The material structure described by V4ZnO10 crystallizes in the orthorhombic Amm2 space group. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(2), one O(3), one O(5), and two equivalent O(4) atoms to form distorted corner-sharing VO5 trigonal bipyramids. In the second V site, V(2) is bonded in a 5-coordinate geometry to one O(1), one O(4), one O(6), and two equivalent O(3) atoms. Zn(1) is bonded in a 6-coordinate geometry to two equivalent O(2), two equivalent O(4), and two equivalent O(5) atoms. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to two equivalent V(2) atoms. In the second O site, O(2) is bonded to two equivalent V(1) and two equivalent Zn(1) atoms to form corner-sharing OV2Zn2 tetrahedra. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one V(1) and two equivalent V(2) atoms. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one V(2), two equivalent V(1), and one Zn(1) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one V(1) and one Zn(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one V(2) atom. is represented by the CIF file [CIF]
data_V4ZnO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.645
_cell_length_b   5.459
_cell_length_c   11.478
_cell_angle_alpha   89.979
_cell_angle_beta   90.000
_cell_angle_gamma   70.500
_symmetry_Int_Tables_number   1
_cell_volume   215.278
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.799  0.402  0.901  1.0
  V  V1  1  0.209  0.582  0.103  1.0
  V  V2  1  0.799  0.402  0.599  1.0
  V  V3  1  0.209  0.582  0.397  1.0
  Zn  Zn4  1  0.101  0.799  0.750  1.0
  O  O5  1  0.274  0.452  0.250  1.0
  O  O6  1  0.699  0.603  0.750  1.0
  O  O7  1  0.758  0.484  0.070  1.0
  O  O8  1  0.758  0.484  0.430  1.0
  O  O9  1  0.237  0.526  0.927  1.0
  O  O10  1  0.237  0.526  0.573  1.0
  O  O11  1  0.958  0.085  0.630  1.0
  O  O12  1  0.957  0.085  0.870  1.0
  O  O13  1  0.055  0.891  0.381  1.0
  O  O14  1  0.055  0.891  0.119  1.0
[/CIF]
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The material structure described by V4ZnO10 crystallizes in the orthorhombic Amm2 space group. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(2), one O(3), one O(5), and two equivalent O(4) atoms to form distorted corner-sharing VO5 trigonal bipyramids. In the second V site, V(2) is bonded in a 5-coordinate geometry to one O(1), one O(4), one O(6), and two equivalent O(3) atoms. Zn(1) is bonded in a 6-coordinate geometry to two equivalent O(2), two equivalent O(4), and two equivalent O(5) atoms. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to two equivalent V(2) atoms. In the second O site, O(2) is bonded to two equivalent V(1) and two equivalent Zn(1) atoms to form corner-sharing OV2Zn2 tetrahedra. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one V(1) and two equivalent V(2) atoms. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one V(2), two equivalent V(1), and one Zn(1) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one V(1) and one Zn(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one V(2) atom. is represented by the CIF file [CIF]
data_V4ZnO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.645
_cell_length_b   5.459
_cell_length_c   11.478
_cell_angle_alpha   89.979
_cell_angle_beta   90.000
_cell_angle_gamma   70.500
_symmetry_Int_Tables_number   1
_cell_volume   215.278
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.799  0.402  0.901  1.0
  V  V1  1  0.209  0.582  0.103  1.0
  V  V2  1  0.799  0.402  0.599  1.0
  V  V3  1  0.209  0.582  0.397  1.0
  Zn  Zn4  1  0.101  0.799  0.750  1.0
  O  O5  1  0.274  0.452  0.250  1.0
  O  O6  1  0.699  0.603  0.750  1.0
  O  O7  1  0.758  0.484  0.070  1.0
  O  O8  1  0.758  0.484  0.430  1.0
  O  O9  1  0.237  0.526  0.927  1.0
  O  O10  1  0.237  0.526  0.573  1.0
  O  O11  1  0.958  0.085  0.630  1.0
  O  O12  1  0.957  0.085  0.870  1.0
  O  O13  1  0.055  0.891  0.381  1.0
  O  O14  1  0.055  0.891  0.119  1.0
[/CIF]
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