The compound described by Th(PS3)2 crystallizes in the tetragonal P4_2/m space group. Th(1) is bonded in a 8-coordinate geometry to four equivalent S(1) and four equivalent S(2) atoms. P(1) is bonded in a distorted tetrahedral geometry to one P(1), one S(2), and two equivalent S(1) atoms. There are two inequivalent S sites. In the first S site, S(2) is bonded in a 3-coordinate geometry to two equivalent Th(1) and one P(1) atom. In the second S site, S(1) is bonded in an L-shaped geometry to one Th(1) and one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Th(PS3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.005
_cell_length_b   7.005
_cell_length_c   9.937
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   487.562
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Th  Th0  1  0.000  0.000  0.750  1.0
  Th  Th1  1  0.000  0.000  0.250  1.0
  P  P2  1  0.649  0.061  0.000  1.0
  P  P3  1  0.351  0.939  0.000  1.0
  P  P4  1  0.061  0.351  0.500  1.0
  P  P5  1  0.939  0.649  0.500  1.0
  S  S6  1  0.213  0.324  0.670  1.0
  S  S7  1  0.676  0.213  0.170  1.0
  S  S8  1  0.178  0.174  0.000  1.0
  S  S9  1  0.826  0.178  0.500  1.0
  S  S10  1  0.174  0.822  0.500  1.0
  S  S11  1  0.822  0.826  0.000  1.0
  S  S12  1  0.213  0.324  0.330  1.0
  S  S13  1  0.676  0.213  0.830  1.0
  S  S14  1  0.324  0.787  0.830  1.0
  S  S15  1  0.787  0.676  0.330  1.0
  S  S16  1  0.787  0.676  0.670  1.0
  S  S17  1  0.324  0.787  0.170  1.0
[/CIF]
.
The compound described by Th(PS3)2 crystallizes in the tetragonal P4_2/m space group. Th(1) is bonded in a 8-coordinate geometry to four equivalent S(1) and four equivalent S(2) atoms. P(1) is bonded in a distorted tetrahedral geometry to one P(1), one S(2), and two equivalent S(1) atoms. There are two inequivalent S sites. In the first S site, S(2) is bonded in a 3-coordinate geometry to two equivalent Th(1) and one P(1) atom. In the second S site, S(1) is bonded in an L-shaped geometry to one Th(1) and one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Th(PS3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.005
_cell_length_b   7.005
_cell_length_c   9.937
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   487.562
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Th  Th0  1  0.000  0.000  0.750  1.0
  Th  Th1  1  0.000  0.000  0.250  1.0
  P  P2  1  0.649  0.061  0.000  1.0
  P  P3  1  0.351  0.939  0.000  1.0
  P  P4  1  0.061  0.351  0.500  1.0
  P  P5  1  0.939  0.649  0.500  1.0
  S  S6  1  0.213  0.324  0.670  1.0
  S  S7  1  0.676  0.213  0.170  1.0
  S  S8  1  0.178  0.174  0.000  1.0
  S  S9  1  0.826  0.178  0.500  1.0
  S  S10  1  0.174  0.822  0.500  1.0
  S  S11  1  0.822  0.826  0.000  1.0
  S  S12  1  0.213  0.324  0.330  1.0
  S  S13  1  0.676  0.213  0.830  1.0
  S  S14  1  0.324  0.787  0.830  1.0
  S  S15  1  0.787  0.676  0.330  1.0
  S  S16  1  0.787  0.676  0.670  1.0
  S  S17  1  0.324  0.787  0.170  1.0
[/CIF]
.