The material structure described by RbNb4Ag(PS10)2 crystallizes in the triclinic P1 space group. Rb(1) is bonded in a 9-coordinate geometry to one S(10), one S(14), one S(16), one S(2), one S(7), one S(8), one S(9), and two equivalent S(20) atoms. There are four inequivalent Nb sites. In the first Nb site, Nb(1) is bonded to one S(1), one S(10), one S(15), one S(17), one S(19), one S(7), one S(8), and one S(9) atom to form distorted NbS8 hexagonal bipyramids that share  an edgeedge with one P(1)S4 tetrahedra,  a faceface with one Nb(2)S8 hexagonal bipyramid, and  a faceface with one Nb(3)S8 hexagonal bipyramid. In the second Nb site, Nb(2) is bonded to one S(10), one S(16), one S(18), one S(2), one S(20), one S(7), one S(8), and one S(9) atom to form distorted NbS8 hexagonal bipyramids that share  a cornercorner with one S(16)RbNb2S trigonal pyramid,  an edgeedge with one P(2)S4 tetrahedra,  a faceface with one Nb(1)S8 hexagonal bipyramid, and  a faceface with one Nb(4)S8 hexagonal bipyramid. In the third Nb site, Nb(3) is bonded to one S(1), one S(11), one S(12), one S(15), one S(17), one S(3), one S(4), and one S(5) atom to form distorted NbS8 hexagonal bipyramids that share  an edgeedge with one P(1)S4 tetrahedra,  a faceface with one Nb(1)S8 hexagonal bipyramid, and  a faceface with one Nb(4)S8 hexagonal bipyramid. In the fourth Nb site, Nb(4) is bonded to one S(11), one S(12), one S(16), one S(18), one S(2), one S(3), one S(4), and one S(6) atom to form distorted NbS8 hexagonal bipyramids that share  a cornercorner with one S(16)RbNb2S trigonal pyramid,  an edgeedge with one P(2)S4 tetrahedra,  a faceface with one Nb(2)S8 hexagonal bipyramid, and  a faceface with one Nb(3)S8 hexagonal bipyramid. Ag(1) is bonded in a linear geometry to one S(13) and one S(14) atom. There are two inequivalent P sites. In the first P site, P(1) is bonded to one S(13), one S(17), one S(19), and one S(5) atom to form PS4 tetrahedra that share  an edgeedge with one Nb(1)S8 hexagonal bipyramid and  an edgeedge with one Nb(3)S8 hexagonal bipyramid. In the second P site, P(2) is bonded to one S(14), one S(18), one S(20), and one S(6) atom to form PS4 tetrahedra that share  an edgeedge with one Nb(2)S8 hexagonal bipyramid and  an edgeedge with one Nb(4)S8 hexagonal bipyramid. There are twenty inequivalent S sites. In the first S site, S(1) is bonded in a 3-coordinate geometry to one Nb(1), one Nb(3), and one S(15) atom. In the second S site, S(2) is bonded in a 4-coordinate geometry to one Rb(1), one Nb(2), one Nb(4), and one S(16) atom. In the third S site, S(3) is bonded in a 3-coordinate geometry to one Nb(3), one Nb(4), and one S(11) atom. In the fourth S site, S(4) is bonded in a 3-coordinate geometry to one Nb(3), one Nb(4), and one S(12) atom. In the fifth S site, S(5) is bonded in an L-shaped geometry to one Nb(3) and one P(1) atom. In the sixth S site, S(6) is bonded in an L-shaped geometry to one Nb(4) and one P(2) atom. In the seventh S site, S(7) is bonded in a 4-coordinate geometry to one Rb(1), one Nb(1), one Nb(2), and one S(9) atom. In the eighth S site, S(8) is bonded in a 4-coordinate geometry to one Rb(1), one Nb(1), one Nb(2), and one S(10) atom. In the ninth S site, S(9) is bonded in a 4-coordinate geometry to one Rb(1), one Nb(1), one Nb(2), and one S(7) atom. In the tenth S site, S(10) is bonded in a 4-coordinate geometry to one Rb(1), one Nb(1), one Nb(2), and one S(8) atom. In the eleventh S site, S(11) is bonded in a 3-coordinate geometry to one Nb(3), one Nb(4), and one S(3) atom. In the twelfth S site, S(12) is bonded in a 3-coordinate geometry to one Nb(3), one Nb(4), and one S(4) atom. In the thirteenth S site, S(13) is bonded in an L-shaped geometry to one Ag(1) and one P(1) atom. In the fourteenth S site, S(14) is bonded in a distorted T-shaped geometry to one Rb(1), one Ag(1), and one P(2) atom. In the fifteenth S site, S(15) is bonded in a 3-coordinate geometry to one Nb(1), one Nb(3), and one S(1) atom. In the sixteenth S site, S(16) is bonded to one Rb(1), one Nb(2), one Nb(4), and one S(2) atom to form distorted SRbNb2S trigonal pyramids that share  a cornercorner with one Nb(2)S8 hexagonal bipyramid and  a cornercorner with one Nb(4)S8 hexagonal bipyramid. In the seventeenth S site, S(17) is bonded in a distorted T-shaped geometry to one Nb(1), one Nb(3), and one P(1) atom. In the eighteenth S site, S(18) is bonded in a distorted T-shaped geometry to one Nb(2), one Nb(4), and one P(2) atom. In the nineteenth S site, S(19) is bonded in an L-shaped geometry to one Nb(1) and one P(1) atom. In the twentieth S site, S(20) is bonded in a distorted L-shaped geometry to two equivalent Rb(1), one Nb(2), and one P(2) atom. is represented by the CIF card [CIF]
data_RbNb4Ag(PS10)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.408
_cell_length_b   7.538
_cell_length_c   13.038
_cell_angle_alpha   89.474
_cell_angle_beta   76.526
_cell_angle_gamma   87.907
_symmetry_Int_Tables_number   1
_cell_volume   707.535
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.056  0.502  0.439  1.0
  Nb  Nb1  1  0.500  0.068  0.605  1.0
  Nb  Nb2  1  0.499  0.932  0.396  1.0
  Nb  Nb3  1  0.502  0.067  0.895  1.0
  Nb  Nb4  1  0.498  0.933  0.105  1.0
  Ag  Ag5  1  0.003  0.500  0.999  1.0
  P  P6  1  0.291  0.383  0.777  1.0
  P  P7  1  0.707  0.619  0.222  1.0
  S  S8  1  0.629  0.865  0.734  1.0
  S  S9  1  0.372  0.135  0.267  1.0
  S  S10  1  0.707  0.170  0.011  1.0
  S  S11  1  0.294  0.830  0.989  1.0
  S  S12  1  0.449  0.409  0.886  1.0
  S  S13  1  0.548  0.591  0.114  1.0
  S  S14  1  0.711  0.166  0.433  1.0
  S  S15  1  0.289  0.831  0.568  1.0
  S  S16  1  0.773  0.918  0.480  1.0
  S  S17  1  0.226  0.080  0.522  1.0
  S  S18  1  0.777  0.921  0.951  1.0
  S  S19  1  0.224  0.079  0.049  1.0
  S  S20  1  0.058  0.537  0.807  1.0
  S  S21  1  0.941  0.463  0.191  1.0
  S  S22  1  0.744  0.110  0.717  1.0
  S  S23  1  0.255  0.892  0.283  1.0
  S  S24  1  0.248  0.108  0.783  1.0
  S  S25  1  0.751  0.892  0.217  1.0
  S  S26  1  0.440  0.411  0.623  1.0
  S  S27  1  0.563  0.588  0.377  1.0
[/CIF]
.
The material structure described by RbNb4Ag(PS10)2 crystallizes in the triclinic P1 space group. Rb(1) is bonded in a 9-coordinate geometry to one S(10), one S(14), one S(16), one S(2), one S(7), one S(8), one S(9), and two equivalent S(20) atoms. There are four inequivalent Nb sites. In the first Nb site, Nb(1) is bonded to one S(1), one S(10), one S(15), one S(17), one S(19), one S(7), one S(8), and one S(9) atom to form distorted NbS8 hexagonal bipyramids that share  an edgeedge with one P(1)S4 tetrahedra,  a faceface with one Nb(2)S8 hexagonal bipyramid, and  a faceface with one Nb(3)S8 hexagonal bipyramid. In the second Nb site, Nb(2) is bonded to one S(10), one S(16), one S(18), one S(2), one S(20), one S(7), one S(8), and one S(9) atom to form distorted NbS8 hexagonal bipyramids that share  a cornercorner with one S(16)RbNb2S trigonal pyramid,  an edgeedge with one P(2)S4 tetrahedra,  a faceface with one Nb(1)S8 hexagonal bipyramid, and  a faceface with one Nb(4)S8 hexagonal bipyramid. In the third Nb site, Nb(3) is bonded to one S(1), one S(11), one S(12), one S(15), one S(17), one S(3), one S(4), and one S(5) atom to form distorted NbS8 hexagonal bipyramids that share  an edgeedge with one P(1)S4 tetrahedra,  a faceface with one Nb(1)S8 hexagonal bipyramid, and  a faceface with one Nb(4)S8 hexagonal bipyramid. In the fourth Nb site, Nb(4) is bonded to one S(11), one S(12), one S(16), one S(18), one S(2), one S(3), one S(4), and one S(6) atom to form distorted NbS8 hexagonal bipyramids that share  a cornercorner with one S(16)RbNb2S trigonal pyramid,  an edgeedge with one P(2)S4 tetrahedra,  a faceface with one Nb(2)S8 hexagonal bipyramid, and  a faceface with one Nb(3)S8 hexagonal bipyramid. Ag(1) is bonded in a linear geometry to one S(13) and one S(14) atom. There are two inequivalent P sites. In the first P site, P(1) is bonded to one S(13), one S(17), one S(19), and one S(5) atom to form PS4 tetrahedra that share  an edgeedge with one Nb(1)S8 hexagonal bipyramid and  an edgeedge with one Nb(3)S8 hexagonal bipyramid. In the second P site, P(2) is bonded to one S(14), one S(18), one S(20), and one S(6) atom to form PS4 tetrahedra that share  an edgeedge with one Nb(2)S8 hexagonal bipyramid and  an edgeedge with one Nb(4)S8 hexagonal bipyramid. There are twenty inequivalent S sites. In the first S site, S(1) is bonded in a 3-coordinate geometry to one Nb(1), one Nb(3), and one S(15) atom. In the second S site, S(2) is bonded in a 4-coordinate geometry to one Rb(1), one Nb(2), one Nb(4), and one S(16) atom. In the third S site, S(3) is bonded in a 3-coordinate geometry to one Nb(3), one Nb(4), and one S(11) atom. In the fourth S site, S(4) is bonded in a 3-coordinate geometry to one Nb(3), one Nb(4), and one S(12) atom. In the fifth S site, S(5) is bonded in an L-shaped geometry to one Nb(3) and one P(1) atom. In the sixth S site, S(6) is bonded in an L-shaped geometry to one Nb(4) and one P(2) atom. In the seventh S site, S(7) is bonded in a 4-coordinate geometry to one Rb(1), one Nb(1), one Nb(2), and one S(9) atom. In the eighth S site, S(8) is bonded in a 4-coordinate geometry to one Rb(1), one Nb(1), one Nb(2), and one S(10) atom. In the ninth S site, S(9) is bonded in a 4-coordinate geometry to one Rb(1), one Nb(1), one Nb(2), and one S(7) atom. In the tenth S site, S(10) is bonded in a 4-coordinate geometry to one Rb(1), one Nb(1), one Nb(2), and one S(8) atom. In the eleventh S site, S(11) is bonded in a 3-coordinate geometry to one Nb(3), one Nb(4), and one S(3) atom. In the twelfth S site, S(12) is bonded in a 3-coordinate geometry to one Nb(3), one Nb(4), and one S(4) atom. In the thirteenth S site, S(13) is bonded in an L-shaped geometry to one Ag(1) and one P(1) atom. In the fourteenth S site, S(14) is bonded in a distorted T-shaped geometry to one Rb(1), one Ag(1), and one P(2) atom. In the fifteenth S site, S(15) is bonded in a 3-coordinate geometry to one Nb(1), one Nb(3), and one S(1) atom. In the sixteenth S site, S(16) is bonded to one Rb(1), one Nb(2), one Nb(4), and one S(2) atom to form distorted SRbNb2S trigonal pyramids that share  a cornercorner with one Nb(2)S8 hexagonal bipyramid and  a cornercorner with one Nb(4)S8 hexagonal bipyramid. In the seventeenth S site, S(17) is bonded in a distorted T-shaped geometry to one Nb(1), one Nb(3), and one P(1) atom. In the eighteenth S site, S(18) is bonded in a distorted T-shaped geometry to one Nb(2), one Nb(4), and one P(2) atom. In the nineteenth S site, S(19) is bonded in an L-shaped geometry to one Nb(1) and one P(1) atom. In the twentieth S site, S(20) is bonded in a distorted L-shaped geometry to two equivalent Rb(1), one Nb(2), and one P(2) atom. is represented by the CIF card [CIF]
data_RbNb4Ag(PS10)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.408
_cell_length_b   7.538
_cell_length_c   13.038
_cell_angle_alpha   89.474
_cell_angle_beta   76.526
_cell_angle_gamma   87.907
_symmetry_Int_Tables_number   1
_cell_volume   707.535
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.056  0.502  0.439  1.0
  Nb  Nb1  1  0.500  0.068  0.605  1.0
  Nb  Nb2  1  0.499  0.932  0.396  1.0
  Nb  Nb3  1  0.502  0.067  0.895  1.0
  Nb  Nb4  1  0.498  0.933  0.105  1.0
  Ag  Ag5  1  0.003  0.500  0.999  1.0
  P  P6  1  0.291  0.383  0.777  1.0
  P  P7  1  0.707  0.619  0.222  1.0
  S  S8  1  0.629  0.865  0.734  1.0
  S  S9  1  0.372  0.135  0.267  1.0
  S  S10  1  0.707  0.170  0.011  1.0
  S  S11  1  0.294  0.830  0.989  1.0
  S  S12  1  0.449  0.409  0.886  1.0
  S  S13  1  0.548  0.591  0.114  1.0
  S  S14  1  0.711  0.166  0.433  1.0
  S  S15  1  0.289  0.831  0.568  1.0
  S  S16  1  0.773  0.918  0.480  1.0
  S  S17  1  0.226  0.080  0.522  1.0
  S  S18  1  0.777  0.921  0.951  1.0
  S  S19  1  0.224  0.079  0.049  1.0
  S  S20  1  0.058  0.537  0.807  1.0
  S  S21  1  0.941  0.463  0.191  1.0
  S  S22  1  0.744  0.110  0.717  1.0
  S  S23  1  0.255  0.892  0.283  1.0
  S  S24  1  0.248  0.108  0.783  1.0
  S  S25  1  0.751  0.892  0.217  1.0
  S  S26  1  0.440  0.411  0.623  1.0
  S  S27  1  0.563  0.588  0.377  1.0
[/CIF]
.