The crystal structure described by K2NaCo(CN)6 is Potassium Silver Cyanide-derived structured and crystallizes in the monoclinic P2_1/c space group. K(1) is bonded in a 5-coordinate geometry to one N(2), two equivalent N(1), and two equivalent N(3) atoms. Na(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(2), and two equivalent N(3) atoms. Co(1) is bonded in an octahedral geometry to two equivalent C(1), two equivalent C(2), and two equivalent C(3) atoms. There are three inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Co(1) and one N(1) atom. In the second C site, C(2) is bonded in a linear geometry to one Co(1) and one N(2) atom. In the third C site, C(3) is bonded in a linear geometry to one Co(1) and one N(3) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a 4-coordinate geometry to two equivalent K(1), one Na(1), and one C(1) atom. In the second N site, N(2) is bonded in a 2-coordinate geometry to one K(1), one Na(1), and one C(2) atom. In the third N site, N(3) is bonded in a 4-coordinate geometry to two equivalent K(1), one Na(1), and one C(3) atom. is represented by the CIF card [CIF]
data_K2NaCo(CN)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.604
_cell_length_b   7.105
_cell_length_c   12.526
_cell_angle_alpha   56.173
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   562.142
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.423  0.222  0.252  1.0
  K  K1  1  0.577  0.778  0.748  1.0
  K  K2  1  0.923  0.778  0.248  1.0
  K  K3  1  0.077  0.222  0.752  1.0
  Na  Na4  1  0.000  0.000  0.500  1.0
  Na  Na5  1  0.500  0.000  0.000  1.0
  Co  Co6  1  0.000  0.500  0.000  1.0
  Co  Co7  1  0.500  0.500  0.500  1.0
  C  C8  1  0.027  0.414  0.170  1.0
  C  C9  1  0.629  0.755  0.463  1.0
  C  C10  1  0.707  0.328  0.547  1.0
  C  C11  1  0.293  0.672  0.453  1.0
  C  C12  1  0.793  0.328  0.047  1.0
  C  C13  1  0.871  0.755  0.963  1.0
  C  C14  1  0.527  0.586  0.330  1.0
  C  C15  1  0.973  0.586  0.830  1.0
  C  C16  1  0.207  0.672  0.953  1.0
  C  C17  1  0.129  0.245  0.037  1.0
  C  C18  1  0.371  0.245  0.537  1.0
  C  C19  1  0.473  0.414  0.670  1.0
  N  N20  1  0.953  0.642  0.723  1.0
  N  N21  1  0.547  0.642  0.223  1.0
  N  N22  1  0.790  0.916  0.937  1.0
  N  N23  1  0.047  0.358  0.277  1.0
  N  N24  1  0.710  0.916  0.437  1.0
  N  N25  1  0.665  0.216  0.077  1.0
  N  N26  1  0.290  0.084  0.563  1.0
  N  N27  1  0.210  0.084  0.063  1.0
  N  N28  1  0.335  0.784  0.923  1.0
  N  N29  1  0.453  0.358  0.777  1.0
  N  N30  1  0.835  0.216  0.577  1.0
  N  N31  1  0.165  0.784  0.423  1.0
[/CIF]
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The crystal structure described by K2NaCo(CN)6 is Potassium Silver Cyanide-derived structured and crystallizes in the monoclinic P2_1/c space group. K(1) is bonded in a 5-coordinate geometry to one N(2), two equivalent N(1), and two equivalent N(3) atoms. Na(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(2), and two equivalent N(3) atoms. Co(1) is bonded in an octahedral geometry to two equivalent C(1), two equivalent C(2), and two equivalent C(3) atoms. There are three inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Co(1) and one N(1) atom. In the second C site, C(2) is bonded in a linear geometry to one Co(1) and one N(2) atom. In the third C site, C(3) is bonded in a linear geometry to one Co(1) and one N(3) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a 4-coordinate geometry to two equivalent K(1), one Na(1), and one C(1) atom. In the second N site, N(2) is bonded in a 2-coordinate geometry to one K(1), one Na(1), and one C(2) atom. In the third N site, N(3) is bonded in a 4-coordinate geometry to two equivalent K(1), one Na(1), and one C(3) atom. is represented by the CIF card [CIF]
data_K2NaCo(CN)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.604
_cell_length_b   7.105
_cell_length_c   12.526
_cell_angle_alpha   56.173
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   562.142
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.423  0.222  0.252  1.0
  K  K1  1  0.577  0.778  0.748  1.0
  K  K2  1  0.923  0.778  0.248  1.0
  K  K3  1  0.077  0.222  0.752  1.0
  Na  Na4  1  0.000  0.000  0.500  1.0
  Na  Na5  1  0.500  0.000  0.000  1.0
  Co  Co6  1  0.000  0.500  0.000  1.0
  Co  Co7  1  0.500  0.500  0.500  1.0
  C  C8  1  0.027  0.414  0.170  1.0
  C  C9  1  0.629  0.755  0.463  1.0
  C  C10  1  0.707  0.328  0.547  1.0
  C  C11  1  0.293  0.672  0.453  1.0
  C  C12  1  0.793  0.328  0.047  1.0
  C  C13  1  0.871  0.755  0.963  1.0
  C  C14  1  0.527  0.586  0.330  1.0
  C  C15  1  0.973  0.586  0.830  1.0
  C  C16  1  0.207  0.672  0.953  1.0
  C  C17  1  0.129  0.245  0.037  1.0
  C  C18  1  0.371  0.245  0.537  1.0
  C  C19  1  0.473  0.414  0.670  1.0
  N  N20  1  0.953  0.642  0.723  1.0
  N  N21  1  0.547  0.642  0.223  1.0
  N  N22  1  0.790  0.916  0.937  1.0
  N  N23  1  0.047  0.358  0.277  1.0
  N  N24  1  0.710  0.916  0.437  1.0
  N  N25  1  0.665  0.216  0.077  1.0
  N  N26  1  0.290  0.084  0.563  1.0
  N  N27  1  0.210  0.084  0.063  1.0
  N  N28  1  0.335  0.784  0.923  1.0
  N  N29  1  0.453  0.358  0.777  1.0
  N  N30  1  0.835  0.216  0.577  1.0
  N  N31  1  0.165  0.784  0.423  1.0
[/CIF]
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