The crystal structure described by (YbH12(O3Cl)2)2Cl2 is beta-prime cadmium gold structured and crystallizes in the monoclinic P2/c space group. The structure is zero-dimensional and consists of two hydrochloric acid atoms and two YbH12(O3Cl)2 clusters. In each YbH12(O3Cl)2 cluster, Yb(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent Cl(1) atoms. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Yb(1), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Yb(1), one H(3), and one H(4) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one Yb(1), one H(5), and one H(6) atom. Cl(1) is bonded in a distorted single-bond geometry to one Yb(1) atom. is represented by the CIF card [CIF]
data_YbH12(ClO2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.077
_cell_length_b   7.977
_cell_length_c   9.591
_cell_angle_alpha   91.137
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   541.354
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Yb  Yb0  1  0.693  0.750  0.750  1.0
  Yb  Yb1  1  0.307  0.250  0.250  1.0
  H  H2  1  0.435  0.077  0.760  1.0
  H  H3  1  0.435  0.423  0.740  1.0
  H  H4  1  0.565  0.923  0.240  1.0
  H  H5  1  0.565  0.577  0.260  1.0
  H  H6  1  0.605  0.106  0.859  1.0
  H  H7  1  0.605  0.394  0.641  1.0
  H  H8  1  0.395  0.894  0.141  1.0
  H  H9  1  0.395  0.606  0.359  1.0
  H  H10  1  0.034  0.634  0.605  1.0
  H  H11  1  0.034  0.866  0.895  1.0
  H  H12  1  0.966  0.366  0.395  1.0
  H  H13  1  0.966  0.134  0.105  1.0
  H  H14  1  0.979  0.476  0.684  1.0
  H  H15  1  0.979  0.024  0.816  1.0
  H  H16  1  0.021  0.524  0.316  1.0
  H  H17  1  0.021  0.976  0.184  1.0
  H  H18  1  0.828  0.843  0.456  1.0
  H  H19  1  0.828  0.657  0.044  1.0
  H  H20  1  0.172  0.157  0.544  1.0
  H  H21  1  0.172  0.343  0.956  1.0
  H  H22  1  0.763  0.005  0.535  1.0
  H  H23  1  0.763  0.495  0.965  1.0
  H  H24  1  0.237  0.995  0.465  1.0
  H  H25  1  0.237  0.505  0.035  1.0
  Cl  Cl26  1  0.324  0.737  0.889  1.0
  Cl  Cl27  1  0.324  0.763  0.611  1.0
  Cl  Cl28  1  0.676  0.263  0.111  1.0
  Cl  Cl29  1  0.676  0.237  0.389  1.0
  Cl  Cl30  1  0.859  0.750  0.250  1.0
  Cl  Cl31  1  0.141  0.250  0.750  1.0
  O  O32  1  0.567  0.043  0.775  1.0
  O  O33  1  0.567  0.457  0.725  1.0
  O  O34  1  0.433  0.957  0.225  1.0
  O  O35  1  0.433  0.543  0.275  1.0
  O  O36  1  0.924  0.577  0.643  1.0
  O  O37  1  0.924  0.923  0.857  1.0
  O  O38  1  0.076  0.423  0.357  1.0
  O  O39  1  0.076  0.077  0.143  1.0
  O  O40  1  0.797  0.888  0.550  1.0
  O  O41  1  0.797  0.612  0.950  1.0
  O  O42  1  0.203  0.112  0.450  1.0
  O  O43  1  0.203  0.388  0.050  1.0
[/CIF]
.
The crystal structure described by (YbH12(O3Cl)2)2Cl2 is beta-prime cadmium gold structured and crystallizes in the monoclinic P2/c space group. The structure is zero-dimensional and consists of two hydrochloric acid atoms and two YbH12(O3Cl)2 clusters. In each YbH12(O3Cl)2 cluster, Yb(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent Cl(1) atoms. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Yb(1), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Yb(1), one H(3), and one H(4) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one Yb(1), one H(5), and one H(6) atom. Cl(1) is bonded in a distorted single-bond geometry to one Yb(1) atom. is represented by the CIF card [CIF]
data_YbH12(ClO2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.077
_cell_length_b   7.977
_cell_length_c   9.591
_cell_angle_alpha   91.137
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   541.354
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Yb  Yb0  1  0.693  0.750  0.750  1.0
  Yb  Yb1  1  0.307  0.250  0.250  1.0
  H  H2  1  0.435  0.077  0.760  1.0
  H  H3  1  0.435  0.423  0.740  1.0
  H  H4  1  0.565  0.923  0.240  1.0
  H  H5  1  0.565  0.577  0.260  1.0
  H  H6  1  0.605  0.106  0.859  1.0
  H  H7  1  0.605  0.394  0.641  1.0
  H  H8  1  0.395  0.894  0.141  1.0
  H  H9  1  0.395  0.606  0.359  1.0
  H  H10  1  0.034  0.634  0.605  1.0
  H  H11  1  0.034  0.866  0.895  1.0
  H  H12  1  0.966  0.366  0.395  1.0
  H  H13  1  0.966  0.134  0.105  1.0
  H  H14  1  0.979  0.476  0.684  1.0
  H  H15  1  0.979  0.024  0.816  1.0
  H  H16  1  0.021  0.524  0.316  1.0
  H  H17  1  0.021  0.976  0.184  1.0
  H  H18  1  0.828  0.843  0.456  1.0
  H  H19  1  0.828  0.657  0.044  1.0
  H  H20  1  0.172  0.157  0.544  1.0
  H  H21  1  0.172  0.343  0.956  1.0
  H  H22  1  0.763  0.005  0.535  1.0
  H  H23  1  0.763  0.495  0.965  1.0
  H  H24  1  0.237  0.995  0.465  1.0
  H  H25  1  0.237  0.505  0.035  1.0
  Cl  Cl26  1  0.324  0.737  0.889  1.0
  Cl  Cl27  1  0.324  0.763  0.611  1.0
  Cl  Cl28  1  0.676  0.263  0.111  1.0
  Cl  Cl29  1  0.676  0.237  0.389  1.0
  Cl  Cl30  1  0.859  0.750  0.250  1.0
  Cl  Cl31  1  0.141  0.250  0.750  1.0
  O  O32  1  0.567  0.043  0.775  1.0
  O  O33  1  0.567  0.457  0.725  1.0
  O  O34  1  0.433  0.957  0.225  1.0
  O  O35  1  0.433  0.543  0.275  1.0
  O  O36  1  0.924  0.577  0.643  1.0
  O  O37  1  0.924  0.923  0.857  1.0
  O  O38  1  0.076  0.423  0.357  1.0
  O  O39  1  0.076  0.077  0.143  1.0
  O  O40  1  0.797  0.888  0.550  1.0
  O  O41  1  0.797  0.612  0.950  1.0
  O  O42  1  0.203  0.112  0.450  1.0
  O  O43  1  0.203  0.388  0.050  1.0
[/CIF]
.