The compound described by NaPdN crystallizes in the orthorhombic Pnma space group. Na(1) is bonded in a 2-coordinate geometry to four equivalent N(1) atoms. Pd(1) is bonded in a 2-coordinate geometry to three equivalent N(1) atoms. N(1) is bonded to four equivalent Na(1) and three equivalent Pd(1) atoms to form a mixture of distorted edge and corner-sharing NNa4Pd3 pentagonal bipyramids. is represented by the CIF card [CIF]
data_NaPdN
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.926
_cell_length_b   3.735
_cell_length_c   6.186
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   206.215
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.667  0.250  0.075  1.0
  Na  Na1  1  0.167  0.250  0.425  1.0
  Na  Na2  1  0.333  0.750  0.925  1.0
  Na  Na3  1  0.833  0.750  0.575  1.0
  Pd  Pd4  1  0.547  0.250  0.637  1.0
  Pd  Pd5  1  0.047  0.250  0.863  1.0
  Pd  Pd6  1  0.453  0.750  0.363  1.0
  Pd  Pd7  1  0.953  0.750  0.137  1.0
  N  N8  1  0.925  0.250  0.225  1.0
  N  N9  1  0.425  0.250  0.275  1.0
  N  N10  1  0.075  0.750  0.775  1.0
  N  N11  1  0.575  0.750  0.725  1.0
[/CIF]
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The compound described by NaPdN crystallizes in the orthorhombic Pnma space group. Na(1) is bonded in a 2-coordinate geometry to four equivalent N(1) atoms. Pd(1) is bonded in a 2-coordinate geometry to three equivalent N(1) atoms. N(1) is bonded to four equivalent Na(1) and three equivalent Pd(1) atoms to form a mixture of distorted edge and corner-sharing NNa4Pd3 pentagonal bipyramids. is represented by the CIF card [CIF]
data_NaPdN
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.926
_cell_length_b   3.735
_cell_length_c   6.186
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   206.215
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.667  0.250  0.075  1.0
  Na  Na1  1  0.167  0.250  0.425  1.0
  Na  Na2  1  0.333  0.750  0.925  1.0
  Na  Na3  1  0.833  0.750  0.575  1.0
  Pd  Pd4  1  0.547  0.250  0.637  1.0
  Pd  Pd5  1  0.047  0.250  0.863  1.0
  Pd  Pd6  1  0.453  0.750  0.363  1.0
  Pd  Pd7  1  0.953  0.750  0.137  1.0
  N  N8  1  0.925  0.250  0.225  1.0
  N  N9  1  0.425  0.250  0.275  1.0
  N  N10  1  0.075  0.750  0.775  1.0
  N  N11  1  0.575  0.750  0.725  1.0
[/CIF]
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