The compound described by TaF5 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one tetrafluorotantalum molecule and one TaF6 cluster. In the TaF6 cluster, Ta(2) is bonded in a 6-coordinate geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(5) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to one Ta(2) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Ta(2) atom. In the third F site, F(5) is bonded in a single-bond geometry to one Ta(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_TaF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.553
_cell_length_b   5.563
_cell_length_c   7.908
_cell_angle_alpha   109.756
_cell_angle_beta   96.771
_cell_angle_gamma   110.368
_symmetry_Int_Tables_number   1
_cell_volume   207.704
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ta  Ta0  1  0.000  0.000  0.000  1.0
  Ta  Ta1  1  0.500  0.000  0.500  1.0
  F  F2  1  0.680  0.930  0.248  1.0
  F  F3  1  0.320  0.070  0.752  1.0
  F  F4  1  0.408  0.249  0.382  1.0
  F  F5  1  0.133  0.785  0.117  1.0
  F  F6  1  0.228  0.297  0.053  1.0
  F  F7  1  0.854  0.272  0.447  1.0
  F  F8  1  0.772  0.703  0.947  1.0
  F  F9  1  0.146  0.728  0.553  1.0
  F  F10  1  0.867  0.215  0.883  1.0
  F  F11  1  0.592  0.751  0.618  1.0
[/CIF]
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The compound described by TaF5 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one tetrafluorotantalum molecule and one TaF6 cluster. In the TaF6 cluster, Ta(2) is bonded in a 6-coordinate geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(5) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to one Ta(2) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Ta(2) atom. In the third F site, F(5) is bonded in a single-bond geometry to one Ta(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_TaF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.553
_cell_length_b   5.563
_cell_length_c   7.908
_cell_angle_alpha   109.756
_cell_angle_beta   96.771
_cell_angle_gamma   110.368
_symmetry_Int_Tables_number   1
_cell_volume   207.704
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ta  Ta0  1  0.000  0.000  0.000  1.0
  Ta  Ta1  1  0.500  0.000  0.500  1.0
  F  F2  1  0.680  0.930  0.248  1.0
  F  F3  1  0.320  0.070  0.752  1.0
  F  F4  1  0.408  0.249  0.382  1.0
  F  F5  1  0.133  0.785  0.117  1.0
  F  F6  1  0.228  0.297  0.053  1.0
  F  F7  1  0.854  0.272  0.447  1.0
  F  F8  1  0.772  0.703  0.947  1.0
  F  F9  1  0.146  0.728  0.553  1.0
  F  F10  1  0.867  0.215  0.883  1.0
  F  F11  1  0.592  0.751  0.618  1.0
[/CIF]
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