The material described by MoBiO2 crystallizes in the tetragonal I4_1/amd space group. Mo(1) is bonded in a distorted square co-planar geometry to four equivalent O(1) atoms. Bi(1) is bonded to six equivalent O(1) atoms to form edge-sharing BiO6 octahedra. O(1) is bonded in a 5-coordinate geometry to two equivalent Mo(1) and three equivalent Bi(1) atoms. is represented by the CIF card [CIF]
data_BiMoO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.811
_cell_length_b   7.811
_cell_length_c   7.811
_cell_angle_alpha   130.457
_cell_angle_beta   130.457
_cell_angle_gamma   72.677
_symmetry_Int_Tables_number   1
_cell_volume   269.611
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.875  0.625  0.250  1.0
  Bi  Bi1  1  0.375  0.625  0.750  1.0
  Bi  Bi2  1  0.375  0.625  0.250  1.0
  Bi  Bi3  1  0.375  0.125  0.750  1.0
  Mo  Mo4  1  0.375  0.125  0.250  1.0
  Mo  Mo5  1  0.875  0.125  0.750  1.0
  Mo  Mo6  1  0.875  0.125  0.250  1.0
  Mo  Mo7  1  0.875  0.625  0.750  1.0
  O  O8  1  0.181  0.387  0.206  1.0
  O  O9  1  0.181  0.975  0.794  1.0
  O  O10  1  0.137  0.431  0.706  1.0
  O  O11  1  0.569  0.863  0.294  1.0
  O  O12  1  0.725  0.431  0.294  1.0
  O  O13  1  0.569  0.275  0.706  1.0
  O  O14  1  0.613  0.819  0.794  1.0
  O  O15  1  0.025  0.819  0.206  1.0
[/CIF]
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The material described by MoBiO2 crystallizes in the tetragonal I4_1/amd space group. Mo(1) is bonded in a distorted square co-planar geometry to four equivalent O(1) atoms. Bi(1) is bonded to six equivalent O(1) atoms to form edge-sharing BiO6 octahedra. O(1) is bonded in a 5-coordinate geometry to two equivalent Mo(1) and three equivalent Bi(1) atoms. is represented by the CIF card [CIF]
data_BiMoO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.811
_cell_length_b   7.811
_cell_length_c   7.811
_cell_angle_alpha   130.457
_cell_angle_beta   130.457
_cell_angle_gamma   72.677
_symmetry_Int_Tables_number   1
_cell_volume   269.611
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.875  0.625  0.250  1.0
  Bi  Bi1  1  0.375  0.625  0.750  1.0
  Bi  Bi2  1  0.375  0.625  0.250  1.0
  Bi  Bi3  1  0.375  0.125  0.750  1.0
  Mo  Mo4  1  0.375  0.125  0.250  1.0
  Mo  Mo5  1  0.875  0.125  0.750  1.0
  Mo  Mo6  1  0.875  0.125  0.250  1.0
  Mo  Mo7  1  0.875  0.625  0.750  1.0
  O  O8  1  0.181  0.387  0.206  1.0
  O  O9  1  0.181  0.975  0.794  1.0
  O  O10  1  0.137  0.431  0.706  1.0
  O  O11  1  0.569  0.863  0.294  1.0
  O  O12  1  0.725  0.431  0.294  1.0
  O  O13  1  0.569  0.275  0.706  1.0
  O  O14  1  0.613  0.819  0.794  1.0
  O  O15  1  0.025  0.819  0.206  1.0
[/CIF]
.