The material structure described by Cs3NO4 crystallizes in the orthorhombic Pnma space group. There are two inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a 6-coordinate geometry to one O(1), one O(3), and four equivalent O(2) atoms. In the second Cs site, Cs(2) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(3), and four equivalent O(2) atoms. N(1) is bonded in a tetrahedral geometry to one O(1), one O(3), and two equivalent O(2) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cs(1), four equivalent Cs(2), and one N(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Cs(1), four equivalent Cs(2), and one N(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Cs(1), four equivalent Cs(2), and one N(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Cs3NO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.319
_cell_length_b   8.920
_cell_length_c   12.170
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   685.925
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.368  0.250  0.072  1.0
  Cs  Cs1  1  0.828  0.009  0.146  1.0
  Cs  Cs2  1  0.828  0.491  0.146  1.0
  Cs  Cs3  1  0.328  0.509  0.354  1.0
  Cs  Cs4  1  0.328  0.991  0.354  1.0
  Cs  Cs5  1  0.868  0.750  0.428  1.0
  Cs  Cs6  1  0.132  0.250  0.572  1.0
  Cs  Cs7  1  0.672  0.009  0.646  1.0
  Cs  Cs8  1  0.672  0.491  0.646  1.0
  Cs  Cs9  1  0.172  0.509  0.854  1.0
  Cs  Cs10  1  0.172  0.991  0.854  1.0
  Cs  Cs11  1  0.632  0.750  0.928  1.0
  N  N12  1  0.217  0.750  0.115  1.0
  N  N13  1  0.717  0.250  0.385  1.0
  N  N14  1  0.283  0.750  0.615  1.0
  N  N15  1  0.783  0.250  0.885  1.0
  O  O16  1  0.069  0.750  0.028  1.0
  O  O17  1  0.343  0.620  0.109  1.0
  O  O18  1  0.343  0.880  0.109  1.0
  O  O19  1  0.105  0.750  0.216  1.0
  O  O20  1  0.605  0.250  0.284  1.0
  O  O21  1  0.843  0.120  0.391  1.0
  O  O22  1  0.843  0.380  0.391  1.0
  O  O23  1  0.569  0.250  0.472  1.0
  O  O24  1  0.431  0.750  0.528  1.0
  O  O25  1  0.157  0.620  0.609  1.0
  O  O26  1  0.157  0.880  0.609  1.0
  O  O27  1  0.395  0.750  0.716  1.0
  O  O28  1  0.895  0.250  0.784  1.0
  O  O29  1  0.657  0.120  0.891  1.0
  O  O30  1  0.657  0.380  0.891  1.0
  O  O31  1  0.931  0.250  0.972  1.0
[/CIF]
.
The material structure described by Cs3NO4 crystallizes in the orthorhombic Pnma space group. There are two inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a 6-coordinate geometry to one O(1), one O(3), and four equivalent O(2) atoms. In the second Cs site, Cs(2) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(3), and four equivalent O(2) atoms. N(1) is bonded in a tetrahedral geometry to one O(1), one O(3), and two equivalent O(2) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cs(1), four equivalent Cs(2), and one N(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Cs(1), four equivalent Cs(2), and one N(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Cs(1), four equivalent Cs(2), and one N(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Cs3NO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.319
_cell_length_b   8.920
_cell_length_c   12.170
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   685.925
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.368  0.250  0.072  1.0
  Cs  Cs1  1  0.828  0.009  0.146  1.0
  Cs  Cs2  1  0.828  0.491  0.146  1.0
  Cs  Cs3  1  0.328  0.509  0.354  1.0
  Cs  Cs4  1  0.328  0.991  0.354  1.0
  Cs  Cs5  1  0.868  0.750  0.428  1.0
  Cs  Cs6  1  0.132  0.250  0.572  1.0
  Cs  Cs7  1  0.672  0.009  0.646  1.0
  Cs  Cs8  1  0.672  0.491  0.646  1.0
  Cs  Cs9  1  0.172  0.509  0.854  1.0
  Cs  Cs10  1  0.172  0.991  0.854  1.0
  Cs  Cs11  1  0.632  0.750  0.928  1.0
  N  N12  1  0.217  0.750  0.115  1.0
  N  N13  1  0.717  0.250  0.385  1.0
  N  N14  1  0.283  0.750  0.615  1.0
  N  N15  1  0.783  0.250  0.885  1.0
  O  O16  1  0.069  0.750  0.028  1.0
  O  O17  1  0.343  0.620  0.109  1.0
  O  O18  1  0.343  0.880  0.109  1.0
  O  O19  1  0.105  0.750  0.216  1.0
  O  O20  1  0.605  0.250  0.284  1.0
  O  O21  1  0.843  0.120  0.391  1.0
  O  O22  1  0.843  0.380  0.391  1.0
  O  O23  1  0.569  0.250  0.472  1.0
  O  O24  1  0.431  0.750  0.528  1.0
  O  O25  1  0.157  0.620  0.609  1.0
  O  O26  1  0.157  0.880  0.609  1.0
  O  O27  1  0.395  0.750  0.716  1.0
  O  O28  1  0.895  0.250  0.784  1.0
  O  O29  1  0.657  0.120  0.891  1.0
  O  O30  1  0.657  0.380  0.891  1.0
  O  O31  1  0.931  0.250  0.972  1.0
[/CIF]
.