The material described by OsC3O3I2 is Indium-like structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of two OsC3O3I2 clusters. Os(1) is bonded to one C(2), two equivalent C(1), one I(2), and two equivalent I(1) atoms to form distorted edge-sharing OsC3I3 octahedra. There are two inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Os(1) and one O(1) atom. In the second C site, C(2) is bonded in a linear geometry to one Os(1) and one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(2) atom. There are two inequivalent I sites. In the first I site, I(1) is bonded in an L-shaped geometry to two equivalent Os(1) atoms. In the second I site, I(2) is bonded in a single-bond geometry to one Os(1) atom. is represented by the CIF file [CIF]
data_OsC3I2O3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.824
_cell_length_b   6.824
_cell_length_c   9.836
_cell_angle_alpha   75.917
_cell_angle_beta   75.917
_cell_angle_gamma   69.759
_symmetry_Int_Tables_number   1
_cell_volume   410.398
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Os  Os0  1  0.568  0.568  0.278  1.0
  Os  Os1  1  0.432  0.432  0.722  1.0
  C  C2  1  0.413  0.777  0.143  1.0
  C  C3  1  0.263  0.263  0.715  1.0
  C  C4  1  0.777  0.413  0.143  1.0
  C  C5  1  0.587  0.223  0.857  1.0
  C  C6  1  0.737  0.737  0.285  1.0
  C  C7  1  0.223  0.587  0.857  1.0
  I  I8  1  0.740  0.260  0.500  1.0
  I  I9  1  0.678  0.678  0.731  1.0
  I  I10  1  0.322  0.322  0.269  1.0
  I  I11  1  0.260  0.740  0.500  1.0
  O  O12  1  0.689  0.094  0.934  1.0
  O  O13  1  0.159  0.159  0.717  1.0
  O  O14  1  0.311  0.906  0.066  1.0
  O  O15  1  0.906  0.311  0.066  1.0
  O  O16  1  0.094  0.689  0.934  1.0
  O  O17  1  0.841  0.841  0.283  1.0
[/CIF]
.
The material described by OsC3O3I2 is Indium-like structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of two OsC3O3I2 clusters. Os(1) is bonded to one C(2), two equivalent C(1), one I(2), and two equivalent I(1) atoms to form distorted edge-sharing OsC3I3 octahedra. There are two inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Os(1) and one O(1) atom. In the second C site, C(2) is bonded in a linear geometry to one Os(1) and one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(2) atom. There are two inequivalent I sites. In the first I site, I(1) is bonded in an L-shaped geometry to two equivalent Os(1) atoms. In the second I site, I(2) is bonded in a single-bond geometry to one Os(1) atom. is represented by the CIF file [CIF]
data_OsC3I2O3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.824
_cell_length_b   6.824
_cell_length_c   9.836
_cell_angle_alpha   75.917
_cell_angle_beta   75.917
_cell_angle_gamma   69.759
_symmetry_Int_Tables_number   1
_cell_volume   410.398
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Os  Os0  1  0.568  0.568  0.278  1.0
  Os  Os1  1  0.432  0.432  0.722  1.0
  C  C2  1  0.413  0.777  0.143  1.0
  C  C3  1  0.263  0.263  0.715  1.0
  C  C4  1  0.777  0.413  0.143  1.0
  C  C5  1  0.587  0.223  0.857  1.0
  C  C6  1  0.737  0.737  0.285  1.0
  C  C7  1  0.223  0.587  0.857  1.0
  I  I8  1  0.740  0.260  0.500  1.0
  I  I9  1  0.678  0.678  0.731  1.0
  I  I10  1  0.322  0.322  0.269  1.0
  I  I11  1  0.260  0.740  0.500  1.0
  O  O12  1  0.689  0.094  0.934  1.0
  O  O13  1  0.159  0.159  0.717  1.0
  O  O14  1  0.311  0.906  0.066  1.0
  O  O15  1  0.906  0.311  0.066  1.0
  O  O16  1  0.094  0.689  0.934  1.0
  O  O17  1  0.841  0.841  0.283  1.0
[/CIF]
.