The material structure described by MgLa2CoZnO6 crystallizes in the triclinic P1 space group. Mg(1) is bonded to one O(1), one O(2), one O(3), one O(5), and one O(6) atom to form distorted MgO5 trigonal bipyramids that share corners with three equivalent Co(1)O6 octahedra,  a cornercorner with one Zn(1)O4 trigonal pyramid,  an edgeedge with one Co(1)O6 octahedra, and  an edgeedge with one Zn(1)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 10-69°. There are two inequivalent La sites. In the first La site, La(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. In the second La site, La(2) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(5), one O(6), and two equivalent O(4) atoms. Co(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form distorted CoO6 octahedra that share corners with three equivalent Mg(1)O5 trigonal bipyramids, corners with two equivalent Zn(1)O4 trigonal pyramids,  an edgeedge with one Mg(1)O5 trigonal bipyramid, and  an edgeedge with one Zn(1)O4 trigonal pyramid. Zn(1) is bonded to one O(3), one O(4), one O(5), and one O(6) atom to form distorted ZnO4 trigonal pyramids that share corners with two equivalent Co(1)O6 octahedra,  a cornercorner with one Mg(1)O5 trigonal bipyramid,  an edgeedge with one Co(1)O6 octahedra, and  an edgeedge with one Mg(1)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 31-68°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Mg(1), one La(1), one La(2), and one Co(1) atom. In the second O site, O(2) is bonded to one Mg(1), one La(1), one La(2), and one Co(1) atom to form a mixture of distorted corner and edge-sharing OLa2MgCo trigonal pyramids. In the third O site, O(3) is bonded to one Mg(1), one La(1), one La(2), one Co(1), and one Zn(1) atom to form a mixture of distorted corner and edge-sharing OLa2MgZnCo trigonal bipyramids. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to one La(1), two equivalent La(2), one Co(1), and one Zn(1) atom. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to one Mg(1), one La(1), one La(2), one Co(1), and one Zn(1) atom. In the sixth O site, O(6) is bonded in a 5-coordinate geometry to one Mg(1), one La(1), one La(2), one Co(1), and one Zn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_La2MgZnCoO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.801
_cell_length_b   6.031
_cell_length_c   5.893
_cell_angle_alpha   74.597
_cell_angle_beta   56.154
_cell_angle_gamma   59.054
_symmetry_Int_Tables_number   1
_cell_volume   146.812
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.776  0.829  0.606  1.0
  La  La1  1  0.268  0.176  0.322  1.0
  Mg  Mg2  1  0.680  0.544  0.171  1.0
  Zn  Zn3  1  0.344  0.463  0.783  1.0
  Co  Co4  1  0.027  0.009  0.957  1.0
  O  O5  1  0.361  0.845  0.087  1.0
  O  O6  1  0.680  0.205  0.311  1.0
  O  O7  1  0.039  0.408  0.761  1.0
  O  O8  1  0.689  0.161  0.827  1.0
  O  O9  1  0.991  0.589  0.191  1.0
  O  O10  1  0.358  0.789  0.603  1.0
[/CIF]
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The material structure described by MgLa2CoZnO6 crystallizes in the triclinic P1 space group. Mg(1) is bonded to one O(1), one O(2), one O(3), one O(5), and one O(6) atom to form distorted MgO5 trigonal bipyramids that share corners with three equivalent Co(1)O6 octahedra,  a cornercorner with one Zn(1)O4 trigonal pyramid,  an edgeedge with one Co(1)O6 octahedra, and  an edgeedge with one Zn(1)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 10-69°. There are two inequivalent La sites. In the first La site, La(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. In the second La site, La(2) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(5), one O(6), and two equivalent O(4) atoms. Co(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form distorted CoO6 octahedra that share corners with three equivalent Mg(1)O5 trigonal bipyramids, corners with two equivalent Zn(1)O4 trigonal pyramids,  an edgeedge with one Mg(1)O5 trigonal bipyramid, and  an edgeedge with one Zn(1)O4 trigonal pyramid. Zn(1) is bonded to one O(3), one O(4), one O(5), and one O(6) atom to form distorted ZnO4 trigonal pyramids that share corners with two equivalent Co(1)O6 octahedra,  a cornercorner with one Mg(1)O5 trigonal bipyramid,  an edgeedge with one Co(1)O6 octahedra, and  an edgeedge with one Mg(1)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 31-68°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Mg(1), one La(1), one La(2), and one Co(1) atom. In the second O site, O(2) is bonded to one Mg(1), one La(1), one La(2), and one Co(1) atom to form a mixture of distorted corner and edge-sharing OLa2MgCo trigonal pyramids. In the third O site, O(3) is bonded to one Mg(1), one La(1), one La(2), one Co(1), and one Zn(1) atom to form a mixture of distorted corner and edge-sharing OLa2MgZnCo trigonal bipyramids. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to one La(1), two equivalent La(2), one Co(1), and one Zn(1) atom. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to one Mg(1), one La(1), one La(2), one Co(1), and one Zn(1) atom. In the sixth O site, O(6) is bonded in a 5-coordinate geometry to one Mg(1), one La(1), one La(2), one Co(1), and one Zn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_La2MgZnCoO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.801
_cell_length_b   6.031
_cell_length_c   5.893
_cell_angle_alpha   74.597
_cell_angle_beta   56.154
_cell_angle_gamma   59.054
_symmetry_Int_Tables_number   1
_cell_volume   146.812
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.776  0.829  0.606  1.0
  La  La1  1  0.268  0.176  0.322  1.0
  Mg  Mg2  1  0.680  0.544  0.171  1.0
  Zn  Zn3  1  0.344  0.463  0.783  1.0
  Co  Co4  1  0.027  0.009  0.957  1.0
  O  O5  1  0.361  0.845  0.087  1.0
  O  O6  1  0.680  0.205  0.311  1.0
  O  O7  1  0.039  0.408  0.761  1.0
  O  O8  1  0.689  0.161  0.827  1.0
  O  O9  1  0.991  0.589  0.191  1.0
  O  O10  1  0.358  0.789  0.603  1.0
[/CIF]
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