The structure described by PN3S2(OCl2)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four PN3S2(OCl2)2 clusters. P(1) is bonded to one N(1), one N(2), one Cl(2), and one Cl(4) atom to form PN2Cl2 tetrahedra that share  a cornercorner with one S(1)N2ClO tetrahedra and  a cornercorner with one S(2)N2ClO tetrahedra. There are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one P(1) and one S(1) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one P(1) and one S(2) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded to one N(1), one N(3), one O(2), and one Cl(1) atom to form distorted SN2ClO tetrahedra that share  a cornercorner with one P(1)N2Cl2 tetrahedra and  a cornercorner with one S(2)N2ClO tetrahedra. In the second S site, S(2) is bonded to one N(2), one N(3), one O(1), and one Cl(3) atom to form distorted SN2ClO tetrahedra that share  a cornercorner with one P(1)N2Cl2 tetrahedra and  a cornercorner with one S(1)N2ClO tetrahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one S(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one P(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one S(2) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_PS2N3(Cl2O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.059
_cell_length_b   11.514
_cell_length_c   15.077
_cell_angle_alpha   52.789
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1114.151
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.158  0.122  0.829  1.0
  P  P1  1  0.342  0.122  0.329  1.0
  P  P2  1  0.658  0.878  0.671  1.0
  P  P3  1  0.842  0.878  0.171  1.0
  S  S4  1  0.581  0.688  0.279  1.0
  S  S5  1  0.642  0.810  0.057  1.0
  S  S6  1  0.358  0.190  0.943  1.0
  S  S7  1  0.142  0.190  0.443  1.0
  S  S8  1  0.919  0.688  0.779  1.0
  S  S9  1  0.858  0.810  0.557  1.0
  S  S10  1  0.081  0.312  0.221  1.0
  S  S11  1  0.419  0.312  0.721  1.0
  N  N12  1  0.211  0.208  0.228  1.0
  N  N13  1  0.289  0.105  0.440  1.0
  N  N14  1  0.020  0.267  0.338  1.0
  N  N15  1  0.789  0.895  0.060  1.0
  N  N16  1  0.789  0.792  0.772  1.0
  N  N17  1  0.211  0.105  0.940  1.0
  N  N18  1  0.980  0.733  0.662  1.0
  N  N19  1  0.711  0.792  0.272  1.0
  N  N20  1  0.480  0.267  0.838  1.0
  N  N21  1  0.520  0.733  0.162  1.0
  N  N22  1  0.289  0.208  0.728  1.0
  N  N23  1  0.711  0.895  0.560  1.0
  Cl  Cl24  1  0.201  0.511  0.144  1.0
  Cl  Cl25  1  0.874  0.074  0.132  1.0
  Cl  Cl26  1  0.249  0.358  0.435  1.0
  Cl  Cl27  1  0.126  0.926  0.868  1.0
  Cl  Cl28  1  0.626  0.074  0.632  1.0
  Cl  Cl29  1  0.565  0.215  0.278  1.0
  Cl  Cl30  1  0.435  0.785  0.722  1.0
  Cl  Cl31  1  0.799  0.489  0.856  1.0
  Cl  Cl32  1  0.251  0.358  0.935  1.0
  Cl  Cl33  1  0.299  0.511  0.644  1.0
  Cl  Cl34  1  0.065  0.785  0.222  1.0
  Cl  Cl35  1  0.935  0.215  0.778  1.0
  Cl  Cl36  1  0.751  0.642  0.565  1.0
  Cl  Cl37  1  0.749  0.642  0.065  1.0
  Cl  Cl38  1  0.374  0.926  0.368  1.0
  Cl  Cl39  1  0.701  0.489  0.356  1.0
  O  O40  1  0.049  0.108  0.544  1.0
  O  O41  1  0.559  0.340  0.652  1.0
  O  O42  1  0.941  0.340  0.152  1.0
  O  O43  1  0.059  0.660  0.848  1.0
  O  O44  1  0.549  0.892  0.956  1.0
  O  O45  1  0.951  0.892  0.456  1.0
  O  O46  1  0.441  0.660  0.348  1.0
  O  O47  1  0.451  0.108  0.044  1.0
[/CIF]
.
The structure described by PN3S2(OCl2)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four PN3S2(OCl2)2 clusters. P(1) is bonded to one N(1), one N(2), one Cl(2), and one Cl(4) atom to form PN2Cl2 tetrahedra that share  a cornercorner with one S(1)N2ClO tetrahedra and  a cornercorner with one S(2)N2ClO tetrahedra. There are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one P(1) and one S(1) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one P(1) and one S(2) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded to one N(1), one N(3), one O(2), and one Cl(1) atom to form distorted SN2ClO tetrahedra that share  a cornercorner with one P(1)N2Cl2 tetrahedra and  a cornercorner with one S(2)N2ClO tetrahedra. In the second S site, S(2) is bonded to one N(2), one N(3), one O(1), and one Cl(3) atom to form distorted SN2ClO tetrahedra that share  a cornercorner with one P(1)N2Cl2 tetrahedra and  a cornercorner with one S(1)N2ClO tetrahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one S(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one P(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one S(2) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_PS2N3(Cl2O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.059
_cell_length_b   11.514
_cell_length_c   15.077
_cell_angle_alpha   52.789
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1114.151
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.158  0.122  0.829  1.0
  P  P1  1  0.342  0.122  0.329  1.0
  P  P2  1  0.658  0.878  0.671  1.0
  P  P3  1  0.842  0.878  0.171  1.0
  S  S4  1  0.581  0.688  0.279  1.0
  S  S5  1  0.642  0.810  0.057  1.0
  S  S6  1  0.358  0.190  0.943  1.0
  S  S7  1  0.142  0.190  0.443  1.0
  S  S8  1  0.919  0.688  0.779  1.0
  S  S9  1  0.858  0.810  0.557  1.0
  S  S10  1  0.081  0.312  0.221  1.0
  S  S11  1  0.419  0.312  0.721  1.0
  N  N12  1  0.211  0.208  0.228  1.0
  N  N13  1  0.289  0.105  0.440  1.0
  N  N14  1  0.020  0.267  0.338  1.0
  N  N15  1  0.789  0.895  0.060  1.0
  N  N16  1  0.789  0.792  0.772  1.0
  N  N17  1  0.211  0.105  0.940  1.0
  N  N18  1  0.980  0.733  0.662  1.0
  N  N19  1  0.711  0.792  0.272  1.0
  N  N20  1  0.480  0.267  0.838  1.0
  N  N21  1  0.520  0.733  0.162  1.0
  N  N22  1  0.289  0.208  0.728  1.0
  N  N23  1  0.711  0.895  0.560  1.0
  Cl  Cl24  1  0.201  0.511  0.144  1.0
  Cl  Cl25  1  0.874  0.074  0.132  1.0
  Cl  Cl26  1  0.249  0.358  0.435  1.0
  Cl  Cl27  1  0.126  0.926  0.868  1.0
  Cl  Cl28  1  0.626  0.074  0.632  1.0
  Cl  Cl29  1  0.565  0.215  0.278  1.0
  Cl  Cl30  1  0.435  0.785  0.722  1.0
  Cl  Cl31  1  0.799  0.489  0.856  1.0
  Cl  Cl32  1  0.251  0.358  0.935  1.0
  Cl  Cl33  1  0.299  0.511  0.644  1.0
  Cl  Cl34  1  0.065  0.785  0.222  1.0
  Cl  Cl35  1  0.935  0.215  0.778  1.0
  Cl  Cl36  1  0.751  0.642  0.565  1.0
  Cl  Cl37  1  0.749  0.642  0.065  1.0
  Cl  Cl38  1  0.374  0.926  0.368  1.0
  Cl  Cl39  1  0.701  0.489  0.356  1.0
  O  O40  1  0.049  0.108  0.544  1.0
  O  O41  1  0.559  0.340  0.652  1.0
  O  O42  1  0.941  0.340  0.152  1.0
  O  O43  1  0.059  0.660  0.848  1.0
  O  O44  1  0.549  0.892  0.956  1.0
  O  O45  1  0.951  0.892  0.456  1.0
  O  O46  1  0.441  0.660  0.348  1.0
  O  O47  1  0.451  0.108  0.044  1.0
[/CIF]
.