The material structure described by NiIn2N2 crystallizes in the orthorhombic Pmmn space group. Ni(1) is bonded in a bent 150 degrees geometry to two equivalent N(1) atoms. In(1) is bonded to five equivalent N(1) atoms to form a mixture of distorted edge and corner-sharing InN5 square pyramids. N(1) is bonded to one Ni(1) and five equivalent In(1) atoms to form a mixture of edge and corner-sharing NIn5Ni octahedra. The corner-sharing octahedral tilt angles range from 7-22°. is represented by the CIF card [CIF]
data_In2NiN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.337
_cell_length_b   3.390
_cell_length_c   11.838
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   133.904
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.750  0.749  0.103  1.0
  In  In1  1  0.750  0.749  0.397  1.0
  In  In2  1  0.250  0.251  0.897  1.0
  In  In3  1  0.250  0.251  0.603  1.0
  Ni  Ni4  1  0.750  0.835  0.750  1.0
  Ni  Ni5  1  0.250  0.165  0.250  1.0
  N  N6  1  0.750  0.728  0.592  1.0
  N  N7  1  0.750  0.728  0.908  1.0
  N  N8  1  0.250  0.272  0.408  1.0
  N  N9  1  0.250  0.272  0.092  1.0
[/CIF]
.
The material structure described by NiIn2N2 crystallizes in the orthorhombic Pmmn space group. Ni(1) is bonded in a bent 150 degrees geometry to two equivalent N(1) atoms. In(1) is bonded to five equivalent N(1) atoms to form a mixture of distorted edge and corner-sharing InN5 square pyramids. N(1) is bonded to one Ni(1) and five equivalent In(1) atoms to form a mixture of edge and corner-sharing NIn5Ni octahedra. The corner-sharing octahedral tilt angles range from 7-22°. is represented by the CIF card [CIF]
data_In2NiN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.337
_cell_length_b   3.390
_cell_length_c   11.838
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   133.904
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.750  0.749  0.103  1.0
  In  In1  1  0.750  0.749  0.397  1.0
  In  In2  1  0.250  0.251  0.897  1.0
  In  In3  1  0.250  0.251  0.603  1.0
  Ni  Ni4  1  0.750  0.835  0.750  1.0
  Ni  Ni5  1  0.250  0.165  0.250  1.0
  N  N6  1  0.750  0.728  0.592  1.0
  N  N7  1  0.750  0.728  0.908  1.0
  N  N8  1  0.250  0.272  0.408  1.0
  N  N9  1  0.250  0.272  0.092  1.0
[/CIF]
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