The compound described by UBiO5 crystallizes in the monoclinic P2_1/c space group. U(1) is bonded to one O(1), one O(2), one O(4), two equivalent O(3), and two equivalent O(5) atoms to form a mixture of distorted edge and corner-sharing UO7 pentagonal bipyramids. Bi(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(5), and two equivalent O(4) atoms. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one U(1) and one Bi(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one U(1) and one Bi(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to two equivalent U(1) and one Bi(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to one U(1) and two equivalent Bi(1) atoms. In the fifth O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to two equivalent U(1) and one Bi(1) atom. is represented by the CIF file [CIF]
data_UBiO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.991
_cell_length_b   7.503
_cell_length_c   10.421
_cell_angle_alpha   46.854
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   455.888
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  U  U0  1  0.502  0.158  0.186  1.0
  U  U1  1  0.998  0.158  0.686  1.0
  U  U2  1  0.498  0.842  0.814  1.0
  U  U3  1  0.002  0.842  0.314  1.0
  Bi  Bi4  1  0.115  0.570  0.821  1.0
  Bi  Bi5  1  0.385  0.570  0.321  1.0
  Bi  Bi6  1  0.885  0.430  0.179  1.0
  Bi  Bi7  1  0.615  0.430  0.679  1.0
  O  O8  1  0.096  0.863  0.466  1.0
  O  O9  1  0.404  0.863  0.966  1.0
  O  O10  1  0.904  0.137  0.534  1.0
  O  O11  1  0.596  0.137  0.034  1.0
  O  O12  1  0.398  0.212  0.317  1.0
  O  O13  1  0.102  0.212  0.817  1.0
  O  O14  1  0.602  0.788  0.683  1.0
  O  O15  1  0.898  0.788  0.183  1.0
  O  O16  1  0.354  0.478  0.947  1.0
  O  O17  1  0.146  0.478  0.447  1.0
  O  O18  1  0.646  0.522  0.053  1.0
  O  O19  1  0.854  0.522  0.553  1.0
  O  O20  1  0.003  0.739  0.912  1.0
  O  O21  1  0.497  0.739  0.412  1.0
  O  O22  1  0.997  0.261  0.088  1.0
  O  O23  1  0.503  0.261  0.588  1.0
  O  O24  1  0.238  0.943  0.695  1.0
  O  O25  1  0.262  0.943  0.195  1.0
  O  O26  1  0.762  0.057  0.305  1.0
  O  O27  1  0.738  0.057  0.805  1.0
[/CIF]
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The compound described by UBiO5 crystallizes in the monoclinic P2_1/c space group. U(1) is bonded to one O(1), one O(2), one O(4), two equivalent O(3), and two equivalent O(5) atoms to form a mixture of distorted edge and corner-sharing UO7 pentagonal bipyramids. Bi(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(5), and two equivalent O(4) atoms. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one U(1) and one Bi(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one U(1) and one Bi(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to two equivalent U(1) and one Bi(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to one U(1) and two equivalent Bi(1) atoms. In the fifth O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to two equivalent U(1) and one Bi(1) atom. is represented by the CIF file [CIF]
data_UBiO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.991
_cell_length_b   7.503
_cell_length_c   10.421
_cell_angle_alpha   46.854
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   455.888
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  U  U0  1  0.502  0.158  0.186  1.0
  U  U1  1  0.998  0.158  0.686  1.0
  U  U2  1  0.498  0.842  0.814  1.0
  U  U3  1  0.002  0.842  0.314  1.0
  Bi  Bi4  1  0.115  0.570  0.821  1.0
  Bi  Bi5  1  0.385  0.570  0.321  1.0
  Bi  Bi6  1  0.885  0.430  0.179  1.0
  Bi  Bi7  1  0.615  0.430  0.679  1.0
  O  O8  1  0.096  0.863  0.466  1.0
  O  O9  1  0.404  0.863  0.966  1.0
  O  O10  1  0.904  0.137  0.534  1.0
  O  O11  1  0.596  0.137  0.034  1.0
  O  O12  1  0.398  0.212  0.317  1.0
  O  O13  1  0.102  0.212  0.817  1.0
  O  O14  1  0.602  0.788  0.683  1.0
  O  O15  1  0.898  0.788  0.183  1.0
  O  O16  1  0.354  0.478  0.947  1.0
  O  O17  1  0.146  0.478  0.447  1.0
  O  O18  1  0.646  0.522  0.053  1.0
  O  O19  1  0.854  0.522  0.553  1.0
  O  O20  1  0.003  0.739  0.912  1.0
  O  O21  1  0.497  0.739  0.412  1.0
  O  O22  1  0.997  0.261  0.088  1.0
  O  O23  1  0.503  0.261  0.588  1.0
  O  O24  1  0.238  0.943  0.695  1.0
  O  O25  1  0.262  0.943  0.195  1.0
  O  O26  1  0.762  0.057  0.305  1.0
  O  O27  1  0.738  0.057  0.805  1.0
[/CIF]
.