The structure described by CN6H3(NH2)3 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six ammonia molecules and one CN6H3 cluster. In the CN6H3 cluster, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one N(5) atom. There are six inequivalent N sites. In the first N site, N(9) is bonded in a trigonal non-coplanar geometry to one H(7), one H(8), and one H(9) atom. In the second N site, N(1) is bonded in a distorted bent 120 degrees geometry to one C(1) and one N(1) atom. In the third N site, N(2) is bonded in a distorted single-bond geometry to one C(1), one N(3), and one H(8) atom. In the fourth N site, N(3) is bonded in a water-like geometry to one N(2) and one N(4) atom. In the fifth N site, N(4) is bonded in a water-like geometry to one N(3) and one N(5) atom. In the sixth N site, N(5) is bonded in a distorted water-like geometry to one C(1) and one N(4) atom. There are three inequivalent H sites. In the first H site, H(7) is bonded in a single-bond geometry to one N(9) atom. In the second H site, H(8) is bonded in a single-bond geometry to one N(2) and one N(9) atom. In the third H site, H(9) is bonded in a single-bond geometry to one N(9) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_H9CN9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.963
_cell_length_b   8.685
_cell_length_c   9.494
_cell_angle_alpha   109.817
_cell_angle_beta   98.615
_cell_angle_gamma   100.320
_symmetry_Int_Tables_number   1
_cell_volume   368.875
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.166  0.625  0.940  1.0
  H  H1  1  0.834  0.375  0.060  1.0
  H  H2  1  0.273  0.818  0.074  1.0
  H  H3  1  0.727  0.182  0.926  1.0
  H  H4  1  0.456  0.819  0.868  1.0
  H  H5  1  0.544  0.181  0.132  1.0
  H  H6  1  0.719  0.823  0.002  1.0
  H  H7  1  0.281  0.177  0.998  1.0
  H  H8  1  0.898  0.522  0.663  1.0
  H  H9  1  0.102  0.478  0.337  1.0
  H  H10  1  0.879  0.326  0.655  1.0
  H  H11  1  0.121  0.674  0.345  1.0
  H  H12  1  0.571  0.556  0.810  1.0
  H  H13  1  0.429  0.444  0.190  1.0
  H  H14  1  0.445  0.359  0.652  1.0
  H  H15  1  0.555  0.641  0.348  1.0
  H  H16  1  0.588  0.370  0.835  1.0
  H  H17  1  0.412  0.630  0.165  1.0
  C  C18  1  0.756  0.946  0.609  1.0
  C  C19  1  0.244  0.054  0.391  1.0
  N  N20  1  0.595  0.042  0.562  1.0
  N  N21  1  0.405  0.958  0.438  1.0
  N  N22  1  0.756  0.783  0.535  1.0
  N  N23  1  0.244  0.217  0.465  1.0
  N  N24  1  0.948  0.752  0.628  1.0
  N  N25  1  0.052  0.248  0.372  1.0
  N  N26  1  0.061  0.891  0.756  1.0
  N  N27  1  0.939  0.109  0.244  1.0
  N  N28  1  0.945  0.015  0.746  1.0
  N  N29  1  0.055  0.985  0.254  1.0
  N  N30  1  0.339  0.713  0.018  1.0
  N  N31  1  0.661  0.287  0.982  1.0
  N  N32  1  0.533  0.750  0.927  1.0
  N  N33  1  0.467  0.250  0.073  1.0
  N  N34  1  0.878  0.445  0.725  1.0
  N  N35  1  0.122  0.555  0.275  1.0
  N  N36  1  0.598  0.431  0.755  1.0
  N  N37  1  0.402  0.569  0.245  1.0
[/CIF]
.
The structure described by CN6H3(NH2)3 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six ammonia molecules and one CN6H3 cluster. In the CN6H3 cluster, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one N(5) atom. There are six inequivalent N sites. In the first N site, N(9) is bonded in a trigonal non-coplanar geometry to one H(7), one H(8), and one H(9) atom. In the second N site, N(1) is bonded in a distorted bent 120 degrees geometry to one C(1) and one N(1) atom. In the third N site, N(2) is bonded in a distorted single-bond geometry to one C(1), one N(3), and one H(8) atom. In the fourth N site, N(3) is bonded in a water-like geometry to one N(2) and one N(4) atom. In the fifth N site, N(4) is bonded in a water-like geometry to one N(3) and one N(5) atom. In the sixth N site, N(5) is bonded in a distorted water-like geometry to one C(1) and one N(4) atom. There are three inequivalent H sites. In the first H site, H(7) is bonded in a single-bond geometry to one N(9) atom. In the second H site, H(8) is bonded in a single-bond geometry to one N(2) and one N(9) atom. In the third H site, H(9) is bonded in a single-bond geometry to one N(9) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_H9CN9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.963
_cell_length_b   8.685
_cell_length_c   9.494
_cell_angle_alpha   109.817
_cell_angle_beta   98.615
_cell_angle_gamma   100.320
_symmetry_Int_Tables_number   1
_cell_volume   368.875
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.166  0.625  0.940  1.0
  H  H1  1  0.834  0.375  0.060  1.0
  H  H2  1  0.273  0.818  0.074  1.0
  H  H3  1  0.727  0.182  0.926  1.0
  H  H4  1  0.456  0.819  0.868  1.0
  H  H5  1  0.544  0.181  0.132  1.0
  H  H6  1  0.719  0.823  0.002  1.0
  H  H7  1  0.281  0.177  0.998  1.0
  H  H8  1  0.898  0.522  0.663  1.0
  H  H9  1  0.102  0.478  0.337  1.0
  H  H10  1  0.879  0.326  0.655  1.0
  H  H11  1  0.121  0.674  0.345  1.0
  H  H12  1  0.571  0.556  0.810  1.0
  H  H13  1  0.429  0.444  0.190  1.0
  H  H14  1  0.445  0.359  0.652  1.0
  H  H15  1  0.555  0.641  0.348  1.0
  H  H16  1  0.588  0.370  0.835  1.0
  H  H17  1  0.412  0.630  0.165  1.0
  C  C18  1  0.756  0.946  0.609  1.0
  C  C19  1  0.244  0.054  0.391  1.0
  N  N20  1  0.595  0.042  0.562  1.0
  N  N21  1  0.405  0.958  0.438  1.0
  N  N22  1  0.756  0.783  0.535  1.0
  N  N23  1  0.244  0.217  0.465  1.0
  N  N24  1  0.948  0.752  0.628  1.0
  N  N25  1  0.052  0.248  0.372  1.0
  N  N26  1  0.061  0.891  0.756  1.0
  N  N27  1  0.939  0.109  0.244  1.0
  N  N28  1  0.945  0.015  0.746  1.0
  N  N29  1  0.055  0.985  0.254  1.0
  N  N30  1  0.339  0.713  0.018  1.0
  N  N31  1  0.661  0.287  0.982  1.0
  N  N32  1  0.533  0.750  0.927  1.0
  N  N33  1  0.467  0.250  0.073  1.0
  N  N34  1  0.878  0.445  0.725  1.0
  N  N35  1  0.122  0.555  0.275  1.0
  N  N36  1  0.598  0.431  0.755  1.0
  N  N37  1  0.402  0.569  0.245  1.0
[/CIF]
.