The crystal structure described by RbMnO2Cl3 crystallizes in the orthorhombic Pcca space group. Rb(1) is bonded to four equivalent O(1), two equivalent Cl(2), and six equivalent Cl(1) atoms to form a mixture of distorted corner, face, and edge-sharing RbCl8O4 cuboctahedra. Mn(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent Cl(1), and two equivalent Cl(2) atoms. O(1) is bonded in a 2-coordinate geometry to two equivalent Rb(1), one Mn(1), and one O(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted single-bond geometry to three equivalent Rb(1) and one Mn(1) atom. In the second Cl site, Cl(2) is bonded in a distorted see-saw-like geometry to two equivalent Rb(1) and two equivalent Mn(1) atoms. is represented by the CIF file [CIF]
data_RbMnCl3O2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.050
_cell_length_b   9.292
_cell_length_c   11.135
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   729.439
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.000  0.750  0.636  1.0
  Rb  Rb1  1  0.000  0.250  0.864  1.0
  Rb  Rb2  1  0.000  0.250  0.364  1.0
  Rb  Rb3  1  0.000  0.750  0.136  1.0
  Mn  Mn4  1  0.559  0.500  0.750  1.0
  Mn  Mn5  1  0.441  0.000  0.750  1.0
  Mn  Mn6  1  0.441  0.500  0.250  1.0
  Mn  Mn7  1  0.559  0.000  0.250  1.0
  Cl  Cl8  1  0.772  0.579  0.893  1.0
  Cl  Cl9  1  0.228  0.921  0.893  1.0
  Cl  Cl10  1  0.228  0.079  0.607  1.0
  Cl  Cl11  1  0.772  0.421  0.607  1.0
  Cl  Cl12  1  0.228  0.421  0.107  1.0
  Cl  Cl13  1  0.772  0.079  0.107  1.0
  Cl  Cl14  1  0.772  0.921  0.393  1.0
  Cl  Cl15  1  0.228  0.579  0.393  1.0
  Cl  Cl16  1  0.500  0.750  0.652  1.0
  Cl  Cl17  1  0.500  0.250  0.848  1.0
  Cl  Cl18  1  0.500  0.250  0.348  1.0
  Cl  Cl19  1  0.500  0.750  0.152  1.0
  O  O20  1  0.279  0.529  0.803  1.0
  O  O21  1  0.721  0.971  0.803  1.0
  O  O22  1  0.721  0.029  0.697  1.0
  O  O23  1  0.279  0.471  0.697  1.0
  O  O24  1  0.721  0.471  0.197  1.0
  O  O25  1  0.279  0.029  0.197  1.0
  O  O26  1  0.279  0.971  0.303  1.0
  O  O27  1  0.721  0.529  0.303  1.0
[/CIF]
.
The crystal structure described by RbMnO2Cl3 crystallizes in the orthorhombic Pcca space group. Rb(1) is bonded to four equivalent O(1), two equivalent Cl(2), and six equivalent Cl(1) atoms to form a mixture of distorted corner, face, and edge-sharing RbCl8O4 cuboctahedra. Mn(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent Cl(1), and two equivalent Cl(2) atoms. O(1) is bonded in a 2-coordinate geometry to two equivalent Rb(1), one Mn(1), and one O(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted single-bond geometry to three equivalent Rb(1) and one Mn(1) atom. In the second Cl site, Cl(2) is bonded in a distorted see-saw-like geometry to two equivalent Rb(1) and two equivalent Mn(1) atoms. is represented by the CIF file [CIF]
data_RbMnCl3O2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.050
_cell_length_b   9.292
_cell_length_c   11.135
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   729.439
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.000  0.750  0.636  1.0
  Rb  Rb1  1  0.000  0.250  0.864  1.0
  Rb  Rb2  1  0.000  0.250  0.364  1.0
  Rb  Rb3  1  0.000  0.750  0.136  1.0
  Mn  Mn4  1  0.559  0.500  0.750  1.0
  Mn  Mn5  1  0.441  0.000  0.750  1.0
  Mn  Mn6  1  0.441  0.500  0.250  1.0
  Mn  Mn7  1  0.559  0.000  0.250  1.0
  Cl  Cl8  1  0.772  0.579  0.893  1.0
  Cl  Cl9  1  0.228  0.921  0.893  1.0
  Cl  Cl10  1  0.228  0.079  0.607  1.0
  Cl  Cl11  1  0.772  0.421  0.607  1.0
  Cl  Cl12  1  0.228  0.421  0.107  1.0
  Cl  Cl13  1  0.772  0.079  0.107  1.0
  Cl  Cl14  1  0.772  0.921  0.393  1.0
  Cl  Cl15  1  0.228  0.579  0.393  1.0
  Cl  Cl16  1  0.500  0.750  0.652  1.0
  Cl  Cl17  1  0.500  0.250  0.848  1.0
  Cl  Cl18  1  0.500  0.250  0.348  1.0
  Cl  Cl19  1  0.500  0.750  0.152  1.0
  O  O20  1  0.279  0.529  0.803  1.0
  O  O21  1  0.721  0.971  0.803  1.0
  O  O22  1  0.721  0.029  0.697  1.0
  O  O23  1  0.279  0.471  0.697  1.0
  O  O24  1  0.721  0.471  0.197  1.0
  O  O25  1  0.279  0.029  0.197  1.0
  O  O26  1  0.279  0.971  0.303  1.0
  O  O27  1  0.721  0.529  0.303  1.0
[/CIF]
.