The material described by CoP4F12 is gamma plutonium structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four CoP4F12 clusters. Co(1) is bonded in a tetrahedral geometry to two equivalent P(1) and two equivalent P(2) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 3-coordinate geometry to one Co(1), one F(1), one F(2), and one F(3) atom. In the second P site, P(2) is bonded in a 3-coordinate geometry to one Co(1), one F(4), one F(5), and one F(6) atom. There are six inequivalent F sites. In the first F site, F(4) is bonded in a single-bond geometry to one P(2) atom. In the second F site, F(5) is bonded in a single-bond geometry to one P(2) atom. In the third F site, F(6) is bonded in a single-bond geometry to one P(2) atom. In the fourth F site, F(1) is bonded in a single-bond geometry to one P(1) atom. In the fifth F site, F(2) is bonded in a single-bond geometry to one P(1) atom. In the sixth F site, F(3) is bonded in a single-bond geometry to one P(1) atom. is represented by the CIF file [CIF]
data_CoP4F12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.875
_cell_length_b   7.875
_cell_length_c   13.034
_cell_angle_alpha   65.813
_cell_angle_beta   65.813
_cell_angle_gamma   60.613
_symmetry_Int_Tables_number   1
_cell_volume   619.890
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.603  0.397  0.250  1.0
  Co  Co1  1  0.397  0.603  0.750  1.0
  P  P2  1  0.725  0.242  0.398  1.0
  P  P3  1  0.758  0.275  0.102  1.0
  P  P4  1  0.275  0.758  0.602  1.0
  P  P5  1  0.242  0.725  0.898  1.0
  P  P6  1  0.570  0.707  0.193  1.0
  P  P7  1  0.293  0.430  0.307  1.0
  P  P8  1  0.430  0.293  0.807  1.0
  P  P9  1  0.707  0.570  0.693  1.0
  F  F10  1  0.772  0.360  0.449  1.0
  F  F11  1  0.640  0.228  0.051  1.0
  F  F12  1  0.228  0.640  0.551  1.0
  F  F13  1  0.360  0.772  0.949  1.0
  F  F14  1  0.600  0.141  0.516  1.0
  F  F15  1  0.859  0.400  0.984  1.0
  F  F16  1  0.400  0.859  0.484  1.0
  F  F17  1  0.141  0.600  0.016  1.0
  F  F18  1  0.935  0.055  0.391  1.0
  F  F19  1  0.945  0.065  0.109  1.0
  F  F20  1  0.065  0.945  0.609  1.0
  F  F21  1  0.055  0.935  0.891  1.0
  F  F22  1  0.358  0.888  0.213  1.0
  F  F23  1  0.112  0.642  0.287  1.0
  F  F24  1  0.642  0.112  0.787  1.0
  F  F25  1  0.888  0.358  0.713  1.0
  F  F26  1  0.685  0.765  0.241  1.0
  F  F27  1  0.235  0.315  0.259  1.0
  F  F28  1  0.315  0.235  0.759  1.0
  F  F29  1  0.765  0.685  0.741  1.0
  F  F30  1  0.654  0.799  0.059  1.0
  F  F31  1  0.201  0.346  0.441  1.0
  F  F32  1  0.346  0.201  0.941  1.0
  F  F33  1  0.799  0.654  0.559  1.0
[/CIF]
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The material described by CoP4F12 is gamma plutonium structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four CoP4F12 clusters. Co(1) is bonded in a tetrahedral geometry to two equivalent P(1) and two equivalent P(2) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 3-coordinate geometry to one Co(1), one F(1), one F(2), and one F(3) atom. In the second P site, P(2) is bonded in a 3-coordinate geometry to one Co(1), one F(4), one F(5), and one F(6) atom. There are six inequivalent F sites. In the first F site, F(4) is bonded in a single-bond geometry to one P(2) atom. In the second F site, F(5) is bonded in a single-bond geometry to one P(2) atom. In the third F site, F(6) is bonded in a single-bond geometry to one P(2) atom. In the fourth F site, F(1) is bonded in a single-bond geometry to one P(1) atom. In the fifth F site, F(2) is bonded in a single-bond geometry to one P(1) atom. In the sixth F site, F(3) is bonded in a single-bond geometry to one P(1) atom. is represented by the CIF file [CIF]
data_CoP4F12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.875
_cell_length_b   7.875
_cell_length_c   13.034
_cell_angle_alpha   65.813
_cell_angle_beta   65.813
_cell_angle_gamma   60.613
_symmetry_Int_Tables_number   1
_cell_volume   619.890
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.603  0.397  0.250  1.0
  Co  Co1  1  0.397  0.603  0.750  1.0
  P  P2  1  0.725  0.242  0.398  1.0
  P  P3  1  0.758  0.275  0.102  1.0
  P  P4  1  0.275  0.758  0.602  1.0
  P  P5  1  0.242  0.725  0.898  1.0
  P  P6  1  0.570  0.707  0.193  1.0
  P  P7  1  0.293  0.430  0.307  1.0
  P  P8  1  0.430  0.293  0.807  1.0
  P  P9  1  0.707  0.570  0.693  1.0
  F  F10  1  0.772  0.360  0.449  1.0
  F  F11  1  0.640  0.228  0.051  1.0
  F  F12  1  0.228  0.640  0.551  1.0
  F  F13  1  0.360  0.772  0.949  1.0
  F  F14  1  0.600  0.141  0.516  1.0
  F  F15  1  0.859  0.400  0.984  1.0
  F  F16  1  0.400  0.859  0.484  1.0
  F  F17  1  0.141  0.600  0.016  1.0
  F  F18  1  0.935  0.055  0.391  1.0
  F  F19  1  0.945  0.065  0.109  1.0
  F  F20  1  0.065  0.945  0.609  1.0
  F  F21  1  0.055  0.935  0.891  1.0
  F  F22  1  0.358  0.888  0.213  1.0
  F  F23  1  0.112  0.642  0.287  1.0
  F  F24  1  0.642  0.112  0.787  1.0
  F  F25  1  0.888  0.358  0.713  1.0
  F  F26  1  0.685  0.765  0.241  1.0
  F  F27  1  0.235  0.315  0.259  1.0
  F  F28  1  0.315  0.235  0.759  1.0
  F  F29  1  0.765  0.685  0.741  1.0
  F  F30  1  0.654  0.799  0.059  1.0
  F  F31  1  0.201  0.346  0.441  1.0
  F  F32  1  0.346  0.201  0.941  1.0
  F  F33  1  0.799  0.654  0.559  1.0
[/CIF]
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