The material structure described by B4N2O11 is Indium-like structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of two B4N2O11 clusters. There are four inequivalent B sites. In the first B site, B(1) is bonded in a trigonal planar geometry to one O(1), one O(6), and one O(7) atom. In the second B site, B(2) is bonded in a tetrahedral geometry to one O(10), one O(2), one O(8), and one O(9) atom. In the third B site, B(3) is bonded in a trigonal planar geometry to one O(3), one O(6), and one O(8) atom. In the fourth B site, B(4) is bonded in a trigonal planar geometry to one O(4), one O(7), and one O(9) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a water-like geometry to one O(3) and one O(5) atom. In the second N site, N(2) is bonded in a water-like geometry to one O(11) and one O(2) atom. There are eleven inequivalent O sites. In the first O site, O(11) is bonded in a distorted water-like geometry to one N(2) and one O(10) atom. In the second O site, O(1) is bonded in a single-bond geometry to one B(1) atom. In the third O site, O(2) is bonded in a water-like geometry to one B(2) and one N(2) atom. In the fourth O site, O(3) is bonded in a bent 120 degrees geometry to one B(3) and one N(1) atom. In the fifth O site, O(4) is bonded in a distorted single-bond geometry to one B(4) atom. In the sixth O site, O(5) is bonded in a single-bond geometry to one N(1) atom. In the seventh O site, O(6) is bonded in a bent 120 degrees geometry to one B(1) and one B(3) atom. In the eighth O site, O(7) is bonded in a bent 150 degrees geometry to one B(1) and one B(4) atom. In the ninth O site, O(8) is bonded in a bent 150 degrees geometry to one B(2) and one B(3) atom. In the tenth O site, O(9) is bonded in a bent 120 degrees geometry to one B(2) and one B(4) atom. In the eleventh O site, O(10) is bonded in a single-bond geometry to one B(2) and one O(11) atom. is represented by the CIF card [CIF]
data_B4N2O11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.749
_cell_length_b   7.883
_cell_length_c   11.622
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   97.124
_symmetry_Int_Tables_number   1
_cell_volume   522.619
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.948  0.112  0.805  1.0
  B  B1  1  0.052  0.888  0.305  1.0
  B  B2  1  0.571  0.398  0.689  1.0
  B  B3  1  0.429  0.602  0.189  1.0
  B  B4  1  0.918  0.414  0.838  1.0
  B  B5  1  0.082  0.586  0.338  1.0
  B  B6  1  0.500  0.102  0.763  1.0
  B  B7  1  0.500  0.898  0.263  1.0
  N  N8  1  0.141  0.301  0.418  1.0
  N  N9  1  0.859  0.699  0.918  1.0
  N  N10  1  0.570  0.614  0.544  1.0
  N  N11  1  0.430  0.386  0.044  1.0
  O  O12  1  0.088  0.988  0.773  1.0
  O  O13  1  0.912  0.012  0.273  1.0
  O  O14  1  0.623  0.466  0.555  1.0
  O  O15  1  0.377  0.534  0.055  1.0
  O  O16  1  0.957  0.526  0.931  1.0
  O  O17  1  0.043  0.474  0.431  1.0
  O  O18  1  0.323  0.999  0.822  1.0
  O  O19  1  0.677  0.001  0.322  1.0
  O  O20  1  0.087  0.217  0.499  1.0
  O  O21  1  0.913  0.783  0.999  1.0
  O  O22  1  0.031  0.269  0.848  1.0
  O  O23  1  0.969  0.731  0.348  1.0
  O  O24  1  0.715  0.055  0.789  1.0
  O  O25  1  0.285  0.945  0.289  1.0
  O  O26  1  0.784  0.443  0.745  1.0
  O  O27  1  0.216  0.557  0.245  1.0
  O  O28  1  0.459  0.230  0.690  1.0
  O  O29  1  0.541  0.770  0.190  1.0
  O  O30  1  0.396  0.523  0.712  1.0
  O  O31  1  0.604  0.477  0.212  1.0
  O  O32  1  0.450  0.661  0.633  1.0
  O  O33  1  0.550  0.339  0.133  1.0
[/CIF]
.
The material structure described by B4N2O11 is Indium-like structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of two B4N2O11 clusters. There are four inequivalent B sites. In the first B site, B(1) is bonded in a trigonal planar geometry to one O(1), one O(6), and one O(7) atom. In the second B site, B(2) is bonded in a tetrahedral geometry to one O(10), one O(2), one O(8), and one O(9) atom. In the third B site, B(3) is bonded in a trigonal planar geometry to one O(3), one O(6), and one O(8) atom. In the fourth B site, B(4) is bonded in a trigonal planar geometry to one O(4), one O(7), and one O(9) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a water-like geometry to one O(3) and one O(5) atom. In the second N site, N(2) is bonded in a water-like geometry to one O(11) and one O(2) atom. There are eleven inequivalent O sites. In the first O site, O(11) is bonded in a distorted water-like geometry to one N(2) and one O(10) atom. In the second O site, O(1) is bonded in a single-bond geometry to one B(1) atom. In the third O site, O(2) is bonded in a water-like geometry to one B(2) and one N(2) atom. In the fourth O site, O(3) is bonded in a bent 120 degrees geometry to one B(3) and one N(1) atom. In the fifth O site, O(4) is bonded in a distorted single-bond geometry to one B(4) atom. In the sixth O site, O(5) is bonded in a single-bond geometry to one N(1) atom. In the seventh O site, O(6) is bonded in a bent 120 degrees geometry to one B(1) and one B(3) atom. In the eighth O site, O(7) is bonded in a bent 150 degrees geometry to one B(1) and one B(4) atom. In the ninth O site, O(8) is bonded in a bent 150 degrees geometry to one B(2) and one B(3) atom. In the tenth O site, O(9) is bonded in a bent 120 degrees geometry to one B(2) and one B(4) atom. In the eleventh O site, O(10) is bonded in a single-bond geometry to one B(2) and one O(11) atom. is represented by the CIF card [CIF]
data_B4N2O11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.749
_cell_length_b   7.883
_cell_length_c   11.622
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   97.124
_symmetry_Int_Tables_number   1
_cell_volume   522.619
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.948  0.112  0.805  1.0
  B  B1  1  0.052  0.888  0.305  1.0
  B  B2  1  0.571  0.398  0.689  1.0
  B  B3  1  0.429  0.602  0.189  1.0
  B  B4  1  0.918  0.414  0.838  1.0
  B  B5  1  0.082  0.586  0.338  1.0
  B  B6  1  0.500  0.102  0.763  1.0
  B  B7  1  0.500  0.898  0.263  1.0
  N  N8  1  0.141  0.301  0.418  1.0
  N  N9  1  0.859  0.699  0.918  1.0
  N  N10  1  0.570  0.614  0.544  1.0
  N  N11  1  0.430  0.386  0.044  1.0
  O  O12  1  0.088  0.988  0.773  1.0
  O  O13  1  0.912  0.012  0.273  1.0
  O  O14  1  0.623  0.466  0.555  1.0
  O  O15  1  0.377  0.534  0.055  1.0
  O  O16  1  0.957  0.526  0.931  1.0
  O  O17  1  0.043  0.474  0.431  1.0
  O  O18  1  0.323  0.999  0.822  1.0
  O  O19  1  0.677  0.001  0.322  1.0
  O  O20  1  0.087  0.217  0.499  1.0
  O  O21  1  0.913  0.783  0.999  1.0
  O  O22  1  0.031  0.269  0.848  1.0
  O  O23  1  0.969  0.731  0.348  1.0
  O  O24  1  0.715  0.055  0.789  1.0
  O  O25  1  0.285  0.945  0.289  1.0
  O  O26  1  0.784  0.443  0.745  1.0
  O  O27  1  0.216  0.557  0.245  1.0
  O  O28  1  0.459  0.230  0.690  1.0
  O  O29  1  0.541  0.770  0.190  1.0
  O  O30  1  0.396  0.523  0.712  1.0
  O  O31  1  0.604  0.477  0.212  1.0
  O  O32  1  0.450  0.661  0.633  1.0
  O  O33  1  0.550  0.339  0.133  1.0
[/CIF]
.