The crystal structure described by Ba2MgCuSb2F14 crystallizes in the triclinic P-1 space group. There are two inequivalent Ba sites. In the first Ba site, Ba(1) is bonded in a 10-coordinate geometry to one F(1), one F(13), one F(14), one F(4), one F(8), one F(9), two equivalent F(2), and two equivalent F(3) atoms. In the second Ba site, Ba(2) is bonded in a 10-coordinate geometry to one F(11), one F(12), one F(14), one F(5), one F(7), one F(8), two equivalent F(10), and two equivalent F(6) atoms. Mg(1) is bonded in a 4-coordinate geometry to one F(1), one F(11), one F(4), one F(7), and one F(9) atom. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a square co-planar geometry to two equivalent F(12) and two equivalent F(5) atoms. In the second Cu site, Cu(2) is bonded in a square co-planar geometry to two equivalent F(13) and two equivalent F(4) atoms. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 6-coordinate geometry to one F(10), one F(12), one F(6), one F(7), one F(8), and one F(9) atom. In the second Sb site, Sb(2) is bonded in a 6-coordinate geometry to one F(1), one F(11), one F(13), one F(14), one F(2), and one F(3) atom. There are fourteen inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one Ba(1), one Mg(1), and one Sb(2) atom. In the second F site, F(2) is bonded in a distorted single-bond geometry to two equivalent Ba(1) and one Sb(2) atom. In the third F site, F(3) is bonded in a distorted bent 120 degrees geometry to two equivalent Ba(1) and one Sb(2) atom. In the fourth F site, F(4) is bonded in a 3-coordinate geometry to one Ba(1), one Mg(1), and one Cu(2) atom. In the fifth F site, F(5) is bonded in a 1-coordinate geometry to one Ba(2) and one Cu(1) atom. In the sixth F site, F(6) is bonded in a 1-coordinate geometry to two equivalent Ba(2) and one Sb(1) atom. In the seventh F site, F(7) is bonded in a distorted trigonal planar geometry to one Ba(2), one Mg(1), and one Sb(1) atom. In the eighth F site, F(8) is bonded in a distorted trigonal non-coplanar geometry to one Ba(1), one Ba(2), and one Sb(1) atom. In the ninth F site, F(9) is bonded in a distorted trigonal planar geometry to one Ba(1), one Mg(1), and one Sb(1) atom. In the tenth F site, F(10) is bonded in a 3-coordinate geometry to two equivalent Ba(2) and one Sb(1) atom. In the eleventh F site, F(11) is bonded in a 3-coordinate geometry to one Ba(2), one Mg(1), and one Sb(2) atom. In the twelfth F site, F(12) is bonded in a 3-coordinate geometry to one Ba(2), one Cu(1), and one Sb(1) atom. In the thirteenth F site, F(13) is bonded in a 3-coordinate geometry to one Ba(1), one Cu(2), and one Sb(2) atom. In the fourteenth F site, F(14) is bonded in a distorted trigonal non-coplanar geometry to one Ba(1), one Ba(2), and one Sb(2) atom. is represented by the CIF file [CIF]
data_Ba2MgCuSb2F14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.352
_cell_length_b   7.713
_cell_length_c   16.224
_cell_angle_alpha   89.881
_cell_angle_beta   90.671
_cell_angle_gamma   109.623
_symmetry_Int_Tables_number   1
_cell_volume   630.814
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.736  0.646  0.373  1.0
  Ba  Ba1  1  0.909  0.648  0.873  1.0
  Ba  Ba2  1  0.264  0.354  0.627  1.0
  Ba  Ba3  1  0.091  0.352  0.127  1.0
  Mg  Mg4  1  0.450  0.001  0.253  1.0
  Mg  Mg5  1  0.550  0.999  0.747  1.0
  Cu  Cu6  1  0.500  0.000  0.000  1.0
  Cu  Cu7  1  0.500  0.000  0.500  1.0
  Sb  Sb8  1  0.846  0.773  0.125  1.0
  Sb  Sb9  1  0.154  0.227  0.875  1.0
  Sb  Sb10  1  0.932  0.774  0.623  1.0
  Sb  Sb11  1  0.068  0.226  0.377  1.0
  F  F12  1  0.845  0.022  0.671  1.0
  F  F13  1  0.587  0.699  0.549  1.0
  F  F14  1  0.413  0.301  0.451  1.0
  F  F15  1  0.119  0.503  0.395  1.0
  F  F16  1  0.594  0.940  0.392  1.0
  F  F17  1  0.663  0.064  0.106  1.0
  F  F18  1  0.112  0.697  0.052  1.0
  F  F19  1  0.810  0.976  0.830  1.0
  F  F20  1  0.992  0.646  0.218  1.0
  F  F21  1  0.881  0.497  0.605  1.0
  F  F22  1  0.562  0.788  0.238  1.0
  F  F23  1  0.616  0.498  0.104  1.0
  F  F24  1  0.227  0.788  0.737  1.0
  F  F25  1  0.438  0.212  0.762  1.0
  F  F26  1  0.337  0.936  0.894  1.0
  F  F27  1  0.008  0.354  0.782  1.0
  F  F28  1  0.292  0.164  0.012  1.0
  F  F29  1  0.155  0.978  0.329  1.0
  F  F30  1  0.708  0.836  0.988  1.0
  F  F31  1  0.867  0.158  0.514  1.0
  F  F32  1  0.888  0.303  0.948  1.0
  F  F33  1  0.773  0.212  0.263  1.0
  F  F34  1  0.665  0.652  0.715  1.0
  F  F35  1  0.133  0.842  0.486  1.0
  F  F36  1  0.406  0.060  0.608  1.0
  F  F37  1  0.190  0.024  0.170  1.0
  F  F38  1  0.335  0.348  0.285  1.0
  F  F39  1  0.384  0.502  0.896  1.0
[/CIF]
.
The crystal structure described by Ba2MgCuSb2F14 crystallizes in the triclinic P-1 space group. There are two inequivalent Ba sites. In the first Ba site, Ba(1) is bonded in a 10-coordinate geometry to one F(1), one F(13), one F(14), one F(4), one F(8), one F(9), two equivalent F(2), and two equivalent F(3) atoms. In the second Ba site, Ba(2) is bonded in a 10-coordinate geometry to one F(11), one F(12), one F(14), one F(5), one F(7), one F(8), two equivalent F(10), and two equivalent F(6) atoms. Mg(1) is bonded in a 4-coordinate geometry to one F(1), one F(11), one F(4), one F(7), and one F(9) atom. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a square co-planar geometry to two equivalent F(12) and two equivalent F(5) atoms. In the second Cu site, Cu(2) is bonded in a square co-planar geometry to two equivalent F(13) and two equivalent F(4) atoms. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 6-coordinate geometry to one F(10), one F(12), one F(6), one F(7), one F(8), and one F(9) atom. In the second Sb site, Sb(2) is bonded in a 6-coordinate geometry to one F(1), one F(11), one F(13), one F(14), one F(2), and one F(3) atom. There are fourteen inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one Ba(1), one Mg(1), and one Sb(2) atom. In the second F site, F(2) is bonded in a distorted single-bond geometry to two equivalent Ba(1) and one Sb(2) atom. In the third F site, F(3) is bonded in a distorted bent 120 degrees geometry to two equivalent Ba(1) and one Sb(2) atom. In the fourth F site, F(4) is bonded in a 3-coordinate geometry to one Ba(1), one Mg(1), and one Cu(2) atom. In the fifth F site, F(5) is bonded in a 1-coordinate geometry to one Ba(2) and one Cu(1) atom. In the sixth F site, F(6) is bonded in a 1-coordinate geometry to two equivalent Ba(2) and one Sb(1) atom. In the seventh F site, F(7) is bonded in a distorted trigonal planar geometry to one Ba(2), one Mg(1), and one Sb(1) atom. In the eighth F site, F(8) is bonded in a distorted trigonal non-coplanar geometry to one Ba(1), one Ba(2), and one Sb(1) atom. In the ninth F site, F(9) is bonded in a distorted trigonal planar geometry to one Ba(1), one Mg(1), and one Sb(1) atom. In the tenth F site, F(10) is bonded in a 3-coordinate geometry to two equivalent Ba(2) and one Sb(1) atom. In the eleventh F site, F(11) is bonded in a 3-coordinate geometry to one Ba(2), one Mg(1), and one Sb(2) atom. In the twelfth F site, F(12) is bonded in a 3-coordinate geometry to one Ba(2), one Cu(1), and one Sb(1) atom. In the thirteenth F site, F(13) is bonded in a 3-coordinate geometry to one Ba(1), one Cu(2), and one Sb(2) atom. In the fourteenth F site, F(14) is bonded in a distorted trigonal non-coplanar geometry to one Ba(1), one Ba(2), and one Sb(2) atom. is represented by the CIF file [CIF]
data_Ba2MgCuSb2F14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.352
_cell_length_b   7.713
_cell_length_c   16.224
_cell_angle_alpha   89.881
_cell_angle_beta   90.671
_cell_angle_gamma   109.623
_symmetry_Int_Tables_number   1
_cell_volume   630.814
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.736  0.646  0.373  1.0
  Ba  Ba1  1  0.909  0.648  0.873  1.0
  Ba  Ba2  1  0.264  0.354  0.627  1.0
  Ba  Ba3  1  0.091  0.352  0.127  1.0
  Mg  Mg4  1  0.450  0.001  0.253  1.0
  Mg  Mg5  1  0.550  0.999  0.747  1.0
  Cu  Cu6  1  0.500  0.000  0.000  1.0
  Cu  Cu7  1  0.500  0.000  0.500  1.0
  Sb  Sb8  1  0.846  0.773  0.125  1.0
  Sb  Sb9  1  0.154  0.227  0.875  1.0
  Sb  Sb10  1  0.932  0.774  0.623  1.0
  Sb  Sb11  1  0.068  0.226  0.377  1.0
  F  F12  1  0.845  0.022  0.671  1.0
  F  F13  1  0.587  0.699  0.549  1.0
  F  F14  1  0.413  0.301  0.451  1.0
  F  F15  1  0.119  0.503  0.395  1.0
  F  F16  1  0.594  0.940  0.392  1.0
  F  F17  1  0.663  0.064  0.106  1.0
  F  F18  1  0.112  0.697  0.052  1.0
  F  F19  1  0.810  0.976  0.830  1.0
  F  F20  1  0.992  0.646  0.218  1.0
  F  F21  1  0.881  0.497  0.605  1.0
  F  F22  1  0.562  0.788  0.238  1.0
  F  F23  1  0.616  0.498  0.104  1.0
  F  F24  1  0.227  0.788  0.737  1.0
  F  F25  1  0.438  0.212  0.762  1.0
  F  F26  1  0.337  0.936  0.894  1.0
  F  F27  1  0.008  0.354  0.782  1.0
  F  F28  1  0.292  0.164  0.012  1.0
  F  F29  1  0.155  0.978  0.329  1.0
  F  F30  1  0.708  0.836  0.988  1.0
  F  F31  1  0.867  0.158  0.514  1.0
  F  F32  1  0.888  0.303  0.948  1.0
  F  F33  1  0.773  0.212  0.263  1.0
  F  F34  1  0.665  0.652  0.715  1.0
  F  F35  1  0.133  0.842  0.486  1.0
  F  F36  1  0.406  0.060  0.608  1.0
  F  F37  1  0.190  0.024  0.170  1.0
  F  F38  1  0.335  0.348  0.285  1.0
  F  F39  1  0.384  0.502  0.896  1.0
[/CIF]
.