The structure described by VZnF5 crystallizes in the monoclinic P2_1/c space group. V(1) is bonded to one F(1), one F(2), one F(3), one F(4), and two equivalent F(5) atoms to form corner-sharing VF6 octahedra. The corner-sharing octahedral tilt angles are 40°. Zn(1) is bonded in a 4-coordinate geometry to one F(1), one F(2), one F(3), one F(4), and one F(5) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a distorted bent 150 degrees geometry to one V(1) and one Zn(1) atom. In the second F site, F(2) is bonded in a distorted bent 150 degrees geometry to one V(1) and one Zn(1) atom. In the third F site, F(3) is bonded in a bent 150 degrees geometry to one V(1) and one Zn(1) atom. In the fourth F site, F(4) is bonded in a linear geometry to one V(1) and one Zn(1) atom. In the fifth F site, F(5) is bonded in a 3-coordinate geometry to two equivalent V(1) and one Zn(1) atom. is represented by the CIF card [CIF]
data_VZnF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.892
_cell_length_b   5.218
_cell_length_c   7.626
_cell_angle_alpha   69.838
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   369.540
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.753  0.099  0.604  1.0
  V  V1  1  0.253  0.901  0.896  1.0
  V  V2  1  0.247  0.901  0.396  1.0
  V  V3  1  0.747  0.099  0.104  1.0
  Zn  Zn4  1  0.007  0.518  0.752  1.0
  Zn  Zn5  1  0.507  0.482  0.748  1.0
  Zn  Zn6  1  0.993  0.482  0.248  1.0
  Zn  Zn7  1  0.493  0.518  0.252  1.0
  F  F8  1  0.886  0.392  0.577  1.0
  F  F9  1  0.386  0.608  0.923  1.0
  F  F10  1  0.114  0.608  0.423  1.0
  F  F11  1  0.614  0.392  0.077  1.0
  F  F12  1  0.607  0.350  0.495  1.0
  F  F13  1  0.107  0.650  0.005  1.0
  F  F14  1  0.393  0.650  0.505  1.0
  F  F15  1  0.893  0.350  0.995  1.0
  F  F16  1  0.403  0.147  0.793  1.0
  F  F17  1  0.903  0.853  0.707  1.0
  F  F18  1  0.597  0.853  0.207  1.0
  F  F19  1  0.097  0.147  0.293  1.0
  F  F20  1  0.137  0.221  0.847  1.0
  F  F21  1  0.637  0.779  0.653  1.0
  F  F22  1  0.863  0.779  0.153  1.0
  F  F23  1  0.363  0.221  0.347  1.0
  F  F24  1  0.683  0.146  0.842  1.0
  F  F25  1  0.183  0.854  0.658  1.0
  F  F26  1  0.317  0.854  0.158  1.0
  F  F27  1  0.817  0.146  0.342  1.0
[/CIF]
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The structure described by VZnF5 crystallizes in the monoclinic P2_1/c space group. V(1) is bonded to one F(1), one F(2), one F(3), one F(4), and two equivalent F(5) atoms to form corner-sharing VF6 octahedra. The corner-sharing octahedral tilt angles are 40°. Zn(1) is bonded in a 4-coordinate geometry to one F(1), one F(2), one F(3), one F(4), and one F(5) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a distorted bent 150 degrees geometry to one V(1) and one Zn(1) atom. In the second F site, F(2) is bonded in a distorted bent 150 degrees geometry to one V(1) and one Zn(1) atom. In the third F site, F(3) is bonded in a bent 150 degrees geometry to one V(1) and one Zn(1) atom. In the fourth F site, F(4) is bonded in a linear geometry to one V(1) and one Zn(1) atom. In the fifth F site, F(5) is bonded in a 3-coordinate geometry to two equivalent V(1) and one Zn(1) atom. is represented by the CIF card [CIF]
data_VZnF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.892
_cell_length_b   5.218
_cell_length_c   7.626
_cell_angle_alpha   69.838
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   369.540
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.753  0.099  0.604  1.0
  V  V1  1  0.253  0.901  0.896  1.0
  V  V2  1  0.247  0.901  0.396  1.0
  V  V3  1  0.747  0.099  0.104  1.0
  Zn  Zn4  1  0.007  0.518  0.752  1.0
  Zn  Zn5  1  0.507  0.482  0.748  1.0
  Zn  Zn6  1  0.993  0.482  0.248  1.0
  Zn  Zn7  1  0.493  0.518  0.252  1.0
  F  F8  1  0.886  0.392  0.577  1.0
  F  F9  1  0.386  0.608  0.923  1.0
  F  F10  1  0.114  0.608  0.423  1.0
  F  F11  1  0.614  0.392  0.077  1.0
  F  F12  1  0.607  0.350  0.495  1.0
  F  F13  1  0.107  0.650  0.005  1.0
  F  F14  1  0.393  0.650  0.505  1.0
  F  F15  1  0.893  0.350  0.995  1.0
  F  F16  1  0.403  0.147  0.793  1.0
  F  F17  1  0.903  0.853  0.707  1.0
  F  F18  1  0.597  0.853  0.207  1.0
  F  F19  1  0.097  0.147  0.293  1.0
  F  F20  1  0.137  0.221  0.847  1.0
  F  F21  1  0.637  0.779  0.653  1.0
  F  F22  1  0.863  0.779  0.153  1.0
  F  F23  1  0.363  0.221  0.347  1.0
  F  F24  1  0.683  0.146  0.842  1.0
  F  F25  1  0.183  0.854  0.658  1.0
  F  F26  1  0.317  0.854  0.158  1.0
  F  F27  1  0.817  0.146  0.342  1.0
[/CIF]
.