The crystal structure described by Fe10HoV2 crystallizes in the orthorhombic Immm space group. Ho(1) is bonded in a 20-coordinate geometry to two equivalent V(1), two equivalent Fe(4), four equivalent Fe(2), four equivalent Fe(3), and eight equivalent Fe(1) atoms. V(1) is bonded in a 14-coordinate geometry to one Ho(1), one V(1), two equivalent Fe(2), two equivalent Fe(3), four equivalent Fe(1), and four equivalent Fe(4) atoms. There are four inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to two equivalent Ho(1), two equivalent V(1), two equivalent Fe(1), two equivalent Fe(2), two equivalent Fe(3), and two equivalent Fe(4) atoms to form a mixture of distorted edge, corner, and face-sharing FeHo2V2Fe8 cuboctahedra. In the second Fe site, Fe(2) is bonded to two equivalent Ho(1), two equivalent V(1), two equivalent Fe(3), two equivalent Fe(4), and four equivalent Fe(1) atoms to form a mixture of distorted edge, corner, and face-sharing FeHo2V2Fe8 cuboctahedra. In the third Fe site, Fe(3) is bonded in a 12-coordinate geometry to two equivalent Ho(1), two equivalent V(1), two equivalent Fe(2), two equivalent Fe(4), and four equivalent Fe(1) atoms. In the fourth Fe site, Fe(4) is bonded in a 14-coordinate geometry to one Ho(1), four equivalent V(1), one Fe(4), two equivalent Fe(2), two equivalent Fe(3), and four equivalent Fe(1) atoms. is represented by the CIF card [CIF]
data_Ho(VFe5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.693
_cell_length_b   6.433
_cell_length_c   6.433
_cell_angle_alpha   97.305
_cell_angle_beta   111.391
_cell_angle_gamma   68.609
_symmetry_Int_Tables_number   1
_cell_volume   168.392
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ho  Ho0  1  0.000  0.000  0.000  1.0
  V  V1  1  0.000  0.359  0.359  1.0
  V  V2  1  0.000  0.641  0.641  1.0
  Fe  Fe3  1  0.500  0.000  0.500  1.0
  Fe  Fe4  1  0.000  0.000  0.500  1.0
  Fe  Fe5  1  0.500  0.500  0.000  1.0
  Fe  Fe6  1  0.000  0.500  0.000  1.0
  Fe  Fe7  1  0.725  0.775  0.225  1.0
  Fe  Fe8  1  0.275  0.225  0.775  1.0
  Fe  Fe9  1  0.500  0.773  0.773  1.0
  Fe  Fe10  1  0.500  0.227  0.227  1.0
  Fe  Fe11  1  0.641  0.359  0.641  1.0
  Fe  Fe12  1  0.359  0.641  0.359  1.0
[/CIF]
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The crystal structure described by Fe10HoV2 crystallizes in the orthorhombic Immm space group. Ho(1) is bonded in a 20-coordinate geometry to two equivalent V(1), two equivalent Fe(4), four equivalent Fe(2), four equivalent Fe(3), and eight equivalent Fe(1) atoms. V(1) is bonded in a 14-coordinate geometry to one Ho(1), one V(1), two equivalent Fe(2), two equivalent Fe(3), four equivalent Fe(1), and four equivalent Fe(4) atoms. There are four inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to two equivalent Ho(1), two equivalent V(1), two equivalent Fe(1), two equivalent Fe(2), two equivalent Fe(3), and two equivalent Fe(4) atoms to form a mixture of distorted edge, corner, and face-sharing FeHo2V2Fe8 cuboctahedra. In the second Fe site, Fe(2) is bonded to two equivalent Ho(1), two equivalent V(1), two equivalent Fe(3), two equivalent Fe(4), and four equivalent Fe(1) atoms to form a mixture of distorted edge, corner, and face-sharing FeHo2V2Fe8 cuboctahedra. In the third Fe site, Fe(3) is bonded in a 12-coordinate geometry to two equivalent Ho(1), two equivalent V(1), two equivalent Fe(2), two equivalent Fe(4), and four equivalent Fe(1) atoms. In the fourth Fe site, Fe(4) is bonded in a 14-coordinate geometry to one Ho(1), four equivalent V(1), one Fe(4), two equivalent Fe(2), two equivalent Fe(3), and four equivalent Fe(1) atoms. is represented by the CIF card [CIF]
data_Ho(VFe5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.693
_cell_length_b   6.433
_cell_length_c   6.433
_cell_angle_alpha   97.305
_cell_angle_beta   111.391
_cell_angle_gamma   68.609
_symmetry_Int_Tables_number   1
_cell_volume   168.392
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ho  Ho0  1  0.000  0.000  0.000  1.0
  V  V1  1  0.000  0.359  0.359  1.0
  V  V2  1  0.000  0.641  0.641  1.0
  Fe  Fe3  1  0.500  0.000  0.500  1.0
  Fe  Fe4  1  0.000  0.000  0.500  1.0
  Fe  Fe5  1  0.500  0.500  0.000  1.0
  Fe  Fe6  1  0.000  0.500  0.000  1.0
  Fe  Fe7  1  0.725  0.775  0.225  1.0
  Fe  Fe8  1  0.275  0.225  0.775  1.0
  Fe  Fe9  1  0.500  0.773  0.773  1.0
  Fe  Fe10  1  0.500  0.227  0.227  1.0
  Fe  Fe11  1  0.641  0.359  0.641  1.0
  Fe  Fe12  1  0.359  0.641  0.359  1.0
[/CIF]
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