The material structure described by Y6Pb8OF32 crystallizes in the trigonal R-3 space group. Y(1) is bonded in a 8-coordinate geometry to one F(1), one F(2), two equivalent F(3), two equivalent F(4), and two equivalent F(5) atoms. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 4-coordinate geometry to one O(1), one F(6), and three equivalent F(2) atoms. In the second Pb site, Pb(2) is bonded in a 7-coordinate geometry to one F(6), three equivalent F(1), and three equivalent F(4) atoms. O(1) is bonded to six equivalent Pb(1) atoms to form OPb6 octahedra that share faces with two equivalent F(6)Pb4 tetrahedra and faces with six equivalent F(2)YPb3 tetrahedra. There are six inequivalent F sites. In the first F site, F(1) is bonded in a distorted water-like geometry to one Y(1) and one Pb(2) atom. In the second F site, F(2) is bonded to one Y(1) and three equivalent Pb(1) atoms to form distorted FYPb3 tetrahedra that share  a cornercorner with one F(6)Pb4 tetrahedra, corners with two equivalent F(2)YPb3 tetrahedra,  an edgeedge with one F(6)Pb4 tetrahedra, edges with two equivalent F(2)YPb3 tetrahedra, and  a faceface with one O(1)Pb6 octahedra. In the third F site, F(3) is bonded in a bent 150 degrees geometry to two equivalent Y(1) atoms. In the fourth F site, F(4) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Y(1) and one Pb(2) atom. In the fifth F site, F(5) is bonded in a bent 150 degrees geometry to two equivalent Y(1) atoms. In the sixth F site, F(6) is bonded to one Pb(2) and three equivalent Pb(1) atoms to form distorted FPb4 tetrahedra that share corners with three equivalent F(2)YPb3 tetrahedra, edges with three equivalent F(2)YPb3 tetrahedra, and  a faceface with one O(1)Pb6 octahedra. is represented by the CIF file [CIF]
data_Y6Pb8OF32
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.308
_cell_length_b   9.308
_cell_length_c   9.308
_cell_angle_alpha   72.781
_cell_angle_beta   72.781
_cell_angle_gamma   72.781
_symmetry_Int_Tables_number   1
_cell_volume   716.302
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  1  0.526  0.840  0.391  1.0
  Y  Y1  1  0.474  0.160  0.609  1.0
  Y  Y2  1  0.609  0.474  0.160  1.0
  Y  Y3  1  0.840  0.391  0.526  1.0
  Y  Y4  1  0.160  0.609  0.474  1.0
  Y  Y5  1  0.391  0.526  0.840  1.0
  Pb  Pb6  1  0.901  0.044  0.290  1.0
  Pb  Pb7  1  0.290  0.901  0.044  1.0
  Pb  Pb8  1  0.710  0.099  0.956  1.0
  Pb  Pb9  1  0.099  0.956  0.710  1.0
  Pb  Pb10  1  0.263  0.263  0.263  1.0
  Pb  Pb11  1  0.956  0.710  0.099  1.0
  Pb  Pb12  1  0.737  0.737  0.737  1.0
  Pb  Pb13  1  0.044  0.290  0.901  1.0
  O  O14  1  0.000  0.000  0.000  1.0
  F  F15  1  0.820  0.549  0.977  1.0
  F  F16  1  0.262  0.080  0.786  1.0
  F  F17  1  0.303  0.787  0.408  1.0
  F  F18  1  0.490  0.357  0.046  1.0
  F  F19  1  0.080  0.786  0.262  1.0
  F  F20  1  0.268  0.353  0.548  1.0
  F  F21  1  0.452  0.732  0.647  1.0
  F  F22  1  0.647  0.452  0.732  1.0
  F  F23  1  0.353  0.548  0.268  1.0
  F  F24  1  0.860  0.860  0.860  1.0
  F  F25  1  0.180  0.451  0.023  1.0
  F  F26  1  0.787  0.408  0.303  1.0
  F  F27  1  0.357  0.046  0.490  1.0
  F  F28  1  0.549  0.977  0.820  1.0
  F  F29  1  0.213  0.592  0.697  1.0
  F  F30  1  0.214  0.738  0.920  1.0
  F  F31  1  0.977  0.820  0.549  1.0
  F  F32  1  0.046  0.490  0.357  1.0
  F  F33  1  0.738  0.920  0.214  1.0
  F  F34  1  0.643  0.954  0.510  1.0
  F  F35  1  0.408  0.303  0.787  1.0
  F  F36  1  0.954  0.510  0.643  1.0
  F  F37  1  0.510  0.643  0.954  1.0
  F  F38  1  0.732  0.647  0.452  1.0
  F  F39  1  0.592  0.697  0.213  1.0
  F  F40  1  0.548  0.268  0.353  1.0
  F  F41  1  0.451  0.023  0.180  1.0
  F  F42  1  0.023  0.180  0.451  1.0
  F  F43  1  0.786  0.262  0.080  1.0
  F  F44  1  0.140  0.140  0.140  1.0
  F  F45  1  0.697  0.213  0.592  1.0
  F  F46  1  0.920  0.214  0.738  1.0
[/CIF]
.
The material structure described by Y6Pb8OF32 crystallizes in the trigonal R-3 space group. Y(1) is bonded in a 8-coordinate geometry to one F(1), one F(2), two equivalent F(3), two equivalent F(4), and two equivalent F(5) atoms. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 4-coordinate geometry to one O(1), one F(6), and three equivalent F(2) atoms. In the second Pb site, Pb(2) is bonded in a 7-coordinate geometry to one F(6), three equivalent F(1), and three equivalent F(4) atoms. O(1) is bonded to six equivalent Pb(1) atoms to form OPb6 octahedra that share faces with two equivalent F(6)Pb4 tetrahedra and faces with six equivalent F(2)YPb3 tetrahedra. There are six inequivalent F sites. In the first F site, F(1) is bonded in a distorted water-like geometry to one Y(1) and one Pb(2) atom. In the second F site, F(2) is bonded to one Y(1) and three equivalent Pb(1) atoms to form distorted FYPb3 tetrahedra that share  a cornercorner with one F(6)Pb4 tetrahedra, corners with two equivalent F(2)YPb3 tetrahedra,  an edgeedge with one F(6)Pb4 tetrahedra, edges with two equivalent F(2)YPb3 tetrahedra, and  a faceface with one O(1)Pb6 octahedra. In the third F site, F(3) is bonded in a bent 150 degrees geometry to two equivalent Y(1) atoms. In the fourth F site, F(4) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Y(1) and one Pb(2) atom. In the fifth F site, F(5) is bonded in a bent 150 degrees geometry to two equivalent Y(1) atoms. In the sixth F site, F(6) is bonded to one Pb(2) and three equivalent Pb(1) atoms to form distorted FPb4 tetrahedra that share corners with three equivalent F(2)YPb3 tetrahedra, edges with three equivalent F(2)YPb3 tetrahedra, and  a faceface with one O(1)Pb6 octahedra. is represented by the CIF file [CIF]
data_Y6Pb8OF32
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.308
_cell_length_b   9.308
_cell_length_c   9.308
_cell_angle_alpha   72.781
_cell_angle_beta   72.781
_cell_angle_gamma   72.781
_symmetry_Int_Tables_number   1
_cell_volume   716.302
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  1  0.526  0.840  0.391  1.0
  Y  Y1  1  0.474  0.160  0.609  1.0
  Y  Y2  1  0.609  0.474  0.160  1.0
  Y  Y3  1  0.840  0.391  0.526  1.0
  Y  Y4  1  0.160  0.609  0.474  1.0
  Y  Y5  1  0.391  0.526  0.840  1.0
  Pb  Pb6  1  0.901  0.044  0.290  1.0
  Pb  Pb7  1  0.290  0.901  0.044  1.0
  Pb  Pb8  1  0.710  0.099  0.956  1.0
  Pb  Pb9  1  0.099  0.956  0.710  1.0
  Pb  Pb10  1  0.263  0.263  0.263  1.0
  Pb  Pb11  1  0.956  0.710  0.099  1.0
  Pb  Pb12  1  0.737  0.737  0.737  1.0
  Pb  Pb13  1  0.044  0.290  0.901  1.0
  O  O14  1  0.000  0.000  0.000  1.0
  F  F15  1  0.820  0.549  0.977  1.0
  F  F16  1  0.262  0.080  0.786  1.0
  F  F17  1  0.303  0.787  0.408  1.0
  F  F18  1  0.490  0.357  0.046  1.0
  F  F19  1  0.080  0.786  0.262  1.0
  F  F20  1  0.268  0.353  0.548  1.0
  F  F21  1  0.452  0.732  0.647  1.0
  F  F22  1  0.647  0.452  0.732  1.0
  F  F23  1  0.353  0.548  0.268  1.0
  F  F24  1  0.860  0.860  0.860  1.0
  F  F25  1  0.180  0.451  0.023  1.0
  F  F26  1  0.787  0.408  0.303  1.0
  F  F27  1  0.357  0.046  0.490  1.0
  F  F28  1  0.549  0.977  0.820  1.0
  F  F29  1  0.213  0.592  0.697  1.0
  F  F30  1  0.214  0.738  0.920  1.0
  F  F31  1  0.977  0.820  0.549  1.0
  F  F32  1  0.046  0.490  0.357  1.0
  F  F33  1  0.738  0.920  0.214  1.0
  F  F34  1  0.643  0.954  0.510  1.0
  F  F35  1  0.408  0.303  0.787  1.0
  F  F36  1  0.954  0.510  0.643  1.0
  F  F37  1  0.510  0.643  0.954  1.0
  F  F38  1  0.732  0.647  0.452  1.0
  F  F39  1  0.592  0.697  0.213  1.0
  F  F40  1  0.548  0.268  0.353  1.0
  F  F41  1  0.451  0.023  0.180  1.0
  F  F42  1  0.023  0.180  0.451  1.0
  F  F43  1  0.786  0.262  0.080  1.0
  F  F44  1  0.140  0.140  0.140  1.0
  F  F45  1  0.697  0.213  0.592  1.0
  F  F46  1  0.920  0.214  0.738  1.0
[/CIF]
.