The compound described by CrOF4 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of sixteen CrOF4 clusters. Cr(1) is bonded in a distorted trigonal bipyramidal geometry to one O(1), one F(1), one F(3), one F(5), and one F(7) atom. O(1) is bonded in a single-bond geometry to one Cr(1) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Cr(1) atom. In the second F site, F(3) is bonded in a single-bond geometry to one Cr(1) atom. In the third F site, F(5) is bonded in a single-bond geometry to one Cr(1) atom. In the fourth F site, F(7) is bonded in a single-bond geometry to one Cr(1) atom. is represented by the CIF file [CIF]
data_CrOF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.983
_cell_length_b   9.983
_cell_length_c   15.117
_cell_angle_alpha   67.519
_cell_angle_beta   67.519
_cell_angle_gamma   33.565
_symmetry_Int_Tables_number   1
_cell_volume   763.617
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.468  0.311  0.177  1.0
  Cr  Cr1  1  0.053  0.218  0.607  1.0
  Cr  Cr2  1  0.689  0.532  0.323  1.0
  Cr  Cr3  1  0.218  0.053  0.107  1.0
  Cr  Cr4  1  0.782  0.947  0.893  1.0
  Cr  Cr5  1  0.311  0.468  0.677  1.0
  Cr  Cr6  1  0.947  0.782  0.393  1.0
  Cr  Cr7  1  0.532  0.689  0.823  1.0
  O  O8  1  0.256  0.485  0.118  1.0
  O  O9  1  0.275  0.068  0.527  1.0
  O  O10  1  0.515  0.744  0.382  1.0
  O  O11  1  0.068  0.275  0.027  1.0
  O  O12  1  0.932  0.725  0.973  1.0
  O  O13  1  0.485  0.256  0.618  1.0
  O  O14  1  0.725  0.932  0.473  1.0
  O  O15  1  0.744  0.515  0.882  1.0
  F  F16  1  0.709  0.033  0.130  1.0
  F  F17  1  0.914  0.675  0.346  1.0
  F  F18  1  0.422  0.184  0.277  1.0
  F  F19  1  0.819  0.514  0.547  1.0
  F  F20  1  0.662  0.499  0.743  1.0
  F  F21  1  0.169  0.000  0.713  1.0
  F  F22  1  0.379  0.647  0.889  1.0
  F  F23  1  0.816  0.578  0.223  1.0
  F  F24  1  0.325  0.086  0.154  1.0
  F  F25  1  0.967  0.291  0.370  1.0
  F  F26  1  0.815  0.092  0.895  1.0
  F  F27  1  0.908  0.185  0.605  1.0
  F  F28  1  0.353  0.621  0.611  1.0
  F  F29  1  0.514  0.819  0.047  1.0
  F  F30  1  1.000  0.831  0.787  1.0
  F  F31  1  0.501  0.338  0.757  1.0
  F  F32  1  0.499  0.662  0.243  1.0
  F  F33  1  0.000  0.169  0.213  1.0
  F  F34  1  0.486  0.181  0.953  1.0
  F  F35  1  0.647  0.379  0.389  1.0
  F  F36  1  0.092  0.815  0.395  1.0
  F  F37  1  0.185  0.908  0.105  1.0
  F  F38  1  0.033  0.709  0.630  1.0
  F  F39  1  0.675  0.914  0.846  1.0
  F  F40  1  0.184  0.422  0.777  1.0
  F  F41  1  0.621  0.353  0.111  1.0
  F  F42  1  0.831  1.000  0.287  1.0
  F  F43  1  0.338  0.501  0.257  1.0
  F  F44  1  0.181  0.486  0.453  1.0
  F  F45  1  0.578  0.816  0.723  1.0
  F  F46  1  0.086  0.325  0.654  1.0
  F  F47  1  0.291  0.967  0.870  1.0
[/CIF]
.
The compound described by CrOF4 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of sixteen CrOF4 clusters. Cr(1) is bonded in a distorted trigonal bipyramidal geometry to one O(1), one F(1), one F(3), one F(5), and one F(7) atom. O(1) is bonded in a single-bond geometry to one Cr(1) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Cr(1) atom. In the second F site, F(3) is bonded in a single-bond geometry to one Cr(1) atom. In the third F site, F(5) is bonded in a single-bond geometry to one Cr(1) atom. In the fourth F site, F(7) is bonded in a single-bond geometry to one Cr(1) atom. is represented by the CIF file [CIF]
data_CrOF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.983
_cell_length_b   9.983
_cell_length_c   15.117
_cell_angle_alpha   67.519
_cell_angle_beta   67.519
_cell_angle_gamma   33.565
_symmetry_Int_Tables_number   1
_cell_volume   763.617
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.468  0.311  0.177  1.0
  Cr  Cr1  1  0.053  0.218  0.607  1.0
  Cr  Cr2  1  0.689  0.532  0.323  1.0
  Cr  Cr3  1  0.218  0.053  0.107  1.0
  Cr  Cr4  1  0.782  0.947  0.893  1.0
  Cr  Cr5  1  0.311  0.468  0.677  1.0
  Cr  Cr6  1  0.947  0.782  0.393  1.0
  Cr  Cr7  1  0.532  0.689  0.823  1.0
  O  O8  1  0.256  0.485  0.118  1.0
  O  O9  1  0.275  0.068  0.527  1.0
  O  O10  1  0.515  0.744  0.382  1.0
  O  O11  1  0.068  0.275  0.027  1.0
  O  O12  1  0.932  0.725  0.973  1.0
  O  O13  1  0.485  0.256  0.618  1.0
  O  O14  1  0.725  0.932  0.473  1.0
  O  O15  1  0.744  0.515  0.882  1.0
  F  F16  1  0.709  0.033  0.130  1.0
  F  F17  1  0.914  0.675  0.346  1.0
  F  F18  1  0.422  0.184  0.277  1.0
  F  F19  1  0.819  0.514  0.547  1.0
  F  F20  1  0.662  0.499  0.743  1.0
  F  F21  1  0.169  0.000  0.713  1.0
  F  F22  1  0.379  0.647  0.889  1.0
  F  F23  1  0.816  0.578  0.223  1.0
  F  F24  1  0.325  0.086  0.154  1.0
  F  F25  1  0.967  0.291  0.370  1.0
  F  F26  1  0.815  0.092  0.895  1.0
  F  F27  1  0.908  0.185  0.605  1.0
  F  F28  1  0.353  0.621  0.611  1.0
  F  F29  1  0.514  0.819  0.047  1.0
  F  F30  1  1.000  0.831  0.787  1.0
  F  F31  1  0.501  0.338  0.757  1.0
  F  F32  1  0.499  0.662  0.243  1.0
  F  F33  1  0.000  0.169  0.213  1.0
  F  F34  1  0.486  0.181  0.953  1.0
  F  F35  1  0.647  0.379  0.389  1.0
  F  F36  1  0.092  0.815  0.395  1.0
  F  F37  1  0.185  0.908  0.105  1.0
  F  F38  1  0.033  0.709  0.630  1.0
  F  F39  1  0.675  0.914  0.846  1.0
  F  F40  1  0.184  0.422  0.777  1.0
  F  F41  1  0.621  0.353  0.111  1.0
  F  F42  1  0.831  1.000  0.287  1.0
  F  F43  1  0.338  0.501  0.257  1.0
  F  F44  1  0.181  0.486  0.453  1.0
  F  F45  1  0.578  0.816  0.723  1.0
  F  F46  1  0.086  0.325  0.654  1.0
  F  F47  1  0.291  0.967  0.870  1.0
[/CIF]
.