The compound described by LiGa(SeO3)2 crystallizes in the tetragonal I-42d space group. Li(1) is bonded in a 4-coordinate geometry to two equivalent O(1) and two equivalent O(2) atoms. Ga(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. Se(1) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one Ga(1), and one Se(1) atom. In the second O site, O(2) is bonded in a trigonal non-coplanar geometry to one Li(1), one Ga(1), and one Se(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Ga(1) and one Se(1) atom. is represented by the CIF file [CIF]
data_LiGa(SeO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.094
_cell_length_b   9.094
_cell_length_c   9.094
_cell_angle_alpha   107.665
_cell_angle_beta   107.665
_cell_angle_gamma   113.147
_symmetry_Int_Tables_number   1
_cell_volume   577.209
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.689  0.875  0.314  1.0
  Li  Li1  1  0.561  0.375  0.686  1.0
  Li  Li2  1  0.625  0.311  0.186  1.0
  Li  Li3  1  0.125  0.439  0.814  1.0
  Ga  Ga4  1  0.413  0.875  0.038  1.0
  Ga  Ga5  1  0.837  0.375  0.962  1.0
  Ga  Ga6  1  0.625  0.587  0.462  1.0
  Ga  Ga7  1  0.125  0.163  0.538  1.0
  Se  Se8  1  0.856  0.135  0.172  1.0
  Se  Se9  1  0.287  0.615  0.221  1.0
  Se  Se10  1  0.963  0.684  0.828  1.0
  Se  Se11  1  0.394  0.066  0.779  1.0
  Se  Se12  1  0.316  0.144  0.279  1.0
  Se  Se13  1  0.385  0.606  0.672  1.0
  Se  Se14  1  0.865  0.037  0.721  1.0
  Se  Se15  1  0.934  0.713  0.328  1.0
  O  O16  1  0.680  0.048  0.221  1.0
  O  O17  1  0.423  0.702  0.133  1.0
  O  O18  1  0.827  0.459  0.779  1.0
  O  O19  1  0.570  0.291  0.867  1.0
  O  O20  1  0.541  0.320  0.367  1.0
  O  O21  1  0.298  0.430  0.721  1.0
  O  O22  1  0.952  0.173  0.633  1.0
  O  O23  1  0.709  0.577  0.279  1.0
  O  O24  1  0.840  0.316  0.158  1.0
  O  O25  1  0.092  0.434  0.024  1.0
  O  O26  1  0.158  0.682  0.842  1.0
  O  O27  1  0.410  0.068  0.976  1.0
  O  O28  1  0.318  0.160  0.476  1.0
  O  O29  1  0.566  0.590  0.658  1.0
  O  O30  1  0.684  0.842  0.524  1.0
  O  O31  1  0.932  0.908  0.342  1.0
  O  O32  1  0.043  0.255  0.378  1.0
  O  O33  1  0.373  0.495  0.288  1.0
  O  O34  1  0.877  0.665  0.622  1.0
  O  O35  1  0.207  0.085  0.712  1.0
  O  O36  1  0.335  0.957  0.212  1.0
  O  O37  1  0.505  0.793  0.878  1.0
  O  O38  1  0.745  0.123  0.788  1.0
  O  O39  1  0.915  0.627  0.122  1.0
[/CIF]
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The compound described by LiGa(SeO3)2 crystallizes in the tetragonal I-42d space group. Li(1) is bonded in a 4-coordinate geometry to two equivalent O(1) and two equivalent O(2) atoms. Ga(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. Se(1) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one Ga(1), and one Se(1) atom. In the second O site, O(2) is bonded in a trigonal non-coplanar geometry to one Li(1), one Ga(1), and one Se(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Ga(1) and one Se(1) atom. is represented by the CIF file [CIF]
data_LiGa(SeO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.094
_cell_length_b   9.094
_cell_length_c   9.094
_cell_angle_alpha   107.665
_cell_angle_beta   107.665
_cell_angle_gamma   113.147
_symmetry_Int_Tables_number   1
_cell_volume   577.209
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.689  0.875  0.314  1.0
  Li  Li1  1  0.561  0.375  0.686  1.0
  Li  Li2  1  0.625  0.311  0.186  1.0
  Li  Li3  1  0.125  0.439  0.814  1.0
  Ga  Ga4  1  0.413  0.875  0.038  1.0
  Ga  Ga5  1  0.837  0.375  0.962  1.0
  Ga  Ga6  1  0.625  0.587  0.462  1.0
  Ga  Ga7  1  0.125  0.163  0.538  1.0
  Se  Se8  1  0.856  0.135  0.172  1.0
  Se  Se9  1  0.287  0.615  0.221  1.0
  Se  Se10  1  0.963  0.684  0.828  1.0
  Se  Se11  1  0.394  0.066  0.779  1.0
  Se  Se12  1  0.316  0.144  0.279  1.0
  Se  Se13  1  0.385  0.606  0.672  1.0
  Se  Se14  1  0.865  0.037  0.721  1.0
  Se  Se15  1  0.934  0.713  0.328  1.0
  O  O16  1  0.680  0.048  0.221  1.0
  O  O17  1  0.423  0.702  0.133  1.0
  O  O18  1  0.827  0.459  0.779  1.0
  O  O19  1  0.570  0.291  0.867  1.0
  O  O20  1  0.541  0.320  0.367  1.0
  O  O21  1  0.298  0.430  0.721  1.0
  O  O22  1  0.952  0.173  0.633  1.0
  O  O23  1  0.709  0.577  0.279  1.0
  O  O24  1  0.840  0.316  0.158  1.0
  O  O25  1  0.092  0.434  0.024  1.0
  O  O26  1  0.158  0.682  0.842  1.0
  O  O27  1  0.410  0.068  0.976  1.0
  O  O28  1  0.318  0.160  0.476  1.0
  O  O29  1  0.566  0.590  0.658  1.0
  O  O30  1  0.684  0.842  0.524  1.0
  O  O31  1  0.932  0.908  0.342  1.0
  O  O32  1  0.043  0.255  0.378  1.0
  O  O33  1  0.373  0.495  0.288  1.0
  O  O34  1  0.877  0.665  0.622  1.0
  O  O35  1  0.207  0.085  0.712  1.0
  O  O36  1  0.335  0.957  0.212  1.0
  O  O37  1  0.505  0.793  0.878  1.0
  O  O38  1  0.745  0.123  0.788  1.0
  O  O39  1  0.915  0.627  0.122  1.0
[/CIF]
.