The compound described by MgWMnZn2O6 crystallizes in the triclinic P1 space group. Mg(1) is bonded to one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form MgO5 trigonal bipyramids that share corners with three equivalent W(1)O6 octahedra, corners with two equivalent Mn(1)O5 trigonal bipyramids, corners with two equivalent Zn(1)O5 trigonal bipyramids, corners with two equivalent Zn(2)O5 trigonal bipyramids,  an edgeedge with one W(1)O6 octahedra,  an edgeedge with one Mn(1)O5 trigonal bipyramid,  an edgeedge with one Zn(1)O5 trigonal bipyramid, and  an edgeedge with one Zn(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 15-68°. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share  a cornercorner with one Mn(1)O5 trigonal bipyramid,  a cornercorner with one Zn(1)O5 trigonal bipyramid,  a cornercorner with one Zn(2)O5 trigonal bipyramid, corners with three equivalent Mg(1)O5 trigonal bipyramids,  an edgeedge with one Mg(1)O5 trigonal bipyramid, edges with two equivalent Mn(1)O5 trigonal bipyramids, edges with two equivalent Zn(1)O5 trigonal bipyramids, and edges with two equivalent Zn(2)O5 trigonal bipyramids. Mn(1) is bonded to one O(1), one O(3), one O(4), one O(5), and one O(6) atom to form MnO5 trigonal bipyramids that share  a cornercorner with one W(1)O6 octahedra, corners with two equivalent Mg(1)O5 trigonal bipyramids, corners with two equivalent Zn(2)O5 trigonal bipyramids, corners with four equivalent Zn(1)O5 trigonal bipyramids, edges with two equivalent W(1)O6 octahedra,  an edgeedge with one Mg(1)O5 trigonal bipyramid, and  an edgeedge with one Zn(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles are 74°. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(2), one O(3), one O(4), and one O(6) atom to form ZnO5 trigonal bipyramids that share  a cornercorner with one W(1)O6 octahedra, corners with two equivalent Mg(1)O5 trigonal bipyramids, corners with two equivalent Zn(2)O5 trigonal bipyramids, corners with four equivalent Mn(1)O5 trigonal bipyramids, edges with two equivalent W(1)O6 octahedra,  an edgeedge with one Mg(1)O5 trigonal bipyramid, and  an edgeedge with one Zn(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles are 28°. In the second Zn site, Zn(2) is bonded to one O(1), one O(2), one O(4), one O(5), and one O(6) atom to form ZnO5 trigonal bipyramids that share  a cornercorner with one W(1)O6 octahedra, corners with two equivalent Mg(1)O5 trigonal bipyramids, corners with two equivalent Mn(1)O5 trigonal bipyramids, corners with two equivalent Zn(1)O5 trigonal bipyramids, edges with two equivalent W(1)O6 octahedra,  an edgeedge with one Mg(1)O5 trigonal bipyramid,  an edgeedge with one Mn(1)O5 trigonal bipyramid, and  an edgeedge with one Zn(1)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles are 65°. There are six inequivalent O sites. In the first O site, O(1) is bonded to one W(1), one Mn(1), one Zn(1), and one Zn(2) atom to form OMnZn2W trigonal pyramids that share corners with two equivalent O(4)MgMnZn2W square pyramids, corners with three equivalent O(5)MgMnZnW tetrahedra, corners with three equivalent O(2)MgZn2W tetrahedra, corners with two equivalent O(6)MgMnZn2W trigonal bipyramids,  an edgeedge with one O(4)MgMnZn2W square pyramid, and  an edgeedge with one O(6)MgMnZn2W trigonal bipyramid. In the second O site, O(2) is bonded to one Mg(1), one W(1), one Zn(1), and one Zn(2) atom to form distorted OMgZn2W tetrahedra that share corners with three equivalent O(5)MgMnZnW tetrahedra, corners with two equivalent O(6)MgMnZn2W trigonal bipyramids, corners with three equivalent O(1)MnZn2W trigonal pyramids, edges with two equivalent O(4)MgMnZn2W square pyramids, and  an edgeedge with one O(6)MgMnZn2W trigonal bipyramid. In the third O site, O(3) is bonded in a distorted see-saw-like geometry to one Mg(1), one W(1), one Mn(1), and one Zn(1) atom. In the fourth O site, O(4) is bonded to one Mg(1), one W(1), one Mn(1), one Zn(1), and one Zn(2) atom to form OMgMnZn2W square pyramids that share corners with two equivalent O(5)MgMnZnW tetrahedra,  a cornercorner with one O(6)MgMnZn2W trigonal bipyramid, corners with two equivalent O(1)MnZn2W trigonal pyramids,  an edgeedge with one O(5)MgMnZnW tetrahedra, edges with two equivalent O(2)MgZn2W tetrahedra, edges with two equivalent O(6)MgMnZn2W trigonal bipyramids, and  an edgeedge with one O(1)MnZn2W trigonal pyramid. In the fifth O site, O(5) is bonded to one Mg(1), one W(1), one Mn(1), and one Zn(2) atom to form OMgMnZnW tetrahedra that share corners with two equivalent O(4)MgMnZn2W square pyramids, corners with three equivalent O(2)MgZn2W tetrahedra, corners with two equivalent O(6)MgMnZn2W trigonal bipyramids, corners with three equivalent O(1)MnZn2W trigonal pyramids,  an edgeedge with one O(4)MgMnZn2W square pyramid, and  an edgeedge with one O(6)MgMnZn2W trigonal bipyramid. In the sixth O site, O(6) is bonded to one Mg(1), one W(1), one Mn(1), one Zn(1), and one Zn(2) atom to form OMgMnZn2W trigonal bipyramids that share  a cornercorner with one O(4)MgMnZn2W square pyramid, corners with two equivalent O(5)MgMnZnW tetrahedra, corners with two equivalent O(2)MgZn2W tetrahedra, corners with two equivalent O(1)MnZn2W trigonal pyramids, edges with two equivalent O(4)MgMnZn2W square pyramids,  an edgeedge with one O(5)MgMnZnW tetrahedra,  an edgeedge with one O(2)MgZn2W tetrahedra, and  an edgeedge with one O(1)MnZn2W trigonal pyramid. is represented by the CIF card [CIF]
data_MgMnZn2WO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.427
_cell_length_b   5.296
_cell_length_c   9.053
_cell_angle_alpha   107.769
_cell_angle_beta   133.590
_cell_angle_gamma   103.889
_symmetry_Int_Tables_number   1
_cell_volume   135.905
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.620  0.946  0.587  1.0
  Mn  Mn1  1  0.096  0.251  0.436  1.0
  Zn  Zn2  1  0.651  0.300  0.960  1.0
  Zn  Zn3  1  0.138  0.618  0.773  1.0
  W  W4  1  0.070  0.967  0.064  1.0
  O  O5  1  0.759  0.752  0.101  1.0
  O  O6  1  0.208  0.048  0.911  1.0
  O  O7  1  0.238  0.422  0.291  1.0
  O  O8  1  0.439  0.814  0.711  1.0
  O  O9  1  0.691  0.123  0.432  1.0
  O  O10  1  0.756  0.428  0.793  1.0
[/CIF]
.
The compound described by MgWMnZn2O6 crystallizes in the triclinic P1 space group. Mg(1) is bonded to one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form MgO5 trigonal bipyramids that share corners with three equivalent W(1)O6 octahedra, corners with two equivalent Mn(1)O5 trigonal bipyramids, corners with two equivalent Zn(1)O5 trigonal bipyramids, corners with two equivalent Zn(2)O5 trigonal bipyramids,  an edgeedge with one W(1)O6 octahedra,  an edgeedge with one Mn(1)O5 trigonal bipyramid,  an edgeedge with one Zn(1)O5 trigonal bipyramid, and  an edgeedge with one Zn(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 15-68°. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share  a cornercorner with one Mn(1)O5 trigonal bipyramid,  a cornercorner with one Zn(1)O5 trigonal bipyramid,  a cornercorner with one Zn(2)O5 trigonal bipyramid, corners with three equivalent Mg(1)O5 trigonal bipyramids,  an edgeedge with one Mg(1)O5 trigonal bipyramid, edges with two equivalent Mn(1)O5 trigonal bipyramids, edges with two equivalent Zn(1)O5 trigonal bipyramids, and edges with two equivalent Zn(2)O5 trigonal bipyramids. Mn(1) is bonded to one O(1), one O(3), one O(4), one O(5), and one O(6) atom to form MnO5 trigonal bipyramids that share  a cornercorner with one W(1)O6 octahedra, corners with two equivalent Mg(1)O5 trigonal bipyramids, corners with two equivalent Zn(2)O5 trigonal bipyramids, corners with four equivalent Zn(1)O5 trigonal bipyramids, edges with two equivalent W(1)O6 octahedra,  an edgeedge with one Mg(1)O5 trigonal bipyramid, and  an edgeedge with one Zn(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles are 74°. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(2), one O(3), one O(4), and one O(6) atom to form ZnO5 trigonal bipyramids that share  a cornercorner with one W(1)O6 octahedra, corners with two equivalent Mg(1)O5 trigonal bipyramids, corners with two equivalent Zn(2)O5 trigonal bipyramids, corners with four equivalent Mn(1)O5 trigonal bipyramids, edges with two equivalent W(1)O6 octahedra,  an edgeedge with one Mg(1)O5 trigonal bipyramid, and  an edgeedge with one Zn(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles are 28°. In the second Zn site, Zn(2) is bonded to one O(1), one O(2), one O(4), one O(5), and one O(6) atom to form ZnO5 trigonal bipyramids that share  a cornercorner with one W(1)O6 octahedra, corners with two equivalent Mg(1)O5 trigonal bipyramids, corners with two equivalent Mn(1)O5 trigonal bipyramids, corners with two equivalent Zn(1)O5 trigonal bipyramids, edges with two equivalent W(1)O6 octahedra,  an edgeedge with one Mg(1)O5 trigonal bipyramid,  an edgeedge with one Mn(1)O5 trigonal bipyramid, and  an edgeedge with one Zn(1)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles are 65°. There are six inequivalent O sites. In the first O site, O(1) is bonded to one W(1), one Mn(1), one Zn(1), and one Zn(2) atom to form OMnZn2W trigonal pyramids that share corners with two equivalent O(4)MgMnZn2W square pyramids, corners with three equivalent O(5)MgMnZnW tetrahedra, corners with three equivalent O(2)MgZn2W tetrahedra, corners with two equivalent O(6)MgMnZn2W trigonal bipyramids,  an edgeedge with one O(4)MgMnZn2W square pyramid, and  an edgeedge with one O(6)MgMnZn2W trigonal bipyramid. In the second O site, O(2) is bonded to one Mg(1), one W(1), one Zn(1), and one Zn(2) atom to form distorted OMgZn2W tetrahedra that share corners with three equivalent O(5)MgMnZnW tetrahedra, corners with two equivalent O(6)MgMnZn2W trigonal bipyramids, corners with three equivalent O(1)MnZn2W trigonal pyramids, edges with two equivalent O(4)MgMnZn2W square pyramids, and  an edgeedge with one O(6)MgMnZn2W trigonal bipyramid. In the third O site, O(3) is bonded in a distorted see-saw-like geometry to one Mg(1), one W(1), one Mn(1), and one Zn(1) atom. In the fourth O site, O(4) is bonded to one Mg(1), one W(1), one Mn(1), one Zn(1), and one Zn(2) atom to form OMgMnZn2W square pyramids that share corners with two equivalent O(5)MgMnZnW tetrahedra,  a cornercorner with one O(6)MgMnZn2W trigonal bipyramid, corners with two equivalent O(1)MnZn2W trigonal pyramids,  an edgeedge with one O(5)MgMnZnW tetrahedra, edges with two equivalent O(2)MgZn2W tetrahedra, edges with two equivalent O(6)MgMnZn2W trigonal bipyramids, and  an edgeedge with one O(1)MnZn2W trigonal pyramid. In the fifth O site, O(5) is bonded to one Mg(1), one W(1), one Mn(1), and one Zn(2) atom to form OMgMnZnW tetrahedra that share corners with two equivalent O(4)MgMnZn2W square pyramids, corners with three equivalent O(2)MgZn2W tetrahedra, corners with two equivalent O(6)MgMnZn2W trigonal bipyramids, corners with three equivalent O(1)MnZn2W trigonal pyramids,  an edgeedge with one O(4)MgMnZn2W square pyramid, and  an edgeedge with one O(6)MgMnZn2W trigonal bipyramid. In the sixth O site, O(6) is bonded to one Mg(1), one W(1), one Mn(1), one Zn(1), and one Zn(2) atom to form OMgMnZn2W trigonal bipyramids that share  a cornercorner with one O(4)MgMnZn2W square pyramid, corners with two equivalent O(5)MgMnZnW tetrahedra, corners with two equivalent O(2)MgZn2W tetrahedra, corners with two equivalent O(1)MnZn2W trigonal pyramids, edges with two equivalent O(4)MgMnZn2W square pyramids,  an edgeedge with one O(5)MgMnZnW tetrahedra,  an edgeedge with one O(2)MgZn2W tetrahedra, and  an edgeedge with one O(1)MnZn2W trigonal pyramid. is represented by the CIF card [CIF]
data_MgMnZn2WO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.427
_cell_length_b   5.296
_cell_length_c   9.053
_cell_angle_alpha   107.769
_cell_angle_beta   133.590
_cell_angle_gamma   103.889
_symmetry_Int_Tables_number   1
_cell_volume   135.905
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.620  0.946  0.587  1.0
  Mn  Mn1  1  0.096  0.251  0.436  1.0
  Zn  Zn2  1  0.651  0.300  0.960  1.0
  Zn  Zn3  1  0.138  0.618  0.773  1.0
  W  W4  1  0.070  0.967  0.064  1.0
  O  O5  1  0.759  0.752  0.101  1.0
  O  O6  1  0.208  0.048  0.911  1.0
  O  O7  1  0.238  0.422  0.291  1.0
  O  O8  1  0.439  0.814  0.711  1.0
  O  O9  1  0.691  0.123  0.432  1.0
  O  O10  1  0.756  0.428  0.793  1.0
[/CIF]
.