The structure described by Cs2TaTlF6 crystallizes in the cubic Fm-3m space group. Cs(1) is bonded to twelve equivalent F(1) atoms to form CsF12 cuboctahedra that share corners with twelve equivalent Cs(1)F12 cuboctahedra, faces with six equivalent Cs(1)F12 cuboctahedra, faces with four equivalent Ta(1)F6 octahedra, and faces with four equivalent Tl(1)F6 octahedra. Ta(1) is bonded to six equivalent F(1) atoms to form TaF6 octahedra that share corners with six equivalent Tl(1)F6 octahedra and faces with eight equivalent Cs(1)F12 cuboctahedra. The corner-sharing octahedra are not tilted. Tl(1) is bonded to six equivalent F(1) atoms to form TlF6 octahedra that share corners with six equivalent Ta(1)F6 octahedra and faces with eight equivalent Cs(1)F12 cuboctahedra. The corner-sharing octahedra are not tilted. F(1) is bonded in a distorted single-bond geometry to four equivalent Cs(1), one Ta(1), and one Tl(1) atom. is represented by the CIF file [CIF]
data_Cs2TaTlF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.693
_cell_length_b   6.693
_cell_length_c   6.693
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   212.020
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.750  0.750  0.750  1.0
  Cs  Cs1  1  0.250  0.250  0.250  1.0
  Ta  Ta2  1  0.000  0.000  0.000  1.0
  Tl  Tl3  1  0.500  0.500  0.500  1.0
  F  F4  1  0.781  0.219  0.219  1.0
  F  F5  1  0.219  0.219  0.781  1.0
  F  F6  1  0.219  0.781  0.781  1.0
  F  F7  1  0.219  0.781  0.219  1.0
  F  F8  1  0.781  0.219  0.781  1.0
  F  F9  1  0.781  0.781  0.219  1.0
[/CIF]
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The structure described by Cs2TaTlF6 crystallizes in the cubic Fm-3m space group. Cs(1) is bonded to twelve equivalent F(1) atoms to form CsF12 cuboctahedra that share corners with twelve equivalent Cs(1)F12 cuboctahedra, faces with six equivalent Cs(1)F12 cuboctahedra, faces with four equivalent Ta(1)F6 octahedra, and faces with four equivalent Tl(1)F6 octahedra. Ta(1) is bonded to six equivalent F(1) atoms to form TaF6 octahedra that share corners with six equivalent Tl(1)F6 octahedra and faces with eight equivalent Cs(1)F12 cuboctahedra. The corner-sharing octahedra are not tilted. Tl(1) is bonded to six equivalent F(1) atoms to form TlF6 octahedra that share corners with six equivalent Ta(1)F6 octahedra and faces with eight equivalent Cs(1)F12 cuboctahedra. The corner-sharing octahedra are not tilted. F(1) is bonded in a distorted single-bond geometry to four equivalent Cs(1), one Ta(1), and one Tl(1) atom. is represented by the CIF file [CIF]
data_Cs2TaTlF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.693
_cell_length_b   6.693
_cell_length_c   6.693
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   212.020
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.750  0.750  0.750  1.0
  Cs  Cs1  1  0.250  0.250  0.250  1.0
  Ta  Ta2  1  0.000  0.000  0.000  1.0
  Tl  Tl3  1  0.500  0.500  0.500  1.0
  F  F4  1  0.781  0.219  0.219  1.0
  F  F5  1  0.219  0.219  0.781  1.0
  F  F6  1  0.219  0.781  0.781  1.0
  F  F7  1  0.219  0.781  0.219  1.0
  F  F8  1  0.781  0.219  0.781  1.0
  F  F9  1  0.781  0.781  0.219  1.0
[/CIF]
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