The compound described by V3OF7 crystallizes in the triclinic P1 space group. There are six inequivalent V sites. In the first V site, V(1) is bonded to one F(10), one F(3), one F(4), one F(9), and two equivalent F(2) atoms to form VF6 octahedra that share  a cornercorner with one V(2)OF5 octahedra,  a cornercorner with one V(3)OF5 octahedra,  a cornercorner with one V(5)OF5 octahedra,  a cornercorner with one V(6)OF5 octahedra, and corners with two equivalent V(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 2-32°. In the second V site, V(2) is bonded to one O(1), one F(13), one F(4), one F(7), and two equivalent F(11) atoms to form VOF5 octahedra that share  a cornercorner with one V(1)F6 octahedra,  a cornercorner with one V(4)F6 octahedra,  a cornercorner with one V(5)OF5 octahedra, corners with two equivalent V(2)OF5 octahedra, and edges with two equivalent V(6)OF5 octahedra. The corner-sharing octahedral tilt angles range from 26-31°. In the third V site, V(3) is bonded to one O(2), one F(12), one F(6), one F(9), and two equivalent F(14) atoms to form distorted VOF5 octahedra that share  a cornercorner with one V(1)F6 octahedra,  a cornercorner with one V(4)F6 octahedra,  a cornercorner with one V(6)OF5 octahedra, corners with two equivalent V(3)OF5 octahedra, and edges with two equivalent V(5)OF5 octahedra. The corner-sharing octahedral tilt angles range from 26-31°. In the fourth V site, V(4) is bonded to one F(5), one F(6), one F(7), one F(8), and two equivalent F(1) atoms to form VF6 octahedra that share  a cornercorner with one V(2)OF5 octahedra,  a cornercorner with one V(3)OF5 octahedra,  a cornercorner with one V(5)OF5 octahedra,  a cornercorner with one V(6)OF5 octahedra, and corners with two equivalent V(4)F6 octahedra. The corner-sharing octahedral tilt angles range from 2-31°. In the fifth V site, V(5) is bonded to one O(1), one F(14), one F(3), one F(8), and two equivalent F(12) atoms to form VOF5 octahedra that share  a cornercorner with one V(1)F6 octahedra,  a cornercorner with one V(4)F6 octahedra,  a cornercorner with one V(2)OF5 octahedra, corners with two equivalent V(5)OF5 octahedra, and edges with two equivalent V(3)OF5 octahedra. The corner-sharing octahedral tilt angles range from 26-32°. In the sixth V site, V(6) is bonded to one O(2), one F(10), one F(11), one F(5), and two equivalent F(13) atoms to form VOF5 octahedra that share  a cornercorner with one V(1)F6 octahedra,  a cornercorner with one V(4)F6 octahedra,  a cornercorner with one V(3)OF5 octahedra, corners with two equivalent V(6)OF5 octahedra, and edges with two equivalent V(2)OF5 octahedra. The corner-sharing octahedral tilt angles range from 26-30°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one V(2) and one V(5) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one V(3) and one V(6) atom. There are fourteen inequivalent F sites. In the first F site, F(1) is bonded in a linear geometry to two equivalent V(4) atoms. In the second F site, F(2) is bonded in a linear geometry to two equivalent V(1) atoms. In the third F site, F(3) is bonded in a bent 150 degrees geometry to one V(1) and one V(5) atom. In the fourth F site, F(4) is bonded in a bent 150 degrees geometry to one V(1) and one V(2) atom. In the fifth F site, F(5) is bonded in a bent 150 degrees geometry to one V(4) and one V(6) atom. In the sixth F site, F(6) is bonded in a bent 150 degrees geometry to one V(3) and one V(4) atom. In the seventh F site, F(7) is bonded in a bent 150 degrees geometry to one V(2) and one V(4) atom. In the eighth F site, F(8) is bonded in a bent 150 degrees geometry to one V(4) and one V(5) atom. In the ninth F site, F(9) is bonded in a bent 150 degrees geometry to one V(1) and one V(3) atom. In the tenth F site, F(10) is bonded in a bent 150 degrees geometry to one V(1) and one V(6) atom. In the eleventh F site, F(11) is bonded in a distorted T-shaped geometry to one V(6) and two equivalent V(2) atoms. In the twelfth F site, F(12) is bonded in a distorted T-shaped geometry to one V(3) and two equivalent V(5) atoms. In the thirteenth F site, F(13) is bonded in a distorted T-shaped geometry to one V(2) and two equivalent V(6) atoms. In the fourteenth F site, F(14) is bonded in a distorted T-shaped geometry to one V(5) and two equivalent V(3) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_V3OF7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.033
_cell_length_b   7.982
_cell_length_c   10.010
_cell_angle_alpha   90.163
_cell_angle_beta   89.956
_cell_angle_gamma   104.650
_symmetry_Int_Tables_number   1
_cell_volume   311.748
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.461  0.920  0.749  1.0
  V  V1  1  0.679  0.358  0.928  1.0
  V  V2  1  0.321  0.641  0.428  1.0
  V  V3  1  0.539  0.080  0.251  1.0
  V  V4  1  0.679  0.359  0.573  1.0
  V  V5  1  0.321  0.644  0.072  1.0
  O  O6  1  0.711  0.422  0.751  1.0
  O  O7  1  0.292  0.580  0.250  1.0
  F  F8  1  0.037  0.075  0.250  1.0
  F  F9  1  0.963  0.926  0.748  1.0
  F  F10  1  0.556  0.111  0.611  1.0
  F  F11  1  0.550  0.104  0.882  1.0
  F  F12  1  0.448  0.894  0.117  1.0
  F  F13  1  0.443  0.889  0.387  1.0
  F  F14  1  0.634  0.267  0.114  1.0
  F  F15  1  0.631  0.263  0.382  1.0
  F  F16  1  0.368  0.736  0.617  1.0
  F  F17  1  0.368  0.734  0.886  1.0
  F  F18  1  0.199  0.398  0.969  1.0
  F  F19  1  0.201  0.404  0.535  1.0
  F  F20  1  0.802  0.603  0.034  1.0
  F  F21  1  0.797  0.595  0.467  1.0
[/CIF]
.
The compound described by V3OF7 crystallizes in the triclinic P1 space group. There are six inequivalent V sites. In the first V site, V(1) is bonded to one F(10), one F(3), one F(4), one F(9), and two equivalent F(2) atoms to form VF6 octahedra that share  a cornercorner with one V(2)OF5 octahedra,  a cornercorner with one V(3)OF5 octahedra,  a cornercorner with one V(5)OF5 octahedra,  a cornercorner with one V(6)OF5 octahedra, and corners with two equivalent V(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 2-32°. In the second V site, V(2) is bonded to one O(1), one F(13), one F(4), one F(7), and two equivalent F(11) atoms to form VOF5 octahedra that share  a cornercorner with one V(1)F6 octahedra,  a cornercorner with one V(4)F6 octahedra,  a cornercorner with one V(5)OF5 octahedra, corners with two equivalent V(2)OF5 octahedra, and edges with two equivalent V(6)OF5 octahedra. The corner-sharing octahedral tilt angles range from 26-31°. In the third V site, V(3) is bonded to one O(2), one F(12), one F(6), one F(9), and two equivalent F(14) atoms to form distorted VOF5 octahedra that share  a cornercorner with one V(1)F6 octahedra,  a cornercorner with one V(4)F6 octahedra,  a cornercorner with one V(6)OF5 octahedra, corners with two equivalent V(3)OF5 octahedra, and edges with two equivalent V(5)OF5 octahedra. The corner-sharing octahedral tilt angles range from 26-31°. In the fourth V site, V(4) is bonded to one F(5), one F(6), one F(7), one F(8), and two equivalent F(1) atoms to form VF6 octahedra that share  a cornercorner with one V(2)OF5 octahedra,  a cornercorner with one V(3)OF5 octahedra,  a cornercorner with one V(5)OF5 octahedra,  a cornercorner with one V(6)OF5 octahedra, and corners with two equivalent V(4)F6 octahedra. The corner-sharing octahedral tilt angles range from 2-31°. In the fifth V site, V(5) is bonded to one O(1), one F(14), one F(3), one F(8), and two equivalent F(12) atoms to form VOF5 octahedra that share  a cornercorner with one V(1)F6 octahedra,  a cornercorner with one V(4)F6 octahedra,  a cornercorner with one V(2)OF5 octahedra, corners with two equivalent V(5)OF5 octahedra, and edges with two equivalent V(3)OF5 octahedra. The corner-sharing octahedral tilt angles range from 26-32°. In the sixth V site, V(6) is bonded to one O(2), one F(10), one F(11), one F(5), and two equivalent F(13) atoms to form VOF5 octahedra that share  a cornercorner with one V(1)F6 octahedra,  a cornercorner with one V(4)F6 octahedra,  a cornercorner with one V(3)OF5 octahedra, corners with two equivalent V(6)OF5 octahedra, and edges with two equivalent V(2)OF5 octahedra. The corner-sharing octahedral tilt angles range from 26-30°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one V(2) and one V(5) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one V(3) and one V(6) atom. There are fourteen inequivalent F sites. In the first F site, F(1) is bonded in a linear geometry to two equivalent V(4) atoms. In the second F site, F(2) is bonded in a linear geometry to two equivalent V(1) atoms. In the third F site, F(3) is bonded in a bent 150 degrees geometry to one V(1) and one V(5) atom. In the fourth F site, F(4) is bonded in a bent 150 degrees geometry to one V(1) and one V(2) atom. In the fifth F site, F(5) is bonded in a bent 150 degrees geometry to one V(4) and one V(6) atom. In the sixth F site, F(6) is bonded in a bent 150 degrees geometry to one V(3) and one V(4) atom. In the seventh F site, F(7) is bonded in a bent 150 degrees geometry to one V(2) and one V(4) atom. In the eighth F site, F(8) is bonded in a bent 150 degrees geometry to one V(4) and one V(5) atom. In the ninth F site, F(9) is bonded in a bent 150 degrees geometry to one V(1) and one V(3) atom. In the tenth F site, F(10) is bonded in a bent 150 degrees geometry to one V(1) and one V(6) atom. In the eleventh F site, F(11) is bonded in a distorted T-shaped geometry to one V(6) and two equivalent V(2) atoms. In the twelfth F site, F(12) is bonded in a distorted T-shaped geometry to one V(3) and two equivalent V(5) atoms. In the thirteenth F site, F(13) is bonded in a distorted T-shaped geometry to one V(2) and two equivalent V(6) atoms. In the fourteenth F site, F(14) is bonded in a distorted T-shaped geometry to one V(5) and two equivalent V(3) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_V3OF7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.033
_cell_length_b   7.982
_cell_length_c   10.010
_cell_angle_alpha   90.163
_cell_angle_beta   89.956
_cell_angle_gamma   104.650
_symmetry_Int_Tables_number   1
_cell_volume   311.748
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.461  0.920  0.749  1.0
  V  V1  1  0.679  0.358  0.928  1.0
  V  V2  1  0.321  0.641  0.428  1.0
  V  V3  1  0.539  0.080  0.251  1.0
  V  V4  1  0.679  0.359  0.573  1.0
  V  V5  1  0.321  0.644  0.072  1.0
  O  O6  1  0.711  0.422  0.751  1.0
  O  O7  1  0.292  0.580  0.250  1.0
  F  F8  1  0.037  0.075  0.250  1.0
  F  F9  1  0.963  0.926  0.748  1.0
  F  F10  1  0.556  0.111  0.611  1.0
  F  F11  1  0.550  0.104  0.882  1.0
  F  F12  1  0.448  0.894  0.117  1.0
  F  F13  1  0.443  0.889  0.387  1.0
  F  F14  1  0.634  0.267  0.114  1.0
  F  F15  1  0.631  0.263  0.382  1.0
  F  F16  1  0.368  0.736  0.617  1.0
  F  F17  1  0.368  0.734  0.886  1.0
  F  F18  1  0.199  0.398  0.969  1.0
  F  F19  1  0.201  0.404  0.535  1.0
  F  F20  1  0.802  0.603  0.034  1.0
  F  F21  1  0.797  0.595  0.467  1.0
[/CIF]
.