The structure described by Rb2LiPu(OCl2)2 crystallizes in the monoclinic Cm space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 9-coordinate geometry to one O(2), four equivalent Cl(1), and four equivalent Cl(2) atoms. In the second Rb site, Rb(2) is bonded in a 9-coordinate geometry to one O(1), four equivalent Cl(1), and four equivalent Cl(2) atoms. Li(1) is bonded in a distorted trigonal planar geometry to one O(2) and two equivalent Cl(1) atoms. Pu(1) is bonded in a distorted linear geometry to one O(1), one O(2), two equivalent Cl(1), and two equivalent Cl(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Rb(2) and one Pu(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Rb(1), one Li(1), and one Pu(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 6-coordinate geometry to two equivalent Rb(1), two equivalent Rb(2), one Li(1), and one Pu(1) atom. In the second Cl site, Cl(2) is bonded in a 5-coordinate geometry to two equivalent Rb(1), two equivalent Rb(2), and one Pu(1) atom. is represented by the CIF file [CIF]
data_Rb2LiPu(Cl2O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.132
_cell_length_b   7.088
_cell_length_c   7.088
_cell_angle_alpha   64.704
_cell_angle_beta   99.505
_cell_angle_gamma   99.505
_symmetry_Int_Tables_number   1
_cell_volume   273.159
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.697  0.868  0.868  1.0
  Rb  Rb1  1  0.297  0.158  0.158  1.0
  Li  Li2  1  0.036  0.645  0.645  1.0
  Pu  Pu3  1  0.479  0.498  0.498  1.0
  Cl  Cl4  1  0.788  0.859  0.380  1.0
  Cl  Cl5  1  0.788  0.380  0.859  1.0
  Cl  Cl6  1  0.224  0.125  0.662  1.0
  Cl  Cl7  1  0.224  0.662  0.125  1.0
  O  O8  1  0.625  0.380  0.380  1.0
  O  O9  1  0.331  0.619  0.619  1.0
[/CIF]
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The structure described by Rb2LiPu(OCl2)2 crystallizes in the monoclinic Cm space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 9-coordinate geometry to one O(2), four equivalent Cl(1), and four equivalent Cl(2) atoms. In the second Rb site, Rb(2) is bonded in a 9-coordinate geometry to one O(1), four equivalent Cl(1), and four equivalent Cl(2) atoms. Li(1) is bonded in a distorted trigonal planar geometry to one O(2) and two equivalent Cl(1) atoms. Pu(1) is bonded in a distorted linear geometry to one O(1), one O(2), two equivalent Cl(1), and two equivalent Cl(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Rb(2) and one Pu(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Rb(1), one Li(1), and one Pu(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 6-coordinate geometry to two equivalent Rb(1), two equivalent Rb(2), one Li(1), and one Pu(1) atom. In the second Cl site, Cl(2) is bonded in a 5-coordinate geometry to two equivalent Rb(1), two equivalent Rb(2), and one Pu(1) atom. is represented by the CIF file [CIF]
data_Rb2LiPu(Cl2O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.132
_cell_length_b   7.088
_cell_length_c   7.088
_cell_angle_alpha   64.704
_cell_angle_beta   99.505
_cell_angle_gamma   99.505
_symmetry_Int_Tables_number   1
_cell_volume   273.159
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.697  0.868  0.868  1.0
  Rb  Rb1  1  0.297  0.158  0.158  1.0
  Li  Li2  1  0.036  0.645  0.645  1.0
  Pu  Pu3  1  0.479  0.498  0.498  1.0
  Cl  Cl4  1  0.788  0.859  0.380  1.0
  Cl  Cl5  1  0.788  0.380  0.859  1.0
  Cl  Cl6  1  0.224  0.125  0.662  1.0
  Cl  Cl7  1  0.224  0.662  0.125  1.0
  O  O8  1  0.625  0.380  0.380  1.0
  O  O9  1  0.331  0.619  0.619  1.0
[/CIF]
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