The compound described by ScBi3(MoO6)2 crystallizes in the monoclinic C2/c space group. Sc(1) is bonded in a 6-coordinate geometry to two equivalent O(5) and four equivalent O(2) atoms. Mo(1) is bonded in a tetrahedral geometry to one O(1), one O(3), one O(4), and one O(6) atom. There are two inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a 8-coordinate geometry to one O(3), one O(5), two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms. In the second Bi site, Bi(2) is bonded in a distorted rectangular see-saw-like geometry to two equivalent O(3) and two equivalent O(5) atoms. There are six inequivalent O sites. In the first O site, O(3) is bonded in a 3-coordinate geometry to one Mo(1), one Bi(1), and one Bi(2) atom. In the second O site, O(4) is bonded in a distorted single-bond geometry to one Mo(1) and two equivalent Bi(1) atoms. In the third O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one Sc(1), one Bi(1), and one Bi(2) atom. In the fourth O site, O(6) is bonded in a distorted single-bond geometry to one Mo(1) and two equivalent Bi(1) atoms. In the fifth O site, O(1) is bonded in a single-bond geometry to one Mo(1) atom. In the sixth O site, O(2) is bonded to two equivalent Sc(1) and two equivalent Bi(1) atoms to form a mixture of distorted corner and edge-sharing OSc2Bi2 tetrahedra. is represented by the CIF file [CIF]
data_ScBi3(MoO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.415
_cell_length_b   10.415
_cell_length_c   5.385
_cell_angle_alpha   77.985
_cell_angle_beta   77.985
_cell_angle_gamma   68.711
_symmetry_Int_Tables_number   1
_cell_volume   526.701
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc0  1  0.090  0.910  0.750  1.0
  Sc  Sc1  1  0.910  0.090  0.250  1.0
  Bi  Bi2  1  0.728  0.963  0.931  1.0
  Bi  Bi3  1  0.272  0.037  0.069  1.0
  Bi  Bi4  1  0.037  0.272  0.569  1.0
  Bi  Bi5  1  0.963  0.728  0.431  1.0
  Bi  Bi6  1  0.663  0.337  0.750  1.0
  Bi  Bi7  1  0.337  0.663  0.250  1.0
  Mo  Mo8  1  0.540  0.797  0.573  1.0
  Mo  Mo9  1  0.460  0.203  0.427  1.0
  Mo  Mo10  1  0.203  0.460  0.927  1.0
  Mo  Mo11  1  0.797  0.540  0.073  1.0
  O  O12  1  0.551  0.638  0.779  1.0
  O  O13  1  0.449  0.362  0.221  1.0
  O  O14  1  0.362  0.449  0.721  1.0
  O  O15  1  0.638  0.551  0.279  1.0
  O  O16  1  0.895  0.942  0.584  1.0
  O  O17  1  0.105  0.058  0.416  1.0
  O  O18  1  0.058  0.105  0.916  1.0
  O  O19  1  0.942  0.895  0.084  1.0
  O  O20  1  0.602  0.166  0.620  1.0
  O  O21  1  0.398  0.834  0.380  1.0
  O  O22  1  0.834  0.398  0.880  1.0
  O  O23  1  0.166  0.602  0.120  1.0
  O  O24  1  0.298  0.208  0.633  1.0
  O  O25  1  0.702  0.792  0.367  1.0
  O  O26  1  0.792  0.702  0.867  1.0
  O  O27  1  0.208  0.298  0.133  1.0
  O  O28  1  0.746  0.155  0.031  1.0
  O  O29  1  0.254  0.845  0.969  1.0
  O  O30  1  0.845  0.254  0.469  1.0
  O  O31  1  0.155  0.746  0.531  1.0
  O  O32  1  0.504  0.929  0.769  1.0
  O  O33  1  0.496  0.071  0.231  1.0
  O  O34  1  0.071  0.496  0.731  1.0
  O  O35  1  0.929  0.504  0.269  1.0
[/CIF]
.
The compound described by ScBi3(MoO6)2 crystallizes in the monoclinic C2/c space group. Sc(1) is bonded in a 6-coordinate geometry to two equivalent O(5) and four equivalent O(2) atoms. Mo(1) is bonded in a tetrahedral geometry to one O(1), one O(3), one O(4), and one O(6) atom. There are two inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a 8-coordinate geometry to one O(3), one O(5), two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms. In the second Bi site, Bi(2) is bonded in a distorted rectangular see-saw-like geometry to two equivalent O(3) and two equivalent O(5) atoms. There are six inequivalent O sites. In the first O site, O(3) is bonded in a 3-coordinate geometry to one Mo(1), one Bi(1), and one Bi(2) atom. In the second O site, O(4) is bonded in a distorted single-bond geometry to one Mo(1) and two equivalent Bi(1) atoms. In the third O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one Sc(1), one Bi(1), and one Bi(2) atom. In the fourth O site, O(6) is bonded in a distorted single-bond geometry to one Mo(1) and two equivalent Bi(1) atoms. In the fifth O site, O(1) is bonded in a single-bond geometry to one Mo(1) atom. In the sixth O site, O(2) is bonded to two equivalent Sc(1) and two equivalent Bi(1) atoms to form a mixture of distorted corner and edge-sharing OSc2Bi2 tetrahedra. is represented by the CIF file [CIF]
data_ScBi3(MoO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.415
_cell_length_b   10.415
_cell_length_c   5.385
_cell_angle_alpha   77.985
_cell_angle_beta   77.985
_cell_angle_gamma   68.711
_symmetry_Int_Tables_number   1
_cell_volume   526.701
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc0  1  0.090  0.910  0.750  1.0
  Sc  Sc1  1  0.910  0.090  0.250  1.0
  Bi  Bi2  1  0.728  0.963  0.931  1.0
  Bi  Bi3  1  0.272  0.037  0.069  1.0
  Bi  Bi4  1  0.037  0.272  0.569  1.0
  Bi  Bi5  1  0.963  0.728  0.431  1.0
  Bi  Bi6  1  0.663  0.337  0.750  1.0
  Bi  Bi7  1  0.337  0.663  0.250  1.0
  Mo  Mo8  1  0.540  0.797  0.573  1.0
  Mo  Mo9  1  0.460  0.203  0.427  1.0
  Mo  Mo10  1  0.203  0.460  0.927  1.0
  Mo  Mo11  1  0.797  0.540  0.073  1.0
  O  O12  1  0.551  0.638  0.779  1.0
  O  O13  1  0.449  0.362  0.221  1.0
  O  O14  1  0.362  0.449  0.721  1.0
  O  O15  1  0.638  0.551  0.279  1.0
  O  O16  1  0.895  0.942  0.584  1.0
  O  O17  1  0.105  0.058  0.416  1.0
  O  O18  1  0.058  0.105  0.916  1.0
  O  O19  1  0.942  0.895  0.084  1.0
  O  O20  1  0.602  0.166  0.620  1.0
  O  O21  1  0.398  0.834  0.380  1.0
  O  O22  1  0.834  0.398  0.880  1.0
  O  O23  1  0.166  0.602  0.120  1.0
  O  O24  1  0.298  0.208  0.633  1.0
  O  O25  1  0.702  0.792  0.367  1.0
  O  O26  1  0.792  0.702  0.867  1.0
  O  O27  1  0.208  0.298  0.133  1.0
  O  O28  1  0.746  0.155  0.031  1.0
  O  O29  1  0.254  0.845  0.969  1.0
  O  O30  1  0.845  0.254  0.469  1.0
  O  O31  1  0.155  0.746  0.531  1.0
  O  O32  1  0.504  0.929  0.769  1.0
  O  O33  1  0.496  0.071  0.231  1.0
  O  O34  1  0.071  0.496  0.731  1.0
  O  O35  1  0.929  0.504  0.269  1.0
[/CIF]
.