The structure described by V6O11F is Hydrophilite-derived structured and crystallizes in the triclinic P1 space group. There are six inequivalent V sites. In the first V site, V(1) is bonded to one O(3), one O(5), one O(6), one O(7), one O(9), and one F(1) atom to form VO5F octahedra that share corners with two equivalent V(5)O5F octahedra, corners with two equivalent V(6)O6 octahedra, corners with four equivalent V(4)O5F octahedra,  an edgeedge with one V(2)O6 octahedra, and  an edgeedge with one V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-50°. In the second V site, V(2) is bonded to one O(11), one O(2), one O(4), one O(5), one O(8), and one O(9) atom to form VO6 octahedra that share corners with two equivalent V(4)O5F octahedra, corners with two equivalent V(5)O5F octahedra, corners with four equivalent V(6)O6 octahedra,  an edgeedge with one V(1)O5F octahedra, and  an edgeedge with one V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 42-53°. In the third V site, V(3) is bonded to one O(1), one O(10), one O(4), one O(6), one O(7), and one O(8) atom to form VO6 octahedra that share corners with two equivalent V(4)O5F octahedra, corners with two equivalent V(6)O6 octahedra, corners with four equivalent V(5)O5F octahedra,  an edgeedge with one V(1)O5F octahedra, and  an edgeedge with one V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-55°. In the fourth V site, V(4) is bonded to one O(1), one O(11), one O(3), one O(5), one O(7), and one F(1) atom to form VO5F octahedra that share corners with two equivalent V(2)O6 octahedra, corners with two equivalent V(3)O6 octahedra, corners with four equivalent V(1)O5F octahedra,  an edgeedge with one V(5)O5F octahedra, and  an edgeedge with one V(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 42-53°. In the fifth V site, V(5) is bonded to one O(1), one O(10), one O(2), one O(6), one O(8), and one F(1) atom to form VO5F octahedra that share corners with two equivalent V(1)O5F octahedra, corners with two equivalent V(2)O6 octahedra, corners with four equivalent V(3)O6 octahedra,  an edgeedge with one V(4)O5F octahedra, and  an edgeedge with one V(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-55°. In the sixth V site, V(6) is bonded to one O(10), one O(11), one O(2), one O(3), one O(4), and one O(9) atom to form VO6 octahedra that share corners with two equivalent V(1)O5F octahedra, corners with two equivalent V(3)O6 octahedra, corners with four equivalent V(2)O6 octahedra,  an edgeedge with one V(4)O5F octahedra, and  an edgeedge with one V(5)O5F octahedra. The corner-sharing octahedral tilt angles range from 46-52°. There are eleven inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one V(3), one V(4), and one V(5) atom. In the second O site, O(2) is bonded in a distorted T-shaped geometry to one V(2), one V(5), and one V(6) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to one V(1), one V(4), and one V(6) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one V(2), one V(3), and one V(6) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one V(4) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one V(1), one V(3), and one V(5) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to one V(1), one V(3), and one V(4) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to one V(2), one V(3), and one V(5) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one V(6) atom. In the tenth O site, O(10) is bonded in a distorted T-shaped geometry to one V(3), one V(5), and one V(6) atom. In the eleventh O site, O(11) is bonded in a distorted T-shaped geometry to one V(2), one V(4), and one V(6) atom. F(1) is bonded in a distorted trigonal planar geometry to one V(1), one V(4), and one V(5) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_V6O11F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.567
_cell_length_b   5.399
_cell_length_c   7.326
_cell_angle_alpha   83.631
_cell_angle_beta   89.331
_cell_angle_gamma   89.103
_symmetry_Int_Tables_number   1
_cell_volume   179.495
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.521  0.838  0.676  1.0
  V  V1  1  0.489  0.494  0.997  1.0
  V  V2  1  0.498  0.174  0.331  1.0
  V  V3  1  0.990  0.311  0.669  1.0
  V  V4  1  0.978  0.673  0.314  1.0
  V  V5  1  0.011  0.008  0.005  1.0
  O  O6  1  0.811  0.374  0.436  1.0
  O  O7  1  0.796  0.698  0.101  1.0
  O  O8  1  0.799  0.032  0.766  1.0
  O  O9  1  0.703  0.199  0.102  1.0
  O  O10  1  0.703  0.533  0.764  1.0
  O  O11  1  0.700  0.866  0.437  1.0
  O  O12  1  0.305  0.127  0.569  1.0
  O  O13  1  0.296  0.468  0.238  1.0
  O  O14  1  0.299  0.804  0.897  1.0
  O  O15  1  0.202  0.964  0.237  1.0
  O  O16  1  0.200  0.305  0.897  1.0
  F  F17  1  0.201  0.631  0.566  1.0
[/CIF]
.
The structure described by V6O11F is Hydrophilite-derived structured and crystallizes in the triclinic P1 space group. There are six inequivalent V sites. In the first V site, V(1) is bonded to one O(3), one O(5), one O(6), one O(7), one O(9), and one F(1) atom to form VO5F octahedra that share corners with two equivalent V(5)O5F octahedra, corners with two equivalent V(6)O6 octahedra, corners with four equivalent V(4)O5F octahedra,  an edgeedge with one V(2)O6 octahedra, and  an edgeedge with one V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-50°. In the second V site, V(2) is bonded to one O(11), one O(2), one O(4), one O(5), one O(8), and one O(9) atom to form VO6 octahedra that share corners with two equivalent V(4)O5F octahedra, corners with two equivalent V(5)O5F octahedra, corners with four equivalent V(6)O6 octahedra,  an edgeedge with one V(1)O5F octahedra, and  an edgeedge with one V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 42-53°. In the third V site, V(3) is bonded to one O(1), one O(10), one O(4), one O(6), one O(7), and one O(8) atom to form VO6 octahedra that share corners with two equivalent V(4)O5F octahedra, corners with two equivalent V(6)O6 octahedra, corners with four equivalent V(5)O5F octahedra,  an edgeedge with one V(1)O5F octahedra, and  an edgeedge with one V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-55°. In the fourth V site, V(4) is bonded to one O(1), one O(11), one O(3), one O(5), one O(7), and one F(1) atom to form VO5F octahedra that share corners with two equivalent V(2)O6 octahedra, corners with two equivalent V(3)O6 octahedra, corners with four equivalent V(1)O5F octahedra,  an edgeedge with one V(5)O5F octahedra, and  an edgeedge with one V(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 42-53°. In the fifth V site, V(5) is bonded to one O(1), one O(10), one O(2), one O(6), one O(8), and one F(1) atom to form VO5F octahedra that share corners with two equivalent V(1)O5F octahedra, corners with two equivalent V(2)O6 octahedra, corners with four equivalent V(3)O6 octahedra,  an edgeedge with one V(4)O5F octahedra, and  an edgeedge with one V(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-55°. In the sixth V site, V(6) is bonded to one O(10), one O(11), one O(2), one O(3), one O(4), and one O(9) atom to form VO6 octahedra that share corners with two equivalent V(1)O5F octahedra, corners with two equivalent V(3)O6 octahedra, corners with four equivalent V(2)O6 octahedra,  an edgeedge with one V(4)O5F octahedra, and  an edgeedge with one V(5)O5F octahedra. The corner-sharing octahedral tilt angles range from 46-52°. There are eleven inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one V(3), one V(4), and one V(5) atom. In the second O site, O(2) is bonded in a distorted T-shaped geometry to one V(2), one V(5), and one V(6) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to one V(1), one V(4), and one V(6) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one V(2), one V(3), and one V(6) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one V(4) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one V(1), one V(3), and one V(5) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to one V(1), one V(3), and one V(4) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to one V(2), one V(3), and one V(5) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one V(6) atom. In the tenth O site, O(10) is bonded in a distorted T-shaped geometry to one V(3), one V(5), and one V(6) atom. In the eleventh O site, O(11) is bonded in a distorted T-shaped geometry to one V(2), one V(4), and one V(6) atom. F(1) is bonded in a distorted trigonal planar geometry to one V(1), one V(4), and one V(5) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_V6O11F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.567
_cell_length_b   5.399
_cell_length_c   7.326
_cell_angle_alpha   83.631
_cell_angle_beta   89.331
_cell_angle_gamma   89.103
_symmetry_Int_Tables_number   1
_cell_volume   179.495
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.521  0.838  0.676  1.0
  V  V1  1  0.489  0.494  0.997  1.0
  V  V2  1  0.498  0.174  0.331  1.0
  V  V3  1  0.990  0.311  0.669  1.0
  V  V4  1  0.978  0.673  0.314  1.0
  V  V5  1  0.011  0.008  0.005  1.0
  O  O6  1  0.811  0.374  0.436  1.0
  O  O7  1  0.796  0.698  0.101  1.0
  O  O8  1  0.799  0.032  0.766  1.0
  O  O9  1  0.703  0.199  0.102  1.0
  O  O10  1  0.703  0.533  0.764  1.0
  O  O11  1  0.700  0.866  0.437  1.0
  O  O12  1  0.305  0.127  0.569  1.0
  O  O13  1  0.296  0.468  0.238  1.0
  O  O14  1  0.299  0.804  0.897  1.0
  O  O15  1  0.202  0.964  0.237  1.0
  O  O16  1  0.200  0.305  0.897  1.0
  F  F17  1  0.201  0.631  0.566  1.0
[/CIF]
.