The structure described by CoZnP2(HO)10H2O crystallizes in the triclinic P-1 space group. The structure consists of two water molecules inside a CoZnP2(HO)10 framework. In the CoZnP2(HO)10 framework, there are two inequivalent Co sites. In the first Co site, Co(1) is bonded to two equivalent O(3), two equivalent O(7), and two equivalent O(8) atoms to form CoO6 octahedra that share corners with two equivalent P(1)HO3 tetrahedra. In the second Co site, Co(2) is bonded to two equivalent O(10), two equivalent O(4), and two equivalent O(9) atoms to form CoO6 octahedra that share corners with two equivalent P(2)HO3 tetrahedra. Zn(1) is bonded to one O(1), one O(2), one O(5), and one O(6) atom to form ZnO4 tetrahedra that share corners with two equivalent P(1)HO3 tetrahedra and corners with two equivalent P(2)HO3 tetrahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to one H(1), one O(1), one O(2), and one O(3) atom to form distorted PHO3 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra and corners with two equivalent Zn(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 33°. In the second P site, P(2) is bonded to one H(2), one O(4), one O(5), and one O(6) atom to form distorted PHO3 tetrahedra that share  a cornercorner with one Co(2)O6 octahedra and corners with two equivalent Zn(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 35°. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one P(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one P(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(6) and one O(7) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(7) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(8) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(8) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(9) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one O(9) atom. In the ninth H site, H(9) is bonded in a distorted single-bond geometry to one O(10) and one O(2) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one O(10) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Zn(1) and one P(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Zn(1), one P(1), and one H(9) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Co(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Co(2) and one P(2) atom. In the fifth O site, O(5) is bonded in a 2-coordinate geometry to one Zn(1) and one P(2) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Zn(1), one P(2), and one H(3) atom. In the seventh O site, O(7) is bonded in a distorted water-like geometry to one Co(1), one H(3), and one H(4) atom. In the eighth O site, O(8) is bonded in a distorted water-like geometry to one Co(1), one H(5), and one H(6) atom. In the ninth O site, O(9) is bonded in a distorted water-like geometry to one Co(2), one H(7), and one H(8) atom. In the tenth O site, O(10) is bonded in a distorted water-like geometry to one Co(2), one H(10), and one H(9) atom. is represented by the CIF card [CIF]
data_ZnCoP2H12O11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.586
_cell_length_b   7.711
_cell_length_c   9.529
_cell_angle_alpha   88.879
_cell_angle_beta   88.934
_cell_angle_gamma   87.620
_symmetry_Int_Tables_number   1
_cell_volume   556.728
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.999  0.496  0.249  1.0
  Zn  Zn1  1  0.001  0.504  0.751  1.0
  Co  Co2  1  0.500  0.500  0.500  1.0
  Co  Co3  1  0.000  0.000  0.000  1.0
  P  P4  1  0.125  0.277  0.492  1.0
  P  P5  1  0.875  0.723  0.508  1.0
  P  P6  1  0.228  0.613  0.986  1.0
  P  P7  1  0.772  0.387  0.014  1.0
  H  H8  1  0.209  0.110  0.488  1.0
  H  H9  1  0.791  0.890  0.512  1.0
  H  H10  1  0.400  0.677  0.972  1.0
  H  H11  1  0.600  0.323  0.028  1.0
  H  H12  1  0.389  0.593  0.243  1.0
  H  H13  1  0.611  0.407  0.757  1.0
  H  H14  1  0.598  0.581  0.234  1.0
  H  H15  1  0.402  0.419  0.766  1.0
  H  H16  1  0.753  0.267  0.406  1.0
  H  H17  1  0.247  0.733  0.594  1.0
  H  H18  1  0.575  0.186  0.357  1.0
  H  H19  1  0.425  0.814  0.643  1.0
  H  H20  1  0.663  0.937  0.108  1.0
  H  H21  1  0.337  0.063  0.892  1.0
  H  H22  1  0.765  0.762  0.065  1.0
  H  H23  1  0.235  0.238  0.935  1.0
  H  H24  1  0.961  0.119  0.728  1.0
  H  H25  1  0.039  0.881  0.272  1.0
  H  H26  1  0.959  0.913  0.737  1.0
  H  H27  1  0.041  0.087  0.263  1.0
  H  H28  1  0.375  0.023  0.207  1.0
  H  H29  1  0.625  0.977  0.793  1.0
  H  H30  1  0.491  0.891  0.292  1.0
  H  H31  1  0.509  0.109  0.708  1.0
  O  O32  1  0.989  0.279  0.369  1.0
  O  O33  1  0.011  0.721  0.631  1.0
  O  O34  1  0.035  0.289  0.638  1.0
  O  O35  1  0.965  0.711  0.362  1.0
  O  O36  1  0.257  0.415  0.462  1.0
  O  O37  1  0.743  0.585  0.538  1.0
  O  O38  1  0.092  0.756  0.952  1.0
  O  O39  1  0.908  0.244  0.048  1.0
  O  O40  1  0.218  0.467  0.875  1.0
  O  O41  1  0.782  0.533  0.125  1.0
  O  O42  1  0.218  0.539  0.138  1.0
  O  O43  1  0.782  0.461  0.862  1.0
  O  O44  1  0.497  0.623  0.294  1.0
  O  O45  1  0.503  0.377  0.706  1.0
  O  O46  1  0.624  0.263  0.426  1.0
  O  O47  1  0.376  0.737  0.574  1.0
  O  O48  1  0.749  0.886  0.039  1.0
  O  O49  1  0.251  0.114  0.961  1.0
  O  O50  1  0.917  0.019  0.786  1.0
  O  O51  1  0.083  0.981  0.214  1.0
  O  O52  1  0.495  0.006  0.246  1.0
  O  O53  1  0.505  0.994  0.754  1.0
[/CIF]
.
The structure described by CoZnP2(HO)10H2O crystallizes in the triclinic P-1 space group. The structure consists of two water molecules inside a CoZnP2(HO)10 framework. In the CoZnP2(HO)10 framework, there are two inequivalent Co sites. In the first Co site, Co(1) is bonded to two equivalent O(3), two equivalent O(7), and two equivalent O(8) atoms to form CoO6 octahedra that share corners with two equivalent P(1)HO3 tetrahedra. In the second Co site, Co(2) is bonded to two equivalent O(10), two equivalent O(4), and two equivalent O(9) atoms to form CoO6 octahedra that share corners with two equivalent P(2)HO3 tetrahedra. Zn(1) is bonded to one O(1), one O(2), one O(5), and one O(6) atom to form ZnO4 tetrahedra that share corners with two equivalent P(1)HO3 tetrahedra and corners with two equivalent P(2)HO3 tetrahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to one H(1), one O(1), one O(2), and one O(3) atom to form distorted PHO3 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra and corners with two equivalent Zn(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 33°. In the second P site, P(2) is bonded to one H(2), one O(4), one O(5), and one O(6) atom to form distorted PHO3 tetrahedra that share  a cornercorner with one Co(2)O6 octahedra and corners with two equivalent Zn(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 35°. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one P(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one P(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(6) and one O(7) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(7) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(8) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(8) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(9) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one O(9) atom. In the ninth H site, H(9) is bonded in a distorted single-bond geometry to one O(10) and one O(2) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one O(10) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Zn(1) and one P(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Zn(1), one P(1), and one H(9) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Co(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Co(2) and one P(2) atom. In the fifth O site, O(5) is bonded in a 2-coordinate geometry to one Zn(1) and one P(2) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Zn(1), one P(2), and one H(3) atom. In the seventh O site, O(7) is bonded in a distorted water-like geometry to one Co(1), one H(3), and one H(4) atom. In the eighth O site, O(8) is bonded in a distorted water-like geometry to one Co(1), one H(5), and one H(6) atom. In the ninth O site, O(9) is bonded in a distorted water-like geometry to one Co(2), one H(7), and one H(8) atom. In the tenth O site, O(10) is bonded in a distorted water-like geometry to one Co(2), one H(10), and one H(9) atom. is represented by the CIF card [CIF]
data_ZnCoP2H12O11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.586
_cell_length_b   7.711
_cell_length_c   9.529
_cell_angle_alpha   88.879
_cell_angle_beta   88.934
_cell_angle_gamma   87.620
_symmetry_Int_Tables_number   1
_cell_volume   556.728
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.999  0.496  0.249  1.0
  Zn  Zn1  1  0.001  0.504  0.751  1.0
  Co  Co2  1  0.500  0.500  0.500  1.0
  Co  Co3  1  0.000  0.000  0.000  1.0
  P  P4  1  0.125  0.277  0.492  1.0
  P  P5  1  0.875  0.723  0.508  1.0
  P  P6  1  0.228  0.613  0.986  1.0
  P  P7  1  0.772  0.387  0.014  1.0
  H  H8  1  0.209  0.110  0.488  1.0
  H  H9  1  0.791  0.890  0.512  1.0
  H  H10  1  0.400  0.677  0.972  1.0
  H  H11  1  0.600  0.323  0.028  1.0
  H  H12  1  0.389  0.593  0.243  1.0
  H  H13  1  0.611  0.407  0.757  1.0
  H  H14  1  0.598  0.581  0.234  1.0
  H  H15  1  0.402  0.419  0.766  1.0
  H  H16  1  0.753  0.267  0.406  1.0
  H  H17  1  0.247  0.733  0.594  1.0
  H  H18  1  0.575  0.186  0.357  1.0
  H  H19  1  0.425  0.814  0.643  1.0
  H  H20  1  0.663  0.937  0.108  1.0
  H  H21  1  0.337  0.063  0.892  1.0
  H  H22  1  0.765  0.762  0.065  1.0
  H  H23  1  0.235  0.238  0.935  1.0
  H  H24  1  0.961  0.119  0.728  1.0
  H  H25  1  0.039  0.881  0.272  1.0
  H  H26  1  0.959  0.913  0.737  1.0
  H  H27  1  0.041  0.087  0.263  1.0
  H  H28  1  0.375  0.023  0.207  1.0
  H  H29  1  0.625  0.977  0.793  1.0
  H  H30  1  0.491  0.891  0.292  1.0
  H  H31  1  0.509  0.109  0.708  1.0
  O  O32  1  0.989  0.279  0.369  1.0
  O  O33  1  0.011  0.721  0.631  1.0
  O  O34  1  0.035  0.289  0.638  1.0
  O  O35  1  0.965  0.711  0.362  1.0
  O  O36  1  0.257  0.415  0.462  1.0
  O  O37  1  0.743  0.585  0.538  1.0
  O  O38  1  0.092  0.756  0.952  1.0
  O  O39  1  0.908  0.244  0.048  1.0
  O  O40  1  0.218  0.467  0.875  1.0
  O  O41  1  0.782  0.533  0.125  1.0
  O  O42  1  0.218  0.539  0.138  1.0
  O  O43  1  0.782  0.461  0.862  1.0
  O  O44  1  0.497  0.623  0.294  1.0
  O  O45  1  0.503  0.377  0.706  1.0
  O  O46  1  0.624  0.263  0.426  1.0
  O  O47  1  0.376  0.737  0.574  1.0
  O  O48  1  0.749  0.886  0.039  1.0
  O  O49  1  0.251  0.114  0.961  1.0
  O  O50  1  0.917  0.019  0.786  1.0
  O  O51  1  0.083  0.981  0.214  1.0
  O  O52  1  0.495  0.006  0.246  1.0
  O  O53  1  0.505  0.994  0.754  1.0
[/CIF]
.