The material described by Li2RhN2 crystallizes in the trigonal P-3m1 space group. Li(1) is bonded to four equivalent N(1) atoms to form distorted LiN4 tetrahedra that share corners with six equivalent Rh(1)N6 octahedra, corners with six equivalent Li(1)N4 tetrahedra, edges with three equivalent Rh(1)N6 octahedra, and edges with three equivalent Li(1)N4 tetrahedra. The corner-sharing octahedral tilt angles range from 8-60°. Rh(1) is bonded to six equivalent N(1) atoms to form distorted RhN6 octahedra that share corners with twelve equivalent Li(1)N4 tetrahedra, edges with six equivalent Rh(1)N6 octahedra, and edges with six equivalent Li(1)N4 tetrahedra. N(1) is bonded in a 7-coordinate geometry to four equivalent Li(1) and three equivalent Rh(1) atoms. is represented by the CIF file [CIF]
data_Li2RhN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.221
_cell_length_b   3.222
_cell_length_c   5.076
_cell_angle_alpha   89.985
_cell_angle_beta   90.010
_cell_angle_gamma   120.001
_symmetry_Int_Tables_number   1
_cell_volume   45.620
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.667  0.333  0.354  1.0
  Li  Li1  1  0.333  0.667  0.646  1.0
  Rh  Rh2  1  0.000  0.000  0.000  1.0
  N  N3  1  0.667  0.333  0.791  1.0
  N  N4  1  0.333  0.667  0.209  1.0
[/CIF]
.
The material described by Li2RhN2 crystallizes in the trigonal P-3m1 space group. Li(1) is bonded to four equivalent N(1) atoms to form distorted LiN4 tetrahedra that share corners with six equivalent Rh(1)N6 octahedra, corners with six equivalent Li(1)N4 tetrahedra, edges with three equivalent Rh(1)N6 octahedra, and edges with three equivalent Li(1)N4 tetrahedra. The corner-sharing octahedral tilt angles range from 8-60°. Rh(1) is bonded to six equivalent N(1) atoms to form distorted RhN6 octahedra that share corners with twelve equivalent Li(1)N4 tetrahedra, edges with six equivalent Rh(1)N6 octahedra, and edges with six equivalent Li(1)N4 tetrahedra. N(1) is bonded in a 7-coordinate geometry to four equivalent Li(1) and three equivalent Rh(1) atoms. is represented by the CIF file [CIF]
data_Li2RhN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.221
_cell_length_b   3.222
_cell_length_c   5.076
_cell_angle_alpha   89.985
_cell_angle_beta   90.010
_cell_angle_gamma   120.001
_symmetry_Int_Tables_number   1
_cell_volume   45.620
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.667  0.333  0.354  1.0
  Li  Li1  1  0.333  0.667  0.646  1.0
  Rh  Rh2  1  0.000  0.000  0.000  1.0
  N  N3  1  0.667  0.333  0.791  1.0
  N  N4  1  0.333  0.667  0.209  1.0
[/CIF]
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