The material structure described by Mg(Ag3O4)2 crystallizes in the triclinic P1 space group. Mg(1) is bonded in a 4-coordinate geometry to one O(1), one O(5), and two equivalent O(4) atoms. There are six inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a rectangular see-saw-like geometry to one O(1), one O(4), one O(5), and one O(8) atom. In the second Ag site, Ag(2) is bonded in a rectangular see-saw-like geometry to one O(2), one O(3), one O(6), and one O(7) atom. In the third Ag site, Ag(3) is bonded in a rectangular see-saw-like geometry to one O(2), one O(3), one O(5), and one O(8) atom. In the fourth Ag site, Ag(4) is bonded in a distorted square co-planar geometry to one O(1), one O(4), one O(6), and one O(7) atom. In the fifth Ag site, Ag(5) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(3), one O(6), and one O(7) atom. In the sixth Ag site, Ag(6) is bonded in a 5-coordinate geometry to one O(2), one O(4), one O(5), and two equivalent O(8) atoms. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted see-saw-like geometry to one Mg(1), one Ag(1), one Ag(4), and one Ag(5) atom. In the second O site, O(2) is bonded in a trigonal non-coplanar geometry to one Ag(2), one Ag(3), and one Ag(6) atom. In the third O site, O(3) is bonded in a trigonal non-coplanar geometry to one Ag(2), one Ag(3), and one Ag(5) atom. In the fourth O site, O(4) is bonded to two equivalent Mg(1), one Ag(1), one Ag(4), and one Ag(6) atom to form distorted OMg2Ag3 trigonal bipyramids that share corners with two equivalent O(5)MgAg3 tetrahedra, corners with two equivalent O(4)Mg2Ag3 trigonal bipyramids, and  an edgeedge with one O(5)MgAg3 tetrahedra. In the fifth O site, O(5) is bonded to one Mg(1), one Ag(1), one Ag(3), and one Ag(6) atom to form a mixture of distorted edge and corner-sharing OMgAg3 tetrahedra. In the sixth O site, O(6) is bonded in a distorted trigonal non-coplanar geometry to one Ag(2), one Ag(4), and one Ag(5) atom. In the seventh O site, O(7) is bonded in a distorted trigonal non-coplanar geometry to one Ag(2), one Ag(4), and one Ag(5) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one Ag(1), one Ag(3), and two equivalent Ag(6) atoms. is represented by the CIF file [CIF]
data_Mg(Ag3O4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.680
_cell_length_b   5.758
_cell_length_c   10.000
_cell_angle_alpha   88.555
_cell_angle_beta   89.241
_cell_angle_gamma   101.959
_symmetry_Int_Tables_number   1
_cell_volume   207.207
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.692  0.088  0.824  1.0
  Ag  Ag1  1  0.286  0.551  0.856  1.0
  Ag  Ag2  1  0.678  0.939  0.356  1.0
  Ag  Ag3  1  0.734  0.444  0.145  1.0
  Ag  Ag4  1  0.211  0.040  0.607  1.0
  Ag  Ag5  1  0.951  0.485  0.489  1.0
  Ag  Ag6  1  0.094  0.972  0.041  1.0
  O  O7  1  0.984  0.321  0.683  1.0
  O  O8  1  0.961  0.161  0.210  1.0
  O  O9  1  0.927  0.657  0.305  1.0
  O  O10  1  0.135  0.914  0.813  1.0
  O  O11  1  0.531  0.268  0.974  1.0
  O  O12  1  0.502  0.224  0.434  1.0
  O  O13  1  0.414  0.754  0.527  1.0
  O  O14  1  0.578  0.724  0.044  1.0
[/CIF]
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The material structure described by Mg(Ag3O4)2 crystallizes in the triclinic P1 space group. Mg(1) is bonded in a 4-coordinate geometry to one O(1), one O(5), and two equivalent O(4) atoms. There are six inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a rectangular see-saw-like geometry to one O(1), one O(4), one O(5), and one O(8) atom. In the second Ag site, Ag(2) is bonded in a rectangular see-saw-like geometry to one O(2), one O(3), one O(6), and one O(7) atom. In the third Ag site, Ag(3) is bonded in a rectangular see-saw-like geometry to one O(2), one O(3), one O(5), and one O(8) atom. In the fourth Ag site, Ag(4) is bonded in a distorted square co-planar geometry to one O(1), one O(4), one O(6), and one O(7) atom. In the fifth Ag site, Ag(5) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(3), one O(6), and one O(7) atom. In the sixth Ag site, Ag(6) is bonded in a 5-coordinate geometry to one O(2), one O(4), one O(5), and two equivalent O(8) atoms. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted see-saw-like geometry to one Mg(1), one Ag(1), one Ag(4), and one Ag(5) atom. In the second O site, O(2) is bonded in a trigonal non-coplanar geometry to one Ag(2), one Ag(3), and one Ag(6) atom. In the third O site, O(3) is bonded in a trigonal non-coplanar geometry to one Ag(2), one Ag(3), and one Ag(5) atom. In the fourth O site, O(4) is bonded to two equivalent Mg(1), one Ag(1), one Ag(4), and one Ag(6) atom to form distorted OMg2Ag3 trigonal bipyramids that share corners with two equivalent O(5)MgAg3 tetrahedra, corners with two equivalent O(4)Mg2Ag3 trigonal bipyramids, and  an edgeedge with one O(5)MgAg3 tetrahedra. In the fifth O site, O(5) is bonded to one Mg(1), one Ag(1), one Ag(3), and one Ag(6) atom to form a mixture of distorted edge and corner-sharing OMgAg3 tetrahedra. In the sixth O site, O(6) is bonded in a distorted trigonal non-coplanar geometry to one Ag(2), one Ag(4), and one Ag(5) atom. In the seventh O site, O(7) is bonded in a distorted trigonal non-coplanar geometry to one Ag(2), one Ag(4), and one Ag(5) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one Ag(1), one Ag(3), and two equivalent Ag(6) atoms. is represented by the CIF file [CIF]
data_Mg(Ag3O4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.680
_cell_length_b   5.758
_cell_length_c   10.000
_cell_angle_alpha   88.555
_cell_angle_beta   89.241
_cell_angle_gamma   101.959
_symmetry_Int_Tables_number   1
_cell_volume   207.207
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.692  0.088  0.824  1.0
  Ag  Ag1  1  0.286  0.551  0.856  1.0
  Ag  Ag2  1  0.678  0.939  0.356  1.0
  Ag  Ag3  1  0.734  0.444  0.145  1.0
  Ag  Ag4  1  0.211  0.040  0.607  1.0
  Ag  Ag5  1  0.951  0.485  0.489  1.0
  Ag  Ag6  1  0.094  0.972  0.041  1.0
  O  O7  1  0.984  0.321  0.683  1.0
  O  O8  1  0.961  0.161  0.210  1.0
  O  O9  1  0.927  0.657  0.305  1.0
  O  O10  1  0.135  0.914  0.813  1.0
  O  O11  1  0.531  0.268  0.974  1.0
  O  O12  1  0.502  0.224  0.434  1.0
  O  O13  1  0.414  0.754  0.527  1.0
  O  O14  1  0.578  0.724  0.044  1.0
[/CIF]
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