The compound described by SnC4H14(NBr2)2 is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two SnC4H14(NBr2)2 clusters. Sn(1) is bonded to two equivalent N(1), two equivalent Br(1), and two equivalent Br(2) atoms to form SnBr4N2 octahedra that share corners with two equivalent C(1)H3N tetrahedra and corners with two equivalent C(2)H3N tetrahedra. There are two inequivalent C sites. In the first C site, C(1) is bonded to one N(1), one H(2), one H(3), and one H(4) atom to form CH3N tetrahedra that share  a cornercorner with one Sn(1)Br4N2 octahedra and  a cornercorner with one C(2)H3N tetrahedra. The corner-sharing octahedral tilt angles are 65°. In the second C site, C(2) is bonded to one N(1), one H(1), one H(6), and one H(7) atom to form CH3N tetrahedra that share  a cornercorner with one Sn(1)Br4N2 octahedra and  a cornercorner with one C(1)H3N tetrahedra. The corner-sharing octahedral tilt angles are 65°. N(1) is bonded in a 1-coordinate geometry to one Sn(1), one C(1), one C(2), and one H(5) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(1) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(1) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(2) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(2) atom. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Sn(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Sn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SnH14C4(Br2N)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.516
_cell_length_b   6.731
_cell_length_c   8.636
_cell_angle_alpha   83.270
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   722.531
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.000  0.000  0.000  1.0
  Sn  Sn1  1  0.500  0.000  0.500  1.0
  H  H2  1  0.405  0.894  0.875  1.0
  H  H3  1  0.803  0.332  0.975  1.0
  H  H4  1  0.697  0.332  0.475  1.0
  H  H5  1  0.763  0.174  0.832  1.0
  H  H6  1  0.212  0.566  0.225  1.0
  H  H7  1  0.263  0.826  0.668  1.0
  H  H8  1  0.029  0.626  0.145  1.0
  H  H9  1  0.971  0.374  0.855  1.0
  H  H10  1  0.197  0.668  0.025  1.0
  H  H11  1  0.288  0.566  0.725  1.0
  H  H12  1  0.918  0.372  0.587  1.0
  H  H13  1  0.303  0.668  0.525  1.0
  H  H14  1  0.095  0.894  0.375  1.0
  H  H15  1  0.788  0.434  0.775  1.0
  H  H16  1  0.418  0.628  0.913  1.0
  H  H17  1  0.737  0.174  0.332  1.0
  H  H18  1  0.967  0.779  0.360  1.0
  H  H19  1  0.905  0.106  0.625  1.0
  H  H20  1  0.237  0.826  0.168  1.0
  H  H21  1  0.582  0.372  0.087  1.0
  H  H22  1  0.467  0.221  0.140  1.0
  H  H23  1  0.529  0.374  0.355  1.0
  H  H24  1  0.533  0.779  0.860  1.0
  H  H25  1  0.033  0.221  0.640  1.0
  H  H26  1  0.595  0.106  0.125  1.0
  H  H27  1  0.712  0.434  0.275  1.0
  H  H28  1  0.471  0.626  0.645  1.0
  H  H29  1  0.082  0.628  0.413  1.0
  C  C30  1  0.187  0.699  0.146  1.0
  C  C31  1  0.947  0.237  0.659  1.0
  C  C32  1  0.053  0.763  0.341  1.0
  C  C33  1  0.313  0.699  0.646  1.0
  C  C34  1  0.447  0.763  0.841  1.0
  C  C35  1  0.687  0.301  0.354  1.0
  C  C36  1  0.813  0.301  0.854  1.0
  C  C37  1  0.553  0.237  0.159  1.0
  Br  Br38  1  0.815  0.842  0.084  1.0
  Br  Br39  1  0.519  0.250  0.713  1.0
  Br  Br40  1  0.481  0.750  0.287  1.0
  Br  Br41  1  0.685  0.842  0.584  1.0
  Br  Br42  1  0.315  0.158  0.416  1.0
  Br  Br43  1  0.185  0.158  0.916  1.0
  Br  Br44  1  0.981  0.250  0.213  1.0
  Br  Br45  1  0.019  0.750  0.787  1.0
  N  N46  1  0.426  0.744  0.675  1.0
  N  N47  1  0.074  0.744  0.175  1.0
  N  N48  1  0.926  0.256  0.825  1.0
  N  N49  1  0.574  0.256  0.325  1.0
[/CIF]
.
The compound described by SnC4H14(NBr2)2 is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two SnC4H14(NBr2)2 clusters. Sn(1) is bonded to two equivalent N(1), two equivalent Br(1), and two equivalent Br(2) atoms to form SnBr4N2 octahedra that share corners with two equivalent C(1)H3N tetrahedra and corners with two equivalent C(2)H3N tetrahedra. There are two inequivalent C sites. In the first C site, C(1) is bonded to one N(1), one H(2), one H(3), and one H(4) atom to form CH3N tetrahedra that share  a cornercorner with one Sn(1)Br4N2 octahedra and  a cornercorner with one C(2)H3N tetrahedra. The corner-sharing octahedral tilt angles are 65°. In the second C site, C(2) is bonded to one N(1), one H(1), one H(6), and one H(7) atom to form CH3N tetrahedra that share  a cornercorner with one Sn(1)Br4N2 octahedra and  a cornercorner with one C(1)H3N tetrahedra. The corner-sharing octahedral tilt angles are 65°. N(1) is bonded in a 1-coordinate geometry to one Sn(1), one C(1), one C(2), and one H(5) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(1) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(1) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(2) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(2) atom. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Sn(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Sn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SnH14C4(Br2N)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.516
_cell_length_b   6.731
_cell_length_c   8.636
_cell_angle_alpha   83.270
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   722.531
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.000  0.000  0.000  1.0
  Sn  Sn1  1  0.500  0.000  0.500  1.0
  H  H2  1  0.405  0.894  0.875  1.0
  H  H3  1  0.803  0.332  0.975  1.0
  H  H4  1  0.697  0.332  0.475  1.0
  H  H5  1  0.763  0.174  0.832  1.0
  H  H6  1  0.212  0.566  0.225  1.0
  H  H7  1  0.263  0.826  0.668  1.0
  H  H8  1  0.029  0.626  0.145  1.0
  H  H9  1  0.971  0.374  0.855  1.0
  H  H10  1  0.197  0.668  0.025  1.0
  H  H11  1  0.288  0.566  0.725  1.0
  H  H12  1  0.918  0.372  0.587  1.0
  H  H13  1  0.303  0.668  0.525  1.0
  H  H14  1  0.095  0.894  0.375  1.0
  H  H15  1  0.788  0.434  0.775  1.0
  H  H16  1  0.418  0.628  0.913  1.0
  H  H17  1  0.737  0.174  0.332  1.0
  H  H18  1  0.967  0.779  0.360  1.0
  H  H19  1  0.905  0.106  0.625  1.0
  H  H20  1  0.237  0.826  0.168  1.0
  H  H21  1  0.582  0.372  0.087  1.0
  H  H22  1  0.467  0.221  0.140  1.0
  H  H23  1  0.529  0.374  0.355  1.0
  H  H24  1  0.533  0.779  0.860  1.0
  H  H25  1  0.033  0.221  0.640  1.0
  H  H26  1  0.595  0.106  0.125  1.0
  H  H27  1  0.712  0.434  0.275  1.0
  H  H28  1  0.471  0.626  0.645  1.0
  H  H29  1  0.082  0.628  0.413  1.0
  C  C30  1  0.187  0.699  0.146  1.0
  C  C31  1  0.947  0.237  0.659  1.0
  C  C32  1  0.053  0.763  0.341  1.0
  C  C33  1  0.313  0.699  0.646  1.0
  C  C34  1  0.447  0.763  0.841  1.0
  C  C35  1  0.687  0.301  0.354  1.0
  C  C36  1  0.813  0.301  0.854  1.0
  C  C37  1  0.553  0.237  0.159  1.0
  Br  Br38  1  0.815  0.842  0.084  1.0
  Br  Br39  1  0.519  0.250  0.713  1.0
  Br  Br40  1  0.481  0.750  0.287  1.0
  Br  Br41  1  0.685  0.842  0.584  1.0
  Br  Br42  1  0.315  0.158  0.416  1.0
  Br  Br43  1  0.185  0.158  0.916  1.0
  Br  Br44  1  0.981  0.250  0.213  1.0
  Br  Br45  1  0.019  0.750  0.787  1.0
  N  N46  1  0.426  0.744  0.675  1.0
  N  N47  1  0.074  0.744  0.175  1.0
  N  N48  1  0.926  0.256  0.825  1.0
  N  N49  1  0.574  0.256  0.325  1.0
[/CIF]
.