The compound described by Na2PdC2 crystallizes in the trigonal P-3m1 space group. Na(1) is bonded in a 6-coordinate geometry to three equivalent Pd(1) and three equivalent C(1) atoms. Pd(1) is bonded in a distorted linear geometry to six equivalent Na(1) and two equivalent C(1) atoms. C(1) is bonded to three equivalent Na(1), one Pd(1), and one C(1) atom to form distorted corner-sharing CNa3PdC trigonal bipyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_Na2PdC2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.512
_cell_length_b   4.512
_cell_length_c   5.283
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   93.147
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.667  0.333  0.280  1.0
  Na  Na1  1  0.333  0.667  0.720  1.0
  Pd  Pd2  1  0.000  0.000  0.000  1.0
  C  C3  1  0.000  0.000  0.380  1.0
  C  C4  1  0.000  0.000  0.620  1.0
[/CIF]
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The compound described by Na2PdC2 crystallizes in the trigonal P-3m1 space group. Na(1) is bonded in a 6-coordinate geometry to three equivalent Pd(1) and three equivalent C(1) atoms. Pd(1) is bonded in a distorted linear geometry to six equivalent Na(1) and two equivalent C(1) atoms. C(1) is bonded to three equivalent Na(1), one Pd(1), and one C(1) atom to form distorted corner-sharing CNa3PdC trigonal bipyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_Na2PdC2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.512
_cell_length_b   4.512
_cell_length_c   5.283
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   93.147
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.667  0.333  0.280  1.0
  Na  Na1  1  0.333  0.667  0.720  1.0
  Pd  Pd2  1  0.000  0.000  0.000  1.0
  C  C3  1  0.000  0.000  0.380  1.0
  C  C4  1  0.000  0.000  0.620  1.0
[/CIF]
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