The material structure described by Cs8Na4Ho3YCl24 is (Cubic) Perovskite-derived structured and crystallizes in the trigonal R-3m space group. There are four inequivalent Cs sites. In the first Cs site, Cs(1) is bonded to three equivalent Cl(4) and nine equivalent Cl(1) atoms to form CsCl12 cuboctahedra that share corners with three equivalent Cs(2)Cl12 cuboctahedra, corners with three equivalent Cs(4)Cl12 cuboctahedra, corners with six equivalent Cs(1)Cl12 cuboctahedra, faces with three equivalent Cs(1)Cl12 cuboctahedra, faces with three equivalent Cs(4)Cl12 cuboctahedra,  a faceface with one Ho(1)Cl6 octahedra, faces with three equivalent Ho(2)Cl6 octahedra, and faces with four equivalent Na(1)Cl6 octahedra. In the second Cs site, Cs(2) is bonded to three equivalent Cl(3), three equivalent Cl(4), and six equivalent Cl(2) atoms to form CsCl12 cuboctahedra that share corners with three equivalent Cs(1)Cl12 cuboctahedra, corners with three equivalent Cs(3)Cl12 cuboctahedra, corners with six equivalent Cs(2)Cl12 cuboctahedra, faces with three equivalent Cs(3)Cl12 cuboctahedra, faces with three equivalent Cs(4)Cl12 cuboctahedra,  a faceface with one Na(1)Cl6 octahedra,  a faceface with one Y(1)Cl6 octahedra, faces with three equivalent Na(2)Cl6 octahedra, and faces with three equivalent Ho(1)Cl6 octahedra. In the third Cs site, Cs(3) is bonded to three equivalent Cl(2) and nine equivalent Cl(3) atoms to form CsCl12 cuboctahedra that share corners with three equivalent Cs(2)Cl12 cuboctahedra, corners with three equivalent Cs(4)Cl12 cuboctahedra, corners with six equivalent Cs(3)Cl12 cuboctahedra, faces with three equivalent Cs(2)Cl12 cuboctahedra, faces with three equivalent Cs(3)Cl12 cuboctahedra,  a faceface with one Ho(1)Cl6 octahedra, faces with three equivalent Y(1)Cl6 octahedra, and faces with four equivalent Na(2)Cl6 octahedra. In the fourth Cs site, Cs(4) is bonded to three equivalent Cl(1), three equivalent Cl(2), and six equivalent Cl(4) atoms to form CsCl12 cuboctahedra that share corners with three equivalent Cs(1)Cl12 cuboctahedra, corners with three equivalent Cs(3)Cl12 cuboctahedra, corners with six equivalent Cs(4)Cl12 cuboctahedra, faces with three equivalent Cs(1)Cl12 cuboctahedra, faces with three equivalent Cs(2)Cl12 cuboctahedra,  a faceface with one Na(2)Cl6 octahedra,  a faceface with one Ho(2)Cl6 octahedra, faces with three equivalent Na(1)Cl6 octahedra, and faces with three equivalent Ho(1)Cl6 octahedra. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded to three equivalent Cl(1) and three equivalent Cl(4) atoms to form NaCl6 octahedra that share corners with three equivalent Ho(1)Cl6 octahedra, corners with three equivalent Ho(2)Cl6 octahedra,  a faceface with one Cs(2)Cl12 cuboctahedra, faces with three equivalent Cs(4)Cl12 cuboctahedra, and faces with four equivalent Cs(1)Cl12 cuboctahedra. The corner-sharing octahedra are not tilted. In the second Na site, Na(2) is bonded to three equivalent Cl(2) and three equivalent Cl(3) atoms to form NaCl6 octahedra that share corners with three equivalent Ho(1)Cl6 octahedra, corners with three equivalent Y(1)Cl6 octahedra,  a faceface with one Cs(4)Cl12 cuboctahedra, faces with three equivalent Cs(2)Cl12 cuboctahedra, and faces with four equivalent Cs(3)Cl12 cuboctahedra. The corner-sharing octahedra are not tilted. There are two inequivalent Ho sites. In the first Ho site, Ho(1) is bonded to three equivalent Cl(2) and three equivalent Cl(4) atoms to form HoCl6 octahedra that share corners with three equivalent Na(1)Cl6 octahedra, corners with three equivalent Na(2)Cl6 octahedra,  a faceface with one Cs(1)Cl12 cuboctahedra,  a faceface with one Cs(3)Cl12 cuboctahedra, faces with three equivalent Cs(2)Cl12 cuboctahedra, and faces with three equivalent Cs(4)Cl12 cuboctahedra. The corner-sharing octahedra are not tilted. In the second Ho site, Ho(2) is bonded to six equivalent Cl(1) atoms to form HoCl6 octahedra that share corners with six equivalent Na(1)Cl6 octahedra, faces with two equivalent Cs(4)Cl12 cuboctahedra, and faces with six equivalent Cs(1)Cl12 cuboctahedra. The corner-sharing octahedra are not tilted. Y(1) is bonded to six equivalent Cl(3) atoms to form YCl6 octahedra that share corners with six equivalent Na(2)Cl6 octahedra, faces with two equivalent Cs(2)Cl12 cuboctahedra, and faces with six equivalent Cs(3)Cl12 cuboctahedra. The corner-sharing octahedra are not tilted. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted linear geometry to one Cs(4), three equivalent Cs(1), one Na(1), and one Ho(2) atom. In the second Cl site, Cl(2) is bonded in a distorted linear geometry to one Cs(3), one Cs(4), two equivalent Cs(2), one Na(2), and one Ho(1) atom. In the third Cl site, Cl(3) is bonded in a distorted linear geometry to one Cs(2), three equivalent Cs(3), one Na(2), and one Y(1) atom. In the fourth Cl site, Cl(4) is bonded in a distorted linear geometry to one Cs(1), one Cs(2), two equivalent Cs(4), one Na(1), and one Ho(1) atom. is represented by the CIF card [CIF]
data_Cs8Na4YHo3Cl24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.709
_cell_length_b   7.709
_cell_length_c   25.568
_cell_angle_alpha   90.000
_cell_angle_beta   81.329
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   1295.949
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.625  0.813  0.562  1.0
  Cs  Cs1  1  0.125  0.063  0.812  1.0
  Cs  Cs2  1  0.625  0.312  0.063  1.0
  Cs  Cs3  1  0.125  0.563  0.312  1.0
  Cs  Cs4  1  0.875  0.437  0.688  1.0
  Cs  Cs5  1  0.375  0.688  0.937  1.0
  Cs  Cs6  1  0.875  0.937  0.188  1.0
  Cs  Cs7  1  0.375  0.187  0.438  1.0
  Na  Na8  1  0.250  0.125  0.625  1.0
  Na  Na9  1  0.750  0.375  0.875  1.0
  Na  Na10  1  0.250  0.625  0.125  1.0
  Na  Na11  1  0.750  0.875  0.375  1.0
  Y  Y12  1  0.000  0.000  0.000  1.0
  Ho  Ho13  1  0.500  0.250  0.250  1.0
  Ho  Ho14  1  0.000  0.500  0.500  1.0
  Ho  Ho15  1  0.500  0.750  0.750  1.0
  Cl  Cl16  1  0.121  0.802  0.560  1.0
  Cl  Cl17  1  0.621  0.052  0.810  1.0
  Cl  Cl18  1  0.121  0.304  0.061  1.0
  Cl  Cl19  1  0.621  0.552  0.310  1.0
  Cl  Cl20  1  0.379  0.931  0.690  1.0
  Cl  Cl21  1  0.879  0.182  0.939  1.0
  Cl  Cl22  1  0.379  0.431  0.190  1.0
  Cl  Cl23  1  0.879  0.681  0.440  1.0
  Cl  Cl24  1  0.638  0.319  0.560  1.0
  Cl  Cl25  1  0.138  0.569  0.810  1.0
  Cl  Cl26  1  0.636  0.818  0.061  1.0
  Cl  Cl27  1  0.138  0.069  0.310  1.0
  Cl  Cl28  1  0.379  0.448  0.690  1.0
  Cl  Cl29  1  0.879  0.696  0.939  1.0
  Cl  Cl30  1  0.379  0.948  0.190  1.0
  Cl  Cl31  1  0.879  0.198  0.440  1.0
  Cl  Cl32  1  0.121  0.319  0.560  1.0
  Cl  Cl33  1  0.621  0.569  0.810  1.0
  Cl  Cl34  1  0.121  0.818  0.061  1.0
  Cl  Cl35  1  0.621  0.069  0.310  1.0
  Cl  Cl36  1  0.862  0.931  0.690  1.0
  Cl  Cl37  1  0.364  0.182  0.939  1.0
  Cl  Cl38  1  0.862  0.431  0.190  1.0
  Cl  Cl39  1  0.362  0.681  0.440  1.0
[/CIF]
.
The material structure described by Cs8Na4Ho3YCl24 is (Cubic) Perovskite-derived structured and crystallizes in the trigonal R-3m space group. There are four inequivalent Cs sites. In the first Cs site, Cs(1) is bonded to three equivalent Cl(4) and nine equivalent Cl(1) atoms to form CsCl12 cuboctahedra that share corners with three equivalent Cs(2)Cl12 cuboctahedra, corners with three equivalent Cs(4)Cl12 cuboctahedra, corners with six equivalent Cs(1)Cl12 cuboctahedra, faces with three equivalent Cs(1)Cl12 cuboctahedra, faces with three equivalent Cs(4)Cl12 cuboctahedra,  a faceface with one Ho(1)Cl6 octahedra, faces with three equivalent Ho(2)Cl6 octahedra, and faces with four equivalent Na(1)Cl6 octahedra. In the second Cs site, Cs(2) is bonded to three equivalent Cl(3), three equivalent Cl(4), and six equivalent Cl(2) atoms to form CsCl12 cuboctahedra that share corners with three equivalent Cs(1)Cl12 cuboctahedra, corners with three equivalent Cs(3)Cl12 cuboctahedra, corners with six equivalent Cs(2)Cl12 cuboctahedra, faces with three equivalent Cs(3)Cl12 cuboctahedra, faces with three equivalent Cs(4)Cl12 cuboctahedra,  a faceface with one Na(1)Cl6 octahedra,  a faceface with one Y(1)Cl6 octahedra, faces with three equivalent Na(2)Cl6 octahedra, and faces with three equivalent Ho(1)Cl6 octahedra. In the third Cs site, Cs(3) is bonded to three equivalent Cl(2) and nine equivalent Cl(3) atoms to form CsCl12 cuboctahedra that share corners with three equivalent Cs(2)Cl12 cuboctahedra, corners with three equivalent Cs(4)Cl12 cuboctahedra, corners with six equivalent Cs(3)Cl12 cuboctahedra, faces with three equivalent Cs(2)Cl12 cuboctahedra, faces with three equivalent Cs(3)Cl12 cuboctahedra,  a faceface with one Ho(1)Cl6 octahedra, faces with three equivalent Y(1)Cl6 octahedra, and faces with four equivalent Na(2)Cl6 octahedra. In the fourth Cs site, Cs(4) is bonded to three equivalent Cl(1), three equivalent Cl(2), and six equivalent Cl(4) atoms to form CsCl12 cuboctahedra that share corners with three equivalent Cs(1)Cl12 cuboctahedra, corners with three equivalent Cs(3)Cl12 cuboctahedra, corners with six equivalent Cs(4)Cl12 cuboctahedra, faces with three equivalent Cs(1)Cl12 cuboctahedra, faces with three equivalent Cs(2)Cl12 cuboctahedra,  a faceface with one Na(2)Cl6 octahedra,  a faceface with one Ho(2)Cl6 octahedra, faces with three equivalent Na(1)Cl6 octahedra, and faces with three equivalent Ho(1)Cl6 octahedra. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded to three equivalent Cl(1) and three equivalent Cl(4) atoms to form NaCl6 octahedra that share corners with three equivalent Ho(1)Cl6 octahedra, corners with three equivalent Ho(2)Cl6 octahedra,  a faceface with one Cs(2)Cl12 cuboctahedra, faces with three equivalent Cs(4)Cl12 cuboctahedra, and faces with four equivalent Cs(1)Cl12 cuboctahedra. The corner-sharing octahedra are not tilted. In the second Na site, Na(2) is bonded to three equivalent Cl(2) and three equivalent Cl(3) atoms to form NaCl6 octahedra that share corners with three equivalent Ho(1)Cl6 octahedra, corners with three equivalent Y(1)Cl6 octahedra,  a faceface with one Cs(4)Cl12 cuboctahedra, faces with three equivalent Cs(2)Cl12 cuboctahedra, and faces with four equivalent Cs(3)Cl12 cuboctahedra. The corner-sharing octahedra are not tilted. There are two inequivalent Ho sites. In the first Ho site, Ho(1) is bonded to three equivalent Cl(2) and three equivalent Cl(4) atoms to form HoCl6 octahedra that share corners with three equivalent Na(1)Cl6 octahedra, corners with three equivalent Na(2)Cl6 octahedra,  a faceface with one Cs(1)Cl12 cuboctahedra,  a faceface with one Cs(3)Cl12 cuboctahedra, faces with three equivalent Cs(2)Cl12 cuboctahedra, and faces with three equivalent Cs(4)Cl12 cuboctahedra. The corner-sharing octahedra are not tilted. In the second Ho site, Ho(2) is bonded to six equivalent Cl(1) atoms to form HoCl6 octahedra that share corners with six equivalent Na(1)Cl6 octahedra, faces with two equivalent Cs(4)Cl12 cuboctahedra, and faces with six equivalent Cs(1)Cl12 cuboctahedra. The corner-sharing octahedra are not tilted. Y(1) is bonded to six equivalent Cl(3) atoms to form YCl6 octahedra that share corners with six equivalent Na(2)Cl6 octahedra, faces with two equivalent Cs(2)Cl12 cuboctahedra, and faces with six equivalent Cs(3)Cl12 cuboctahedra. The corner-sharing octahedra are not tilted. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted linear geometry to one Cs(4), three equivalent Cs(1), one Na(1), and one Ho(2) atom. In the second Cl site, Cl(2) is bonded in a distorted linear geometry to one Cs(3), one Cs(4), two equivalent Cs(2), one Na(2), and one Ho(1) atom. In the third Cl site, Cl(3) is bonded in a distorted linear geometry to one Cs(2), three equivalent Cs(3), one Na(2), and one Y(1) atom. In the fourth Cl site, Cl(4) is bonded in a distorted linear geometry to one Cs(1), one Cs(2), two equivalent Cs(4), one Na(1), and one Ho(1) atom. is represented by the CIF card [CIF]
data_Cs8Na4YHo3Cl24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.709
_cell_length_b   7.709
_cell_length_c   25.568
_cell_angle_alpha   90.000
_cell_angle_beta   81.329
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   1295.949
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.625  0.813  0.562  1.0
  Cs  Cs1  1  0.125  0.063  0.812  1.0
  Cs  Cs2  1  0.625  0.312  0.063  1.0
  Cs  Cs3  1  0.125  0.563  0.312  1.0
  Cs  Cs4  1  0.875  0.437  0.688  1.0
  Cs  Cs5  1  0.375  0.688  0.937  1.0
  Cs  Cs6  1  0.875  0.937  0.188  1.0
  Cs  Cs7  1  0.375  0.187  0.438  1.0
  Na  Na8  1  0.250  0.125  0.625  1.0
  Na  Na9  1  0.750  0.375  0.875  1.0
  Na  Na10  1  0.250  0.625  0.125  1.0
  Na  Na11  1  0.750  0.875  0.375  1.0
  Y  Y12  1  0.000  0.000  0.000  1.0
  Ho  Ho13  1  0.500  0.250  0.250  1.0
  Ho  Ho14  1  0.000  0.500  0.500  1.0
  Ho  Ho15  1  0.500  0.750  0.750  1.0
  Cl  Cl16  1  0.121  0.802  0.560  1.0
  Cl  Cl17  1  0.621  0.052  0.810  1.0
  Cl  Cl18  1  0.121  0.304  0.061  1.0
  Cl  Cl19  1  0.621  0.552  0.310  1.0
  Cl  Cl20  1  0.379  0.931  0.690  1.0
  Cl  Cl21  1  0.879  0.182  0.939  1.0
  Cl  Cl22  1  0.379  0.431  0.190  1.0
  Cl  Cl23  1  0.879  0.681  0.440  1.0
  Cl  Cl24  1  0.638  0.319  0.560  1.0
  Cl  Cl25  1  0.138  0.569  0.810  1.0
  Cl  Cl26  1  0.636  0.818  0.061  1.0
  Cl  Cl27  1  0.138  0.069  0.310  1.0
  Cl  Cl28  1  0.379  0.448  0.690  1.0
  Cl  Cl29  1  0.879  0.696  0.939  1.0
  Cl  Cl30  1  0.379  0.948  0.190  1.0
  Cl  Cl31  1  0.879  0.198  0.440  1.0
  Cl  Cl32  1  0.121  0.319  0.560  1.0
  Cl  Cl33  1  0.621  0.569  0.810  1.0
  Cl  Cl34  1  0.121  0.818  0.061  1.0
  Cl  Cl35  1  0.621  0.069  0.310  1.0
  Cl  Cl36  1  0.862  0.931  0.690  1.0
  Cl  Cl37  1  0.364  0.182  0.939  1.0
  Cl  Cl38  1  0.862  0.431  0.190  1.0
  Cl  Cl39  1  0.362  0.681  0.440  1.0
[/CIF]
.