The crystal structure described by Re2Pt(NO2)4 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one Re2Pt(NO2)4 cluster. Re(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. Pt(1) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent N(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Pt(1) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one Pt(1) and one O(3) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Re(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Re(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Re(1) and one N(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Re(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Re2Pt(NO2)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.817
_cell_length_b   8.421
_cell_length_c   7.035
_cell_angle_alpha   71.351
_cell_angle_beta   89.655
_cell_angle_gamma   86.543
_symmetry_Int_Tables_number   1
_cell_volume   269.831
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.036  0.653  0.704  1.0
  Re  Re1  1  0.964  0.347  0.296  1.0
  Pt  Pt2  1  0.500  0.000  0.000  1.0
  N  N3  1  0.539  0.898  0.268  1.0
  N  N4  1  0.461  0.102  0.732  1.0
  N  N5  1  0.694  0.196  0.035  1.0
  N  N6  1  0.306  0.804  0.965  1.0
  O  O7  1  0.676  0.666  0.710  1.0
  O  O8  1  0.324  0.334  0.290  1.0
  O  O9  1  0.154  0.451  0.836  1.0
  O  O10  1  0.846  0.549  0.164  1.0
  O  O11  1  0.163  0.833  0.799  1.0
  O  O12  1  0.837  0.167  0.201  1.0
  O  O13  1  0.131  0.698  0.456  1.0
  O  O14  1  0.869  0.302  0.544  1.0
[/CIF]
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The crystal structure described by Re2Pt(NO2)4 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one Re2Pt(NO2)4 cluster. Re(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. Pt(1) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent N(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Pt(1) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one Pt(1) and one O(3) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Re(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Re(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Re(1) and one N(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Re(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Re2Pt(NO2)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.817
_cell_length_b   8.421
_cell_length_c   7.035
_cell_angle_alpha   71.351
_cell_angle_beta   89.655
_cell_angle_gamma   86.543
_symmetry_Int_Tables_number   1
_cell_volume   269.831
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.036  0.653  0.704  1.0
  Re  Re1  1  0.964  0.347  0.296  1.0
  Pt  Pt2  1  0.500  0.000  0.000  1.0
  N  N3  1  0.539  0.898  0.268  1.0
  N  N4  1  0.461  0.102  0.732  1.0
  N  N5  1  0.694  0.196  0.035  1.0
  N  N6  1  0.306  0.804  0.965  1.0
  O  O7  1  0.676  0.666  0.710  1.0
  O  O8  1  0.324  0.334  0.290  1.0
  O  O9  1  0.154  0.451  0.836  1.0
  O  O10  1  0.846  0.549  0.164  1.0
  O  O11  1  0.163  0.833  0.799  1.0
  O  O12  1  0.837  0.167  0.201  1.0
  O  O13  1  0.131  0.698  0.456  1.0
  O  O14  1  0.869  0.302  0.544  1.0
[/CIF]
.