The crystal structure described by Pt(SCl3)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one Pt(SCl3)2 cluster. Pt(1) is bonded in a square co-planar geometry to two equivalent S(1) and two equivalent Cl(2) atoms. S(1) is bonded in a trigonal non-coplanar geometry to one Pt(1), one Cl(1), and one Cl(3) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one S(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Pt(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Pt(SCl3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.895
_cell_length_b   6.949
_cell_length_c   8.399
_cell_angle_alpha   104.099
_cell_angle_beta   96.996
_cell_angle_gamma   92.981
_symmetry_Int_Tables_number   1
_cell_volume   274.036
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pt  Pt0  1  0.500  0.500  0.500  1.0
  S  S1  1  0.217  0.274  0.296  1.0
  S  S2  1  0.783  0.726  0.704  1.0
  Cl  Cl3  1  0.593  0.985  0.719  1.0
  Cl  Cl4  1  0.223  0.373  0.663  1.0
  Cl  Cl5  1  0.777  0.627  0.337  1.0
  Cl  Cl6  1  0.251  0.321  0.069  1.0
  Cl  Cl7  1  0.749  0.679  0.931  1.0
  Cl  Cl8  1  0.407  0.015  0.281  1.0
[/CIF]
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The crystal structure described by Pt(SCl3)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one Pt(SCl3)2 cluster. Pt(1) is bonded in a square co-planar geometry to two equivalent S(1) and two equivalent Cl(2) atoms. S(1) is bonded in a trigonal non-coplanar geometry to one Pt(1), one Cl(1), and one Cl(3) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one S(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Pt(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Pt(SCl3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.895
_cell_length_b   6.949
_cell_length_c   8.399
_cell_angle_alpha   104.099
_cell_angle_beta   96.996
_cell_angle_gamma   92.981
_symmetry_Int_Tables_number   1
_cell_volume   274.036
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pt  Pt0  1  0.500  0.500  0.500  1.0
  S  S1  1  0.217  0.274  0.296  1.0
  S  S2  1  0.783  0.726  0.704  1.0
  Cl  Cl3  1  0.593  0.985  0.719  1.0
  Cl  Cl4  1  0.223  0.373  0.663  1.0
  Cl  Cl5  1  0.777  0.627  0.337  1.0
  Cl  Cl6  1  0.251  0.321  0.069  1.0
  Cl  Cl7  1  0.749  0.679  0.931  1.0
  Cl  Cl8  1  0.407  0.015  0.281  1.0
[/CIF]
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