The material structure described by WCoZn2O6 crystallizes in the triclinic P1 space group. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share corners with six equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 41-42°. Co(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form CoO6 octahedra that share corners with six equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 41-42°. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. In the second Zn site, Zn(2) is bonded in a trigonal planar geometry to one O(1), one O(5), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded to one W(1), one Co(1), one Zn(1), and one Zn(2) atom to form a mixture of edge and corner-sharing OZn2CoW tetrahedra. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one W(1), one Co(1), and one Zn(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one W(1), one Co(1), and one Zn(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one W(1), one Co(1), and one Zn(1) atom. In the fifth O site, O(5) is bonded to one W(1), one Co(1), one Zn(1), and one Zn(2) atom to form a mixture of distorted edge and corner-sharing OZn2CoW tetrahedra. In the sixth O site, O(6) is bonded to one W(1), one Co(1), one Zn(1), and one Zn(2) atom to form a mixture of distorted edge and corner-sharing OZn2CoW tetrahedra. is represented by the CIF card [CIF]
data_Zn2CoWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.258
_cell_length_b   5.212
_cell_length_c   5.526
_cell_angle_alpha   90.146
_cell_angle_beta   117.467
_cell_angle_gamma   119.234
_symmetry_Int_Tables_number   1
_cell_volume   112.068
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.555  0.782  0.347  1.0
  Zn  Zn1  1  0.497  0.259  0.750  1.0
  Co  Co2  1  0.980  0.496  0.479  1.0
  W  W3  1  0.988  0.003  0.988  1.0
  O  O4  1  0.820  0.623  0.705  1.0
  O  O5  1  0.105  0.369  0.208  1.0
  O  O6  1  0.440  0.086  0.195  1.0
  O  O7  1  0.835  0.749  0.204  1.0
  O  O8  1  0.095  0.221  0.715  1.0
  O  O9  1  0.512  0.898  0.713  1.0
[/CIF]
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The material structure described by WCoZn2O6 crystallizes in the triclinic P1 space group. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share corners with six equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 41-42°. Co(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form CoO6 octahedra that share corners with six equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 41-42°. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. In the second Zn site, Zn(2) is bonded in a trigonal planar geometry to one O(1), one O(5), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded to one W(1), one Co(1), one Zn(1), and one Zn(2) atom to form a mixture of edge and corner-sharing OZn2CoW tetrahedra. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one W(1), one Co(1), and one Zn(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one W(1), one Co(1), and one Zn(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one W(1), one Co(1), and one Zn(1) atom. In the fifth O site, O(5) is bonded to one W(1), one Co(1), one Zn(1), and one Zn(2) atom to form a mixture of distorted edge and corner-sharing OZn2CoW tetrahedra. In the sixth O site, O(6) is bonded to one W(1), one Co(1), one Zn(1), and one Zn(2) atom to form a mixture of distorted edge and corner-sharing OZn2CoW tetrahedra. is represented by the CIF card [CIF]
data_Zn2CoWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.258
_cell_length_b   5.212
_cell_length_c   5.526
_cell_angle_alpha   90.146
_cell_angle_beta   117.467
_cell_angle_gamma   119.234
_symmetry_Int_Tables_number   1
_cell_volume   112.068
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.555  0.782  0.347  1.0
  Zn  Zn1  1  0.497  0.259  0.750  1.0
  Co  Co2  1  0.980  0.496  0.479  1.0
  W  W3  1  0.988  0.003  0.988  1.0
  O  O4  1  0.820  0.623  0.705  1.0
  O  O5  1  0.105  0.369  0.208  1.0
  O  O6  1  0.440  0.086  0.195  1.0
  O  O7  1  0.835  0.749  0.204  1.0
  O  O8  1  0.095  0.221  0.715  1.0
  O  O9  1  0.512  0.898  0.713  1.0
[/CIF]
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