The crystal structure described by MnWO4 crystallizes in the tetragonal I-4m2 space group. W(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles are 7°. Mn(1) is bonded in a 6-coordinate geometry to two equivalent O(2) and four equivalent O(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one W(1) and two equivalent Mn(1) atoms. In the second O site, O(2) is bonded in a distorted T-shaped geometry to two equivalent W(1) and one Mn(1) atom. is represented by the CIF file [CIF]
data_MnWO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.882
_cell_length_b   3.882
_cell_length_c   6.218
_cell_angle_alpha   108.188
_cell_angle_beta   108.188
_cell_angle_gamma   90.001
_symmetry_Int_Tables_number   1
_cell_volume   84.091
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  1.000  0.000  1.000  1.0
  O  O1  1  0.922  0.422  0.845  1.0
  O  O2  1  0.578  0.078  0.155  1.0
  O  O3  1  0.761  0.761  0.522  1.0
  O  O4  1  0.239  0.239  0.478  1.0
  W  W5  1  0.750  0.250  0.500  1.0
[/CIF]
.
The crystal structure described by MnWO4 crystallizes in the tetragonal I-4m2 space group. W(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles are 7°. Mn(1) is bonded in a 6-coordinate geometry to two equivalent O(2) and four equivalent O(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one W(1) and two equivalent Mn(1) atoms. In the second O site, O(2) is bonded in a distorted T-shaped geometry to two equivalent W(1) and one Mn(1) atom. is represented by the CIF file [CIF]
data_MnWO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.882
_cell_length_b   3.882
_cell_length_c   6.218
_cell_angle_alpha   108.188
_cell_angle_beta   108.188
_cell_angle_gamma   90.001
_symmetry_Int_Tables_number   1
_cell_volume   84.091
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  1.000  0.000  1.000  1.0
  O  O1  1  0.922  0.422  0.845  1.0
  O  O2  1  0.578  0.078  0.155  1.0
  O  O3  1  0.761  0.761  0.522  1.0
  O  O4  1  0.239  0.239  0.478  1.0
  W  W5  1  0.750  0.250  0.500  1.0
[/CIF]
.