The material structure described by Rb4NaW2N5O crystallizes in the triclinic P-1 space group. There are four inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 3-coordinate geometry to one N(3), one N(5), and one O(1) atom. In the second Rb site, Rb(2) is bonded in a 4-coordinate geometry to one N(5), two equivalent N(1), and one O(1) atom. In the third Rb site, Rb(3) is bonded in a 3-coordinate geometry to one N(2), one N(4), and one O(1) atom. In the fourth Rb site, Rb(4) is bonded in a 3-coordinate geometry to one N(3), one N(5), and one O(1) atom. Na(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one N(3) atom. There are two inequivalent W sites. In the first W site, W(1) is bonded in a distorted single-bond geometry to one N(5) atom. In the second W site, W(2) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one N(2), and one N(3) atom. There are five inequivalent N sites. In the first N site, N(1) is bonded in a 2-coordinate geometry to two equivalent Rb(2), one Na(1), and one W(2) atom. In the second N site, N(2) is bonded in a 3-coordinate geometry to one Rb(3), one W(2), and one N(4) atom. In the third N site, N(3) is bonded in a 4-coordinate geometry to one Rb(1), one Rb(4), one Na(1), and one W(2) atom. In the fourth N site, N(4) is bonded in a distorted single-bond geometry to one Rb(3), one N(2), and one O(1) atom. In the fifth N site, N(5) is bonded in a 4-coordinate geometry to one Rb(1), one Rb(2), one Rb(4), and one W(1) atom. O(1) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(2), one Rb(3), one Rb(4), and one N(4) atom. is represented by the CIF file [CIF]
data_Rb4NaW2N5O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.827
_cell_length_b   9.115
_cell_length_c   10.064
_cell_angle_alpha   81.893
_cell_angle_beta   65.715
_cell_angle_gamma   85.149
_symmetry_Int_Tables_number   1
_cell_volume   730.339
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.195  0.342  0.760  1.0
  Rb  Rb1  1  0.231  0.948  0.418  1.0
  Rb  Rb2  1  0.717  0.460  0.728  1.0
  Rb  Rb3  1  0.640  0.202  0.266  1.0
  Rb  Rb4  1  0.360  0.798  0.734  1.0
  Rb  Rb5  1  0.283  0.540  0.272  1.0
  Rb  Rb6  1  0.769  0.052  0.582  1.0
  Rb  Rb7  1  0.805  0.658  0.240  1.0
  Na  Na8  1  0.854  0.113  0.944  1.0
  Na  Na9  1  0.146  0.887  0.056  1.0
  W  W10  1  0.587  0.879  0.023  1.0
  W  W11  1  0.065  0.185  0.176  1.0
  W  W12  1  0.935  0.815  0.824  1.0
  W  W13  1  0.413  0.121  0.977  1.0
  N  N14  1  0.014  0.996  0.731  1.0
  N  N15  1  0.969  0.692  0.657  1.0
  N  N16  1  0.968  0.256  0.052  1.0
  N  N17  1  0.915  0.369  0.441  1.0
  N  N18  1  0.577  0.908  0.197  1.0
  N  N19  1  0.423  0.092  0.803  1.0
  N  N20  1  0.085  0.631  0.559  1.0
  N  N21  1  0.032  0.744  0.948  1.0
  N  N22  1  0.031  0.308  0.343  1.0
  N  N23  1  0.986  0.004  0.269  1.0
  O  O24  1  0.758  0.368  0.446  1.0
  O  O25  1  0.242  0.632  0.554  1.0
[/CIF]
.
The material structure described by Rb4NaW2N5O crystallizes in the triclinic P-1 space group. There are four inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 3-coordinate geometry to one N(3), one N(5), and one O(1) atom. In the second Rb site, Rb(2) is bonded in a 4-coordinate geometry to one N(5), two equivalent N(1), and one O(1) atom. In the third Rb site, Rb(3) is bonded in a 3-coordinate geometry to one N(2), one N(4), and one O(1) atom. In the fourth Rb site, Rb(4) is bonded in a 3-coordinate geometry to one N(3), one N(5), and one O(1) atom. Na(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one N(3) atom. There are two inequivalent W sites. In the first W site, W(1) is bonded in a distorted single-bond geometry to one N(5) atom. In the second W site, W(2) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one N(2), and one N(3) atom. There are five inequivalent N sites. In the first N site, N(1) is bonded in a 2-coordinate geometry to two equivalent Rb(2), one Na(1), and one W(2) atom. In the second N site, N(2) is bonded in a 3-coordinate geometry to one Rb(3), one W(2), and one N(4) atom. In the third N site, N(3) is bonded in a 4-coordinate geometry to one Rb(1), one Rb(4), one Na(1), and one W(2) atom. In the fourth N site, N(4) is bonded in a distorted single-bond geometry to one Rb(3), one N(2), and one O(1) atom. In the fifth N site, N(5) is bonded in a 4-coordinate geometry to one Rb(1), one Rb(2), one Rb(4), and one W(1) atom. O(1) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(2), one Rb(3), one Rb(4), and one N(4) atom. is represented by the CIF file [CIF]
data_Rb4NaW2N5O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.827
_cell_length_b   9.115
_cell_length_c   10.064
_cell_angle_alpha   81.893
_cell_angle_beta   65.715
_cell_angle_gamma   85.149
_symmetry_Int_Tables_number   1
_cell_volume   730.339
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.195  0.342  0.760  1.0
  Rb  Rb1  1  0.231  0.948  0.418  1.0
  Rb  Rb2  1  0.717  0.460  0.728  1.0
  Rb  Rb3  1  0.640  0.202  0.266  1.0
  Rb  Rb4  1  0.360  0.798  0.734  1.0
  Rb  Rb5  1  0.283  0.540  0.272  1.0
  Rb  Rb6  1  0.769  0.052  0.582  1.0
  Rb  Rb7  1  0.805  0.658  0.240  1.0
  Na  Na8  1  0.854  0.113  0.944  1.0
  Na  Na9  1  0.146  0.887  0.056  1.0
  W  W10  1  0.587  0.879  0.023  1.0
  W  W11  1  0.065  0.185  0.176  1.0
  W  W12  1  0.935  0.815  0.824  1.0
  W  W13  1  0.413  0.121  0.977  1.0
  N  N14  1  0.014  0.996  0.731  1.0
  N  N15  1  0.969  0.692  0.657  1.0
  N  N16  1  0.968  0.256  0.052  1.0
  N  N17  1  0.915  0.369  0.441  1.0
  N  N18  1  0.577  0.908  0.197  1.0
  N  N19  1  0.423  0.092  0.803  1.0
  N  N20  1  0.085  0.631  0.559  1.0
  N  N21  1  0.032  0.744  0.948  1.0
  N  N22  1  0.031  0.308  0.343  1.0
  N  N23  1  0.986  0.004  0.269  1.0
  O  O24  1  0.758  0.368  0.446  1.0
  O  O25  1  0.242  0.632  0.554  1.0
[/CIF]
.