The material structure described by AsPHOCl3F6 is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four AsPHOCl3F6 clusters. As(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), and two equivalent F(5) atoms. P(1) is bonded in a tetrahedral geometry to one O(1), one Cl(1), and two equivalent Cl(2) atoms. H(1) is bonded in a linear geometry to one O(1) and one F(2) atom. O(1) is bonded in a bent 120 degrees geometry to one P(1) and one H(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one P(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one P(1) atom. There are five inequivalent F sites. In the first F site, F(2) is bonded in a bent 120 degrees geometry to one As(1) and one H(1) atom. In the second F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(1) is bonded in a single-bond geometry to one As(1) atom. is represented by the CIF card [CIF]
data_AsPHCl3OF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.658
_cell_length_b   8.820
_cell_length_c   13.137
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1003.182
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.802  0.750  0.440  1.0
  As  As1  1  0.698  0.750  0.940  1.0
  As  As2  1  0.198  0.250  0.560  1.0
  As  As3  1  0.302  0.250  0.060  1.0
  P  P4  1  0.275  0.750  0.224  1.0
  P  P5  1  0.225  0.750  0.724  1.0
  P  P6  1  0.725  0.250  0.776  1.0
  P  P7  1  0.775  0.250  0.276  1.0
  H  H8  1  0.459  0.750  0.096  1.0
  H  H9  1  0.041  0.750  0.596  1.0
  H  H10  1  0.541  0.250  0.904  1.0
  H  H11  1  0.959  0.250  0.404  1.0
  Cl  Cl12  1  0.101  0.750  0.128  1.0
  Cl  Cl13  1  0.399  0.750  0.628  1.0
  Cl  Cl14  1  0.899  0.250  0.872  1.0
  Cl  Cl15  1  0.601  0.250  0.372  1.0
  Cl  Cl16  1  0.256  0.572  0.313  1.0
  Cl  Cl17  1  0.244  0.928  0.813  1.0
  Cl  Cl18  1  0.744  0.072  0.687  1.0
  Cl  Cl19  1  0.756  0.428  0.187  1.0
  Cl  Cl20  1  0.744  0.428  0.687  1.0
  Cl  Cl21  1  0.756  0.072  0.187  1.0
  Cl  Cl22  1  0.256  0.928  0.313  1.0
  Cl  Cl23  1  0.244  0.572  0.813  1.0
  O  O24  1  0.433  0.750  0.174  1.0
  O  O25  1  0.067  0.750  0.674  1.0
  O  O26  1  0.567  0.250  0.826  1.0
  O  O27  1  0.933  0.250  0.326  1.0
  F  F28  1  0.737  0.750  0.568  1.0
  F  F29  1  0.763  0.750  0.068  1.0
  F  F30  1  0.263  0.250  0.432  1.0
  F  F31  1  0.237  0.250  0.932  1.0
  F  F32  1  0.001  0.750  0.492  1.0
  F  F33  1  0.499  0.750  0.992  1.0
  F  F34  1  0.999  0.250  0.508  1.0
  F  F35  1  0.501  0.250  0.008  1.0
  F  F36  1  0.611  0.750  0.396  1.0
  F  F37  1  0.889  0.750  0.896  1.0
  F  F38  1  0.389  0.250  0.604  1.0
  F  F39  1  0.111  0.250  0.104  1.0
  F  F40  1  0.882  0.750  0.317  1.0
  F  F41  1  0.618  0.750  0.817  1.0
  F  F42  1  0.118  0.250  0.683  1.0
  F  F43  1  0.382  0.250  0.183  1.0
  F  F44  1  0.809  0.550  0.442  1.0
  F  F45  1  0.691  0.950  0.942  1.0
  F  F46  1  0.191  0.050  0.558  1.0
  F  F47  1  0.309  0.450  0.058  1.0
  F  F48  1  0.191  0.450  0.558  1.0
  F  F49  1  0.309  0.050  0.058  1.0
  F  F50  1  0.809  0.950  0.442  1.0
  F  F51  1  0.691  0.550  0.942  1.0
[/CIF]
.
The material structure described by AsPHOCl3F6 is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four AsPHOCl3F6 clusters. As(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), and two equivalent F(5) atoms. P(1) is bonded in a tetrahedral geometry to one O(1), one Cl(1), and two equivalent Cl(2) atoms. H(1) is bonded in a linear geometry to one O(1) and one F(2) atom. O(1) is bonded in a bent 120 degrees geometry to one P(1) and one H(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one P(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one P(1) atom. There are five inequivalent F sites. In the first F site, F(2) is bonded in a bent 120 degrees geometry to one As(1) and one H(1) atom. In the second F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(1) is bonded in a single-bond geometry to one As(1) atom. is represented by the CIF card [CIF]
data_AsPHCl3OF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.658
_cell_length_b   8.820
_cell_length_c   13.137
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1003.182
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.802  0.750  0.440  1.0
  As  As1  1  0.698  0.750  0.940  1.0
  As  As2  1  0.198  0.250  0.560  1.0
  As  As3  1  0.302  0.250  0.060  1.0
  P  P4  1  0.275  0.750  0.224  1.0
  P  P5  1  0.225  0.750  0.724  1.0
  P  P6  1  0.725  0.250  0.776  1.0
  P  P7  1  0.775  0.250  0.276  1.0
  H  H8  1  0.459  0.750  0.096  1.0
  H  H9  1  0.041  0.750  0.596  1.0
  H  H10  1  0.541  0.250  0.904  1.0
  H  H11  1  0.959  0.250  0.404  1.0
  Cl  Cl12  1  0.101  0.750  0.128  1.0
  Cl  Cl13  1  0.399  0.750  0.628  1.0
  Cl  Cl14  1  0.899  0.250  0.872  1.0
  Cl  Cl15  1  0.601  0.250  0.372  1.0
  Cl  Cl16  1  0.256  0.572  0.313  1.0
  Cl  Cl17  1  0.244  0.928  0.813  1.0
  Cl  Cl18  1  0.744  0.072  0.687  1.0
  Cl  Cl19  1  0.756  0.428  0.187  1.0
  Cl  Cl20  1  0.744  0.428  0.687  1.0
  Cl  Cl21  1  0.756  0.072  0.187  1.0
  Cl  Cl22  1  0.256  0.928  0.313  1.0
  Cl  Cl23  1  0.244  0.572  0.813  1.0
  O  O24  1  0.433  0.750  0.174  1.0
  O  O25  1  0.067  0.750  0.674  1.0
  O  O26  1  0.567  0.250  0.826  1.0
  O  O27  1  0.933  0.250  0.326  1.0
  F  F28  1  0.737  0.750  0.568  1.0
  F  F29  1  0.763  0.750  0.068  1.0
  F  F30  1  0.263  0.250  0.432  1.0
  F  F31  1  0.237  0.250  0.932  1.0
  F  F32  1  0.001  0.750  0.492  1.0
  F  F33  1  0.499  0.750  0.992  1.0
  F  F34  1  0.999  0.250  0.508  1.0
  F  F35  1  0.501  0.250  0.008  1.0
  F  F36  1  0.611  0.750  0.396  1.0
  F  F37  1  0.889  0.750  0.896  1.0
  F  F38  1  0.389  0.250  0.604  1.0
  F  F39  1  0.111  0.250  0.104  1.0
  F  F40  1  0.882  0.750  0.317  1.0
  F  F41  1  0.618  0.750  0.817  1.0
  F  F42  1  0.118  0.250  0.683  1.0
  F  F43  1  0.382  0.250  0.183  1.0
  F  F44  1  0.809  0.550  0.442  1.0
  F  F45  1  0.691  0.950  0.942  1.0
  F  F46  1  0.191  0.050  0.558  1.0
  F  F47  1  0.309  0.450  0.058  1.0
  F  F48  1  0.191  0.450  0.558  1.0
  F  F49  1  0.309  0.050  0.058  1.0
  F  F50  1  0.809  0.950  0.442  1.0
  F  F51  1  0.691  0.550  0.942  1.0
[/CIF]
.