The structure described by LaTiSbO6 is Hydrophilite-derived structured and crystallizes in the trigonal P312 space group. La(1) is bonded to six equivalent O(1) atoms to form LaO6 octahedra that share corners with six equivalent Ti(1)O6 octahedra and corners with six equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-54°. Ti(1) is bonded to six equivalent O(1) atoms to form TiO6 octahedra that share corners with six equivalent La(1)O6 octahedra and edges with three equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles are 53°. Sb(1) is bonded to six equivalent O(1) atoms to form SbO6 octahedra that share corners with six equivalent La(1)O6 octahedra and edges with three equivalent Ti(1)O6 octahedra. The corner-sharing octahedral tilt angles are 54°. O(1) is bonded in a distorted trigonal planar geometry to one La(1), one Ti(1), and one Sb(1) atom. is represented by the CIF file [CIF]
data_LaTiSbO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.291
_cell_length_b   5.291
_cell_length_c   5.187
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   125.744
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.000  0.000  0.000  1.0
  Ti  Ti1  1  0.667  0.333  0.500  1.0
  Sb  Sb2  1  0.333  0.667  0.500  1.0
  O  O3  1  0.627  0.624  0.714  1.0
  O  O4  1  0.997  0.373  0.714  1.0
  O  O5  1  0.376  0.003  0.714  1.0
  O  O6  1  0.376  0.373  0.286  1.0
  O  O7  1  0.997  0.624  0.286  1.0
  O  O8  1  0.627  0.003  0.286  1.0
[/CIF]
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The structure described by LaTiSbO6 is Hydrophilite-derived structured and crystallizes in the trigonal P312 space group. La(1) is bonded to six equivalent O(1) atoms to form LaO6 octahedra that share corners with six equivalent Ti(1)O6 octahedra and corners with six equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-54°. Ti(1) is bonded to six equivalent O(1) atoms to form TiO6 octahedra that share corners with six equivalent La(1)O6 octahedra and edges with three equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles are 53°. Sb(1) is bonded to six equivalent O(1) atoms to form SbO6 octahedra that share corners with six equivalent La(1)O6 octahedra and edges with three equivalent Ti(1)O6 octahedra. The corner-sharing octahedral tilt angles are 54°. O(1) is bonded in a distorted trigonal planar geometry to one La(1), one Ti(1), and one Sb(1) atom. is represented by the CIF file [CIF]
data_LaTiSbO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.291
_cell_length_b   5.291
_cell_length_c   5.187
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   125.744
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.000  0.000  0.000  1.0
  Ti  Ti1  1  0.667  0.333  0.500  1.0
  Sb  Sb2  1  0.333  0.667  0.500  1.0
  O  O3  1  0.627  0.624  0.714  1.0
  O  O4  1  0.997  0.373  0.714  1.0
  O  O5  1  0.376  0.003  0.714  1.0
  O  O6  1  0.376  0.373  0.286  1.0
  O  O7  1  0.997  0.624  0.286  1.0
  O  O8  1  0.627  0.003  0.286  1.0
[/CIF]
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