The material structure described by CsAgCl2 crystallizes in the tetragonal P4/nmm space group. Cs(1) is bonded in a 5-coordinate geometry to five equivalent Cl(1) atoms. Ag(1) is bonded in a 5-coordinate geometry to one Cl(1) and four equivalent Cl(2) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded to five equivalent Cs(1) and one Ag(1) atom to form a mixture of distorted corner and edge-sharing ClCs5Ag octahedra. The corner-sharing octahedral tilt angles are 19°. In the second Cl site, Cl(2) is bonded in a 4-coordinate geometry to four equivalent Ag(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_CsAgCl2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.068
_cell_length_b   5.068
_cell_length_c   9.859
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   253.255
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.250  0.250  0.705  1.0
  Cs  Cs1  1  0.750  0.750  0.295  1.0
  Ag  Ag2  1  0.750  0.750  0.901  1.0
  Ag  Ag3  1  0.250  0.250  0.099  1.0
  Cl  Cl4  1  0.750  0.750  0.645  1.0
  Cl  Cl5  1  0.250  0.250  0.355  1.0
  Cl  Cl6  1  0.250  0.750  0.000  1.0
  Cl  Cl7  1  0.750  0.250  0.000  1.0
[/CIF]
.
The material structure described by CsAgCl2 crystallizes in the tetragonal P4/nmm space group. Cs(1) is bonded in a 5-coordinate geometry to five equivalent Cl(1) atoms. Ag(1) is bonded in a 5-coordinate geometry to one Cl(1) and four equivalent Cl(2) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded to five equivalent Cs(1) and one Ag(1) atom to form a mixture of distorted corner and edge-sharing ClCs5Ag octahedra. The corner-sharing octahedral tilt angles are 19°. In the second Cl site, Cl(2) is bonded in a 4-coordinate geometry to four equivalent Ag(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_CsAgCl2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.068
_cell_length_b   5.068
_cell_length_c   9.859
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   253.255
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.250  0.250  0.705  1.0
  Cs  Cs1  1  0.750  0.750  0.295  1.0
  Ag  Ag2  1  0.750  0.750  0.901  1.0
  Ag  Ag3  1  0.250  0.250  0.099  1.0
  Cl  Cl4  1  0.750  0.750  0.645  1.0
  Cl  Cl5  1  0.250  0.250  0.355  1.0
  Cl  Cl6  1  0.250  0.750  0.000  1.0
  Cl  Cl7  1  0.750  0.250  0.000  1.0
[/CIF]
.