The material structure described by Sb3PbAgS6 crystallizes in the monoclinic Pc space group. Ag(1) is bonded in a T-shaped geometry to one S(2), one S(4), and one S(6) atom. Pb(1) is bonded in a 5-coordinate geometry to one S(4), one S(5), one S(6), and two equivalent S(1) atoms. There are three inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a trigonal non-coplanar geometry to one S(2), one S(4), and one S(6) atom. In the second Sb site, Sb(2) is bonded in a distorted T-shaped geometry to one S(2), one S(3), and one S(5) atom. In the third Sb site, Sb(3) is bonded in a 3-coordinate geometry to one S(1), one S(2), and one S(3) atom. There are six inequivalent S sites. In the first S site, S(1) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Pb(1) and one Sb(3) atom. In the second S site, S(2) is bonded in a distorted tetrahedral geometry to one Ag(1), one Sb(1), one Sb(2), and one Sb(3) atom. In the third S site, S(3) is bonded in a water-like geometry to one Sb(2) and one Sb(3) atom. In the fourth S site, S(4) is bonded in a distorted T-shaped geometry to one Ag(1), one Pb(1), and one Sb(1) atom. In the fifth S site, S(5) is bonded in a 1-coordinate geometry to one Pb(1) and one Sb(2) atom. In the sixth S site, S(6) is bonded in a distorted water-like geometry to one Ag(1), one Pb(1), and one Sb(1) atom. is represented by the CIF file [CIF]
data_AgSb3PbS6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.109
_cell_length_b   11.128
_cell_length_c   12.339
_cell_angle_alpha   112.515
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   647.985
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.338  0.989  0.271  1.0
  Ag  Ag1  1  0.662  0.489  0.771  1.0
  Sb  Sb2  1  0.749  0.705  0.097  1.0
  Sb  Sb3  1  0.805  0.811  0.410  1.0
  Sb  Sb4  1  0.386  0.491  0.213  1.0
  Sb  Sb5  1  0.614  0.991  0.713  1.0
  Sb  Sb6  1  0.195  0.311  0.910  1.0
  Sb  Sb7  1  0.251  0.205  0.597  1.0
  Pb  Pb8  1  0.837  0.206  0.230  1.0
  Pb  Pb9  1  0.163  0.706  0.730  1.0
  S  S10  1  0.322  0.331  0.301  1.0
  S  S11  1  0.678  0.831  0.801  1.0
  S  S12  1  0.135  0.743  0.243  1.0
  S  S13  1  0.865  0.243  0.743  1.0
  S  S14  1  0.311  0.085  0.885  1.0
  S  S15  1  0.336  0.429  0.617  1.0
  S  S16  1  0.664  0.929  0.117  1.0
  S  S17  1  0.689  0.585  0.385  1.0
  S  S18  1  0.885  0.349  0.069  1.0
  S  S19  1  0.115  0.849  0.569  1.0
  S  S20  1  0.998  0.611  0.916  1.0
  S  S21  1  0.002  0.111  0.416  1.0
[/CIF]
.
The material structure described by Sb3PbAgS6 crystallizes in the monoclinic Pc space group. Ag(1) is bonded in a T-shaped geometry to one S(2), one S(4), and one S(6) atom. Pb(1) is bonded in a 5-coordinate geometry to one S(4), one S(5), one S(6), and two equivalent S(1) atoms. There are three inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a trigonal non-coplanar geometry to one S(2), one S(4), and one S(6) atom. In the second Sb site, Sb(2) is bonded in a distorted T-shaped geometry to one S(2), one S(3), and one S(5) atom. In the third Sb site, Sb(3) is bonded in a 3-coordinate geometry to one S(1), one S(2), and one S(3) atom. There are six inequivalent S sites. In the first S site, S(1) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Pb(1) and one Sb(3) atom. In the second S site, S(2) is bonded in a distorted tetrahedral geometry to one Ag(1), one Sb(1), one Sb(2), and one Sb(3) atom. In the third S site, S(3) is bonded in a water-like geometry to one Sb(2) and one Sb(3) atom. In the fourth S site, S(4) is bonded in a distorted T-shaped geometry to one Ag(1), one Pb(1), and one Sb(1) atom. In the fifth S site, S(5) is bonded in a 1-coordinate geometry to one Pb(1) and one Sb(2) atom. In the sixth S site, S(6) is bonded in a distorted water-like geometry to one Ag(1), one Pb(1), and one Sb(1) atom. is represented by the CIF file [CIF]
data_AgSb3PbS6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.109
_cell_length_b   11.128
_cell_length_c   12.339
_cell_angle_alpha   112.515
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   647.985
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.338  0.989  0.271  1.0
  Ag  Ag1  1  0.662  0.489  0.771  1.0
  Sb  Sb2  1  0.749  0.705  0.097  1.0
  Sb  Sb3  1  0.805  0.811  0.410  1.0
  Sb  Sb4  1  0.386  0.491  0.213  1.0
  Sb  Sb5  1  0.614  0.991  0.713  1.0
  Sb  Sb6  1  0.195  0.311  0.910  1.0
  Sb  Sb7  1  0.251  0.205  0.597  1.0
  Pb  Pb8  1  0.837  0.206  0.230  1.0
  Pb  Pb9  1  0.163  0.706  0.730  1.0
  S  S10  1  0.322  0.331  0.301  1.0
  S  S11  1  0.678  0.831  0.801  1.0
  S  S12  1  0.135  0.743  0.243  1.0
  S  S13  1  0.865  0.243  0.743  1.0
  S  S14  1  0.311  0.085  0.885  1.0
  S  S15  1  0.336  0.429  0.617  1.0
  S  S16  1  0.664  0.929  0.117  1.0
  S  S17  1  0.689  0.585  0.385  1.0
  S  S18  1  0.885  0.349  0.069  1.0
  S  S19  1  0.115  0.849  0.569  1.0
  S  S20  1  0.998  0.611  0.916  1.0
  S  S21  1  0.002  0.111  0.416  1.0
[/CIF]
.