The structure described by NaAg(CN)2 is Potassium Silver Cyanide-like structured and crystallizes in the monoclinic C2/c space group. Na(1) is bonded to six equivalent N(1) atoms to form edge-sharing NaN6 octahedra. Ag(1) is bonded in a linear geometry to two equivalent C(1) atoms. C(1) is bonded in a linear geometry to one Ag(1) and one N(1) atom. N(1) is bonded in a distorted rectangular see-saw-like geometry to three equivalent Na(1) and one C(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_NaAg(CN)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.844
_cell_length_b   3.844
_cell_length_c   17.642
_cell_angle_alpha   88.716
_cell_angle_beta   88.716
_cell_angle_gamma   59.558
_symmetry_Int_Tables_number   1
_cell_volume   224.618
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.047  0.953  0.750  1.0
  Na  Na1  1  0.953  0.047  0.250  1.0
  Ag  Ag2  1  0.500  0.000  0.000  1.0
  Ag  Ag3  1  0.000  0.500  0.500  1.0
  C  C4  1  0.809  0.585  0.611  1.0
  C  C5  1  0.415  0.191  0.889  1.0
  C  C6  1  0.191  0.415  0.389  1.0
  C  C7  1  0.585  0.809  0.111  1.0
  N  N8  1  0.707  0.631  0.675  1.0
  N  N9  1  0.293  0.369  0.325  1.0
  N  N10  1  0.631  0.707  0.175  1.0
  N  N11  1  0.369  0.293  0.825  1.0
[/CIF]
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The structure described by NaAg(CN)2 is Potassium Silver Cyanide-like structured and crystallizes in the monoclinic C2/c space group. Na(1) is bonded to six equivalent N(1) atoms to form edge-sharing NaN6 octahedra. Ag(1) is bonded in a linear geometry to two equivalent C(1) atoms. C(1) is bonded in a linear geometry to one Ag(1) and one N(1) atom. N(1) is bonded in a distorted rectangular see-saw-like geometry to three equivalent Na(1) and one C(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_NaAg(CN)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.844
_cell_length_b   3.844
_cell_length_c   17.642
_cell_angle_alpha   88.716
_cell_angle_beta   88.716
_cell_angle_gamma   59.558
_symmetry_Int_Tables_number   1
_cell_volume   224.618
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.047  0.953  0.750  1.0
  Na  Na1  1  0.953  0.047  0.250  1.0
  Ag  Ag2  1  0.500  0.000  0.000  1.0
  Ag  Ag3  1  0.000  0.500  0.500  1.0
  C  C4  1  0.809  0.585  0.611  1.0
  C  C5  1  0.415  0.191  0.889  1.0
  C  C6  1  0.191  0.415  0.389  1.0
  C  C7  1  0.585  0.809  0.111  1.0
  N  N8  1  0.707  0.631  0.675  1.0
  N  N9  1  0.293  0.369  0.325  1.0
  N  N10  1  0.631  0.707  0.175  1.0
  N  N11  1  0.369  0.293  0.825  1.0
[/CIF]
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