The crystal structure described by AlCl3AlTeCl4Te is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two aluminum trichloride molecules, one ditelluride molecule, and one AlTeCl4 cluster. In the AlTeCl4 cluster, Al(1) is bonded in a tetrahedral geometry to one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. Te(1) is bonded in a distorted bent 120 degrees geometry to one Te(1) and one Cl(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted water-like geometry to one Al(1) and one Te(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Al(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Al(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Al(1) atom. is represented by the CIF card [CIF]
data_Al2Te2Cl7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.699
_cell_length_b   11.307
_cell_length_c   12.475
_cell_angle_alpha   93.142
_cell_angle_beta   93.646
_cell_angle_gamma   99.210
_symmetry_Int_Tables_number   1
_cell_volume   1206.234
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  0.615  0.835  0.701  1.0
  Al  Al1  1  0.385  0.165  0.299  1.0
  Al  Al2  1  0.806  0.412  0.845  1.0
  Al  Al3  1  0.194  0.588  0.155  1.0
  Te  Te4  1  0.930  0.897  0.960  1.0
  Te  Te5  1  0.070  0.103  0.040  1.0
  Te  Te6  1  0.861  0.453  0.470  1.0
  Te  Te7  1  0.139  0.547  0.530  1.0
  Cl  Cl8  1  0.608  0.828  0.881  1.0
  Cl  Cl9  1  0.392  0.172  0.119  1.0
  Cl  Cl10  1  0.858  0.882  0.672  1.0
  Cl  Cl11  1  0.142  0.118  0.328  1.0
  Cl  Cl12  1  0.529  0.655  0.635  1.0
  Cl  Cl13  1  0.471  0.345  0.365  1.0
  Cl  Cl14  1  0.472  0.961  0.652  1.0
  Cl  Cl15  1  0.528  0.039  0.348  1.0
  Cl  Cl16  1  0.794  0.371  0.006  1.0
  Cl  Cl17  1  0.206  0.629  0.994  1.0
  Cl  Cl18  1  0.760  0.274  0.725  1.0
  Cl  Cl19  1  0.240  0.726  0.275  1.0
  Cl  Cl20  1  0.863  0.588  0.804  1.0
  Cl  Cl21  1  0.137  0.412  0.196  1.0
[/CIF]
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The crystal structure described by AlCl3AlTeCl4Te is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two aluminum trichloride molecules, one ditelluride molecule, and one AlTeCl4 cluster. In the AlTeCl4 cluster, Al(1) is bonded in a tetrahedral geometry to one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. Te(1) is bonded in a distorted bent 120 degrees geometry to one Te(1) and one Cl(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted water-like geometry to one Al(1) and one Te(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Al(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Al(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Al(1) atom. is represented by the CIF card [CIF]
data_Al2Te2Cl7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.699
_cell_length_b   11.307
_cell_length_c   12.475
_cell_angle_alpha   93.142
_cell_angle_beta   93.646
_cell_angle_gamma   99.210
_symmetry_Int_Tables_number   1
_cell_volume   1206.234
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  0.615  0.835  0.701  1.0
  Al  Al1  1  0.385  0.165  0.299  1.0
  Al  Al2  1  0.806  0.412  0.845  1.0
  Al  Al3  1  0.194  0.588  0.155  1.0
  Te  Te4  1  0.930  0.897  0.960  1.0
  Te  Te5  1  0.070  0.103  0.040  1.0
  Te  Te6  1  0.861  0.453  0.470  1.0
  Te  Te7  1  0.139  0.547  0.530  1.0
  Cl  Cl8  1  0.608  0.828  0.881  1.0
  Cl  Cl9  1  0.392  0.172  0.119  1.0
  Cl  Cl10  1  0.858  0.882  0.672  1.0
  Cl  Cl11  1  0.142  0.118  0.328  1.0
  Cl  Cl12  1  0.529  0.655  0.635  1.0
  Cl  Cl13  1  0.471  0.345  0.365  1.0
  Cl  Cl14  1  0.472  0.961  0.652  1.0
  Cl  Cl15  1  0.528  0.039  0.348  1.0
  Cl  Cl16  1  0.794  0.371  0.006  1.0
  Cl  Cl17  1  0.206  0.629  0.994  1.0
  Cl  Cl18  1  0.760  0.274  0.725  1.0
  Cl  Cl19  1  0.240  0.726  0.275  1.0
  Cl  Cl20  1  0.863  0.588  0.804  1.0
  Cl  Cl21  1  0.137  0.412  0.196  1.0
[/CIF]
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