The structure described by CON4S4OCl is Indium-derived structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of four formaldehyde molecules and four N4S4OCl clusters. In each N4S4OCl cluster, there are four inequivalent N sites. In the first N site, N(4) is bonded in a bent 120 degrees geometry to one S(2) and one S(3) atom. In the second N site, N(1) is bonded in a bent 120 degrees geometry to one S(1) and one S(3) atom. In the third N site, N(2) is bonded in a bent 120 degrees geometry to one S(1) and one S(4) atom. In the fourth N site, N(3) is bonded in a bent 120 degrees geometry to one S(2) and one S(4) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a bent 120 degrees geometry to one N(1) and one N(2) atom. In the second S site, S(2) is bonded in a bent 120 degrees geometry to one N(3) and one N(4) atom. In the third S site, S(3) is bonded in a water-like geometry to one N(1) and one N(4) atom. In the fourth S site, S(4) is bonded in a distorted tetrahedral geometry to one N(2), one N(3), one O(1), and one Cl(1) atom. O(1) is bonded in a single-bond geometry to one S(4) atom. Cl(1) is bonded in a single-bond geometry to one S(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CS4N4ClO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.607
_cell_length_b   11.200
_cell_length_c   15.802
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1169.326
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  C  C0  1  0.642  0.789  0.802  1.0
  C  C1  1  0.858  0.211  0.302  1.0
  C  C2  1  0.142  0.711  0.198  1.0
  C  C3  1  0.358  0.289  0.698  1.0
  S  S4  1  0.222  0.436  0.914  1.0
  S  S5  1  0.278  0.564  0.414  1.0
  S  S6  1  0.722  0.064  0.086  1.0
  S  S7  1  0.778  0.936  0.586  1.0
  S  S8  1  0.929  0.293  0.889  1.0
  S  S9  1  0.571  0.707  0.389  1.0
  S  S10  1  0.429  0.207  0.111  1.0
  S  S11  1  0.071  0.793  0.611  1.0
  S  S12  1  0.943  0.499  0.785  1.0
  S  S13  1  0.557  0.501  0.285  1.0
  S  S14  1  0.443  0.001  0.215  1.0
  S  S15  1  0.057  0.999  0.715  1.0
  S  S16  1  0.910  0.440  0.034  1.0
  S  S17  1  0.590  0.560  0.534  1.0
  S  S18  1  0.410  0.060  0.966  1.0
  S  S19  1  0.090  0.940  0.466  1.0
  N  N20  1  0.156  0.516  0.835  1.0
  N  N21  1  0.344  0.484  0.335  1.0
  N  N22  1  0.656  0.984  0.165  1.0
  N  N23  1  0.844  0.016  0.665  1.0
  N  N24  1  0.132  0.475  0.006  1.0
  N  N25  1  0.368  0.525  0.506  1.0
  N  N26  1  0.632  0.025  0.994  1.0
  N  N27  1  0.868  0.975  0.494  1.0
  N  N28  1  0.823  0.335  0.978  1.0
  N  N29  1  0.677  0.665  0.478  1.0
  N  N30  1  0.323  0.165  0.022  1.0
  N  N31  1  0.177  0.835  0.522  1.0
  N  N32  1  0.863  0.364  0.805  1.0
  N  N33  1  0.637  0.636  0.305  1.0
  N  N34  1  0.363  0.136  0.195  1.0
  N  N35  1  0.137  0.864  0.695  1.0
  Cl  Cl36  1  0.727  0.590  0.013  1.0
  Cl  Cl37  1  0.773  0.410  0.513  1.0
  Cl  Cl38  1  0.227  0.910  0.987  1.0
  Cl  Cl39  1  0.273  0.090  0.487  1.0
  O  O40  1  0.890  0.419  0.123  1.0
  O  O41  1  0.610  0.581  0.623  1.0
  O  O42  1  0.390  0.081  0.877  1.0
  O  O43  1  0.110  0.919  0.377  1.0
  O  O44  1  0.578  0.707  0.835  1.0
  O  O45  1  0.922  0.293  0.335  1.0
  O  O46  1  0.078  0.793  0.165  1.0
  O  O47  1  0.422  0.207  0.665  1.0
[/CIF]
.
The structure described by CON4S4OCl is Indium-derived structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of four formaldehyde molecules and four N4S4OCl clusters. In each N4S4OCl cluster, there are four inequivalent N sites. In the first N site, N(4) is bonded in a bent 120 degrees geometry to one S(2) and one S(3) atom. In the second N site, N(1) is bonded in a bent 120 degrees geometry to one S(1) and one S(3) atom. In the third N site, N(2) is bonded in a bent 120 degrees geometry to one S(1) and one S(4) atom. In the fourth N site, N(3) is bonded in a bent 120 degrees geometry to one S(2) and one S(4) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a bent 120 degrees geometry to one N(1) and one N(2) atom. In the second S site, S(2) is bonded in a bent 120 degrees geometry to one N(3) and one N(4) atom. In the third S site, S(3) is bonded in a water-like geometry to one N(1) and one N(4) atom. In the fourth S site, S(4) is bonded in a distorted tetrahedral geometry to one N(2), one N(3), one O(1), and one Cl(1) atom. O(1) is bonded in a single-bond geometry to one S(4) atom. Cl(1) is bonded in a single-bond geometry to one S(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CS4N4ClO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.607
_cell_length_b   11.200
_cell_length_c   15.802
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1169.326
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  C  C0  1  0.642  0.789  0.802  1.0
  C  C1  1  0.858  0.211  0.302  1.0
  C  C2  1  0.142  0.711  0.198  1.0
  C  C3  1  0.358  0.289  0.698  1.0
  S  S4  1  0.222  0.436  0.914  1.0
  S  S5  1  0.278  0.564  0.414  1.0
  S  S6  1  0.722  0.064  0.086  1.0
  S  S7  1  0.778  0.936  0.586  1.0
  S  S8  1  0.929  0.293  0.889  1.0
  S  S9  1  0.571  0.707  0.389  1.0
  S  S10  1  0.429  0.207  0.111  1.0
  S  S11  1  0.071  0.793  0.611  1.0
  S  S12  1  0.943  0.499  0.785  1.0
  S  S13  1  0.557  0.501  0.285  1.0
  S  S14  1  0.443  0.001  0.215  1.0
  S  S15  1  0.057  0.999  0.715  1.0
  S  S16  1  0.910  0.440  0.034  1.0
  S  S17  1  0.590  0.560  0.534  1.0
  S  S18  1  0.410  0.060  0.966  1.0
  S  S19  1  0.090  0.940  0.466  1.0
  N  N20  1  0.156  0.516  0.835  1.0
  N  N21  1  0.344  0.484  0.335  1.0
  N  N22  1  0.656  0.984  0.165  1.0
  N  N23  1  0.844  0.016  0.665  1.0
  N  N24  1  0.132  0.475  0.006  1.0
  N  N25  1  0.368  0.525  0.506  1.0
  N  N26  1  0.632  0.025  0.994  1.0
  N  N27  1  0.868  0.975  0.494  1.0
  N  N28  1  0.823  0.335  0.978  1.0
  N  N29  1  0.677  0.665  0.478  1.0
  N  N30  1  0.323  0.165  0.022  1.0
  N  N31  1  0.177  0.835  0.522  1.0
  N  N32  1  0.863  0.364  0.805  1.0
  N  N33  1  0.637  0.636  0.305  1.0
  N  N34  1  0.363  0.136  0.195  1.0
  N  N35  1  0.137  0.864  0.695  1.0
  Cl  Cl36  1  0.727  0.590  0.013  1.0
  Cl  Cl37  1  0.773  0.410  0.513  1.0
  Cl  Cl38  1  0.227  0.910  0.987  1.0
  Cl  Cl39  1  0.273  0.090  0.487  1.0
  O  O40  1  0.890  0.419  0.123  1.0
  O  O41  1  0.610  0.581  0.623  1.0
  O  O42  1  0.390  0.081  0.877  1.0
  O  O43  1  0.110  0.919  0.377  1.0
  O  O44  1  0.578  0.707  0.835  1.0
  O  O45  1  0.922  0.293  0.335  1.0
  O  O46  1  0.078  0.793  0.165  1.0
  O  O47  1  0.422  0.207  0.665  1.0
[/CIF]
.