The compound described by TlWSbO6 crystallizes in the orthorhombic Ima2 space group. The structure consists of four 7440-28-0 atoms inside a WSbO6 framework. In the WSbO6 framework, W(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form WO6 octahedra that share corners with two equivalent W(1)O6 octahedra and corners with four equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 36-41°. Sb(1) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form SbO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra and corners with four equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-47°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to two equivalent W(1) atoms. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to two equivalent Sb(1) atoms. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one W(1) and one Sb(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one W(1) and one Sb(1) atom. is represented by the CIF card [CIF]
data_TlSbWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.383
_cell_length_b   7.383
_cell_length_c   7.383
_cell_angle_alpha   120.630
_cell_angle_beta   119.682
_cell_angle_gamma   89.733
_symmetry_Int_Tables_number   1
_cell_volume   283.822
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.709  0.902  0.307  1.0
  Tl  Tl1  1  0.404  0.098  0.807  1.0
  Sb  Sb2  1  0.001  0.000  0.001  1.0
  Sb  Sb3  1  0.001  0.500  0.501  1.0
  W  W4  1  0.501  0.498  0.503  1.0
  W  W5  1  0.005  0.502  0.003  1.0
  O  O6  1  0.692  0.442  0.750  1.0
  O  O7  1  0.072  0.825  0.747  1.0
  O  O8  1  0.063  0.433  0.752  1.0
  O  O9  1  0.680  0.812  0.746  1.0
  O  O10  1  0.063  0.811  0.131  1.0
  O  O11  1  0.680  0.434  0.368  1.0
  O  O12  1  0.309  0.558  0.250  1.0
  O  O13  1  0.922  0.175  0.247  1.0
  O  O14  1  0.934  0.566  0.246  1.0
  O  O15  1  0.320  0.189  0.252  1.0
  O  O16  1  0.934  0.188  0.868  1.0
  O  O17  1  0.320  0.567  0.631  1.0
[/CIF]
.
The compound described by TlWSbO6 crystallizes in the orthorhombic Ima2 space group. The structure consists of four 7440-28-0 atoms inside a WSbO6 framework. In the WSbO6 framework, W(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form WO6 octahedra that share corners with two equivalent W(1)O6 octahedra and corners with four equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 36-41°. Sb(1) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form SbO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra and corners with four equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-47°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to two equivalent W(1) atoms. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to two equivalent Sb(1) atoms. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one W(1) and one Sb(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one W(1) and one Sb(1) atom. is represented by the CIF card [CIF]
data_TlSbWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.383
_cell_length_b   7.383
_cell_length_c   7.383
_cell_angle_alpha   120.630
_cell_angle_beta   119.682
_cell_angle_gamma   89.733
_symmetry_Int_Tables_number   1
_cell_volume   283.822
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.709  0.902  0.307  1.0
  Tl  Tl1  1  0.404  0.098  0.807  1.0
  Sb  Sb2  1  0.001  0.000  0.001  1.0
  Sb  Sb3  1  0.001  0.500  0.501  1.0
  W  W4  1  0.501  0.498  0.503  1.0
  W  W5  1  0.005  0.502  0.003  1.0
  O  O6  1  0.692  0.442  0.750  1.0
  O  O7  1  0.072  0.825  0.747  1.0
  O  O8  1  0.063  0.433  0.752  1.0
  O  O9  1  0.680  0.812  0.746  1.0
  O  O10  1  0.063  0.811  0.131  1.0
  O  O11  1  0.680  0.434  0.368  1.0
  O  O12  1  0.309  0.558  0.250  1.0
  O  O13  1  0.922  0.175  0.247  1.0
  O  O14  1  0.934  0.566  0.246  1.0
  O  O15  1  0.320  0.189  0.252  1.0
  O  O16  1  0.934  0.188  0.868  1.0
  O  O17  1  0.320  0.567  0.631  1.0
[/CIF]
.