The compound described by C3OCl2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two chloranil molecules. There are three inequivalent C sites. In the first C site, C(1) is bonded in a single-bond geometry to one C(2), one C(3), and one O(1) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one Cl(2) atom. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(1), one C(2), and one Cl(1) atom. O(1) is bonded in a single-bond geometry to one C(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one C(3) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one C(2) atom. is represented by the CIF card [CIF]
data_C3Cl2O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.886
_cell_length_b   8.863
_cell_length_c   9.242
_cell_angle_alpha   72.608
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   460.132
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  C  C0  1  0.296  0.996  0.591  1.0
  C  C1  1  0.704  0.004  0.409  1.0
  C  C2  1  0.796  0.004  0.909  1.0
  C  C3  1  0.204  0.996  0.091  1.0
  C  C4  1  0.905  0.851  0.995  1.0
  C  C5  1  0.095  0.149  0.005  1.0
  C  C6  1  0.405  0.149  0.505  1.0
  C  C7  1  0.595  0.851  0.495  1.0
  C  C8  1  0.408  0.848  0.582  1.0
  C  C9  1  0.592  0.152  0.418  1.0
  C  C10  1  0.908  0.152  0.918  1.0
  C  C11  1  0.092  0.848  0.082  1.0
  Cl  Cl12  1  0.285  0.677  0.687  1.0
  Cl  Cl13  1  0.715  0.323  0.313  1.0
  Cl  Cl14  1  0.785  0.323  0.813  1.0
  Cl  Cl15  1  0.215  0.677  0.187  1.0
  Cl  Cl16  1  0.280  0.316  0.522  1.0
  Cl  Cl17  1  0.720  0.684  0.478  1.0
  Cl  Cl18  1  0.780  0.684  0.978  1.0
  Cl  Cl19  1  0.220  0.316  0.022  1.0
  O  O20  1  0.120  0.993  0.663  1.0
  O  O21  1  0.880  0.007  0.337  1.0
  O  O22  1  0.620  0.007  0.837  1.0
  O  O23  1  0.380  0.993  0.163  1.0
[/CIF]
.
The compound described by C3OCl2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two chloranil molecules. There are three inequivalent C sites. In the first C site, C(1) is bonded in a single-bond geometry to one C(2), one C(3), and one O(1) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one Cl(2) atom. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(1), one C(2), and one Cl(1) atom. O(1) is bonded in a single-bond geometry to one C(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one C(3) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one C(2) atom. is represented by the CIF card [CIF]
data_C3Cl2O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.886
_cell_length_b   8.863
_cell_length_c   9.242
_cell_angle_alpha   72.608
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   460.132
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  C  C0  1  0.296  0.996  0.591  1.0
  C  C1  1  0.704  0.004  0.409  1.0
  C  C2  1  0.796  0.004  0.909  1.0
  C  C3  1  0.204  0.996  0.091  1.0
  C  C4  1  0.905  0.851  0.995  1.0
  C  C5  1  0.095  0.149  0.005  1.0
  C  C6  1  0.405  0.149  0.505  1.0
  C  C7  1  0.595  0.851  0.495  1.0
  C  C8  1  0.408  0.848  0.582  1.0
  C  C9  1  0.592  0.152  0.418  1.0
  C  C10  1  0.908  0.152  0.918  1.0
  C  C11  1  0.092  0.848  0.082  1.0
  Cl  Cl12  1  0.285  0.677  0.687  1.0
  Cl  Cl13  1  0.715  0.323  0.313  1.0
  Cl  Cl14  1  0.785  0.323  0.813  1.0
  Cl  Cl15  1  0.215  0.677  0.187  1.0
  Cl  Cl16  1  0.280  0.316  0.522  1.0
  Cl  Cl17  1  0.720  0.684  0.478  1.0
  Cl  Cl18  1  0.780  0.684  0.978  1.0
  Cl  Cl19  1  0.220  0.316  0.022  1.0
  O  O20  1  0.120  0.993  0.663  1.0
  O  O21  1  0.880  0.007  0.337  1.0
  O  O22  1  0.620  0.007  0.837  1.0
  O  O23  1  0.380  0.993  0.163  1.0
[/CIF]
.