The material structure described by K3InC12O12F18 crystallizes in the trigonal P-3 space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a distorted hexagonal planar geometry to six equivalent O(1) atoms. In the second K site, K(2) is bonded in a 6-coordinate geometry to three equivalent O(2) and three equivalent F(3) atoms. In(1) is bonded in an octahedral geometry to six equivalent O(1) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal non-coplanar geometry to one F(1), one F(2), and one F(3) atom. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one K(1), one In(1), and one C(2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one K(2) and one C(2) atom. There are three inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one C(1) atom. In the second F site, F(3) is bonded in a single-bond geometry to one K(2) and one C(1) atom. In the third F site, F(1) is bonded in a single-bond geometry to one C(1) atom. is represented by the CIF card [CIF]
data_K3InC12(O2F3)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.207
_cell_length_b   10.207
_cell_length_c   7.511
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   677.670
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.000  0.000  0.500  1.0
  K  K1  1  0.333  0.667  0.079  1.0
  K  K2  1  0.667  0.333  0.921  1.0
  In  In3  1  0.000  0.000  0.000  1.0
  C  C4  1  0.402  0.053  0.311  1.0
  C  C5  1  0.598  0.947  0.689  1.0
  C  C6  1  0.947  0.349  0.311  1.0
  C  C7  1  0.053  0.651  0.689  1.0
  C  C8  1  0.651  0.598  0.311  1.0
  C  C9  1  0.349  0.402  0.689  1.0
  C  C10  1  0.315  0.075  0.153  1.0
  C  C11  1  0.685  0.925  0.847  1.0
  C  C12  1  0.925  0.240  0.153  1.0
  C  C13  1  0.075  0.760  0.847  1.0
  C  C14  1  0.760  0.685  0.153  1.0
  C  C15  1  0.240  0.315  0.847  1.0
  O  O16  1  0.179  0.039  0.194  1.0
  O  O17  1  0.821  0.961  0.806  1.0
  O  O18  1  0.961  0.140  0.194  1.0
  O  O19  1  0.039  0.860  0.806  1.0
  O  O20  1  0.860  0.821  0.194  1.0
  O  O21  1  0.140  0.179  0.806  1.0
  O  O22  1  0.383  0.119  0.010  1.0
  O  O23  1  0.617  0.881  0.990  1.0
  O  O24  1  0.881  0.263  0.010  1.0
  O  O25  1  0.119  0.737  0.990  1.0
  O  O26  1  0.737  0.617  0.010  1.0
  O  O27  1  0.263  0.383  0.990  1.0
  F  F28  1  0.361  0.080  0.473  1.0
  F  F29  1  0.639  0.920  0.527  1.0
  F  F30  1  0.920  0.281  0.473  1.0
  F  F31  1  0.080  0.719  0.527  1.0
  F  F32  1  0.719  0.639  0.473  1.0
  F  F33  1  0.281  0.361  0.527  1.0
  F  F34  1  0.554  0.142  0.295  1.0
  F  F35  1  0.446  0.858  0.705  1.0
  F  F36  1  0.858  0.412  0.295  1.0
  F  F37  1  0.142  0.588  0.705  1.0
  F  F38  1  0.588  0.446  0.295  1.0
  F  F39  1  0.412  0.554  0.705  1.0
  F  F40  1  0.094  0.467  0.313  1.0
  F  F41  1  0.906  0.533  0.687  1.0
  F  F42  1  0.533  0.627  0.313  1.0
  F  F43  1  0.467  0.373  0.687  1.0
  F  F44  1  0.373  0.906  0.313  1.0
  F  F45  1  0.627  0.094  0.687  1.0
[/CIF]
.
The material structure described by K3InC12O12F18 crystallizes in the trigonal P-3 space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a distorted hexagonal planar geometry to six equivalent O(1) atoms. In the second K site, K(2) is bonded in a 6-coordinate geometry to three equivalent O(2) and three equivalent F(3) atoms. In(1) is bonded in an octahedral geometry to six equivalent O(1) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal non-coplanar geometry to one F(1), one F(2), and one F(3) atom. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one K(1), one In(1), and one C(2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one K(2) and one C(2) atom. There are three inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one C(1) atom. In the second F site, F(3) is bonded in a single-bond geometry to one K(2) and one C(1) atom. In the third F site, F(1) is bonded in a single-bond geometry to one C(1) atom. is represented by the CIF card [CIF]
data_K3InC12(O2F3)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.207
_cell_length_b   10.207
_cell_length_c   7.511
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   677.670
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.000  0.000  0.500  1.0
  K  K1  1  0.333  0.667  0.079  1.0
  K  K2  1  0.667  0.333  0.921  1.0
  In  In3  1  0.000  0.000  0.000  1.0
  C  C4  1  0.402  0.053  0.311  1.0
  C  C5  1  0.598  0.947  0.689  1.0
  C  C6  1  0.947  0.349  0.311  1.0
  C  C7  1  0.053  0.651  0.689  1.0
  C  C8  1  0.651  0.598  0.311  1.0
  C  C9  1  0.349  0.402  0.689  1.0
  C  C10  1  0.315  0.075  0.153  1.0
  C  C11  1  0.685  0.925  0.847  1.0
  C  C12  1  0.925  0.240  0.153  1.0
  C  C13  1  0.075  0.760  0.847  1.0
  C  C14  1  0.760  0.685  0.153  1.0
  C  C15  1  0.240  0.315  0.847  1.0
  O  O16  1  0.179  0.039  0.194  1.0
  O  O17  1  0.821  0.961  0.806  1.0
  O  O18  1  0.961  0.140  0.194  1.0
  O  O19  1  0.039  0.860  0.806  1.0
  O  O20  1  0.860  0.821  0.194  1.0
  O  O21  1  0.140  0.179  0.806  1.0
  O  O22  1  0.383  0.119  0.010  1.0
  O  O23  1  0.617  0.881  0.990  1.0
  O  O24  1  0.881  0.263  0.010  1.0
  O  O25  1  0.119  0.737  0.990  1.0
  O  O26  1  0.737  0.617  0.010  1.0
  O  O27  1  0.263  0.383  0.990  1.0
  F  F28  1  0.361  0.080  0.473  1.0
  F  F29  1  0.639  0.920  0.527  1.0
  F  F30  1  0.920  0.281  0.473  1.0
  F  F31  1  0.080  0.719  0.527  1.0
  F  F32  1  0.719  0.639  0.473  1.0
  F  F33  1  0.281  0.361  0.527  1.0
  F  F34  1  0.554  0.142  0.295  1.0
  F  F35  1  0.446  0.858  0.705  1.0
  F  F36  1  0.858  0.412  0.295  1.0
  F  F37  1  0.142  0.588  0.705  1.0
  F  F38  1  0.588  0.446  0.295  1.0
  F  F39  1  0.412  0.554  0.705  1.0
  F  F40  1  0.094  0.467  0.313  1.0
  F  F41  1  0.906  0.533  0.687  1.0
  F  F42  1  0.533  0.627  0.313  1.0
  F  F43  1  0.467  0.373  0.687  1.0
  F  F44  1  0.373  0.906  0.313  1.0
  F  F45  1  0.627  0.094  0.687  1.0
[/CIF]
.