The compound described by TeO2 crystallizes in the orthorhombic P2_12_12_1 space group. Te(1) is bonded in a 4-coordinate geometry to two equivalent O(1) and two equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(2) is bonded in a distorted bent 120 degrees geometry to two equivalent Te(1) atoms. In the second O site, O(1) is bonded in a bent 120 degrees geometry to two equivalent Te(1) atoms. is represented by the CIF file [CIF]
data_TeO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.407
_cell_length_b   4.871
_cell_length_c   8.729
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   187.381
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.377  0.030  0.602  1.0
  Te  Te1  1  0.877  0.470  0.398  1.0
  Te  Te2  1  0.623  0.530  0.898  1.0
  Te  Te3  1  0.123  0.970  0.102  1.0
  O  O4  1  0.772  0.142  0.539  1.0
  O  O5  1  0.272  0.358  0.461  1.0
  O  O6  1  0.228  0.642  0.961  1.0
  O  O7  1  0.728  0.858  0.039  1.0
  O  O8  1  0.172  0.757  0.277  1.0
  O  O9  1  0.672  0.743  0.723  1.0
  O  O10  1  0.828  0.257  0.223  1.0
  O  O11  1  0.328  0.243  0.777  1.0
[/CIF]
.
The compound described by TeO2 crystallizes in the orthorhombic P2_12_12_1 space group. Te(1) is bonded in a 4-coordinate geometry to two equivalent O(1) and two equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(2) is bonded in a distorted bent 120 degrees geometry to two equivalent Te(1) atoms. In the second O site, O(1) is bonded in a bent 120 degrees geometry to two equivalent Te(1) atoms. is represented by the CIF file [CIF]
data_TeO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.407
_cell_length_b   4.871
_cell_length_c   8.729
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   187.381
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.377  0.030  0.602  1.0
  Te  Te1  1  0.877  0.470  0.398  1.0
  Te  Te2  1  0.623  0.530  0.898  1.0
  Te  Te3  1  0.123  0.970  0.102  1.0
  O  O4  1  0.772  0.142  0.539  1.0
  O  O5  1  0.272  0.358  0.461  1.0
  O  O6  1  0.228  0.642  0.961  1.0
  O  O7  1  0.728  0.858  0.039  1.0
  O  O8  1  0.172  0.757  0.277  1.0
  O  O9  1  0.672  0.743  0.723  1.0
  O  O10  1  0.828  0.257  0.223  1.0
  O  O11  1  0.328  0.243  0.777  1.0
[/CIF]
.