The compound described by Mn3(O2F)2 is Hydrophilite-derived structured and crystallizes in the triclinic P1 space group. There are six inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(2), one O(3), one O(4), one O(7), one O(8), and one F(4) atom to form MnO5F octahedra that share corners with two equivalent Mn(4)O3F3 octahedra, corners with two equivalent Mn(5)O4F2 octahedra, corners with four equivalent Mn(6)O3F3 octahedra,  an edgeedge with one Mn(2)O4F2 octahedra, and  an edgeedge with one Mn(3)O5F octahedra. The corner-sharing octahedral tilt angles range from 49-52°. In the second Mn site, Mn(2) is bonded to one O(4), one O(5), one O(6), one O(8), one F(1), and one F(2) atom to form MnO4F2 octahedra that share corners with two equivalent Mn(6)O3F3 octahedra, corners with two equivalent Mn(5)O4F2 octahedra, corners with four equivalent Mn(4)O3F3 octahedra,  an edgeedge with one Mn(1)O5F octahedra, and  an edgeedge with one Mn(3)O5F octahedra. The corner-sharing octahedral tilt angles range from 45-52°. In the third Mn site, Mn(3) is bonded to one O(1), one O(3), one O(5), one O(6), one O(7), and one F(3) atom to form MnO5F octahedra that share corners with two equivalent Mn(4)O3F3 octahedra, corners with two equivalent Mn(6)O3F3 octahedra, corners with four equivalent Mn(5)O4F2 octahedra,  an edgeedge with one Mn(2)O4F2 octahedra, and  an edgeedge with one Mn(1)O5F octahedra. The corner-sharing octahedral tilt angles range from 38-52°. In the fourth Mn site, Mn(4) is bonded to one O(1), one O(4), one O(6), one F(1), one F(2), and one F(4) atom to form MnO3F3 octahedra that share corners with two equivalent Mn(1)O5F octahedra, corners with two equivalent Mn(3)O5F octahedra, corners with four equivalent Mn(2)O4F2 octahedra,  an edgeedge with one Mn(6)O3F3 octahedra, and  an edgeedge with one Mn(5)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 49-52°. In the fifth Mn site, Mn(5) is bonded to one O(1), one O(2), one O(5), one O(7), one F(2), and one F(3) atom to form MnO4F2 octahedra that share corners with two equivalent Mn(2)O4F2 octahedra, corners with two equivalent Mn(1)O5F octahedra, corners with four equivalent Mn(3)O5F octahedra,  an edgeedge with one Mn(4)O3F3 octahedra, and  an edgeedge with one Mn(6)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 38-52°. In the sixth Mn site, Mn(6) is bonded to one O(2), one O(3), one O(8), one F(1), one F(3), and one F(4) atom to form MnO3F3 octahedra that share corners with two equivalent Mn(2)O4F2 octahedra, corners with two equivalent Mn(3)O5F octahedra, corners with four equivalent Mn(1)O5F octahedra,  an edgeedge with one Mn(4)O3F3 octahedra, and  an edgeedge with one Mn(5)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 50-52°. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Mn(3), one Mn(4), and one Mn(5) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(5), and one Mn(6) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Mn(1), one Mn(3), and one Mn(6) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Mn(1), one Mn(2), and one Mn(4) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one Mn(2), one Mn(3), and one Mn(5) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one Mn(2), one Mn(3), and one Mn(4) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Mn(1), one Mn(3), and one Mn(5) atom. In the eighth O site, O(8) is bonded in a trigonal planar geometry to one Mn(1), one Mn(2), and one Mn(6) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(4), and one Mn(6) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(4), and one Mn(5) atom. In the third F site, F(3) is bonded in a distorted T-shaped geometry to one Mn(3), one Mn(5), and one Mn(6) atom. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(4), and one Mn(6) atom. is represented by the CIF file [CIF]
data_Mn3(O2F)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.712
_cell_length_b   5.543
_cell_length_c   7.726
_cell_angle_alpha   84.157
_cell_angle_beta   85.264
_cell_angle_gamma   85.068
_symmetry_Int_Tables_number   1
_cell_volume   199.460
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.520  0.511  0.005  1.0
  Mn  Mn1  1  0.493  0.829  0.664  1.0
  Mn  Mn2  1  0.518  0.183  0.339  1.0
  Mn  Mn3  1  0.987  0.330  0.657  1.0
  Mn  Mn4  1  0.981  0.659  0.325  1.0
  Mn  Mn5  1  0.999  0.991  0.006  1.0
  O  O6  1  0.800  0.381  0.429  1.0
  O  O7  1  0.823  0.710  0.111  1.0
  O  O8  1  0.694  0.203  0.105  1.0
  O  O9  1  0.697  0.534  0.766  1.0
  O  O10  1  0.705  0.878  0.436  1.0
  O  O11  1  0.306  0.136  0.565  1.0
  O  O12  1  0.302  0.462  0.232  1.0
  O  O13  1  0.309  0.795  0.899  1.0
  F  F14  1  0.805  0.039  0.762  1.0
  F  F15  1  0.178  0.625  0.554  1.0
  F  F16  1  0.203  0.950  0.249  1.0
  F  F17  1  0.178  0.283  0.895  1.0
[/CIF]
.
The compound described by Mn3(O2F)2 is Hydrophilite-derived structured and crystallizes in the triclinic P1 space group. There are six inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(2), one O(3), one O(4), one O(7), one O(8), and one F(4) atom to form MnO5F octahedra that share corners with two equivalent Mn(4)O3F3 octahedra, corners with two equivalent Mn(5)O4F2 octahedra, corners with four equivalent Mn(6)O3F3 octahedra,  an edgeedge with one Mn(2)O4F2 octahedra, and  an edgeedge with one Mn(3)O5F octahedra. The corner-sharing octahedral tilt angles range from 49-52°. In the second Mn site, Mn(2) is bonded to one O(4), one O(5), one O(6), one O(8), one F(1), and one F(2) atom to form MnO4F2 octahedra that share corners with two equivalent Mn(6)O3F3 octahedra, corners with two equivalent Mn(5)O4F2 octahedra, corners with four equivalent Mn(4)O3F3 octahedra,  an edgeedge with one Mn(1)O5F octahedra, and  an edgeedge with one Mn(3)O5F octahedra. The corner-sharing octahedral tilt angles range from 45-52°. In the third Mn site, Mn(3) is bonded to one O(1), one O(3), one O(5), one O(6), one O(7), and one F(3) atom to form MnO5F octahedra that share corners with two equivalent Mn(4)O3F3 octahedra, corners with two equivalent Mn(6)O3F3 octahedra, corners with four equivalent Mn(5)O4F2 octahedra,  an edgeedge with one Mn(2)O4F2 octahedra, and  an edgeedge with one Mn(1)O5F octahedra. The corner-sharing octahedral tilt angles range from 38-52°. In the fourth Mn site, Mn(4) is bonded to one O(1), one O(4), one O(6), one F(1), one F(2), and one F(4) atom to form MnO3F3 octahedra that share corners with two equivalent Mn(1)O5F octahedra, corners with two equivalent Mn(3)O5F octahedra, corners with four equivalent Mn(2)O4F2 octahedra,  an edgeedge with one Mn(6)O3F3 octahedra, and  an edgeedge with one Mn(5)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 49-52°. In the fifth Mn site, Mn(5) is bonded to one O(1), one O(2), one O(5), one O(7), one F(2), and one F(3) atom to form MnO4F2 octahedra that share corners with two equivalent Mn(2)O4F2 octahedra, corners with two equivalent Mn(1)O5F octahedra, corners with four equivalent Mn(3)O5F octahedra,  an edgeedge with one Mn(4)O3F3 octahedra, and  an edgeedge with one Mn(6)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 38-52°. In the sixth Mn site, Mn(6) is bonded to one O(2), one O(3), one O(8), one F(1), one F(3), and one F(4) atom to form MnO3F3 octahedra that share corners with two equivalent Mn(2)O4F2 octahedra, corners with two equivalent Mn(3)O5F octahedra, corners with four equivalent Mn(1)O5F octahedra,  an edgeedge with one Mn(4)O3F3 octahedra, and  an edgeedge with one Mn(5)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 50-52°. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Mn(3), one Mn(4), and one Mn(5) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(5), and one Mn(6) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Mn(1), one Mn(3), and one Mn(6) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Mn(1), one Mn(2), and one Mn(4) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one Mn(2), one Mn(3), and one Mn(5) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one Mn(2), one Mn(3), and one Mn(4) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Mn(1), one Mn(3), and one Mn(5) atom. In the eighth O site, O(8) is bonded in a trigonal planar geometry to one Mn(1), one Mn(2), and one Mn(6) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(4), and one Mn(6) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(4), and one Mn(5) atom. In the third F site, F(3) is bonded in a distorted T-shaped geometry to one Mn(3), one Mn(5), and one Mn(6) atom. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(4), and one Mn(6) atom. is represented by the CIF file [CIF]
data_Mn3(O2F)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.712
_cell_length_b   5.543
_cell_length_c   7.726
_cell_angle_alpha   84.157
_cell_angle_beta   85.264
_cell_angle_gamma   85.068
_symmetry_Int_Tables_number   1
_cell_volume   199.460
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.520  0.511  0.005  1.0
  Mn  Mn1  1  0.493  0.829  0.664  1.0
  Mn  Mn2  1  0.518  0.183  0.339  1.0
  Mn  Mn3  1  0.987  0.330  0.657  1.0
  Mn  Mn4  1  0.981  0.659  0.325  1.0
  Mn  Mn5  1  0.999  0.991  0.006  1.0
  O  O6  1  0.800  0.381  0.429  1.0
  O  O7  1  0.823  0.710  0.111  1.0
  O  O8  1  0.694  0.203  0.105  1.0
  O  O9  1  0.697  0.534  0.766  1.0
  O  O10  1  0.705  0.878  0.436  1.0
  O  O11  1  0.306  0.136  0.565  1.0
  O  O12  1  0.302  0.462  0.232  1.0
  O  O13  1  0.309  0.795  0.899  1.0
  F  F14  1  0.805  0.039  0.762  1.0
  F  F15  1  0.178  0.625  0.554  1.0
  F  F16  1  0.203  0.950  0.249  1.0
  F  F17  1  0.178  0.283  0.895  1.0
[/CIF]
.