The material described by Re5Co2B4 crystallizes in the orthorhombic Cmmm space group. There are three inequivalent Re sites. In the first Re site, Re(1) is bonded in a 5-coordinate geometry to one B(1), two equivalent B(2), and two equivalent B(3) atoms. In the second Re site, Re(2) is bonded in a 5-coordinate geometry to one B(2), two equivalent B(1), and two equivalent B(3) atoms. In the third Re site, Re(3) is bonded in a 4-coordinate geometry to four equivalent B(3) atoms. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a square co-planar geometry to two equivalent B(1) and two equivalent B(2) atoms. In the second Co site, Co(2) is bonded in a 4-coordinate geometry to four equivalent B(3) atoms. There are three inequivalent B sites. In the first B site, B(3) is bonded in a 9-coordinate geometry to two equivalent Re(1), two equivalent Re(2), two equivalent Re(3), two equivalent Co(2), and one B(3) atom. In the second B site, B(1) is bonded in a 9-coordinate geometry to two equivalent Re(1), four equivalent Re(2), two equivalent Co(1), and one B(1) atom. In the third B site, B(2) is bonded in a 9-coordinate geometry to two equivalent Re(2), four equivalent Re(1), two equivalent Co(1), and one B(2) atom. is represented by the CIF card [CIF]
data_Co2Re5B4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.381
_cell_length_b   5.381
_cell_length_c   8.097
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.026
_symmetry_Int_Tables_number   1
_cell_volume   234.467
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.000  0.500  0.500  1.0
  Co  Co1  1  0.500  0.000  0.500  1.0
  Co  Co2  1  0.838  0.838  0.000  1.0
  Co  Co3  1  0.162  0.162  0.000  1.0
  Re  Re4  1  0.677  0.677  0.717  1.0
  Re  Re5  1  0.323  0.323  0.717  1.0
  Re  Re6  1  0.827  0.173  0.716  1.0
  Re  Re7  1  0.173  0.827  0.716  1.0
  Re  Re8  1  0.323  0.323  0.283  1.0
  Re  Re9  1  0.677  0.677  0.283  1.0
  Re  Re10  1  0.173  0.827  0.284  1.0
  Re  Re11  1  0.827  0.173  0.284  1.0
  Re  Re12  1  0.665  0.335  0.000  1.0
  Re  Re13  1  0.335  0.665  0.000  1.0
  B  B14  1  0.877  0.877  0.500  1.0
  B  B15  1  0.123  0.123  0.500  1.0
  B  B16  1  0.621  0.379  0.500  1.0
  B  B17  1  0.379  0.621  0.500  1.0
  B  B18  1  0.000  0.500  0.864  1.0
  B  B19  1  0.500  0.000  0.864  1.0
  B  B20  1  0.000  0.500  0.136  1.0
  B  B21  1  0.500  0.000  0.136  1.0
[/CIF]
.
The material described by Re5Co2B4 crystallizes in the orthorhombic Cmmm space group. There are three inequivalent Re sites. In the first Re site, Re(1) is bonded in a 5-coordinate geometry to one B(1), two equivalent B(2), and two equivalent B(3) atoms. In the second Re site, Re(2) is bonded in a 5-coordinate geometry to one B(2), two equivalent B(1), and two equivalent B(3) atoms. In the third Re site, Re(3) is bonded in a 4-coordinate geometry to four equivalent B(3) atoms. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a square co-planar geometry to two equivalent B(1) and two equivalent B(2) atoms. In the second Co site, Co(2) is bonded in a 4-coordinate geometry to four equivalent B(3) atoms. There are three inequivalent B sites. In the first B site, B(3) is bonded in a 9-coordinate geometry to two equivalent Re(1), two equivalent Re(2), two equivalent Re(3), two equivalent Co(2), and one B(3) atom. In the second B site, B(1) is bonded in a 9-coordinate geometry to two equivalent Re(1), four equivalent Re(2), two equivalent Co(1), and one B(1) atom. In the third B site, B(2) is bonded in a 9-coordinate geometry to two equivalent Re(2), four equivalent Re(1), two equivalent Co(1), and one B(2) atom. is represented by the CIF card [CIF]
data_Co2Re5B4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.381
_cell_length_b   5.381
_cell_length_c   8.097
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.026
_symmetry_Int_Tables_number   1
_cell_volume   234.467
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.000  0.500  0.500  1.0
  Co  Co1  1  0.500  0.000  0.500  1.0
  Co  Co2  1  0.838  0.838  0.000  1.0
  Co  Co3  1  0.162  0.162  0.000  1.0
  Re  Re4  1  0.677  0.677  0.717  1.0
  Re  Re5  1  0.323  0.323  0.717  1.0
  Re  Re6  1  0.827  0.173  0.716  1.0
  Re  Re7  1  0.173  0.827  0.716  1.0
  Re  Re8  1  0.323  0.323  0.283  1.0
  Re  Re9  1  0.677  0.677  0.283  1.0
  Re  Re10  1  0.173  0.827  0.284  1.0
  Re  Re11  1  0.827  0.173  0.284  1.0
  Re  Re12  1  0.665  0.335  0.000  1.0
  Re  Re13  1  0.335  0.665  0.000  1.0
  B  B14  1  0.877  0.877  0.500  1.0
  B  B15  1  0.123  0.123  0.500  1.0
  B  B16  1  0.621  0.379  0.500  1.0
  B  B17  1  0.379  0.621  0.500  1.0
  B  B18  1  0.000  0.500  0.864  1.0
  B  B19  1  0.500  0.000  0.864  1.0
  B  B20  1  0.000  0.500  0.136  1.0
  B  B21  1  0.500  0.000  0.136  1.0
[/CIF]
.