The structure described by Li4ZnIn2F12 crystallizes in the orthorhombic Pnc2 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to two equivalent F(1), two equivalent F(2), and two equivalent F(6) atoms to form LiF6 octahedra that share corners with four equivalent Li(2)F6 octahedra, corners with four equivalent In(2)F6 octahedra,  an edgeedge with one Li(4)F6 octahedra,  an edgeedge with one In(1)F6 octahedra, and faces with two equivalent Li(3)F6 octahedra. The corner-sharing octahedral tilt angles range from 42-51°. In the second Li site, Li(2) is bonded to two equivalent F(1), two equivalent F(2), and two equivalent F(5) atoms to form LiF6 octahedra that share corners with four equivalent Li(1)F6 octahedra, corners with four equivalent In(1)F6 octahedra,  an edgeedge with one Zn(1)F6 octahedra,  an edgeedge with one In(2)F6 octahedra, and edges with two equivalent Li(3)F6 octahedra. The corner-sharing octahedral tilt angles range from 46-52°. In the third Li site, Li(3) is bonded to two equivalent F(1), two equivalent F(2), and two equivalent F(6) atoms to form distorted LiF6 octahedra that share corners with two equivalent Li(4)F6 octahedra, corners with two equivalent In(1)F6 octahedra, edges with two equivalent Li(2)F6 octahedra, edges with two equivalent In(2)F6 octahedra, and faces with two equivalent Li(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 46-49°. In the fourth Li site, Li(4) is bonded to two equivalent F(3), two equivalent F(4), and two equivalent F(6) atoms to form LiF6 octahedra that share corners with two equivalent Li(3)F6 octahedra, corners with two equivalent In(1)F6 octahedra, corners with four equivalent In(2)F6 octahedra,  an edgeedge with one Li(1)F6 octahedra, and edges with two equivalent Zn(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 46-52°. Zn(1) is bonded to two equivalent F(3), two equivalent F(4), and two equivalent F(5) atoms to form ZnF6 octahedra that share corners with two equivalent In(2)F6 octahedra, corners with four equivalent In(1)F6 octahedra,  an edgeedge with one Li(2)F6 octahedra, and edges with two equivalent Li(4)F6 octahedra. The corner-sharing octahedral tilt angles are 50°. There are two inequivalent In sites. In the first In site, In(1) is bonded to two equivalent F(2), two equivalent F(4), and two equivalent F(5) atoms to form InF6 octahedra that share corners with two equivalent Li(3)F6 octahedra, corners with two equivalent Li(4)F6 octahedra, corners with four equivalent Li(2)F6 octahedra, corners with four equivalent Zn(1)F6 octahedra, and  an edgeedge with one Li(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 47-52°. In the second In site, In(2) is bonded to two equivalent F(1), two equivalent F(3), and two equivalent F(6) atoms to form InF6 octahedra that share corners with two equivalent Zn(1)F6 octahedra, corners with four equivalent Li(1)F6 octahedra, corners with four equivalent Li(4)F6 octahedra,  an edgeedge with one Li(2)F6 octahedra, and edges with two equivalent Li(3)F6 octahedra. The corner-sharing octahedral tilt angles range from 42-52°. There are six inequivalent F sites. In the first F site, F(1) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Li(2), one Li(3), and one In(2) atom. In the second F site, F(2) is bonded in a 4-coordinate geometry to one Li(1), one Li(2), one Li(3), and one In(1) atom. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one Li(4), one Zn(1), and one In(2) atom. In the fourth F site, F(4) is bonded in a distorted T-shaped geometry to one Li(4), one Zn(1), and one In(1) atom. In the fifth F site, F(5) is bonded in a distorted T-shaped geometry to one Li(2), one Zn(1), and one In(1) atom. In the sixth F site, F(6) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(3), one Li(4), and one In(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li4ZnIn2F12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.873
_cell_length_b   5.086
_cell_length_c   18.059
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   447.525
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.000  0.704  1.0
  Li  Li1  1  0.500  0.500  0.792  1.0
  Li  Li2  1  0.000  0.500  0.292  1.0
  Li  Li3  1  0.500  0.000  0.204  1.0
  Li  Li4  1  0.000  0.000  0.225  1.0
  Li  Li5  1  0.500  0.000  0.725  1.0
  Li  Li6  1  0.000  0.000  0.549  1.0
  Li  Li7  1  0.500  0.000  0.049  1.0
  Zn  Zn8  1  0.500  0.500  0.957  1.0
  Zn  Zn9  1  0.000  0.500  0.457  1.0
  In  In10  1  0.000  0.000  0.879  1.0
  In  In11  1  0.500  0.500  0.618  1.0
  In  In12  1  0.000  0.500  0.118  1.0
  In  In13  1  0.500  0.000  0.379  1.0
  F  F14  1  0.705  0.691  0.707  1.0
  F  F15  1  0.767  0.160  0.791  1.0
  F  F16  1  0.233  0.840  0.791  1.0
  F  F17  1  0.295  0.309  0.707  1.0
  F  F18  1  0.267  0.840  0.291  1.0
  F  F19  1  0.205  0.309  0.207  1.0
  F  F20  1  0.795  0.691  0.207  1.0
  F  F21  1  0.733  0.160  0.291  1.0
  F  F22  1  0.764  0.672  0.538  1.0
  F  F23  1  0.740  0.167  0.961  1.0
  F  F24  1  0.260  0.833  0.961  1.0
  F  F25  1  0.236  0.328  0.538  1.0
  F  F26  1  0.240  0.833  0.461  1.0
  F  F27  1  0.264  0.328  0.038  1.0
  F  F28  1  0.736  0.672  0.038  1.0
  F  F29  1  0.760  0.167  0.461  1.0
  F  F30  1  0.768  0.667  0.375  1.0
  F  F31  1  0.743  0.165  0.128  1.0
  F  F32  1  0.257  0.835  0.128  1.0
  F  F33  1  0.232  0.333  0.375  1.0
  F  F34  1  0.243  0.835  0.628  1.0
  F  F35  1  0.268  0.333  0.875  1.0
  F  F36  1  0.732  0.667  0.875  1.0
  F  F37  1  0.757  0.165  0.628  1.0
[/CIF]
.
The structure described by Li4ZnIn2F12 crystallizes in the orthorhombic Pnc2 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to two equivalent F(1), two equivalent F(2), and two equivalent F(6) atoms to form LiF6 octahedra that share corners with four equivalent Li(2)F6 octahedra, corners with four equivalent In(2)F6 octahedra,  an edgeedge with one Li(4)F6 octahedra,  an edgeedge with one In(1)F6 octahedra, and faces with two equivalent Li(3)F6 octahedra. The corner-sharing octahedral tilt angles range from 42-51°. In the second Li site, Li(2) is bonded to two equivalent F(1), two equivalent F(2), and two equivalent F(5) atoms to form LiF6 octahedra that share corners with four equivalent Li(1)F6 octahedra, corners with four equivalent In(1)F6 octahedra,  an edgeedge with one Zn(1)F6 octahedra,  an edgeedge with one In(2)F6 octahedra, and edges with two equivalent Li(3)F6 octahedra. The corner-sharing octahedral tilt angles range from 46-52°. In the third Li site, Li(3) is bonded to two equivalent F(1), two equivalent F(2), and two equivalent F(6) atoms to form distorted LiF6 octahedra that share corners with two equivalent Li(4)F6 octahedra, corners with two equivalent In(1)F6 octahedra, edges with two equivalent Li(2)F6 octahedra, edges with two equivalent In(2)F6 octahedra, and faces with two equivalent Li(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 46-49°. In the fourth Li site, Li(4) is bonded to two equivalent F(3), two equivalent F(4), and two equivalent F(6) atoms to form LiF6 octahedra that share corners with two equivalent Li(3)F6 octahedra, corners with two equivalent In(1)F6 octahedra, corners with four equivalent In(2)F6 octahedra,  an edgeedge with one Li(1)F6 octahedra, and edges with two equivalent Zn(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 46-52°. Zn(1) is bonded to two equivalent F(3), two equivalent F(4), and two equivalent F(5) atoms to form ZnF6 octahedra that share corners with two equivalent In(2)F6 octahedra, corners with four equivalent In(1)F6 octahedra,  an edgeedge with one Li(2)F6 octahedra, and edges with two equivalent Li(4)F6 octahedra. The corner-sharing octahedral tilt angles are 50°. There are two inequivalent In sites. In the first In site, In(1) is bonded to two equivalent F(2), two equivalent F(4), and two equivalent F(5) atoms to form InF6 octahedra that share corners with two equivalent Li(3)F6 octahedra, corners with two equivalent Li(4)F6 octahedra, corners with four equivalent Li(2)F6 octahedra, corners with four equivalent Zn(1)F6 octahedra, and  an edgeedge with one Li(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 47-52°. In the second In site, In(2) is bonded to two equivalent F(1), two equivalent F(3), and two equivalent F(6) atoms to form InF6 octahedra that share corners with two equivalent Zn(1)F6 octahedra, corners with four equivalent Li(1)F6 octahedra, corners with four equivalent Li(4)F6 octahedra,  an edgeedge with one Li(2)F6 octahedra, and edges with two equivalent Li(3)F6 octahedra. The corner-sharing octahedral tilt angles range from 42-52°. There are six inequivalent F sites. In the first F site, F(1) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Li(2), one Li(3), and one In(2) atom. In the second F site, F(2) is bonded in a 4-coordinate geometry to one Li(1), one Li(2), one Li(3), and one In(1) atom. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one Li(4), one Zn(1), and one In(2) atom. In the fourth F site, F(4) is bonded in a distorted T-shaped geometry to one Li(4), one Zn(1), and one In(1) atom. In the fifth F site, F(5) is bonded in a distorted T-shaped geometry to one Li(2), one Zn(1), and one In(1) atom. In the sixth F site, F(6) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(3), one Li(4), and one In(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li4ZnIn2F12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.873
_cell_length_b   5.086
_cell_length_c   18.059
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   447.525
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.000  0.704  1.0
  Li  Li1  1  0.500  0.500  0.792  1.0
  Li  Li2  1  0.000  0.500  0.292  1.0
  Li  Li3  1  0.500  0.000  0.204  1.0
  Li  Li4  1  0.000  0.000  0.225  1.0
  Li  Li5  1  0.500  0.000  0.725  1.0
  Li  Li6  1  0.000  0.000  0.549  1.0
  Li  Li7  1  0.500  0.000  0.049  1.0
  Zn  Zn8  1  0.500  0.500  0.957  1.0
  Zn  Zn9  1  0.000  0.500  0.457  1.0
  In  In10  1  0.000  0.000  0.879  1.0
  In  In11  1  0.500  0.500  0.618  1.0
  In  In12  1  0.000  0.500  0.118  1.0
  In  In13  1  0.500  0.000  0.379  1.0
  F  F14  1  0.705  0.691  0.707  1.0
  F  F15  1  0.767  0.160  0.791  1.0
  F  F16  1  0.233  0.840  0.791  1.0
  F  F17  1  0.295  0.309  0.707  1.0
  F  F18  1  0.267  0.840  0.291  1.0
  F  F19  1  0.205  0.309  0.207  1.0
  F  F20  1  0.795  0.691  0.207  1.0
  F  F21  1  0.733  0.160  0.291  1.0
  F  F22  1  0.764  0.672  0.538  1.0
  F  F23  1  0.740  0.167  0.961  1.0
  F  F24  1  0.260  0.833  0.961  1.0
  F  F25  1  0.236  0.328  0.538  1.0
  F  F26  1  0.240  0.833  0.461  1.0
  F  F27  1  0.264  0.328  0.038  1.0
  F  F28  1  0.736  0.672  0.038  1.0
  F  F29  1  0.760  0.167  0.461  1.0
  F  F30  1  0.768  0.667  0.375  1.0
  F  F31  1  0.743  0.165  0.128  1.0
  F  F32  1  0.257  0.835  0.128  1.0
  F  F33  1  0.232  0.333  0.375  1.0
  F  F34  1  0.243  0.835  0.628  1.0
  F  F35  1  0.268  0.333  0.875  1.0
  F  F36  1  0.732  0.667  0.875  1.0
  F  F37  1  0.757  0.165  0.628  1.0
[/CIF]
.