The structure described by Rb3P3H2O11H2O crystallizes in the triclinic P-1 space group. The structure consists of two water molecules inside a Rb3P3H2O11 framework. In the Rb3P3H2O11 framework, there are three inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 9-coordinate geometry to one P(2), one H(1), one O(1), one O(10), one O(2), one O(7), one O(8), and two equivalent O(9) atoms. In the second Rb site, Rb(2) is bonded in a 1-coordinate geometry to one O(10) atom. In the third Rb site, Rb(3) is bonded in a 3-coordinate geometry to one H(4), one O(4), one O(6), and one O(7) atom. There are three inequivalent P sites. In the first P site, P(1) is bonded in a distorted T-shaped geometry to one O(12), one O(6), and one O(7) atom. In the second P site, P(2) is bonded in a 1-coordinate geometry to one Rb(1), one O(10), one O(2), and one O(5) atom. In the third P site, P(3) is bonded in a 3-coordinate geometry to one O(11), one O(12), one O(8), and one O(9) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one Rb(1) and one O(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one Rb(3) and one O(1) atom. There are eleven inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Rb(1), one H(1), and one H(4) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Rb(1) and one P(2) atom. In the third O site, O(4) is bonded in an L-shaped geometry to one Rb(3) and one O(4) atom. In the fourth O site, O(5) is bonded in a single-bond geometry to one P(2) atom. In the fifth O site, O(6) is bonded in a 2-coordinate geometry to one Rb(3) and one P(1) atom. In the sixth O site, O(7) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(3), and one P(1) atom. In the seventh O site, O(8) is bonded in a distorted single-bond geometry to one Rb(1) and one P(3) atom. In the eighth O site, O(9) is bonded in a distorted T-shaped geometry to two equivalent Rb(1) and one P(3) atom. In the ninth O site, O(10) is bonded in a 2-coordinate geometry to one Rb(1), one Rb(2), and one P(2) atom. In the tenth O site, O(11) is bonded in a single-bond geometry to one P(3) atom. In the eleventh O site, O(12) is bonded in a 2-coordinate geometry to one P(1) and one P(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Rb3P3(HO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.828
_cell_length_b   9.707
_cell_length_c   9.734
_cell_angle_alpha   119.771
_cell_angle_beta   94.175
_cell_angle_gamma   107.751
_symmetry_Int_Tables_number   1
_cell_volume   663.743
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.138  0.060  0.212  1.0
  Rb  Rb1  1  0.593  0.333  0.488  1.0
  Rb  Rb2  1  0.758  0.321  0.982  1.0
  Rb  Rb3  1  0.242  0.679  0.018  1.0
  Rb  Rb4  1  0.407  0.667  0.512  1.0
  Rb  Rb5  1  0.862  0.940  0.788  1.0
  P  P6  1  0.959  0.607  0.228  1.0
  P  P7  1  0.089  0.304  0.398  1.0
  P  P8  1  0.252  0.222  0.754  1.0
  P  P9  1  0.748  0.778  0.246  1.0
  P  P10  1  0.911  0.696  0.602  1.0
  P  P11  1  0.041  0.393  0.772  1.0
  H  H12  1  0.379  0.035  0.077  1.0
  H  H13  1  0.597  0.065  0.343  1.0
  H  H14  1  0.785  0.124  0.394  1.0
  H  H15  1  0.493  0.088  0.799  1.0
  H  H16  1  0.507  0.912  0.201  1.0
  H  H17  1  0.215  0.876  0.606  1.0
  H  H18  1  0.403  0.935  0.657  1.0
  H  H19  1  0.621  0.965  0.923  1.0
  O  O20  1  0.468  0.008  0.183  1.0
  O  O21  1  0.970  0.197  0.322  1.0
  O  O22  1  0.682  0.094  0.429  1.0
  O  O23  1  0.465  0.439  0.047  1.0
  O  O24  1  0.988  0.430  0.380  1.0
  O  O25  1  0.903  0.599  0.066  1.0
  O  O26  1  0.897  0.269  0.746  1.0
  O  O27  1  0.124  0.194  0.597  1.0
  O  O28  1  0.214  0.077  0.904  1.0
  O  O29  1  0.247  0.390  0.351  1.0
  O  O30  1  0.427  0.270  0.741  1.0
  O  O31  1  0.798  0.619  0.266  1.0
  O  O32  1  0.202  0.381  0.734  1.0
  O  O33  1  0.573  0.730  0.259  1.0
  O  O34  1  0.753  0.610  0.649  1.0
  O  O35  1  0.786  0.923  0.096  1.0
  O  O36  1  0.876  0.806  0.403  1.0
  O  O37  1  0.103  0.731  0.254  1.0
  O  O38  1  0.097  0.401  0.934  1.0
  O  O39  1  0.012  0.570  0.620  1.0
  O  O40  1  0.535  0.561  0.953  1.0
  O  O41  1  0.318  0.906  0.571  1.0
  O  O42  1  0.030  0.803  0.678  1.0
  O  O43  1  0.532  0.992  0.817  1.0
[/CIF]
.
The structure described by Rb3P3H2O11H2O crystallizes in the triclinic P-1 space group. The structure consists of two water molecules inside a Rb3P3H2O11 framework. In the Rb3P3H2O11 framework, there are three inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 9-coordinate geometry to one P(2), one H(1), one O(1), one O(10), one O(2), one O(7), one O(8), and two equivalent O(9) atoms. In the second Rb site, Rb(2) is bonded in a 1-coordinate geometry to one O(10) atom. In the third Rb site, Rb(3) is bonded in a 3-coordinate geometry to one H(4), one O(4), one O(6), and one O(7) atom. There are three inequivalent P sites. In the first P site, P(1) is bonded in a distorted T-shaped geometry to one O(12), one O(6), and one O(7) atom. In the second P site, P(2) is bonded in a 1-coordinate geometry to one Rb(1), one O(10), one O(2), and one O(5) atom. In the third P site, P(3) is bonded in a 3-coordinate geometry to one O(11), one O(12), one O(8), and one O(9) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one Rb(1) and one O(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one Rb(3) and one O(1) atom. There are eleven inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Rb(1), one H(1), and one H(4) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Rb(1) and one P(2) atom. In the third O site, O(4) is bonded in an L-shaped geometry to one Rb(3) and one O(4) atom. In the fourth O site, O(5) is bonded in a single-bond geometry to one P(2) atom. In the fifth O site, O(6) is bonded in a 2-coordinate geometry to one Rb(3) and one P(1) atom. In the sixth O site, O(7) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(3), and one P(1) atom. In the seventh O site, O(8) is bonded in a distorted single-bond geometry to one Rb(1) and one P(3) atom. In the eighth O site, O(9) is bonded in a distorted T-shaped geometry to two equivalent Rb(1) and one P(3) atom. In the ninth O site, O(10) is bonded in a 2-coordinate geometry to one Rb(1), one Rb(2), and one P(2) atom. In the tenth O site, O(11) is bonded in a single-bond geometry to one P(3) atom. In the eleventh O site, O(12) is bonded in a 2-coordinate geometry to one P(1) and one P(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Rb3P3(HO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.828
_cell_length_b   9.707
_cell_length_c   9.734
_cell_angle_alpha   119.771
_cell_angle_beta   94.175
_cell_angle_gamma   107.751
_symmetry_Int_Tables_number   1
_cell_volume   663.743
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.138  0.060  0.212  1.0
  Rb  Rb1  1  0.593  0.333  0.488  1.0
  Rb  Rb2  1  0.758  0.321  0.982  1.0
  Rb  Rb3  1  0.242  0.679  0.018  1.0
  Rb  Rb4  1  0.407  0.667  0.512  1.0
  Rb  Rb5  1  0.862  0.940  0.788  1.0
  P  P6  1  0.959  0.607  0.228  1.0
  P  P7  1  0.089  0.304  0.398  1.0
  P  P8  1  0.252  0.222  0.754  1.0
  P  P9  1  0.748  0.778  0.246  1.0
  P  P10  1  0.911  0.696  0.602  1.0
  P  P11  1  0.041  0.393  0.772  1.0
  H  H12  1  0.379  0.035  0.077  1.0
  H  H13  1  0.597  0.065  0.343  1.0
  H  H14  1  0.785  0.124  0.394  1.0
  H  H15  1  0.493  0.088  0.799  1.0
  H  H16  1  0.507  0.912  0.201  1.0
  H  H17  1  0.215  0.876  0.606  1.0
  H  H18  1  0.403  0.935  0.657  1.0
  H  H19  1  0.621  0.965  0.923  1.0
  O  O20  1  0.468  0.008  0.183  1.0
  O  O21  1  0.970  0.197  0.322  1.0
  O  O22  1  0.682  0.094  0.429  1.0
  O  O23  1  0.465  0.439  0.047  1.0
  O  O24  1  0.988  0.430  0.380  1.0
  O  O25  1  0.903  0.599  0.066  1.0
  O  O26  1  0.897  0.269  0.746  1.0
  O  O27  1  0.124  0.194  0.597  1.0
  O  O28  1  0.214  0.077  0.904  1.0
  O  O29  1  0.247  0.390  0.351  1.0
  O  O30  1  0.427  0.270  0.741  1.0
  O  O31  1  0.798  0.619  0.266  1.0
  O  O32  1  0.202  0.381  0.734  1.0
  O  O33  1  0.573  0.730  0.259  1.0
  O  O34  1  0.753  0.610  0.649  1.0
  O  O35  1  0.786  0.923  0.096  1.0
  O  O36  1  0.876  0.806  0.403  1.0
  O  O37  1  0.103  0.731  0.254  1.0
  O  O38  1  0.097  0.401  0.934  1.0
  O  O39  1  0.012  0.570  0.620  1.0
  O  O40  1  0.535  0.561  0.953  1.0
  O  O41  1  0.318  0.906  0.571  1.0
  O  O42  1  0.030  0.803  0.678  1.0
  O  O43  1  0.532  0.992  0.817  1.0
[/CIF]
.