The compound described by VF4 is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two tetrafluorovanadium molecules. V(1) is bonded in a square co-planar geometry to one F(1), one F(2), one F(3), and one F(5) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one V(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one V(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one V(1) atom. In the fourth F site, F(5) is bonded in a single-bond geometry to one V(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_VF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.568
_cell_length_b   5.572
_cell_length_c   6.586
_cell_angle_alpha   115.592
_cell_angle_beta   115.000
_cell_angle_gamma   90.004
_symmetry_Int_Tables_number   1
_cell_volume   162.786
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.995  0.504  0.999  1.0
  V  V1  1  0.508  0.010  0.999  1.0
  F  F2  1  0.948  0.440  0.229  1.0
  F  F3  1  0.710  0.218  0.761  1.0
  F  F4  1  0.050  0.547  0.765  1.0
  F  F5  1  0.212  0.047  0.767  1.0
  F  F6  1  0.282  0.783  0.239  1.0
  F  F7  1  0.456  0.284  0.239  1.0
  F  F8  1  0.777  0.940  0.229  1.0
  F  F9  1  0.548  0.719  0.760  1.0
[/CIF]
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The compound described by VF4 is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two tetrafluorovanadium molecules. V(1) is bonded in a square co-planar geometry to one F(1), one F(2), one F(3), and one F(5) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one V(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one V(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one V(1) atom. In the fourth F site, F(5) is bonded in a single-bond geometry to one V(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_VF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.568
_cell_length_b   5.572
_cell_length_c   6.586
_cell_angle_alpha   115.592
_cell_angle_beta   115.000
_cell_angle_gamma   90.004
_symmetry_Int_Tables_number   1
_cell_volume   162.786
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.995  0.504  0.999  1.0
  V  V1  1  0.508  0.010  0.999  1.0
  F  F2  1  0.948  0.440  0.229  1.0
  F  F3  1  0.710  0.218  0.761  1.0
  F  F4  1  0.050  0.547  0.765  1.0
  F  F5  1  0.212  0.047  0.767  1.0
  F  F6  1  0.282  0.783  0.239  1.0
  F  F7  1  0.456  0.284  0.239  1.0
  F  F8  1  0.777  0.940  0.229  1.0
  F  F9  1  0.548  0.719  0.760  1.0
[/CIF]
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