The material described by BiOF crystallizes in the orthorhombic Pnma space group. Bi(1) is bonded in a 5-coordinate geometry to four equivalent O(1) and one F(1) atom. O(1) is bonded to four equivalent Bi(1) atoms to form a mixture of edge and corner-sharing OBi4 tetrahedra. F(1) is bonded in a single-bond geometry to one Bi(1) atom. is represented by the CIF file [CIF]
data_BiOF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.792
_cell_length_b   6.377
_cell_length_c   7.389
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   178.643
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.250  0.220  0.914  1.0
  Bi  Bi1  1  0.750  0.280  0.414  1.0
  Bi  Bi2  1  0.250  0.720  0.586  1.0
  Bi  Bi3  1  0.750  0.780  0.086  1.0
  O  O4  1  0.750  0.137  0.068  1.0
  O  O5  1  0.250  0.363  0.568  1.0
  O  O6  1  0.750  0.637  0.432  1.0
  O  O7  1  0.250  0.863  0.932  1.0
  F  F8  1  0.750  0.043  0.661  1.0
  F  F9  1  0.250  0.457  0.161  1.0
  F  F10  1  0.750  0.543  0.839  1.0
  F  F11  1  0.250  0.957  0.339  1.0
[/CIF]
.
The material described by BiOF crystallizes in the orthorhombic Pnma space group. Bi(1) is bonded in a 5-coordinate geometry to four equivalent O(1) and one F(1) atom. O(1) is bonded to four equivalent Bi(1) atoms to form a mixture of edge and corner-sharing OBi4 tetrahedra. F(1) is bonded in a single-bond geometry to one Bi(1) atom. is represented by the CIF file [CIF]
data_BiOF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.792
_cell_length_b   6.377
_cell_length_c   7.389
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   178.643
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.250  0.220  0.914  1.0
  Bi  Bi1  1  0.750  0.280  0.414  1.0
  Bi  Bi2  1  0.250  0.720  0.586  1.0
  Bi  Bi3  1  0.750  0.780  0.086  1.0
  O  O4  1  0.750  0.137  0.068  1.0
  O  O5  1  0.250  0.363  0.568  1.0
  O  O6  1  0.750  0.637  0.432  1.0
  O  O7  1  0.250  0.863  0.932  1.0
  F  F8  1  0.750  0.043  0.661  1.0
  F  F9  1  0.250  0.457  0.161  1.0
  F  F10  1  0.750  0.543  0.839  1.0
  F  F11  1  0.250  0.957  0.339  1.0
[/CIF]
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