The material described by Li2V3SnO8 is Spinel-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(6), one O(8), and one O(9) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(5)O6 octahedra, corners with two equivalent Li(4)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent V(4)O6 octahedra, and corners with two equivalent V(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-63°. In the second Li site, Li(2) is bonded to one O(10), one O(2), one O(5), and one O(7) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one V(6)O6 octahedra, corners with two equivalent Li(3)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(3)O6 octahedra, and corners with two equivalent V(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-63°. In the third Li site, Li(3) is bonded to one O(11), one O(13), one O(15), one O(5), one O(7), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Sn(1)O4 tetrahedra, corners with two equivalent Li(2)O4 tetrahedra, corners with two equivalent Sn(2)O4 tetrahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one V(5)O6 octahedra,  an edgeedge with one V(6)O6 octahedra, and edges with two equivalent V(1)O6 octahedra. In the fourth Li site, Li(4) is bonded to one O(10), one O(12), one O(14), one O(16), one O(6), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Sn(2)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra, corners with two equivalent Sn(1)O4 tetrahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one V(5)O6 octahedra,  an edgeedge with one V(6)O6 octahedra, and edges with two equivalent V(2)O6 octahedra. There are six inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(13), one O(15), one O(3), one O(5), and one O(7) atom to form VO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Sn(1)O4 tetrahedra, corners with two equivalent Li(2)O4 tetrahedra, corners with two equivalent Sn(2)O4 tetrahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one V(5)O6 octahedra,  an edgeedge with one V(6)O6 octahedra, and edges with two equivalent Li(3)O6 octahedra. In the second V site, V(2) is bonded to one O(14), one O(16), one O(2), one O(4), one O(6), and one O(8) atom to form VO6 octahedra that share  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Sn(2)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra, corners with two equivalent Sn(1)O4 tetrahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one V(5)O6 octahedra,  an edgeedge with one V(6)O6 octahedra, and edges with two equivalent Li(4)O6 octahedra. In the third V site, V(3) is bonded to one O(10), one O(11), one O(13), one O(2), one O(3), and one O(8) atom to form VO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Sn(2)O4 tetrahedra, corners with two equivalent Li(2)O4 tetrahedra, corners with two equivalent Sn(1)O4 tetrahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, and edges with two equivalent V(5)O6 octahedra. In the fourth V site, V(4) is bonded to one O(1), one O(12), one O(16), one O(4), one O(5), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Sn(1)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra, corners with two equivalent Sn(2)O4 tetrahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, and edges with two equivalent V(6)O6 octahedra. In the fifth V site, V(5) is bonded to one O(10), one O(11), one O(15), one O(2), one O(3), and one O(6) atom to form VO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Sn(2)O4 tetrahedra, corners with two equivalent Li(2)O4 tetrahedra, corners with two equivalent Sn(1)O4 tetrahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, and edges with two equivalent V(3)O6 octahedra. In the sixth V site, V(6) is bonded to one O(1), one O(12), one O(14), one O(4), one O(7), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Sn(1)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra, corners with two equivalent Sn(2)O4 tetrahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, and edges with two equivalent V(4)O6 octahedra. There are two inequivalent Sn sites. In the first Sn site, Sn(1) is bonded to one O(11), one O(14), one O(16), and one O(3) atom to form SnO4 tetrahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one V(6)O6 octahedra, corners with two equivalent Li(4)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent V(3)O6 octahedra, and corners with two equivalent V(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 58-63°. In the second Sn site, Sn(2) is bonded to one O(12), one O(13), one O(15), and one O(4) atom to form SnO4 tetrahedra that share  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(5)O6 octahedra, corners with two equivalent Li(3)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(4)O6 octahedra, and corners with two equivalent V(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-62°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(1), one V(1), one V(4), and one V(6) atom. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(2), one V(3), and one V(5) atom. In the third O site, O(3) is bonded to one V(1), one V(3), one V(5), and one Sn(1) atom to form a mixture of distorted corner and edge-sharing OV3Sn trigonal pyramids. In the fourth O site, O(4) is bonded to one V(2), one V(4), one V(6), and one Sn(2) atom to form a mixture of distorted corner and edge-sharing OV3Sn trigonal pyramids. In the fifth O site, O(5) is bonded in a rectangular see-saw-like geometry to one Li(2), one Li(3), one V(1), and one V(4) atom. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(4), one V(2), and one V(5) atom. In the seventh O site, O(7) is bonded in a rectangular see-saw-like geometry to one Li(2), one Li(3), one V(1), and one V(6) atom. In the eighth O site, O(8) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(4), one V(2), and one V(3) atom. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(3), one V(4), and one V(6) atom. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one Li(2), one Li(4), one V(3), and one V(5) atom. In the eleventh O site, O(11) is bonded to one Li(3), one V(3), one V(5), and one Sn(1) atom to form distorted OLiV2Sn trigonal pyramids that share  a cornercorner with one O(14)LiV2Sn tetrahedra,  a cornercorner with one O(16)LiV2Sn tetrahedra,  a cornercorner with one O(3)V3Sn trigonal pyramid,  an edgeedge with one O(13)LiV2Sn tetrahedra,  an edgeedge with one O(15)LiV2Sn trigonal pyramid, and  an edgeedge with one O(3)V3Sn trigonal pyramid. In the twelfth O site, O(12) is bonded to one Li(4), one V(4), one V(6), and one Sn(2) atom to form distorted OLiV2Sn tetrahedra that share  a cornercorner with one O(13)LiV2Sn tetrahedra,  a cornercorner with one O(15)LiV2Sn trigonal pyramid,  a cornercorner with one O(4)V3Sn trigonal pyramid,  an edgeedge with one O(14)LiV2Sn tetrahedra,  an edgeedge with one O(16)LiV2Sn tetrahedra, and  an edgeedge with one O(4)V3Sn trigonal pyramid. In the thirteenth O site, O(13) is bonded to one Li(3), one V(1), one V(3), and one Sn(2) atom to form distorted OLiV2Sn tetrahedra that share  a cornercorner with one O(12)LiV2Sn tetrahedra,  a cornercorner with one O(15)LiV2Sn trigonal pyramid,  a cornercorner with one O(4)V3Sn trigonal pyramid,  an edgeedge with one O(11)LiV2Sn trigonal pyramid,  an edgeedge with one O(15)LiV2Sn trigonal pyramid, and  an edgeedge with one O(3)V3Sn trigonal pyramid. In the fourteenth O site, O(14) is bonded to one Li(4), one V(2), one V(6), and one Sn(1) atom to form distorted OLiV2Sn tetrahedra that share  a cornercorner with one O(16)LiV2Sn tetrahedra,  a cornercorner with one O(11)LiV2Sn trigonal pyramid,  a cornercorner with one O(3)V3Sn trigonal pyramid,  an edgeedge with one O(12)LiV2Sn tetrahedra,  an edgeedge with one O(16)LiV2Sn tetrahedra, and  an edgeedge with one O(4)V3Sn trigonal pyramid. In the fifteenth O site, O(15) is bonded to one Li(3), one V(1), one V(5), and one Sn(2) atom to form distorted OLiV2Sn trigonal pyramids that share  a cornercorner with one O(12)LiV2Sn tetrahedra,  a cornercorner with one O(13)LiV2Sn tetrahedra,  a cornercorner with one O(4)V3Sn trigonal pyramid,  an edgeedge with one O(13)LiV2Sn tetrahedra,  an edgeedge with one O(11)LiV2Sn trigonal pyramid, and  an edgeedge with one O(3)V3Sn trigonal pyramid. In the sixteenth O site, O(16) is bonded to one Li(4), one V(2), one V(4), and one Sn(1) atom to form distorted OLiV2Sn tetrahedra that share  a cornercorner with one O(14)LiV2Sn tetrahedra,  a cornercorner with one O(11)LiV2Sn trigonal pyramid,  a cornercorner with one O(3)V3Sn trigonal pyramid,  an edgeedge with one O(12)LiV2Sn tetrahedra,  an edgeedge with one O(14)LiV2Sn tetrahedra, and  an edgeedge with one O(4)V3Sn trigonal pyramid. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li2V3SnO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.028
_cell_length_b   6.039
_cell_length_c   6.051
_cell_angle_alpha   60.192
_cell_angle_beta   60.234
_cell_angle_gamma   60.399
_symmetry_Int_Tables_number   1
_cell_volume   156.717
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.878  0.879  0.878  1.0
  Li  Li1  1  0.501  0.501  0.501  1.0
  O  O2  1  0.747  0.746  0.733  1.0
  O  O3  1  0.253  0.253  0.259  1.0
  O  O4  1  0.755  0.753  0.283  1.0
  O  O5  1  0.283  0.757  0.744  1.0
  O  O6  1  0.757  0.284  0.746  1.0
  O  O7  1  0.256  0.715  0.257  1.0
  O  O8  1  0.713  0.255  0.258  1.0
  O  O9  1  0.257  0.256  0.717  1.0
  Sn  Sn10  1  0.117  0.118  0.120  1.0
  V  V11  1  0.503  0.976  0.510  1.0
  V  V12  1  0.504  0.505  0.985  1.0
  V  V13  1  0.977  0.503  0.508  1.0
[/CIF]
.
The material described by Li2V3SnO8 is Spinel-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(6), one O(8), and one O(9) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(5)O6 octahedra, corners with two equivalent Li(4)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent V(4)O6 octahedra, and corners with two equivalent V(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-63°. In the second Li site, Li(2) is bonded to one O(10), one O(2), one O(5), and one O(7) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one V(6)O6 octahedra, corners with two equivalent Li(3)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(3)O6 octahedra, and corners with two equivalent V(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-63°. In the third Li site, Li(3) is bonded to one O(11), one O(13), one O(15), one O(5), one O(7), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Sn(1)O4 tetrahedra, corners with two equivalent Li(2)O4 tetrahedra, corners with two equivalent Sn(2)O4 tetrahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one V(5)O6 octahedra,  an edgeedge with one V(6)O6 octahedra, and edges with two equivalent V(1)O6 octahedra. In the fourth Li site, Li(4) is bonded to one O(10), one O(12), one O(14), one O(16), one O(6), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Sn(2)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra, corners with two equivalent Sn(1)O4 tetrahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one V(5)O6 octahedra,  an edgeedge with one V(6)O6 octahedra, and edges with two equivalent V(2)O6 octahedra. There are six inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(13), one O(15), one O(3), one O(5), and one O(7) atom to form VO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Sn(1)O4 tetrahedra, corners with two equivalent Li(2)O4 tetrahedra, corners with two equivalent Sn(2)O4 tetrahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one V(5)O6 octahedra,  an edgeedge with one V(6)O6 octahedra, and edges with two equivalent Li(3)O6 octahedra. In the second V site, V(2) is bonded to one O(14), one O(16), one O(2), one O(4), one O(6), and one O(8) atom to form VO6 octahedra that share  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Sn(2)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra, corners with two equivalent Sn(1)O4 tetrahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(4)O6 octahedra,  an edgeedge with one V(5)O6 octahedra,  an edgeedge with one V(6)O6 octahedra, and edges with two equivalent Li(4)O6 octahedra. In the third V site, V(3) is bonded to one O(10), one O(11), one O(13), one O(2), one O(3), and one O(8) atom to form VO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Sn(2)O4 tetrahedra, corners with two equivalent Li(2)O4 tetrahedra, corners with two equivalent Sn(1)O4 tetrahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, and edges with two equivalent V(5)O6 octahedra. In the fourth V site, V(4) is bonded to one O(1), one O(12), one O(16), one O(4), one O(5), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Sn(1)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra, corners with two equivalent Sn(2)O4 tetrahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, and edges with two equivalent V(6)O6 octahedra. In the fifth V site, V(5) is bonded to one O(10), one O(11), one O(15), one O(2), one O(3), and one O(6) atom to form VO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Sn(2)O4 tetrahedra, corners with two equivalent Li(2)O4 tetrahedra, corners with two equivalent Sn(1)O4 tetrahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, and edges with two equivalent V(3)O6 octahedra. In the sixth V site, V(6) is bonded to one O(1), one O(12), one O(14), one O(4), one O(7), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Sn(1)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra, corners with two equivalent Sn(2)O4 tetrahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, and edges with two equivalent V(4)O6 octahedra. There are two inequivalent Sn sites. In the first Sn site, Sn(1) is bonded to one O(11), one O(14), one O(16), and one O(3) atom to form SnO4 tetrahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(4)O6 octahedra,  a cornercorner with one V(6)O6 octahedra, corners with two equivalent Li(4)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent V(3)O6 octahedra, and corners with two equivalent V(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 58-63°. In the second Sn site, Sn(2) is bonded to one O(12), one O(13), one O(15), and one O(4) atom to form SnO4 tetrahedra that share  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(5)O6 octahedra, corners with two equivalent Li(3)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(4)O6 octahedra, and corners with two equivalent V(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-62°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(1), one V(1), one V(4), and one V(6) atom. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(2), one V(3), and one V(5) atom. In the third O site, O(3) is bonded to one V(1), one V(3), one V(5), and one Sn(1) atom to form a mixture of distorted corner and edge-sharing OV3Sn trigonal pyramids. In the fourth O site, O(4) is bonded to one V(2), one V(4), one V(6), and one Sn(2) atom to form a mixture of distorted corner and edge-sharing OV3Sn trigonal pyramids. In the fifth O site, O(5) is bonded in a rectangular see-saw-like geometry to one Li(2), one Li(3), one V(1), and one V(4) atom. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(4), one V(2), and one V(5) atom. In the seventh O site, O(7) is bonded in a rectangular see-saw-like geometry to one Li(2), one Li(3), one V(1), and one V(6) atom. In the eighth O site, O(8) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(4), one V(2), and one V(3) atom. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(3), one V(4), and one V(6) atom. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one Li(2), one Li(4), one V(3), and one V(5) atom. In the eleventh O site, O(11) is bonded to one Li(3), one V(3), one V(5), and one Sn(1) atom to form distorted OLiV2Sn trigonal pyramids that share  a cornercorner with one O(14)LiV2Sn tetrahedra,  a cornercorner with one O(16)LiV2Sn tetrahedra,  a cornercorner with one O(3)V3Sn trigonal pyramid,  an edgeedge with one O(13)LiV2Sn tetrahedra,  an edgeedge with one O(15)LiV2Sn trigonal pyramid, and  an edgeedge with one O(3)V3Sn trigonal pyramid. In the twelfth O site, O(12) is bonded to one Li(4), one V(4), one V(6), and one Sn(2) atom to form distorted OLiV2Sn tetrahedra that share  a cornercorner with one O(13)LiV2Sn tetrahedra,  a cornercorner with one O(15)LiV2Sn trigonal pyramid,  a cornercorner with one O(4)V3Sn trigonal pyramid,  an edgeedge with one O(14)LiV2Sn tetrahedra,  an edgeedge with one O(16)LiV2Sn tetrahedra, and  an edgeedge with one O(4)V3Sn trigonal pyramid. In the thirteenth O site, O(13) is bonded to one Li(3), one V(1), one V(3), and one Sn(2) atom to form distorted OLiV2Sn tetrahedra that share  a cornercorner with one O(12)LiV2Sn tetrahedra,  a cornercorner with one O(15)LiV2Sn trigonal pyramid,  a cornercorner with one O(4)V3Sn trigonal pyramid,  an edgeedge with one O(11)LiV2Sn trigonal pyramid,  an edgeedge with one O(15)LiV2Sn trigonal pyramid, and  an edgeedge with one O(3)V3Sn trigonal pyramid. In the fourteenth O site, O(14) is bonded to one Li(4), one V(2), one V(6), and one Sn(1) atom to form distorted OLiV2Sn tetrahedra that share  a cornercorner with one O(16)LiV2Sn tetrahedra,  a cornercorner with one O(11)LiV2Sn trigonal pyramid,  a cornercorner with one O(3)V3Sn trigonal pyramid,  an edgeedge with one O(12)LiV2Sn tetrahedra,  an edgeedge with one O(16)LiV2Sn tetrahedra, and  an edgeedge with one O(4)V3Sn trigonal pyramid. In the fifteenth O site, O(15) is bonded to one Li(3), one V(1), one V(5), and one Sn(2) atom to form distorted OLiV2Sn trigonal pyramids that share  a cornercorner with one O(12)LiV2Sn tetrahedra,  a cornercorner with one O(13)LiV2Sn tetrahedra,  a cornercorner with one O(4)V3Sn trigonal pyramid,  an edgeedge with one O(13)LiV2Sn tetrahedra,  an edgeedge with one O(11)LiV2Sn trigonal pyramid, and  an edgeedge with one O(3)V3Sn trigonal pyramid. In the sixteenth O site, O(16) is bonded to one Li(4), one V(2), one V(4), and one Sn(1) atom to form distorted OLiV2Sn tetrahedra that share  a cornercorner with one O(14)LiV2Sn tetrahedra,  a cornercorner with one O(11)LiV2Sn trigonal pyramid,  a cornercorner with one O(3)V3Sn trigonal pyramid,  an edgeedge with one O(12)LiV2Sn tetrahedra,  an edgeedge with one O(14)LiV2Sn tetrahedra, and  an edgeedge with one O(4)V3Sn trigonal pyramid. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li2V3SnO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.028
_cell_length_b   6.039
_cell_length_c   6.051
_cell_angle_alpha   60.192
_cell_angle_beta   60.234
_cell_angle_gamma   60.399
_symmetry_Int_Tables_number   1
_cell_volume   156.717
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.878  0.879  0.878  1.0
  Li  Li1  1  0.501  0.501  0.501  1.0
  O  O2  1  0.747  0.746  0.733  1.0
  O  O3  1  0.253  0.253  0.259  1.0
  O  O4  1  0.755  0.753  0.283  1.0
  O  O5  1  0.283  0.757  0.744  1.0
  O  O6  1  0.757  0.284  0.746  1.0
  O  O7  1  0.256  0.715  0.257  1.0
  O  O8  1  0.713  0.255  0.258  1.0
  O  O9  1  0.257  0.256  0.717  1.0
  Sn  Sn10  1  0.117  0.118  0.120  1.0
  V  V11  1  0.503  0.976  0.510  1.0
  V  V12  1  0.504  0.505  0.985  1.0
  V  V13  1  0.977  0.503  0.508  1.0
[/CIF]
.