The material structure described by CsNiP crystallizes in the orthorhombic Cmcm space group. Cs(1) is bonded in a distorted rectangular see-saw-like geometry to four equivalent P(1) atoms. Ni(1) is bonded in a linear geometry to two equivalent P(1) atoms. P(1) is bonded to four equivalent Cs(1) and two equivalent Ni(1) atoms to form a mixture of distorted corner and edge-sharing PCs4Ni2 octahedra. The corner-sharing octahedral tilt angles range from 0-80°. is represented by the Crystallographic Information File (CIF) [CIF]
data_CsNiP
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.762
_cell_length_b   6.762
_cell_length_c   5.263
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   116.165
_symmetry_Int_Tables_number   1
_cell_volume   216.024
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.663  0.337  0.750  1.0
  Cs  Cs1  1  0.337  0.663  0.250  1.0
  Ni  Ni2  1  0.000  0.000  0.000  1.0
  Ni  Ni3  1  0.000  0.000  0.500  1.0
  P  P4  1  0.856  0.144  0.250  1.0
  P  P5  1  0.144  0.856  0.750  1.0
[/CIF]
.
The material structure described by CsNiP crystallizes in the orthorhombic Cmcm space group. Cs(1) is bonded in a distorted rectangular see-saw-like geometry to four equivalent P(1) atoms. Ni(1) is bonded in a linear geometry to two equivalent P(1) atoms. P(1) is bonded to four equivalent Cs(1) and two equivalent Ni(1) atoms to form a mixture of distorted corner and edge-sharing PCs4Ni2 octahedra. The corner-sharing octahedral tilt angles range from 0-80°. is represented by the Crystallographic Information File (CIF) [CIF]
data_CsNiP
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.762
_cell_length_b   6.762
_cell_length_c   5.263
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   116.165
_symmetry_Int_Tables_number   1
_cell_volume   216.024
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.663  0.337  0.750  1.0
  Cs  Cs1  1  0.337  0.663  0.250  1.0
  Ni  Ni2  1  0.000  0.000  0.000  1.0
  Ni  Ni3  1  0.000  0.000  0.500  1.0
  P  P4  1  0.856  0.144  0.250  1.0
  P  P5  1  0.144  0.856  0.750  1.0
[/CIF]
.