The structure described by RbO2 is Anatase structured and crystallizes in the tetragonal I4_1/amd space group. Rb(1) is bonded to six equivalent O(1) atoms to form a mixture of corner and edge-sharing RbO6 octahedra. The corner-sharing octahedral tilt angles are 11°. O(1) is bonded in a T-shaped geometry to three equivalent Rb(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.809
_cell_length_b   6.809
_cell_length_c   6.809
_cell_angle_alpha   131.776
_cell_angle_beta   131.776
_cell_angle_gamma   70.583
_symmetry_Int_Tables_number   1
_cell_volume   171.988
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.000  0.000  0.000  1.0
  Rb  Rb1  1  0.750  0.250  0.500  1.0
  O  O2  1  0.726  0.726  0.000  1.0
  O  O3  1  0.274  0.274  0.000  1.0
  O  O4  1  0.024  0.524  0.500  1.0
  O  O5  1  0.476  0.976  0.500  1.0
[/CIF]
.
The structure described by RbO2 is Anatase structured and crystallizes in the tetragonal I4_1/amd space group. Rb(1) is bonded to six equivalent O(1) atoms to form a mixture of corner and edge-sharing RbO6 octahedra. The corner-sharing octahedral tilt angles are 11°. O(1) is bonded in a T-shaped geometry to three equivalent Rb(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.809
_cell_length_b   6.809
_cell_length_c   6.809
_cell_angle_alpha   131.776
_cell_angle_beta   131.776
_cell_angle_gamma   70.583
_symmetry_Int_Tables_number   1
_cell_volume   171.988
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.000  0.000  0.000  1.0
  Rb  Rb1  1  0.750  0.250  0.500  1.0
  O  O2  1  0.726  0.726  0.000  1.0
  O  O3  1  0.274  0.274  0.000  1.0
  O  O4  1  0.024  0.524  0.500  1.0
  O  O5  1  0.476  0.976  0.500  1.0
[/CIF]
.