The compound described by CsAu(O3I)4 crystallizes in the triclinic P-1 space group. Cs(1) is bonded in a 10-coordinate geometry to one O(1), one O(3), one O(4), one O(5), one O(6), one O(8), two equivalent O(10), and two equivalent O(12) atoms. Au(1) is bonded in a rectangular see-saw-like geometry to one O(1), one O(10), one O(6), and one O(7) atom. There are twelve inequivalent O sites. In the first O site, O(11) is bonded in a distorted bent 120 degrees geometry to one I(1) and one I(4) atom. In the second O site, O(12) is bonded in a distorted single-bond geometry to two equivalent Cs(1) and one I(4) atom. In the third O site, O(1) is bonded in a distorted trigonal planar geometry to one Cs(1), one Au(1), and one I(1) atom. In the fourth O site, O(2) is bonded in a single-bond geometry to one I(1) atom. In the fifth O site, O(3) is bonded in a distorted single-bond geometry to one Cs(1), one I(1), and one I(3) atom. In the sixth O site, O(4) is bonded in a distorted single-bond geometry to one Cs(1) and one I(2) atom. In the seventh O site, O(5) is bonded in a distorted single-bond geometry to one Cs(1) and one I(2) atom. In the eighth O site, O(6) is bonded in a 3-coordinate geometry to one Cs(1), one Au(1), and one I(2) atom. In the ninth O site, O(7) is bonded in a bent 120 degrees geometry to one Au(1) and one I(3) atom. In the tenth O site, O(8) is bonded in a distorted single-bond geometry to one Cs(1), one I(1), and one I(3) atom. In the eleventh O site, O(9) is bonded in a distorted single-bond geometry to one I(3) atom. In the twelfth O site, O(10) is bonded in a distorted bent 120 degrees geometry to two equivalent Cs(1), one Au(1), and one I(4) atom. There are four inequivalent I sites. In the first I site, I(1) is bonded in a distorted square pyramidal geometry to one O(1), one O(11), one O(2), one O(3), and one O(8) atom. In the second I site, I(2) is bonded in a distorted trigonal non-coplanar geometry to one O(4), one O(5), and one O(6) atom. In the third I site, I(3) is bonded in a distorted rectangular see-saw-like geometry to one O(3), one O(7), one O(8), and one O(9) atom. In the fourth I site, I(4) is bonded in a 3-coordinate geometry to one O(10), one O(11), and one O(12) atom. is represented by the CIF card [CIF]
data_CsAu(IO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.982
_cell_length_b   8.116
_cell_length_c   11.221
_cell_angle_alpha   75.436
_cell_angle_beta   71.306
_cell_angle_gamma   84.536
_symmetry_Int_Tables_number   1
_cell_volume   666.313
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.056  0.178  0.144  1.0
  Cs  Cs1  1  0.944  0.822  0.856  1.0
  Au  Au2  1  0.572  0.047  0.213  1.0
  Au  Au3  1  0.428  0.953  0.787  1.0
  I  I4  1  0.283  0.291  0.413  1.0
  I  I5  1  0.717  0.709  0.587  1.0
  I  I6  1  0.660  0.334  0.904  1.0
  I  I7  1  0.340  0.666  0.096  1.0
  I  I8  1  0.240  0.792  0.469  1.0
  I  I9  1  0.760  0.208  0.531  1.0
  I  I10  1  0.760  0.654  0.249  1.0
  I  I11  1  0.240  0.346  0.751  1.0
  O  O12  1  0.366  0.211  0.254  1.0
  O  O13  1  0.634  0.789  0.746  1.0
  O  O14  1  0.346  0.514  0.338  1.0
  O  O15  1  0.654  0.486  0.662  1.0
  O  O16  1  0.060  0.313  0.398  1.0
  O  O17  1  0.940  0.687  0.602  1.0
  O  O18  1  0.704  0.148  0.836  1.0
  O  O19  1  0.296  0.852  0.164  1.0
  O  O20  1  0.421  0.353  0.950  1.0
  O  O21  1  0.579  0.647  0.050  1.0
  O  O22  1  0.701  0.237  0.068  1.0
  O  O23  1  0.299  0.763  0.932  1.0
  O  O24  1  0.486  0.853  0.372  1.0
  O  O25  1  0.514  0.147  0.628  1.0
  O  O26  1  0.183  0.982  0.532  1.0
  O  O27  1  0.817  0.018  0.468  1.0
  O  O28  1  0.314  0.657  0.599  1.0
  O  O29  1  0.686  0.343  0.401  1.0
  O  O30  1  0.779  0.889  0.154  1.0
  O  O31  1  0.221  0.111  0.846  1.0
  O  O32  1  0.862  0.678  0.369  1.0
  O  O33  1  0.138  0.322  0.631  1.0
  O  O34  1  0.953  0.591  0.132  1.0
  O  O35  1  0.047  0.409  0.868  1.0
[/CIF]
.
The compound described by CsAu(O3I)4 crystallizes in the triclinic P-1 space group. Cs(1) is bonded in a 10-coordinate geometry to one O(1), one O(3), one O(4), one O(5), one O(6), one O(8), two equivalent O(10), and two equivalent O(12) atoms. Au(1) is bonded in a rectangular see-saw-like geometry to one O(1), one O(10), one O(6), and one O(7) atom. There are twelve inequivalent O sites. In the first O site, O(11) is bonded in a distorted bent 120 degrees geometry to one I(1) and one I(4) atom. In the second O site, O(12) is bonded in a distorted single-bond geometry to two equivalent Cs(1) and one I(4) atom. In the third O site, O(1) is bonded in a distorted trigonal planar geometry to one Cs(1), one Au(1), and one I(1) atom. In the fourth O site, O(2) is bonded in a single-bond geometry to one I(1) atom. In the fifth O site, O(3) is bonded in a distorted single-bond geometry to one Cs(1), one I(1), and one I(3) atom. In the sixth O site, O(4) is bonded in a distorted single-bond geometry to one Cs(1) and one I(2) atom. In the seventh O site, O(5) is bonded in a distorted single-bond geometry to one Cs(1) and one I(2) atom. In the eighth O site, O(6) is bonded in a 3-coordinate geometry to one Cs(1), one Au(1), and one I(2) atom. In the ninth O site, O(7) is bonded in a bent 120 degrees geometry to one Au(1) and one I(3) atom. In the tenth O site, O(8) is bonded in a distorted single-bond geometry to one Cs(1), one I(1), and one I(3) atom. In the eleventh O site, O(9) is bonded in a distorted single-bond geometry to one I(3) atom. In the twelfth O site, O(10) is bonded in a distorted bent 120 degrees geometry to two equivalent Cs(1), one Au(1), and one I(4) atom. There are four inequivalent I sites. In the first I site, I(1) is bonded in a distorted square pyramidal geometry to one O(1), one O(11), one O(2), one O(3), and one O(8) atom. In the second I site, I(2) is bonded in a distorted trigonal non-coplanar geometry to one O(4), one O(5), and one O(6) atom. In the third I site, I(3) is bonded in a distorted rectangular see-saw-like geometry to one O(3), one O(7), one O(8), and one O(9) atom. In the fourth I site, I(4) is bonded in a 3-coordinate geometry to one O(10), one O(11), and one O(12) atom. is represented by the CIF card [CIF]
data_CsAu(IO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.982
_cell_length_b   8.116
_cell_length_c   11.221
_cell_angle_alpha   75.436
_cell_angle_beta   71.306
_cell_angle_gamma   84.536
_symmetry_Int_Tables_number   1
_cell_volume   666.313
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.056  0.178  0.144  1.0
  Cs  Cs1  1  0.944  0.822  0.856  1.0
  Au  Au2  1  0.572  0.047  0.213  1.0
  Au  Au3  1  0.428  0.953  0.787  1.0
  I  I4  1  0.283  0.291  0.413  1.0
  I  I5  1  0.717  0.709  0.587  1.0
  I  I6  1  0.660  0.334  0.904  1.0
  I  I7  1  0.340  0.666  0.096  1.0
  I  I8  1  0.240  0.792  0.469  1.0
  I  I9  1  0.760  0.208  0.531  1.0
  I  I10  1  0.760  0.654  0.249  1.0
  I  I11  1  0.240  0.346  0.751  1.0
  O  O12  1  0.366  0.211  0.254  1.0
  O  O13  1  0.634  0.789  0.746  1.0
  O  O14  1  0.346  0.514  0.338  1.0
  O  O15  1  0.654  0.486  0.662  1.0
  O  O16  1  0.060  0.313  0.398  1.0
  O  O17  1  0.940  0.687  0.602  1.0
  O  O18  1  0.704  0.148  0.836  1.0
  O  O19  1  0.296  0.852  0.164  1.0
  O  O20  1  0.421  0.353  0.950  1.0
  O  O21  1  0.579  0.647  0.050  1.0
  O  O22  1  0.701  0.237  0.068  1.0
  O  O23  1  0.299  0.763  0.932  1.0
  O  O24  1  0.486  0.853  0.372  1.0
  O  O25  1  0.514  0.147  0.628  1.0
  O  O26  1  0.183  0.982  0.532  1.0
  O  O27  1  0.817  0.018  0.468  1.0
  O  O28  1  0.314  0.657  0.599  1.0
  O  O29  1  0.686  0.343  0.401  1.0
  O  O30  1  0.779  0.889  0.154  1.0
  O  O31  1  0.221  0.111  0.846  1.0
  O  O32  1  0.862  0.678  0.369  1.0
  O  O33  1  0.138  0.322  0.631  1.0
  O  O34  1  0.953  0.591  0.132  1.0
  O  O35  1  0.047  0.409  0.868  1.0
[/CIF]
.