The structure described by Rb3LiZn2(MoO4)4 crystallizes in the tetragonal I-42d space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded to four equivalent O(1), four equivalent O(2), and four equivalent O(4) atoms to form distorted RbO12 cuboctahedra that share corners with four equivalent Mo(1)O4 tetrahedra, edges with eight equivalent Rb(2)O12 cuboctahedra, edges with four equivalent Mo(1)O4 tetrahedra, and edges with four equivalent Zn(1)O4 tetrahedra. In the second Rb site, Rb(2) is bonded to two equivalent O(2), two equivalent O(4), four equivalent O(1), and four equivalent O(3) atoms to form distorted RbO12 cuboctahedra that share corners with four equivalent Mo(1)O4 tetrahedra, edges with four equivalent Rb(1)O12 cuboctahedra, edges with four equivalent Rb(2)O12 cuboctahedra, edges with two equivalent Li(1)O4 tetrahedra, edges with two equivalent Zn(1)O4 tetrahedra, and edges with four equivalent Mo(1)O4 tetrahedra. Li(1) is bonded to four equivalent O(3) atoms to form LiO4 tetrahedra that share corners with four equivalent Mo(1)O4 tetrahedra and edges with four equivalent Rb(2)O12 cuboctahedra. Mo(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form MoO4 tetrahedra that share  a cornercorner with one Rb(1)O12 cuboctahedra, corners with two equivalent Rb(2)O12 cuboctahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Zn(1)O4 tetrahedra,  an edgeedge with one Rb(1)O12 cuboctahedra, and edges with two equivalent Rb(2)O12 cuboctahedra. Zn(1) is bonded to two equivalent O(2) and two equivalent O(4) atoms to form ZnO4 tetrahedra that share corners with four equivalent Mo(1)O4 tetrahedra, edges with two equivalent Rb(1)O12 cuboctahedra, and edges with two equivalent Rb(2)O12 cuboctahedra. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Rb(1), two equivalent Rb(2), and one Mo(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Rb(1), one Rb(2), one Mo(1), and one Zn(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to two equivalent Rb(2), one Li(1), and one Mo(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Rb(1), one Rb(2), one Mo(1), and one Zn(1) atom. is represented by the CIF file [CIF]
data_Rb3LiZn2(MoO4)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.496
_cell_length_b   10.496
_cell_length_c   10.496
_cell_angle_alpha   109.307
_cell_angle_beta   109.307
_cell_angle_gamma   109.800
_symmetry_Int_Tables_number   1
_cell_volume   890.123
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.750  0.250  0.500  1.0
  Rb  Rb1  1  0.500  0.500  0.000  1.0
  Rb  Rb2  1  0.125  0.752  0.127  1.0
  Rb  Rb3  1  0.002  0.875  0.627  1.0
  Rb  Rb4  1  0.625  0.998  0.873  1.0
  Rb  Rb5  1  0.248  0.375  0.373  1.0
  Li  Li6  1  0.250  0.750  0.500  1.0
  Li  Li7  1  0.000  0.000  0.000  1.0
  Zn  Zn8  1  0.500  0.875  0.125  1.0
  Zn  Zn9  1  0.125  0.250  0.625  1.0
  Zn  Zn10  1  0.750  0.375  0.875  1.0
  Zn  Zn11  1  0.625  0.500  0.375  1.0
  Mo  Mo12  1  0.160  0.626  0.750  1.0
  Mo  Mo13  1  0.661  0.626  0.750  1.0
  Mo  Mo14  1  0.876  0.910  0.250  1.0
  Mo  Mo15  1  0.374  0.124  0.535  1.0
  Mo  Mo16  1  0.090  0.339  0.965  1.0
  Mo  Mo17  1  0.374  0.124  0.035  1.0
  Mo  Mo18  1  0.589  0.840  0.465  1.0
  Mo  Mo19  1  0.876  0.411  0.250  1.0
  O  O20  1  0.993  0.625  0.749  1.0
  O  O21  1  0.302  0.693  0.950  1.0
  O  O22  1  0.005  0.983  0.184  1.0
  O  O23  1  0.675  0.852  0.117  1.0
  O  O24  1  0.493  0.626  0.751  1.0
  O  O25  1  0.102  0.425  0.617  1.0
  O  O26  1  0.735  0.558  0.883  1.0
  O  O27  1  0.515  0.898  0.323  1.0
  O  O28  1  0.307  0.257  0.609  1.0
  O  O29  1  0.148  0.265  0.823  1.0
  O  O30  1  0.943  0.052  0.450  1.0
  O  O31  1  0.375  0.124  0.368  1.0
  O  O32  1  0.442  0.325  0.177  1.0
  O  O33  1  0.948  0.398  0.891  1.0
  O  O34  1  0.575  0.192  0.677  1.0
  O  O35  1  0.743  0.352  0.050  1.0
  O  O36  1  0.257  0.507  0.132  1.0
  O  O37  1  0.374  0.125  0.868  1.0
  O  O38  1  0.875  0.743  0.249  1.0
  O  O39  1  0.245  0.929  0.478  1.0
  O  O40  1  0.648  0.698  0.391  1.0
  O  O41  1  0.179  0.995  0.978  1.0
  O  O42  1  0.757  0.007  0.632  1.0
  O  O43  1  0.017  0.200  0.022  1.0
  O  O44  1  0.507  0.057  0.109  1.0
  O  O45  1  0.233  0.755  0.684  1.0
  O  O46  1  0.450  0.767  0.522  1.0
  O  O47  1  0.071  0.550  0.316  1.0
  O  O48  1  0.808  0.485  0.383  1.0
  O  O49  1  0.800  0.821  0.816  1.0
  O  O50  1  0.876  0.243  0.251  1.0
  O  O51  1  0.602  0.493  0.550  1.0
[/CIF]
.
The structure described by Rb3LiZn2(MoO4)4 crystallizes in the tetragonal I-42d space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded to four equivalent O(1), four equivalent O(2), and four equivalent O(4) atoms to form distorted RbO12 cuboctahedra that share corners with four equivalent Mo(1)O4 tetrahedra, edges with eight equivalent Rb(2)O12 cuboctahedra, edges with four equivalent Mo(1)O4 tetrahedra, and edges with four equivalent Zn(1)O4 tetrahedra. In the second Rb site, Rb(2) is bonded to two equivalent O(2), two equivalent O(4), four equivalent O(1), and four equivalent O(3) atoms to form distorted RbO12 cuboctahedra that share corners with four equivalent Mo(1)O4 tetrahedra, edges with four equivalent Rb(1)O12 cuboctahedra, edges with four equivalent Rb(2)O12 cuboctahedra, edges with two equivalent Li(1)O4 tetrahedra, edges with two equivalent Zn(1)O4 tetrahedra, and edges with four equivalent Mo(1)O4 tetrahedra. Li(1) is bonded to four equivalent O(3) atoms to form LiO4 tetrahedra that share corners with four equivalent Mo(1)O4 tetrahedra and edges with four equivalent Rb(2)O12 cuboctahedra. Mo(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form MoO4 tetrahedra that share  a cornercorner with one Rb(1)O12 cuboctahedra, corners with two equivalent Rb(2)O12 cuboctahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Zn(1)O4 tetrahedra,  an edgeedge with one Rb(1)O12 cuboctahedra, and edges with two equivalent Rb(2)O12 cuboctahedra. Zn(1) is bonded to two equivalent O(2) and two equivalent O(4) atoms to form ZnO4 tetrahedra that share corners with four equivalent Mo(1)O4 tetrahedra, edges with two equivalent Rb(1)O12 cuboctahedra, and edges with two equivalent Rb(2)O12 cuboctahedra. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Rb(1), two equivalent Rb(2), and one Mo(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Rb(1), one Rb(2), one Mo(1), and one Zn(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to two equivalent Rb(2), one Li(1), and one Mo(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Rb(1), one Rb(2), one Mo(1), and one Zn(1) atom. is represented by the CIF file [CIF]
data_Rb3LiZn2(MoO4)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.496
_cell_length_b   10.496
_cell_length_c   10.496
_cell_angle_alpha   109.307
_cell_angle_beta   109.307
_cell_angle_gamma   109.800
_symmetry_Int_Tables_number   1
_cell_volume   890.123
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.750  0.250  0.500  1.0
  Rb  Rb1  1  0.500  0.500  0.000  1.0
  Rb  Rb2  1  0.125  0.752  0.127  1.0
  Rb  Rb3  1  0.002  0.875  0.627  1.0
  Rb  Rb4  1  0.625  0.998  0.873  1.0
  Rb  Rb5  1  0.248  0.375  0.373  1.0
  Li  Li6  1  0.250  0.750  0.500  1.0
  Li  Li7  1  0.000  0.000  0.000  1.0
  Zn  Zn8  1  0.500  0.875  0.125  1.0
  Zn  Zn9  1  0.125  0.250  0.625  1.0
  Zn  Zn10  1  0.750  0.375  0.875  1.0
  Zn  Zn11  1  0.625  0.500  0.375  1.0
  Mo  Mo12  1  0.160  0.626  0.750  1.0
  Mo  Mo13  1  0.661  0.626  0.750  1.0
  Mo  Mo14  1  0.876  0.910  0.250  1.0
  Mo  Mo15  1  0.374  0.124  0.535  1.0
  Mo  Mo16  1  0.090  0.339  0.965  1.0
  Mo  Mo17  1  0.374  0.124  0.035  1.0
  Mo  Mo18  1  0.589  0.840  0.465  1.0
  Mo  Mo19  1  0.876  0.411  0.250  1.0
  O  O20  1  0.993  0.625  0.749  1.0
  O  O21  1  0.302  0.693  0.950  1.0
  O  O22  1  0.005  0.983  0.184  1.0
  O  O23  1  0.675  0.852  0.117  1.0
  O  O24  1  0.493  0.626  0.751  1.0
  O  O25  1  0.102  0.425  0.617  1.0
  O  O26  1  0.735  0.558  0.883  1.0
  O  O27  1  0.515  0.898  0.323  1.0
  O  O28  1  0.307  0.257  0.609  1.0
  O  O29  1  0.148  0.265  0.823  1.0
  O  O30  1  0.943  0.052  0.450  1.0
  O  O31  1  0.375  0.124  0.368  1.0
  O  O32  1  0.442  0.325  0.177  1.0
  O  O33  1  0.948  0.398  0.891  1.0
  O  O34  1  0.575  0.192  0.677  1.0
  O  O35  1  0.743  0.352  0.050  1.0
  O  O36  1  0.257  0.507  0.132  1.0
  O  O37  1  0.374  0.125  0.868  1.0
  O  O38  1  0.875  0.743  0.249  1.0
  O  O39  1  0.245  0.929  0.478  1.0
  O  O40  1  0.648  0.698  0.391  1.0
  O  O41  1  0.179  0.995  0.978  1.0
  O  O42  1  0.757  0.007  0.632  1.0
  O  O43  1  0.017  0.200  0.022  1.0
  O  O44  1  0.507  0.057  0.109  1.0
  O  O45  1  0.233  0.755  0.684  1.0
  O  O46  1  0.450  0.767  0.522  1.0
  O  O47  1  0.071  0.550  0.316  1.0
  O  O48  1  0.808  0.485  0.383  1.0
  O  O49  1  0.800  0.821  0.816  1.0
  O  O50  1  0.876  0.243  0.251  1.0
  O  O51  1  0.602  0.493  0.550  1.0
[/CIF]
.