The compound described by PuCP2H2O6 crystallizes in the monoclinic C2/m space group. Pu(1) is bonded in a 8-coordinate geometry to two equivalent O(2), two equivalent O(3), and four equivalent O(1) atoms. C(1) is bonded in a distorted tetrahedral geometry to two equivalent P(1), one H(1), and one H(2) atom. P(1) is bonded to one C(1), one O(1), one O(2), and one O(3) atom to form distorted corner-sharing PCO3 tetrahedra. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. There are three inequivalent O sites. In the first O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Pu(1) and one P(1) atom. In the second O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Pu(1) and one P(1) atom. In the third O site, O(2) is bonded in a water-like geometry to one Pu(1) and one P(1) atom. is represented by the CIF card [CIF]
data_PuP2H2CO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.420
_cell_length_b   8.043
_cell_length_c   8.122
_cell_angle_alpha   114.323
_cell_angle_beta   102.130
_cell_angle_gamma   104.452
_symmetry_Int_Tables_number   1
_cell_volume   292.140
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pu  Pu0  1  0.767  0.767  0.533  1.0
  Pu  Pu1  1  0.233  0.233  0.467  1.0
  P  P2  1  0.735  0.367  0.233  1.0
  P  P3  1  0.502  0.134  0.767  1.0
  P  P4  1  0.265  0.633  0.767  1.0
  P  P5  1  0.498  0.866  0.233  1.0
  H  H6  1  0.335  0.097  0.000  1.0
  H  H7  1  0.665  0.903  0.000  1.0
  H  H8  1  0.340  0.318  0.000  1.0
  H  H9  1  0.660  0.682  0.000  1.0
  C  C10  1  0.463  0.227  0.000  1.0
  C  C11  1  0.537  0.773  0.000  1.0
  O  O12  1  0.411  0.609  0.617  1.0
  O  O13  1  0.793  0.992  0.383  1.0
  O  O14  1  0.589  0.391  0.383  1.0
  O  O15  1  0.207  0.008  0.617  1.0
  O  O16  1  0.877  0.583  0.282  1.0
  O  O17  1  0.595  0.301  0.718  1.0
  O  O18  1  0.123  0.417  0.718  1.0
  O  O19  1  0.405  0.699  0.282  1.0
  O  O20  1  0.069  0.740  0.756  1.0
  O  O21  1  0.312  0.983  0.244  1.0
  O  O22  1  0.931  0.260  0.244  1.0
  O  O23  1  0.688  0.017  0.756  1.0
[/CIF]
.
The compound described by PuCP2H2O6 crystallizes in the monoclinic C2/m space group. Pu(1) is bonded in a 8-coordinate geometry to two equivalent O(2), two equivalent O(3), and four equivalent O(1) atoms. C(1) is bonded in a distorted tetrahedral geometry to two equivalent P(1), one H(1), and one H(2) atom. P(1) is bonded to one C(1), one O(1), one O(2), and one O(3) atom to form distorted corner-sharing PCO3 tetrahedra. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. There are three inequivalent O sites. In the first O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Pu(1) and one P(1) atom. In the second O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Pu(1) and one P(1) atom. In the third O site, O(2) is bonded in a water-like geometry to one Pu(1) and one P(1) atom. is represented by the CIF card [CIF]
data_PuP2H2CO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.420
_cell_length_b   8.043
_cell_length_c   8.122
_cell_angle_alpha   114.323
_cell_angle_beta   102.130
_cell_angle_gamma   104.452
_symmetry_Int_Tables_number   1
_cell_volume   292.140
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pu  Pu0  1  0.767  0.767  0.533  1.0
  Pu  Pu1  1  0.233  0.233  0.467  1.0
  P  P2  1  0.735  0.367  0.233  1.0
  P  P3  1  0.502  0.134  0.767  1.0
  P  P4  1  0.265  0.633  0.767  1.0
  P  P5  1  0.498  0.866  0.233  1.0
  H  H6  1  0.335  0.097  0.000  1.0
  H  H7  1  0.665  0.903  0.000  1.0
  H  H8  1  0.340  0.318  0.000  1.0
  H  H9  1  0.660  0.682  0.000  1.0
  C  C10  1  0.463  0.227  0.000  1.0
  C  C11  1  0.537  0.773  0.000  1.0
  O  O12  1  0.411  0.609  0.617  1.0
  O  O13  1  0.793  0.992  0.383  1.0
  O  O14  1  0.589  0.391  0.383  1.0
  O  O15  1  0.207  0.008  0.617  1.0
  O  O16  1  0.877  0.583  0.282  1.0
  O  O17  1  0.595  0.301  0.718  1.0
  O  O18  1  0.123  0.417  0.718  1.0
  O  O19  1  0.405  0.699  0.282  1.0
  O  O20  1  0.069  0.740  0.756  1.0
  O  O21  1  0.312  0.983  0.244  1.0
  O  O22  1  0.931  0.260  0.244  1.0
  O  O23  1  0.688  0.017  0.756  1.0
[/CIF]
.