The material structure described by Mn2Hg(CO)10 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one Mn2Hg(CO)10 cluster. Mn(1) is bonded to one Hg(1), one C(1), one C(2), one C(3), one C(4), and one C(5) atom to form distorted corner-sharing MnHgC5 square pyramids. Hg(1) is bonded in a linear geometry to two equivalent Mn(1) atoms. There are five inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Mn(1) and one O(2) atom. In the second C site, C(2) is bonded in a linear geometry to one Mn(1) and one O(1,4) atom. In the third C site, C(3) is bonded in a linear geometry to one Mn(1) and one O(5) atom. In the fourth C site, C(4) is bonded in a linear geometry to one Mn(1) and one O(3) atom. In the fifth C site, C(5) is bonded in a linear geometry to one Mn(1) and one O(1,4) atom. There are four inequivalent O sites. In the first O site, O(1,4) is bonded in a single-bond geometry to one C(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth O site, O(5) is bonded in a single-bond geometry to one C(3) atom. is represented by the CIF file [CIF]
data_Mn2Hg(CO)10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.382
_cell_length_b   6.383
_cell_length_c   9.588
_cell_angle_alpha   97.250
_cell_angle_beta   89.305
_cell_angle_gamma   98.414
_symmetry_Int_Tables_number   1
_cell_volume   383.237
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.867  0.185  0.242  1.0
  Mn  Mn1  1  0.133  0.815  0.758  1.0
  Hg  Hg2  1  0.000  0.000  0.000  1.0
  C  C3  1  0.027  0.429  0.189  1.0
  C  C4  1  0.642  0.232  0.134  1.0
  C  C5  1  0.226  0.686  0.593  1.0
  C  C6  1  0.973  0.571  0.811  1.0
  C  C7  1  0.358  0.768  0.866  1.0
  C  C8  1  0.727  0.912  0.259  1.0
  C  C9  1  0.109  0.112  0.318  1.0
  C  C10  1  0.774  0.314  0.407  1.0
  C  C11  1  0.273  0.088  0.741  1.0
  C  C12  1  0.891  0.888  0.682  1.0
  O  O13  1  0.499  0.262  0.070  1.0
  O  O14  1  0.123  0.585  0.157  1.0
  O  O15  1  0.359  0.258  0.729  1.0
  O  O16  1  0.877  0.415  0.843  1.0
  O  O17  1  0.259  0.069  0.369  1.0
  O  O18  1  0.741  0.931  0.631  1.0
  O  O19  1  0.501  0.738  0.930  1.0
  O  O20  1  0.719  0.399  0.512  1.0
  O  O21  1  0.281  0.601  0.488  1.0
  O  O22  1  0.641  0.742  0.271  1.0
[/CIF]
.
The material structure described by Mn2Hg(CO)10 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one Mn2Hg(CO)10 cluster. Mn(1) is bonded to one Hg(1), one C(1), one C(2), one C(3), one C(4), and one C(5) atom to form distorted corner-sharing MnHgC5 square pyramids. Hg(1) is bonded in a linear geometry to two equivalent Mn(1) atoms. There are five inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Mn(1) and one O(2) atom. In the second C site, C(2) is bonded in a linear geometry to one Mn(1) and one O(1,4) atom. In the third C site, C(3) is bonded in a linear geometry to one Mn(1) and one O(5) atom. In the fourth C site, C(4) is bonded in a linear geometry to one Mn(1) and one O(3) atom. In the fifth C site, C(5) is bonded in a linear geometry to one Mn(1) and one O(1,4) atom. There are four inequivalent O sites. In the first O site, O(1,4) is bonded in a single-bond geometry to one C(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth O site, O(5) is bonded in a single-bond geometry to one C(3) atom. is represented by the CIF file [CIF]
data_Mn2Hg(CO)10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.382
_cell_length_b   6.383
_cell_length_c   9.588
_cell_angle_alpha   97.250
_cell_angle_beta   89.305
_cell_angle_gamma   98.414
_symmetry_Int_Tables_number   1
_cell_volume   383.237
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.867  0.185  0.242  1.0
  Mn  Mn1  1  0.133  0.815  0.758  1.0
  Hg  Hg2  1  0.000  0.000  0.000  1.0
  C  C3  1  0.027  0.429  0.189  1.0
  C  C4  1  0.642  0.232  0.134  1.0
  C  C5  1  0.226  0.686  0.593  1.0
  C  C6  1  0.973  0.571  0.811  1.0
  C  C7  1  0.358  0.768  0.866  1.0
  C  C8  1  0.727  0.912  0.259  1.0
  C  C9  1  0.109  0.112  0.318  1.0
  C  C10  1  0.774  0.314  0.407  1.0
  C  C11  1  0.273  0.088  0.741  1.0
  C  C12  1  0.891  0.888  0.682  1.0
  O  O13  1  0.499  0.262  0.070  1.0
  O  O14  1  0.123  0.585  0.157  1.0
  O  O15  1  0.359  0.258  0.729  1.0
  O  O16  1  0.877  0.415  0.843  1.0
  O  O17  1  0.259  0.069  0.369  1.0
  O  O18  1  0.741  0.931  0.631  1.0
  O  O19  1  0.501  0.738  0.930  1.0
  O  O20  1  0.719  0.399  0.512  1.0
  O  O21  1  0.281  0.601  0.488  1.0
  O  O22  1  0.641  0.742  0.271  1.0
[/CIF]
.