The structure described by AgPO3 crystallizes in the monoclinic P2_1/c space group. Ag(1) is bonded in a 6-coordinate geometry to three equivalent O(1) and three equivalent O(2) atoms. P(1) is bonded to one O(1), one O(2), and two equivalent O(3) atoms to form corner-sharing PO4 tetrahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to three equivalent Ag(1) and one P(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to three equivalent Ag(1) and one P(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to two equivalent P(1) atoms. is represented by the CIF card [CIF]
data_AgPO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.050
_cell_length_b   5.873
_cell_length_c   11.965
_cell_angle_alpha   68.466
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   264.727
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.860  0.318  0.910  1.0
  Ag  Ag1  1  0.360  0.682  0.590  1.0
  Ag  Ag2  1  0.640  0.318  0.410  1.0
  Ag  Ag3  1  0.140  0.682  0.090  1.0
  P  P4  1  0.512  0.845  0.829  1.0
  P  P5  1  0.012  0.155  0.671  1.0
  P  P6  1  0.988  0.845  0.329  1.0
  P  P7  1  0.488  0.155  0.171  1.0
  O  O8  1  0.681  0.854  0.939  1.0
  O  O9  1  0.351  0.613  0.830  1.0
  O  O10  1  0.257  0.075  0.787  1.0
  O  O11  1  0.757  0.925  0.713  1.0
  O  O12  1  0.851  0.387  0.670  1.0
  O  O13  1  0.181  0.146  0.561  1.0
  O  O14  1  0.819  0.854  0.439  1.0
  O  O15  1  0.149  0.613  0.330  1.0
  O  O16  1  0.243  0.075  0.287  1.0
  O  O17  1  0.743  0.925  0.213  1.0
  O  O18  1  0.649  0.387  0.170  1.0
  O  O19  1  0.319  0.146  0.061  1.0
[/CIF]
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The structure described by AgPO3 crystallizes in the monoclinic P2_1/c space group. Ag(1) is bonded in a 6-coordinate geometry to three equivalent O(1) and three equivalent O(2) atoms. P(1) is bonded to one O(1), one O(2), and two equivalent O(3) atoms to form corner-sharing PO4 tetrahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to three equivalent Ag(1) and one P(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to three equivalent Ag(1) and one P(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to two equivalent P(1) atoms. is represented by the CIF card [CIF]
data_AgPO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.050
_cell_length_b   5.873
_cell_length_c   11.965
_cell_angle_alpha   68.466
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   264.727
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.860  0.318  0.910  1.0
  Ag  Ag1  1  0.360  0.682  0.590  1.0
  Ag  Ag2  1  0.640  0.318  0.410  1.0
  Ag  Ag3  1  0.140  0.682  0.090  1.0
  P  P4  1  0.512  0.845  0.829  1.0
  P  P5  1  0.012  0.155  0.671  1.0
  P  P6  1  0.988  0.845  0.329  1.0
  P  P7  1  0.488  0.155  0.171  1.0
  O  O8  1  0.681  0.854  0.939  1.0
  O  O9  1  0.351  0.613  0.830  1.0
  O  O10  1  0.257  0.075  0.787  1.0
  O  O11  1  0.757  0.925  0.713  1.0
  O  O12  1  0.851  0.387  0.670  1.0
  O  O13  1  0.181  0.146  0.561  1.0
  O  O14  1  0.819  0.854  0.439  1.0
  O  O15  1  0.149  0.613  0.330  1.0
  O  O16  1  0.243  0.075  0.287  1.0
  O  O17  1  0.743  0.925  0.213  1.0
  O  O18  1  0.649  0.387  0.170  1.0
  O  O19  1  0.319  0.146  0.061  1.0
[/CIF]
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