The material structure described by NaAuO2 crystallizes in the monoclinic C2/m space group. Na(1) is bonded to six equivalent O(1) atoms to form edge-sharing NaO6 octahedra. Au(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. O(1) is bonded to three equivalent Na(1) and two equivalent Au(1) atoms to form a mixture of distorted corner and edge-sharing ONa3Au2 trigonal bipyramids. is represented by the CIF file [CIF]
data_NaAuO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.022
_cell_length_b   3.596
_cell_length_c   5.601
_cell_angle_alpha   79.872
_cell_angle_beta   74.348
_cell_angle_gamma   65.150
_symmetry_Int_Tables_number   1
_cell_volume   53.037
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.500  0.500  0.500  1.0
  Au  Au1  1  0.500  0.000  0.000  1.0
  O  O2  1  0.090  0.069  0.752  1.0
  O  O3  1  0.910  0.931  0.248  1.0
[/CIF]
.
The material structure described by NaAuO2 crystallizes in the monoclinic C2/m space group. Na(1) is bonded to six equivalent O(1) atoms to form edge-sharing NaO6 octahedra. Au(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. O(1) is bonded to three equivalent Na(1) and two equivalent Au(1) atoms to form a mixture of distorted corner and edge-sharing ONa3Au2 trigonal bipyramids. is represented by the CIF file [CIF]
data_NaAuO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.022
_cell_length_b   3.596
_cell_length_c   5.601
_cell_angle_alpha   79.872
_cell_angle_beta   74.348
_cell_angle_gamma   65.150
_symmetry_Int_Tables_number   1
_cell_volume   53.037
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.500  0.500  0.500  1.0
  Au  Au1  1  0.500  0.000  0.000  1.0
  O  O2  1  0.090  0.069  0.752  1.0
  O  O3  1  0.910  0.931  0.248  1.0
[/CIF]
.