The crystal structure described by RhInO3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. Rh(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form corner-sharing RhO6 octahedra. The corner-sharing octahedral tilt angles range from 42-45°. In(1) is bonded in a 6-coordinate geometry to two equivalent O(1) and four equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Rh(1) and two equivalent In(1) atoms to form a mixture of edge and corner-sharing OIn2Rh2 trigonal pyramids. In the second O site, O(2) is bonded to two equivalent Rh(1) and two equivalent In(1) atoms to form a mixture of distorted edge and corner-sharing OIn2Rh2 trigonal pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_InRhO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.341
_cell_length_b   5.499
_cell_length_c   7.866
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   231.011
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.525  0.562  0.250  1.0
  In  In1  1  0.975  0.062  0.250  1.0
  In  In2  1  0.475  0.438  0.750  1.0
  In  In3  1  0.025  0.938  0.750  1.0
  Rh  Rh4  1  0.000  0.500  0.000  1.0
  Rh  Rh5  1  0.500  0.000  0.500  1.0
  Rh  Rh6  1  0.000  0.500  0.500  1.0
  Rh  Rh7  1  0.500  0.000  0.000  1.0
  O  O8  1  0.364  0.930  0.250  1.0
  O  O9  1  0.136  0.430  0.250  1.0
  O  O10  1  0.636  0.070  0.750  1.0
  O  O11  1  0.864  0.570  0.750  1.0
  O  O12  1  0.803  0.800  0.078  1.0
  O  O13  1  0.697  0.300  0.422  1.0
  O  O14  1  0.197  0.200  0.578  1.0
  O  O15  1  0.303  0.700  0.922  1.0
  O  O16  1  0.197  0.200  0.922  1.0
  O  O17  1  0.303  0.700  0.578  1.0
  O  O18  1  0.803  0.800  0.422  1.0
  O  O19  1  0.697  0.300  0.078  1.0
[/CIF]
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The crystal structure described by RhInO3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. Rh(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form corner-sharing RhO6 octahedra. The corner-sharing octahedral tilt angles range from 42-45°. In(1) is bonded in a 6-coordinate geometry to two equivalent O(1) and four equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Rh(1) and two equivalent In(1) atoms to form a mixture of edge and corner-sharing OIn2Rh2 trigonal pyramids. In the second O site, O(2) is bonded to two equivalent Rh(1) and two equivalent In(1) atoms to form a mixture of distorted edge and corner-sharing OIn2Rh2 trigonal pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_InRhO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.341
_cell_length_b   5.499
_cell_length_c   7.866
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   231.011
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.525  0.562  0.250  1.0
  In  In1  1  0.975  0.062  0.250  1.0
  In  In2  1  0.475  0.438  0.750  1.0
  In  In3  1  0.025  0.938  0.750  1.0
  Rh  Rh4  1  0.000  0.500  0.000  1.0
  Rh  Rh5  1  0.500  0.000  0.500  1.0
  Rh  Rh6  1  0.000  0.500  0.500  1.0
  Rh  Rh7  1  0.500  0.000  0.000  1.0
  O  O8  1  0.364  0.930  0.250  1.0
  O  O9  1  0.136  0.430  0.250  1.0
  O  O10  1  0.636  0.070  0.750  1.0
  O  O11  1  0.864  0.570  0.750  1.0
  O  O12  1  0.803  0.800  0.078  1.0
  O  O13  1  0.697  0.300  0.422  1.0
  O  O14  1  0.197  0.200  0.578  1.0
  O  O15  1  0.303  0.700  0.922  1.0
  O  O16  1  0.197  0.200  0.922  1.0
  O  O17  1  0.303  0.700  0.578  1.0
  O  O18  1  0.803  0.800  0.422  1.0
  O  O19  1  0.697  0.300  0.078  1.0
[/CIF]
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