The crystal structure described by Eu3Rh4Pb13 crystallizes in the cubic Pm-3n space group. Eu(1) is bonded in a 16-coordinate geometry to four equivalent Rh(1) and twelve equivalent Pb(2) atoms. Rh(1) is bonded in a 9-coordinate geometry to three equivalent Eu(1) and six equivalent Pb(2) atoms. There are two inequivalent Pb sites. In the first Pb site, Pb(2) is bonded in a 9-coordinate geometry to three equivalent Eu(1), two equivalent Rh(1), one Pb(1), and three equivalent Pb(2) atoms. In the second Pb site, Pb(1) is bonded in a cuboctahedral geometry to twelve equivalent Pb(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Eu3Rh4Pb13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.232
_cell_length_b   10.232
_cell_length_c   10.232
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1071.087
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Eu  Eu0  1  0.000  0.500  0.750  1.0
  Eu  Eu1  1  0.500  0.250  0.000  1.0
  Eu  Eu2  1  0.750  0.000  0.500  1.0
  Eu  Eu3  1  0.000  0.500  0.250  1.0
  Eu  Eu4  1  0.500  0.750  0.000  1.0
  Eu  Eu5  1  0.250  0.000  0.500  1.0
  Rh  Rh6  1  0.750  0.250  0.750  1.0
  Rh  Rh7  1  0.250  0.750  0.250  1.0
  Rh  Rh8  1  0.750  0.750  0.250  1.0
  Rh  Rh9  1  0.250  0.250  0.750  1.0
  Rh  Rh10  1  0.250  0.750  0.750  1.0
  Rh  Rh11  1  0.750  0.250  0.250  1.0
  Rh  Rh12  1  0.250  0.250  0.250  1.0
  Rh  Rh13  1  0.750  0.750  0.750  1.0
  Pb  Pb14  1  0.500  0.500  0.500  1.0
  Pb  Pb15  1  0.000  0.000  0.000  1.0
  Pb  Pb16  1  0.806  0.345  0.500  1.0
  Pb  Pb17  1  0.655  0.500  0.806  1.0
  Pb  Pb18  1  0.500  0.194  0.655  1.0
  Pb  Pb19  1  0.194  0.655  0.500  1.0
  Pb  Pb20  1  0.345  0.500  0.194  1.0
  Pb  Pb21  1  0.500  0.806  0.345  1.0
  Pb  Pb22  1  0.806  0.655  0.500  1.0
  Pb  Pb23  1  0.655  0.500  0.194  1.0
  Pb  Pb24  1  0.194  0.345  0.500  1.0
  Pb  Pb25  1  0.345  0.500  0.806  1.0
  Pb  Pb26  1  0.500  0.806  0.655  1.0
  Pb  Pb27  1  0.500  0.194  0.345  1.0
  Pb  Pb28  1  0.306  0.000  0.845  1.0
  Pb  Pb29  1  0.155  0.306  0.000  1.0
  Pb  Pb30  1  0.000  0.155  0.694  1.0
  Pb  Pb31  1  0.694  0.000  0.155  1.0
  Pb  Pb32  1  0.845  0.694  0.000  1.0
  Pb  Pb33  1  0.000  0.845  0.306  1.0
  Pb  Pb34  1  0.306  0.000  0.155  1.0
  Pb  Pb35  1  0.155  0.694  0.000  1.0
  Pb  Pb36  1  0.694  0.000  0.845  1.0
  Pb  Pb37  1  0.845  0.306  0.000  1.0
  Pb  Pb38  1  0.000  0.155  0.306  1.0
  Pb  Pb39  1  0.000  0.845  0.694  1.0
[/CIF]
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The crystal structure described by Eu3Rh4Pb13 crystallizes in the cubic Pm-3n space group. Eu(1) is bonded in a 16-coordinate geometry to four equivalent Rh(1) and twelve equivalent Pb(2) atoms. Rh(1) is bonded in a 9-coordinate geometry to three equivalent Eu(1) and six equivalent Pb(2) atoms. There are two inequivalent Pb sites. In the first Pb site, Pb(2) is bonded in a 9-coordinate geometry to three equivalent Eu(1), two equivalent Rh(1), one Pb(1), and three equivalent Pb(2) atoms. In the second Pb site, Pb(1) is bonded in a cuboctahedral geometry to twelve equivalent Pb(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Eu3Rh4Pb13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.232
_cell_length_b   10.232
_cell_length_c   10.232
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1071.087
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Eu  Eu0  1  0.000  0.500  0.750  1.0
  Eu  Eu1  1  0.500  0.250  0.000  1.0
  Eu  Eu2  1  0.750  0.000  0.500  1.0
  Eu  Eu3  1  0.000  0.500  0.250  1.0
  Eu  Eu4  1  0.500  0.750  0.000  1.0
  Eu  Eu5  1  0.250  0.000  0.500  1.0
  Rh  Rh6  1  0.750  0.250  0.750  1.0
  Rh  Rh7  1  0.250  0.750  0.250  1.0
  Rh  Rh8  1  0.750  0.750  0.250  1.0
  Rh  Rh9  1  0.250  0.250  0.750  1.0
  Rh  Rh10  1  0.250  0.750  0.750  1.0
  Rh  Rh11  1  0.750  0.250  0.250  1.0
  Rh  Rh12  1  0.250  0.250  0.250  1.0
  Rh  Rh13  1  0.750  0.750  0.750  1.0
  Pb  Pb14  1  0.500  0.500  0.500  1.0
  Pb  Pb15  1  0.000  0.000  0.000  1.0
  Pb  Pb16  1  0.806  0.345  0.500  1.0
  Pb  Pb17  1  0.655  0.500  0.806  1.0
  Pb  Pb18  1  0.500  0.194  0.655  1.0
  Pb  Pb19  1  0.194  0.655  0.500  1.0
  Pb  Pb20  1  0.345  0.500  0.194  1.0
  Pb  Pb21  1  0.500  0.806  0.345  1.0
  Pb  Pb22  1  0.806  0.655  0.500  1.0
  Pb  Pb23  1  0.655  0.500  0.194  1.0
  Pb  Pb24  1  0.194  0.345  0.500  1.0
  Pb  Pb25  1  0.345  0.500  0.806  1.0
  Pb  Pb26  1  0.500  0.806  0.655  1.0
  Pb  Pb27  1  0.500  0.194  0.345  1.0
  Pb  Pb28  1  0.306  0.000  0.845  1.0
  Pb  Pb29  1  0.155  0.306  0.000  1.0
  Pb  Pb30  1  0.000  0.155  0.694  1.0
  Pb  Pb31  1  0.694  0.000  0.155  1.0
  Pb  Pb32  1  0.845  0.694  0.000  1.0
  Pb  Pb33  1  0.000  0.845  0.306  1.0
  Pb  Pb34  1  0.306  0.000  0.155  1.0
  Pb  Pb35  1  0.155  0.694  0.000  1.0
  Pb  Pb36  1  0.694  0.000  0.845  1.0
  Pb  Pb37  1  0.845  0.306  0.000  1.0
  Pb  Pb38  1  0.000  0.155  0.306  1.0
  Pb  Pb39  1  0.000  0.845  0.694  1.0
[/CIF]
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