The material described by K3ReC4(N2O)2 crystallizes in the triclinic P-1 space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 1-coordinate geometry to one C(1) and one O(1) atom. In the second K site, K(2) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent N(2) atoms. Re(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent N(1) and two equivalent O(1) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted L-shaped geometry to one K(1), one C(2), and one N(2) atom. In the second C site, C(2) is bonded in a distorted water-like geometry to one C(1) and one N(1) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 4-coordinate geometry to one K(2), one Re(1), one C(2), and one O(1) atom. In the second N site, N(2) is bonded in a distorted single-bond geometry to one K(2) and one C(1) atom. O(1) is bonded in a 3-coordinate geometry to one K(1), one Re(1), and one N(1) atom. is represented by the CIF file [CIF]
data_K3ReC4(N2O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.989
_cell_length_b   7.382
_cell_length_c   8.492
_cell_angle_alpha   108.857
_cell_angle_beta   101.072
_cell_angle_gamma   112.706
_symmetry_Int_Tables_number   1
_cell_volume   356.411
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.404  0.746  0.876  1.0
  K  K1  1  0.596  0.254  0.124  1.0
  K  K2  1  0.500  0.500  0.500  1.0
  Re  Re3  1  0.000  0.000  0.000  1.0
  C  C4  1  0.640  0.816  0.136  1.0
  C  C5  1  0.916  0.906  0.322  1.0
  C  C6  1  0.084  0.094  0.678  1.0
  C  C7  1  0.360  0.184  0.864  1.0
  N  N8  1  0.882  0.989  0.772  1.0
  N  N9  1  0.440  0.699  0.207  1.0
  N  N10  1  0.118  0.011  0.228  1.0
  N  N11  1  0.560  0.301  0.793  1.0
  O  O12  1  0.012  0.758  0.012  1.0
  O  O13  1  0.988  0.242  0.988  1.0
[/CIF]
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The material described by K3ReC4(N2O)2 crystallizes in the triclinic P-1 space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 1-coordinate geometry to one C(1) and one O(1) atom. In the second K site, K(2) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent N(2) atoms. Re(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent N(1) and two equivalent O(1) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted L-shaped geometry to one K(1), one C(2), and one N(2) atom. In the second C site, C(2) is bonded in a distorted water-like geometry to one C(1) and one N(1) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 4-coordinate geometry to one K(2), one Re(1), one C(2), and one O(1) atom. In the second N site, N(2) is bonded in a distorted single-bond geometry to one K(2) and one C(1) atom. O(1) is bonded in a 3-coordinate geometry to one K(1), one Re(1), and one N(1) atom. is represented by the CIF file [CIF]
data_K3ReC4(N2O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.989
_cell_length_b   7.382
_cell_length_c   8.492
_cell_angle_alpha   108.857
_cell_angle_beta   101.072
_cell_angle_gamma   112.706
_symmetry_Int_Tables_number   1
_cell_volume   356.411
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.404  0.746  0.876  1.0
  K  K1  1  0.596  0.254  0.124  1.0
  K  K2  1  0.500  0.500  0.500  1.0
  Re  Re3  1  0.000  0.000  0.000  1.0
  C  C4  1  0.640  0.816  0.136  1.0
  C  C5  1  0.916  0.906  0.322  1.0
  C  C6  1  0.084  0.094  0.678  1.0
  C  C7  1  0.360  0.184  0.864  1.0
  N  N8  1  0.882  0.989  0.772  1.0
  N  N9  1  0.440  0.699  0.207  1.0
  N  N10  1  0.118  0.011  0.228  1.0
  N  N11  1  0.560  0.301  0.793  1.0
  O  O12  1  0.012  0.758  0.012  1.0
  O  O13  1  0.988  0.242  0.988  1.0
[/CIF]
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