The material structure described by Mn(PbN)4 crystallizes in the triclinic P-1 space group. Mn(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one N(3), and one N(4) atom. There are four inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a water-like geometry to one N(2) and one N(4) atom. In the second Pb site, Pb(2) is bonded in a 4-coordinate geometry to one N(3), one N(4), and two equivalent N(2) atoms. In the third Pb site, Pb(3) is bonded in an L-shaped geometry to one N(3) and one N(4) atom. In the fourth Pb site, Pb(4) is bonded in a distorted T-shaped geometry to one N(3) and two equivalent N(1) atoms. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted single-bond geometry to one Mn(1) and two equivalent Pb(4) atoms. In the second N site, N(2) is bonded in a distorted single-bond geometry to one Mn(1), one Pb(1), and two equivalent Pb(2) atoms. In the third N site, N(3) is bonded in a distorted single-bond geometry to one Mn(1), one Pb(2), one Pb(3), and one Pb(4) atom. In the fourth N site, N(4) is bonded in a 4-coordinate geometry to one Mn(1), one Pb(1), one Pb(2), and one Pb(3) atom. is represented by the CIF file [CIF]
data_Mn(PbN)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.337
_cell_length_b   6.443
_cell_length_c   9.334
_cell_angle_alpha   82.620
_cell_angle_beta   83.992
_cell_angle_gamma   69.878
_symmetry_Int_Tables_number   1
_cell_volume   354.161
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.731  0.914  0.790  1.0
  Mn  Mn1  1  0.269  0.086  0.210  1.0
  Pb  Pb2  1  0.807  0.628  0.177  1.0
  Pb  Pb3  1  0.193  0.372  0.823  1.0
  Pb  Pb4  1  0.725  0.231  0.014  1.0
  Pb  Pb5  1  0.275  0.769  0.986  1.0
  Pb  Pb6  1  0.719  0.472  0.625  1.0
  Pb  Pb7  1  0.281  0.528  0.375  1.0
  Pb  Pb8  1  0.241  0.991  0.592  1.0
  Pb  Pb9  1  0.759  0.009  0.408  1.0
  N  N10  1  0.937  0.850  0.655  1.0
  N  N11  1  0.063  0.150  0.345  1.0
  N  N12  1  0.843  0.862  0.963  1.0
  N  N13  1  0.157  0.138  0.037  1.0
  N  N14  1  0.550  0.767  0.780  1.0
  N  N15  1  0.450  0.233  0.220  1.0
  N  N16  1  0.417  0.797  0.228  1.0
  N  N17  1  0.583  0.203  0.772  1.0
[/CIF]
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The material structure described by Mn(PbN)4 crystallizes in the triclinic P-1 space group. Mn(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one N(3), and one N(4) atom. There are four inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a water-like geometry to one N(2) and one N(4) atom. In the second Pb site, Pb(2) is bonded in a 4-coordinate geometry to one N(3), one N(4), and two equivalent N(2) atoms. In the third Pb site, Pb(3) is bonded in an L-shaped geometry to one N(3) and one N(4) atom. In the fourth Pb site, Pb(4) is bonded in a distorted T-shaped geometry to one N(3) and two equivalent N(1) atoms. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted single-bond geometry to one Mn(1) and two equivalent Pb(4) atoms. In the second N site, N(2) is bonded in a distorted single-bond geometry to one Mn(1), one Pb(1), and two equivalent Pb(2) atoms. In the third N site, N(3) is bonded in a distorted single-bond geometry to one Mn(1), one Pb(2), one Pb(3), and one Pb(4) atom. In the fourth N site, N(4) is bonded in a 4-coordinate geometry to one Mn(1), one Pb(1), one Pb(2), and one Pb(3) atom. is represented by the CIF file [CIF]
data_Mn(PbN)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.337
_cell_length_b   6.443
_cell_length_c   9.334
_cell_angle_alpha   82.620
_cell_angle_beta   83.992
_cell_angle_gamma   69.878
_symmetry_Int_Tables_number   1
_cell_volume   354.161
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.731  0.914  0.790  1.0
  Mn  Mn1  1  0.269  0.086  0.210  1.0
  Pb  Pb2  1  0.807  0.628  0.177  1.0
  Pb  Pb3  1  0.193  0.372  0.823  1.0
  Pb  Pb4  1  0.725  0.231  0.014  1.0
  Pb  Pb5  1  0.275  0.769  0.986  1.0
  Pb  Pb6  1  0.719  0.472  0.625  1.0
  Pb  Pb7  1  0.281  0.528  0.375  1.0
  Pb  Pb8  1  0.241  0.991  0.592  1.0
  Pb  Pb9  1  0.759  0.009  0.408  1.0
  N  N10  1  0.937  0.850  0.655  1.0
  N  N11  1  0.063  0.150  0.345  1.0
  N  N12  1  0.843  0.862  0.963  1.0
  N  N13  1  0.157  0.138  0.037  1.0
  N  N14  1  0.550  0.767  0.780  1.0
  N  N15  1  0.450  0.233  0.220  1.0
  N  N16  1  0.417  0.797  0.228  1.0
  N  N17  1  0.583  0.203  0.772  1.0
[/CIF]
.