The material described by SbF6HFSF3 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four hydrofluoric acid molecules, four SF3 clusters, and four SbF6 clusters. In each SF3 cluster, S(1) is bonded in a distorted T-shaped geometry to one F(7) and two equivalent F(8,9) atoms. There are two inequivalent F sites. In the first F site, F(8,9) is bonded in a single-bond geometry to one S(1) atom. In the second F site, F(7) is bonded in a single-bond geometry to one S(1) atom. In each SbF6 cluster, Sb(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. There are six inequivalent F sites. In the first F site, F(6) is bonded in a distorted single-bond geometry to one Sb(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the CIF card [CIF]
data_SbHSF10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.740
_cell_length_b   10.649
_cell_length_c   12.971
_cell_angle_alpha   90.000
_cell_angle_beta   98.185
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   784.820
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.123  0.745  0.967  1.0
  Sb  Sb1  1  0.877  0.245  0.533  1.0
  Sb  Sb2  1  0.877  0.255  0.033  1.0
  Sb  Sb3  1  0.123  0.755  0.467  1.0
  H  H4  1  0.259  0.109  0.881  1.0
  H  H5  1  0.741  0.609  0.619  1.0
  H  H6  1  0.741  0.891  0.119  1.0
  H  H7  1  0.259  0.391  0.381  1.0
  S  S8  1  0.454  0.473  0.793  1.0
  S  S9  1  0.546  0.973  0.707  1.0
  S  S10  1  0.546  0.527  0.207  1.0
  S  S11  1  0.454  0.027  0.293  1.0
  F  F12  1  0.224  0.672  0.103  1.0
  F  F13  1  0.776  0.172  0.397  1.0
  F  F14  1  0.776  0.328  0.897  1.0
  F  F15  1  0.224  0.828  0.603  1.0
  F  F16  1  0.033  0.815  0.832  1.0
  F  F17  1  0.967  0.315  0.668  1.0
  F  F18  1  0.967  0.185  0.168  1.0
  F  F19  1  0.033  0.685  0.332  1.0
  F  F20  1  0.348  0.875  1.000  1.0
  F  F21  1  0.652  0.375  0.500  1.0
  F  F22  1  0.652  0.125  0.000  1.0
  F  F23  1  0.348  0.625  0.500  1.0
  F  F24  1  0.900  0.613  0.936  1.0
  F  F25  1  0.100  0.113  0.564  1.0
  F  F26  1  0.100  0.387  0.064  1.0
  F  F27  1  0.900  0.887  0.436  1.0
  F  F28  1  0.362  0.642  0.915  1.0
  F  F29  1  0.638  0.142  0.585  1.0
  F  F30  1  0.638  0.358  0.085  1.0
  F  F31  1  0.362  0.858  0.415  1.0
  F  F32  1  0.889  0.844  0.024  1.0
  F  F33  1  0.111  0.344  0.476  1.0
  F  F34  1  0.111  0.156  0.976  1.0
  F  F35  1  0.889  0.656  0.524  1.0
  F  F36  1  0.487  0.368  0.714  1.0
  F  F37  1  0.513  0.868  0.786  1.0
  F  F38  1  0.513  0.632  0.286  1.0
  F  F39  1  0.487  0.132  0.214  1.0
  F  F40  1  0.296  0.397  0.858  1.0
  F  F41  1  0.704  0.897  0.642  1.0
  F  F42  1  0.704  0.603  0.142  1.0
  F  F43  1  0.296  0.103  0.358  1.0
  F  F44  1  0.256  0.544  0.724  1.0
  F  F45  1  0.744  0.044  0.776  1.0
  F  F46  1  0.744  0.456  0.276  1.0
  F  F47  1  0.256  0.956  0.224  1.0
  F  F48  1  0.293  0.098  0.811  1.0
  F  F49  1  0.707  0.598  0.689  1.0
  F  F50  1  0.707  0.902  0.189  1.0
  F  F51  1  0.293  0.402  0.311  1.0
[/CIF]
.
The material described by SbF6HFSF3 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four hydrofluoric acid molecules, four SF3 clusters, and four SbF6 clusters. In each SF3 cluster, S(1) is bonded in a distorted T-shaped geometry to one F(7) and two equivalent F(8,9) atoms. There are two inequivalent F sites. In the first F site, F(8,9) is bonded in a single-bond geometry to one S(1) atom. In the second F site, F(7) is bonded in a single-bond geometry to one S(1) atom. In each SbF6 cluster, Sb(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. There are six inequivalent F sites. In the first F site, F(6) is bonded in a distorted single-bond geometry to one Sb(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the CIF card [CIF]
data_SbHSF10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.740
_cell_length_b   10.649
_cell_length_c   12.971
_cell_angle_alpha   90.000
_cell_angle_beta   98.185
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   784.820
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.123  0.745  0.967  1.0
  Sb  Sb1  1  0.877  0.245  0.533  1.0
  Sb  Sb2  1  0.877  0.255  0.033  1.0
  Sb  Sb3  1  0.123  0.755  0.467  1.0
  H  H4  1  0.259  0.109  0.881  1.0
  H  H5  1  0.741  0.609  0.619  1.0
  H  H6  1  0.741  0.891  0.119  1.0
  H  H7  1  0.259  0.391  0.381  1.0
  S  S8  1  0.454  0.473  0.793  1.0
  S  S9  1  0.546  0.973  0.707  1.0
  S  S10  1  0.546  0.527  0.207  1.0
  S  S11  1  0.454  0.027  0.293  1.0
  F  F12  1  0.224  0.672  0.103  1.0
  F  F13  1  0.776  0.172  0.397  1.0
  F  F14  1  0.776  0.328  0.897  1.0
  F  F15  1  0.224  0.828  0.603  1.0
  F  F16  1  0.033  0.815  0.832  1.0
  F  F17  1  0.967  0.315  0.668  1.0
  F  F18  1  0.967  0.185  0.168  1.0
  F  F19  1  0.033  0.685  0.332  1.0
  F  F20  1  0.348  0.875  1.000  1.0
  F  F21  1  0.652  0.375  0.500  1.0
  F  F22  1  0.652  0.125  0.000  1.0
  F  F23  1  0.348  0.625  0.500  1.0
  F  F24  1  0.900  0.613  0.936  1.0
  F  F25  1  0.100  0.113  0.564  1.0
  F  F26  1  0.100  0.387  0.064  1.0
  F  F27  1  0.900  0.887  0.436  1.0
  F  F28  1  0.362  0.642  0.915  1.0
  F  F29  1  0.638  0.142  0.585  1.0
  F  F30  1  0.638  0.358  0.085  1.0
  F  F31  1  0.362  0.858  0.415  1.0
  F  F32  1  0.889  0.844  0.024  1.0
  F  F33  1  0.111  0.344  0.476  1.0
  F  F34  1  0.111  0.156  0.976  1.0
  F  F35  1  0.889  0.656  0.524  1.0
  F  F36  1  0.487  0.368  0.714  1.0
  F  F37  1  0.513  0.868  0.786  1.0
  F  F38  1  0.513  0.632  0.286  1.0
  F  F39  1  0.487  0.132  0.214  1.0
  F  F40  1  0.296  0.397  0.858  1.0
  F  F41  1  0.704  0.897  0.642  1.0
  F  F42  1  0.704  0.603  0.142  1.0
  F  F43  1  0.296  0.103  0.358  1.0
  F  F44  1  0.256  0.544  0.724  1.0
  F  F45  1  0.744  0.044  0.776  1.0
  F  F46  1  0.744  0.456  0.276  1.0
  F  F47  1  0.256  0.956  0.224  1.0
  F  F48  1  0.293  0.098  0.811  1.0
  F  F49  1  0.707  0.598  0.689  1.0
  F  F50  1  0.707  0.902  0.189  1.0
  F  F51  1  0.293  0.402  0.311  1.0
[/CIF]
.