The compound described by TcRh crystallizes in the hexagonal P-6m2 space group. Tc(1) is bonded to six equivalent Tc(1) and six equivalent Rh(1) atoms to form distorted TcTc6Rh6 cuboctahedra that share corners with eighteen equivalent Tc(1)Tc6Rh6 cuboctahedra, edges with six equivalent Tc(1)Tc6Rh6 cuboctahedra, edges with twelve equivalent Rh(1)Tc6Rh6 cuboctahedra, faces with eight equivalent Tc(1)Tc6Rh6 cuboctahedra, and faces with twelve equivalent Rh(1)Tc6Rh6 cuboctahedra. Rh(1) is bonded to six equivalent Tc(1) and six equivalent Rh(1) atoms to form distorted RhTc6Rh6 cuboctahedra that share corners with eighteen equivalent Rh(1)Tc6Rh6 cuboctahedra, edges with six equivalent Rh(1)Tc6Rh6 cuboctahedra, edges with twelve equivalent Tc(1)Tc6Rh6 cuboctahedra, faces with eight equivalent Rh(1)Tc6Rh6 cuboctahedra, and faces with twelve equivalent Tc(1)Tc6Rh6 cuboctahedra. is represented by the CIF file [CIF]
data_TcRh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.722
_cell_length_b   2.722
_cell_length_c   4.331
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   27.792
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tc  Tc0  1  1.000  0.000  0.000  1.0
  Rh  Rh1  1  0.333  0.667  0.500  1.0
[/CIF]
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The compound described by TcRh crystallizes in the hexagonal P-6m2 space group. Tc(1) is bonded to six equivalent Tc(1) and six equivalent Rh(1) atoms to form distorted TcTc6Rh6 cuboctahedra that share corners with eighteen equivalent Tc(1)Tc6Rh6 cuboctahedra, edges with six equivalent Tc(1)Tc6Rh6 cuboctahedra, edges with twelve equivalent Rh(1)Tc6Rh6 cuboctahedra, faces with eight equivalent Tc(1)Tc6Rh6 cuboctahedra, and faces with twelve equivalent Rh(1)Tc6Rh6 cuboctahedra. Rh(1) is bonded to six equivalent Tc(1) and six equivalent Rh(1) atoms to form distorted RhTc6Rh6 cuboctahedra that share corners with eighteen equivalent Rh(1)Tc6Rh6 cuboctahedra, edges with six equivalent Rh(1)Tc6Rh6 cuboctahedra, edges with twelve equivalent Tc(1)Tc6Rh6 cuboctahedra, faces with eight equivalent Rh(1)Tc6Rh6 cuboctahedra, and faces with twelve equivalent Tc(1)Tc6Rh6 cuboctahedra. is represented by the CIF file [CIF]
data_TcRh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.722
_cell_length_b   2.722
_cell_length_c   4.331
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   27.792
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tc  Tc0  1  1.000  0.000  0.000  1.0
  Rh  Rh1  1  0.333  0.667  0.500  1.0
[/CIF]
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