The structure described by MgLaWCrO6 is Orthorhombic Perovskite-derived structured and crystallizes in the triclinic P1 space group. Mg(1) is bonded in a 5-coordinate geometry to one O(2), one O(3), one O(4), one O(5), and one O(6) atom. La(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(3), one O(4), and one O(5) atom. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share corners with six equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 31-43°. Cr(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form CrO6 octahedra that share corners with six equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 31-43°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one La(1), one W(1), and one Cr(1) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Mg(1), one La(1), one W(1), and one Cr(1) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Mg(1), one La(1), one W(1), and one Cr(1) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Mg(1), one La(1), one W(1), and one Cr(1) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one Mg(1), one La(1), one W(1), and one Cr(1) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Mg(1), one W(1), and one Cr(1) atom. is represented by the CIF file [CIF]
data_LaMgCrWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.433
_cell_length_b   5.601
_cell_length_c   5.563
_cell_angle_alpha   59.475
_cell_angle_beta   118.545
_cell_angle_gamma   89.982
_symmetry_Int_Tables_number   1
_cell_volume   121.315
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.760  0.261  0.498  1.0
  Mg  Mg1  1  0.220  0.772  0.508  1.0
  Cr  Cr2  1  0.999  0.510  0.997  1.0
  W  W3  1  0.500  0.010  0.001  1.0
  O  O4  1  0.343  0.258  0.485  1.0
  O  O5  1  0.218  0.360  0.864  1.0
  O  O6  1  0.820  0.690  0.133  1.0
  O  O7  1  0.187  0.823  0.865  1.0
  O  O8  1  0.852  0.163  0.138  1.0
  O  O9  1  0.611  0.756  0.512  1.0
[/CIF]
.
The structure described by MgLaWCrO6 is Orthorhombic Perovskite-derived structured and crystallizes in the triclinic P1 space group. Mg(1) is bonded in a 5-coordinate geometry to one O(2), one O(3), one O(4), one O(5), and one O(6) atom. La(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(3), one O(4), and one O(5) atom. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share corners with six equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 31-43°. Cr(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form CrO6 octahedra that share corners with six equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 31-43°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one La(1), one W(1), and one Cr(1) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Mg(1), one La(1), one W(1), and one Cr(1) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Mg(1), one La(1), one W(1), and one Cr(1) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Mg(1), one La(1), one W(1), and one Cr(1) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one Mg(1), one La(1), one W(1), and one Cr(1) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Mg(1), one W(1), and one Cr(1) atom. is represented by the CIF file [CIF]
data_LaMgCrWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.433
_cell_length_b   5.601
_cell_length_c   5.563
_cell_angle_alpha   59.475
_cell_angle_beta   118.545
_cell_angle_gamma   89.982
_symmetry_Int_Tables_number   1
_cell_volume   121.315
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.760  0.261  0.498  1.0
  Mg  Mg1  1  0.220  0.772  0.508  1.0
  Cr  Cr2  1  0.999  0.510  0.997  1.0
  W  W3  1  0.500  0.010  0.001  1.0
  O  O4  1  0.343  0.258  0.485  1.0
  O  O5  1  0.218  0.360  0.864  1.0
  O  O6  1  0.820  0.690  0.133  1.0
  O  O7  1  0.187  0.823  0.865  1.0
  O  O8  1  0.852  0.163  0.138  1.0
  O  O9  1  0.611  0.756  0.512  1.0
[/CIF]
.