The structure described by CsO3Cl crystallizes in the orthorhombic Pmn2_1 space group. Cs(1) is bonded in a 12-coordinate geometry to four equivalent O(2) and eight equivalent O(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to four equivalent Cs(1) and one Cl(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to four equivalent Cs(1) and one Cl(1) atom. Cl(1) is bonded in a trigonal non-coplanar geometry to one O(2) and two equivalent O(1) atoms. is represented by the CIF card [CIF]
data_CsClO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.726
_cell_length_b   6.573
_cell_length_c   6.813
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   211.655
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.003  0.000  0.489  1.0
  Cs  Cs1  1  0.997  0.500  0.989  1.0
  Cl  Cl2  1  0.469  0.000  0.030  1.0
  Cl  Cl3  1  0.531  0.500  0.530  1.0
  O  O4  1  0.520  0.816  0.157  1.0
  O  O5  1  0.520  0.184  0.157  1.0
  O  O6  1  0.843  0.500  0.480  1.0
  O  O7  1  0.480  0.684  0.657  1.0
  O  O8  1  0.480  0.316  0.657  1.0
  O  O9  1  0.157  0.000  0.980  1.0
[/CIF]
.
The structure described by CsO3Cl crystallizes in the orthorhombic Pmn2_1 space group. Cs(1) is bonded in a 12-coordinate geometry to four equivalent O(2) and eight equivalent O(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to four equivalent Cs(1) and one Cl(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to four equivalent Cs(1) and one Cl(1) atom. Cl(1) is bonded in a trigonal non-coplanar geometry to one O(2) and two equivalent O(1) atoms. is represented by the CIF card [CIF]
data_CsClO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.726
_cell_length_b   6.573
_cell_length_c   6.813
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   211.655
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.003  0.000  0.489  1.0
  Cs  Cs1  1  0.997  0.500  0.989  1.0
  Cl  Cl2  1  0.469  0.000  0.030  1.0
  Cl  Cl3  1  0.531  0.500  0.530  1.0
  O  O4  1  0.520  0.816  0.157  1.0
  O  O5  1  0.520  0.184  0.157  1.0
  O  O6  1  0.843  0.500  0.480  1.0
  O  O7  1  0.480  0.684  0.657  1.0
  O  O8  1  0.480  0.316  0.657  1.0
  O  O9  1  0.157  0.000  0.980  1.0
[/CIF]
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