The compound described by Mn6O7F5 is Hydrophilite-derived structured and crystallizes in the triclinic P1 space group. There are twelve inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(12), one O(5), one O(8), one F(6), and one F(7) atom to form MnO4F2 octahedra that share corners with two equivalent Mn(7)O4F2 octahedra, corners with two equivalent Mn(9)O4F2 octahedra, corners with four equivalent Mn(11)O4F2 octahedra,  an edgeedge with one Mn(2)O3F3 octahedra, and  an edgeedge with one Mn(5)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 45-59°. In the second Mn site, Mn(2) is bonded to one O(1), one O(11), one O(4), one F(1), one F(5), and one F(7) atom to form a mixture of edge and corner-sharing MnO3F3 octahedra. The corner-sharing octahedral tilt angles range from 42-62°. In the third Mn site, Mn(3) is bonded to one O(10), one O(3), one O(4), one O(7), one F(5), and one F(8) atom to form MnO4F2 octahedra that share corners with two equivalent Mn(8)O3F3 octahedra, corners with two equivalent Mn(9)O4F2 octahedra, corners with four equivalent Mn(10)O4F2 octahedra,  an edgeedge with one Mn(6)O2F4 octahedra, and  an edgeedge with one Mn(2)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 44-56°. In the fourth Mn site, Mn(4) is bonded to one O(14), one O(2), one O(6), one O(9), one F(10), and one F(9) atom to form MnO4F2 octahedra that share corners with two equivalent Mn(8)O3F3 octahedra, corners with two equivalent Mn(7)O4F2 octahedra, corners with four equivalent Mn(12)O3F3 octahedra,  an edgeedge with one Mn(6)O2F4 octahedra, and  an edgeedge with one Mn(5)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 46-64°. In the fifth Mn site, Mn(5) is bonded to one O(13), one O(2), one O(5), one F(10), one F(2), and one F(6) atom to form MnO3F3 octahedra that share corners with two equivalent Mn(12)O3F3 octahedra, corners with two equivalent Mn(11)O4F2 octahedra, corners with four equivalent Mn(7)O4F2 octahedra,  an edgeedge with one Mn(1)O4F2 octahedra, and  an edgeedge with one Mn(4)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 47-58°. In the sixth Mn site, Mn(6) is bonded to one O(3), one O(6), one F(3), one F(4), one F(8), and one F(9) atom to form MnO2F4 octahedra that share corners with two equivalent Mn(12)O3F3 octahedra, corners with two equivalent Mn(10)O4F2 octahedra, corners with four equivalent Mn(8)O3F3 octahedra,  an edgeedge with one Mn(3)O4F2 octahedra, and  an edgeedge with one Mn(4)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 43-60°. In the seventh Mn site, Mn(7) is bonded to one O(13), one O(14), one O(2), one O(8), one F(2), and one F(6) atom to form MnO4F2 octahedra that share corners with two equivalent Mn(1)O4F2 octahedra, corners with two equivalent Mn(4)O4F2 octahedra, corners with four equivalent Mn(5)O3F3 octahedra,  an edgeedge with one Mn(12)O3F3 octahedra, and  an edgeedge with one Mn(11)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 46-60°. In the eighth Mn site, Mn(8) is bonded to one O(10), one O(3), one O(9), one F(3), one F(4), and one F(9) atom to form MnO3F3 octahedra that share corners with two equivalent Mn(3)O4F2 octahedra, corners with two equivalent Mn(4)O4F2 octahedra, corners with four equivalent Mn(6)O2F4 octahedra,  an edgeedge with one Mn(12)O3F3 octahedra, and  an edgeedge with one Mn(10)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 43-60°. In the ninth Mn site, Mn(9) is bonded to one O(1), one O(11), one O(12), one O(7), one F(1), and one F(5) atom to form MnO4F2 octahedra that share corners with two equivalent Mn(1)O4F2 octahedra, corners with two equivalent Mn(3)O4F2 octahedra, corners with four equivalent Mn(2)O3F3 octahedra,  an edgeedge with one Mn(10)O4F2 octahedra, and  an edgeedge with one Mn(11)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 47-62°. In the tenth Mn site, Mn(10) is bonded to one O(10), one O(11), one O(4), one O(7), one F(3), and one F(8) atom to form MnO4F2 octahedra that share corners with two equivalent Mn(6)O2F4 octahedra, corners with two equivalent Mn(2)O3F3 octahedra, corners with four equivalent Mn(3)O4F2 octahedra,  an edgeedge with one Mn(8)O3F3 octahedra, and  an edgeedge with one Mn(9)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 43-59°. In the eleventh Mn site, Mn(11) is bonded to one O(12), one O(13), one O(5), one O(8), one F(1), and one F(7) atom to form MnO4F2 octahedra that share corners with two equivalent Mn(2)O3F3 octahedra, corners with two equivalent Mn(5)O3F3 octahedra, corners with four equivalent Mn(1)O4F2 octahedra,  an edgeedge with one Mn(7)O4F2 octahedra, and  an edgeedge with one Mn(9)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 42-58°. In the twelfth Mn site, Mn(12) is bonded to one O(14), one O(6), one O(9), one F(10), one F(2), and one F(4) atom to form MnO3F3 octahedra that share corners with two equivalent Mn(6)O2F4 octahedra, corners with two equivalent Mn(5)O3F3 octahedra, corners with four equivalent Mn(4)O4F2 octahedra,  an edgeedge with one Mn(8)O3F3 octahedra, and  an edgeedge with one Mn(7)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 47-64°. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Mn(1), one Mn(2), and one Mn(9) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Mn(4), one Mn(5), and one Mn(7) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Mn(3), one Mn(6), and one Mn(8) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Mn(10), one Mn(2), and one Mn(3) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one Mn(1), one Mn(11), and one Mn(5) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one Mn(12), one Mn(4), and one Mn(6) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Mn(10), one Mn(3), and one Mn(9) atom. In the eighth O site, O(8) is bonded in a trigonal planar geometry to one Mn(1), one Mn(11), and one Mn(7) atom. In the ninth O site, O(9) is bonded in a trigonal planar geometry to one Mn(12), one Mn(4), and one Mn(8) atom. In the tenth O site, O(10) is bonded in a trigonal planar geometry to one Mn(10), one Mn(3), and one Mn(8) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal planar geometry to one Mn(10), one Mn(2), and one Mn(9) atom. In the twelfth O site, O(12) is bonded in a trigonal planar geometry to one Mn(1), one Mn(11), and one Mn(9) atom. In the thirteenth O site, O(13) is bonded in a distorted trigonal planar geometry to one Mn(11), one Mn(5), and one Mn(7) atom. In the fourteenth O site, O(14) is bonded in a trigonal planar geometry to one Mn(12), one Mn(4), and one Mn(7) atom. There are ten inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one Mn(11), one Mn(2), and one Mn(9) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one Mn(12), one Mn(5), and one Mn(7) atom. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one Mn(10), one Mn(6), and one Mn(8) atom. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one Mn(12), one Mn(6), and one Mn(8) atom. In the fifth F site, F(5) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(3), and one Mn(9) atom. In the sixth F site, F(6) is bonded in a trigonal planar geometry to one Mn(1), one Mn(5), and one Mn(7) atom. In the seventh F site, F(7) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(11), and one Mn(2) atom. In the eighth F site, F(8) is bonded in a distorted trigonal planar geometry to one Mn(10), one Mn(3), and one Mn(6) atom. In the ninth F site, F(9) is bonded in a distorted trigonal planar geometry to one Mn(4), one Mn(6), and one Mn(8) atom. In the tenth F site, F(10) is bonded in a distorted trigonal planar geometry to one Mn(12), one Mn(4), and one Mn(5) atom. is represented by the CIF card [CIF]
data_Mn6O7F5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.572
_cell_length_b   5.640
_cell_length_c   15.331
_cell_angle_alpha   90.118
_cell_angle_beta   90.310
_cell_angle_gamma   90.386
_symmetry_Int_Tables_number   1
_cell_volume   395.278
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.977  0.840  0.410  1.0
  Mn  Mn1  1  0.990  0.155  0.244  1.0
  Mn  Mn2  1  0.982  0.840  0.081  1.0
  Mn  Mn3  1  0.980  0.834  0.743  1.0
  Mn  Mn4  1  0.997  0.150  0.575  1.0
  Mn  Mn5  1  0.969  0.140  0.913  1.0
  Mn  Mn6  1  0.502  0.653  0.586  1.0
  Mn  Mn7  1  0.502  0.658  0.922  1.0
  Mn  Mn8  1  0.500  0.651  0.255  1.0
  Mn  Mn9  1  0.495  0.366  0.094  1.0
  Mn  Mn10  1  0.498  0.365  0.426  1.0
  Mn  Mn11  1  0.511  0.362  0.753  1.0
  O  O12  1  0.781  0.887  0.300  1.0
  O  O13  1  0.782  0.891  0.634  1.0
  O  O14  1  0.778  0.884  0.971  1.0
  O  O15  1  0.768  0.115  0.136  1.0
  O  O16  1  0.767  0.114  0.467  1.0
  O  O17  1  0.769  0.107  0.802  1.0
  O  O18  1  0.721  0.603  0.147  1.0
  O  O19  1  0.718  0.609  0.478  1.0
  O  O20  1  0.719  0.601  0.817  1.0
  O  O21  1  0.273  0.617  0.030  1.0
  O  O22  1  0.276  0.384  0.197  1.0
  O  O23  1  0.272  0.614  0.362  1.0
  O  O24  1  0.279  0.382  0.529  1.0
  O  O25  1  0.280  0.618  0.694  1.0
  F  F26  1  0.741  0.381  0.319  1.0
  F  F27  1  0.764  0.391  0.642  1.0
  F  F28  1  0.729  0.381  0.985  1.0
  F  F29  1  0.246  0.381  0.869  1.0
  F  F30  1  0.234  0.883  0.184  1.0
  F  F31  1  0.229  0.879  0.516  1.0
  F  F32  1  0.246  0.128  0.357  1.0
  F  F33  1  0.241  0.130  0.023  1.0
  F  F34  1  0.231  0.877  0.852  1.0
  F  F35  1  0.252  0.128  0.688  1.0
[/CIF]
.
The compound described by Mn6O7F5 is Hydrophilite-derived structured and crystallizes in the triclinic P1 space group. There are twelve inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(12), one O(5), one O(8), one F(6), and one F(7) atom to form MnO4F2 octahedra that share corners with two equivalent Mn(7)O4F2 octahedra, corners with two equivalent Mn(9)O4F2 octahedra, corners with four equivalent Mn(11)O4F2 octahedra,  an edgeedge with one Mn(2)O3F3 octahedra, and  an edgeedge with one Mn(5)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 45-59°. In the second Mn site, Mn(2) is bonded to one O(1), one O(11), one O(4), one F(1), one F(5), and one F(7) atom to form a mixture of edge and corner-sharing MnO3F3 octahedra. The corner-sharing octahedral tilt angles range from 42-62°. In the third Mn site, Mn(3) is bonded to one O(10), one O(3), one O(4), one O(7), one F(5), and one F(8) atom to form MnO4F2 octahedra that share corners with two equivalent Mn(8)O3F3 octahedra, corners with two equivalent Mn(9)O4F2 octahedra, corners with four equivalent Mn(10)O4F2 octahedra,  an edgeedge with one Mn(6)O2F4 octahedra, and  an edgeedge with one Mn(2)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 44-56°. In the fourth Mn site, Mn(4) is bonded to one O(14), one O(2), one O(6), one O(9), one F(10), and one F(9) atom to form MnO4F2 octahedra that share corners with two equivalent Mn(8)O3F3 octahedra, corners with two equivalent Mn(7)O4F2 octahedra, corners with four equivalent Mn(12)O3F3 octahedra,  an edgeedge with one Mn(6)O2F4 octahedra, and  an edgeedge with one Mn(5)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 46-64°. In the fifth Mn site, Mn(5) is bonded to one O(13), one O(2), one O(5), one F(10), one F(2), and one F(6) atom to form MnO3F3 octahedra that share corners with two equivalent Mn(12)O3F3 octahedra, corners with two equivalent Mn(11)O4F2 octahedra, corners with four equivalent Mn(7)O4F2 octahedra,  an edgeedge with one Mn(1)O4F2 octahedra, and  an edgeedge with one Mn(4)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 47-58°. In the sixth Mn site, Mn(6) is bonded to one O(3), one O(6), one F(3), one F(4), one F(8), and one F(9) atom to form MnO2F4 octahedra that share corners with two equivalent Mn(12)O3F3 octahedra, corners with two equivalent Mn(10)O4F2 octahedra, corners with four equivalent Mn(8)O3F3 octahedra,  an edgeedge with one Mn(3)O4F2 octahedra, and  an edgeedge with one Mn(4)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 43-60°. In the seventh Mn site, Mn(7) is bonded to one O(13), one O(14), one O(2), one O(8), one F(2), and one F(6) atom to form MnO4F2 octahedra that share corners with two equivalent Mn(1)O4F2 octahedra, corners with two equivalent Mn(4)O4F2 octahedra, corners with four equivalent Mn(5)O3F3 octahedra,  an edgeedge with one Mn(12)O3F3 octahedra, and  an edgeedge with one Mn(11)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 46-60°. In the eighth Mn site, Mn(8) is bonded to one O(10), one O(3), one O(9), one F(3), one F(4), and one F(9) atom to form MnO3F3 octahedra that share corners with two equivalent Mn(3)O4F2 octahedra, corners with two equivalent Mn(4)O4F2 octahedra, corners with four equivalent Mn(6)O2F4 octahedra,  an edgeedge with one Mn(12)O3F3 octahedra, and  an edgeedge with one Mn(10)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 43-60°. In the ninth Mn site, Mn(9) is bonded to one O(1), one O(11), one O(12), one O(7), one F(1), and one F(5) atom to form MnO4F2 octahedra that share corners with two equivalent Mn(1)O4F2 octahedra, corners with two equivalent Mn(3)O4F2 octahedra, corners with four equivalent Mn(2)O3F3 octahedra,  an edgeedge with one Mn(10)O4F2 octahedra, and  an edgeedge with one Mn(11)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 47-62°. In the tenth Mn site, Mn(10) is bonded to one O(10), one O(11), one O(4), one O(7), one F(3), and one F(8) atom to form MnO4F2 octahedra that share corners with two equivalent Mn(6)O2F4 octahedra, corners with two equivalent Mn(2)O3F3 octahedra, corners with four equivalent Mn(3)O4F2 octahedra,  an edgeedge with one Mn(8)O3F3 octahedra, and  an edgeedge with one Mn(9)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 43-59°. In the eleventh Mn site, Mn(11) is bonded to one O(12), one O(13), one O(5), one O(8), one F(1), and one F(7) atom to form MnO4F2 octahedra that share corners with two equivalent Mn(2)O3F3 octahedra, corners with two equivalent Mn(5)O3F3 octahedra, corners with four equivalent Mn(1)O4F2 octahedra,  an edgeedge with one Mn(7)O4F2 octahedra, and  an edgeedge with one Mn(9)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 42-58°. In the twelfth Mn site, Mn(12) is bonded to one O(14), one O(6), one O(9), one F(10), one F(2), and one F(4) atom to form MnO3F3 octahedra that share corners with two equivalent Mn(6)O2F4 octahedra, corners with two equivalent Mn(5)O3F3 octahedra, corners with four equivalent Mn(4)O4F2 octahedra,  an edgeedge with one Mn(8)O3F3 octahedra, and  an edgeedge with one Mn(7)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 47-64°. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Mn(1), one Mn(2), and one Mn(9) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Mn(4), one Mn(5), and one Mn(7) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Mn(3), one Mn(6), and one Mn(8) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Mn(10), one Mn(2), and one Mn(3) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one Mn(1), one Mn(11), and one Mn(5) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one Mn(12), one Mn(4), and one Mn(6) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Mn(10), one Mn(3), and one Mn(9) atom. In the eighth O site, O(8) is bonded in a trigonal planar geometry to one Mn(1), one Mn(11), and one Mn(7) atom. In the ninth O site, O(9) is bonded in a trigonal planar geometry to one Mn(12), one Mn(4), and one Mn(8) atom. In the tenth O site, O(10) is bonded in a trigonal planar geometry to one Mn(10), one Mn(3), and one Mn(8) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal planar geometry to one Mn(10), one Mn(2), and one Mn(9) atom. In the twelfth O site, O(12) is bonded in a trigonal planar geometry to one Mn(1), one Mn(11), and one Mn(9) atom. In the thirteenth O site, O(13) is bonded in a distorted trigonal planar geometry to one Mn(11), one Mn(5), and one Mn(7) atom. In the fourteenth O site, O(14) is bonded in a trigonal planar geometry to one Mn(12), one Mn(4), and one Mn(7) atom. There are ten inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one Mn(11), one Mn(2), and one Mn(9) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one Mn(12), one Mn(5), and one Mn(7) atom. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one Mn(10), one Mn(6), and one Mn(8) atom. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one Mn(12), one Mn(6), and one Mn(8) atom. In the fifth F site, F(5) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(3), and one Mn(9) atom. In the sixth F site, F(6) is bonded in a trigonal planar geometry to one Mn(1), one Mn(5), and one Mn(7) atom. In the seventh F site, F(7) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(11), and one Mn(2) atom. In the eighth F site, F(8) is bonded in a distorted trigonal planar geometry to one Mn(10), one Mn(3), and one Mn(6) atom. In the ninth F site, F(9) is bonded in a distorted trigonal planar geometry to one Mn(4), one Mn(6), and one Mn(8) atom. In the tenth F site, F(10) is bonded in a distorted trigonal planar geometry to one Mn(12), one Mn(4), and one Mn(5) atom. is represented by the CIF card [CIF]
data_Mn6O7F5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.572
_cell_length_b   5.640
_cell_length_c   15.331
_cell_angle_alpha   90.118
_cell_angle_beta   90.310
_cell_angle_gamma   90.386
_symmetry_Int_Tables_number   1
_cell_volume   395.278
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.977  0.840  0.410  1.0
  Mn  Mn1  1  0.990  0.155  0.244  1.0
  Mn  Mn2  1  0.982  0.840  0.081  1.0
  Mn  Mn3  1  0.980  0.834  0.743  1.0
  Mn  Mn4  1  0.997  0.150  0.575  1.0
  Mn  Mn5  1  0.969  0.140  0.913  1.0
  Mn  Mn6  1  0.502  0.653  0.586  1.0
  Mn  Mn7  1  0.502  0.658  0.922  1.0
  Mn  Mn8  1  0.500  0.651  0.255  1.0
  Mn  Mn9  1  0.495  0.366  0.094  1.0
  Mn  Mn10  1  0.498  0.365  0.426  1.0
  Mn  Mn11  1  0.511  0.362  0.753  1.0
  O  O12  1  0.781  0.887  0.300  1.0
  O  O13  1  0.782  0.891  0.634  1.0
  O  O14  1  0.778  0.884  0.971  1.0
  O  O15  1  0.768  0.115  0.136  1.0
  O  O16  1  0.767  0.114  0.467  1.0
  O  O17  1  0.769  0.107  0.802  1.0
  O  O18  1  0.721  0.603  0.147  1.0
  O  O19  1  0.718  0.609  0.478  1.0
  O  O20  1  0.719  0.601  0.817  1.0
  O  O21  1  0.273  0.617  0.030  1.0
  O  O22  1  0.276  0.384  0.197  1.0
  O  O23  1  0.272  0.614  0.362  1.0
  O  O24  1  0.279  0.382  0.529  1.0
  O  O25  1  0.280  0.618  0.694  1.0
  F  F26  1  0.741  0.381  0.319  1.0
  F  F27  1  0.764  0.391  0.642  1.0
  F  F28  1  0.729  0.381  0.985  1.0
  F  F29  1  0.246  0.381  0.869  1.0
  F  F30  1  0.234  0.883  0.184  1.0
  F  F31  1  0.229  0.879  0.516  1.0
  F  F32  1  0.246  0.128  0.357  1.0
  F  F33  1  0.241  0.130  0.023  1.0
  F  F34  1  0.231  0.877  0.852  1.0
  F  F35  1  0.252  0.128  0.688  1.0
[/CIF]
.