The crystal structure described by Rb2PO3F crystallizes in the orthorhombic Pnma space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 8-coordinate geometry to three equivalent O(1), four equivalent O(2), and one F(1) atom. In the second Rb site, Rb(2) is bonded in a 7-coordinate geometry to two equivalent O(1), four equivalent O(2), and one F(1) atom. P(1) is bonded in a tetrahedral geometry to one O(1), two equivalent O(2), and one F(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Rb(2), three equivalent Rb(1), and one P(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Rb(1), two equivalent Rb(2), and one P(1) atom. F(1) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(2), and one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Rb2PO3F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.131
_cell_length_b   7.884
_cell_length_c   10.483
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   506.692
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.250  0.172  0.922  1.0
  Rb  Rb1  1  0.750  0.828  0.078  1.0
  Rb  Rb2  1  0.250  0.672  0.578  1.0
  Rb  Rb3  1  0.750  0.328  0.422  1.0
  Rb  Rb4  1  0.250  0.007  0.284  1.0
  Rb  Rb5  1  0.750  0.993  0.716  1.0
  Rb  Rb6  1  0.250  0.507  0.216  1.0
  Rb  Rb7  1  0.750  0.493  0.784  1.0
  P  P8  1  0.250  0.241  0.586  1.0
  P  P9  1  0.750  0.759  0.414  1.0
  P  P10  1  0.250  0.741  0.914  1.0
  P  P11  1  0.750  0.259  0.086  1.0
  O  O12  1  0.750  0.689  0.548  1.0
  O  O13  1  0.250  0.311  0.452  1.0
  O  O14  1  0.250  0.811  0.048  1.0
  O  O15  1  0.750  0.189  0.952  1.0
  O  O16  1  0.543  0.729  0.340  1.0
  O  O17  1  0.043  0.271  0.660  1.0
  O  O18  1  0.957  0.229  0.160  1.0
  O  O19  1  0.457  0.771  0.840  1.0
  O  O20  1  0.457  0.271  0.660  1.0
  O  O21  1  0.957  0.729  0.340  1.0
  O  O22  1  0.043  0.771  0.840  1.0
  O  O23  1  0.543  0.229  0.160  1.0
  F  F24  1  0.750  0.466  0.064  1.0
  F  F25  1  0.250  0.534  0.936  1.0
  F  F26  1  0.250  0.034  0.564  1.0
  F  F27  1  0.750  0.966  0.436  1.0
[/CIF]
.
The crystal structure described by Rb2PO3F crystallizes in the orthorhombic Pnma space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 8-coordinate geometry to three equivalent O(1), four equivalent O(2), and one F(1) atom. In the second Rb site, Rb(2) is bonded in a 7-coordinate geometry to two equivalent O(1), four equivalent O(2), and one F(1) atom. P(1) is bonded in a tetrahedral geometry to one O(1), two equivalent O(2), and one F(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Rb(2), three equivalent Rb(1), and one P(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Rb(1), two equivalent Rb(2), and one P(1) atom. F(1) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(2), and one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Rb2PO3F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.131
_cell_length_b   7.884
_cell_length_c   10.483
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   506.692
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.250  0.172  0.922  1.0
  Rb  Rb1  1  0.750  0.828  0.078  1.0
  Rb  Rb2  1  0.250  0.672  0.578  1.0
  Rb  Rb3  1  0.750  0.328  0.422  1.0
  Rb  Rb4  1  0.250  0.007  0.284  1.0
  Rb  Rb5  1  0.750  0.993  0.716  1.0
  Rb  Rb6  1  0.250  0.507  0.216  1.0
  Rb  Rb7  1  0.750  0.493  0.784  1.0
  P  P8  1  0.250  0.241  0.586  1.0
  P  P9  1  0.750  0.759  0.414  1.0
  P  P10  1  0.250  0.741  0.914  1.0
  P  P11  1  0.750  0.259  0.086  1.0
  O  O12  1  0.750  0.689  0.548  1.0
  O  O13  1  0.250  0.311  0.452  1.0
  O  O14  1  0.250  0.811  0.048  1.0
  O  O15  1  0.750  0.189  0.952  1.0
  O  O16  1  0.543  0.729  0.340  1.0
  O  O17  1  0.043  0.271  0.660  1.0
  O  O18  1  0.957  0.229  0.160  1.0
  O  O19  1  0.457  0.771  0.840  1.0
  O  O20  1  0.457  0.271  0.660  1.0
  O  O21  1  0.957  0.729  0.340  1.0
  O  O22  1  0.043  0.771  0.840  1.0
  O  O23  1  0.543  0.229  0.160  1.0
  F  F24  1  0.750  0.466  0.064  1.0
  F  F25  1  0.250  0.534  0.936  1.0
  F  F26  1  0.250  0.034  0.564  1.0
  F  F27  1  0.750  0.966  0.436  1.0
[/CIF]
.