The structure described by NdCP2H2O6 crystallizes in the monoclinic C2/m space group. Nd(1) is bonded in a 8-coordinate geometry to two equivalent O(2), two equivalent O(3), and four equivalent O(1) atoms. C(1) is bonded in a distorted tetrahedral geometry to two equivalent P(1), one H(1), and one H(2) atom. P(1) is bonded to one C(1), one O(1), one O(2), and one O(3) atom to form corner-sharing PCO3 tetrahedra. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. There are three inequivalent O sites. In the first O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Nd(1) and one P(1) atom. In the second O site, O(1) is bonded in a 3-coordinate geometry to two equivalent Nd(1) and one P(1) atom. In the third O site, O(2) is bonded in a distorted water-like geometry to one Nd(1) and one P(1) atom. is represented by the CIF card [CIF]
data_NdP2H2CO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.369
_cell_length_b   8.187
_cell_length_c   8.291
_cell_angle_alpha   113.551
_cell_angle_beta   100.380
_cell_angle_gamma   106.912
_symmetry_Int_Tables_number   1
_cell_volume   300.838
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Nd  Nd0  1  0.271  0.771  0.542  1.0
  Nd  Nd1  1  0.729  0.229  0.458  1.0
  P  P2  1  0.240  0.367  0.223  1.0
  P  P3  1  0.017  0.144  0.777  1.0
  P  P4  1  0.760  0.633  0.777  1.0
  P  P5  1  0.983  0.856  0.223  1.0
  H  H6  1  0.844  0.319  0.000  1.0
  H  H7  1  0.156  0.681  0.000  1.0
  H  H8  1  0.828  0.098  0.000  1.0
  H  H9  1  0.172  0.902  0.000  1.0
  C  C10  1  0.962  0.229  0.000  1.0
  C  C11  1  0.038  0.771  0.000  1.0
  O  O12  1  0.098  0.394  0.374  1.0
  O  O13  1  0.724  0.021  0.626  1.0
  O  O14  1  0.902  0.606  0.626  1.0
  O  O15  1  0.276  0.979  0.374  1.0
  O  O16  1  0.387  0.581  0.263  1.0
  O  O17  1  0.124  0.318  0.737  1.0
  O  O18  1  0.613  0.419  0.737  1.0
  O  O19  1  0.876  0.682  0.263  1.0
  O  O20  1  0.433  0.264  0.235  1.0
  O  O21  1  0.198  0.030  0.765  1.0
  O  O22  1  0.567  0.736  0.765  1.0
  O  O23  1  0.802  0.970  0.235  1.0
[/CIF]
.
The structure described by NdCP2H2O6 crystallizes in the monoclinic C2/m space group. Nd(1) is bonded in a 8-coordinate geometry to two equivalent O(2), two equivalent O(3), and four equivalent O(1) atoms. C(1) is bonded in a distorted tetrahedral geometry to two equivalent P(1), one H(1), and one H(2) atom. P(1) is bonded to one C(1), one O(1), one O(2), and one O(3) atom to form corner-sharing PCO3 tetrahedra. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. There are three inequivalent O sites. In the first O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Nd(1) and one P(1) atom. In the second O site, O(1) is bonded in a 3-coordinate geometry to two equivalent Nd(1) and one P(1) atom. In the third O site, O(2) is bonded in a distorted water-like geometry to one Nd(1) and one P(1) atom. is represented by the CIF card [CIF]
data_NdP2H2CO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.369
_cell_length_b   8.187
_cell_length_c   8.291
_cell_angle_alpha   113.551
_cell_angle_beta   100.380
_cell_angle_gamma   106.912
_symmetry_Int_Tables_number   1
_cell_volume   300.838
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Nd  Nd0  1  0.271  0.771  0.542  1.0
  Nd  Nd1  1  0.729  0.229  0.458  1.0
  P  P2  1  0.240  0.367  0.223  1.0
  P  P3  1  0.017  0.144  0.777  1.0
  P  P4  1  0.760  0.633  0.777  1.0
  P  P5  1  0.983  0.856  0.223  1.0
  H  H6  1  0.844  0.319  0.000  1.0
  H  H7  1  0.156  0.681  0.000  1.0
  H  H8  1  0.828  0.098  0.000  1.0
  H  H9  1  0.172  0.902  0.000  1.0
  C  C10  1  0.962  0.229  0.000  1.0
  C  C11  1  0.038  0.771  0.000  1.0
  O  O12  1  0.098  0.394  0.374  1.0
  O  O13  1  0.724  0.021  0.626  1.0
  O  O14  1  0.902  0.606  0.626  1.0
  O  O15  1  0.276  0.979  0.374  1.0
  O  O16  1  0.387  0.581  0.263  1.0
  O  O17  1  0.124  0.318  0.737  1.0
  O  O18  1  0.613  0.419  0.737  1.0
  O  O19  1  0.876  0.682  0.263  1.0
  O  O20  1  0.433  0.264  0.235  1.0
  O  O21  1  0.198  0.030  0.765  1.0
  O  O22  1  0.567  0.736  0.765  1.0
  O  O23  1  0.802  0.970  0.235  1.0
[/CIF]
.