The material described by Li(H2O)4B(OH)4(H2O)2 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two water molecules, one B(OH)4 cluster, and one Li(H2O)4 cluster. In the B(OH)4 cluster, B(1) is bonded in a tetrahedral geometry to one O(10), one O(4), one O(8), and one O(9) atom. There are four inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one O(9) atom. In the second H site, H(3) is bonded in a single-bond geometry to one O(10) atom. In the third H site, H(4) is bonded in a single-bond geometry to one O(8) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one O(4) atom. There are four inequivalent O sites. In the first O site, O(4) is bonded in a 2-coordinate geometry to one B(1) and one H(8) atom. In the second O site, O(8) is bonded in a distorted water-like geometry to one B(1) and one H(4) atom. In the third O site, O(9) is bonded in a distorted bent 120 degrees geometry to one B(1) and one H(2) atom. In the fourth O site, O(10) is bonded in a distorted bent 120 degrees geometry to one B(1) and one H(3) atom. In the Li(H2O)4 cluster, Li(1) is bonded in a tetrahedral geometry to one O(2), one O(5), one O(6), and one O(7) atom. There are eight inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one O(6) atom. In the second H site, H(6) is bonded in a single-bond geometry to one O(7) atom. In the third H site, H(7) is bonded in a single-bond geometry to one O(5) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one O(6) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one O(7) atom. In the sixth H site, H(12) is bonded in a distorted single-bond geometry to one O(5) atom. In the seventh H site, H(15) is bonded in a single-bond geometry to one O(2) atom. In the eighth H site, H(16) is bonded in a single-bond geometry to one O(2) atom. There are four inequivalent O sites. In the first O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one H(15), and one H(16) atom. In the second O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one H(12), and one H(7) atom. In the third O site, O(6) is bonded in a 2-coordinate geometry to one Li(1), one H(5), and one H(9) atom. In the fourth O site, O(7) is bonded in a distorted water-like geometry to one Li(1), one H(10), and one H(6) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiB(H8O5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.017
_cell_length_b   6.499
_cell_length_c   6.636
_cell_angle_alpha   61.729
_cell_angle_beta   89.727
_cell_angle_gamma   91.016
_symmetry_Int_Tables_number   1
_cell_volume   228.493
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.716  0.677  0.663  1.0
  B  B1  1  0.292  0.346  0.335  1.0
  H  H2  1  0.444  0.004  0.014  1.0
  H  H3  1  0.224  0.690  0.250  1.0
  H  H4  1  0.293  0.987  0.549  1.0
  H  H5  1  0.214  0.252  0.087  1.0
  H  H6  1  0.957  0.447  0.530  1.0
  H  H7  1  0.955  0.042  0.442  1.0
  H  H8  1  0.957  0.553  0.023  1.0
  H  H9  1  0.610  0.452  0.184  1.0
  H  H10  1  0.701  0.384  0.514  1.0
  H  H11  1  0.701  0.108  0.386  1.0
  H  H12  1  0.222  0.029  0.880  1.0
  H  H13  1  0.805  0.775  0.978  1.0
  H  H14  1  0.779  0.164  0.862  1.0
  H  H15  1  0.784  0.011  0.141  1.0
  H  H16  1  0.321  0.583  0.834  1.0
  H  H17  1  0.320  0.609  0.581  1.0
  O  O18  1  0.278  0.993  0.032  1.0
  O  O19  1  0.386  0.676  0.677  1.0
  O  O20  1  0.730  0.013  0.997  1.0
  O  O21  1  0.541  0.337  0.332  1.0
  O  O22  1  0.812  0.630  0.963  1.0
  O  O23  1  0.809  0.415  0.612  1.0
  O  O24  1  0.811  0.985  0.407  1.0
  O  O25  1  0.204  0.394  0.105  1.0
  O  O26  1  0.211  0.532  0.384  1.0
  O  O27  1  0.204  0.124  0.521  1.0
[/CIF]
.
The material described by Li(H2O)4B(OH)4(H2O)2 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two water molecules, one B(OH)4 cluster, and one Li(H2O)4 cluster. In the B(OH)4 cluster, B(1) is bonded in a tetrahedral geometry to one O(10), one O(4), one O(8), and one O(9) atom. There are four inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one O(9) atom. In the second H site, H(3) is bonded in a single-bond geometry to one O(10) atom. In the third H site, H(4) is bonded in a single-bond geometry to one O(8) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one O(4) atom. There are four inequivalent O sites. In the first O site, O(4) is bonded in a 2-coordinate geometry to one B(1) and one H(8) atom. In the second O site, O(8) is bonded in a distorted water-like geometry to one B(1) and one H(4) atom. In the third O site, O(9) is bonded in a distorted bent 120 degrees geometry to one B(1) and one H(2) atom. In the fourth O site, O(10) is bonded in a distorted bent 120 degrees geometry to one B(1) and one H(3) atom. In the Li(H2O)4 cluster, Li(1) is bonded in a tetrahedral geometry to one O(2), one O(5), one O(6), and one O(7) atom. There are eight inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one O(6) atom. In the second H site, H(6) is bonded in a single-bond geometry to one O(7) atom. In the third H site, H(7) is bonded in a single-bond geometry to one O(5) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one O(6) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one O(7) atom. In the sixth H site, H(12) is bonded in a distorted single-bond geometry to one O(5) atom. In the seventh H site, H(15) is bonded in a single-bond geometry to one O(2) atom. In the eighth H site, H(16) is bonded in a single-bond geometry to one O(2) atom. There are four inequivalent O sites. In the first O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one H(15), and one H(16) atom. In the second O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one H(12), and one H(7) atom. In the third O site, O(6) is bonded in a 2-coordinate geometry to one Li(1), one H(5), and one H(9) atom. In the fourth O site, O(7) is bonded in a distorted water-like geometry to one Li(1), one H(10), and one H(6) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiB(H8O5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.017
_cell_length_b   6.499
_cell_length_c   6.636
_cell_angle_alpha   61.729
_cell_angle_beta   89.727
_cell_angle_gamma   91.016
_symmetry_Int_Tables_number   1
_cell_volume   228.493
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.716  0.677  0.663  1.0
  B  B1  1  0.292  0.346  0.335  1.0
  H  H2  1  0.444  0.004  0.014  1.0
  H  H3  1  0.224  0.690  0.250  1.0
  H  H4  1  0.293  0.987  0.549  1.0
  H  H5  1  0.214  0.252  0.087  1.0
  H  H6  1  0.957  0.447  0.530  1.0
  H  H7  1  0.955  0.042  0.442  1.0
  H  H8  1  0.957  0.553  0.023  1.0
  H  H9  1  0.610  0.452  0.184  1.0
  H  H10  1  0.701  0.384  0.514  1.0
  H  H11  1  0.701  0.108  0.386  1.0
  H  H12  1  0.222  0.029  0.880  1.0
  H  H13  1  0.805  0.775  0.978  1.0
  H  H14  1  0.779  0.164  0.862  1.0
  H  H15  1  0.784  0.011  0.141  1.0
  H  H16  1  0.321  0.583  0.834  1.0
  H  H17  1  0.320  0.609  0.581  1.0
  O  O18  1  0.278  0.993  0.032  1.0
  O  O19  1  0.386  0.676  0.677  1.0
  O  O20  1  0.730  0.013  0.997  1.0
  O  O21  1  0.541  0.337  0.332  1.0
  O  O22  1  0.812  0.630  0.963  1.0
  O  O23  1  0.809  0.415  0.612  1.0
  O  O24  1  0.811  0.985  0.407  1.0
  O  O25  1  0.204  0.394  0.105  1.0
  O  O26  1  0.211  0.532  0.384  1.0
  O  O27  1  0.204  0.124  0.521  1.0
[/CIF]
.