The crystal structure described by SmOs2CP crystallizes in the orthorhombic Cmcm space group. Sm(1) is bonded in a 4-coordinate geometry to four equivalent C(1) and three equivalent P(1) atoms. Os(1) is bonded in a distorted single-bond geometry to one C(1) and three equivalent P(1) atoms. C(1) is bonded to four equivalent Sm(1) and two equivalent Os(1) atoms to form a mixture of corner and edge-sharing CSm4Os2 octahedra. The corner-sharing octahedral tilt angles are 22°. P(1) is bonded in a 9-coordinate geometry to three equivalent Sm(1) and six equivalent Os(1) atoms. is represented by the CIF card [CIF]
data_SmPOs2C
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.875
_cell_length_b   5.875
_cell_length_c   7.100
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   141.224
_symmetry_Int_Tables_number   1
_cell_volume   153.465
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sm  Sm0  1  0.545  0.455  0.250  1.0
  Sm  Sm1  1  0.455  0.545  0.750  1.0
  P  P2  1  0.269  0.731  0.250  1.0
  P  P3  1  0.731  0.269  0.750  1.0
  Os  Os4  1  0.833  0.167  0.053  1.0
  Os  Os5  1  0.167  0.833  0.947  1.0
  Os  Os6  1  0.167  0.833  0.553  1.0
  Os  Os7  1  0.833  0.167  0.447  1.0
  C  C8  1  0.000  0.000  0.000  1.0
  C  C9  1  0.000  0.000  0.500  1.0
[/CIF]
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The crystal structure described by SmOs2CP crystallizes in the orthorhombic Cmcm space group. Sm(1) is bonded in a 4-coordinate geometry to four equivalent C(1) and three equivalent P(1) atoms. Os(1) is bonded in a distorted single-bond geometry to one C(1) and three equivalent P(1) atoms. C(1) is bonded to four equivalent Sm(1) and two equivalent Os(1) atoms to form a mixture of corner and edge-sharing CSm4Os2 octahedra. The corner-sharing octahedral tilt angles are 22°. P(1) is bonded in a 9-coordinate geometry to three equivalent Sm(1) and six equivalent Os(1) atoms. is represented by the CIF card [CIF]
data_SmPOs2C
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.875
_cell_length_b   5.875
_cell_length_c   7.100
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   141.224
_symmetry_Int_Tables_number   1
_cell_volume   153.465
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sm  Sm0  1  0.545  0.455  0.250  1.0
  Sm  Sm1  1  0.455  0.545  0.750  1.0
  P  P2  1  0.269  0.731  0.250  1.0
  P  P3  1  0.731  0.269  0.750  1.0
  Os  Os4  1  0.833  0.167  0.053  1.0
  Os  Os5  1  0.167  0.833  0.947  1.0
  Os  Os6  1  0.167  0.833  0.553  1.0
  Os  Os7  1  0.833  0.167  0.447  1.0
  C  C8  1  0.000  0.000  0.000  1.0
  C  C9  1  0.000  0.000  0.500  1.0
[/CIF]
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