The structure described by RbO2Cl crystallizes in the orthorhombic Cmcm space group. Rb(1) is bonded to eight equivalent O(1) atoms to form a mixture of distorted face, corner, and edge-sharing RbO8 hexagonal bipyramids. O(1) is bonded in a 5-coordinate geometry to four equivalent Rb(1) and one Cl(1) atom. Cl(1) is bonded in a water-like geometry to two equivalent O(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbClO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.652
_cell_length_b   4.652
_cell_length_c   8.013
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   91.675
_symmetry_Int_Tables_number   1
_cell_volume   173.337
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.500  0.500  0.000  1.0
  Rb  Rb1  1  0.500  0.500  0.500  1.0
  Cl  Cl2  1  0.964  0.036  0.250  1.0
  Cl  Cl3  1  0.036  0.964  0.750  1.0
  O  O4  1  0.973  0.627  0.750  1.0
  O  O5  1  0.627  0.973  0.250  1.0
  O  O6  1  0.373  0.027  0.750  1.0
  O  O7  1  0.027  0.373  0.250  1.0
[/CIF]
.
The structure described by RbO2Cl crystallizes in the orthorhombic Cmcm space group. Rb(1) is bonded to eight equivalent O(1) atoms to form a mixture of distorted face, corner, and edge-sharing RbO8 hexagonal bipyramids. O(1) is bonded in a 5-coordinate geometry to four equivalent Rb(1) and one Cl(1) atom. Cl(1) is bonded in a water-like geometry to two equivalent O(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbClO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.652
_cell_length_b   4.652
_cell_length_c   8.013
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   91.675
_symmetry_Int_Tables_number   1
_cell_volume   173.337
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.500  0.500  0.000  1.0
  Rb  Rb1  1  0.500  0.500  0.500  1.0
  Cl  Cl2  1  0.964  0.036  0.250  1.0
  Cl  Cl3  1  0.036  0.964  0.750  1.0
  O  O4  1  0.973  0.627  0.750  1.0
  O  O5  1  0.627  0.973  0.250  1.0
  O  O6  1  0.373  0.027  0.750  1.0
  O  O7  1  0.027  0.373  0.250  1.0
[/CIF]
.