The material described by Th(CoP)2 crystallizes in the tetragonal P4/nmm space group. Th(1) is bonded in a 16-coordinate geometry to four equivalent Co(1), four equivalent Co(2), four equivalent P(1), and four equivalent P(2) atoms. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a 4-coordinate geometry to four equivalent Th(1) and four equivalent P(2) atoms. In the second Co site, Co(2) is bonded in a 5-coordinate geometry to four equivalent Th(1), one P(2), and four equivalent P(1) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 4-coordinate geometry to four equivalent Th(1) and four equivalent Co(2) atoms. In the second P site, P(2) is bonded in a 5-coordinate geometry to four equivalent Th(1), one Co(2), and four equivalent Co(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Th(CoP)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.027
_cell_length_b   4.027
_cell_length_c   9.044
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   146.693
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Th  Th0  1  0.000  0.500  0.249  1.0
  Th  Th1  1  0.500  0.000  0.751  1.0
  Co  Co2  1  0.000  0.000  0.000  1.0
  Co  Co3  1  0.500  0.500  0.000  1.0
  Co  Co4  1  0.000  0.500  0.609  1.0
  Co  Co5  1  0.500  0.000  0.391  1.0
  P  P6  1  0.000  0.000  0.500  1.0
  P  P7  1  0.500  0.500  0.500  1.0
  P  P8  1  0.000  0.500  0.870  1.0
  P  P9  1  0.500  0.000  0.130  1.0
[/CIF]
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The material described by Th(CoP)2 crystallizes in the tetragonal P4/nmm space group. Th(1) is bonded in a 16-coordinate geometry to four equivalent Co(1), four equivalent Co(2), four equivalent P(1), and four equivalent P(2) atoms. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a 4-coordinate geometry to four equivalent Th(1) and four equivalent P(2) atoms. In the second Co site, Co(2) is bonded in a 5-coordinate geometry to four equivalent Th(1), one P(2), and four equivalent P(1) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 4-coordinate geometry to four equivalent Th(1) and four equivalent Co(2) atoms. In the second P site, P(2) is bonded in a 5-coordinate geometry to four equivalent Th(1), one Co(2), and four equivalent Co(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Th(CoP)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.027
_cell_length_b   4.027
_cell_length_c   9.044
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   146.693
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Th  Th0  1  0.000  0.500  0.249  1.0
  Th  Th1  1  0.500  0.000  0.751  1.0
  Co  Co2  1  0.000  0.000  0.000  1.0
  Co  Co3  1  0.500  0.500  0.000  1.0
  Co  Co4  1  0.000  0.500  0.609  1.0
  Co  Co5  1  0.500  0.000  0.391  1.0
  P  P6  1  0.000  0.000  0.500  1.0
  P  P7  1  0.500  0.500  0.500  1.0
  P  P8  1  0.000  0.500  0.870  1.0
  P  P9  1  0.500  0.000  0.130  1.0
[/CIF]
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