The material structure described by LiMnPO4 crystallizes in the tetragonal I-4 space group. Li(1) is bonded to four equivalent O(1) atoms to form distorted LiO4 tetrahedra that share corners with four equivalent Mn(1)O4 tetrahedra and corners with four equivalent P(1)O4 tetrahedra. Mn(1) is bonded to four equivalent O(1) atoms to form distorted MnO4 tetrahedra that share corners with four equivalent Li(1)O4 tetrahedra and corners with four equivalent P(1)O4 tetrahedra. P(1) is bonded to four equivalent O(1) atoms to form PO4 tetrahedra that share corners with four equivalent Li(1)O4 tetrahedra and corners with four equivalent Mn(1)O4 tetrahedra. O(1) is bonded in a distorted trigonal planar geometry to one Li(1), one Mn(1), and one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiMnPO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.373
_cell_length_b   4.373
_cell_length_c   5.626
_cell_angle_alpha   112.872
_cell_angle_beta   112.872
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   89.879
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.500  0.500  0.000  1.0
  Mn  Mn1  1  0.250  0.750  0.500  1.0
  O  O2  1  0.684  0.714  0.808  1.0
  O  O3  1  0.286  0.876  0.192  1.0
  O  O4  1  0.124  0.095  0.808  1.0
  O  O5  1  0.905  0.316  0.192  1.0
  P  P6  1  0.000  0.000  0.000  1.0
[/CIF]
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The material structure described by LiMnPO4 crystallizes in the tetragonal I-4 space group. Li(1) is bonded to four equivalent O(1) atoms to form distorted LiO4 tetrahedra that share corners with four equivalent Mn(1)O4 tetrahedra and corners with four equivalent P(1)O4 tetrahedra. Mn(1) is bonded to four equivalent O(1) atoms to form distorted MnO4 tetrahedra that share corners with four equivalent Li(1)O4 tetrahedra and corners with four equivalent P(1)O4 tetrahedra. P(1) is bonded to four equivalent O(1) atoms to form PO4 tetrahedra that share corners with four equivalent Li(1)O4 tetrahedra and corners with four equivalent Mn(1)O4 tetrahedra. O(1) is bonded in a distorted trigonal planar geometry to one Li(1), one Mn(1), and one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiMnPO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.373
_cell_length_b   4.373
_cell_length_c   5.626
_cell_angle_alpha   112.872
_cell_angle_beta   112.872
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   89.879
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.500  0.500  0.000  1.0
  Mn  Mn1  1  0.250  0.750  0.500  1.0
  O  O2  1  0.684  0.714  0.808  1.0
  O  O3  1  0.286  0.876  0.192  1.0
  O  O4  1  0.124  0.095  0.808  1.0
  O  O5  1  0.905  0.316  0.192  1.0
  P  P6  1  0.000  0.000  0.000  1.0
[/CIF]
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