The crystal structure described by VCrP2(HO5)2 crystallizes in the triclinic P-1 space group. V(1) is bonded in a distorted linear geometry to two equivalent O(2) and two equivalent O(3) atoms. Cr(1) is bonded in a 4-coordinate geometry to two equivalent O(4) and two equivalent O(5) atoms. P(1) is bonded in a distorted L-shaped geometry to one O(2), one O(3), one O(4), and one O(5) atom. H(1) is bonded in a distorted single-bond geometry to one O(1) and one O(2) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one H(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one V(1), one P(1), and one H(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one V(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one Cr(1) and one P(1) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Cr(1) and one P(1) atom. is represented by the CIF card [CIF]
data_VCrP2(HO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.161
_cell_length_b   5.243
_cell_length_c   7.353
_cell_angle_alpha   109.688
_cell_angle_beta   104.952
_cell_angle_gamma   98.676
_symmetry_Int_Tables_number   1
_cell_volume   174.737
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.500  0.500  0.500  1.0
  Cr  Cr1  1  0.000  0.000  0.000  1.0
  P  P2  1  0.872  0.543  0.781  1.0
  P  P3  1  0.128  0.457  0.219  1.0
  H  H4  1  0.305  0.991  0.660  1.0
  H  H5  1  0.695  0.009  0.340  1.0
  O  O6  1  0.684  0.853  0.288  1.0
  O  O7  1  0.197  0.653  0.621  1.0
  O  O8  1  0.312  0.384  0.348  1.0
  O  O9  1  0.829  0.700  0.928  1.0
  O  O10  1  0.790  0.234  0.882  1.0
  O  O11  1  0.210  0.766  0.118  1.0
  O  O12  1  0.171  0.300  0.072  1.0
  O  O13  1  0.688  0.616  0.652  1.0
  O  O14  1  0.803  0.347  0.379  1.0
  O  O15  1  0.316  0.147  0.712  1.0
[/CIF]
.
The crystal structure described by VCrP2(HO5)2 crystallizes in the triclinic P-1 space group. V(1) is bonded in a distorted linear geometry to two equivalent O(2) and two equivalent O(3) atoms. Cr(1) is bonded in a 4-coordinate geometry to two equivalent O(4) and two equivalent O(5) atoms. P(1) is bonded in a distorted L-shaped geometry to one O(2), one O(3), one O(4), and one O(5) atom. H(1) is bonded in a distorted single-bond geometry to one O(1) and one O(2) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one H(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one V(1), one P(1), and one H(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one V(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one Cr(1) and one P(1) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Cr(1) and one P(1) atom. is represented by the CIF card [CIF]
data_VCrP2(HO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.161
_cell_length_b   5.243
_cell_length_c   7.353
_cell_angle_alpha   109.688
_cell_angle_beta   104.952
_cell_angle_gamma   98.676
_symmetry_Int_Tables_number   1
_cell_volume   174.737
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.500  0.500  0.500  1.0
  Cr  Cr1  1  0.000  0.000  0.000  1.0
  P  P2  1  0.872  0.543  0.781  1.0
  P  P3  1  0.128  0.457  0.219  1.0
  H  H4  1  0.305  0.991  0.660  1.0
  H  H5  1  0.695  0.009  0.340  1.0
  O  O6  1  0.684  0.853  0.288  1.0
  O  O7  1  0.197  0.653  0.621  1.0
  O  O8  1  0.312  0.384  0.348  1.0
  O  O9  1  0.829  0.700  0.928  1.0
  O  O10  1  0.790  0.234  0.882  1.0
  O  O11  1  0.210  0.766  0.118  1.0
  O  O12  1  0.171  0.300  0.072  1.0
  O  O13  1  0.688  0.616  0.652  1.0
  O  O14  1  0.803  0.347  0.379  1.0
  O  O15  1  0.316  0.147  0.712  1.0
[/CIF]
.