The structure described by Mn3Zn2AsO10O2 crystallizes in the monoclinic Cm space group. The structure consists of two hydrogen peroxide molecules inside a Mn3Zn2AsO10 framework. In the Mn3Zn2AsO10 framework, there are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(5), one O(6), two equivalent O(10), and two equivalent O(9) atoms to form MnO6 octahedra that share corners with two equivalent As(1)O4 tetrahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. In the second Mn site, Mn(2) is bonded to one O(2), one O(9), two equivalent O(5), and two equivalent O(7) atoms to form MnO6 octahedra that share edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and edges with two equivalent Zn(1)O5 trigonal bipyramids. In the third Mn site, Mn(3) is bonded in a 5-coordinate geometry to one O(1), two equivalent O(6), and two equivalent O(8) atoms. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(7), two equivalent O(2), and two equivalent O(3) atoms to form distorted ZnO5 trigonal bipyramids that share edges with two equivalent Mn(2)O6 octahedra and edges with two equivalent Zn(1)O5 trigonal bipyramids. In the second Zn site, Zn(2) is bonded in a linear geometry to one O(3) and one O(8) atom. As(1) is bonded to one O(1), one O(10), and two equivalent O(11) atoms to form AsO4 tetrahedra that share corners with two equivalent Mn(1)O6 octahedra and corners with two equivalent As(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 48°. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a linear geometry to one Mn(3) and one As(1) atom. In the second O site, O(2) is bonded in a distorted T-shaped geometry to one Mn(2) and two equivalent Zn(1) atoms. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Zn(2) and two equivalent Zn(1) atoms. In the fourth O site, O(5) is bonded in a distorted T-shaped geometry to one Mn(1) and two equivalent Mn(2) atoms. In the fifth O site, O(6) is bonded in a trigonal non-coplanar geometry to one Mn(1) and two equivalent Mn(3) atoms. In the sixth O site, O(7) is bonded in a distorted T-shaped geometry to two equivalent Mn(2) and one Zn(1) atom. In the seventh O site, O(8) is bonded in a trigonal planar geometry to two equivalent Mn(3) and one Zn(2) atom. In the eighth O site, O(9) is bonded in a distorted trigonal non-coplanar geometry to one Mn(2) and two equivalent Mn(1) atoms. In the ninth O site, O(10) is bonded in a 3-coordinate geometry to two equivalent Mn(1) and one As(1) atom. In the tenth O site, O(11) is bonded in a water-like geometry to two equivalent As(1) atoms. is represented by the CIF card [CIF]
data_Mn3Zn2AsO12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.997
_cell_length_b   7.793
_cell_length_c   12.400
_cell_angle_alpha   97.091
_cell_angle_beta   83.060
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   285.244
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.997  0.990  0.007  1.0
  Mn  Mn1  1  0.585  0.785  0.830  1.0
  Mn  Mn2  1  0.413  0.292  0.175  1.0
  Zn  Zn3  1  0.178  0.597  0.644  1.0
  Zn  Zn4  1  0.797  0.447  0.406  1.0
  As  As5  1  0.386  0.797  0.227  1.0
  O  O6  1  0.401  0.584  0.199  1.0
  O  O7  1  0.623  0.565  0.753  1.0
  O  O8  1  0.732  0.575  0.536  1.0
  O  O9  1  0.258  0.169  0.485  1.0
  O  O10  1  0.033  0.759  0.935  1.0
  O  O11  1  0.961  0.230  0.077  1.0
  O  O12  1  0.129  0.841  0.742  1.0
  O  O13  1  0.860  0.303  0.280  1.0
  O  O14  1  0.541  0.021  0.918  1.0
  O  O15  1  0.435  0.937  0.131  1.0
  O  O16  1  0.845  0.858  0.309  1.0
  O  O17  1  0.209  0.146  0.582  1.0
[/CIF]
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The structure described by Mn3Zn2AsO10O2 crystallizes in the monoclinic Cm space group. The structure consists of two hydrogen peroxide molecules inside a Mn3Zn2AsO10 framework. In the Mn3Zn2AsO10 framework, there are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(5), one O(6), two equivalent O(10), and two equivalent O(9) atoms to form MnO6 octahedra that share corners with two equivalent As(1)O4 tetrahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. In the second Mn site, Mn(2) is bonded to one O(2), one O(9), two equivalent O(5), and two equivalent O(7) atoms to form MnO6 octahedra that share edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and edges with two equivalent Zn(1)O5 trigonal bipyramids. In the third Mn site, Mn(3) is bonded in a 5-coordinate geometry to one O(1), two equivalent O(6), and two equivalent O(8) atoms. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(7), two equivalent O(2), and two equivalent O(3) atoms to form distorted ZnO5 trigonal bipyramids that share edges with two equivalent Mn(2)O6 octahedra and edges with two equivalent Zn(1)O5 trigonal bipyramids. In the second Zn site, Zn(2) is bonded in a linear geometry to one O(3) and one O(8) atom. As(1) is bonded to one O(1), one O(10), and two equivalent O(11) atoms to form AsO4 tetrahedra that share corners with two equivalent Mn(1)O6 octahedra and corners with two equivalent As(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 48°. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a linear geometry to one Mn(3) and one As(1) atom. In the second O site, O(2) is bonded in a distorted T-shaped geometry to one Mn(2) and two equivalent Zn(1) atoms. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Zn(2) and two equivalent Zn(1) atoms. In the fourth O site, O(5) is bonded in a distorted T-shaped geometry to one Mn(1) and two equivalent Mn(2) atoms. In the fifth O site, O(6) is bonded in a trigonal non-coplanar geometry to one Mn(1) and two equivalent Mn(3) atoms. In the sixth O site, O(7) is bonded in a distorted T-shaped geometry to two equivalent Mn(2) and one Zn(1) atom. In the seventh O site, O(8) is bonded in a trigonal planar geometry to two equivalent Mn(3) and one Zn(2) atom. In the eighth O site, O(9) is bonded in a distorted trigonal non-coplanar geometry to one Mn(2) and two equivalent Mn(1) atoms. In the ninth O site, O(10) is bonded in a 3-coordinate geometry to two equivalent Mn(1) and one As(1) atom. In the tenth O site, O(11) is bonded in a water-like geometry to two equivalent As(1) atoms. is represented by the CIF card [CIF]
data_Mn3Zn2AsO12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.997
_cell_length_b   7.793
_cell_length_c   12.400
_cell_angle_alpha   97.091
_cell_angle_beta   83.060
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   285.244
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.997  0.990  0.007  1.0
  Mn  Mn1  1  0.585  0.785  0.830  1.0
  Mn  Mn2  1  0.413  0.292  0.175  1.0
  Zn  Zn3  1  0.178  0.597  0.644  1.0
  Zn  Zn4  1  0.797  0.447  0.406  1.0
  As  As5  1  0.386  0.797  0.227  1.0
  O  O6  1  0.401  0.584  0.199  1.0
  O  O7  1  0.623  0.565  0.753  1.0
  O  O8  1  0.732  0.575  0.536  1.0
  O  O9  1  0.258  0.169  0.485  1.0
  O  O10  1  0.033  0.759  0.935  1.0
  O  O11  1  0.961  0.230  0.077  1.0
  O  O12  1  0.129  0.841  0.742  1.0
  O  O13  1  0.860  0.303  0.280  1.0
  O  O14  1  0.541  0.021  0.918  1.0
  O  O15  1  0.435  0.937  0.131  1.0
  O  O16  1  0.845  0.858  0.309  1.0
  O  O17  1  0.209  0.146  0.582  1.0
[/CIF]
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