The structure described by PrLa4(CoP)10 crystallizes in the tetragonal I4/mmm space group. Pr(1) is bonded in a distorted body-centered cubic geometry to eight equivalent P(1) atoms. There are two inequivalent La sites. In the first La site, La(1) is bonded in a distorted body-centered cubic geometry to four equivalent P(2) and four equivalent P(5) atoms. In the second La site, La(2) is bonded in a distorted body-centered cubic geometry to four equivalent P(3) and four equivalent P(4) atoms. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded to two equivalent P(1) and two equivalent P(5) atoms to form a mixture of corner and edge-sharing CoP4 tetrahedra. In the second Co site, Co(2) is bonded to two equivalent P(2) and two equivalent P(4) atoms to form a mixture of corner and edge-sharing CoP4 tetrahedra. In the third Co site, Co(3) is bonded to four equivalent P(3) atoms to form a mixture of corner and edge-sharing CoP4 tetrahedra. There are five inequivalent P sites. In the first P site, P(3) is bonded in a 8-coordinate geometry to four equivalent La(2) and four equivalent Co(3) atoms. In the second P site, P(4) is bonded in a 8-coordinate geometry to four equivalent La(2) and four equivalent Co(2) atoms. In the third P site, P(5) is bonded in a 8-coordinate geometry to four equivalent La(1) and four equivalent Co(1) atoms. In the fourth P site, P(1) is bonded in a 8-coordinate geometry to four equivalent Pr(1) and four equivalent Co(1) atoms. In the fifth P site, P(2) is bonded in a 8-coordinate geometry to four equivalent La(1) and four equivalent Co(2) atoms. is represented by the CIF file [CIF]
data_La4Pr(CoP)10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.803
_cell_length_b   3.803
_cell_length_c   27.787
_cell_angle_alpha   93.924
_cell_angle_beta   93.924
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   399.920
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.600  0.600  0.200  1.0
  La  La1  1  0.200  0.200  0.400  1.0
  La  La2  1  0.800  0.800  0.600  1.0
  La  La3  1  0.400  0.400  0.800  1.0
  Pr  Pr4  1  0.000  0.000  0.000  1.0
  Co  Co5  1  0.049  0.549  0.099  1.0
  Co  Co6  1  0.650  0.150  0.300  1.0
  Co  Co7  1  0.250  0.750  0.500  1.0
  Co  Co8  1  0.850  0.350  0.700  1.0
  Co  Co9  1  0.451  0.951  0.901  1.0
  Co  Co10  1  0.549  0.049  0.099  1.0
  Co  Co11  1  0.150  0.650  0.300  1.0
  Co  Co12  1  0.750  0.250  0.500  1.0
  Co  Co13  1  0.350  0.850  0.700  1.0
  Co  Co14  1  0.951  0.451  0.901  1.0
  P  P15  1  0.528  0.528  0.057  1.0
  P  P16  1  0.129  0.129  0.259  1.0
  P  P17  1  0.729  0.729  0.459  1.0
  P  P18  1  0.329  0.329  0.659  1.0
  P  P19  1  0.930  0.930  0.859  1.0
  P  P20  1  0.070  0.070  0.141  1.0
  P  P21  1  0.671  0.671  0.341  1.0
  P  P22  1  0.271  0.271  0.541  1.0
  P  P23  1  0.871  0.871  0.741  1.0
  P  P24  1  0.472  0.472  0.943  1.0
[/CIF]
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The structure described by PrLa4(CoP)10 crystallizes in the tetragonal I4/mmm space group. Pr(1) is bonded in a distorted body-centered cubic geometry to eight equivalent P(1) atoms. There are two inequivalent La sites. In the first La site, La(1) is bonded in a distorted body-centered cubic geometry to four equivalent P(2) and four equivalent P(5) atoms. In the second La site, La(2) is bonded in a distorted body-centered cubic geometry to four equivalent P(3) and four equivalent P(4) atoms. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded to two equivalent P(1) and two equivalent P(5) atoms to form a mixture of corner and edge-sharing CoP4 tetrahedra. In the second Co site, Co(2) is bonded to two equivalent P(2) and two equivalent P(4) atoms to form a mixture of corner and edge-sharing CoP4 tetrahedra. In the third Co site, Co(3) is bonded to four equivalent P(3) atoms to form a mixture of corner and edge-sharing CoP4 tetrahedra. There are five inequivalent P sites. In the first P site, P(3) is bonded in a 8-coordinate geometry to four equivalent La(2) and four equivalent Co(3) atoms. In the second P site, P(4) is bonded in a 8-coordinate geometry to four equivalent La(2) and four equivalent Co(2) atoms. In the third P site, P(5) is bonded in a 8-coordinate geometry to four equivalent La(1) and four equivalent Co(1) atoms. In the fourth P site, P(1) is bonded in a 8-coordinate geometry to four equivalent Pr(1) and four equivalent Co(1) atoms. In the fifth P site, P(2) is bonded in a 8-coordinate geometry to four equivalent La(1) and four equivalent Co(2) atoms. is represented by the CIF file [CIF]
data_La4Pr(CoP)10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.803
_cell_length_b   3.803
_cell_length_c   27.787
_cell_angle_alpha   93.924
_cell_angle_beta   93.924
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   399.920
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.600  0.600  0.200  1.0
  La  La1  1  0.200  0.200  0.400  1.0
  La  La2  1  0.800  0.800  0.600  1.0
  La  La3  1  0.400  0.400  0.800  1.0
  Pr  Pr4  1  0.000  0.000  0.000  1.0
  Co  Co5  1  0.049  0.549  0.099  1.0
  Co  Co6  1  0.650  0.150  0.300  1.0
  Co  Co7  1  0.250  0.750  0.500  1.0
  Co  Co8  1  0.850  0.350  0.700  1.0
  Co  Co9  1  0.451  0.951  0.901  1.0
  Co  Co10  1  0.549  0.049  0.099  1.0
  Co  Co11  1  0.150  0.650  0.300  1.0
  Co  Co12  1  0.750  0.250  0.500  1.0
  Co  Co13  1  0.350  0.850  0.700  1.0
  Co  Co14  1  0.951  0.451  0.901  1.0
  P  P15  1  0.528  0.528  0.057  1.0
  P  P16  1  0.129  0.129  0.259  1.0
  P  P17  1  0.729  0.729  0.459  1.0
  P  P18  1  0.329  0.329  0.659  1.0
  P  P19  1  0.930  0.930  0.859  1.0
  P  P20  1  0.070  0.070  0.141  1.0
  P  P21  1  0.671  0.671  0.341  1.0
  P  P22  1  0.271  0.271  0.541  1.0
  P  P23  1  0.871  0.871  0.741  1.0
  P  P24  1  0.472  0.472  0.943  1.0
[/CIF]
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