The structure described by Na3IrN2S2(O5Cl2)2 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(4), one Cl(1), and two equivalent Cl(2) atoms. In the second Na site, Na(2) is bonded to two equivalent O(3), two equivalent Cl(1), and two equivalent Cl(2) atoms to form distorted NaCl4O2 octahedra that share edges with two equivalent Ir(1)S2Cl4 octahedra. Ir(1) is bonded to two equivalent S(1), two equivalent Cl(1), and two equivalent Cl(2) atoms to form IrS2Cl4 octahedra that share edges with two equivalent Na(2)Cl4O2 octahedra. N(1) is bonded in a bent 120 degrees geometry to one O(4) and one O(5) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one Ir(1), one O(1), one O(2), and one O(3) atom. There are five inequivalent O sites. In the first O site, O(3) is bonded in a bent 120 degrees geometry to one Na(2) and one S(1) atom. In the second O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Na(1) and one N(1) atom. In the third O site, O(5) is bonded in a single-bond geometry to one N(1) atom. In the fourth O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Na(1) and one S(1) atom. In the fifth O site, O(2) is bonded in a bent 150 degrees geometry to one Na(1) and one S(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a T-shaped geometry to one Na(1), one Na(2), and one Ir(1) atom. In the second Cl site, Cl(2) is bonded to one Na(2), two equivalent Na(1), and one Ir(1) atom to form corner-sharing ClNa3Ir tetrahedra. is represented by the CIF card [CIF]
data_Na3IrS2N2(Cl2O5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.677
_cell_length_b   7.327
_cell_length_c   12.983
_cell_angle_alpha   72.174
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   876.359
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.202  0.046  0.238  1.0
  Na  Na1  1  0.702  0.954  0.262  1.0
  Na  Na2  1  0.798  0.954  0.762  1.0
  Na  Na3  1  0.298  0.046  0.738  1.0
  Na  Na4  1  0.000  0.500  0.500  1.0
  Na  Na5  1  0.500  0.500  0.000  1.0
  Ir  Ir6  1  0.000  0.000  0.500  1.0
  Ir  Ir7  1  0.500  0.000  0.000  1.0
  S  S8  1  0.234  0.832  0.521  1.0
  S  S9  1  0.734  0.168  0.979  1.0
  S  S10  1  0.766  0.168  0.479  1.0
  S  S11  1  0.266  0.832  0.021  1.0
  N  N12  1  0.042  0.520  0.876  1.0
  N  N13  1  0.542  0.480  0.624  1.0
  N  N14  1  0.958  0.480  0.124  1.0
  N  N15  1  0.458  0.520  0.376  1.0
  Cl  Cl16  1  0.897  0.732  0.620  1.0
  Cl  Cl17  1  0.397  0.268  0.880  1.0
  Cl  Cl18  1  0.103  0.268  0.380  1.0
  Cl  Cl19  1  0.603  0.732  0.120  1.0
  Cl  Cl20  1  0.035  0.130  0.644  1.0
  Cl  Cl21  1  0.535  0.870  0.856  1.0
  Cl  Cl22  1  0.965  0.870  0.356  1.0
  Cl  Cl23  1  0.465  0.130  0.144  1.0
  O  O24  1  0.299  0.909  0.414  1.0
  O  O25  1  0.799  0.091  0.086  1.0
  O  O26  1  0.701  0.091  0.586  1.0
  O  O27  1  0.201  0.909  0.914  1.0
  O  O28  1  0.302  0.887  0.608  1.0
  O  O29  1  0.802  0.113  0.892  1.0
  O  O30  1  0.698  0.113  0.392  1.0
  O  O31  1  0.198  0.887  0.108  1.0
  O  O32  1  0.199  0.627  0.550  1.0
  O  O33  1  0.699  0.373  0.950  1.0
  O  O34  1  0.801  0.373  0.450  1.0
  O  O35  1  0.301  0.627  0.050  1.0
  O  O36  1  0.450  0.370  0.618  1.0
  O  O37  1  0.950  0.630  0.882  1.0
  O  O38  1  0.550  0.630  0.382  1.0
  O  O39  1  0.050  0.370  0.118  1.0
  O  O40  1  0.552  0.653  0.591  1.0
  O  O41  1  0.052  0.347  0.909  1.0
  O  O42  1  0.448  0.347  0.409  1.0
  O  O43  1  0.948  0.653  0.091  1.0
[/CIF]
.
The structure described by Na3IrN2S2(O5Cl2)2 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(4), one Cl(1), and two equivalent Cl(2) atoms. In the second Na site, Na(2) is bonded to two equivalent O(3), two equivalent Cl(1), and two equivalent Cl(2) atoms to form distorted NaCl4O2 octahedra that share edges with two equivalent Ir(1)S2Cl4 octahedra. Ir(1) is bonded to two equivalent S(1), two equivalent Cl(1), and two equivalent Cl(2) atoms to form IrS2Cl4 octahedra that share edges with two equivalent Na(2)Cl4O2 octahedra. N(1) is bonded in a bent 120 degrees geometry to one O(4) and one O(5) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one Ir(1), one O(1), one O(2), and one O(3) atom. There are five inequivalent O sites. In the first O site, O(3) is bonded in a bent 120 degrees geometry to one Na(2) and one S(1) atom. In the second O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Na(1) and one N(1) atom. In the third O site, O(5) is bonded in a single-bond geometry to one N(1) atom. In the fourth O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Na(1) and one S(1) atom. In the fifth O site, O(2) is bonded in a bent 150 degrees geometry to one Na(1) and one S(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a T-shaped geometry to one Na(1), one Na(2), and one Ir(1) atom. In the second Cl site, Cl(2) is bonded to one Na(2), two equivalent Na(1), and one Ir(1) atom to form corner-sharing ClNa3Ir tetrahedra. is represented by the CIF card [CIF]
data_Na3IrS2N2(Cl2O5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.677
_cell_length_b   7.327
_cell_length_c   12.983
_cell_angle_alpha   72.174
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   876.359
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.202  0.046  0.238  1.0
  Na  Na1  1  0.702  0.954  0.262  1.0
  Na  Na2  1  0.798  0.954  0.762  1.0
  Na  Na3  1  0.298  0.046  0.738  1.0
  Na  Na4  1  0.000  0.500  0.500  1.0
  Na  Na5  1  0.500  0.500  0.000  1.0
  Ir  Ir6  1  0.000  0.000  0.500  1.0
  Ir  Ir7  1  0.500  0.000  0.000  1.0
  S  S8  1  0.234  0.832  0.521  1.0
  S  S9  1  0.734  0.168  0.979  1.0
  S  S10  1  0.766  0.168  0.479  1.0
  S  S11  1  0.266  0.832  0.021  1.0
  N  N12  1  0.042  0.520  0.876  1.0
  N  N13  1  0.542  0.480  0.624  1.0
  N  N14  1  0.958  0.480  0.124  1.0
  N  N15  1  0.458  0.520  0.376  1.0
  Cl  Cl16  1  0.897  0.732  0.620  1.0
  Cl  Cl17  1  0.397  0.268  0.880  1.0
  Cl  Cl18  1  0.103  0.268  0.380  1.0
  Cl  Cl19  1  0.603  0.732  0.120  1.0
  Cl  Cl20  1  0.035  0.130  0.644  1.0
  Cl  Cl21  1  0.535  0.870  0.856  1.0
  Cl  Cl22  1  0.965  0.870  0.356  1.0
  Cl  Cl23  1  0.465  0.130  0.144  1.0
  O  O24  1  0.299  0.909  0.414  1.0
  O  O25  1  0.799  0.091  0.086  1.0
  O  O26  1  0.701  0.091  0.586  1.0
  O  O27  1  0.201  0.909  0.914  1.0
  O  O28  1  0.302  0.887  0.608  1.0
  O  O29  1  0.802  0.113  0.892  1.0
  O  O30  1  0.698  0.113  0.392  1.0
  O  O31  1  0.198  0.887  0.108  1.0
  O  O32  1  0.199  0.627  0.550  1.0
  O  O33  1  0.699  0.373  0.950  1.0
  O  O34  1  0.801  0.373  0.450  1.0
  O  O35  1  0.301  0.627  0.050  1.0
  O  O36  1  0.450  0.370  0.618  1.0
  O  O37  1  0.950  0.630  0.882  1.0
  O  O38  1  0.550  0.630  0.382  1.0
  O  O39  1  0.050  0.370  0.118  1.0
  O  O40  1  0.552  0.653  0.591  1.0
  O  O41  1  0.052  0.347  0.909  1.0
  O  O42  1  0.448  0.347  0.409  1.0
  O  O43  1  0.948  0.653  0.091  1.0
[/CIF]
.