The compound described by Pb2CoTeO6 crystallizes in the cubic Fm-3m space group. Co(1) is bonded to six equivalent O(1) atoms to form CoO6 octahedra that share corners with six equivalent Te(1)O6 octahedra and faces with eight equivalent Pb(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. Pb(1) is bonded to twelve equivalent O(1) atoms to form PbO12 cuboctahedra that share corners with twelve equivalent Pb(1)O12 cuboctahedra, faces with six equivalent Pb(1)O12 cuboctahedra, faces with four equivalent Co(1)O6 octahedra, and faces with four equivalent Te(1)O6 octahedra. Te(1) is bonded to six equivalent O(1) atoms to form TeO6 octahedra that share corners with six equivalent Co(1)O6 octahedra and faces with eight equivalent Pb(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. O(1) is bonded in a linear geometry to one Co(1), four equivalent Pb(1), and one Te(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CoTe(PbO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.724
_cell_length_b   5.724
_cell_length_c   5.724
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   132.584
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.000  0.000  0.000  1.0
  Te  Te1  1  0.500  0.500  0.500  1.0
  Pb  Pb2  1  0.250  0.250  0.250  1.0
  Pb  Pb3  1  0.750  0.750  0.750  1.0
  O  O4  1  0.255  0.745  0.255  1.0
  O  O5  1  0.745  0.255  0.745  1.0
  O  O6  1  0.255  0.255  0.745  1.0
  O  O7  1  0.255  0.745  0.745  1.0
  O  O8  1  0.745  0.745  0.255  1.0
  O  O9  1  0.745  0.255  0.255  1.0
[/CIF]
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The compound described by Pb2CoTeO6 crystallizes in the cubic Fm-3m space group. Co(1) is bonded to six equivalent O(1) atoms to form CoO6 octahedra that share corners with six equivalent Te(1)O6 octahedra and faces with eight equivalent Pb(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. Pb(1) is bonded to twelve equivalent O(1) atoms to form PbO12 cuboctahedra that share corners with twelve equivalent Pb(1)O12 cuboctahedra, faces with six equivalent Pb(1)O12 cuboctahedra, faces with four equivalent Co(1)O6 octahedra, and faces with four equivalent Te(1)O6 octahedra. Te(1) is bonded to six equivalent O(1) atoms to form TeO6 octahedra that share corners with six equivalent Co(1)O6 octahedra and faces with eight equivalent Pb(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. O(1) is bonded in a linear geometry to one Co(1), four equivalent Pb(1), and one Te(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CoTe(PbO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.724
_cell_length_b   5.724
_cell_length_c   5.724
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   132.584
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.000  0.000  0.000  1.0
  Te  Te1  1  0.500  0.500  0.500  1.0
  Pb  Pb2  1  0.250  0.250  0.250  1.0
  Pb  Pb3  1  0.750  0.750  0.750  1.0
  O  O4  1  0.255  0.745  0.255  1.0
  O  O5  1  0.745  0.255  0.745  1.0
  O  O6  1  0.255  0.255  0.745  1.0
  O  O7  1  0.255  0.745  0.745  1.0
  O  O8  1  0.745  0.745  0.255  1.0
  O  O9  1  0.745  0.255  0.255  1.0
[/CIF]
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