The structure described by RbPNO2 crystallizes in the trigonal R-3 space group. Rb(1) is bonded in a 9-coordinate geometry to two equivalent N(1), three equivalent O(1), and four equivalent O(2) atoms. P(1) is bonded to two equivalent N(1), one O(1), and one O(2) atom to form corner-sharing PN2O2 tetrahedra. N(1) is bonded in a distorted bent 120 degrees geometry to two equivalent Rb(1) and two equivalent P(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to three equivalent Rb(1) and one P(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to four equivalent Rb(1) and one P(1) atom. is represented by the CIF card [CIF]
data_RbPNO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.438
_cell_length_b   8.438
_cell_length_c   8.438
_cell_angle_alpha   101.143
_cell_angle_beta   101.143
_cell_angle_gamma   101.143
_symmetry_Int_Tables_number   1
_cell_volume   561.412
_cell_formula_units_Z   6
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.188  0.853  0.661  1.0
  Rb  Rb1  1  0.661  0.188  0.853  1.0
  Rb  Rb2  1  0.853  0.661  0.188  1.0
  Rb  Rb3  1  0.812  0.147  0.339  1.0
  Rb  Rb4  1  0.339  0.812  0.147  1.0
  Rb  Rb5  1  0.147  0.339  0.812  1.0
  P  P6  1  0.284  0.182  0.442  1.0
  P  P7  1  0.442  0.284  0.182  1.0
  P  P8  1  0.182  0.442  0.284  1.0
  P  P9  1  0.716  0.818  0.558  1.0
  P  P10  1  0.558  0.716  0.818  1.0
  P  P11  1  0.818  0.558  0.716  1.0
  N  N12  1  0.570  0.813  0.665  1.0
  N  N13  1  0.665  0.570  0.813  1.0
  N  N14  1  0.813  0.665  0.570  1.0
  N  N15  1  0.430  0.187  0.335  1.0
  N  N16  1  0.335  0.430  0.187  1.0
  N  N17  1  0.187  0.335  0.430  1.0
  O  O18  1  0.376  0.638  0.805  1.0
  O  O19  1  0.805  0.376  0.638  1.0
  O  O20  1  0.638  0.805  0.376  1.0
  O  O21  1  0.624  0.362  0.195  1.0
  O  O22  1  0.195  0.624  0.362  1.0
  O  O23  1  0.362  0.195  0.624  1.0
  O  O24  1  0.851  0.977  0.645  1.0
  O  O25  1  0.645  0.851  0.977  1.0
  O  O26  1  0.977  0.645  0.851  1.0
  O  O27  1  0.149  0.023  0.355  1.0
  O  O28  1  0.355  0.149  0.023  1.0
  O  O29  1  0.023  0.355  0.149  1.0
[/CIF]
.
The structure described by RbPNO2 crystallizes in the trigonal R-3 space group. Rb(1) is bonded in a 9-coordinate geometry to two equivalent N(1), three equivalent O(1), and four equivalent O(2) atoms. P(1) is bonded to two equivalent N(1), one O(1), and one O(2) atom to form corner-sharing PN2O2 tetrahedra. N(1) is bonded in a distorted bent 120 degrees geometry to two equivalent Rb(1) and two equivalent P(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to three equivalent Rb(1) and one P(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to four equivalent Rb(1) and one P(1) atom. is represented by the CIF card [CIF]
data_RbPNO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.438
_cell_length_b   8.438
_cell_length_c   8.438
_cell_angle_alpha   101.143
_cell_angle_beta   101.143
_cell_angle_gamma   101.143
_symmetry_Int_Tables_number   1
_cell_volume   561.412
_cell_formula_units_Z   6
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.188  0.853  0.661  1.0
  Rb  Rb1  1  0.661  0.188  0.853  1.0
  Rb  Rb2  1  0.853  0.661  0.188  1.0
  Rb  Rb3  1  0.812  0.147  0.339  1.0
  Rb  Rb4  1  0.339  0.812  0.147  1.0
  Rb  Rb5  1  0.147  0.339  0.812  1.0
  P  P6  1  0.284  0.182  0.442  1.0
  P  P7  1  0.442  0.284  0.182  1.0
  P  P8  1  0.182  0.442  0.284  1.0
  P  P9  1  0.716  0.818  0.558  1.0
  P  P10  1  0.558  0.716  0.818  1.0
  P  P11  1  0.818  0.558  0.716  1.0
  N  N12  1  0.570  0.813  0.665  1.0
  N  N13  1  0.665  0.570  0.813  1.0
  N  N14  1  0.813  0.665  0.570  1.0
  N  N15  1  0.430  0.187  0.335  1.0
  N  N16  1  0.335  0.430  0.187  1.0
  N  N17  1  0.187  0.335  0.430  1.0
  O  O18  1  0.376  0.638  0.805  1.0
  O  O19  1  0.805  0.376  0.638  1.0
  O  O20  1  0.638  0.805  0.376  1.0
  O  O21  1  0.624  0.362  0.195  1.0
  O  O22  1  0.195  0.624  0.362  1.0
  O  O23  1  0.362  0.195  0.624  1.0
  O  O24  1  0.851  0.977  0.645  1.0
  O  O25  1  0.645  0.851  0.977  1.0
  O  O26  1  0.977  0.645  0.851  1.0
  O  O27  1  0.149  0.023  0.355  1.0
  O  O28  1  0.355  0.149  0.023  1.0
  O  O29  1  0.023  0.355  0.149  1.0
[/CIF]
.