The structure described by ScPO4O2 crystallizes in the monoclinic P2_1/c space group. The structure consists of four hydrogen peroxide molecules inside a ScPO4 framework. In the ScPO4 framework, Sc(1) is bonded to one O(3), one O(4), one O(5), and one O(6) atom to form ScO4 tetrahedra that share corners with four equivalent P(1)O4 tetrahedra. P(1) is bonded to one O(3), one O(4), one O(5), and one O(6) atom to form PO4 tetrahedra that share corners with four equivalent Sc(1)O4 tetrahedra. There are four inequivalent O sites. In the first O site, O(3) is bonded in a bent 150 degrees geometry to one Sc(1) and one P(1) atom. In the second O site, O(4) is bonded in a linear geometry to one Sc(1) and one P(1) atom. In the third O site, O(5) is bonded in a bent 150 degrees geometry to one Sc(1) and one P(1) atom. In the fourth O site, O(6) is bonded in a linear geometry to one Sc(1) and one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_ScPO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.967
_cell_length_b   5.579
_cell_length_c   11.110
_cell_angle_alpha   60.647
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   538.487
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc0  1  0.696  0.788  0.163  1.0
  Sc  Sc1  1  0.304  0.212  0.837  1.0
  Sc  Sc2  1  0.196  0.212  0.337  1.0
  Sc  Sc3  1  0.804  0.788  0.663  1.0
  P  P4  1  0.349  0.869  0.188  1.0
  P  P5  1  0.651  0.131  0.812  1.0
  P  P6  1  0.849  0.131  0.312  1.0
  P  P7  1  0.151  0.869  0.688  1.0
  O  O8  1  0.046  0.692  0.059  1.0
  O  O9  1  0.954  0.308  0.941  1.0
  O  O10  1  0.546  0.308  0.441  1.0
  O  O11  1  0.454  0.692  0.559  1.0
  O  O12  1  0.032  0.750  0.152  1.0
  O  O13  1  0.968  0.250  0.848  1.0
  O  O14  1  0.532  0.250  0.348  1.0
  O  O15  1  0.468  0.750  0.652  1.0
  O  O16  1  0.296  0.059  0.039  1.0
  O  O17  1  0.704  0.941  0.961  1.0
  O  O18  1  0.796  0.941  0.461  1.0
  O  O19  1  0.204  0.059  0.539  1.0
  O  O20  1  0.504  0.855  0.187  1.0
  O  O21  1  0.496  0.145  0.813  1.0
  O  O22  1  0.004  0.145  0.313  1.0
  O  O23  1  0.996  0.855  0.687  1.0
  O  O24  1  0.302  0.988  0.280  1.0
  O  O25  1  0.698  0.012  0.720  1.0
  O  O26  1  0.802  0.012  0.220  1.0
  O  O27  1  0.198  0.988  0.780  1.0
  O  O28  1  0.290  0.576  0.245  1.0
  O  O29  1  0.710  0.424  0.755  1.0
  O  O30  1  0.790  0.424  0.255  1.0
  O  O31  1  0.210  0.576  0.745  1.0
[/CIF]
.
The structure described by ScPO4O2 crystallizes in the monoclinic P2_1/c space group. The structure consists of four hydrogen peroxide molecules inside a ScPO4 framework. In the ScPO4 framework, Sc(1) is bonded to one O(3), one O(4), one O(5), and one O(6) atom to form ScO4 tetrahedra that share corners with four equivalent P(1)O4 tetrahedra. P(1) is bonded to one O(3), one O(4), one O(5), and one O(6) atom to form PO4 tetrahedra that share corners with four equivalent Sc(1)O4 tetrahedra. There are four inequivalent O sites. In the first O site, O(3) is bonded in a bent 150 degrees geometry to one Sc(1) and one P(1) atom. In the second O site, O(4) is bonded in a linear geometry to one Sc(1) and one P(1) atom. In the third O site, O(5) is bonded in a bent 150 degrees geometry to one Sc(1) and one P(1) atom. In the fourth O site, O(6) is bonded in a linear geometry to one Sc(1) and one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_ScPO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.967
_cell_length_b   5.579
_cell_length_c   11.110
_cell_angle_alpha   60.647
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   538.487
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc0  1  0.696  0.788  0.163  1.0
  Sc  Sc1  1  0.304  0.212  0.837  1.0
  Sc  Sc2  1  0.196  0.212  0.337  1.0
  Sc  Sc3  1  0.804  0.788  0.663  1.0
  P  P4  1  0.349  0.869  0.188  1.0
  P  P5  1  0.651  0.131  0.812  1.0
  P  P6  1  0.849  0.131  0.312  1.0
  P  P7  1  0.151  0.869  0.688  1.0
  O  O8  1  0.046  0.692  0.059  1.0
  O  O9  1  0.954  0.308  0.941  1.0
  O  O10  1  0.546  0.308  0.441  1.0
  O  O11  1  0.454  0.692  0.559  1.0
  O  O12  1  0.032  0.750  0.152  1.0
  O  O13  1  0.968  0.250  0.848  1.0
  O  O14  1  0.532  0.250  0.348  1.0
  O  O15  1  0.468  0.750  0.652  1.0
  O  O16  1  0.296  0.059  0.039  1.0
  O  O17  1  0.704  0.941  0.961  1.0
  O  O18  1  0.796  0.941  0.461  1.0
  O  O19  1  0.204  0.059  0.539  1.0
  O  O20  1  0.504  0.855  0.187  1.0
  O  O21  1  0.496  0.145  0.813  1.0
  O  O22  1  0.004  0.145  0.313  1.0
  O  O23  1  0.996  0.855  0.687  1.0
  O  O24  1  0.302  0.988  0.280  1.0
  O  O25  1  0.698  0.012  0.720  1.0
  O  O26  1  0.802  0.012  0.220  1.0
  O  O27  1  0.198  0.988  0.780  1.0
  O  O28  1  0.290  0.576  0.245  1.0
  O  O29  1  0.710  0.424  0.755  1.0
  O  O30  1  0.790  0.424  0.255  1.0
  O  O31  1  0.210  0.576  0.745  1.0
[/CIF]
.