The compound described by KGa(PH)2 crystallizes in the orthorhombic Pnma space group. K(1) is bonded in a 9-coordinate geometry to six equivalent P(1), one H(2), and two equivalent H(1) atoms. Ga(1) is bonded in a distorted tetrahedral geometry to two equivalent P(1), one H(1), and one H(2) atom. P(1) is bonded in a 6-coordinate geometry to three equivalent K(1), one Ga(1), and two equivalent P(1) atoms. There are two inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to two equivalent K(1) and one Ga(1) atom. In the second H site, H(2) is bonded in a distorted bent 150 degrees geometry to one K(1) and one Ga(1) atom. is represented by the CIF card [CIF]
data_KGa(PH)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.325
_cell_length_b   7.978
_cell_length_c   11.902
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   505.633
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.250  0.734  0.194  1.0
  K  K1  1  0.750  0.266  0.806  1.0
  K  K2  1  0.750  0.234  0.306  1.0
  K  K3  1  0.250  0.766  0.694  1.0
  Ga  Ga4  1  0.250  0.190  0.007  1.0
  Ga  Ga5  1  0.750  0.810  0.993  1.0
  Ga  Ga6  1  0.750  0.690  0.493  1.0
  Ga  Ga7  1  0.250  0.310  0.507  1.0
  P  P8  1  0.964  0.408  0.068  1.0
  P  P9  1  0.036  0.592  0.932  1.0
  P  P10  1  0.036  0.908  0.432  1.0
  P  P11  1  0.464  0.592  0.932  1.0
  P  P12  1  0.964  0.092  0.568  1.0
  P  P13  1  0.536  0.408  0.068  1.0
  P  P14  1  0.536  0.092  0.568  1.0
  P  P15  1  0.464  0.908  0.432  1.0
  H  H16  1  0.250  0.363  0.377  1.0
  H  H17  1  0.750  0.637  0.623  1.0
  H  H18  1  0.750  0.863  0.123  1.0
  H  H19  1  0.250  0.137  0.877  1.0
  H  H20  1  0.250  0.048  0.099  1.0
  H  H21  1  0.750  0.952  0.901  1.0
  H  H22  1  0.750  0.548  0.401  1.0
  H  H23  1  0.250  0.452  0.599  1.0
[/CIF]
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The compound described by KGa(PH)2 crystallizes in the orthorhombic Pnma space group. K(1) is bonded in a 9-coordinate geometry to six equivalent P(1), one H(2), and two equivalent H(1) atoms. Ga(1) is bonded in a distorted tetrahedral geometry to two equivalent P(1), one H(1), and one H(2) atom. P(1) is bonded in a 6-coordinate geometry to three equivalent K(1), one Ga(1), and two equivalent P(1) atoms. There are two inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to two equivalent K(1) and one Ga(1) atom. In the second H site, H(2) is bonded in a distorted bent 150 degrees geometry to one K(1) and one Ga(1) atom. is represented by the CIF card [CIF]
data_KGa(PH)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.325
_cell_length_b   7.978
_cell_length_c   11.902
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   505.633
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.250  0.734  0.194  1.0
  K  K1  1  0.750  0.266  0.806  1.0
  K  K2  1  0.750  0.234  0.306  1.0
  K  K3  1  0.250  0.766  0.694  1.0
  Ga  Ga4  1  0.250  0.190  0.007  1.0
  Ga  Ga5  1  0.750  0.810  0.993  1.0
  Ga  Ga6  1  0.750  0.690  0.493  1.0
  Ga  Ga7  1  0.250  0.310  0.507  1.0
  P  P8  1  0.964  0.408  0.068  1.0
  P  P9  1  0.036  0.592  0.932  1.0
  P  P10  1  0.036  0.908  0.432  1.0
  P  P11  1  0.464  0.592  0.932  1.0
  P  P12  1  0.964  0.092  0.568  1.0
  P  P13  1  0.536  0.408  0.068  1.0
  P  P14  1  0.536  0.092  0.568  1.0
  P  P15  1  0.464  0.908  0.432  1.0
  H  H16  1  0.250  0.363  0.377  1.0
  H  H17  1  0.750  0.637  0.623  1.0
  H  H18  1  0.750  0.863  0.123  1.0
  H  H19  1  0.250  0.137  0.877  1.0
  H  H20  1  0.250  0.048  0.099  1.0
  H  H21  1  0.750  0.952  0.901  1.0
  H  H22  1  0.750  0.548  0.401  1.0
  H  H23  1  0.250  0.452  0.599  1.0
[/CIF]
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