The material structure described by ZrF6(N(CH3)4)2 is Silicon tetrafluoride-derived structured and crystallizes in the trigonal R-3 space group. The structure is zero-dimensional and consists of six tetramethylammonium molecules and three ZrF6 clusters. In each ZrF6 cluster, Zr(1) is bonded in an octahedral geometry to six equivalent F(1) atoms. F(1) is bonded in a single-bond geometry to one Zr(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZrH24C8(NF3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.641
_cell_length_b   8.641
_cell_length_c   8.641
_cell_angle_alpha   58.712
_cell_angle_beta   58.712
_cell_angle_gamma   58.712
_symmetry_Int_Tables_number   1
_cell_volume   442.806
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr0  1  0.000  0.000  0.000  1.0
  H  H1  1  0.296  0.234  0.986  1.0
  H  H2  1  0.986  0.296  0.234  1.0
  H  H3  1  0.234  0.986  0.296  1.0
  H  H4  1  0.704  0.766  0.014  1.0
  H  H5  1  0.014  0.704  0.766  1.0
  H  H6  1  0.766  0.014  0.704  1.0
  H  H7  1  0.505  0.207  0.010  1.0
  H  H8  1  0.010  0.505  0.207  1.0
  H  H9  1  0.207  0.010  0.505  1.0
  H  H10  1  0.495  0.793  0.990  1.0
  H  H11  1  0.990  0.495  0.793  1.0
  H  H12  1  0.793  0.990  0.495  1.0
  H  H13  1  0.321  0.440  0.963  1.0
  H  H14  1  0.963  0.321  0.440  1.0
  H  H15  1  0.440  0.963  0.321  1.0
  H  H16  1  0.679  0.560  0.037  1.0
  H  H17  1  0.037  0.679  0.560  1.0
  H  H18  1  0.560  0.037  0.679  1.0
  H  H19  1  0.473  0.247  0.278  1.0
  H  H20  1  0.278  0.473  0.247  1.0
  H  H21  1  0.247  0.278  0.473  1.0
  H  H22  1  0.527  0.753  0.722  1.0
  H  H23  1  0.722  0.527  0.753  1.0
  H  H24  1  0.753  0.722  0.527  1.0
  C  C25  1  0.350  0.285  0.035  1.0
  C  C26  1  0.035  0.350  0.285  1.0
  C  C27  1  0.285  0.035  0.350  1.0
  C  C28  1  0.650  0.715  0.965  1.0
  C  C29  1  0.965  0.650  0.715  1.0
  C  C30  1  0.715  0.965  0.650  1.0
  C  C31  1  0.317  0.317  0.317  1.0
  C  C32  1  0.683  0.683  0.683  1.0
  N  N33  1  0.247  0.247  0.247  1.0
  N  N34  1  0.753  0.753  0.753  1.0
  F  F35  1  0.878  0.166  0.789  1.0
  F  F36  1  0.789  0.878  0.166  1.0
  F  F37  1  0.166  0.789  0.878  1.0
  F  F38  1  0.122  0.834  0.211  1.0
  F  F39  1  0.211  0.122  0.834  1.0
  F  F40  1  0.834  0.211  0.122  1.0
[/CIF]
.
The material structure described by ZrF6(N(CH3)4)2 is Silicon tetrafluoride-derived structured and crystallizes in the trigonal R-3 space group. The structure is zero-dimensional and consists of six tetramethylammonium molecules and three ZrF6 clusters. In each ZrF6 cluster, Zr(1) is bonded in an octahedral geometry to six equivalent F(1) atoms. F(1) is bonded in a single-bond geometry to one Zr(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZrH24C8(NF3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.641
_cell_length_b   8.641
_cell_length_c   8.641
_cell_angle_alpha   58.712
_cell_angle_beta   58.712
_cell_angle_gamma   58.712
_symmetry_Int_Tables_number   1
_cell_volume   442.806
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr0  1  0.000  0.000  0.000  1.0
  H  H1  1  0.296  0.234  0.986  1.0
  H  H2  1  0.986  0.296  0.234  1.0
  H  H3  1  0.234  0.986  0.296  1.0
  H  H4  1  0.704  0.766  0.014  1.0
  H  H5  1  0.014  0.704  0.766  1.0
  H  H6  1  0.766  0.014  0.704  1.0
  H  H7  1  0.505  0.207  0.010  1.0
  H  H8  1  0.010  0.505  0.207  1.0
  H  H9  1  0.207  0.010  0.505  1.0
  H  H10  1  0.495  0.793  0.990  1.0
  H  H11  1  0.990  0.495  0.793  1.0
  H  H12  1  0.793  0.990  0.495  1.0
  H  H13  1  0.321  0.440  0.963  1.0
  H  H14  1  0.963  0.321  0.440  1.0
  H  H15  1  0.440  0.963  0.321  1.0
  H  H16  1  0.679  0.560  0.037  1.0
  H  H17  1  0.037  0.679  0.560  1.0
  H  H18  1  0.560  0.037  0.679  1.0
  H  H19  1  0.473  0.247  0.278  1.0
  H  H20  1  0.278  0.473  0.247  1.0
  H  H21  1  0.247  0.278  0.473  1.0
  H  H22  1  0.527  0.753  0.722  1.0
  H  H23  1  0.722  0.527  0.753  1.0
  H  H24  1  0.753  0.722  0.527  1.0
  C  C25  1  0.350  0.285  0.035  1.0
  C  C26  1  0.035  0.350  0.285  1.0
  C  C27  1  0.285  0.035  0.350  1.0
  C  C28  1  0.650  0.715  0.965  1.0
  C  C29  1  0.965  0.650  0.715  1.0
  C  C30  1  0.715  0.965  0.650  1.0
  C  C31  1  0.317  0.317  0.317  1.0
  C  C32  1  0.683  0.683  0.683  1.0
  N  N33  1  0.247  0.247  0.247  1.0
  N  N34  1  0.753  0.753  0.753  1.0
  F  F35  1  0.878  0.166  0.789  1.0
  F  F36  1  0.789  0.878  0.166  1.0
  F  F37  1  0.166  0.789  0.878  1.0
  F  F38  1  0.122  0.834  0.211  1.0
  F  F39  1  0.211  0.122  0.834  1.0
  F  F40  1  0.834  0.211  0.122  1.0
[/CIF]
.