The compound described by (Mo3(NO4)2)2(O2)3 is Indium-derived structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two trioxidane molecules and two Mo3(NO4)2 clusters. In each Mo3(NO4)2 cluster, there are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one O(4), and one O(5) atom. In the second Mo site, Mo(2) is bonded in a 6-coordinate geometry to two equivalent N(1), one O(2), one O(3), and two equivalent O(1) atoms. N(1) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(2), and one O(1) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Mo(2) and one N(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Mo(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Mo(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Mo(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Mo(1) atom. is represented by the CIF file [CIF]
data_Mo3N2O11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.143
_cell_length_b   8.702
_cell_length_c   10.260
_cell_angle_alpha   76.368
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   706.621
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.566  0.027  0.189  1.0
  Mo  Mo1  1  0.066  0.973  0.811  1.0
  Mo  Mo2  1  0.434  0.973  0.811  1.0
  Mo  Mo3  1  0.934  0.027  0.189  1.0
  Mo  Mo4  1  0.250  0.701  0.161  1.0
  Mo  Mo5  1  0.750  0.299  0.839  1.0
  N  N6  1  0.582  0.107  0.900  1.0
  N  N7  1  0.082  0.893  0.100  1.0
  N  N8  1  0.418  0.893  0.100  1.0
  N  N9  1  0.918  0.107  0.900  1.0
  O  O10  1  0.510  0.763  0.152  1.0
  O  O11  1  0.010  0.237  0.848  1.0
  O  O12  1  0.490  0.237  0.848  1.0
  O  O13  1  0.990  0.763  0.152  1.0
  O  O14  1  0.250  0.629  0.332  1.0
  O  O15  1  0.750  0.371  0.668  1.0
  O  O16  1  0.250  0.550  0.080  1.0
  O  O17  1  0.750  0.450  0.920  1.0
  O  O18  1  0.515  0.224  0.147  1.0
  O  O19  1  0.015  0.776  0.853  1.0
  O  O20  1  0.485  0.776  0.853  1.0
  O  O21  1  0.985  0.224  0.147  1.0
  O  O22  1  0.546  0.963  0.359  1.0
  O  O23  1  0.046  0.037  0.641  1.0
  O  O24  1  0.454  0.037  0.641  1.0
  O  O25  1  0.954  0.963  0.359  1.0
  O  O26  1  0.385  0.310  0.432  1.0
  O  O27  1  0.885  0.690  0.568  1.0
  O  O28  1  0.615  0.690  0.568  1.0
  O  O29  1  0.115  0.310  0.432  1.0
  O  O30  1  0.250  0.280  0.379  1.0
  O  O31  1  0.750  0.720  0.621  1.0
[/CIF]
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The compound described by (Mo3(NO4)2)2(O2)3 is Indium-derived structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two trioxidane molecules and two Mo3(NO4)2 clusters. In each Mo3(NO4)2 cluster, there are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one O(4), and one O(5) atom. In the second Mo site, Mo(2) is bonded in a 6-coordinate geometry to two equivalent N(1), one O(2), one O(3), and two equivalent O(1) atoms. N(1) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(2), and one O(1) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Mo(2) and one N(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Mo(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Mo(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Mo(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Mo(1) atom. is represented by the CIF file [CIF]
data_Mo3N2O11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.143
_cell_length_b   8.702
_cell_length_c   10.260
_cell_angle_alpha   76.368
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   706.621
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.566  0.027  0.189  1.0
  Mo  Mo1  1  0.066  0.973  0.811  1.0
  Mo  Mo2  1  0.434  0.973  0.811  1.0
  Mo  Mo3  1  0.934  0.027  0.189  1.0
  Mo  Mo4  1  0.250  0.701  0.161  1.0
  Mo  Mo5  1  0.750  0.299  0.839  1.0
  N  N6  1  0.582  0.107  0.900  1.0
  N  N7  1  0.082  0.893  0.100  1.0
  N  N8  1  0.418  0.893  0.100  1.0
  N  N9  1  0.918  0.107  0.900  1.0
  O  O10  1  0.510  0.763  0.152  1.0
  O  O11  1  0.010  0.237  0.848  1.0
  O  O12  1  0.490  0.237  0.848  1.0
  O  O13  1  0.990  0.763  0.152  1.0
  O  O14  1  0.250  0.629  0.332  1.0
  O  O15  1  0.750  0.371  0.668  1.0
  O  O16  1  0.250  0.550  0.080  1.0
  O  O17  1  0.750  0.450  0.920  1.0
  O  O18  1  0.515  0.224  0.147  1.0
  O  O19  1  0.015  0.776  0.853  1.0
  O  O20  1  0.485  0.776  0.853  1.0
  O  O21  1  0.985  0.224  0.147  1.0
  O  O22  1  0.546  0.963  0.359  1.0
  O  O23  1  0.046  0.037  0.641  1.0
  O  O24  1  0.454  0.037  0.641  1.0
  O  O25  1  0.954  0.963  0.359  1.0
  O  O26  1  0.385  0.310  0.432  1.0
  O  O27  1  0.885  0.690  0.568  1.0
  O  O28  1  0.615  0.690  0.568  1.0
  O  O29  1  0.115  0.310  0.432  1.0
  O  O30  1  0.250  0.280  0.379  1.0
  O  O31  1  0.750  0.720  0.621  1.0
[/CIF]
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