The structure described by Mn3(InN2)2 crystallizes in the monoclinic C2/c space group. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a distorted trigonal non-coplanar geometry to one In(1), one N(2), and two equivalent N(1) atoms. In the second Mn site, Mn(2) is bonded in a distorted tetrahedral geometry to two equivalent N(1) and two equivalent N(2) atoms. In(1) is bonded in a 4-coordinate geometry to one Mn(1) and three equivalent N(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Mn(2) and two equivalent Mn(1) atoms. In the second N site, N(2) is bonded to one Mn(1), one Mn(2), and three equivalent In(1) atoms to form a mixture of distorted corner and edge-sharing NMn2In3 trigonal bipyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mn3(InN2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.331
_cell_length_b   7.278
_cell_length_c   6.010
_cell_angle_alpha   90.000
_cell_angle_beta   72.067
_cell_angle_gamma   119.759
_symmetry_Int_Tables_number   1
_cell_volume   260.278
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.304  0.027  0.901  1.0
  Mn  Mn1  1  0.696  0.723  0.599  1.0
  Mn  Mn2  1  0.696  0.973  0.099  1.0
  Mn  Mn3  1  0.304  0.277  0.401  1.0
  Mn  Mn4  1  0.000  0.817  0.750  1.0
  Mn  Mn5  1  0.000  0.183  0.250  1.0
  In  In6  1  0.750  0.256  0.699  1.0
  In  In7  1  0.250  0.507  0.801  1.0
  In  In8  1  0.250  0.744  0.301  1.0
  In  In9  1  0.750  0.493  0.199  1.0
  N  N10  1  0.251  0.100  0.648  1.0
  N  N11  1  0.749  0.849  0.852  1.0
  N  N12  1  0.749  0.900  0.352  1.0
  N  N13  1  0.251  0.151  0.148  1.0
  N  N14  1  0.896  0.267  0.037  1.0
  N  N15  1  0.104  0.370  0.463  1.0
  N  N16  1  0.104  0.733  0.963  1.0
  N  N17  1  0.896  0.630  0.537  1.0
[/CIF]
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The structure described by Mn3(InN2)2 crystallizes in the monoclinic C2/c space group. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a distorted trigonal non-coplanar geometry to one In(1), one N(2), and two equivalent N(1) atoms. In the second Mn site, Mn(2) is bonded in a distorted tetrahedral geometry to two equivalent N(1) and two equivalent N(2) atoms. In(1) is bonded in a 4-coordinate geometry to one Mn(1) and three equivalent N(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Mn(2) and two equivalent Mn(1) atoms. In the second N site, N(2) is bonded to one Mn(1), one Mn(2), and three equivalent In(1) atoms to form a mixture of distorted corner and edge-sharing NMn2In3 trigonal bipyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mn3(InN2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.331
_cell_length_b   7.278
_cell_length_c   6.010
_cell_angle_alpha   90.000
_cell_angle_beta   72.067
_cell_angle_gamma   119.759
_symmetry_Int_Tables_number   1
_cell_volume   260.278
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.304  0.027  0.901  1.0
  Mn  Mn1  1  0.696  0.723  0.599  1.0
  Mn  Mn2  1  0.696  0.973  0.099  1.0
  Mn  Mn3  1  0.304  0.277  0.401  1.0
  Mn  Mn4  1  0.000  0.817  0.750  1.0
  Mn  Mn5  1  0.000  0.183  0.250  1.0
  In  In6  1  0.750  0.256  0.699  1.0
  In  In7  1  0.250  0.507  0.801  1.0
  In  In8  1  0.250  0.744  0.301  1.0
  In  In9  1  0.750  0.493  0.199  1.0
  N  N10  1  0.251  0.100  0.648  1.0
  N  N11  1  0.749  0.849  0.852  1.0
  N  N12  1  0.749  0.900  0.352  1.0
  N  N13  1  0.251  0.151  0.148  1.0
  N  N14  1  0.896  0.267  0.037  1.0
  N  N15  1  0.104  0.370  0.463  1.0
  N  N16  1  0.104  0.733  0.963  1.0
  N  N17  1  0.896  0.630  0.537  1.0
[/CIF]
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