The material structure described by Nd2RhSn4 crystallizes in the orthorhombic Amm2 space group. There are two inequivalent Nd sites. In the first Nd site, Nd(1) is bonded in a 10-coordinate geometry to two equivalent Sn(1), two equivalent Sn(3), two equivalent Sn(4), and four equivalent Sn(2) atoms. In the second Nd site, Nd(2) is bonded in a 14-coordinate geometry to four equivalent Rh(1), two equivalent Sn(2), two equivalent Sn(3), two equivalent Sn(4), and four equivalent Sn(1) atoms. Rh(1) is bonded in a 5-coordinate geometry to four equivalent Nd(2), one Sn(1), two equivalent Sn(3), and two equivalent Sn(4) atoms. There are four inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a 9-coordinate geometry to two equivalent Nd(1), four equivalent Nd(2), one Rh(1), and two equivalent Sn(2) atoms. In the second Sn site, Sn(2) is bonded in a 8-coordinate geometry to two equivalent Nd(2), four equivalent Nd(1), and two equivalent Sn(1) atoms. In the third Sn site, Sn(3) is bonded in a 10-coordinate geometry to two equivalent Nd(1), two equivalent Nd(2), two equivalent Rh(1), and four equivalent Sn(4) atoms. In the fourth Sn site, Sn(4) is bonded in a 10-coordinate geometry to two equivalent Nd(1), two equivalent Nd(2), two equivalent Rh(1), and four equivalent Sn(3) atoms. is represented by the CIF file [CIF]
data_Nd2Sn4Rh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.600
_cell_length_b   4.598
_cell_length_c   9.023
_cell_angle_alpha   75.241
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   184.528
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Nd  Nd0  1  0.250  0.895  0.210  1.0
  Nd  Nd1  1  0.750  0.104  0.793  1.0
  Sn  Sn2  1  0.250  0.542  0.915  1.0
  Sn  Sn3  1  0.750  0.433  0.134  1.0
  Sn  Sn4  1  0.250  0.261  0.478  1.0
  Sn  Sn5  1  0.750  0.760  0.479  1.0
  Rh  Rh6  1  0.250  0.689  0.621  1.0
[/CIF]
.
The material structure described by Nd2RhSn4 crystallizes in the orthorhombic Amm2 space group. There are two inequivalent Nd sites. In the first Nd site, Nd(1) is bonded in a 10-coordinate geometry to two equivalent Sn(1), two equivalent Sn(3), two equivalent Sn(4), and four equivalent Sn(2) atoms. In the second Nd site, Nd(2) is bonded in a 14-coordinate geometry to four equivalent Rh(1), two equivalent Sn(2), two equivalent Sn(3), two equivalent Sn(4), and four equivalent Sn(1) atoms. Rh(1) is bonded in a 5-coordinate geometry to four equivalent Nd(2), one Sn(1), two equivalent Sn(3), and two equivalent Sn(4) atoms. There are four inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a 9-coordinate geometry to two equivalent Nd(1), four equivalent Nd(2), one Rh(1), and two equivalent Sn(2) atoms. In the second Sn site, Sn(2) is bonded in a 8-coordinate geometry to two equivalent Nd(2), four equivalent Nd(1), and two equivalent Sn(1) atoms. In the third Sn site, Sn(3) is bonded in a 10-coordinate geometry to two equivalent Nd(1), two equivalent Nd(2), two equivalent Rh(1), and four equivalent Sn(4) atoms. In the fourth Sn site, Sn(4) is bonded in a 10-coordinate geometry to two equivalent Nd(1), two equivalent Nd(2), two equivalent Rh(1), and four equivalent Sn(3) atoms. is represented by the CIF file [CIF]
data_Nd2Sn4Rh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.600
_cell_length_b   4.598
_cell_length_c   9.023
_cell_angle_alpha   75.241
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   184.528
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Nd  Nd0  1  0.250  0.895  0.210  1.0
  Nd  Nd1  1  0.750  0.104  0.793  1.0
  Sn  Sn2  1  0.250  0.542  0.915  1.0
  Sn  Sn3  1  0.750  0.433  0.134  1.0
  Sn  Sn4  1  0.250  0.261  0.478  1.0
  Sn  Sn5  1  0.750  0.760  0.479  1.0
  Rh  Rh6  1  0.250  0.689  0.621  1.0
[/CIF]
.