The compound described by LaWN3 crystallizes in the trigonal R3m space group. La(1) is bonded to twelve equivalent N(1) atoms to form distorted LaN12 cuboctahedra that share corners with twelve equivalent La(1)N12 cuboctahedra, faces with six equivalent La(1)N12 cuboctahedra, and faces with eight equivalent W(1)N6 octahedra. W(1) is bonded to six equivalent N(1) atoms to form distorted WN6 octahedra that share corners with six equivalent W(1)N6 octahedra and faces with eight equivalent La(1)N12 cuboctahedra. The corner-sharing octahedral tilt angles are 15°. N(1) is bonded in a 6-coordinate geometry to four equivalent La(1) and two equivalent W(1) atoms. is represented by the CIF file [CIF]
data_LaWN3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.047
_cell_length_b   4.047
_cell_length_c   4.047
_cell_angle_alpha   89.572
_cell_angle_beta   89.572
_cell_angle_gamma   89.572
_symmetry_Int_Tables_number   1
_cell_volume   66.300
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.045  0.045  0.045  1.0
  W  W1  1  0.551  0.551  0.551  1.0
  N  N2  1  0.596  0.087  0.596  1.0
  N  N3  1  0.087  0.596  0.596  1.0
  N  N4  1  0.596  0.596  0.087  1.0
[/CIF]
.
The compound described by LaWN3 crystallizes in the trigonal R3m space group. La(1) is bonded to twelve equivalent N(1) atoms to form distorted LaN12 cuboctahedra that share corners with twelve equivalent La(1)N12 cuboctahedra, faces with six equivalent La(1)N12 cuboctahedra, and faces with eight equivalent W(1)N6 octahedra. W(1) is bonded to six equivalent N(1) atoms to form distorted WN6 octahedra that share corners with six equivalent W(1)N6 octahedra and faces with eight equivalent La(1)N12 cuboctahedra. The corner-sharing octahedral tilt angles are 15°. N(1) is bonded in a 6-coordinate geometry to four equivalent La(1) and two equivalent W(1) atoms. is represented by the CIF file [CIF]
data_LaWN3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.047
_cell_length_b   4.047
_cell_length_c   4.047
_cell_angle_alpha   89.572
_cell_angle_beta   89.572
_cell_angle_gamma   89.572
_symmetry_Int_Tables_number   1
_cell_volume   66.300
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.045  0.045  0.045  1.0
  W  W1  1  0.551  0.551  0.551  1.0
  N  N2  1  0.596  0.087  0.596  1.0
  N  N3  1  0.087  0.596  0.596  1.0
  N  N4  1  0.596  0.596  0.087  1.0
[/CIF]
.