The material described by Li3MnCO3PO4 crystallizes in the monoclinic P2_1/c space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(4), and one O(5) atom. In the second Li site, Li(2) is bonded to one O(2), one O(3), one O(4), one O(6), and one O(7) atom to form distorted LiO5 trigonal bipyramids that share corners with three equivalent P(1)O4 tetrahedra and edges with two equivalent Mn(1)O5 trigonal bipyramids. In the third Li site, Li(3) is bonded in a 6-coordinate geometry to one O(1), one O(3), one O(4), one O(5), one O(6), and one O(7) atom. Mn(1) is bonded to one O(2), one O(3), one O(5), one O(6), and one O(7) atom to form distorted MnO5 trigonal bipyramids that share corners with three equivalent P(1)O4 tetrahedra and edges with two equivalent Li(2)O5 trigonal bipyramids. C(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. P(1) is bonded to one O(4), one O(5), one O(6), and one O(7) atom to form PO4 tetrahedra that share corners with three equivalent Li(2)O5 trigonal bipyramids and corners with three equivalent Mn(1)O5 trigonal bipyramids. There are seven inequivalent O sites. In the first O site, O(6) is bonded to one Li(2), one Li(3), one Mn(1), and one P(1) atom to form distorted OLi2MnP trigonal pyramids that share corners with two equivalent O(2)Li2MnC tetrahedra, corners with four equivalent O(7)Li2MnP tetrahedra,  a cornercorner with one O(5)Li2MnP trigonal pyramid, and  an edgeedge with one O(5)Li2MnP trigonal pyramid. In the second O site, O(7) is bonded to one Li(2), one Li(3), one Mn(1), and one P(1) atom to form OLi2MnP tetrahedra that share corners with three equivalent O(5)Li2MnP trigonal pyramids, corners with four equivalent O(6)Li2MnP trigonal pyramids, and  an edgeedge with one O(2)Li2MnC tetrahedra. In the third O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Li(1), one Li(3), and one C(1) atom. In the fourth O site, O(2) is bonded to one Li(1), one Li(2), one Mn(1), and one C(1) atom to form a mixture of distorted corner and edge-sharing OLi2MnC tetrahedra. In the fifth O site, O(3) is bonded in a 4-coordinate geometry to one Li(2), one Li(3), one Mn(1), and one C(1) atom. In the sixth O site, O(4) is bonded in a 4-coordinate geometry to one Li(1), one Li(2), one Li(3), and one P(1) atom. In the seventh O site, O(5) is bonded to one Li(1), one Li(3), one Mn(1), and one P(1) atom to form distorted OLi2MnP trigonal pyramids that share corners with two equivalent O(2)Li2MnC tetrahedra, corners with three equivalent O(7)Li2MnP tetrahedra,  a cornercorner with one O(6)Li2MnP trigonal pyramid, and  an edgeedge with one O(6)Li2MnP trigonal pyramid. is represented by the CIF card [CIF]
data_Li3MnPCO7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.481
_cell_length_b   8.586
_cell_length_c   9.855
_cell_angle_alpha   85.376
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   546.663
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.748  0.899  0.365  1.0
  Li  Li1  1  0.752  0.899  0.865  1.0
  Li  Li2  1  0.513  0.716  0.633  1.0
  Li  Li3  1  0.987  0.716  0.133  1.0
  Li  Li4  1  0.246  0.649  0.360  1.0
  Li  Li5  1  0.254  0.649  0.860  1.0
  Li  Li6  1  0.754  0.351  0.640  1.0
  Li  Li7  1  0.746  0.351  0.140  1.0
  Li  Li8  1  0.487  0.284  0.367  1.0
  Li  Li9  1  0.013  0.284  0.867  1.0
  Li  Li10  1  0.252  0.101  0.635  1.0
  Li  Li11  1  0.248  0.101  0.135  1.0
  Mn  Mn12  1  0.998  0.729  0.620  1.0
  Mn  Mn13  1  0.502  0.729  0.120  1.0
  Mn  Mn14  1  0.002  0.271  0.380  1.0
  Mn  Mn15  1  0.498  0.271  0.880  1.0
  P  P16  1  0.749  0.593  0.390  1.0
  P  P17  1  0.751  0.593  0.890  1.0
  P  P18  1  0.251  0.407  0.610  1.0
  P  P19  1  0.249  0.407  0.110  1.0
  C  C20  1  0.248  0.958  0.397  1.0
  C  C21  1  0.252  0.958  0.897  1.0
  C  C22  1  0.752  0.042  0.603  1.0
  C  C23  1  0.748  0.042  0.103  1.0
  O  O24  1  0.259  0.930  0.273  1.0
  O  O25  1  0.752  0.895  0.569  1.0
  O  O26  1  0.241  0.930  0.773  1.0
  O  O27  1  0.241  0.847  0.495  1.0
  O  O28  1  0.748  0.895  0.069  1.0
  O  O29  1  0.259  0.847  0.995  1.0
  O  O30  1  0.938  0.690  0.340  1.0
  O  O31  1  0.558  0.690  0.337  1.0
  O  O32  1  0.942  0.690  0.837  1.0
  O  O33  1  0.562  0.690  0.840  1.0
  O  O34  1  0.255  0.574  0.660  1.0
  O  O35  1  0.750  0.577  0.550  1.0
  O  O36  1  0.245  0.574  0.160  1.0
  O  O37  1  0.750  0.577  0.050  1.0
  O  O38  1  0.250  0.423  0.450  1.0
  O  O39  1  0.745  0.426  0.340  1.0
  O  O40  1  0.250  0.423  0.950  1.0
  O  O41  1  0.755  0.426  0.840  1.0
  O  O42  1  0.062  0.310  0.660  1.0
  O  O43  1  0.442  0.310  0.663  1.0
  O  O44  1  0.438  0.310  0.160  1.0
  O  O45  1  0.058  0.310  0.163  1.0
  O  O46  1  0.759  0.153  0.505  1.0
  O  O47  1  0.248  0.105  0.431  1.0
  O  O48  1  0.741  0.153  0.005  1.0
  O  O49  1  0.741  0.070  0.727  1.0
  O  O50  1  0.252  0.105  0.931  1.0
  O  O51  1  0.759  0.070  0.227  1.0
[/CIF]
.
The material described by Li3MnCO3PO4 crystallizes in the monoclinic P2_1/c space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(4), and one O(5) atom. In the second Li site, Li(2) is bonded to one O(2), one O(3), one O(4), one O(6), and one O(7) atom to form distorted LiO5 trigonal bipyramids that share corners with three equivalent P(1)O4 tetrahedra and edges with two equivalent Mn(1)O5 trigonal bipyramids. In the third Li site, Li(3) is bonded in a 6-coordinate geometry to one O(1), one O(3), one O(4), one O(5), one O(6), and one O(7) atom. Mn(1) is bonded to one O(2), one O(3), one O(5), one O(6), and one O(7) atom to form distorted MnO5 trigonal bipyramids that share corners with three equivalent P(1)O4 tetrahedra and edges with two equivalent Li(2)O5 trigonal bipyramids. C(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. P(1) is bonded to one O(4), one O(5), one O(6), and one O(7) atom to form PO4 tetrahedra that share corners with three equivalent Li(2)O5 trigonal bipyramids and corners with three equivalent Mn(1)O5 trigonal bipyramids. There are seven inequivalent O sites. In the first O site, O(6) is bonded to one Li(2), one Li(3), one Mn(1), and one P(1) atom to form distorted OLi2MnP trigonal pyramids that share corners with two equivalent O(2)Li2MnC tetrahedra, corners with four equivalent O(7)Li2MnP tetrahedra,  a cornercorner with one O(5)Li2MnP trigonal pyramid, and  an edgeedge with one O(5)Li2MnP trigonal pyramid. In the second O site, O(7) is bonded to one Li(2), one Li(3), one Mn(1), and one P(1) atom to form OLi2MnP tetrahedra that share corners with three equivalent O(5)Li2MnP trigonal pyramids, corners with four equivalent O(6)Li2MnP trigonal pyramids, and  an edgeedge with one O(2)Li2MnC tetrahedra. In the third O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Li(1), one Li(3), and one C(1) atom. In the fourth O site, O(2) is bonded to one Li(1), one Li(2), one Mn(1), and one C(1) atom to form a mixture of distorted corner and edge-sharing OLi2MnC tetrahedra. In the fifth O site, O(3) is bonded in a 4-coordinate geometry to one Li(2), one Li(3), one Mn(1), and one C(1) atom. In the sixth O site, O(4) is bonded in a 4-coordinate geometry to one Li(1), one Li(2), one Li(3), and one P(1) atom. In the seventh O site, O(5) is bonded to one Li(1), one Li(3), one Mn(1), and one P(1) atom to form distorted OLi2MnP trigonal pyramids that share corners with two equivalent O(2)Li2MnC tetrahedra, corners with three equivalent O(7)Li2MnP tetrahedra,  a cornercorner with one O(6)Li2MnP trigonal pyramid, and  an edgeedge with one O(6)Li2MnP trigonal pyramid. is represented by the CIF card [CIF]
data_Li3MnPCO7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.481
_cell_length_b   8.586
_cell_length_c   9.855
_cell_angle_alpha   85.376
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   546.663
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.748  0.899  0.365  1.0
  Li  Li1  1  0.752  0.899  0.865  1.0
  Li  Li2  1  0.513  0.716  0.633  1.0
  Li  Li3  1  0.987  0.716  0.133  1.0
  Li  Li4  1  0.246  0.649  0.360  1.0
  Li  Li5  1  0.254  0.649  0.860  1.0
  Li  Li6  1  0.754  0.351  0.640  1.0
  Li  Li7  1  0.746  0.351  0.140  1.0
  Li  Li8  1  0.487  0.284  0.367  1.0
  Li  Li9  1  0.013  0.284  0.867  1.0
  Li  Li10  1  0.252  0.101  0.635  1.0
  Li  Li11  1  0.248  0.101  0.135  1.0
  Mn  Mn12  1  0.998  0.729  0.620  1.0
  Mn  Mn13  1  0.502  0.729  0.120  1.0
  Mn  Mn14  1  0.002  0.271  0.380  1.0
  Mn  Mn15  1  0.498  0.271  0.880  1.0
  P  P16  1  0.749  0.593  0.390  1.0
  P  P17  1  0.751  0.593  0.890  1.0
  P  P18  1  0.251  0.407  0.610  1.0
  P  P19  1  0.249  0.407  0.110  1.0
  C  C20  1  0.248  0.958  0.397  1.0
  C  C21  1  0.252  0.958  0.897  1.0
  C  C22  1  0.752  0.042  0.603  1.0
  C  C23  1  0.748  0.042  0.103  1.0
  O  O24  1  0.259  0.930  0.273  1.0
  O  O25  1  0.752  0.895  0.569  1.0
  O  O26  1  0.241  0.930  0.773  1.0
  O  O27  1  0.241  0.847  0.495  1.0
  O  O28  1  0.748  0.895  0.069  1.0
  O  O29  1  0.259  0.847  0.995  1.0
  O  O30  1  0.938  0.690  0.340  1.0
  O  O31  1  0.558  0.690  0.337  1.0
  O  O32  1  0.942  0.690  0.837  1.0
  O  O33  1  0.562  0.690  0.840  1.0
  O  O34  1  0.255  0.574  0.660  1.0
  O  O35  1  0.750  0.577  0.550  1.0
  O  O36  1  0.245  0.574  0.160  1.0
  O  O37  1  0.750  0.577  0.050  1.0
  O  O38  1  0.250  0.423  0.450  1.0
  O  O39  1  0.745  0.426  0.340  1.0
  O  O40  1  0.250  0.423  0.950  1.0
  O  O41  1  0.755  0.426  0.840  1.0
  O  O42  1  0.062  0.310  0.660  1.0
  O  O43  1  0.442  0.310  0.663  1.0
  O  O44  1  0.438  0.310  0.160  1.0
  O  O45  1  0.058  0.310  0.163  1.0
  O  O46  1  0.759  0.153  0.505  1.0
  O  O47  1  0.248  0.105  0.431  1.0
  O  O48  1  0.741  0.153  0.005  1.0
  O  O49  1  0.741  0.070  0.727  1.0
  O  O50  1  0.252  0.105  0.931  1.0
  O  O51  1  0.759  0.070  0.227  1.0
[/CIF]
.