The material structure described by KCdC3(NO)3 crystallizes in the orthorhombic Pnma space group. K(1) is bonded in a 8-coordinate geometry to one N(2), two equivalent N(1), one O(3), two equivalent O(1), and two equivalent O(2) atoms. Cd(1) is bonded to one N(1), two equivalent N(2), and three equivalent N(3) atoms to form edge-sharing CdN6 octahedra. There are three inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one N(3) and one O(3) atom. In the second C site, C(2) is bonded in a linear geometry to one N(2) and one O(1) atom. In the third C site, C(3) is bonded in a linear geometry to one N(1) and one O(2) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a 4-coordinate geometry to two equivalent K(1), one Cd(1), and one C(3) atom. In the second N site, N(2) is bonded in a 3-coordinate geometry to one K(1), two equivalent Cd(1), and one C(2) atom. In the third N site, N(3) is bonded in a 4-coordinate geometry to three equivalent Cd(1) and one C(1) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent K(1) and one C(2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent K(1) and one C(3) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one K(1) and one C(1) atom. is represented by the CIF card [CIF]
data_KCdC3(NO)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.773
_cell_length_b   10.224
_cell_length_c   18.555
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   715.771
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.750  0.428  0.835  1.0
  K  K1  1  0.250  0.572  0.165  1.0
  K  K2  1  0.750  0.928  0.665  1.0
  K  K3  1  0.250  0.072  0.335  1.0
  Cd  Cd4  1  0.750  0.362  0.456  1.0
  Cd  Cd5  1  0.250  0.638  0.544  1.0
  Cd  Cd6  1  0.750  0.862  0.044  1.0
  Cd  Cd7  1  0.250  0.138  0.956  1.0
  C  C8  1  0.250  0.084  0.124  1.0
  C  C9  1  0.250  0.584  0.376  1.0
  C  C10  1  0.750  0.416  0.624  1.0
  C  C11  1  0.750  0.916  0.876  1.0
  C  C12  1  0.250  0.139  0.530  1.0
  C  C13  1  0.750  0.861  0.470  1.0
  C  C14  1  0.250  0.639  0.970  1.0
  C  C15  1  0.750  0.361  0.030  1.0
  C  C16  1  0.750  0.352  0.288  1.0
  C  C17  1  0.250  0.648  0.712  1.0
  C  C18  1  0.750  0.852  0.212  1.0
  C  C19  1  0.250  0.148  0.788  1.0
  N  N20  1  0.750  0.786  0.158  1.0
  N  N21  1  0.750  0.266  0.991  1.0
  N  N22  1  0.250  0.023  0.067  1.0
  N  N23  1  0.750  0.977  0.933  1.0
  N  N24  1  0.250  0.523  0.433  1.0
  N  N25  1  0.750  0.477  0.567  1.0
  N  N26  1  0.250  0.234  0.491  1.0
  N  N27  1  0.750  0.766  0.509  1.0
  N  N28  1  0.750  0.286  0.342  1.0
  N  N29  1  0.250  0.714  0.658  1.0
  N  N30  1  0.250  0.214  0.842  1.0
  N  N31  1  0.250  0.734  0.009  1.0
  O  O32  1  0.250  0.544  0.932  1.0
  O  O33  1  0.250  0.083  0.734  1.0
  O  O34  1  0.750  0.857  0.821  1.0
  O  O35  1  0.250  0.643  0.321  1.0
  O  O36  1  0.750  0.456  0.068  1.0
  O  O37  1  0.750  0.357  0.679  1.0
  O  O38  1  0.250  0.044  0.568  1.0
  O  O39  1  0.750  0.956  0.432  1.0
  O  O40  1  0.750  0.417  0.234  1.0
  O  O41  1  0.250  0.583  0.766  1.0
  O  O42  1  0.250  0.143  0.179  1.0
  O  O43  1  0.750  0.917  0.266  1.0
[/CIF]
.
The material structure described by KCdC3(NO)3 crystallizes in the orthorhombic Pnma space group. K(1) is bonded in a 8-coordinate geometry to one N(2), two equivalent N(1), one O(3), two equivalent O(1), and two equivalent O(2) atoms. Cd(1) is bonded to one N(1), two equivalent N(2), and three equivalent N(3) atoms to form edge-sharing CdN6 octahedra. There are three inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one N(3) and one O(3) atom. In the second C site, C(2) is bonded in a linear geometry to one N(2) and one O(1) atom. In the third C site, C(3) is bonded in a linear geometry to one N(1) and one O(2) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a 4-coordinate geometry to two equivalent K(1), one Cd(1), and one C(3) atom. In the second N site, N(2) is bonded in a 3-coordinate geometry to one K(1), two equivalent Cd(1), and one C(2) atom. In the third N site, N(3) is bonded in a 4-coordinate geometry to three equivalent Cd(1) and one C(1) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent K(1) and one C(2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent K(1) and one C(3) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one K(1) and one C(1) atom. is represented by the CIF card [CIF]
data_KCdC3(NO)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.773
_cell_length_b   10.224
_cell_length_c   18.555
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   715.771
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.750  0.428  0.835  1.0
  K  K1  1  0.250  0.572  0.165  1.0
  K  K2  1  0.750  0.928  0.665  1.0
  K  K3  1  0.250  0.072  0.335  1.0
  Cd  Cd4  1  0.750  0.362  0.456  1.0
  Cd  Cd5  1  0.250  0.638  0.544  1.0
  Cd  Cd6  1  0.750  0.862  0.044  1.0
  Cd  Cd7  1  0.250  0.138  0.956  1.0
  C  C8  1  0.250  0.084  0.124  1.0
  C  C9  1  0.250  0.584  0.376  1.0
  C  C10  1  0.750  0.416  0.624  1.0
  C  C11  1  0.750  0.916  0.876  1.0
  C  C12  1  0.250  0.139  0.530  1.0
  C  C13  1  0.750  0.861  0.470  1.0
  C  C14  1  0.250  0.639  0.970  1.0
  C  C15  1  0.750  0.361  0.030  1.0
  C  C16  1  0.750  0.352  0.288  1.0
  C  C17  1  0.250  0.648  0.712  1.0
  C  C18  1  0.750  0.852  0.212  1.0
  C  C19  1  0.250  0.148  0.788  1.0
  N  N20  1  0.750  0.786  0.158  1.0
  N  N21  1  0.750  0.266  0.991  1.0
  N  N22  1  0.250  0.023  0.067  1.0
  N  N23  1  0.750  0.977  0.933  1.0
  N  N24  1  0.250  0.523  0.433  1.0
  N  N25  1  0.750  0.477  0.567  1.0
  N  N26  1  0.250  0.234  0.491  1.0
  N  N27  1  0.750  0.766  0.509  1.0
  N  N28  1  0.750  0.286  0.342  1.0
  N  N29  1  0.250  0.714  0.658  1.0
  N  N30  1  0.250  0.214  0.842  1.0
  N  N31  1  0.250  0.734  0.009  1.0
  O  O32  1  0.250  0.544  0.932  1.0
  O  O33  1  0.250  0.083  0.734  1.0
  O  O34  1  0.750  0.857  0.821  1.0
  O  O35  1  0.250  0.643  0.321  1.0
  O  O36  1  0.750  0.456  0.068  1.0
  O  O37  1  0.750  0.357  0.679  1.0
  O  O38  1  0.250  0.044  0.568  1.0
  O  O39  1  0.750  0.956  0.432  1.0
  O  O40  1  0.750  0.417  0.234  1.0
  O  O41  1  0.250  0.583  0.766  1.0
  O  O42  1  0.250  0.143  0.179  1.0
  O  O43  1  0.750  0.917  0.266  1.0
[/CIF]
.