The structure described by Rb3OCl crystallizes in the orthorhombic Pnma space group. There are three inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 3-coordinate geometry to three equivalent O(1) and two equivalent Cl(1) atoms. In the second Rb site, Rb(2) is bonded in a distorted water-like geometry to two equivalent O(1) and three equivalent Cl(1) atoms. In the third Rb site, Rb(3) is bonded in a 5-coordinate geometry to one O(1) and four equivalent Cl(1) atoms. O(1) is bonded to one Rb(3), two equivalent Rb(2), and three equivalent Rb(1) atoms to form edge-sharing ORb6 octahedra. Cl(1) is bonded in a 9-coordinate geometry to two equivalent Rb(1), three equivalent Rb(2), and four equivalent Rb(3) atoms. is represented by the CIF card [CIF]
data_Rb3ClO
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.714
_cell_length_b   4.321
_cell_length_c   15.721
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   591.981
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.024  0.250  0.596  1.0
  Rb  Rb1  1  0.169  0.250  0.002  1.0
  Rb  Rb2  1  0.199  0.750  0.790  1.0
  Rb  Rb3  1  0.301  0.250  0.290  1.0
  Rb  Rb4  1  0.331  0.750  0.502  1.0
  Rb  Rb5  1  0.476  0.750  0.096  1.0
  Rb  Rb6  1  0.524  0.250  0.904  1.0
  Rb  Rb7  1  0.669  0.250  0.498  1.0
  Rb  Rb8  1  0.699  0.750  0.710  1.0
  Rb  Rb9  1  0.801  0.250  0.210  1.0
  Rb  Rb10  1  0.831  0.750  0.998  1.0
  Rb  Rb11  1  0.976  0.750  0.404  1.0
  Cl  Cl12  1  0.089  0.750  0.174  1.0
  Cl  Cl13  1  0.411  0.250  0.674  1.0
  Cl  Cl14  1  0.589  0.750  0.326  1.0
  Cl  Cl15  1  0.911  0.250  0.826  1.0
  O  O16  1  0.172  0.250  0.438  1.0
  O  O17  1  0.328  0.750  0.938  1.0
  O  O18  1  0.672  0.250  0.062  1.0
  O  O19  1  0.828  0.750  0.562  1.0
[/CIF]
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The structure described by Rb3OCl crystallizes in the orthorhombic Pnma space group. There are three inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 3-coordinate geometry to three equivalent O(1) and two equivalent Cl(1) atoms. In the second Rb site, Rb(2) is bonded in a distorted water-like geometry to two equivalent O(1) and three equivalent Cl(1) atoms. In the third Rb site, Rb(3) is bonded in a 5-coordinate geometry to one O(1) and four equivalent Cl(1) atoms. O(1) is bonded to one Rb(3), two equivalent Rb(2), and three equivalent Rb(1) atoms to form edge-sharing ORb6 octahedra. Cl(1) is bonded in a 9-coordinate geometry to two equivalent Rb(1), three equivalent Rb(2), and four equivalent Rb(3) atoms. is represented by the CIF card [CIF]
data_Rb3ClO
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.714
_cell_length_b   4.321
_cell_length_c   15.721
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   591.981
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.024  0.250  0.596  1.0
  Rb  Rb1  1  0.169  0.250  0.002  1.0
  Rb  Rb2  1  0.199  0.750  0.790  1.0
  Rb  Rb3  1  0.301  0.250  0.290  1.0
  Rb  Rb4  1  0.331  0.750  0.502  1.0
  Rb  Rb5  1  0.476  0.750  0.096  1.0
  Rb  Rb6  1  0.524  0.250  0.904  1.0
  Rb  Rb7  1  0.669  0.250  0.498  1.0
  Rb  Rb8  1  0.699  0.750  0.710  1.0
  Rb  Rb9  1  0.801  0.250  0.210  1.0
  Rb  Rb10  1  0.831  0.750  0.998  1.0
  Rb  Rb11  1  0.976  0.750  0.404  1.0
  Cl  Cl12  1  0.089  0.750  0.174  1.0
  Cl  Cl13  1  0.411  0.250  0.674  1.0
  Cl  Cl14  1  0.589  0.750  0.326  1.0
  Cl  Cl15  1  0.911  0.250  0.826  1.0
  O  O16  1  0.172  0.250  0.438  1.0
  O  O17  1  0.328  0.750  0.938  1.0
  O  O18  1  0.672  0.250  0.062  1.0
  O  O19  1  0.828  0.750  0.562  1.0
[/CIF]
.