Answer: 1007.

Solution: Let's break down the numbers of Petrov and Vasechkin into pairs as follows: $(2,3),(4,5), \ldots,(98,99),(100,101), \ldots$ (2012,2013), with 1 left unpaired for Petrov. Notice that in each pair, the sum of the digits of the second number is 1 greater than that of the first (since they differ only in the last digit). There will be a total of $\frac{2012}{2}=1006$ such pairs. Therefore, the difference in the sums of the digits will be 1006, and considering the 1 left unpaired for Petrov, it will be -1007.
3. Petrov lists the odd numbers: $1,3,5, \ldots, 2013$, while Vasechkin lists the even numbers: $2,4, \ldots, 2012$. Each of them calculated the sum of all digits of all their numbers and told the excellent student Masha. Masha subtracted Vasechkin's result from Petrov's result. What did she get?