The compound described by LiPu2TeO2 crystallizes in the tetragonal I4/mmm space group. Li(1) is bonded to two equivalent Pu(1) and four equivalent Te(1) atoms to form LiPu2Te4 octahedra that share corners with four equivalent Li(1)Pu2Te4 octahedra, corners with eight equivalent O(1)Pu4 tetrahedra, and edges with four equivalent Li(1)Pu2Te4 octahedra. The corner-sharing octahedra are not tilted. Pu(1) is bonded in a 4-coordinate geometry to one Li(1) and four equivalent O(1) atoms. Te(1) is bonded in a square co-planar geometry to four equivalent Li(1) atoms. O(1) is bonded to four equivalent Pu(1) atoms to form OPu4 tetrahedra that share corners with four equivalent Li(1)Pu2Te4 octahedra, corners with four equivalent O(1)Pu4 tetrahedra, and edges with four equivalent O(1)Pu4 tetrahedra. The corner-sharing octahedral tilt angles are 61°. is represented by the CIF card [CIF]
data_LiPu2TeO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.011
_cell_length_b   4.011
_cell_length_c   8.477
_cell_angle_alpha   103.686
_cell_angle_beta   103.686
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   128.549
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.500  0.500  0.000  1.0
  Pu  Pu1  1  0.320  0.320  0.640  1.0
  Pu  Pu2  1  0.680  0.680  0.360  1.0
  Te  Te3  1  0.000  0.000  0.000  1.0
  O  O4  1  0.250  0.750  0.500  1.0
  O  O5  1  0.750  0.250  0.500  1.0
[/CIF]
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The compound described by LiPu2TeO2 crystallizes in the tetragonal I4/mmm space group. Li(1) is bonded to two equivalent Pu(1) and four equivalent Te(1) atoms to form LiPu2Te4 octahedra that share corners with four equivalent Li(1)Pu2Te4 octahedra, corners with eight equivalent O(1)Pu4 tetrahedra, and edges with four equivalent Li(1)Pu2Te4 octahedra. The corner-sharing octahedra are not tilted. Pu(1) is bonded in a 4-coordinate geometry to one Li(1) and four equivalent O(1) atoms. Te(1) is bonded in a square co-planar geometry to four equivalent Li(1) atoms. O(1) is bonded to four equivalent Pu(1) atoms to form OPu4 tetrahedra that share corners with four equivalent Li(1)Pu2Te4 octahedra, corners with four equivalent O(1)Pu4 tetrahedra, and edges with four equivalent O(1)Pu4 tetrahedra. The corner-sharing octahedral tilt angles are 61°. is represented by the CIF card [CIF]
data_LiPu2TeO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.011
_cell_length_b   4.011
_cell_length_c   8.477
_cell_angle_alpha   103.686
_cell_angle_beta   103.686
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   128.549
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.500  0.500  0.000  1.0
  Pu  Pu1  1  0.320  0.320  0.640  1.0
  Pu  Pu2  1  0.680  0.680  0.360  1.0
  Te  Te3  1  0.000  0.000  0.000  1.0
  O  O4  1  0.250  0.750  0.500  1.0
  O  O5  1  0.750  0.250  0.500  1.0
[/CIF]
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