The compound described by Yb(DyS2)2 crystallizes in the tetragonal I-42d space group. Yb(1) is bonded in a 8-coordinate geometry to eight equivalent S(1) atoms. Dy(1) is bonded in a 8-coordinate geometry to eight equivalent S(1) atoms. S(1) is bonded to two equivalent Yb(1) and four equivalent Dy(1) atoms to form a mixture of distorted edge, face, and corner-sharing SYb2Dy4 octahedra. The corner-sharing octahedral tilt angles range from 18-50°. is represented by the CIF card [CIF]
data_Yb(DyS2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.199
_cell_length_b   7.199
_cell_length_c   7.199
_cell_angle_alpha   109.409
_cell_angle_beta   109.409
_cell_angle_gamma   109.596
_symmetry_Int_Tables_number   1
_cell_volume   287.171
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Yb  Yb0  1  0.750  0.250  0.500  1.0
  Yb  Yb1  1  0.500  0.500  0.000  1.0
  Dy  Dy2  1  0.997  0.375  0.122  1.0
  Dy  Dy3  1  0.625  0.747  0.622  1.0
  Dy  Dy4  1  0.253  0.875  0.878  1.0
  Dy  Dy5  1  0.125  0.003  0.378  1.0
  S  S6  1  0.513  0.121  0.750  1.0
  S  S7  1  0.012  0.120  0.750  1.0
  S  S8  1  0.880  0.629  0.892  1.0
  S  S9  1  0.371  0.263  0.250  1.0
  S  S10  1  0.238  0.487  0.608  1.0
  S  S11  1  0.370  0.762  0.250  1.0
  S  S12  1  0.879  0.630  0.392  1.0
  S  S13  1  0.737  0.987  0.108  1.0
[/CIF]
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The compound described by Yb(DyS2)2 crystallizes in the tetragonal I-42d space group. Yb(1) is bonded in a 8-coordinate geometry to eight equivalent S(1) atoms. Dy(1) is bonded in a 8-coordinate geometry to eight equivalent S(1) atoms. S(1) is bonded to two equivalent Yb(1) and four equivalent Dy(1) atoms to form a mixture of distorted edge, face, and corner-sharing SYb2Dy4 octahedra. The corner-sharing octahedral tilt angles range from 18-50°. is represented by the CIF card [CIF]
data_Yb(DyS2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.199
_cell_length_b   7.199
_cell_length_c   7.199
_cell_angle_alpha   109.409
_cell_angle_beta   109.409
_cell_angle_gamma   109.596
_symmetry_Int_Tables_number   1
_cell_volume   287.171
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Yb  Yb0  1  0.750  0.250  0.500  1.0
  Yb  Yb1  1  0.500  0.500  0.000  1.0
  Dy  Dy2  1  0.997  0.375  0.122  1.0
  Dy  Dy3  1  0.625  0.747  0.622  1.0
  Dy  Dy4  1  0.253  0.875  0.878  1.0
  Dy  Dy5  1  0.125  0.003  0.378  1.0
  S  S6  1  0.513  0.121  0.750  1.0
  S  S7  1  0.012  0.120  0.750  1.0
  S  S8  1  0.880  0.629  0.892  1.0
  S  S9  1  0.371  0.263  0.250  1.0
  S  S10  1  0.238  0.487  0.608  1.0
  S  S11  1  0.370  0.762  0.250  1.0
  S  S12  1  0.879  0.630  0.392  1.0
  S  S13  1  0.737  0.987  0.108  1.0
[/CIF]
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