The material structure described by NiO6SO4 is Indium-derived structured and crystallizes in the tetragonal P4_12_12 space group. The structure is zero-dimensional and consists of four sulfuric acid molecules and four NiO6 clusters. In each NiO6 cluster, Ni(1) is bonded in an octahedral geometry to two equivalent O(3), two equivalent O(4), and two equivalent O(5) atoms. There are three inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one Ni(1) atom. In the second O site, O(4) is bonded in a single-bond geometry to one Ni(1) atom. In the third O site, O(5) is bonded in a single-bond geometry to one Ni(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_NiSO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.363
_cell_length_b   6.363
_cell_length_c   15.966
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   646.386
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni0  1  0.215  0.785  0.750  1.0
  Ni  Ni1  1  0.785  0.215  0.250  1.0
  Ni  Ni2  1  0.285  0.285  0.500  1.0
  Ni  Ni3  1  0.715  0.715  0.000  1.0
  S  S4  1  0.712  0.288  0.750  1.0
  S  S5  1  0.288  0.712  0.250  1.0
  S  S6  1  0.788  0.788  0.500  1.0
  S  S7  1  0.212  0.212  0.000  1.0
  O  O8  1  0.610  0.382  0.674  1.0
  O  O9  1  0.390  0.618  0.174  1.0
  O  O10  1  0.882  0.890  0.424  1.0
  O  O11  1  0.118  0.110  0.924  1.0
  O  O12  1  0.618  0.390  0.826  1.0
  O  O13  1  0.382  0.610  0.326  1.0
  O  O14  1  0.890  0.882  0.576  1.0
  O  O15  1  0.110  0.118  0.076  1.0
  O  O16  1  0.943  0.325  0.745  1.0
  O  O17  1  0.057  0.675  0.245  1.0
  O  O18  1  0.825  0.557  0.495  1.0
  O  O19  1  0.175  0.443  0.995  1.0
  O  O20  1  0.675  0.057  0.755  1.0
  O  O21  1  0.325  0.943  0.255  1.0
  O  O22  1  0.557  0.825  0.505  1.0
  O  O23  1  0.443  0.175  0.005  1.0
  O  O24  1  0.199  0.028  0.687  1.0
  O  O25  1  0.801  0.972  0.187  1.0
  O  O26  1  0.528  0.301  0.437  1.0
  O  O27  1  0.472  0.699  0.937  1.0
  O  O28  1  0.972  0.801  0.813  1.0
  O  O29  1  0.028  0.199  0.313  1.0
  O  O30  1  0.301  0.528  0.563  1.0
  O  O31  1  0.699  0.472  0.063  1.0
  O  O32  1  0.444  0.777  0.682  1.0
  O  O33  1  0.556  0.223  0.182  1.0
  O  O34  1  0.277  0.056  0.432  1.0
  O  O35  1  0.723  0.944  0.932  1.0
  O  O36  1  0.223  0.556  0.818  1.0
  O  O37  1  0.777  0.444  0.318  1.0
  O  O38  1  0.056  0.277  0.568  1.0
  O  O39  1  0.944  0.723  0.068  1.0
  O  O40  1  0.072  0.645  0.665  1.0
  O  O41  1  0.928  0.355  0.165  1.0
  O  O42  1  0.145  0.428  0.415  1.0
  O  O43  1  0.855  0.572  0.915  1.0
  O  O44  1  0.355  0.928  0.835  1.0
  O  O45  1  0.645  0.072  0.335  1.0
  O  O46  1  0.428  0.145  0.585  1.0
  O  O47  1  0.572  0.855  0.085  1.0
[/CIF]
.
The material structure described by NiO6SO4 is Indium-derived structured and crystallizes in the tetragonal P4_12_12 space group. The structure is zero-dimensional and consists of four sulfuric acid molecules and four NiO6 clusters. In each NiO6 cluster, Ni(1) is bonded in an octahedral geometry to two equivalent O(3), two equivalent O(4), and two equivalent O(5) atoms. There are three inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one Ni(1) atom. In the second O site, O(4) is bonded in a single-bond geometry to one Ni(1) atom. In the third O site, O(5) is bonded in a single-bond geometry to one Ni(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_NiSO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.363
_cell_length_b   6.363
_cell_length_c   15.966
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   646.386
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni0  1  0.215  0.785  0.750  1.0
  Ni  Ni1  1  0.785  0.215  0.250  1.0
  Ni  Ni2  1  0.285  0.285  0.500  1.0
  Ni  Ni3  1  0.715  0.715  0.000  1.0
  S  S4  1  0.712  0.288  0.750  1.0
  S  S5  1  0.288  0.712  0.250  1.0
  S  S6  1  0.788  0.788  0.500  1.0
  S  S7  1  0.212  0.212  0.000  1.0
  O  O8  1  0.610  0.382  0.674  1.0
  O  O9  1  0.390  0.618  0.174  1.0
  O  O10  1  0.882  0.890  0.424  1.0
  O  O11  1  0.118  0.110  0.924  1.0
  O  O12  1  0.618  0.390  0.826  1.0
  O  O13  1  0.382  0.610  0.326  1.0
  O  O14  1  0.890  0.882  0.576  1.0
  O  O15  1  0.110  0.118  0.076  1.0
  O  O16  1  0.943  0.325  0.745  1.0
  O  O17  1  0.057  0.675  0.245  1.0
  O  O18  1  0.825  0.557  0.495  1.0
  O  O19  1  0.175  0.443  0.995  1.0
  O  O20  1  0.675  0.057  0.755  1.0
  O  O21  1  0.325  0.943  0.255  1.0
  O  O22  1  0.557  0.825  0.505  1.0
  O  O23  1  0.443  0.175  0.005  1.0
  O  O24  1  0.199  0.028  0.687  1.0
  O  O25  1  0.801  0.972  0.187  1.0
  O  O26  1  0.528  0.301  0.437  1.0
  O  O27  1  0.472  0.699  0.937  1.0
  O  O28  1  0.972  0.801  0.813  1.0
  O  O29  1  0.028  0.199  0.313  1.0
  O  O30  1  0.301  0.528  0.563  1.0
  O  O31  1  0.699  0.472  0.063  1.0
  O  O32  1  0.444  0.777  0.682  1.0
  O  O33  1  0.556  0.223  0.182  1.0
  O  O34  1  0.277  0.056  0.432  1.0
  O  O35  1  0.723  0.944  0.932  1.0
  O  O36  1  0.223  0.556  0.818  1.0
  O  O37  1  0.777  0.444  0.318  1.0
  O  O38  1  0.056  0.277  0.568  1.0
  O  O39  1  0.944  0.723  0.068  1.0
  O  O40  1  0.072  0.645  0.665  1.0
  O  O41  1  0.928  0.355  0.165  1.0
  O  O42  1  0.145  0.428  0.415  1.0
  O  O43  1  0.855  0.572  0.915  1.0
  O  O44  1  0.355  0.928  0.835  1.0
  O  O45  1  0.645  0.072  0.335  1.0
  O  O46  1  0.428  0.145  0.585  1.0
  O  O47  1  0.572  0.855  0.085  1.0
[/CIF]
.