The structure described by LiSb(PO3)4 crystallizes in the monoclinic C2/c space group. Li(1) is bonded in a 4-coordinate geometry to two equivalent O(4) and two equivalent O(5) atoms. Sb(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(5) atoms to form SbO6 octahedra that share corners with two equivalent P(2)O4 tetrahedra and corners with four equivalent P(1)O4 tetrahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(3), one O(5), and one O(6) atom to form PO4 tetrahedra that share corners with two equivalent Sb(1)O6 octahedra and corners with two equivalent P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 21-58°. In the second P site, P(2) is bonded to one O(2), one O(3), one O(4), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one Sb(1)O6 octahedra and corners with two equivalent P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 55°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Sb(1) and one P(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Sb(1) and one P(2) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one P(1) and one P(2) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Li(1) and one P(2) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Li(1), one Sb(1), and one P(1) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one P(1) and one P(2) atom. is represented by the CIF card [CIF]
data_LiSb(PO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.644
_cell_length_b   7.644
_cell_length_c   10.811
_cell_angle_alpha   65.265
_cell_angle_beta   65.265
_cell_angle_gamma   69.127
_symmetry_Int_Tables_number   1
_cell_volume   508.359
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.995  0.005  0.250  1.0
  Li  Li1  1  0.005  0.995  0.750  1.0
  Sb  Sb2  1  0.000  0.500  0.500  1.0
  Sb  Sb3  1  0.500  0.000  0.000  1.0
  P  P4  1  0.694  0.681  0.811  1.0
  P  P5  1  0.254  0.726  0.978  1.0
  P  P6  1  0.274  0.746  0.522  1.0
  P  P7  1  0.681  0.694  0.311  1.0
  P  P8  1  0.319  0.306  0.689  1.0
  P  P9  1  0.726  0.254  0.478  1.0
  P  P10  1  0.746  0.274  0.022  1.0
  P  P11  1  0.306  0.319  0.189  1.0
  O  O12  1  0.792  0.648  0.667  1.0
  O  O13  1  0.286  0.804  0.074  1.0
  O  O14  1  0.465  0.684  0.854  1.0
  O  O15  1  0.099  0.833  0.910  1.0
  O  O16  1  0.863  0.718  0.321  1.0
  O  O17  1  0.226  0.502  0.068  1.0
  O  O18  1  0.804  0.286  0.574  1.0
  O  O19  1  0.167  0.901  0.590  1.0
  O  O20  1  0.498  0.774  0.432  1.0
  O  O21  1  0.648  0.792  0.167  1.0
  O  O22  1  0.316  0.535  0.646  1.0
  O  O23  1  0.282  0.137  0.179  1.0
  O  O24  1  0.718  0.863  0.821  1.0
  O  O25  1  0.684  0.465  0.354  1.0
  O  O26  1  0.352  0.208  0.833  1.0
  O  O27  1  0.502  0.226  0.568  1.0
  O  O28  1  0.833  0.099  0.410  1.0
  O  O29  1  0.196  0.714  0.426  1.0
  O  O30  1  0.774  0.498  0.932  1.0
  O  O31  1  0.137  0.282  0.679  1.0
  O  O32  1  0.901  0.167  0.090  1.0
  O  O33  1  0.535  0.316  0.146  1.0
  O  O34  1  0.714  0.196  0.926  1.0
  O  O35  1  0.208  0.352  0.333  1.0
[/CIF]
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The structure described by LiSb(PO3)4 crystallizes in the monoclinic C2/c space group. Li(1) is bonded in a 4-coordinate geometry to two equivalent O(4) and two equivalent O(5) atoms. Sb(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(5) atoms to form SbO6 octahedra that share corners with two equivalent P(2)O4 tetrahedra and corners with four equivalent P(1)O4 tetrahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(3), one O(5), and one O(6) atom to form PO4 tetrahedra that share corners with two equivalent Sb(1)O6 octahedra and corners with two equivalent P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 21-58°. In the second P site, P(2) is bonded to one O(2), one O(3), one O(4), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one Sb(1)O6 octahedra and corners with two equivalent P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 55°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Sb(1) and one P(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Sb(1) and one P(2) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one P(1) and one P(2) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Li(1) and one P(2) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Li(1), one Sb(1), and one P(1) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one P(1) and one P(2) atom. is represented by the CIF card [CIF]
data_LiSb(PO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.644
_cell_length_b   7.644
_cell_length_c   10.811
_cell_angle_alpha   65.265
_cell_angle_beta   65.265
_cell_angle_gamma   69.127
_symmetry_Int_Tables_number   1
_cell_volume   508.359
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.995  0.005  0.250  1.0
  Li  Li1  1  0.005  0.995  0.750  1.0
  Sb  Sb2  1  0.000  0.500  0.500  1.0
  Sb  Sb3  1  0.500  0.000  0.000  1.0
  P  P4  1  0.694  0.681  0.811  1.0
  P  P5  1  0.254  0.726  0.978  1.0
  P  P6  1  0.274  0.746  0.522  1.0
  P  P7  1  0.681  0.694  0.311  1.0
  P  P8  1  0.319  0.306  0.689  1.0
  P  P9  1  0.726  0.254  0.478  1.0
  P  P10  1  0.746  0.274  0.022  1.0
  P  P11  1  0.306  0.319  0.189  1.0
  O  O12  1  0.792  0.648  0.667  1.0
  O  O13  1  0.286  0.804  0.074  1.0
  O  O14  1  0.465  0.684  0.854  1.0
  O  O15  1  0.099  0.833  0.910  1.0
  O  O16  1  0.863  0.718  0.321  1.0
  O  O17  1  0.226  0.502  0.068  1.0
  O  O18  1  0.804  0.286  0.574  1.0
  O  O19  1  0.167  0.901  0.590  1.0
  O  O20  1  0.498  0.774  0.432  1.0
  O  O21  1  0.648  0.792  0.167  1.0
  O  O22  1  0.316  0.535  0.646  1.0
  O  O23  1  0.282  0.137  0.179  1.0
  O  O24  1  0.718  0.863  0.821  1.0
  O  O25  1  0.684  0.465  0.354  1.0
  O  O26  1  0.352  0.208  0.833  1.0
  O  O27  1  0.502  0.226  0.568  1.0
  O  O28  1  0.833  0.099  0.410  1.0
  O  O29  1  0.196  0.714  0.426  1.0
  O  O30  1  0.774  0.498  0.932  1.0
  O  O31  1  0.137  0.282  0.679  1.0
  O  O32  1  0.901  0.167  0.090  1.0
  O  O33  1  0.535  0.316  0.146  1.0
  O  O34  1  0.714  0.196  0.926  1.0
  O  O35  1  0.208  0.352  0.333  1.0
[/CIF]
.