The material described by Cs2Na(C2N3)3 crystallizes in the hexagonal P6_3/m space group. Cs(1) is bonded in a 6-coordinate geometry to six equivalent N(1) atoms. Na(1) is bonded in an octahedral geometry to six equivalent N(1) atoms. C(1) is bonded in a linear geometry to one N(1) and one N(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 2-coordinate geometry to two equivalent Cs(1), one Na(1), and one C(1) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to two equivalent C(1) atoms. is represented by the CIF file [CIF]
data_Cs2Na(C2N3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.240
_cell_length_b   7.240
_cell_length_c   14.850
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   674.114
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.333  0.667  0.070  1.0
  Cs  Cs1  1  0.667  0.333  0.930  1.0
  Cs  Cs2  1  0.333  0.667  0.430  1.0
  Cs  Cs3  1  0.667  0.333  0.570  1.0
  Na  Na4  1  0.000  0.000  0.000  1.0
  Na  Na5  1  0.000  0.000  0.500  1.0
  C  C6  1  0.858  0.198  0.328  1.0
  C  C7  1  0.858  0.198  0.172  1.0
  C  C8  1  0.660  0.858  0.828  1.0
  C  C9  1  0.340  0.142  0.328  1.0
  C  C10  1  0.142  0.802  0.672  1.0
  C  C11  1  0.142  0.802  0.828  1.0
  C  C12  1  0.660  0.858  0.672  1.0
  C  C13  1  0.802  0.660  0.328  1.0
  C  C14  1  0.802  0.660  0.172  1.0
  C  C15  1  0.198  0.340  0.672  1.0
  C  C16  1  0.340  0.142  0.172  1.0
  C  C17  1  0.198  0.340  0.828  1.0
  N  N18  1  0.866  0.673  0.402  1.0
  N  N19  1  0.327  0.193  0.402  1.0
  N  N20  1  0.713  0.644  0.250  1.0
  N  N21  1  0.807  0.134  0.402  1.0
  N  N22  1  0.673  0.807  0.598  1.0
  N  N23  1  0.673  0.807  0.902  1.0
  N  N24  1  0.287  0.356  0.750  1.0
  N  N25  1  0.134  0.327  0.902  1.0
  N  N26  1  0.193  0.866  0.902  1.0
  N  N27  1  0.193  0.866  0.598  1.0
  N  N28  1  0.069  0.713  0.750  1.0
  N  N29  1  0.134  0.327  0.598  1.0
  N  N30  1  0.644  0.931  0.750  1.0
  N  N31  1  0.807  0.134  0.098  1.0
  N  N32  1  0.356  0.069  0.250  1.0
  N  N33  1  0.327  0.193  0.098  1.0
  N  N34  1  0.931  0.287  0.250  1.0
  N  N35  1  0.866  0.673  0.098  1.0
[/CIF]
.
The material described by Cs2Na(C2N3)3 crystallizes in the hexagonal P6_3/m space group. Cs(1) is bonded in a 6-coordinate geometry to six equivalent N(1) atoms. Na(1) is bonded in an octahedral geometry to six equivalent N(1) atoms. C(1) is bonded in a linear geometry to one N(1) and one N(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 2-coordinate geometry to two equivalent Cs(1), one Na(1), and one C(1) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to two equivalent C(1) atoms. is represented by the CIF file [CIF]
data_Cs2Na(C2N3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.240
_cell_length_b   7.240
_cell_length_c   14.850
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   674.114
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.333  0.667  0.070  1.0
  Cs  Cs1  1  0.667  0.333  0.930  1.0
  Cs  Cs2  1  0.333  0.667  0.430  1.0
  Cs  Cs3  1  0.667  0.333  0.570  1.0
  Na  Na4  1  0.000  0.000  0.000  1.0
  Na  Na5  1  0.000  0.000  0.500  1.0
  C  C6  1  0.858  0.198  0.328  1.0
  C  C7  1  0.858  0.198  0.172  1.0
  C  C8  1  0.660  0.858  0.828  1.0
  C  C9  1  0.340  0.142  0.328  1.0
  C  C10  1  0.142  0.802  0.672  1.0
  C  C11  1  0.142  0.802  0.828  1.0
  C  C12  1  0.660  0.858  0.672  1.0
  C  C13  1  0.802  0.660  0.328  1.0
  C  C14  1  0.802  0.660  0.172  1.0
  C  C15  1  0.198  0.340  0.672  1.0
  C  C16  1  0.340  0.142  0.172  1.0
  C  C17  1  0.198  0.340  0.828  1.0
  N  N18  1  0.866  0.673  0.402  1.0
  N  N19  1  0.327  0.193  0.402  1.0
  N  N20  1  0.713  0.644  0.250  1.0
  N  N21  1  0.807  0.134  0.402  1.0
  N  N22  1  0.673  0.807  0.598  1.0
  N  N23  1  0.673  0.807  0.902  1.0
  N  N24  1  0.287  0.356  0.750  1.0
  N  N25  1  0.134  0.327  0.902  1.0
  N  N26  1  0.193  0.866  0.902  1.0
  N  N27  1  0.193  0.866  0.598  1.0
  N  N28  1  0.069  0.713  0.750  1.0
  N  N29  1  0.134  0.327  0.598  1.0
  N  N30  1  0.644  0.931  0.750  1.0
  N  N31  1  0.807  0.134  0.098  1.0
  N  N32  1  0.356  0.069  0.250  1.0
  N  N33  1  0.327  0.193  0.098  1.0
  N  N34  1  0.931  0.287  0.250  1.0
  N  N35  1  0.866  0.673  0.098  1.0
[/CIF]
.