The structure described by LiSn3Sb(PO4)6 crystallizes in the triclinic P1 space group. Li(1) is bonded in a 6-coordinate geometry to one O(10), one O(12), one O(14), one O(15), one O(19), and one O(8) atom. There are three inequivalent Sn sites. In the first Sn site, Sn(1) is bonded to one O(1), one O(16), one O(21), one O(3), one O(4), and one O(7) atom to form SnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, and  a cornercorner with one P(6)O4 tetrahedra. In the second Sn site, Sn(2) is bonded to one O(10), one O(12), one O(2), one O(5), one O(8), and one O(9) atom to form SnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, and  a cornercorner with one P(6)O4 tetrahedra. In the third Sn site, Sn(3) is bonded to one O(14), one O(15), one O(17), one O(19), one O(22), and one O(24) atom to form SnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, and  a cornercorner with one P(6)O4 tetrahedra. Sb(1) is bonded to one O(11), one O(13), one O(18), one O(20), one O(23), and one O(6) atom to form SbO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, and  a cornercorner with one P(6)O4 tetrahedra. There are six inequivalent P sites. In the first P site, P(1) is bonded to one O(24), one O(4), one O(6), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Sn(1)O6 octahedra,  a cornercorner with one Sn(2)O6 octahedra,  a cornercorner with one Sn(3)O6 octahedra, and  a cornercorner with one Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 23-46°. In the second P site, P(2) is bonded to one O(10), one O(13), one O(17), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Sn(1)O6 octahedra,  a cornercorner with one Sn(2)O6 octahedra,  a cornercorner with one Sn(3)O6 octahedra, and  a cornercorner with one Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 21-47°. In the third P site, P(3) is bonded to one O(1), one O(11), one O(14), and one O(5) atom to form PO4 tetrahedra that share  a cornercorner with one Sn(1)O6 octahedra,  a cornercorner with one Sn(2)O6 octahedra,  a cornercorner with one Sn(3)O6 octahedra, and  a cornercorner with one Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 23-45°. In the fourth P site, P(4) is bonded to one O(12), one O(16), one O(18), and one O(22) atom to form PO4 tetrahedra that share  a cornercorner with one Sn(1)O6 octahedra,  a cornercorner with one Sn(2)O6 octahedra,  a cornercorner with one Sn(3)O6 octahedra, and  a cornercorner with one Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 23-47°. In the fifth P site, P(5) is bonded to one O(15), one O(20), one O(3), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Sn(1)O6 octahedra,  a cornercorner with one Sn(2)O6 octahedra,  a cornercorner with one Sn(3)O6 octahedra, and  a cornercorner with one Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 13-45°. In the sixth P site, P(6) is bonded to one O(19), one O(2), one O(21), and one O(23) atom to form PO4 tetrahedra that share  a cornercorner with one Sn(1)O6 octahedra,  a cornercorner with one Sn(2)O6 octahedra,  a cornercorner with one Sn(3)O6 octahedra, and  a cornercorner with one Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 23-41°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Sn(1) and one P(3) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Sn(2) and one P(6) atom. In the third O site, O(3) is bonded in a linear geometry to one Sn(1) and one P(5) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Sn(1) and one P(1) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Sn(2) and one P(3) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one Sb(1) and one P(1) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one Sn(1) and one P(2) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Li(1), one Sn(2), and one P(1) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one Sn(2) and one P(5) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Li(1), one Sn(2), and one P(2) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to one Sb(1) and one P(3) atom. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to one Li(1), one Sn(2), and one P(4) atom. In the thirteenth O site, O(13) is bonded in a bent 150 degrees geometry to one Sb(1) and one P(2) atom. In the fourteenth O site, O(14) is bonded in a 3-coordinate geometry to one Li(1), one Sn(3), and one P(3) atom. In the fifteenth O site, O(15) is bonded in a 3-coordinate geometry to one Li(1), one Sn(3), and one P(5) atom. In the sixteenth O site, O(16) is bonded in a bent 150 degrees geometry to one Sn(1) and one P(4) atom. In the seventeenth O site, O(17) is bonded in a bent 150 degrees geometry to one Sn(3) and one P(2) atom. In the eighteenth O site, O(18) is bonded in a bent 150 degrees geometry to one Sb(1) and one P(4) atom. In the nineteenth O site, O(19) is bonded in a 3-coordinate geometry to one Li(1), one Sn(3), and one P(6) atom. In the twentieth O site, O(20) is bonded in a bent 150 degrees geometry to one Sb(1) and one P(5) atom. In the twenty-first O site, O(21) is bonded in a bent 150 degrees geometry to one Sn(1) and one P(6) atom. In the twenty-second O site, O(22) is bonded in a bent 150 degrees geometry to one Sn(3) and one P(4) atom. In the twenty-third O site, O(23) is bonded in a bent 150 degrees geometry to one Sb(1) and one P(6) atom. In the twenty-fourth O site, O(24) is bonded in a bent 150 degrees geometry to one Sn(3) and one P(1) atom. is represented by the CIF card [CIF]
data_LiSn3Sb(PO4)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.753
_cell_length_b   8.756
_cell_length_c   8.784
_cell_angle_alpha   90.105
_cell_angle_beta   119.783
_cell_angle_gamma   119.877
_symmetry_Int_Tables_number   1
_cell_volume   478.074
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.991  0.499  0.504  1.0
  Sn  Sn1  1  0.719  0.857  0.584  1.0
  Sn  Sn2  1  0.290  0.644  0.929  1.0
  Sn  Sn3  1  0.715  0.354  0.075  1.0
  Sb  Sb4  1  0.281  0.139  0.421  1.0
  P  P5  1  0.794  0.255  0.748  1.0
  P  P6  1  0.209  0.955  0.748  1.0
  P  P7  1  0.500  0.456  0.254  1.0
  P  P8  1  0.495  0.536  0.749  1.0
  P  P9  1  0.791  0.038  0.248  1.0
  P  P10  1  0.213  0.750  0.260  1.0
  O  O11  1  0.613  0.609  0.428  1.0
  O  O12  1  0.207  0.710  0.086  1.0
  O  O13  1  0.789  0.983  0.411  1.0
  O  O14  1  0.829  0.101  0.747  1.0
  O  O15  1  0.368  0.481  0.072  1.0
  O  O16  1  0.574  0.195  0.569  1.0
  O  O17  1  0.022  0.926  0.748  1.0
  O  O18  1  0.964  0.429  0.736  1.0
  O  O19  1  0.593  0.885  0.059  1.0
  O  O20  1  0.197  0.772  0.734  1.0
  O  O21  1  0.335  0.262  0.248  1.0
  O  O22  1  0.310  0.535  0.734  1.0
  O  O23  1  0.193  0.001  0.572  1.0
  O  O24  1  0.679  0.446  0.266  1.0
  O  O25  1  0.812  0.226  0.263  1.0
  O  O26  1  0.659  0.723  0.755  1.0
  O  O27  1  0.416  0.112  0.929  1.0
  O  O28  1  0.379  0.378  0.569  1.0
  O  O29  1  0.030  0.581  0.261  1.0
  O  O30  1  0.986  0.071  0.254  1.0
  O  O31  1  0.420  0.805  0.442  1.0
  O  O32  1  0.620  0.503  0.927  1.0
  O  O33  1  0.180  0.910  0.253  1.0
  O  O34  1  0.813  0.302  0.927  1.0
[/CIF]
.
The structure described by LiSn3Sb(PO4)6 crystallizes in the triclinic P1 space group. Li(1) is bonded in a 6-coordinate geometry to one O(10), one O(12), one O(14), one O(15), one O(19), and one O(8) atom. There are three inequivalent Sn sites. In the first Sn site, Sn(1) is bonded to one O(1), one O(16), one O(21), one O(3), one O(4), and one O(7) atom to form SnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, and  a cornercorner with one P(6)O4 tetrahedra. In the second Sn site, Sn(2) is bonded to one O(10), one O(12), one O(2), one O(5), one O(8), and one O(9) atom to form SnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, and  a cornercorner with one P(6)O4 tetrahedra. In the third Sn site, Sn(3) is bonded to one O(14), one O(15), one O(17), one O(19), one O(22), and one O(24) atom to form SnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, and  a cornercorner with one P(6)O4 tetrahedra. Sb(1) is bonded to one O(11), one O(13), one O(18), one O(20), one O(23), and one O(6) atom to form SbO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, and  a cornercorner with one P(6)O4 tetrahedra. There are six inequivalent P sites. In the first P site, P(1) is bonded to one O(24), one O(4), one O(6), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Sn(1)O6 octahedra,  a cornercorner with one Sn(2)O6 octahedra,  a cornercorner with one Sn(3)O6 octahedra, and  a cornercorner with one Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 23-46°. In the second P site, P(2) is bonded to one O(10), one O(13), one O(17), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Sn(1)O6 octahedra,  a cornercorner with one Sn(2)O6 octahedra,  a cornercorner with one Sn(3)O6 octahedra, and  a cornercorner with one Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 21-47°. In the third P site, P(3) is bonded to one O(1), one O(11), one O(14), and one O(5) atom to form PO4 tetrahedra that share  a cornercorner with one Sn(1)O6 octahedra,  a cornercorner with one Sn(2)O6 octahedra,  a cornercorner with one Sn(3)O6 octahedra, and  a cornercorner with one Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 23-45°. In the fourth P site, P(4) is bonded to one O(12), one O(16), one O(18), and one O(22) atom to form PO4 tetrahedra that share  a cornercorner with one Sn(1)O6 octahedra,  a cornercorner with one Sn(2)O6 octahedra,  a cornercorner with one Sn(3)O6 octahedra, and  a cornercorner with one Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 23-47°. In the fifth P site, P(5) is bonded to one O(15), one O(20), one O(3), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Sn(1)O6 octahedra,  a cornercorner with one Sn(2)O6 octahedra,  a cornercorner with one Sn(3)O6 octahedra, and  a cornercorner with one Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 13-45°. In the sixth P site, P(6) is bonded to one O(19), one O(2), one O(21), and one O(23) atom to form PO4 tetrahedra that share  a cornercorner with one Sn(1)O6 octahedra,  a cornercorner with one Sn(2)O6 octahedra,  a cornercorner with one Sn(3)O6 octahedra, and  a cornercorner with one Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 23-41°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Sn(1) and one P(3) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Sn(2) and one P(6) atom. In the third O site, O(3) is bonded in a linear geometry to one Sn(1) and one P(5) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Sn(1) and one P(1) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Sn(2) and one P(3) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one Sb(1) and one P(1) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one Sn(1) and one P(2) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Li(1), one Sn(2), and one P(1) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one Sn(2) and one P(5) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Li(1), one Sn(2), and one P(2) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to one Sb(1) and one P(3) atom. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to one Li(1), one Sn(2), and one P(4) atom. In the thirteenth O site, O(13) is bonded in a bent 150 degrees geometry to one Sb(1) and one P(2) atom. In the fourteenth O site, O(14) is bonded in a 3-coordinate geometry to one Li(1), one Sn(3), and one P(3) atom. In the fifteenth O site, O(15) is bonded in a 3-coordinate geometry to one Li(1), one Sn(3), and one P(5) atom. In the sixteenth O site, O(16) is bonded in a bent 150 degrees geometry to one Sn(1) and one P(4) atom. In the seventeenth O site, O(17) is bonded in a bent 150 degrees geometry to one Sn(3) and one P(2) atom. In the eighteenth O site, O(18) is bonded in a bent 150 degrees geometry to one Sb(1) and one P(4) atom. In the nineteenth O site, O(19) is bonded in a 3-coordinate geometry to one Li(1), one Sn(3), and one P(6) atom. In the twentieth O site, O(20) is bonded in a bent 150 degrees geometry to one Sb(1) and one P(5) atom. In the twenty-first O site, O(21) is bonded in a bent 150 degrees geometry to one Sn(1) and one P(6) atom. In the twenty-second O site, O(22) is bonded in a bent 150 degrees geometry to one Sn(3) and one P(4) atom. In the twenty-third O site, O(23) is bonded in a bent 150 degrees geometry to one Sb(1) and one P(6) atom. In the twenty-fourth O site, O(24) is bonded in a bent 150 degrees geometry to one Sn(3) and one P(1) atom. is represented by the CIF card [CIF]
data_LiSn3Sb(PO4)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.753
_cell_length_b   8.756
_cell_length_c   8.784
_cell_angle_alpha   90.105
_cell_angle_beta   119.783
_cell_angle_gamma   119.877
_symmetry_Int_Tables_number   1
_cell_volume   478.074
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.991  0.499  0.504  1.0
  Sn  Sn1  1  0.719  0.857  0.584  1.0
  Sn  Sn2  1  0.290  0.644  0.929  1.0
  Sn  Sn3  1  0.715  0.354  0.075  1.0
  Sb  Sb4  1  0.281  0.139  0.421  1.0
  P  P5  1  0.794  0.255  0.748  1.0
  P  P6  1  0.209  0.955  0.748  1.0
  P  P7  1  0.500  0.456  0.254  1.0
  P  P8  1  0.495  0.536  0.749  1.0
  P  P9  1  0.791  0.038  0.248  1.0
  P  P10  1  0.213  0.750  0.260  1.0
  O  O11  1  0.613  0.609  0.428  1.0
  O  O12  1  0.207  0.710  0.086  1.0
  O  O13  1  0.789  0.983  0.411  1.0
  O  O14  1  0.829  0.101  0.747  1.0
  O  O15  1  0.368  0.481  0.072  1.0
  O  O16  1  0.574  0.195  0.569  1.0
  O  O17  1  0.022  0.926  0.748  1.0
  O  O18  1  0.964  0.429  0.736  1.0
  O  O19  1  0.593  0.885  0.059  1.0
  O  O20  1  0.197  0.772  0.734  1.0
  O  O21  1  0.335  0.262  0.248  1.0
  O  O22  1  0.310  0.535  0.734  1.0
  O  O23  1  0.193  0.001  0.572  1.0
  O  O24  1  0.679  0.446  0.266  1.0
  O  O25  1  0.812  0.226  0.263  1.0
  O  O26  1  0.659  0.723  0.755  1.0
  O  O27  1  0.416  0.112  0.929  1.0
  O  O28  1  0.379  0.378  0.569  1.0
  O  O29  1  0.030  0.581  0.261  1.0
  O  O30  1  0.986  0.071  0.254  1.0
  O  O31  1  0.420  0.805  0.442  1.0
  O  O32  1  0.620  0.503  0.927  1.0
  O  O33  1  0.180  0.910  0.253  1.0
  O  O34  1  0.813  0.302  0.927  1.0
[/CIF]
.