The compound described by RhSbSe is Spinel-like structured and crystallizes in the cubic P2_13 space group. Rh(1) is bonded to three equivalent Sb(1) and three equivalent Se(1) atoms to form RhSb3Se3 octahedra that share corners with twelve equivalent Rh(1)Sb3Se3 octahedra, corners with three equivalent Sb(1)Rh3Se tetrahedra, and corners with three equivalent Se(1)SbRh3 tetrahedra. The corner-sharing octahedral tilt angles are 63°. Sb(1) is bonded to three equivalent Rh(1) and one Se(1) atom to form SbRh3Se tetrahedra that share corners with three equivalent Rh(1)Sb3Se3 octahedra, corners with six equivalent Sb(1)Rh3Se tetrahedra, and corners with nine equivalent Se(1)SbRh3 tetrahedra. The corner-sharing octahedral tilt angles are 80°. Se(1) is bonded to three equivalent Rh(1) and one Sb(1) atom to form SeSbRh3 tetrahedra that share corners with three equivalent Rh(1)Sb3Se3 octahedra, corners with six equivalent Se(1)SbRh3 tetrahedra, and corners with nine equivalent Sb(1)Rh3Se tetrahedra. The corner-sharing octahedral tilt angles are 79°. is represented by the Crystallographic Information File (CIF) [CIF]
data_SbRhSe
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.261
_cell_length_b   6.261
_cell_length_c   6.261
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   245.485
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.877  0.377  0.123  1.0
  Sb  Sb1  1  0.377  0.123  0.877  1.0
  Sb  Sb2  1  0.123  0.877  0.377  1.0
  Sb  Sb3  1  0.623  0.623  0.623  1.0
  Rh  Rh4  1  0.505  0.005  0.495  1.0
  Rh  Rh5  1  0.005  0.495  0.505  1.0
  Rh  Rh6  1  0.495  0.505  0.005  1.0
  Rh  Rh7  1  0.995  0.995  0.995  1.0
  Se  Se8  1  0.122  0.622  0.878  1.0
  Se  Se9  1  0.622  0.878  0.122  1.0
  Se  Se10  1  0.878  0.122  0.622  1.0
  Se  Se11  1  0.378  0.378  0.378  1.0
[/CIF]
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The compound described by RhSbSe is Spinel-like structured and crystallizes in the cubic P2_13 space group. Rh(1) is bonded to three equivalent Sb(1) and three equivalent Se(1) atoms to form RhSb3Se3 octahedra that share corners with twelve equivalent Rh(1)Sb3Se3 octahedra, corners with three equivalent Sb(1)Rh3Se tetrahedra, and corners with three equivalent Se(1)SbRh3 tetrahedra. The corner-sharing octahedral tilt angles are 63°. Sb(1) is bonded to three equivalent Rh(1) and one Se(1) atom to form SbRh3Se tetrahedra that share corners with three equivalent Rh(1)Sb3Se3 octahedra, corners with six equivalent Sb(1)Rh3Se tetrahedra, and corners with nine equivalent Se(1)SbRh3 tetrahedra. The corner-sharing octahedral tilt angles are 80°. Se(1) is bonded to three equivalent Rh(1) and one Sb(1) atom to form SeSbRh3 tetrahedra that share corners with three equivalent Rh(1)Sb3Se3 octahedra, corners with six equivalent Se(1)SbRh3 tetrahedra, and corners with nine equivalent Sb(1)Rh3Se tetrahedra. The corner-sharing octahedral tilt angles are 79°. is represented by the Crystallographic Information File (CIF) [CIF]
data_SbRhSe
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.261
_cell_length_b   6.261
_cell_length_c   6.261
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   245.485
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.877  0.377  0.123  1.0
  Sb  Sb1  1  0.377  0.123  0.877  1.0
  Sb  Sb2  1  0.123  0.877  0.377  1.0
  Sb  Sb3  1  0.623  0.623  0.623  1.0
  Rh  Rh4  1  0.505  0.005  0.495  1.0
  Rh  Rh5  1  0.005  0.495  0.505  1.0
  Rh  Rh6  1  0.495  0.505  0.005  1.0
  Rh  Rh7  1  0.995  0.995  0.995  1.0
  Se  Se8  1  0.122  0.622  0.878  1.0
  Se  Se9  1  0.622  0.878  0.122  1.0
  Se  Se10  1  0.878  0.122  0.622  1.0
  Se  Se11  1  0.378  0.378  0.378  1.0
[/CIF]
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