The material described by Ge2N2O crystallizes in the monoclinic Cc space group. There are two inequivalent Ge sites. In the first Ge site, Ge(1) is bonded to one N(1), two equivalent N(2), and one O(1) atom to form corner-sharing GeN3O tetrahedra. In the second Ge site, Ge(2) is bonded to one N(2), two equivalent N(1), and one O(1) atom to form corner-sharing GeN3O tetrahedra. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal non-coplanar geometry to one Ge(1) and two equivalent Ge(2) atoms. In the second N site, N(2) is bonded in a trigonal non-coplanar geometry to one Ge(2) and two equivalent Ge(1) atoms. O(1) is bonded in a bent 120 degrees geometry to one Ge(1) and one Ge(2) atom. is represented by the CIF card [CIF]
data_Ge2N2O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.573
_cell_length_b   5.573
_cell_length_c   5.358
_cell_angle_alpha   81.212
_cell_angle_beta   81.212
_cell_angle_gamma   122.197
_symmetry_Int_Tables_number   1
_cell_volume   133.602
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ge  Ge0  1  0.823  0.333  0.505  1.0
  Ge  Ge1  1  0.504  0.668  0.502  1.0
  Ge  Ge2  1  0.333  0.823  0.005  1.0
  Ge  Ge3  1  0.668  0.504  0.002  1.0
  N  N4  1  0.587  0.427  0.363  1.0
  N  N5  1  0.213  0.664  0.370  1.0
  N  N6  1  0.427  0.587  0.863  1.0
  N  N7  1  0.664  0.213  0.870  1.0
  O  O8  1  0.050  0.815  0.884  1.0
  O  O9  1  0.815  0.050  0.384  1.0
[/CIF]
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The material described by Ge2N2O crystallizes in the monoclinic Cc space group. There are two inequivalent Ge sites. In the first Ge site, Ge(1) is bonded to one N(1), two equivalent N(2), and one O(1) atom to form corner-sharing GeN3O tetrahedra. In the second Ge site, Ge(2) is bonded to one N(2), two equivalent N(1), and one O(1) atom to form corner-sharing GeN3O tetrahedra. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal non-coplanar geometry to one Ge(1) and two equivalent Ge(2) atoms. In the second N site, N(2) is bonded in a trigonal non-coplanar geometry to one Ge(2) and two equivalent Ge(1) atoms. O(1) is bonded in a bent 120 degrees geometry to one Ge(1) and one Ge(2) atom. is represented by the CIF card [CIF]
data_Ge2N2O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.573
_cell_length_b   5.573
_cell_length_c   5.358
_cell_angle_alpha   81.212
_cell_angle_beta   81.212
_cell_angle_gamma   122.197
_symmetry_Int_Tables_number   1
_cell_volume   133.602
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ge  Ge0  1  0.823  0.333  0.505  1.0
  Ge  Ge1  1  0.504  0.668  0.502  1.0
  Ge  Ge2  1  0.333  0.823  0.005  1.0
  Ge  Ge3  1  0.668  0.504  0.002  1.0
  N  N4  1  0.587  0.427  0.363  1.0
  N  N5  1  0.213  0.664  0.370  1.0
  N  N6  1  0.427  0.587  0.863  1.0
  N  N7  1  0.664  0.213  0.870  1.0
  O  O8  1  0.050  0.815  0.884  1.0
  O  O9  1  0.815  0.050  0.384  1.0
[/CIF]
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