The material described by Re(OCl2)2 is Indium-like structured and crystallizes in the orthorhombic Pna2_1 space group. The structure is zero-dimensional and consists of four Re(OCl2)2 clusters. Re(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Re(1) and one Cl(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Re(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 2-coordinate geometry to one Re(1) and one O(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Re(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Re(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Re(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Re(Cl2O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.669
_cell_length_b   11.537
_cell_length_c   12.033
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   786.977
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.062  0.640  0.758  1.0
  Re  Re1  1  0.938  0.360  0.258  1.0
  Re  Re2  1  0.562  0.860  0.258  1.0
  Re  Re3  1  0.438  0.140  0.758  1.0
  Cl  Cl4  1  0.238  0.511  0.608  1.0
  Cl  Cl5  1  0.762  0.489  0.108  1.0
  Cl  Cl6  1  0.738  0.989  0.108  1.0
  Cl  Cl7  1  0.262  0.011  0.608  1.0
  Cl  Cl8  1  0.265  0.535  0.893  1.0
  Cl  Cl9  1  0.735  0.465  0.393  1.0
  Cl  Cl10  1  0.765  0.965  0.393  1.0
  Cl  Cl11  1  0.235  0.035  0.893  1.0
  Cl  Cl12  1  0.834  0.720  0.889  1.0
  Cl  Cl13  1  0.166  0.280  0.389  1.0
  Cl  Cl14  1  0.334  0.780  0.389  1.0
  Cl  Cl15  1  0.666  0.220  0.889  1.0
  Cl  Cl16  1  0.866  0.743  0.621  1.0
  Cl  Cl17  1  0.134  0.257  0.121  1.0
  Cl  Cl18  1  0.366  0.757  0.121  1.0
  Cl  Cl19  1  0.634  0.243  0.621  1.0
  O  O20  1  0.903  0.508  0.720  1.0
  O  O21  1  0.097  0.492  0.220  1.0
  O  O22  1  0.403  0.992  0.220  1.0
  O  O23  1  0.597  0.008  0.720  1.0
  O  O24  1  0.313  0.725  0.738  1.0
  O  O25  1  0.687  0.275  0.238  1.0
  O  O26  1  0.813  0.775  0.238  1.0
  O  O27  1  0.187  0.225  0.738  1.0
[/CIF]
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The material described by Re(OCl2)2 is Indium-like structured and crystallizes in the orthorhombic Pna2_1 space group. The structure is zero-dimensional and consists of four Re(OCl2)2 clusters. Re(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Re(1) and one Cl(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Re(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 2-coordinate geometry to one Re(1) and one O(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Re(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Re(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Re(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Re(Cl2O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.669
_cell_length_b   11.537
_cell_length_c   12.033
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   786.977
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.062  0.640  0.758  1.0
  Re  Re1  1  0.938  0.360  0.258  1.0
  Re  Re2  1  0.562  0.860  0.258  1.0
  Re  Re3  1  0.438  0.140  0.758  1.0
  Cl  Cl4  1  0.238  0.511  0.608  1.0
  Cl  Cl5  1  0.762  0.489  0.108  1.0
  Cl  Cl6  1  0.738  0.989  0.108  1.0
  Cl  Cl7  1  0.262  0.011  0.608  1.0
  Cl  Cl8  1  0.265  0.535  0.893  1.0
  Cl  Cl9  1  0.735  0.465  0.393  1.0
  Cl  Cl10  1  0.765  0.965  0.393  1.0
  Cl  Cl11  1  0.235  0.035  0.893  1.0
  Cl  Cl12  1  0.834  0.720  0.889  1.0
  Cl  Cl13  1  0.166  0.280  0.389  1.0
  Cl  Cl14  1  0.334  0.780  0.389  1.0
  Cl  Cl15  1  0.666  0.220  0.889  1.0
  Cl  Cl16  1  0.866  0.743  0.621  1.0
  Cl  Cl17  1  0.134  0.257  0.121  1.0
  Cl  Cl18  1  0.366  0.757  0.121  1.0
  Cl  Cl19  1  0.634  0.243  0.621  1.0
  O  O20  1  0.903  0.508  0.720  1.0
  O  O21  1  0.097  0.492  0.220  1.0
  O  O22  1  0.403  0.992  0.220  1.0
  O  O23  1  0.597  0.008  0.720  1.0
  O  O24  1  0.313  0.725  0.738  1.0
  O  O25  1  0.687  0.275  0.238  1.0
  O  O26  1  0.813  0.775  0.238  1.0
  O  O27  1  0.187  0.225  0.738  1.0
[/CIF]
.