The material described by Hf5Re24 crystallizes in the cubic I-43m space group. There are two inequivalent Hf sites. In the first Hf site, Hf(1) is bonded in a 16-coordinate geometry to one Hf(2), six equivalent Re(1), and nine equivalent Re(2) atoms. In the second Hf site, Hf(2) is bonded in a 16-coordinate geometry to four equivalent Hf(1) and twelve equivalent Re(2) atoms. There are two inequivalent Re sites. In the first Re site, Re(1) is bonded in a 13-coordinate geometry to two equivalent Hf(1), five equivalent Re(2), and six equivalent Re(1) atoms. In the second Re site, Re(2) is bonded to one Hf(2), three equivalent Hf(1), three equivalent Re(2), and five equivalent Re(1) atoms to form a mixture of distorted face, corner, and edge-sharing ReHf4Re8 cuboctahedra. is represented by the CIF card [CIF]
data_Hf5Re24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.426
_cell_length_b   8.426
_cell_length_c   8.426
_cell_angle_alpha   109.471
_cell_angle_beta   109.471
_cell_angle_gamma   109.471
_symmetry_Int_Tables_number   1
_cell_volume   460.558
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Hf  Hf0  1  0.000  0.372  0.000  1.0
  Hf  Hf1  1  0.000  0.000  0.000  1.0
  Hf  Hf2  1  0.000  0.000  0.372  1.0
  Hf  Hf3  1  0.372  0.000  0.000  1.0
  Hf  Hf4  1  0.628  0.628  0.628  1.0
  Re  Re5  1  0.677  0.677  0.281  1.0
  Re  Re6  1  0.376  0.376  0.182  1.0
  Re  Re7  1  0.000  0.624  0.806  1.0
  Re  Re8  1  0.323  0.000  0.604  1.0
  Re  Re9  1  0.396  0.719  0.396  1.0
  Re  Re10  1  0.000  0.604  0.323  1.0
  Re  Re11  1  0.719  0.396  0.396  1.0
  Re  Re12  1  0.000  0.806  0.624  1.0
  Re  Re13  1  0.396  0.396  0.719  1.0
  Re  Re14  1  0.624  0.806  0.000  1.0
  Re  Re15  1  0.281  0.677  0.677  1.0
  Re  Re16  1  0.677  0.281  0.677  1.0
  Re  Re17  1  0.818  0.194  0.194  1.0
  Re  Re18  1  0.194  0.194  0.818  1.0
  Re  Re19  1  0.604  0.323  0.000  1.0
  Re  Re20  1  0.806  0.000  0.624  1.0
  Re  Re21  1  0.194  0.818  0.194  1.0
  Re  Re22  1  0.376  0.182  0.376  1.0
  Re  Re23  1  0.323  0.604  0.000  1.0
  Re  Re24  1  0.624  0.000  0.806  1.0
  Re  Re25  1  0.000  0.323  0.604  1.0
  Re  Re26  1  0.604  0.000  0.323  1.0
  Re  Re27  1  0.806  0.624  0.000  1.0
  Re  Re28  1  0.182  0.376  0.376  1.0
[/CIF]
.
The material described by Hf5Re24 crystallizes in the cubic I-43m space group. There are two inequivalent Hf sites. In the first Hf site, Hf(1) is bonded in a 16-coordinate geometry to one Hf(2), six equivalent Re(1), and nine equivalent Re(2) atoms. In the second Hf site, Hf(2) is bonded in a 16-coordinate geometry to four equivalent Hf(1) and twelve equivalent Re(2) atoms. There are two inequivalent Re sites. In the first Re site, Re(1) is bonded in a 13-coordinate geometry to two equivalent Hf(1), five equivalent Re(2), and six equivalent Re(1) atoms. In the second Re site, Re(2) is bonded to one Hf(2), three equivalent Hf(1), three equivalent Re(2), and five equivalent Re(1) atoms to form a mixture of distorted face, corner, and edge-sharing ReHf4Re8 cuboctahedra. is represented by the CIF card [CIF]
data_Hf5Re24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.426
_cell_length_b   8.426
_cell_length_c   8.426
_cell_angle_alpha   109.471
_cell_angle_beta   109.471
_cell_angle_gamma   109.471
_symmetry_Int_Tables_number   1
_cell_volume   460.558
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Hf  Hf0  1  0.000  0.372  0.000  1.0
  Hf  Hf1  1  0.000  0.000  0.000  1.0
  Hf  Hf2  1  0.000  0.000  0.372  1.0
  Hf  Hf3  1  0.372  0.000  0.000  1.0
  Hf  Hf4  1  0.628  0.628  0.628  1.0
  Re  Re5  1  0.677  0.677  0.281  1.0
  Re  Re6  1  0.376  0.376  0.182  1.0
  Re  Re7  1  0.000  0.624  0.806  1.0
  Re  Re8  1  0.323  0.000  0.604  1.0
  Re  Re9  1  0.396  0.719  0.396  1.0
  Re  Re10  1  0.000  0.604  0.323  1.0
  Re  Re11  1  0.719  0.396  0.396  1.0
  Re  Re12  1  0.000  0.806  0.624  1.0
  Re  Re13  1  0.396  0.396  0.719  1.0
  Re  Re14  1  0.624  0.806  0.000  1.0
  Re  Re15  1  0.281  0.677  0.677  1.0
  Re  Re16  1  0.677  0.281  0.677  1.0
  Re  Re17  1  0.818  0.194  0.194  1.0
  Re  Re18  1  0.194  0.194  0.818  1.0
  Re  Re19  1  0.604  0.323  0.000  1.0
  Re  Re20  1  0.806  0.000  0.624  1.0
  Re  Re21  1  0.194  0.818  0.194  1.0
  Re  Re22  1  0.376  0.182  0.376  1.0
  Re  Re23  1  0.323  0.604  0.000  1.0
  Re  Re24  1  0.624  0.000  0.806  1.0
  Re  Re25  1  0.000  0.323  0.604  1.0
  Re  Re26  1  0.604  0.000  0.323  1.0
  Re  Re27  1  0.806  0.624  0.000  1.0
  Re  Re28  1  0.182  0.376  0.376  1.0
[/CIF]
.