The crystal structure described by As3Se4SbF6 is beta-prime cadmium gold structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two As3Se4 clusters and two SbF6 clusters. In each As3Se4 cluster, there are two inequivalent As sites. In the first As site, As(1) is bonded in a distorted trigonal non-coplanar geometry to one Se(3) and two equivalent Se(1) atoms. In the second As site, As(2) is bonded in a 3-coordinate geometry to one As(2), one Se(1), and one Se(2) atom. There are three inequivalent Se sites. In the first Se site, Se(1) is bonded in a water-like geometry to one As(1) and one As(2) atom. In the second Se site, Se(2) is bonded in a 3-coordinate geometry to two equivalent As(2) and one Se(3) atom. In the third Se site, Se(3) is bonded in a water-like geometry to one As(1) and one Se(2) atom. In each SbF6 cluster, Sb(1) is bonded in an octahedral geometry to one F(1), one F(4), two equivalent F(2), and two equivalent F(3) atoms. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the CIF file [CIF]
data_SbAs3(Se2F3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.980
_cell_length_b   6.453
_cell_length_c   10.773
_cell_angle_alpha   87.641
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   693.159
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.750  0.499  0.833  1.0
  Sb  Sb1  1  0.250  0.501  0.167  1.0
  As  As2  1  0.250  0.059  0.518  1.0
  As  As3  1  0.124  0.974  0.845  1.0
  As  As4  1  0.624  0.026  0.155  1.0
  As  As5  1  0.750  0.941  0.482  1.0
  As  As6  1  0.876  0.026  0.155  1.0
  As  As7  1  0.376  0.974  0.845  1.0
  Se  Se8  1  0.066  0.136  0.653  1.0
  Se  Se9  1  0.434  0.136  0.653  1.0
  Se  Se10  1  0.750  0.341  0.226  1.0
  Se  Se11  1  0.250  0.659  0.774  1.0
  Se  Se12  1  0.566  0.864  0.347  1.0
  Se  Se13  1  0.750  0.314  0.443  1.0
  Se  Se14  1  0.934  0.864  0.347  1.0
  Se  Se15  1  0.250  0.686  0.557  1.0
  F  F16  1  0.750  0.277  0.717  1.0
  F  F17  1  0.615  0.352  0.929  1.0
  F  F18  1  0.387  0.361  0.265  1.0
  F  F19  1  0.750  0.718  0.949  1.0
  F  F20  1  0.113  0.361  0.265  1.0
  F  F21  1  0.250  0.282  0.051  1.0
  F  F22  1  0.115  0.648  0.071  1.0
  F  F23  1  0.613  0.639  0.735  1.0
  F  F24  1  0.887  0.639  0.735  1.0
  F  F25  1  0.885  0.352  0.929  1.0
  F  F26  1  0.385  0.648  0.071  1.0
  F  F27  1  0.250  0.723  0.283  1.0
[/CIF]
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The crystal structure described by As3Se4SbF6 is beta-prime cadmium gold structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two As3Se4 clusters and two SbF6 clusters. In each As3Se4 cluster, there are two inequivalent As sites. In the first As site, As(1) is bonded in a distorted trigonal non-coplanar geometry to one Se(3) and two equivalent Se(1) atoms. In the second As site, As(2) is bonded in a 3-coordinate geometry to one As(2), one Se(1), and one Se(2) atom. There are three inequivalent Se sites. In the first Se site, Se(1) is bonded in a water-like geometry to one As(1) and one As(2) atom. In the second Se site, Se(2) is bonded in a 3-coordinate geometry to two equivalent As(2) and one Se(3) atom. In the third Se site, Se(3) is bonded in a water-like geometry to one As(1) and one Se(2) atom. In each SbF6 cluster, Sb(1) is bonded in an octahedral geometry to one F(1), one F(4), two equivalent F(2), and two equivalent F(3) atoms. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the CIF file [CIF]
data_SbAs3(Se2F3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.980
_cell_length_b   6.453
_cell_length_c   10.773
_cell_angle_alpha   87.641
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   693.159
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.750  0.499  0.833  1.0
  Sb  Sb1  1  0.250  0.501  0.167  1.0
  As  As2  1  0.250  0.059  0.518  1.0
  As  As3  1  0.124  0.974  0.845  1.0
  As  As4  1  0.624  0.026  0.155  1.0
  As  As5  1  0.750  0.941  0.482  1.0
  As  As6  1  0.876  0.026  0.155  1.0
  As  As7  1  0.376  0.974  0.845  1.0
  Se  Se8  1  0.066  0.136  0.653  1.0
  Se  Se9  1  0.434  0.136  0.653  1.0
  Se  Se10  1  0.750  0.341  0.226  1.0
  Se  Se11  1  0.250  0.659  0.774  1.0
  Se  Se12  1  0.566  0.864  0.347  1.0
  Se  Se13  1  0.750  0.314  0.443  1.0
  Se  Se14  1  0.934  0.864  0.347  1.0
  Se  Se15  1  0.250  0.686  0.557  1.0
  F  F16  1  0.750  0.277  0.717  1.0
  F  F17  1  0.615  0.352  0.929  1.0
  F  F18  1  0.387  0.361  0.265  1.0
  F  F19  1  0.750  0.718  0.949  1.0
  F  F20  1  0.113  0.361  0.265  1.0
  F  F21  1  0.250  0.282  0.051  1.0
  F  F22  1  0.115  0.648  0.071  1.0
  F  F23  1  0.613  0.639  0.735  1.0
  F  F24  1  0.887  0.639  0.735  1.0
  F  F25  1  0.885  0.352  0.929  1.0
  F  F26  1  0.385  0.648  0.071  1.0
  F  F27  1  0.250  0.723  0.283  1.0
[/CIF]
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