The crystal structure described by Na3GaP6(NO4)6 crystallizes in the triclinic P-1 space group. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded in a 7-coordinate geometry to one O(10), one O(12), one O(3), one O(4), one O(5), one O(8), and one O(9) atom. In the second Na site, Na(2) is bonded in a distorted hexagonal planar geometry to two equivalent O(7), two equivalent O(8), and two equivalent O(9) atoms. Ga(1) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form GaO6 octahedra that share corners with two equivalent P(1)N2O2 tetrahedra and corners with two equivalent P(3)N2O2 tetrahedra. There are three inequivalent P sites. In the first P site, P(1) is bonded to one N(2), one N(3), one O(5), and one O(6) atom to form PN2O2 tetrahedra that share  a cornercorner with one Ga(1)O6 octahedra and  a cornercorner with one P(3)N2O2 tetrahedra. The corner-sharing octahedral tilt angles are 43°. In the second P site, P(2) is bonded in a trigonal planar geometry to one N(1), one O(3), and one O(4) atom. In the third P site, P(3) is bonded to one N(1), one N(2), one O(1), and one O(2) atom to form PN2O2 tetrahedra that share  a cornercorner with one Ga(1)O6 octahedra and  a cornercorner with one P(1)N2O2 tetrahedra. The corner-sharing octahedral tilt angles are 44°. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one P(2), one P(3), and one O(7) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one P(1), one P(3), and one O(10) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one P(1), one O(12), and one O(9) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one P(3) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Ga(1) and one P(3) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one Na(1) and one P(2) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Na(1), one Ga(1), and one P(2) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Na(1) and one P(1) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Ga(1) and one P(1) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one Na(2) and one N(1) atom. In the eighth O site, O(8) is bonded in a trigonal non-coplanar geometry to one Na(1), one Na(2), and one O(11) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one Na(1), one Na(2), and one N(3) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Na(1) and one N(2) atom. In the eleventh O site, O(11) is bonded in a single-bond geometry to one O(8) atom. In the twelfth O site, O(12) is bonded in a distorted bent 120 degrees geometry to one Na(1) and one N(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Na3GaP6(NO4)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.768
_cell_length_b   9.135
_cell_length_c   8.493
_cell_angle_alpha   77.367
_cell_angle_beta   79.704
_cell_angle_gamma   76.780
_symmetry_Int_Tables_number   1
_cell_volume   640.295
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.745  0.797  0.671  1.0
  Na  Na1  1  0.255  0.203  0.329  1.0
  Na  Na2  1  0.500  0.500  0.500  1.0
  Ga  Ga3  1  0.000  0.000  0.000  1.0
  P  P4  1  0.356  0.978  0.794  1.0
  P  P5  1  0.644  0.022  0.206  1.0
  P  P6  1  0.080  0.759  0.773  1.0
  P  P7  1  0.920  0.241  0.227  1.0
  P  P8  1  0.724  0.297  0.951  1.0
  P  P9  1  0.276  0.703  0.049  1.0
  N  N10  1  0.217  0.639  0.885  1.0
  N  N11  1  0.783  0.361  0.115  1.0
  N  N12  1  0.414  0.812  0.933  1.0
  N  N13  1  0.586  0.188  0.067  1.0
  N  N14  1  0.330  0.891  0.620  1.0
  N  N15  1  0.670  0.109  0.380  1.0
  O  O16  1  0.654  0.428  0.835  1.0
  O  O17  1  0.346  0.572  0.165  1.0
  O  O18  1  0.869  0.183  0.897  1.0
  O  O19  1  0.131  0.817  0.103  1.0
  O  O20  1  0.039  0.701  0.639  1.0
  O  O21  1  0.961  0.299  0.361  1.0
  O  O22  1  0.958  0.882  0.847  1.0
  O  O23  1  0.042  0.118  0.153  1.0
  O  O24  1  0.489  0.057  0.725  1.0
  O  O25  1  0.511  0.943  0.275  1.0
  O  O26  1  0.192  0.058  0.854  1.0
  O  O27  1  0.808  0.942  0.146  1.0
  O  O28  1  0.311  0.532  0.818  1.0
  O  O29  1  0.689  0.468  0.182  1.0
  O  O30  1  0.787  0.576  0.495  1.0
  O  O31  1  0.213  0.424  0.505  1.0
  O  O32  1  0.424  0.771  0.595  1.0
  O  O33  1  0.576  0.229  0.405  1.0
  O  O34  1  0.564  0.748  0.912  1.0
  O  O35  1  0.436  0.252  0.088  1.0
  O  O36  1  0.133  0.378  0.634  1.0
  O  O37  1  0.867  0.622  0.366  1.0
  O  O38  1  0.763  0.028  0.477  1.0
  O  O39  1  0.237  0.972  0.523  1.0
[/CIF]
.
The crystal structure described by Na3GaP6(NO4)6 crystallizes in the triclinic P-1 space group. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded in a 7-coordinate geometry to one O(10), one O(12), one O(3), one O(4), one O(5), one O(8), and one O(9) atom. In the second Na site, Na(2) is bonded in a distorted hexagonal planar geometry to two equivalent O(7), two equivalent O(8), and two equivalent O(9) atoms. Ga(1) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form GaO6 octahedra that share corners with two equivalent P(1)N2O2 tetrahedra and corners with two equivalent P(3)N2O2 tetrahedra. There are three inequivalent P sites. In the first P site, P(1) is bonded to one N(2), one N(3), one O(5), and one O(6) atom to form PN2O2 tetrahedra that share  a cornercorner with one Ga(1)O6 octahedra and  a cornercorner with one P(3)N2O2 tetrahedra. The corner-sharing octahedral tilt angles are 43°. In the second P site, P(2) is bonded in a trigonal planar geometry to one N(1), one O(3), and one O(4) atom. In the third P site, P(3) is bonded to one N(1), one N(2), one O(1), and one O(2) atom to form PN2O2 tetrahedra that share  a cornercorner with one Ga(1)O6 octahedra and  a cornercorner with one P(1)N2O2 tetrahedra. The corner-sharing octahedral tilt angles are 44°. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one P(2), one P(3), and one O(7) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one P(1), one P(3), and one O(10) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one P(1), one O(12), and one O(9) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one P(3) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Ga(1) and one P(3) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one Na(1) and one P(2) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Na(1), one Ga(1), and one P(2) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Na(1) and one P(1) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Ga(1) and one P(1) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one Na(2) and one N(1) atom. In the eighth O site, O(8) is bonded in a trigonal non-coplanar geometry to one Na(1), one Na(2), and one O(11) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one Na(1), one Na(2), and one N(3) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Na(1) and one N(2) atom. In the eleventh O site, O(11) is bonded in a single-bond geometry to one O(8) atom. In the twelfth O site, O(12) is bonded in a distorted bent 120 degrees geometry to one Na(1) and one N(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Na3GaP6(NO4)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.768
_cell_length_b   9.135
_cell_length_c   8.493
_cell_angle_alpha   77.367
_cell_angle_beta   79.704
_cell_angle_gamma   76.780
_symmetry_Int_Tables_number   1
_cell_volume   640.295
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.745  0.797  0.671  1.0
  Na  Na1  1  0.255  0.203  0.329  1.0
  Na  Na2  1  0.500  0.500  0.500  1.0
  Ga  Ga3  1  0.000  0.000  0.000  1.0
  P  P4  1  0.356  0.978  0.794  1.0
  P  P5  1  0.644  0.022  0.206  1.0
  P  P6  1  0.080  0.759  0.773  1.0
  P  P7  1  0.920  0.241  0.227  1.0
  P  P8  1  0.724  0.297  0.951  1.0
  P  P9  1  0.276  0.703  0.049  1.0
  N  N10  1  0.217  0.639  0.885  1.0
  N  N11  1  0.783  0.361  0.115  1.0
  N  N12  1  0.414  0.812  0.933  1.0
  N  N13  1  0.586  0.188  0.067  1.0
  N  N14  1  0.330  0.891  0.620  1.0
  N  N15  1  0.670  0.109  0.380  1.0
  O  O16  1  0.654  0.428  0.835  1.0
  O  O17  1  0.346  0.572  0.165  1.0
  O  O18  1  0.869  0.183  0.897  1.0
  O  O19  1  0.131  0.817  0.103  1.0
  O  O20  1  0.039  0.701  0.639  1.0
  O  O21  1  0.961  0.299  0.361  1.0
  O  O22  1  0.958  0.882  0.847  1.0
  O  O23  1  0.042  0.118  0.153  1.0
  O  O24  1  0.489  0.057  0.725  1.0
  O  O25  1  0.511  0.943  0.275  1.0
  O  O26  1  0.192  0.058  0.854  1.0
  O  O27  1  0.808  0.942  0.146  1.0
  O  O28  1  0.311  0.532  0.818  1.0
  O  O29  1  0.689  0.468  0.182  1.0
  O  O30  1  0.787  0.576  0.495  1.0
  O  O31  1  0.213  0.424  0.505  1.0
  O  O32  1  0.424  0.771  0.595  1.0
  O  O33  1  0.576  0.229  0.405  1.0
  O  O34  1  0.564  0.748  0.912  1.0
  O  O35  1  0.436  0.252  0.088  1.0
  O  O36  1  0.133  0.378  0.634  1.0
  O  O37  1  0.867  0.622  0.366  1.0
  O  O38  1  0.763  0.028  0.477  1.0
  O  O39  1  0.237  0.972  0.523  1.0
[/CIF]
.