The crystal structure described by Na3Mn2P2(CO7)2 crystallizes in the triclinic P-1 space group. There are three inequivalent Na sites. In the first Na site, Na(1) is bonded in a 6-coordinate geometry to one O(1), one O(11), one O(12), one O(4), one O(5), and one O(9) atom. In the second Na site, Na(2) is bonded in a 7-coordinate geometry to one O(1), one O(10), one O(11), one O(12), one O(4), one O(5), and one O(8) atom. In the third Na site, Na(3) is bonded in a 6-coordinate geometry to one O(13), one O(14), one O(2), one O(3), one O(6), and one O(7) atom. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(11), one O(14), one O(3), one O(5), one O(7), and one O(8) atom to form MnO6 octahedra that share  a cornercorner with one P(2)O4 tetrahedra and corners with three equivalent P(1)O4 tetrahedra. In the second Mn site, Mn(2) is bonded to one O(10), one O(12), one O(13), one O(4), one O(6), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra and corners with three equivalent P(2)O4 tetrahedra. There are two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one O(1), one O(3), and one O(5) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one O(2), one O(4), and one O(6) atom. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(11), one O(12), one O(7), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(2)O6 octahedra and corners with three equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 38-48°. In the second P site, P(2) is bonded to one O(10), one O(13), one O(14), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra and corners with three equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-47°. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Na(1), one Na(2), and one C(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Na(3) and one C(2) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Na(3), one Mn(1), and one C(1) atom. In the fourth O site, O(4) is bonded in a distorted rectangular see-saw-like geometry to one Na(1), one Na(2), one Mn(2), and one C(2) atom. In the fifth O site, O(5) is bonded in a distorted trigonal pyramidal geometry to one Na(1), one Na(2), one Mn(1), and one C(1) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Na(3), one Mn(2), and one C(2) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Na(3), one Mn(1), and one P(1) atom. In the eighth O site, O(8) is bonded in a 2-coordinate geometry to one Na(2), one Mn(1), and one P(1) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Na(1), one Mn(2), and one P(2) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Na(2), one Mn(2), and one P(2) atom. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one Na(1), one Na(2), one Mn(1), and one P(1) atom. In the twelfth O site, O(12) is bonded in a distorted rectangular see-saw-like geometry to one Na(1), one Na(2), one Mn(2), and one P(1) atom. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one Na(3), one Mn(2), and one P(2) atom. In the fourteenth O site, O(14) is bonded in a 3-coordinate geometry to one Na(3), one Mn(1), and one P(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Na3Mn2P2(CO7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.578
_cell_length_b   8.981
_cell_length_c   10.387
_cell_angle_alpha   91.493
_cell_angle_beta   90.382
_cell_angle_gamma   91.239
_symmetry_Int_Tables_number   1
_cell_volume   613.276
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.005  0.240  0.131  1.0
  Na  Na1  1  0.487  0.239  0.125  1.0
  Na  Na2  1  0.025  0.242  0.628  1.0
  Na  Na3  1  0.513  0.761  0.875  1.0
  Na  Na4  1  0.995  0.760  0.869  1.0
  Na  Na5  1  0.975  0.758  0.372  1.0
  Mn  Mn6  1  0.744  0.346  0.854  1.0
  Mn  Mn7  1  0.743  0.348  0.362  1.0
  Mn  Mn8  1  0.256  0.654  0.146  1.0
  Mn  Mn9  1  0.257  0.652  0.638  1.0
  P  P10  1  0.249  0.426  0.897  1.0
  P  P11  1  0.246  0.428  0.390  1.0
  P  P12  1  0.751  0.574  0.103  1.0
  P  P13  1  0.754  0.572  0.610  1.0
  C  C14  1  0.753  0.077  0.884  1.0
  C  C15  1  0.746  0.078  0.385  1.0
  C  C16  1  0.247  0.923  0.116  1.0
  C  C17  1  0.254  0.922  0.615  1.0
  O  O18  1  0.240  0.060  0.101  1.0
  O  O19  1  0.247  0.059  0.605  1.0
  O  O20  1  0.751  0.141  0.773  1.0
  O  O21  1  0.736  0.147  0.273  1.0
  O  O22  1  0.747  0.176  0.981  1.0
  O  O23  1  0.749  0.176  0.482  1.0
  O  O24  1  0.061  0.327  0.860  1.0
  O  O25  1  0.436  0.330  0.871  1.0
  O  O26  1  0.058  0.327  0.355  1.0
  O  O27  1  0.432  0.336  0.350  1.0
  O  O28  1  0.242  0.463  0.046  1.0
  O  O29  1  0.747  0.426  0.176  1.0
  O  O30  1  0.242  0.466  0.537  1.0
  O  O31  1  0.762  0.423  0.681  1.0
  O  O32  1  0.253  0.574  0.824  1.0
  O  O33  1  0.758  0.537  0.954  1.0
  O  O34  1  0.238  0.577  0.319  1.0
  O  O35  1  0.758  0.534  0.463  1.0
  O  O36  1  0.564  0.670  0.129  1.0
  O  O37  1  0.939  0.673  0.140  1.0
  O  O38  1  0.568  0.664  0.650  1.0
  O  O39  1  0.942  0.673  0.645  1.0
  O  O40  1  0.253  0.824  0.019  1.0
  O  O41  1  0.251  0.824  0.518  1.0
  O  O42  1  0.249  0.859  0.227  1.0
  O  O43  1  0.264  0.853  0.727  1.0
  O  O44  1  0.760  0.940  0.899  1.0
  O  O45  1  0.753  0.941  0.395  1.0
[/CIF]
.
The crystal structure described by Na3Mn2P2(CO7)2 crystallizes in the triclinic P-1 space group. There are three inequivalent Na sites. In the first Na site, Na(1) is bonded in a 6-coordinate geometry to one O(1), one O(11), one O(12), one O(4), one O(5), and one O(9) atom. In the second Na site, Na(2) is bonded in a 7-coordinate geometry to one O(1), one O(10), one O(11), one O(12), one O(4), one O(5), and one O(8) atom. In the third Na site, Na(3) is bonded in a 6-coordinate geometry to one O(13), one O(14), one O(2), one O(3), one O(6), and one O(7) atom. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(11), one O(14), one O(3), one O(5), one O(7), and one O(8) atom to form MnO6 octahedra that share  a cornercorner with one P(2)O4 tetrahedra and corners with three equivalent P(1)O4 tetrahedra. In the second Mn site, Mn(2) is bonded to one O(10), one O(12), one O(13), one O(4), one O(6), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra and corners with three equivalent P(2)O4 tetrahedra. There are two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one O(1), one O(3), and one O(5) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one O(2), one O(4), and one O(6) atom. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(11), one O(12), one O(7), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(2)O6 octahedra and corners with three equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 38-48°. In the second P site, P(2) is bonded to one O(10), one O(13), one O(14), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra and corners with three equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-47°. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Na(1), one Na(2), and one C(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Na(3) and one C(2) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Na(3), one Mn(1), and one C(1) atom. In the fourth O site, O(4) is bonded in a distorted rectangular see-saw-like geometry to one Na(1), one Na(2), one Mn(2), and one C(2) atom. In the fifth O site, O(5) is bonded in a distorted trigonal pyramidal geometry to one Na(1), one Na(2), one Mn(1), and one C(1) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Na(3), one Mn(2), and one C(2) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Na(3), one Mn(1), and one P(1) atom. In the eighth O site, O(8) is bonded in a 2-coordinate geometry to one Na(2), one Mn(1), and one P(1) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Na(1), one Mn(2), and one P(2) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Na(2), one Mn(2), and one P(2) atom. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one Na(1), one Na(2), one Mn(1), and one P(1) atom. In the twelfth O site, O(12) is bonded in a distorted rectangular see-saw-like geometry to one Na(1), one Na(2), one Mn(2), and one P(1) atom. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one Na(3), one Mn(2), and one P(2) atom. In the fourteenth O site, O(14) is bonded in a 3-coordinate geometry to one Na(3), one Mn(1), and one P(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Na3Mn2P2(CO7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.578
_cell_length_b   8.981
_cell_length_c   10.387
_cell_angle_alpha   91.493
_cell_angle_beta   90.382
_cell_angle_gamma   91.239
_symmetry_Int_Tables_number   1
_cell_volume   613.276
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.005  0.240  0.131  1.0
  Na  Na1  1  0.487  0.239  0.125  1.0
  Na  Na2  1  0.025  0.242  0.628  1.0
  Na  Na3  1  0.513  0.761  0.875  1.0
  Na  Na4  1  0.995  0.760  0.869  1.0
  Na  Na5  1  0.975  0.758  0.372  1.0
  Mn  Mn6  1  0.744  0.346  0.854  1.0
  Mn  Mn7  1  0.743  0.348  0.362  1.0
  Mn  Mn8  1  0.256  0.654  0.146  1.0
  Mn  Mn9  1  0.257  0.652  0.638  1.0
  P  P10  1  0.249  0.426  0.897  1.0
  P  P11  1  0.246  0.428  0.390  1.0
  P  P12  1  0.751  0.574  0.103  1.0
  P  P13  1  0.754  0.572  0.610  1.0
  C  C14  1  0.753  0.077  0.884  1.0
  C  C15  1  0.746  0.078  0.385  1.0
  C  C16  1  0.247  0.923  0.116  1.0
  C  C17  1  0.254  0.922  0.615  1.0
  O  O18  1  0.240  0.060  0.101  1.0
  O  O19  1  0.247  0.059  0.605  1.0
  O  O20  1  0.751  0.141  0.773  1.0
  O  O21  1  0.736  0.147  0.273  1.0
  O  O22  1  0.747  0.176  0.981  1.0
  O  O23  1  0.749  0.176  0.482  1.0
  O  O24  1  0.061  0.327  0.860  1.0
  O  O25  1  0.436  0.330  0.871  1.0
  O  O26  1  0.058  0.327  0.355  1.0
  O  O27  1  0.432  0.336  0.350  1.0
  O  O28  1  0.242  0.463  0.046  1.0
  O  O29  1  0.747  0.426  0.176  1.0
  O  O30  1  0.242  0.466  0.537  1.0
  O  O31  1  0.762  0.423  0.681  1.0
  O  O32  1  0.253  0.574  0.824  1.0
  O  O33  1  0.758  0.537  0.954  1.0
  O  O34  1  0.238  0.577  0.319  1.0
  O  O35  1  0.758  0.534  0.463  1.0
  O  O36  1  0.564  0.670  0.129  1.0
  O  O37  1  0.939  0.673  0.140  1.0
  O  O38  1  0.568  0.664  0.650  1.0
  O  O39  1  0.942  0.673  0.645  1.0
  O  O40  1  0.253  0.824  0.019  1.0
  O  O41  1  0.251  0.824  0.518  1.0
  O  O42  1  0.249  0.859  0.227  1.0
  O  O43  1  0.264  0.853  0.727  1.0
  O  O44  1  0.760  0.940  0.899  1.0
  O  O45  1  0.753  0.941  0.395  1.0
[/CIF]
.