The crystal structure described by KVH6SO9 crystallizes in the monoclinic P2_1 space group. K(1) is bonded in a 10-coordinate geometry to one O(1), one O(2), one O(4), one O(5), one O(6), one O(7), one O(8), one O(9), and two equivalent O(3) atoms. V(1) is bonded in a 6-coordinate geometry to one O(2), one O(3), one O(4), one O(6), one O(7), and one O(9) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(7) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(7) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(8) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(8) atom. In the sixth H site, H(6) is bonded in a distorted linear geometry to one O(6) and one O(8) atom. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(4), and one O(5) atom. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one K(1) and one S(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one K(1), one V(1), and one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to two equivalent K(1) and one V(1) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to one K(1), one V(1), and one S(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one K(1) and one S(1) atom. In the sixth O site, O(6) is bonded in a distorted water-like geometry to one K(1), one V(1), one H(3), and one H(6) atom. In the seventh O site, O(7) is bonded in a water-like geometry to one K(1), one V(1), one H(1), and one H(2) atom. In the eighth O site, O(8) is bonded in a distorted water-like geometry to one K(1), one H(4), one H(5), and one H(6) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one K(1) and one V(1) atom. is represented by the CIF file [CIF]
data_KVH6SO9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.951
_cell_length_b   6.281
_cell_length_c   6.624
_cell_angle_alpha   72.885
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   395.720
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.153  0.300  0.187  1.0
  K  K1  1  0.653  0.700  0.813  1.0
  V  V2  1  0.002  0.611  0.623  1.0
  V  V3  1  0.502  0.389  0.377  1.0
  H  H4  1  0.216  0.763  0.307  1.0
  H  H5  1  0.582  0.200  0.820  1.0
  H  H6  1  0.266  0.464  0.663  1.0
  H  H7  1  0.766  0.536  0.337  1.0
  H  H8  1  0.356  0.030  0.687  1.0
  H  H9  1  0.856  0.970  0.313  1.0
  H  H10  1  0.352  0.887  0.923  1.0
  H  H11  1  0.716  0.237  0.693  1.0
  H  H12  1  0.766  0.314  0.258  1.0
  H  H13  1  0.082  0.800  0.180  1.0
  H  H14  1  0.266  0.686  0.742  1.0
  H  H15  1  0.852  0.113  0.077  1.0
  S  S16  1  0.003  0.075  0.737  1.0
  S  S17  1  0.503  0.925  0.263  1.0
  O  O18  1  0.081  0.031  0.931  1.0
  O  O19  1  0.050  0.928  0.606  1.0
  O  O20  1  0.550  0.072  0.394  1.0
  O  O21  1  0.941  0.537  0.864  1.0
  O  O22  1  0.533  0.694  0.410  1.0
  O  O23  1  0.357  0.949  0.222  1.0
  O  O24  1  0.581  0.969  0.069  1.0
  O  O25  1  0.210  0.556  0.730  1.0
  O  O26  1  0.125  0.700  0.307  1.0
  O  O27  1  0.441  0.463  0.136  1.0
  O  O28  1  0.033  0.306  0.590  1.0
  O  O29  1  0.857  0.051  0.778  1.0
  O  O30  1  0.865  0.124  0.220  1.0
  O  O31  1  0.866  0.677  0.465  1.0
  O  O32  1  0.365  0.876  0.780  1.0
  O  O33  1  0.710  0.444  0.270  1.0
  O  O34  1  0.625  0.300  0.693  1.0
  O  O35  1  0.366  0.323  0.535  1.0
[/CIF]
.
The crystal structure described by KVH6SO9 crystallizes in the monoclinic P2_1 space group. K(1) is bonded in a 10-coordinate geometry to one O(1), one O(2), one O(4), one O(5), one O(6), one O(7), one O(8), one O(9), and two equivalent O(3) atoms. V(1) is bonded in a 6-coordinate geometry to one O(2), one O(3), one O(4), one O(6), one O(7), and one O(9) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(7) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(7) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(8) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(8) atom. In the sixth H site, H(6) is bonded in a distorted linear geometry to one O(6) and one O(8) atom. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(4), and one O(5) atom. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one K(1) and one S(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one K(1), one V(1), and one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to two equivalent K(1) and one V(1) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to one K(1), one V(1), and one S(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one K(1) and one S(1) atom. In the sixth O site, O(6) is bonded in a distorted water-like geometry to one K(1), one V(1), one H(3), and one H(6) atom. In the seventh O site, O(7) is bonded in a water-like geometry to one K(1), one V(1), one H(1), and one H(2) atom. In the eighth O site, O(8) is bonded in a distorted water-like geometry to one K(1), one H(4), one H(5), and one H(6) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one K(1) and one V(1) atom. is represented by the CIF file [CIF]
data_KVH6SO9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.951
_cell_length_b   6.281
_cell_length_c   6.624
_cell_angle_alpha   72.885
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   395.720
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.153  0.300  0.187  1.0
  K  K1  1  0.653  0.700  0.813  1.0
  V  V2  1  0.002  0.611  0.623  1.0
  V  V3  1  0.502  0.389  0.377  1.0
  H  H4  1  0.216  0.763  0.307  1.0
  H  H5  1  0.582  0.200  0.820  1.0
  H  H6  1  0.266  0.464  0.663  1.0
  H  H7  1  0.766  0.536  0.337  1.0
  H  H8  1  0.356  0.030  0.687  1.0
  H  H9  1  0.856  0.970  0.313  1.0
  H  H10  1  0.352  0.887  0.923  1.0
  H  H11  1  0.716  0.237  0.693  1.0
  H  H12  1  0.766  0.314  0.258  1.0
  H  H13  1  0.082  0.800  0.180  1.0
  H  H14  1  0.266  0.686  0.742  1.0
  H  H15  1  0.852  0.113  0.077  1.0
  S  S16  1  0.003  0.075  0.737  1.0
  S  S17  1  0.503  0.925  0.263  1.0
  O  O18  1  0.081  0.031  0.931  1.0
  O  O19  1  0.050  0.928  0.606  1.0
  O  O20  1  0.550  0.072  0.394  1.0
  O  O21  1  0.941  0.537  0.864  1.0
  O  O22  1  0.533  0.694  0.410  1.0
  O  O23  1  0.357  0.949  0.222  1.0
  O  O24  1  0.581  0.969  0.069  1.0
  O  O25  1  0.210  0.556  0.730  1.0
  O  O26  1  0.125  0.700  0.307  1.0
  O  O27  1  0.441  0.463  0.136  1.0
  O  O28  1  0.033  0.306  0.590  1.0
  O  O29  1  0.857  0.051  0.778  1.0
  O  O30  1  0.865  0.124  0.220  1.0
  O  O31  1  0.866  0.677  0.465  1.0
  O  O32  1  0.365  0.876  0.780  1.0
  O  O33  1  0.710  0.444  0.270  1.0
  O  O34  1  0.625  0.300  0.693  1.0
  O  O35  1  0.366  0.323  0.535  1.0
[/CIF]
.