The material structure described by Tm5Ni2In4 crystallizes in the orthorhombic Pbam space group. There are three inequivalent Tm sites. In the first Tm site, Tm(1) is bonded in a distorted body-centered cubic geometry to four equivalent In(1) and four equivalent In(2) atoms. In the second Tm site, Tm(2) is bonded in a 10-coordinate geometry to four equivalent Ni(1), two equivalent In(1), and four equivalent In(2) atoms. In the third Tm site, Tm(3) is bonded in a 8-coordinate geometry to two equivalent Ni(1), two equivalent In(2), and four equivalent In(1) atoms. Ni(1) is bonded in a 8-coordinate geometry to two equivalent Tm(3), four equivalent Tm(2), one In(1), and one In(2) atom. There are two inequivalent In sites. In the first In site, In(1) is bonded in a 9-coordinate geometry to two equivalent Tm(1), two equivalent Tm(2), four equivalent Tm(3), and one Ni(1) atom. In the second In site, In(2) is bonded in a 9-coordinate geometry to two equivalent Tm(1), two equivalent Tm(3), four equivalent Tm(2), and one Ni(1) atom. is represented by the CIF file [CIF]
data_Tm5(In2Ni)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.520
_cell_length_b   7.977
_cell_length_c   17.826
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   500.629
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tm  Tm0  1  0.000  0.500  0.500  1.0
  Tm  Tm1  1  0.000  0.000  0.000  1.0
  Tm  Tm2  1  0.000  0.746  0.279  1.0
  Tm  Tm3  1  0.000  0.254  0.721  1.0
  Tm  Tm4  1  0.000  0.754  0.779  1.0
  Tm  Tm5  1  0.000  0.246  0.221  1.0
  Tm  Tm6  1  0.000  0.618  0.087  1.0
  Tm  Tm7  1  0.000  0.382  0.913  1.0
  Tm  Tm8  1  0.000  0.882  0.587  1.0
  Tm  Tm9  1  0.000  0.118  0.413  1.0
  In  In10  1  0.500  0.706  0.930  1.0
  In  In11  1  0.500  0.294  0.070  1.0
  In  In12  1  0.500  0.794  0.430  1.0
  In  In13  1  0.500  0.206  0.570  1.0
  In  In14  1  0.500  0.573  0.652  1.0
  In  In15  1  0.500  0.427  0.348  1.0
  In  In16  1  0.500  0.927  0.152  1.0
  In  In17  1  0.500  0.073  0.848  1.0
  Ni  Ni18  1  0.500  0.525  0.195  1.0
  Ni  Ni19  1  0.500  0.475  0.805  1.0
  Ni  Ni20  1  0.500  0.975  0.695  1.0
  Ni  Ni21  1  0.500  0.025  0.305  1.0
[/CIF]
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The material structure described by Tm5Ni2In4 crystallizes in the orthorhombic Pbam space group. There are three inequivalent Tm sites. In the first Tm site, Tm(1) is bonded in a distorted body-centered cubic geometry to four equivalent In(1) and four equivalent In(2) atoms. In the second Tm site, Tm(2) is bonded in a 10-coordinate geometry to four equivalent Ni(1), two equivalent In(1), and four equivalent In(2) atoms. In the third Tm site, Tm(3) is bonded in a 8-coordinate geometry to two equivalent Ni(1), two equivalent In(2), and four equivalent In(1) atoms. Ni(1) is bonded in a 8-coordinate geometry to two equivalent Tm(3), four equivalent Tm(2), one In(1), and one In(2) atom. There are two inequivalent In sites. In the first In site, In(1) is bonded in a 9-coordinate geometry to two equivalent Tm(1), two equivalent Tm(2), four equivalent Tm(3), and one Ni(1) atom. In the second In site, In(2) is bonded in a 9-coordinate geometry to two equivalent Tm(1), two equivalent Tm(3), four equivalent Tm(2), and one Ni(1) atom. is represented by the CIF file [CIF]
data_Tm5(In2Ni)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.520
_cell_length_b   7.977
_cell_length_c   17.826
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   500.629
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tm  Tm0  1  0.000  0.500  0.500  1.0
  Tm  Tm1  1  0.000  0.000  0.000  1.0
  Tm  Tm2  1  0.000  0.746  0.279  1.0
  Tm  Tm3  1  0.000  0.254  0.721  1.0
  Tm  Tm4  1  0.000  0.754  0.779  1.0
  Tm  Tm5  1  0.000  0.246  0.221  1.0
  Tm  Tm6  1  0.000  0.618  0.087  1.0
  Tm  Tm7  1  0.000  0.382  0.913  1.0
  Tm  Tm8  1  0.000  0.882  0.587  1.0
  Tm  Tm9  1  0.000  0.118  0.413  1.0
  In  In10  1  0.500  0.706  0.930  1.0
  In  In11  1  0.500  0.294  0.070  1.0
  In  In12  1  0.500  0.794  0.430  1.0
  In  In13  1  0.500  0.206  0.570  1.0
  In  In14  1  0.500  0.573  0.652  1.0
  In  In15  1  0.500  0.427  0.348  1.0
  In  In16  1  0.500  0.927  0.152  1.0
  In  In17  1  0.500  0.073  0.848  1.0
  Ni  Ni18  1  0.500  0.525  0.195  1.0
  Ni  Ni19  1  0.500  0.475  0.805  1.0
  Ni  Ni20  1  0.500  0.975  0.695  1.0
  Ni  Ni21  1  0.500  0.025  0.305  1.0
[/CIF]
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