The structure described by KLi2HO3H2 crystallizes in the monoclinic P2_1/m space group. The structure consists of two 1333-74-0 molecules inside a KLi2HO3 framework. In the KLi2HO3 framework, K(1) is bonded in a 2-coordinate geometry to one O(1) and three equivalent O(2) atoms. Li(1) is bonded in a 5-coordinate geometry to one H(3), one O(1), one O(2), and two equivalent O(3) atoms. H(3) is bonded in a single-bond geometry to two equivalent Li(1) and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one K(1), two equivalent Li(1), and one O(2) atom. In the second O site, O(2) is bonded in a 6-coordinate geometry to three equivalent K(1), two equivalent Li(1), and one O(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to four equivalent Li(1) and one H(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_KLi2(HO)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.703
_cell_length_b   6.145
_cell_length_c   7.439
_cell_angle_alpha   75.125
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   251.982
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.250  0.735  0.481  1.0
  K  K1  1  0.750  0.265  0.519  1.0
  Li  Li2  1  0.544  0.662  0.855  1.0
  Li  Li3  1  0.956  0.662  0.855  1.0
  Li  Li4  1  0.456  0.338  0.145  1.0
  Li  Li5  1  0.044  0.338  0.145  1.0
  H  H6  1  0.250  0.257  0.839  1.0
  H  H7  1  0.750  0.743  0.161  1.0
  H  H8  1  0.250  0.155  0.802  1.0
  H  H9  1  0.750  0.845  0.198  1.0
  H  H10  1  0.750  0.388  0.918  1.0
  H  H11  1  0.250  0.612  0.082  1.0
  O  O12  1  0.750  0.849  0.690  1.0
  O  O13  1  0.250  0.151  0.310  1.0
  O  O14  1  0.750  0.615  0.654  1.0
  O  O15  1  0.750  0.422  0.040  1.0
  O  O16  1  0.250  0.385  0.346  1.0
  O  O17  1  0.250  0.578  0.960  1.0
[/CIF]
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The structure described by KLi2HO3H2 crystallizes in the monoclinic P2_1/m space group. The structure consists of two 1333-74-0 molecules inside a KLi2HO3 framework. In the KLi2HO3 framework, K(1) is bonded in a 2-coordinate geometry to one O(1) and three equivalent O(2) atoms. Li(1) is bonded in a 5-coordinate geometry to one H(3), one O(1), one O(2), and two equivalent O(3) atoms. H(3) is bonded in a single-bond geometry to two equivalent Li(1) and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one K(1), two equivalent Li(1), and one O(2) atom. In the second O site, O(2) is bonded in a 6-coordinate geometry to three equivalent K(1), two equivalent Li(1), and one O(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to four equivalent Li(1) and one H(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_KLi2(HO)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.703
_cell_length_b   6.145
_cell_length_c   7.439
_cell_angle_alpha   75.125
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   251.982
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.250  0.735  0.481  1.0
  K  K1  1  0.750  0.265  0.519  1.0
  Li  Li2  1  0.544  0.662  0.855  1.0
  Li  Li3  1  0.956  0.662  0.855  1.0
  Li  Li4  1  0.456  0.338  0.145  1.0
  Li  Li5  1  0.044  0.338  0.145  1.0
  H  H6  1  0.250  0.257  0.839  1.0
  H  H7  1  0.750  0.743  0.161  1.0
  H  H8  1  0.250  0.155  0.802  1.0
  H  H9  1  0.750  0.845  0.198  1.0
  H  H10  1  0.750  0.388  0.918  1.0
  H  H11  1  0.250  0.612  0.082  1.0
  O  O12  1  0.750  0.849  0.690  1.0
  O  O13  1  0.250  0.151  0.310  1.0
  O  O14  1  0.750  0.615  0.654  1.0
  O  O15  1  0.750  0.422  0.040  1.0
  O  O16  1  0.250  0.385  0.346  1.0
  O  O17  1  0.250  0.578  0.960  1.0
[/CIF]
.