The compound described by Cs3InO3 crystallizes in the monoclinic P2_1/c space group. There are three inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a 4-coordinate geometry to one O(1), one O(3), and two equivalent O(2) atoms. In the second Cs site, Cs(2) is bonded in a 5-coordinate geometry to one O(3), two equivalent O(1), and two equivalent O(2) atoms. In the third Cs site, Cs(3) is bonded in a 4-coordinate geometry to one O(1), two equivalent O(2), and two equivalent O(3) atoms. In(1) is bonded to one O(1), one O(2), and two equivalent O(3) atoms to form edge-sharing InO4 tetrahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to one Cs(1), one Cs(3), two equivalent Cs(2), and one In(1) atom. In the second O site, O(2) is bonded in a 7-coordinate geometry to two equivalent Cs(1), two equivalent Cs(2), two equivalent Cs(3), and one In(1) atom. In the third O site, O(3) is bonded in a 6-coordinate geometry to one Cs(1), one Cs(2), two equivalent Cs(3), and two equivalent In(1) atoms. is represented by the CIF file [CIF]
data_Cs3InO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.352
_cell_length_b   8.208
_cell_length_c   11.835
_cell_angle_alpha   84.550
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   711.018
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.832  0.651  0.428  1.0
  Cs  Cs1  1  0.821  0.374  0.194  1.0
  Cs  Cs2  1  0.321  0.626  0.306  1.0
  Cs  Cs3  1  0.679  0.374  0.694  1.0
  Cs  Cs4  1  0.623  0.952  0.156  1.0
  Cs  Cs5  1  0.168  0.349  0.572  1.0
  Cs  Cs6  1  0.877  0.952  0.656  1.0
  Cs  Cs7  1  0.179  0.626  0.806  1.0
  Cs  Cs8  1  0.668  0.651  0.928  1.0
  Cs  Cs9  1  0.377  0.048  0.844  1.0
  Cs  Cs10  1  0.123  0.048  0.344  1.0
  Cs  Cs11  1  0.332  0.349  0.072  1.0
  In  In12  1  0.416  0.844  0.567  1.0
  In  In13  1  0.084  0.844  0.067  1.0
  In  In14  1  0.584  0.156  0.433  1.0
  In  In15  1  0.916  0.156  0.933  1.0
  O  O16  1  0.943  0.708  0.192  1.0
  O  O17  1  0.161  0.754  0.540  1.0
  O  O18  1  0.447  0.099  0.591  1.0
  O  O19  1  0.339  0.754  0.040  1.0
  O  O20  1  0.557  0.708  0.692  1.0
  O  O21  1  0.553  0.901  0.409  1.0
  O  O22  1  0.057  0.292  0.808  1.0
  O  O23  1  0.443  0.292  0.308  1.0
  O  O24  1  0.839  0.246  0.460  1.0
  O  O25  1  0.661  0.246  0.960  1.0
  O  O26  1  0.053  0.099  0.091  1.0
  O  O27  1  0.947  0.901  0.909  1.0
[/CIF]
.
The compound described by Cs3InO3 crystallizes in the monoclinic P2_1/c space group. There are three inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a 4-coordinate geometry to one O(1), one O(3), and two equivalent O(2) atoms. In the second Cs site, Cs(2) is bonded in a 5-coordinate geometry to one O(3), two equivalent O(1), and two equivalent O(2) atoms. In the third Cs site, Cs(3) is bonded in a 4-coordinate geometry to one O(1), two equivalent O(2), and two equivalent O(3) atoms. In(1) is bonded to one O(1), one O(2), and two equivalent O(3) atoms to form edge-sharing InO4 tetrahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to one Cs(1), one Cs(3), two equivalent Cs(2), and one In(1) atom. In the second O site, O(2) is bonded in a 7-coordinate geometry to two equivalent Cs(1), two equivalent Cs(2), two equivalent Cs(3), and one In(1) atom. In the third O site, O(3) is bonded in a 6-coordinate geometry to one Cs(1), one Cs(2), two equivalent Cs(3), and two equivalent In(1) atoms. is represented by the CIF file [CIF]
data_Cs3InO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.352
_cell_length_b   8.208
_cell_length_c   11.835
_cell_angle_alpha   84.550
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   711.018
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.832  0.651  0.428  1.0
  Cs  Cs1  1  0.821  0.374  0.194  1.0
  Cs  Cs2  1  0.321  0.626  0.306  1.0
  Cs  Cs3  1  0.679  0.374  0.694  1.0
  Cs  Cs4  1  0.623  0.952  0.156  1.0
  Cs  Cs5  1  0.168  0.349  0.572  1.0
  Cs  Cs6  1  0.877  0.952  0.656  1.0
  Cs  Cs7  1  0.179  0.626  0.806  1.0
  Cs  Cs8  1  0.668  0.651  0.928  1.0
  Cs  Cs9  1  0.377  0.048  0.844  1.0
  Cs  Cs10  1  0.123  0.048  0.344  1.0
  Cs  Cs11  1  0.332  0.349  0.072  1.0
  In  In12  1  0.416  0.844  0.567  1.0
  In  In13  1  0.084  0.844  0.067  1.0
  In  In14  1  0.584  0.156  0.433  1.0
  In  In15  1  0.916  0.156  0.933  1.0
  O  O16  1  0.943  0.708  0.192  1.0
  O  O17  1  0.161  0.754  0.540  1.0
  O  O18  1  0.447  0.099  0.591  1.0
  O  O19  1  0.339  0.754  0.040  1.0
  O  O20  1  0.557  0.708  0.692  1.0
  O  O21  1  0.553  0.901  0.409  1.0
  O  O22  1  0.057  0.292  0.808  1.0
  O  O23  1  0.443  0.292  0.308  1.0
  O  O24  1  0.839  0.246  0.460  1.0
  O  O25  1  0.661  0.246  0.960  1.0
  O  O26  1  0.053  0.099  0.091  1.0
  O  O27  1  0.947  0.901  0.909  1.0
[/CIF]
.