The structure described by N2S2Cl is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four N2S2Cl clusters. There are four inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(2) and one S(4) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one S(3) and one S(4) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to one S(1) and one S(3) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to one N(3), one N(4), and one Cl(1) atom. In the second S site, S(2) is bonded in a water-like geometry to one N(1) and one N(3) atom. In the third S site, S(3) is bonded in a water-like geometry to one N(2) and one N(4) atom. In the fourth S site, S(4) is bonded in a trigonal non-coplanar geometry to one N(1), one N(2), and one Cl(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one S(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one S(4) atom. is represented by the CIF file [CIF]
data_S2N2Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.060
_cell_length_b   9.956
_cell_length_c   14.070
_cell_angle_alpha   69.263
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   924.826
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.365  0.946  0.710  1.0
  S  S1  1  0.257  0.654  0.772  1.0
  S  S2  1  0.537  0.734  0.649  1.0
  S  S3  1  0.963  0.734  0.149  1.0
  S  S4  1  0.463  0.266  0.351  1.0
  S  S5  1  0.865  0.054  0.790  1.0
  S  S6  1  0.243  0.654  0.272  1.0
  S  S7  1  0.635  0.054  0.290  1.0
  S  S8  1  0.697  0.333  0.930  1.0
  S  S9  1  0.037  0.266  0.851  1.0
  S  S10  1  0.303  0.667  0.070  1.0
  S  S11  1  0.757  0.346  0.728  1.0
  S  S12  1  0.135  0.946  0.210  1.0
  S  S13  1  0.803  0.333  0.430  1.0
  S  S14  1  0.743  0.346  0.228  1.0
  S  S15  1  0.197  0.667  0.570  1.0
  N  N16  1  0.618  0.345  0.820  1.0
  N  N17  1  0.098  0.737  0.055  1.0
  N  N18  1  0.758  0.193  0.713  1.0
  N  N19  1  0.541  0.887  0.664  1.0
  N  N20  1  0.959  0.887  0.164  1.0
  N  N21  1  0.902  0.263  0.945  1.0
  N  N22  1  0.459  0.113  0.336  1.0
  N  N23  1  0.882  0.345  0.320  1.0
  N  N24  1  0.041  0.113  0.836  1.0
  N  N25  1  0.258  0.807  0.787  1.0
  N  N26  1  0.742  0.193  0.213  1.0
  N  N27  1  0.242  0.807  0.287  1.0
  N  N28  1  0.118  0.655  0.680  1.0
  N  N29  1  0.382  0.655  0.180  1.0
  N  N30  1  0.402  0.737  0.555  1.0
  N  N31  1  0.598  0.263  0.445  1.0
  Cl  Cl32  1  0.333  0.043  0.085  1.0
  Cl  Cl33  1  0.249  0.435  0.588  1.0
  Cl  Cl34  1  0.251  0.435  0.088  1.0
  Cl  Cl35  1  0.167  0.043  0.585  1.0
  Cl  Cl36  1  0.667  0.957  0.915  1.0
  Cl  Cl37  1  0.751  0.565  0.412  1.0
  Cl  Cl38  1  0.833  0.957  0.415  1.0
  Cl  Cl39  1  0.749  0.565  0.912  1.0
[/CIF]
.
The structure described by N2S2Cl is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four N2S2Cl clusters. There are four inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(2) and one S(4) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one S(3) and one S(4) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to one S(1) and one S(3) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to one N(3), one N(4), and one Cl(1) atom. In the second S site, S(2) is bonded in a water-like geometry to one N(1) and one N(3) atom. In the third S site, S(3) is bonded in a water-like geometry to one N(2) and one N(4) atom. In the fourth S site, S(4) is bonded in a trigonal non-coplanar geometry to one N(1), one N(2), and one Cl(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one S(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one S(4) atom. is represented by the CIF file [CIF]
data_S2N2Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.060
_cell_length_b   9.956
_cell_length_c   14.070
_cell_angle_alpha   69.263
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   924.826
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.365  0.946  0.710  1.0
  S  S1  1  0.257  0.654  0.772  1.0
  S  S2  1  0.537  0.734  0.649  1.0
  S  S3  1  0.963  0.734  0.149  1.0
  S  S4  1  0.463  0.266  0.351  1.0
  S  S5  1  0.865  0.054  0.790  1.0
  S  S6  1  0.243  0.654  0.272  1.0
  S  S7  1  0.635  0.054  0.290  1.0
  S  S8  1  0.697  0.333  0.930  1.0
  S  S9  1  0.037  0.266  0.851  1.0
  S  S10  1  0.303  0.667  0.070  1.0
  S  S11  1  0.757  0.346  0.728  1.0
  S  S12  1  0.135  0.946  0.210  1.0
  S  S13  1  0.803  0.333  0.430  1.0
  S  S14  1  0.743  0.346  0.228  1.0
  S  S15  1  0.197  0.667  0.570  1.0
  N  N16  1  0.618  0.345  0.820  1.0
  N  N17  1  0.098  0.737  0.055  1.0
  N  N18  1  0.758  0.193  0.713  1.0
  N  N19  1  0.541  0.887  0.664  1.0
  N  N20  1  0.959  0.887  0.164  1.0
  N  N21  1  0.902  0.263  0.945  1.0
  N  N22  1  0.459  0.113  0.336  1.0
  N  N23  1  0.882  0.345  0.320  1.0
  N  N24  1  0.041  0.113  0.836  1.0
  N  N25  1  0.258  0.807  0.787  1.0
  N  N26  1  0.742  0.193  0.213  1.0
  N  N27  1  0.242  0.807  0.287  1.0
  N  N28  1  0.118  0.655  0.680  1.0
  N  N29  1  0.382  0.655  0.180  1.0
  N  N30  1  0.402  0.737  0.555  1.0
  N  N31  1  0.598  0.263  0.445  1.0
  Cl  Cl32  1  0.333  0.043  0.085  1.0
  Cl  Cl33  1  0.249  0.435  0.588  1.0
  Cl  Cl34  1  0.251  0.435  0.088  1.0
  Cl  Cl35  1  0.167  0.043  0.585  1.0
  Cl  Cl36  1  0.667  0.957  0.915  1.0
  Cl  Cl37  1  0.751  0.565  0.412  1.0
  Cl  Cl38  1  0.833  0.957  0.415  1.0
  Cl  Cl39  1  0.749  0.565  0.912  1.0
[/CIF]
.