The structure described by Cs3NaLi2(BO3)2 crystallizes in the triclinic P-1 space group. There are three inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a 6-coordinate geometry to one O(3), one O(6), two equivalent O(1), and two equivalent O(2) atoms. In the second Cs site, Cs(2) is bonded in a 4-coordinate geometry to one O(4), one O(6), and two equivalent O(5) atoms. In the third Cs site, Cs(3) is bonded in a 6-coordinate geometry to one O(1), one O(3), one O(5), one O(6), and two equivalent O(2) atoms. Na(1) is bonded in a 5-coordinate geometry to one O(3), one O(5), one O(6), and two equivalent O(4) atoms. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(3), and one O(4) atom. In the second Li site, Li(2) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(5), and one O(6) atom. There are two inequivalent B sites. In the first B site, B(1) is bonded in a trigonal planar geometry to one O(2), one O(4), and one O(5) atom. In the second B site, B(2) is bonded in a trigonal planar geometry to one O(1), one O(3), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Cs(3), two equivalent Cs(1), one Li(1), one Li(2), and one B(2) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Cs(1), two equivalent Cs(3), one Li(1), one Li(2), and one B(1) atom. In the third O site, O(3) is bonded in a 1-coordinate geometry to one Cs(1), one Cs(3), one Na(1), one Li(1), and one B(2) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to one Cs(2), two equivalent Na(1), one Li(1), and one B(1) atom. In the fifth O site, O(5) is bonded in a 1-coordinate geometry to one Cs(3), two equivalent Cs(2), one Na(1), one Li(2), and one B(1) atom. In the sixth O site, O(6) is bonded in a 1-coordinate geometry to one Cs(1), one Cs(2), one Cs(3), one Na(1), one Li(2), and one B(2) atom. is represented by the CIF card [CIF]
data_Cs3NaLi2(BO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.815
_cell_length_b   7.418
_cell_length_c   10.397
_cell_angle_alpha   96.609
_cell_angle_beta   101.489
_cell_angle_gamma   103.868
_symmetry_Int_Tables_number   1
_cell_volume   492.692
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.647  0.269  0.924  1.0
  Cs  Cs1  1  0.817  0.696  0.517  1.0
  Cs  Cs2  1  0.353  0.731  0.076  1.0
  Cs  Cs3  1  0.183  0.304  0.483  1.0
  Cs  Cs4  1  0.786  0.774  0.871  1.0
  Cs  Cs5  1  0.214  0.226  0.129  1.0
  Na  Na6  1  0.327  0.827  0.416  1.0
  Na  Na7  1  0.673  0.173  0.584  1.0
  Li  Li8  1  0.202  0.090  0.764  1.0
  Li  Li9  1  0.226  0.598  0.759  1.0
  Li  Li10  1  0.774  0.402  0.241  1.0
  Li  Li11  1  0.798  0.910  0.236  1.0
  B  B12  1  0.349  0.869  0.687  1.0
  B  B13  1  0.032  0.313  0.782  1.0
  B  B14  1  0.651  0.131  0.313  1.0
  B  B15  1  0.968  0.687  0.218  1.0
  O  O16  1  0.248  0.369  0.837  1.0
  O  O17  1  0.307  0.875  0.815  1.0
  O  O18  1  0.072  0.878  0.237  1.0
  O  O19  1  0.693  0.125  0.185  1.0
  O  O20  1  0.348  0.025  0.624  1.0
  O  O21  1  0.378  0.703  0.626  1.0
  O  O22  1  0.752  0.631  0.163  1.0
  O  O23  1  0.652  0.975  0.376  1.0
  O  O24  1  0.932  0.447  0.739  1.0
  O  O25  1  0.928  0.122  0.763  1.0
  O  O26  1  0.622  0.297  0.374  1.0
  O  O27  1  0.068  0.553  0.261  1.0
[/CIF]
.
The structure described by Cs3NaLi2(BO3)2 crystallizes in the triclinic P-1 space group. There are three inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a 6-coordinate geometry to one O(3), one O(6), two equivalent O(1), and two equivalent O(2) atoms. In the second Cs site, Cs(2) is bonded in a 4-coordinate geometry to one O(4), one O(6), and two equivalent O(5) atoms. In the third Cs site, Cs(3) is bonded in a 6-coordinate geometry to one O(1), one O(3), one O(5), one O(6), and two equivalent O(2) atoms. Na(1) is bonded in a 5-coordinate geometry to one O(3), one O(5), one O(6), and two equivalent O(4) atoms. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(3), and one O(4) atom. In the second Li site, Li(2) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(5), and one O(6) atom. There are two inequivalent B sites. In the first B site, B(1) is bonded in a trigonal planar geometry to one O(2), one O(4), and one O(5) atom. In the second B site, B(2) is bonded in a trigonal planar geometry to one O(1), one O(3), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Cs(3), two equivalent Cs(1), one Li(1), one Li(2), and one B(2) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Cs(1), two equivalent Cs(3), one Li(1), one Li(2), and one B(1) atom. In the third O site, O(3) is bonded in a 1-coordinate geometry to one Cs(1), one Cs(3), one Na(1), one Li(1), and one B(2) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to one Cs(2), two equivalent Na(1), one Li(1), and one B(1) atom. In the fifth O site, O(5) is bonded in a 1-coordinate geometry to one Cs(3), two equivalent Cs(2), one Na(1), one Li(2), and one B(1) atom. In the sixth O site, O(6) is bonded in a 1-coordinate geometry to one Cs(1), one Cs(2), one Cs(3), one Na(1), one Li(2), and one B(2) atom. is represented by the CIF card [CIF]
data_Cs3NaLi2(BO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.815
_cell_length_b   7.418
_cell_length_c   10.397
_cell_angle_alpha   96.609
_cell_angle_beta   101.489
_cell_angle_gamma   103.868
_symmetry_Int_Tables_number   1
_cell_volume   492.692
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.647  0.269  0.924  1.0
  Cs  Cs1  1  0.817  0.696  0.517  1.0
  Cs  Cs2  1  0.353  0.731  0.076  1.0
  Cs  Cs3  1  0.183  0.304  0.483  1.0
  Cs  Cs4  1  0.786  0.774  0.871  1.0
  Cs  Cs5  1  0.214  0.226  0.129  1.0
  Na  Na6  1  0.327  0.827  0.416  1.0
  Na  Na7  1  0.673  0.173  0.584  1.0
  Li  Li8  1  0.202  0.090  0.764  1.0
  Li  Li9  1  0.226  0.598  0.759  1.0
  Li  Li10  1  0.774  0.402  0.241  1.0
  Li  Li11  1  0.798  0.910  0.236  1.0
  B  B12  1  0.349  0.869  0.687  1.0
  B  B13  1  0.032  0.313  0.782  1.0
  B  B14  1  0.651  0.131  0.313  1.0
  B  B15  1  0.968  0.687  0.218  1.0
  O  O16  1  0.248  0.369  0.837  1.0
  O  O17  1  0.307  0.875  0.815  1.0
  O  O18  1  0.072  0.878  0.237  1.0
  O  O19  1  0.693  0.125  0.185  1.0
  O  O20  1  0.348  0.025  0.624  1.0
  O  O21  1  0.378  0.703  0.626  1.0
  O  O22  1  0.752  0.631  0.163  1.0
  O  O23  1  0.652  0.975  0.376  1.0
  O  O24  1  0.932  0.447  0.739  1.0
  O  O25  1  0.928  0.122  0.763  1.0
  O  O26  1  0.622  0.297  0.374  1.0
  O  O27  1  0.068  0.553  0.261  1.0
[/CIF]
.