The material structure described by KC2PH5S2(NO)3 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one KC2PH5S2(NO)3 cluster. K(1) is bonded in a 3-coordinate geometry to one O(1), one O(2), and one O(3) atom. There are two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(3), and one O(1) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(2), one N(3), and one O(3) atom. P(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one S(1), and one S(2) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one P(1), and one H(1) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(2), one P(1), and one H(2) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(1), one C(2), and one H(3) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(2) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted single-bond geometry to one P(1) atom. In the second S site, S(2) is bonded in a single-bond geometry to one P(1) atom. There are three inequivalent O sites. In the first O site, O(3) is bonded in a distorted single-bond geometry to one K(1) and one C(2) atom. In the second O site, O(1) is bonded in a distorted single-bond geometry to one K(1) and one C(1) atom. In the third O site, O(2) is bonded in a water-like geometry to one K(1), one H(4), and one H(5) atom. is represented by the CIF card [CIF]
data_KPH5C2S2(NO)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.761
_cell_length_b   7.028
_cell_length_c   10.513
_cell_angle_alpha   89.988
_cell_angle_beta   101.675
_cell_angle_gamma   96.182
_symmetry_Int_Tables_number   1
_cell_volume   486.258
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.666  0.641  0.289  1.0
  K  K1  1  0.334  0.359  0.711  1.0
  P  P2  1  0.092  0.197  0.262  1.0
  P  P3  1  0.908  0.803  0.738  1.0
  H  H4  1  0.155  0.873  0.271  1.0
  H  H5  1  0.845  0.127  0.729  1.0
  H  H6  1  0.968  0.411  0.095  1.0
  H  H7  1  0.032  0.589  0.905  1.0
  H  H8  1  0.421  0.143  0.990  1.0
  H  H9  1  0.579  0.857  0.010  1.0
  H  H10  1  0.155  0.589  0.392  1.0
  H  H11  1  0.845  0.411  0.608  1.0
  H  H12  1  0.106  0.756  0.476  1.0
  H  H13  1  0.894  0.244  0.524  1.0
  C  C14  1  0.300  0.987  0.129  1.0
  C  C15  1  0.700  0.013  0.871  1.0
  C  C16  1  0.193  0.291  0.030  1.0
  C  C17  1  0.807  0.709  0.970  1.0
  S  S18  1  0.321  0.334  0.391  1.0
  S  S19  1  0.679  0.666  0.609  1.0
  S  S20  1  0.824  0.151  0.309  1.0
  S  S21  1  0.176  0.849  0.691  1.0
  N  N22  1  0.169  0.990  0.211  1.0
  N  N23  1  0.831  0.010  0.789  1.0
  N  N24  1  0.067  0.306  0.115  1.0
  N  N25  1  0.933  0.694  0.885  1.0
  N  N26  1  0.318  0.145  0.051  1.0
  N  N27  1  0.682  0.855  0.949  1.0
  O  O28  1  0.399  0.849  0.120  1.0
  O  O29  1  0.601  0.151  0.880  1.0
  O  O30  1  0.083  0.705  0.386  1.0
  O  O31  1  0.917  0.295  0.614  1.0
  O  O32  1  0.801  0.600  0.063  1.0
  O  O33  1  0.199  0.400  0.937  1.0
[/CIF]
.
The material structure described by KC2PH5S2(NO)3 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one KC2PH5S2(NO)3 cluster. K(1) is bonded in a 3-coordinate geometry to one O(1), one O(2), and one O(3) atom. There are two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(3), and one O(1) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(2), one N(3), and one O(3) atom. P(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one S(1), and one S(2) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one P(1), and one H(1) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(2), one P(1), and one H(2) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(1), one C(2), and one H(3) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(2) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted single-bond geometry to one P(1) atom. In the second S site, S(2) is bonded in a single-bond geometry to one P(1) atom. There are three inequivalent O sites. In the first O site, O(3) is bonded in a distorted single-bond geometry to one K(1) and one C(2) atom. In the second O site, O(1) is bonded in a distorted single-bond geometry to one K(1) and one C(1) atom. In the third O site, O(2) is bonded in a water-like geometry to one K(1), one H(4), and one H(5) atom. is represented by the CIF card [CIF]
data_KPH5C2S2(NO)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.761
_cell_length_b   7.028
_cell_length_c   10.513
_cell_angle_alpha   89.988
_cell_angle_beta   101.675
_cell_angle_gamma   96.182
_symmetry_Int_Tables_number   1
_cell_volume   486.258
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.666  0.641  0.289  1.0
  K  K1  1  0.334  0.359  0.711  1.0
  P  P2  1  0.092  0.197  0.262  1.0
  P  P3  1  0.908  0.803  0.738  1.0
  H  H4  1  0.155  0.873  0.271  1.0
  H  H5  1  0.845  0.127  0.729  1.0
  H  H6  1  0.968  0.411  0.095  1.0
  H  H7  1  0.032  0.589  0.905  1.0
  H  H8  1  0.421  0.143  0.990  1.0
  H  H9  1  0.579  0.857  0.010  1.0
  H  H10  1  0.155  0.589  0.392  1.0
  H  H11  1  0.845  0.411  0.608  1.0
  H  H12  1  0.106  0.756  0.476  1.0
  H  H13  1  0.894  0.244  0.524  1.0
  C  C14  1  0.300  0.987  0.129  1.0
  C  C15  1  0.700  0.013  0.871  1.0
  C  C16  1  0.193  0.291  0.030  1.0
  C  C17  1  0.807  0.709  0.970  1.0
  S  S18  1  0.321  0.334  0.391  1.0
  S  S19  1  0.679  0.666  0.609  1.0
  S  S20  1  0.824  0.151  0.309  1.0
  S  S21  1  0.176  0.849  0.691  1.0
  N  N22  1  0.169  0.990  0.211  1.0
  N  N23  1  0.831  0.010  0.789  1.0
  N  N24  1  0.067  0.306  0.115  1.0
  N  N25  1  0.933  0.694  0.885  1.0
  N  N26  1  0.318  0.145  0.051  1.0
  N  N27  1  0.682  0.855  0.949  1.0
  O  O28  1  0.399  0.849  0.120  1.0
  O  O29  1  0.601  0.151  0.880  1.0
  O  O30  1  0.083  0.705  0.386  1.0
  O  O31  1  0.917  0.295  0.614  1.0
  O  O32  1  0.801  0.600  0.063  1.0
  O  O33  1  0.199  0.400  0.937  1.0
[/CIF]
.