The compound described by NaClO4 is Zircon-like structured and crystallizes in the tetragonal I-42m space group. Na(1) is bonded in a 8-coordinate geometry to eight equivalent O(1) atoms. O(1) is bonded in a 3-coordinate geometry to two equivalent Na(1) and one Cl(1) atom. Cl(1) is bonded in a tetrahedral geometry to four equivalent O(1) atoms. is represented by the CIF card [CIF]
data_NaClO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.698
_cell_length_b   4.925
_cell_length_c   4.698
_cell_angle_alpha   58.386
_cell_angle_beta   63.229
_cell_angle_gamma   58.386
_symmetry_Int_Tables_number   1
_cell_volume   76.491
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.500  0.500  0.500  1.0
  Cl  Cl1  1  0.000  0.000  0.000  1.0
  O  O2  1  0.302  0.034  0.966  1.0
  O  O3  1  0.698  0.302  0.034  1.0
  O  O4  1  0.034  0.966  0.698  1.0
  O  O5  1  0.966  0.698  0.302  1.0
[/CIF]
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The compound described by NaClO4 is Zircon-like structured and crystallizes in the tetragonal I-42m space group. Na(1) is bonded in a 8-coordinate geometry to eight equivalent O(1) atoms. O(1) is bonded in a 3-coordinate geometry to two equivalent Na(1) and one Cl(1) atom. Cl(1) is bonded in a tetrahedral geometry to four equivalent O(1) atoms. is represented by the CIF card [CIF]
data_NaClO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.698
_cell_length_b   4.925
_cell_length_c   4.698
_cell_angle_alpha   58.386
_cell_angle_beta   63.229
_cell_angle_gamma   58.386
_symmetry_Int_Tables_number   1
_cell_volume   76.491
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.500  0.500  0.500  1.0
  Cl  Cl1  1  0.000  0.000  0.000  1.0
  O  O2  1  0.302  0.034  0.966  1.0
  O  O3  1  0.698  0.302  0.034  1.0
  O  O4  1  0.034  0.966  0.698  1.0
  O  O5  1  0.966  0.698  0.302  1.0
[/CIF]
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