The material described by Rb2Th(MoO4)3 is Zircon-derived structured and crystallizes in the monoclinic C2/c space group. Rb(1) is bonded in a 8-coordinate geometry to one O(2), one O(3), two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms. Th(1) is bonded in a 8-coordinate geometry to two equivalent O(2), two equivalent O(3), and four equivalent O(1) atoms. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a tetrahedral geometry to two equivalent O(3) and two equivalent O(6) atoms. In the second Mo site, Mo(2) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(4), and one O(5) atom. There are six inequivalent O sites. In the first O site, O(3) is bonded in a 3-coordinate geometry to one Rb(1), one Th(1), and one Mo(1) atom. In the second O site, O(4) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one Mo(2) atom. In the third O site, O(5) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one Mo(2) atom. In the fourth O site, O(6) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one Mo(1) atom. In the fifth O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent Th(1) and one Mo(2) atom. In the sixth O site, O(2) is bonded in a 3-coordinate geometry to one Rb(1), one Th(1), and one Mo(2) atom. is represented by the CIF card [CIF]
data_Rb2Th(MoO4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.210
_cell_length_b   11.210
_cell_length_c   5.475
_cell_angle_alpha   77.706
_cell_angle_beta   77.706
_cell_angle_gamma   69.228
_symmetry_Int_Tables_number   1
_cell_volume   621.449
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.544  0.789  0.071  1.0
  Rb  Rb1  1  0.211  0.456  0.429  1.0
  Rb  Rb2  1  0.456  0.211  0.929  1.0
  Rb  Rb3  1  0.789  0.544  0.571  1.0
  Th  Th4  1  0.124  0.876  0.250  1.0
  Th  Th5  1  0.876  0.124  0.750  1.0
  Mo  Mo6  1  0.345  0.655  0.750  1.0
  Mo  Mo7  1  0.655  0.345  0.250  1.0
  Mo  Mo8  1  0.256  0.046  0.605  1.0
  Mo  Mo9  1  0.954  0.744  0.895  1.0
  Mo  Mo10  1  0.744  0.954  0.395  1.0
  Mo  Mo11  1  0.046  0.256  0.105  1.0
  O  O12  1  0.110  0.031  0.854  1.0
  O  O13  1  0.969  0.890  0.646  1.0
  O  O14  1  0.890  0.969  0.146  1.0
  O  O15  1  0.031  0.110  0.354  1.0
  O  O16  1  0.284  0.927  0.399  1.0
  O  O17  1  0.073  0.716  0.101  1.0
  O  O18  1  0.716  0.073  0.601  1.0
  O  O19  1  0.927  0.284  0.899  1.0
  O  O20  1  0.226  0.698  0.532  1.0
  O  O21  1  0.302  0.774  0.968  1.0
  O  O22  1  0.774  0.302  0.468  1.0
  O  O23  1  0.698  0.226  0.032  1.0
  O  O24  1  0.395  0.008  0.742  1.0
  O  O25  1  0.992  0.605  0.758  1.0
  O  O26  1  0.605  0.992  0.258  1.0
  O  O27  1  0.008  0.395  0.242  1.0
  O  O28  1  0.241  0.193  0.399  1.0
  O  O29  1  0.807  0.759  0.101  1.0
  O  O30  1  0.759  0.807  0.601  1.0
  O  O31  1  0.193  0.241  0.899  1.0
  O  O32  1  0.499  0.646  0.581  1.0
  O  O33  1  0.354  0.501  0.919  1.0
  O  O34  1  0.501  0.354  0.419  1.0
  O  O35  1  0.646  0.499  0.081  1.0
[/CIF]
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The material described by Rb2Th(MoO4)3 is Zircon-derived structured and crystallizes in the monoclinic C2/c space group. Rb(1) is bonded in a 8-coordinate geometry to one O(2), one O(3), two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms. Th(1) is bonded in a 8-coordinate geometry to two equivalent O(2), two equivalent O(3), and four equivalent O(1) atoms. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a tetrahedral geometry to two equivalent O(3) and two equivalent O(6) atoms. In the second Mo site, Mo(2) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(4), and one O(5) atom. There are six inequivalent O sites. In the first O site, O(3) is bonded in a 3-coordinate geometry to one Rb(1), one Th(1), and one Mo(1) atom. In the second O site, O(4) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one Mo(2) atom. In the third O site, O(5) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one Mo(2) atom. In the fourth O site, O(6) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one Mo(1) atom. In the fifth O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent Th(1) and one Mo(2) atom. In the sixth O site, O(2) is bonded in a 3-coordinate geometry to one Rb(1), one Th(1), and one Mo(2) atom. is represented by the CIF card [CIF]
data_Rb2Th(MoO4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.210
_cell_length_b   11.210
_cell_length_c   5.475
_cell_angle_alpha   77.706
_cell_angle_beta   77.706
_cell_angle_gamma   69.228
_symmetry_Int_Tables_number   1
_cell_volume   621.449
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.544  0.789  0.071  1.0
  Rb  Rb1  1  0.211  0.456  0.429  1.0
  Rb  Rb2  1  0.456  0.211  0.929  1.0
  Rb  Rb3  1  0.789  0.544  0.571  1.0
  Th  Th4  1  0.124  0.876  0.250  1.0
  Th  Th5  1  0.876  0.124  0.750  1.0
  Mo  Mo6  1  0.345  0.655  0.750  1.0
  Mo  Mo7  1  0.655  0.345  0.250  1.0
  Mo  Mo8  1  0.256  0.046  0.605  1.0
  Mo  Mo9  1  0.954  0.744  0.895  1.0
  Mo  Mo10  1  0.744  0.954  0.395  1.0
  Mo  Mo11  1  0.046  0.256  0.105  1.0
  O  O12  1  0.110  0.031  0.854  1.0
  O  O13  1  0.969  0.890  0.646  1.0
  O  O14  1  0.890  0.969  0.146  1.0
  O  O15  1  0.031  0.110  0.354  1.0
  O  O16  1  0.284  0.927  0.399  1.0
  O  O17  1  0.073  0.716  0.101  1.0
  O  O18  1  0.716  0.073  0.601  1.0
  O  O19  1  0.927  0.284  0.899  1.0
  O  O20  1  0.226  0.698  0.532  1.0
  O  O21  1  0.302  0.774  0.968  1.0
  O  O22  1  0.774  0.302  0.468  1.0
  O  O23  1  0.698  0.226  0.032  1.0
  O  O24  1  0.395  0.008  0.742  1.0
  O  O25  1  0.992  0.605  0.758  1.0
  O  O26  1  0.605  0.992  0.258  1.0
  O  O27  1  0.008  0.395  0.242  1.0
  O  O28  1  0.241  0.193  0.399  1.0
  O  O29  1  0.807  0.759  0.101  1.0
  O  O30  1  0.759  0.807  0.601  1.0
  O  O31  1  0.193  0.241  0.899  1.0
  O  O32  1  0.499  0.646  0.581  1.0
  O  O33  1  0.354  0.501  0.919  1.0
  O  O34  1  0.501  0.354  0.419  1.0
  O  O35  1  0.646  0.499  0.081  1.0
[/CIF]
.