The material structure described by GeCNH3O is beta Np structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four germane, isocyanato- molecules. Ge(1) is bonded in a tetrahedral geometry to one N(1), one H(1), and two equivalent H(2) atoms. C(1) is bonded in a linear geometry to one N(1) and one O(1) atom. N(1) is bonded in a bent 150 degrees geometry to one Ge(1) and one C(1) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one Ge(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one Ge(1) atom. O(1) is bonded in a single-bond geometry to one C(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_GeH3CNO
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.375
_cell_length_b   7.671
_cell_length_c   8.585
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   551.532
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ge  Ge0  1  0.250  0.319  0.755  1.0
  Ge  Ge1  1  0.250  0.181  0.255  1.0
  Ge  Ge2  1  0.750  0.681  0.245  1.0
  Ge  Ge3  1  0.750  0.819  0.745  1.0
  H  H4  1  0.250  0.134  0.689  1.0
  H  H5  1  0.250  0.366  0.189  1.0
  H  H6  1  0.750  0.866  0.311  1.0
  H  H7  1  0.750  0.634  0.811  1.0
  H  H8  1  0.097  0.359  0.844  1.0
  H  H9  1  0.403  0.141  0.344  1.0
  H  H10  1  0.597  0.641  0.156  1.0
  H  H11  1  0.903  0.859  0.656  1.0
  H  H12  1  0.903  0.641  0.156  1.0
  H  H13  1  0.597  0.859  0.656  1.0
  H  H14  1  0.403  0.359  0.844  1.0
  H  H15  1  0.097  0.141  0.344  1.0
  C  C16  1  0.250  0.598  0.514  1.0
  C  C17  1  0.250  0.902  0.014  1.0
  C  C18  1  0.750  0.402  0.486  1.0
  C  C19  1  0.750  0.098  0.986  1.0
  N  N20  1  0.250  0.457  0.577  1.0
  N  N21  1  0.250  0.043  0.077  1.0
  N  N22  1  0.750  0.543  0.423  1.0
  N  N23  1  0.750  0.957  0.923  1.0
  O  O24  1  0.250  0.731  0.443  1.0
  O  O25  1  0.250  0.769  0.943  1.0
  O  O26  1  0.750  0.269  0.557  1.0
  O  O27  1  0.750  0.231  0.057  1.0
[/CIF]
.
The material structure described by GeCNH3O is beta Np structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four germane, isocyanato- molecules. Ge(1) is bonded in a tetrahedral geometry to one N(1), one H(1), and two equivalent H(2) atoms. C(1) is bonded in a linear geometry to one N(1) and one O(1) atom. N(1) is bonded in a bent 150 degrees geometry to one Ge(1) and one C(1) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one Ge(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one Ge(1) atom. O(1) is bonded in a single-bond geometry to one C(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_GeH3CNO
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.375
_cell_length_b   7.671
_cell_length_c   8.585
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   551.532
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ge  Ge0  1  0.250  0.319  0.755  1.0
  Ge  Ge1  1  0.250  0.181  0.255  1.0
  Ge  Ge2  1  0.750  0.681  0.245  1.0
  Ge  Ge3  1  0.750  0.819  0.745  1.0
  H  H4  1  0.250  0.134  0.689  1.0
  H  H5  1  0.250  0.366  0.189  1.0
  H  H6  1  0.750  0.866  0.311  1.0
  H  H7  1  0.750  0.634  0.811  1.0
  H  H8  1  0.097  0.359  0.844  1.0
  H  H9  1  0.403  0.141  0.344  1.0
  H  H10  1  0.597  0.641  0.156  1.0
  H  H11  1  0.903  0.859  0.656  1.0
  H  H12  1  0.903  0.641  0.156  1.0
  H  H13  1  0.597  0.859  0.656  1.0
  H  H14  1  0.403  0.359  0.844  1.0
  H  H15  1  0.097  0.141  0.344  1.0
  C  C16  1  0.250  0.598  0.514  1.0
  C  C17  1  0.250  0.902  0.014  1.0
  C  C18  1  0.750  0.402  0.486  1.0
  C  C19  1  0.750  0.098  0.986  1.0
  N  N20  1  0.250  0.457  0.577  1.0
  N  N21  1  0.250  0.043  0.077  1.0
  N  N22  1  0.750  0.543  0.423  1.0
  N  N23  1  0.750  0.957  0.923  1.0
  O  O24  1  0.250  0.731  0.443  1.0
  O  O25  1  0.250  0.769  0.943  1.0
  O  O26  1  0.750  0.269  0.557  1.0
  O  O27  1  0.750  0.231  0.057  1.0
[/CIF]
.