The compound described by K4PtC6H4S2(NO6)2 crystallizes in the triclinic P-1 space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 7-coordinate geometry to two equivalent N(1), one O(2), one O(4), one O(5), and two equivalent O(3) atoms. In the second K site, K(2) is bonded in a 8-coordinate geometry to one N(1), one S(1), one O(1), one O(2), one O(3), one O(5), and two equivalent O(6) atoms. Pt(1) is bonded in a distorted square co-planar geometry to two equivalent S(1) and two equivalent O(1) atoms. There are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one N(1) and one S(1) atom. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. N(1) is bonded in a distorted single-bond geometry to one K(2), two equivalent K(1), and one C(1) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(5) atom. S(1) is bonded in a distorted water-like geometry to one K(2), one Pt(1), and one C(1) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one K(2), one Pt(1), and one C(2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one K(1), one K(2), and one C(2) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one K(2), two equivalent K(1), and one C(3) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one K(1) and one C(3) atom. In the fifth O site, O(5) is bonded in a distorted water-like geometry to one K(1), one K(2), one H(1), and one H(2) atom. In the sixth O site, O(6) is bonded in an L-shaped geometry to two equivalent K(2) atoms. is represented by the CIF card [CIF]
data_K4H4PtC6S2(NO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.724
_cell_length_b   7.154
_cell_length_c   11.221
_cell_angle_alpha   101.087
_cell_angle_beta   90.178
_cell_angle_gamma   108.661
_symmetry_Int_Tables_number   1
_cell_volume   500.626
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.594  0.756  0.449  1.0
  K  K1  1  0.406  0.244  0.551  1.0
  K  K2  1  0.550  0.098  0.192  1.0
  K  K3  1  0.450  0.902  0.808  1.0
  H  H4  1  0.854  0.457  0.401  1.0
  H  H5  1  0.146  0.543  0.599  1.0
  H  H6  1  0.847  0.283  0.466  1.0
  H  H7  1  0.153  0.717  0.534  1.0
  Pt  Pt8  1  0.000  0.000  0.000  1.0
  C  C9  1  0.198  0.356  0.228  1.0
  C  C10  1  0.802  0.644  0.772  1.0
  C  C11  1  0.988  0.867  0.233  1.0
  C  C12  1  0.012  0.133  0.767  1.0
  C  C13  1  0.109  0.835  0.344  1.0
  C  C14  1  0.891  0.165  0.656  1.0
  S  S15  1  0.057  0.329  0.100  1.0
  S  S16  1  0.943  0.671  0.900  1.0
  N  N17  1  0.302  0.379  0.318  1.0
  N  N18  1  0.698  0.621  0.682  1.0
  O  O19  1  0.113  0.924  0.147  1.0
  O  O20  1  0.887  0.076  0.853  1.0
  O  O21  1  0.799  0.846  0.234  1.0
  O  O22  1  0.201  0.154  0.766  1.0
  O  O23  1  0.307  0.908  0.354  1.0
  O  O24  1  0.693  0.092  0.646  1.0
  O  O25  1  0.993  0.743  0.418  1.0
  O  O26  1  0.007  0.257  0.582  1.0
  O  O27  1  0.763  0.321  0.408  1.0
  O  O28  1  0.237  0.679  0.592  1.0
  O  O29  1  0.533  0.269  0.984  1.0
  O  O30  1  0.467  0.731  0.016  1.0
[/CIF]
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The compound described by K4PtC6H4S2(NO6)2 crystallizes in the triclinic P-1 space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 7-coordinate geometry to two equivalent N(1), one O(2), one O(4), one O(5), and two equivalent O(3) atoms. In the second K site, K(2) is bonded in a 8-coordinate geometry to one N(1), one S(1), one O(1), one O(2), one O(3), one O(5), and two equivalent O(6) atoms. Pt(1) is bonded in a distorted square co-planar geometry to two equivalent S(1) and two equivalent O(1) atoms. There are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one N(1) and one S(1) atom. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. N(1) is bonded in a distorted single-bond geometry to one K(2), two equivalent K(1), and one C(1) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(5) atom. S(1) is bonded in a distorted water-like geometry to one K(2), one Pt(1), and one C(1) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one K(2), one Pt(1), and one C(2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one K(1), one K(2), and one C(2) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one K(2), two equivalent K(1), and one C(3) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one K(1) and one C(3) atom. In the fifth O site, O(5) is bonded in a distorted water-like geometry to one K(1), one K(2), one H(1), and one H(2) atom. In the sixth O site, O(6) is bonded in an L-shaped geometry to two equivalent K(2) atoms. is represented by the CIF card [CIF]
data_K4H4PtC6S2(NO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.724
_cell_length_b   7.154
_cell_length_c   11.221
_cell_angle_alpha   101.087
_cell_angle_beta   90.178
_cell_angle_gamma   108.661
_symmetry_Int_Tables_number   1
_cell_volume   500.626
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.594  0.756  0.449  1.0
  K  K1  1  0.406  0.244  0.551  1.0
  K  K2  1  0.550  0.098  0.192  1.0
  K  K3  1  0.450  0.902  0.808  1.0
  H  H4  1  0.854  0.457  0.401  1.0
  H  H5  1  0.146  0.543  0.599  1.0
  H  H6  1  0.847  0.283  0.466  1.0
  H  H7  1  0.153  0.717  0.534  1.0
  Pt  Pt8  1  0.000  0.000  0.000  1.0
  C  C9  1  0.198  0.356  0.228  1.0
  C  C10  1  0.802  0.644  0.772  1.0
  C  C11  1  0.988  0.867  0.233  1.0
  C  C12  1  0.012  0.133  0.767  1.0
  C  C13  1  0.109  0.835  0.344  1.0
  C  C14  1  0.891  0.165  0.656  1.0
  S  S15  1  0.057  0.329  0.100  1.0
  S  S16  1  0.943  0.671  0.900  1.0
  N  N17  1  0.302  0.379  0.318  1.0
  N  N18  1  0.698  0.621  0.682  1.0
  O  O19  1  0.113  0.924  0.147  1.0
  O  O20  1  0.887  0.076  0.853  1.0
  O  O21  1  0.799  0.846  0.234  1.0
  O  O22  1  0.201  0.154  0.766  1.0
  O  O23  1  0.307  0.908  0.354  1.0
  O  O24  1  0.693  0.092  0.646  1.0
  O  O25  1  0.993  0.743  0.418  1.0
  O  O26  1  0.007  0.257  0.582  1.0
  O  O27  1  0.763  0.321  0.408  1.0
  O  O28  1  0.237  0.679  0.592  1.0
  O  O29  1  0.533  0.269  0.984  1.0
  O  O30  1  0.467  0.731  0.016  1.0
[/CIF]
.