The crystal structure described by Li5V3(CoO5)2 is Caswellsilverite-derived structured and crystallizes in the triclinic P-1 space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(4), two equivalent O(3), and two equivalent O(5) atoms to form distorted LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, corners with three equivalent V(2)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with three equivalent Li(2)O6 octahedra, and edges with three equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-17°. In the second Li site, Li(2) is bonded to one O(1), one O(3), one O(4), one O(5), and two equivalent O(2) atoms to form distorted LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with three equivalent Co(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and edges with three equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-21°. In the third Li site, Li(3) is bonded to two equivalent O(3), two equivalent O(4), and two equivalent O(5) atoms to form LiO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent V(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(2)O6 octahedra, edges with four equivalent Li(1)O6 octahedra, and edges with four equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-15°. There are two inequivalent V sites. In the first V site, V(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms to form VO6 octahedra that share corners with two equivalent Li(3)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with four equivalent Li(2)O6 octahedra, and edges with four equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles are 10°. In the second V site, V(2) is bonded to one O(4), one O(5), two equivalent O(1), and two equivalent O(2) atoms to form VO6 octahedra that share  a cornercorner with one V(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with three equivalent Li(1)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with two equivalent V(2)O6 octahedra, edges with three equivalent Li(2)O6 octahedra, and edges with three equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-17°. Co(1) is bonded to one O(1), one O(2), one O(4), one O(5), and two equivalent O(3) atoms to form distorted CoO6 octahedra that share  a cornercorner with one V(1)O6 octahedra, corners with two equivalent Li(1)O6 octahedra, corners with three equivalent Li(2)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and edges with three equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-21°. There are five inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one Li(2), one V(1), two equivalent V(2), and one Co(1) atom to form OLi2V3Co octahedra that share  a cornercorner with one O(1)Li2V3Co octahedra,  a cornercorner with one O(2)Li2V3Co octahedra,  a cornercorner with one O(4)Li3V2Co octahedra,  a cornercorner with one O(3)Li4Co2 octahedra, corners with two equivalent O(5)Li4VCo octahedra,  an edgeedge with one O(1)Li2V3Co octahedra, edges with two equivalent O(3)Li4Co2 octahedra, edges with two equivalent O(5)Li4VCo octahedra, edges with three equivalent O(4)Li3V2Co octahedra, and edges with four equivalent O(2)Li2V3Co octahedra. The corner-sharing octahedral tilt angles range from 0-20°. In the second O site, O(2) is bonded to two equivalent Li(2), one V(1), two equivalent V(2), and one Co(1) atom to form OLi2V3Co octahedra that share  a cornercorner with one O(1)Li2V3Co octahedra,  a cornercorner with one O(2)Li2V3Co octahedra,  a cornercorner with one O(4)Li3V2Co octahedra,  a cornercorner with one O(5)Li4VCo octahedra, corners with two equivalent O(3)Li4Co2 octahedra,  an edgeedge with one O(3)Li4Co2 octahedra, edges with two equivalent O(2)Li2V3Co octahedra, edges with two equivalent O(5)Li4VCo octahedra, edges with three equivalent O(4)Li3V2Co octahedra, and edges with four equivalent O(1)Li2V3Co octahedra. The corner-sharing octahedral tilt angles range from 0-14°. In the third O site, O(3) is bonded to one Li(2), one Li(3), two equivalent Li(1), and two equivalent Co(1) atoms to form OLi4Co2 octahedra that share  a cornercorner with one O(1)Li2V3Co octahedra,  a cornercorner with one O(4)Li3V2Co octahedra,  a cornercorner with one O(3)Li4Co2 octahedra,  a cornercorner with one O(5)Li4VCo octahedra, corners with two equivalent O(2)Li2V3Co octahedra,  an edgeedge with one O(2)Li2V3Co octahedra, edges with two equivalent O(1)Li2V3Co octahedra, edges with two equivalent O(3)Li4Co2 octahedra, edges with three equivalent O(4)Li3V2Co octahedra, and edges with four equivalent O(5)Li4VCo octahedra. The corner-sharing octahedral tilt angles range from 0-14°. In the fourth O site, O(4) is bonded to one Li(1), one Li(2), one Li(3), one V(1), one V(2), and one Co(1) atom to form distorted OLi3V2Co octahedra that share  a cornercorner with one O(1)Li2V3Co octahedra,  a cornercorner with one O(2)Li2V3Co octahedra,  a cornercorner with one O(3)Li4Co2 octahedra,  a cornercorner with one O(5)Li4VCo octahedra, corners with two equivalent O(4)Li3V2Co octahedra, edges with three equivalent O(1)Li2V3Co octahedra, edges with three equivalent O(2)Li2V3Co octahedra, edges with three equivalent O(3)Li4Co2 octahedra, and edges with three equivalent O(5)Li4VCo octahedra. The corner-sharing octahedral tilt angles range from 0-20°. In the fifth O site, O(5) is bonded to one Li(2), one Li(3), two equivalent Li(1), one V(2), and one Co(1) atom to form distorted OLi4VCo octahedra that share  a cornercorner with one O(2)Li2V3Co octahedra,  a cornercorner with one O(4)Li3V2Co octahedra,  a cornercorner with one O(3)Li4Co2 octahedra,  a cornercorner with one O(5)Li4VCo octahedra, corners with two equivalent O(1)Li2V3Co octahedra,  an edgeedge with one O(5)Li4VCo octahedra, edges with two equivalent O(1)Li2V3Co octahedra, edges with two equivalent O(2)Li2V3Co octahedra, edges with three equivalent O(4)Li3V2Co octahedra, and edges with four equivalent O(3)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 0-18°. is represented by the CIF card [CIF]
data_Li5V3(CoO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.096
_cell_length_b   5.228
_cell_length_c   7.920
_cell_angle_alpha   107.281
_cell_angle_beta   102.668
_cell_angle_gamma   100.849
_symmetry_Int_Tables_number   1
_cell_volume   189.167
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.194  0.926  0.422  1.0
  Li  Li1  1  0.382  0.284  0.774  1.0
  Li  Li2  1  0.500  0.500  0.500  1.0
  Li  Li3  1  0.618  0.716  0.226  1.0
  Li  Li4  1  0.806  0.074  0.578  1.0
  V  V5  1  0.000  0.500  0.000  1.0
  V  V6  1  0.684  0.892  0.882  1.0
  V  V7  1  0.316  0.108  0.118  1.0
  Co  Co8  1  0.088  0.677  0.680  1.0
  Co  Co9  1  0.912  0.323  0.320  1.0
  O  O10  1  0.051  0.101  0.872  1.0
  O  O11  1  0.347  0.732  0.958  1.0
  O  O12  1  0.145  0.304  0.550  1.0
  O  O13  1  0.247  0.472  0.223  1.0
  O  O14  1  0.481  0.906  0.672  1.0
  O  O15  1  0.519  0.094  0.328  1.0
  O  O16  1  0.753  0.528  0.777  1.0
  O  O17  1  0.855  0.696  0.450  1.0
  O  O18  1  0.653  0.268  0.042  1.0
  O  O19  1  0.949  0.899  0.128  1.0
[/CIF]
.
The crystal structure described by Li5V3(CoO5)2 is Caswellsilverite-derived structured and crystallizes in the triclinic P-1 space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(4), two equivalent O(3), and two equivalent O(5) atoms to form distorted LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, corners with three equivalent V(2)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with three equivalent Li(2)O6 octahedra, and edges with three equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-17°. In the second Li site, Li(2) is bonded to one O(1), one O(3), one O(4), one O(5), and two equivalent O(2) atoms to form distorted LiO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with three equivalent Co(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and edges with three equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-21°. In the third Li site, Li(3) is bonded to two equivalent O(3), two equivalent O(4), and two equivalent O(5) atoms to form LiO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent V(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(2)O6 octahedra, edges with four equivalent Li(1)O6 octahedra, and edges with four equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-15°. There are two inequivalent V sites. In the first V site, V(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms to form VO6 octahedra that share corners with two equivalent Li(3)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with four equivalent Li(2)O6 octahedra, and edges with four equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles are 10°. In the second V site, V(2) is bonded to one O(4), one O(5), two equivalent O(1), and two equivalent O(2) atoms to form VO6 octahedra that share  a cornercorner with one V(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with three equivalent Li(1)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with two equivalent V(2)O6 octahedra, edges with three equivalent Li(2)O6 octahedra, and edges with three equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-17°. Co(1) is bonded to one O(1), one O(2), one O(4), one O(5), and two equivalent O(3) atoms to form distorted CoO6 octahedra that share  a cornercorner with one V(1)O6 octahedra, corners with two equivalent Li(1)O6 octahedra, corners with three equivalent Li(2)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and edges with three equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-21°. There are five inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one Li(2), one V(1), two equivalent V(2), and one Co(1) atom to form OLi2V3Co octahedra that share  a cornercorner with one O(1)Li2V3Co octahedra,  a cornercorner with one O(2)Li2V3Co octahedra,  a cornercorner with one O(4)Li3V2Co octahedra,  a cornercorner with one O(3)Li4Co2 octahedra, corners with two equivalent O(5)Li4VCo octahedra,  an edgeedge with one O(1)Li2V3Co octahedra, edges with two equivalent O(3)Li4Co2 octahedra, edges with two equivalent O(5)Li4VCo octahedra, edges with three equivalent O(4)Li3V2Co octahedra, and edges with four equivalent O(2)Li2V3Co octahedra. The corner-sharing octahedral tilt angles range from 0-20°. In the second O site, O(2) is bonded to two equivalent Li(2), one V(1), two equivalent V(2), and one Co(1) atom to form OLi2V3Co octahedra that share  a cornercorner with one O(1)Li2V3Co octahedra,  a cornercorner with one O(2)Li2V3Co octahedra,  a cornercorner with one O(4)Li3V2Co octahedra,  a cornercorner with one O(5)Li4VCo octahedra, corners with two equivalent O(3)Li4Co2 octahedra,  an edgeedge with one O(3)Li4Co2 octahedra, edges with two equivalent O(2)Li2V3Co octahedra, edges with two equivalent O(5)Li4VCo octahedra, edges with three equivalent O(4)Li3V2Co octahedra, and edges with four equivalent O(1)Li2V3Co octahedra. The corner-sharing octahedral tilt angles range from 0-14°. In the third O site, O(3) is bonded to one Li(2), one Li(3), two equivalent Li(1), and two equivalent Co(1) atoms to form OLi4Co2 octahedra that share  a cornercorner with one O(1)Li2V3Co octahedra,  a cornercorner with one O(4)Li3V2Co octahedra,  a cornercorner with one O(3)Li4Co2 octahedra,  a cornercorner with one O(5)Li4VCo octahedra, corners with two equivalent O(2)Li2V3Co octahedra,  an edgeedge with one O(2)Li2V3Co octahedra, edges with two equivalent O(1)Li2V3Co octahedra, edges with two equivalent O(3)Li4Co2 octahedra, edges with three equivalent O(4)Li3V2Co octahedra, and edges with four equivalent O(5)Li4VCo octahedra. The corner-sharing octahedral tilt angles range from 0-14°. In the fourth O site, O(4) is bonded to one Li(1), one Li(2), one Li(3), one V(1), one V(2), and one Co(1) atom to form distorted OLi3V2Co octahedra that share  a cornercorner with one O(1)Li2V3Co octahedra,  a cornercorner with one O(2)Li2V3Co octahedra,  a cornercorner with one O(3)Li4Co2 octahedra,  a cornercorner with one O(5)Li4VCo octahedra, corners with two equivalent O(4)Li3V2Co octahedra, edges with three equivalent O(1)Li2V3Co octahedra, edges with three equivalent O(2)Li2V3Co octahedra, edges with three equivalent O(3)Li4Co2 octahedra, and edges with three equivalent O(5)Li4VCo octahedra. The corner-sharing octahedral tilt angles range from 0-20°. In the fifth O site, O(5) is bonded to one Li(2), one Li(3), two equivalent Li(1), one V(2), and one Co(1) atom to form distorted OLi4VCo octahedra that share  a cornercorner with one O(2)Li2V3Co octahedra,  a cornercorner with one O(4)Li3V2Co octahedra,  a cornercorner with one O(3)Li4Co2 octahedra,  a cornercorner with one O(5)Li4VCo octahedra, corners with two equivalent O(1)Li2V3Co octahedra,  an edgeedge with one O(5)Li4VCo octahedra, edges with two equivalent O(1)Li2V3Co octahedra, edges with two equivalent O(2)Li2V3Co octahedra, edges with three equivalent O(4)Li3V2Co octahedra, and edges with four equivalent O(3)Li4Co2 octahedra. The corner-sharing octahedral tilt angles range from 0-18°. is represented by the CIF card [CIF]
data_Li5V3(CoO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.096
_cell_length_b   5.228
_cell_length_c   7.920
_cell_angle_alpha   107.281
_cell_angle_beta   102.668
_cell_angle_gamma   100.849
_symmetry_Int_Tables_number   1
_cell_volume   189.167
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.194  0.926  0.422  1.0
  Li  Li1  1  0.382  0.284  0.774  1.0
  Li  Li2  1  0.500  0.500  0.500  1.0
  Li  Li3  1  0.618  0.716  0.226  1.0
  Li  Li4  1  0.806  0.074  0.578  1.0
  V  V5  1  0.000  0.500  0.000  1.0
  V  V6  1  0.684  0.892  0.882  1.0
  V  V7  1  0.316  0.108  0.118  1.0
  Co  Co8  1  0.088  0.677  0.680  1.0
  Co  Co9  1  0.912  0.323  0.320  1.0
  O  O10  1  0.051  0.101  0.872  1.0
  O  O11  1  0.347  0.732  0.958  1.0
  O  O12  1  0.145  0.304  0.550  1.0
  O  O13  1  0.247  0.472  0.223  1.0
  O  O14  1  0.481  0.906  0.672  1.0
  O  O15  1  0.519  0.094  0.328  1.0
  O  O16  1  0.753  0.528  0.777  1.0
  O  O17  1  0.855  0.696  0.450  1.0
  O  O18  1  0.653  0.268  0.042  1.0
  O  O19  1  0.949  0.899  0.128  1.0
[/CIF]
.