The structure described by BiNiO3 is Pb (Zr_0.50 Ti_0.48) O_3 structured and crystallizes in the monoclinic Cm space group. Ni(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form corner-sharing NiO6 octahedra. The corner-sharing octahedral tilt angles are 10°. Bi(1) is bonded in a 7-coordinate geometry to three equivalent O(2) and four equivalent O(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to two equivalent Ni(1) and two equivalent Bi(1) atoms. In the second O site, O(2) is bonded in a distorted T-shaped geometry to two equivalent Ni(1) and three equivalent Bi(1) atoms. is represented by the CIF card [CIF]
data_NiBiO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.918
_cell_length_b   3.918
_cell_length_c   3.871
_cell_angle_alpha   89.278
_cell_angle_beta   89.278
_cell_angle_gamma   88.369
_symmetry_Int_Tables_number   1
_cell_volume   59.395
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni0  1  0.509  0.509  0.507  1.0
  Bi  Bi1  1  0.937  0.937  0.969  1.0
  O  O2  1  0.018  0.551  0.522  1.0
  O  O3  1  0.551  0.018  0.522  1.0
  O  O4  1  0.539  0.539  0.010  1.0
[/CIF]
.
The structure described by BiNiO3 is Pb (Zr_0.50 Ti_0.48) O_3 structured and crystallizes in the monoclinic Cm space group. Ni(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form corner-sharing NiO6 octahedra. The corner-sharing octahedral tilt angles are 10°. Bi(1) is bonded in a 7-coordinate geometry to three equivalent O(2) and four equivalent O(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to two equivalent Ni(1) and two equivalent Bi(1) atoms. In the second O site, O(2) is bonded in a distorted T-shaped geometry to two equivalent Ni(1) and three equivalent Bi(1) atoms. is represented by the CIF card [CIF]
data_NiBiO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.918
_cell_length_b   3.918
_cell_length_c   3.871
_cell_angle_alpha   89.278
_cell_angle_beta   89.278
_cell_angle_gamma   88.369
_symmetry_Int_Tables_number   1
_cell_volume   59.395
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni0  1  0.509  0.509  0.507  1.0
  Bi  Bi1  1  0.937  0.937  0.969  1.0
  O  O2  1  0.018  0.551  0.522  1.0
  O  O3  1  0.551  0.018  0.522  1.0
  O  O4  1  0.539  0.539  0.010  1.0
[/CIF]
.