The compound described by C3SbPOCl5 is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of four C3SbPOCl5 clusters. There are three inequivalent C sites. In the first C site, C(2) is bonded in a 2-coordinate geometry to one C(5) and one P(1) atom. In the second C site, C(5) is bonded in a 3-coordinate geometry to one C(11), one C(2), and one P(1) atom. In the third C site, C(11) is bonded in a 3-coordinate geometry to one C(5), one P(1), and one Cl(1) atom. Sb(1) is bonded in a distorted square pyramidal geometry to one O(1), one Cl(13), one Cl(19), one Cl(5), and one Cl(9) atom. P(1) is bonded in a distorted single-bond geometry to one C(11), one C(2), one C(5), and one O(1) atom. O(1) is bonded in a bent 120 degrees geometry to one Sb(1) and one P(1) atom. There are five inequivalent Cl sites. In the first Cl site, Cl(13) is bonded in a single-bond geometry to one Sb(1) atom. In the second Cl site, Cl(19) is bonded in a single-bond geometry to one Sb(1) atom. In the third Cl site, Cl(1) is bonded in a single-bond geometry to one C(11) atom. In the fourth Cl site, Cl(5) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth Cl site, Cl(9) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the CIF file [CIF]
data_SbPC3Cl5O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.063
_cell_length_b   9.333
_cell_length_c   16.544
_cell_angle_alpha   89.801
_cell_angle_beta   89.761
_cell_angle_gamma   89.987
_symmetry_Int_Tables_number   1
_cell_volume   1399.428
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.751  0.404  0.625  1.0
  Sb  Sb1  1  0.745  0.096  0.125  1.0
  Sb  Sb2  1  0.251  0.596  0.375  1.0
  Sb  Sb3  1  0.254  0.905  0.875  1.0
  P  P4  1  0.666  0.733  0.559  1.0
  P  P5  1  0.834  0.768  0.059  1.0
  P  P6  1  0.166  0.268  0.441  1.0
  P  P7  1  0.166  0.232  0.941  1.0
  C  C8  1  0.681  0.619  0.040  1.0
  C  C9  1  0.820  0.882  0.540  1.0
  C  C10  1  0.319  0.381  0.960  1.0
  C  C11  1  0.319  0.118  0.461  1.0
  C  C12  1  0.807  0.862  0.619  1.0
  C  C13  1  0.693  0.638  0.119  1.0
  C  C14  1  0.308  0.138  0.382  1.0
  C  C15  1  0.216  0.283  0.833  1.0
  C  C16  1  0.217  0.217  0.333  1.0
  C  C17  1  0.307  0.362  0.881  1.0
  C  C18  1  0.715  0.783  0.667  1.0
  C  C19  1  0.784  0.717  0.167  1.0
  Cl  Cl20  1  0.736  0.682  0.749  1.0
  Cl  Cl21  1  0.764  0.817  0.249  1.0
  Cl  Cl22  1  0.240  0.317  0.250  1.0
  Cl  Cl23  1  0.238  0.182  0.751  1.0
  Cl  Cl24  1  0.750  0.239  0.521  1.0
  Cl  Cl25  1  0.742  0.262  0.020  1.0
  Cl  Cl26  1  0.248  0.761  0.479  1.0
  Cl  Cl27  1  0.257  0.738  0.979  1.0
  Cl  Cl28  1  0.750  0.248  0.740  1.0
  Cl  Cl29  1  0.749  0.252  0.240  1.0
  Cl  Cl30  1  0.250  0.753  0.260  1.0
  Cl  Cl31  1  0.250  0.749  0.760  1.0
  Cl  Cl32  1  0.011  0.442  0.638  1.0
  Cl  Cl33  1  0.486  0.055  0.141  1.0
  Cl  Cl34  1  0.512  0.560  0.361  1.0
  Cl  Cl35  1  0.990  0.941  0.863  1.0
  Cl  Cl36  1  0.990  0.555  0.361  1.0
  Cl  Cl37  1  0.512  0.945  0.859  1.0
  Cl  Cl38  1  0.489  0.443  0.639  1.0
  Cl  Cl39  1  0.009  0.059  0.137  1.0
  O  O40  1  0.754  0.585  0.550  1.0
  O  O41  1  0.746  0.916  0.050  1.0
  O  O42  1  0.255  0.415  0.449  1.0
  O  O43  1  0.253  0.084  0.950  1.0
[/CIF]
.
The compound described by C3SbPOCl5 is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of four C3SbPOCl5 clusters. There are three inequivalent C sites. In the first C site, C(2) is bonded in a 2-coordinate geometry to one C(5) and one P(1) atom. In the second C site, C(5) is bonded in a 3-coordinate geometry to one C(11), one C(2), and one P(1) atom. In the third C site, C(11) is bonded in a 3-coordinate geometry to one C(5), one P(1), and one Cl(1) atom. Sb(1) is bonded in a distorted square pyramidal geometry to one O(1), one Cl(13), one Cl(19), one Cl(5), and one Cl(9) atom. P(1) is bonded in a distorted single-bond geometry to one C(11), one C(2), one C(5), and one O(1) atom. O(1) is bonded in a bent 120 degrees geometry to one Sb(1) and one P(1) atom. There are five inequivalent Cl sites. In the first Cl site, Cl(13) is bonded in a single-bond geometry to one Sb(1) atom. In the second Cl site, Cl(19) is bonded in a single-bond geometry to one Sb(1) atom. In the third Cl site, Cl(1) is bonded in a single-bond geometry to one C(11) atom. In the fourth Cl site, Cl(5) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth Cl site, Cl(9) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the CIF file [CIF]
data_SbPC3Cl5O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.063
_cell_length_b   9.333
_cell_length_c   16.544
_cell_angle_alpha   89.801
_cell_angle_beta   89.761
_cell_angle_gamma   89.987
_symmetry_Int_Tables_number   1
_cell_volume   1399.428
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.751  0.404  0.625  1.0
  Sb  Sb1  1  0.745  0.096  0.125  1.0
  Sb  Sb2  1  0.251  0.596  0.375  1.0
  Sb  Sb3  1  0.254  0.905  0.875  1.0
  P  P4  1  0.666  0.733  0.559  1.0
  P  P5  1  0.834  0.768  0.059  1.0
  P  P6  1  0.166  0.268  0.441  1.0
  P  P7  1  0.166  0.232  0.941  1.0
  C  C8  1  0.681  0.619  0.040  1.0
  C  C9  1  0.820  0.882  0.540  1.0
  C  C10  1  0.319  0.381  0.960  1.0
  C  C11  1  0.319  0.118  0.461  1.0
  C  C12  1  0.807  0.862  0.619  1.0
  C  C13  1  0.693  0.638  0.119  1.0
  C  C14  1  0.308  0.138  0.382  1.0
  C  C15  1  0.216  0.283  0.833  1.0
  C  C16  1  0.217  0.217  0.333  1.0
  C  C17  1  0.307  0.362  0.881  1.0
  C  C18  1  0.715  0.783  0.667  1.0
  C  C19  1  0.784  0.717  0.167  1.0
  Cl  Cl20  1  0.736  0.682  0.749  1.0
  Cl  Cl21  1  0.764  0.817  0.249  1.0
  Cl  Cl22  1  0.240  0.317  0.250  1.0
  Cl  Cl23  1  0.238  0.182  0.751  1.0
  Cl  Cl24  1  0.750  0.239  0.521  1.0
  Cl  Cl25  1  0.742  0.262  0.020  1.0
  Cl  Cl26  1  0.248  0.761  0.479  1.0
  Cl  Cl27  1  0.257  0.738  0.979  1.0
  Cl  Cl28  1  0.750  0.248  0.740  1.0
  Cl  Cl29  1  0.749  0.252  0.240  1.0
  Cl  Cl30  1  0.250  0.753  0.260  1.0
  Cl  Cl31  1  0.250  0.749  0.760  1.0
  Cl  Cl32  1  0.011  0.442  0.638  1.0
  Cl  Cl33  1  0.486  0.055  0.141  1.0
  Cl  Cl34  1  0.512  0.560  0.361  1.0
  Cl  Cl35  1  0.990  0.941  0.863  1.0
  Cl  Cl36  1  0.990  0.555  0.361  1.0
  Cl  Cl37  1  0.512  0.945  0.859  1.0
  Cl  Cl38  1  0.489  0.443  0.639  1.0
  Cl  Cl39  1  0.009  0.059  0.137  1.0
  O  O40  1  0.754  0.585  0.550  1.0
  O  O41  1  0.746  0.916  0.050  1.0
  O  O42  1  0.255  0.415  0.449  1.0
  O  O43  1  0.253  0.084  0.950  1.0
[/CIF]
.