The material structure described by V2HgO6 crystallizes in the orthorhombic Pbca space group. V(1) is bonded in a 6-coordinate geometry to one O(1), two equivalent O(2), and three equivalent O(3) atoms. Hg(1) is bonded in a distorted linear geometry to two equivalent O(2) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one V(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to two equivalent V(1) and one Hg(1) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to three equivalent V(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_V2HgO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.898
_cell_length_b   5.958
_cell_length_c   14.507
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   423.329
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.032  0.439  0.829  1.0
  V  V1  1  0.532  0.061  0.829  1.0
  V  V2  1  0.968  0.561  0.171  1.0
  V  V3  1  0.468  0.439  0.329  1.0
  V  V4  1  0.532  0.561  0.671  1.0
  V  V5  1  0.032  0.939  0.671  1.0
  V  V6  1  0.968  0.061  0.329  1.0
  V  V7  1  0.468  0.939  0.171  1.0
  Hg  Hg8  1  0.500  0.000  0.500  1.0
  Hg  Hg9  1  0.000  0.000  0.000  1.0
  Hg  Hg10  1  0.500  0.500  0.000  1.0
  Hg  Hg11  1  0.000  0.500  0.500  1.0
  O  O12  1  0.933  0.626  0.904  1.0
  O  O13  1  0.666  0.177  0.390  1.0
  O  O14  1  0.433  0.874  0.904  1.0
  O  O15  1  0.278  0.600  0.247  1.0
  O  O16  1  0.334  0.323  0.890  1.0
  O  O17  1  0.334  0.823  0.610  1.0
  O  O18  1  0.722  0.900  0.747  1.0
  O  O19  1  0.567  0.126  0.096  1.0
  O  O20  1  0.166  0.823  0.110  1.0
  O  O21  1  0.778  0.900  0.247  1.0
  O  O22  1  0.222  0.600  0.747  1.0
  O  O23  1  0.666  0.677  0.110  1.0
  O  O24  1  0.067  0.374  0.096  1.0
  O  O25  1  0.567  0.626  0.404  1.0
  O  O26  1  0.222  0.100  0.753  1.0
  O  O27  1  0.166  0.323  0.390  1.0
  O  O28  1  0.933  0.126  0.596  1.0
  O  O29  1  0.834  0.177  0.890  1.0
  O  O30  1  0.067  0.874  0.404  1.0
  O  O31  1  0.722  0.400  0.753  1.0
  O  O32  1  0.433  0.374  0.596  1.0
  O  O33  1  0.834  0.677  0.610  1.0
  O  O34  1  0.278  0.100  0.253  1.0
  O  O35  1  0.778  0.400  0.253  1.0
[/CIF]
.
The material structure described by V2HgO6 crystallizes in the orthorhombic Pbca space group. V(1) is bonded in a 6-coordinate geometry to one O(1), two equivalent O(2), and three equivalent O(3) atoms. Hg(1) is bonded in a distorted linear geometry to two equivalent O(2) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one V(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to two equivalent V(1) and one Hg(1) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to three equivalent V(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_V2HgO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.898
_cell_length_b   5.958
_cell_length_c   14.507
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   423.329
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.032  0.439  0.829  1.0
  V  V1  1  0.532  0.061  0.829  1.0
  V  V2  1  0.968  0.561  0.171  1.0
  V  V3  1  0.468  0.439  0.329  1.0
  V  V4  1  0.532  0.561  0.671  1.0
  V  V5  1  0.032  0.939  0.671  1.0
  V  V6  1  0.968  0.061  0.329  1.0
  V  V7  1  0.468  0.939  0.171  1.0
  Hg  Hg8  1  0.500  0.000  0.500  1.0
  Hg  Hg9  1  0.000  0.000  0.000  1.0
  Hg  Hg10  1  0.500  0.500  0.000  1.0
  Hg  Hg11  1  0.000  0.500  0.500  1.0
  O  O12  1  0.933  0.626  0.904  1.0
  O  O13  1  0.666  0.177  0.390  1.0
  O  O14  1  0.433  0.874  0.904  1.0
  O  O15  1  0.278  0.600  0.247  1.0
  O  O16  1  0.334  0.323  0.890  1.0
  O  O17  1  0.334  0.823  0.610  1.0
  O  O18  1  0.722  0.900  0.747  1.0
  O  O19  1  0.567  0.126  0.096  1.0
  O  O20  1  0.166  0.823  0.110  1.0
  O  O21  1  0.778  0.900  0.247  1.0
  O  O22  1  0.222  0.600  0.747  1.0
  O  O23  1  0.666  0.677  0.110  1.0
  O  O24  1  0.067  0.374  0.096  1.0
  O  O25  1  0.567  0.626  0.404  1.0
  O  O26  1  0.222  0.100  0.753  1.0
  O  O27  1  0.166  0.323  0.390  1.0
  O  O28  1  0.933  0.126  0.596  1.0
  O  O29  1  0.834  0.177  0.890  1.0
  O  O30  1  0.067  0.874  0.404  1.0
  O  O31  1  0.722  0.400  0.753  1.0
  O  O32  1  0.433  0.374  0.596  1.0
  O  O33  1  0.834  0.677  0.610  1.0
  O  O34  1  0.278  0.100  0.253  1.0
  O  O35  1  0.778  0.400  0.253  1.0
[/CIF]
.