The material structure described by Mg(AgO2)2 crystallizes in the orthorhombic Pbcm space group. Mg(1) is bonded in a 6-coordinate geometry to two equivalent O(2), two equivalent O(3), and four equivalent O(1) atoms. Ag(1) is bonded to one O(3), two equivalent O(1), and two equivalent O(2) atoms to form a mixture of distorted corner and edge-sharing AgO5 square pyramids. There are three inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Mg(1) and two equivalent Ag(1) atoms to form a mixture of distorted corner and edge-sharing OMg2Ag2 tetrahedra. In the second O site, O(2) is bonded in a 6-coordinate geometry to two equivalent Mg(1) and four equivalent Ag(1) atoms. In the third O site, O(3) is bonded to two equivalent Mg(1) and two equivalent Ag(1) atoms to form a mixture of corner and edge-sharing OMg2Ag2 tetrahedra. is represented by the CIF card [CIF]
data_Mg(AgO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.185
_cell_length_b   9.825
_cell_length_c   10.824
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   338.749
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.344  0.750  0.851  1.0
  Mg  Mg1  1  0.344  0.250  0.649  1.0
  Mg  Mg2  1  0.656  0.750  0.351  1.0
  Mg  Mg3  1  0.656  0.250  0.149  1.0
  Ag  Ag4  1  0.835  0.572  0.615  1.0
  Ag  Ag5  1  0.835  0.072  0.885  1.0
  Ag  Ag6  1  0.165  0.072  0.385  1.0
  Ag  Ag7  1  0.835  0.428  0.885  1.0
  Ag  Ag8  1  0.165  0.428  0.385  1.0
  Ag  Ag9  1  0.835  0.928  0.615  1.0
  Ag  Ag10  1  0.165  0.928  0.115  1.0
  Ag  Ag11  1  0.165  0.572  0.115  1.0
  O  O12  1  0.133  0.875  0.450  1.0
  O  O13  1  0.867  0.125  0.550  1.0
  O  O14  1  0.464  0.000  0.750  1.0
  O  O15  1  0.867  0.875  0.950  1.0
  O  O16  1  0.867  0.625  0.950  1.0
  O  O17  1  0.836  0.250  0.785  1.0
  O  O18  1  0.133  0.125  0.050  1.0
  O  O19  1  0.164  0.250  0.285  1.0
  O  O20  1  0.464  0.500  0.750  1.0
  O  O21  1  0.536  0.000  0.250  1.0
  O  O22  1  0.133  0.625  0.450  1.0
  O  O23  1  0.164  0.750  0.215  1.0
  O  O24  1  0.836  0.750  0.715  1.0
  O  O25  1  0.536  0.500  0.250  1.0
  O  O26  1  0.133  0.375  0.050  1.0
  O  O27  1  0.867  0.375  0.550  1.0
[/CIF]
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The material structure described by Mg(AgO2)2 crystallizes in the orthorhombic Pbcm space group. Mg(1) is bonded in a 6-coordinate geometry to two equivalent O(2), two equivalent O(3), and four equivalent O(1) atoms. Ag(1) is bonded to one O(3), two equivalent O(1), and two equivalent O(2) atoms to form a mixture of distorted corner and edge-sharing AgO5 square pyramids. There are three inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Mg(1) and two equivalent Ag(1) atoms to form a mixture of distorted corner and edge-sharing OMg2Ag2 tetrahedra. In the second O site, O(2) is bonded in a 6-coordinate geometry to two equivalent Mg(1) and four equivalent Ag(1) atoms. In the third O site, O(3) is bonded to two equivalent Mg(1) and two equivalent Ag(1) atoms to form a mixture of corner and edge-sharing OMg2Ag2 tetrahedra. is represented by the CIF card [CIF]
data_Mg(AgO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.185
_cell_length_b   9.825
_cell_length_c   10.824
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   338.749
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.344  0.750  0.851  1.0
  Mg  Mg1  1  0.344  0.250  0.649  1.0
  Mg  Mg2  1  0.656  0.750  0.351  1.0
  Mg  Mg3  1  0.656  0.250  0.149  1.0
  Ag  Ag4  1  0.835  0.572  0.615  1.0
  Ag  Ag5  1  0.835  0.072  0.885  1.0
  Ag  Ag6  1  0.165  0.072  0.385  1.0
  Ag  Ag7  1  0.835  0.428  0.885  1.0
  Ag  Ag8  1  0.165  0.428  0.385  1.0
  Ag  Ag9  1  0.835  0.928  0.615  1.0
  Ag  Ag10  1  0.165  0.928  0.115  1.0
  Ag  Ag11  1  0.165  0.572  0.115  1.0
  O  O12  1  0.133  0.875  0.450  1.0
  O  O13  1  0.867  0.125  0.550  1.0
  O  O14  1  0.464  0.000  0.750  1.0
  O  O15  1  0.867  0.875  0.950  1.0
  O  O16  1  0.867  0.625  0.950  1.0
  O  O17  1  0.836  0.250  0.785  1.0
  O  O18  1  0.133  0.125  0.050  1.0
  O  O19  1  0.164  0.250  0.285  1.0
  O  O20  1  0.464  0.500  0.750  1.0
  O  O21  1  0.536  0.000  0.250  1.0
  O  O22  1  0.133  0.625  0.450  1.0
  O  O23  1  0.164  0.750  0.215  1.0
  O  O24  1  0.836  0.750  0.715  1.0
  O  O25  1  0.536  0.500  0.250  1.0
  O  O26  1  0.133  0.375  0.050  1.0
  O  O27  1  0.867  0.375  0.550  1.0
[/CIF]
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