The structure described by Cs3SbO3 is Calaverite-derived structured and crystallizes in the cubic P2_13 space group. There are three inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. In the second Cs site, Cs(2) is bonded in a distorted T-shaped geometry to three equivalent O(1) atoms. In the third Cs site, Cs(3) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. Sb(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent O(1) atoms. O(1) is bonded in a 6-coordinate geometry to one Cs(2), two equivalent Cs(1), two equivalent Cs(3), and one Sb(1) atom. is represented by the CIF card [CIF]
data_Cs3SbO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.202
_cell_length_b   9.202
_cell_length_c   9.202
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   779.254
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.278  0.722  0.222  1.0
  Cs  Cs1  1  0.483  0.983  0.517  1.0
  Cs  Cs2  1  0.222  0.278  0.722  1.0
  Cs  Cs3  1  0.017  0.017  0.017  1.0
  Cs  Cs4  1  0.773  0.227  0.727  1.0
  Cs  Cs5  1  0.727  0.773  0.227  1.0
  Cs  Cs6  1  0.517  0.483  0.983  1.0
  Cs  Cs7  1  0.983  0.517  0.483  1.0
  Cs  Cs8  1  0.227  0.727  0.773  1.0
  Cs  Cs9  1  0.722  0.222  0.278  1.0
  Cs  Cs10  1  0.778  0.778  0.778  1.0
  Cs  Cs11  1  0.273  0.273  0.273  1.0
  Sb  Sb12  1  0.503  0.503  0.503  1.0
  Sb  Sb13  1  0.997  0.497  0.003  1.0
  Sb  Sb14  1  0.497  0.003  0.997  1.0
  Sb  Sb15  1  0.003  0.997  0.497  1.0
  O  O16  1  0.462  0.005  0.206  1.0
  O  O17  1  0.706  0.038  0.995  1.0
  O  O18  1  0.005  0.206  0.462  1.0
  O  O19  1  0.962  0.495  0.794  1.0
  O  O20  1  0.038  0.995  0.706  1.0
  O  O21  1  0.495  0.794  0.962  1.0
  O  O22  1  0.794  0.962  0.495  1.0
  O  O23  1  0.206  0.462  0.005  1.0
  O  O24  1  0.995  0.706  0.038  1.0
  O  O25  1  0.538  0.505  0.294  1.0
  O  O26  1  0.294  0.538  0.505  1.0
  O  O27  1  0.505  0.294  0.538  1.0
[/CIF]
.
The structure described by Cs3SbO3 is Calaverite-derived structured and crystallizes in the cubic P2_13 space group. There are three inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. In the second Cs site, Cs(2) is bonded in a distorted T-shaped geometry to three equivalent O(1) atoms. In the third Cs site, Cs(3) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. Sb(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent O(1) atoms. O(1) is bonded in a 6-coordinate geometry to one Cs(2), two equivalent Cs(1), two equivalent Cs(3), and one Sb(1) atom. is represented by the CIF card [CIF]
data_Cs3SbO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.202
_cell_length_b   9.202
_cell_length_c   9.202
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   779.254
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.278  0.722  0.222  1.0
  Cs  Cs1  1  0.483  0.983  0.517  1.0
  Cs  Cs2  1  0.222  0.278  0.722  1.0
  Cs  Cs3  1  0.017  0.017  0.017  1.0
  Cs  Cs4  1  0.773  0.227  0.727  1.0
  Cs  Cs5  1  0.727  0.773  0.227  1.0
  Cs  Cs6  1  0.517  0.483  0.983  1.0
  Cs  Cs7  1  0.983  0.517  0.483  1.0
  Cs  Cs8  1  0.227  0.727  0.773  1.0
  Cs  Cs9  1  0.722  0.222  0.278  1.0
  Cs  Cs10  1  0.778  0.778  0.778  1.0
  Cs  Cs11  1  0.273  0.273  0.273  1.0
  Sb  Sb12  1  0.503  0.503  0.503  1.0
  Sb  Sb13  1  0.997  0.497  0.003  1.0
  Sb  Sb14  1  0.497  0.003  0.997  1.0
  Sb  Sb15  1  0.003  0.997  0.497  1.0
  O  O16  1  0.462  0.005  0.206  1.0
  O  O17  1  0.706  0.038  0.995  1.0
  O  O18  1  0.005  0.206  0.462  1.0
  O  O19  1  0.962  0.495  0.794  1.0
  O  O20  1  0.038  0.995  0.706  1.0
  O  O21  1  0.495  0.794  0.962  1.0
  O  O22  1  0.794  0.962  0.495  1.0
  O  O23  1  0.206  0.462  0.005  1.0
  O  O24  1  0.995  0.706  0.038  1.0
  O  O25  1  0.538  0.505  0.294  1.0
  O  O26  1  0.294  0.538  0.505  1.0
  O  O27  1  0.505  0.294  0.538  1.0
[/CIF]
.