The material structure described by SbPOF8 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four SbPOF8 clusters. Sb(1) is bonded to one O(1), one F(1), one F(2), one F(3), one F(4), and one F(5) atom to form SbOF5 octahedra that share  a cornercorner with one P(1)OF3 tetrahedra. P(1) is bonded to one O(1), one F(6), one F(7), and one F(8) atom to form POF3 tetrahedra that share  a cornercorner with one Sb(1)OF5 octahedra. The corner-sharing octahedral tilt angles are 15°. O(1) is bonded in a distorted linear geometry to one Sb(1) and one P(1) atom. There are eight inequivalent F sites. In the first F site, F(8) is bonded in a single-bond geometry to one P(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom. In the seventh F site, F(6) is bonded in a single-bond geometry to one P(1) atom. In the eighth F site, F(7) is bonded in a single-bond geometry to one P(1) atom. is represented by the CIF card [CIF]
data_SbPOF8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   16.904
_cell_length_b   5.188
_cell_length_c   7.467
_cell_angle_alpha   82.154
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   648.778
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.120  0.031  0.739  1.0
  Sb  Sb1  1  0.880  0.969  0.261  1.0
  Sb  Sb2  1  0.380  0.031  0.239  1.0
  Sb  Sb3  1  0.620  0.969  0.761  1.0
  P  P4  1  0.131  0.615  0.147  1.0
  P  P5  1  0.369  0.615  0.647  1.0
  P  P6  1  0.631  0.385  0.353  1.0
  P  P7  1  0.869  0.385  0.853  1.0
  O  O8  1  0.871  0.180  0.007  1.0
  O  O9  1  0.371  0.820  0.493  1.0
  O  O10  1  0.629  0.180  0.507  1.0
  O  O11  1  0.129  0.820  0.993  1.0
  F  F12  1  0.424  0.733  0.165  1.0
  F  F13  1  0.162  0.305  0.851  1.0
  F  F14  1  0.616  0.776  0.992  1.0
  F  F15  1  0.518  0.869  0.691  1.0
  F  F16  1  0.777  0.085  0.299  1.0
  F  F17  1  0.116  0.224  0.508  1.0
  F  F18  1  0.706  0.547  0.339  1.0
  F  F19  1  0.277  0.915  0.201  1.0
  F  F20  1  0.924  0.267  0.335  1.0
  F  F21  1  0.206  0.453  0.161  1.0
  F  F22  1  0.935  0.580  0.851  1.0
  F  F23  1  0.065  0.420  0.149  1.0
  F  F24  1  0.723  0.085  0.799  1.0
  F  F25  1  0.223  0.915  0.701  1.0
  F  F26  1  0.482  0.131  0.309  1.0
  F  F27  1  0.435  0.420  0.649  1.0
  F  F28  1  0.294  0.453  0.661  1.0
  F  F29  1  0.384  0.224  0.008  1.0
  F  F30  1  0.565  0.580  0.351  1.0
  F  F31  1  0.076  0.733  0.665  1.0
  F  F32  1  0.873  0.279  0.676  1.0
  F  F33  1  0.662  0.695  0.649  1.0
  F  F34  1  0.884  0.776  0.492  1.0
  F  F35  1  0.794  0.547  0.839  1.0
  F  F36  1  0.127  0.721  0.324  1.0
  F  F37  1  0.576  0.267  0.835  1.0
  F  F38  1  0.018  0.131  0.809  1.0
  F  F39  1  0.373  0.721  0.824  1.0
  F  F40  1  0.338  0.305  0.351  1.0
  F  F41  1  0.838  0.695  0.149  1.0
  F  F42  1  0.627  0.279  0.176  1.0
  F  F43  1  0.982  0.869  0.191  1.0
[/CIF]
.
The material structure described by SbPOF8 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four SbPOF8 clusters. Sb(1) is bonded to one O(1), one F(1), one F(2), one F(3), one F(4), and one F(5) atom to form SbOF5 octahedra that share  a cornercorner with one P(1)OF3 tetrahedra. P(1) is bonded to one O(1), one F(6), one F(7), and one F(8) atom to form POF3 tetrahedra that share  a cornercorner with one Sb(1)OF5 octahedra. The corner-sharing octahedral tilt angles are 15°. O(1) is bonded in a distorted linear geometry to one Sb(1) and one P(1) atom. There are eight inequivalent F sites. In the first F site, F(8) is bonded in a single-bond geometry to one P(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom. In the seventh F site, F(6) is bonded in a single-bond geometry to one P(1) atom. In the eighth F site, F(7) is bonded in a single-bond geometry to one P(1) atom. is represented by the CIF card [CIF]
data_SbPOF8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   16.904
_cell_length_b   5.188
_cell_length_c   7.467
_cell_angle_alpha   82.154
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   648.778
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.120  0.031  0.739  1.0
  Sb  Sb1  1  0.880  0.969  0.261  1.0
  Sb  Sb2  1  0.380  0.031  0.239  1.0
  Sb  Sb3  1  0.620  0.969  0.761  1.0
  P  P4  1  0.131  0.615  0.147  1.0
  P  P5  1  0.369  0.615  0.647  1.0
  P  P6  1  0.631  0.385  0.353  1.0
  P  P7  1  0.869  0.385  0.853  1.0
  O  O8  1  0.871  0.180  0.007  1.0
  O  O9  1  0.371  0.820  0.493  1.0
  O  O10  1  0.629  0.180  0.507  1.0
  O  O11  1  0.129  0.820  0.993  1.0
  F  F12  1  0.424  0.733  0.165  1.0
  F  F13  1  0.162  0.305  0.851  1.0
  F  F14  1  0.616  0.776  0.992  1.0
  F  F15  1  0.518  0.869  0.691  1.0
  F  F16  1  0.777  0.085  0.299  1.0
  F  F17  1  0.116  0.224  0.508  1.0
  F  F18  1  0.706  0.547  0.339  1.0
  F  F19  1  0.277  0.915  0.201  1.0
  F  F20  1  0.924  0.267  0.335  1.0
  F  F21  1  0.206  0.453  0.161  1.0
  F  F22  1  0.935  0.580  0.851  1.0
  F  F23  1  0.065  0.420  0.149  1.0
  F  F24  1  0.723  0.085  0.799  1.0
  F  F25  1  0.223  0.915  0.701  1.0
  F  F26  1  0.482  0.131  0.309  1.0
  F  F27  1  0.435  0.420  0.649  1.0
  F  F28  1  0.294  0.453  0.661  1.0
  F  F29  1  0.384  0.224  0.008  1.0
  F  F30  1  0.565  0.580  0.351  1.0
  F  F31  1  0.076  0.733  0.665  1.0
  F  F32  1  0.873  0.279  0.676  1.0
  F  F33  1  0.662  0.695  0.649  1.0
  F  F34  1  0.884  0.776  0.492  1.0
  F  F35  1  0.794  0.547  0.839  1.0
  F  F36  1  0.127  0.721  0.324  1.0
  F  F37  1  0.576  0.267  0.835  1.0
  F  F38  1  0.018  0.131  0.809  1.0
  F  F39  1  0.373  0.721  0.824  1.0
  F  F40  1  0.338  0.305  0.351  1.0
  F  F41  1  0.838  0.695  0.149  1.0
  F  F42  1  0.627  0.279  0.176  1.0
  F  F43  1  0.982  0.869  0.191  1.0
[/CIF]
.