The structure described by LaVN3 crystallizes in the triclinic P1 space group. There are two inequivalent La sites. In the first La site, La(1) is bonded in a 8-coordinate geometry to one N(2), one N(4), two equivalent N(1), two equivalent N(3), and two equivalent N(6) atoms. In the second La site, La(2) is bonded in a 8-coordinate geometry to one N(2), one N(4), two equivalent N(3), two equivalent N(5), and two equivalent N(6) atoms. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 5-coordinate geometry to one N(1), one N(5), one N(6), and two equivalent N(2) atoms. In the second V site, V(2) is bonded to one N(1), one N(3), one N(5), and two equivalent N(4) atoms to form distorted corner-sharing VN5 trigonal bipyramids. There are six inequivalent N sites. In the first N site, N(1) is bonded to two equivalent La(1), one V(1), one V(2), and one N(2) atom to form distorted corner-sharing NLa2V2N trigonal bipyramids. In the second N site, N(2) is bonded in a 5-coordinate geometry to one La(1), one La(2), two equivalent V(1), and one N(1) atom. In the third N site, N(3) is bonded in a 5-coordinate geometry to two equivalent La(1), two equivalent La(2), and one V(2) atom. In the fourth N site, N(4) is bonded in a 4-coordinate geometry to one La(1), one La(2), and two equivalent V(2) atoms. In the fifth N site, N(5) is bonded in a 4-coordinate geometry to two equivalent La(2), one V(1), and one V(2) atom. In the sixth N site, N(6) is bonded in a distorted single-bond geometry to two equivalent La(1), two equivalent La(2), and one V(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LaVN3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.630
_cell_length_b   6.025
_cell_length_c   6.329
_cell_angle_alpha   106.963
_cell_angle_beta   96.412
_cell_angle_gamma   90.838
_symmetry_Int_Tables_number   1
_cell_volume   131.387
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.551  0.789  0.271  1.0
  La  La1  1  0.626  0.333  0.728  1.0
  V  V2  1  0.148  0.818  0.753  1.0
  V  V3  1  0.077  0.288  0.252  1.0
  N  N4  1  0.970  0.947  0.050  1.0
  N  N5  1  0.677  0.835  0.887  1.0
  N  N6  1  0.066  0.468  0.081  1.0
  N  N7  1  0.553  0.222  0.311  1.0
  N  N8  1  0.107  0.524  0.565  1.0
  N  N9  1  0.111  0.002  0.585  1.0
[/CIF]
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The structure described by LaVN3 crystallizes in the triclinic P1 space group. There are two inequivalent La sites. In the first La site, La(1) is bonded in a 8-coordinate geometry to one N(2), one N(4), two equivalent N(1), two equivalent N(3), and two equivalent N(6) atoms. In the second La site, La(2) is bonded in a 8-coordinate geometry to one N(2), one N(4), two equivalent N(3), two equivalent N(5), and two equivalent N(6) atoms. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 5-coordinate geometry to one N(1), one N(5), one N(6), and two equivalent N(2) atoms. In the second V site, V(2) is bonded to one N(1), one N(3), one N(5), and two equivalent N(4) atoms to form distorted corner-sharing VN5 trigonal bipyramids. There are six inequivalent N sites. In the first N site, N(1) is bonded to two equivalent La(1), one V(1), one V(2), and one N(2) atom to form distorted corner-sharing NLa2V2N trigonal bipyramids. In the second N site, N(2) is bonded in a 5-coordinate geometry to one La(1), one La(2), two equivalent V(1), and one N(1) atom. In the third N site, N(3) is bonded in a 5-coordinate geometry to two equivalent La(1), two equivalent La(2), and one V(2) atom. In the fourth N site, N(4) is bonded in a 4-coordinate geometry to one La(1), one La(2), and two equivalent V(2) atoms. In the fifth N site, N(5) is bonded in a 4-coordinate geometry to two equivalent La(2), one V(1), and one V(2) atom. In the sixth N site, N(6) is bonded in a distorted single-bond geometry to two equivalent La(1), two equivalent La(2), and one V(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LaVN3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.630
_cell_length_b   6.025
_cell_length_c   6.329
_cell_angle_alpha   106.963
_cell_angle_beta   96.412
_cell_angle_gamma   90.838
_symmetry_Int_Tables_number   1
_cell_volume   131.387
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.551  0.789  0.271  1.0
  La  La1  1  0.626  0.333  0.728  1.0
  V  V2  1  0.148  0.818  0.753  1.0
  V  V3  1  0.077  0.288  0.252  1.0
  N  N4  1  0.970  0.947  0.050  1.0
  N  N5  1  0.677  0.835  0.887  1.0
  N  N6  1  0.066  0.468  0.081  1.0
  N  N7  1  0.553  0.222  0.311  1.0
  N  N8  1  0.107  0.524  0.565  1.0
  N  N9  1  0.111  0.002  0.585  1.0
[/CIF]
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