The crystal structure described by NS2 is Indium-like structured and crystallizes in the tetragonal P4_2nm space group. The structure is zero-dimensional and consists of four 1,2,3,5,4,6-tetrathiadiazinane molecules. N(1) is bonded in a bent 120 degrees geometry to one S(1) and one S(3) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a distorted single-bond geometry to one N(1) and one S(2) atom. In the second S site, S(2) is bonded in a water-like geometry to two equivalent S(1) atoms. In the third S site, S(3) is bonded in a bent 120 degrees geometry to two equivalent N(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_S2N
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.868
_cell_length_b   11.868
_cell_length_c   4.248
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   598.371
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.154  0.349  0.312  1.0
  S  S1  1  0.849  0.346  0.812  1.0
  S  S2  1  0.151  0.654  0.812  1.0
  S  S3  1  0.846  0.651  0.312  1.0
  S  S4  1  0.654  0.151  0.812  1.0
  S  S5  1  0.346  0.849  0.812  1.0
  S  S6  1  0.651  0.846  0.312  1.0
  S  S7  1  0.349  0.154  0.312  1.0
  S  S8  1  0.681  0.681  0.174  1.0
  S  S9  1  0.181  0.819  0.674  1.0
  S  S10  1  0.819  0.181  0.674  1.0
  S  S11  1  0.319  0.319  0.174  1.0
  S  S12  1  0.882  0.882  0.111  1.0
  S  S13  1  0.382  0.618  0.611  1.0
  S  S14  1  0.618  0.382  0.611  1.0
  S  S15  1  0.118  0.118  0.111  1.0
  N  N16  1  0.244  0.079  0.161  1.0
  N  N17  1  0.756  0.921  0.161  1.0
  N  N18  1  0.421  0.744  0.661  1.0
  N  N19  1  0.579  0.256  0.661  1.0
  N  N20  1  0.921  0.756  0.161  1.0
  N  N21  1  0.256  0.579  0.661  1.0
  N  N22  1  0.744  0.421  0.661  1.0
  N  N23  1  0.079  0.244  0.161  1.0
[/CIF]
.
The crystal structure described by NS2 is Indium-like structured and crystallizes in the tetragonal P4_2nm space group. The structure is zero-dimensional and consists of four 1,2,3,5,4,6-tetrathiadiazinane molecules. N(1) is bonded in a bent 120 degrees geometry to one S(1) and one S(3) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a distorted single-bond geometry to one N(1) and one S(2) atom. In the second S site, S(2) is bonded in a water-like geometry to two equivalent S(1) atoms. In the third S site, S(3) is bonded in a bent 120 degrees geometry to two equivalent N(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_S2N
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.868
_cell_length_b   11.868
_cell_length_c   4.248
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   598.371
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.154  0.349  0.312  1.0
  S  S1  1  0.849  0.346  0.812  1.0
  S  S2  1  0.151  0.654  0.812  1.0
  S  S3  1  0.846  0.651  0.312  1.0
  S  S4  1  0.654  0.151  0.812  1.0
  S  S5  1  0.346  0.849  0.812  1.0
  S  S6  1  0.651  0.846  0.312  1.0
  S  S7  1  0.349  0.154  0.312  1.0
  S  S8  1  0.681  0.681  0.174  1.0
  S  S9  1  0.181  0.819  0.674  1.0
  S  S10  1  0.819  0.181  0.674  1.0
  S  S11  1  0.319  0.319  0.174  1.0
  S  S12  1  0.882  0.882  0.111  1.0
  S  S13  1  0.382  0.618  0.611  1.0
  S  S14  1  0.618  0.382  0.611  1.0
  S  S15  1  0.118  0.118  0.111  1.0
  N  N16  1  0.244  0.079  0.161  1.0
  N  N17  1  0.756  0.921  0.161  1.0
  N  N18  1  0.421  0.744  0.661  1.0
  N  N19  1  0.579  0.256  0.661  1.0
  N  N20  1  0.921  0.756  0.161  1.0
  N  N21  1  0.256  0.579  0.661  1.0
  N  N22  1  0.744  0.421  0.661  1.0
  N  N23  1  0.079  0.244  0.161  1.0
[/CIF]
.