The crystal structure described by WO2F is alpha Rhenium trioxide-derived structured and crystallizes in the monoclinic C2/c space group. W(1) is bonded to four equivalent O(1) and two equivalent F(1) atoms to form corner-sharing WO4F2 octahedra. The corner-sharing octahedral tilt angles range from 4-6°. O(1) is bonded in a linear geometry to two equivalent W(1) atoms. F(1) is bonded in a linear geometry to two equivalent W(1) atoms. is represented by the CIF card [CIF]
data_WO2F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.691
_cell_length_b   5.691
_cell_length_c   5.502
_cell_angle_alpha   61.043
_cell_angle_beta   61.043
_cell_angle_gamma   57.862
_symmetry_Int_Tables_number   1
_cell_volume   125.697
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  W  W0  1  0.500  0.000  0.500  1.0
  W  W1  1  0.000  0.500  0.000  1.0
  O  O2  1  0.257  0.230  0.262  1.0
  O  O3  1  0.770  0.743  0.238  1.0
  O  O4  1  0.230  0.257  0.762  1.0
  O  O5  1  0.743  0.770  0.738  1.0
  F  F6  1  0.269  0.731  0.750  1.0
  F  F7  1  0.731  0.269  0.250  1.0
[/CIF]
.
The crystal structure described by WO2F is alpha Rhenium trioxide-derived structured and crystallizes in the monoclinic C2/c space group. W(1) is bonded to four equivalent O(1) and two equivalent F(1) atoms to form corner-sharing WO4F2 octahedra. The corner-sharing octahedral tilt angles range from 4-6°. O(1) is bonded in a linear geometry to two equivalent W(1) atoms. F(1) is bonded in a linear geometry to two equivalent W(1) atoms. is represented by the CIF card [CIF]
data_WO2F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.691
_cell_length_b   5.691
_cell_length_c   5.502
_cell_angle_alpha   61.043
_cell_angle_beta   61.043
_cell_angle_gamma   57.862
_symmetry_Int_Tables_number   1
_cell_volume   125.697
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  W  W0  1  0.500  0.000  0.500  1.0
  W  W1  1  0.000  0.500  0.000  1.0
  O  O2  1  0.257  0.230  0.262  1.0
  O  O3  1  0.770  0.743  0.238  1.0
  O  O4  1  0.230  0.257  0.762  1.0
  O  O5  1  0.743  0.770  0.738  1.0
  F  F6  1  0.269  0.731  0.750  1.0
  F  F7  1  0.731  0.269  0.250  1.0
[/CIF]
.