The crystal structure described by Mn(C2N3)2 crystallizes in the orthorhombic Pnnm space group. Mn(1) is bonded in an octahedral geometry to two equivalent N(2) and four equivalent N(1) atoms. C(1) is bonded in a linear geometry to one N(1) and one N(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to one Mn(1) and one C(1) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Mn(1) and two equivalent C(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mn(C2N3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.262
_cell_length_b   7.443
_cell_length_c   7.521
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   350.543
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.000  0.000  0.000  1.0
  Mn  Mn1  1  0.500  0.500  0.500  1.0
  C  C2  1  0.739  0.146  0.349  1.0
  C  C3  1  0.739  0.146  0.651  1.0
  C  C4  1  0.239  0.354  0.849  1.0
  C  C5  1  0.261  0.854  0.349  1.0
  C  C6  1  0.761  0.646  0.151  1.0
  C  C7  1  0.261  0.854  0.651  1.0
  C  C8  1  0.239  0.354  0.151  1.0
  C  C9  1  0.761  0.646  0.849  1.0
  N  N10  1  0.211  0.906  0.208  1.0
  N  N11  1  0.711  0.594  0.708  1.0
  N  N12  1  0.173  0.286  0.000  1.0
  N  N13  1  0.211  0.906  0.792  1.0
  N  N14  1  0.289  0.406  0.292  1.0
  N  N15  1  0.327  0.786  0.500  1.0
  N  N16  1  0.289  0.406  0.708  1.0
  N  N17  1  0.789  0.094  0.792  1.0
  N  N18  1  0.827  0.714  0.000  1.0
  N  N19  1  0.789  0.094  0.208  1.0
  N  N20  1  0.673  0.214  0.500  1.0
  N  N21  1  0.711  0.594  0.292  1.0
[/CIF]
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The crystal structure described by Mn(C2N3)2 crystallizes in the orthorhombic Pnnm space group. Mn(1) is bonded in an octahedral geometry to two equivalent N(2) and four equivalent N(1) atoms. C(1) is bonded in a linear geometry to one N(1) and one N(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to one Mn(1) and one C(1) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Mn(1) and two equivalent C(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mn(C2N3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.262
_cell_length_b   7.443
_cell_length_c   7.521
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   350.543
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.000  0.000  0.000  1.0
  Mn  Mn1  1  0.500  0.500  0.500  1.0
  C  C2  1  0.739  0.146  0.349  1.0
  C  C3  1  0.739  0.146  0.651  1.0
  C  C4  1  0.239  0.354  0.849  1.0
  C  C5  1  0.261  0.854  0.349  1.0
  C  C6  1  0.761  0.646  0.151  1.0
  C  C7  1  0.261  0.854  0.651  1.0
  C  C8  1  0.239  0.354  0.151  1.0
  C  C9  1  0.761  0.646  0.849  1.0
  N  N10  1  0.211  0.906  0.208  1.0
  N  N11  1  0.711  0.594  0.708  1.0
  N  N12  1  0.173  0.286  0.000  1.0
  N  N13  1  0.211  0.906  0.792  1.0
  N  N14  1  0.289  0.406  0.292  1.0
  N  N15  1  0.327  0.786  0.500  1.0
  N  N16  1  0.289  0.406  0.708  1.0
  N  N17  1  0.789  0.094  0.792  1.0
  N  N18  1  0.827  0.714  0.000  1.0
  N  N19  1  0.789  0.094  0.208  1.0
  N  N20  1  0.673  0.214  0.500  1.0
  N  N21  1  0.711  0.594  0.292  1.0
[/CIF]
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