The structure described by RuN6Re3O14 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four hexaami-noruthenium molecules and four Re3O14 clusters. In each Re3O14 cluster, there are two inequivalent Re sites. In the first Re site, Re(1) is bonded to one O(1), one O(3), one O(4), one O(5), and one O(6) atom to form distorted corner-sharing ReO5 trigonal bipyramids. In the second Re site, Re(2) is bonded to two equivalent O(1) and two equivalent O(7) atoms to form corner-sharing ReO4 tetrahedra. There are seven inequivalent O sites. In the first O site, O(7) is bonded in a single-bond geometry to one Re(2) atom. In the second O site, O(1) is bonded in a bent 120 degrees geometry to one Re(1) and one Re(2) atom. In the third O site, O(2) is bonded in a single-bond geometry to one O(3) atom. In the fourth O site, O(3) is bonded in a bent 120 degrees geometry to one Re(1) and one O(2) atom. In the fifth O site, O(4) is bonded in a single-bond geometry to one Re(1) atom. In the sixth O site, O(5) is bonded in a single-bond geometry to one Re(1) atom. In the seventh O site, O(6) is bonded in a single-bond geometry to one Re(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Re3Ru(N3O7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.913
_cell_length_b   7.913
_cell_length_c   16.067
_cell_angle_alpha   101.857
_cell_angle_beta   101.857
_cell_angle_gamma   90.550
_symmetry_Int_Tables_number   1
_cell_volume   962.228
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.128  0.489  0.155  1.0
  Re  Re1  1  0.511  0.872  0.345  1.0
  Re  Re2  1  0.872  0.511  0.845  1.0
  Re  Re3  1  0.489  0.128  0.655  1.0
  Re  Re4  1  0.069  0.931  0.250  1.0
  Re  Re5  1  0.931  0.069  0.750  1.0
  Ru  Ru6  1  0.000  0.500  0.500  1.0
  Ru  Ru7  1  0.500  0.000  0.000  1.0
  N  N8  1  0.047  0.749  0.493  1.0
  N  N9  1  0.251  0.953  0.007  1.0
  N  N10  1  0.953  0.251  0.507  1.0
  N  N11  1  0.749  0.047  0.993  1.0
  N  N12  1  0.212  0.450  0.481  1.0
  N  N13  1  0.550  0.788  0.019  1.0
  N  N14  1  0.788  0.550  0.519  1.0
  N  N15  1  0.450  0.212  0.981  1.0
  N  N16  1  0.903  0.442  0.368  1.0
  N  N17  1  0.558  0.097  0.132  1.0
  N  N18  1  0.097  0.558  0.632  1.0
  N  N19  1  0.442  0.903  0.868  1.0
  O  O20  1  0.013  0.702  0.230  1.0
  O  O21  1  0.298  0.987  0.270  1.0
  O  O22  1  0.987  0.298  0.770  1.0
  O  O23  1  0.702  0.013  0.730  1.0
  O  O24  1  0.734  0.479  0.153  1.0
  O  O25  1  0.521  0.266  0.347  1.0
  O  O26  1  0.266  0.521  0.847  1.0
  O  O27  1  0.479  0.734  0.653  1.0
  O  O28  1  0.862  0.390  0.139  1.0
  O  O29  1  0.610  0.138  0.361  1.0
  O  O30  1  0.138  0.610  0.861  1.0
  O  O31  1  0.390  0.862  0.639  1.0
  O  O32  1  0.133  0.298  0.082  1.0
  O  O33  1  0.702  0.867  0.418  1.0
  O  O34  1  0.867  0.702  0.918  1.0
  O  O35  1  0.298  0.133  0.582  1.0
  O  O36  1  0.209  0.642  0.109  1.0
  O  O37  1  0.358  0.791  0.391  1.0
  O  O38  1  0.791  0.358  0.891  1.0
  O  O39  1  0.642  0.209  0.609  1.0
  O  O40  1  0.274  0.468  0.248  1.0
  O  O41  1  0.532  0.726  0.252  1.0
  O  O42  1  0.726  0.532  0.752  1.0
  O  O43  1  0.468  0.274  0.748  1.0
  O  O44  1  0.967  0.011  0.162  1.0
  O  O45  1  0.989  0.033  0.338  1.0
  O  O46  1  0.033  0.989  0.838  1.0
  O  O47  1  0.011  0.967  0.662  1.0
[/CIF]
.
The structure described by RuN6Re3O14 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four hexaami-noruthenium molecules and four Re3O14 clusters. In each Re3O14 cluster, there are two inequivalent Re sites. In the first Re site, Re(1) is bonded to one O(1), one O(3), one O(4), one O(5), and one O(6) atom to form distorted corner-sharing ReO5 trigonal bipyramids. In the second Re site, Re(2) is bonded to two equivalent O(1) and two equivalent O(7) atoms to form corner-sharing ReO4 tetrahedra. There are seven inequivalent O sites. In the first O site, O(7) is bonded in a single-bond geometry to one Re(2) atom. In the second O site, O(1) is bonded in a bent 120 degrees geometry to one Re(1) and one Re(2) atom. In the third O site, O(2) is bonded in a single-bond geometry to one O(3) atom. In the fourth O site, O(3) is bonded in a bent 120 degrees geometry to one Re(1) and one O(2) atom. In the fifth O site, O(4) is bonded in a single-bond geometry to one Re(1) atom. In the sixth O site, O(5) is bonded in a single-bond geometry to one Re(1) atom. In the seventh O site, O(6) is bonded in a single-bond geometry to one Re(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Re3Ru(N3O7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.913
_cell_length_b   7.913
_cell_length_c   16.067
_cell_angle_alpha   101.857
_cell_angle_beta   101.857
_cell_angle_gamma   90.550
_symmetry_Int_Tables_number   1
_cell_volume   962.228
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.128  0.489  0.155  1.0
  Re  Re1  1  0.511  0.872  0.345  1.0
  Re  Re2  1  0.872  0.511  0.845  1.0
  Re  Re3  1  0.489  0.128  0.655  1.0
  Re  Re4  1  0.069  0.931  0.250  1.0
  Re  Re5  1  0.931  0.069  0.750  1.0
  Ru  Ru6  1  0.000  0.500  0.500  1.0
  Ru  Ru7  1  0.500  0.000  0.000  1.0
  N  N8  1  0.047  0.749  0.493  1.0
  N  N9  1  0.251  0.953  0.007  1.0
  N  N10  1  0.953  0.251  0.507  1.0
  N  N11  1  0.749  0.047  0.993  1.0
  N  N12  1  0.212  0.450  0.481  1.0
  N  N13  1  0.550  0.788  0.019  1.0
  N  N14  1  0.788  0.550  0.519  1.0
  N  N15  1  0.450  0.212  0.981  1.0
  N  N16  1  0.903  0.442  0.368  1.0
  N  N17  1  0.558  0.097  0.132  1.0
  N  N18  1  0.097  0.558  0.632  1.0
  N  N19  1  0.442  0.903  0.868  1.0
  O  O20  1  0.013  0.702  0.230  1.0
  O  O21  1  0.298  0.987  0.270  1.0
  O  O22  1  0.987  0.298  0.770  1.0
  O  O23  1  0.702  0.013  0.730  1.0
  O  O24  1  0.734  0.479  0.153  1.0
  O  O25  1  0.521  0.266  0.347  1.0
  O  O26  1  0.266  0.521  0.847  1.0
  O  O27  1  0.479  0.734  0.653  1.0
  O  O28  1  0.862  0.390  0.139  1.0
  O  O29  1  0.610  0.138  0.361  1.0
  O  O30  1  0.138  0.610  0.861  1.0
  O  O31  1  0.390  0.862  0.639  1.0
  O  O32  1  0.133  0.298  0.082  1.0
  O  O33  1  0.702  0.867  0.418  1.0
  O  O34  1  0.867  0.702  0.918  1.0
  O  O35  1  0.298  0.133  0.582  1.0
  O  O36  1  0.209  0.642  0.109  1.0
  O  O37  1  0.358  0.791  0.391  1.0
  O  O38  1  0.791  0.358  0.891  1.0
  O  O39  1  0.642  0.209  0.609  1.0
  O  O40  1  0.274  0.468  0.248  1.0
  O  O41  1  0.532  0.726  0.252  1.0
  O  O42  1  0.726  0.532  0.752  1.0
  O  O43  1  0.468  0.274  0.748  1.0
  O  O44  1  0.967  0.011  0.162  1.0
  O  O45  1  0.989  0.033  0.338  1.0
  O  O46  1  0.033  0.989  0.838  1.0
  O  O47  1  0.011  0.967  0.662  1.0
[/CIF]
.