The material structure described by Li2VMnP2(O4F)2 crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(10), one O(16), one O(6), one O(8), and one F(2) atom to form distorted LiO4F square pyramids that share  a cornercorner with one V(2)O4F2 octahedra,  a cornercorner with one Mn(2)O4F2 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  an edgeedge with one V(1)O4F2 octahedra,  an edgeedge with one Mn(1)O4F2 octahedra,  an edgeedge with one Li(3)O4F square pyramid, and  an edgeedge with one P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 53-59°. In the second Li site, Li(2) is bonded to one O(11), one O(13), one O(5), one O(7), and one F(1) atom to form distorted LiO4F square pyramids that share  a cornercorner with one V(2)O4F2 octahedra,  a cornercorner with one Mn(2)O4F2 octahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one V(1)O4F2 octahedra,  an edgeedge with one Mn(1)O4F2 octahedra,  an edgeedge with one Li(4)O4F square pyramid, and  an edgeedge with one P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 51-60°. In the third Li site, Li(3) is bonded to one O(10), one O(12), one O(4), one O(6), and one F(4) atom to form distorted LiO4F square pyramids that share  a cornercorner with one V(2)O4F2 octahedra,  a cornercorner with one Mn(2)O4F2 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  an edgeedge with one V(1)O4F2 octahedra,  an edgeedge with one Mn(1)O4F2 octahedra,  an edgeedge with one Li(1)O4F square pyramid, and  an edgeedge with one P(4)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 52-63°. In the fourth Li site, Li(4) is bonded to one O(1), one O(11), one O(7), one O(9), and one F(3) atom to form distorted LiO4F square pyramids that share  a cornercorner with one V(2)O4F2 octahedra,  a cornercorner with one Mn(2)O4F2 octahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one V(1)O4F2 octahedra,  an edgeedge with one Mn(1)O4F2 octahedra,  an edgeedge with one Li(2)O4F square pyramid, and  an edgeedge with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 52-57°. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(10), one O(16), one O(7), one F(1), and one F(4) atom to form VO4F2 octahedra that share  a cornercorner with one V(2)O4F2 octahedra,  a cornercorner with one Mn(2)O4F2 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one Li(1)O4F square pyramid,  an edgeedge with one Li(2)O4F square pyramid,  an edgeedge with one Li(3)O4F square pyramid, and  an edgeedge with one Li(4)O4F square pyramid. The corner-sharing octahedral tilt angles range from 47-48°. In the second V site, V(2) is bonded to one O(2), one O(3), one O(4), one O(8), one F(1), and one F(3) atom to form VO4F2 octahedra that share  a cornercorner with one V(1)O4F2 octahedra,  a cornercorner with one Mn(1)O4F2 octahedra,  a cornercorner with one Li(1)O4F square pyramid,  a cornercorner with one Li(2)O4F square pyramid,  a cornercorner with one Li(3)O4F square pyramid,  a cornercorner with one Li(4)O4F square pyramid,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one P(4)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 47-49°. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(11), one O(12), one O(5), one O(6), one F(2), and one F(3) atom to form MnO4F2 octahedra that share  a cornercorner with one V(2)O4F2 octahedra,  a cornercorner with one Mn(2)O4F2 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one Li(1)O4F square pyramid,  an edgeedge with one Li(2)O4F square pyramid,  an edgeedge with one Li(3)O4F square pyramid, and  an edgeedge with one Li(4)O4F square pyramid. The corner-sharing octahedral tilt angles range from 49-51°. In the second Mn site, Mn(2) is bonded to one O(13), one O(14), one O(15), one O(9), one F(2), and one F(4) atom to form MnO4F2 octahedra that share  a cornercorner with one V(1)O4F2 octahedra,  a cornercorner with one Mn(1)O4F2 octahedra,  a cornercorner with one Li(1)O4F square pyramid,  a cornercorner with one Li(2)O4F square pyramid,  a cornercorner with one Li(3)O4F square pyramid,  a cornercorner with one Li(4)O4F square pyramid,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one P(4)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 48-51°. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(10), one O(13), one O(2), and one O(5) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O4F2 octahedra,  a cornercorner with one V(2)O4F2 octahedra,  a cornercorner with one Mn(1)O4F2 octahedra,  a cornercorner with one Mn(2)O4F2 octahedra,  a cornercorner with one Li(1)O4F square pyramid,  a cornercorner with one Li(3)O4F square pyramid, and  an edgeedge with one Li(2)O4F square pyramid. The corner-sharing octahedral tilt angles range from 33-53°. In the second P site, P(2) is bonded to one O(1), one O(3), one O(6), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O4F2 octahedra,  a cornercorner with one V(2)O4F2 octahedra,  a cornercorner with one Mn(1)O4F2 octahedra,  a cornercorner with one Mn(2)O4F2 octahedra,  a cornercorner with one Li(1)O4F square pyramid,  a cornercorner with one Li(3)O4F square pyramid, and  an edgeedge with one Li(4)O4F square pyramid. The corner-sharing octahedral tilt angles range from 33-53°. In the third P site, P(3) is bonded to one O(11), one O(14), one O(16), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O4F2 octahedra,  a cornercorner with one V(2)O4F2 octahedra,  a cornercorner with one Mn(1)O4F2 octahedra,  a cornercorner with one Mn(2)O4F2 octahedra,  a cornercorner with one Li(2)O4F square pyramid,  a cornercorner with one Li(4)O4F square pyramid, and  an edgeedge with one Li(1)O4F square pyramid. The corner-sharing octahedral tilt angles range from 31-54°. In the fourth P site, P(4) is bonded to one O(12), one O(15), one O(4), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O4F2 octahedra,  a cornercorner with one V(2)O4F2 octahedra,  a cornercorner with one Mn(1)O4F2 octahedra,  a cornercorner with one Mn(2)O4F2 octahedra,  a cornercorner with one Li(2)O4F square pyramid,  a cornercorner with one Li(4)O4F square pyramid, and  an edgeedge with one Li(3)O4F square pyramid. The corner-sharing octahedral tilt angles range from 32-53°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one Li(4), one V(1), and one P(2) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one V(2) and one P(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one V(2) and one P(2) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Li(3), one V(2), and one P(4) atom. In the fifth O site, O(5) is bonded in a T-shaped geometry to one Li(2), one Mn(1), and one P(1) atom. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(3), one Mn(1), and one P(2) atom. In the seventh O site, O(7) is bonded in a rectangular see-saw-like geometry to one Li(2), one Li(4), one V(1), and one P(4) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to one Li(1), one V(2), and one P(3) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one Li(4), one Mn(2), and one P(2) atom. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(3), one V(1), and one P(1) atom. In the eleventh O site, O(11) is bonded in a rectangular see-saw-like geometry to one Li(2), one Li(4), one Mn(1), and one P(3) atom. In the twelfth O site, O(12) is bonded in a T-shaped geometry to one Li(3), one Mn(1), and one P(4) atom. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one Li(2), one Mn(2), and one P(1) atom. In the fourteenth O site, O(14) is bonded in a bent 150 degrees geometry to one Mn(2) and one P(3) atom. In the fifteenth O site, O(15) is bonded in a bent 150 degrees geometry to one Mn(2) and one P(4) atom. In the sixteenth O site, O(16) is bonded in a T-shaped geometry to one Li(1), one V(1), and one P(3) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one Li(2), one V(1), and one V(2) atom. In the second F site, F(2) is bonded in a trigonal planar geometry to one Li(1), one Mn(1), and one Mn(2) atom. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one Li(4), one V(2), and one Mn(1) atom. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one Li(3), one V(1), and one Mn(2) atom. is represented by the CIF file [CIF]
data_Li2MnVP2(O4F)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.611
_cell_length_b   6.965
_cell_length_c   7.839
_cell_angle_alpha   90.256
_cell_angle_beta   118.263
_cell_angle_gamma   91.411
_symmetry_Int_Tables_number   1
_cell_volume   365.831
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.078  0.651  0.266  1.0
  Li  Li1  1  0.581  0.151  0.769  1.0
  Li  Li2  1  0.420  0.847  0.233  1.0
  Li  Li3  1  0.920  0.351  0.730  1.0
  Mn  Mn4  1  0.500  0.499  0.500  1.0
  Mn  Mn5  1  0.249  0.749  0.749  1.0
  V  V6  1  0.000  0.002  0.002  1.0
  V  V7  1  0.751  0.249  0.250  1.0
  P  P8  1  0.223  0.100  0.460  1.0
  P  P9  1  0.281  0.403  0.042  1.0
  P  P10  1  0.718  0.601  0.955  1.0
  P  P11  1  0.780  0.896  0.544  1.0
  O  O12  1  0.104  0.269  0.018  1.0
  O  O13  1  0.039  0.212  0.426  1.0
  O  O14  1  0.463  0.288  0.074  1.0
  O  O15  1  0.689  0.001  0.348  1.0
  O  O16  1  0.400  0.235  0.484  1.0
  O  O17  1  0.330  0.548  0.213  1.0
  O  O18  1  0.826  0.044  0.713  1.0
  O  O19  1  0.809  0.495  0.151  1.0
  O  O20  1  0.187  0.510  0.846  1.0
  O  O21  1  0.174  0.955  0.289  1.0
  O  O22  1  0.671  0.454  0.785  1.0
  O  O23  1  0.603  0.761  0.519  1.0
  O  O24  1  0.314  0.993  0.655  1.0
  O  O25  1  0.534  0.713  0.921  1.0
  O  O26  1  0.964  0.786  0.578  1.0
  O  O27  1  0.893  0.737  0.981  1.0
  F  F28  1  0.768  0.103  0.031  1.0
  F  F29  1  0.256  0.599  0.520  1.0
  F  F30  1  0.742  0.393  0.470  1.0
  F  F31  1  0.232  0.904  0.977  1.0
[/CIF]
.
The material structure described by Li2VMnP2(O4F)2 crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(10), one O(16), one O(6), one O(8), and one F(2) atom to form distorted LiO4F square pyramids that share  a cornercorner with one V(2)O4F2 octahedra,  a cornercorner with one Mn(2)O4F2 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  an edgeedge with one V(1)O4F2 octahedra,  an edgeedge with one Mn(1)O4F2 octahedra,  an edgeedge with one Li(3)O4F square pyramid, and  an edgeedge with one P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 53-59°. In the second Li site, Li(2) is bonded to one O(11), one O(13), one O(5), one O(7), and one F(1) atom to form distorted LiO4F square pyramids that share  a cornercorner with one V(2)O4F2 octahedra,  a cornercorner with one Mn(2)O4F2 octahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one V(1)O4F2 octahedra,  an edgeedge with one Mn(1)O4F2 octahedra,  an edgeedge with one Li(4)O4F square pyramid, and  an edgeedge with one P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 51-60°. In the third Li site, Li(3) is bonded to one O(10), one O(12), one O(4), one O(6), and one F(4) atom to form distorted LiO4F square pyramids that share  a cornercorner with one V(2)O4F2 octahedra,  a cornercorner with one Mn(2)O4F2 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  an edgeedge with one V(1)O4F2 octahedra,  an edgeedge with one Mn(1)O4F2 octahedra,  an edgeedge with one Li(1)O4F square pyramid, and  an edgeedge with one P(4)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 52-63°. In the fourth Li site, Li(4) is bonded to one O(1), one O(11), one O(7), one O(9), and one F(3) atom to form distorted LiO4F square pyramids that share  a cornercorner with one V(2)O4F2 octahedra,  a cornercorner with one Mn(2)O4F2 octahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one V(1)O4F2 octahedra,  an edgeedge with one Mn(1)O4F2 octahedra,  an edgeedge with one Li(2)O4F square pyramid, and  an edgeedge with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 52-57°. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(10), one O(16), one O(7), one F(1), and one F(4) atom to form VO4F2 octahedra that share  a cornercorner with one V(2)O4F2 octahedra,  a cornercorner with one Mn(2)O4F2 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one Li(1)O4F square pyramid,  an edgeedge with one Li(2)O4F square pyramid,  an edgeedge with one Li(3)O4F square pyramid, and  an edgeedge with one Li(4)O4F square pyramid. The corner-sharing octahedral tilt angles range from 47-48°. In the second V site, V(2) is bonded to one O(2), one O(3), one O(4), one O(8), one F(1), and one F(3) atom to form VO4F2 octahedra that share  a cornercorner with one V(1)O4F2 octahedra,  a cornercorner with one Mn(1)O4F2 octahedra,  a cornercorner with one Li(1)O4F square pyramid,  a cornercorner with one Li(2)O4F square pyramid,  a cornercorner with one Li(3)O4F square pyramid,  a cornercorner with one Li(4)O4F square pyramid,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one P(4)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 47-49°. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(11), one O(12), one O(5), one O(6), one F(2), and one F(3) atom to form MnO4F2 octahedra that share  a cornercorner with one V(2)O4F2 octahedra,  a cornercorner with one Mn(2)O4F2 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  an edgeedge with one Li(1)O4F square pyramid,  an edgeedge with one Li(2)O4F square pyramid,  an edgeedge with one Li(3)O4F square pyramid, and  an edgeedge with one Li(4)O4F square pyramid. The corner-sharing octahedral tilt angles range from 49-51°. In the second Mn site, Mn(2) is bonded to one O(13), one O(14), one O(15), one O(9), one F(2), and one F(4) atom to form MnO4F2 octahedra that share  a cornercorner with one V(1)O4F2 octahedra,  a cornercorner with one Mn(1)O4F2 octahedra,  a cornercorner with one Li(1)O4F square pyramid,  a cornercorner with one Li(2)O4F square pyramid,  a cornercorner with one Li(3)O4F square pyramid,  a cornercorner with one Li(4)O4F square pyramid,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one P(4)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 48-51°. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(10), one O(13), one O(2), and one O(5) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O4F2 octahedra,  a cornercorner with one V(2)O4F2 octahedra,  a cornercorner with one Mn(1)O4F2 octahedra,  a cornercorner with one Mn(2)O4F2 octahedra,  a cornercorner with one Li(1)O4F square pyramid,  a cornercorner with one Li(3)O4F square pyramid, and  an edgeedge with one Li(2)O4F square pyramid. The corner-sharing octahedral tilt angles range from 33-53°. In the second P site, P(2) is bonded to one O(1), one O(3), one O(6), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O4F2 octahedra,  a cornercorner with one V(2)O4F2 octahedra,  a cornercorner with one Mn(1)O4F2 octahedra,  a cornercorner with one Mn(2)O4F2 octahedra,  a cornercorner with one Li(1)O4F square pyramid,  a cornercorner with one Li(3)O4F square pyramid, and  an edgeedge with one Li(4)O4F square pyramid. The corner-sharing octahedral tilt angles range from 33-53°. In the third P site, P(3) is bonded to one O(11), one O(14), one O(16), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O4F2 octahedra,  a cornercorner with one V(2)O4F2 octahedra,  a cornercorner with one Mn(1)O4F2 octahedra,  a cornercorner with one Mn(2)O4F2 octahedra,  a cornercorner with one Li(2)O4F square pyramid,  a cornercorner with one Li(4)O4F square pyramid, and  an edgeedge with one Li(1)O4F square pyramid. The corner-sharing octahedral tilt angles range from 31-54°. In the fourth P site, P(4) is bonded to one O(12), one O(15), one O(4), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O4F2 octahedra,  a cornercorner with one V(2)O4F2 octahedra,  a cornercorner with one Mn(1)O4F2 octahedra,  a cornercorner with one Mn(2)O4F2 octahedra,  a cornercorner with one Li(2)O4F square pyramid,  a cornercorner with one Li(4)O4F square pyramid, and  an edgeedge with one Li(3)O4F square pyramid. The corner-sharing octahedral tilt angles range from 32-53°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one Li(4), one V(1), and one P(2) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one V(2) and one P(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one V(2) and one P(2) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Li(3), one V(2), and one P(4) atom. In the fifth O site, O(5) is bonded in a T-shaped geometry to one Li(2), one Mn(1), and one P(1) atom. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(3), one Mn(1), and one P(2) atom. In the seventh O site, O(7) is bonded in a rectangular see-saw-like geometry to one Li(2), one Li(4), one V(1), and one P(4) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to one Li(1), one V(2), and one P(3) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one Li(4), one Mn(2), and one P(2) atom. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(3), one V(1), and one P(1) atom. In the eleventh O site, O(11) is bonded in a rectangular see-saw-like geometry to one Li(2), one Li(4), one Mn(1), and one P(3) atom. In the twelfth O site, O(12) is bonded in a T-shaped geometry to one Li(3), one Mn(1), and one P(4) atom. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one Li(2), one Mn(2), and one P(1) atom. In the fourteenth O site, O(14) is bonded in a bent 150 degrees geometry to one Mn(2) and one P(3) atom. In the fifteenth O site, O(15) is bonded in a bent 150 degrees geometry to one Mn(2) and one P(4) atom. In the sixteenth O site, O(16) is bonded in a T-shaped geometry to one Li(1), one V(1), and one P(3) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one Li(2), one V(1), and one V(2) atom. In the second F site, F(2) is bonded in a trigonal planar geometry to one Li(1), one Mn(1), and one Mn(2) atom. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one Li(4), one V(2), and one Mn(1) atom. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one Li(3), one V(1), and one Mn(2) atom. is represented by the CIF file [CIF]
data_Li2MnVP2(O4F)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.611
_cell_length_b   6.965
_cell_length_c   7.839
_cell_angle_alpha   90.256
_cell_angle_beta   118.263
_cell_angle_gamma   91.411
_symmetry_Int_Tables_number   1
_cell_volume   365.831
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.078  0.651  0.266  1.0
  Li  Li1  1  0.581  0.151  0.769  1.0
  Li  Li2  1  0.420  0.847  0.233  1.0
  Li  Li3  1  0.920  0.351  0.730  1.0
  Mn  Mn4  1  0.500  0.499  0.500  1.0
  Mn  Mn5  1  0.249  0.749  0.749  1.0
  V  V6  1  0.000  0.002  0.002  1.0
  V  V7  1  0.751  0.249  0.250  1.0
  P  P8  1  0.223  0.100  0.460  1.0
  P  P9  1  0.281  0.403  0.042  1.0
  P  P10  1  0.718  0.601  0.955  1.0
  P  P11  1  0.780  0.896  0.544  1.0
  O  O12  1  0.104  0.269  0.018  1.0
  O  O13  1  0.039  0.212  0.426  1.0
  O  O14  1  0.463  0.288  0.074  1.0
  O  O15  1  0.689  0.001  0.348  1.0
  O  O16  1  0.400  0.235  0.484  1.0
  O  O17  1  0.330  0.548  0.213  1.0
  O  O18  1  0.826  0.044  0.713  1.0
  O  O19  1  0.809  0.495  0.151  1.0
  O  O20  1  0.187  0.510  0.846  1.0
  O  O21  1  0.174  0.955  0.289  1.0
  O  O22  1  0.671  0.454  0.785  1.0
  O  O23  1  0.603  0.761  0.519  1.0
  O  O24  1  0.314  0.993  0.655  1.0
  O  O25  1  0.534  0.713  0.921  1.0
  O  O26  1  0.964  0.786  0.578  1.0
  O  O27  1  0.893  0.737  0.981  1.0
  F  F28  1  0.768  0.103  0.031  1.0
  F  F29  1  0.256  0.599  0.520  1.0
  F  F30  1  0.742  0.393  0.470  1.0
  F  F31  1  0.232  0.904  0.977  1.0
[/CIF]
.