The crystal structure described by Li2VMn(PO4)3 crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(24), one O(3), one O(6), and one O(8) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and  an edgeedge with one V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 64-68°. In the second Li site, Li(2) is bonded to one O(10), one O(19), one O(2), and one O(5) atom to form distorted LiO4 trigonal pyramids that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, and  an edgeedge with one V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 64-68°. In the third Li site, Li(3) is bonded to one O(1), one O(17), one O(19), and one O(22) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one Li(2)O4 trigonal pyramid, and  an edgeedge with one V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 64-69°. In the fourth Li site, Li(4) is bonded in a 4-coordinate geometry to one O(14), one O(21), one O(24), and one O(5) atom. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(10), one O(19), one O(20), one O(24), one O(3), and one O(4) atom to form VO6 octahedra that share  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  an edgeedge with one Li(1)O4 tetrahedra, and  an edgeedge with one Li(2)O4 trigonal pyramid. In the second V site, V(2) is bonded to one O(1), one O(15), one O(21), one O(22), one O(5), and one O(6) atom to form VO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one Li(2)O4 trigonal pyramid, and  an edgeedge with one Li(3)O4 tetrahedra. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(12), one O(14), one O(17), one O(23), one O(7), and one O(9) atom to form distorted MnO6 octahedra that share  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, and  a cornercorner with one P(6)O4 tetrahedra. In the second Mn site, Mn(2) is bonded to one O(11), one O(13), one O(16), one O(18), one O(2), and one O(8) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and  a cornercorner with one Li(2)O4 trigonal pyramid. There are six inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(3), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, and  a cornercorner with one Li(2)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 31-53°. In the second P site, P(2) is bonded to one O(4), one O(5), one O(8), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, and  a cornercorner with one Li(2)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 26-47°. In the third P site, P(3) is bonded to one O(10), one O(11), one O(12), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, and  a cornercorner with one Li(2)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 30-45°. In the fourth P site, P(4) is bonded to one O(13), one O(14), one O(15), and one O(19) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Li(3)O4 tetrahedra, and  a cornercorner with one Li(2)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 27-49°. In the fifth P site, P(5) is bonded to one O(16), one O(17), one O(20), and one O(21) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, and  a cornercorner with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 31-50°. In the sixth P site, P(6) is bonded to one O(18), one O(22), one O(23), and one O(24) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, and  a cornercorner with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 26-46°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one Li(3), one V(2), and one P(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Li(2), one Mn(2), and one P(1) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to one Li(1), one V(1), and one P(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one V(1) and one P(2) atom. In the fifth O site, O(5) is bonded to one Li(2), one Li(4), one V(2), and one P(2) atom to form distorted corner-sharing OLi2VP tetrahedra. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one Li(1), one V(2), and one P(3) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one Mn(1) and one P(1) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to one Li(1), one Mn(2), and one P(2) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one Mn(1) and one P(2) atom. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one Li(2), one V(1), and one P(3) atom. In the eleventh O site, O(11) is bonded in a distorted bent 150 degrees geometry to one Mn(2) and one P(3) atom. In the twelfth O site, O(12) is bonded in a bent 150 degrees geometry to one Mn(1) and one P(3) atom. In the thirteenth O site, O(13) is bonded in a bent 150 degrees geometry to one Mn(2) and one P(4) atom. In the fourteenth O site, O(14) is bonded in a distorted trigonal planar geometry to one Li(4), one Mn(1), and one P(4) atom. In the fifteenth O site, O(15) is bonded in a bent 150 degrees geometry to one V(2) and one P(4) atom. In the sixteenth O site, O(16) is bonded in a bent 150 degrees geometry to one Mn(2) and one P(5) atom. In the seventeenth O site, O(17) is bonded in a distorted trigonal planar geometry to one Li(3), one Mn(1), and one P(5) atom. In the eighteenth O site, O(18) is bonded in a bent 150 degrees geometry to one Mn(2) and one P(6) atom. In the nineteenth O site, O(19) is bonded to one Li(2), one Li(3), one V(1), and one P(4) atom to form distorted corner-sharing OLi2VP trigonal pyramids. In the twentieth O site, O(20) is bonded in a bent 150 degrees geometry to one V(1) and one P(5) atom. In the twenty-first O site, O(21) is bonded in a distorted trigonal planar geometry to one Li(4), one V(2), and one P(5) atom. In the twenty-second O site, O(22) is bonded in a distorted T-shaped geometry to one Li(3), one V(2), and one P(6) atom. In the twenty-third O site, O(23) is bonded in a distorted bent 150 degrees geometry to one Mn(1) and one P(6) atom. In the twenty-fourth O site, O(24) is bonded to one Li(1), one Li(4), one V(1), and one P(6) atom to form distorted corner-sharing OLi2VP trigonal pyramids. is represented by the CIF card [CIF]
data_Li2MnV(PO4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.331
_cell_length_b   8.366
_cell_length_c   8.889
_cell_angle_alpha   90.016
_cell_angle_beta   116.534
_cell_angle_gamma   119.373
_symmetry_Int_Tables_number   1
_cell_volume   463.477
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.945  0.262  0.873  1.0
  Li  Li1  1  0.189  0.924  0.853  1.0
  Li  Li2  1  0.051  0.735  0.127  1.0
  Li  Li3  1  0.403  0.326  0.144  1.0
  Mn  Mn4  1  0.289  0.151  0.436  1.0
  Mn  Mn5  1  0.705  0.847  0.564  1.0
  V  V6  1  0.318  0.654  0.955  1.0
  V  V7  1  0.697  0.343  0.043  1.0
  P  P8  1  0.803  0.540  0.753  1.0
  P  P9  1  0.213  0.256  0.751  1.0
  P  P10  1  0.501  0.966  0.742  1.0
  P  P11  1  0.496  0.038  0.248  1.0
  P  P12  1  0.780  0.742  0.249  1.0
  P  P13  1  0.210  0.461  0.254  1.0
  O  O14  1  0.746  0.515  0.905  1.0
  O  O15  1  0.883  0.749  0.750  1.0
  O  O16  1  0.002  0.521  0.825  1.0
  O  O17  1  0.294  0.470  0.806  1.0
  O  O18  1  0.371  0.214  0.902  1.0
  O  O19  1  0.684  0.165  0.886  1.0
  O  O20  1  0.616  0.390  0.584  1.0
  O  O21  1  0.996  0.128  0.741  1.0
  O  O22  1  0.198  0.209  0.579  1.0
  O  O23  1  0.355  0.839  0.813  1.0
  O  O24  1  0.622  0.881  0.726  1.0
  O  O25  1  0.365  0.989  0.571  1.0
  O  O26  1  0.631  0.014  0.415  1.0
  O  O27  1  0.376  0.126  0.263  1.0
  O  O28  1  0.640  0.176  0.178  1.0
  O  O29  1  0.806  0.789  0.429  1.0
  O  O30  1  0.988  0.862  0.250  1.0
  O  O31  1  0.399  0.621  0.418  1.0
  O  O32  1  0.310  0.846  0.095  1.0
  O  O33  1  0.607  0.779  0.110  1.0
  O  O34  1  0.686  0.524  0.186  1.0
  O  O35  1  0.014  0.482  0.189  1.0
  O  O36  1  0.147  0.259  0.273  1.0
  O  O37  1  0.258  0.467  0.098  1.0
[/CIF]
.
The crystal structure described by Li2VMn(PO4)3 crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(24), one O(3), one O(6), and one O(8) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and  an edgeedge with one V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 64-68°. In the second Li site, Li(2) is bonded to one O(10), one O(19), one O(2), and one O(5) atom to form distorted LiO4 trigonal pyramids that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, and  an edgeedge with one V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 64-68°. In the third Li site, Li(3) is bonded to one O(1), one O(17), one O(19), and one O(22) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one Li(2)O4 trigonal pyramid, and  an edgeedge with one V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 64-69°. In the fourth Li site, Li(4) is bonded in a 4-coordinate geometry to one O(14), one O(21), one O(24), and one O(5) atom. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(10), one O(19), one O(20), one O(24), one O(3), and one O(4) atom to form VO6 octahedra that share  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  an edgeedge with one Li(1)O4 tetrahedra, and  an edgeedge with one Li(2)O4 trigonal pyramid. In the second V site, V(2) is bonded to one O(1), one O(15), one O(21), one O(22), one O(5), and one O(6) atom to form VO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one Li(2)O4 trigonal pyramid, and  an edgeedge with one Li(3)O4 tetrahedra. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(12), one O(14), one O(17), one O(23), one O(7), and one O(9) atom to form distorted MnO6 octahedra that share  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, and  a cornercorner with one P(6)O4 tetrahedra. In the second Mn site, Mn(2) is bonded to one O(11), one O(13), one O(16), one O(18), one O(2), and one O(8) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and  a cornercorner with one Li(2)O4 trigonal pyramid. There are six inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(3), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, and  a cornercorner with one Li(2)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 31-53°. In the second P site, P(2) is bonded to one O(4), one O(5), one O(8), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, and  a cornercorner with one Li(2)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 26-47°. In the third P site, P(3) is bonded to one O(10), one O(11), one O(12), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, and  a cornercorner with one Li(2)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 30-45°. In the fourth P site, P(4) is bonded to one O(13), one O(14), one O(15), and one O(19) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Li(3)O4 tetrahedra, and  a cornercorner with one Li(2)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 27-49°. In the fifth P site, P(5) is bonded to one O(16), one O(17), one O(20), and one O(21) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, and  a cornercorner with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 31-50°. In the sixth P site, P(6) is bonded to one O(18), one O(22), one O(23), and one O(24) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, and  a cornercorner with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 26-46°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one Li(3), one V(2), and one P(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Li(2), one Mn(2), and one P(1) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to one Li(1), one V(1), and one P(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one V(1) and one P(2) atom. In the fifth O site, O(5) is bonded to one Li(2), one Li(4), one V(2), and one P(2) atom to form distorted corner-sharing OLi2VP tetrahedra. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one Li(1), one V(2), and one P(3) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one Mn(1) and one P(1) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to one Li(1), one Mn(2), and one P(2) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one Mn(1) and one P(2) atom. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one Li(2), one V(1), and one P(3) atom. In the eleventh O site, O(11) is bonded in a distorted bent 150 degrees geometry to one Mn(2) and one P(3) atom. In the twelfth O site, O(12) is bonded in a bent 150 degrees geometry to one Mn(1) and one P(3) atom. In the thirteenth O site, O(13) is bonded in a bent 150 degrees geometry to one Mn(2) and one P(4) atom. In the fourteenth O site, O(14) is bonded in a distorted trigonal planar geometry to one Li(4), one Mn(1), and one P(4) atom. In the fifteenth O site, O(15) is bonded in a bent 150 degrees geometry to one V(2) and one P(4) atom. In the sixteenth O site, O(16) is bonded in a bent 150 degrees geometry to one Mn(2) and one P(5) atom. In the seventeenth O site, O(17) is bonded in a distorted trigonal planar geometry to one Li(3), one Mn(1), and one P(5) atom. In the eighteenth O site, O(18) is bonded in a bent 150 degrees geometry to one Mn(2) and one P(6) atom. In the nineteenth O site, O(19) is bonded to one Li(2), one Li(3), one V(1), and one P(4) atom to form distorted corner-sharing OLi2VP trigonal pyramids. In the twentieth O site, O(20) is bonded in a bent 150 degrees geometry to one V(1) and one P(5) atom. In the twenty-first O site, O(21) is bonded in a distorted trigonal planar geometry to one Li(4), one V(2), and one P(5) atom. In the twenty-second O site, O(22) is bonded in a distorted T-shaped geometry to one Li(3), one V(2), and one P(6) atom. In the twenty-third O site, O(23) is bonded in a distorted bent 150 degrees geometry to one Mn(1) and one P(6) atom. In the twenty-fourth O site, O(24) is bonded to one Li(1), one Li(4), one V(1), and one P(6) atom to form distorted corner-sharing OLi2VP trigonal pyramids. is represented by the CIF card [CIF]
data_Li2MnV(PO4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.331
_cell_length_b   8.366
_cell_length_c   8.889
_cell_angle_alpha   90.016
_cell_angle_beta   116.534
_cell_angle_gamma   119.373
_symmetry_Int_Tables_number   1
_cell_volume   463.477
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.945  0.262  0.873  1.0
  Li  Li1  1  0.189  0.924  0.853  1.0
  Li  Li2  1  0.051  0.735  0.127  1.0
  Li  Li3  1  0.403  0.326  0.144  1.0
  Mn  Mn4  1  0.289  0.151  0.436  1.0
  Mn  Mn5  1  0.705  0.847  0.564  1.0
  V  V6  1  0.318  0.654  0.955  1.0
  V  V7  1  0.697  0.343  0.043  1.0
  P  P8  1  0.803  0.540  0.753  1.0
  P  P9  1  0.213  0.256  0.751  1.0
  P  P10  1  0.501  0.966  0.742  1.0
  P  P11  1  0.496  0.038  0.248  1.0
  P  P12  1  0.780  0.742  0.249  1.0
  P  P13  1  0.210  0.461  0.254  1.0
  O  O14  1  0.746  0.515  0.905  1.0
  O  O15  1  0.883  0.749  0.750  1.0
  O  O16  1  0.002  0.521  0.825  1.0
  O  O17  1  0.294  0.470  0.806  1.0
  O  O18  1  0.371  0.214  0.902  1.0
  O  O19  1  0.684  0.165  0.886  1.0
  O  O20  1  0.616  0.390  0.584  1.0
  O  O21  1  0.996  0.128  0.741  1.0
  O  O22  1  0.198  0.209  0.579  1.0
  O  O23  1  0.355  0.839  0.813  1.0
  O  O24  1  0.622  0.881  0.726  1.0
  O  O25  1  0.365  0.989  0.571  1.0
  O  O26  1  0.631  0.014  0.415  1.0
  O  O27  1  0.376  0.126  0.263  1.0
  O  O28  1  0.640  0.176  0.178  1.0
  O  O29  1  0.806  0.789  0.429  1.0
  O  O30  1  0.988  0.862  0.250  1.0
  O  O31  1  0.399  0.621  0.418  1.0
  O  O32  1  0.310  0.846  0.095  1.0
  O  O33  1  0.607  0.779  0.110  1.0
  O  O34  1  0.686  0.524  0.186  1.0
  O  O35  1  0.014  0.482  0.189  1.0
  O  O36  1  0.147  0.259  0.273  1.0
  O  O37  1  0.258  0.467  0.098  1.0
[/CIF]
.