The compound described by PrSbO4 crystallizes in the monoclinic P2_1/c space group. Pr(1) is bonded in a 8-coordinate geometry to one O(2), one O(4), three equivalent O(1), and three equivalent O(3) atoms. Sb(1) is bonded to one O(1), one O(3), two equivalent O(2), and two equivalent O(4) atoms to form corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 33-43°. There are four inequivalent O sites. In the first O site, O(1) is bonded to three equivalent Pr(1) and one Sb(1) atom to form a mixture of distorted edge and corner-sharing OPr3Sb tetrahedra. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Pr(1) and two equivalent Sb(1) atoms. In the third O site, O(3) is bonded in a 4-coordinate geometry to three equivalent Pr(1) and one Sb(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Pr(1) and two equivalent Sb(1) atoms. is represented by the CIF card [CIF]
data_PrSbO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.556
_cell_length_b   7.710
_cell_length_c   7.690
_cell_angle_alpha   79.246
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   323.652
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pr  Pr0  1  0.273  0.099  0.152  1.0
  Pr  Pr1  1  0.773  0.401  0.848  1.0
  Pr  Pr2  1  0.727  0.901  0.848  1.0
  Pr  Pr3  1  0.227  0.599  0.152  1.0
  Sb  Sb4  1  0.768  0.300  0.336  1.0
  Sb  Sb5  1  0.268  0.200  0.664  1.0
  Sb  Sb6  1  0.232  0.700  0.664  1.0
  Sb  Sb7  1  0.732  0.800  0.336  1.0
  O  O8  1  0.976  0.327  0.121  1.0
  O  O9  1  0.476  0.173  0.879  1.0
  O  O10  1  0.024  0.673  0.879  1.0
  O  O11  1  0.524  0.827  0.121  1.0
  O  O12  1  0.646  0.054  0.333  1.0
  O  O13  1  0.146  0.446  0.667  1.0
  O  O14  1  0.354  0.946  0.667  1.0
  O  O15  1  0.854  0.554  0.333  1.0
  O  O16  1  0.995  0.868  0.172  1.0
  O  O17  1  0.495  0.632  0.828  1.0
  O  O18  1  0.005  0.132  0.828  1.0
  O  O19  1  0.505  0.368  0.172  1.0
  O  O20  1  0.913  0.795  0.559  1.0
  O  O21  1  0.413  0.705  0.441  1.0
  O  O22  1  0.087  0.205  0.441  1.0
  O  O23  1  0.587  0.295  0.559  1.0
[/CIF]
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The compound described by PrSbO4 crystallizes in the monoclinic P2_1/c space group. Pr(1) is bonded in a 8-coordinate geometry to one O(2), one O(4), three equivalent O(1), and three equivalent O(3) atoms. Sb(1) is bonded to one O(1), one O(3), two equivalent O(2), and two equivalent O(4) atoms to form corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 33-43°. There are four inequivalent O sites. In the first O site, O(1) is bonded to three equivalent Pr(1) and one Sb(1) atom to form a mixture of distorted edge and corner-sharing OPr3Sb tetrahedra. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Pr(1) and two equivalent Sb(1) atoms. In the third O site, O(3) is bonded in a 4-coordinate geometry to three equivalent Pr(1) and one Sb(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Pr(1) and two equivalent Sb(1) atoms. is represented by the CIF card [CIF]
data_PrSbO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.556
_cell_length_b   7.710
_cell_length_c   7.690
_cell_angle_alpha   79.246
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   323.652
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pr  Pr0  1  0.273  0.099  0.152  1.0
  Pr  Pr1  1  0.773  0.401  0.848  1.0
  Pr  Pr2  1  0.727  0.901  0.848  1.0
  Pr  Pr3  1  0.227  0.599  0.152  1.0
  Sb  Sb4  1  0.768  0.300  0.336  1.0
  Sb  Sb5  1  0.268  0.200  0.664  1.0
  Sb  Sb6  1  0.232  0.700  0.664  1.0
  Sb  Sb7  1  0.732  0.800  0.336  1.0
  O  O8  1  0.976  0.327  0.121  1.0
  O  O9  1  0.476  0.173  0.879  1.0
  O  O10  1  0.024  0.673  0.879  1.0
  O  O11  1  0.524  0.827  0.121  1.0
  O  O12  1  0.646  0.054  0.333  1.0
  O  O13  1  0.146  0.446  0.667  1.0
  O  O14  1  0.354  0.946  0.667  1.0
  O  O15  1  0.854  0.554  0.333  1.0
  O  O16  1  0.995  0.868  0.172  1.0
  O  O17  1  0.495  0.632  0.828  1.0
  O  O18  1  0.005  0.132  0.828  1.0
  O  O19  1  0.505  0.368  0.172  1.0
  O  O20  1  0.913  0.795  0.559  1.0
  O  O21  1  0.413  0.705  0.441  1.0
  O  O22  1  0.087  0.205  0.441  1.0
  O  O23  1  0.587  0.295  0.559  1.0
[/CIF]
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