The structure described by LiCo3OF5 crystallizes in the triclinic P1 space group. Li(1) is bonded in a distorted bent 150 degrees geometry to one F(1), one F(2), and one F(4) atom. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded in a 6-coordinate geometry to one O(1), one F(1), one F(2), one F(3), one F(4), and one F(5) atom. In the second Co site, Co(2) is bonded in a 5-coordinate geometry to one F(1), one F(2), one F(3), one F(4), and one F(5) atom. In the third Co site, Co(3) is bonded in a distorted bent 120 degrees geometry to one O(1), one F(3), and one F(5) atom. O(1) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one Co(3) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to one Li(1), one Co(1), and one Co(2) atom. In the second F site, F(2) is bonded in a distorted bent 120 degrees geometry to one Li(1), one Co(1), and one Co(2) atom. In the third F site, F(3) is bonded in a distorted bent 120 degrees geometry to one Co(1), one Co(2), and one Co(3) atom. In the fourth F site, F(4) is bonded in a 3-coordinate geometry to one Li(1), one Co(1), and one Co(2) atom. In the fifth F site, F(5) is bonded in a 3-coordinate geometry to one Co(1), one Co(2), and one Co(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiCo3OF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.234
_cell_length_b   5.268
_cell_length_c   5.569
_cell_angle_alpha   117.022
_cell_angle_beta   90.794
_cell_angle_gamma   119.431
_symmetry_Int_Tables_number   1
_cell_volume   113.450
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.317  0.164  0.564  1.0
  Co  Co1  1  0.705  0.338  0.964  1.0
  Co  Co2  1  0.272  0.625  0.062  1.0
  Co  Co3  1  0.713  0.879  0.427  1.0
  O  O4  1  0.809  0.254  0.238  1.0
  F  F5  1  0.518  0.453  0.754  1.0
  F  F6  1  0.190  0.936  0.233  1.0
  F  F7  1  0.795  0.039  0.753  1.0
  F  F8  1  0.193  0.757  0.741  1.0
  F  F9  1  0.489  0.555  0.265  1.0
[/CIF]
.
The structure described by LiCo3OF5 crystallizes in the triclinic P1 space group. Li(1) is bonded in a distorted bent 150 degrees geometry to one F(1), one F(2), and one F(4) atom. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded in a 6-coordinate geometry to one O(1), one F(1), one F(2), one F(3), one F(4), and one F(5) atom. In the second Co site, Co(2) is bonded in a 5-coordinate geometry to one F(1), one F(2), one F(3), one F(4), and one F(5) atom. In the third Co site, Co(3) is bonded in a distorted bent 120 degrees geometry to one O(1), one F(3), and one F(5) atom. O(1) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one Co(3) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to one Li(1), one Co(1), and one Co(2) atom. In the second F site, F(2) is bonded in a distorted bent 120 degrees geometry to one Li(1), one Co(1), and one Co(2) atom. In the third F site, F(3) is bonded in a distorted bent 120 degrees geometry to one Co(1), one Co(2), and one Co(3) atom. In the fourth F site, F(4) is bonded in a 3-coordinate geometry to one Li(1), one Co(1), and one Co(2) atom. In the fifth F site, F(5) is bonded in a 3-coordinate geometry to one Co(1), one Co(2), and one Co(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiCo3OF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.234
_cell_length_b   5.268
_cell_length_c   5.569
_cell_angle_alpha   117.022
_cell_angle_beta   90.794
_cell_angle_gamma   119.431
_symmetry_Int_Tables_number   1
_cell_volume   113.450
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.317  0.164  0.564  1.0
  Co  Co1  1  0.705  0.338  0.964  1.0
  Co  Co2  1  0.272  0.625  0.062  1.0
  Co  Co3  1  0.713  0.879  0.427  1.0
  O  O4  1  0.809  0.254  0.238  1.0
  F  F5  1  0.518  0.453  0.754  1.0
  F  F6  1  0.190  0.936  0.233  1.0
  F  F7  1  0.795  0.039  0.753  1.0
  F  F8  1  0.193  0.757  0.741  1.0
  F  F9  1  0.489  0.555  0.265  1.0
[/CIF]
.