The material structure described by K4MoC4(N2O)2 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 6-coordinate geometry to one C(2), one N(1), two equivalent N(2), and two equivalent O(1) atoms. In the second K site, K(2) is bonded in a 4-coordinate geometry to one N(2), two equivalent N(1), and one O(1) atom. Mo(1) is bonded in a distorted octahedral geometry to two equivalent C(1), two equivalent C(2), and two equivalent O(1) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one Mo(1) and one N(1) atom. In the second C site, C(2) is bonded in a 1-coordinate geometry to one K(1), one Mo(1), and one N(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 4-coordinate geometry to one K(1), two equivalent K(2), and one C(1) atom. In the second N site, N(2) is bonded in a 3-coordinate geometry to one K(2), two equivalent K(1), and one C(2) atom. O(1) is bonded in a distorted rectangular see-saw-like geometry to one K(2), two equivalent K(1), and one Mo(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_K4MoC4(N2O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.583
_cell_length_b   8.317
_cell_length_c   12.355
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   106.510
_symmetry_Int_Tables_number   1
_cell_volume   648.588
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.075  0.740  0.467  1.0
  K  K1  1  0.925  0.260  0.533  1.0
  K  K2  1  0.425  0.760  0.967  1.0
  K  K3  1  0.575  0.240  0.033  1.0
  K  K4  1  0.146  0.504  0.223  1.0
  K  K5  1  0.854  0.496  0.777  1.0
  K  K6  1  0.354  0.996  0.723  1.0
  K  K7  1  0.646  0.004  0.277  1.0
  Mo  Mo8  1  0.000  0.000  0.000  1.0
  Mo  Mo9  1  0.500  0.500  0.500  1.0
  C  C10  1  0.645  0.428  0.351  1.0
  C  C11  1  0.355  0.572  0.649  1.0
  C  C12  1  0.855  0.072  0.851  1.0
  C  C13  1  0.145  0.928  0.149  1.0
  C  C14  1  0.865  0.724  0.987  1.0
  C  C15  1  0.135  0.276  0.013  1.0
  C  C16  1  0.635  0.776  0.487  1.0
  C  C17  1  0.365  0.224  0.513  1.0
  N  N18  1  0.714  0.367  0.278  1.0
  N  N19  1  0.286  0.633  0.722  1.0
  N  N20  1  0.786  0.133  0.778  1.0
  N  N21  1  0.214  0.867  0.222  1.0
  N  N22  1  0.783  0.578  0.990  1.0
  N  N23  1  0.217  0.422  0.010  1.0
  N  N24  1  0.717  0.922  0.490  1.0
  N  N25  1  0.283  0.078  0.510  1.0
  O  O26  1  0.745  0.498  0.576  1.0
  O  O27  1  0.255  0.502  0.424  1.0
  O  O28  1  0.755  0.002  0.076  1.0
  O  O29  1  0.245  0.998  0.924  1.0
[/CIF]
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The material structure described by K4MoC4(N2O)2 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 6-coordinate geometry to one C(2), one N(1), two equivalent N(2), and two equivalent O(1) atoms. In the second K site, K(2) is bonded in a 4-coordinate geometry to one N(2), two equivalent N(1), and one O(1) atom. Mo(1) is bonded in a distorted octahedral geometry to two equivalent C(1), two equivalent C(2), and two equivalent O(1) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one Mo(1) and one N(1) atom. In the second C site, C(2) is bonded in a 1-coordinate geometry to one K(1), one Mo(1), and one N(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 4-coordinate geometry to one K(1), two equivalent K(2), and one C(1) atom. In the second N site, N(2) is bonded in a 3-coordinate geometry to one K(2), two equivalent K(1), and one C(2) atom. O(1) is bonded in a distorted rectangular see-saw-like geometry to one K(2), two equivalent K(1), and one Mo(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_K4MoC4(N2O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.583
_cell_length_b   8.317
_cell_length_c   12.355
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   106.510
_symmetry_Int_Tables_number   1
_cell_volume   648.588
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.075  0.740  0.467  1.0
  K  K1  1  0.925  0.260  0.533  1.0
  K  K2  1  0.425  0.760  0.967  1.0
  K  K3  1  0.575  0.240  0.033  1.0
  K  K4  1  0.146  0.504  0.223  1.0
  K  K5  1  0.854  0.496  0.777  1.0
  K  K6  1  0.354  0.996  0.723  1.0
  K  K7  1  0.646  0.004  0.277  1.0
  Mo  Mo8  1  0.000  0.000  0.000  1.0
  Mo  Mo9  1  0.500  0.500  0.500  1.0
  C  C10  1  0.645  0.428  0.351  1.0
  C  C11  1  0.355  0.572  0.649  1.0
  C  C12  1  0.855  0.072  0.851  1.0
  C  C13  1  0.145  0.928  0.149  1.0
  C  C14  1  0.865  0.724  0.987  1.0
  C  C15  1  0.135  0.276  0.013  1.0
  C  C16  1  0.635  0.776  0.487  1.0
  C  C17  1  0.365  0.224  0.513  1.0
  N  N18  1  0.714  0.367  0.278  1.0
  N  N19  1  0.286  0.633  0.722  1.0
  N  N20  1  0.786  0.133  0.778  1.0
  N  N21  1  0.214  0.867  0.222  1.0
  N  N22  1  0.783  0.578  0.990  1.0
  N  N23  1  0.217  0.422  0.010  1.0
  N  N24  1  0.717  0.922  0.490  1.0
  N  N25  1  0.283  0.078  0.510  1.0
  O  O26  1  0.745  0.498  0.576  1.0
  O  O27  1  0.255  0.502  0.424  1.0
  O  O28  1  0.755  0.002  0.076  1.0
  O  O29  1  0.245  0.998  0.924  1.0
[/CIF]
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