The material structure described by VF5 is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four mfcd00137321 molecules. V(1) is bonded in a distorted trigonal bipyramidal geometry to one F(2), two equivalent F(1), and two equivalent F(3) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one V(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one V(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one V(1) atom. is represented by the CIF file [CIF]
data_VF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.747
_cell_length_b   8.089
_cell_length_c   9.592
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   368.309
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.294  0.086  0.250  1.0
  V  V1  1  0.794  0.414  0.750  1.0
  V  V2  1  0.206  0.586  0.250  1.0
  V  V3  1  0.706  0.914  0.750  1.0
  F  F4  1  0.027  0.068  0.126  1.0
  F  F5  1  0.027  0.068  0.374  1.0
  F  F6  1  0.547  0.105  0.750  1.0
  F  F7  1  0.476  0.200  0.125  1.0
  F  F8  1  0.476  0.200  0.375  1.0
  F  F9  1  0.976  0.300  0.625  1.0
  F  F10  1  0.976  0.300  0.875  1.0
  F  F11  1  0.047  0.395  0.250  1.0
  F  F12  1  0.527  0.432  0.626  1.0
  F  F13  1  0.527  0.432  0.874  1.0
  F  F14  1  0.473  0.568  0.126  1.0
  F  F15  1  0.473  0.568  0.374  1.0
  F  F16  1  0.953  0.605  0.750  1.0
  F  F17  1  0.024  0.700  0.125  1.0
  F  F18  1  0.024  0.700  0.375  1.0
  F  F19  1  0.524  0.800  0.625  1.0
  F  F20  1  0.524  0.800  0.875  1.0
  F  F21  1  0.453  0.895  0.250  1.0
  F  F22  1  0.973  0.932  0.626  1.0
  F  F23  1  0.973  0.932  0.874  1.0
[/CIF]
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The material structure described by VF5 is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four mfcd00137321 molecules. V(1) is bonded in a distorted trigonal bipyramidal geometry to one F(2), two equivalent F(1), and two equivalent F(3) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one V(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one V(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one V(1) atom. is represented by the CIF file [CIF]
data_VF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.747
_cell_length_b   8.089
_cell_length_c   9.592
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   368.309
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.294  0.086  0.250  1.0
  V  V1  1  0.794  0.414  0.750  1.0
  V  V2  1  0.206  0.586  0.250  1.0
  V  V3  1  0.706  0.914  0.750  1.0
  F  F4  1  0.027  0.068  0.126  1.0
  F  F5  1  0.027  0.068  0.374  1.0
  F  F6  1  0.547  0.105  0.750  1.0
  F  F7  1  0.476  0.200  0.125  1.0
  F  F8  1  0.476  0.200  0.375  1.0
  F  F9  1  0.976  0.300  0.625  1.0
  F  F10  1  0.976  0.300  0.875  1.0
  F  F11  1  0.047  0.395  0.250  1.0
  F  F12  1  0.527  0.432  0.626  1.0
  F  F13  1  0.527  0.432  0.874  1.0
  F  F14  1  0.473  0.568  0.126  1.0
  F  F15  1  0.473  0.568  0.374  1.0
  F  F16  1  0.953  0.605  0.750  1.0
  F  F17  1  0.024  0.700  0.125  1.0
  F  F18  1  0.024  0.700  0.375  1.0
  F  F19  1  0.524  0.800  0.625  1.0
  F  F20  1  0.524  0.800  0.875  1.0
  F  F21  1  0.453  0.895  0.250  1.0
  F  F22  1  0.973  0.932  0.626  1.0
  F  F23  1  0.973  0.932  0.874  1.0
[/CIF]
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