The crystal structure described by (MoO3)4N2(NO)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two ammonia atoms, two nitroxyl molecules, and one MoO3 cluster. In the MoO3 cluster, there are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(1), one O(2), one O(3), and one O(5) atom to form corner-sharing MoO4 tetrahedra. In the second Mo site, Mo(2) is bonded to one O(1), one O(4), one O(5), and one O(7) atom to form corner-sharing MoO4 tetrahedra. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Mo(1) and one Mo(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Mo(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Mo(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Mo(2) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Mo(1) and one Mo(2) atom. In the sixth O site, O(7) is bonded in a single-bond geometry to one Mo(2) atom. is represented by the CIF file [CIF]
data_Mo2N2O7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.927
_cell_length_b   8.425
_cell_length_c   8.525
_cell_angle_alpha   82.596
_cell_angle_beta   117.026
_cell_angle_gamma   107.891
_symmetry_Int_Tables_number   1
_cell_volume   482.561
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.202  0.262  0.067  1.0
  Mo  Mo1  1  0.798  0.738  0.933  1.0
  Mo  Mo2  1  0.248  0.886  0.313  1.0
  Mo  Mo3  1  0.752  0.114  0.687  1.0
  N  N4  1  0.760  0.614  0.448  1.0
  N  N5  1  0.240  0.386  0.552  1.0
  N  N6  1  0.770  0.273  0.150  1.0
  N  N7  1  0.230  0.727  0.850  1.0
  O  O8  1  0.196  0.100  0.246  1.0
  O  O9  1  0.804  0.900  0.754  1.0
  O  O10  1  0.320  0.211  0.963  1.0
  O  O11  1  0.680  0.789  0.037  1.0
  O  O12  1  0.328  0.459  0.155  1.0
  O  O13  1  0.672  0.541  0.845  1.0
  O  O14  1  0.194  0.788  0.481  1.0
  O  O15  1  0.806  0.212  0.519  1.0
  O  O16  1  0.933  0.244  0.896  1.0
  O  O17  1  0.067  0.756  0.104  1.0
  O  O18  1  0.882  0.404  0.194  1.0
  O  O19  1  0.118  0.596  0.806  1.0
  O  O20  1  0.487  0.893  0.363  1.0
  O  O21  1  0.513  0.107  0.637  1.0
[/CIF]
.
The crystal structure described by (MoO3)4N2(NO)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two ammonia atoms, two nitroxyl molecules, and one MoO3 cluster. In the MoO3 cluster, there are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(1), one O(2), one O(3), and one O(5) atom to form corner-sharing MoO4 tetrahedra. In the second Mo site, Mo(2) is bonded to one O(1), one O(4), one O(5), and one O(7) atom to form corner-sharing MoO4 tetrahedra. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Mo(1) and one Mo(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Mo(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Mo(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Mo(2) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Mo(1) and one Mo(2) atom. In the sixth O site, O(7) is bonded in a single-bond geometry to one Mo(2) atom. is represented by the CIF file [CIF]
data_Mo2N2O7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.927
_cell_length_b   8.425
_cell_length_c   8.525
_cell_angle_alpha   82.596
_cell_angle_beta   117.026
_cell_angle_gamma   107.891
_symmetry_Int_Tables_number   1
_cell_volume   482.561
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.202  0.262  0.067  1.0
  Mo  Mo1  1  0.798  0.738  0.933  1.0
  Mo  Mo2  1  0.248  0.886  0.313  1.0
  Mo  Mo3  1  0.752  0.114  0.687  1.0
  N  N4  1  0.760  0.614  0.448  1.0
  N  N5  1  0.240  0.386  0.552  1.0
  N  N6  1  0.770  0.273  0.150  1.0
  N  N7  1  0.230  0.727  0.850  1.0
  O  O8  1  0.196  0.100  0.246  1.0
  O  O9  1  0.804  0.900  0.754  1.0
  O  O10  1  0.320  0.211  0.963  1.0
  O  O11  1  0.680  0.789  0.037  1.0
  O  O12  1  0.328  0.459  0.155  1.0
  O  O13  1  0.672  0.541  0.845  1.0
  O  O14  1  0.194  0.788  0.481  1.0
  O  O15  1  0.806  0.212  0.519  1.0
  O  O16  1  0.933  0.244  0.896  1.0
  O  O17  1  0.067  0.756  0.104  1.0
  O  O18  1  0.882  0.404  0.194  1.0
  O  O19  1  0.118  0.596  0.806  1.0
  O  O20  1  0.487  0.893  0.363  1.0
  O  O21  1  0.513  0.107  0.637  1.0
[/CIF]
.