The material described by PdC4H16(N2S)4(NO3)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two nitric acid molecules and one PdC4H16(N2S)4 cluster. In the PdC4H16(N2S)4 cluster, Pd(1) is bonded in a square co-planar geometry to two equivalent S(1) and two equivalent S(2) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one N(3), one N(5), and one S(2) atom. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one N(2), one N(4), and one S(1) atom. There are four inequivalent N sites. In the first N site, N(5) is bonded in a trigonal planar geometry to one C(1), one H(2), and one H(7) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(2), one H(1), and one H(3) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(1), one H(4), and one H(6) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(2), one H(5), and one H(8) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(5) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(4) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one N(5) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one N(4) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one Pd(1) and one C(2) atom. In the second S site, S(2) is bonded in a water-like geometry to one Pd(1) and one C(1) atom. is represented by the CIF file [CIF]
data_H16PdC4S4(N5O3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.931
_cell_length_b   7.313
_cell_length_c   11.669
_cell_angle_alpha   99.336
_cell_angle_beta   101.639
_cell_angle_gamma   102.170
_symmetry_Int_Tables_number   1
_cell_volume   473.328
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.488  0.225  0.183  1.0
  H  H1  1  0.512  0.775  0.817  1.0
  H  H2  1  0.051  0.346  0.871  1.0
  H  H3  1  0.949  0.654  0.129  1.0
  H  H4  1  0.585  0.202  0.333  1.0
  H  H5  1  0.415  0.798  0.667  1.0
  H  H6  1  0.149  0.407  0.587  1.0
  H  H7  1  0.851  0.593  0.413  1.0
  H  H8  1  0.082  0.190  0.109  1.0
  H  H9  1  0.918  0.810  0.891  1.0
  H  H10  1  0.285  0.403  0.733  1.0
  H  H11  1  0.715  0.597  0.267  1.0
  H  H12  1  0.261  0.700  0.181  1.0
  H  H13  1  0.739  0.300  0.819  1.0
  H  H14  1  0.879  0.096  0.189  1.0
  H  H15  1  0.121  0.904  0.811  1.0
  Pd  Pd16  1  0.500  0.000  0.500  1.0
  C  C17  1  0.076  0.639  0.305  1.0
  C  C18  1  0.924  0.361  0.695  1.0
  C  C19  1  0.229  0.148  0.274  1.0
  C  C20  1  0.771  0.852  0.726  1.0
  S  S21  1  0.168  0.094  0.405  1.0
  S  S22  1  0.832  0.906  0.595  1.0
  S  S23  1  0.332  0.667  0.420  1.0
  S  S24  1  0.668  0.333  0.580  1.0
  N  N25  1  0.547  0.741  0.033  1.0
  N  N26  1  0.453  0.259  0.967  1.0
  N  N27  1  0.451  0.194  0.261  1.0
  N  N28  1  0.549  0.806  0.739  1.0
  N  N29  1  0.138  0.413  0.673  1.0
  N  N30  1  0.862  0.587  0.327  1.0
  N  N31  1  0.049  0.147  0.184  1.0
  N  N32  1  0.951  0.853  0.816  1.0
  N  N33  1  0.095  0.659  0.196  1.0
  N  N34  1  0.905  0.341  0.804  1.0
  O  O35  1  0.563  0.770  0.145  1.0
  O  O36  1  0.437  0.230  0.855  1.0
  O  O37  1  0.285  0.309  0.008  1.0
  O  O38  1  0.715  0.691  0.992  1.0
  O  O39  1  0.631  0.238  0.039  1.0
  O  O40  1  0.369  0.762  0.961  1.0
[/CIF]
.
The material described by PdC4H16(N2S)4(NO3)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two nitric acid molecules and one PdC4H16(N2S)4 cluster. In the PdC4H16(N2S)4 cluster, Pd(1) is bonded in a square co-planar geometry to two equivalent S(1) and two equivalent S(2) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one N(3), one N(5), and one S(2) atom. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one N(2), one N(4), and one S(1) atom. There are four inequivalent N sites. In the first N site, N(5) is bonded in a trigonal planar geometry to one C(1), one H(2), and one H(7) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(2), one H(1), and one H(3) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(1), one H(4), and one H(6) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(2), one H(5), and one H(8) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(5) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(4) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one N(5) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one N(4) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one Pd(1) and one C(2) atom. In the second S site, S(2) is bonded in a water-like geometry to one Pd(1) and one C(1) atom. is represented by the CIF file [CIF]
data_H16PdC4S4(N5O3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.931
_cell_length_b   7.313
_cell_length_c   11.669
_cell_angle_alpha   99.336
_cell_angle_beta   101.639
_cell_angle_gamma   102.170
_symmetry_Int_Tables_number   1
_cell_volume   473.328
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.488  0.225  0.183  1.0
  H  H1  1  0.512  0.775  0.817  1.0
  H  H2  1  0.051  0.346  0.871  1.0
  H  H3  1  0.949  0.654  0.129  1.0
  H  H4  1  0.585  0.202  0.333  1.0
  H  H5  1  0.415  0.798  0.667  1.0
  H  H6  1  0.149  0.407  0.587  1.0
  H  H7  1  0.851  0.593  0.413  1.0
  H  H8  1  0.082  0.190  0.109  1.0
  H  H9  1  0.918  0.810  0.891  1.0
  H  H10  1  0.285  0.403  0.733  1.0
  H  H11  1  0.715  0.597  0.267  1.0
  H  H12  1  0.261  0.700  0.181  1.0
  H  H13  1  0.739  0.300  0.819  1.0
  H  H14  1  0.879  0.096  0.189  1.0
  H  H15  1  0.121  0.904  0.811  1.0
  Pd  Pd16  1  0.500  0.000  0.500  1.0
  C  C17  1  0.076  0.639  0.305  1.0
  C  C18  1  0.924  0.361  0.695  1.0
  C  C19  1  0.229  0.148  0.274  1.0
  C  C20  1  0.771  0.852  0.726  1.0
  S  S21  1  0.168  0.094  0.405  1.0
  S  S22  1  0.832  0.906  0.595  1.0
  S  S23  1  0.332  0.667  0.420  1.0
  S  S24  1  0.668  0.333  0.580  1.0
  N  N25  1  0.547  0.741  0.033  1.0
  N  N26  1  0.453  0.259  0.967  1.0
  N  N27  1  0.451  0.194  0.261  1.0
  N  N28  1  0.549  0.806  0.739  1.0
  N  N29  1  0.138  0.413  0.673  1.0
  N  N30  1  0.862  0.587  0.327  1.0
  N  N31  1  0.049  0.147  0.184  1.0
  N  N32  1  0.951  0.853  0.816  1.0
  N  N33  1  0.095  0.659  0.196  1.0
  N  N34  1  0.905  0.341  0.804  1.0
  O  O35  1  0.563  0.770  0.145  1.0
  O  O36  1  0.437  0.230  0.855  1.0
  O  O37  1  0.285  0.309  0.008  1.0
  O  O38  1  0.715  0.691  0.992  1.0
  O  O39  1  0.631  0.238  0.039  1.0
  O  O40  1  0.369  0.762  0.961  1.0
[/CIF]
.