The structure described by W7(OF5)6 is Protactinium structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one W7(OF5)6 cluster. There are three inequivalent W sites. In the first W site, W(1,3) is bonded to one O(2), one F(1), one F(10), one F(2), one F(3), and one F(8) atom to form corner-sharing WOF5 octahedra. The corner-sharing octahedral tilt angles are 30°. In the second W site, W(2) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 29-30°. In the third W site, W(4) is bonded to one O(3), one F(14), one F(15), one F(6), one F(7), and one F(9) atom to form corner-sharing WOF5 octahedra. The corner-sharing octahedral tilt angles are 29°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one W(1,3) and one W(2) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one W(1,3) and one W(2) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one W(2) and one W(4) atom. There are fifteen inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one W(1,3) atom. In the second F site, F(2) is bonded in a single-bond geometry to one W(1,3) atom. In the third F site, F(3) is bonded in a single-bond geometry to one W(1,3) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one W(1,3) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one W(1,3) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one W(4) atom. In the seventh F site, F(7) is bonded in a single-bond geometry to one W(4) atom. In the eighth F site, F(8) is bonded in a single-bond geometry to one W(1,3) atom. In the ninth F site, F(9) is bonded in a single-bond geometry to one W(4) atom. In the tenth F site, F(10) is bonded in a single-bond geometry to one W(1,3) atom. In the eleventh F site, F(11) is bonded in a single-bond geometry to one W(1,3) atom. In the twelfth F site, F(12) is bonded in a single-bond geometry to one W(1,3) atom. In the thirteenth F site, F(13) is bonded in a single-bond geometry to one W(1,3) atom. In the fourteenth F site, F(14) is bonded in a single-bond geometry to one W(4) atom. In the fifteenth F site, F(15) is bonded in a single-bond geometry to one W(4) atom. is represented by the CIF file [CIF]
data_W7(OF5)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.279
_cell_length_b   9.491
_cell_length_c   9.532
_cell_angle_alpha   115.506
_cell_angle_beta   100.213
_cell_angle_gamma   99.910
_symmetry_Int_Tables_number   1
_cell_volume   715.844
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  W  W0  1  0.245  0.076  0.395  1.0
  W  W1  1  0.000  0.000  0.000  1.0
  W  W2  1  0.772  0.242  0.241  1.0
  W  W3  1  0.752  0.603  0.916  1.0
  W  W4  1  0.248  0.397  0.084  1.0
  W  W5  1  0.228  0.758  0.759  1.0
  W  W6  1  0.755  0.924  0.605  1.0
  O  O7  1  0.882  0.088  0.149  1.0
  O  O8  1  0.169  0.047  0.181  1.0
  O  O9  1  0.920  0.786  0.977  1.0
  O  O10  1  0.080  0.214  0.023  1.0
  O  O11  1  0.831  0.953  0.819  1.0
  O  O12  1  0.118  0.912  0.851  1.0
  F  F13  1  0.940  0.077  0.648  1.0
  F  F14  1  0.662  0.093  0.680  1.0
  F  F15  1  0.301  0.099  0.604  1.0
  F  F16  1  0.592  0.075  0.171  1.0
  F  F17  1  0.819  0.242  0.441  1.0
  F  F18  1  0.870  0.456  0.861  1.0
  F  F19  1  0.203  0.371  0.872  1.0
  F  F20  1  0.429  0.226  0.437  1.0
  F  F21  1  0.575  0.434  0.853  1.0
  F  F22  1  0.153  0.246  0.474  1.0
  F  F23  1  0.724  0.244  0.041  1.0
  F  F24  1  0.952  0.411  0.314  1.0
  F  F25  1  0.666  0.399  0.318  1.0
  F  F26  1  0.706  0.573  0.703  1.0
  F  F27  1  0.369  0.250  0.029  1.0
  F  F28  1  0.631  0.750  0.971  1.0
  F  F29  1  0.294  0.427  0.297  1.0
  F  F30  1  0.334  0.601  0.682  1.0
  F  F31  1  0.048  0.589  0.686  1.0
  F  F32  1  0.276  0.756  0.959  1.0
  F  F33  1  0.847  0.754  0.526  1.0
  F  F34  1  0.425  0.566  0.147  1.0
  F  F35  1  0.571  0.774  0.563  1.0
  F  F36  1  0.797  0.629  0.128  1.0
  F  F37  1  0.130  0.544  0.139  1.0
  F  F38  1  0.181  0.758  0.559  1.0
  F  F39  1  0.408  0.925  0.829  1.0
  F  F40  1  0.699  0.901  0.396  1.0
  F  F41  1  0.338  0.907  0.320  1.0
  F  F42  1  0.060  0.923  0.352  1.0
[/CIF]
.
The structure described by W7(OF5)6 is Protactinium structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one W7(OF5)6 cluster. There are three inequivalent W sites. In the first W site, W(1,3) is bonded to one O(2), one F(1), one F(10), one F(2), one F(3), and one F(8) atom to form corner-sharing WOF5 octahedra. The corner-sharing octahedral tilt angles are 30°. In the second W site, W(2) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 29-30°. In the third W site, W(4) is bonded to one O(3), one F(14), one F(15), one F(6), one F(7), and one F(9) atom to form corner-sharing WOF5 octahedra. The corner-sharing octahedral tilt angles are 29°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one W(1,3) and one W(2) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one W(1,3) and one W(2) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one W(2) and one W(4) atom. There are fifteen inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one W(1,3) atom. In the second F site, F(2) is bonded in a single-bond geometry to one W(1,3) atom. In the third F site, F(3) is bonded in a single-bond geometry to one W(1,3) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one W(1,3) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one W(1,3) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one W(4) atom. In the seventh F site, F(7) is bonded in a single-bond geometry to one W(4) atom. In the eighth F site, F(8) is bonded in a single-bond geometry to one W(1,3) atom. In the ninth F site, F(9) is bonded in a single-bond geometry to one W(4) atom. In the tenth F site, F(10) is bonded in a single-bond geometry to one W(1,3) atom. In the eleventh F site, F(11) is bonded in a single-bond geometry to one W(1,3) atom. In the twelfth F site, F(12) is bonded in a single-bond geometry to one W(1,3) atom. In the thirteenth F site, F(13) is bonded in a single-bond geometry to one W(1,3) atom. In the fourteenth F site, F(14) is bonded in a single-bond geometry to one W(4) atom. In the fifteenth F site, F(15) is bonded in a single-bond geometry to one W(4) atom. is represented by the CIF file [CIF]
data_W7(OF5)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.279
_cell_length_b   9.491
_cell_length_c   9.532
_cell_angle_alpha   115.506
_cell_angle_beta   100.213
_cell_angle_gamma   99.910
_symmetry_Int_Tables_number   1
_cell_volume   715.844
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  W  W0  1  0.245  0.076  0.395  1.0
  W  W1  1  0.000  0.000  0.000  1.0
  W  W2  1  0.772  0.242  0.241  1.0
  W  W3  1  0.752  0.603  0.916  1.0
  W  W4  1  0.248  0.397  0.084  1.0
  W  W5  1  0.228  0.758  0.759  1.0
  W  W6  1  0.755  0.924  0.605  1.0
  O  O7  1  0.882  0.088  0.149  1.0
  O  O8  1  0.169  0.047  0.181  1.0
  O  O9  1  0.920  0.786  0.977  1.0
  O  O10  1  0.080  0.214  0.023  1.0
  O  O11  1  0.831  0.953  0.819  1.0
  O  O12  1  0.118  0.912  0.851  1.0
  F  F13  1  0.940  0.077  0.648  1.0
  F  F14  1  0.662  0.093  0.680  1.0
  F  F15  1  0.301  0.099  0.604  1.0
  F  F16  1  0.592  0.075  0.171  1.0
  F  F17  1  0.819  0.242  0.441  1.0
  F  F18  1  0.870  0.456  0.861  1.0
  F  F19  1  0.203  0.371  0.872  1.0
  F  F20  1  0.429  0.226  0.437  1.0
  F  F21  1  0.575  0.434  0.853  1.0
  F  F22  1  0.153  0.246  0.474  1.0
  F  F23  1  0.724  0.244  0.041  1.0
  F  F24  1  0.952  0.411  0.314  1.0
  F  F25  1  0.666  0.399  0.318  1.0
  F  F26  1  0.706  0.573  0.703  1.0
  F  F27  1  0.369  0.250  0.029  1.0
  F  F28  1  0.631  0.750  0.971  1.0
  F  F29  1  0.294  0.427  0.297  1.0
  F  F30  1  0.334  0.601  0.682  1.0
  F  F31  1  0.048  0.589  0.686  1.0
  F  F32  1  0.276  0.756  0.959  1.0
  F  F33  1  0.847  0.754  0.526  1.0
  F  F34  1  0.425  0.566  0.147  1.0
  F  F35  1  0.571  0.774  0.563  1.0
  F  F36  1  0.797  0.629  0.128  1.0
  F  F37  1  0.130  0.544  0.139  1.0
  F  F38  1  0.181  0.758  0.559  1.0
  F  F39  1  0.408  0.925  0.829  1.0
  F  F40  1  0.699  0.901  0.396  1.0
  F  F41  1  0.338  0.907  0.320  1.0
  F  F42  1  0.060  0.923  0.352  1.0
[/CIF]
.