The compound described by KAg2PS4 crystallizes in the tetragonal I-42m space group. K(1) is bonded in a 8-coordinate geometry to eight equivalent S(1) atoms. Ag(1) is bonded to four equivalent S(1) atoms to form distorted AgS4 trigonal pyramids that share corners with four equivalent P(1)S4 tetrahedra and corners with four equivalent Ag(1)S4 trigonal pyramids. P(1) is bonded to four equivalent S(1) atoms to form PS4 tetrahedra that share corners with eight equivalent Ag(1)S4 trigonal pyramids. S(1) is bonded in a 5-coordinate geometry to two equivalent K(1), two equivalent Ag(1), and one P(1) atom. is represented by the CIF file [CIF]
data_KAg2PS4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.352
_cell_length_b   6.352
_cell_length_c   6.352
_cell_angle_alpha   95.133
_cell_angle_beta   117.082
_cell_angle_gamma   117.082
_symmetry_Int_Tables_number   1
_cell_volume   188.361
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.000  0.500  0.500  1.0
  Ag  Ag1  1  0.500  0.250  0.750  1.0
  Ag  Ag2  1  0.500  0.750  0.250  1.0
  P  P3  1  0.000  0.000  0.000  1.0
  S  S4  1  0.000  0.681  0.045  1.0
  S  S5  1  0.000  0.045  0.681  1.0
  S  S6  1  0.637  0.955  0.955  1.0
  S  S7  1  0.363  0.319  0.319  1.0
[/CIF]
.
The compound described by KAg2PS4 crystallizes in the tetragonal I-42m space group. K(1) is bonded in a 8-coordinate geometry to eight equivalent S(1) atoms. Ag(1) is bonded to four equivalent S(1) atoms to form distorted AgS4 trigonal pyramids that share corners with four equivalent P(1)S4 tetrahedra and corners with four equivalent Ag(1)S4 trigonal pyramids. P(1) is bonded to four equivalent S(1) atoms to form PS4 tetrahedra that share corners with eight equivalent Ag(1)S4 trigonal pyramids. S(1) is bonded in a 5-coordinate geometry to two equivalent K(1), two equivalent Ag(1), and one P(1) atom. is represented by the CIF file [CIF]
data_KAg2PS4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.352
_cell_length_b   6.352
_cell_length_c   6.352
_cell_angle_alpha   95.133
_cell_angle_beta   117.082
_cell_angle_gamma   117.082
_symmetry_Int_Tables_number   1
_cell_volume   188.361
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.000  0.500  0.500  1.0
  Ag  Ag1  1  0.500  0.250  0.750  1.0
  Ag  Ag2  1  0.500  0.750  0.250  1.0
  P  P3  1  0.000  0.000  0.000  1.0
  S  S4  1  0.000  0.681  0.045  1.0
  S  S5  1  0.000  0.045  0.681  1.0
  S  S6  1  0.637  0.955  0.955  1.0
  S  S7  1  0.363  0.319  0.319  1.0
[/CIF]
.