The compound described by Sr10Mn(RuO5)4 is (La,Ba)CuO4-derived structured and crystallizes in the tetragonal I4/mmm space group. There are five inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 9-coordinate geometry to one O(1), four equivalent O(5), and four equivalent O(6) atoms. In the second Sr site, Sr(2) is bonded in a 9-coordinate geometry to one O(2), four equivalent O(4), and four equivalent O(7) atoms. In the third Sr site, Sr(3) is bonded in a 9-coordinate geometry to four equivalent O(8) and five equivalent O(3) atoms. In the fourth Sr site, Sr(4) is bonded in a 9-coordinate geometry to one O(4), four equivalent O(2), and four equivalent O(8) atoms. In the fifth Sr site, Sr(5) is bonded in a 9-coordinate geometry to one O(5), four equivalent O(1), and four equivalent O(7) atoms. Mn(1) is bonded to two equivalent O(5) and four equivalent O(6) atoms to form corner-sharing MnO6 octahedra. The corner-sharing octahedra are not tilted. There are two inequivalent Ru sites. In the first Ru site, Ru(1) is bonded to one O(1), one O(4), and four equivalent O(7) atoms to form corner-sharing RuO6 octahedra. The corner-sharing octahedral tilt angles are 1°. In the second Ru site, Ru(2) is bonded to one O(2), one O(3), and four equivalent O(8) atoms to form corner-sharing RuO6 octahedra. The corner-sharing octahedra are not tilted. There are eight inequivalent O sites. In the first O site, O(3) is bonded to five equivalent Sr(3) and one Ru(2) atom to form OSr5Ru octahedra that share  a cornercorner with one O(2)Sr5Ru octahedra, corners with four equivalent O(3)Sr5Ru octahedra, corners with twelve equivalent O(8)Sr4Ru2 octahedra, edges with eight equivalent O(3)Sr5Ru octahedra, and faces with four equivalent O(8)Sr4Ru2 octahedra. The corner-sharing octahedral tilt angles range from 0-56°. In the second O site, O(4) is bonded to one Sr(4), four equivalent Sr(2), and one Ru(1) atom to form OSr5Ru octahedra that share  a cornercorner with one O(1)Sr5Ru octahedra, corners with four equivalent O(8)Sr4Ru2 octahedra, corners with four equivalent O(4)Sr5Ru octahedra, corners with eight equivalent O(7)Sr4Ru2 octahedra, edges with four equivalent O(2)Sr5Ru octahedra, edges with four equivalent O(4)Sr5Ru octahedra, and faces with four equivalent O(7)Sr4Ru2 octahedra. The corner-sharing octahedral tilt angles range from 0-56°. In the third O site, O(5) is bonded to one Sr(5), four equivalent Sr(1), and one Mn(1) atom to form distorted OSr5Mn octahedra that share corners with four equivalent O(7)Sr4Ru2 octahedra, corners with five equivalent O(5)Sr5Mn octahedra, corners with eight equivalent O(6)Sr4Mn2 octahedra, edges with four equivalent O(5)Sr5Mn octahedra, edges with four equivalent O(1)Sr5Ru octahedra, and faces with four equivalent O(6)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-54°. In the fourth O site, O(6) is bonded to four equivalent Sr(1) and two equivalent Mn(1) atoms to form distorted OSr4Mn2 octahedra that share corners with two equivalent O(6)Sr4Mn2 octahedra, corners with four equivalent O(1)Sr5Ru octahedra, corners with eight equivalent O(5)Sr5Mn octahedra, edges with two equivalent O(6)Sr4Mn2 octahedra, faces with four equivalent O(6)Sr4Mn2 octahedra, and faces with four equivalent O(5)Sr5Mn octahedra. The corner-sharing octahedral tilt angles range from 0-54°. In the fifth O site, O(7) is bonded to two equivalent Sr(2), two equivalent Sr(5), and two equivalent Ru(1) atoms to form distorted OSr4Ru2 octahedra that share corners with two equivalent O(7)Sr4Ru2 octahedra, corners with two equivalent O(5)Sr5Mn octahedra, corners with two equivalent O(2)Sr5Ru octahedra, corners with four equivalent O(1)Sr5Ru octahedra, corners with four equivalent O(4)Sr5Ru octahedra, edges with two equivalent O(7)Sr4Ru2 octahedra, faces with two equivalent O(1)Sr5Ru octahedra, faces with two equivalent O(4)Sr5Ru octahedra, and faces with four equivalent O(7)Sr4Ru2 octahedra. The corner-sharing octahedral tilt angles range from 1-58°. In the sixth O site, O(8) is bonded to two equivalent Sr(3), two equivalent Sr(4), and two equivalent Ru(2) atoms to form distorted OSr4Ru2 octahedra that share corners with two equivalent O(8)Sr4Ru2 octahedra, corners with two equivalent O(4)Sr5Ru octahedra, corners with four equivalent O(2)Sr5Ru octahedra, corners with six equivalent O(3)Sr5Ru octahedra, edges with two equivalent O(8)Sr4Ru2 octahedra, faces with two equivalent O(2)Sr5Ru octahedra, faces with two equivalent O(3)Sr5Ru octahedra, and faces with four equivalent O(8)Sr4Ru2 octahedra. The corner-sharing octahedral tilt angles range from 0-56°. In the seventh O site, O(1) is bonded to one Sr(1), four equivalent Sr(5), and one Ru(1) atom to form OSr5Ru octahedra that share  a cornercorner with one O(4)Sr5Ru octahedra, corners with four equivalent O(6)Sr4Mn2 octahedra, corners with four equivalent O(1)Sr5Ru octahedra, corners with eight equivalent O(7)Sr4Ru2 octahedra, edges with four equivalent O(5)Sr5Mn octahedra, edges with four equivalent O(1)Sr5Ru octahedra, and faces with four equivalent O(7)Sr4Ru2 octahedra. The corner-sharing octahedral tilt angles range from 0-58°. In the eighth O site, O(2) is bonded to one Sr(2), four equivalent Sr(4), and one Ru(2) atom to form OSr5Ru octahedra that share  a cornercorner with one O(3)Sr5Ru octahedra, corners with four equivalent O(7)Sr4Ru2 octahedra, corners with four equivalent O(2)Sr5Ru octahedra, corners with eight equivalent O(8)Sr4Ru2 octahedra, edges with four equivalent O(2)Sr5Ru octahedra, edges with four equivalent O(4)Sr5Ru octahedra, and faces with four equivalent O(8)Sr4Ru2 octahedra. The corner-sharing octahedral tilt angles range from 0-56°. is represented by the CIF card [CIF]
data_Sr10Mn(RuO5)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.919
_cell_length_b   3.919
_cell_length_c   32.112
_cell_angle_alpha   86.501
_cell_angle_beta   86.501
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   491.409
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.473  0.473  0.055  1.0
  Sr  Sr1  1  0.871  0.871  0.258  1.0
  Sr  Sr2  1  0.271  0.271  0.459  1.0
  Sr  Sr3  1  0.671  0.671  0.659  1.0
  Sr  Sr4  1  0.069  0.069  0.861  1.0
  Sr  Sr5  1  0.931  0.931  0.139  1.0
  Sr  Sr6  1  0.329  0.329  0.341  1.0
  Sr  Sr7  1  0.729  0.729  0.541  1.0
  Sr  Sr8  1  0.129  0.129  0.742  1.0
  Sr  Sr9  1  0.527  0.527  0.945  1.0
  Mn  Mn10  1  0.000  0.000  0.000  1.0
  Ru  Ru11  1  0.400  0.400  0.200  1.0
  Ru  Ru12  1  0.800  0.800  0.400  1.0
  Ru  Ru13  1  0.200  0.200  0.600  1.0
  Ru  Ru14  1  0.600  0.600  0.800  1.0
  O  O15  1  0.432  0.432  0.136  1.0
  O  O16  1  0.833  0.833  0.335  1.0
  O  O17  1  0.233  0.233  0.535  1.0
  O  O18  1  0.633  0.633  0.735  1.0
  O  O19  1  0.032  0.032  0.937  1.0
  O  O20  1  0.968  0.968  0.063  1.0
  O  O21  1  0.367  0.367  0.265  1.0
  O  O22  1  0.767  0.767  0.465  1.0
  O  O23  1  0.167  0.167  0.665  1.0
  O  O24  1  0.568  0.568  0.864  1.0
  O  O25  1  0.500  0.000  0.000  1.0
  O  O26  1  0.900  0.400  0.200  1.0
  O  O27  1  0.300  0.800  0.400  1.0
  O  O28  1  0.700  0.200  0.600  1.0
  O  O29  1  0.100  0.600  0.800  1.0
  O  O30  1  0.000  0.500  0.000  1.0
  O  O31  1  0.400  0.900  0.200  1.0
  O  O32  1  0.800  0.300  0.400  1.0
  O  O33  1  0.200  0.700  0.600  1.0
  O  O34  1  0.600  0.100  0.800  1.0
[/CIF]
.
The compound described by Sr10Mn(RuO5)4 is (La,Ba)CuO4-derived structured and crystallizes in the tetragonal I4/mmm space group. There are five inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 9-coordinate geometry to one O(1), four equivalent O(5), and four equivalent O(6) atoms. In the second Sr site, Sr(2) is bonded in a 9-coordinate geometry to one O(2), four equivalent O(4), and four equivalent O(7) atoms. In the third Sr site, Sr(3) is bonded in a 9-coordinate geometry to four equivalent O(8) and five equivalent O(3) atoms. In the fourth Sr site, Sr(4) is bonded in a 9-coordinate geometry to one O(4), four equivalent O(2), and four equivalent O(8) atoms. In the fifth Sr site, Sr(5) is bonded in a 9-coordinate geometry to one O(5), four equivalent O(1), and four equivalent O(7) atoms. Mn(1) is bonded to two equivalent O(5) and four equivalent O(6) atoms to form corner-sharing MnO6 octahedra. The corner-sharing octahedra are not tilted. There are two inequivalent Ru sites. In the first Ru site, Ru(1) is bonded to one O(1), one O(4), and four equivalent O(7) atoms to form corner-sharing RuO6 octahedra. The corner-sharing octahedral tilt angles are 1°. In the second Ru site, Ru(2) is bonded to one O(2), one O(3), and four equivalent O(8) atoms to form corner-sharing RuO6 octahedra. The corner-sharing octahedra are not tilted. There are eight inequivalent O sites. In the first O site, O(3) is bonded to five equivalent Sr(3) and one Ru(2) atom to form OSr5Ru octahedra that share  a cornercorner with one O(2)Sr5Ru octahedra, corners with four equivalent O(3)Sr5Ru octahedra, corners with twelve equivalent O(8)Sr4Ru2 octahedra, edges with eight equivalent O(3)Sr5Ru octahedra, and faces with four equivalent O(8)Sr4Ru2 octahedra. The corner-sharing octahedral tilt angles range from 0-56°. In the second O site, O(4) is bonded to one Sr(4), four equivalent Sr(2), and one Ru(1) atom to form OSr5Ru octahedra that share  a cornercorner with one O(1)Sr5Ru octahedra, corners with four equivalent O(8)Sr4Ru2 octahedra, corners with four equivalent O(4)Sr5Ru octahedra, corners with eight equivalent O(7)Sr4Ru2 octahedra, edges with four equivalent O(2)Sr5Ru octahedra, edges with four equivalent O(4)Sr5Ru octahedra, and faces with four equivalent O(7)Sr4Ru2 octahedra. The corner-sharing octahedral tilt angles range from 0-56°. In the third O site, O(5) is bonded to one Sr(5), four equivalent Sr(1), and one Mn(1) atom to form distorted OSr5Mn octahedra that share corners with four equivalent O(7)Sr4Ru2 octahedra, corners with five equivalent O(5)Sr5Mn octahedra, corners with eight equivalent O(6)Sr4Mn2 octahedra, edges with four equivalent O(5)Sr5Mn octahedra, edges with four equivalent O(1)Sr5Ru octahedra, and faces with four equivalent O(6)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-54°. In the fourth O site, O(6) is bonded to four equivalent Sr(1) and two equivalent Mn(1) atoms to form distorted OSr4Mn2 octahedra that share corners with two equivalent O(6)Sr4Mn2 octahedra, corners with four equivalent O(1)Sr5Ru octahedra, corners with eight equivalent O(5)Sr5Mn octahedra, edges with two equivalent O(6)Sr4Mn2 octahedra, faces with four equivalent O(6)Sr4Mn2 octahedra, and faces with four equivalent O(5)Sr5Mn octahedra. The corner-sharing octahedral tilt angles range from 0-54°. In the fifth O site, O(7) is bonded to two equivalent Sr(2), two equivalent Sr(5), and two equivalent Ru(1) atoms to form distorted OSr4Ru2 octahedra that share corners with two equivalent O(7)Sr4Ru2 octahedra, corners with two equivalent O(5)Sr5Mn octahedra, corners with two equivalent O(2)Sr5Ru octahedra, corners with four equivalent O(1)Sr5Ru octahedra, corners with four equivalent O(4)Sr5Ru octahedra, edges with two equivalent O(7)Sr4Ru2 octahedra, faces with two equivalent O(1)Sr5Ru octahedra, faces with two equivalent O(4)Sr5Ru octahedra, and faces with four equivalent O(7)Sr4Ru2 octahedra. The corner-sharing octahedral tilt angles range from 1-58°. In the sixth O site, O(8) is bonded to two equivalent Sr(3), two equivalent Sr(4), and two equivalent Ru(2) atoms to form distorted OSr4Ru2 octahedra that share corners with two equivalent O(8)Sr4Ru2 octahedra, corners with two equivalent O(4)Sr5Ru octahedra, corners with four equivalent O(2)Sr5Ru octahedra, corners with six equivalent O(3)Sr5Ru octahedra, edges with two equivalent O(8)Sr4Ru2 octahedra, faces with two equivalent O(2)Sr5Ru octahedra, faces with two equivalent O(3)Sr5Ru octahedra, and faces with four equivalent O(8)Sr4Ru2 octahedra. The corner-sharing octahedral tilt angles range from 0-56°. In the seventh O site, O(1) is bonded to one Sr(1), four equivalent Sr(5), and one Ru(1) atom to form OSr5Ru octahedra that share  a cornercorner with one O(4)Sr5Ru octahedra, corners with four equivalent O(6)Sr4Mn2 octahedra, corners with four equivalent O(1)Sr5Ru octahedra, corners with eight equivalent O(7)Sr4Ru2 octahedra, edges with four equivalent O(5)Sr5Mn octahedra, edges with four equivalent O(1)Sr5Ru octahedra, and faces with four equivalent O(7)Sr4Ru2 octahedra. The corner-sharing octahedral tilt angles range from 0-58°. In the eighth O site, O(2) is bonded to one Sr(2), four equivalent Sr(4), and one Ru(2) atom to form OSr5Ru octahedra that share  a cornercorner with one O(3)Sr5Ru octahedra, corners with four equivalent O(7)Sr4Ru2 octahedra, corners with four equivalent O(2)Sr5Ru octahedra, corners with eight equivalent O(8)Sr4Ru2 octahedra, edges with four equivalent O(2)Sr5Ru octahedra, edges with four equivalent O(4)Sr5Ru octahedra, and faces with four equivalent O(8)Sr4Ru2 octahedra. The corner-sharing octahedral tilt angles range from 0-56°. is represented by the CIF card [CIF]
data_Sr10Mn(RuO5)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.919
_cell_length_b   3.919
_cell_length_c   32.112
_cell_angle_alpha   86.501
_cell_angle_beta   86.501
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   491.409
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.473  0.473  0.055  1.0
  Sr  Sr1  1  0.871  0.871  0.258  1.0
  Sr  Sr2  1  0.271  0.271  0.459  1.0
  Sr  Sr3  1  0.671  0.671  0.659  1.0
  Sr  Sr4  1  0.069  0.069  0.861  1.0
  Sr  Sr5  1  0.931  0.931  0.139  1.0
  Sr  Sr6  1  0.329  0.329  0.341  1.0
  Sr  Sr7  1  0.729  0.729  0.541  1.0
  Sr  Sr8  1  0.129  0.129  0.742  1.0
  Sr  Sr9  1  0.527  0.527  0.945  1.0
  Mn  Mn10  1  0.000  0.000  0.000  1.0
  Ru  Ru11  1  0.400  0.400  0.200  1.0
  Ru  Ru12  1  0.800  0.800  0.400  1.0
  Ru  Ru13  1  0.200  0.200  0.600  1.0
  Ru  Ru14  1  0.600  0.600  0.800  1.0
  O  O15  1  0.432  0.432  0.136  1.0
  O  O16  1  0.833  0.833  0.335  1.0
  O  O17  1  0.233  0.233  0.535  1.0
  O  O18  1  0.633  0.633  0.735  1.0
  O  O19  1  0.032  0.032  0.937  1.0
  O  O20  1  0.968  0.968  0.063  1.0
  O  O21  1  0.367  0.367  0.265  1.0
  O  O22  1  0.767  0.767  0.465  1.0
  O  O23  1  0.167  0.167  0.665  1.0
  O  O24  1  0.568  0.568  0.864  1.0
  O  O25  1  0.500  0.000  0.000  1.0
  O  O26  1  0.900  0.400  0.200  1.0
  O  O27  1  0.300  0.800  0.400  1.0
  O  O28  1  0.700  0.200  0.600  1.0
  O  O29  1  0.100  0.600  0.800  1.0
  O  O30  1  0.000  0.500  0.000  1.0
  O  O31  1  0.400  0.900  0.200  1.0
  O  O32  1  0.800  0.300  0.400  1.0
  O  O33  1  0.200  0.700  0.600  1.0
  O  O34  1  0.600  0.100  0.800  1.0
[/CIF]
.