The material structure described by CoH8(O2Br)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two dibromocobalt;tetrahydrate molecules. Co(1) is bonded in a distorted octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent Br(1) atoms. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Co(1), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Co(1), one H(3), and one H(4) atom. Br(1) is bonded in a distorted single-bond geometry to one Co(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CoH8(BrO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.596
_cell_length_b   6.122
_cell_length_c   8.652
_cell_angle_alpha   69.722
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   377.438
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.000  0.000  0.000  1.0
  Co  Co1  1  0.500  0.000  0.500  1.0
  H  H2  1  0.702  0.631  0.497  1.0
  H  H3  1  0.202  0.369  0.003  1.0
  H  H4  1  0.298  0.369  0.503  1.0
  H  H5  1  0.798  0.631  0.997  1.0
  H  H6  1  0.682  0.617  0.679  1.0
  H  H7  1  0.182  0.383  0.821  1.0
  H  H8  1  0.318  0.383  0.321  1.0
  H  H9  1  0.818  0.617  0.179  1.0
  H  H10  1  0.571  0.109  0.167  1.0
  H  H11  1  0.071  0.891  0.333  1.0
  H  H12  1  0.429  0.891  0.833  1.0
  H  H13  1  0.929  0.109  0.667  1.0
  H  H14  1  0.431  0.904  0.215  1.0
  H  H15  1  0.931  0.096  0.285  1.0
  H  H16  1  0.069  0.904  0.715  1.0
  H  H17  1  0.569  0.096  0.785  1.0
  Br  Br18  1  0.230  0.699  0.576  1.0
  Br  Br19  1  0.730  0.301  0.924  1.0
  Br  Br20  1  0.270  0.699  0.076  1.0
  Br  Br21  1  0.770  0.301  0.424  1.0
  O  O22  1  0.684  0.728  0.565  1.0
  O  O23  1  0.184  0.272  0.935  1.0
  O  O24  1  0.316  0.272  0.435  1.0
  O  O25  1  0.816  0.728  0.065  1.0
  O  O26  1  0.498  0.008  0.259  1.0
  O  O27  1  0.998  0.992  0.241  1.0
  O  O28  1  0.502  0.992  0.741  1.0
  O  O29  1  0.002  0.008  0.759  1.0
[/CIF]
.
The material structure described by CoH8(O2Br)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two dibromocobalt;tetrahydrate molecules. Co(1) is bonded in a distorted octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent Br(1) atoms. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Co(1), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Co(1), one H(3), and one H(4) atom. Br(1) is bonded in a distorted single-bond geometry to one Co(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CoH8(BrO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.596
_cell_length_b   6.122
_cell_length_c   8.652
_cell_angle_alpha   69.722
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   377.438
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.000  0.000  0.000  1.0
  Co  Co1  1  0.500  0.000  0.500  1.0
  H  H2  1  0.702  0.631  0.497  1.0
  H  H3  1  0.202  0.369  0.003  1.0
  H  H4  1  0.298  0.369  0.503  1.0
  H  H5  1  0.798  0.631  0.997  1.0
  H  H6  1  0.682  0.617  0.679  1.0
  H  H7  1  0.182  0.383  0.821  1.0
  H  H8  1  0.318  0.383  0.321  1.0
  H  H9  1  0.818  0.617  0.179  1.0
  H  H10  1  0.571  0.109  0.167  1.0
  H  H11  1  0.071  0.891  0.333  1.0
  H  H12  1  0.429  0.891  0.833  1.0
  H  H13  1  0.929  0.109  0.667  1.0
  H  H14  1  0.431  0.904  0.215  1.0
  H  H15  1  0.931  0.096  0.285  1.0
  H  H16  1  0.069  0.904  0.715  1.0
  H  H17  1  0.569  0.096  0.785  1.0
  Br  Br18  1  0.230  0.699  0.576  1.0
  Br  Br19  1  0.730  0.301  0.924  1.0
  Br  Br20  1  0.270  0.699  0.076  1.0
  Br  Br21  1  0.770  0.301  0.424  1.0
  O  O22  1  0.684  0.728  0.565  1.0
  O  O23  1  0.184  0.272  0.935  1.0
  O  O24  1  0.316  0.272  0.435  1.0
  O  O25  1  0.816  0.728  0.065  1.0
  O  O26  1  0.498  0.008  0.259  1.0
  O  O27  1  0.998  0.992  0.241  1.0
  O  O28  1  0.502  0.992  0.741  1.0
  O  O29  1  0.002  0.008  0.759  1.0
[/CIF]
.