The material structure described by CsN2H5 crystallizes in the orthorhombic Pnma space group. Cs(1) is bonded in a 8-coordinate geometry to one H(3), two equivalent H(1), two equivalent H(4), and three equivalent H(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a water-like geometry to one H(1) and one H(2) atom. In the second N site, N(2) is bonded in a trigonal non-coplanar geometry to one H(3) and two equivalent H(4) atoms. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to two equivalent Cs(1) and one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to three equivalent Cs(1) and one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one Cs(1) and one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one Cs(1) and one N(2) atom. is represented by the CIF card [CIF]
data_CsH5N2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.323
_cell_length_b   7.175
_cell_length_c   9.928
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   379.219
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.750  0.220  0.571  1.0
  Cs  Cs1  1  0.750  0.720  0.929  1.0
  Cs  Cs2  1  0.250  0.780  0.429  1.0
  Cs  Cs3  1  0.250  0.280  0.071  1.0
  H  H4  1  0.750  0.287  0.869  1.0
  H  H5  1  0.750  0.787  0.631  1.0
  H  H6  1  0.250  0.713  0.131  1.0
  H  H7  1  0.250  0.213  0.369  1.0
  H  H8  1  0.750  0.125  0.979  1.0
  H  H9  1  0.750  0.625  0.521  1.0
  H  H10  1  0.250  0.875  0.021  1.0
  H  H11  1  0.250  0.375  0.479  1.0
  H  H12  1  0.750  0.134  0.256  1.0
  H  H13  1  0.750  0.634  0.244  1.0
  H  H14  1  0.250  0.866  0.744  1.0
  H  H15  1  0.250  0.366  0.756  1.0
  H  H16  1  0.592  0.949  0.206  1.0
  H  H17  1  0.908  0.449  0.294  1.0
  H  H18  1  0.092  0.051  0.794  1.0
  H  H19  1  0.408  0.551  0.706  1.0
  H  H20  1  0.408  0.051  0.794  1.0
  H  H21  1  0.092  0.551  0.706  1.0
  H  H22  1  0.908  0.949  0.206  1.0
  H  H23  1  0.592  0.449  0.294  1.0
  N  N24  1  0.750  0.144  0.877  1.0
  N  N25  1  0.750  0.644  0.623  1.0
  N  N26  1  0.250  0.856  0.123  1.0
  N  N27  1  0.250  0.356  0.377  1.0
  N  N28  1  0.750  0.493  0.241  1.0
  N  N29  1  0.750  0.993  0.259  1.0
  N  N30  1  0.250  0.507  0.759  1.0
  N  N31  1  0.250  0.007  0.741  1.0
[/CIF]
.
The material structure described by CsN2H5 crystallizes in the orthorhombic Pnma space group. Cs(1) is bonded in a 8-coordinate geometry to one H(3), two equivalent H(1), two equivalent H(4), and three equivalent H(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a water-like geometry to one H(1) and one H(2) atom. In the second N site, N(2) is bonded in a trigonal non-coplanar geometry to one H(3) and two equivalent H(4) atoms. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to two equivalent Cs(1) and one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to three equivalent Cs(1) and one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one Cs(1) and one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one Cs(1) and one N(2) atom. is represented by the CIF card [CIF]
data_CsH5N2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.323
_cell_length_b   7.175
_cell_length_c   9.928
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   379.219
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.750  0.220  0.571  1.0
  Cs  Cs1  1  0.750  0.720  0.929  1.0
  Cs  Cs2  1  0.250  0.780  0.429  1.0
  Cs  Cs3  1  0.250  0.280  0.071  1.0
  H  H4  1  0.750  0.287  0.869  1.0
  H  H5  1  0.750  0.787  0.631  1.0
  H  H6  1  0.250  0.713  0.131  1.0
  H  H7  1  0.250  0.213  0.369  1.0
  H  H8  1  0.750  0.125  0.979  1.0
  H  H9  1  0.750  0.625  0.521  1.0
  H  H10  1  0.250  0.875  0.021  1.0
  H  H11  1  0.250  0.375  0.479  1.0
  H  H12  1  0.750  0.134  0.256  1.0
  H  H13  1  0.750  0.634  0.244  1.0
  H  H14  1  0.250  0.866  0.744  1.0
  H  H15  1  0.250  0.366  0.756  1.0
  H  H16  1  0.592  0.949  0.206  1.0
  H  H17  1  0.908  0.449  0.294  1.0
  H  H18  1  0.092  0.051  0.794  1.0
  H  H19  1  0.408  0.551  0.706  1.0
  H  H20  1  0.408  0.051  0.794  1.0
  H  H21  1  0.092  0.551  0.706  1.0
  H  H22  1  0.908  0.949  0.206  1.0
  H  H23  1  0.592  0.449  0.294  1.0
  N  N24  1  0.750  0.144  0.877  1.0
  N  N25  1  0.750  0.644  0.623  1.0
  N  N26  1  0.250  0.856  0.123  1.0
  N  N27  1  0.250  0.356  0.377  1.0
  N  N28  1  0.750  0.493  0.241  1.0
  N  N29  1  0.750  0.993  0.259  1.0
  N  N30  1  0.250  0.507  0.759  1.0
  N  N31  1  0.250  0.007  0.741  1.0
[/CIF]
.