The structure described by CN2SnI3 is High-temperature superconductor-derived structured and crystallizes in the orthorhombic Imm2 space group. The structure consists of eight cyanamide molecules inside a SnI3 framework. In the SnI3 framework, Sn(1) is bonded to one I(2), one I(3), one I(4), one I(5), and two equivalent I(1) atoms to form corner-sharing SnI6 octahedra. The corner-sharing octahedral tilt angles range from 2-16°. There are five inequivalent I sites. In the first I site, I(1) is bonded in a linear geometry to two equivalent Sn(1) atoms. In the second I site, I(2) is bonded in a linear geometry to two equivalent Sn(1) atoms. In the third I site, I(3) is bonded in a linear geometry to two equivalent Sn(1) atoms. In the fourth I site, I(4) is bonded in a linear geometry to two equivalent Sn(1) atoms. In the fifth I site, I(5) is bonded in a linear geometry to two equivalent Sn(1) atoms. is represented by the CIF file [CIF]
data_SnCI3N2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.429
_cell_length_b   10.429
_cell_length_c   10.429
_cell_angle_alpha   109.830
_cell_angle_beta   109.323
_cell_angle_gamma   109.261
_symmetry_Int_Tables_number   1
_cell_volume   873.255
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.000  0.924  0.424  1.0
  Sn  Sn1  1  1.000  0.424  0.924  1.0
  Sn  Sn2  1  0.500  0.424  0.424  1.0
  Sn  Sn3  1  0.500  0.924  0.924  1.0
  C  C4  1  0.000  0.947  0.947  1.0
  C  C5  1  0.500  0.390  0.890  1.0
  C  C6  1  0.500  0.931  0.431  1.0
  C  C7  1  0.000  0.438  0.438  1.0
  I  I8  1  0.005  0.182  0.678  1.0
  I  I9  1  0.995  0.673  0.177  1.0
  I  I10  1  0.496  0.673  0.678  1.0
  I  I11  1  0.504  0.182  0.177  1.0
  I  I12  1  0.779  0.176  0.955  1.0
  I  I13  1  0.221  0.176  0.398  1.0
  I  I14  1  0.776  0.687  0.464  1.0
  I  I15  1  0.224  0.687  0.911  1.0
  I  I16  1  0.271  0.949  0.678  1.0
  I  I17  1  0.729  0.407  0.678  1.0
  I  I18  1  0.284  0.461  0.177  1.0
  I  I19  1  0.716  0.894  0.177  1.0
  N  N20  1  0.603  0.391  0.994  1.0
  N  N21  1  0.397  0.391  0.789  1.0
  N  N22  1  0.603  0.932  0.534  1.0
  N  N23  1  0.397  0.932  0.329  1.0
  N  N24  1  0.102  0.049  0.947  1.0
  N  N25  1  0.898  0.845  0.947  1.0
  N  N26  1  0.102  0.540  0.437  1.0
  N  N27  1  0.898  0.335  0.437  1.0
[/CIF]
.
The structure described by CN2SnI3 is High-temperature superconductor-derived structured and crystallizes in the orthorhombic Imm2 space group. The structure consists of eight cyanamide molecules inside a SnI3 framework. In the SnI3 framework, Sn(1) is bonded to one I(2), one I(3), one I(4), one I(5), and two equivalent I(1) atoms to form corner-sharing SnI6 octahedra. The corner-sharing octahedral tilt angles range from 2-16°. There are five inequivalent I sites. In the first I site, I(1) is bonded in a linear geometry to two equivalent Sn(1) atoms. In the second I site, I(2) is bonded in a linear geometry to two equivalent Sn(1) atoms. In the third I site, I(3) is bonded in a linear geometry to two equivalent Sn(1) atoms. In the fourth I site, I(4) is bonded in a linear geometry to two equivalent Sn(1) atoms. In the fifth I site, I(5) is bonded in a linear geometry to two equivalent Sn(1) atoms. is represented by the CIF file [CIF]
data_SnCI3N2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.429
_cell_length_b   10.429
_cell_length_c   10.429
_cell_angle_alpha   109.830
_cell_angle_beta   109.323
_cell_angle_gamma   109.261
_symmetry_Int_Tables_number   1
_cell_volume   873.255
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.000  0.924  0.424  1.0
  Sn  Sn1  1  1.000  0.424  0.924  1.0
  Sn  Sn2  1  0.500  0.424  0.424  1.0
  Sn  Sn3  1  0.500  0.924  0.924  1.0
  C  C4  1  0.000  0.947  0.947  1.0
  C  C5  1  0.500  0.390  0.890  1.0
  C  C6  1  0.500  0.931  0.431  1.0
  C  C7  1  0.000  0.438  0.438  1.0
  I  I8  1  0.005  0.182  0.678  1.0
  I  I9  1  0.995  0.673  0.177  1.0
  I  I10  1  0.496  0.673  0.678  1.0
  I  I11  1  0.504  0.182  0.177  1.0
  I  I12  1  0.779  0.176  0.955  1.0
  I  I13  1  0.221  0.176  0.398  1.0
  I  I14  1  0.776  0.687  0.464  1.0
  I  I15  1  0.224  0.687  0.911  1.0
  I  I16  1  0.271  0.949  0.678  1.0
  I  I17  1  0.729  0.407  0.678  1.0
  I  I18  1  0.284  0.461  0.177  1.0
  I  I19  1  0.716  0.894  0.177  1.0
  N  N20  1  0.603  0.391  0.994  1.0
  N  N21  1  0.397  0.391  0.789  1.0
  N  N22  1  0.603  0.932  0.534  1.0
  N  N23  1  0.397  0.932  0.329  1.0
  N  N24  1  0.102  0.049  0.947  1.0
  N  N25  1  0.898  0.845  0.947  1.0
  N  N26  1  0.102  0.540  0.437  1.0
  N  N27  1  0.898  0.335  0.437  1.0
[/CIF]
.