The structure described by Ce4ZrCo25 crystallizes in the monoclinic Pm space group. There are four inequivalent Ce sites. In the first Ce site, Ce(1) is bonded in a 18-coordinate geometry to one Co(2), one Co(6), two equivalent Co(1), two equivalent Co(16), two equivalent Co(17), two equivalent Co(21), two equivalent Co(22), two equivalent Co(7), and four equivalent Co(11) atoms. In the second Ce site, Ce(2) is bonded in a distorted hexagonal planar geometry to one Co(3), one Co(7), two equivalent Co(17), two equivalent Co(18), two equivalent Co(2), two equivalent Co(22), two equivalent Co(23), two equivalent Co(8), and four equivalent Co(12) atoms. In the third Ce site, Ce(3) is bonded in a distorted hexagonal planar geometry to one Co(4), one Co(8), two equivalent Co(18), two equivalent Co(19), two equivalent Co(23), two equivalent Co(24), two equivalent Co(3), two equivalent Co(9), and four equivalent Co(13) atoms. In the fourth Ce site, Ce(4) is bonded in a 18-coordinate geometry to one Co(5), one Co(9), two equivalent Co(10), two equivalent Co(19), two equivalent Co(20), two equivalent Co(24), two equivalent Co(25), two equivalent Co(4), and four equivalent Co(14) atoms. Zr(1) is bonded in a 18-coordinate geometry to one Co(1), one Co(10), two equivalent Co(16), two equivalent Co(20), two equivalent Co(21), two equivalent Co(25), two equivalent Co(5), two equivalent Co(6), and four equivalent Co(15) atoms. There are twenty-five inequivalent Co sites. In the first Co site, Co(1) is bonded in a 12-coordinate geometry to two equivalent Ce(1), one Zr(1), one Co(7), two equivalent Co(11), two equivalent Co(16), two equivalent Co(21), and two equivalent Co(6) atoms. In the second Co site, Co(2) is bonded in a 12-coordinate geometry to one Ce(1), two equivalent Ce(2), one Co(8), two equivalent Co(12), two equivalent Co(17), two equivalent Co(22), and two equivalent Co(7) atoms. In the third Co site, Co(3) is bonded in a 12-coordinate geometry to one Ce(2), two equivalent Ce(3), one Co(9), two equivalent Co(13), two equivalent Co(18), two equivalent Co(23), and two equivalent Co(8) atoms. In the fourth Co site, Co(4) is bonded in a 12-coordinate geometry to one Ce(3), two equivalent Ce(4), one Co(10), two equivalent Co(14), two equivalent Co(19), two equivalent Co(24), and two equivalent Co(9) atoms. In the fifth Co site, Co(5) is bonded in a 12-coordinate geometry to one Ce(4), two equivalent Zr(1), one Co(6), two equivalent Co(10), two equivalent Co(15), two equivalent Co(20), and two equivalent Co(25) atoms. In the sixth Co site, Co(6) is bonded in a 12-coordinate geometry to one Ce(1), two equivalent Zr(1), one Co(5), two equivalent Co(1), two equivalent Co(15), two equivalent Co(16), and two equivalent Co(21) atoms. In the seventh Co site, Co(7) is bonded in a 12-coordinate geometry to one Ce(2), two equivalent Ce(1), one Co(1), two equivalent Co(11), two equivalent Co(17), two equivalent Co(2), and two equivalent Co(22) atoms. In the eighth Co site, Co(8) is bonded in a 12-coordinate geometry to one Ce(3), two equivalent Ce(2), one Co(2), two equivalent Co(12), two equivalent Co(18), two equivalent Co(23), and two equivalent Co(3) atoms. In the ninth Co site, Co(9) is bonded in a 12-coordinate geometry to one Ce(4), two equivalent Ce(3), one Co(3), two equivalent Co(13), two equivalent Co(19), two equivalent Co(24), and two equivalent Co(4) atoms. In the tenth Co site, Co(10) is bonded in a 12-coordinate geometry to two equivalent Ce(4), one Zr(1), one Co(4), two equivalent Co(14), two equivalent Co(20), two equivalent Co(25), and two equivalent Co(5) atoms. In the eleventh Co site, Co(11) is bonded to four equivalent Ce(1), one Co(16), one Co(17), one Co(21), one Co(22), two equivalent Co(1), and two equivalent Co(7) atoms to form CoCe4Co8 cuboctahedra that share corners with two equivalent Co(16)Ce2Zr2Co8 cuboctahedra, corners with two equivalent Co(21)Ce2Zr2Co8 cuboctahedra, corners with two equivalent Co(12)Ce4Co8 cuboctahedra, corners with two equivalent Co(17)Ce4Co8 cuboctahedra, corners with two equivalent Co(22)Ce4Co8 cuboctahedra, corners with two equivalent Co(15)Zr4Co8 cuboctahedra, corners with four equivalent Co(11)Ce4Co8 cuboctahedra, edges with two equivalent Co(16)Ce2Zr2Co8 cuboctahedra, edges with two equivalent Co(21)Ce2Zr2Co8 cuboctahedra, edges with two equivalent Co(11)Ce4Co8 cuboctahedra, edges with two equivalent Co(17)Ce4Co8 cuboctahedra, edges with two equivalent Co(22)Ce4Co8 cuboctahedra, faces with two equivalent Co(16)Ce2Zr2Co8 cuboctahedra, faces with two equivalent Co(21)Ce2Zr2Co8 cuboctahedra, faces with two equivalent Co(11)Ce4Co8 cuboctahedra, faces with two equivalent Co(17)Ce4Co8 cuboctahedra, and faces with two equivalent Co(22)Ce4Co8 cuboctahedra. In the twelfth Co site, Co(12) is bonded to four equivalent Ce(2), one Co(17), one Co(18), one Co(22), one Co(23), two equivalent Co(2), and two equivalent Co(8) atoms to form a mixture of edge, face, and corner-sharing CoCe4Co8 cuboctahedra. In the thirteenth Co site, Co(13) is bonded to four equivalent Ce(3), one Co(18), one Co(19), one Co(23), one Co(24), two equivalent Co(3), and two equivalent Co(9) atoms to form a mixture of edge, face, and corner-sharing CoCe4Co8 cuboctahedra. In the fourteenth Co site, Co(14) is bonded to four equivalent Ce(4), one Co(19), one Co(20), one Co(24), one Co(25), two equivalent Co(10), and two equivalent Co(4) atoms to form CoCe4Co8 cuboctahedra that share corners with two equivalent Co(20)Ce2Zr2Co8 cuboctahedra, corners with two equivalent Co(25)Ce2Zr2Co8 cuboctahedra, corners with two equivalent Co(13)Ce4Co8 cuboctahedra, corners with two equivalent Co(19)Ce4Co8 cuboctahedra, corners with two equivalent Co(24)Ce4Co8 cuboctahedra, corners with two equivalent Co(15)Zr4Co8 cuboctahedra, corners with four equivalent Co(14)Ce4Co8 cuboctahedra, edges with two equivalent Co(20)Ce2Zr2Co8 cuboctahedra, edges with two equivalent Co(25)Ce2Zr2Co8 cuboctahedra, edges with two equivalent Co(14)Ce4Co8 cuboctahedra, edges with two equivalent Co(19)Ce4Co8 cuboctahedra, edges with two equivalent Co(24)Ce4Co8 cuboctahedra, faces with two equivalent Co(20)Ce2Zr2Co8 cuboctahedra, faces with two equivalent Co(25)Ce2Zr2Co8 cuboctahedra, faces with two equivalent Co(14)Ce4Co8 cuboctahedra, faces with two equivalent Co(19)Ce4Co8 cuboctahedra, and faces with two equivalent Co(24)Ce4Co8 cuboctahedra. In the fifteenth Co site, Co(15) is bonded to four equivalent Zr(1), one Co(16), one Co(20), one Co(21), one Co(25), two equivalent Co(5), and two equivalent Co(6) atoms to form CoZr4Co8 cuboctahedra that share corners with two equivalent Co(16)Ce2Zr2Co8 cuboctahedra, corners with two equivalent Co(20)Ce2Zr2Co8 cuboctahedra, corners with two equivalent Co(21)Ce2Zr2Co8 cuboctahedra, corners with two equivalent Co(25)Ce2Zr2Co8 cuboctahedra, corners with two equivalent Co(11)Ce4Co8 cuboctahedra, corners with two equivalent Co(14)Ce4Co8 cuboctahedra, corners with four equivalent Co(15)Zr4Co8 cuboctahedra, edges with two equivalent Co(16)Ce2Zr2Co8 cuboctahedra, edges with two equivalent Co(20)Ce2Zr2Co8 cuboctahedra, edges with two equivalent Co(21)Ce2Zr2Co8 cuboctahedra, edges with two equivalent Co(25)Ce2Zr2Co8 cuboctahedra, edges with two equivalent Co(15)Zr4Co8 cuboctahedra, faces with two equivalent Co(16)Ce2Zr2Co8 cuboctahedra, faces with two equivalent Co(20)Ce2Zr2Co8 cuboctahedra, faces with two equivalent Co(21)Ce2Zr2Co8 cuboctahedra, faces with two equivalent Co(25)Ce2Zr2Co8 cuboctahedra, and faces with two equivalent Co(15)Zr4Co8 cuboctahedra. In the sixteenth Co site, Co(16) is bonded to two equivalent Ce(1), two equivalent Zr(1), one Co(11), one Co(15), two equivalent Co(1), two equivalent Co(21), and two equivalent Co(6) atoms to form CoCe2Zr2Co8 cuboctahedra that share corners with two equivalent Co(16)Ce2Zr2Co8 cuboctahedra, corners with two equivalent Co(25)Ce2Zr2Co8 cuboctahedra, corners with two equivalent Co(11)Ce4Co8 cuboctahedra, corners with two equivalent Co(22)Ce4Co8 cuboctahedra, corners with two equivalent Co(15)Zr4Co8 cuboctahedra, corners with three equivalent Co(20)Ce2Zr2Co8 cuboctahedra, corners with three equivalent Co(17)Ce4Co8 cuboctahedra,  an edgeedge with one Co(20)Ce2Zr2Co8 cuboctahedra,  an edgeedge with one Co(17)Ce4Co8 cuboctahedra, edges with two equivalent Co(11)Ce4Co8 cuboctahedra, edges with two equivalent Co(15)Zr4Co8 cuboctahedra, edges with four equivalent Co(21)Ce2Zr2Co8 cuboctahedra,  a faceface with one Co(25)Ce2Zr2Co8 cuboctahedra,  a faceface with one Co(22)Ce4Co8 cuboctahedra, faces with two equivalent Co(16)Ce2Zr2Co8 cuboctahedra, faces with two equivalent Co(21)Ce2Zr2Co8 cuboctahedra, faces with two equivalent Co(11)Ce4Co8 cuboctahedra, and faces with two equivalent Co(15)Zr4Co8 cuboctahedra. In the seventeenth Co site, Co(17) is bonded to two equivalent Ce(1), two equivalent Ce(2), one Co(11), one Co(12), two equivalent Co(2), two equivalent Co(22), and two equivalent Co(7) atoms to form CoCe4Co8 cuboctahedra that share corners with two equivalent Co(21)Ce2Zr2Co8 cuboctahedra, corners with two equivalent Co(11)Ce4Co8 cuboctahedra, corners with two equivalent Co(12)Ce4Co8 cuboctahedra, corners with two equivalent Co(17)Ce4Co8 cuboctahedra, corners with two equivalent Co(23)Ce4Co8 cuboctahedra, corners with three equivalent Co(16)Ce2Zr2Co8 cuboctahedra, corners with three equivalent Co(18)Ce4Co8 cuboctahedra,  an edgeedge with one Co(16)Ce2Zr2Co8 cuboctahedra,  an edgeedge with one Co(18)Ce4Co8 cuboctahedra, edges with two equivalent Co(11)Ce4Co8 cuboctahedra, edges with two equivalent Co(12)Ce4Co8 cuboctahedra, edges with four equivalent Co(22)Ce4Co8 cuboctahedra,  a faceface with one Co(21)Ce2Zr2Co8 cuboctahedra,  a faceface with one Co(23)Ce4Co8 cuboctahedra, faces with two equivalent Co(11)Ce4Co8 cuboctahedra, faces with two equivalent Co(12)Ce4Co8 cuboctahedra, faces with two equivalent Co(17)Ce4Co8 cuboctahedra, and faces with two equivalent Co(22)Ce4Co8 cuboctahedra. In the eighteenth Co site, Co(18) is bonded to two equivalent Ce(2), two equivalent Ce(3), one Co(12), one Co(13), two equivalent Co(23), two equivalent Co(3), and two equivalent Co(8) atoms to form a mixture of edge, face, and corner-sharing CoCe4Co8 cuboctahedra. In the nineteenth Co site, Co(19) is bonded to two equivalent Ce(3), two equivalent Ce(4), one Co(13), one Co(14), two equivalent Co(24), two equivalent Co(4), and two equivalent Co(9) atoms to form CoCe4Co8 cuboctahedra that share corners with two equivalent Co(25)Ce2Zr2Co8 cuboctahedra, corners with two equivalent Co(13)Ce4Co8 cuboctahedra, corners with two equivalent Co(14)Ce4Co8 cuboctahedra, corners with two equivalent Co(19)Ce4Co8 cuboctahedra, corners with two equivalent Co(23)Ce4Co8 cuboctahedra, corners with three equivalent Co(20)Ce2Zr2Co8 cuboctahedra, corners with three equivalent Co(18)Ce4Co8 cuboctahedra,  an edgeedge with one Co(20)Ce2Zr2Co8 cuboctahedra,  an edgeedge with one Co(18)Ce4Co8 cuboctahedra, edges with two equivalent Co(13)Ce4Co8 cuboctahedra, edges with two equivalent Co(14)Ce4Co8 cuboctahedra, edges with four equivalent Co(24)Ce4Co8 cuboctahedra,  a faceface with one Co(25)Ce2Zr2Co8 cuboctahedra,  a faceface with one Co(23)Ce4Co8 cuboctahedra, faces with two equivalent Co(13)Ce4Co8 cuboctahedra, faces with two equivalent Co(14)Ce4Co8 cuboctahedra, faces with two equivalent Co(19)Ce4Co8 cuboctahedra, and faces with two equivalent Co(24)Ce4Co8 cuboctahedra. In the twentieth Co site, Co(20) is bonded to two equivalent Ce(4), two equivalent Zr(1), one Co(14), one Co(15), two equivalent Co(10), two equivalent Co(25), and two equivalent Co(5) atoms to form CoCe2Zr2Co8 cuboctahedra that share corners with two equivalent Co(20)Ce2Zr2Co8 cuboctahedra, corners with two equivalent Co(21)Ce2Zr2Co8 cuboctahedra, corners with two equivalent Co(14)Ce4Co8 cuboctahedra, corners with two equivalent Co(24)Ce4Co8 cuboctahedra, corners with two equivalent Co(15)Zr4Co8 cuboctahedra, corners with three equivalent Co(16)Ce2Zr2Co8 cuboctahedra, corners with three equivalent Co(19)Ce4Co8 cuboctahedra,  an edgeedge with one Co(16)Ce2Zr2Co8 cuboctahedra,  an edgeedge with one Co(19)Ce4Co8 cuboctahedra, edges with two equivalent Co(14)Ce4Co8 cuboctahedra, edges with two equivalent Co(15)Zr4Co8 cuboctahedra, edges with four equivalent Co(25)Ce2Zr2Co8 cuboctahedra,  a faceface with one Co(21)Ce2Zr2Co8 cuboctahedra,  a faceface with one Co(24)Ce4Co8 cuboctahedra, faces with two equivalent Co(20)Ce2Zr2Co8 cuboctahedra, faces with two equivalent Co(25)Ce2Zr2Co8 cuboctahedra, faces with two equivalent Co(14)Ce4Co8 cuboctahedra, and faces with two equivalent Co(15)Zr4Co8 cuboctahedra. In the twenty-first Co site, Co(21) is bonded to two equivalent Ce(1), two equivalent Zr(1), one Co(11), one Co(15), two equivalent Co(1), two equivalent Co(16), and two equivalent Co(6) atoms to form CoCe2Zr2Co8 cuboctahedra that share corners with two equivalent Co(20)Ce2Zr2Co8 cuboctahedra, corners with two equivalent Co(21)Ce2Zr2Co8 cuboctahedra, corners with two equivalent Co(11)Ce4Co8 cuboctahedra, corners with two equivalent Co(17)Ce4Co8 cuboctahedra, corners with two equivalent Co(15)Zr4Co8 cuboctahedra, corners with three equivalent Co(25)Ce2Zr2Co8 cuboctahedra, corners with three equivalent Co(22)Ce4Co8 cuboctahedra,  an edgeedge with one Co(25)Ce2Zr2Co8 cuboctahedra,  an edgeedge with one Co(22)Ce4Co8 cuboctahedra, edges with two equivalent Co(11)Ce4Co8 cuboctahedra, edges with two equivalent Co(15)Zr4Co8 cuboctahedra, edges with four equivalent Co(16)Ce2Zr2Co8 cuboctahedra,  a faceface with one Co(20)Ce2Zr2Co8 cuboctahedra,  a faceface with one Co(17)Ce4Co8 cuboctahedra, faces with two equivalent Co(16)Ce2Zr2Co8 cuboctahedra, faces with two equivalent Co(21)Ce2Zr2Co8 cuboctahedra, faces with two equivalent Co(11)Ce4Co8 cuboctahedra, and faces with two equivalent Co(15)Zr4Co8 cuboctahedra. In the twenty-second Co site, Co(22) is bonded to two equivalent Ce(1), two equivalent Ce(2), one Co(11), one Co(12), two equivalent Co(17), two equivalent Co(2), and two equivalent Co(7) atoms to form CoCe4Co8 cuboctahedra that share corners with two equivalent Co(16)Ce2Zr2Co8 cuboctahedra, corners with two equivalent Co(11)Ce4Co8 cuboctahedra, corners with two equivalent Co(12)Ce4Co8 cuboctahedra, corners with two equivalent Co(18)Ce4Co8 cuboctahedra, corners with two equivalent Co(22)Ce4Co8 cuboctahedra, corners with three equivalent Co(21)Ce2Zr2Co8 cuboctahedra, corners with three equivalent Co(23)Ce4Co8 cuboctahedra,  an edgeedge with one Co(21)Ce2Zr2Co8 cuboctahedra,  an edgeedge with one Co(23)Ce4Co8 cuboctahedra, edges with two equivalent Co(11)Ce4Co8 cuboctahedra, edges with two equivalent Co(12)Ce4Co8 cuboctahedra, edges with four equivalent Co(17)Ce4Co8 cuboctahedra,  a faceface with one Co(16)Ce2Zr2Co8 cuboctahedra,  a faceface with one Co(18)Ce4Co8 cuboctahedra, faces with two equivalent Co(11)Ce4Co8 cuboctahedra, faces with two equivalent Co(12)Ce4Co8 cuboctahedra, faces with two equivalent Co(17)Ce4Co8 cuboctahedra, and faces with two equivalent Co(22)Ce4Co8 cuboctahedra. In the twenty-third Co site, Co(23) is bonded to two equivalent Ce(2), two equivalent Ce(3), one Co(12), one Co(13), two equivalent Co(18), two equivalent Co(3), and two equivalent Co(8) atoms to form a mixture of edge, face, and corner-sharing CoCe4Co8 cuboctahedra. In the twenty-fourth Co site, Co(24) is bonded to two equivalent Ce(3), two equivalent Ce(4), one Co(13), one Co(14), two equivalent Co(19), two equivalent Co(4), and two equivalent Co(9) atoms to form CoCe4Co8 cuboctahedra that share corners with two equivalent Co(20)Ce2Zr2Co8 cuboctahedra, corners with two equivalent Co(13)Ce4Co8 cuboctahedra, corners with two equivalent Co(14)Ce4Co8 cuboctahedra, corners with two equivalent Co(18)Ce4Co8 cuboctahedra, corners with two equivalent Co(24)Ce4Co8 cuboctahedra, corners with three equivalent Co(25)Ce2Zr2Co8 cuboctahedra, corners with three equivalent Co(23)Ce4Co8 cuboctahedra,  an edgeedge with one Co(25)Ce2Zr2Co8 cuboctahedra,  an edgeedge with one Co(23)Ce4Co8 cuboctahedra, edges with two equivalent Co(13)Ce4Co8 cuboctahedra, edges with two equivalent Co(14)Ce4Co8 cuboctahedra, edges with four equivalent Co(19)Ce4Co8 cuboctahedra,  a faceface with one Co(20)Ce2Zr2Co8 cuboctahedra,  a faceface with one Co(18)Ce4Co8 cuboctahedra, faces with two equivalent Co(13)Ce4Co8 cuboctahedra, faces with two equivalent Co(14)Ce4Co8 cuboctahedra, faces with two equivalent Co(19)Ce4Co8 cuboctahedra, and faces with two equivalent Co(24)Ce4Co8 cuboctahedra. In the twenty-fifth Co site, Co(25) is bonded to two equivalent Ce(4), two equivalent Zr(1), one Co(14), one Co(15), two equivalent Co(10), two equivalent Co(20), and two equivalent Co(5) atoms to form CoCe2Zr2Co8 cuboctahedra that share corners with two equivalent Co(16)Ce2Zr2Co8 cuboctahedra, corners with two equivalent Co(25)Ce2Zr2Co8 cuboctahedra, corners with two equivalent Co(14)Ce4Co8 cuboctahedra, corners with two equivalent Co(19)Ce4Co8 cuboctahedra, corners with two equivalent Co(15)Zr4Co8 cuboctahedra, corners with three equivalent Co(21)Ce2Zr2Co8 cuboctahedra, corners with three equivalent Co(24)Ce4Co8 cuboctahedra,  an edgeedge with one Co(21)Ce2Zr2Co8 cuboctahedra,  an edgeedge with one Co(24)Ce4Co8 cuboctahedra, edges with two equivalent Co(14)Ce4Co8 cuboctahedra, edges with two equivalent Co(15)Zr4Co8 cuboctahedra, edges with four equivalent Co(20)Ce2Zr2Co8 cuboctahedra,  a faceface with one Co(16)Ce2Zr2Co8 cuboctahedra,  a faceface with one Co(19)Ce4Co8 cuboctahedra, faces with two equivalent Co(20)Ce2Zr2Co8 cuboctahedra, faces with two equivalent Co(25)Ce2Zr2Co8 cuboctahedra, faces with two equivalent Co(14)Ce4Co8 cuboctahedra, and faces with two equivalent Co(15)Zr4Co8 cuboctahedra. is represented by the CIF file [CIF]
data_Ce4ZrCo25
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.006
_cell_length_b   4.854
_cell_length_c   21.195
_cell_angle_alpha   96.434
_cell_angle_beta   89.997
_cell_angle_gamma   90.013
_symmetry_Int_Tables_number   1
_cell_volume   409.547
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  1.000  0.599  0.198  1.0
  Ce  Ce1  1  0.000  0.201  0.401  1.0
  Ce  Ce2  1  1.000  0.800  0.600  1.0
  Ce  Ce3  1  0.000  0.401  0.801  1.0
  Zr  Zr4  1  0.000  1.000  1.000  1.0
  Co  Co5  1  0.000  0.066  0.131  1.0
  Co  Co6  1  1.000  0.665  0.333  1.0
  Co  Co7  1  1.000  0.266  0.533  1.0
  Co  Co8  1  1.000  0.866  0.733  1.0
  Co  Co9  1  0.000  0.468  0.934  1.0
  Co  Co10  1  1.000  0.532  0.066  1.0
  Co  Co11  1  0.000  0.134  0.267  1.0
  Co  Co12  1  0.000  0.734  0.468  1.0
  Co  Co13  1  0.000  0.334  0.667  1.0
  Co  Co14  1  1.000  0.934  0.869  1.0
  Co  Co15  1  0.500  0.099  0.199  1.0
  Co  Co16  1  0.500  0.701  0.400  1.0
  Co  Co17  1  0.500  0.299  0.600  1.0
  Co  Co18  1  0.500  0.901  0.801  1.0
  Co  Co19  1  0.500  0.500  1.000  1.0
  Co  Co20  1  0.500  0.286  0.095  1.0
  Co  Co21  1  0.500  0.901  0.300  1.0
  Co  Co22  1  0.500  0.500  0.500  1.0
  Co  Co23  1  0.500  0.100  0.700  1.0
  Co  Co24  1  0.500  0.713  0.905  1.0
  Co  Co25  1  0.500  0.808  0.094  1.0
  Co  Co26  1  0.500  0.399  0.300  1.0
  Co  Co27  1  0.500  0.000  0.500  1.0
  Co  Co28  1  0.500  0.601  0.700  1.0
  Co  Co29  1  0.500  0.192  0.905  1.0
[/CIF]
.
The structure described by Ce4ZrCo25 crystallizes in the monoclinic Pm space group. There are four inequivalent Ce sites. In the first Ce site, Ce(1) is bonded in a 18-coordinate geometry to one Co(2), one Co(6), two equivalent Co(1), two equivalent Co(16), two equivalent Co(17), two equivalent Co(21), two equivalent Co(22), two equivalent Co(7), and four equivalent Co(11) atoms. In the second Ce site, Ce(2) is bonded in a distorted hexagonal planar geometry to one Co(3), one Co(7), two equivalent Co(17), two equivalent Co(18), two equivalent Co(2), two equivalent Co(22), two equivalent Co(23), two equivalent Co(8), and four equivalent Co(12) atoms. In the third Ce site, Ce(3) is bonded in a distorted hexagonal planar geometry to one Co(4), one Co(8), two equivalent Co(18), two equivalent Co(19), two equivalent Co(23), two equivalent Co(24), two equivalent Co(3), two equivalent Co(9), and four equivalent Co(13) atoms. In the fourth Ce site, Ce(4) is bonded in a 18-coordinate geometry to one Co(5), one Co(9), two equivalent Co(10), two equivalent Co(19), two equivalent Co(20), two equivalent Co(24), two equivalent Co(25), two equivalent Co(4), and four equivalent Co(14) atoms. Zr(1) is bonded in a 18-coordinate geometry to one Co(1), one Co(10), two equivalent Co(16), two equivalent Co(20), two equivalent Co(21), two equivalent Co(25), two equivalent Co(5), two equivalent Co(6), and four equivalent Co(15) atoms. There are twenty-five inequivalent Co sites. In the first Co site, Co(1) is bonded in a 12-coordinate geometry to two equivalent Ce(1), one Zr(1), one Co(7), two equivalent Co(11), two equivalent Co(16), two equivalent Co(21), and two equivalent Co(6) atoms. In the second Co site, Co(2) is bonded in a 12-coordinate geometry to one Ce(1), two equivalent Ce(2), one Co(8), two equivalent Co(12), two equivalent Co(17), two equivalent Co(22), and two equivalent Co(7) atoms. In the third Co site, Co(3) is bonded in a 12-coordinate geometry to one Ce(2), two equivalent Ce(3), one Co(9), two equivalent Co(13), two equivalent Co(18), two equivalent Co(23), and two equivalent Co(8) atoms. In the fourth Co site, Co(4) is bonded in a 12-coordinate geometry to one Ce(3), two equivalent Ce(4), one Co(10), two equivalent Co(14), two equivalent Co(19), two equivalent Co(24), and two equivalent Co(9) atoms. In the fifth Co site, Co(5) is bonded in a 12-coordinate geometry to one Ce(4), two equivalent Zr(1), one Co(6), two equivalent Co(10), two equivalent Co(15), two equivalent Co(20), and two equivalent Co(25) atoms. In the sixth Co site, Co(6) is bonded in a 12-coordinate geometry to one Ce(1), two equivalent Zr(1), one Co(5), two equivalent Co(1), two equivalent Co(15), two equivalent Co(16), and two equivalent Co(21) atoms. In the seventh Co site, Co(7) is bonded in a 12-coordinate geometry to one Ce(2), two equivalent Ce(1), one Co(1), two equivalent Co(11), two equivalent Co(17), two equivalent Co(2), and two equivalent Co(22) atoms. In the eighth Co site, Co(8) is bonded in a 12-coordinate geometry to one Ce(3), two equivalent Ce(2), one Co(2), two equivalent Co(12), two equivalent Co(18), two equivalent Co(23), and two equivalent Co(3) atoms. In the ninth Co site, Co(9) is bonded in a 12-coordinate geometry to one Ce(4), two equivalent Ce(3), one Co(3), two equivalent Co(13), two equivalent Co(19), two equivalent Co(24), and two equivalent Co(4) atoms. In the tenth Co site, Co(10) is bonded in a 12-coordinate geometry to two equivalent Ce(4), one Zr(1), one Co(4), two equivalent Co(14), two equivalent Co(20), two equivalent Co(25), and two equivalent Co(5) atoms. In the eleventh Co site, Co(11) is bonded to four equivalent Ce(1), one Co(16), one Co(17), one Co(21), one Co(22), two equivalent Co(1), and two equivalent Co(7) atoms to form CoCe4Co8 cuboctahedra that share corners with two equivalent Co(16)Ce2Zr2Co8 cuboctahedra, corners with two equivalent Co(21)Ce2Zr2Co8 cuboctahedra, corners with two equivalent Co(12)Ce4Co8 cuboctahedra, corners with two equivalent Co(17)Ce4Co8 cuboctahedra, corners with two equivalent Co(22)Ce4Co8 cuboctahedra, corners with two equivalent Co(15)Zr4Co8 cuboctahedra, corners with four equivalent Co(11)Ce4Co8 cuboctahedra, edges with two equivalent Co(16)Ce2Zr2Co8 cuboctahedra, edges with two equivalent Co(21)Ce2Zr2Co8 cuboctahedra, edges with two equivalent Co(11)Ce4Co8 cuboctahedra, edges with two equivalent Co(17)Ce4Co8 cuboctahedra, edges with two equivalent Co(22)Ce4Co8 cuboctahedra, faces with two equivalent Co(16)Ce2Zr2Co8 cuboctahedra, faces with two equivalent Co(21)Ce2Zr2Co8 cuboctahedra, faces with two equivalent Co(11)Ce4Co8 cuboctahedra, faces with two equivalent Co(17)Ce4Co8 cuboctahedra, and faces with two equivalent Co(22)Ce4Co8 cuboctahedra. In the twelfth Co site, Co(12) is bonded to four equivalent Ce(2), one Co(17), one Co(18), one Co(22), one Co(23), two equivalent Co(2), and two equivalent Co(8) atoms to form a mixture of edge, face, and corner-sharing CoCe4Co8 cuboctahedra. In the thirteenth Co site, Co(13) is bonded to four equivalent Ce(3), one Co(18), one Co(19), one Co(23), one Co(24), two equivalent Co(3), and two equivalent Co(9) atoms to form a mixture of edge, face, and corner-sharing CoCe4Co8 cuboctahedra. In the fourteenth Co site, Co(14) is bonded to four equivalent Ce(4), one Co(19), one Co(20), one Co(24), one Co(25), two equivalent Co(10), and two equivalent Co(4) atoms to form CoCe4Co8 cuboctahedra that share corners with two equivalent Co(20)Ce2Zr2Co8 cuboctahedra, corners with two equivalent Co(25)Ce2Zr2Co8 cuboctahedra, corners with two equivalent Co(13)Ce4Co8 cuboctahedra, corners with two equivalent Co(19)Ce4Co8 cuboctahedra, corners with two equivalent Co(24)Ce4Co8 cuboctahedra, corners with two equivalent Co(15)Zr4Co8 cuboctahedra, corners with four equivalent Co(14)Ce4Co8 cuboctahedra, edges with two equivalent Co(20)Ce2Zr2Co8 cuboctahedra, edges with two equivalent Co(25)Ce2Zr2Co8 cuboctahedra, edges with two equivalent Co(14)Ce4Co8 cuboctahedra, edges with two equivalent Co(19)Ce4Co8 cuboctahedra, edges with two equivalent Co(24)Ce4Co8 cuboctahedra, faces with two equivalent Co(20)Ce2Zr2Co8 cuboctahedra, faces with two equivalent Co(25)Ce2Zr2Co8 cuboctahedra, faces with two equivalent Co(14)Ce4Co8 cuboctahedra, faces with two equivalent Co(19)Ce4Co8 cuboctahedra, and faces with two equivalent Co(24)Ce4Co8 cuboctahedra. In the fifteenth Co site, Co(15) is bonded to four equivalent Zr(1), one Co(16), one Co(20), one Co(21), one Co(25), two equivalent Co(5), and two equivalent Co(6) atoms to form CoZr4Co8 cuboctahedra that share corners with two equivalent Co(16)Ce2Zr2Co8 cuboctahedra, corners with two equivalent Co(20)Ce2Zr2Co8 cuboctahedra, corners with two equivalent Co(21)Ce2Zr2Co8 cuboctahedra, corners with two equivalent Co(25)Ce2Zr2Co8 cuboctahedra, corners with two equivalent Co(11)Ce4Co8 cuboctahedra, corners with two equivalent Co(14)Ce4Co8 cuboctahedra, corners with four equivalent Co(15)Zr4Co8 cuboctahedra, edges with two equivalent Co(16)Ce2Zr2Co8 cuboctahedra, edges with two equivalent Co(20)Ce2Zr2Co8 cuboctahedra, edges with two equivalent Co(21)Ce2Zr2Co8 cuboctahedra, edges with two equivalent Co(25)Ce2Zr2Co8 cuboctahedra, edges with two equivalent Co(15)Zr4Co8 cuboctahedra, faces with two equivalent Co(16)Ce2Zr2Co8 cuboctahedra, faces with two equivalent Co(20)Ce2Zr2Co8 cuboctahedra, faces with two equivalent Co(21)Ce2Zr2Co8 cuboctahedra, faces with two equivalent Co(25)Ce2Zr2Co8 cuboctahedra, and faces with two equivalent Co(15)Zr4Co8 cuboctahedra. In the sixteenth Co site, Co(16) is bonded to two equivalent Ce(1), two equivalent Zr(1), one Co(11), one Co(15), two equivalent Co(1), two equivalent Co(21), and two equivalent Co(6) atoms to form CoCe2Zr2Co8 cuboctahedra that share corners with two equivalent Co(16)Ce2Zr2Co8 cuboctahedra, corners with two equivalent Co(25)Ce2Zr2Co8 cuboctahedra, corners with two equivalent Co(11)Ce4Co8 cuboctahedra, corners with two equivalent Co(22)Ce4Co8 cuboctahedra, corners with two equivalent Co(15)Zr4Co8 cuboctahedra, corners with three equivalent Co(20)Ce2Zr2Co8 cuboctahedra, corners with three equivalent Co(17)Ce4Co8 cuboctahedra,  an edgeedge with one Co(20)Ce2Zr2Co8 cuboctahedra,  an edgeedge with one Co(17)Ce4Co8 cuboctahedra, edges with two equivalent Co(11)Ce4Co8 cuboctahedra, edges with two equivalent Co(15)Zr4Co8 cuboctahedra, edges with four equivalent Co(21)Ce2Zr2Co8 cuboctahedra,  a faceface with one Co(25)Ce2Zr2Co8 cuboctahedra,  a faceface with one Co(22)Ce4Co8 cuboctahedra, faces with two equivalent Co(16)Ce2Zr2Co8 cuboctahedra, faces with two equivalent Co(21)Ce2Zr2Co8 cuboctahedra, faces with two equivalent Co(11)Ce4Co8 cuboctahedra, and faces with two equivalent Co(15)Zr4Co8 cuboctahedra. In the seventeenth Co site, Co(17) is bonded to two equivalent Ce(1), two equivalent Ce(2), one Co(11), one Co(12), two equivalent Co(2), two equivalent Co(22), and two equivalent Co(7) atoms to form CoCe4Co8 cuboctahedra that share corners with two equivalent Co(21)Ce2Zr2Co8 cuboctahedra, corners with two equivalent Co(11)Ce4Co8 cuboctahedra, corners with two equivalent Co(12)Ce4Co8 cuboctahedra, corners with two equivalent Co(17)Ce4Co8 cuboctahedra, corners with two equivalent Co(23)Ce4Co8 cuboctahedra, corners with three equivalent Co(16)Ce2Zr2Co8 cuboctahedra, corners with three equivalent Co(18)Ce4Co8 cuboctahedra,  an edgeedge with one Co(16)Ce2Zr2Co8 cuboctahedra,  an edgeedge with one Co(18)Ce4Co8 cuboctahedra, edges with two equivalent Co(11)Ce4Co8 cuboctahedra, edges with two equivalent Co(12)Ce4Co8 cuboctahedra, edges with four equivalent Co(22)Ce4Co8 cuboctahedra,  a faceface with one Co(21)Ce2Zr2Co8 cuboctahedra,  a faceface with one Co(23)Ce4Co8 cuboctahedra, faces with two equivalent Co(11)Ce4Co8 cuboctahedra, faces with two equivalent Co(12)Ce4Co8 cuboctahedra, faces with two equivalent Co(17)Ce4Co8 cuboctahedra, and faces with two equivalent Co(22)Ce4Co8 cuboctahedra. In the eighteenth Co site, Co(18) is bonded to two equivalent Ce(2), two equivalent Ce(3), one Co(12), one Co(13), two equivalent Co(23), two equivalent Co(3), and two equivalent Co(8) atoms to form a mixture of edge, face, and corner-sharing CoCe4Co8 cuboctahedra. In the nineteenth Co site, Co(19) is bonded to two equivalent Ce(3), two equivalent Ce(4), one Co(13), one Co(14), two equivalent Co(24), two equivalent Co(4), and two equivalent Co(9) atoms to form CoCe4Co8 cuboctahedra that share corners with two equivalent Co(25)Ce2Zr2Co8 cuboctahedra, corners with two equivalent Co(13)Ce4Co8 cuboctahedra, corners with two equivalent Co(14)Ce4Co8 cuboctahedra, corners with two equivalent Co(19)Ce4Co8 cuboctahedra, corners with two equivalent Co(23)Ce4Co8 cuboctahedra, corners with three equivalent Co(20)Ce2Zr2Co8 cuboctahedra, corners with three equivalent Co(18)Ce4Co8 cuboctahedra,  an edgeedge with one Co(20)Ce2Zr2Co8 cuboctahedra,  an edgeedge with one Co(18)Ce4Co8 cuboctahedra, edges with two equivalent Co(13)Ce4Co8 cuboctahedra, edges with two equivalent Co(14)Ce4Co8 cuboctahedra, edges with four equivalent Co(24)Ce4Co8 cuboctahedra,  a faceface with one Co(25)Ce2Zr2Co8 cuboctahedra,  a faceface with one Co(23)Ce4Co8 cuboctahedra, faces with two equivalent Co(13)Ce4Co8 cuboctahedra, faces with two equivalent Co(14)Ce4Co8 cuboctahedra, faces with two equivalent Co(19)Ce4Co8 cuboctahedra, and faces with two equivalent Co(24)Ce4Co8 cuboctahedra. In the twentieth Co site, Co(20) is bonded to two equivalent Ce(4), two equivalent Zr(1), one Co(14), one Co(15), two equivalent Co(10), two equivalent Co(25), and two equivalent Co(5) atoms to form CoCe2Zr2Co8 cuboctahedra that share corners with two equivalent Co(20)Ce2Zr2Co8 cuboctahedra, corners with two equivalent Co(21)Ce2Zr2Co8 cuboctahedra, corners with two equivalent Co(14)Ce4Co8 cuboctahedra, corners with two equivalent Co(24)Ce4Co8 cuboctahedra, corners with two equivalent Co(15)Zr4Co8 cuboctahedra, corners with three equivalent Co(16)Ce2Zr2Co8 cuboctahedra, corners with three equivalent Co(19)Ce4Co8 cuboctahedra,  an edgeedge with one Co(16)Ce2Zr2Co8 cuboctahedra,  an edgeedge with one Co(19)Ce4Co8 cuboctahedra, edges with two equivalent Co(14)Ce4Co8 cuboctahedra, edges with two equivalent Co(15)Zr4Co8 cuboctahedra, edges with four equivalent Co(25)Ce2Zr2Co8 cuboctahedra,  a faceface with one Co(21)Ce2Zr2Co8 cuboctahedra,  a faceface with one Co(24)Ce4Co8 cuboctahedra, faces with two equivalent Co(20)Ce2Zr2Co8 cuboctahedra, faces with two equivalent Co(25)Ce2Zr2Co8 cuboctahedra, faces with two equivalent Co(14)Ce4Co8 cuboctahedra, and faces with two equivalent Co(15)Zr4Co8 cuboctahedra. In the twenty-first Co site, Co(21) is bonded to two equivalent Ce(1), two equivalent Zr(1), one Co(11), one Co(15), two equivalent Co(1), two equivalent Co(16), and two equivalent Co(6) atoms to form CoCe2Zr2Co8 cuboctahedra that share corners with two equivalent Co(20)Ce2Zr2Co8 cuboctahedra, corners with two equivalent Co(21)Ce2Zr2Co8 cuboctahedra, corners with two equivalent Co(11)Ce4Co8 cuboctahedra, corners with two equivalent Co(17)Ce4Co8 cuboctahedra, corners with two equivalent Co(15)Zr4Co8 cuboctahedra, corners with three equivalent Co(25)Ce2Zr2Co8 cuboctahedra, corners with three equivalent Co(22)Ce4Co8 cuboctahedra,  an edgeedge with one Co(25)Ce2Zr2Co8 cuboctahedra,  an edgeedge with one Co(22)Ce4Co8 cuboctahedra, edges with two equivalent Co(11)Ce4Co8 cuboctahedra, edges with two equivalent Co(15)Zr4Co8 cuboctahedra, edges with four equivalent Co(16)Ce2Zr2Co8 cuboctahedra,  a faceface with one Co(20)Ce2Zr2Co8 cuboctahedra,  a faceface with one Co(17)Ce4Co8 cuboctahedra, faces with two equivalent Co(16)Ce2Zr2Co8 cuboctahedra, faces with two equivalent Co(21)Ce2Zr2Co8 cuboctahedra, faces with two equivalent Co(11)Ce4Co8 cuboctahedra, and faces with two equivalent Co(15)Zr4Co8 cuboctahedra. In the twenty-second Co site, Co(22) is bonded to two equivalent Ce(1), two equivalent Ce(2), one Co(11), one Co(12), two equivalent Co(17), two equivalent Co(2), and two equivalent Co(7) atoms to form CoCe4Co8 cuboctahedra that share corners with two equivalent Co(16)Ce2Zr2Co8 cuboctahedra, corners with two equivalent Co(11)Ce4Co8 cuboctahedra, corners with two equivalent Co(12)Ce4Co8 cuboctahedra, corners with two equivalent Co(18)Ce4Co8 cuboctahedra, corners with two equivalent Co(22)Ce4Co8 cuboctahedra, corners with three equivalent Co(21)Ce2Zr2Co8 cuboctahedra, corners with three equivalent Co(23)Ce4Co8 cuboctahedra,  an edgeedge with one Co(21)Ce2Zr2Co8 cuboctahedra,  an edgeedge with one Co(23)Ce4Co8 cuboctahedra, edges with two equivalent Co(11)Ce4Co8 cuboctahedra, edges with two equivalent Co(12)Ce4Co8 cuboctahedra, edges with four equivalent Co(17)Ce4Co8 cuboctahedra,  a faceface with one Co(16)Ce2Zr2Co8 cuboctahedra,  a faceface with one Co(18)Ce4Co8 cuboctahedra, faces with two equivalent Co(11)Ce4Co8 cuboctahedra, faces with two equivalent Co(12)Ce4Co8 cuboctahedra, faces with two equivalent Co(17)Ce4Co8 cuboctahedra, and faces with two equivalent Co(22)Ce4Co8 cuboctahedra. In the twenty-third Co site, Co(23) is bonded to two equivalent Ce(2), two equivalent Ce(3), one Co(12), one Co(13), two equivalent Co(18), two equivalent Co(3), and two equivalent Co(8) atoms to form a mixture of edge, face, and corner-sharing CoCe4Co8 cuboctahedra. In the twenty-fourth Co site, Co(24) is bonded to two equivalent Ce(3), two equivalent Ce(4), one Co(13), one Co(14), two equivalent Co(19), two equivalent Co(4), and two equivalent Co(9) atoms to form CoCe4Co8 cuboctahedra that share corners with two equivalent Co(20)Ce2Zr2Co8 cuboctahedra, corners with two equivalent Co(13)Ce4Co8 cuboctahedra, corners with two equivalent Co(14)Ce4Co8 cuboctahedra, corners with two equivalent Co(18)Ce4Co8 cuboctahedra, corners with two equivalent Co(24)Ce4Co8 cuboctahedra, corners with three equivalent Co(25)Ce2Zr2Co8 cuboctahedra, corners with three equivalent Co(23)Ce4Co8 cuboctahedra,  an edgeedge with one Co(25)Ce2Zr2Co8 cuboctahedra,  an edgeedge with one Co(23)Ce4Co8 cuboctahedra, edges with two equivalent Co(13)Ce4Co8 cuboctahedra, edges with two equivalent Co(14)Ce4Co8 cuboctahedra, edges with four equivalent Co(19)Ce4Co8 cuboctahedra,  a faceface with one Co(20)Ce2Zr2Co8 cuboctahedra,  a faceface with one Co(18)Ce4Co8 cuboctahedra, faces with two equivalent Co(13)Ce4Co8 cuboctahedra, faces with two equivalent Co(14)Ce4Co8 cuboctahedra, faces with two equivalent Co(19)Ce4Co8 cuboctahedra, and faces with two equivalent Co(24)Ce4Co8 cuboctahedra. In the twenty-fifth Co site, Co(25) is bonded to two equivalent Ce(4), two equivalent Zr(1), one Co(14), one Co(15), two equivalent Co(10), two equivalent Co(20), and two equivalent Co(5) atoms to form CoCe2Zr2Co8 cuboctahedra that share corners with two equivalent Co(16)Ce2Zr2Co8 cuboctahedra, corners with two equivalent Co(25)Ce2Zr2Co8 cuboctahedra, corners with two equivalent Co(14)Ce4Co8 cuboctahedra, corners with two equivalent Co(19)Ce4Co8 cuboctahedra, corners with two equivalent Co(15)Zr4Co8 cuboctahedra, corners with three equivalent Co(21)Ce2Zr2Co8 cuboctahedra, corners with three equivalent Co(24)Ce4Co8 cuboctahedra,  an edgeedge with one Co(21)Ce2Zr2Co8 cuboctahedra,  an edgeedge with one Co(24)Ce4Co8 cuboctahedra, edges with two equivalent Co(14)Ce4Co8 cuboctahedra, edges with two equivalent Co(15)Zr4Co8 cuboctahedra, edges with four equivalent Co(20)Ce2Zr2Co8 cuboctahedra,  a faceface with one Co(16)Ce2Zr2Co8 cuboctahedra,  a faceface with one Co(19)Ce4Co8 cuboctahedra, faces with two equivalent Co(20)Ce2Zr2Co8 cuboctahedra, faces with two equivalent Co(25)Ce2Zr2Co8 cuboctahedra, faces with two equivalent Co(14)Ce4Co8 cuboctahedra, and faces with two equivalent Co(15)Zr4Co8 cuboctahedra. is represented by the CIF file [CIF]
data_Ce4ZrCo25
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.006
_cell_length_b   4.854
_cell_length_c   21.195
_cell_angle_alpha   96.434
_cell_angle_beta   89.997
_cell_angle_gamma   90.013
_symmetry_Int_Tables_number   1
_cell_volume   409.547
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  1.000  0.599  0.198  1.0
  Ce  Ce1  1  0.000  0.201  0.401  1.0
  Ce  Ce2  1  1.000  0.800  0.600  1.0
  Ce  Ce3  1  0.000  0.401  0.801  1.0
  Zr  Zr4  1  0.000  1.000  1.000  1.0
  Co  Co5  1  0.000  0.066  0.131  1.0
  Co  Co6  1  1.000  0.665  0.333  1.0
  Co  Co7  1  1.000  0.266  0.533  1.0
  Co  Co8  1  1.000  0.866  0.733  1.0
  Co  Co9  1  0.000  0.468  0.934  1.0
  Co  Co10  1  1.000  0.532  0.066  1.0
  Co  Co11  1  0.000  0.134  0.267  1.0
  Co  Co12  1  0.000  0.734  0.468  1.0
  Co  Co13  1  0.000  0.334  0.667  1.0
  Co  Co14  1  1.000  0.934  0.869  1.0
  Co  Co15  1  0.500  0.099  0.199  1.0
  Co  Co16  1  0.500  0.701  0.400  1.0
  Co  Co17  1  0.500  0.299  0.600  1.0
  Co  Co18  1  0.500  0.901  0.801  1.0
  Co  Co19  1  0.500  0.500  1.000  1.0
  Co  Co20  1  0.500  0.286  0.095  1.0
  Co  Co21  1  0.500  0.901  0.300  1.0
  Co  Co22  1  0.500  0.500  0.500  1.0
  Co  Co23  1  0.500  0.100  0.700  1.0
  Co  Co24  1  0.500  0.713  0.905  1.0
  Co  Co25  1  0.500  0.808  0.094  1.0
  Co  Co26  1  0.500  0.399  0.300  1.0
  Co  Co27  1  0.500  0.000  0.500  1.0
  Co  Co28  1  0.500  0.601  0.700  1.0
  Co  Co29  1  0.500  0.192  0.905  1.0
[/CIF]
.