The compound described by VOF is alpha bismuth trifluoride-derived structured and crystallizes in the trigonal R-3m space group. V(1) is bonded in a body-centered cubic geometry to four equivalent O(1) and four equivalent F(1) atoms. O(1) is bonded to four equivalent V(1) atoms to form OV4 tetrahedra that share corners with six equivalent O(1)V4 tetrahedra, corners with ten equivalent F(1)V4 tetrahedra, edges with three equivalent O(1)V4 tetrahedra, and edges with three equivalent F(1)V4 tetrahedra. F(1) is bonded to four equivalent V(1) atoms to form FV4 tetrahedra that share corners with six equivalent F(1)V4 tetrahedra, corners with ten equivalent O(1)V4 tetrahedra, edges with three equivalent O(1)V4 tetrahedra, and edges with three equivalent F(1)V4 tetrahedra. is represented by the CIF file [CIF]
data_VOF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.441
_cell_length_b   3.441
_cell_length_c   6.340
_cell_angle_alpha   74.254
_cell_angle_beta   90.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   61.726
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.761  0.479  0.282  1.0
  V  V1  1  0.239  0.521  0.718  1.0
  O  O2  1  0.875  0.250  0.625  1.0
  O  O3  1  0.125  0.750  0.375  1.0
  F  F4  1  0.627  0.747  0.880  1.0
  F  F5  1  0.373  0.253  0.120  1.0
[/CIF]
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The compound described by VOF is alpha bismuth trifluoride-derived structured and crystallizes in the trigonal R-3m space group. V(1) is bonded in a body-centered cubic geometry to four equivalent O(1) and four equivalent F(1) atoms. O(1) is bonded to four equivalent V(1) atoms to form OV4 tetrahedra that share corners with six equivalent O(1)V4 tetrahedra, corners with ten equivalent F(1)V4 tetrahedra, edges with three equivalent O(1)V4 tetrahedra, and edges with three equivalent F(1)V4 tetrahedra. F(1) is bonded to four equivalent V(1) atoms to form FV4 tetrahedra that share corners with six equivalent F(1)V4 tetrahedra, corners with ten equivalent O(1)V4 tetrahedra, edges with three equivalent O(1)V4 tetrahedra, and edges with three equivalent F(1)V4 tetrahedra. is represented by the CIF file [CIF]
data_VOF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.441
_cell_length_b   3.441
_cell_length_c   6.340
_cell_angle_alpha   74.254
_cell_angle_beta   90.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   61.726
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.761  0.479  0.282  1.0
  V  V1  1  0.239  0.521  0.718  1.0
  O  O2  1  0.875  0.250  0.625  1.0
  O  O3  1  0.125  0.750  0.375  1.0
  F  F4  1  0.627  0.747  0.880  1.0
  F  F5  1  0.373  0.253  0.120  1.0
[/CIF]
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