The compound described by RbCd6C12O24ClO2 crystallizes in the trigonal R-3 space group. The structure consists of six water atoms inside a RbCd6C12O24Cl framework. In the RbCd6C12O24Cl framework, Rb(1) is bonded in a cuboctahedral geometry to six equivalent O(2) and six equivalent O(3) atoms. Cd(1) is bonded in a 7-coordinate geometry to one O(2), one O(3), two equivalent O(1), two equivalent O(4), and one Cl(1) atom. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. There are four inequivalent O sites. In the first O site, O(2) is bonded in a distorted single-bond geometry to one Rb(1), one Cd(1), and one C(1) atom. In the second O site, O(3) is bonded in a distorted single-bond geometry to one Rb(1), one Cd(1), and one C(2) atom. In the third O site, O(4) is bonded in a distorted trigonal planar geometry to two equivalent Cd(1) and one C(2) atom. In the fourth O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent Cd(1) and one C(1) atom. Cl(1) is bonded in an octahedral geometry to six equivalent Cd(1) atoms. is represented by the CIF card [CIF]
data_RbCd6C12ClO26
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.803
_cell_length_b   9.803
_cell_length_c   9.803
_cell_angle_alpha   58.377
_cell_angle_beta   58.377
_cell_angle_gamma   58.377
_symmetry_Int_Tables_number   1
_cell_volume   641.368
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.000  0.000  0.000  1.0
  Cd  Cd1  1  0.710  0.354  0.225  1.0
  Cd  Cd2  1  0.354  0.225  0.710  1.0
  Cd  Cd3  1  0.225  0.710  0.354  1.0
  Cd  Cd4  1  0.290  0.646  0.775  1.0
  Cd  Cd5  1  0.646  0.775  0.290  1.0
  Cd  Cd6  1  0.775  0.290  0.646  1.0
  C  C7  1  0.567  0.044  0.429  1.0
  C  C8  1  0.044  0.429  0.567  1.0
  C  C9  1  0.429  0.567  0.044  1.0
  C  C10  1  0.433  0.956  0.571  1.0
  C  C11  1  0.956  0.571  0.433  1.0
  C  C12  1  0.571  0.433  0.956  1.0
  C  C13  1  0.054  0.424  0.966  1.0
  C  C14  1  0.424  0.966  0.054  1.0
  C  C15  1  0.966  0.054  0.424  1.0
  C  C16  1  0.946  0.576  0.034  1.0
  C  C17  1  0.576  0.034  0.946  1.0
  C  C18  1  0.034  0.946  0.576  1.0
  Cl  Cl19  1  0.500  0.500  0.500  1.0
  O  O20  1  0.557  0.170  0.447  1.0
  O  O21  1  0.170  0.447  0.557  1.0
  O  O22  1  0.447  0.557  0.170  1.0
  O  O23  1  0.443  0.830  0.553  1.0
  O  O24  1  0.830  0.553  0.443  1.0
  O  O25  1  0.553  0.443  0.830  1.0
  O  O26  1  0.674  0.989  0.308  1.0
  O  O27  1  0.989  0.308  0.674  1.0
  O  O28  1  0.308  0.674  0.989  1.0
  O  O29  1  0.326  0.011  0.692  1.0
  O  O30  1  0.011  0.692  0.326  1.0
  O  O31  1  0.692  0.326  0.011  1.0
  O  O32  1  0.985  0.325  0.007  1.0
  O  O33  1  0.325  0.007  0.985  1.0
  O  O34  1  0.007  0.985  0.325  1.0
  O  O35  1  0.015  0.675  0.993  1.0
  O  O36  1  0.675  0.993  0.015  1.0
  O  O37  1  0.993  0.015  0.675  1.0
  O  O38  1  0.209  0.412  0.869  1.0
  O  O39  1  0.412  0.869  0.209  1.0
  O  O40  1  0.869  0.209  0.412  1.0
  O  O41  1  0.791  0.588  0.131  1.0
  O  O42  1  0.588  0.131  0.791  1.0
  O  O43  1  0.131  0.791  0.588  1.0
  O  O44  1  0.743  0.743  0.743  1.0
  O  O45  1  0.257  0.257  0.257  1.0
[/CIF]
.
The compound described by RbCd6C12O24ClO2 crystallizes in the trigonal R-3 space group. The structure consists of six water atoms inside a RbCd6C12O24Cl framework. In the RbCd6C12O24Cl framework, Rb(1) is bonded in a cuboctahedral geometry to six equivalent O(2) and six equivalent O(3) atoms. Cd(1) is bonded in a 7-coordinate geometry to one O(2), one O(3), two equivalent O(1), two equivalent O(4), and one Cl(1) atom. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. There are four inequivalent O sites. In the first O site, O(2) is bonded in a distorted single-bond geometry to one Rb(1), one Cd(1), and one C(1) atom. In the second O site, O(3) is bonded in a distorted single-bond geometry to one Rb(1), one Cd(1), and one C(2) atom. In the third O site, O(4) is bonded in a distorted trigonal planar geometry to two equivalent Cd(1) and one C(2) atom. In the fourth O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent Cd(1) and one C(1) atom. Cl(1) is bonded in an octahedral geometry to six equivalent Cd(1) atoms. is represented by the CIF card [CIF]
data_RbCd6C12ClO26
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.803
_cell_length_b   9.803
_cell_length_c   9.803
_cell_angle_alpha   58.377
_cell_angle_beta   58.377
_cell_angle_gamma   58.377
_symmetry_Int_Tables_number   1
_cell_volume   641.368
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.000  0.000  0.000  1.0
  Cd  Cd1  1  0.710  0.354  0.225  1.0
  Cd  Cd2  1  0.354  0.225  0.710  1.0
  Cd  Cd3  1  0.225  0.710  0.354  1.0
  Cd  Cd4  1  0.290  0.646  0.775  1.0
  Cd  Cd5  1  0.646  0.775  0.290  1.0
  Cd  Cd6  1  0.775  0.290  0.646  1.0
  C  C7  1  0.567  0.044  0.429  1.0
  C  C8  1  0.044  0.429  0.567  1.0
  C  C9  1  0.429  0.567  0.044  1.0
  C  C10  1  0.433  0.956  0.571  1.0
  C  C11  1  0.956  0.571  0.433  1.0
  C  C12  1  0.571  0.433  0.956  1.0
  C  C13  1  0.054  0.424  0.966  1.0
  C  C14  1  0.424  0.966  0.054  1.0
  C  C15  1  0.966  0.054  0.424  1.0
  C  C16  1  0.946  0.576  0.034  1.0
  C  C17  1  0.576  0.034  0.946  1.0
  C  C18  1  0.034  0.946  0.576  1.0
  Cl  Cl19  1  0.500  0.500  0.500  1.0
  O  O20  1  0.557  0.170  0.447  1.0
  O  O21  1  0.170  0.447  0.557  1.0
  O  O22  1  0.447  0.557  0.170  1.0
  O  O23  1  0.443  0.830  0.553  1.0
  O  O24  1  0.830  0.553  0.443  1.0
  O  O25  1  0.553  0.443  0.830  1.0
  O  O26  1  0.674  0.989  0.308  1.0
  O  O27  1  0.989  0.308  0.674  1.0
  O  O28  1  0.308  0.674  0.989  1.0
  O  O29  1  0.326  0.011  0.692  1.0
  O  O30  1  0.011  0.692  0.326  1.0
  O  O31  1  0.692  0.326  0.011  1.0
  O  O32  1  0.985  0.325  0.007  1.0
  O  O33  1  0.325  0.007  0.985  1.0
  O  O34  1  0.007  0.985  0.325  1.0
  O  O35  1  0.015  0.675  0.993  1.0
  O  O36  1  0.675  0.993  0.015  1.0
  O  O37  1  0.993  0.015  0.675  1.0
  O  O38  1  0.209  0.412  0.869  1.0
  O  O39  1  0.412  0.869  0.209  1.0
  O  O40  1  0.869  0.209  0.412  1.0
  O  O41  1  0.791  0.588  0.131  1.0
  O  O42  1  0.588  0.131  0.791  1.0
  O  O43  1  0.131  0.791  0.588  1.0
  O  O44  1  0.743  0.743  0.743  1.0
  O  O45  1  0.257  0.257  0.257  1.0
[/CIF]
.