, and  an edgeedge with one Sb(1)AsRh3 tetrahedra. The corner-sharing octahedral tilt angles range from 70-74°. As(1) is bonded to three equivalent Rh(1) and one Sb(1) atom to form distorted AsSbRh3 tetrahedra that share corners with three equivalent Rh(1)Sb3As3 octahedra, corners with four equivalent As(1)SbRh3 tetrahedra, corners with nine equivalent Sb(1)AsRh3 tetrahedra, and  an edgeedge with one As(1)SbRh3 tetrahedra. The corner-sharing octahedral tilt angles are 75°. is represented by the Crystallographic Information File (CIF) [CIF]
data_SbAsRh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.351
_cell_length_b   6.384
_cell_length_c   6.433
_cell_angle_alpha   114.765
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   236.846
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.129  0.845  0.134  1.0
  Sb  Sb1  1  0.629  0.155  0.366  1.0
  Sb  Sb2  1  0.871  0.155  0.866  1.0
  Sb  Sb3  1  0.371  0.845  0.634  1.0
  As  As4  1  0.863  0.652  0.325  1.0
  As  As5  1  0.363  0.348  0.175  1.0
  As  As6  1  0.137  0.348  0.675  1.0
  As  As7  1  0.637  0.652  0.825  1.0
  Rh  Rh8  1  0.508  0.715  0.206  1.0
  Rh  Rh9  1  0.008  0.285  0.294  1.0
  Rh  Rh10  1  0.492  0.285  0.794  1.0
  Rh  Rh11  1  0.992  0.715  0.706  1.0
[/CIF]
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The structure described by RhSbAs crystallizes in the monoclinic P2_1/c space group. Rh(1) is bonded to three equivalent Sb(1) and three equivalent As(1) atoms to form distorted RhSb3As3 octahedra that share corners with eight equivalent Rh(1)Sb3As3 octahedra, corners with three equivalent Sb(1)AsRh3 tetrahedra, corners with three equivalent As(1)SbRh3 tetrahedra, and edges with two equivalent Rh(1)Sb3As3 octahedra. The corner-sharing octahedral tilt angles range from 51-60°. Sb(1) is bonded to three equivalent Rh(1) and one As(1) atom to form SbAsRh3 tetrahedra that share corners with three equivalent Rh(1)Sb3As3 octahedra, corners with four equivalent Sb(1)AsRh3 tetrahedra, corners with nine equivalent As(1)SbRh3 tetrahedra, and  an edgeedge with one Sb(1)AsRh3 tetrahedra. The corner-sharing octahedral tilt angles range from 70-74°. As(1) is bonded to three equivalent Rh(1) and one Sb(1) atom to form distorted AsSbRh3 tetrahedra that share corners with three equivalent Rh(1)Sb3As3 octahedra, corners with four equivalent As(1)SbRh3 tetrahedra, corners with nine equivalent Sb(1)AsRh3 tetrahedra, and  an edgeedge with one As(1)SbRh3 tetrahedra. The corner-sharing octahedral tilt angles are 75°. is represented by the Crystallographic Information File (CIF) [CIF]
data_SbAsRh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.351
_cell_length_b   6.384
_cell_length_c   6.433
_cell_angle_alpha   114.765
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   236.846
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.129  0.845  0.134  1.0
  Sb  Sb1  1  0.629  0.155  0.366  1.0
  Sb  Sb2  1  0.871  0.155  0.866  1.0
  Sb  Sb3  1  0.371  0.845  0.634  1.0
  As  As4  1  0.863  0.652  0.325  1.0
  As  As5  1  0.363  0.348  0.175  1.0
  As  As6  1  0.137  0.348  0.675  1.0
  As  As7  1  0.637  0.652  0.825  1.0
  Rh  Rh8  1  0.508  0.715  0.206  1.0
  Rh  Rh9  1  0.008  0.285  0.294  1.0
  Rh  Rh10  1  0.492  0.285  0.794  1.0
  Rh  Rh11  1  0.992  0.715  0.706  1.0
[/CIF]
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