The structure described by RbSb3S5O crystallizes in the triclinic P-1 space group. Rb(1) is bonded in a 7-coordinate geometry to one S(1), one S(2), one S(4), two equivalent S(5), and two equivalent O(1) atoms. There are three inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a see-saw-like geometry to one S(1), one S(5), and two equivalent S(3) atoms. In the second Sb site, Sb(2) is bonded in a 3-coordinate geometry to one S(4) and two equivalent S(2) atoms. In the third Sb site, Sb(3) is bonded in a distorted rectangular see-saw-like geometry to one S(4), one S(5), and two equivalent S(1) atoms. There are five inequivalent S sites. In the first S site, S(1) is bonded in a distorted rectangular see-saw-like geometry to one Rb(1), one Sb(1), and two equivalent Sb(3) atoms. In the second S site, S(2) is bonded in a 3-coordinate geometry to one Rb(1) and two equivalent Sb(2) atoms. In the third S site, S(3) is bonded in a distorted L-shaped geometry to two equivalent Sb(1) atoms. In the fourth S site, S(4) is bonded in a distorted single-bond geometry to one Rb(1), one Sb(2), one Sb(3), and one O(1) atom. In the fifth S site, S(5) is bonded to two equivalent Rb(1), one Sb(1), and one Sb(3) atom to form corner-sharing SRb2Sb2 trigonal pyramids. O(1) is bonded in a 1-coordinate geometry to two equivalent Rb(1) and one S(4) atom. is represented by the CIF card [CIF]
data_RbSb3S5O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.972
_cell_length_b   9.119
_cell_length_c   10.999
_cell_angle_alpha   76.637
_cell_angle_beta   86.370
_cell_angle_gamma   83.248
_symmetry_Int_Tables_number   1
_cell_volume   578.339
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.787  0.867  0.159  1.0
  Rb  Rb1  1  0.213  0.133  0.841  1.0
  Sb  Sb2  1  0.716  0.342  0.464  1.0
  Sb  Sb3  1  0.284  0.658  0.536  1.0
  Sb  Sb4  1  0.296  0.480  0.125  1.0
  Sb  Sb5  1  0.704  0.520  0.875  1.0
  Sb  Sb6  1  0.283  0.082  0.368  1.0
  Sb  Sb7  1  0.717  0.918  0.632  1.0
  S  S8  1  0.693  0.087  0.376  1.0
  S  S9  1  0.307  0.913  0.624  1.0
  S  S10  1  0.705  0.480  0.115  1.0
  S  S11  1  0.295  0.520  0.885  1.0
  S  S12  1  0.315  0.415  0.422  1.0
  S  S13  1  0.685  0.585  0.578  1.0
  S  S14  1  0.324  0.193  0.117  1.0
  S  S15  1  0.676  0.807  0.883  1.0
  S  S16  1  0.296  0.824  0.319  1.0
  S  S17  1  0.704  0.176  0.681  1.0
  O  O18  1  0.553  0.156  0.052  1.0
  O  O19  1  0.447  0.844  0.948  1.0
[/CIF]
.
The structure described by RbSb3S5O crystallizes in the triclinic P-1 space group. Rb(1) is bonded in a 7-coordinate geometry to one S(1), one S(2), one S(4), two equivalent S(5), and two equivalent O(1) atoms. There are three inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a see-saw-like geometry to one S(1), one S(5), and two equivalent S(3) atoms. In the second Sb site, Sb(2) is bonded in a 3-coordinate geometry to one S(4) and two equivalent S(2) atoms. In the third Sb site, Sb(3) is bonded in a distorted rectangular see-saw-like geometry to one S(4), one S(5), and two equivalent S(1) atoms. There are five inequivalent S sites. In the first S site, S(1) is bonded in a distorted rectangular see-saw-like geometry to one Rb(1), one Sb(1), and two equivalent Sb(3) atoms. In the second S site, S(2) is bonded in a 3-coordinate geometry to one Rb(1) and two equivalent Sb(2) atoms. In the third S site, S(3) is bonded in a distorted L-shaped geometry to two equivalent Sb(1) atoms. In the fourth S site, S(4) is bonded in a distorted single-bond geometry to one Rb(1), one Sb(2), one Sb(3), and one O(1) atom. In the fifth S site, S(5) is bonded to two equivalent Rb(1), one Sb(1), and one Sb(3) atom to form corner-sharing SRb2Sb2 trigonal pyramids. O(1) is bonded in a 1-coordinate geometry to two equivalent Rb(1) and one S(4) atom. is represented by the CIF card [CIF]
data_RbSb3S5O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.972
_cell_length_b   9.119
_cell_length_c   10.999
_cell_angle_alpha   76.637
_cell_angle_beta   86.370
_cell_angle_gamma   83.248
_symmetry_Int_Tables_number   1
_cell_volume   578.339
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.787  0.867  0.159  1.0
  Rb  Rb1  1  0.213  0.133  0.841  1.0
  Sb  Sb2  1  0.716  0.342  0.464  1.0
  Sb  Sb3  1  0.284  0.658  0.536  1.0
  Sb  Sb4  1  0.296  0.480  0.125  1.0
  Sb  Sb5  1  0.704  0.520  0.875  1.0
  Sb  Sb6  1  0.283  0.082  0.368  1.0
  Sb  Sb7  1  0.717  0.918  0.632  1.0
  S  S8  1  0.693  0.087  0.376  1.0
  S  S9  1  0.307  0.913  0.624  1.0
  S  S10  1  0.705  0.480  0.115  1.0
  S  S11  1  0.295  0.520  0.885  1.0
  S  S12  1  0.315  0.415  0.422  1.0
  S  S13  1  0.685  0.585  0.578  1.0
  S  S14  1  0.324  0.193  0.117  1.0
  S  S15  1  0.676  0.807  0.883  1.0
  S  S16  1  0.296  0.824  0.319  1.0
  S  S17  1  0.704  0.176  0.681  1.0
  O  O18  1  0.553  0.156  0.052  1.0
  O  O19  1  0.447  0.844  0.948  1.0
[/CIF]
.