The material structure described by AlSb(WO4)2 is Hydrophilite-derived structured and crystallizes in the monoclinic P2/c space group. W(1) is bonded to one O(1), one O(3), two equivalent O(2), and two equivalent O(4) atoms to form WO6 octahedra that share corners with four equivalent Al(1)O6 octahedra, corners with four equivalent Sb(1)O6 octahedra, and edges with two equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-58°. Al(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form AlO6 octahedra that share corners with eight equivalent W(1)O6 octahedra and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-51°. Sb(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form SbO6 octahedra that share corners with eight equivalent W(1)O6 octahedra and edges with two equivalent Al(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-58°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one W(1), one Al(1), and one Sb(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent W(1) and one Sb(1) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one W(1), one Al(1), and one Sb(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to two equivalent W(1) and one Al(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_AlSb(WO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.628
_cell_length_b   5.198
_cell_length_c   10.687
_cell_angle_alpha   60.811
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   272.914
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  0.666  0.500  0.250  1.0
  Al  Al1  1  0.334  0.500  0.750  1.0
  Sb  Sb2  1  0.362  0.000  0.250  1.0
  Sb  Sb3  1  0.638  0.000  0.750  1.0
  W  W4  1  0.158  0.755  0.002  1.0
  W  W5  1  0.158  0.245  0.498  1.0
  W  W6  1  0.842  0.245  0.998  1.0
  W  W7  1  0.842  0.755  0.502  1.0
  O  O8  1  0.400  0.224  0.360  1.0
  O  O9  1  0.400  0.776  0.140  1.0
  O  O10  1  0.600  0.776  0.640  1.0
  O  O11  1  0.600  0.224  0.860  1.0
  O  O12  1  0.879  0.712  0.882  1.0
  O  O13  1  0.879  0.288  0.618  1.0
  O  O14  1  0.121  0.288  0.118  1.0
  O  O15  1  0.121  0.712  0.382  1.0
  O  O16  1  0.621  0.707  0.360  1.0
  O  O17  1  0.621  0.293  0.140  1.0
  O  O18  1  0.379  0.293  0.640  1.0
  O  O19  1  0.379  0.707  0.860  1.0
  O  O20  1  0.884  0.216  0.378  1.0
  O  O21  1  0.116  0.784  0.622  1.0
  O  O22  1  0.884  0.784  0.122  1.0
  O  O23  1  0.116  0.216  0.878  1.0
[/CIF]
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The material structure described by AlSb(WO4)2 is Hydrophilite-derived structured and crystallizes in the monoclinic P2/c space group. W(1) is bonded to one O(1), one O(3), two equivalent O(2), and two equivalent O(4) atoms to form WO6 octahedra that share corners with four equivalent Al(1)O6 octahedra, corners with four equivalent Sb(1)O6 octahedra, and edges with two equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-58°. Al(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form AlO6 octahedra that share corners with eight equivalent W(1)O6 octahedra and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-51°. Sb(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form SbO6 octahedra that share corners with eight equivalent W(1)O6 octahedra and edges with two equivalent Al(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-58°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one W(1), one Al(1), and one Sb(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent W(1) and one Sb(1) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one W(1), one Al(1), and one Sb(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to two equivalent W(1) and one Al(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_AlSb(WO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.628
_cell_length_b   5.198
_cell_length_c   10.687
_cell_angle_alpha   60.811
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   272.914
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  0.666  0.500  0.250  1.0
  Al  Al1  1  0.334  0.500  0.750  1.0
  Sb  Sb2  1  0.362  0.000  0.250  1.0
  Sb  Sb3  1  0.638  0.000  0.750  1.0
  W  W4  1  0.158  0.755  0.002  1.0
  W  W5  1  0.158  0.245  0.498  1.0
  W  W6  1  0.842  0.245  0.998  1.0
  W  W7  1  0.842  0.755  0.502  1.0
  O  O8  1  0.400  0.224  0.360  1.0
  O  O9  1  0.400  0.776  0.140  1.0
  O  O10  1  0.600  0.776  0.640  1.0
  O  O11  1  0.600  0.224  0.860  1.0
  O  O12  1  0.879  0.712  0.882  1.0
  O  O13  1  0.879  0.288  0.618  1.0
  O  O14  1  0.121  0.288  0.118  1.0
  O  O15  1  0.121  0.712  0.382  1.0
  O  O16  1  0.621  0.707  0.360  1.0
  O  O17  1  0.621  0.293  0.140  1.0
  O  O18  1  0.379  0.293  0.640  1.0
  O  O19  1  0.379  0.707  0.860  1.0
  O  O20  1  0.884  0.216  0.378  1.0
  O  O21  1  0.116  0.784  0.622  1.0
  O  O22  1  0.884  0.784  0.122  1.0
  O  O23  1  0.116  0.216  0.878  1.0
[/CIF]
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