The structure described by LaWO4Cl crystallizes in the orthorhombic Pnma space group. La(1) is bonded in a 7-coordinate geometry to one O(2), four equivalent O(1), and four equivalent Cl(1) atoms. W(1) is bonded to one O(2), two equivalent O(1), and two equivalent O(3) atoms to form corner-sharing WO5 trigonal bipyramids. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent La(1) and one W(1) atom. In the second O site, O(2) is bonded in a linear geometry to one La(1) and one W(1) atom. In the third O site, O(3) is bonded in a linear geometry to two equivalent W(1) atoms. Cl(1) is bonded to four equivalent La(1) atoms to form a mixture of distorted edge and corner-sharing ClLa4 tetrahedra. is represented by the CIF card [CIF]
data_LaWClO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.940
_cell_length_b   6.058
_cell_length_c   19.542
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   466.359
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.256  0.750  0.103  1.0
  La  La1  1  0.744  0.250  0.897  1.0
  La  La2  1  0.244  0.750  0.603  1.0
  La  La3  1  0.756  0.250  0.397  1.0
  W  W4  1  0.709  0.250  0.679  1.0
  W  W5  1  0.791  0.250  0.179  1.0
  W  W6  1  0.291  0.750  0.321  1.0
  W  W7  1  0.209  0.750  0.821  1.0
  Cl  Cl8  1  0.747  0.750  0.488  1.0
  Cl  Cl9  1  0.753  0.750  0.988  1.0
  Cl  Cl10  1  0.253  0.250  0.512  1.0
  Cl  Cl11  1  0.247  0.250  0.012  1.0
  O  O12  1  0.255  0.020  0.366  1.0
  O  O13  1  0.755  0.520  0.134  1.0
  O  O14  1  0.754  0.250  0.271  1.0
  O  O15  1  0.755  0.980  0.134  1.0
  O  O16  1  0.265  0.250  0.175  1.0
  O  O17  1  0.245  0.480  0.866  1.0
  O  O18  1  0.746  0.250  0.771  1.0
  O  O19  1  0.246  0.750  0.729  1.0
  O  O20  1  0.254  0.750  0.229  1.0
  O  O21  1  0.255  0.480  0.366  1.0
  O  O22  1  0.235  0.250  0.675  1.0
  O  O23  1  0.765  0.750  0.325  1.0
  O  O24  1  0.735  0.750  0.825  1.0
  O  O25  1  0.745  0.980  0.634  1.0
  O  O26  1  0.245  0.020  0.866  1.0
  O  O27  1  0.745  0.520  0.634  1.0
[/CIF]
.
The structure described by LaWO4Cl crystallizes in the orthorhombic Pnma space group. La(1) is bonded in a 7-coordinate geometry to one O(2), four equivalent O(1), and four equivalent Cl(1) atoms. W(1) is bonded to one O(2), two equivalent O(1), and two equivalent O(3) atoms to form corner-sharing WO5 trigonal bipyramids. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent La(1) and one W(1) atom. In the second O site, O(2) is bonded in a linear geometry to one La(1) and one W(1) atom. In the third O site, O(3) is bonded in a linear geometry to two equivalent W(1) atoms. Cl(1) is bonded to four equivalent La(1) atoms to form a mixture of distorted edge and corner-sharing ClLa4 tetrahedra. is represented by the CIF card [CIF]
data_LaWClO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.940
_cell_length_b   6.058
_cell_length_c   19.542
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   466.359
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.256  0.750  0.103  1.0
  La  La1  1  0.744  0.250  0.897  1.0
  La  La2  1  0.244  0.750  0.603  1.0
  La  La3  1  0.756  0.250  0.397  1.0
  W  W4  1  0.709  0.250  0.679  1.0
  W  W5  1  0.791  0.250  0.179  1.0
  W  W6  1  0.291  0.750  0.321  1.0
  W  W7  1  0.209  0.750  0.821  1.0
  Cl  Cl8  1  0.747  0.750  0.488  1.0
  Cl  Cl9  1  0.753  0.750  0.988  1.0
  Cl  Cl10  1  0.253  0.250  0.512  1.0
  Cl  Cl11  1  0.247  0.250  0.012  1.0
  O  O12  1  0.255  0.020  0.366  1.0
  O  O13  1  0.755  0.520  0.134  1.0
  O  O14  1  0.754  0.250  0.271  1.0
  O  O15  1  0.755  0.980  0.134  1.0
  O  O16  1  0.265  0.250  0.175  1.0
  O  O17  1  0.245  0.480  0.866  1.0
  O  O18  1  0.746  0.250  0.771  1.0
  O  O19  1  0.246  0.750  0.729  1.0
  O  O20  1  0.254  0.750  0.229  1.0
  O  O21  1  0.255  0.480  0.366  1.0
  O  O22  1  0.235  0.250  0.675  1.0
  O  O23  1  0.765  0.750  0.325  1.0
  O  O24  1  0.735  0.750  0.825  1.0
  O  O25  1  0.745  0.980  0.634  1.0
  O  O26  1  0.245  0.020  0.866  1.0
  O  O27  1  0.745  0.520  0.634  1.0
[/CIF]
.