The structure described by Co(IO3)2 crystallizes in the triclinic P1 space group. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded in an octahedral geometry to one O(2), one O(20), one O(22), one O(23), one O(3), and one O(5) atom. In the second Co site, Co(2) is bonded in an octahedral geometry to one O(1), one O(16), one O(19), one O(24), one O(6), and one O(9) atom. In the third Co site, Co(3) is bonded in an octahedral geometry to one O(11), one O(14), one O(18), one O(21), one O(4), and one O(7) atom. In the fourth Co site, Co(4) is bonded in an octahedral geometry to one O(10), one O(12), one O(13), one O(15), one O(17), and one O(8) atom. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Co(2) and one I(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one I(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Co(1) and one I(3) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Co(3) and one I(1) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one I(2) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Co(2) and one I(2) atom. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Co(3) and one I(3) atom. In the eighth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one Co(4) and one I(3) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Co(2) and one I(5) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Co(4) and one I(2) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Co(3) and one I(4) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Co(4) and one I(4) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 150 degrees geometry to one Co(4) and one I(5) atom. In the fourteenth O site, O(14) is bonded in a distorted bent 150 degrees geometry to one Co(3) and one I(5) atom. In the fifteenth O site, O(15) is bonded in a distorted bent 150 degrees geometry to one Co(4) and one I(6) atom. In the sixteenth O site, O(16) is bonded in a distorted bent 150 degrees geometry to one Co(2), one I(4), and one I(6) atom. In the seventeenth O site, O(17) is bonded in a bent 120 degrees geometry to one Co(4) and one I(7) atom. In the eighteenth O site, O(18) is bonded in a bent 120 degrees geometry to one Co(3) and one I(7) atom. In the nineteenth O site, O(19) is bonded in a bent 120 degrees geometry to one Co(2) and one I(6) atom. In the twentieth O site, O(20) is bonded in a water-like geometry to one Co(1) and one I(6) atom. In the twenty-first O site, O(21) is bonded in a distorted bent 150 degrees geometry to one Co(3) and one I(8) atom. In the twenty-second O site, O(22) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one I(7) atom. In the twenty-third O site, O(23) is bonded in a bent 120 degrees geometry to one Co(1) and one I(8) atom. In the twenty-fourth O site, O(24) is bonded in a bent 120 degrees geometry to one Co(2) and one I(8) atom. There are eight inequivalent I sites. In the first I site, I(1) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(2), and one O(4) atom. In the second I site, I(2) is bonded in a distorted trigonal non-coplanar geometry to one O(10), one O(5), and one O(6) atom. In the third I site, I(3) is bonded in a distorted trigonal non-coplanar geometry to one O(3), one O(7), and one O(8) atom. In the fourth I site, I(4) is bonded in a 3-coordinate geometry to one O(11), one O(12), and one O(16) atom. In the fifth I site, I(5) is bonded in a 3-coordinate geometry to one O(13), one O(14), and one O(9) atom. In the sixth I site, I(6) is bonded in a 3-coordinate geometry to one O(15), one O(16), one O(19), and one O(20) atom. In the seventh I site, I(7) is bonded in a 3-coordinate geometry to one O(17), one O(18), and one O(22) atom. In the eighth I site, I(8) is bonded in a 3-coordinate geometry to one O(21), one O(23), and one O(24) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Co(IO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.454
_cell_length_b   5.507
_cell_length_c   9.395
_cell_angle_alpha   90.234
_cell_angle_beta   90.004
_cell_angle_gamma   89.961
_symmetry_Int_Tables_number   1
_cell_volume   282.161
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.429  0.011  0.004  1.0
  Co  Co1  1  0.928  0.489  0.496  1.0
  I  I2  1  0.037  0.519  0.149  1.0
  I  I3  1  0.537  0.981  0.351  1.0
  I  I4  1  0.007  0.990  0.685  1.0
  I  I5  1  0.507  0.509  0.815  1.0
  O  O6  1  0.217  0.802  0.150  1.0
  O  O7  1  0.217  0.334  0.021  1.0
  O  O8  1  0.639  0.109  0.181  1.0
  O  O9  1  0.139  0.391  0.319  1.0
  O  O10  1  0.716  0.166  0.478  1.0
  O  O11  1  0.716  0.698  0.350  1.0
  O  O12  1  0.152  0.279  0.633  1.0
  O  O13  1  0.136  0.796  0.545  1.0
  O  O14  1  0.720  0.603  0.672  1.0
  O  O15  1  0.220  0.896  0.828  1.0
  O  O16  1  0.636  0.702  0.956  1.0
  O  O17  1  0.653  0.220  0.867  1.0
[/CIF]
.
The structure described by Co(IO3)2 crystallizes in the triclinic P1 space group. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded in an octahedral geometry to one O(2), one O(20), one O(22), one O(23), one O(3), and one O(5) atom. In the second Co site, Co(2) is bonded in an octahedral geometry to one O(1), one O(16), one O(19), one O(24), one O(6), and one O(9) atom. In the third Co site, Co(3) is bonded in an octahedral geometry to one O(11), one O(14), one O(18), one O(21), one O(4), and one O(7) atom. In the fourth Co site, Co(4) is bonded in an octahedral geometry to one O(10), one O(12), one O(13), one O(15), one O(17), and one O(8) atom. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Co(2) and one I(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one I(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Co(1) and one I(3) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Co(3) and one I(1) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one I(2) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Co(2) and one I(2) atom. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Co(3) and one I(3) atom. In the eighth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one Co(4) and one I(3) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Co(2) and one I(5) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Co(4) and one I(2) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Co(3) and one I(4) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Co(4) and one I(4) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 150 degrees geometry to one Co(4) and one I(5) atom. In the fourteenth O site, O(14) is bonded in a distorted bent 150 degrees geometry to one Co(3) and one I(5) atom. In the fifteenth O site, O(15) is bonded in a distorted bent 150 degrees geometry to one Co(4) and one I(6) atom. In the sixteenth O site, O(16) is bonded in a distorted bent 150 degrees geometry to one Co(2), one I(4), and one I(6) atom. In the seventeenth O site, O(17) is bonded in a bent 120 degrees geometry to one Co(4) and one I(7) atom. In the eighteenth O site, O(18) is bonded in a bent 120 degrees geometry to one Co(3) and one I(7) atom. In the nineteenth O site, O(19) is bonded in a bent 120 degrees geometry to one Co(2) and one I(6) atom. In the twentieth O site, O(20) is bonded in a water-like geometry to one Co(1) and one I(6) atom. In the twenty-first O site, O(21) is bonded in a distorted bent 150 degrees geometry to one Co(3) and one I(8) atom. In the twenty-second O site, O(22) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one I(7) atom. In the twenty-third O site, O(23) is bonded in a bent 120 degrees geometry to one Co(1) and one I(8) atom. In the twenty-fourth O site, O(24) is bonded in a bent 120 degrees geometry to one Co(2) and one I(8) atom. There are eight inequivalent I sites. In the first I site, I(1) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(2), and one O(4) atom. In the second I site, I(2) is bonded in a distorted trigonal non-coplanar geometry to one O(10), one O(5), and one O(6) atom. In the third I site, I(3) is bonded in a distorted trigonal non-coplanar geometry to one O(3), one O(7), and one O(8) atom. In the fourth I site, I(4) is bonded in a 3-coordinate geometry to one O(11), one O(12), and one O(16) atom. In the fifth I site, I(5) is bonded in a 3-coordinate geometry to one O(13), one O(14), and one O(9) atom. In the sixth I site, I(6) is bonded in a 3-coordinate geometry to one O(15), one O(16), one O(19), and one O(20) atom. In the seventh I site, I(7) is bonded in a 3-coordinate geometry to one O(17), one O(18), and one O(22) atom. In the eighth I site, I(8) is bonded in a 3-coordinate geometry to one O(21), one O(23), and one O(24) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Co(IO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.454
_cell_length_b   5.507
_cell_length_c   9.395
_cell_angle_alpha   90.234
_cell_angle_beta   90.004
_cell_angle_gamma   89.961
_symmetry_Int_Tables_number   1
_cell_volume   282.161
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.429  0.011  0.004  1.0
  Co  Co1  1  0.928  0.489  0.496  1.0
  I  I2  1  0.037  0.519  0.149  1.0
  I  I3  1  0.537  0.981  0.351  1.0
  I  I4  1  0.007  0.990  0.685  1.0
  I  I5  1  0.507  0.509  0.815  1.0
  O  O6  1  0.217  0.802  0.150  1.0
  O  O7  1  0.217  0.334  0.021  1.0
  O  O8  1  0.639  0.109  0.181  1.0
  O  O9  1  0.139  0.391  0.319  1.0
  O  O10  1  0.716  0.166  0.478  1.0
  O  O11  1  0.716  0.698  0.350  1.0
  O  O12  1  0.152  0.279  0.633  1.0
  O  O13  1  0.136  0.796  0.545  1.0
  O  O14  1  0.720  0.603  0.672  1.0
  O  O15  1  0.220  0.896  0.828  1.0
  O  O16  1  0.636  0.702  0.956  1.0
  O  O17  1  0.653  0.220  0.867  1.0
[/CIF]
.