The compound described by Ag4CuTeO6 crystallizes in the monoclinic C2/c space group. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 6-coordinate geometry to two equivalent O(3) and four equivalent O(1) atoms. In the second Ag site, Ag(2) is bonded in a 2-coordinate geometry to one O(1) and one O(2) atom. In the third Ag site, Ag(3) is bonded in a distorted linear geometry to two equivalent O(1) atoms. Cu(1) is bonded in a 6-coordinate geometry to two equivalent O(3) and four equivalent O(2) atoms. Te(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Ag(2), one Ag(3), two equivalent Ag(1), and one Te(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Ag(2), two equivalent Cu(1), and one Te(1) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Ag(1), one Cu(1), and one Te(1) atom. is represented by the CIF card [CIF]
data_CuAg4TeO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.573
_cell_length_b   7.573
_cell_length_c   5.839
_cell_angle_alpha   82.646
_cell_angle_beta   82.646
_cell_angle_gamma   81.404
_symmetry_Int_Tables_number   1
_cell_volume   326.362
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cu  Cu0  1  0.083  0.917  0.750  1.0
  Cu  Cu1  1  0.917  0.083  0.250  1.0
  Ag  Ag2  1  0.428  0.572  0.750  1.0
  Ag  Ag3  1  0.349  0.179  0.029  1.0
  Ag  Ag4  1  0.572  0.428  0.250  1.0
  Ag  Ag5  1  0.179  0.349  0.529  1.0
  Ag  Ag6  1  0.821  0.651  0.471  1.0
  Ag  Ag7  1  0.651  0.821  0.971  1.0
  Ag  Ag8  1  0.500  0.000  0.500  1.0
  Ag  Ag9  1  0.000  0.500  0.000  1.0
  Te  Te10  1  0.778  0.222  0.750  1.0
  Te  Te11  1  0.222  0.778  0.250  1.0
  O  O12  1  0.475  0.756  0.313  1.0
  O  O13  1  0.756  0.475  0.813  1.0
  O  O14  1  0.967  0.826  0.180  1.0
  O  O15  1  0.525  0.244  0.687  1.0
  O  O16  1  0.244  0.525  0.187  1.0
  O  O17  1  0.852  0.298  0.419  1.0
  O  O18  1  0.298  0.852  0.919  1.0
  O  O19  1  0.702  0.148  0.081  1.0
  O  O20  1  0.174  0.033  0.320  1.0
  O  O21  1  0.826  0.967  0.680  1.0
  O  O22  1  0.148  0.702  0.581  1.0
  O  O23  1  0.033  0.174  0.820  1.0
[/CIF]
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The compound described by Ag4CuTeO6 crystallizes in the monoclinic C2/c space group. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 6-coordinate geometry to two equivalent O(3) and four equivalent O(1) atoms. In the second Ag site, Ag(2) is bonded in a 2-coordinate geometry to one O(1) and one O(2) atom. In the third Ag site, Ag(3) is bonded in a distorted linear geometry to two equivalent O(1) atoms. Cu(1) is bonded in a 6-coordinate geometry to two equivalent O(3) and four equivalent O(2) atoms. Te(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Ag(2), one Ag(3), two equivalent Ag(1), and one Te(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Ag(2), two equivalent Cu(1), and one Te(1) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Ag(1), one Cu(1), and one Te(1) atom. is represented by the CIF card [CIF]
data_CuAg4TeO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.573
_cell_length_b   7.573
_cell_length_c   5.839
_cell_angle_alpha   82.646
_cell_angle_beta   82.646
_cell_angle_gamma   81.404
_symmetry_Int_Tables_number   1
_cell_volume   326.362
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cu  Cu0  1  0.083  0.917  0.750  1.0
  Cu  Cu1  1  0.917  0.083  0.250  1.0
  Ag  Ag2  1  0.428  0.572  0.750  1.0
  Ag  Ag3  1  0.349  0.179  0.029  1.0
  Ag  Ag4  1  0.572  0.428  0.250  1.0
  Ag  Ag5  1  0.179  0.349  0.529  1.0
  Ag  Ag6  1  0.821  0.651  0.471  1.0
  Ag  Ag7  1  0.651  0.821  0.971  1.0
  Ag  Ag8  1  0.500  0.000  0.500  1.0
  Ag  Ag9  1  0.000  0.500  0.000  1.0
  Te  Te10  1  0.778  0.222  0.750  1.0
  Te  Te11  1  0.222  0.778  0.250  1.0
  O  O12  1  0.475  0.756  0.313  1.0
  O  O13  1  0.756  0.475  0.813  1.0
  O  O14  1  0.967  0.826  0.180  1.0
  O  O15  1  0.525  0.244  0.687  1.0
  O  O16  1  0.244  0.525  0.187  1.0
  O  O17  1  0.852  0.298  0.419  1.0
  O  O18  1  0.298  0.852  0.919  1.0
  O  O19  1  0.702  0.148  0.081  1.0
  O  O20  1  0.174  0.033  0.320  1.0
  O  O21  1  0.826  0.967  0.680  1.0
  O  O22  1  0.148  0.702  0.581  1.0
  O  O23  1  0.033  0.174  0.820  1.0
[/CIF]
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