The material described by Ce3(BN2)2 crystallizes in the orthorhombic Immm space group. There are two inequivalent Ce sites. In the first Ce site, Ce(1) is bonded in a 6-coordinate geometry to six equivalent N(1) atoms. In the second Ce site, Ce(2) is bonded in a distorted body-centered cubic geometry to eight equivalent N(1) atoms. B(1) is bonded in a bent 120 degrees geometry to two equivalent N(1) atoms. N(1) is bonded in a distorted single-bond geometry to two equivalent Ce(2), three equivalent Ce(1), and one B(1) atom. is represented by the CIF file [CIF]
data_Ce3(BN2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.524
_cell_length_b   6.250
_cell_length_c   6.405
_cell_angle_alpha   119.206
_cell_angle_beta   105.968
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   116.846
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.199  0.699  0.399  1.0
  Ce  Ce1  1  0.801  0.301  0.601  1.0
  Ce  Ce2  1  0.000  0.000  0.000  1.0
  B  B3  1  0.500  0.359  0.000  1.0
  B  B4  1  0.500  0.641  0.000  1.0
  N  N5  1  0.621  0.362  0.243  1.0
  N  N6  1  0.621  0.880  0.243  1.0
  N  N7  1  0.379  0.120  0.757  1.0
  N  N8  1  0.379  0.638  0.757  1.0
[/CIF]
.
The material described by Ce3(BN2)2 crystallizes in the orthorhombic Immm space group. There are two inequivalent Ce sites. In the first Ce site, Ce(1) is bonded in a 6-coordinate geometry to six equivalent N(1) atoms. In the second Ce site, Ce(2) is bonded in a distorted body-centered cubic geometry to eight equivalent N(1) atoms. B(1) is bonded in a bent 120 degrees geometry to two equivalent N(1) atoms. N(1) is bonded in a distorted single-bond geometry to two equivalent Ce(2), three equivalent Ce(1), and one B(1) atom. is represented by the CIF file [CIF]
data_Ce3(BN2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.524
_cell_length_b   6.250
_cell_length_c   6.405
_cell_angle_alpha   119.206
_cell_angle_beta   105.968
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   116.846
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.199  0.699  0.399  1.0
  Ce  Ce1  1  0.801  0.301  0.601  1.0
  Ce  Ce2  1  0.000  0.000  0.000  1.0
  B  B3  1  0.500  0.359  0.000  1.0
  B  B4  1  0.500  0.641  0.000  1.0
  N  N5  1  0.621  0.362  0.243  1.0
  N  N6  1  0.621  0.880  0.243  1.0
  N  N7  1  0.379  0.120  0.757  1.0
  N  N8  1  0.379  0.638  0.757  1.0
[/CIF]
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