The compound described by CsNH2SO3 crystallizes in the orthorhombic Pnma space group. Cs(1) is bonded in a 9-coordinate geometry to three equivalent O(1) and six equivalent O(2) atoms. N(1) is bonded in a distorted trigonal non-coplanar geometry to two equivalent H(1) and one S(1) atom. H(1) is bonded in a single-bond geometry to one N(1) atom. S(1) is bonded in a tetrahedral geometry to one N(1), one O(1), and two equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to three equivalent Cs(1) and one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to three equivalent Cs(1) and one S(1) atom. is represented by the CIF card [CIF]
data_CsH2SNO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.789
_cell_length_b   8.686
_cell_length_c   8.702
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   513.144
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.750  0.900  0.391  1.0
  Cs  Cs1  1  0.750  0.600  0.891  1.0
  Cs  Cs2  1  0.250  0.100  0.609  1.0
  Cs  Cs3  1  0.250  0.400  0.109  1.0
  H  H4  1  0.130  0.032  0.002  1.0
  H  H5  1  0.370  0.468  0.502  1.0
  H  H6  1  0.630  0.968  0.998  1.0
  H  H7  1  0.870  0.532  0.498  1.0
  H  H8  1  0.870  0.968  0.998  1.0
  H  H9  1  0.630  0.532  0.498  1.0
  H  H10  1  0.370  0.032  0.002  1.0
  H  H11  1  0.130  0.468  0.502  1.0
  S  S12  1  0.250  0.844  0.155  1.0
  S  S13  1  0.250  0.656  0.655  1.0
  S  S14  1  0.750  0.156  0.845  1.0
  S  S15  1  0.750  0.344  0.345  1.0
  N  N16  1  0.250  0.960  0.997  1.0
  N  N17  1  0.250  0.540  0.497  1.0
  N  N18  1  0.750  0.040  0.003  1.0
  N  N19  1  0.750  0.460  0.503  1.0
  O  O20  1  0.250  0.942  0.293  1.0
  O  O21  1  0.250  0.558  0.793  1.0
  O  O22  1  0.750  0.058  0.707  1.0
  O  O23  1  0.750  0.442  0.207  1.0
  O  O24  1  0.432  0.755  0.138  1.0
  O  O25  1  0.068  0.745  0.638  1.0
  O  O26  1  0.932  0.245  0.862  1.0
  O  O27  1  0.568  0.255  0.362  1.0
  O  O28  1  0.568  0.245  0.862  1.0
  O  O29  1  0.932  0.255  0.362  1.0
  O  O30  1  0.068  0.755  0.138  1.0
  O  O31  1  0.432  0.745  0.638  1.0
[/CIF]
.
The compound described by CsNH2SO3 crystallizes in the orthorhombic Pnma space group. Cs(1) is bonded in a 9-coordinate geometry to three equivalent O(1) and six equivalent O(2) atoms. N(1) is bonded in a distorted trigonal non-coplanar geometry to two equivalent H(1) and one S(1) atom. H(1) is bonded in a single-bond geometry to one N(1) atom. S(1) is bonded in a tetrahedral geometry to one N(1), one O(1), and two equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to three equivalent Cs(1) and one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to three equivalent Cs(1) and one S(1) atom. is represented by the CIF card [CIF]
data_CsH2SNO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.789
_cell_length_b   8.686
_cell_length_c   8.702
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   513.144
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.750  0.900  0.391  1.0
  Cs  Cs1  1  0.750  0.600  0.891  1.0
  Cs  Cs2  1  0.250  0.100  0.609  1.0
  Cs  Cs3  1  0.250  0.400  0.109  1.0
  H  H4  1  0.130  0.032  0.002  1.0
  H  H5  1  0.370  0.468  0.502  1.0
  H  H6  1  0.630  0.968  0.998  1.0
  H  H7  1  0.870  0.532  0.498  1.0
  H  H8  1  0.870  0.968  0.998  1.0
  H  H9  1  0.630  0.532  0.498  1.0
  H  H10  1  0.370  0.032  0.002  1.0
  H  H11  1  0.130  0.468  0.502  1.0
  S  S12  1  0.250  0.844  0.155  1.0
  S  S13  1  0.250  0.656  0.655  1.0
  S  S14  1  0.750  0.156  0.845  1.0
  S  S15  1  0.750  0.344  0.345  1.0
  N  N16  1  0.250  0.960  0.997  1.0
  N  N17  1  0.250  0.540  0.497  1.0
  N  N18  1  0.750  0.040  0.003  1.0
  N  N19  1  0.750  0.460  0.503  1.0
  O  O20  1  0.250  0.942  0.293  1.0
  O  O21  1  0.250  0.558  0.793  1.0
  O  O22  1  0.750  0.058  0.707  1.0
  O  O23  1  0.750  0.442  0.207  1.0
  O  O24  1  0.432  0.755  0.138  1.0
  O  O25  1  0.068  0.745  0.638  1.0
  O  O26  1  0.932  0.245  0.862  1.0
  O  O27  1  0.568  0.255  0.362  1.0
  O  O28  1  0.568  0.245  0.862  1.0
  O  O29  1  0.932  0.255  0.362  1.0
  O  O30  1  0.068  0.755  0.138  1.0
  O  O31  1  0.432  0.745  0.638  1.0
[/CIF]
.