The crystal structure described by Rb2CrCl4 crystallizes in the tetragonal I4/mmm space group. Rb(1) is bonded to one Cl(1) and four equivalent Cl(2) atoms to form a mixture of edge and corner-sharing RbCl5 square pyramids. Cr(1) is bonded in a linear geometry to two equivalent Cl(1) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a square co-planar geometry to four equivalent Rb(1) atoms. In the second Cl site, Cl(1) is bonded in a linear geometry to one Rb(1) and one Cr(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Rb2CrCl4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.474
_cell_length_b   11.474
_cell_length_c   11.474
_cell_angle_alpha   147.620
_cell_angle_beta   147.620
_cell_angle_gamma   46.446
_symmetry_Int_Tables_number   1
_cell_volume   431.663
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.273  0.273  0.000  1.0
  Rb  Rb1  1  0.727  0.727  0.000  1.0
  Cr  Cr2  1  0.000  0.000  0.000  1.0
  Cl  Cl3  1  0.103  0.103  0.000  1.0
  Cl  Cl4  1  0.897  0.897  0.000  1.0
  Cl  Cl5  1  0.750  0.250  0.500  1.0
  Cl  Cl6  1  0.250  0.750  0.500  1.0
[/CIF]
.
The crystal structure described by Rb2CrCl4 crystallizes in the tetragonal I4/mmm space group. Rb(1) is bonded to one Cl(1) and four equivalent Cl(2) atoms to form a mixture of edge and corner-sharing RbCl5 square pyramids. Cr(1) is bonded in a linear geometry to two equivalent Cl(1) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a square co-planar geometry to four equivalent Rb(1) atoms. In the second Cl site, Cl(1) is bonded in a linear geometry to one Rb(1) and one Cr(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Rb2CrCl4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.474
_cell_length_b   11.474
_cell_length_c   11.474
_cell_angle_alpha   147.620
_cell_angle_beta   147.620
_cell_angle_gamma   46.446
_symmetry_Int_Tables_number   1
_cell_volume   431.663
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.273  0.273  0.000  1.0
  Rb  Rb1  1  0.727  0.727  0.000  1.0
  Cr  Cr2  1  0.000  0.000  0.000  1.0
  Cl  Cl3  1  0.103  0.103  0.000  1.0
  Cl  Cl4  1  0.897  0.897  0.000  1.0
  Cl  Cl5  1  0.750  0.250  0.500  1.0
  Cl  Cl6  1  0.250  0.750  0.500  1.0
[/CIF]
.