The crystal structure described by Rb2V2Mn(O3Cl)2 crystallizes in the monoclinic Cm space group. Rb(1) is bonded in a 9-coordinate geometry to one O(1), one O(3), three equivalent O(2), two equivalent Cl(1), and two equivalent Cl(2) atoms. V(1) is bonded to one O(1), one O(2), and two equivalent O(3) atoms to form corner-sharing VO4 tetrahedra. Mn(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent Cl(1), and two equivalent Cl(2) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Rb(1), one V(1), and one Mn(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to three equivalent Rb(1) and one V(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Rb(1) and two equivalent V(1) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded to four equivalent Rb(1) and two equivalent Mn(1) atoms to form a mixture of distorted corner and edge-sharing ClRb4Mn2 octahedra. The corner-sharing octahedral tilt angles are 3°. In the second Cl site, Cl(2) is bonded in a 6-coordinate geometry to four equivalent Rb(1) and two equivalent Mn(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Rb2MnV2(ClO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.345
_cell_length_b   5.602
_cell_length_c   9.330
_cell_angle_alpha   107.463
_cell_angle_beta   90.401
_cell_angle_gamma   88.655
_symmetry_Int_Tables_number   1
_cell_volume   266.442
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cl  Cl0  1  0.618  0.548  0.000  1.0
  Cl  Cl1  1  0.084  0.019  0.000  1.0
  Mn  Mn2  1  0.605  0.998  0.000  1.0
  O  O3  1  0.557  0.946  0.773  1.0
  O  O4  1  0.557  0.173  0.227  1.0
  O  O5  1  0.970  0.768  0.596  1.0
  O  O6  1  0.970  0.172  0.404  1.0
  O  O7  1  0.549  0.457  0.546  1.0
  O  O8  1  0.549  0.911  0.454  1.0
  Rb  Rb9  1  0.149  0.348  0.746  1.0
  Rb  Rb10  1  0.149  0.602  0.254  1.0
  V  V11  1  0.661  0.776  0.599  1.0
  V  V12  1  0.661  0.178  0.401  1.0
[/CIF]
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The crystal structure described by Rb2V2Mn(O3Cl)2 crystallizes in the monoclinic Cm space group. Rb(1) is bonded in a 9-coordinate geometry to one O(1), one O(3), three equivalent O(2), two equivalent Cl(1), and two equivalent Cl(2) atoms. V(1) is bonded to one O(1), one O(2), and two equivalent O(3) atoms to form corner-sharing VO4 tetrahedra. Mn(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent Cl(1), and two equivalent Cl(2) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Rb(1), one V(1), and one Mn(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to three equivalent Rb(1) and one V(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Rb(1) and two equivalent V(1) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded to four equivalent Rb(1) and two equivalent Mn(1) atoms to form a mixture of distorted corner and edge-sharing ClRb4Mn2 octahedra. The corner-sharing octahedral tilt angles are 3°. In the second Cl site, Cl(2) is bonded in a 6-coordinate geometry to four equivalent Rb(1) and two equivalent Mn(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Rb2MnV2(ClO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.345
_cell_length_b   5.602
_cell_length_c   9.330
_cell_angle_alpha   107.463
_cell_angle_beta   90.401
_cell_angle_gamma   88.655
_symmetry_Int_Tables_number   1
_cell_volume   266.442
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cl  Cl0  1  0.618  0.548  0.000  1.0
  Cl  Cl1  1  0.084  0.019  0.000  1.0
  Mn  Mn2  1  0.605  0.998  0.000  1.0
  O  O3  1  0.557  0.946  0.773  1.0
  O  O4  1  0.557  0.173  0.227  1.0
  O  O5  1  0.970  0.768  0.596  1.0
  O  O6  1  0.970  0.172  0.404  1.0
  O  O7  1  0.549  0.457  0.546  1.0
  O  O8  1  0.549  0.911  0.454  1.0
  Rb  Rb9  1  0.149  0.348  0.746  1.0
  Rb  Rb10  1  0.149  0.602  0.254  1.0
  V  V11  1  0.661  0.776  0.599  1.0
  V  V12  1  0.661  0.178  0.401  1.0
[/CIF]
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