The material structure described by ZnBiF5 crystallizes in the monoclinic P2_1/c space group. Zn(1) is bonded in a distorted see-saw-like geometry to one F(1), one F(2), one F(3), and one F(4) atom. Bi(1) is bonded to one F(1), one F(2), one F(3), one F(4), and two equivalent F(5) atoms to form corner-sharing BiF6 octahedra. The corner-sharing octahedral tilt angles are 41°. There are five inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to one Zn(1) and one Bi(1) atom. In the second F site, F(2) is bonded in a bent 150 degrees geometry to one Zn(1) and one Bi(1) atom. In the third F site, F(3) is bonded in a bent 150 degrees geometry to one Zn(1) and one Bi(1) atom. In the fourth F site, F(4) is bonded in a linear geometry to one Zn(1) and one Bi(1) atom. In the fifth F site, F(5) is bonded in a bent 150 degrees geometry to two equivalent Bi(1) atoms. is represented by the CIF file [CIF]
data_ZnBiF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.776
_cell_length_b   5.569
_cell_length_c   8.587
_cell_angle_alpha   71.302
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   488.076
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.993  0.498  0.777  1.0
  Zn  Zn1  1  0.493  0.502  0.723  1.0
  Zn  Zn2  1  0.007  0.502  0.223  1.0
  Zn  Zn3  1  0.507  0.498  0.277  1.0
  Bi  Bi4  1  0.758  0.091  0.608  1.0
  Bi  Bi5  1  0.258  0.909  0.892  1.0
  Bi  Bi6  1  0.242  0.909  0.392  1.0
  Bi  Bi7  1  0.742  0.091  0.108  1.0
  F  F8  1  0.892  0.394  0.611  1.0
  F  F9  1  0.392  0.606  0.889  1.0
  F  F10  1  0.108  0.606  0.389  1.0
  F  F11  1  0.608  0.394  0.111  1.0
  F  F12  1  0.603  0.363  0.489  1.0
  F  F13  1  0.103  0.637  0.011  1.0
  F  F14  1  0.397  0.637  0.511  1.0
  F  F15  1  0.897  0.363  0.989  1.0
  F  F16  1  0.426  0.162  0.792  1.0
  F  F17  1  0.926  0.838  0.708  1.0
  F  F18  1  0.574  0.838  0.208  1.0
  F  F19  1  0.074  0.162  0.292  1.0
  F  F20  1  0.128  0.262  0.819  1.0
  F  F21  1  0.628  0.738  0.681  1.0
  F  F22  1  0.872  0.738  0.181  1.0
  F  F23  1  0.372  0.262  0.319  1.0
  F  F24  1  0.688  0.177  0.835  1.0
  F  F25  1  0.188  0.823  0.665  1.0
  F  F26  1  0.312  0.823  0.165  1.0
  F  F27  1  0.812  0.177  0.335  1.0
[/CIF]
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The material structure described by ZnBiF5 crystallizes in the monoclinic P2_1/c space group. Zn(1) is bonded in a distorted see-saw-like geometry to one F(1), one F(2), one F(3), and one F(4) atom. Bi(1) is bonded to one F(1), one F(2), one F(3), one F(4), and two equivalent F(5) atoms to form corner-sharing BiF6 octahedra. The corner-sharing octahedral tilt angles are 41°. There are five inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to one Zn(1) and one Bi(1) atom. In the second F site, F(2) is bonded in a bent 150 degrees geometry to one Zn(1) and one Bi(1) atom. In the third F site, F(3) is bonded in a bent 150 degrees geometry to one Zn(1) and one Bi(1) atom. In the fourth F site, F(4) is bonded in a linear geometry to one Zn(1) and one Bi(1) atom. In the fifth F site, F(5) is bonded in a bent 150 degrees geometry to two equivalent Bi(1) atoms. is represented by the CIF file [CIF]
data_ZnBiF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.776
_cell_length_b   5.569
_cell_length_c   8.587
_cell_angle_alpha   71.302
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   488.076
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.993  0.498  0.777  1.0
  Zn  Zn1  1  0.493  0.502  0.723  1.0
  Zn  Zn2  1  0.007  0.502  0.223  1.0
  Zn  Zn3  1  0.507  0.498  0.277  1.0
  Bi  Bi4  1  0.758  0.091  0.608  1.0
  Bi  Bi5  1  0.258  0.909  0.892  1.0
  Bi  Bi6  1  0.242  0.909  0.392  1.0
  Bi  Bi7  1  0.742  0.091  0.108  1.0
  F  F8  1  0.892  0.394  0.611  1.0
  F  F9  1  0.392  0.606  0.889  1.0
  F  F10  1  0.108  0.606  0.389  1.0
  F  F11  1  0.608  0.394  0.111  1.0
  F  F12  1  0.603  0.363  0.489  1.0
  F  F13  1  0.103  0.637  0.011  1.0
  F  F14  1  0.397  0.637  0.511  1.0
  F  F15  1  0.897  0.363  0.989  1.0
  F  F16  1  0.426  0.162  0.792  1.0
  F  F17  1  0.926  0.838  0.708  1.0
  F  F18  1  0.574  0.838  0.208  1.0
  F  F19  1  0.074  0.162  0.292  1.0
  F  F20  1  0.128  0.262  0.819  1.0
  F  F21  1  0.628  0.738  0.681  1.0
  F  F22  1  0.872  0.738  0.181  1.0
  F  F23  1  0.372  0.262  0.319  1.0
  F  F24  1  0.688  0.177  0.835  1.0
  F  F25  1  0.188  0.823  0.665  1.0
  F  F26  1  0.312  0.823  0.165  1.0
  F  F27  1  0.812  0.177  0.335  1.0
[/CIF]
.