The crystal structure described by Co3(BiN2)2 crystallizes in the monoclinic C2/c space group. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent N(1) and two equivalent N(2) atoms. In the second Co site, Co(2) is bonded in a distorted see-saw-like geometry to two equivalent N(1) and two equivalent N(2) atoms. Bi(1) is bonded in a 2-coordinate geometry to one N(1) and one N(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 4-coordinate geometry to one Co(2), two equivalent Co(1), and one Bi(1) atom. In the second N site, N(2) is bonded in a rectangular see-saw-like geometry to one Co(2), two equivalent Co(1), and one Bi(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Co3(BiN2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.647
_cell_length_b   10.138
_cell_length_c   5.919
_cell_angle_alpha   90.000
_cell_angle_beta   88.705
_cell_angle_gamma   139.691
_symmetry_Int_Tables_number   1
_cell_volume   257.850
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.241  0.921  0.141  1.0
  Co  Co1  1  0.759  0.680  0.359  1.0
  Co  Co2  1  0.759  0.079  0.859  1.0
  Co  Co3  1  0.241  0.320  0.641  1.0
  Co  Co4  1  0.000  0.767  0.750  1.0
  Co  Co5  1  0.000  0.233  0.250  1.0
  Bi  Bi6  1  0.565  0.234  0.580  1.0
  Bi  Bi7  1  0.435  0.668  0.920  1.0
  Bi  Bi8  1  0.435  0.766  0.420  1.0
  Bi  Bi9  1  0.565  0.332  0.080  1.0
  N  N10  1  0.177  0.893  0.453  1.0
  N  N11  1  0.823  0.716  0.047  1.0
  N  N12  1  0.823  0.107  0.547  1.0
  N  N13  1  0.177  0.284  0.953  1.0
  N  N14  1  0.678  0.148  0.107  1.0
  N  N15  1  0.322  0.470  0.393  1.0
  N  N16  1  0.322  0.852  0.893  1.0
  N  N17  1  0.678  0.530  0.607  1.0
[/CIF]
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The crystal structure described by Co3(BiN2)2 crystallizes in the monoclinic C2/c space group. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent N(1) and two equivalent N(2) atoms. In the second Co site, Co(2) is bonded in a distorted see-saw-like geometry to two equivalent N(1) and two equivalent N(2) atoms. Bi(1) is bonded in a 2-coordinate geometry to one N(1) and one N(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 4-coordinate geometry to one Co(2), two equivalent Co(1), and one Bi(1) atom. In the second N site, N(2) is bonded in a rectangular see-saw-like geometry to one Co(2), two equivalent Co(1), and one Bi(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Co3(BiN2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.647
_cell_length_b   10.138
_cell_length_c   5.919
_cell_angle_alpha   90.000
_cell_angle_beta   88.705
_cell_angle_gamma   139.691
_symmetry_Int_Tables_number   1
_cell_volume   257.850
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.241  0.921  0.141  1.0
  Co  Co1  1  0.759  0.680  0.359  1.0
  Co  Co2  1  0.759  0.079  0.859  1.0
  Co  Co3  1  0.241  0.320  0.641  1.0
  Co  Co4  1  0.000  0.767  0.750  1.0
  Co  Co5  1  0.000  0.233  0.250  1.0
  Bi  Bi6  1  0.565  0.234  0.580  1.0
  Bi  Bi7  1  0.435  0.668  0.920  1.0
  Bi  Bi8  1  0.435  0.766  0.420  1.0
  Bi  Bi9  1  0.565  0.332  0.080  1.0
  N  N10  1  0.177  0.893  0.453  1.0
  N  N11  1  0.823  0.716  0.047  1.0
  N  N12  1  0.823  0.107  0.547  1.0
  N  N13  1  0.177  0.284  0.953  1.0
  N  N14  1  0.678  0.148  0.107  1.0
  N  N15  1  0.322  0.470  0.393  1.0
  N  N16  1  0.322  0.852  0.893  1.0
  N  N17  1  0.678  0.530  0.607  1.0
[/CIF]
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