The compound described by UNO8NO2 is Indium-derived structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two nitrous acid molecules and two UNO8 clusters. In each UNO8 cluster, U(1) is bonded in a distorted linear geometry to one O(1), one O(2), two equivalent O(5), two equivalent O(6), and two equivalent O(7) atoms. N(1) is bonded in a bent 120 degrees geometry to two equivalent O(6) atoms. There are five inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one U(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one U(1) atom. In the third O site, O(5) is bonded in a 2-coordinate geometry to one U(1) and one O(7) atom. In the fourth O site, O(6) is bonded in a distorted L-shaped geometry to one U(1) and one N(1) atom. In the fifth O site, O(7) is bonded in a distorted L-shaped geometry to one U(1) and one O(5) atom. is represented by the CIF file [CIF]
data_U(NO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.341
_cell_length_b   7.341
_cell_length_c   7.765
_cell_angle_alpha   78.895
_cell_angle_beta   78.895
_cell_angle_gamma   61.025
_symmetry_Int_Tables_number   1
_cell_volume   356.784
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  U  U0  1  0.996  0.996  0.009  1.0
  N  N1  1  0.224  0.224  0.798  1.0
  N  N2  1  0.272  0.272  0.399  1.0
  O  O3  1  0.052  0.052  0.202  1.0
  O  O4  1  0.946  0.946  0.810  1.0
  O  O5  1  0.353  0.353  0.453  1.0
  O  O6  1  0.175  0.175  0.455  1.0
  O  O7  1  0.633  0.262  0.054  1.0
  O  O8  1  0.262  0.633  0.054  1.0
  O  O9  1  0.031  0.319  0.850  1.0
  O  O10  1  0.319  0.031  0.850  1.0
  O  O11  1  0.087  0.641  0.139  1.0
  O  O12  1  0.641  0.087  0.139  1.0
[/CIF]
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The compound described by UNO8NO2 is Indium-derived structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two nitrous acid molecules and two UNO8 clusters. In each UNO8 cluster, U(1) is bonded in a distorted linear geometry to one O(1), one O(2), two equivalent O(5), two equivalent O(6), and two equivalent O(7) atoms. N(1) is bonded in a bent 120 degrees geometry to two equivalent O(6) atoms. There are five inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one U(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one U(1) atom. In the third O site, O(5) is bonded in a 2-coordinate geometry to one U(1) and one O(7) atom. In the fourth O site, O(6) is bonded in a distorted L-shaped geometry to one U(1) and one N(1) atom. In the fifth O site, O(7) is bonded in a distorted L-shaped geometry to one U(1) and one O(5) atom. is represented by the CIF file [CIF]
data_U(NO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.341
_cell_length_b   7.341
_cell_length_c   7.765
_cell_angle_alpha   78.895
_cell_angle_beta   78.895
_cell_angle_gamma   61.025
_symmetry_Int_Tables_number   1
_cell_volume   356.784
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  U  U0  1  0.996  0.996  0.009  1.0
  N  N1  1  0.224  0.224  0.798  1.0
  N  N2  1  0.272  0.272  0.399  1.0
  O  O3  1  0.052  0.052  0.202  1.0
  O  O4  1  0.946  0.946  0.810  1.0
  O  O5  1  0.353  0.353  0.453  1.0
  O  O6  1  0.175  0.175  0.455  1.0
  O  O7  1  0.633  0.262  0.054  1.0
  O  O8  1  0.262  0.633  0.054  1.0
  O  O9  1  0.031  0.319  0.850  1.0
  O  O10  1  0.319  0.031  0.850  1.0
  O  O11  1  0.087  0.641  0.139  1.0
  O  O12  1  0.641  0.087  0.139  1.0
[/CIF]
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