The material described by Cs(CO)2 crystallizes in the monoclinic C2/m space group. Cs(1) is bonded in a 8-coordinate geometry to eight equivalent O(1) atoms. C(1) is bonded in a distorted single-bond geometry to one O(1) atom. O(1) is bonded in a distorted single-bond geometry to four equivalent Cs(1) and one C(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Cs(CO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.845
_cell_length_b   6.787
_cell_length_c   6.787
_cell_angle_alpha   63.746
_cell_angle_beta   88.974
_cell_angle_gamma   88.974
_symmetry_Int_Tables_number   1
_cell_volume   200.139
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.803  0.343  0.343  1.0
  Cs  Cs1  1  0.197  0.657  0.657  1.0
  C  C2  1  0.599  0.152  0.945  1.0
  C  C3  1  0.401  0.848  0.055  1.0
  C  C4  1  0.401  0.055  0.848  1.0
  C  C5  1  0.599  0.945  0.152  1.0
  O  O6  1  0.715  0.336  0.877  1.0
  O  O7  1  0.715  0.877  0.336  1.0
  O  O8  1  0.285  0.123  0.664  1.0
  O  O9  1  0.285  0.664  0.123  1.0
[/CIF]
.
The material described by Cs(CO)2 crystallizes in the monoclinic C2/m space group. Cs(1) is bonded in a 8-coordinate geometry to eight equivalent O(1) atoms. C(1) is bonded in a distorted single-bond geometry to one O(1) atom. O(1) is bonded in a distorted single-bond geometry to four equivalent Cs(1) and one C(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Cs(CO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.845
_cell_length_b   6.787
_cell_length_c   6.787
_cell_angle_alpha   63.746
_cell_angle_beta   88.974
_cell_angle_gamma   88.974
_symmetry_Int_Tables_number   1
_cell_volume   200.139
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.803  0.343  0.343  1.0
  Cs  Cs1  1  0.197  0.657  0.657  1.0
  C  C2  1  0.599  0.152  0.945  1.0
  C  C3  1  0.401  0.848  0.055  1.0
  C  C4  1  0.401  0.055  0.848  1.0
  C  C5  1  0.599  0.945  0.152  1.0
  O  O6  1  0.715  0.336  0.877  1.0
  O  O7  1  0.715  0.877  0.336  1.0
  O  O8  1  0.285  0.123  0.664  1.0
  O  O9  1  0.285  0.664  0.123  1.0
[/CIF]
.