The structure described by PtSbS is Spinel-like structured and crystallizes in the cubic P2_13 space group. Pt(1) is bonded to three equivalent Sb(1) and three equivalent S(1) atoms to form PtSb3S3 octahedra that share corners with twelve equivalent Pt(1)Sb3S3 octahedra, corners with three equivalent Sb(1)Pt3S tetrahedra, and corners with three equivalent S(1)SbPt3 tetrahedra. The corner-sharing octahedral tilt angles are 64°. Sb(1) is bonded to three equivalent Pt(1) and one S(1) atom to form SbPt3S tetrahedra that share corners with three equivalent Pt(1)Sb3S3 octahedra, corners with six equivalent Sb(1)Pt3S tetrahedra, and corners with nine equivalent S(1)SbPt3 tetrahedra. The corner-sharing octahedral tilt angles are 78°. S(1) is bonded to three equivalent Pt(1) and one Sb(1) atom to form SSbPt3 tetrahedra that share corners with three equivalent Pt(1)Sb3S3 octahedra, corners with six equivalent S(1)SbPt3 tetrahedra, and corners with nine equivalent Sb(1)Pt3S tetrahedra. The corner-sharing octahedral tilt angles are 78°. is represented by the CIF file [CIF]
data_SbPtS
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.287
_cell_length_b   6.287
_cell_length_c   6.287
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   248.510
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.881  0.381  0.119  1.0
  Sb  Sb1  1  0.381  0.119  0.881  1.0
  Sb  Sb2  1  0.119  0.881  0.381  1.0
  Sb  Sb3  1  0.619  0.619  0.619  1.0
  Pt  Pt4  1  0.506  0.006  0.494  1.0
  Pt  Pt5  1  0.006  0.494  0.506  1.0
  Pt  Pt6  1  0.494  0.506  0.006  1.0
  Pt  Pt7  1  0.994  0.994  0.994  1.0
  S  S8  1  0.115  0.615  0.885  1.0
  S  S9  1  0.615  0.885  0.115  1.0
  S  S10  1  0.885  0.115  0.615  1.0
  S  S11  1  0.385  0.385  0.385  1.0
[/CIF]
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The structure described by PtSbS is Spinel-like structured and crystallizes in the cubic P2_13 space group. Pt(1) is bonded to three equivalent Sb(1) and three equivalent S(1) atoms to form PtSb3S3 octahedra that share corners with twelve equivalent Pt(1)Sb3S3 octahedra, corners with three equivalent Sb(1)Pt3S tetrahedra, and corners with three equivalent S(1)SbPt3 tetrahedra. The corner-sharing octahedral tilt angles are 64°. Sb(1) is bonded to three equivalent Pt(1) and one S(1) atom to form SbPt3S tetrahedra that share corners with three equivalent Pt(1)Sb3S3 octahedra, corners with six equivalent Sb(1)Pt3S tetrahedra, and corners with nine equivalent S(1)SbPt3 tetrahedra. The corner-sharing octahedral tilt angles are 78°. S(1) is bonded to three equivalent Pt(1) and one Sb(1) atom to form SSbPt3 tetrahedra that share corners with three equivalent Pt(1)Sb3S3 octahedra, corners with six equivalent S(1)SbPt3 tetrahedra, and corners with nine equivalent Sb(1)Pt3S tetrahedra. The corner-sharing octahedral tilt angles are 78°. is represented by the CIF file [CIF]
data_SbPtS
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.287
_cell_length_b   6.287
_cell_length_c   6.287
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   248.510
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.881  0.381  0.119  1.0
  Sb  Sb1  1  0.381  0.119  0.881  1.0
  Sb  Sb2  1  0.119  0.881  0.381  1.0
  Sb  Sb3  1  0.619  0.619  0.619  1.0
  Pt  Pt4  1  0.506  0.006  0.494  1.0
  Pt  Pt5  1  0.006  0.494  0.506  1.0
  Pt  Pt6  1  0.494  0.506  0.006  1.0
  Pt  Pt7  1  0.994  0.994  0.994  1.0
  S  S8  1  0.115  0.615  0.885  1.0
  S  S9  1  0.615  0.885  0.115  1.0
  S  S10  1  0.885  0.115  0.615  1.0
  S  S11  1  0.385  0.385  0.385  1.0
[/CIF]
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