The crystal structure described by K(NaIn3)3 crystallizes in the orthorhombic Cmce space group. K(1) is bonded in a 7-coordinate geometry to one In(5), two equivalent In(3), two equivalent In(6), and four equivalent In(4) atoms. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded in a 9-coordinate geometry to one In(1), one In(4), one In(5), one In(6), one In(7), two equivalent In(2), and two equivalent In(3) atoms. In the second Na site, Na(2) is bonded in a 4-coordinate geometry to two equivalent In(1), two equivalent In(3), two equivalent In(4), and two equivalent In(7) atoms. There are seven inequivalent In sites. In the first In site, In(1) is bonded in a 10-coordinate geometry to two equivalent Na(1), two equivalent Na(2), one In(2), one In(7), two equivalent In(3), and two equivalent In(4) atoms. In the second In site, In(7) is bonded in a 8-coordinate geometry to two equivalent Na(1), two equivalent Na(2), one In(1), one In(5), and two equivalent In(6) atoms. In the third In site, In(2) is bonded in a 10-coordinate geometry to four equivalent Na(1), one In(1), one In(5), two equivalent In(3), and two equivalent In(4) atoms. In the fourth In site, In(3) is bonded in a 10-coordinate geometry to one K(1), one Na(2), two equivalent Na(1), one In(1), one In(2), one In(3), one In(5), and two equivalent In(4) atoms. In the fifth In site, In(4) is bonded in a 10-coordinate geometry to two equivalent K(1), one Na(1), one Na(2), one In(1), one In(2), one In(4), one In(6), and two equivalent In(3) atoms. In the sixth In site, In(5) is bonded in a 7-coordinate geometry to one K(1), two equivalent Na(1), one In(2), one In(7), and two equivalent In(3) atoms. In the seventh In site, In(6) is bonded in a 2-coordinate geometry to two equivalent K(1), two equivalent Na(1), two equivalent In(4), and two equivalent In(7) atoms. is represented by the CIF card [CIF]
data_K(NaIn3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.901
_cell_length_b   9.901
_cell_length_c   17.791
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   117.706
_symmetry_Int_Tables_number   1
_cell_volume   1544.067
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.466  0.534  0.341  1.0
  K  K1  1  0.534  0.466  0.659  1.0
  K  K2  1  0.034  0.966  0.841  1.0
  K  K3  1  0.966  0.034  0.159  1.0
  Na  Na4  1  0.960  0.424  0.089  1.0
  Na  Na5  1  0.424  0.960  0.911  1.0
  Na  Na6  1  0.924  0.460  0.589  1.0
  Na  Na7  1  0.460  0.924  0.411  1.0
  Na  Na8  1  0.040  0.576  0.911  1.0
  Na  Na9  1  0.576  0.040  0.089  1.0
  Na  Na10  1  0.076  0.540  0.411  1.0
  Na  Na11  1  0.540  0.076  0.589  1.0
  Na  Na12  1  0.865  0.635  0.250  1.0
  Na  Na13  1  0.635  0.865  0.750  1.0
  Na  Na14  1  0.135  0.365  0.750  1.0
  Na  Na15  1  0.365  0.135  0.250  1.0
  In  In16  1  0.604  0.396  0.139  1.0
  In  In17  1  0.396  0.604  0.861  1.0
  In  In18  1  0.896  0.104  0.639  1.0
  In  In19  1  0.104  0.896  0.361  1.0
  In  In20  1  0.663  0.337  0.977  1.0
  In  In21  1  0.337  0.663  0.023  1.0
  In  In22  1  0.837  0.163  0.477  1.0
  In  In23  1  0.163  0.837  0.523  1.0
  In  In24  1  0.840  0.677  0.038  1.0
  In  In25  1  0.677  0.840  0.962  1.0
  In  In26  1  0.177  0.340  0.538  1.0
  In  In27  1  0.340  0.177  0.462  1.0
  In  In28  1  0.160  0.323  0.962  1.0
  In  In29  1  0.323  0.160  0.038  1.0
  In  In30  1  0.823  0.660  0.462  1.0
  In  In31  1  0.660  0.823  0.538  1.0
  In  In32  1  0.293  0.407  0.130  1.0
  In  In33  1  0.407  0.293  0.870  1.0
  In  In34  1  0.907  0.793  0.630  1.0
  In  In35  1  0.793  0.907  0.370  1.0
  In  In36  1  0.707  0.593  0.870  1.0
  In  In37  1  0.593  0.707  0.130  1.0
  In  In38  1  0.093  0.207  0.370  1.0
  In  In39  1  0.207  0.093  0.630  1.0
  In  In40  1  0.826  0.174  0.914  1.0
  In  In41  1  0.174  0.826  0.086  1.0
  In  In42  1  0.674  0.326  0.414  1.0
  In  In43  1  0.326  0.674  0.586  1.0
  In  In44  1  0.587  0.913  0.250  1.0
  In  In45  1  0.913  0.587  0.750  1.0
  In  In46  1  0.413  0.087  0.750  1.0
  In  In47  1  0.087  0.413  0.250  1.0
  In  In48  1  0.742  0.258  0.255  1.0
  In  In49  1  0.258  0.742  0.745  1.0
  In  In50  1  0.758  0.242  0.755  1.0
  In  In51  1  0.242  0.758  0.245  1.0
[/CIF]
.
The crystal structure described by K(NaIn3)3 crystallizes in the orthorhombic Cmce space group. K(1) is bonded in a 7-coordinate geometry to one In(5), two equivalent In(3), two equivalent In(6), and four equivalent In(4) atoms. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded in a 9-coordinate geometry to one In(1), one In(4), one In(5), one In(6), one In(7), two equivalent In(2), and two equivalent In(3) atoms. In the second Na site, Na(2) is bonded in a 4-coordinate geometry to two equivalent In(1), two equivalent In(3), two equivalent In(4), and two equivalent In(7) atoms. There are seven inequivalent In sites. In the first In site, In(1) is bonded in a 10-coordinate geometry to two equivalent Na(1), two equivalent Na(2), one In(2), one In(7), two equivalent In(3), and two equivalent In(4) atoms. In the second In site, In(7) is bonded in a 8-coordinate geometry to two equivalent Na(1), two equivalent Na(2), one In(1), one In(5), and two equivalent In(6) atoms. In the third In site, In(2) is bonded in a 10-coordinate geometry to four equivalent Na(1), one In(1), one In(5), two equivalent In(3), and two equivalent In(4) atoms. In the fourth In site, In(3) is bonded in a 10-coordinate geometry to one K(1), one Na(2), two equivalent Na(1), one In(1), one In(2), one In(3), one In(5), and two equivalent In(4) atoms. In the fifth In site, In(4) is bonded in a 10-coordinate geometry to two equivalent K(1), one Na(1), one Na(2), one In(1), one In(2), one In(4), one In(6), and two equivalent In(3) atoms. In the sixth In site, In(5) is bonded in a 7-coordinate geometry to one K(1), two equivalent Na(1), one In(2), one In(7), and two equivalent In(3) atoms. In the seventh In site, In(6) is bonded in a 2-coordinate geometry to two equivalent K(1), two equivalent Na(1), two equivalent In(4), and two equivalent In(7) atoms. is represented by the CIF card [CIF]
data_K(NaIn3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.901
_cell_length_b   9.901
_cell_length_c   17.791
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   117.706
_symmetry_Int_Tables_number   1
_cell_volume   1544.067
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.466  0.534  0.341  1.0
  K  K1  1  0.534  0.466  0.659  1.0
  K  K2  1  0.034  0.966  0.841  1.0
  K  K3  1  0.966  0.034  0.159  1.0
  Na  Na4  1  0.960  0.424  0.089  1.0
  Na  Na5  1  0.424  0.960  0.911  1.0
  Na  Na6  1  0.924  0.460  0.589  1.0
  Na  Na7  1  0.460  0.924  0.411  1.0
  Na  Na8  1  0.040  0.576  0.911  1.0
  Na  Na9  1  0.576  0.040  0.089  1.0
  Na  Na10  1  0.076  0.540  0.411  1.0
  Na  Na11  1  0.540  0.076  0.589  1.0
  Na  Na12  1  0.865  0.635  0.250  1.0
  Na  Na13  1  0.635  0.865  0.750  1.0
  Na  Na14  1  0.135  0.365  0.750  1.0
  Na  Na15  1  0.365  0.135  0.250  1.0
  In  In16  1  0.604  0.396  0.139  1.0
  In  In17  1  0.396  0.604  0.861  1.0
  In  In18  1  0.896  0.104  0.639  1.0
  In  In19  1  0.104  0.896  0.361  1.0
  In  In20  1  0.663  0.337  0.977  1.0
  In  In21  1  0.337  0.663  0.023  1.0
  In  In22  1  0.837  0.163  0.477  1.0
  In  In23  1  0.163  0.837  0.523  1.0
  In  In24  1  0.840  0.677  0.038  1.0
  In  In25  1  0.677  0.840  0.962  1.0
  In  In26  1  0.177  0.340  0.538  1.0
  In  In27  1  0.340  0.177  0.462  1.0
  In  In28  1  0.160  0.323  0.962  1.0
  In  In29  1  0.323  0.160  0.038  1.0
  In  In30  1  0.823  0.660  0.462  1.0
  In  In31  1  0.660  0.823  0.538  1.0
  In  In32  1  0.293  0.407  0.130  1.0
  In  In33  1  0.407  0.293  0.870  1.0
  In  In34  1  0.907  0.793  0.630  1.0
  In  In35  1  0.793  0.907  0.370  1.0
  In  In36  1  0.707  0.593  0.870  1.0
  In  In37  1  0.593  0.707  0.130  1.0
  In  In38  1  0.093  0.207  0.370  1.0
  In  In39  1  0.207  0.093  0.630  1.0
  In  In40  1  0.826  0.174  0.914  1.0
  In  In41  1  0.174  0.826  0.086  1.0
  In  In42  1  0.674  0.326  0.414  1.0
  In  In43  1  0.326  0.674  0.586  1.0
  In  In44  1  0.587  0.913  0.250  1.0
  In  In45  1  0.913  0.587  0.750  1.0
  In  In46  1  0.413  0.087  0.750  1.0
  In  In47  1  0.087  0.413  0.250  1.0
  In  In48  1  0.742  0.258  0.255  1.0
  In  In49  1  0.258  0.742  0.745  1.0
  In  In50  1  0.758  0.242  0.755  1.0
  In  In51  1  0.242  0.758  0.245  1.0
[/CIF]
.