The material structure described by Zn(SbO2)2 crystallizes in the triclinic P1 space group. There are six inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a distorted T-shaped geometry to one O(1), one O(3), and one O(4) atom. In the second Zn site, Zn(2) is bonded in a trigonal pyramidal geometry to one O(5), one O(6), one O(8), and one O(9) atom. In the third Zn site, Zn(3) is bonded in a rectangular see-saw-like geometry to one O(1), one O(10), one O(2), and one O(3) atom. In the fourth Zn site, Zn(4) is bonded in a distorted trigonal pyramidal geometry to one O(13), one O(15), one O(19), and one O(20) atom. In the fifth Zn site, Zn(5) is bonded in a 4-coordinate geometry to one O(15), one O(20), one O(5), and one O(9) atom. In the sixth Zn site, Zn(6) is bonded in a see-saw-like geometry to one O(13), one O(16), one O(22), and one O(23) atom. There are twelve inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 3-coordinate geometry to one O(10), one O(12), one O(4), and one O(6) atom. In the second Sb site, Sb(2) is bonded in a distorted T-shaped geometry to one O(11), one O(2), and one O(5) atom. In the third Sb site, Sb(3) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(21), and one O(3) atom. In the fourth Sb site, Sb(4) is bonded in a 4-coordinate geometry to one O(10), one O(4), one O(6), and one O(8) atom. In the fifth Sb site, Sb(5) is bonded in a distorted rectangular see-saw-like geometry to one O(14), one O(18), one O(20), and one O(7) atom. In the sixth Sb site, Sb(6) is bonded in a distorted T-shaped geometry to one O(13), one O(16), and one O(7) atom. In the seventh Sb site, Sb(7) is bonded in a distorted trigonal non-coplanar geometry to one O(11), one O(18), and one O(9) atom. In the eighth Sb site, Sb(8) is bonded in a 5-coordinate geometry to one O(13), one O(17), one O(19), one O(23), and one O(24) atom. In the ninth Sb site, Sb(9) is bonded in a distorted rectangular see-saw-like geometry to one O(12), one O(18), one O(4), and one O(8) atom. In the tenth Sb site, Sb(10) is bonded in a 3-coordinate geometry to one O(16), one O(17), and one O(19) atom. In the eleventh Sb site, Sb(11) is bonded in a distorted T-shaped geometry to one O(14), one O(15), and one O(23) atom. In the twelfth Sb site, Sb(12) is bonded in a distorted T-shaped geometry to one O(21), one O(22), and one O(24) atom. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Zn(1), one Zn(3), and one Sb(3) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Zn(3) and one Sb(2) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to one Zn(1), one Zn(3), and one Sb(3) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Zn(1), one Sb(1), one Sb(4), and one Sb(9) atom. In the fifth O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one Zn(2), one Zn(5), and one Sb(2) atom. In the sixth O site, O(6) is bonded in a distorted trigonal non-coplanar geometry to one Zn(2), one Sb(1), and one Sb(4) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Sb(5) and one Sb(6) atom. In the eighth O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to one Zn(2), one Sb(4), and one Sb(9) atom. In the ninth O site, O(9) is bonded in a distorted trigonal non-coplanar geometry to one Zn(2), one Zn(5), and one Sb(7) atom. In the tenth O site, O(10) is bonded in a trigonal non-coplanar geometry to one Zn(3), one Sb(1), and one Sb(4) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Sb(2) and one Sb(7) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Sb(1) and one Sb(9) atom. In the thirteenth O site, O(13) is bonded in a distorted trigonal non-coplanar geometry to one Zn(4), one Zn(6), one Sb(6), and one Sb(8) atom. In the fourteenth O site, O(14) is bonded in a bent 120 degrees geometry to one Sb(11) and one Sb(5) atom. In the fifteenth O site, O(15) is bonded in a distorted trigonal planar geometry to one Zn(4), one Zn(5), and one Sb(11) atom. In the sixteenth O site, O(16) is bonded in a trigonal planar geometry to one Zn(6), one Sb(10), and one Sb(6) atom. In the seventeenth O site, O(17) is bonded in a water-like geometry to one Sb(10) and one Sb(8) atom. In the eighteenth O site, O(18) is bonded in a distorted bent 120 degrees geometry to one Sb(5), one Sb(7), and one Sb(9) atom. In the nineteenth O site, O(19) is bonded in a trigonal non-coplanar geometry to one Zn(4), one Sb(10), and one Sb(8) atom. In the twentieth O site, O(20) is bonded in a trigonal non-coplanar geometry to one Zn(4), one Zn(5), and one Sb(5) atom. In the twenty-first O site, O(21) is bonded in a bent 150 degrees geometry to one Sb(12) and one Sb(3) atom. In the twenty-second O site, O(22) is bonded in a bent 150 degrees geometry to one Zn(6) and one Sb(12) atom. In the twenty-third O site, O(23) is bonded in a distorted trigonal planar geometry to one Zn(6), one Sb(11), and one Sb(8) atom. In the twenty-fourth O site, O(24) is bonded in a bent 120 degrees geometry to one Sb(12) and one Sb(8) atom. is represented by the CIF file [CIF]
data_Zn(SbO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.523
_cell_length_b   7.180
_cell_length_c   17.138
_cell_angle_alpha   89.194
_cell_angle_beta   88.829
_cell_angle_gamma   63.081
_symmetry_Int_Tables_number   1
_cell_volume   715.610
_cell_formula_units_Z   6
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.600  0.212  0.083  1.0
  Zn  Zn1  1  0.442  0.673  0.340  1.0
  Zn  Zn2  1  0.117  0.206  0.165  1.0
  Zn  Zn3  1  0.721  0.248  0.652  1.0
  Zn  Zn4  1  0.571  0.485  0.496  1.0
  Zn  Zn5  1  0.836  0.871  0.792  1.0
  Sb  Sb6  1  0.130  0.739  0.177  1.0
  Sb  Sb7  1  0.016  0.429  0.358  1.0
  Sb  Sb8  1  0.049  0.333  0.996  1.0
  Sb  Sb9  1  0.632  0.725  0.171  1.0
  Sb  Sb10  1  0.519  0.006  0.534  1.0
  Sb  Sb11  1  0.307  0.898  0.718  1.0
  Sb  Sb12  1  0.046  0.997  0.464  1.0
  Sb  Sb13  1  0.779  0.406  0.826  1.0
  Sb  Sb14  1  0.677  0.067  0.299  1.0
  Sb  Sb15  1  0.340  0.329  0.822  1.0
  Sb  Sb16  1  0.982  0.564  0.627  1.0
  Sb  Sb17  1  0.311  0.765  0.941  1.0
  O  O18  1  0.271  0.312  0.078  1.0
  O  O19  1  0.993  0.412  0.244  1.0
  O  O20  1  0.877  0.246  0.074  1.0
  O  O21  1  0.673  0.996  0.162  1.0
  O  O22  1  0.720  0.432  0.391  1.0
  O  O23  1  0.428  0.579  0.233  1.0
  O  O24  1  0.284  0.062  0.622  1.0
  O  O25  1  0.624  0.808  0.286  1.0
  O  O26  1  0.296  0.710  0.443  1.0
  O  O27  1  0.293  0.910  0.139  1.0
  O  O28  1  0.181  0.123  0.384  1.0
  O  O29  1  0.011  0.931  0.267  1.0
  O  O30  1  0.957  0.069  0.731  1.0
  O  O31  1  0.800  0.867  0.599  1.0
  O  O32  1  0.751  0.483  0.590  1.0
  O  O33  1  0.491  0.042  0.771  1.0
  O  O34  1  0.585  0.289  0.896  1.0
  O  O35  1  0.799  0.959  0.410  1.0
  O  O36  1  0.532  0.421  0.749  1.0
  O  O37  1  0.530  0.269  0.558  1.0
  O  O38  1  0.243  0.067  0.941  1.0
  O  O39  1  0.123  0.760  0.854  1.0
  O  O40  1  0.867  0.608  0.737  1.0
  O  O41  1  0.596  0.689  0.877  1.0
[/CIF]
.
The material structure described by Zn(SbO2)2 crystallizes in the triclinic P1 space group. There are six inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a distorted T-shaped geometry to one O(1), one O(3), and one O(4) atom. In the second Zn site, Zn(2) is bonded in a trigonal pyramidal geometry to one O(5), one O(6), one O(8), and one O(9) atom. In the third Zn site, Zn(3) is bonded in a rectangular see-saw-like geometry to one O(1), one O(10), one O(2), and one O(3) atom. In the fourth Zn site, Zn(4) is bonded in a distorted trigonal pyramidal geometry to one O(13), one O(15), one O(19), and one O(20) atom. In the fifth Zn site, Zn(5) is bonded in a 4-coordinate geometry to one O(15), one O(20), one O(5), and one O(9) atom. In the sixth Zn site, Zn(6) is bonded in a see-saw-like geometry to one O(13), one O(16), one O(22), and one O(23) atom. There are twelve inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 3-coordinate geometry to one O(10), one O(12), one O(4), and one O(6) atom. In the second Sb site, Sb(2) is bonded in a distorted T-shaped geometry to one O(11), one O(2), and one O(5) atom. In the third Sb site, Sb(3) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(21), and one O(3) atom. In the fourth Sb site, Sb(4) is bonded in a 4-coordinate geometry to one O(10), one O(4), one O(6), and one O(8) atom. In the fifth Sb site, Sb(5) is bonded in a distorted rectangular see-saw-like geometry to one O(14), one O(18), one O(20), and one O(7) atom. In the sixth Sb site, Sb(6) is bonded in a distorted T-shaped geometry to one O(13), one O(16), and one O(7) atom. In the seventh Sb site, Sb(7) is bonded in a distorted trigonal non-coplanar geometry to one O(11), one O(18), and one O(9) atom. In the eighth Sb site, Sb(8) is bonded in a 5-coordinate geometry to one O(13), one O(17), one O(19), one O(23), and one O(24) atom. In the ninth Sb site, Sb(9) is bonded in a distorted rectangular see-saw-like geometry to one O(12), one O(18), one O(4), and one O(8) atom. In the tenth Sb site, Sb(10) is bonded in a 3-coordinate geometry to one O(16), one O(17), and one O(19) atom. In the eleventh Sb site, Sb(11) is bonded in a distorted T-shaped geometry to one O(14), one O(15), and one O(23) atom. In the twelfth Sb site, Sb(12) is bonded in a distorted T-shaped geometry to one O(21), one O(22), and one O(24) atom. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Zn(1), one Zn(3), and one Sb(3) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Zn(3) and one Sb(2) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to one Zn(1), one Zn(3), and one Sb(3) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Zn(1), one Sb(1), one Sb(4), and one Sb(9) atom. In the fifth O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one Zn(2), one Zn(5), and one Sb(2) atom. In the sixth O site, O(6) is bonded in a distorted trigonal non-coplanar geometry to one Zn(2), one Sb(1), and one Sb(4) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Sb(5) and one Sb(6) atom. In the eighth O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to one Zn(2), one Sb(4), and one Sb(9) atom. In the ninth O site, O(9) is bonded in a distorted trigonal non-coplanar geometry to one Zn(2), one Zn(5), and one Sb(7) atom. In the tenth O site, O(10) is bonded in a trigonal non-coplanar geometry to one Zn(3), one Sb(1), and one Sb(4) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Sb(2) and one Sb(7) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Sb(1) and one Sb(9) atom. In the thirteenth O site, O(13) is bonded in a distorted trigonal non-coplanar geometry to one Zn(4), one Zn(6), one Sb(6), and one Sb(8) atom. In the fourteenth O site, O(14) is bonded in a bent 120 degrees geometry to one Sb(11) and one Sb(5) atom. In the fifteenth O site, O(15) is bonded in a distorted trigonal planar geometry to one Zn(4), one Zn(5), and one Sb(11) atom. In the sixteenth O site, O(16) is bonded in a trigonal planar geometry to one Zn(6), one Sb(10), and one Sb(6) atom. In the seventeenth O site, O(17) is bonded in a water-like geometry to one Sb(10) and one Sb(8) atom. In the eighteenth O site, O(18) is bonded in a distorted bent 120 degrees geometry to one Sb(5), one Sb(7), and one Sb(9) atom. In the nineteenth O site, O(19) is bonded in a trigonal non-coplanar geometry to one Zn(4), one Sb(10), and one Sb(8) atom. In the twentieth O site, O(20) is bonded in a trigonal non-coplanar geometry to one Zn(4), one Zn(5), and one Sb(5) atom. In the twenty-first O site, O(21) is bonded in a bent 150 degrees geometry to one Sb(12) and one Sb(3) atom. In the twenty-second O site, O(22) is bonded in a bent 150 degrees geometry to one Zn(6) and one Sb(12) atom. In the twenty-third O site, O(23) is bonded in a distorted trigonal planar geometry to one Zn(6), one Sb(11), and one Sb(8) atom. In the twenty-fourth O site, O(24) is bonded in a bent 120 degrees geometry to one Sb(12) and one Sb(8) atom. is represented by the CIF file [CIF]
data_Zn(SbO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.523
_cell_length_b   7.180
_cell_length_c   17.138
_cell_angle_alpha   89.194
_cell_angle_beta   88.829
_cell_angle_gamma   63.081
_symmetry_Int_Tables_number   1
_cell_volume   715.610
_cell_formula_units_Z   6
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.600  0.212  0.083  1.0
  Zn  Zn1  1  0.442  0.673  0.340  1.0
  Zn  Zn2  1  0.117  0.206  0.165  1.0
  Zn  Zn3  1  0.721  0.248  0.652  1.0
  Zn  Zn4  1  0.571  0.485  0.496  1.0
  Zn  Zn5  1  0.836  0.871  0.792  1.0
  Sb  Sb6  1  0.130  0.739  0.177  1.0
  Sb  Sb7  1  0.016  0.429  0.358  1.0
  Sb  Sb8  1  0.049  0.333  0.996  1.0
  Sb  Sb9  1  0.632  0.725  0.171  1.0
  Sb  Sb10  1  0.519  0.006  0.534  1.0
  Sb  Sb11  1  0.307  0.898  0.718  1.0
  Sb  Sb12  1  0.046  0.997  0.464  1.0
  Sb  Sb13  1  0.779  0.406  0.826  1.0
  Sb  Sb14  1  0.677  0.067  0.299  1.0
  Sb  Sb15  1  0.340  0.329  0.822  1.0
  Sb  Sb16  1  0.982  0.564  0.627  1.0
  Sb  Sb17  1  0.311  0.765  0.941  1.0
  O  O18  1  0.271  0.312  0.078  1.0
  O  O19  1  0.993  0.412  0.244  1.0
  O  O20  1  0.877  0.246  0.074  1.0
  O  O21  1  0.673  0.996  0.162  1.0
  O  O22  1  0.720  0.432  0.391  1.0
  O  O23  1  0.428  0.579  0.233  1.0
  O  O24  1  0.284  0.062  0.622  1.0
  O  O25  1  0.624  0.808  0.286  1.0
  O  O26  1  0.296  0.710  0.443  1.0
  O  O27  1  0.293  0.910  0.139  1.0
  O  O28  1  0.181  0.123  0.384  1.0
  O  O29  1  0.011  0.931  0.267  1.0
  O  O30  1  0.957  0.069  0.731  1.0
  O  O31  1  0.800  0.867  0.599  1.0
  O  O32  1  0.751  0.483  0.590  1.0
  O  O33  1  0.491  0.042  0.771  1.0
  O  O34  1  0.585  0.289  0.896  1.0
  O  O35  1  0.799  0.959  0.410  1.0
  O  O36  1  0.532  0.421  0.749  1.0
  O  O37  1  0.530  0.269  0.558  1.0
  O  O38  1  0.243  0.067  0.941  1.0
  O  O39  1  0.123  0.760  0.854  1.0
  O  O40  1  0.867  0.608  0.737  1.0
  O  O41  1  0.596  0.689  0.877  1.0
[/CIF]
.