The compound described by GdAu3C6(N2O)3 crystallizes in the hexagonal P6_3/mcm space group. Gd(1) is bonded in a 9-coordinate geometry to six equivalent N(1) and three equivalent O(1) atoms. Au(1) is bonded in a linear geometry to two equivalent C(1) atoms. C(1) is bonded in a distorted single-bond geometry to one Au(1) and one N(1) atom. N(1) is bonded in a linear geometry to one Gd(1) and one C(1) atom. O(1) is bonded in a single-bond geometry to one Gd(1) atom. is represented by the CIF file [CIF]
data_GdAu3C6(N2O)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.924
_cell_length_b   6.924
_cell_length_c   17.664
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   733.478
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Gd  Gd0  1  0.000  0.000  0.250  1.0
  Gd  Gd1  1  0.000  0.000  0.750  1.0
  Au  Au2  1  0.500  0.500  0.500  1.0
  Au  Au3  1  0.500  0.000  0.500  1.0
  Au  Au4  1  0.000  0.500  0.500  1.0
  Au  Au5  1  0.500  0.500  0.000  1.0
  Au  Au6  1  0.500  0.000  0.000  1.0
  Au  Au7  1  0.000  0.500  0.000  1.0
  C  C8  1  0.350  0.350  0.404  1.0
  C  C9  1  0.650  0.000  0.404  1.0
  C  C10  1  0.000  0.650  0.404  1.0
  C  C11  1  0.650  0.650  0.596  1.0
  C  C12  1  0.350  0.000  0.596  1.0
  C  C13  1  0.000  0.350  0.596  1.0
  C  C14  1  0.650  0.650  0.904  1.0
  C  C15  1  0.350  0.000  0.904  1.0
  C  C16  1  0.000  0.350  0.904  1.0
  C  C17  1  0.350  0.350  0.096  1.0
  C  C18  1  0.650  0.000  0.096  1.0
  C  C19  1  0.000  0.650  0.096  1.0
  N  N20  1  0.254  0.254  0.349  1.0
  N  N21  1  0.746  0.000  0.349  1.0
  N  N22  1  0.000  0.746  0.349  1.0
  N  N23  1  0.746  0.746  0.651  1.0
  N  N24  1  0.254  0.000  0.651  1.0
  N  N25  1  0.000  0.254  0.651  1.0
  N  N26  1  0.746  0.746  0.849  1.0
  N  N27  1  0.254  0.000  0.849  1.0
  N  N28  1  0.000  0.254  0.849  1.0
  N  N29  1  0.254  0.254  0.151  1.0
  N  N30  1  0.746  0.000  0.151  1.0
  N  N31  1  0.000  0.746  0.151  1.0
  O  O32  1  0.650  0.650  0.250  1.0
  O  O33  1  0.350  0.000  0.250  1.0
  O  O34  1  0.000  0.350  0.250  1.0
  O  O35  1  0.350  0.350  0.750  1.0
  O  O36  1  0.650  0.000  0.750  1.0
  O  O37  1  0.000  0.650  0.750  1.0
[/CIF]
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The compound described by GdAu3C6(N2O)3 crystallizes in the hexagonal P6_3/mcm space group. Gd(1) is bonded in a 9-coordinate geometry to six equivalent N(1) and three equivalent O(1) atoms. Au(1) is bonded in a linear geometry to two equivalent C(1) atoms. C(1) is bonded in a distorted single-bond geometry to one Au(1) and one N(1) atom. N(1) is bonded in a linear geometry to one Gd(1) and one C(1) atom. O(1) is bonded in a single-bond geometry to one Gd(1) atom. is represented by the CIF file [CIF]
data_GdAu3C6(N2O)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.924
_cell_length_b   6.924
_cell_length_c   17.664
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   733.478
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Gd  Gd0  1  0.000  0.000  0.250  1.0
  Gd  Gd1  1  0.000  0.000  0.750  1.0
  Au  Au2  1  0.500  0.500  0.500  1.0
  Au  Au3  1  0.500  0.000  0.500  1.0
  Au  Au4  1  0.000  0.500  0.500  1.0
  Au  Au5  1  0.500  0.500  0.000  1.0
  Au  Au6  1  0.500  0.000  0.000  1.0
  Au  Au7  1  0.000  0.500  0.000  1.0
  C  C8  1  0.350  0.350  0.404  1.0
  C  C9  1  0.650  0.000  0.404  1.0
  C  C10  1  0.000  0.650  0.404  1.0
  C  C11  1  0.650  0.650  0.596  1.0
  C  C12  1  0.350  0.000  0.596  1.0
  C  C13  1  0.000  0.350  0.596  1.0
  C  C14  1  0.650  0.650  0.904  1.0
  C  C15  1  0.350  0.000  0.904  1.0
  C  C16  1  0.000  0.350  0.904  1.0
  C  C17  1  0.350  0.350  0.096  1.0
  C  C18  1  0.650  0.000  0.096  1.0
  C  C19  1  0.000  0.650  0.096  1.0
  N  N20  1  0.254  0.254  0.349  1.0
  N  N21  1  0.746  0.000  0.349  1.0
  N  N22  1  0.000  0.746  0.349  1.0
  N  N23  1  0.746  0.746  0.651  1.0
  N  N24  1  0.254  0.000  0.651  1.0
  N  N25  1  0.000  0.254  0.651  1.0
  N  N26  1  0.746  0.746  0.849  1.0
  N  N27  1  0.254  0.000  0.849  1.0
  N  N28  1  0.000  0.254  0.849  1.0
  N  N29  1  0.254  0.254  0.151  1.0
  N  N30  1  0.746  0.000  0.151  1.0
  N  N31  1  0.000  0.746  0.151  1.0
  O  O32  1  0.650  0.650  0.250  1.0
  O  O33  1  0.350  0.000  0.250  1.0
  O  O34  1  0.000  0.350  0.250  1.0
  O  O35  1  0.350  0.350  0.750  1.0
  O  O36  1  0.650  0.000  0.750  1.0
  O  O37  1  0.000  0.650  0.750  1.0
[/CIF]
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