The material structure described by YWFe6Co5 crystallizes in the orthorhombic Imm2 space group. Y(1) is bonded in a 20-coordinate geometry to one W(1), two equivalent Fe(2), two equivalent Fe(3), eight equivalent Fe(1), one Co(2), two equivalent Co(1), and four equivalent Co(3) atoms. W(1) is bonded in a 14-coordinate geometry to one Y(1), two equivalent Fe(2), four equivalent Fe(1), one Co(2), two equivalent Co(3), and four equivalent Co(1) atoms. There are three inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to two equivalent Y(1), one W(1), one Fe(2), one Fe(3), two equivalent Fe(1), one Co(2), two equivalent Co(1), and two equivalent Co(3) atoms to form distorted FeY2Fe4Co5W cuboctahedra that share corners with two equivalent Fe(2)Y2Fe4Co4W2 cuboctahedra, corners with two equivalent Fe(3)Y2Fe4Co6 cuboctahedra, corners with ten equivalent Fe(1)Y2Fe4Co5W cuboctahedra,  an edgeedge with one Fe(2)Y2Fe4Co4W2 cuboctahedra,  an edgeedge with one Fe(3)Y2Fe4Co6 cuboctahedra, edges with four equivalent Fe(1)Y2Fe4Co5W cuboctahedra, faces with two equivalent Fe(2)Y2Fe4Co4W2 cuboctahedra, faces with two equivalent Fe(3)Y2Fe4Co6 cuboctahedra, and faces with six equivalent Fe(1)Y2Fe4Co5W cuboctahedra. In the second Fe site, Fe(2) is bonded to two equivalent Y(1), two equivalent W(1), four equivalent Fe(1), two equivalent Co(1), and two equivalent Co(3) atoms to form distorted FeY2Fe4Co4W2 cuboctahedra that share corners with six equivalent Fe(3)Y2Fe4Co6 cuboctahedra, corners with eight equivalent Fe(1)Y2Fe4Co5W cuboctahedra,  an edgeedge with one Fe(3)Y2Fe4Co6 cuboctahedra, edges with two equivalent Fe(2)Y2Fe4Co4W2 cuboctahedra, edges with four equivalent Fe(1)Y2Fe4Co5W cuboctahedra,  a faceface with one Fe(3)Y2Fe4Co6 cuboctahedra, and faces with eight equivalent Fe(1)Y2Fe4Co5W cuboctahedra. In the third Fe site, Fe(3) is bonded to two equivalent Y(1), four equivalent Fe(1), two equivalent Co(1), two equivalent Co(2), and two equivalent Co(3) atoms to form FeY2Fe4Co6 cuboctahedra that share corners with six equivalent Fe(2)Y2Fe4Co4W2 cuboctahedra, corners with eight equivalent Fe(1)Y2Fe4Co5W cuboctahedra,  an edgeedge with one Fe(2)Y2Fe4Co4W2 cuboctahedra, edges with two equivalent Fe(3)Y2Fe4Co6 cuboctahedra, edges with four equivalent Fe(1)Y2Fe4Co5W cuboctahedra,  a faceface with one Fe(2)Y2Fe4Co4W2 cuboctahedra, and faces with eight equivalent Fe(1)Y2Fe4Co5W cuboctahedra. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded in a 14-coordinate geometry to one Y(1), two equivalent W(1), one Fe(2), one Fe(3), four equivalent Fe(1), one Co(1), two equivalent Co(2), and two equivalent Co(3) atoms. In the second Co site, Co(2) is bonded in a distorted single-bond geometry to one Y(1), one W(1), two equivalent Fe(3), four equivalent Fe(1), two equivalent Co(3), and four equivalent Co(1) atoms. In the third Co site, Co(3) is bonded in a 12-coordinate geometry to two equivalent Y(1), one W(1), one Fe(2), one Fe(3), four equivalent Fe(1), one Co(2), and two equivalent Co(1) atoms. is represented by the CIF card [CIF]
data_YFe6Co5W
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.706
_cell_length_b   6.414
_cell_length_c   6.414
_cell_angle_alpha   97.640
_cell_angle_beta   111.520
_cell_angle_gamma   68.480
_symmetry_Int_Tables_number   1
_cell_volume   167.563
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  1  0.000  0.004  0.004  1.0
  Fe  Fe1  1  0.498  0.004  0.502  1.0
  Fe  Fe2  1  0.000  0.004  0.502  1.0
  Fe  Fe3  1  0.502  0.502  0.004  1.0
  Fe  Fe4  1  1.000  0.502  0.004  1.0
  Fe  Fe5  1  0.500  0.774  0.774  1.0
  Fe  Fe6  1  0.500  0.231  0.231  1.0
  Co  Co7  1  0.640  0.361  0.641  1.0
  Co  Co8  1  0.360  0.641  0.361  1.0
  Co  Co9  1  0.000  0.351  0.351  1.0
  Co  Co10  1  0.723  0.776  0.222  1.0
  Co  Co11  1  0.277  0.222  0.776  1.0
  W  W12  1  0.000  0.630  0.630  1.0
[/CIF]
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The material structure described by YWFe6Co5 crystallizes in the orthorhombic Imm2 space group. Y(1) is bonded in a 20-coordinate geometry to one W(1), two equivalent Fe(2), two equivalent Fe(3), eight equivalent Fe(1), one Co(2), two equivalent Co(1), and four equivalent Co(3) atoms. W(1) is bonded in a 14-coordinate geometry to one Y(1), two equivalent Fe(2), four equivalent Fe(1), one Co(2), two equivalent Co(3), and four equivalent Co(1) atoms. There are three inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to two equivalent Y(1), one W(1), one Fe(2), one Fe(3), two equivalent Fe(1), one Co(2), two equivalent Co(1), and two equivalent Co(3) atoms to form distorted FeY2Fe4Co5W cuboctahedra that share corners with two equivalent Fe(2)Y2Fe4Co4W2 cuboctahedra, corners with two equivalent Fe(3)Y2Fe4Co6 cuboctahedra, corners with ten equivalent Fe(1)Y2Fe4Co5W cuboctahedra,  an edgeedge with one Fe(2)Y2Fe4Co4W2 cuboctahedra,  an edgeedge with one Fe(3)Y2Fe4Co6 cuboctahedra, edges with four equivalent Fe(1)Y2Fe4Co5W cuboctahedra, faces with two equivalent Fe(2)Y2Fe4Co4W2 cuboctahedra, faces with two equivalent Fe(3)Y2Fe4Co6 cuboctahedra, and faces with six equivalent Fe(1)Y2Fe4Co5W cuboctahedra. In the second Fe site, Fe(2) is bonded to two equivalent Y(1), two equivalent W(1), four equivalent Fe(1), two equivalent Co(1), and two equivalent Co(3) atoms to form distorted FeY2Fe4Co4W2 cuboctahedra that share corners with six equivalent Fe(3)Y2Fe4Co6 cuboctahedra, corners with eight equivalent Fe(1)Y2Fe4Co5W cuboctahedra,  an edgeedge with one Fe(3)Y2Fe4Co6 cuboctahedra, edges with two equivalent Fe(2)Y2Fe4Co4W2 cuboctahedra, edges with four equivalent Fe(1)Y2Fe4Co5W cuboctahedra,  a faceface with one Fe(3)Y2Fe4Co6 cuboctahedra, and faces with eight equivalent Fe(1)Y2Fe4Co5W cuboctahedra. In the third Fe site, Fe(3) is bonded to two equivalent Y(1), four equivalent Fe(1), two equivalent Co(1), two equivalent Co(2), and two equivalent Co(3) atoms to form FeY2Fe4Co6 cuboctahedra that share corners with six equivalent Fe(2)Y2Fe4Co4W2 cuboctahedra, corners with eight equivalent Fe(1)Y2Fe4Co5W cuboctahedra,  an edgeedge with one Fe(2)Y2Fe4Co4W2 cuboctahedra, edges with two equivalent Fe(3)Y2Fe4Co6 cuboctahedra, edges with four equivalent Fe(1)Y2Fe4Co5W cuboctahedra,  a faceface with one Fe(2)Y2Fe4Co4W2 cuboctahedra, and faces with eight equivalent Fe(1)Y2Fe4Co5W cuboctahedra. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded in a 14-coordinate geometry to one Y(1), two equivalent W(1), one Fe(2), one Fe(3), four equivalent Fe(1), one Co(1), two equivalent Co(2), and two equivalent Co(3) atoms. In the second Co site, Co(2) is bonded in a distorted single-bond geometry to one Y(1), one W(1), two equivalent Fe(3), four equivalent Fe(1), two equivalent Co(3), and four equivalent Co(1) atoms. In the third Co site, Co(3) is bonded in a 12-coordinate geometry to two equivalent Y(1), one W(1), one Fe(2), one Fe(3), four equivalent Fe(1), one Co(2), and two equivalent Co(1) atoms. is represented by the CIF card [CIF]
data_YFe6Co5W
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.706
_cell_length_b   6.414
_cell_length_c   6.414
_cell_angle_alpha   97.640
_cell_angle_beta   111.520
_cell_angle_gamma   68.480
_symmetry_Int_Tables_number   1
_cell_volume   167.563
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  1  0.000  0.004  0.004  1.0
  Fe  Fe1  1  0.498  0.004  0.502  1.0
  Fe  Fe2  1  0.000  0.004  0.502  1.0
  Fe  Fe3  1  0.502  0.502  0.004  1.0
  Fe  Fe4  1  1.000  0.502  0.004  1.0
  Fe  Fe5  1  0.500  0.774  0.774  1.0
  Fe  Fe6  1  0.500  0.231  0.231  1.0
  Co  Co7  1  0.640  0.361  0.641  1.0
  Co  Co8  1  0.360  0.641  0.361  1.0
  Co  Co9  1  0.000  0.351  0.351  1.0
  Co  Co10  1  0.723  0.776  0.222  1.0
  Co  Co11  1  0.277  0.222  0.776  1.0
  W  W12  1  0.000  0.630  0.630  1.0
[/CIF]
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