The structure described by V2Mn(PbO4)2 crystallizes in the monoclinic P2_1 space group. There are two inequivalent V sites. In the first V site, V(1) is bonded in a tetrahedral geometry to one O(3), one O(4), one O(7), and one O(8) atom. In the second V site, V(2) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(5), and one O(6) atom. Mn(1) is bonded in a square co-planar geometry to one O(5), one O(6), and two equivalent O(4) atoms. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 7-coordinate geometry to one O(1), one O(2), one O(3), one O(5), one O(6), one O(7), and one O(8) atom. In the second Pb site, Pb(2) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(7), and one O(8) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one V(2), one Pb(1), and one Pb(2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one V(2), one Pb(1), and one Pb(2) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one V(1) and one Pb(1) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one V(1) and two equivalent Mn(1) atoms. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one V(2), one Mn(1), and one Pb(1) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one V(2), one Mn(1), and one Pb(1) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one V(1), one Pb(1), and one Pb(2) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one V(1), one Pb(1), and one Pb(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_MnV2(PbO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.638
_cell_length_b   7.489
_cell_length_c   9.130
_cell_angle_alpha   112.518
_cell_angle_beta   89.997
_cell_angle_gamma   90.003
_symmetry_Int_Tables_number   1
_cell_volume   419.250
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.500  0.000  1.000  1.0
  Mn  Mn1  1  0.999  0.999  0.000  1.0
  V  V2  1  0.250  0.554  0.848  1.0
  V  V3  1  0.750  0.446  0.152  1.0
  V  V4  1  0.250  0.955  0.666  1.0
  V  V5  1  0.750  0.045  0.334  1.0
  Pb  Pb6  1  0.250  0.735  0.261  1.0
  Pb  Pb7  1  0.750  0.264  0.739  1.0
  Pb  Pb8  1  0.250  0.352  0.476  1.0
  Pb  Pb9  1  0.750  0.648  0.524  1.0
  O  O10  1  0.250  0.712  0.541  1.0
  O  O11  1  0.750  0.288  0.459  1.0
  O  O12  1  0.250  0.070  0.535  1.0
  O  O13  1  0.750  0.930  0.465  1.0
  O  O14  1  0.250  0.456  0.986  1.0
  O  O15  1  0.750  0.544  0.014  1.0
  O  O16  1  0.250  0.813  0.953  1.0
  O  O17  1  0.750  0.187  0.047  1.0
  O  O18  1  0.473  0.012  0.781  1.0
  O  O19  1  0.528  0.988  0.219  1.0
  O  O20  1  0.973  0.988  0.219  1.0
  O  O21  1  0.028  0.012  0.781  1.0
  O  O22  1  0.457  0.476  0.718  1.0
  O  O23  1  0.543  0.524  0.283  1.0
  O  O24  1  0.957  0.524  0.282  1.0
  O  O25  1  0.043  0.476  0.718  1.0
[/CIF]
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The structure described by V2Mn(PbO4)2 crystallizes in the monoclinic P2_1 space group. There are two inequivalent V sites. In the first V site, V(1) is bonded in a tetrahedral geometry to one O(3), one O(4), one O(7), and one O(8) atom. In the second V site, V(2) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(5), and one O(6) atom. Mn(1) is bonded in a square co-planar geometry to one O(5), one O(6), and two equivalent O(4) atoms. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 7-coordinate geometry to one O(1), one O(2), one O(3), one O(5), one O(6), one O(7), and one O(8) atom. In the second Pb site, Pb(2) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(7), and one O(8) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one V(2), one Pb(1), and one Pb(2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one V(2), one Pb(1), and one Pb(2) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one V(1) and one Pb(1) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one V(1) and two equivalent Mn(1) atoms. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one V(2), one Mn(1), and one Pb(1) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one V(2), one Mn(1), and one Pb(1) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one V(1), one Pb(1), and one Pb(2) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one V(1), one Pb(1), and one Pb(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_MnV2(PbO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.638
_cell_length_b   7.489
_cell_length_c   9.130
_cell_angle_alpha   112.518
_cell_angle_beta   89.997
_cell_angle_gamma   90.003
_symmetry_Int_Tables_number   1
_cell_volume   419.250
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.500  0.000  1.000  1.0
  Mn  Mn1  1  0.999  0.999  0.000  1.0
  V  V2  1  0.250  0.554  0.848  1.0
  V  V3  1  0.750  0.446  0.152  1.0
  V  V4  1  0.250  0.955  0.666  1.0
  V  V5  1  0.750  0.045  0.334  1.0
  Pb  Pb6  1  0.250  0.735  0.261  1.0
  Pb  Pb7  1  0.750  0.264  0.739  1.0
  Pb  Pb8  1  0.250  0.352  0.476  1.0
  Pb  Pb9  1  0.750  0.648  0.524  1.0
  O  O10  1  0.250  0.712  0.541  1.0
  O  O11  1  0.750  0.288  0.459  1.0
  O  O12  1  0.250  0.070  0.535  1.0
  O  O13  1  0.750  0.930  0.465  1.0
  O  O14  1  0.250  0.456  0.986  1.0
  O  O15  1  0.750  0.544  0.014  1.0
  O  O16  1  0.250  0.813  0.953  1.0
  O  O17  1  0.750  0.187  0.047  1.0
  O  O18  1  0.473  0.012  0.781  1.0
  O  O19  1  0.528  0.988  0.219  1.0
  O  O20  1  0.973  0.988  0.219  1.0
  O  O21  1  0.028  0.012  0.781  1.0
  O  O22  1  0.457  0.476  0.718  1.0
  O  O23  1  0.543  0.524  0.283  1.0
  O  O24  1  0.957  0.524  0.282  1.0
  O  O25  1  0.043  0.476  0.718  1.0
[/CIF]
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