The structure described by Mg(ReO5)2O2 is alpha carbon monoxide-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one 7782-44-7 molecule and one Mg(ReO5)2 cluster. In the Mg(ReO5)2 cluster, Mg(1) is bonded to one O(1), one O(11), one O(12), and one O(3) atom to form distorted MgO4 tetrahedra that share  a cornercorner with one Re(1)O4 tetrahedra and  a cornercorner with one Re(2)O4 tetrahedra. There are two inequivalent Re sites. In the first Re site, Re(1) is bonded to one O(11), one O(6), one O(7), and one O(9) atom to form ReO4 tetrahedra that share  a cornercorner with one Mg(1)O4 tetrahedra. In the second Re site, Re(2) is bonded to one O(10), one O(12), one O(5), and one O(8) atom to form ReO4 tetrahedra that share  a cornercorner with one Mg(1)O4 tetrahedra. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Mg(1) atom. In the second O site, O(3) is bonded in a single-bond geometry to one Mg(1) atom. In the third O site, O(5) is bonded in a single-bond geometry to one Re(2) atom. In the fourth O site, O(6) is bonded in a single-bond geometry to one Re(1) atom. In the fifth O site, O(7) is bonded in a single-bond geometry to one Re(1) atom. In the sixth O site, O(8) is bonded in a single-bond geometry to one Re(2) atom. In the seventh O site, O(9) is bonded in a single-bond geometry to one Re(1) atom. In the eighth O site, O(10) is bonded in a single-bond geometry to one Re(2) atom. In the ninth O site, O(11) is bonded in a bent 150 degrees geometry to one Mg(1) and one Re(1) atom. In the tenth O site, O(12) is bonded in a bent 150 degrees geometry to one Mg(1) and one Re(2) atom. is represented by the CIF card [CIF]
data_Mg(ReO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.378
_cell_length_b   7.193
_cell_length_c   7.462
_cell_angle_alpha   100.793
_cell_angle_beta   110.001
_cell_angle_gamma   108.927
_symmetry_Int_Tables_number   1
_cell_volume   286.656
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.861  0.916  0.906  1.0
  Re  Re1  1  0.896  0.665  0.294  1.0
  Re  Re2  1  0.138  0.342  0.730  1.0
  O  O3  1  0.770  0.636  0.703  1.0
  O  O4  1  0.328  0.271  0.274  1.0
  O  O5  1  0.682  0.105  0.860  1.0
  O  O6  1  0.396  0.134  0.239  1.0
  O  O7  1  0.259  0.586  0.912  1.0
  O  O8  1  0.760  0.409  0.133  1.0
  O  O9  1  0.720  0.702  0.424  1.0
  O  O10  1  0.358  0.331  0.645  1.0
  O  O11  1  0.190  0.724  0.468  1.0
  O  O12  1  0.880  0.311  0.526  1.0
  O  O13  1  0.907  0.835  0.146  1.0
  O  O14  1  0.059  0.133  0.833  1.0
[/CIF]
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The structure described by Mg(ReO5)2O2 is alpha carbon monoxide-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one 7782-44-7 molecule and one Mg(ReO5)2 cluster. In the Mg(ReO5)2 cluster, Mg(1) is bonded to one O(1), one O(11), one O(12), and one O(3) atom to form distorted MgO4 tetrahedra that share  a cornercorner with one Re(1)O4 tetrahedra and  a cornercorner with one Re(2)O4 tetrahedra. There are two inequivalent Re sites. In the first Re site, Re(1) is bonded to one O(11), one O(6), one O(7), and one O(9) atom to form ReO4 tetrahedra that share  a cornercorner with one Mg(1)O4 tetrahedra. In the second Re site, Re(2) is bonded to one O(10), one O(12), one O(5), and one O(8) atom to form ReO4 tetrahedra that share  a cornercorner with one Mg(1)O4 tetrahedra. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Mg(1) atom. In the second O site, O(3) is bonded in a single-bond geometry to one Mg(1) atom. In the third O site, O(5) is bonded in a single-bond geometry to one Re(2) atom. In the fourth O site, O(6) is bonded in a single-bond geometry to one Re(1) atom. In the fifth O site, O(7) is bonded in a single-bond geometry to one Re(1) atom. In the sixth O site, O(8) is bonded in a single-bond geometry to one Re(2) atom. In the seventh O site, O(9) is bonded in a single-bond geometry to one Re(1) atom. In the eighth O site, O(10) is bonded in a single-bond geometry to one Re(2) atom. In the ninth O site, O(11) is bonded in a bent 150 degrees geometry to one Mg(1) and one Re(1) atom. In the tenth O site, O(12) is bonded in a bent 150 degrees geometry to one Mg(1) and one Re(2) atom. is represented by the CIF card [CIF]
data_Mg(ReO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.378
_cell_length_b   7.193
_cell_length_c   7.462
_cell_angle_alpha   100.793
_cell_angle_beta   110.001
_cell_angle_gamma   108.927
_symmetry_Int_Tables_number   1
_cell_volume   286.656
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.861  0.916  0.906  1.0
  Re  Re1  1  0.896  0.665  0.294  1.0
  Re  Re2  1  0.138  0.342  0.730  1.0
  O  O3  1  0.770  0.636  0.703  1.0
  O  O4  1  0.328  0.271  0.274  1.0
  O  O5  1  0.682  0.105  0.860  1.0
  O  O6  1  0.396  0.134  0.239  1.0
  O  O7  1  0.259  0.586  0.912  1.0
  O  O8  1  0.760  0.409  0.133  1.0
  O  O9  1  0.720  0.702  0.424  1.0
  O  O10  1  0.358  0.331  0.645  1.0
  O  O11  1  0.190  0.724  0.468  1.0
  O  O12  1  0.880  0.311  0.526  1.0
  O  O13  1  0.907  0.835  0.146  1.0
  O  O14  1  0.059  0.133  0.833  1.0
[/CIF]
.