The crystal structure described by Li2AgF3 crystallizes in the orthorhombic Pnma space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a rectangular see-saw-like geometry to two equivalent F(1) and two equivalent F(2) atoms. In the second Li site, Li(2) is bonded to two equivalent F(3) and three equivalent F(1) atoms to form edge-sharing LiF5 square pyramids. Ag(1) is bonded in a 4-coordinate geometry to one F(2) and three equivalent F(3) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded to two equivalent Li(1) and three equivalent Li(2) atoms to form edge-sharing FLi5 square pyramids. In the second F site, F(2) is bonded in a trigonal non-coplanar geometry to two equivalent Li(1) and one Ag(1) atom. In the third F site, F(3) is bonded in a 5-coordinate geometry to two equivalent Li(2) and three equivalent Ag(1) atoms. is represented by the CIF card [CIF]
data_Li2AgF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.874
_cell_length_b   7.196
_cell_length_c   14.706
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   304.120
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.750  0.057  0.333  1.0
  Li  Li1  1  0.250  0.160  0.506  1.0
  Li  Li2  1  0.750  0.341  0.006  1.0
  Li  Li3  1  0.250  0.443  0.833  1.0
  Li  Li4  1  0.750  0.557  0.167  1.0
  Li  Li5  1  0.250  0.659  0.994  1.0
  Li  Li6  1  0.750  0.841  0.494  1.0
  Li  Li7  1  0.250  0.943  0.667  1.0
  Ag  Ag8  1  0.250  0.027  0.124  1.0
  Ag  Ag9  1  0.750  0.473  0.624  1.0
  Ag  Ag10  1  0.250  0.527  0.376  1.0
  Ag  Ag11  1  0.750  0.973  0.876  1.0
  F  F12  1  0.750  0.039  0.583  1.0
  F  F13  1  0.250  0.147  0.260  1.0
  F  F14  1  0.250  0.177  0.965  1.0
  F  F15  1  0.750  0.323  0.465  1.0
  F  F16  1  0.750  0.353  0.760  1.0
  F  F17  1  0.250  0.461  0.083  1.0
  F  F18  1  0.750  0.539  0.917  1.0
  F  F19  1  0.250  0.647  0.240  1.0
  F  F20  1  0.250  0.677  0.535  1.0
  F  F21  1  0.750  0.823  0.035  1.0
  F  F22  1  0.750  0.853  0.740  1.0
  F  F23  1  0.250  0.961  0.417  1.0
[/CIF]
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The crystal structure described by Li2AgF3 crystallizes in the orthorhombic Pnma space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a rectangular see-saw-like geometry to two equivalent F(1) and two equivalent F(2) atoms. In the second Li site, Li(2) is bonded to two equivalent F(3) and three equivalent F(1) atoms to form edge-sharing LiF5 square pyramids. Ag(1) is bonded in a 4-coordinate geometry to one F(2) and three equivalent F(3) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded to two equivalent Li(1) and three equivalent Li(2) atoms to form edge-sharing FLi5 square pyramids. In the second F site, F(2) is bonded in a trigonal non-coplanar geometry to two equivalent Li(1) and one Ag(1) atom. In the third F site, F(3) is bonded in a 5-coordinate geometry to two equivalent Li(2) and three equivalent Ag(1) atoms. is represented by the CIF card [CIF]
data_Li2AgF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.874
_cell_length_b   7.196
_cell_length_c   14.706
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   304.120
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.750  0.057  0.333  1.0
  Li  Li1  1  0.250  0.160  0.506  1.0
  Li  Li2  1  0.750  0.341  0.006  1.0
  Li  Li3  1  0.250  0.443  0.833  1.0
  Li  Li4  1  0.750  0.557  0.167  1.0
  Li  Li5  1  0.250  0.659  0.994  1.0
  Li  Li6  1  0.750  0.841  0.494  1.0
  Li  Li7  1  0.250  0.943  0.667  1.0
  Ag  Ag8  1  0.250  0.027  0.124  1.0
  Ag  Ag9  1  0.750  0.473  0.624  1.0
  Ag  Ag10  1  0.250  0.527  0.376  1.0
  Ag  Ag11  1  0.750  0.973  0.876  1.0
  F  F12  1  0.750  0.039  0.583  1.0
  F  F13  1  0.250  0.147  0.260  1.0
  F  F14  1  0.250  0.177  0.965  1.0
  F  F15  1  0.750  0.323  0.465  1.0
  F  F16  1  0.750  0.353  0.760  1.0
  F  F17  1  0.250  0.461  0.083  1.0
  F  F18  1  0.750  0.539  0.917  1.0
  F  F19  1  0.250  0.647  0.240  1.0
  F  F20  1  0.250  0.677  0.535  1.0
  F  F21  1  0.750  0.823  0.035  1.0
  F  F22  1  0.750  0.853  0.740  1.0
  F  F23  1  0.250  0.961  0.417  1.0
[/CIF]
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