The compound described by NaNH crystallizes in the orthorhombic Fddd space group. The structure consists of a NaNH framework. Na(1) is bonded in a 3-coordinate geometry to three equivalent N(1) atoms. N(1) is bonded in a distorted single-bond geometry to three equivalent Na(1) and one H(1) atom. H(1) is bonded in a single-bond geometry to one N(1) atom. is represented by the CIF file [CIF]
data_NaHN
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.898
_cell_length_b   7.898
_cell_length_c   8.486
_cell_angle_alpha   118.048
_cell_angle_beta   118.048
_cell_angle_gamma   89.397
_symmetry_Int_Tables_number   1
_cell_volume   396.950
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.576  0.754  0.519  1.0
  Na  Na1  1  0.943  0.765  0.519  1.0
  Na  Na2  1  0.246  0.424  0.481  1.0
  Na  Na3  1  0.674  0.996  0.981  1.0
  Na  Na4  1  0.235  0.057  0.481  1.0
  Na  Na5  1  0.307  0.985  0.981  1.0
  Na  Na6  1  0.004  0.326  0.019  1.0
  Na  Na7  1  0.015  0.693  0.019  1.0
  H  H8  1  0.460  0.627  0.902  1.0
  H  H9  1  0.443  0.275  0.902  1.0
  H  H10  1  0.373  0.540  0.098  1.0
  H  H11  1  0.790  0.123  0.598  1.0
  H  H12  1  0.725  0.557  0.098  1.0
  H  H13  1  0.807  0.475  0.598  1.0
  H  H14  1  0.877  0.210  0.402  1.0
  H  H15  1  0.525  0.193  0.402  1.0
  N  N16  1  0.424  0.705  0.825  1.0
  N  N17  1  0.401  0.120  0.825  1.0
  N  N18  1  0.295  0.576  0.175  1.0
  N  N19  1  0.826  0.045  0.675  1.0
  N  N20  1  0.880  0.599  0.175  1.0
  N  N21  1  0.849  0.630  0.675  1.0
  N  N22  1  0.955  0.174  0.325  1.0
  N  N23  1  0.370  0.151  0.325  1.0
[/CIF]
.
The compound described by NaNH crystallizes in the orthorhombic Fddd space group. The structure consists of a NaNH framework. Na(1) is bonded in a 3-coordinate geometry to three equivalent N(1) atoms. N(1) is bonded in a distorted single-bond geometry to three equivalent Na(1) and one H(1) atom. H(1) is bonded in a single-bond geometry to one N(1) atom. is represented by the CIF file [CIF]
data_NaHN
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.898
_cell_length_b   7.898
_cell_length_c   8.486
_cell_angle_alpha   118.048
_cell_angle_beta   118.048
_cell_angle_gamma   89.397
_symmetry_Int_Tables_number   1
_cell_volume   396.950
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.576  0.754  0.519  1.0
  Na  Na1  1  0.943  0.765  0.519  1.0
  Na  Na2  1  0.246  0.424  0.481  1.0
  Na  Na3  1  0.674  0.996  0.981  1.0
  Na  Na4  1  0.235  0.057  0.481  1.0
  Na  Na5  1  0.307  0.985  0.981  1.0
  Na  Na6  1  0.004  0.326  0.019  1.0
  Na  Na7  1  0.015  0.693  0.019  1.0
  H  H8  1  0.460  0.627  0.902  1.0
  H  H9  1  0.443  0.275  0.902  1.0
  H  H10  1  0.373  0.540  0.098  1.0
  H  H11  1  0.790  0.123  0.598  1.0
  H  H12  1  0.725  0.557  0.098  1.0
  H  H13  1  0.807  0.475  0.598  1.0
  H  H14  1  0.877  0.210  0.402  1.0
  H  H15  1  0.525  0.193  0.402  1.0
  N  N16  1  0.424  0.705  0.825  1.0
  N  N17  1  0.401  0.120  0.825  1.0
  N  N18  1  0.295  0.576  0.175  1.0
  N  N19  1  0.826  0.045  0.675  1.0
  N  N20  1  0.880  0.599  0.175  1.0
  N  N21  1  0.849  0.630  0.675  1.0
  N  N22  1  0.955  0.174  0.325  1.0
  N  N23  1  0.370  0.151  0.325  1.0
[/CIF]
.