The crystal structure described by LiCo(PtO2)3 crystallizes in the monoclinic Pm space group. Li(1) is bonded in a 4-coordinate geometry to one Pt(2), one O(5), and two equivalent O(1) atoms. Co(1) is bonded in a 5-coordinate geometry to one O(4), two equivalent O(5), and two equivalent O(6) atoms. There are three inequivalent Pt sites. In the first Pt site, Pt(1) is bonded in a rectangular see-saw-like geometry to one O(1), one O(2), one O(3), and one O(4) atom. In the second Pt site, Pt(2) is bonded to one Li(1), two equivalent O(3), and two equivalent O(4) atoms to form distorted edge-sharing PtLiO4 square pyramids. In the third Pt site, Pt(3) is bonded to one O(5), one O(6), two equivalent O(1), and two equivalent O(2) atoms to form distorted edge-sharing PtO6 octahedra. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to two equivalent Li(1), one Pt(1), and two equivalent Pt(3) atoms. In the second O site, O(2) is bonded in a trigonal planar geometry to one Pt(1) and two equivalent Pt(3) atoms. In the third O site, O(3) is bonded in a trigonal planar geometry to one Pt(1) and two equivalent Pt(2) atoms. In the fourth O site, O(4) is bonded in a distorted rectangular see-saw-like geometry to one Co(1), one Pt(1), and two equivalent Pt(2) atoms. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one Li(1), two equivalent Co(1), and one Pt(3) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to two equivalent Co(1) and one Pt(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiCo(PtO2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.034
_cell_length_b   6.415
_cell_length_c   6.750
_cell_angle_alpha   95.506
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   130.775
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.500  0.260  0.763  1.0
  Co  Co1  1  0.000  0.476  0.459  1.0
  Pt  Pt2  1  0.000  1.000  0.019  1.0
  Pt  Pt3  1  0.500  0.516  0.037  1.0
  Pt  Pt4  1  0.500  0.973  0.500  1.0
  O  O5  1  0.000  0.048  0.717  1.0
  O  O6  1  0.000  0.920  0.301  1.0
  O  O7  1  0.000  0.689  0.945  1.0
  O  O8  1  0.000  0.324  0.110  1.0
  O  O9  1  0.500  0.289  0.488  1.0
  O  O10  1  0.500  0.660  0.505  1.0
[/CIF]
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The crystal structure described by LiCo(PtO2)3 crystallizes in the monoclinic Pm space group. Li(1) is bonded in a 4-coordinate geometry to one Pt(2), one O(5), and two equivalent O(1) atoms. Co(1) is bonded in a 5-coordinate geometry to one O(4), two equivalent O(5), and two equivalent O(6) atoms. There are three inequivalent Pt sites. In the first Pt site, Pt(1) is bonded in a rectangular see-saw-like geometry to one O(1), one O(2), one O(3), and one O(4) atom. In the second Pt site, Pt(2) is bonded to one Li(1), two equivalent O(3), and two equivalent O(4) atoms to form distorted edge-sharing PtLiO4 square pyramids. In the third Pt site, Pt(3) is bonded to one O(5), one O(6), two equivalent O(1), and two equivalent O(2) atoms to form distorted edge-sharing PtO6 octahedra. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to two equivalent Li(1), one Pt(1), and two equivalent Pt(3) atoms. In the second O site, O(2) is bonded in a trigonal planar geometry to one Pt(1) and two equivalent Pt(3) atoms. In the third O site, O(3) is bonded in a trigonal planar geometry to one Pt(1) and two equivalent Pt(2) atoms. In the fourth O site, O(4) is bonded in a distorted rectangular see-saw-like geometry to one Co(1), one Pt(1), and two equivalent Pt(2) atoms. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one Li(1), two equivalent Co(1), and one Pt(3) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to two equivalent Co(1) and one Pt(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiCo(PtO2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.034
_cell_length_b   6.415
_cell_length_c   6.750
_cell_angle_alpha   95.506
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   130.775
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.500  0.260  0.763  1.0
  Co  Co1  1  0.000  0.476  0.459  1.0
  Pt  Pt2  1  0.000  1.000  0.019  1.0
  Pt  Pt3  1  0.500  0.516  0.037  1.0
  Pt  Pt4  1  0.500  0.973  0.500  1.0
  O  O5  1  0.000  0.048  0.717  1.0
  O  O6  1  0.000  0.920  0.301  1.0
  O  O7  1  0.000  0.689  0.945  1.0
  O  O8  1  0.000  0.324  0.110  1.0
  O  O9  1  0.500  0.289  0.488  1.0
  O  O10  1  0.500  0.660  0.505  1.0
[/CIF]
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