The compound described by NaZnSb is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. Na(1) is bonded in a 9-coordinate geometry to four equivalent Zn(1) and five equivalent Sb(1) atoms. Zn(1) is bonded in a 4-coordinate geometry to four equivalent Na(1) and four equivalent Sb(1) atoms. Sb(1) is bonded in a 9-coordinate geometry to five equivalent Na(1) and four equivalent Zn(1) atoms. is represented by the CIF file [CIF]
data_NaZnSb
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.430
_cell_length_b   4.430
_cell_length_c   7.405
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   145.325
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.750  0.750  0.343  1.0
  Na  Na1  1  0.250  0.250  0.657  1.0
  Zn  Zn2  1  0.250  0.750  0.000  1.0
  Zn  Zn3  1  0.750  0.250  0.000  1.0
  Sb  Sb4  1  0.250  0.250  0.223  1.0
  Sb  Sb5  1  0.750  0.750  0.777  1.0
[/CIF]
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The compound described by NaZnSb is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. Na(1) is bonded in a 9-coordinate geometry to four equivalent Zn(1) and five equivalent Sb(1) atoms. Zn(1) is bonded in a 4-coordinate geometry to four equivalent Na(1) and four equivalent Sb(1) atoms. Sb(1) is bonded in a 9-coordinate geometry to five equivalent Na(1) and four equivalent Zn(1) atoms. is represented by the CIF file [CIF]
data_NaZnSb
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.430
_cell_length_b   4.430
_cell_length_c   7.405
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   145.325
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.750  0.750  0.343  1.0
  Na  Na1  1  0.250  0.250  0.657  1.0
  Zn  Zn2  1  0.250  0.750  0.000  1.0
  Zn  Zn3  1  0.750  0.250  0.000  1.0
  Sb  Sb4  1  0.250  0.250  0.223  1.0
  Sb  Sb5  1  0.750  0.750  0.777  1.0
[/CIF]
.