The material structure described by WCo3O8 is beta Vanadium nitride-derived structured and crystallizes in the hexagonal P6_3mc space group. W(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form WO6 octahedra that share corners with six equivalent Co(1)O6 octahedra and edges with three equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles are 50°. Co(1) is bonded to one O(3), one O(4), two equivalent O(1), and two equivalent O(2) atoms to form CoO6 octahedra that share corners with two equivalent W(1)O6 octahedra,  an edgeedge with one W(1)O6 octahedra, and edges with four equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles are 50°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one W(1) and two equivalent Co(1) atoms. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one W(1) and two equivalent Co(1) atoms. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Co(1) atoms. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Co(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Co3WO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.787
_cell_length_b   5.787
_cell_length_c   9.182
_cell_angle_alpha   89.997
_cell_angle_beta   90.001
_cell_angle_gamma   120.001
_symmetry_Int_Tables_number   1
_cell_volume   266.322
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.167  0.833  0.213  1.0
  Co  Co1  1  0.167  0.335  0.213  1.0
  Co  Co2  1  0.665  0.833  0.213  1.0
  Co  Co3  1  0.335  0.167  0.713  1.0
  Co  Co4  1  0.833  0.665  0.713  1.0
  Co  Co5  1  0.833  0.167  0.713  1.0
  W  W6  1  0.333  0.667  0.492  1.0
  W  W7  1  0.667  0.333  0.992  1.0
  O  O8  1  0.170  0.830  0.595  1.0
  O  O9  1  0.041  0.520  0.340  1.0
  O  O10  1  0.333  0.667  0.113  1.0
  O  O11  1  0.000  0.000  0.309  1.0
  O  O12  1  1.000  0.000  0.809  1.0
  O  O13  1  0.170  0.340  0.595  1.0
  O  O14  1  0.480  0.959  0.340  1.0
  O  O15  1  0.480  0.520  0.340  1.0
  O  O16  1  0.340  0.170  0.095  1.0
  O  O17  1  0.660  0.830  0.595  1.0
  O  O18  1  0.520  0.480  0.840  1.0
  O  O19  1  0.520  0.041  0.840  1.0
  O  O20  1  0.667  0.333  0.613  1.0
  O  O21  1  0.830  0.660  0.095  1.0
  O  O22  1  0.959  0.479  0.840  1.0
  O  O23  1  0.830  0.170  0.095  1.0
[/CIF]
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The material structure described by WCo3O8 is beta Vanadium nitride-derived structured and crystallizes in the hexagonal P6_3mc space group. W(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form WO6 octahedra that share corners with six equivalent Co(1)O6 octahedra and edges with three equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles are 50°. Co(1) is bonded to one O(3), one O(4), two equivalent O(1), and two equivalent O(2) atoms to form CoO6 octahedra that share corners with two equivalent W(1)O6 octahedra,  an edgeedge with one W(1)O6 octahedra, and edges with four equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles are 50°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one W(1) and two equivalent Co(1) atoms. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one W(1) and two equivalent Co(1) atoms. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Co(1) atoms. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Co(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Co3WO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.787
_cell_length_b   5.787
_cell_length_c   9.182
_cell_angle_alpha   89.997
_cell_angle_beta   90.001
_cell_angle_gamma   120.001
_symmetry_Int_Tables_number   1
_cell_volume   266.322
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.167  0.833  0.213  1.0
  Co  Co1  1  0.167  0.335  0.213  1.0
  Co  Co2  1  0.665  0.833  0.213  1.0
  Co  Co3  1  0.335  0.167  0.713  1.0
  Co  Co4  1  0.833  0.665  0.713  1.0
  Co  Co5  1  0.833  0.167  0.713  1.0
  W  W6  1  0.333  0.667  0.492  1.0
  W  W7  1  0.667  0.333  0.992  1.0
  O  O8  1  0.170  0.830  0.595  1.0
  O  O9  1  0.041  0.520  0.340  1.0
  O  O10  1  0.333  0.667  0.113  1.0
  O  O11  1  0.000  0.000  0.309  1.0
  O  O12  1  1.000  0.000  0.809  1.0
  O  O13  1  0.170  0.340  0.595  1.0
  O  O14  1  0.480  0.959  0.340  1.0
  O  O15  1  0.480  0.520  0.340  1.0
  O  O16  1  0.340  0.170  0.095  1.0
  O  O17  1  0.660  0.830  0.595  1.0
  O  O18  1  0.520  0.480  0.840  1.0
  O  O19  1  0.520  0.041  0.840  1.0
  O  O20  1  0.667  0.333  0.613  1.0
  O  O21  1  0.830  0.660  0.095  1.0
  O  O22  1  0.959  0.479  0.840  1.0
  O  O23  1  0.830  0.170  0.095  1.0
[/CIF]
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