The structure described by Cs4SnO4 crystallizes in the monoclinic P2_1/c space group. There are four inequivalent Cs sites. In the first Cs site, Cs(1) is bonded to one O(2), one O(4), and two equivalent O(3) atoms to form distorted CsO4 tetrahedra that share corners with four equivalent Sn(1)O4 tetrahedra and  an edgeedge with one Cs(1)O4 tetrahedra. In the second Cs site, Cs(2) is bonded in a 6-coordinate geometry to one O(4), two equivalent O(2), and three equivalent O(1) atoms. In the third Cs site, Cs(3) is bonded in a 5-coordinate geometry to one O(2), one O(3), one O(4), and two equivalent O(1) atoms. In the fourth Cs site, Cs(4) is bonded in a 5-coordinate geometry to one O(2), two equivalent O(3), and two equivalent O(4) atoms. Sn(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form SnO4 tetrahedra that share corners with four equivalent Cs(1)O4 tetrahedra. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 6-coordinate geometry to two equivalent Cs(3), three equivalent Cs(2), and one Sn(1) atom. In the second O site, O(2) is bonded in a 6-coordinate geometry to one Cs(1), one Cs(3), one Cs(4), two equivalent Cs(2), and one Sn(1) atom. In the third O site, O(3) is bonded in a 6-coordinate geometry to one Cs(3), two equivalent Cs(1), two equivalent Cs(4), and one Sn(1) atom. In the fourth O site, O(4) is bonded in a 6-coordinate geometry to one Cs(1), one Cs(2), one Cs(3), two equivalent Cs(4), and one Sn(1) atom. is represented by the CIF card [CIF]
data_Cs4SnO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.351
_cell_length_b   11.745
_cell_length_c   11.789
_cell_angle_alpha   68.463
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   946.744
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.660  0.891  0.633  1.0
  Cs  Cs1  1  0.340  0.109  0.367  1.0
  Cs  Cs2  1  0.840  0.391  0.633  1.0
  Cs  Cs3  1  0.592  0.299  0.060  1.0
  Cs  Cs4  1  0.092  0.201  0.940  1.0
  Cs  Cs5  1  0.408  0.701  0.940  1.0
  Cs  Cs6  1  0.908  0.799  0.060  1.0
  Cs  Cs7  1  0.613  0.087  0.842  1.0
  Cs  Cs8  1  0.113  0.413  0.158  1.0
  Cs  Cs9  1  0.387  0.913  0.158  1.0
  Cs  Cs10  1  0.887  0.587  0.842  1.0
  Cs  Cs11  1  0.675  0.704  0.428  1.0
  Cs  Cs12  1  0.175  0.796  0.572  1.0
  Cs  Cs13  1  0.325  0.296  0.572  1.0
  Cs  Cs14  1  0.825  0.204  0.428  1.0
  Cs  Cs15  1  0.160  0.609  0.367  1.0
  Sn  Sn16  1  0.371  0.493  0.758  1.0
  Sn  Sn17  1  0.871  0.007  0.242  1.0
  Sn  Sn18  1  0.129  0.993  0.758  1.0
  Sn  Sn19  1  0.629  0.507  0.242  1.0
  O  O20  1  0.237  0.973  0.919  1.0
  O  O21  1  0.008  0.159  0.218  1.0
  O  O22  1  0.508  0.341  0.782  1.0
  O  O23  1  0.992  0.841  0.782  1.0
  O  O24  1  0.737  0.527  0.081  1.0
  O  O25  1  0.763  0.027  0.081  1.0
  O  O26  1  0.263  0.473  0.919  1.0
  O  O27  1  0.326  0.017  0.637  1.0
  O  O28  1  0.826  0.483  0.363  1.0
  O  O29  1  0.674  0.983  0.363  1.0
  O  O30  1  0.174  0.517  0.637  1.0
  O  O31  1  0.027  0.858  0.303  1.0
  O  O32  1  0.527  0.642  0.697  1.0
  O  O33  1  0.973  0.142  0.697  1.0
  O  O34  1  0.473  0.358  0.303  1.0
  O  O35  1  0.492  0.659  0.218  1.0
[/CIF]
.
The structure described by Cs4SnO4 crystallizes in the monoclinic P2_1/c space group. There are four inequivalent Cs sites. In the first Cs site, Cs(1) is bonded to one O(2), one O(4), and two equivalent O(3) atoms to form distorted CsO4 tetrahedra that share corners with four equivalent Sn(1)O4 tetrahedra and  an edgeedge with one Cs(1)O4 tetrahedra. In the second Cs site, Cs(2) is bonded in a 6-coordinate geometry to one O(4), two equivalent O(2), and three equivalent O(1) atoms. In the third Cs site, Cs(3) is bonded in a 5-coordinate geometry to one O(2), one O(3), one O(4), and two equivalent O(1) atoms. In the fourth Cs site, Cs(4) is bonded in a 5-coordinate geometry to one O(2), two equivalent O(3), and two equivalent O(4) atoms. Sn(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form SnO4 tetrahedra that share corners with four equivalent Cs(1)O4 tetrahedra. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 6-coordinate geometry to two equivalent Cs(3), three equivalent Cs(2), and one Sn(1) atom. In the second O site, O(2) is bonded in a 6-coordinate geometry to one Cs(1), one Cs(3), one Cs(4), two equivalent Cs(2), and one Sn(1) atom. In the third O site, O(3) is bonded in a 6-coordinate geometry to one Cs(3), two equivalent Cs(1), two equivalent Cs(4), and one Sn(1) atom. In the fourth O site, O(4) is bonded in a 6-coordinate geometry to one Cs(1), one Cs(2), one Cs(3), two equivalent Cs(4), and one Sn(1) atom. is represented by the CIF card [CIF]
data_Cs4SnO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.351
_cell_length_b   11.745
_cell_length_c   11.789
_cell_angle_alpha   68.463
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   946.744
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.660  0.891  0.633  1.0
  Cs  Cs1  1  0.340  0.109  0.367  1.0
  Cs  Cs2  1  0.840  0.391  0.633  1.0
  Cs  Cs3  1  0.592  0.299  0.060  1.0
  Cs  Cs4  1  0.092  0.201  0.940  1.0
  Cs  Cs5  1  0.408  0.701  0.940  1.0
  Cs  Cs6  1  0.908  0.799  0.060  1.0
  Cs  Cs7  1  0.613  0.087  0.842  1.0
  Cs  Cs8  1  0.113  0.413  0.158  1.0
  Cs  Cs9  1  0.387  0.913  0.158  1.0
  Cs  Cs10  1  0.887  0.587  0.842  1.0
  Cs  Cs11  1  0.675  0.704  0.428  1.0
  Cs  Cs12  1  0.175  0.796  0.572  1.0
  Cs  Cs13  1  0.325  0.296  0.572  1.0
  Cs  Cs14  1  0.825  0.204  0.428  1.0
  Cs  Cs15  1  0.160  0.609  0.367  1.0
  Sn  Sn16  1  0.371  0.493  0.758  1.0
  Sn  Sn17  1  0.871  0.007  0.242  1.0
  Sn  Sn18  1  0.129  0.993  0.758  1.0
  Sn  Sn19  1  0.629  0.507  0.242  1.0
  O  O20  1  0.237  0.973  0.919  1.0
  O  O21  1  0.008  0.159  0.218  1.0
  O  O22  1  0.508  0.341  0.782  1.0
  O  O23  1  0.992  0.841  0.782  1.0
  O  O24  1  0.737  0.527  0.081  1.0
  O  O25  1  0.763  0.027  0.081  1.0
  O  O26  1  0.263  0.473  0.919  1.0
  O  O27  1  0.326  0.017  0.637  1.0
  O  O28  1  0.826  0.483  0.363  1.0
  O  O29  1  0.674  0.983  0.363  1.0
  O  O30  1  0.174  0.517  0.637  1.0
  O  O31  1  0.027  0.858  0.303  1.0
  O  O32  1  0.527  0.642  0.697  1.0
  O  O33  1  0.973  0.142  0.697  1.0
  O  O34  1  0.473  0.358  0.303  1.0
  O  O35  1  0.492  0.659  0.218  1.0
[/CIF]
.