The structure described by Ag5(Sn3S8)2 crystallizes in the orthorhombic C222_1 space group. There are four inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to two equivalent S(1), two equivalent S(4), and two equivalent S(6) atoms to form AgS6 octahedra that share corners with two equivalent Ag(2)S6 octahedra, corners with four equivalent Sn(2)S6 octahedra,  an edgeedge with one Ag(2)S6 octahedra,  an edgeedge with one Sn(4)S6 octahedra, edges with two equivalent Ag(3)S6 octahedra, edges with two equivalent Sn(1)S6 octahedra, and edges with two equivalent Sn(3)S6 octahedra. The corner-sharing octahedral tilt angles range from 1-10°. In the second Ag site, Ag(2) is bonded to two equivalent S(1), two equivalent S(2), and two equivalent S(6) atoms to form AgS6 octahedra that share corners with two equivalent Ag(1)S6 octahedra, corners with four equivalent Ag(3)S6 octahedra,  an edgeedge with one Ag(1)S6 octahedra, edges with two equivalent Sn(1)S6 octahedra, edges with two equivalent Sn(2)S6 octahedra, and edges with two equivalent Sn(3)S6 octahedra. The corner-sharing octahedral tilt angles range from 8-10°. In the third Ag site, Ag(3) is bonded to one S(2), one S(3), one S(4), one S(5), one S(6), and one S(8) atom to form AgS6 octahedra that share corners with two equivalent Ag(2)S6 octahedra, corners with two equivalent Sn(2)S6 octahedra, corners with two equivalent Sn(4)S6 octahedra,  an edgeedge with one Ag(1)S6 octahedra,  an edgeedge with one Ag(4)S6 octahedra,  an edgeedge with one Sn(3)S6 octahedra, edges with two equivalent Sn(1)S6 octahedra, and edges with two equivalent Sn(2)S6 octahedra. The corner-sharing octahedral tilt angles range from 2-10°. In the fourth Ag site, Ag(4) is bonded to two equivalent S(3), two equivalent S(7), and two equivalent S(8) atoms to form AgS6 octahedra that share edges with two equivalent Ag(3)S6 octahedra, edges with two equivalent Sn(1)S6 octahedra, edges with two equivalent Sn(2)S6 octahedra, and edges with two equivalent Sn(4)S6 octahedra. There are four inequivalent Sn sites. In the first Sn site, Sn(1) is bonded to one S(1), one S(2), one S(3), one S(4), one S(5), and one S(7) atom to form SnS6 octahedra that share  an edgeedge with one Ag(1)S6 octahedra,  an edgeedge with one Ag(2)S6 octahedra,  an edgeedge with one Ag(4)S6 octahedra,  an edgeedge with one Sn(3)S6 octahedra,  an edgeedge with one Sn(4)S6 octahedra, edges with two equivalent Ag(3)S6 octahedra, and edges with two equivalent Sn(2)S6 octahedra. In the second Sn site, Sn(2) is bonded to one S(2), one S(3), one S(4), one S(5), one S(6), and one S(8) atom to form SnS6 octahedra that share corners with two equivalent Ag(1)S6 octahedra, corners with two equivalent Ag(3)S6 octahedra,  an edgeedge with one Ag(2)S6 octahedra,  an edgeedge with one Ag(4)S6 octahedra,  an edgeedge with one Sn(3)S6 octahedra,  an edgeedge with one Sn(4)S6 octahedra, edges with two equivalent Ag(3)S6 octahedra, and edges with two equivalent Sn(1)S6 octahedra. The corner-sharing octahedral tilt angles range from 1-8°. In the third Sn site, Sn(3) is bonded to two equivalent S(1), two equivalent S(5), and two equivalent S(6) atoms to form SnS6 octahedra that share edges with two equivalent Ag(1)S6 octahedra, edges with two equivalent Ag(2)S6 octahedra, edges with two equivalent Ag(3)S6 octahedra, edges with two equivalent Sn(1)S6 octahedra, and edges with two equivalent Sn(2)S6 octahedra. In the fourth Sn site, Sn(4) is bonded to two equivalent S(4), two equivalent S(7), and two equivalent S(8) atoms to form SnS6 octahedra that share corners with four equivalent Ag(3)S6 octahedra,  an edgeedge with one Ag(1)S6 octahedra, edges with two equivalent Ag(4)S6 octahedra, edges with two equivalent Sn(1)S6 octahedra, and edges with two equivalent Sn(2)S6 octahedra. The corner-sharing octahedral tilt angles range from 2-6°. There are eight inequivalent S sites. In the first S site, S(1) is bonded in a rectangular see-saw-like geometry to one Ag(1), one Ag(2), one Sn(1), and one Sn(3) atom. In the second S site, S(2) is bonded in a rectangular see-saw-like geometry to one Ag(2), one Ag(3), one Sn(1), and one Sn(2) atom. In the third S site, S(3) is bonded in a rectangular see-saw-like geometry to one Ag(3), one Ag(4), one Sn(1), and one Sn(2) atom. In the fourth S site, S(4) is bonded to one Ag(1), one Ag(3), one Sn(1), one Sn(2), and one Sn(4) atom to form SAg2Sn3 square pyramids that share corners with two equivalent S(6)Ag3Sn2 square pyramids,  an edgeedge with one S(4)Ag2Sn3 square pyramid, and  an edgeedge with one S(6)Ag3Sn2 square pyramid. In the fifth S site, S(5) is bonded in a rectangular see-saw-like geometry to one Ag(3), one Sn(1), one Sn(2), and one Sn(3) atom. In the sixth S site, S(6) is bonded to one Ag(1), one Ag(2), one Ag(3), one Sn(2), and one Sn(3) atom to form SAg3Sn2 square pyramids that share  a cornercorner with one S(6)Ag3Sn2 square pyramid, corners with two equivalent S(4)Ag2Sn3 square pyramids,  an edgeedge with one S(4)Ag2Sn3 square pyramid, and  an edgeedge with one S(6)Ag3Sn2 square pyramid. In the seventh S site, S(7) is bonded in a distorted T-shaped geometry to one Ag(4), one Sn(1), and one Sn(4) atom. In the eighth S site, S(8) is bonded in a rectangular see-saw-like geometry to one Ag(3), one Ag(4), one Sn(2), and one Sn(4) atom. is represented by the CIF card [CIF]
data_Ag5(Sn3S8)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.741
_cell_length_b   10.741
_cell_length_c   10.722
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.971
_symmetry_Int_Tables_number   1
_cell_volume   1236.791
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.388  0.388  0.000  1.0
  Ag  Ag1  1  0.371  0.371  0.500  1.0
  Ag  Ag2  1  0.878  0.364  0.493  1.0
  Ag  Ag3  1  0.877  0.123  0.250  1.0
  Ag  Ag4  1  0.636  0.122  0.007  1.0
  Ag  Ag5  1  0.123  0.877  0.750  1.0
  Ag  Ag6  1  0.364  0.878  0.507  1.0
  Ag  Ag7  1  0.122  0.636  0.993  1.0
  Ag  Ag8  1  0.629  0.629  0.000  1.0
  Ag  Ag9  1  0.612  0.612  0.500  1.0
  Sn  Sn10  1  0.126  0.378  0.244  1.0
  Sn  Sn11  1  0.885  0.374  0.993  1.0
  Sn  Sn12  1  0.635  0.365  0.750  1.0
  Sn  Sn13  1  0.127  0.127  0.000  1.0
  Sn  Sn14  1  0.378  0.126  0.756  1.0
  Sn  Sn15  1  0.626  0.115  0.507  1.0
  Sn  Sn16  1  0.374  0.885  0.007  1.0
  Sn  Sn17  1  0.622  0.874  0.256  1.0
  Sn  Sn18  1  0.873  0.873  0.500  1.0
  Sn  Sn19  1  0.365  0.635  0.250  1.0
  Sn  Sn20  1  0.115  0.626  0.493  1.0
  Sn  Sn21  1  0.874  0.622  0.744  1.0
  S  S22  1  0.364  0.395  0.241  1.0
  S  S23  1  0.118  0.386  0.484  1.0
  S  S24  1  0.887  0.368  0.236  1.0
  S  S25  1  0.128  0.378  0.997  1.0
  S  S26  1  0.878  0.375  0.747  1.0
  S  S27  1  0.643  0.365  0.990  1.0
  S  S28  1  0.395  0.364  0.759  1.0
  S  S29  1  0.635  0.357  0.510  1.0
  S  S30  1  0.122  0.140  0.239  1.0
  S  S31  1  0.888  0.136  0.998  1.0
  S  S32  1  0.140  0.122  0.761  1.0
  S  S33  1  0.378  0.128  0.003  1.0
  S  S34  1  0.625  0.122  0.753  1.0
  S  S35  1  0.386  0.118  0.516  1.0
  S  S36  1  0.632  0.113  0.264  1.0
  S  S37  1  0.864  0.112  0.502  1.0
  S  S38  1  0.136  0.888  0.002  1.0
  S  S39  1  0.368  0.887  0.764  1.0
  S  S40  1  0.614  0.882  0.016  1.0
  S  S41  1  0.375  0.878  0.253  1.0
  S  S42  1  0.622  0.872  0.503  1.0
  S  S43  1  0.860  0.878  0.261  1.0
  S  S44  1  0.112  0.864  0.498  1.0
  S  S45  1  0.878  0.860  0.739  1.0
  S  S46  1  0.365  0.643  0.010  1.0
  S  S47  1  0.605  0.636  0.259  1.0
  S  S48  1  0.357  0.635  0.490  1.0
  S  S49  1  0.122  0.625  0.247  1.0
  S  S50  1  0.872  0.622  0.497  1.0
  S  S51  1  0.113  0.632  0.736  1.0
  S  S52  1  0.882  0.614  0.984  1.0
  S  S53  1  0.636  0.605  0.741  1.0
[/CIF]
.
The structure described by Ag5(Sn3S8)2 crystallizes in the orthorhombic C222_1 space group. There are four inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to two equivalent S(1), two equivalent S(4), and two equivalent S(6) atoms to form AgS6 octahedra that share corners with two equivalent Ag(2)S6 octahedra, corners with four equivalent Sn(2)S6 octahedra,  an edgeedge with one Ag(2)S6 octahedra,  an edgeedge with one Sn(4)S6 octahedra, edges with two equivalent Ag(3)S6 octahedra, edges with two equivalent Sn(1)S6 octahedra, and edges with two equivalent Sn(3)S6 octahedra. The corner-sharing octahedral tilt angles range from 1-10°. In the second Ag site, Ag(2) is bonded to two equivalent S(1), two equivalent S(2), and two equivalent S(6) atoms to form AgS6 octahedra that share corners with two equivalent Ag(1)S6 octahedra, corners with four equivalent Ag(3)S6 octahedra,  an edgeedge with one Ag(1)S6 octahedra, edges with two equivalent Sn(1)S6 octahedra, edges with two equivalent Sn(2)S6 octahedra, and edges with two equivalent Sn(3)S6 octahedra. The corner-sharing octahedral tilt angles range from 8-10°. In the third Ag site, Ag(3) is bonded to one S(2), one S(3), one S(4), one S(5), one S(6), and one S(8) atom to form AgS6 octahedra that share corners with two equivalent Ag(2)S6 octahedra, corners with two equivalent Sn(2)S6 octahedra, corners with two equivalent Sn(4)S6 octahedra,  an edgeedge with one Ag(1)S6 octahedra,  an edgeedge with one Ag(4)S6 octahedra,  an edgeedge with one Sn(3)S6 octahedra, edges with two equivalent Sn(1)S6 octahedra, and edges with two equivalent Sn(2)S6 octahedra. The corner-sharing octahedral tilt angles range from 2-10°. In the fourth Ag site, Ag(4) is bonded to two equivalent S(3), two equivalent S(7), and two equivalent S(8) atoms to form AgS6 octahedra that share edges with two equivalent Ag(3)S6 octahedra, edges with two equivalent Sn(1)S6 octahedra, edges with two equivalent Sn(2)S6 octahedra, and edges with two equivalent Sn(4)S6 octahedra. There are four inequivalent Sn sites. In the first Sn site, Sn(1) is bonded to one S(1), one S(2), one S(3), one S(4), one S(5), and one S(7) atom to form SnS6 octahedra that share  an edgeedge with one Ag(1)S6 octahedra,  an edgeedge with one Ag(2)S6 octahedra,  an edgeedge with one Ag(4)S6 octahedra,  an edgeedge with one Sn(3)S6 octahedra,  an edgeedge with one Sn(4)S6 octahedra, edges with two equivalent Ag(3)S6 octahedra, and edges with two equivalent Sn(2)S6 octahedra. In the second Sn site, Sn(2) is bonded to one S(2), one S(3), one S(4), one S(5), one S(6), and one S(8) atom to form SnS6 octahedra that share corners with two equivalent Ag(1)S6 octahedra, corners with two equivalent Ag(3)S6 octahedra,  an edgeedge with one Ag(2)S6 octahedra,  an edgeedge with one Ag(4)S6 octahedra,  an edgeedge with one Sn(3)S6 octahedra,  an edgeedge with one Sn(4)S6 octahedra, edges with two equivalent Ag(3)S6 octahedra, and edges with two equivalent Sn(1)S6 octahedra. The corner-sharing octahedral tilt angles range from 1-8°. In the third Sn site, Sn(3) is bonded to two equivalent S(1), two equivalent S(5), and two equivalent S(6) atoms to form SnS6 octahedra that share edges with two equivalent Ag(1)S6 octahedra, edges with two equivalent Ag(2)S6 octahedra, edges with two equivalent Ag(3)S6 octahedra, edges with two equivalent Sn(1)S6 octahedra, and edges with two equivalent Sn(2)S6 octahedra. In the fourth Sn site, Sn(4) is bonded to two equivalent S(4), two equivalent S(7), and two equivalent S(8) atoms to form SnS6 octahedra that share corners with four equivalent Ag(3)S6 octahedra,  an edgeedge with one Ag(1)S6 octahedra, edges with two equivalent Ag(4)S6 octahedra, edges with two equivalent Sn(1)S6 octahedra, and edges with two equivalent Sn(2)S6 octahedra. The corner-sharing octahedral tilt angles range from 2-6°. There are eight inequivalent S sites. In the first S site, S(1) is bonded in a rectangular see-saw-like geometry to one Ag(1), one Ag(2), one Sn(1), and one Sn(3) atom. In the second S site, S(2) is bonded in a rectangular see-saw-like geometry to one Ag(2), one Ag(3), one Sn(1), and one Sn(2) atom. In the third S site, S(3) is bonded in a rectangular see-saw-like geometry to one Ag(3), one Ag(4), one Sn(1), and one Sn(2) atom. In the fourth S site, S(4) is bonded to one Ag(1), one Ag(3), one Sn(1), one Sn(2), and one Sn(4) atom to form SAg2Sn3 square pyramids that share corners with two equivalent S(6)Ag3Sn2 square pyramids,  an edgeedge with one S(4)Ag2Sn3 square pyramid, and  an edgeedge with one S(6)Ag3Sn2 square pyramid. In the fifth S site, S(5) is bonded in a rectangular see-saw-like geometry to one Ag(3), one Sn(1), one Sn(2), and one Sn(3) atom. In the sixth S site, S(6) is bonded to one Ag(1), one Ag(2), one Ag(3), one Sn(2), and one Sn(3) atom to form SAg3Sn2 square pyramids that share  a cornercorner with one S(6)Ag3Sn2 square pyramid, corners with two equivalent S(4)Ag2Sn3 square pyramids,  an edgeedge with one S(4)Ag2Sn3 square pyramid, and  an edgeedge with one S(6)Ag3Sn2 square pyramid. In the seventh S site, S(7) is bonded in a distorted T-shaped geometry to one Ag(4), one Sn(1), and one Sn(4) atom. In the eighth S site, S(8) is bonded in a rectangular see-saw-like geometry to one Ag(3), one Ag(4), one Sn(2), and one Sn(4) atom. is represented by the CIF card [CIF]
data_Ag5(Sn3S8)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.741
_cell_length_b   10.741
_cell_length_c   10.722
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.971
_symmetry_Int_Tables_number   1
_cell_volume   1236.791
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.388  0.388  0.000  1.0
  Ag  Ag1  1  0.371  0.371  0.500  1.0
  Ag  Ag2  1  0.878  0.364  0.493  1.0
  Ag  Ag3  1  0.877  0.123  0.250  1.0
  Ag  Ag4  1  0.636  0.122  0.007  1.0
  Ag  Ag5  1  0.123  0.877  0.750  1.0
  Ag  Ag6  1  0.364  0.878  0.507  1.0
  Ag  Ag7  1  0.122  0.636  0.993  1.0
  Ag  Ag8  1  0.629  0.629  0.000  1.0
  Ag  Ag9  1  0.612  0.612  0.500  1.0
  Sn  Sn10  1  0.126  0.378  0.244  1.0
  Sn  Sn11  1  0.885  0.374  0.993  1.0
  Sn  Sn12  1  0.635  0.365  0.750  1.0
  Sn  Sn13  1  0.127  0.127  0.000  1.0
  Sn  Sn14  1  0.378  0.126  0.756  1.0
  Sn  Sn15  1  0.626  0.115  0.507  1.0
  Sn  Sn16  1  0.374  0.885  0.007  1.0
  Sn  Sn17  1  0.622  0.874  0.256  1.0
  Sn  Sn18  1  0.873  0.873  0.500  1.0
  Sn  Sn19  1  0.365  0.635  0.250  1.0
  Sn  Sn20  1  0.115  0.626  0.493  1.0
  Sn  Sn21  1  0.874  0.622  0.744  1.0
  S  S22  1  0.364  0.395  0.241  1.0
  S  S23  1  0.118  0.386  0.484  1.0
  S  S24  1  0.887  0.368  0.236  1.0
  S  S25  1  0.128  0.378  0.997  1.0
  S  S26  1  0.878  0.375  0.747  1.0
  S  S27  1  0.643  0.365  0.990  1.0
  S  S28  1  0.395  0.364  0.759  1.0
  S  S29  1  0.635  0.357  0.510  1.0
  S  S30  1  0.122  0.140  0.239  1.0
  S  S31  1  0.888  0.136  0.998  1.0
  S  S32  1  0.140  0.122  0.761  1.0
  S  S33  1  0.378  0.128  0.003  1.0
  S  S34  1  0.625  0.122  0.753  1.0
  S  S35  1  0.386  0.118  0.516  1.0
  S  S36  1  0.632  0.113  0.264  1.0
  S  S37  1  0.864  0.112  0.502  1.0
  S  S38  1  0.136  0.888  0.002  1.0
  S  S39  1  0.368  0.887  0.764  1.0
  S  S40  1  0.614  0.882  0.016  1.0
  S  S41  1  0.375  0.878  0.253  1.0
  S  S42  1  0.622  0.872  0.503  1.0
  S  S43  1  0.860  0.878  0.261  1.0
  S  S44  1  0.112  0.864  0.498  1.0
  S  S45  1  0.878  0.860  0.739  1.0
  S  S46  1  0.365  0.643  0.010  1.0
  S  S47  1  0.605  0.636  0.259  1.0
  S  S48  1  0.357  0.635  0.490  1.0
  S  S49  1  0.122  0.625  0.247  1.0
  S  S50  1  0.872  0.622  0.497  1.0
  S  S51  1  0.113  0.632  0.736  1.0
  S  S52  1  0.882  0.614  0.984  1.0
  S  S53  1  0.636  0.605  0.741  1.0
[/CIF]
.