The material described by Zn(AgO2)2 is Spinel-like structured and crystallizes in the trigonal P3m1 space group. There are six inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to one O(2), one O(6), two equivalent O(1), and two equivalent O(4) atoms to form AgO6 octahedra that share  a cornercorner with one Ag(6)O4 tetrahedra,  a cornercorner with one Zn(2)O4 tetrahedra, corners with two equivalent Ag(4)O4 tetrahedra, corners with two equivalent Zn(1)O4 tetrahedra,  an edgeedge with one Zn(3)O6 octahedra,  an edgeedge with one Zn(5)O6 octahedra, and edges with four equivalent Ag(1)O6 octahedra. In the second Ag site, Ag(2) is bonded to one O(10), one O(5), two equivalent O(3), and two equivalent O(8) atoms to form AgO6 octahedra that share  a cornercorner with one Ag(4)O4 tetrahedra,  a cornercorner with one Zn(4)O4 tetrahedra, corners with two equivalent Zn(2)O4 tetrahedra, corners with two equivalent Zn(6)O4 tetrahedra,  an edgeedge with one Ag(3)O6 octahedra,  an edgeedge with one Zn(3)O6 octahedra, and edges with four equivalent Ag(2)O6 octahedra. In the third Ag site, Ag(3) is bonded to three equivalent O(7) and three equivalent O(8) atoms to form AgO6 octahedra that share corners with three equivalent Zn(4)O4 tetrahedra, corners with three equivalent Zn(6)O4 tetrahedra, edges with three equivalent Ag(2)O6 octahedra, and edges with three equivalent Ag(5)O6 octahedra. In the fourth Ag site, Ag(4) is bonded to one O(10) and three equivalent O(4) atoms to form AgO4 tetrahedra that share corners with three equivalent Ag(2)O6 octahedra, corners with three equivalent Zn(3)O6 octahedra, and corners with six equivalent Ag(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 60-61°. In the fifth Ag site, Ag(5) is bonded to one O(12), one O(9), two equivalent O(11), and two equivalent O(7) atoms to form AgO6 octahedra that share  a cornercorner with one Zn(1)O4 tetrahedra,  a cornercorner with one Zn(6)O4 tetrahedra, corners with two equivalent Ag(6)O4 tetrahedra, corners with two equivalent Zn(4)O4 tetrahedra,  an edgeedge with one Ag(3)O6 octahedra,  an edgeedge with one Zn(5)O6 octahedra, and edges with four equivalent Ag(5)O6 octahedra. In the sixth Ag site, Ag(6) is bonded to one O(6) and three equivalent O(11) atoms to form AgO4 tetrahedra that share corners with three equivalent Ag(1)O6 octahedra, corners with three equivalent Zn(5)O6 octahedra, and corners with six equivalent Ag(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 58-60°. There are six inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(9) and three equivalent O(1) atoms to form ZnO4 tetrahedra that share corners with three equivalent Ag(5)O6 octahedra, corners with three equivalent Zn(5)O6 octahedra, and corners with six equivalent Ag(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-59°. In the second Zn site, Zn(2) is bonded to one O(2) and three equivalent O(3) atoms to form ZnO4 tetrahedra that share corners with three equivalent Ag(1)O6 octahedra, corners with three equivalent Zn(3)O6 octahedra, and corners with six equivalent Ag(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-59°. In the third Zn site, Zn(3) is bonded to three equivalent O(3) and three equivalent O(4) atoms to form ZnO6 octahedra that share corners with three equivalent Ag(4)O4 tetrahedra, corners with three equivalent Zn(2)O4 tetrahedra, edges with three equivalent Ag(1)O6 octahedra, and edges with three equivalent Ag(2)O6 octahedra. In the fourth Zn site, Zn(4) is bonded to one O(5) and three equivalent O(7) atoms to form ZnO4 tetrahedra that share corners with three equivalent Ag(2)O6 octahedra, corners with three equivalent Ag(3)O6 octahedra, and corners with six equivalent Ag(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-59°. In the fifth Zn site, Zn(5) is bonded to three equivalent O(1) and three equivalent O(11) atoms to form ZnO6 octahedra that share corners with three equivalent Ag(6)O4 tetrahedra, corners with three equivalent Zn(1)O4 tetrahedra, edges with three equivalent Ag(1)O6 octahedra, and edges with three equivalent Ag(5)O6 octahedra. In the sixth Zn site, Zn(6) is bonded to one O(12) and three equivalent O(8) atoms to form ZnO4 tetrahedra that share corners with three equivalent Ag(3)O6 octahedra, corners with three equivalent Ag(5)O6 octahedra, and corners with six equivalent Ag(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-57°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to two equivalent Ag(1), one Zn(1), and one Zn(5) atom. In the second O site, O(2) is bonded in a distorted rectangular see-saw-like geometry to three equivalent Ag(1) and one Zn(2) atom. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to two equivalent Ag(2), one Zn(2), and one Zn(3) atom. In the fourth O site, O(4) is bonded to one Ag(4), two equivalent Ag(1), and one Zn(3) atom to form distorted OZnAg3 tetrahedra that share  a cornercorner with one O(10)Ag4 tetrahedra, corners with two equivalent O(4)ZnAg3 tetrahedra, edges with two equivalent O(4)ZnAg3 tetrahedra, and  an edgeedge with one O(6)Ag4 trigonal pyramid. In the fifth O site, O(5) is bonded in a distorted rectangular see-saw-like geometry to three equivalent Ag(2) and one Zn(4) atom. In the sixth O site, O(6) is bonded to one Ag(6) and three equivalent Ag(1) atoms to form a mixture of distorted edge and corner-sharing OAg4 trigonal pyramids. In the seventh O site, O(7) is bonded in a rectangular see-saw-like geometry to one Ag(3), two equivalent Ag(5), and one Zn(4) atom. In the eighth O site, O(8) is bonded in a rectangular see-saw-like geometry to one Ag(3), two equivalent Ag(2), and one Zn(6) atom. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to three equivalent Ag(5) and one Zn(1) atom. In the tenth O site, O(10) is bonded to one Ag(4) and three equivalent Ag(2) atoms to form distorted corner-sharing OAg4 tetrahedra. In the eleventh O site, O(11) is bonded to one Ag(6), two equivalent Ag(5), and one Zn(5) atom to form distorted OZnAg3 tetrahedra that share corners with two equivalent O(11)ZnAg3 tetrahedra,  a cornercorner with one O(6)Ag4 trigonal pyramid, and edges with two equivalent O(11)ZnAg3 tetrahedra. In the twelfth O site, O(12) is bonded in a rectangular see-saw-like geometry to three equivalent Ag(5) and one Zn(6) atom. is represented by the CIF file [CIF]
data_Zn(AgO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.407
_cell_length_b   6.407
_cell_length_c   15.362
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   546.080
_cell_formula_units_Z   6
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.000  0.000  0.952  1.0
  Zn  Zn1  1  0.667  0.333  0.620  1.0
  Zn  Zn2  1  0.333  0.667  0.665  1.0
  Zn  Zn3  1  0.333  0.667  0.287  1.0
  Zn  Zn4  1  0.667  0.333  0.998  1.0
  Zn  Zn5  1  0.667  0.333  0.380  1.0
  Ag  Ag6  1  0.998  0.499  0.833  1.0
  Ag  Ag7  1  0.501  0.499  0.833  1.0
  Ag  Ag8  1  0.661  0.831  0.500  1.0
  Ag  Ag9  1  0.501  0.002  0.833  1.0
  Ag  Ag10  1  0.169  0.831  0.500  1.0
  Ag  Ag11  1  0.000  0.000  0.334  1.0
  Ag  Ag12  1  0.000  0.000  0.710  1.0
  Ag  Ag13  1  0.337  0.168  0.166  1.0
  Ag  Ag14  1  0.169  0.339  0.500  1.0
  Ag  Ag15  1  0.832  0.168  0.166  1.0
  Ag  Ag16  1  0.832  0.663  0.166  1.0
  Ag  Ag17  1  0.333  0.667  0.045  1.0
  O  O18  1  0.359  0.179  0.913  1.0
  O  O19  1  0.667  0.333  0.750  1.0
  O  O20  1  0.821  0.179  0.913  1.0
  O  O21  1  0.821  0.641  0.913  1.0
  O  O22  1  0.020  0.510  0.585  1.0
  O  O23  1  0.188  0.376  0.758  1.0
  O  O24  1  0.333  0.667  0.418  1.0
  O  O25  1  0.188  0.812  0.758  1.0
  O  O26  1  0.333  0.667  0.910  1.0
  O  O27  1  0.490  0.510  0.585  1.0
  O  O28  1  0.490  0.980  0.585  1.0
  O  O29  1  0.624  0.812  0.758  1.0
  O  O30  1  0.683  0.841  0.242  1.0
  O  O31  1  0.838  0.676  0.421  1.0
  O  O32  1  0.838  0.162  0.421  1.0
  O  O33  1  0.000  0.000  0.080  1.0
  O  O34  1  0.000  0.000  0.571  1.0
  O  O35  1  0.159  0.841  0.242  1.0
  O  O36  1  0.159  0.317  0.242  1.0
  O  O37  1  0.324  0.162  0.421  1.0
  O  O38  1  0.521  0.043  0.091  1.0
  O  O39  1  0.521  0.479  0.091  1.0
  O  O40  1  0.667  0.333  0.253  1.0
  O  O41  1  0.957  0.479  0.091  1.0
[/CIF]
.
The material described by Zn(AgO2)2 is Spinel-like structured and crystallizes in the trigonal P3m1 space group. There are six inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to one O(2), one O(6), two equivalent O(1), and two equivalent O(4) atoms to form AgO6 octahedra that share  a cornercorner with one Ag(6)O4 tetrahedra,  a cornercorner with one Zn(2)O4 tetrahedra, corners with two equivalent Ag(4)O4 tetrahedra, corners with two equivalent Zn(1)O4 tetrahedra,  an edgeedge with one Zn(3)O6 octahedra,  an edgeedge with one Zn(5)O6 octahedra, and edges with four equivalent Ag(1)O6 octahedra. In the second Ag site, Ag(2) is bonded to one O(10), one O(5), two equivalent O(3), and two equivalent O(8) atoms to form AgO6 octahedra that share  a cornercorner with one Ag(4)O4 tetrahedra,  a cornercorner with one Zn(4)O4 tetrahedra, corners with two equivalent Zn(2)O4 tetrahedra, corners with two equivalent Zn(6)O4 tetrahedra,  an edgeedge with one Ag(3)O6 octahedra,  an edgeedge with one Zn(3)O6 octahedra, and edges with four equivalent Ag(2)O6 octahedra. In the third Ag site, Ag(3) is bonded to three equivalent O(7) and three equivalent O(8) atoms to form AgO6 octahedra that share corners with three equivalent Zn(4)O4 tetrahedra, corners with three equivalent Zn(6)O4 tetrahedra, edges with three equivalent Ag(2)O6 octahedra, and edges with three equivalent Ag(5)O6 octahedra. In the fourth Ag site, Ag(4) is bonded to one O(10) and three equivalent O(4) atoms to form AgO4 tetrahedra that share corners with three equivalent Ag(2)O6 octahedra, corners with three equivalent Zn(3)O6 octahedra, and corners with six equivalent Ag(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 60-61°. In the fifth Ag site, Ag(5) is bonded to one O(12), one O(9), two equivalent O(11), and two equivalent O(7) atoms to form AgO6 octahedra that share  a cornercorner with one Zn(1)O4 tetrahedra,  a cornercorner with one Zn(6)O4 tetrahedra, corners with two equivalent Ag(6)O4 tetrahedra, corners with two equivalent Zn(4)O4 tetrahedra,  an edgeedge with one Ag(3)O6 octahedra,  an edgeedge with one Zn(5)O6 octahedra, and edges with four equivalent Ag(5)O6 octahedra. In the sixth Ag site, Ag(6) is bonded to one O(6) and three equivalent O(11) atoms to form AgO4 tetrahedra that share corners with three equivalent Ag(1)O6 octahedra, corners with three equivalent Zn(5)O6 octahedra, and corners with six equivalent Ag(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 58-60°. There are six inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(9) and three equivalent O(1) atoms to form ZnO4 tetrahedra that share corners with three equivalent Ag(5)O6 octahedra, corners with three equivalent Zn(5)O6 octahedra, and corners with six equivalent Ag(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-59°. In the second Zn site, Zn(2) is bonded to one O(2) and three equivalent O(3) atoms to form ZnO4 tetrahedra that share corners with three equivalent Ag(1)O6 octahedra, corners with three equivalent Zn(3)O6 octahedra, and corners with six equivalent Ag(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-59°. In the third Zn site, Zn(3) is bonded to three equivalent O(3) and three equivalent O(4) atoms to form ZnO6 octahedra that share corners with three equivalent Ag(4)O4 tetrahedra, corners with three equivalent Zn(2)O4 tetrahedra, edges with three equivalent Ag(1)O6 octahedra, and edges with three equivalent Ag(2)O6 octahedra. In the fourth Zn site, Zn(4) is bonded to one O(5) and three equivalent O(7) atoms to form ZnO4 tetrahedra that share corners with three equivalent Ag(2)O6 octahedra, corners with three equivalent Ag(3)O6 octahedra, and corners with six equivalent Ag(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-59°. In the fifth Zn site, Zn(5) is bonded to three equivalent O(1) and three equivalent O(11) atoms to form ZnO6 octahedra that share corners with three equivalent Ag(6)O4 tetrahedra, corners with three equivalent Zn(1)O4 tetrahedra, edges with three equivalent Ag(1)O6 octahedra, and edges with three equivalent Ag(5)O6 octahedra. In the sixth Zn site, Zn(6) is bonded to one O(12) and three equivalent O(8) atoms to form ZnO4 tetrahedra that share corners with three equivalent Ag(3)O6 octahedra, corners with three equivalent Ag(5)O6 octahedra, and corners with six equivalent Ag(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-57°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to two equivalent Ag(1), one Zn(1), and one Zn(5) atom. In the second O site, O(2) is bonded in a distorted rectangular see-saw-like geometry to three equivalent Ag(1) and one Zn(2) atom. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to two equivalent Ag(2), one Zn(2), and one Zn(3) atom. In the fourth O site, O(4) is bonded to one Ag(4), two equivalent Ag(1), and one Zn(3) atom to form distorted OZnAg3 tetrahedra that share  a cornercorner with one O(10)Ag4 tetrahedra, corners with two equivalent O(4)ZnAg3 tetrahedra, edges with two equivalent O(4)ZnAg3 tetrahedra, and  an edgeedge with one O(6)Ag4 trigonal pyramid. In the fifth O site, O(5) is bonded in a distorted rectangular see-saw-like geometry to three equivalent Ag(2) and one Zn(4) atom. In the sixth O site, O(6) is bonded to one Ag(6) and three equivalent Ag(1) atoms to form a mixture of distorted edge and corner-sharing OAg4 trigonal pyramids. In the seventh O site, O(7) is bonded in a rectangular see-saw-like geometry to one Ag(3), two equivalent Ag(5), and one Zn(4) atom. In the eighth O site, O(8) is bonded in a rectangular see-saw-like geometry to one Ag(3), two equivalent Ag(2), and one Zn(6) atom. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to three equivalent Ag(5) and one Zn(1) atom. In the tenth O site, O(10) is bonded to one Ag(4) and three equivalent Ag(2) atoms to form distorted corner-sharing OAg4 tetrahedra. In the eleventh O site, O(11) is bonded to one Ag(6), two equivalent Ag(5), and one Zn(5) atom to form distorted OZnAg3 tetrahedra that share corners with two equivalent O(11)ZnAg3 tetrahedra,  a cornercorner with one O(6)Ag4 trigonal pyramid, and edges with two equivalent O(11)ZnAg3 tetrahedra. In the twelfth O site, O(12) is bonded in a rectangular see-saw-like geometry to three equivalent Ag(5) and one Zn(6) atom. is represented by the CIF file [CIF]
data_Zn(AgO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.407
_cell_length_b   6.407
_cell_length_c   15.362
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   546.080
_cell_formula_units_Z   6
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.000  0.000  0.952  1.0
  Zn  Zn1  1  0.667  0.333  0.620  1.0
  Zn  Zn2  1  0.333  0.667  0.665  1.0
  Zn  Zn3  1  0.333  0.667  0.287  1.0
  Zn  Zn4  1  0.667  0.333  0.998  1.0
  Zn  Zn5  1  0.667  0.333  0.380  1.0
  Ag  Ag6  1  0.998  0.499  0.833  1.0
  Ag  Ag7  1  0.501  0.499  0.833  1.0
  Ag  Ag8  1  0.661  0.831  0.500  1.0
  Ag  Ag9  1  0.501  0.002  0.833  1.0
  Ag  Ag10  1  0.169  0.831  0.500  1.0
  Ag  Ag11  1  0.000  0.000  0.334  1.0
  Ag  Ag12  1  0.000  0.000  0.710  1.0
  Ag  Ag13  1  0.337  0.168  0.166  1.0
  Ag  Ag14  1  0.169  0.339  0.500  1.0
  Ag  Ag15  1  0.832  0.168  0.166  1.0
  Ag  Ag16  1  0.832  0.663  0.166  1.0
  Ag  Ag17  1  0.333  0.667  0.045  1.0
  O  O18  1  0.359  0.179  0.913  1.0
  O  O19  1  0.667  0.333  0.750  1.0
  O  O20  1  0.821  0.179  0.913  1.0
  O  O21  1  0.821  0.641  0.913  1.0
  O  O22  1  0.020  0.510  0.585  1.0
  O  O23  1  0.188  0.376  0.758  1.0
  O  O24  1  0.333  0.667  0.418  1.0
  O  O25  1  0.188  0.812  0.758  1.0
  O  O26  1  0.333  0.667  0.910  1.0
  O  O27  1  0.490  0.510  0.585  1.0
  O  O28  1  0.490  0.980  0.585  1.0
  O  O29  1  0.624  0.812  0.758  1.0
  O  O30  1  0.683  0.841  0.242  1.0
  O  O31  1  0.838  0.676  0.421  1.0
  O  O32  1  0.838  0.162  0.421  1.0
  O  O33  1  0.000  0.000  0.080  1.0
  O  O34  1  0.000  0.000  0.571  1.0
  O  O35  1  0.159  0.841  0.242  1.0
  O  O36  1  0.159  0.317  0.242  1.0
  O  O37  1  0.324  0.162  0.421  1.0
  O  O38  1  0.521  0.043  0.091  1.0
  O  O39  1  0.521  0.479  0.091  1.0
  O  O40  1  0.667  0.333  0.253  1.0
  O  O41  1  0.957  0.479  0.091  1.0
[/CIF]
.