The crystal structure described by CoSnO3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. Co(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form distorted CoO4 tetrahedra that share corners with eight equivalent Sn(1)O6 octahedra and corners with two equivalent Co(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 65-82°. Sn(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form SnO6 octahedra that share corners with six equivalent Sn(1)O6 octahedra and corners with eight equivalent Co(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 47°. There are two inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Co(1) and two equivalent Sn(1) atoms to form distorted corner-sharing OCo2Sn2 tetrahedra. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Co(1) and two equivalent Sn(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_CoSnO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.395
_cell_length_b   5.423
_cell_length_c   7.811
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   228.500
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.027  0.013  0.750  1.0
  Co  Co1  1  0.527  0.487  0.750  1.0
  Co  Co2  1  0.473  0.513  0.250  1.0
  Co  Co3  1  0.973  0.987  0.250  1.0
  Sn  Sn4  1  0.500  0.000  0.000  1.0
  Sn  Sn5  1  0.500  0.000  0.500  1.0
  Sn  Sn6  1  0.000  0.500  0.000  1.0
  Sn  Sn7  1  0.000  0.500  0.500  1.0
  O  O8  1  0.594  0.875  0.250  1.0
  O  O9  1  0.832  0.835  0.567  1.0
  O  O10  1  0.832  0.835  0.933  1.0
  O  O11  1  0.332  0.665  0.567  1.0
  O  O12  1  0.332  0.665  0.933  1.0
  O  O13  1  0.094  0.625  0.250  1.0
  O  O14  1  0.906  0.375  0.750  1.0
  O  O15  1  0.668  0.335  0.067  1.0
  O  O16  1  0.668  0.335  0.433  1.0
  O  O17  1  0.168  0.165  0.067  1.0
  O  O18  1  0.168  0.165  0.433  1.0
  O  O19  1  0.406  0.125  0.750  1.0
[/CIF]
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The crystal structure described by CoSnO3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. Co(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form distorted CoO4 tetrahedra that share corners with eight equivalent Sn(1)O6 octahedra and corners with two equivalent Co(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 65-82°. Sn(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form SnO6 octahedra that share corners with six equivalent Sn(1)O6 octahedra and corners with eight equivalent Co(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 47°. There are two inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Co(1) and two equivalent Sn(1) atoms to form distorted corner-sharing OCo2Sn2 tetrahedra. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Co(1) and two equivalent Sn(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_CoSnO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.395
_cell_length_b   5.423
_cell_length_c   7.811
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   228.500
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.027  0.013  0.750  1.0
  Co  Co1  1  0.527  0.487  0.750  1.0
  Co  Co2  1  0.473  0.513  0.250  1.0
  Co  Co3  1  0.973  0.987  0.250  1.0
  Sn  Sn4  1  0.500  0.000  0.000  1.0
  Sn  Sn5  1  0.500  0.000  0.500  1.0
  Sn  Sn6  1  0.000  0.500  0.000  1.0
  Sn  Sn7  1  0.000  0.500  0.500  1.0
  O  O8  1  0.594  0.875  0.250  1.0
  O  O9  1  0.832  0.835  0.567  1.0
  O  O10  1  0.832  0.835  0.933  1.0
  O  O11  1  0.332  0.665  0.567  1.0
  O  O12  1  0.332  0.665  0.933  1.0
  O  O13  1  0.094  0.625  0.250  1.0
  O  O14  1  0.906  0.375  0.750  1.0
  O  O15  1  0.668  0.335  0.067  1.0
  O  O16  1  0.668  0.335  0.433  1.0
  O  O17  1  0.168  0.165  0.067  1.0
  O  O18  1  0.168  0.165  0.433  1.0
  O  O19  1  0.406  0.125  0.750  1.0
[/CIF]
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