The material described by BaCoSO crystallizes in the orthorhombic Cmcm space group. Ba(1) is bonded in a 8-coordinate geometry to four equivalent S(1) and four equivalent O(1) atoms. Co(1) is bonded to two equivalent S(1) and two equivalent O(1) atoms to form distorted corner-sharing CoS2O2 tetrahedra. S(1) is bonded in a 6-coordinate geometry to four equivalent Ba(1) and two equivalent Co(1) atoms. O(1) is bonded to four equivalent Ba(1) and two equivalent Co(1) atoms to form a mixture of distorted edge, face, and corner-sharing OBa4Co2 octahedra. The corner-sharing octahedral tilt angles are 60°. is represented by the CIF card [CIF]
data_BaCoSO
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.035
_cell_length_b   6.180
_cell_length_c   6.765
_cell_angle_alpha   90.000
_cell_angle_beta   107.353
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   161.016
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.614  0.250  0.227  1.0
  Ba  Ba1  1  0.386  0.750  0.773  1.0
  Co  Co2  1  0.906  0.250  0.811  1.0
  Co  Co3  1  0.094  0.750  0.189  1.0
  S  S4  1  0.310  0.250  0.619  1.0
  S  S5  1  0.690  0.750  0.381  1.0
  O  O6  1  0.000  0.000  0.000  1.0
  O  O7  1  0.000  0.500  0.000  1.0
[/CIF]
.
The material described by BaCoSO crystallizes in the orthorhombic Cmcm space group. Ba(1) is bonded in a 8-coordinate geometry to four equivalent S(1) and four equivalent O(1) atoms. Co(1) is bonded to two equivalent S(1) and two equivalent O(1) atoms to form distorted corner-sharing CoS2O2 tetrahedra. S(1) is bonded in a 6-coordinate geometry to four equivalent Ba(1) and two equivalent Co(1) atoms. O(1) is bonded to four equivalent Ba(1) and two equivalent Co(1) atoms to form a mixture of distorted edge, face, and corner-sharing OBa4Co2 octahedra. The corner-sharing octahedral tilt angles are 60°. is represented by the CIF card [CIF]
data_BaCoSO
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.035
_cell_length_b   6.180
_cell_length_c   6.765
_cell_angle_alpha   90.000
_cell_angle_beta   107.353
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   161.016
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.614  0.250  0.227  1.0
  Ba  Ba1  1  0.386  0.750  0.773  1.0
  Co  Co2  1  0.906  0.250  0.811  1.0
  Co  Co3  1  0.094  0.750  0.189  1.0
  S  S4  1  0.310  0.250  0.619  1.0
  S  S5  1  0.690  0.750  0.381  1.0
  O  O6  1  0.000  0.000  0.000  1.0
  O  O7  1  0.000  0.500  0.000  1.0
[/CIF]
.