The compound described by LiCo2OF5 is Hydrophilite-derived structured and crystallizes in the monoclinic Cc space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one F(1), one F(10), one F(3), one F(6), and one F(9) atom to form LiOF5 octahedra that share corners with four equivalent Co(3)OF5 octahedra, corners with four equivalent Co(4)OF5 octahedra,  an edgeedge with one Co(1)OF5 octahedra, and  an edgeedge with one Co(2)OF5 octahedra. The corner-sharing octahedral tilt angles range from 47-56°. In the second Li site, Li(2) is bonded to one O(2), one F(2), one F(4), one F(5), one F(7), and one F(8) atom to form LiOF5 octahedra that share corners with four equivalent Co(1)OF5 octahedra, corners with four equivalent Co(2)OF5 octahedra,  an edgeedge with one Co(3)OF5 octahedra, and  an edgeedge with one Co(4)OF5 octahedra. The corner-sharing octahedral tilt angles range from 48-56°. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one F(10), one F(2), one F(5), one F(7), and one F(8) atom to form CoOF5 octahedra that share corners with four equivalent Li(2)OF5 octahedra, corners with four equivalent Co(4)OF5 octahedra,  an edgeedge with one Li(1)OF5 octahedra, and  an edgeedge with one Co(2)OF5 octahedra. The corner-sharing octahedral tilt angles range from 42-50°. In the second Co site, Co(2) is bonded to one O(2), one F(1), one F(2), one F(4), one F(8), and one F(9) atom to form CoOF5 octahedra that share corners with four equivalent Li(2)OF5 octahedra, corners with four equivalent Co(3)OF5 octahedra,  an edgeedge with one Li(1)OF5 octahedra, and  an edgeedge with one Co(1)OF5 octahedra. The corner-sharing octahedral tilt angles range from 42-56°. In the third Co site, Co(3) is bonded to one O(2), one F(1), one F(3), one F(4), one F(6), and one F(9) atom to form CoOF5 octahedra that share corners with four equivalent Li(1)OF5 octahedra, corners with four equivalent Co(2)OF5 octahedra,  an edgeedge with one Li(2)OF5 octahedra, and  an edgeedge with one Co(4)OF5 octahedra. The corner-sharing octahedral tilt angles range from 42-52°. In the fourth Co site, Co(4) is bonded to one O(1), one F(10), one F(3), one F(5), one F(6), and one F(7) atom to form CoOF5 octahedra that share corners with four equivalent Li(1)OF5 octahedra, corners with four equivalent Co(1)OF5 octahedra,  an edgeedge with one Li(2)OF5 octahedra, and  an edgeedge with one Co(3)OF5 octahedra. The corner-sharing octahedral tilt angles range from 42-56°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Li(1), one Co(1), and one Co(4) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Li(2), one Co(2), and one Co(3) atom. There are ten inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one Li(1), one Co(2), and one Co(3) atom. In the second F site, F(2) is bonded in a trigonal planar geometry to one Li(2), one Co(1), and one Co(2) atom. In the third F site, F(3) is bonded in a trigonal planar geometry to one Li(1), one Co(3), and one Co(4) atom. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one Li(2), one Co(2), and one Co(3) atom. In the fifth F site, F(5) is bonded in a distorted trigonal planar geometry to one Li(2), one Co(1), and one Co(4) atom. In the sixth F site, F(6) is bonded in a trigonal planar geometry to one Li(1), one Co(3), and one Co(4) atom. In the seventh F site, F(7) is bonded in a distorted trigonal planar geometry to one Li(2), one Co(1), and one Co(4) atom. In the eighth F site, F(8) is bonded in a trigonal planar geometry to one Li(2), one Co(1), and one Co(2) atom. In the ninth F site, F(9) is bonded in a distorted trigonal planar geometry to one Li(1), one Co(2), and one Co(3) atom. In the tenth F site, F(10) is bonded in a distorted trigonal planar geometry to one Li(1), one Co(1), and one Co(4) atom. is represented by the CIF file [CIF]
data_LiCo2OF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.579
_cell_length_b   4.579
_cell_length_c   18.368
_cell_angle_alpha   89.242
_cell_angle_beta   89.242
_cell_angle_gamma   89.945
_symmetry_Int_Tables_number   1
_cell_volume   385.008
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.994  0.986  1.000  1.0
  Li  Li1  1  0.986  0.994  0.500  1.0
  Li  Li2  1  0.496  0.514  0.750  1.0
  Li  Li3  1  0.514  0.496  0.250  1.0
  Co  Co4  1  0.008  0.010  0.664  1.0
  Co  Co5  1  0.977  0.029  0.833  1.0
  Co  Co6  1  0.029  0.977  0.333  1.0
  Co  Co7  1  0.010  0.008  0.164  1.0
  Co  Co8  1  0.491  0.507  0.414  1.0
  Co  Co9  1  0.507  0.491  0.914  1.0
  Co  Co10  1  0.474  0.478  0.583  1.0
  Co  Co11  1  0.478  0.474  0.083  1.0
  O  O12  1  0.203  0.206  0.591  1.0
  O  O13  1  0.206  0.203  0.091  1.0
  O  O14  1  0.300  0.706  0.341  1.0
  O  O15  1  0.706  0.300  0.841  1.0
  F  F16  1  0.209  0.200  0.916  1.0
  F  F17  1  0.198  0.201  0.749  1.0
  F  F18  1  0.200  0.209  0.416  1.0
  F  F19  1  0.201  0.198  0.249  1.0
  F  F20  1  0.313  0.684  0.995  1.0
  F  F21  1  0.292  0.714  0.835  1.0
  F  F22  1  0.300  0.709  0.166  1.0
  F  F23  1  0.300  0.698  0.500  1.0
  F  F24  1  0.297  0.711  0.666  1.0
  F  F25  1  0.698  0.300  1.000  1.0
  F  F26  1  0.709  0.300  0.666  1.0
  F  F27  1  0.684  0.313  0.495  1.0
  F  F28  1  0.711  0.297  0.166  1.0
  F  F29  1  0.714  0.292  0.335  1.0
  F  F30  1  0.814  0.817  0.746  1.0
  F  F31  1  0.799  0.788  0.915  1.0
  F  F32  1  0.787  0.791  0.586  1.0
  F  F33  1  0.788  0.799  0.415  1.0
  F  F34  1  0.817  0.814  0.246  1.0
  F  F35  1  0.791  0.787  0.086  1.0
[/CIF]
.
The compound described by LiCo2OF5 is Hydrophilite-derived structured and crystallizes in the monoclinic Cc space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one F(1), one F(10), one F(3), one F(6), and one F(9) atom to form LiOF5 octahedra that share corners with four equivalent Co(3)OF5 octahedra, corners with four equivalent Co(4)OF5 octahedra,  an edgeedge with one Co(1)OF5 octahedra, and  an edgeedge with one Co(2)OF5 octahedra. The corner-sharing octahedral tilt angles range from 47-56°. In the second Li site, Li(2) is bonded to one O(2), one F(2), one F(4), one F(5), one F(7), and one F(8) atom to form LiOF5 octahedra that share corners with four equivalent Co(1)OF5 octahedra, corners with four equivalent Co(2)OF5 octahedra,  an edgeedge with one Co(3)OF5 octahedra, and  an edgeedge with one Co(4)OF5 octahedra. The corner-sharing octahedral tilt angles range from 48-56°. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one F(10), one F(2), one F(5), one F(7), and one F(8) atom to form CoOF5 octahedra that share corners with four equivalent Li(2)OF5 octahedra, corners with four equivalent Co(4)OF5 octahedra,  an edgeedge with one Li(1)OF5 octahedra, and  an edgeedge with one Co(2)OF5 octahedra. The corner-sharing octahedral tilt angles range from 42-50°. In the second Co site, Co(2) is bonded to one O(2), one F(1), one F(2), one F(4), one F(8), and one F(9) atom to form CoOF5 octahedra that share corners with four equivalent Li(2)OF5 octahedra, corners with four equivalent Co(3)OF5 octahedra,  an edgeedge with one Li(1)OF5 octahedra, and  an edgeedge with one Co(1)OF5 octahedra. The corner-sharing octahedral tilt angles range from 42-56°. In the third Co site, Co(3) is bonded to one O(2), one F(1), one F(3), one F(4), one F(6), and one F(9) atom to form CoOF5 octahedra that share corners with four equivalent Li(1)OF5 octahedra, corners with four equivalent Co(2)OF5 octahedra,  an edgeedge with one Li(2)OF5 octahedra, and  an edgeedge with one Co(4)OF5 octahedra. The corner-sharing octahedral tilt angles range from 42-52°. In the fourth Co site, Co(4) is bonded to one O(1), one F(10), one F(3), one F(5), one F(6), and one F(7) atom to form CoOF5 octahedra that share corners with four equivalent Li(1)OF5 octahedra, corners with four equivalent Co(1)OF5 octahedra,  an edgeedge with one Li(2)OF5 octahedra, and  an edgeedge with one Co(3)OF5 octahedra. The corner-sharing octahedral tilt angles range from 42-56°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Li(1), one Co(1), and one Co(4) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Li(2), one Co(2), and one Co(3) atom. There are ten inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one Li(1), one Co(2), and one Co(3) atom. In the second F site, F(2) is bonded in a trigonal planar geometry to one Li(2), one Co(1), and one Co(2) atom. In the third F site, F(3) is bonded in a trigonal planar geometry to one Li(1), one Co(3), and one Co(4) atom. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one Li(2), one Co(2), and one Co(3) atom. In the fifth F site, F(5) is bonded in a distorted trigonal planar geometry to one Li(2), one Co(1), and one Co(4) atom. In the sixth F site, F(6) is bonded in a trigonal planar geometry to one Li(1), one Co(3), and one Co(4) atom. In the seventh F site, F(7) is bonded in a distorted trigonal planar geometry to one Li(2), one Co(1), and one Co(4) atom. In the eighth F site, F(8) is bonded in a trigonal planar geometry to one Li(2), one Co(1), and one Co(2) atom. In the ninth F site, F(9) is bonded in a distorted trigonal planar geometry to one Li(1), one Co(2), and one Co(3) atom. In the tenth F site, F(10) is bonded in a distorted trigonal planar geometry to one Li(1), one Co(1), and one Co(4) atom. is represented by the CIF file [CIF]
data_LiCo2OF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.579
_cell_length_b   4.579
_cell_length_c   18.368
_cell_angle_alpha   89.242
_cell_angle_beta   89.242
_cell_angle_gamma   89.945
_symmetry_Int_Tables_number   1
_cell_volume   385.008
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.994  0.986  1.000  1.0
  Li  Li1  1  0.986  0.994  0.500  1.0
  Li  Li2  1  0.496  0.514  0.750  1.0
  Li  Li3  1  0.514  0.496  0.250  1.0
  Co  Co4  1  0.008  0.010  0.664  1.0
  Co  Co5  1  0.977  0.029  0.833  1.0
  Co  Co6  1  0.029  0.977  0.333  1.0
  Co  Co7  1  0.010  0.008  0.164  1.0
  Co  Co8  1  0.491  0.507  0.414  1.0
  Co  Co9  1  0.507  0.491  0.914  1.0
  Co  Co10  1  0.474  0.478  0.583  1.0
  Co  Co11  1  0.478  0.474  0.083  1.0
  O  O12  1  0.203  0.206  0.591  1.0
  O  O13  1  0.206  0.203  0.091  1.0
  O  O14  1  0.300  0.706  0.341  1.0
  O  O15  1  0.706  0.300  0.841  1.0
  F  F16  1  0.209  0.200  0.916  1.0
  F  F17  1  0.198  0.201  0.749  1.0
  F  F18  1  0.200  0.209  0.416  1.0
  F  F19  1  0.201  0.198  0.249  1.0
  F  F20  1  0.313  0.684  0.995  1.0
  F  F21  1  0.292  0.714  0.835  1.0
  F  F22  1  0.300  0.709  0.166  1.0
  F  F23  1  0.300  0.698  0.500  1.0
  F  F24  1  0.297  0.711  0.666  1.0
  F  F25  1  0.698  0.300  1.000  1.0
  F  F26  1  0.709  0.300  0.666  1.0
  F  F27  1  0.684  0.313  0.495  1.0
  F  F28  1  0.711  0.297  0.166  1.0
  F  F29  1  0.714  0.292  0.335  1.0
  F  F30  1  0.814  0.817  0.746  1.0
  F  F31  1  0.799  0.788  0.915  1.0
  F  F32  1  0.787  0.791  0.586  1.0
  F  F33  1  0.788  0.799  0.415  1.0
  F  F34  1  0.817  0.814  0.246  1.0
  F  F35  1  0.791  0.787  0.086  1.0
[/CIF]
.