The compound described by Ti4NiBi2 crystallizes in the tetragonal I4/mcm space group. Ti(1) is bonded in a 6-coordinate geometry to two equivalent Ni(1) and four equivalent Bi(1) atoms. Ni(1) is bonded in a 10-coordinate geometry to eight equivalent Ti(1) and two equivalent Ni(1) atoms. Bi(1) is bonded in a 8-coordinate geometry to eight equivalent Ti(1) atoms. is represented by the CIF file [CIF]
data_Ti4NiBi2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.782
_cell_length_b   7.908
_cell_length_c   7.908
_cell_angle_alpha   84.755
_cell_angle_beta   72.401
_cell_angle_gamma   72.401
_symmetry_Int_Tables_number   1
_cell_volume   271.724
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.080  0.116  0.724  1.0
  Ti  Ti1  1  0.804  0.276  0.116  1.0
  Ti  Ti2  1  0.304  0.116  0.276  1.0
  Ti  Ti3  1  0.580  0.724  0.116  1.0
  Ti  Ti4  1  0.196  0.724  0.884  1.0
  Ti  Ti5  1  0.920  0.884  0.276  1.0
  Ti  Ti6  1  0.420  0.276  0.884  1.0
  Ti  Ti7  1  0.696  0.884  0.724  1.0
  Ni  Ni8  1  0.750  0.000  0.000  1.0
  Ni  Ni9  1  0.250  0.000  0.000  1.0
  Bi  Bi10  1  0.358  0.784  0.500  1.0
  Bi  Bi11  1  0.642  0.216  0.500  1.0
  Bi  Bi12  1  0.142  0.500  0.216  1.0
  Bi  Bi13  1  0.858  0.500  0.784  1.0
[/CIF]
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The compound described by Ti4NiBi2 crystallizes in the tetragonal I4/mcm space group. Ti(1) is bonded in a 6-coordinate geometry to two equivalent Ni(1) and four equivalent Bi(1) atoms. Ni(1) is bonded in a 10-coordinate geometry to eight equivalent Ti(1) and two equivalent Ni(1) atoms. Bi(1) is bonded in a 8-coordinate geometry to eight equivalent Ti(1) atoms. is represented by the CIF file [CIF]
data_Ti4NiBi2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.782
_cell_length_b   7.908
_cell_length_c   7.908
_cell_angle_alpha   84.755
_cell_angle_beta   72.401
_cell_angle_gamma   72.401
_symmetry_Int_Tables_number   1
_cell_volume   271.724
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.080  0.116  0.724  1.0
  Ti  Ti1  1  0.804  0.276  0.116  1.0
  Ti  Ti2  1  0.304  0.116  0.276  1.0
  Ti  Ti3  1  0.580  0.724  0.116  1.0
  Ti  Ti4  1  0.196  0.724  0.884  1.0
  Ti  Ti5  1  0.920  0.884  0.276  1.0
  Ti  Ti6  1  0.420  0.276  0.884  1.0
  Ti  Ti7  1  0.696  0.884  0.724  1.0
  Ni  Ni8  1  0.750  0.000  0.000  1.0
  Ni  Ni9  1  0.250  0.000  0.000  1.0
  Bi  Bi10  1  0.358  0.784  0.500  1.0
  Bi  Bi11  1  0.642  0.216  0.500  1.0
  Bi  Bi12  1  0.142  0.500  0.216  1.0
  Bi  Bi13  1  0.858  0.500  0.784  1.0
[/CIF]
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