The crystal structure described by InCl4NH4 is Silicon tetrafluoride-derived structured and crystallizes in the tetragonal I4_1/a space group. The structure is zero-dimensional and consists of four ammonium molecules and four InCl4 clusters. In each InCl4 cluster, In(1) is bonded in a tetrahedral geometry to four equivalent Cl(1) atoms. Cl(1) is bonded in a single-bond geometry to one In(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_InH4NCl4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.322
_cell_length_b   9.322
_cell_length_c   9.322
_cell_angle_alpha   134.800
_cell_angle_beta   134.800
_cell_angle_gamma   65.841
_symmetry_Int_Tables_number   1
_cell_volume   401.631
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.500  0.500  0.000  1.0
  In  In1  1  0.250  0.750  0.500  1.0
  H  H2  1  0.905  0.291  0.620  1.0
  H  H3  1  0.714  0.095  0.386  1.0
  H  H4  1  0.709  0.328  0.614  1.0
  H  H5  1  0.078  0.964  0.120  1.0
  H  H6  1  0.672  0.286  0.380  1.0
  H  H7  1  0.041  0.922  0.886  1.0
  H  H8  1  0.036  0.155  0.114  1.0
  H  H9  1  0.845  0.959  0.880  1.0
  N  N10  1  0.750  0.250  0.500  1.0
  N  N11  1  0.000  0.000  0.000  1.0
  Cl  Cl12  1  0.731  0.346  0.909  1.0
  Cl  Cl13  1  0.096  0.688  0.115  1.0
  Cl  Cl14  1  0.177  0.269  0.615  1.0
  Cl  Cl15  1  0.438  0.823  0.091  1.0
  Cl  Cl16  1  0.312  0.427  0.409  1.0
  Cl  Cl17  1  0.573  0.981  0.885  1.0
  Cl  Cl18  1  0.654  0.562  0.385  1.0
  Cl  Cl19  1  0.019  0.904  0.591  1.0
[/CIF]
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The crystal structure described by InCl4NH4 is Silicon tetrafluoride-derived structured and crystallizes in the tetragonal I4_1/a space group. The structure is zero-dimensional and consists of four ammonium molecules and four InCl4 clusters. In each InCl4 cluster, In(1) is bonded in a tetrahedral geometry to four equivalent Cl(1) atoms. Cl(1) is bonded in a single-bond geometry to one In(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_InH4NCl4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.322
_cell_length_b   9.322
_cell_length_c   9.322
_cell_angle_alpha   134.800
_cell_angle_beta   134.800
_cell_angle_gamma   65.841
_symmetry_Int_Tables_number   1
_cell_volume   401.631
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.500  0.500  0.000  1.0
  In  In1  1  0.250  0.750  0.500  1.0
  H  H2  1  0.905  0.291  0.620  1.0
  H  H3  1  0.714  0.095  0.386  1.0
  H  H4  1  0.709  0.328  0.614  1.0
  H  H5  1  0.078  0.964  0.120  1.0
  H  H6  1  0.672  0.286  0.380  1.0
  H  H7  1  0.041  0.922  0.886  1.0
  H  H8  1  0.036  0.155  0.114  1.0
  H  H9  1  0.845  0.959  0.880  1.0
  N  N10  1  0.750  0.250  0.500  1.0
  N  N11  1  0.000  0.000  0.000  1.0
  Cl  Cl12  1  0.731  0.346  0.909  1.0
  Cl  Cl13  1  0.096  0.688  0.115  1.0
  Cl  Cl14  1  0.177  0.269  0.615  1.0
  Cl  Cl15  1  0.438  0.823  0.091  1.0
  Cl  Cl16  1  0.312  0.427  0.409  1.0
  Cl  Cl17  1  0.573  0.981  0.885  1.0
  Cl  Cl18  1  0.654  0.562  0.385  1.0
  Cl  Cl19  1  0.019  0.904  0.591  1.0
[/CIF]
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