The crystal structure described by HgCl3N3S4 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four HgCl3 clusters and four N3S4 clusters. In each HgCl3 cluster, Hg(1) is bonded in a 3-coordinate geometry to one Cl(1), one Cl(2), and one Cl(3) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Hg(1) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one Hg(1) atom. In the third Cl site, Cl(1) is bonded in a single-bond geometry to one Hg(1) atom. In each N3S4 cluster, there are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to one S(1) and one S(4) atom. In the second N site, N(2) is bonded in a bent 150 degrees geometry to one S(1) and one S(3) atom. In the third N site, N(3) is bonded in a bent 150 degrees geometry to one S(2) and one S(3) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a bent 120 degrees geometry to one N(1) and one N(2) atom. In the second S site, S(2) is bonded in a distorted single-bond geometry to one N(3) atom. In the third S site, S(3) is bonded in a bent 120 degrees geometry to one N(2) and one N(3) atom. In the fourth S site, S(4) is bonded in a distorted single-bond geometry to one N(1) atom. is represented by the CIF card [CIF]
data_HgS4(NCl)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   17.727
_cell_length_b   6.374
_cell_length_c   10.016
_cell_angle_alpha   73.281
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1083.903
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Hg  Hg0  1  0.572  0.211  0.556  1.0
  Hg  Hg1  1  0.428  0.789  0.444  1.0
  Hg  Hg2  1  0.928  0.211  0.056  1.0
  Hg  Hg3  1  0.072  0.789  0.944  1.0
  S  S4  1  0.547  0.701  0.098  1.0
  S  S5  1  0.736  0.656  0.528  1.0
  S  S6  1  0.047  0.299  0.402  1.0
  S  S7  1  0.453  0.299  0.902  1.0
  S  S8  1  0.823  0.926  0.679  1.0
  S  S9  1  0.953  0.701  0.598  1.0
  S  S10  1  0.177  0.074  0.321  1.0
  S  S11  1  0.830  0.500  0.465  1.0
  S  S12  1  0.264  0.344  0.472  1.0
  S  S13  1  0.236  0.344  0.972  1.0
  S  S14  1  0.670  0.500  0.965  1.0
  S  S15  1  0.764  0.656  0.028  1.0
  S  S16  1  0.170  0.500  0.535  1.0
  S  S17  1  0.330  0.500  0.035  1.0
  S  S18  1  0.323  0.074  0.821  1.0
  S  S19  1  0.677  0.926  0.179  1.0
  N  N20  1  0.093  0.433  0.481  1.0
  N  N21  1  0.907  0.567  0.519  1.0
  N  N22  1  0.592  0.861  0.165  1.0
  N  N23  1  0.739  0.820  0.110  1.0
  N  N24  1  0.761  0.820  0.610  1.0
  N  N25  1  0.239  0.180  0.390  1.0
  N  N26  1  0.593  0.567  0.019  1.0
  N  N27  1  0.261  0.180  0.890  1.0
  N  N28  1  0.092  0.139  0.335  1.0
  N  N29  1  0.407  0.433  0.981  1.0
  N  N30  1  0.408  0.139  0.835  1.0
  N  N31  1  0.908  0.861  0.665  1.0
  Cl  Cl32  1  0.323  0.662  0.628  1.0
  Cl  Cl33  1  0.452  0.275  0.432  1.0
  Cl  Cl34  1  0.876  0.116  0.289  1.0
  Cl  Cl35  1  0.952  0.725  0.068  1.0
  Cl  Cl36  1  0.677  0.338  0.372  1.0
  Cl  Cl37  1  0.124  0.884  0.711  1.0
  Cl  Cl38  1  0.048  0.275  0.932  1.0
  Cl  Cl39  1  0.177  0.662  0.128  1.0
  Cl  Cl40  1  0.548  0.725  0.568  1.0
  Cl  Cl41  1  0.823  0.338  0.872  1.0
  Cl  Cl42  1  0.376  0.884  0.211  1.0
  Cl  Cl43  1  0.624  0.116  0.789  1.0
[/CIF]
.
The crystal structure described by HgCl3N3S4 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four HgCl3 clusters and four N3S4 clusters. In each HgCl3 cluster, Hg(1) is bonded in a 3-coordinate geometry to one Cl(1), one Cl(2), and one Cl(3) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Hg(1) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one Hg(1) atom. In the third Cl site, Cl(1) is bonded in a single-bond geometry to one Hg(1) atom. In each N3S4 cluster, there are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to one S(1) and one S(4) atom. In the second N site, N(2) is bonded in a bent 150 degrees geometry to one S(1) and one S(3) atom. In the third N site, N(3) is bonded in a bent 150 degrees geometry to one S(2) and one S(3) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a bent 120 degrees geometry to one N(1) and one N(2) atom. In the second S site, S(2) is bonded in a distorted single-bond geometry to one N(3) atom. In the third S site, S(3) is bonded in a bent 120 degrees geometry to one N(2) and one N(3) atom. In the fourth S site, S(4) is bonded in a distorted single-bond geometry to one N(1) atom. is represented by the CIF card [CIF]
data_HgS4(NCl)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   17.727
_cell_length_b   6.374
_cell_length_c   10.016
_cell_angle_alpha   73.281
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1083.903
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Hg  Hg0  1  0.572  0.211  0.556  1.0
  Hg  Hg1  1  0.428  0.789  0.444  1.0
  Hg  Hg2  1  0.928  0.211  0.056  1.0
  Hg  Hg3  1  0.072  0.789  0.944  1.0
  S  S4  1  0.547  0.701  0.098  1.0
  S  S5  1  0.736  0.656  0.528  1.0
  S  S6  1  0.047  0.299  0.402  1.0
  S  S7  1  0.453  0.299  0.902  1.0
  S  S8  1  0.823  0.926  0.679  1.0
  S  S9  1  0.953  0.701  0.598  1.0
  S  S10  1  0.177  0.074  0.321  1.0
  S  S11  1  0.830  0.500  0.465  1.0
  S  S12  1  0.264  0.344  0.472  1.0
  S  S13  1  0.236  0.344  0.972  1.0
  S  S14  1  0.670  0.500  0.965  1.0
  S  S15  1  0.764  0.656  0.028  1.0
  S  S16  1  0.170  0.500  0.535  1.0
  S  S17  1  0.330  0.500  0.035  1.0
  S  S18  1  0.323  0.074  0.821  1.0
  S  S19  1  0.677  0.926  0.179  1.0
  N  N20  1  0.093  0.433  0.481  1.0
  N  N21  1  0.907  0.567  0.519  1.0
  N  N22  1  0.592  0.861  0.165  1.0
  N  N23  1  0.739  0.820  0.110  1.0
  N  N24  1  0.761  0.820  0.610  1.0
  N  N25  1  0.239  0.180  0.390  1.0
  N  N26  1  0.593  0.567  0.019  1.0
  N  N27  1  0.261  0.180  0.890  1.0
  N  N28  1  0.092  0.139  0.335  1.0
  N  N29  1  0.407  0.433  0.981  1.0
  N  N30  1  0.408  0.139  0.835  1.0
  N  N31  1  0.908  0.861  0.665  1.0
  Cl  Cl32  1  0.323  0.662  0.628  1.0
  Cl  Cl33  1  0.452  0.275  0.432  1.0
  Cl  Cl34  1  0.876  0.116  0.289  1.0
  Cl  Cl35  1  0.952  0.725  0.068  1.0
  Cl  Cl36  1  0.677  0.338  0.372  1.0
  Cl  Cl37  1  0.124  0.884  0.711  1.0
  Cl  Cl38  1  0.048  0.275  0.932  1.0
  Cl  Cl39  1  0.177  0.662  0.128  1.0
  Cl  Cl40  1  0.548  0.725  0.568  1.0
  Cl  Cl41  1  0.823  0.338  0.872  1.0
  Cl  Cl42  1  0.376  0.884  0.211  1.0
  Cl  Cl43  1  0.624  0.116  0.789  1.0
[/CIF]
.