The structure described by K3PdHS2(O3Cl)2 crystallizes in the orthorhombic Cmc2_1 space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 8-coordinate geometry to one O(3), two equivalent O(2), three equivalent O(1), and two equivalent Cl(1) atoms. In the second K site, K(2) is bonded in a 6-coordinate geometry to two equivalent O(2) and four equivalent Cl(1) atoms. Pd(1) is bonded in a square co-planar geometry to two equivalent S(1) and two equivalent Cl(1) atoms. H(1) is bonded in a linear geometry to two equivalent O(3) atoms. S(1) is bonded in a distorted trigonal non-coplanar geometry to one Pd(1), one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to three equivalent K(1) and one S(1) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one K(2), two equivalent K(1), and one S(1) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one K(1), one H(1), and one S(1) atom. Cl(1) is bonded to two equivalent K(1), two equivalent K(2), and one Pd(1) atom to form a mixture of distorted corner and face-sharing ClK4Pd square pyramids. is represented by the CIF file [CIF]
data_K3HPdS2(ClO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.320
_cell_length_b   9.320
_cell_length_c   7.144
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   110.508
_symmetry_Int_Tables_number   1
_cell_volume   581.216
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.418  0.864  0.095  1.0
  K  K1  1  0.864  0.418  0.095  1.0
  K  K2  1  0.582  0.136  0.595  1.0
  K  K3  1  0.136  0.582  0.595  1.0
  K  K4  1  0.879  0.879  0.273  1.0
  K  K5  1  0.121  0.121  0.773  1.0
  H  H6  1  0.511  0.511  0.522  1.0
  H  H7  1  0.489  0.489  0.022  1.0
  Pd  Pd8  1  0.752  0.752  0.750  1.0
  Pd  Pd9  1  0.248  0.248  0.250  1.0
  S  S10  1  0.539  0.757  0.592  1.0
  S  S11  1  0.757  0.539  0.592  1.0
  S  S12  1  0.461  0.243  0.092  1.0
  S  S13  1  0.243  0.461  0.092  1.0
  Cl  Cl14  1  0.769  0.991  0.899  1.0
  Cl  Cl15  1  0.991  0.769  0.899  1.0
  Cl  Cl16  1  0.231  0.009  0.399  1.0
  Cl  Cl17  1  0.009  0.231  0.399  1.0
  O  O18  1  0.437  0.817  0.703  1.0
  O  O19  1  0.817  0.437  0.703  1.0
  O  O20  1  0.563  0.183  0.203  1.0
  O  O21  1  0.183  0.563  0.203  1.0
  O  O22  1  0.597  0.854  0.423  1.0
  O  O23  1  0.854  0.597  0.423  1.0
  O  O24  1  0.403  0.146  0.923  1.0
  O  O25  1  0.146  0.403  0.923  1.0
  O  O26  1  0.438  0.595  0.528  1.0
  O  O27  1  0.595  0.438  0.528  1.0
  O  O28  1  0.562  0.405  0.028  1.0
  O  O29  1  0.405  0.562  0.028  1.0
[/CIF]
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The structure described by K3PdHS2(O3Cl)2 crystallizes in the orthorhombic Cmc2_1 space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 8-coordinate geometry to one O(3), two equivalent O(2), three equivalent O(1), and two equivalent Cl(1) atoms. In the second K site, K(2) is bonded in a 6-coordinate geometry to two equivalent O(2) and four equivalent Cl(1) atoms. Pd(1) is bonded in a square co-planar geometry to two equivalent S(1) and two equivalent Cl(1) atoms. H(1) is bonded in a linear geometry to two equivalent O(3) atoms. S(1) is bonded in a distorted trigonal non-coplanar geometry to one Pd(1), one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to three equivalent K(1) and one S(1) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one K(2), two equivalent K(1), and one S(1) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one K(1), one H(1), and one S(1) atom. Cl(1) is bonded to two equivalent K(1), two equivalent K(2), and one Pd(1) atom to form a mixture of distorted corner and face-sharing ClK4Pd square pyramids. is represented by the CIF file [CIF]
data_K3HPdS2(ClO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.320
_cell_length_b   9.320
_cell_length_c   7.144
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   110.508
_symmetry_Int_Tables_number   1
_cell_volume   581.216
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.418  0.864  0.095  1.0
  K  K1  1  0.864  0.418  0.095  1.0
  K  K2  1  0.582  0.136  0.595  1.0
  K  K3  1  0.136  0.582  0.595  1.0
  K  K4  1  0.879  0.879  0.273  1.0
  K  K5  1  0.121  0.121  0.773  1.0
  H  H6  1  0.511  0.511  0.522  1.0
  H  H7  1  0.489  0.489  0.022  1.0
  Pd  Pd8  1  0.752  0.752  0.750  1.0
  Pd  Pd9  1  0.248  0.248  0.250  1.0
  S  S10  1  0.539  0.757  0.592  1.0
  S  S11  1  0.757  0.539  0.592  1.0
  S  S12  1  0.461  0.243  0.092  1.0
  S  S13  1  0.243  0.461  0.092  1.0
  Cl  Cl14  1  0.769  0.991  0.899  1.0
  Cl  Cl15  1  0.991  0.769  0.899  1.0
  Cl  Cl16  1  0.231  0.009  0.399  1.0
  Cl  Cl17  1  0.009  0.231  0.399  1.0
  O  O18  1  0.437  0.817  0.703  1.0
  O  O19  1  0.817  0.437  0.703  1.0
  O  O20  1  0.563  0.183  0.203  1.0
  O  O21  1  0.183  0.563  0.203  1.0
  O  O22  1  0.597  0.854  0.423  1.0
  O  O23  1  0.854  0.597  0.423  1.0
  O  O24  1  0.403  0.146  0.923  1.0
  O  O25  1  0.146  0.403  0.923  1.0
  O  O26  1  0.438  0.595  0.528  1.0
  O  O27  1  0.595  0.438  0.528  1.0
  O  O28  1  0.562  0.405  0.028  1.0
  O  O29  1  0.405  0.562  0.028  1.0
[/CIF]
.