The structure described by Li3Mn3TeO8 crystallizes in the triclinic P1 space group. There are six inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(14), one O(15), one O(3), one O(8), and one O(9) atom to form distorted LiO5 square pyramids that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, corners with three equivalent Mn(2)O6 octahedra, corners with two equivalent Li(6)O5 square pyramids,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Te(1)O6 octahedra, and  an edgeedge with one Te(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 11-89°. In the second Li site, Li(2) is bonded to one O(10), one O(13), one O(16), one O(2), and one O(7) atom to form LiO5 square pyramids that share  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, corners with three equivalent Mn(2)O6 octahedra, corners with two equivalent Li(5)O5 square pyramids,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Te(1)O6 octahedra, and  an edgeedge with one Te(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 11-89°. In the third Li site, Li(3) is bonded to one O(1), one O(12), one O(15), one O(3), one O(6), and one O(9) atom to form LiO6 octahedra that share corners with three equivalent Mn(4)O6 octahedra, corners with three equivalent Mn(5)O6 octahedra,  a cornercorner with one Li(1)O5 square pyramid,  a cornercorner with one Li(6)O5 square pyramid,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra,  an edgeedge with one Li(1)O5 square pyramid, and  an edgeedge with one Li(6)O5 square pyramid. The corner-sharing octahedral tilt angles range from 13-16°. In the fourth Li site, Li(4) is bonded to one O(10), one O(11), one O(16), one O(2), one O(4), and one O(5) atom to form LiO6 octahedra that share corners with three equivalent Mn(4)O6 octahedra, corners with three equivalent Mn(5)O6 octahedra,  a cornercorner with one Li(2)O5 square pyramid,  a cornercorner with one Li(5)O5 square pyramid,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra,  an edgeedge with one Li(2)O5 square pyramid, and  an edgeedge with one Li(5)O5 square pyramid. The corner-sharing octahedral tilt angles range from 13-16°. In the fifth Li site, Li(5) is bonded to one O(11), one O(13), one O(4), one O(5), and one O(7) atom to form distorted LiO5 square pyramids that share  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra, corners with two equivalent Mn(6)O6 octahedra, corners with three equivalent Mn(3)O6 octahedra, corners with two equivalent Li(2)O5 square pyramids,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Te(1)O6 octahedra, and  an edgeedge with one Te(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 11-90°. In the sixth Li site, Li(6) is bonded to one O(1), one O(12), one O(14), one O(6), and one O(8) atom to form distorted LiO5 square pyramids that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra, corners with two equivalent Mn(6)O6 octahedra, corners with three equivalent Mn(3)O6 octahedra, corners with two equivalent Li(1)O5 square pyramids,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Te(1)O6 octahedra, and  an edgeedge with one Te(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 11-90°. There are six inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(13), one O(16), one O(4), one O(8), and one O(9) atom to form MnO6 octahedra that share corners with two equivalent Li(1)O5 square pyramids, corners with two equivalent Li(2)O5 square pyramids,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra, edges with two equivalent Te(2)O6 octahedra,  an edgeedge with one Li(5)O5 square pyramid, and  an edgeedge with one Li(6)O5 square pyramid. In the second Mn site, Mn(2) is bonded to one O(10), one O(14), one O(15), one O(2), one O(3), and one O(7) atom to form MnO6 octahedra that share  a cornercorner with one Li(5)O5 square pyramid,  a cornercorner with one Li(6)O5 square pyramid, corners with three equivalent Li(1)O5 square pyramids, corners with three equivalent Li(2)O5 square pyramids,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra, edges with two equivalent Mn(4)O6 octahedra, edges with two equivalent Mn(6)O6 octahedra, and edges with two equivalent Te(1)O6 octahedra. In the third Mn site, Mn(3) is bonded to one O(1), one O(11), one O(13), one O(4), one O(6), and one O(8) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O5 square pyramid,  a cornercorner with one Li(2)O5 square pyramid, corners with three equivalent Li(5)O5 square pyramids, corners with three equivalent Li(6)O5 square pyramids,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra, and edges with two equivalent Te(2)O6 octahedra. In the fourth Mn site, Mn(4) is bonded to one O(10), one O(12), one O(15), one O(2), one O(3), and one O(5) atom to form MnO6 octahedra that share corners with three equivalent Li(3)O6 octahedra, corners with three equivalent Li(4)O6 octahedra,  a cornercorner with one Li(5)O5 square pyramid,  a cornercorner with one Li(6)O5 square pyramid, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Mn(6)O6 octahedra, edges with two equivalent Te(1)O6 octahedra,  an edgeedge with one Li(1)O5 square pyramid, and  an edgeedge with one Li(2)O5 square pyramid. The corner-sharing octahedral tilt angles range from 14-16°. In the fifth Mn site, Mn(5) is bonded to one O(1), one O(11), one O(16), one O(4), one O(6), and one O(9) atom to form MnO6 octahedra that share corners with three equivalent Li(3)O6 octahedra, corners with three equivalent Li(4)O6 octahedra,  a cornercorner with one Li(1)O5 square pyramid,  a cornercorner with one Li(2)O5 square pyramid, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, edges with two equivalent Te(2)O6 octahedra,  an edgeedge with one Li(5)O5 square pyramid, and  an edgeedge with one Li(6)O5 square pyramid. The corner-sharing octahedral tilt angles range from 13-16°. In the sixth Mn site, Mn(6) is bonded to one O(12), one O(14), one O(2), one O(3), one O(5), and one O(7) atom to form MnO6 octahedra that share corners with two equivalent Li(5)O5 square pyramids, corners with two equivalent Li(6)O5 square pyramids,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Mn(4)O6 octahedra, edges with two equivalent Te(1)O6 octahedra,  an edgeedge with one Li(1)O5 square pyramid, and  an edgeedge with one Li(2)O5 square pyramid. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(10), one O(12), one O(14), one O(15), one O(5), and one O(7) atom to form TeO6 octahedra that share  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Mn(4)O6 octahedra, edges with two equivalent Mn(6)O6 octahedra,  an edgeedge with one Li(1)O5 square pyramid,  an edgeedge with one Li(2)O5 square pyramid,  an edgeedge with one Li(5)O5 square pyramid, and  an edgeedge with one Li(6)O5 square pyramid. In the second Te site, Te(2) is bonded to one O(11), one O(13), one O(16), one O(6), one O(8), and one O(9) atom to form TeO6 octahedra that share  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra,  an edgeedge with one Li(1)O5 square pyramid,  an edgeedge with one Li(2)O5 square pyramid,  an edgeedge with one Li(5)O5 square pyramid, and  an edgeedge with one Li(6)O5 square pyramid. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded to one Li(3), one Li(6), one Mn(1), one Mn(3), and one Mn(5) atom to form distorted OLi2Mn3 square pyramids that share  a cornercorner with one O(14)Li2Mn2Te square pyramid,  a cornercorner with one O(15)Li2Mn2Te square pyramid,  a cornercorner with one O(8)Li2Mn2Te square pyramid,  a cornercorner with one O(9)Li2Mn2Te square pyramid,  a cornercorner with one O(3)Li2Mn3 square pyramid, corners with three equivalent O(4)Li2Mn3 square pyramids,  an edgeedge with one O(11)Li2Mn2Te square pyramid,  an edgeedge with one O(12)Li2Mn2Te square pyramid,  an edgeedge with one O(13)Li2Mn2Te square pyramid,  an edgeedge with one O(16)Li2Mn2Te square pyramid,  an edgeedge with one O(8)Li2Mn2Te square pyramid,  an edgeedge with one O(9)Li2Mn2Te square pyramid, and edges with two equivalent O(6)Li2Mn2Te square pyramids. In the second O site, O(2) is bonded to one Li(2), one Li(4), one Mn(2), one Mn(4), and one Mn(6) atom to form distorted OLi2Mn3 square pyramids that share  a cornercorner with one O(11)Li2Mn2Te square pyramid,  a cornercorner with one O(13)Li2Mn2Te square pyramid,  a cornercorner with one O(5)Li2Mn2Te square pyramid,  a cornercorner with one O(7)Li2Mn2Te square pyramid,  a cornercorner with one O(4)Li2Mn3 square pyramid, corners with three equivalent O(3)Li2Mn3 square pyramids,  an edgeedge with one O(12)Li2Mn2Te square pyramid,  an edgeedge with one O(14)Li2Mn2Te square pyramid,  an edgeedge with one O(15)Li2Mn2Te square pyramid,  an edgeedge with one O(16)Li2Mn2Te square pyramid,  an edgeedge with one O(5)Li2Mn2Te square pyramid,  an edgeedge with one O(7)Li2Mn2Te square pyramid, and edges with two equivalent O(10)Li2Mn2Te square pyramids. In the third O site, O(3) is bonded to one Li(1), one Li(3), one Mn(2), one Mn(4), and one Mn(6) atom to form distorted OLi2Mn3 square pyramids that share  a cornercorner with one O(12)Li2Mn2Te square pyramid,  a cornercorner with one O(14)Li2Mn2Te square pyramid,  a cornercorner with one O(6)Li2Mn2Te square pyramid,  a cornercorner with one O(8)Li2Mn2Te square pyramid,  a cornercorner with one O(1)Li2Mn3 square pyramid, corners with three equivalent O(2)Li2Mn3 square pyramids,  an edgeedge with one O(10)Li2Mn2Te square pyramid,  an edgeedge with one O(12)Li2Mn2Te square pyramid,  an edgeedge with one O(14)Li2Mn2Te square pyramid,  an edgeedge with one O(5)Li2Mn2Te square pyramid,  an edgeedge with one O(7)Li2Mn2Te square pyramid,  an edgeedge with one O(9)Li2Mn2Te square pyramid, and edges with two equivalent O(15)Li2Mn2Te square pyramids. In the fourth O site, O(4) is bonded to one Li(4), one Li(5), one Mn(1), one Mn(3), and one Mn(5) atom to form distorted OLi2Mn3 square pyramids that share  a cornercorner with one O(10)Li2Mn2Te square pyramid,  a cornercorner with one O(13)Li2Mn2Te square pyramid,  a cornercorner with one O(16)Li2Mn2Te square pyramid,  a cornercorner with one O(7)Li2Mn2Te square pyramid,  a cornercorner with one O(2)Li2Mn3 square pyramid, corners with three equivalent O(1)Li2Mn3 square pyramids,  an edgeedge with one O(13)Li2Mn2Te square pyramid,  an edgeedge with one O(16)Li2Mn2Te square pyramid,  an edgeedge with one O(5)Li2Mn2Te square pyramid,  an edgeedge with one O(6)Li2Mn2Te square pyramid,  an edgeedge with one O(8)Li2Mn2Te square pyramid,  an edgeedge with one O(9)Li2Mn2Te square pyramid, and edges with two equivalent O(11)Li2Mn2Te square pyramids. In the fifth O site, O(5) is bonded to one Li(4), one Li(5), one Mn(4), one Mn(6), and one Te(1) atom to form OLi2Mn2Te square pyramids that share  a cornercorner with one O(10)Li2Mn2Te square pyramid,  a cornercorner with one O(13)Li2Mn2Te square pyramid,  a cornercorner with one O(16)Li2Mn2Te square pyramid,  a cornercorner with one O(7)Li2Mn2Te square pyramid,  a cornercorner with one O(2)Li2Mn3 square pyramid, corners with two equivalent O(11)Li2Mn2Te square pyramids, corners with three equivalent O(12)Li2Mn2Te square pyramids,  an edgeedge with one O(10)Li2Mn2Te square pyramid,  an edgeedge with one O(14)Li2Mn2Te square pyramid,  an edgeedge with one O(15)Li2Mn2Te square pyramid,  an edgeedge with one O(7)Li2Mn2Te square pyramid,  an edgeedge with one O(2)Li2Mn3 square pyramid,  an edgeedge with one O(3)Li2Mn3 square pyramid, and  an edgeedge with one O(4)Li2Mn3 square pyramid. In the sixth O site, O(6) is bonded to one Li(3), one Li(6), one Mn(3), one Mn(5), and one Te(2) atom to form OLi2Mn2Te square pyramids that share  a cornercorner with one O(14)Li2Mn2Te square pyramid,  a cornercorner with one O(15)Li2Mn2Te square pyramid,  a cornercorner with one O(8)Li2Mn2Te square pyramid,  a cornercorner with one O(9)Li2Mn2Te square pyramid,  a cornercorner with one O(3)Li2Mn3 square pyramid, corners with two equivalent O(12)Li2Mn2Te square pyramids, corners with three equivalent O(11)Li2Mn2Te square pyramids,  an edgeedge with one O(13)Li2Mn2Te square pyramid,  an edgeedge with one O(16)Li2Mn2Te square pyramid,  an edgeedge with one O(8)Li2Mn2Te square pyramid,  an edgeedge with one O(9)Li2Mn2Te square pyramid,  an edgeedge with one O(4)Li2Mn3 square pyramid, and edges with two equivalent O(1)Li2Mn3 square pyramids. In the seventh O site, O(7) is bonded to one Li(2), one Li(5), one Mn(2), one Mn(6), and one Te(1) atom to form OLi2Mn2Te square pyramids that share  a cornercorner with one O(10)Li2Mn2Te square pyramid,  a cornercorner with one O(11)Li2Mn2Te square pyramid,  a cornercorner with one O(16)Li2Mn2Te square pyramid,  a cornercorner with one O(5)Li2Mn2Te square pyramid,  a cornercorner with one O(2)Li2Mn3 square pyramid,  a cornercorner with one O(4)Li2Mn3 square pyramid, corners with two equivalent O(13)Li2Mn2Te square pyramids, corners with three equivalent O(14)Li2Mn2Te square pyramids,  an edgeedge with one O(10)Li2Mn2Te square pyramid,  an edgeedge with one O(12)Li2Mn2Te square pyramid,  an edgeedge with one O(15)Li2Mn2Te square pyramid,  an edgeedge with one O(5)Li2Mn2Te square pyramid,  an edgeedge with one O(2)Li2Mn3 square pyramid, and  an edgeedge with one O(3)Li2Mn3 square pyramid. In the eighth O site, O(8) is bonded to one Li(1), one Li(6), one Mn(1), one Mn(3), and one Te(2) atom to form OLi2Mn2Te square pyramids that share  a cornercorner with one O(12)Li2Mn2Te square pyramid,  a cornercorner with one O(15)Li2Mn2Te square pyramid,  a cornercorner with one O(6)Li2Mn2Te square pyramid,  a cornercorner with one O(9)Li2Mn2Te square pyramid,  a cornercorner with one O(1)Li2Mn3 square pyramid,  a cornercorner with one O(3)Li2Mn3 square pyramid, corners with two equivalent O(14)Li2Mn2Te square pyramids, corners with three equivalent O(13)Li2Mn2Te square pyramids,  an edgeedge with one O(11)Li2Mn2Te square pyramid,  an edgeedge with one O(16)Li2Mn2Te square pyramid,  an edgeedge with one O(6)Li2Mn2Te square pyramid,  an edgeedge with one O(9)Li2Mn2Te square pyramid,  an edgeedge with one O(1)Li2Mn3 square pyramid, and  an edgeedge with one O(4)Li2Mn3 square pyramid. In the ninth O site, O(9) is bonded to one Li(1), one Li(3), one Mn(1), one Mn(5), and one Te(2) atom to form OLi2Mn2Te square pyramids that share  a cornercorner with one O(12)Li2Mn2Te square pyramid,  a cornercorner with one O(14)Li2Mn2Te square pyramid,  a cornercorner with one O(6)Li2Mn2Te square pyramid,  a cornercorner with one O(8)Li2Mn2Te square pyramid,  a cornercorner with one O(1)Li2Mn3 square pyramid, corners with two equivalent O(15)Li2Mn2Te square pyramids, corners with three equivalent O(16)Li2Mn2Te square pyramids,  an edgeedge with one O(11)Li2Mn2Te square pyramid,  an edgeedge with one O(13)Li2Mn2Te square pyramid,  an edgeedge with one O(6)Li2Mn2Te square pyramid,  an edgeedge with one O(8)Li2Mn2Te square pyramid,  an edgeedge with one O(1)Li2Mn3 square pyramid,  an edgeedge with one O(3)Li2Mn3 square pyramid, and  an edgeedge with one O(4)Li2Mn3 square pyramid. In the tenth O site, O(10) is bonded to one Li(2), one Li(4), one Mn(2), one Mn(4), and one Te(1) atom to form OLi2Mn2Te square pyramids that share  a cornercorner with one O(11)Li2Mn2Te square pyramid,  a cornercorner with one O(13)Li2Mn2Te square pyramid,  a cornercorner with one O(5)Li2Mn2Te square pyramid,  a cornercorner with one O(7)Li2Mn2Te square pyramid,  a cornercorner with one O(4)Li2Mn3 square pyramid, corners with two equivalent O(16)Li2Mn2Te square pyramids, corners with three equivalent O(15)Li2Mn2Te square pyramids,  an edgeedge with one O(12)Li2Mn2Te square pyramid,  an edgeedge with one O(14)Li2Mn2Te square pyramid,  an edgeedge with one O(5)Li2Mn2Te square pyramid,  an edgeedge with one O(7)Li2Mn2Te square pyramid,  an edgeedge with one O(3)Li2Mn3 square pyramid, and edges with two equivalent O(2)Li2Mn3 square pyramids. In the eleventh O site, O(11) is bonded to one Li(4), one Li(5), one Mn(3), one Mn(5), and one Te(2) atom to form OLi2Mn2Te square pyramids that share  a cornercorner with one O(10)Li2Mn2Te square pyramid,  a cornercorner with one O(13)Li2Mn2Te square pyramid,  a cornercorner with one O(16)Li2Mn2Te square pyramid,  a cornercorner with one O(7)Li2Mn2Te square pyramid,  a cornercorner with one O(2)Li2Mn3 square pyramid, corners with two equivalent O(5)Li2Mn2Te square pyramids, corners with three equivalent O(6)Li2Mn2Te square pyramids,  an edgeedge with one O(13)Li2Mn2Te square pyramid,  an edgeedge with one O(16)Li2Mn2Te square pyramid,  an edgeedge with one O(8)Li2Mn2Te square pyramid,  an edgeedge with one O(9)Li2Mn2Te square pyramid,  an edgeedge with one O(1)Li2Mn3 square pyramid, and edges with two equivalent O(4)Li2Mn3 square pyramids. In the twelfth O site, O(12) is bonded to one Li(3), one Li(6), one Mn(4), one Mn(6), and one Te(1) atom to form OLi2Mn2Te square pyramids that share  a cornercorner with one O(14)Li2Mn2Te square pyramid,  a cornercorner with one O(15)Li2Mn2Te square pyramid,  a cornercorner with one O(8)Li2Mn2Te square pyramid,  a cornercorner with one O(9)Li2Mn2Te square pyramid,  a cornercorner with one O(3)Li2Mn3 square pyramid, corners with two equivalent O(6)Li2Mn2Te square pyramids, corners with three equivalent O(5)Li2Mn2Te square pyramids,  an edgeedge with one O(10)Li2Mn2Te square pyramid,  an edgeedge with one O(14)Li2Mn2Te square pyramid,  an edgeedge with one O(15)Li2Mn2Te square pyramid,  an edgeedge with one O(7)Li2Mn2Te square pyramid,  an edgeedge with one O(1)Li2Mn3 square pyramid,  an edgeedge with one O(2)Li2Mn3 square pyramid, and  an edgeedge with one O(3)Li2Mn3 square pyramid. In the thirteenth O site, O(13) is bonded to one Li(2), one Li(5), one Mn(1), one Mn(3), and one Te(2) atom to form OLi2Mn2Te square pyramids that share  a cornercorner with one O(10)Li2Mn2Te square pyramid,  a cornercorner with one O(11)Li2Mn2Te square pyramid,  a cornercorner with one O(16)Li2Mn2Te square pyramid,  a cornercorner with one O(5)Li2Mn2Te square pyramid,  a cornercorner with one O(2)Li2Mn3 square pyramid,  a cornercorner with one O(4)Li2Mn3 square pyramid, corners with two equivalent O(7)Li2Mn2Te square pyramids, corners with three equivalent O(8)Li2Mn2Te square pyramids,  an edgeedge with one O(11)Li2Mn2Te square pyramid,  an edgeedge with one O(16)Li2Mn2Te square pyramid,  an edgeedge with one O(6)Li2Mn2Te square pyramid,  an edgeedge with one O(9)Li2Mn2Te square pyramid,  an edgeedge with one O(1)Li2Mn3 square pyramid, and  an edgeedge with one O(4)Li2Mn3 square pyramid. In the fourteenth O site, O(14) is bonded to one Li(1), one Li(6), one Mn(2), one Mn(6), and one Te(1) atom to form OLi2Mn2Te square pyramids that share  a cornercorner with one O(12)Li2Mn2Te square pyramid,  a cornercorner with one O(15)Li2Mn2Te square pyramid,  a cornercorner with one O(6)Li2Mn2Te square pyramid,  a cornercorner with one O(9)Li2Mn2Te square pyramid,  a cornercorner with one O(1)Li2Mn3 square pyramid,  a cornercorner with one O(3)Li2Mn3 square pyramid, corners with two equivalent O(8)Li2Mn2Te square pyramids, corners with three equivalent O(7)Li2Mn2Te square pyramids,  an edgeedge with one O(10)Li2Mn2Te square pyramid,  an edgeedge with one O(12)Li2Mn2Te square pyramid,  an edgeedge with one O(15)Li2Mn2Te square pyramid,  an edgeedge with one O(5)Li2Mn2Te square pyramid,  an edgeedge with one O(2)Li2Mn3 square pyramid, and  an edgeedge with one O(3)Li2Mn3 square pyramid. In the fifteenth O site, O(15) is bonded to one Li(1), one Li(3), one Mn(2), one Mn(4), and one Te(1) atom to form OLi2Mn2Te square pyramids that share  a cornercorner with one O(12)Li2Mn2Te square pyramid,  a cornercorner with one O(14)Li2Mn2Te square pyramid,  a cornercorner with one O(6)Li2Mn2Te square pyramid,  a cornercorner with one O(8)Li2Mn2Te square pyramid,  a cornercorner with one O(1)Li2Mn3 square pyramid, corners with two equivalent O(9)Li2Mn2Te square pyramids, corners with three equivalent O(10)Li2Mn2Te square pyramids,  an edgeedge with one O(12)Li2Mn2Te square pyramid,  an edgeedge with one O(14)Li2Mn2Te square pyramid,  an edgeedge with one O(5)Li2Mn2Te square pyramid,  an edgeedge with one O(7)Li2Mn2Te square pyramid,  an edgeedge with one O(2)Li2Mn3 square pyramid, and edges with two equivalent O(3)Li2Mn3 square pyramids. In the sixteenth O site, O(16) is bonded to one Li(2), one Li(4), one Mn(1), one Mn(5), and one Te(2) atom to form OLi2Mn2Te square pyramids that share  a cornercorner with one O(11)Li2Mn2Te square pyramid,  a cornercorner with one O(13)Li2Mn2Te square pyramid,  a cornercorner with one O(5)Li2Mn2Te square pyramid,  a cornercorner with one O(7)Li2Mn2Te square pyramid,  a cornercorner with one O(4)Li2Mn3 square pyramid, corners with two equivalent O(10)Li2Mn2Te square pyramids, corners with three equivalent O(9)Li2Mn2Te square pyramids,  an edgeedge with one O(11)Li2Mn2Te square pyramid,  an edgeedge with one O(13)Li2Mn2Te square pyramid,  an edgeedge with one O(6)Li2Mn2Te square pyramid,  an edgeedge with one O(8)Li2Mn2Te square pyramid,  an edgeedge with one O(1)Li2Mn3 square pyramid,  an edgeedge with one O(2)Li2Mn3 square pyramid, and  an edgeedge with one O(4)Li2Mn3 square pyramid. is represented by the CIF card [CIF]
data_Li3Mn3TeO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.275
_cell_length_b   6.273
_cell_length_c   10.425
_cell_angle_alpha   105.785
_cell_angle_beta   105.705
_cell_angle_gamma   60.995
_symmetry_Int_Tables_number   1
_cell_volume   340.657
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.215  0.758  0.738  1.0
  Li  Li1  1  0.785  0.241  0.262  1.0
  Li  Li2  1  0.752  0.747  0.750  1.0
  Li  Li3  1  0.248  0.253  0.250  1.0
  Li  Li4  1  0.261  0.716  0.238  1.0
  Li  Li5  1  0.740  0.284  0.762  1.0
  Mn  Mn6  1  0.999  0.500  0.000  1.0
  Mn  Mn7  1  0.500  0.000  0.500  1.0
  Mn  Mn8  1  0.499  0.000  1.000  1.0
  Mn  Mn9  1  0.001  0.000  0.500  1.0
  Mn  Mn10  1  0.499  0.500  1.000  1.0
  Mn  Mn11  1  0.000  0.500  0.500  1.0
  Te  Te12  1  0.500  0.500  0.500  1.0
  Te  Te13  1  1.000  0.000  1.000  1.0
  O  O14  1  0.672  0.615  0.896  1.0
  O  O15  1  0.115  0.172  0.397  1.0
  O  O16  1  0.886  0.828  0.604  1.0
  O  O17  1  0.327  0.385  0.104  1.0
  O  O18  1  0.164  0.601  0.393  1.0
  O  O19  1  0.674  0.111  0.887  1.0
  O  O20  1  0.596  0.615  0.379  1.0
  O  O21  1  0.114  0.099  0.880  1.0
  O  O22  1  0.102  0.664  0.891  1.0
  O  O23  1  0.611  0.174  0.387  1.0
  O  O24  1  0.326  0.889  0.112  1.0
  O  O25  1  0.837  0.399  0.608  1.0
  O  O26  1  0.886  0.902  0.120  1.0
  O  O27  1  0.405  0.385  0.621  1.0
  O  O28  1  0.390  0.826  0.613  1.0
  O  O29  1  0.897  0.336  0.109  1.0
[/CIF]
.
The structure described by Li3Mn3TeO8 crystallizes in the triclinic P1 space group. There are six inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(14), one O(15), one O(3), one O(8), and one O(9) atom to form distorted LiO5 square pyramids that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, corners with three equivalent Mn(2)O6 octahedra, corners with two equivalent Li(6)O5 square pyramids,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Te(1)O6 octahedra, and  an edgeedge with one Te(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 11-89°. In the second Li site, Li(2) is bonded to one O(10), one O(13), one O(16), one O(2), and one O(7) atom to form LiO5 square pyramids that share  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, corners with three equivalent Mn(2)O6 octahedra, corners with two equivalent Li(5)O5 square pyramids,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Te(1)O6 octahedra, and  an edgeedge with one Te(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 11-89°. In the third Li site, Li(3) is bonded to one O(1), one O(12), one O(15), one O(3), one O(6), and one O(9) atom to form LiO6 octahedra that share corners with three equivalent Mn(4)O6 octahedra, corners with three equivalent Mn(5)O6 octahedra,  a cornercorner with one Li(1)O5 square pyramid,  a cornercorner with one Li(6)O5 square pyramid,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra,  an edgeedge with one Li(1)O5 square pyramid, and  an edgeedge with one Li(6)O5 square pyramid. The corner-sharing octahedral tilt angles range from 13-16°. In the fourth Li site, Li(4) is bonded to one O(10), one O(11), one O(16), one O(2), one O(4), and one O(5) atom to form LiO6 octahedra that share corners with three equivalent Mn(4)O6 octahedra, corners with three equivalent Mn(5)O6 octahedra,  a cornercorner with one Li(2)O5 square pyramid,  a cornercorner with one Li(5)O5 square pyramid,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra,  an edgeedge with one Li(2)O5 square pyramid, and  an edgeedge with one Li(5)O5 square pyramid. The corner-sharing octahedral tilt angles range from 13-16°. In the fifth Li site, Li(5) is bonded to one O(11), one O(13), one O(4), one O(5), and one O(7) atom to form distorted LiO5 square pyramids that share  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra, corners with two equivalent Mn(6)O6 octahedra, corners with three equivalent Mn(3)O6 octahedra, corners with two equivalent Li(2)O5 square pyramids,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Te(1)O6 octahedra, and  an edgeedge with one Te(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 11-90°. In the sixth Li site, Li(6) is bonded to one O(1), one O(12), one O(14), one O(6), and one O(8) atom to form distorted LiO5 square pyramids that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra, corners with two equivalent Mn(6)O6 octahedra, corners with three equivalent Mn(3)O6 octahedra, corners with two equivalent Li(1)O5 square pyramids,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Te(1)O6 octahedra, and  an edgeedge with one Te(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 11-90°. There are six inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(13), one O(16), one O(4), one O(8), and one O(9) atom to form MnO6 octahedra that share corners with two equivalent Li(1)O5 square pyramids, corners with two equivalent Li(2)O5 square pyramids,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra, edges with two equivalent Te(2)O6 octahedra,  an edgeedge with one Li(5)O5 square pyramid, and  an edgeedge with one Li(6)O5 square pyramid. In the second Mn site, Mn(2) is bonded to one O(10), one O(14), one O(15), one O(2), one O(3), and one O(7) atom to form MnO6 octahedra that share  a cornercorner with one Li(5)O5 square pyramid,  a cornercorner with one Li(6)O5 square pyramid, corners with three equivalent Li(1)O5 square pyramids, corners with three equivalent Li(2)O5 square pyramids,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra, edges with two equivalent Mn(4)O6 octahedra, edges with two equivalent Mn(6)O6 octahedra, and edges with two equivalent Te(1)O6 octahedra. In the third Mn site, Mn(3) is bonded to one O(1), one O(11), one O(13), one O(4), one O(6), and one O(8) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O5 square pyramid,  a cornercorner with one Li(2)O5 square pyramid, corners with three equivalent Li(5)O5 square pyramids, corners with three equivalent Li(6)O5 square pyramids,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra, and edges with two equivalent Te(2)O6 octahedra. In the fourth Mn site, Mn(4) is bonded to one O(10), one O(12), one O(15), one O(2), one O(3), and one O(5) atom to form MnO6 octahedra that share corners with three equivalent Li(3)O6 octahedra, corners with three equivalent Li(4)O6 octahedra,  a cornercorner with one Li(5)O5 square pyramid,  a cornercorner with one Li(6)O5 square pyramid, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Mn(6)O6 octahedra, edges with two equivalent Te(1)O6 octahedra,  an edgeedge with one Li(1)O5 square pyramid, and  an edgeedge with one Li(2)O5 square pyramid. The corner-sharing octahedral tilt angles range from 14-16°. In the fifth Mn site, Mn(5) is bonded to one O(1), one O(11), one O(16), one O(4), one O(6), and one O(9) atom to form MnO6 octahedra that share corners with three equivalent Li(3)O6 octahedra, corners with three equivalent Li(4)O6 octahedra,  a cornercorner with one Li(1)O5 square pyramid,  a cornercorner with one Li(2)O5 square pyramid, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, edges with two equivalent Te(2)O6 octahedra,  an edgeedge with one Li(5)O5 square pyramid, and  an edgeedge with one Li(6)O5 square pyramid. The corner-sharing octahedral tilt angles range from 13-16°. In the sixth Mn site, Mn(6) is bonded to one O(12), one O(14), one O(2), one O(3), one O(5), and one O(7) atom to form MnO6 octahedra that share corners with two equivalent Li(5)O5 square pyramids, corners with two equivalent Li(6)O5 square pyramids,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Mn(4)O6 octahedra, edges with two equivalent Te(1)O6 octahedra,  an edgeedge with one Li(1)O5 square pyramid, and  an edgeedge with one Li(2)O5 square pyramid. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(10), one O(12), one O(14), one O(15), one O(5), and one O(7) atom to form TeO6 octahedra that share  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Mn(4)O6 octahedra, edges with two equivalent Mn(6)O6 octahedra,  an edgeedge with one Li(1)O5 square pyramid,  an edgeedge with one Li(2)O5 square pyramid,  an edgeedge with one Li(5)O5 square pyramid, and  an edgeedge with one Li(6)O5 square pyramid. In the second Te site, Te(2) is bonded to one O(11), one O(13), one O(16), one O(6), one O(8), and one O(9) atom to form TeO6 octahedra that share  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra,  an edgeedge with one Li(1)O5 square pyramid,  an edgeedge with one Li(2)O5 square pyramid,  an edgeedge with one Li(5)O5 square pyramid, and  an edgeedge with one Li(6)O5 square pyramid. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded to one Li(3), one Li(6), one Mn(1), one Mn(3), and one Mn(5) atom to form distorted OLi2Mn3 square pyramids that share  a cornercorner with one O(14)Li2Mn2Te square pyramid,  a cornercorner with one O(15)Li2Mn2Te square pyramid,  a cornercorner with one O(8)Li2Mn2Te square pyramid,  a cornercorner with one O(9)Li2Mn2Te square pyramid,  a cornercorner with one O(3)Li2Mn3 square pyramid, corners with three equivalent O(4)Li2Mn3 square pyramids,  an edgeedge with one O(11)Li2Mn2Te square pyramid,  an edgeedge with one O(12)Li2Mn2Te square pyramid,  an edgeedge with one O(13)Li2Mn2Te square pyramid,  an edgeedge with one O(16)Li2Mn2Te square pyramid,  an edgeedge with one O(8)Li2Mn2Te square pyramid,  an edgeedge with one O(9)Li2Mn2Te square pyramid, and edges with two equivalent O(6)Li2Mn2Te square pyramids. In the second O site, O(2) is bonded to one Li(2), one Li(4), one Mn(2), one Mn(4), and one Mn(6) atom to form distorted OLi2Mn3 square pyramids that share  a cornercorner with one O(11)Li2Mn2Te square pyramid,  a cornercorner with one O(13)Li2Mn2Te square pyramid,  a cornercorner with one O(5)Li2Mn2Te square pyramid,  a cornercorner with one O(7)Li2Mn2Te square pyramid,  a cornercorner with one O(4)Li2Mn3 square pyramid, corners with three equivalent O(3)Li2Mn3 square pyramids,  an edgeedge with one O(12)Li2Mn2Te square pyramid,  an edgeedge with one O(14)Li2Mn2Te square pyramid,  an edgeedge with one O(15)Li2Mn2Te square pyramid,  an edgeedge with one O(16)Li2Mn2Te square pyramid,  an edgeedge with one O(5)Li2Mn2Te square pyramid,  an edgeedge with one O(7)Li2Mn2Te square pyramid, and edges with two equivalent O(10)Li2Mn2Te square pyramids. In the third O site, O(3) is bonded to one Li(1), one Li(3), one Mn(2), one Mn(4), and one Mn(6) atom to form distorted OLi2Mn3 square pyramids that share  a cornercorner with one O(12)Li2Mn2Te square pyramid,  a cornercorner with one O(14)Li2Mn2Te square pyramid,  a cornercorner with one O(6)Li2Mn2Te square pyramid,  a cornercorner with one O(8)Li2Mn2Te square pyramid,  a cornercorner with one O(1)Li2Mn3 square pyramid, corners with three equivalent O(2)Li2Mn3 square pyramids,  an edgeedge with one O(10)Li2Mn2Te square pyramid,  an edgeedge with one O(12)Li2Mn2Te square pyramid,  an edgeedge with one O(14)Li2Mn2Te square pyramid,  an edgeedge with one O(5)Li2Mn2Te square pyramid,  an edgeedge with one O(7)Li2Mn2Te square pyramid,  an edgeedge with one O(9)Li2Mn2Te square pyramid, and edges with two equivalent O(15)Li2Mn2Te square pyramids. In the fourth O site, O(4) is bonded to one Li(4), one Li(5), one Mn(1), one Mn(3), and one Mn(5) atom to form distorted OLi2Mn3 square pyramids that share  a cornercorner with one O(10)Li2Mn2Te square pyramid,  a cornercorner with one O(13)Li2Mn2Te square pyramid,  a cornercorner with one O(16)Li2Mn2Te square pyramid,  a cornercorner with one O(7)Li2Mn2Te square pyramid,  a cornercorner with one O(2)Li2Mn3 square pyramid, corners with three equivalent O(1)Li2Mn3 square pyramids,  an edgeedge with one O(13)Li2Mn2Te square pyramid,  an edgeedge with one O(16)Li2Mn2Te square pyramid,  an edgeedge with one O(5)Li2Mn2Te square pyramid,  an edgeedge with one O(6)Li2Mn2Te square pyramid,  an edgeedge with one O(8)Li2Mn2Te square pyramid,  an edgeedge with one O(9)Li2Mn2Te square pyramid, and edges with two equivalent O(11)Li2Mn2Te square pyramids. In the fifth O site, O(5) is bonded to one Li(4), one Li(5), one Mn(4), one Mn(6), and one Te(1) atom to form OLi2Mn2Te square pyramids that share  a cornercorner with one O(10)Li2Mn2Te square pyramid,  a cornercorner with one O(13)Li2Mn2Te square pyramid,  a cornercorner with one O(16)Li2Mn2Te square pyramid,  a cornercorner with one O(7)Li2Mn2Te square pyramid,  a cornercorner with one O(2)Li2Mn3 square pyramid, corners with two equivalent O(11)Li2Mn2Te square pyramids, corners with three equivalent O(12)Li2Mn2Te square pyramids,  an edgeedge with one O(10)Li2Mn2Te square pyramid,  an edgeedge with one O(14)Li2Mn2Te square pyramid,  an edgeedge with one O(15)Li2Mn2Te square pyramid,  an edgeedge with one O(7)Li2Mn2Te square pyramid,  an edgeedge with one O(2)Li2Mn3 square pyramid,  an edgeedge with one O(3)Li2Mn3 square pyramid, and  an edgeedge with one O(4)Li2Mn3 square pyramid. In the sixth O site, O(6) is bonded to one Li(3), one Li(6), one Mn(3), one Mn(5), and one Te(2) atom to form OLi2Mn2Te square pyramids that share  a cornercorner with one O(14)Li2Mn2Te square pyramid,  a cornercorner with one O(15)Li2Mn2Te square pyramid,  a cornercorner with one O(8)Li2Mn2Te square pyramid,  a cornercorner with one O(9)Li2Mn2Te square pyramid,  a cornercorner with one O(3)Li2Mn3 square pyramid, corners with two equivalent O(12)Li2Mn2Te square pyramids, corners with three equivalent O(11)Li2Mn2Te square pyramids,  an edgeedge with one O(13)Li2Mn2Te square pyramid,  an edgeedge with one O(16)Li2Mn2Te square pyramid,  an edgeedge with one O(8)Li2Mn2Te square pyramid,  an edgeedge with one O(9)Li2Mn2Te square pyramid,  an edgeedge with one O(4)Li2Mn3 square pyramid, and edges with two equivalent O(1)Li2Mn3 square pyramids. In the seventh O site, O(7) is bonded to one Li(2), one Li(5), one Mn(2), one Mn(6), and one Te(1) atom to form OLi2Mn2Te square pyramids that share  a cornercorner with one O(10)Li2Mn2Te square pyramid,  a cornercorner with one O(11)Li2Mn2Te square pyramid,  a cornercorner with one O(16)Li2Mn2Te square pyramid,  a cornercorner with one O(5)Li2Mn2Te square pyramid,  a cornercorner with one O(2)Li2Mn3 square pyramid,  a cornercorner with one O(4)Li2Mn3 square pyramid, corners with two equivalent O(13)Li2Mn2Te square pyramids, corners with three equivalent O(14)Li2Mn2Te square pyramids,  an edgeedge with one O(10)Li2Mn2Te square pyramid,  an edgeedge with one O(12)Li2Mn2Te square pyramid,  an edgeedge with one O(15)Li2Mn2Te square pyramid,  an edgeedge with one O(5)Li2Mn2Te square pyramid,  an edgeedge with one O(2)Li2Mn3 square pyramid, and  an edgeedge with one O(3)Li2Mn3 square pyramid. In the eighth O site, O(8) is bonded to one Li(1), one Li(6), one Mn(1), one Mn(3), and one Te(2) atom to form OLi2Mn2Te square pyramids that share  a cornercorner with one O(12)Li2Mn2Te square pyramid,  a cornercorner with one O(15)Li2Mn2Te square pyramid,  a cornercorner with one O(6)Li2Mn2Te square pyramid,  a cornercorner with one O(9)Li2Mn2Te square pyramid,  a cornercorner with one O(1)Li2Mn3 square pyramid,  a cornercorner with one O(3)Li2Mn3 square pyramid, corners with two equivalent O(14)Li2Mn2Te square pyramids, corners with three equivalent O(13)Li2Mn2Te square pyramids,  an edgeedge with one O(11)Li2Mn2Te square pyramid,  an edgeedge with one O(16)Li2Mn2Te square pyramid,  an edgeedge with one O(6)Li2Mn2Te square pyramid,  an edgeedge with one O(9)Li2Mn2Te square pyramid,  an edgeedge with one O(1)Li2Mn3 square pyramid, and  an edgeedge with one O(4)Li2Mn3 square pyramid. In the ninth O site, O(9) is bonded to one Li(1), one Li(3), one Mn(1), one Mn(5), and one Te(2) atom to form OLi2Mn2Te square pyramids that share  a cornercorner with one O(12)Li2Mn2Te square pyramid,  a cornercorner with one O(14)Li2Mn2Te square pyramid,  a cornercorner with one O(6)Li2Mn2Te square pyramid,  a cornercorner with one O(8)Li2Mn2Te square pyramid,  a cornercorner with one O(1)Li2Mn3 square pyramid, corners with two equivalent O(15)Li2Mn2Te square pyramids, corners with three equivalent O(16)Li2Mn2Te square pyramids,  an edgeedge with one O(11)Li2Mn2Te square pyramid,  an edgeedge with one O(13)Li2Mn2Te square pyramid,  an edgeedge with one O(6)Li2Mn2Te square pyramid,  an edgeedge with one O(8)Li2Mn2Te square pyramid,  an edgeedge with one O(1)Li2Mn3 square pyramid,  an edgeedge with one O(3)Li2Mn3 square pyramid, and  an edgeedge with one O(4)Li2Mn3 square pyramid. In the tenth O site, O(10) is bonded to one Li(2), one Li(4), one Mn(2), one Mn(4), and one Te(1) atom to form OLi2Mn2Te square pyramids that share  a cornercorner with one O(11)Li2Mn2Te square pyramid,  a cornercorner with one O(13)Li2Mn2Te square pyramid,  a cornercorner with one O(5)Li2Mn2Te square pyramid,  a cornercorner with one O(7)Li2Mn2Te square pyramid,  a cornercorner with one O(4)Li2Mn3 square pyramid, corners with two equivalent O(16)Li2Mn2Te square pyramids, corners with three equivalent O(15)Li2Mn2Te square pyramids,  an edgeedge with one O(12)Li2Mn2Te square pyramid,  an edgeedge with one O(14)Li2Mn2Te square pyramid,  an edgeedge with one O(5)Li2Mn2Te square pyramid,  an edgeedge with one O(7)Li2Mn2Te square pyramid,  an edgeedge with one O(3)Li2Mn3 square pyramid, and edges with two equivalent O(2)Li2Mn3 square pyramids. In the eleventh O site, O(11) is bonded to one Li(4), one Li(5), one Mn(3), one Mn(5), and one Te(2) atom to form OLi2Mn2Te square pyramids that share  a cornercorner with one O(10)Li2Mn2Te square pyramid,  a cornercorner with one O(13)Li2Mn2Te square pyramid,  a cornercorner with one O(16)Li2Mn2Te square pyramid,  a cornercorner with one O(7)Li2Mn2Te square pyramid,  a cornercorner with one O(2)Li2Mn3 square pyramid, corners with two equivalent O(5)Li2Mn2Te square pyramids, corners with three equivalent O(6)Li2Mn2Te square pyramids,  an edgeedge with one O(13)Li2Mn2Te square pyramid,  an edgeedge with one O(16)Li2Mn2Te square pyramid,  an edgeedge with one O(8)Li2Mn2Te square pyramid,  an edgeedge with one O(9)Li2Mn2Te square pyramid,  an edgeedge with one O(1)Li2Mn3 square pyramid, and edges with two equivalent O(4)Li2Mn3 square pyramids. In the twelfth O site, O(12) is bonded to one Li(3), one Li(6), one Mn(4), one Mn(6), and one Te(1) atom to form OLi2Mn2Te square pyramids that share  a cornercorner with one O(14)Li2Mn2Te square pyramid,  a cornercorner with one O(15)Li2Mn2Te square pyramid,  a cornercorner with one O(8)Li2Mn2Te square pyramid,  a cornercorner with one O(9)Li2Mn2Te square pyramid,  a cornercorner with one O(3)Li2Mn3 square pyramid, corners with two equivalent O(6)Li2Mn2Te square pyramids, corners with three equivalent O(5)Li2Mn2Te square pyramids,  an edgeedge with one O(10)Li2Mn2Te square pyramid,  an edgeedge with one O(14)Li2Mn2Te square pyramid,  an edgeedge with one O(15)Li2Mn2Te square pyramid,  an edgeedge with one O(7)Li2Mn2Te square pyramid,  an edgeedge with one O(1)Li2Mn3 square pyramid,  an edgeedge with one O(2)Li2Mn3 square pyramid, and  an edgeedge with one O(3)Li2Mn3 square pyramid. In the thirteenth O site, O(13) is bonded to one Li(2), one Li(5), one Mn(1), one Mn(3), and one Te(2) atom to form OLi2Mn2Te square pyramids that share  a cornercorner with one O(10)Li2Mn2Te square pyramid,  a cornercorner with one O(11)Li2Mn2Te square pyramid,  a cornercorner with one O(16)Li2Mn2Te square pyramid,  a cornercorner with one O(5)Li2Mn2Te square pyramid,  a cornercorner with one O(2)Li2Mn3 square pyramid,  a cornercorner with one O(4)Li2Mn3 square pyramid, corners with two equivalent O(7)Li2Mn2Te square pyramids, corners with three equivalent O(8)Li2Mn2Te square pyramids,  an edgeedge with one O(11)Li2Mn2Te square pyramid,  an edgeedge with one O(16)Li2Mn2Te square pyramid,  an edgeedge with one O(6)Li2Mn2Te square pyramid,  an edgeedge with one O(9)Li2Mn2Te square pyramid,  an edgeedge with one O(1)Li2Mn3 square pyramid, and  an edgeedge with one O(4)Li2Mn3 square pyramid. In the fourteenth O site, O(14) is bonded to one Li(1), one Li(6), one Mn(2), one Mn(6), and one Te(1) atom to form OLi2Mn2Te square pyramids that share  a cornercorner with one O(12)Li2Mn2Te square pyramid,  a cornercorner with one O(15)Li2Mn2Te square pyramid,  a cornercorner with one O(6)Li2Mn2Te square pyramid,  a cornercorner with one O(9)Li2Mn2Te square pyramid,  a cornercorner with one O(1)Li2Mn3 square pyramid,  a cornercorner with one O(3)Li2Mn3 square pyramid, corners with two equivalent O(8)Li2Mn2Te square pyramids, corners with three equivalent O(7)Li2Mn2Te square pyramids,  an edgeedge with one O(10)Li2Mn2Te square pyramid,  an edgeedge with one O(12)Li2Mn2Te square pyramid,  an edgeedge with one O(15)Li2Mn2Te square pyramid,  an edgeedge with one O(5)Li2Mn2Te square pyramid,  an edgeedge with one O(2)Li2Mn3 square pyramid, and  an edgeedge with one O(3)Li2Mn3 square pyramid. In the fifteenth O site, O(15) is bonded to one Li(1), one Li(3), one Mn(2), one Mn(4), and one Te(1) atom to form OLi2Mn2Te square pyramids that share  a cornercorner with one O(12)Li2Mn2Te square pyramid,  a cornercorner with one O(14)Li2Mn2Te square pyramid,  a cornercorner with one O(6)Li2Mn2Te square pyramid,  a cornercorner with one O(8)Li2Mn2Te square pyramid,  a cornercorner with one O(1)Li2Mn3 square pyramid, corners with two equivalent O(9)Li2Mn2Te square pyramids, corners with three equivalent O(10)Li2Mn2Te square pyramids,  an edgeedge with one O(12)Li2Mn2Te square pyramid,  an edgeedge with one O(14)Li2Mn2Te square pyramid,  an edgeedge with one O(5)Li2Mn2Te square pyramid,  an edgeedge with one O(7)Li2Mn2Te square pyramid,  an edgeedge with one O(2)Li2Mn3 square pyramid, and edges with two equivalent O(3)Li2Mn3 square pyramids. In the sixteenth O site, O(16) is bonded to one Li(2), one Li(4), one Mn(1), one Mn(5), and one Te(2) atom to form OLi2Mn2Te square pyramids that share  a cornercorner with one O(11)Li2Mn2Te square pyramid,  a cornercorner with one O(13)Li2Mn2Te square pyramid,  a cornercorner with one O(5)Li2Mn2Te square pyramid,  a cornercorner with one O(7)Li2Mn2Te square pyramid,  a cornercorner with one O(4)Li2Mn3 square pyramid, corners with two equivalent O(10)Li2Mn2Te square pyramids, corners with three equivalent O(9)Li2Mn2Te square pyramids,  an edgeedge with one O(11)Li2Mn2Te square pyramid,  an edgeedge with one O(13)Li2Mn2Te square pyramid,  an edgeedge with one O(6)Li2Mn2Te square pyramid,  an edgeedge with one O(8)Li2Mn2Te square pyramid,  an edgeedge with one O(1)Li2Mn3 square pyramid,  an edgeedge with one O(2)Li2Mn3 square pyramid, and  an edgeedge with one O(4)Li2Mn3 square pyramid. is represented by the CIF card [CIF]
data_Li3Mn3TeO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.275
_cell_length_b   6.273
_cell_length_c   10.425
_cell_angle_alpha   105.785
_cell_angle_beta   105.705
_cell_angle_gamma   60.995
_symmetry_Int_Tables_number   1
_cell_volume   340.657
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.215  0.758  0.738  1.0
  Li  Li1  1  0.785  0.241  0.262  1.0
  Li  Li2  1  0.752  0.747  0.750  1.0
  Li  Li3  1  0.248  0.253  0.250  1.0
  Li  Li4  1  0.261  0.716  0.238  1.0
  Li  Li5  1  0.740  0.284  0.762  1.0
  Mn  Mn6  1  0.999  0.500  0.000  1.0
  Mn  Mn7  1  0.500  0.000  0.500  1.0
  Mn  Mn8  1  0.499  0.000  1.000  1.0
  Mn  Mn9  1  0.001  0.000  0.500  1.0
  Mn  Mn10  1  0.499  0.500  1.000  1.0
  Mn  Mn11  1  0.000  0.500  0.500  1.0
  Te  Te12  1  0.500  0.500  0.500  1.0
  Te  Te13  1  1.000  0.000  1.000  1.0
  O  O14  1  0.672  0.615  0.896  1.0
  O  O15  1  0.115  0.172  0.397  1.0
  O  O16  1  0.886  0.828  0.604  1.0
  O  O17  1  0.327  0.385  0.104  1.0
  O  O18  1  0.164  0.601  0.393  1.0
  O  O19  1  0.674  0.111  0.887  1.0
  O  O20  1  0.596  0.615  0.379  1.0
  O  O21  1  0.114  0.099  0.880  1.0
  O  O22  1  0.102  0.664  0.891  1.0
  O  O23  1  0.611  0.174  0.387  1.0
  O  O24  1  0.326  0.889  0.112  1.0
  O  O25  1  0.837  0.399  0.608  1.0
  O  O26  1  0.886  0.902  0.120  1.0
  O  O27  1  0.405  0.385  0.621  1.0
  O  O28  1  0.390  0.826  0.613  1.0
  O  O29  1  0.897  0.336  0.109  1.0
[/CIF]
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