The material structure described by LaFeSbO6 crystallizes in the monoclinic Pc space group. La(1) is bonded in a 8-coordinate geometry to one O(1), one O(4), one O(5), one O(6), two equivalent O(2), and two equivalent O(3) atoms. Fe(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form FeO6 octahedra that share corners with six equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 13-26°. Sb(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form SbO6 octahedra that share corners with six equivalent Fe(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 13-26°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one La(1), one Fe(1), and one Sb(1) atom. In the second O site, O(2) is bonded in a distorted rectangular see-saw-like geometry to two equivalent La(1), one Fe(1), and one Sb(1) atom. In the third O site, O(3) is bonded in a distorted rectangular see-saw-like geometry to two equivalent La(1), one Fe(1), and one Sb(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one La(1), one Fe(1), and one Sb(1) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one La(1), one Fe(1), and one Sb(1) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one La(1), one Fe(1), and one Sb(1) atom. is represented by the CIF file [CIF]
data_LaFeSbO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.621
_cell_length_b   5.600
_cell_length_c   9.668
_cell_angle_alpha   54.722
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   248.430
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.213  0.741  0.250  1.0
  La  La1  1  0.787  0.741  0.750  1.0
  Fe  Fe2  1  0.736  0.001  0.997  1.0
  Fe  Fe3  1  0.264  0.001  0.497  1.0
  Sb  Sb4  1  0.738  0.494  0.503  1.0
  Sb  Sb5  1  0.262  0.494  0.003  1.0
  O  O6  1  0.232  0.793  0.752  1.0
  O  O7  1  0.020  0.260  0.974  1.0
  O  O8  1  0.012  0.705  0.525  1.0
  O  O9  1  0.988  0.705  0.025  1.0
  O  O10  1  0.980  0.260  0.474  1.0
  O  O11  1  0.768  0.793  0.252  1.0
  O  O12  1  0.744  0.173  0.749  1.0
  O  O13  1  0.537  0.745  0.539  1.0
  O  O14  1  0.539  0.327  0.961  1.0
  O  O15  1  0.461  0.327  0.461  1.0
  O  O16  1  0.463  0.745  0.039  1.0
  O  O17  1  0.256  0.173  0.249  1.0
[/CIF]
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The material structure described by LaFeSbO6 crystallizes in the monoclinic Pc space group. La(1) is bonded in a 8-coordinate geometry to one O(1), one O(4), one O(5), one O(6), two equivalent O(2), and two equivalent O(3) atoms. Fe(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form FeO6 octahedra that share corners with six equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 13-26°. Sb(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form SbO6 octahedra that share corners with six equivalent Fe(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 13-26°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one La(1), one Fe(1), and one Sb(1) atom. In the second O site, O(2) is bonded in a distorted rectangular see-saw-like geometry to two equivalent La(1), one Fe(1), and one Sb(1) atom. In the third O site, O(3) is bonded in a distorted rectangular see-saw-like geometry to two equivalent La(1), one Fe(1), and one Sb(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one La(1), one Fe(1), and one Sb(1) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one La(1), one Fe(1), and one Sb(1) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one La(1), one Fe(1), and one Sb(1) atom. is represented by the CIF file [CIF]
data_LaFeSbO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.621
_cell_length_b   5.600
_cell_length_c   9.668
_cell_angle_alpha   54.722
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   248.430
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.213  0.741  0.250  1.0
  La  La1  1  0.787  0.741  0.750  1.0
  Fe  Fe2  1  0.736  0.001  0.997  1.0
  Fe  Fe3  1  0.264  0.001  0.497  1.0
  Sb  Sb4  1  0.738  0.494  0.503  1.0
  Sb  Sb5  1  0.262  0.494  0.003  1.0
  O  O6  1  0.232  0.793  0.752  1.0
  O  O7  1  0.020  0.260  0.974  1.0
  O  O8  1  0.012  0.705  0.525  1.0
  O  O9  1  0.988  0.705  0.025  1.0
  O  O10  1  0.980  0.260  0.474  1.0
  O  O11  1  0.768  0.793  0.252  1.0
  O  O12  1  0.744  0.173  0.749  1.0
  O  O13  1  0.537  0.745  0.539  1.0
  O  O14  1  0.539  0.327  0.961  1.0
  O  O15  1  0.461  0.327  0.461  1.0
  O  O16  1  0.463  0.745  0.039  1.0
  O  O17  1  0.256  0.173  0.249  1.0
[/CIF]
.