The crystal structure described by Bi is beta Polonium-like structured and crystallizes in the monoclinic P2_1/m space group. There are two inequivalent Bi sites. In the first Bi site, Bi(1) is bonded to six equivalent Bi(2) atoms to form a mixture of edge and corner-sharing BiBi6 octahedra. The corner-sharing octahedral tilt angles range from 7-21°. In the second Bi site, Bi(2) is bonded to six equivalent Bi(1) atoms to form a mixture of edge and corner-sharing BiBi6 octahedra. The corner-sharing octahedral tilt angles range from 7-21°. is represented by the CIF card [CIF]
data_Bi
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.293
_cell_length_b   3.293
_cell_length_c   6.457
_cell_angle_alpha   90.372
_cell_angle_beta   89.628
_cell_angle_gamma   89.970
_symmetry_Int_Tables_number   1
_cell_volume   70.025
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.564  0.936  0.749  1.0
  Bi  Bi1  1  0.436  0.064  0.251  1.0
[/CIF]
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The crystal structure described by Bi is beta Polonium-like structured and crystallizes in the monoclinic P2_1/m space group. There are two inequivalent Bi sites. In the first Bi site, Bi(1) is bonded to six equivalent Bi(2) atoms to form a mixture of edge and corner-sharing BiBi6 octahedra. The corner-sharing octahedral tilt angles range from 7-21°. In the second Bi site, Bi(2) is bonded to six equivalent Bi(1) atoms to form a mixture of edge and corner-sharing BiBi6 octahedra. The corner-sharing octahedral tilt angles range from 7-21°. is represented by the CIF card [CIF]
data_Bi
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.293
_cell_length_b   3.293
_cell_length_c   6.457
_cell_angle_alpha   90.372
_cell_angle_beta   89.628
_cell_angle_gamma   89.970
_symmetry_Int_Tables_number   1
_cell_volume   70.025
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.564  0.936  0.749  1.0
  Bi  Bi1  1  0.436  0.064  0.251  1.0
[/CIF]
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