The material structure described by TmWO5 crystallizes in the monoclinic P2_1/c space group. Tm(1) is bonded in a 8-coordinate geometry to one O(4), one O(5), two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. W(1) is bonded in a distorted trigonal bipyramidal geometry to one O(1), one O(2), one O(3), one O(4), and one O(5) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a trigonal non-coplanar geometry to two equivalent Tm(1) and one W(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent Tm(1) and one W(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to two equivalent Tm(1) and one W(1) atom. In the fourth O site, O(4) is bonded in a linear geometry to one Tm(1) and one W(1) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Tm(1) and one W(1) atom. is represented by the CIF card [CIF]
data_TmWO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.274
_cell_length_b   6.513
_cell_length_c   12.548
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   109.318
_symmetry_Int_Tables_number   1
_cell_volume   406.729
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tm  Tm0  1  0.145  0.786  0.445  1.0
  Tm  Tm1  1  0.855  0.214  0.555  1.0
  Tm  Tm2  1  0.355  0.714  0.945  1.0
  Tm  Tm3  1  0.645  0.286  0.055  1.0
  W  W4  1  0.952  0.847  0.139  1.0
  W  W5  1  0.048  0.153  0.861  1.0
  W  W6  1  0.548  0.653  0.639  1.0
  W  W7  1  0.452  0.347  0.361  1.0
  O  O8  1  0.047  0.557  0.085  1.0
  O  O9  1  0.953  0.443  0.915  1.0
  O  O10  1  0.453  0.943  0.585  1.0
  O  O11  1  0.547  0.057  0.415  1.0
  O  O12  1  0.861  0.846  0.572  1.0
  O  O13  1  0.139  0.154  0.428  1.0
  O  O14  1  0.639  0.654  0.072  1.0
  O  O15  1  0.361  0.346  0.928  1.0
  O  O16  1  0.273  0.972  0.064  1.0
  O  O17  1  0.727  0.028  0.936  1.0
  O  O18  1  0.227  0.528  0.564  1.0
  O  O19  1  0.773  0.472  0.436  1.0
  O  O20  1  0.998  0.791  0.276  1.0
  O  O21  1  0.002  0.209  0.724  1.0
  O  O22  1  0.502  0.709  0.776  1.0
  O  O23  1  0.498  0.291  0.224  1.0
  O  O24  1  0.155  0.917  0.851  1.0
  O  O25  1  0.845  0.083  0.149  1.0
  O  O26  1  0.345  0.583  0.351  1.0
  O  O27  1  0.655  0.417  0.649  1.0
[/CIF]
.
The material structure described by TmWO5 crystallizes in the monoclinic P2_1/c space group. Tm(1) is bonded in a 8-coordinate geometry to one O(4), one O(5), two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. W(1) is bonded in a distorted trigonal bipyramidal geometry to one O(1), one O(2), one O(3), one O(4), and one O(5) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a trigonal non-coplanar geometry to two equivalent Tm(1) and one W(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent Tm(1) and one W(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to two equivalent Tm(1) and one W(1) atom. In the fourth O site, O(4) is bonded in a linear geometry to one Tm(1) and one W(1) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Tm(1) and one W(1) atom. is represented by the CIF card [CIF]
data_TmWO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.274
_cell_length_b   6.513
_cell_length_c   12.548
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   109.318
_symmetry_Int_Tables_number   1
_cell_volume   406.729
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tm  Tm0  1  0.145  0.786  0.445  1.0
  Tm  Tm1  1  0.855  0.214  0.555  1.0
  Tm  Tm2  1  0.355  0.714  0.945  1.0
  Tm  Tm3  1  0.645  0.286  0.055  1.0
  W  W4  1  0.952  0.847  0.139  1.0
  W  W5  1  0.048  0.153  0.861  1.0
  W  W6  1  0.548  0.653  0.639  1.0
  W  W7  1  0.452  0.347  0.361  1.0
  O  O8  1  0.047  0.557  0.085  1.0
  O  O9  1  0.953  0.443  0.915  1.0
  O  O10  1  0.453  0.943  0.585  1.0
  O  O11  1  0.547  0.057  0.415  1.0
  O  O12  1  0.861  0.846  0.572  1.0
  O  O13  1  0.139  0.154  0.428  1.0
  O  O14  1  0.639  0.654  0.072  1.0
  O  O15  1  0.361  0.346  0.928  1.0
  O  O16  1  0.273  0.972  0.064  1.0
  O  O17  1  0.727  0.028  0.936  1.0
  O  O18  1  0.227  0.528  0.564  1.0
  O  O19  1  0.773  0.472  0.436  1.0
  O  O20  1  0.998  0.791  0.276  1.0
  O  O21  1  0.002  0.209  0.724  1.0
  O  O22  1  0.502  0.709  0.776  1.0
  O  O23  1  0.498  0.291  0.224  1.0
  O  O24  1  0.155  0.917  0.851  1.0
  O  O25  1  0.845  0.083  0.149  1.0
  O  O26  1  0.345  0.583  0.351  1.0
  O  O27  1  0.655  0.417  0.649  1.0
[/CIF]
.