The material structure described by Ti(CoN)4 crystallizes in the triclinic P-1 space group. Ti(1) is bonded in a distorted rectangular see-saw-like geometry to one N(1), one N(2), one N(3), and one N(4) atom. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded in a distorted rectangular see-saw-like geometry to one N(1), one N(2), one N(3), and one N(4) atom. In the second Co site, Co(2) is bonded in a rectangular see-saw-like geometry to two equivalent N(2) and two equivalent N(3) atoms. In the third Co site, Co(3) is bonded to one N(3), two equivalent N(1), and two equivalent N(4) atoms to form a mixture of edge and corner-sharing CoN5 square pyramids. In the fourth Co site, Co(4) is bonded to one N(3), two equivalent N(1), and two equivalent N(4) atoms to form a mixture of edge and corner-sharing CoN5 square pyramids. There are four inequivalent N sites. In the first N site, N(1) is bonded to one Ti(1), one Co(1), two equivalent Co(3), and two equivalent Co(4) atoms to form NTiCo5 octahedra that share corners with two equivalent N(3)TiCo5 octahedra, corners with two equivalent N(4)TiCo5 octahedra, corners with two equivalent N(2)TiCo3 tetrahedra, edges with two equivalent N(1)TiCo5 octahedra, edges with two equivalent N(3)TiCo5 octahedra, and edges with four equivalent N(4)TiCo5 octahedra. The corner-sharing octahedral tilt angles range from 3-9°. In the second N site, N(2) is bonded to one Ti(1), one Co(1), and two equivalent Co(2) atoms to form distorted NTiCo3 tetrahedra that share corners with two equivalent N(1)TiCo5 octahedra, corners with two equivalent N(4)TiCo5 octahedra, corners with six equivalent N(3)TiCo5 octahedra, and  an edgeedge with one N(2)TiCo3 tetrahedra. The corner-sharing octahedral tilt angles range from 41-77°. In the third N site, N(3) is bonded to one Ti(1), one Co(1), one Co(3), one Co(4), and two equivalent Co(2) atoms to form distorted NTiCo5 octahedra that share corners with two equivalent N(1)TiCo5 octahedra, corners with six equivalent N(2)TiCo3 tetrahedra,  an edgeedge with one N(3)TiCo5 octahedra, edges with two equivalent N(1)TiCo5 octahedra, and edges with three equivalent N(4)TiCo5 octahedra. The corner-sharing octahedral tilt angles range from 3-9°. In the fourth N site, N(4) is bonded to one Ti(1), one Co(1), two equivalent Co(3), and two equivalent Co(4) atoms to form NTiCo5 octahedra that share corners with two equivalent N(1)TiCo5 octahedra, corners with two equivalent N(2)TiCo3 tetrahedra, edges with two equivalent N(4)TiCo5 octahedra, edges with three equivalent N(3)TiCo5 octahedra, and edges with four equivalent N(1)TiCo5 octahedra. The corner-sharing octahedral tilt angles range from 5-6°. is represented by the CIF card [CIF]
data_Ti(CoN)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.873
_cell_length_b   5.000
_cell_length_c   7.641
_cell_angle_alpha   72.953
_cell_angle_beta   81.674
_cell_angle_gamma   69.558
_symmetry_Int_Tables_number   1
_cell_volume   166.588
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.714  0.868  0.780  1.0
  Ti  Ti1  1  0.286  0.132  0.220  1.0
  Co  Co2  1  0.763  0.598  0.217  1.0
  Co  Co3  1  0.237  0.402  0.783  1.0
  Co  Co4  1  0.748  0.273  0.955  1.0
  Co  Co5  1  0.252  0.727  0.045  1.0
  Co  Co6  1  0.746  0.455  0.598  1.0
  Co  Co7  1  0.254  0.545  0.402  1.0
  Co  Co8  1  0.254  0.953  0.599  1.0
  Co  Co9  1  0.746  0.047  0.401  1.0
  N  N10  1  0.989  0.716  0.583  1.0
  N  N11  1  0.011  0.284  0.417  1.0
  N  N12  1  0.847  0.860  0.014  1.0
  N  N13  1  0.153  0.140  0.986  1.0
  N  N14  1  0.455  0.630  0.813  1.0
  N  N15  1  0.545  0.370  0.187  1.0
  N  N16  1  0.515  0.787  0.406  1.0
  N  N17  1  0.485  0.213  0.594  1.0
[/CIF]
.
The material structure described by Ti(CoN)4 crystallizes in the triclinic P-1 space group. Ti(1) is bonded in a distorted rectangular see-saw-like geometry to one N(1), one N(2), one N(3), and one N(4) atom. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded in a distorted rectangular see-saw-like geometry to one N(1), one N(2), one N(3), and one N(4) atom. In the second Co site, Co(2) is bonded in a rectangular see-saw-like geometry to two equivalent N(2) and two equivalent N(3) atoms. In the third Co site, Co(3) is bonded to one N(3), two equivalent N(1), and two equivalent N(4) atoms to form a mixture of edge and corner-sharing CoN5 square pyramids. In the fourth Co site, Co(4) is bonded to one N(3), two equivalent N(1), and two equivalent N(4) atoms to form a mixture of edge and corner-sharing CoN5 square pyramids. There are four inequivalent N sites. In the first N site, N(1) is bonded to one Ti(1), one Co(1), two equivalent Co(3), and two equivalent Co(4) atoms to form NTiCo5 octahedra that share corners with two equivalent N(3)TiCo5 octahedra, corners with two equivalent N(4)TiCo5 octahedra, corners with two equivalent N(2)TiCo3 tetrahedra, edges with two equivalent N(1)TiCo5 octahedra, edges with two equivalent N(3)TiCo5 octahedra, and edges with four equivalent N(4)TiCo5 octahedra. The corner-sharing octahedral tilt angles range from 3-9°. In the second N site, N(2) is bonded to one Ti(1), one Co(1), and two equivalent Co(2) atoms to form distorted NTiCo3 tetrahedra that share corners with two equivalent N(1)TiCo5 octahedra, corners with two equivalent N(4)TiCo5 octahedra, corners with six equivalent N(3)TiCo5 octahedra, and  an edgeedge with one N(2)TiCo3 tetrahedra. The corner-sharing octahedral tilt angles range from 41-77°. In the third N site, N(3) is bonded to one Ti(1), one Co(1), one Co(3), one Co(4), and two equivalent Co(2) atoms to form distorted NTiCo5 octahedra that share corners with two equivalent N(1)TiCo5 octahedra, corners with six equivalent N(2)TiCo3 tetrahedra,  an edgeedge with one N(3)TiCo5 octahedra, edges with two equivalent N(1)TiCo5 octahedra, and edges with three equivalent N(4)TiCo5 octahedra. The corner-sharing octahedral tilt angles range from 3-9°. In the fourth N site, N(4) is bonded to one Ti(1), one Co(1), two equivalent Co(3), and two equivalent Co(4) atoms to form NTiCo5 octahedra that share corners with two equivalent N(1)TiCo5 octahedra, corners with two equivalent N(2)TiCo3 tetrahedra, edges with two equivalent N(4)TiCo5 octahedra, edges with three equivalent N(3)TiCo5 octahedra, and edges with four equivalent N(1)TiCo5 octahedra. The corner-sharing octahedral tilt angles range from 5-6°. is represented by the CIF card [CIF]
data_Ti(CoN)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.873
_cell_length_b   5.000
_cell_length_c   7.641
_cell_angle_alpha   72.953
_cell_angle_beta   81.674
_cell_angle_gamma   69.558
_symmetry_Int_Tables_number   1
_cell_volume   166.588
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.714  0.868  0.780  1.0
  Ti  Ti1  1  0.286  0.132  0.220  1.0
  Co  Co2  1  0.763  0.598  0.217  1.0
  Co  Co3  1  0.237  0.402  0.783  1.0
  Co  Co4  1  0.748  0.273  0.955  1.0
  Co  Co5  1  0.252  0.727  0.045  1.0
  Co  Co6  1  0.746  0.455  0.598  1.0
  Co  Co7  1  0.254  0.545  0.402  1.0
  Co  Co8  1  0.254  0.953  0.599  1.0
  Co  Co9  1  0.746  0.047  0.401  1.0
  N  N10  1  0.989  0.716  0.583  1.0
  N  N11  1  0.011  0.284  0.417  1.0
  N  N12  1  0.847  0.860  0.014  1.0
  N  N13  1  0.153  0.140  0.986  1.0
  N  N14  1  0.455  0.630  0.813  1.0
  N  N15  1  0.545  0.370  0.187  1.0
  N  N16  1  0.515  0.787  0.406  1.0
  N  N17  1  0.485  0.213  0.594  1.0
[/CIF]
.