The structure described by LiAg2F4 crystallizes in the orthorhombic Ccce space group. Li(1) is bonded in a rectangular see-saw-like geometry to two equivalent F(1) and two equivalent F(2) atoms. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to two equivalent F(1) and four equivalent F(2) atoms to form edge-sharing AgF6 pentagonal pyramids. In the second Ag site, Ag(2) is bonded in a rectangular see-saw-like geometry to two equivalent F(1) and two equivalent F(2) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded in a 3-coordinate geometry to one Li(1), one Ag(1), and one Ag(2) atom. In the second F site, F(2) is bonded in a 4-coordinate geometry to one Li(1), one Ag(2), and two equivalent Ag(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiAg2F4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.114
_cell_length_b   8.114
_cell_length_c   6.173
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.708
_symmetry_Int_Tables_number   1
_cell_volume   406.448
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.500  0.000  0.779  1.0
  Li  Li1  1  0.500  0.000  0.279  1.0
  Li  Li2  1  0.000  0.500  0.221  1.0
  Li  Li3  1  0.000  0.500  0.721  1.0
  Ag  Ag4  1  0.831  0.831  0.500  1.0
  Ag  Ag5  1  0.155  0.845  0.000  1.0
  Ag  Ag6  1  0.845  0.155  0.000  1.0
  Ag  Ag7  1  0.169  0.169  0.500  1.0
  Ag  Ag8  1  0.655  0.345  0.500  1.0
  Ag  Ag9  1  0.331  0.331  0.000  1.0
  Ag  Ag10  1  0.345  0.655  0.500  1.0
  Ag  Ag11  1  0.669  0.669  0.000  1.0
  F  F12  1  0.444  0.761  0.792  1.0
  F  F13  1  0.553  0.771  0.317  1.0
  F  F14  1  0.729  0.947  0.817  1.0
  F  F15  1  0.261  0.944  0.292  1.0
  F  F16  1  0.739  0.056  0.292  1.0
  F  F17  1  0.271  0.053  0.817  1.0
  F  F18  1  0.447  0.229  0.317  1.0
  F  F19  1  0.556  0.239  0.792  1.0
  F  F20  1  0.944  0.261  0.708  1.0
  F  F21  1  0.053  0.271  0.183  1.0
  F  F22  1  0.229  0.447  0.683  1.0
  F  F23  1  0.761  0.444  0.208  1.0
  F  F24  1  0.239  0.556  0.208  1.0
  F  F25  1  0.771  0.553  0.683  1.0
  F  F26  1  0.947  0.729  0.183  1.0
  F  F27  1  0.056  0.739  0.708  1.0
[/CIF]
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The structure described by LiAg2F4 crystallizes in the orthorhombic Ccce space group. Li(1) is bonded in a rectangular see-saw-like geometry to two equivalent F(1) and two equivalent F(2) atoms. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to two equivalent F(1) and four equivalent F(2) atoms to form edge-sharing AgF6 pentagonal pyramids. In the second Ag site, Ag(2) is bonded in a rectangular see-saw-like geometry to two equivalent F(1) and two equivalent F(2) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded in a 3-coordinate geometry to one Li(1), one Ag(1), and one Ag(2) atom. In the second F site, F(2) is bonded in a 4-coordinate geometry to one Li(1), one Ag(2), and two equivalent Ag(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiAg2F4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.114
_cell_length_b   8.114
_cell_length_c   6.173
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.708
_symmetry_Int_Tables_number   1
_cell_volume   406.448
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.500  0.000  0.779  1.0
  Li  Li1  1  0.500  0.000  0.279  1.0
  Li  Li2  1  0.000  0.500  0.221  1.0
  Li  Li3  1  0.000  0.500  0.721  1.0
  Ag  Ag4  1  0.831  0.831  0.500  1.0
  Ag  Ag5  1  0.155  0.845  0.000  1.0
  Ag  Ag6  1  0.845  0.155  0.000  1.0
  Ag  Ag7  1  0.169  0.169  0.500  1.0
  Ag  Ag8  1  0.655  0.345  0.500  1.0
  Ag  Ag9  1  0.331  0.331  0.000  1.0
  Ag  Ag10  1  0.345  0.655  0.500  1.0
  Ag  Ag11  1  0.669  0.669  0.000  1.0
  F  F12  1  0.444  0.761  0.792  1.0
  F  F13  1  0.553  0.771  0.317  1.0
  F  F14  1  0.729  0.947  0.817  1.0
  F  F15  1  0.261  0.944  0.292  1.0
  F  F16  1  0.739  0.056  0.292  1.0
  F  F17  1  0.271  0.053  0.817  1.0
  F  F18  1  0.447  0.229  0.317  1.0
  F  F19  1  0.556  0.239  0.792  1.0
  F  F20  1  0.944  0.261  0.708  1.0
  F  F21  1  0.053  0.271  0.183  1.0
  F  F22  1  0.229  0.447  0.683  1.0
  F  F23  1  0.761  0.444  0.208  1.0
  F  F24  1  0.239  0.556  0.208  1.0
  F  F25  1  0.771  0.553  0.683  1.0
  F  F26  1  0.947  0.729  0.183  1.0
  F  F27  1  0.056  0.739  0.708  1.0
[/CIF]
.