The material described by VCl5PCl4 is Indium-derived structured and crystallizes in the orthorhombic Cmme space group. The structure is zero-dimensional and consists of four [pcl4]+1 molecules and four pentachlorovanadium molecules. is represented by the CIF file [CIF]
data_VPCl9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.189
_cell_length_b   10.189
_cell_length_c   6.213
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   108.270
_symmetry_Int_Tables_number   1
_cell_volume   612.510
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.750  0.250  0.617  1.0
  V  V1  1  0.250  0.750  0.383  1.0
  P  P2  1  0.750  0.750  0.000  1.0
  P  P3  1  0.250  0.250  0.000  1.0
  Cl  Cl4  1  0.224  0.089  0.818  1.0
  Cl  Cl5  1  0.411  0.276  0.182  1.0
  Cl  Cl6  1  0.915  0.415  0.767  1.0
  Cl  Cl7  1  0.085  0.585  0.233  1.0
  Cl  Cl8  1  0.415  0.915  0.233  1.0
  Cl  Cl9  1  0.585  0.085  0.767  1.0
  Cl  Cl10  1  0.750  0.250  0.262  1.0
  Cl  Cl11  1  0.250  0.750  0.738  1.0
  Cl  Cl12  1  0.109  0.891  0.382  1.0
  Cl  Cl13  1  0.609  0.391  0.618  1.0
  Cl  Cl14  1  0.391  0.609  0.382  1.0
  Cl  Cl15  1  0.891  0.109  0.618  1.0
  Cl  Cl16  1  0.276  0.411  0.818  1.0
  Cl  Cl17  1  0.089  0.224  0.182  1.0
  Cl  Cl18  1  0.776  0.911  0.182  1.0
  Cl  Cl19  1  0.589  0.724  0.818  1.0
  Cl  Cl20  1  0.911  0.776  0.818  1.0
  Cl  Cl21  1  0.724  0.589  0.182  1.0
[/CIF]
.
The material described by VCl5PCl4 is Indium-derived structured and crystallizes in the orthorhombic Cmme space group. The structure is zero-dimensional and consists of four [pcl4]+1 molecules and four pentachlorovanadium molecules. is represented by the CIF file [CIF]
data_VPCl9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.189
_cell_length_b   10.189
_cell_length_c   6.213
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   108.270
_symmetry_Int_Tables_number   1
_cell_volume   612.510
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.750  0.250  0.617  1.0
  V  V1  1  0.250  0.750  0.383  1.0
  P  P2  1  0.750  0.750  0.000  1.0
  P  P3  1  0.250  0.250  0.000  1.0
  Cl  Cl4  1  0.224  0.089  0.818  1.0
  Cl  Cl5  1  0.411  0.276  0.182  1.0
  Cl  Cl6  1  0.915  0.415  0.767  1.0
  Cl  Cl7  1  0.085  0.585  0.233  1.0
  Cl  Cl8  1  0.415  0.915  0.233  1.0
  Cl  Cl9  1  0.585  0.085  0.767  1.0
  Cl  Cl10  1  0.750  0.250  0.262  1.0
  Cl  Cl11  1  0.250  0.750  0.738  1.0
  Cl  Cl12  1  0.109  0.891  0.382  1.0
  Cl  Cl13  1  0.609  0.391  0.618  1.0
  Cl  Cl14  1  0.391  0.609  0.382  1.0
  Cl  Cl15  1  0.891  0.109  0.618  1.0
  Cl  Cl16  1  0.276  0.411  0.818  1.0
  Cl  Cl17  1  0.089  0.224  0.182  1.0
  Cl  Cl18  1  0.776  0.911  0.182  1.0
  Cl  Cl19  1  0.589  0.724  0.818  1.0
  Cl  Cl20  1  0.911  0.776  0.818  1.0
  Cl  Cl21  1  0.724  0.589  0.182  1.0
[/CIF]
.