The compound described by Y3RhSi3 crystallizes in the monoclinic C2/m space group. There are three inequivalent Y sites. In the first Y site, Y(1) is bonded in a 7-coordinate geometry to two equivalent Si(1) and five equivalent Si(3) atoms. In the second Y site, Y(2) is bonded in a 10-coordinate geometry to four equivalent Rh(1), two equivalent Si(1), and four equivalent Si(2) atoms. In the third Y site, Y(3) is bonded in a 8-coordinate geometry to two equivalent Rh(1), one Si(2), two equivalent Si(3), and three equivalent Si(1) atoms. Rh(1) is bonded in a 10-coordinate geometry to two equivalent Y(3), four equivalent Y(2), one Si(1), and three equivalent Si(2) atoms. There are three inequivalent Si sites. In the first Si site, Si(1) is bonded in a 9-coordinate geometry to two equivalent Y(1), two equivalent Y(2), three equivalent Y(3), one Rh(1), and one Si(3) atom. In the second Si site, Si(2) is bonded in a 9-coordinate geometry to one Y(3), four equivalent Y(2), three equivalent Rh(1), and one Si(2) atom. In the third Si site, Si(3) is bonded in a 9-coordinate geometry to two equivalent Y(3), five equivalent Y(1), one Si(1), and one Si(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Y3Si3Rh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.698
_cell_length_b   5.698
_cell_length_c   13.565
_cell_angle_alpha   70.663
_cell_angle_beta   70.663
_cell_angle_gamma   43.525
_symmetry_Int_Tables_number   1
_cell_volume   283.368
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  1  0.602  0.602  0.079  1.0
  Y  Y1  1  0.398  0.398  0.921  1.0
  Y  Y2  1  0.522  0.522  0.624  1.0
  Y  Y3  1  0.478  0.478  0.376  1.0
  Y  Y4  1  0.257  0.257  0.228  1.0
  Y  Y5  1  0.743  0.743  0.772  1.0
  Si  Si6  1  0.952  0.952  0.237  1.0
  Si  Si7  1  0.048  0.048  0.763  1.0
  Si  Si8  1  0.868  0.868  0.544  1.0
  Si  Si9  1  0.132  0.132  0.456  1.0
  Si  Si10  1  0.113  0.113  0.924  1.0
  Si  Si11  1  0.887  0.887  0.076  1.0
  Rh  Rh12  1  0.753  0.753  0.416  1.0
  Rh  Rh13  1  0.247  0.247  0.584  1.0
[/CIF]
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The compound described by Y3RhSi3 crystallizes in the monoclinic C2/m space group. There are three inequivalent Y sites. In the first Y site, Y(1) is bonded in a 7-coordinate geometry to two equivalent Si(1) and five equivalent Si(3) atoms. In the second Y site, Y(2) is bonded in a 10-coordinate geometry to four equivalent Rh(1), two equivalent Si(1), and four equivalent Si(2) atoms. In the third Y site, Y(3) is bonded in a 8-coordinate geometry to two equivalent Rh(1), one Si(2), two equivalent Si(3), and three equivalent Si(1) atoms. Rh(1) is bonded in a 10-coordinate geometry to two equivalent Y(3), four equivalent Y(2), one Si(1), and three equivalent Si(2) atoms. There are three inequivalent Si sites. In the first Si site, Si(1) is bonded in a 9-coordinate geometry to two equivalent Y(1), two equivalent Y(2), three equivalent Y(3), one Rh(1), and one Si(3) atom. In the second Si site, Si(2) is bonded in a 9-coordinate geometry to one Y(3), four equivalent Y(2), three equivalent Rh(1), and one Si(2) atom. In the third Si site, Si(3) is bonded in a 9-coordinate geometry to two equivalent Y(3), five equivalent Y(1), one Si(1), and one Si(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Y3Si3Rh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.698
_cell_length_b   5.698
_cell_length_c   13.565
_cell_angle_alpha   70.663
_cell_angle_beta   70.663
_cell_angle_gamma   43.525
_symmetry_Int_Tables_number   1
_cell_volume   283.368
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  1  0.602  0.602  0.079  1.0
  Y  Y1  1  0.398  0.398  0.921  1.0
  Y  Y2  1  0.522  0.522  0.624  1.0
  Y  Y3  1  0.478  0.478  0.376  1.0
  Y  Y4  1  0.257  0.257  0.228  1.0
  Y  Y5  1  0.743  0.743  0.772  1.0
  Si  Si6  1  0.952  0.952  0.237  1.0
  Si  Si7  1  0.048  0.048  0.763  1.0
  Si  Si8  1  0.868  0.868  0.544  1.0
  Si  Si9  1  0.132  0.132  0.456  1.0
  Si  Si10  1  0.113  0.113  0.924  1.0
  Si  Si11  1  0.887  0.887  0.076  1.0
  Rh  Rh12  1  0.753  0.753  0.416  1.0
  Rh  Rh13  1  0.247  0.247  0.584  1.0
[/CIF]
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