The material structure described by AgSbS2 is Caswellsilverite-like structured and crystallizes in the tetragonal I4_1/amd space group. Ag(1) is bonded to six S(1,1,1) atoms to form AgS6 octahedra that share corners with two equivalent Sb(1)S6 octahedra, corners with four equivalent Ag(1)S6 octahedra, edges with four equivalent Ag(1)S6 octahedra, and edges with eight equivalent Sb(1)S6 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. Sb(1) is bonded to six S(1,1) atoms to form SbS6 octahedra that share corners with two equivalent Ag(1)S6 octahedra, corners with four equivalent Sb(1)S6 octahedra, edges with four equivalent Sb(1)S6 octahedra, and edges with eight equivalent Ag(1)S6 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. There are four inequivalent S sites. In the first S site, S(1) is bonded to three equivalent Ag(1) and three equivalent Sb(1) atoms to form a mixture of edge and corner-sharing SAg3Sb3 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. In the second S site, S(1) is bonded to three equivalent Ag(1) and three equivalent Sb(1) atoms to form a mixture of edge and corner-sharing SAg3Sb3 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. In the third S site, S(1) is bonded to three equivalent Ag(1) and three equivalent Sb(1) atoms to form a mixture of edge and corner-sharing SAg3Sb3 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. In the fourth S site, S(1) is bonded to three equivalent Ag(1) and three equivalent Sb(1) atoms to form a mixture of edge and corner-sharing SAg3Sb3 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. is represented by the CIF card [CIF]
data_AgSbS2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.909
_cell_length_b   6.909
_cell_length_c   6.909
_cell_angle_alpha   133.157
_cell_angle_beta   133.157
_cell_angle_gamma   68.408
_symmetry_Int_Tables_number   1
_cell_volume   172.401
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.500  0.500  0.000  1.0
  Ag  Ag1  1  0.250  0.750  0.500  1.0
  Sb  Sb2  1  0.000  0.000  0.000  1.0
  Sb  Sb3  1  0.750  0.250  0.500  1.0
  S  S4  1  0.758  0.758  0.000  1.0
  S  S5  1  0.242  0.242  0.000  1.0
  S  S6  1  0.992  0.492  0.500  1.0
  S  S7  1  0.508  0.008  0.500  1.0
[/CIF]
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The material structure described by AgSbS2 is Caswellsilverite-like structured and crystallizes in the tetragonal I4_1/amd space group. Ag(1) is bonded to six S(1,1,1) atoms to form AgS6 octahedra that share corners with two equivalent Sb(1)S6 octahedra, corners with four equivalent Ag(1)S6 octahedra, edges with four equivalent Ag(1)S6 octahedra, and edges with eight equivalent Sb(1)S6 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. Sb(1) is bonded to six S(1,1) atoms to form SbS6 octahedra that share corners with two equivalent Ag(1)S6 octahedra, corners with four equivalent Sb(1)S6 octahedra, edges with four equivalent Sb(1)S6 octahedra, and edges with eight equivalent Ag(1)S6 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. There are four inequivalent S sites. In the first S site, S(1) is bonded to three equivalent Ag(1) and three equivalent Sb(1) atoms to form a mixture of edge and corner-sharing SAg3Sb3 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. In the second S site, S(1) is bonded to three equivalent Ag(1) and three equivalent Sb(1) atoms to form a mixture of edge and corner-sharing SAg3Sb3 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. In the third S site, S(1) is bonded to three equivalent Ag(1) and three equivalent Sb(1) atoms to form a mixture of edge and corner-sharing SAg3Sb3 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. In the fourth S site, S(1) is bonded to three equivalent Ag(1) and three equivalent Sb(1) atoms to form a mixture of edge and corner-sharing SAg3Sb3 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. is represented by the CIF card [CIF]
data_AgSbS2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.909
_cell_length_b   6.909
_cell_length_c   6.909
_cell_angle_alpha   133.157
_cell_angle_beta   133.157
_cell_angle_gamma   68.408
_symmetry_Int_Tables_number   1
_cell_volume   172.401
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.500  0.500  0.000  1.0
  Ag  Ag1  1  0.250  0.750  0.500  1.0
  Sb  Sb2  1  0.000  0.000  0.000  1.0
  Sb  Sb3  1  0.750  0.250  0.500  1.0
  S  S4  1  0.758  0.758  0.000  1.0
  S  S5  1  0.242  0.242  0.000  1.0
  S  S6  1  0.992  0.492  0.500  1.0
  S  S7  1  0.508  0.008  0.500  1.0
[/CIF]
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