The structure described by LiFe13Zn4O24 is Spinel-derived structured and crystallizes in the monoclinic Cm space group. Li(1) is bonded to one O(11), one O(13), and two equivalent O(9) atoms to form LiO4 tetrahedra that share  a cornercorner with one Zn(3)O6 octahedra, corners with two equivalent Fe(5)O6 octahedra, corners with two equivalent Fe(8)O6 octahedra, corners with three equivalent Fe(9)O6 octahedra, and corners with four equivalent Fe(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 58-63°. There are ten inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to one O(16), one O(7), and two equivalent O(17) atoms to form FeO4 tetrahedra that share  a cornercorner with one Zn(2)O6 octahedra, corners with two equivalent Fe(2)O6 octahedra, corners with two equivalent Fe(8)O6 octahedra, corners with three equivalent Zn(1)O6 octahedra, and corners with four equivalent Fe(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-58°. In the second Fe site, Fe(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(6), and one O(7) atom to form FeO6 octahedra that share  a cornercorner with one Fe(1)O4 tetrahedra,  a cornercorner with one Fe(7)O4 tetrahedra, corners with two equivalent Fe(3)O4 tetrahedra, corners with two equivalent Fe(4)O4 tetrahedra,  an edgeedge with one Zn(1)O6 octahedra,  an edgeedge with one Zn(4)O6 octahedra, edges with two equivalent Fe(2)O6 octahedra, and edges with two equivalent Zn(2)O6 octahedra. In the third Fe site, Fe(3) is bonded to one O(18), one O(4), and two equivalent O(2) atoms to form FeO4 tetrahedra that share  a cornercorner with one Fe(8)O6 octahedra, corners with two equivalent Fe(6)O6 octahedra, corners with two equivalent Zn(2)O6 octahedra, corners with three equivalent Zn(1)O6 octahedra, and corners with four equivalent Fe(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-59°. In the fourth Fe site, Fe(4) is bonded to one O(5), one O(6), and two equivalent O(1) atoms to form FeO4 tetrahedra that share  a cornercorner with one Zn(3)O6 octahedra, corners with two equivalent Fe(5)O6 octahedra, corners with two equivalent Zn(2)O6 octahedra, corners with three equivalent Zn(4)O6 octahedra, and corners with four equivalent Fe(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-59°. In the fifth Fe site, Fe(5) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(8) atom to form FeO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Fe(4)O4 tetrahedra, corners with two equivalent Fe(10)O4 tetrahedra, corners with two equivalent Fe(7)O4 tetrahedra,  an edgeedge with one Fe(9)O6 octahedra,  an edgeedge with one Zn(4)O6 octahedra, edges with two equivalent Fe(5)O6 octahedra, and edges with two equivalent Zn(3)O6 octahedra. In the sixth Fe site, Fe(6) is bonded to one O(11), one O(14), one O(16), one O(17), one O(18), and one O(9) atom to form FeO6 octahedra that share  a cornercorner with one Fe(10)O4 tetrahedra,  a cornercorner with one Fe(3)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra, corners with two equivalent Fe(1)O4 tetrahedra,  an edgeedge with one Fe(9)O6 octahedra,  an edgeedge with one Zn(1)O6 octahedra, edges with two equivalent Fe(6)O6 octahedra, and edges with two equivalent Fe(8)O6 octahedra. In the seventh Fe site, Fe(7) is bonded to one O(12), one O(3), and two equivalent O(10) atoms to form FeO4 tetrahedra that share  a cornercorner with one Zn(2)O6 octahedra, corners with two equivalent Fe(2)O6 octahedra, corners with two equivalent Zn(3)O6 octahedra, corners with three equivalent Zn(4)O6 octahedra, and corners with four equivalent Fe(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-57°. In the eighth Fe site, Fe(8) is bonded to one O(14), one O(18), two equivalent O(17), and two equivalent O(9) atoms to form FeO6 octahedra that share  a cornercorner with one Fe(10)O4 tetrahedra,  a cornercorner with one Fe(3)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra, corners with two equivalent Fe(1)O4 tetrahedra,  an edgeedge with one Fe(9)O6 octahedra,  an edgeedge with one Zn(1)O6 octahedra, and edges with four equivalent Fe(6)O6 octahedra. In the ninth Fe site, Fe(9) is bonded to one O(11), one O(15), two equivalent O(8), and two equivalent O(9) atoms to form FeO6 octahedra that share corners with three equivalent Li(1)O4 tetrahedra, corners with three equivalent Fe(10)O4 tetrahedra,  an edgeedge with one Fe(8)O6 octahedra,  an edgeedge with one Zn(3)O6 octahedra, edges with two equivalent Fe(5)O6 octahedra, and edges with two equivalent Fe(6)O6 octahedra. In the tenth Fe site, Fe(10) is bonded to one O(14), one O(15), and two equivalent O(8) atoms to form FeO4 tetrahedra that share  a cornercorner with one Fe(8)O6 octahedra, corners with two equivalent Fe(6)O6 octahedra, corners with two equivalent Zn(3)O6 octahedra, corners with three equivalent Fe(9)O6 octahedra, and corners with four equivalent Fe(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-60°. There are four inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(16), one O(4), two equivalent O(17), and two equivalent O(2) atoms to form ZnO6 octahedra that share corners with three equivalent Fe(1)O4 tetrahedra, corners with three equivalent Fe(3)O4 tetrahedra,  an edgeedge with one Fe(8)O6 octahedra,  an edgeedge with one Zn(2)O6 octahedra, edges with two equivalent Fe(2)O6 octahedra, and edges with two equivalent Fe(6)O6 octahedra. In the second Zn site, Zn(2) is bonded to one O(3), one O(7), two equivalent O(1), and two equivalent O(2) atoms to form ZnO6 octahedra that share  a cornercorner with one Fe(1)O4 tetrahedra,  a cornercorner with one Fe(7)O4 tetrahedra, corners with two equivalent Fe(3)O4 tetrahedra, corners with two equivalent Fe(4)O4 tetrahedra,  an edgeedge with one Zn(1)O6 octahedra,  an edgeedge with one Zn(4)O6 octahedra, and edges with four equivalent Fe(2)O6 octahedra. In the third Zn site, Zn(3) is bonded to one O(13), one O(5), two equivalent O(10), and two equivalent O(8) atoms to form ZnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Fe(4)O4 tetrahedra, corners with two equivalent Fe(10)O4 tetrahedra, corners with two equivalent Fe(7)O4 tetrahedra,  an edgeedge with one Fe(9)O6 octahedra,  an edgeedge with one Zn(4)O6 octahedra, and edges with four equivalent Fe(5)O6 octahedra. In the fourth Zn site, Zn(4) is bonded to one O(12), one O(6), two equivalent O(1), and two equivalent O(10) atoms to form ZnO6 octahedra that share corners with three equivalent Fe(4)O4 tetrahedra, corners with three equivalent Fe(7)O4 tetrahedra,  an edgeedge with one Zn(2)O6 octahedra,  an edgeedge with one Zn(3)O6 octahedra, edges with two equivalent Fe(2)O6 octahedra, and edges with two equivalent Fe(5)O6 octahedra. There are eighteen inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Fe(2), one Fe(4), one Zn(2), and one Zn(4) atom. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one Fe(2), one Fe(3), one Zn(1), and one Zn(2) atom. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Fe(7), two equivalent Fe(2), and one Zn(2) atom. In the fourth O site, O(4) is bonded in a distorted rectangular see-saw-like geometry to one Fe(3), two equivalent Fe(2), and one Zn(1) atom. In the fifth O site, O(5) is bonded in a distorted rectangular see-saw-like geometry to one Fe(4), two equivalent Fe(5), and one Zn(3) atom. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Fe(4), two equivalent Fe(2), and one Zn(4) atom. In the seventh O site, O(7) is bonded in a rectangular see-saw-like geometry to one Fe(1), two equivalent Fe(2), and one Zn(2) atom. In the eighth O site, O(8) is bonded in a rectangular see-saw-like geometry to one Fe(10), one Fe(5), one Fe(9), and one Zn(3) atom. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Li(1), one Fe(6), one Fe(8), and one Fe(9) atom. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one Fe(5), one Fe(7), one Zn(3), and one Zn(4) atom. In the eleventh O site, O(11) is bonded to one Li(1), one Fe(9), and two equivalent Fe(6) atoms to form distorted corner-sharing OLiFe3 trigonal pyramids. In the twelfth O site, O(12) is bonded in a rectangular see-saw-like geometry to one Fe(7), two equivalent Fe(5), and one Zn(4) atom. In the thirteenth O site, O(13) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), two equivalent Fe(5), and one Zn(3) atom. In the fourteenth O site, O(14) is bonded to one Fe(10), one Fe(8), and two equivalent Fe(6) atoms to form distorted OFe4 trigonal pyramids that share  a cornercorner with one O(15)Fe4 trigonal pyramid and corners with two equivalent O(11)LiFe3 trigonal pyramids. In the fifteenth O site, O(15) is bonded to one Fe(10), one Fe(9), and two equivalent Fe(5) atoms to form distorted OFe4 trigonal pyramids that share  a cornercorner with one O(14)Fe4 trigonal pyramid and  a cornercorner with one O(11)LiFe3 trigonal pyramid. In the sixteenth O site, O(16) is bonded in a distorted rectangular see-saw-like geometry to one Fe(1), two equivalent Fe(6), and one Zn(1) atom. In the seventeenth O site, O(17) is bonded in a rectangular see-saw-like geometry to one Fe(1), one Fe(6), one Fe(8), and one Zn(1) atom. In the eighteenth O site, O(18) is bonded in a rectangular see-saw-like geometry to one Fe(3), one Fe(8), and two equivalent Fe(6) atoms. is represented by the CIF card [CIF]
data_LiZn4Fe13O24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.059
_cell_length_b   6.059
_cell_length_c   14.814
_cell_angle_alpha   89.743
_cell_angle_beta   89.743
_cell_angle_gamma   59.983
_symmetry_Int_Tables_number   1
_cell_volume   470.974
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.001  0.001  0.250  1.0
  Zn  Zn1  1  0.668  0.668  0.959  1.0
  Zn  Zn2  1  0.834  0.834  0.792  1.0
  Zn  Zn3  1  0.164  0.164  0.456  1.0
  Zn  Zn4  1  1.000  1.000  0.624  1.0
  Fe  Fe5  1  0.001  0.001  0.004  1.0
  Fe  Fe6  1  0.333  0.834  0.792  1.0
  Fe  Fe7  1  0.331  0.331  0.912  1.0
  Fe  Fe8  1  0.338  0.338  0.667  1.0
  Fe  Fe9  1  0.162  0.671  0.458  1.0
  Fe  Fe10  1  0.834  0.333  0.792  1.0
  Fe  Fe11  1  0.005  0.498  0.127  1.0
  Fe  Fe12  1  0.671  0.162  0.458  1.0
  Fe  Fe13  1  0.661  0.661  0.583  1.0
  Fe  Fe14  1  0.498  0.498  0.127  1.0
  Fe  Fe15  1  0.334  0.334  0.288  1.0
  Fe  Fe16  1  0.669  0.669  0.334  1.0
  Fe  Fe17  1  0.498  0.005  0.127  1.0
  O  O18  1  0.682  0.169  0.713  1.0
  O  O19  1  0.499  0.985  0.872  1.0
  O  O20  1  0.662  0.662  0.716  1.0
  O  O21  1  0.507  0.507  0.870  1.0
  O  O22  1  0.336  0.336  0.535  1.0
  O  O23  1  0.162  0.162  0.715  1.0
  O  O24  1  0.006  0.006  0.872  1.0
  O  O25  1  0.019  0.498  0.374  1.0
  O  O26  1  0.169  0.682  0.713  1.0
  O  O27  1  0.183  0.635  0.202  1.0
  O  O28  1  0.828  0.321  0.538  1.0
  O  O29  1  0.985  0.499  0.872  1.0
  O  O30  1  0.321  0.828  0.538  1.0
  O  O31  1  0.184  0.184  0.203  1.0
  O  O32  1  0.835  0.835  0.537  1.0
  O  O33  1  0.993  0.993  0.389  1.0
  O  O34  1  0.667  0.667  0.201  1.0
  O  O35  1  0.491  0.491  0.376  1.0
  O  O36  1  0.827  0.827  0.048  1.0
  O  O37  1  0.349  0.828  0.048  1.0
  O  O38  1  0.498  0.019  0.374  1.0
  O  O39  1  0.828  0.349  0.048  1.0
  O  O40  1  0.635  0.183  0.202  1.0
  O  O41  1  0.334  0.334  0.045  1.0
[/CIF]
.
The structure described by LiFe13Zn4O24 is Spinel-derived structured and crystallizes in the monoclinic Cm space group. Li(1) is bonded to one O(11), one O(13), and two equivalent O(9) atoms to form LiO4 tetrahedra that share  a cornercorner with one Zn(3)O6 octahedra, corners with two equivalent Fe(5)O6 octahedra, corners with two equivalent Fe(8)O6 octahedra, corners with three equivalent Fe(9)O6 octahedra, and corners with four equivalent Fe(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 58-63°. There are ten inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to one O(16), one O(7), and two equivalent O(17) atoms to form FeO4 tetrahedra that share  a cornercorner with one Zn(2)O6 octahedra, corners with two equivalent Fe(2)O6 octahedra, corners with two equivalent Fe(8)O6 octahedra, corners with three equivalent Zn(1)O6 octahedra, and corners with four equivalent Fe(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-58°. In the second Fe site, Fe(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(6), and one O(7) atom to form FeO6 octahedra that share  a cornercorner with one Fe(1)O4 tetrahedra,  a cornercorner with one Fe(7)O4 tetrahedra, corners with two equivalent Fe(3)O4 tetrahedra, corners with two equivalent Fe(4)O4 tetrahedra,  an edgeedge with one Zn(1)O6 octahedra,  an edgeedge with one Zn(4)O6 octahedra, edges with two equivalent Fe(2)O6 octahedra, and edges with two equivalent Zn(2)O6 octahedra. In the third Fe site, Fe(3) is bonded to one O(18), one O(4), and two equivalent O(2) atoms to form FeO4 tetrahedra that share  a cornercorner with one Fe(8)O6 octahedra, corners with two equivalent Fe(6)O6 octahedra, corners with two equivalent Zn(2)O6 octahedra, corners with three equivalent Zn(1)O6 octahedra, and corners with four equivalent Fe(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-59°. In the fourth Fe site, Fe(4) is bonded to one O(5), one O(6), and two equivalent O(1) atoms to form FeO4 tetrahedra that share  a cornercorner with one Zn(3)O6 octahedra, corners with two equivalent Fe(5)O6 octahedra, corners with two equivalent Zn(2)O6 octahedra, corners with three equivalent Zn(4)O6 octahedra, and corners with four equivalent Fe(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-59°. In the fifth Fe site, Fe(5) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(8) atom to form FeO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Fe(4)O4 tetrahedra, corners with two equivalent Fe(10)O4 tetrahedra, corners with two equivalent Fe(7)O4 tetrahedra,  an edgeedge with one Fe(9)O6 octahedra,  an edgeedge with one Zn(4)O6 octahedra, edges with two equivalent Fe(5)O6 octahedra, and edges with two equivalent Zn(3)O6 octahedra. In the sixth Fe site, Fe(6) is bonded to one O(11), one O(14), one O(16), one O(17), one O(18), and one O(9) atom to form FeO6 octahedra that share  a cornercorner with one Fe(10)O4 tetrahedra,  a cornercorner with one Fe(3)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra, corners with two equivalent Fe(1)O4 tetrahedra,  an edgeedge with one Fe(9)O6 octahedra,  an edgeedge with one Zn(1)O6 octahedra, edges with two equivalent Fe(6)O6 octahedra, and edges with two equivalent Fe(8)O6 octahedra. In the seventh Fe site, Fe(7) is bonded to one O(12), one O(3), and two equivalent O(10) atoms to form FeO4 tetrahedra that share  a cornercorner with one Zn(2)O6 octahedra, corners with two equivalent Fe(2)O6 octahedra, corners with two equivalent Zn(3)O6 octahedra, corners with three equivalent Zn(4)O6 octahedra, and corners with four equivalent Fe(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-57°. In the eighth Fe site, Fe(8) is bonded to one O(14), one O(18), two equivalent O(17), and two equivalent O(9) atoms to form FeO6 octahedra that share  a cornercorner with one Fe(10)O4 tetrahedra,  a cornercorner with one Fe(3)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra, corners with two equivalent Fe(1)O4 tetrahedra,  an edgeedge with one Fe(9)O6 octahedra,  an edgeedge with one Zn(1)O6 octahedra, and edges with four equivalent Fe(6)O6 octahedra. In the ninth Fe site, Fe(9) is bonded to one O(11), one O(15), two equivalent O(8), and two equivalent O(9) atoms to form FeO6 octahedra that share corners with three equivalent Li(1)O4 tetrahedra, corners with three equivalent Fe(10)O4 tetrahedra,  an edgeedge with one Fe(8)O6 octahedra,  an edgeedge with one Zn(3)O6 octahedra, edges with two equivalent Fe(5)O6 octahedra, and edges with two equivalent Fe(6)O6 octahedra. In the tenth Fe site, Fe(10) is bonded to one O(14), one O(15), and two equivalent O(8) atoms to form FeO4 tetrahedra that share  a cornercorner with one Fe(8)O6 octahedra, corners with two equivalent Fe(6)O6 octahedra, corners with two equivalent Zn(3)O6 octahedra, corners with three equivalent Fe(9)O6 octahedra, and corners with four equivalent Fe(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-60°. There are four inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(16), one O(4), two equivalent O(17), and two equivalent O(2) atoms to form ZnO6 octahedra that share corners with three equivalent Fe(1)O4 tetrahedra, corners with three equivalent Fe(3)O4 tetrahedra,  an edgeedge with one Fe(8)O6 octahedra,  an edgeedge with one Zn(2)O6 octahedra, edges with two equivalent Fe(2)O6 octahedra, and edges with two equivalent Fe(6)O6 octahedra. In the second Zn site, Zn(2) is bonded to one O(3), one O(7), two equivalent O(1), and two equivalent O(2) atoms to form ZnO6 octahedra that share  a cornercorner with one Fe(1)O4 tetrahedra,  a cornercorner with one Fe(7)O4 tetrahedra, corners with two equivalent Fe(3)O4 tetrahedra, corners with two equivalent Fe(4)O4 tetrahedra,  an edgeedge with one Zn(1)O6 octahedra,  an edgeedge with one Zn(4)O6 octahedra, and edges with four equivalent Fe(2)O6 octahedra. In the third Zn site, Zn(3) is bonded to one O(13), one O(5), two equivalent O(10), and two equivalent O(8) atoms to form ZnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Fe(4)O4 tetrahedra, corners with two equivalent Fe(10)O4 tetrahedra, corners with two equivalent Fe(7)O4 tetrahedra,  an edgeedge with one Fe(9)O6 octahedra,  an edgeedge with one Zn(4)O6 octahedra, and edges with four equivalent Fe(5)O6 octahedra. In the fourth Zn site, Zn(4) is bonded to one O(12), one O(6), two equivalent O(1), and two equivalent O(10) atoms to form ZnO6 octahedra that share corners with three equivalent Fe(4)O4 tetrahedra, corners with three equivalent Fe(7)O4 tetrahedra,  an edgeedge with one Zn(2)O6 octahedra,  an edgeedge with one Zn(3)O6 octahedra, edges with two equivalent Fe(2)O6 octahedra, and edges with two equivalent Fe(5)O6 octahedra. There are eighteen inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Fe(2), one Fe(4), one Zn(2), and one Zn(4) atom. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one Fe(2), one Fe(3), one Zn(1), and one Zn(2) atom. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Fe(7), two equivalent Fe(2), and one Zn(2) atom. In the fourth O site, O(4) is bonded in a distorted rectangular see-saw-like geometry to one Fe(3), two equivalent Fe(2), and one Zn(1) atom. In the fifth O site, O(5) is bonded in a distorted rectangular see-saw-like geometry to one Fe(4), two equivalent Fe(5), and one Zn(3) atom. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Fe(4), two equivalent Fe(2), and one Zn(4) atom. In the seventh O site, O(7) is bonded in a rectangular see-saw-like geometry to one Fe(1), two equivalent Fe(2), and one Zn(2) atom. In the eighth O site, O(8) is bonded in a rectangular see-saw-like geometry to one Fe(10), one Fe(5), one Fe(9), and one Zn(3) atom. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Li(1), one Fe(6), one Fe(8), and one Fe(9) atom. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one Fe(5), one Fe(7), one Zn(3), and one Zn(4) atom. In the eleventh O site, O(11) is bonded to one Li(1), one Fe(9), and two equivalent Fe(6) atoms to form distorted corner-sharing OLiFe3 trigonal pyramids. In the twelfth O site, O(12) is bonded in a rectangular see-saw-like geometry to one Fe(7), two equivalent Fe(5), and one Zn(4) atom. In the thirteenth O site, O(13) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), two equivalent Fe(5), and one Zn(3) atom. In the fourteenth O site, O(14) is bonded to one Fe(10), one Fe(8), and two equivalent Fe(6) atoms to form distorted OFe4 trigonal pyramids that share  a cornercorner with one O(15)Fe4 trigonal pyramid and corners with two equivalent O(11)LiFe3 trigonal pyramids. In the fifteenth O site, O(15) is bonded to one Fe(10), one Fe(9), and two equivalent Fe(5) atoms to form distorted OFe4 trigonal pyramids that share  a cornercorner with one O(14)Fe4 trigonal pyramid and  a cornercorner with one O(11)LiFe3 trigonal pyramid. In the sixteenth O site, O(16) is bonded in a distorted rectangular see-saw-like geometry to one Fe(1), two equivalent Fe(6), and one Zn(1) atom. In the seventeenth O site, O(17) is bonded in a rectangular see-saw-like geometry to one Fe(1), one Fe(6), one Fe(8), and one Zn(1) atom. In the eighteenth O site, O(18) is bonded in a rectangular see-saw-like geometry to one Fe(3), one Fe(8), and two equivalent Fe(6) atoms. is represented by the CIF card [CIF]
data_LiZn4Fe13O24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.059
_cell_length_b   6.059
_cell_length_c   14.814
_cell_angle_alpha   89.743
_cell_angle_beta   89.743
_cell_angle_gamma   59.983
_symmetry_Int_Tables_number   1
_cell_volume   470.974
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.001  0.001  0.250  1.0
  Zn  Zn1  1  0.668  0.668  0.959  1.0
  Zn  Zn2  1  0.834  0.834  0.792  1.0
  Zn  Zn3  1  0.164  0.164  0.456  1.0
  Zn  Zn4  1  1.000  1.000  0.624  1.0
  Fe  Fe5  1  0.001  0.001  0.004  1.0
  Fe  Fe6  1  0.333  0.834  0.792  1.0
  Fe  Fe7  1  0.331  0.331  0.912  1.0
  Fe  Fe8  1  0.338  0.338  0.667  1.0
  Fe  Fe9  1  0.162  0.671  0.458  1.0
  Fe  Fe10  1  0.834  0.333  0.792  1.0
  Fe  Fe11  1  0.005  0.498  0.127  1.0
  Fe  Fe12  1  0.671  0.162  0.458  1.0
  Fe  Fe13  1  0.661  0.661  0.583  1.0
  Fe  Fe14  1  0.498  0.498  0.127  1.0
  Fe  Fe15  1  0.334  0.334  0.288  1.0
  Fe  Fe16  1  0.669  0.669  0.334  1.0
  Fe  Fe17  1  0.498  0.005  0.127  1.0
  O  O18  1  0.682  0.169  0.713  1.0
  O  O19  1  0.499  0.985  0.872  1.0
  O  O20  1  0.662  0.662  0.716  1.0
  O  O21  1  0.507  0.507  0.870  1.0
  O  O22  1  0.336  0.336  0.535  1.0
  O  O23  1  0.162  0.162  0.715  1.0
  O  O24  1  0.006  0.006  0.872  1.0
  O  O25  1  0.019  0.498  0.374  1.0
  O  O26  1  0.169  0.682  0.713  1.0
  O  O27  1  0.183  0.635  0.202  1.0
  O  O28  1  0.828  0.321  0.538  1.0
  O  O29  1  0.985  0.499  0.872  1.0
  O  O30  1  0.321  0.828  0.538  1.0
  O  O31  1  0.184  0.184  0.203  1.0
  O  O32  1  0.835  0.835  0.537  1.0
  O  O33  1  0.993  0.993  0.389  1.0
  O  O34  1  0.667  0.667  0.201  1.0
  O  O35  1  0.491  0.491  0.376  1.0
  O  O36  1  0.827  0.827  0.048  1.0
  O  O37  1  0.349  0.828  0.048  1.0
  O  O38  1  0.498  0.019  0.374  1.0
  O  O39  1  0.828  0.349  0.048  1.0
  O  O40  1  0.635  0.183  0.202  1.0
  O  O41  1  0.334  0.334  0.045  1.0
[/CIF]
.