The structure described by MnF3 crystallizes in the monoclinic C2/c space group. Mn(1) is bonded to two equivalent F(1) and four equivalent F(2) atoms to form corner-sharing MnF6 octahedra. The corner-sharing octahedral tilt angles range from 24-25°. There are two inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to two equivalent Mn(1) atoms. In the second F site, F(2) is bonded in a bent 150 degrees geometry to two equivalent Mn(1) atoms. is represented by the CIF card [CIF]
data_MnF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.341
_cell_length_b   5.341
_cell_length_c   5.468
_cell_angle_alpha   61.322
_cell_angle_beta   61.322
_cell_angle_gamma   61.849
_symmetry_Int_Tables_number   1
_cell_volume   114.006
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.000  0.500  0.000  1.0
  Mn  Mn1  1  0.500  0.000  0.500  1.0
  F  F2  1  0.674  0.326  0.250  1.0
  F  F3  1  0.326  0.674  0.750  1.0
  F  F4  1  0.839  0.738  0.235  1.0
  F  F5  1  0.262  0.161  0.265  1.0
  F  F6  1  0.161  0.262  0.765  1.0
  F  F7  1  0.738  0.839  0.735  1.0
[/CIF]
.
The structure described by MnF3 crystallizes in the monoclinic C2/c space group. Mn(1) is bonded to two equivalent F(1) and four equivalent F(2) atoms to form corner-sharing MnF6 octahedra. The corner-sharing octahedral tilt angles range from 24-25°. There are two inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to two equivalent Mn(1) atoms. In the second F site, F(2) is bonded in a bent 150 degrees geometry to two equivalent Mn(1) atoms. is represented by the CIF card [CIF]
data_MnF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.341
_cell_length_b   5.341
_cell_length_c   5.468
_cell_angle_alpha   61.322
_cell_angle_beta   61.322
_cell_angle_gamma   61.849
_symmetry_Int_Tables_number   1
_cell_volume   114.006
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.000  0.500  0.000  1.0
  Mn  Mn1  1  0.500  0.000  0.500  1.0
  F  F2  1  0.674  0.326  0.250  1.0
  F  F3  1  0.326  0.674  0.750  1.0
  F  F4  1  0.839  0.738  0.235  1.0
  F  F5  1  0.262  0.161  0.265  1.0
  F  F6  1  0.161  0.262  0.765  1.0
  F  F7  1  0.738  0.839  0.735  1.0
[/CIF]
.