The material structure described by InP2HO8(NH4)2 crystallizes in the orthorhombic Fdd2 space group. The structure consists of sixteen ammonium molecules inside a InP2HO8 framework. In the InP2HO8 framework, In(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form InO6 octahedra that share corners with six equivalent P(1)O4 tetrahedra. P(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form PO4 tetrahedra that share corners with three equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 29-42°. H(1) is bonded in a linear geometry to two equivalent O(4) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one In(1) and one P(1) atom. In the second O site, O(4) is bonded in a distorted bent 120 degrees geometry to one P(1) and one H(1) atom. In the third O site, O(2) is bonded in a 2-coordinate geometry to one In(1) and one P(1) atom. In the fourth O site, O(3) is bonded in a bent 150 degrees geometry to one In(1) and one P(1) atom. is represented by the CIF file [CIF]
data_InP2H9(NO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.159
_cell_length_b   10.057
_cell_length_c   6.748
_cell_angle_alpha   71.314
_cell_angle_beta   69.692
_cell_angle_gamma   38.994
_symmetry_Int_Tables_number   1
_cell_volume   405.357
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.398  0.102  0.398  1.0
  In  In1  1  0.148  0.852  0.148  1.0
  P  P2  1  0.959  0.637  0.288  1.0
  P  P3  1  0.288  0.116  0.959  1.0
  P  P4  1  0.613  0.291  0.134  1.0
  P  P5  1  0.134  0.962  0.613  1.0
  H  H6  1  0.025  0.475  0.025  1.0
  H  H7  1  0.775  0.225  0.775  1.0
  H  H8  1  0.625  0.010  0.745  1.0
  H  H9  1  0.745  0.619  0.625  1.0
  H  H10  1  0.240  0.625  0.631  1.0
  H  H11  1  0.631  0.505  0.240  1.0
  H  H12  1  0.858  0.821  0.840  1.0
  H  H13  1  0.840  0.480  0.858  1.0
  H  H14  1  0.429  0.392  0.770  1.0
  H  H15  1  0.770  0.410  0.429  1.0
  H  H16  1  0.791  0.026  0.674  1.0
  H  H17  1  0.674  0.508  0.791  1.0
  H  H18  1  0.224  0.459  0.742  1.0
  H  H19  1  0.742  0.576  0.224  1.0
  H  H20  1  0.854  0.849  0.574  1.0
  H  H21  1  0.574  0.723  0.854  1.0
  H  H22  1  0.401  0.396  0.527  1.0
  H  H23  1  0.527  0.676  0.401  1.0
  N  N24  1  0.783  0.926  0.709  1.0
  N  N25  1  0.709  0.582  0.783  1.0
  N  N26  1  0.324  0.467  0.668  1.0
  N  N27  1  0.668  0.541  0.324  1.0
  O  O28  1  0.083  0.420  0.417  1.0
  O  O29  1  0.417  0.081  0.083  1.0
  O  O30  1  0.830  0.167  0.169  1.0
  O  O31  1  0.169  0.833  0.830  1.0
  O  O32  1  0.723  0.781  0.396  1.0
  O  O33  1  0.396  0.100  0.723  1.0
  O  O34  1  0.469  0.527  0.150  1.0
  O  O35  1  0.150  0.854  0.469  1.0
  O  O36  1  0.023  0.730  0.301  1.0
  O  O37  1  0.301  0.946  0.023  1.0
  O  O38  1  0.520  0.227  0.304  1.0
  O  O39  1  0.304  0.949  0.520  1.0
  O  O40  1  0.986  0.617  0.051  1.0
  O  O41  1  0.051  0.345  0.986  1.0
  O  O42  1  0.633  0.264  0.905  1.0
  O  O43  1  0.905  0.199  0.633  1.0
[/CIF]
.
The material structure described by InP2HO8(NH4)2 crystallizes in the orthorhombic Fdd2 space group. The structure consists of sixteen ammonium molecules inside a InP2HO8 framework. In the InP2HO8 framework, In(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form InO6 octahedra that share corners with six equivalent P(1)O4 tetrahedra. P(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form PO4 tetrahedra that share corners with three equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 29-42°. H(1) is bonded in a linear geometry to two equivalent O(4) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one In(1) and one P(1) atom. In the second O site, O(4) is bonded in a distorted bent 120 degrees geometry to one P(1) and one H(1) atom. In the third O site, O(2) is bonded in a 2-coordinate geometry to one In(1) and one P(1) atom. In the fourth O site, O(3) is bonded in a bent 150 degrees geometry to one In(1) and one P(1) atom. is represented by the CIF file [CIF]
data_InP2H9(NO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.159
_cell_length_b   10.057
_cell_length_c   6.748
_cell_angle_alpha   71.314
_cell_angle_beta   69.692
_cell_angle_gamma   38.994
_symmetry_Int_Tables_number   1
_cell_volume   405.357
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.398  0.102  0.398  1.0
  In  In1  1  0.148  0.852  0.148  1.0
  P  P2  1  0.959  0.637  0.288  1.0
  P  P3  1  0.288  0.116  0.959  1.0
  P  P4  1  0.613  0.291  0.134  1.0
  P  P5  1  0.134  0.962  0.613  1.0
  H  H6  1  0.025  0.475  0.025  1.0
  H  H7  1  0.775  0.225  0.775  1.0
  H  H8  1  0.625  0.010  0.745  1.0
  H  H9  1  0.745  0.619  0.625  1.0
  H  H10  1  0.240  0.625  0.631  1.0
  H  H11  1  0.631  0.505  0.240  1.0
  H  H12  1  0.858  0.821  0.840  1.0
  H  H13  1  0.840  0.480  0.858  1.0
  H  H14  1  0.429  0.392  0.770  1.0
  H  H15  1  0.770  0.410  0.429  1.0
  H  H16  1  0.791  0.026  0.674  1.0
  H  H17  1  0.674  0.508  0.791  1.0
  H  H18  1  0.224  0.459  0.742  1.0
  H  H19  1  0.742  0.576  0.224  1.0
  H  H20  1  0.854  0.849  0.574  1.0
  H  H21  1  0.574  0.723  0.854  1.0
  H  H22  1  0.401  0.396  0.527  1.0
  H  H23  1  0.527  0.676  0.401  1.0
  N  N24  1  0.783  0.926  0.709  1.0
  N  N25  1  0.709  0.582  0.783  1.0
  N  N26  1  0.324  0.467  0.668  1.0
  N  N27  1  0.668  0.541  0.324  1.0
  O  O28  1  0.083  0.420  0.417  1.0
  O  O29  1  0.417  0.081  0.083  1.0
  O  O30  1  0.830  0.167  0.169  1.0
  O  O31  1  0.169  0.833  0.830  1.0
  O  O32  1  0.723  0.781  0.396  1.0
  O  O33  1  0.396  0.100  0.723  1.0
  O  O34  1  0.469  0.527  0.150  1.0
  O  O35  1  0.150  0.854  0.469  1.0
  O  O36  1  0.023  0.730  0.301  1.0
  O  O37  1  0.301  0.946  0.023  1.0
  O  O38  1  0.520  0.227  0.304  1.0
  O  O39  1  0.304  0.949  0.520  1.0
  O  O40  1  0.986  0.617  0.051  1.0
  O  O41  1  0.051  0.345  0.986  1.0
  O  O42  1  0.633  0.264  0.905  1.0
  O  O43  1  0.905  0.199  0.633  1.0
[/CIF]
.