The crystal structure described by K5V3F14 crystallizes in the tetragonal P4/mnc space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 6-coordinate geometry to two equivalent F(1) and four equivalent F(3) atoms. In the second K site, K(2) is bonded in a body-centered cubic geometry to eight equivalent F(3) atoms. There are two inequivalent V sites. In the first V site, V(1) is bonded to two equivalent F(1) and four equivalent F(2) atoms to form corner-sharing VF6 octahedra. The corner-sharing octahedral tilt angles are 33°. In the second V site, V(2) is bonded to two equivalent F(2) and four equivalent F(3) atoms to form corner-sharing VF6 octahedra. The corner-sharing octahedral tilt angles are 33°. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to four equivalent K(1) and one V(1) atom. In the second F site, F(2) is bonded in a bent 150 degrees geometry to one V(1) and one V(2) atom. In the third F site, F(3) is bonded in a 4-coordinate geometry to one K(2), two equivalent K(1), and one V(2) atom. is represented by the CIF file [CIF]
data_K5V3F14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.785
_cell_length_b   7.785
_cell_length_c   11.931
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   723.069
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.217  0.283  0.750  1.0
  K  K1  1  0.717  0.217  0.750  1.0
  K  K2  1  0.283  0.783  0.750  1.0
  K  K3  1  0.783  0.717  0.750  1.0
  K  K4  1  0.783  0.717  0.250  1.0
  K  K5  1  0.283  0.783  0.250  1.0
  K  K6  1  0.717  0.217  0.250  1.0
  K  K7  1  0.217  0.283  0.250  1.0
  K  K8  1  0.000  0.000  0.000  1.0
  K  K9  1  0.500  0.500  0.500  1.0
  V  V10  1  0.500  0.500  0.000  1.0
  V  V11  1  0.000  0.000  0.500  1.0
  V  V12  1  0.500  0.000  0.000  1.0
  V  V13  1  0.000  0.500  0.000  1.0
  V  V14  1  0.000  0.500  0.500  1.0
  V  V15  1  0.500  0.000  0.500  1.0
  F  F16  1  0.500  0.500  0.836  1.0
  F  F17  1  0.000  0.000  0.664  1.0
  F  F18  1  0.500  0.500  0.164  1.0
  F  F19  1  0.000  0.000  0.336  1.0
  F  F20  1  0.427  0.747  0.000  1.0
  F  F21  1  0.573  0.253  0.000  1.0
  F  F22  1  0.247  0.927  0.500  1.0
  F  F23  1  0.747  0.573  0.000  1.0
  F  F24  1  0.253  0.427  0.000  1.0
  F  F25  1  0.073  0.247  0.500  1.0
  F  F26  1  0.927  0.753  0.500  1.0
  F  F27  1  0.753  0.073  0.500  1.0
  F  F28  1  0.675  0.958  0.886  1.0
  F  F29  1  0.325  0.042  0.886  1.0
  F  F30  1  0.458  0.175  0.614  1.0
  F  F31  1  0.958  0.325  0.886  1.0
  F  F32  1  0.458  0.175  0.386  1.0
  F  F33  1  0.825  0.458  0.386  1.0
  F  F34  1  0.175  0.542  0.386  1.0
  F  F35  1  0.958  0.325  0.114  1.0
  F  F36  1  0.042  0.675  0.114  1.0
  F  F37  1  0.542  0.825  0.386  1.0
  F  F38  1  0.675  0.958  0.114  1.0
  F  F39  1  0.325  0.042  0.114  1.0
  F  F40  1  0.542  0.825  0.614  1.0
  F  F41  1  0.175  0.542  0.614  1.0
  F  F42  1  0.825  0.458  0.614  1.0
  F  F43  1  0.042  0.675  0.886  1.0
[/CIF]
.
The crystal structure described by K5V3F14 crystallizes in the tetragonal P4/mnc space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 6-coordinate geometry to two equivalent F(1) and four equivalent F(3) atoms. In the second K site, K(2) is bonded in a body-centered cubic geometry to eight equivalent F(3) atoms. There are two inequivalent V sites. In the first V site, V(1) is bonded to two equivalent F(1) and four equivalent F(2) atoms to form corner-sharing VF6 octahedra. The corner-sharing octahedral tilt angles are 33°. In the second V site, V(2) is bonded to two equivalent F(2) and four equivalent F(3) atoms to form corner-sharing VF6 octahedra. The corner-sharing octahedral tilt angles are 33°. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to four equivalent K(1) and one V(1) atom. In the second F site, F(2) is bonded in a bent 150 degrees geometry to one V(1) and one V(2) atom. In the third F site, F(3) is bonded in a 4-coordinate geometry to one K(2), two equivalent K(1), and one V(2) atom. is represented by the CIF file [CIF]
data_K5V3F14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.785
_cell_length_b   7.785
_cell_length_c   11.931
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   723.069
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.217  0.283  0.750  1.0
  K  K1  1  0.717  0.217  0.750  1.0
  K  K2  1  0.283  0.783  0.750  1.0
  K  K3  1  0.783  0.717  0.750  1.0
  K  K4  1  0.783  0.717  0.250  1.0
  K  K5  1  0.283  0.783  0.250  1.0
  K  K6  1  0.717  0.217  0.250  1.0
  K  K7  1  0.217  0.283  0.250  1.0
  K  K8  1  0.000  0.000  0.000  1.0
  K  K9  1  0.500  0.500  0.500  1.0
  V  V10  1  0.500  0.500  0.000  1.0
  V  V11  1  0.000  0.000  0.500  1.0
  V  V12  1  0.500  0.000  0.000  1.0
  V  V13  1  0.000  0.500  0.000  1.0
  V  V14  1  0.000  0.500  0.500  1.0
  V  V15  1  0.500  0.000  0.500  1.0
  F  F16  1  0.500  0.500  0.836  1.0
  F  F17  1  0.000  0.000  0.664  1.0
  F  F18  1  0.500  0.500  0.164  1.0
  F  F19  1  0.000  0.000  0.336  1.0
  F  F20  1  0.427  0.747  0.000  1.0
  F  F21  1  0.573  0.253  0.000  1.0
  F  F22  1  0.247  0.927  0.500  1.0
  F  F23  1  0.747  0.573  0.000  1.0
  F  F24  1  0.253  0.427  0.000  1.0
  F  F25  1  0.073  0.247  0.500  1.0
  F  F26  1  0.927  0.753  0.500  1.0
  F  F27  1  0.753  0.073  0.500  1.0
  F  F28  1  0.675  0.958  0.886  1.0
  F  F29  1  0.325  0.042  0.886  1.0
  F  F30  1  0.458  0.175  0.614  1.0
  F  F31  1  0.958  0.325  0.886  1.0
  F  F32  1  0.458  0.175  0.386  1.0
  F  F33  1  0.825  0.458  0.386  1.0
  F  F34  1  0.175  0.542  0.386  1.0
  F  F35  1  0.958  0.325  0.114  1.0
  F  F36  1  0.042  0.675  0.114  1.0
  F  F37  1  0.542  0.825  0.386  1.0
  F  F38  1  0.675  0.958  0.114  1.0
  F  F39  1  0.325  0.042  0.114  1.0
  F  F40  1  0.542  0.825  0.614  1.0
  F  F41  1  0.175  0.542  0.614  1.0
  F  F42  1  0.825  0.458  0.614  1.0
  F  F43  1  0.042  0.675  0.886  1.0
[/CIF]
.