The crystal structure described by MnTeO3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. Mn(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent O(1) and two equivalent O(2) atoms. Te(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form corner-sharing TeO6 octahedra. The corner-sharing octahedral tilt angles range from 46-50°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Mn(1) and two equivalent Te(1) atoms. In the second O site, O(2) is bonded to two equivalent Mn(1) and two equivalent Te(1) atoms to form distorted corner-sharing OMn2Te2 trigonal pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_MnTeO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.587
_cell_length_b   5.746
_cell_length_c   8.227
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   264.143
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.005  0.456  0.250  1.0
  Mn  Mn1  1  0.995  0.544  0.750  1.0
  Mn  Mn2  1  0.505  0.044  0.750  1.0
  Mn  Mn3  1  0.495  0.956  0.250  1.0
  Te  Te4  1  0.000  0.000  0.000  1.0
  Te  Te5  1  0.500  0.500  0.000  1.0
  Te  Te6  1  0.000  0.000  0.500  1.0
  Te  Te7  1  0.500  0.500  0.500  1.0
  O  O8  1  0.325  0.180  0.074  1.0
  O  O9  1  0.675  0.820  0.926  1.0
  O  O10  1  0.825  0.320  0.926  1.0
  O  O11  1  0.675  0.820  0.574  1.0
  O  O12  1  0.175  0.680  0.074  1.0
  O  O13  1  0.325  0.180  0.426  1.0
  O  O14  1  0.175  0.680  0.426  1.0
  O  O15  1  0.825  0.320  0.574  1.0
  O  O16  1  0.641  0.595  0.250  1.0
  O  O17  1  0.359  0.405  0.750  1.0
  O  O18  1  0.141  0.905  0.750  1.0
  O  O19  1  0.859  0.095  0.250  1.0
[/CIF]
.
The crystal structure described by MnTeO3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. Mn(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent O(1) and two equivalent O(2) atoms. Te(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form corner-sharing TeO6 octahedra. The corner-sharing octahedral tilt angles range from 46-50°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Mn(1) and two equivalent Te(1) atoms. In the second O site, O(2) is bonded to two equivalent Mn(1) and two equivalent Te(1) atoms to form distorted corner-sharing OMn2Te2 trigonal pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_MnTeO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.587
_cell_length_b   5.746
_cell_length_c   8.227
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   264.143
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.005  0.456  0.250  1.0
  Mn  Mn1  1  0.995  0.544  0.750  1.0
  Mn  Mn2  1  0.505  0.044  0.750  1.0
  Mn  Mn3  1  0.495  0.956  0.250  1.0
  Te  Te4  1  0.000  0.000  0.000  1.0
  Te  Te5  1  0.500  0.500  0.000  1.0
  Te  Te6  1  0.000  0.000  0.500  1.0
  Te  Te7  1  0.500  0.500  0.500  1.0
  O  O8  1  0.325  0.180  0.074  1.0
  O  O9  1  0.675  0.820  0.926  1.0
  O  O10  1  0.825  0.320  0.926  1.0
  O  O11  1  0.675  0.820  0.574  1.0
  O  O12  1  0.175  0.680  0.074  1.0
  O  O13  1  0.325  0.180  0.426  1.0
  O  O14  1  0.175  0.680  0.426  1.0
  O  O15  1  0.825  0.320  0.574  1.0
  O  O16  1  0.641  0.595  0.250  1.0
  O  O17  1  0.359  0.405  0.750  1.0
  O  O18  1  0.141  0.905  0.750  1.0
  O  O19  1  0.859  0.095  0.250  1.0
[/CIF]
.