The structure described by CrN5Cl2NO2 is Iron Boride structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four nitrous acid molecules and four CrN5Cl2 clusters. In each CrN5Cl2 cluster, Cr(1) is bonded in a 5-coordinate geometry to one N(1), one N(3), one N(4), and two equivalent N(2) atoms. There are four inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Cr(1) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Cr(1) atom. In the third N site, N(3) is bonded in a single-bond geometry to one Cr(1) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cr(1) and two equivalent Cl(1) atoms. Cl(1) is bonded in a single-bond geometry to one N(4) atom. is represented by the CIF card [CIF]
data_CrN6(ClO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.836
_cell_length_b   6.719
_cell_length_c   14.761
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   777.111
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.778  0.750  0.371  1.0
  Cr  Cr1  1  0.722  0.750  0.871  1.0
  Cr  Cr2  1  0.222  0.250  0.629  1.0
  Cr  Cr3  1  0.278  0.250  0.129  1.0
  N  N4  1  0.575  0.750  0.358  1.0
  N  N5  1  0.925  0.750  0.858  1.0
  N  N6  1  0.425  0.250  0.642  1.0
  N  N7  1  0.075  0.250  0.142  1.0
  N  N8  1  0.832  0.021  0.395  1.0
  N  N9  1  0.668  0.479  0.895  1.0
  N  N10  1  0.168  0.521  0.605  1.0
  N  N11  1  0.332  0.979  0.105  1.0
  N  N12  1  0.168  0.979  0.605  1.0
  N  N13  1  0.332  0.521  0.105  1.0
  N  N14  1  0.832  0.479  0.395  1.0
  N  N15  1  0.668  0.021  0.895  1.0
  N  N16  1  0.842  0.750  0.261  1.0
  N  N17  1  0.658  0.750  0.761  1.0
  N  N18  1  0.158  0.250  0.739  1.0
  N  N19  1  0.342  0.250  0.239  1.0
  N  N20  1  0.815  0.750  0.531  1.0
  N  N21  1  0.685  0.750  0.031  1.0
  N  N22  1  0.185  0.250  0.469  1.0
  N  N23  1  0.315  0.250  0.969  1.0
  N  N24  1  0.175  0.750  0.121  1.0
  N  N25  1  0.325  0.750  0.621  1.0
  N  N26  1  0.825  0.250  0.879  1.0
  N  N27  1  0.675  0.250  0.379  1.0
  Cl  Cl28  1  0.650  0.953  0.092  1.0
  Cl  Cl29  1  0.850  0.547  0.592  1.0
  Cl  Cl30  1  0.350  0.453  0.908  1.0
  Cl  Cl31  1  0.150  0.047  0.408  1.0
  Cl  Cl32  1  0.350  0.047  0.908  1.0
  Cl  Cl33  1  0.150  0.453  0.408  1.0
  Cl  Cl34  1  0.650  0.547  0.092  1.0
  Cl  Cl35  1  0.850  0.953  0.592  1.0
  O  O36  1  0.082  0.750  0.056  1.0
  O  O37  1  0.418  0.750  0.556  1.0
  O  O38  1  0.918  0.250  0.944  1.0
  O  O39  1  0.582  0.250  0.444  1.0
  O  O40  1  0.152  0.750  0.202  1.0
  O  O41  1  0.348  0.750  0.702  1.0
  O  O42  1  0.848  0.250  0.798  1.0
  O  O43  1  0.652  0.250  0.298  1.0
[/CIF]
.
The structure described by CrN5Cl2NO2 is Iron Boride structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four nitrous acid molecules and four CrN5Cl2 clusters. In each CrN5Cl2 cluster, Cr(1) is bonded in a 5-coordinate geometry to one N(1), one N(3), one N(4), and two equivalent N(2) atoms. There are four inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Cr(1) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Cr(1) atom. In the third N site, N(3) is bonded in a single-bond geometry to one Cr(1) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cr(1) and two equivalent Cl(1) atoms. Cl(1) is bonded in a single-bond geometry to one N(4) atom. is represented by the CIF card [CIF]
data_CrN6(ClO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.836
_cell_length_b   6.719
_cell_length_c   14.761
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   777.111
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.778  0.750  0.371  1.0
  Cr  Cr1  1  0.722  0.750  0.871  1.0
  Cr  Cr2  1  0.222  0.250  0.629  1.0
  Cr  Cr3  1  0.278  0.250  0.129  1.0
  N  N4  1  0.575  0.750  0.358  1.0
  N  N5  1  0.925  0.750  0.858  1.0
  N  N6  1  0.425  0.250  0.642  1.0
  N  N7  1  0.075  0.250  0.142  1.0
  N  N8  1  0.832  0.021  0.395  1.0
  N  N9  1  0.668  0.479  0.895  1.0
  N  N10  1  0.168  0.521  0.605  1.0
  N  N11  1  0.332  0.979  0.105  1.0
  N  N12  1  0.168  0.979  0.605  1.0
  N  N13  1  0.332  0.521  0.105  1.0
  N  N14  1  0.832  0.479  0.395  1.0
  N  N15  1  0.668  0.021  0.895  1.0
  N  N16  1  0.842  0.750  0.261  1.0
  N  N17  1  0.658  0.750  0.761  1.0
  N  N18  1  0.158  0.250  0.739  1.0
  N  N19  1  0.342  0.250  0.239  1.0
  N  N20  1  0.815  0.750  0.531  1.0
  N  N21  1  0.685  0.750  0.031  1.0
  N  N22  1  0.185  0.250  0.469  1.0
  N  N23  1  0.315  0.250  0.969  1.0
  N  N24  1  0.175  0.750  0.121  1.0
  N  N25  1  0.325  0.750  0.621  1.0
  N  N26  1  0.825  0.250  0.879  1.0
  N  N27  1  0.675  0.250  0.379  1.0
  Cl  Cl28  1  0.650  0.953  0.092  1.0
  Cl  Cl29  1  0.850  0.547  0.592  1.0
  Cl  Cl30  1  0.350  0.453  0.908  1.0
  Cl  Cl31  1  0.150  0.047  0.408  1.0
  Cl  Cl32  1  0.350  0.047  0.908  1.0
  Cl  Cl33  1  0.150  0.453  0.408  1.0
  Cl  Cl34  1  0.650  0.547  0.092  1.0
  Cl  Cl35  1  0.850  0.953  0.592  1.0
  O  O36  1  0.082  0.750  0.056  1.0
  O  O37  1  0.418  0.750  0.556  1.0
  O  O38  1  0.918  0.250  0.944  1.0
  O  O39  1  0.582  0.250  0.444  1.0
  O  O40  1  0.152  0.750  0.202  1.0
  O  O41  1  0.348  0.750  0.702  1.0
  O  O42  1  0.848  0.250  0.798  1.0
  O  O43  1  0.652  0.250  0.298  1.0
[/CIF]
.