The structure described by Bi is alpha Po-like structured and crystallizes in the monoclinic P2/m space group. Bi(1) is bonded to six equivalent Bi(1) atoms to form a mixture of corner and edge-sharing BiBi6 octahedra. The corner-sharing octahedral tilt angles range from 0-10°. is represented by the CIF card [CIF]
data_Bi
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.238
_cell_length_b   3.222
_cell_length_c   6.444
_cell_angle_alpha   90.000
_cell_angle_beta   90.715
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   67.228
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.456  0.000  0.250  1.0
  Bi  Bi1  1  0.544  0.000  0.750  1.0
[/CIF]
.
The structure described by Bi is alpha Po-like structured and crystallizes in the monoclinic P2/m space group. Bi(1) is bonded to six equivalent Bi(1) atoms to form a mixture of corner and edge-sharing BiBi6 octahedra. The corner-sharing octahedral tilt angles range from 0-10°. is represented by the CIF card [CIF]
data_Bi
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.238
_cell_length_b   3.222
_cell_length_c   6.444
_cell_angle_alpha   90.000
_cell_angle_beta   90.715
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   67.228
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.456  0.000  0.250  1.0
  Bi  Bi1  1  0.544  0.000  0.750  1.0
[/CIF]
.