The compound described by K2MoH(OF2)2 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 10-coordinate geometry to two equivalent O(2), two equivalent F(1), two equivalent F(2), two equivalent F(3), and two equivalent F(4) atoms. In the second K site, K(2) is bonded in a 6-coordinate geometry to two equivalent H(1), one O(1), one O(2), one F(1), one F(2), one F(3), and one F(4) atom. Mo(1) is bonded in a distorted octahedral geometry to one O(1), one O(2), one F(1), one F(2), one F(3), and one F(4) atom. H(1) is bonded in a water-like geometry to two equivalent K(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one K(2) and one Mo(1) atom. In the second O site, O(2) is bonded in a 1-coordinate geometry to one K(2), two equivalent K(1), and one Mo(1) atom. There are four inequivalent F sites. In the first F site, F(3) is bonded in a 4-coordinate geometry to one K(2), two equivalent K(1), and one Mo(1) atom. In the second F site, F(4) is bonded in a 4-coordinate geometry to one K(2), two equivalent K(1), and one Mo(1) atom. In the third F site, F(1) is bonded in a 3-coordinate geometry to one K(2), two equivalent K(1), and one Mo(1) atom. In the fourth F site, F(2) is bonded to one K(2), two equivalent K(1), and one Mo(1) atom to form distorted corner-sharing FK3Mo tetrahedra. is represented by the CIF card [CIF]
data_K2MoH(OF2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.296
_cell_length_b   6.292
_cell_length_c   18.301
_cell_angle_alpha   84.846
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   722.063
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.649  0.248  0.251  1.0
  K  K1  1  0.351  0.752  0.749  1.0
  K  K2  1  0.149  0.752  0.249  1.0
  K  K3  1  0.851  0.248  0.751  1.0
  K  K4  1  0.668  0.699  0.397  1.0
  K  K5  1  0.332  0.301  0.603  1.0
  K  K6  1  0.168  0.301  0.103  1.0
  K  K7  1  0.832  0.699  0.897  1.0
  Mo  Mo8  1  0.655  0.797  0.130  1.0
  Mo  Mo9  1  0.345  0.203  0.870  1.0
  Mo  Mo10  1  0.155  0.203  0.370  1.0
  Mo  Mo11  1  0.845  0.797  0.630  1.0
  H  H12  1  0.181  0.720  0.009  1.0
  H  H13  1  0.819  0.280  0.991  1.0
  H  H14  1  0.681  0.280  0.491  1.0
  H  H15  1  0.319  0.720  0.509  1.0
  O  O16  1  0.677  0.769  0.037  1.0
  O  O17  1  0.323  0.231  0.963  1.0
  O  O18  1  0.177  0.231  0.463  1.0
  O  O19  1  0.823  0.769  0.537  1.0
  O  O20  1  0.470  0.002  0.135  1.0
  O  O21  1  0.530  0.998  0.865  1.0
  O  O22  1  0.970  0.998  0.365  1.0
  O  O23  1  0.030  0.002  0.635  1.0
  F  F24  1  0.907  0.982  0.135  1.0
  F  F25  1  0.093  0.018  0.865  1.0
  F  F26  1  0.407  0.018  0.365  1.0
  F  F27  1  0.593  0.982  0.635  1.0
  F  F28  1  0.871  0.550  0.155  1.0
  F  F29  1  0.129  0.450  0.845  1.0
  F  F30  1  0.371  0.450  0.345  1.0
  F  F31  1  0.629  0.550  0.655  1.0
  F  F32  1  0.683  0.784  0.245  1.0
  F  F33  1  0.317  0.216  0.755  1.0
  F  F34  1  0.183  0.216  0.255  1.0
  F  F35  1  0.817  0.784  0.745  1.0
  F  F36  1  0.943  0.433  0.347  1.0
  F  F37  1  0.057  0.567  0.653  1.0
  F  F38  1  0.443  0.567  0.153  1.0
  F  F39  1  0.557  0.433  0.847  1.0
[/CIF]
.
The compound described by K2MoH(OF2)2 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 10-coordinate geometry to two equivalent O(2), two equivalent F(1), two equivalent F(2), two equivalent F(3), and two equivalent F(4) atoms. In the second K site, K(2) is bonded in a 6-coordinate geometry to two equivalent H(1), one O(1), one O(2), one F(1), one F(2), one F(3), and one F(4) atom. Mo(1) is bonded in a distorted octahedral geometry to one O(1), one O(2), one F(1), one F(2), one F(3), and one F(4) atom. H(1) is bonded in a water-like geometry to two equivalent K(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one K(2) and one Mo(1) atom. In the second O site, O(2) is bonded in a 1-coordinate geometry to one K(2), two equivalent K(1), and one Mo(1) atom. There are four inequivalent F sites. In the first F site, F(3) is bonded in a 4-coordinate geometry to one K(2), two equivalent K(1), and one Mo(1) atom. In the second F site, F(4) is bonded in a 4-coordinate geometry to one K(2), two equivalent K(1), and one Mo(1) atom. In the third F site, F(1) is bonded in a 3-coordinate geometry to one K(2), two equivalent K(1), and one Mo(1) atom. In the fourth F site, F(2) is bonded to one K(2), two equivalent K(1), and one Mo(1) atom to form distorted corner-sharing FK3Mo tetrahedra. is represented by the CIF card [CIF]
data_K2MoH(OF2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.296
_cell_length_b   6.292
_cell_length_c   18.301
_cell_angle_alpha   84.846
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   722.063
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.649  0.248  0.251  1.0
  K  K1  1  0.351  0.752  0.749  1.0
  K  K2  1  0.149  0.752  0.249  1.0
  K  K3  1  0.851  0.248  0.751  1.0
  K  K4  1  0.668  0.699  0.397  1.0
  K  K5  1  0.332  0.301  0.603  1.0
  K  K6  1  0.168  0.301  0.103  1.0
  K  K7  1  0.832  0.699  0.897  1.0
  Mo  Mo8  1  0.655  0.797  0.130  1.0
  Mo  Mo9  1  0.345  0.203  0.870  1.0
  Mo  Mo10  1  0.155  0.203  0.370  1.0
  Mo  Mo11  1  0.845  0.797  0.630  1.0
  H  H12  1  0.181  0.720  0.009  1.0
  H  H13  1  0.819  0.280  0.991  1.0
  H  H14  1  0.681  0.280  0.491  1.0
  H  H15  1  0.319  0.720  0.509  1.0
  O  O16  1  0.677  0.769  0.037  1.0
  O  O17  1  0.323  0.231  0.963  1.0
  O  O18  1  0.177  0.231  0.463  1.0
  O  O19  1  0.823  0.769  0.537  1.0
  O  O20  1  0.470  0.002  0.135  1.0
  O  O21  1  0.530  0.998  0.865  1.0
  O  O22  1  0.970  0.998  0.365  1.0
  O  O23  1  0.030  0.002  0.635  1.0
  F  F24  1  0.907  0.982  0.135  1.0
  F  F25  1  0.093  0.018  0.865  1.0
  F  F26  1  0.407  0.018  0.365  1.0
  F  F27  1  0.593  0.982  0.635  1.0
  F  F28  1  0.871  0.550  0.155  1.0
  F  F29  1  0.129  0.450  0.845  1.0
  F  F30  1  0.371  0.450  0.345  1.0
  F  F31  1  0.629  0.550  0.655  1.0
  F  F32  1  0.683  0.784  0.245  1.0
  F  F33  1  0.317  0.216  0.755  1.0
  F  F34  1  0.183  0.216  0.255  1.0
  F  F35  1  0.817  0.784  0.745  1.0
  F  F36  1  0.943  0.433  0.347  1.0
  F  F37  1  0.057  0.567  0.653  1.0
  F  F38  1  0.443  0.567  0.153  1.0
  F  F39  1  0.557  0.433  0.847  1.0
[/CIF]
.