The structure described by KVOF4 crystallizes in the monoclinic P2_1/c space group. K(1) is bonded in a 9-coordinate geometry to one O(1), two equivalent F(1), two equivalent F(2), two equivalent F(3), and two equivalent F(4) atoms. V(1) is bonded in a 5-coordinate geometry to one O(1), one F(1), one F(2), one F(3), and one F(4) atom. O(1) is bonded in a single-bond geometry to one K(1) and one V(1) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to two equivalent K(1) and one V(1) atom. In the second F site, F(2) is bonded in a distorted single-bond geometry to two equivalent K(1) and one V(1) atom. In the third F site, F(3) is bonded in a distorted single-bond geometry to two equivalent K(1) and one V(1) atom. In the fourth F site, F(4) is bonded in a distorted single-bond geometry to two equivalent K(1) and one V(1) atom. is represented by the CIF file [CIF]
data_KVOF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   14.002
_cell_length_b   5.642
_cell_length_c   5.685
_cell_angle_alpha   84.154
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   446.755
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.877  0.454  0.731  1.0
  K  K1  1  0.623  0.954  0.731  1.0
  K  K2  1  0.123  0.546  0.269  1.0
  K  K3  1  0.377  0.046  0.269  1.0
  V  V4  1  0.646  0.444  0.216  1.0
  V  V5  1  0.854  0.944  0.216  1.0
  V  V6  1  0.354  0.556  0.784  1.0
  V  V7  1  0.146  0.056  0.784  1.0
  O  O8  1  0.586  0.665  0.299  1.0
  O  O9  1  0.414  0.335  0.701  1.0
  O  O10  1  0.914  0.165  0.299  1.0
  O  O11  1  0.086  0.835  0.701  1.0
  F  F12  1  0.392  0.563  0.091  1.0
  F  F13  1  0.066  0.310  0.704  1.0
  F  F14  1  0.245  0.396  0.914  1.0
  F  F15  1  0.783  0.847  0.480  1.0
  F  F16  1  0.283  0.653  0.520  1.0
  F  F17  1  0.108  0.063  0.091  1.0
  F  F18  1  0.255  0.896  0.914  1.0
  F  F19  1  0.717  0.347  0.480  1.0
  F  F20  1  0.892  0.937  0.909  1.0
  F  F21  1  0.434  0.810  0.704  1.0
  F  F22  1  0.745  0.104  0.086  1.0
  F  F23  1  0.934  0.690  0.296  1.0
  F  F24  1  0.566  0.190  0.296  1.0
  F  F25  1  0.755  0.604  0.086  1.0
  F  F26  1  0.217  0.153  0.520  1.0
  F  F27  1  0.608  0.437  0.909  1.0
[/CIF]
.
The structure described by KVOF4 crystallizes in the monoclinic P2_1/c space group. K(1) is bonded in a 9-coordinate geometry to one O(1), two equivalent F(1), two equivalent F(2), two equivalent F(3), and two equivalent F(4) atoms. V(1) is bonded in a 5-coordinate geometry to one O(1), one F(1), one F(2), one F(3), and one F(4) atom. O(1) is bonded in a single-bond geometry to one K(1) and one V(1) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to two equivalent K(1) and one V(1) atom. In the second F site, F(2) is bonded in a distorted single-bond geometry to two equivalent K(1) and one V(1) atom. In the third F site, F(3) is bonded in a distorted single-bond geometry to two equivalent K(1) and one V(1) atom. In the fourth F site, F(4) is bonded in a distorted single-bond geometry to two equivalent K(1) and one V(1) atom. is represented by the CIF file [CIF]
data_KVOF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   14.002
_cell_length_b   5.642
_cell_length_c   5.685
_cell_angle_alpha   84.154
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   446.755
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.877  0.454  0.731  1.0
  K  K1  1  0.623  0.954  0.731  1.0
  K  K2  1  0.123  0.546  0.269  1.0
  K  K3  1  0.377  0.046  0.269  1.0
  V  V4  1  0.646  0.444  0.216  1.0
  V  V5  1  0.854  0.944  0.216  1.0
  V  V6  1  0.354  0.556  0.784  1.0
  V  V7  1  0.146  0.056  0.784  1.0
  O  O8  1  0.586  0.665  0.299  1.0
  O  O9  1  0.414  0.335  0.701  1.0
  O  O10  1  0.914  0.165  0.299  1.0
  O  O11  1  0.086  0.835  0.701  1.0
  F  F12  1  0.392  0.563  0.091  1.0
  F  F13  1  0.066  0.310  0.704  1.0
  F  F14  1  0.245  0.396  0.914  1.0
  F  F15  1  0.783  0.847  0.480  1.0
  F  F16  1  0.283  0.653  0.520  1.0
  F  F17  1  0.108  0.063  0.091  1.0
  F  F18  1  0.255  0.896  0.914  1.0
  F  F19  1  0.717  0.347  0.480  1.0
  F  F20  1  0.892  0.937  0.909  1.0
  F  F21  1  0.434  0.810  0.704  1.0
  F  F22  1  0.745  0.104  0.086  1.0
  F  F23  1  0.934  0.690  0.296  1.0
  F  F24  1  0.566  0.190  0.296  1.0
  F  F25  1  0.755  0.604  0.086  1.0
  F  F26  1  0.217  0.153  0.520  1.0
  F  F27  1  0.608  0.437  0.909  1.0
[/CIF]
.