The material described by Ge2C2(SF2)3 is diamond structured and crystallizes in the cubic Fd-3m space group. The structure is zero-dimensional and consists of eight 1,3,5,7-tetrakis(trifluoromethyl)-2,4,6,8,9,10-hexathia-1,3,5,7-tetragermatricyclo[3.3.1.13,7]decane molecules. Ge(1) is bonded to one C(1) and three equivalent S(1) atoms to form corner-sharing GeCS3 tetrahedra. C(1) is bonded in a distorted trigonal non-coplanar geometry to one Ge(1) and three equivalent F(1) atoms. S(1) is bonded in a water-like geometry to two equivalent Ge(1) atoms. F(1) is bonded in a single-bond geometry to one C(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ge2C2(SF2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.399
_cell_length_b   11.399
_cell_length_c   11.399
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   1047.270
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ge  Ge0  1  0.425  0.725  0.425  1.0
  Ge  Ge1  1  0.825  0.825  0.525  1.0
  Ge  Ge2  1  0.525  0.825  0.825  1.0
  Ge  Ge3  1  0.825  0.825  0.825  1.0
  Ge  Ge4  1  0.725  0.425  0.425  1.0
  Ge  Ge5  1  0.425  0.425  0.425  1.0
  Ge  Ge6  1  0.425  0.425  0.725  1.0
  Ge  Ge7  1  0.825  0.525  0.825  1.0
  C  C8  1  0.352  0.945  0.352  1.0
  C  C9  1  0.898  0.898  0.305  1.0
  C  C10  1  0.305  0.898  0.898  1.0
  C  C11  1  0.898  0.898  0.898  1.0
  C  C12  1  0.945  0.352  0.352  1.0
  C  C13  1  0.352  0.352  0.352  1.0
  C  C14  1  0.352  0.352  0.945  1.0
  C  C15  1  0.898  0.305  0.898  1.0
  S  S16  1  0.665  0.665  0.335  1.0
  S  S17  1  0.915  0.585  0.585  1.0
  S  S18  1  0.585  0.915  0.915  1.0
  S  S19  1  0.915  0.915  0.585  1.0
  S  S20  1  0.915  0.585  0.915  1.0
  S  S21  1  0.585  0.915  0.585  1.0
  S  S22  1  0.335  0.665  0.335  1.0
  S  S23  1  0.335  0.665  0.665  1.0
  S  S24  1  0.665  0.335  0.335  1.0
  S  S25  1  0.665  0.335  0.665  1.0
  S  S26  1  0.585  0.585  0.915  1.0
  S  S27  1  0.335  0.335  0.665  1.0
  F  F28  1  0.270  0.998  0.463  1.0
  F  F29  1  0.980  0.980  0.252  1.0
  F  F30  1  0.252  0.787  0.980  1.0
  F  F31  1  0.980  0.787  0.980  1.0
  F  F32  1  0.787  0.980  0.252  1.0
  F  F33  1  0.787  0.980  0.980  1.0
  F  F34  1  0.252  0.980  0.980  1.0
  F  F35  1  0.463  0.998  0.270  1.0
  F  F36  1  0.270  0.998  0.270  1.0
  F  F37  1  0.998  0.270  0.463  1.0
  F  F38  1  0.270  0.270  0.463  1.0
  F  F39  1  0.998  0.463  0.270  1.0
  F  F40  1  0.463  0.270  0.998  1.0
  F  F41  1  0.270  0.270  0.998  1.0
  F  F42  1  0.270  0.463  0.270  1.0
  F  F43  1  0.252  0.980  0.787  1.0
  F  F44  1  0.980  0.980  0.787  1.0
  F  F45  1  0.980  0.787  0.252  1.0
  F  F46  1  0.980  0.252  0.787  1.0
  F  F47  1  0.787  0.252  0.980  1.0
  F  F48  1  0.980  0.252  0.980  1.0
  F  F49  1  0.463  0.270  0.270  1.0
  F  F50  1  0.998  0.270  0.270  1.0
  F  F51  1  0.270  0.463  0.998  1.0
[/CIF]
.
The material described by Ge2C2(SF2)3 is diamond structured and crystallizes in the cubic Fd-3m space group. The structure is zero-dimensional and consists of eight 1,3,5,7-tetrakis(trifluoromethyl)-2,4,6,8,9,10-hexathia-1,3,5,7-tetragermatricyclo[3.3.1.13,7]decane molecules. Ge(1) is bonded to one C(1) and three equivalent S(1) atoms to form corner-sharing GeCS3 tetrahedra. C(1) is bonded in a distorted trigonal non-coplanar geometry to one Ge(1) and three equivalent F(1) atoms. S(1) is bonded in a water-like geometry to two equivalent Ge(1) atoms. F(1) is bonded in a single-bond geometry to one C(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ge2C2(SF2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.399
_cell_length_b   11.399
_cell_length_c   11.399
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   1047.270
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ge  Ge0  1  0.425  0.725  0.425  1.0
  Ge  Ge1  1  0.825  0.825  0.525  1.0
  Ge  Ge2  1  0.525  0.825  0.825  1.0
  Ge  Ge3  1  0.825  0.825  0.825  1.0
  Ge  Ge4  1  0.725  0.425  0.425  1.0
  Ge  Ge5  1  0.425  0.425  0.425  1.0
  Ge  Ge6  1  0.425  0.425  0.725  1.0
  Ge  Ge7  1  0.825  0.525  0.825  1.0
  C  C8  1  0.352  0.945  0.352  1.0
  C  C9  1  0.898  0.898  0.305  1.0
  C  C10  1  0.305  0.898  0.898  1.0
  C  C11  1  0.898  0.898  0.898  1.0
  C  C12  1  0.945  0.352  0.352  1.0
  C  C13  1  0.352  0.352  0.352  1.0
  C  C14  1  0.352  0.352  0.945  1.0
  C  C15  1  0.898  0.305  0.898  1.0
  S  S16  1  0.665  0.665  0.335  1.0
  S  S17  1  0.915  0.585  0.585  1.0
  S  S18  1  0.585  0.915  0.915  1.0
  S  S19  1  0.915  0.915  0.585  1.0
  S  S20  1  0.915  0.585  0.915  1.0
  S  S21  1  0.585  0.915  0.585  1.0
  S  S22  1  0.335  0.665  0.335  1.0
  S  S23  1  0.335  0.665  0.665  1.0
  S  S24  1  0.665  0.335  0.335  1.0
  S  S25  1  0.665  0.335  0.665  1.0
  S  S26  1  0.585  0.585  0.915  1.0
  S  S27  1  0.335  0.335  0.665  1.0
  F  F28  1  0.270  0.998  0.463  1.0
  F  F29  1  0.980  0.980  0.252  1.0
  F  F30  1  0.252  0.787  0.980  1.0
  F  F31  1  0.980  0.787  0.980  1.0
  F  F32  1  0.787  0.980  0.252  1.0
  F  F33  1  0.787  0.980  0.980  1.0
  F  F34  1  0.252  0.980  0.980  1.0
  F  F35  1  0.463  0.998  0.270  1.0
  F  F36  1  0.270  0.998  0.270  1.0
  F  F37  1  0.998  0.270  0.463  1.0
  F  F38  1  0.270  0.270  0.463  1.0
  F  F39  1  0.998  0.463  0.270  1.0
  F  F40  1  0.463  0.270  0.998  1.0
  F  F41  1  0.270  0.270  0.998  1.0
  F  F42  1  0.270  0.463  0.270  1.0
  F  F43  1  0.252  0.980  0.787  1.0
  F  F44  1  0.980  0.980  0.787  1.0
  F  F45  1  0.980  0.787  0.252  1.0
  F  F46  1  0.980  0.252  0.787  1.0
  F  F47  1  0.787  0.252  0.980  1.0
  F  F48  1  0.980  0.252  0.980  1.0
  F  F49  1  0.463  0.270  0.270  1.0
  F  F50  1  0.998  0.270  0.270  1.0
  F  F51  1  0.270  0.463  0.998  1.0
[/CIF]
.