The crystal structure described by PrN3O11(O2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 7782-44-7 molecules and two PrN3O11 clusters. In each PrN3O11 cluster, Pr(1) is bonded in a 8-coordinate geometry to one O(11), one O(13), one O(2), one O(3), one O(4), one O(5), one O(7), and one O(9) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(4), one O(5), and one O(6) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one O(7), one O(8), and one O(9) atom. There are eleven inequivalent O sites. In the first O site, O(13) is bonded in an L-shaped geometry to one Pr(1) and one O(11) atom. In the second O site, O(1) is bonded in a single-bond geometry to one N(1) atom. In the third O site, O(2) is bonded in a water-like geometry to one Pr(1) and one N(1) atom. In the fourth O site, O(3) is bonded in an L-shaped geometry to one Pr(1) and one N(1) atom. In the fifth O site, O(4) is bonded in a water-like geometry to one Pr(1) and one N(2) atom. In the sixth O site, O(5) is bonded in a distorted L-shaped geometry to one Pr(1) and one N(2) atom. In the seventh O site, O(6) is bonded in a single-bond geometry to one N(2) atom. In the eighth O site, O(7) is bonded in a distorted L-shaped geometry to one Pr(1) and one N(3) atom. In the ninth O site, O(8) is bonded in a single-bond geometry to one N(3) atom. In the tenth O site, O(9) is bonded in a distorted L-shaped geometry to one Pr(1) and one N(3) atom. In the eleventh O site, O(11) is bonded in a 2-coordinate geometry to one Pr(1) and one O(13) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Pr(NO5)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.095
_cell_length_b   11.701
_cell_length_c   7.073
_cell_angle_alpha   91.508
_cell_angle_beta   115.141
_cell_angle_gamma   109.129
_symmetry_Int_Tables_number   1
_cell_volume   631.578
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pr  Pr0  1  0.867  0.712  0.862  1.0
  Pr  Pr1  1  0.133  0.288  0.138  1.0
  N  N2  1  0.658  0.836  0.923  1.0
  N  N3  1  0.342  0.164  0.077  1.0
  N  N4  1  0.663  0.481  0.927  1.0
  N  N5  1  0.337  0.519  0.073  1.0
  N  N6  1  0.761  0.181  0.837  1.0
  N  N7  1  0.239  0.819  0.163  1.0
  O  O8  1  0.569  0.881  0.961  1.0
  O  O9  1  0.431  0.119  0.039  1.0
  O  O10  1  0.812  0.843  0.070  1.0
  O  O11  1  0.188  0.157  0.930  1.0
  O  O12  1  0.612  0.777  0.737  1.0
  O  O13  1  0.388  0.223  0.263  1.0
  O  O14  1  0.821  0.555  0.067  1.0
  O  O15  1  0.179  0.445  0.933  1.0
  O  O16  1  0.611  0.507  0.739  1.0
  O  O17  1  0.389  0.493  0.261  1.0
  O  O18  1  0.574  0.395  0.974  1.0
  O  O19  1  0.426  0.605  0.026  1.0
  O  O20  1  0.845  0.299  0.912  1.0
  O  O21  1  0.155  0.701  0.088  1.0
  O  O22  1  0.612  0.138  0.692  1.0
  O  O23  1  0.388  0.862  0.308  1.0
  O  O24  1  0.850  0.113  0.925  1.0
  O  O25  1  0.150  0.887  0.075  1.0
  O  O26  1  0.834  0.942  0.533  1.0
  O  O27  1  0.166  0.058  0.467  1.0
  O  O28  1  0.849  0.714  0.441  1.0
  O  O29  1  0.151  0.286  0.559  1.0
  O  O30  1  0.836  0.456  0.538  1.0
  O  O31  1  0.164  0.544  0.462  1.0
  O  O32  1  0.993  0.253  0.426  1.0
  O  O33  1  0.007  0.747  0.574  1.0
  O  O34  1  0.761  0.006  0.426  1.0
  O  O35  1  0.239  0.994  0.574  1.0
  O  O36  1  0.779  0.353  0.431  1.0
  O  O37  1  0.221  0.647  0.569  1.0
[/CIF]
.
The crystal structure described by PrN3O11(O2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 7782-44-7 molecules and two PrN3O11 clusters. In each PrN3O11 cluster, Pr(1) is bonded in a 8-coordinate geometry to one O(11), one O(13), one O(2), one O(3), one O(4), one O(5), one O(7), and one O(9) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(4), one O(5), and one O(6) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one O(7), one O(8), and one O(9) atom. There are eleven inequivalent O sites. In the first O site, O(13) is bonded in an L-shaped geometry to one Pr(1) and one O(11) atom. In the second O site, O(1) is bonded in a single-bond geometry to one N(1) atom. In the third O site, O(2) is bonded in a water-like geometry to one Pr(1) and one N(1) atom. In the fourth O site, O(3) is bonded in an L-shaped geometry to one Pr(1) and one N(1) atom. In the fifth O site, O(4) is bonded in a water-like geometry to one Pr(1) and one N(2) atom. In the sixth O site, O(5) is bonded in a distorted L-shaped geometry to one Pr(1) and one N(2) atom. In the seventh O site, O(6) is bonded in a single-bond geometry to one N(2) atom. In the eighth O site, O(7) is bonded in a distorted L-shaped geometry to one Pr(1) and one N(3) atom. In the ninth O site, O(8) is bonded in a single-bond geometry to one N(3) atom. In the tenth O site, O(9) is bonded in a distorted L-shaped geometry to one Pr(1) and one N(3) atom. In the eleventh O site, O(11) is bonded in a 2-coordinate geometry to one Pr(1) and one O(13) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Pr(NO5)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.095
_cell_length_b   11.701
_cell_length_c   7.073
_cell_angle_alpha   91.508
_cell_angle_beta   115.141
_cell_angle_gamma   109.129
_symmetry_Int_Tables_number   1
_cell_volume   631.578
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pr  Pr0  1  0.867  0.712  0.862  1.0
  Pr  Pr1  1  0.133  0.288  0.138  1.0
  N  N2  1  0.658  0.836  0.923  1.0
  N  N3  1  0.342  0.164  0.077  1.0
  N  N4  1  0.663  0.481  0.927  1.0
  N  N5  1  0.337  0.519  0.073  1.0
  N  N6  1  0.761  0.181  0.837  1.0
  N  N7  1  0.239  0.819  0.163  1.0
  O  O8  1  0.569  0.881  0.961  1.0
  O  O9  1  0.431  0.119  0.039  1.0
  O  O10  1  0.812  0.843  0.070  1.0
  O  O11  1  0.188  0.157  0.930  1.0
  O  O12  1  0.612  0.777  0.737  1.0
  O  O13  1  0.388  0.223  0.263  1.0
  O  O14  1  0.821  0.555  0.067  1.0
  O  O15  1  0.179  0.445  0.933  1.0
  O  O16  1  0.611  0.507  0.739  1.0
  O  O17  1  0.389  0.493  0.261  1.0
  O  O18  1  0.574  0.395  0.974  1.0
  O  O19  1  0.426  0.605  0.026  1.0
  O  O20  1  0.845  0.299  0.912  1.0
  O  O21  1  0.155  0.701  0.088  1.0
  O  O22  1  0.612  0.138  0.692  1.0
  O  O23  1  0.388  0.862  0.308  1.0
  O  O24  1  0.850  0.113  0.925  1.0
  O  O25  1  0.150  0.887  0.075  1.0
  O  O26  1  0.834  0.942  0.533  1.0
  O  O27  1  0.166  0.058  0.467  1.0
  O  O28  1  0.849  0.714  0.441  1.0
  O  O29  1  0.151  0.286  0.559  1.0
  O  O30  1  0.836  0.456  0.538  1.0
  O  O31  1  0.164  0.544  0.462  1.0
  O  O32  1  0.993  0.253  0.426  1.0
  O  O33  1  0.007  0.747  0.574  1.0
  O  O34  1  0.761  0.006  0.426  1.0
  O  O35  1  0.239  0.994  0.574  1.0
  O  O36  1  0.779  0.353  0.431  1.0
  O  O37  1  0.221  0.647  0.569  1.0
[/CIF]
.