The crystal structure described by V2N2S crystallizes in the trigonal P-3m1 space group. V(1) is bonded to four equivalent N(1) and three equivalent S(1) atoms to form a mixture of distorted corner and edge-sharing VS3N4 trigonal pyramids. N(1) is bonded to four equivalent V(1) atoms to form NV4 trigonal pyramids that share corners with six equivalent S(1)V6 octahedra, corners with six equivalent N(1)V4 trigonal pyramids, edges with three equivalent S(1)V6 octahedra, and edges with three equivalent N(1)V4 trigonal pyramids. The corner-sharing octahedral tilt angles range from 38-46°. S(1) is bonded to six equivalent V(1) atoms to form distorted SV6 octahedra that share corners with twelve equivalent N(1)V4 trigonal pyramids, edges with six equivalent S(1)V6 octahedra, and edges with six equivalent N(1)V4 trigonal pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_V2SN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.334
_cell_length_b   3.334
_cell_length_c   5.918
_cell_angle_alpha   90.000
_cell_angle_beta   90.001
_cell_angle_gamma   120.002
_symmetry_Int_Tables_number   1
_cell_volume   56.979
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.667  0.333  0.684  1.0
  V  V1  1  0.333  0.667  0.316  1.0
  S  S2  1  0.000  0.000  0.000  1.0
  N  N3  1  0.667  0.333  0.350  1.0
  N  N4  1  0.333  0.667  0.650  1.0
[/CIF]
.
The crystal structure described by V2N2S crystallizes in the trigonal P-3m1 space group. V(1) is bonded to four equivalent N(1) and three equivalent S(1) atoms to form a mixture of distorted corner and edge-sharing VS3N4 trigonal pyramids. N(1) is bonded to four equivalent V(1) atoms to form NV4 trigonal pyramids that share corners with six equivalent S(1)V6 octahedra, corners with six equivalent N(1)V4 trigonal pyramids, edges with three equivalent S(1)V6 octahedra, and edges with three equivalent N(1)V4 trigonal pyramids. The corner-sharing octahedral tilt angles range from 38-46°. S(1) is bonded to six equivalent V(1) atoms to form distorted SV6 octahedra that share corners with twelve equivalent N(1)V4 trigonal pyramids, edges with six equivalent S(1)V6 octahedra, and edges with six equivalent N(1)V4 trigonal pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_V2SN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.334
_cell_length_b   3.334
_cell_length_c   5.918
_cell_angle_alpha   90.000
_cell_angle_beta   90.001
_cell_angle_gamma   120.002
_symmetry_Int_Tables_number   1
_cell_volume   56.979
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.667  0.333  0.684  1.0
  V  V1  1  0.333  0.667  0.316  1.0
  S  S2  1  0.000  0.000  0.000  1.0
  N  N3  1  0.667  0.333  0.350  1.0
  N  N4  1  0.333  0.667  0.650  1.0
[/CIF]
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