The compound described by (CNH)2H2N2H4S2II is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four 1333-74-0 molecules, four hydriodic acid atoms, eight methanimine molecules, and four N2H4S2I clusters. In each N2H4S2I cluster, N(2) is bonded in a distorted single-bond geometry to one H(4), one S(1), and one I(2) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one S(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one N(2) atom. S(1) is bonded in a water-like geometry to one N(2) and one H(1) atom. I(2) is bonded in a bent 150 degrees geometry to two equivalent N(2) atoms. is represented by the CIF file [CIF]
data_H4CSIN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.503
_cell_length_b   9.503
_cell_length_c   12.731
_cell_angle_alpha   73.847
_cell_angle_beta   106.153
_cell_angle_gamma   140.713
_symmetry_Int_Tables_number   1
_cell_volume   695.509
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.732  0.348  0.767  1.0
  H  H1  1  0.348  0.732  0.733  1.0
  H  H2  1  0.268  0.652  0.233  1.0
  H  H3  1  0.652  0.268  0.267  1.0
  H  H4  1  0.990  0.215  0.986  1.0
  H  H5  1  0.215  0.990  0.514  1.0
  H  H6  1  0.010  0.785  0.014  1.0
  H  H7  1  0.785  0.010  0.486  1.0
  H  H8  1  0.592  0.553  0.271  1.0
  H  H9  1  0.553  0.592  0.229  1.0
  H  H10  1  0.408  0.447  0.729  1.0
  H  H11  1  0.447  0.408  0.771  1.0
  H  H12  1  0.629  0.831  0.849  1.0
  H  H13  1  0.831  0.629  0.651  1.0
  H  H14  1  0.371  0.169  0.151  1.0
  H  H15  1  0.169  0.371  0.349  1.0
  C  C16  1  0.291  0.505  0.903  1.0
  C  C17  1  0.505  0.291  0.597  1.0
  C  C18  1  0.709  0.495  0.097  1.0
  C  C19  1  0.495  0.709  0.403  1.0
  S  S20  1  0.543  0.924  0.687  1.0
  S  S21  1  0.924  0.543  0.813  1.0
  S  S22  1  0.457  0.076  0.313  1.0
  S  S23  1  0.076  0.457  0.187  1.0
  I  I24  1  0.000  0.500  0.500  1.0
  I  I25  1  0.500  0.000  0.000  1.0
  I  I26  1  0.095  0.095  0.250  1.0
  I  I27  1  0.905  0.905  0.750  1.0
  N  N28  1  0.131  0.344  0.948  1.0
  N  N29  1  0.344  0.131  0.552  1.0
  N  N30  1  0.869  0.656  0.052  1.0
  N  N31  1  0.656  0.869  0.448  1.0
  N  N32  1  0.718  0.948  0.782  1.0
  N  N33  1  0.948  0.718  0.718  1.0
  N  N34  1  0.282  0.052  0.218  1.0
  N  N35  1  0.052  0.282  0.282  1.0
[/CIF]
.
The compound described by (CNH)2H2N2H4S2II is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four 1333-74-0 molecules, four hydriodic acid atoms, eight methanimine molecules, and four N2H4S2I clusters. In each N2H4S2I cluster, N(2) is bonded in a distorted single-bond geometry to one H(4), one S(1), and one I(2) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one S(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one N(2) atom. S(1) is bonded in a water-like geometry to one N(2) and one H(1) atom. I(2) is bonded in a bent 150 degrees geometry to two equivalent N(2) atoms. is represented by the CIF file [CIF]
data_H4CSIN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.503
_cell_length_b   9.503
_cell_length_c   12.731
_cell_angle_alpha   73.847
_cell_angle_beta   106.153
_cell_angle_gamma   140.713
_symmetry_Int_Tables_number   1
_cell_volume   695.509
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.732  0.348  0.767  1.0
  H  H1  1  0.348  0.732  0.733  1.0
  H  H2  1  0.268  0.652  0.233  1.0
  H  H3  1  0.652  0.268  0.267  1.0
  H  H4  1  0.990  0.215  0.986  1.0
  H  H5  1  0.215  0.990  0.514  1.0
  H  H6  1  0.010  0.785  0.014  1.0
  H  H7  1  0.785  0.010  0.486  1.0
  H  H8  1  0.592  0.553  0.271  1.0
  H  H9  1  0.553  0.592  0.229  1.0
  H  H10  1  0.408  0.447  0.729  1.0
  H  H11  1  0.447  0.408  0.771  1.0
  H  H12  1  0.629  0.831  0.849  1.0
  H  H13  1  0.831  0.629  0.651  1.0
  H  H14  1  0.371  0.169  0.151  1.0
  H  H15  1  0.169  0.371  0.349  1.0
  C  C16  1  0.291  0.505  0.903  1.0
  C  C17  1  0.505  0.291  0.597  1.0
  C  C18  1  0.709  0.495  0.097  1.0
  C  C19  1  0.495  0.709  0.403  1.0
  S  S20  1  0.543  0.924  0.687  1.0
  S  S21  1  0.924  0.543  0.813  1.0
  S  S22  1  0.457  0.076  0.313  1.0
  S  S23  1  0.076  0.457  0.187  1.0
  I  I24  1  0.000  0.500  0.500  1.0
  I  I25  1  0.500  0.000  0.000  1.0
  I  I26  1  0.095  0.095  0.250  1.0
  I  I27  1  0.905  0.905  0.750  1.0
  N  N28  1  0.131  0.344  0.948  1.0
  N  N29  1  0.344  0.131  0.552  1.0
  N  N30  1  0.869  0.656  0.052  1.0
  N  N31  1  0.656  0.869  0.448  1.0
  N  N32  1  0.718  0.948  0.782  1.0
  N  N33  1  0.948  0.718  0.718  1.0
  N  N34  1  0.282  0.052  0.218  1.0
  N  N35  1  0.052  0.282  0.282  1.0
[/CIF]
.