The compound described by Cu(TeO3)4 crystallizes in the triclinic P1 space group. Cu(1) is bonded in a 6-coordinate geometry to one O(1), one O(11), one O(4), one O(7), one O(8), and one O(9) atom. There are four inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(10), one O(11), one O(2), one O(3), one O(5), and one O(8) atom to form corner-sharing TeO6 octahedra. The corner-sharing octahedral tilt angles range from 32-40°. In the second Te site, Te(2) is bonded to one O(1), one O(12), one O(4), one O(6), one O(7), and one O(9) atom to form corner-sharing TeO6 octahedra. The corner-sharing octahedral tilt angles range from 35-42°. In the third Te site, Te(3) is bonded to one O(1), one O(11), one O(12), one O(2), one O(4), and one O(9) atom to form corner-sharing TeO6 octahedra. The corner-sharing octahedral tilt angles range from 32-42°. In the fourth Te site, Te(4) is bonded to one O(10), one O(3), one O(5), one O(6), one O(7), and one O(8) atom to form corner-sharing TeO6 octahedra. The corner-sharing octahedral tilt angles range from 33-41°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one Cu(1), one Te(2), and one Te(3) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Te(1) and one Te(3) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Te(1) and one Te(4) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Cu(1), one Te(2), and one Te(3) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Te(1) and one Te(4) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one Te(2) and one Te(4) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to one Cu(1), one Te(2), and one Te(4) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to one Cu(1), one Te(1), and one Te(4) atom. In the ninth O site, O(9) is bonded in a distorted T-shaped geometry to one Cu(1), one Te(2), and one Te(3) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one Te(1) and one Te(4) atom. In the eleventh O site, O(11) is bonded in a distorted T-shaped geometry to one Cu(1), one Te(1), and one Te(3) atom. In the twelfth O site, O(12) is bonded in a bent 150 degrees geometry to one Te(2) and one Te(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Cu(TeO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.217
_cell_length_b   5.431
_cell_length_c   7.543
_cell_angle_alpha   86.947
_cell_angle_beta   89.877
_cell_angle_gamma   89.895
_symmetry_Int_Tables_number   1
_cell_volume   213.446
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cu  Cu0  1  0.001  0.522  0.255  1.0
  Te  Te1  1  0.002  0.983  0.982  1.0
  Te  Te2  1  0.499  0.477  0.498  1.0
  Te  Te3  1  0.004  0.976  0.494  1.0
  Te  Te4  1  0.497  0.473  0.981  1.0
  O  O5  1  0.698  0.776  0.428  1.0
  O  O6  1  0.876  0.978  0.738  1.0
  O  O7  1  0.694  0.173  0.048  1.0
  O  O8  1  0.814  0.292  0.421  1.0
  O  O9  1  0.189  0.288  0.927  1.0
  O  O10  1  0.627  0.475  0.739  1.0
  O  O11  1  0.374  0.472  0.239  1.0
  O  O12  1  0.810  0.664  0.051  1.0
  O  O13  1  0.186  0.660  0.545  1.0
  O  O14  1  0.306  0.781  0.928  1.0
  O  O15  1  0.109  0.964  0.237  1.0
  O  O16  1  0.314  0.165  0.546  1.0
[/CIF]
.
The compound described by Cu(TeO3)4 crystallizes in the triclinic P1 space group. Cu(1) is bonded in a 6-coordinate geometry to one O(1), one O(11), one O(4), one O(7), one O(8), and one O(9) atom. There are four inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(10), one O(11), one O(2), one O(3), one O(5), and one O(8) atom to form corner-sharing TeO6 octahedra. The corner-sharing octahedral tilt angles range from 32-40°. In the second Te site, Te(2) is bonded to one O(1), one O(12), one O(4), one O(6), one O(7), and one O(9) atom to form corner-sharing TeO6 octahedra. The corner-sharing octahedral tilt angles range from 35-42°. In the third Te site, Te(3) is bonded to one O(1), one O(11), one O(12), one O(2), one O(4), and one O(9) atom to form corner-sharing TeO6 octahedra. The corner-sharing octahedral tilt angles range from 32-42°. In the fourth Te site, Te(4) is bonded to one O(10), one O(3), one O(5), one O(6), one O(7), and one O(8) atom to form corner-sharing TeO6 octahedra. The corner-sharing octahedral tilt angles range from 33-41°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one Cu(1), one Te(2), and one Te(3) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Te(1) and one Te(3) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Te(1) and one Te(4) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Cu(1), one Te(2), and one Te(3) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Te(1) and one Te(4) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one Te(2) and one Te(4) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to one Cu(1), one Te(2), and one Te(4) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to one Cu(1), one Te(1), and one Te(4) atom. In the ninth O site, O(9) is bonded in a distorted T-shaped geometry to one Cu(1), one Te(2), and one Te(3) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one Te(1) and one Te(4) atom. In the eleventh O site, O(11) is bonded in a distorted T-shaped geometry to one Cu(1), one Te(1), and one Te(3) atom. In the twelfth O site, O(12) is bonded in a bent 150 degrees geometry to one Te(2) and one Te(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Cu(TeO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.217
_cell_length_b   5.431
_cell_length_c   7.543
_cell_angle_alpha   86.947
_cell_angle_beta   89.877
_cell_angle_gamma   89.895
_symmetry_Int_Tables_number   1
_cell_volume   213.446
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cu  Cu0  1  0.001  0.522  0.255  1.0
  Te  Te1  1  0.002  0.983  0.982  1.0
  Te  Te2  1  0.499  0.477  0.498  1.0
  Te  Te3  1  0.004  0.976  0.494  1.0
  Te  Te4  1  0.497  0.473  0.981  1.0
  O  O5  1  0.698  0.776  0.428  1.0
  O  O6  1  0.876  0.978  0.738  1.0
  O  O7  1  0.694  0.173  0.048  1.0
  O  O8  1  0.814  0.292  0.421  1.0
  O  O9  1  0.189  0.288  0.927  1.0
  O  O10  1  0.627  0.475  0.739  1.0
  O  O11  1  0.374  0.472  0.239  1.0
  O  O12  1  0.810  0.664  0.051  1.0
  O  O13  1  0.186  0.660  0.545  1.0
  O  O14  1  0.306  0.781  0.928  1.0
  O  O15  1  0.109  0.964  0.237  1.0
  O  O16  1  0.314  0.165  0.546  1.0
[/CIF]
.