27	Mechanism estimated for this compound based on the following assumptions. Reaction at group not adjacent to the nitro group, followed by O2 reaction with the alkoxy radical formed assumed to dominate. Nitrate formation ignored. HCOCH2NO2 represented by Acetaldehyde + XN, and CH3CH(NO2)CHO represented by RCHO + XN.
   28	Mechanism estimated for this compound based on the following assumptions. Reaction assumed to occur at the CH3 group, followed by reaction of the alkoxy radical formed with O2, forming CHF2CHO. The latter is represented by acetaldehyde (which probably overestimates its reactivity).
   29	Mechanism estimated for this compound based on the following assumptions. Decomposition of alkoxy radical, forming CF3 and inert F2CO assumed. CF3O assumed to react with other VOCs to form CF3OH, which is treated as inert. The effect of the CF3O + VOC reaction is represented by the formation of OH.
   30	Mechanism estimated for this compound based on the following assumptions. Overall nitrate yield estimated by assuming it is the same as the alkyl peroxy radical with the same number of carbons. Products formed assumed to be unreactive. Reaction of alkoxy radical with O2 assumed to dominate.
   31	Mechanism estimated for this compound based on the following assumptions. Overall nitrate yield estimated by assuming it is the same as the alkyl peroxy radical with the same number of carbons. Products formed assumed to be unreactive. Decomposition to form chlorine atoms assumed to dominate.
   32	Mechanism estimated for this compound based on the following assumptions. Most of reaction is assumed to occur at CH2 group, with the alkoxy radical formed assumed to react with O2 to form a relatively unreactive fluorinated carbonyl product. Overall nitrate yield estimated by assuming it is the same as the alkyl peroxy radical with the same number of carbons.
   33	Mechanism estimated for this compound based on the following assumptions. Alkoxy radical formed following abstraction from either hydrogen is assumed to decompose forming an alpha-hydrogen-substituted radical that reacts to form an alkoxy radical that reacts with O2 forming HO2 and an unreactive carbonyl fluoride. Nitrate yields in peroxy radical reactions assumed to be the same as in the corresponding alkylperoxy radical with the same number of carbons.
   34	Mechanism estimated for this compound based on the following assumptions. Reaction assumed to occur primarily at the CH2 group, ultimately giving rise to methyl radicals and C4F9OCHO, which is assumed to be unreactive. Nitrate yield from peroxy radical formed assumed to be the same as that formed from ethyl propyl ether.
   35	Mechanism estimated for this compound based on the following assumptions. Alkoxy radical formed assumed to react with O2 forming HO2 and a perfluoro formate, which is assumed to be unreactive. Nitrate yield from peroxy radical formed assumed to be the same as that formed from ethyl propyl ether.
   36	It is assumed that the primary reaction is OH or NO3 adding to terminal position, forming an allylic-stabilized radical. In the case of the OH reaction, the 1,2-unsaturated alpha-hydroxy radical reacts with O2 to form HO2 and 1,2-butadien-4-al, and in the case of the NO3 reaction the analogous compound reacts unimolecularly to form NO2 and the same aldehyde. The aldehyde is represented by RCHO, on the basis that this is probably not as bad an approximation as MACR. It is assumed that the reaction with O3 is slow.
   A	The atmospheric reactivity values were derived using the "Adjusted Products" version of the mechanism, where the major oxidation products are represented explicitly using mechanisms derived using the mechanism generation system. See Carter (2000a, 2009) for more details concerning how adjusted products mechanisms are derived.
   LM	This compound is represented using the "lumped molecule" approach, where the atmospheric reactivity of this compound is assumed to have the same per-molecule atmospheric impact as another compound. See Table B-9 for the compounds used to represent other compounds using the lumped molecule approach.
[c]	Structures used when deriving the mechanism using the mechanism generation system. If no structure is given then the mechanism generation system was not used to derive the mechanisms. "*", "*1", "*2" indicate join points for cyclic or bicyclic compounds. "^" and "v" are used to indicate cis/trans isomerization for alkenes (cis/trans isomerization for cyclic compounds isn't recognized by the system). "#" indicates a triple bond.

Table B-5.	Listing of compounds for which mechanisms have been derived. 2. Rate constants for reactions with O3, NO3, and O[3]P at 300[o]K, where applicable.
Compound
              Rate constant at 300 K (cm[3] molec[-1] s[-1]) [a]

                                      O3
                                      NO3
                                     O[3]P

Propene
                                   1.05E-17
                                       1
                                   9.73E-15
                                       1
                                   4.01E-12
                                       2
1-Butene
                                   9.08E-18
                                       1
                                   1.38E-14
                                       1
                                   4.17E-12
                                       2
Isobutene
                                   1.17E-17
                                       1
                                   3.44E-13
                                       1
                                   1.68E-11
                                       2
cis-2-Butene
                                   1.28E-16
                                       1
                                   3.52E-13
                                       1
                                   1.75E-11
                                       2
trans-2-Butene
                                   1.95E-16
                                       1
                                   3.93E-13
                                       1
                                   1.99E-11
                                       2
1,3-Butadiene
                                   6.64E-18
                                       1
                                   1.00E-13
                                       1
                                   1.98E-11
                                       2
1-Pentene
                                   1.10E-17
                                       1
                                   1.50E-14
                                       1
                                   4.69E-12
                                       2
3-Methyl-1-Butene
                                   9.87E-18
                                       3
                                   1.39E-14
                                      e1
                                   4.19E-12
                                       2
2-Methyl-1-Butene
                                   1.48E-17
                                       1
                                   3.32E-13
                                      e1
                                   1.80E-11
                                       2
2-Methyl-2-Butene
                                   4.11E-16
                                       1
                                   9.37E-12
                                       1
                                   5.08E-11
                                       2
cis-2-Pentene
                                   1.31E-16
                                       1
                                   3.70E-13
                                      e1
                                   1.70E-11
                                       2
trans-2-Pentene
                                   1.63E-16
                                       1
                                   3.70E-13
                                      e1
                                   2.10E-11
                                       2
Cyclopentene
                                   5.61E-16
                                       1
                                   4.20E-13
                                       1
                                   2.10E-11
                                       2
Trans 1,3-Pentadiene
                                   1.33E-17
                                      e2
                                   5.69E-13
                                      e1
                                   4.76E-11
                                      e3
1,4-Pentadiene
                                   1.51E-17
                                       3
                                   2.76E-14
                                      e1
                                   1.41E-11
                                      e3
Isoprene
                                   1.34E-17
                                       1
                                   6.81E-13
                                       1
                                   3.50E-11
                                       2
1-Hexene
                                   1.17E-17
                                       1
                                   1.80E-14
                                       1
                                   5.03E-12
                                       2
3,3-Dimethyl-1-Butene
                                   4.08E-18
                                       3
                                   1.38E-14
                                      e1
                                   4.80E-12
                                       2
3-Methyl-1-Pentene
                                   3.97E-18
                                       3
                                   1.39E-14
                                      e1
                                   5.60E-12
                                      e1
4-Methyl-1-Pentene
                                   1.04E-17
                                       3
                                   1.39E-14
                                      e1
                                   5.60E-12
                                      e1
2,3-Dimethyl-1-Butene
                                   1.04E-17
                                       4
                                   3.32E-13
                                      e1
                                   1.73E-11
                                      e1
2-Ethyl-1-Butene
                                   1.35E-17
                                       4
                                   4.52E-13
                                       1
                                   1.73E-11
                                      e1
2-Methyl-1-Pentene
                                   1.66E-17
                                       4
                                   3.32E-13
                                      e1
                                   2.03E-11
                                      e1
2,3-Dimethyl-2-Butene
                                   1.14E-15
                                       1
                                   5.72E-11
                                       1
                                   7.64E-11
                                       2
2-Methyl-2-Pentene
                                   3.48E-16
                                      e1
                                   9.37E-12
                                      e1
                                   3.86E-11
                                      e1
Cis-2-Hexene
                                   1.08E-16
                                       1
                                   3.70E-13
                                      e1
                                   2.05E-11
                                      e1
Cis-3-Hexene
                                   1.43E-16
                                       6
                                   3.70E-13
                                      e1
                                   2.05E-11
                                      e1
Cis-3-Methyl-2-Pentene
                                   4.58E-16
                                       7
                                   9.37E-12
                                      e1
                                   3.71E-11
                                      e1
Trans 3-Methyl-2-Pentene
                                   5.69E-16
                                       7
                                   9.37E-12
                                      e1
                                   3.71E-11
                                      e1
Trans 4-Methyl-2-Pentene
                                   1.15E-16
                                      e1
                                   3.70E-13
                                      e1
                                   1.84E-11
                                      e1
Trans-2-Hexene
                                   1.57E-16
                                       1
                                   3.70E-13
                                      e1
                                   2.05E-11
                                      e1
Trans-3-Hexene
                                   1.64E-16
                                       8
                                   3.70E-13
                                      e1
                                   2.05E-11
                                      e1
3-methylcyclopentene
                                   1.15E-16
                                      e1
                                   3.70E-13
                                      e1
                                   2.05E-11
                                      e1
1-Methyl cyclopentene
                                   6.81E-16
                                      10
                                   9.37E-12
                                      e1
                                   3.71E-11
                                      e1
Cyclohexene
                                   8.30E-17
                                       1
                                   5.10E-13
                                       1
                                   2.00E-11
                                       2
Trans 1,4-Hexadiene
                                   1.69E-16
                                      e4
                                   3.84E-13
                                      e1
                                   3.91E-11
                                      e3
1-Methyl Cyclohexene
                                   1.64E-16
                                       1
                                   1.00E-11
                                       1
                                   9.00E-11
                                      11
4-Methyl Cyclohexene
                                   9.04E-17
                                       1
                                   3.70E-13
                                      e1
                                   2.05E-11
                                      e1
1-Heptene
                                   1.21E-17
                                       1
                                   2.00E-14
                                       1
                                   8.70E-12
                                      e1
3,4-dimethyl-1-pentene
                                   1.01E-17
                                      e1
                                   1.40E-14
                                      e1
                                   5.60E-12
                                      e1
3-methyl-1-hexene
                                   1.01E-17
                                      e1
                                   1.40E-14
                                      e1
                                   5.60E-12
                                      e1
2,4-dimethyl-1-pentene
                                   1.18E-17
                                      e1
                                   3.32E-13
                                      e1
                                   1.73E-11
                                      e1
2,3-dimethyl-1-pentene
                                   1.18E-17
                                      e1
                                   3.32E-13
                                      e1
                                   1.73E-11
                                      e1
3,3-dimethyl-1-pentene
                                   1.01E-17
                                      e1
                                   1.38E-14
                                      e1
                                   5.60E-12
                                      e1
2-methyl-1-hexene
                                   1.18E-17
                                      e1
                                   3.32E-13
                                      e1
                                   1.73E-11
                                      e1
2,3,3-trimethyl-1-Butene
                                   8.09E-18
                                       4
                                   3.32E-13
                                      e1
                                   1.73E-11
                                      e1
4,4-dimethyl-cis-2-pentene
                                   1.15E-16
                                      e1
                                   3.70E-13
                                      e1
                                   1.55E-11
                                      e1
2,4-dimethyl-2-pentene
                                   3.48E-16
                                      e1
                                   9.37E-12
                                      e1
                                   3.71E-11
                                      e1
2-methyl-2-hexene
                                   3.48E-16
                                      e1
                                   9.37E-12
                                      e1
                                   3.71E-11
                                      e1
3-ethyl-2-pentene
                                   3.48E-16
                                      e1
                                   9.37E-12
                                      e1
                                   3.71E-11
                                      e1
3-methyl-trans-3-hexene
                                   3.48E-16
                                      e1
                                   9.37E-12
                                      e1
                                   3.71E-11
                                      e1
cis-2-heptene
                                   1.15E-16
                                      e1
                                   3.70E-13
                                      e1
                                   2.05E-11
                                      e1
2-Methyl-trans-3-Hexene
                                   1.15E-16
                                      e1
                                   3.70E-13
                                      e1
                                   2.05E-11
                                      e1
3-methyl-cis-3-hexene
                                   3.48E-16
                                      e1
                                   9.37E-12
                                      e1
                                   3.71E-11
                                      e1
3,4-dimethyl-cis-2-pentene
                                   3.48E-16
                                      e1
                                   9.37E-12
                                      e1
                                   3.71E-11
                                      e1
2,3-Dimethyl-2-Pentene
                                   6.74E-16
                                      e1
                                   5.72E-11
                                      e1
                                   5.07E-11
                                      e1
Cis-3-Heptene
                                   1.15E-16
                                      e1
                                   3.70E-13
                                      e1
                                   2.05E-11
                                      e1
Trans 4,4-dimethyl-2-Pentene
                                   1.15E-16
                                      e1
                                   3.70E-13
                                      e1
                                   1.57E-11
                                      e1
Trans-2-Heptene
                                   1.15E-16
                                      e1
                                   3.70E-13
                                      e1
                                   2.34E-11
                                      e1
Trans-3-Heptene
                                   1.15E-16
                                      e1
                                   3.70E-13
                                      e1
                                   2.05E-11
                                      e1
cis-3-methyl-2-hexene
                                   3.48E-16
                                      e1
                                   9.37E-12
                                      e1
                                   3.71E-11
                                      e1
trans-4-methyl-2-hexene
                                   1.15E-16
                                      e1
                                   3.70E-13
                                      e1
                                   2.05E-11
                                      e1
trans-3-methyl-2-hexene
                                   3.48E-16
                                      e1
                                   9.37E-12
                                      e1
                                   3.71E-11
                                      e1
1,2-Dimethyl Cyclohexene
                                   2.11E-16
                                      12
                                   5.72E-11
                                      e1
                                   5.29E-11
                                      e1
1-Octene
                                   1.45E-17
                                       3
                                   1.39E-14
                                      e1
                                   5.60E-12
                                      e1
2,4,4-trimethyl-1-pentene
                                   1.18E-17
                                      e1
                                   3.32E-13
                                      e1
                                   1.73E-11
                                      e1
3-Methyl-2-Isopropyl-1-Butene
                                   3.45E-18
                                       5
                                   3.32E-13
                                      e1
                                   1.73E-11
                                      e1
trans-2-octene
                                   1.15E-16
                                      e1
                                   3.70E-13
                                      e1
                                   2.05E-11
                                      e1
2-Methyl-2-heptene
                                   3.48E-16
                                      e1
                                   9.37E-12
                                      e1
                                   3.71E-11
                                      e1
Cis-4-Octene
                                   9.22E-17
                                       6
                                   3.70E-13
                                      e1
                                   2.05E-11
                                      e1
Trans 2,2-Dimethyl 3-Hexene
                                   4.34E-17
                                       9
                                   3.70E-13
                                      e1
                                   2.05E-11
                                      e1
Trans 2,5-Dimethyl 3-Hexene
                                   4.24E-17
                                       9
                                   3.70E-13
                                      e1
                                   2.05E-11
                                      e1
Trans-3-Octene
                                   1.15E-16
                                      e1
                                   3.70E-13
                                      e1
                                   2.05E-11
                                      e1
Trans-4-Octene
                                   1.34E-16
                                       8
                                   3.70E-13
                                      e1
                                   2.40E-11
                                      e1
2,4,4-trimethyl-2-Pentene
                                   1.44E-16
                                      10
                                   9.37E-12
                                      e1
                                   3.71E-11
                                      e1
2,3-dimethyl-2-hexene
                                   6.74E-16
                                      e1
                                   5.72E-11
                                      e1
                                   5.29E-11
                                      e1
1-Nonene
                                   1.01E-17
                                      e1
                                   1.39E-14
                                      e1
                                   5.60E-12
                                      e1
4,4-dimethyl-1-pentene
                                   1.01E-17
                                      e1
                                   1.39E-14
                                      e1
                                   5.60E-12
                                      e1
Trans-4-Nonene
                                   1.15E-16
                                      e1
                                   3.70E-13
                                      e1
                                   2.05E-11
                                      e1
1-Decene
                                   9.68E-18
                                       3
                                   1.40E-14
                                      e1
                                   5.60E-12
                                      e1
3,4-Diethyl-2-Hexene
                                   4.28E-18
                                       7
                                   9.37E-12
                                      e1
                                   3.71E-11
                                      e1
Cis-5-Decene
                                   1.13E-16
                                       6
                                   3.70E-13
                                      e1
                                   2.05E-11
                                      e1
Trans-4-Decene
                                   1.15E-16
                                      e1
                                   3.70E-13
                                      e1
                                   2.05E-11
                                      e1
3-Carene
                                   3.76E-17
                                      13
                                   9.10E-12
                                       1
                                   3.20E-11
                                       2
a-Pinene
                                   8.55E-17
                                       1
                                   6.09E-12
                                       1
                                   3.20E-11
                                       2
b-Pinene
                                   1.57E-17
                                       1
                                   2.51E-12
                                       1
                                   2.70E-11
                                       2
d-Limonene
                                   2.17E-16
                                       1
                                   1.22E-11
                                       1
                                   7.20E-11
                                       2
Sabinene
                                   8.40E-17
                                      13
                                   1.00E-11
                                       1
                                   6.27E-11
                                      e3
Terpinolene
                                   1.02E-15
                                      e1
                                   6.66E-11
                                      e1
                                   1.63E-10
                                      e1
1-Undecene
                                   1.01E-17
                                      e1
                                   1.40E-14
                                      e1
                                   5.60E-12
                                      e1
Trans-5-Undecene
                                   1.15E-16
                                      e1
                                   3.70E-13
                                      e1
                                   2.05E-11
                                      e1
1-Dodecene
                                   1.01E-17
                                      e1
                                   1.40E-14
                                      e1
                                   5.60E-12
                                      e1
Trans-5-Dodecene
                                   1.15E-16
                                      e1
                                   3.70E-13
                                      e1
                                   2.05E-11
                                      e1
1-Tridecene
                                   1.01E-17
                                      e1
                                   1.41E-14
                                      e1
                                   5.60E-12
                                      e1
Trans-5-Tridecene
                                   1.15E-16
                                      e1
                                   3.70E-13
                                      e1
                                   2.05E-11
                                      e1
1-Tetradecene
                                   1.01E-17
                                      e1
                                   1.41E-14
                                      e1
                                   5.60E-12
                                      e1
Trans-5-Tetradecene
                                   1.15E-16
                                      e1
                                   3.70E-13
                                      e1
                                   2.05E-11
                                      e1
Trans-5-Pentadecene
                                   1.15E-16
                                      e1
                                   3.70E-13
                                      e1
                                   2.05E-11
                                      e1
Styrene
                                   1.76E-17
                                       3
                                   1.50E-13
                                       1
                                   1.75E-11
                                      e5
b-Methyl Styrene
                                   3.25E-16
                                      e6
                                   3.92E-13
                                      e7
                                   1.62E-11
                                      e3
Glyoxal

                                   1.02E-15
                                      e8

glycolaldehyde

                                   2.84E-15
                                      e17

Acrolein
                                   3.07E-19
                                      17
                                   1.18E-15
                                      18
                                   2.37E-12
                                      e1
Acrylic Acid
                                   1.01E-17
                                      e1
                                   2.76E-18
                                      e1
                                   4.60E-12
                                      e1
Methyl Glyoxal

                                   2.53E-15
                                      e8

Crotonaldehyde
                                   1.58E-18
                                      19
                                   5.12E-15
                                      20
                                   7.29E-12
                                      e1
Methacrolein
                                   1.28E-18
                                       1
                                   3.54E-15
                                       1
                                   6.34E-12
                                      e8
Methylvinyl ketone
                                   5.36E-18
                                       1

                                   4.32E-12
                                      e8
2-Methylpropanal

                                   1.15E-14
                                       1

Butanal

                                   1.15E-14
                                       1

Methacrylic Acid
                                   1.18E-17
                                      e1
                                   6.71E-17
                                      e1
                                   1.42E-11
                                      e1
Methyl Acrylate
                                   1.01E-17
                                      e1
                                   2.76E-18
                                      e1
                                   4.60E-12
                                      e1
Vinyl Acetate
                                   1.01E-17
                                      e1
                                   1.38E-14
                                      e1
                                   5.60E-12
                                      e1
Hydroxy Methacrolein
                                   1.28E-18
                                      e9
                                   3.40E-15
                                      e10
                                   9.95E-12
                                      e1
2-Methyl-3-Butene-2-ol
                                   9.68E-18
                                      15
                                   1.21E-14
                                      16
                                   2.01E-11
                                      e1
2,2-Dimethylpropanal (pivaldehyde)

                                   2.40E-14
                                       1

3-Methylbutanal (Isovaleraldehyde)

                                   1.90E-14
                                       1

Pentanal (Valeraldehyde)

                                   1.50E-14
                                       1

Ethyl Acrylate
                                   1.01E-17
                                      e1
                                   3.70E-18
                                      e1
                                   4.60E-12
                                      e1
Methyl Methacrylate
                                   1.18E-17
                                      e1
                                   6.71E-17
                                      e1
                                   1.42E-11
                                      e1
Glutaraldehyde

                                   7.63E-15
                                      e1

Hexanal

                                   1.60E-14
                                       1

Ethyl Methacrylate
                                   1.18E-17
                                      e1
                                   6.80E-17
                                      e1
                                   1.42E-11
                                      e1
hydroxypropyl acrylate
                                   1.01E-17
                                      e1
                                   2.96E-17
                                      e1
                                   4.60E-12
                                      e1
Benzaldehyde

                                   2.73E-15
                                      21

o-Cresol

                                   1.40E-11
                                       2

Heptanal

                                   1.90E-14
                                       1

2-methyl-hexanal

                                   3.90E-15
                                      e1

n-butyl acrylate
                                   1.01E-17
                                      e1
                                   5.06E-17
                                      e1
                                   4.60E-12
                                      e1
isobutyl acrylate
                                   1.01E-17
                                      e1
                                   1.14E-16
                                      e1
                                   4.60E-12
                                      e1
Octanal

                                   1.70E-14
                                       1

Butyl Methacrylate
                                   1.18E-17
                                      e1
                                   1.15E-16
                                      e1
                                   1.42E-11
                                      e1
Isobutyl Methacrylate
                                   1.18E-17
                                      e1
                                   1.79E-16
                                      e1
                                   1.42E-11
                                      e1
a-terpineol
                                   3.48E-16
                                      e1
                                   9.37E-12
                                      e1
                                   3.71E-11
                                      e1
Citronellol (3,7-dimethy-6-octen-1-ol)
                                   3.48E-16
                                      e1
                                   9.37E-12
                                      e1
                                   3.71E-11
                                      e1
Hydroxycitronellal

                                   4.03E-15
                                      e1

Linalool
                                   3.58E-16
                                      e1
                                   9.38E-12
                                      e1
                                   6.60E-11
                                      e1
Geraniol
                                   6.96E-16
                                      e1
                                   1.87E-11
                                      e1
                                   1.35E-10
                                      e1
2-Ethyl-Hexyl Acrylate
                                   1.01E-17
                                      e1
                                   2.95E-16
                                      e1
                                   4.60E-12
                                      e1
methyl cis-9-pentadecenoate
                                   1.15E-16
                                      e1
                                   3.70E-13
                                      e1
                                   2.05E-11
                                      e1
methyl linolenate (methyl cis,cis,cis-9,12,15-octadecatrienoate)
                                   3.45E-16
                                      e1
                                   1.11E-12
                                      e1
                                   1.59E-10
                                      e1
methyl linoelate (methyl cis,cis-9,12-octadecadienoate)
                                   2.30E-16
                                      e1
                                   7.40E-13
                                      e1
                                   7.47E-11
                                      e1
Methylamine
                                   7.40E-21
                                      22
                                   9.60E-14
                                      e11

Acetylene
                                   1.16E-20
                                      14

Dimethyl Amine
                                   1.67E-18
                                      22
                                   2.03E-13
                                      e11

Ethyl Amine
                                   2.09E-20
                                      e12
                                   1.16E-13
                                      e11

Ethanolamine
                                   6.86E-20
                                      e12
                                   1.35E-13
                                      e11

Dimethyl Sulfoxide

                                   3.00E-13
                                      27

Trichloroethylene

                                   2.99E-16
                                      18
                                   4.37E-14
                                      e1
Trimethyl Amine
                                   7.84E-18
                                      22
                                   1.56E-13
                                      e11

isopropylamine
                                   3.48E-20
                                      e12
                                   1.21E-13
                                      e11

1-amino-2-propanol
                                   6.58E-20
                                      e18
                                   1.35E-13
                                      e1

trans-1,3-dichloropropene
                                   7.12E-19
                                      24
                                   9.13E-17
                                      e13
                                   1.30E-12
                                      e14
cis-1,3-dichloropropene
                                   1.60E-19
                                      25
                                   5.57E-18
                                      e13
                                   4.79E-13
                                      e14
1,3-butadiyne

                                   1.00E-15
                                      e7

t-butyl amine
                                       0
                                      e12
                                   5.88E-14
                                      e11

morpholine
                                   3.77E-18
                                      e18
                                   3.30E-13
                                      e1

Dimethylaminoethanol
                                   6.76E-18
                                      22
                                   1.80E-13
                                      e11

2-amino-1-butanol
                                   3.74E-19
                                      e12
                                   1.70E-13
                                      e11

2-Amino-2-Methyl-1-Propanol
                                       0
                                      e12
                                   5.88E-14
                                      e11

Diethanol Amine
                                   3.78E-18
                                      e12
                                   3.30E-13
                                      e11

2-(Cl-methyl)-3-Cl-Propene
                                   4.14E-19
                                      26
                                   1.00E-15
                                      e15
                                   5.60E-12
                                      e1
2-amino-2-ethyl-1,3-propanediol

                                   5.89E-14
                                      e1

N-Methyl-2-Pyrrolidone

                                   1.26E-13
                                      23

Triethyl Amine
                                   1.20E-17
                                      e12
                                   1.71E-13
                                      e11

Triethanolamine
                                   3.94E-17
                                      e12
                                   2.29E-13
                                      e11

Molinate

                                   9.20E-15
                                      e16

EPTC (S-Ethyl Dipropylthiocarbamate)

                                   9.20E-15
                                      28

triisopropanolamine
                                   3.94E-17
                                      e12
                                   2.29E-13
                                      e11

Pebulate

                                   9.20E-15
                                      e16

Thiobencarb

                                   9.20E-15
                                      e16

 [a]	See the complete mechanism listing in the electronic version of the report for the temperature dependences, where available. Footnotes for measured rate constants are as follows:
   1	As recommended or tabulated by Atkinson and Arey (2003)
   2	As recommended or tabulated by Calvert et al (2002)
   3	Rate constant at 298K as recommended or tabulated by Atkinson and Arey (2003). Temperature dependence estimated by assuming that the A factor is the same as that for 1 butene.
   4	Rate constant at 298K as recommended or tabulated by Atkinson and Arey (2003). Temperature dependence estimated by assuming that the A factor is the same as that for 2 methyl-1-butene.
   5	T=298K rate constant recommended by Atkinson (1997).  Temperature dependence estimated by assuming the A factor is the same as for isobutene.
   6	Rate constant at 298K as recommended or tabulated by Atkinson and Arey (2003). Temperature dependence estimated by assuming that the A factor is the same as that for cis-2-butene.
   7	Rate constant at 298K as recommended by Atkinson (1997). Temperature dependence estimated by assuming that the A factor is the same as that for 2-methyl-1-butene.
   8	Rate constant at 298K as recommended or tabulated by Atkinson and Arey (2003). Temperature dependence estimated by assuming that the A factor is the same as that for trans-2-butene.
   9	Rate constant at 298K as recommended by Atkinson (1997). Temperature dependence estimated by assuming that the A factor is the same as that for trans-2-butene.
   10	Rate constant at 298K as recommended or tabulated by Atkinson and Arey (2003). Temperature dependence estimated by assuming that the A factor is the same as that for 2-methyl-2-butene.
   11	Atkinson (1997) Recommendation
   12	Rate constant at 298K as recommended by Atkinson (1997). Temperature dependence estimated by assuming that the A factor is the same as that for 2,3-dimethyl-2-butene.
   13	Rate constant at 298K as recommended or tabulated by Atkinson and Arey (2003). Temperature dependence estimated by assuming that the A factor is the same as that for alpha-pinene.
   14	Rate constant at 298K recommended by IUPAC (2006). A factor estimated to be approximately 2 times that for ethene, as assumed by Carter (2000a).
   15	Rate constant at 298K is average of 291K rate constant of Grosjean and Grosjean (1994) and the 298K rate constant of Fantechi et al (1998). Temperature dependence estimated by assuming that the A factor is the same as that for 1-butene
   16	Rate expression of Rudich et al (1996), as recommended by Atkinson (private communication, 2000). Reasonable agreement with data of Fantechi et al (1998).
   17	Rate constant at 298K recommended by Atkinson (1994). Temperature dependence estimated by assuming that the A factor is the same as that for methacrolein.
   18	Rate constant relative to ethene from Atkinson et al (1987). Placed on an absolute basis using 300K rate constant for ethene recommended by Atkinson and Arey (2003).
   19	Sato et al (2004b).
   20	Rate constant relative to propene from Atkinson et al (1987). Placed on an absolute basis using 300K rate constant for propene recommended by Atkinson and Arey (2003).
   21	The T=298K rate constant recommended by Atkinson (1994). Temperature dependence estimated by assuming the reaction has the same A factor as the reaction of NO3 with acetaldehyde. This gives the same 298K rate constant but a slightly different temperature dependence than used in SAPRC-99.
   22	Rate constant from Tuazon et al (1994)
   23	Rate constant from Aschmann and Atkinson (1999)
   24	Rate constant at 298K from Tuazon et al (1984). Temperature dependence estimated by assuming that the A factor is the same as that for trans-2-butene.
   25	Rate constant at 298K from Tuazon et al (1984). Temperature dependence estimated by assuming that the A factor is the same as that for cis-2-butene.
   26	Rate constant at 298K from Atkinson and Carter (1984). Temperature dependence estimated by assuming that the A factor is the same as that for isobutene.
   27	Rate constant is geometric mean of measurements of Barnes et al (1989) and Falbe-Hansen et al (2000), as used by Carter et al (2000).
   28	Rate constant from Kwok et al (1992)
   Footnotes for estimated rate constants are as follows:
   e1	Estimated using the group-additivity estimation assignments implemented in the current mechanism generation system. See Carter (2000a).
   e2	Rate constant unknown. Roughly estimate that it is similar to that for isoprene
   e3	Estimated from correlation between measured OH and O[3]P rate constants (with ethene, allene, and some other outliers excluded) at 300K.
   e4	Estimated as the sum of the 300K rate constants for 1-hexene and trans-2-hexene.
   e5	Assumed to have the same rate constant as cis-2-butene on the basis of their having similar OH radical rate constants.
   e6	Estimated from the 300K styrene, propene, and trans-2-butene rate constants by assuming that the styrene/b-methyl styrene ratio is the same as the ratio for propene to trans-2-butene.
   e7	Estimated from the correlation between OH and NO3 rate constants, using the assigned 300K OH rate constant for this compound.
   e8	Estimated value used in SAPRC-99 mechanism. See base mechanism listing and Carter (2000a).
   e9	Estimated to have the same rate constant and kinetic parameters as methacrolein, as assumed by Carter and Atkinson (1996).
   e10	Rate constant assumed to be the same as for methacrolein (Carter and Atkinson, 1996)
   e11	Estimated based on the NO3 + NMP rate constant and assuming ratios of rate constants for reactions of NO3 at various types of amine groups is the same as those estimated for the reactions of OH with those groups. Reaction assumed to occur only from NH or NH2 or from C-H bonds on carbons bonded to the amino group.
   e12	Estimated from the estimated rate of reaction of OH at the alpha position, and correlations between this and the measured O3 rate constants of Tuazon et al (1994) for the methylamines and DMAE. Reaction assumed to be slow if no abstractable hydrogens in a group adjacent to the amino group.
   e13	Estimated by Carter and Malkina (2007) based on correlation between O3 and NO3 rate constants.
   e14	Estimated by Carter and Malkina (2007) based on correlation between O3 and NO3 rate constants.
   e15	This rate constant estimated by Atkinson (private communication, 1997) based on the rate constant for NO3 + Allyl chloride (Atkinson, 1991)
   e16	Estimated by Carter and Malkina (2007) to have the same rate constant as EPTC.
   e17	Assumed to have the same rate constant as acetaldehyde.
   e18	Estimated from estimated rate of reaction of OH at the alpha position, and correlations between this and the measured O3 rate constants of Tuazon et al (1994) for the methylamines and DMAE.

Table B-6.	Listing of compounds for which mechanisms have been derived. 3. Absorption cross-sections, quantum yields, and mechanisms for photolysis reactions, where applicable.
Compound
                                 Phot Data [a]
Mechanism

glycolaldehyde
HOCCHO

                                       6
GLCLALD + HV = CO + #2 HO2 + HCHO
Acrolein
MACR-06

                                      e2
ACROLEIN + HV = #.178 OH + #1.066 HO2 + #.234 MEO2 + #.33 MACO3 + #1.188 CO + #.102 CO2 + #.34 HCHO + #.05 CCOOH + #-.284 XC
Hydroxy Acetone
MEK-06
                                     0.175
                                      e3
HOACET + HV = HO2 + MECO3 + HCHO
Crotonaldehyde
MACR-06

                                      e2
CROTALD + HV = #2 HO2 + #2 CO + CCHO
2-Methylpropanal
C2CHO

                                      e1
2MEC3AL + HV = HO2 + #.96 RO2C + #.04 RO2XC + #.04 zRNO3 + CO + #.96 xHO2 + #.96 xACET + yROOH + #-.12 XC
Butanal
C2CHO

                                      e1
1C4RCHO + HV = HO2 + #.98 RO2C + #.02 RO2XC + #.02 zRNO3 + CO + #.98 xHO2 + #.98 xRCHO + yROOH + #-.06 XC
Hydroxy Methacrolein
MACR-06

                                      e2
HOMACR + HV = HO2 + RCO3 + CO + HCHO + #-1 XC
Methoxy Acetone
MEK-06
                                      0.1
                                      e3
MEOACET + HV = MECO3 + RO2C + xHO2 + #.079 xHCHO + yROOH + #1.921 XC
2,2-Dimethylpropanal (pivaldehyde)
C2CHO

                                      e1
22DMC3AL + HV = HO2 + #.961 RO2C + #.039 RO2XC + #.039 zRNO3 + CO + #.961 xTBUO + yR6OOH + #-.079 XC
3-Methylbutanal (Isovaleraldehyde)
C2CHO

                                      e1
3MC4RCHO + HV = HO2 + #1.294 RO2C + #.053 RO2XC + #.053 zRNO3 + CO + #.947 xHO2 + #.348 xHCHO + #.613 xRCHO + #.334 xACET + yR6OOH + #.492 XC
Pentanal (Valeraldehyde)
C2CHO

                                      e1
1C5RCHO + HV = HO2 + #1.686 RO2C + #.069 RO2XC + #.069 zRNO3 + CO + #.931 xHO2 + #.931 xRCHO + yR6OOH + #.792 XC
2-Pentanone
MEK-06
                                      0.1
                                      e3
MPK + HV = MECO3 + #.98 RO2C + #.02 RO2XC + #.02 zRNO3 + #.98 xHO2 + #.98 xRCHO + yR6OOH + #-.06 XC
3-Pentanone
MEK-06
                                      0.1
                                      e3
DEK + HV = RCO3 + RO2C + xHO2 + xCCHO + yR6OOH
Methyl Isopropyl Ketone
MEK-06
                                      0.1
                                      e3
MIPRK + HV = MECO3 + #.96 RO2C + #.04 RO2XC + #.04 zRNO3 + #.96 xHO2 + #.96 xACET + yR6OOH + #-.12 XC
Glutaraldehyde
C2CHO

                                      e1
GLTRALD + HV = HO2 + #.961 RO2C + #.039 RO2XC + #.039 zRNO3 + CO + #.961 xRCO3 + yR6OOH + #.882 XC
2,4-pentanedione
MEK-06
                                      0.1
                                      e3
24C5-K + HV = MECO3 + RO2C + xMECO3 + xHCHO + yR6OOH
Hexanal
C2CHO

                                      e1
1C6RCHO + HV = HO2 + #1.809 RO2C + #.126 RO2XC + #.126 zRNO3 + CO + #.874 xHO2 + #.874 xRCHO + yR6OOH + #1.623 XC
4-Methyl-2-Pentanone
MEK-06
                                     0.02
                                      e3
MIBK + HV = MECO3 + #1.294 RO2C + #.053 RO2XC + #.053 zRNO3 + #.947 xHO2 + #.348 xHCHO + #.613 xRCHO + #.334 xACET + yR6OOH + #.492 XC
Methyl n-Butyl Ketone
MEK-06
                                     0.02
                                      e3
MNBK + HV = MECO3 + #1.686 RO2C + #.069 RO2XC + #.069 zRNO3 + #.931 xHO2 + #.931 xRCHO + yR6OOH + #.792 XC
Methyl t-Butyl Ketone
MEK-06
                                     0.02
                                      e3
MTBK + HV = MECO3 + #.961 RO2C + #.039 RO2XC + #.039 zRNO3 + #.961 xTBUO + yR6OOH + #-.079 XC
Heptanal
C2CHO

                                      e1
1C7RCHO + HV = HO2 + #1.717 RO2C + #.186 RO2XC + #.186 zRNO3 + CO + #.814 xHO2 + #.814 xRCHO + yR6OOH + #2.443 XC
2-methyl-hexanal
C2CHO

                                      e1
2MEXAL + HV = HO2 + #1.608 RO2C + #.237 RO2XC + #.237 zRNO3 + CO + #.763 xHO2 + #.763 xPROD2 + yR6OOH
2-Heptanone
MEK-06
                                     0.004
                                      e3
C7-KET-2 + HV = MECO3 + #1.809 RO2C + #.126 RO2XC + #.126 zRNO3 + #.874 xHO2 + #.874 xRCHO + yR6OOH + #1.623 XC
2-Methyl-3-Hexanone
MEK-06
                                     0.004
                                      e3
2M-3-HXO + HV = RCO3 + #.98 RO2C + #.02 RO2XC + #.02 zRNO3 + #.98 xHO2 + #.98 xRCHO + yR6OOH + #.94 XC
Di-Isopropyl Ketone
MEK-06
                                     0.004
                                      e3
DIPK + HV = RCO3 + #.96 RO2C + #.04 RO2XC + #.04 zRNO3 + #.96 xHO2 + #.96 xACET + yR6OOH + #.88 XC
5-Methyl-2-Hexanone
MEK-06
                                     0.004
                                      e3
5M2HXO + HV = MECO3 + #1.722 RO2C + #.119 RO2XC + #.119 zRNO3 + #.881 xHO2 + #.881 xRCHO + yR6OOH + #1.642 XC
3-Methyl-2-Hexanone
MEK-06
                                     0.004
                                      e3
3M2HXO + HV = MECO3 + #1.612 RO2C + #.165 RO2XC + #.165 zRNO3 + #.835 xHO2 + #.029 xCCHO + #.029 xRCHO + #.107 xMEK + #.699 xPROD2 + yR6OOH + #-.758 XC
Octanal
C2CHO

                                      e1
1C8RCHO + HV = HO2 + #1.613 RO2C + #.252 RO2XC + #.252 zRNO3 + CO + #.748 xHO2 + #.748 xRCHO + yR6OOH + #3.244 XC
2-Octanone
MEK-06
                                    0.0001
                                      e3
C8-KET-2 + HV = MECO3 + #1.717 RO2C + #.186 RO2XC + #.186 zRNO3 + #.814 xHO2 + #.814 xRCHO + yR6OOH + #2.443 XC
Hydroxycitronellal
C2CHO

                                      e1
HYCITRLL + HV = HO2 + #1.43 RO2C + #.372 RO2XC + #.372 zRNO3 + CO + #.628 xHO2 + #.006 xHCHO + #.622 xRCHO + #.006 xPROD2 + yR6OOH + #4.86 XC
Methyl Nitrite
CONO

                                       1
ME-NITRT + HV = HCHO + HO2 + NO
Carbon Disulfide
CS2
                                     0.012
                                       3
CS2 + HV = SO2 + O3P + XC
methyl iodide
CH3I

                                       5
CH3I + OH = RO2C + xHO2 + xHCHO + I
Chloropicrin
CLPICERI
                                     0.87
                                       2
CCL3NO2 + HV = NO2 + RO2C + xCL + XC
Methyl Isothiocyanate
MITC

                                       4
MITC + HV = XC + SO2 + #2 O3P
Methyl Isothiocyanate
MITC

                                       4
MITC + HV = XC + SO2 + #2 O3P
PROD2 Species #1
MEK-06
                                     0.02
                                      e3
PROD2-1 + HV = MECO3 + #1.013 RO2C + xHO2 + #.033 xHCHO + #.002 xCCHO + #.987 xRCHO + yR6OOH
PROD2 Species #2
MEK-06
                                     0.004
                                      e3
PROD2-2 + HV = MECO3 + #1.697 RO2C + #.051 RO2XC + #.051 zRNO3 + #.949 xHO2 + #1.484 xHCHO + #.736 xCCHO + #.213 xRCHO + yR6OOH + #.1 XC
PROD2 Species #3
MEK-06
                                    0.0001
                                      e3
PROD2-3 + HV = RCO3 + #1.715 RO2C + #.07 RO2XC + #.07 zRNO3 + #.93 xHO2 + #.93 xRCHO + yR6OOH + #.789 XC
PROD2 Species #4
MEK-06
                                    0.0001
                                      e3
PROD2-4 + HV = RCO3 + #1.809 RO2C + #.126 RO2XC + #.126 zRNO3 + #.874 xHO2 + #.077 xCCHO + #.874 xRCHO + yR6OOH + #1.469 XC
PROD2 Species #5
MEK-06
                                    0.0001
                                      e3
PROD2-5 + HV = RCO3 + #1.717 RO2C + #.186 RO2XC + #.186 zRNO3 + #.814 xHO2 + #.898 xRCHO + yR6OOH + #2.193 XC
RNO3 Species #1
IC3ONO2

                                      e4
RNO3-1 + HV = NO2 + #.606 HO2 + #.394 RO2C + #.394 CCHO + #.606 MEK + #.394 xHO2 + #.394 xCCHO + #.394 yROOH
RNO3 Species #2
IC3ONO2

                                      e4
RNO3-2 + HV = NO2 + HO2 + PROD2 + #-1 XC
RNO3 Species #3
IC3ONO2

                                      e4
RNO3-3 + HV = NO2 + #.016 HO2 + #1.226 RO2C + #.081 RO2XC + #.081 zRNO3 + #.89 CCHO + #.016 PROD2 + #.904 xHO2 + #.645 xCCHO + #.495 xMEK + #.085 xPROD2 + #.984 yR6OOH + #-.143 XC
RNO3 Species #4
IC3ONO2

                                      e4
RNO3-4 + HV = NO2 + #.441 HO2 + #.483 RO2C + #.075 RO2XC + #.075 zRNO3 + #.441 HCHO + #.441 RCHO + #.483 xHO2 + #.483 xPROD2 + #.559 yR6OOH + #1.882 XC
RNO3 Species #5
IC3ONO2

                                      e4
RNO3-5 + HV = NO2 + #1.422 RO2C + #.215 RO2XC + #.215 zRNO3 + #.137 MEK + #.124 PROD2 + #.785 xHO2 + #.367 xHCHO + #.341 xCCHO + #.379 xRCHO + #.046 xACET + #.236 xPROD2 + yR6OOH + #1.678 XC
RNO3 Species #6
IC3ONO2

                                      e4
RNO3-6 + HV = NO2 + #.802 RO2C + #.24 RO2XC + #.24 zRNO3 + #.76 xHO2 + #.76 xPROD2 + yR6OOH + #4 XC

 [a]	The first column gives the photolysis set name that refers to the set of absorption cross-sections and (in some cases) quantum yields. The second column gives the overall quantum yield, if quantum yields are not given in the photolysis set. If blank, then unit quantum yields are used. The third column gives the footnote for the measured or estimated absorption cross-sections and quantum yields. Footnotes for measured data are as follows. In all these cases, the absorption cross sections are given in Table B-8.
   1	Absorption cross-sections from Calvert and Pitts (1966). Unit quantum yields assumed.
   2	Absorption cross-sections and quantum yields from Carter et al (1997b).
   3	Absorption cross-sections from current IUPAC (2006) recommendation. Quantum yield is IUPAC (2006) upper limit recommendation, but chamber data are best fit is this upper limit is used. See Carter and Malkina (2007).
   4	Based on data from Alvarez (1993) and Alvarez and Moore (1994).
   5	IUPAC (2006) recommendation. Unit quantum yields assumed.
   6	IUPAC (2006) recommendation for absorption cross-sections and overall quantum yield.
   Footnotes for estimated absorption cross-sections and quantum yields are as follows. In all these cases, the photolysis sets are associated with the base mechanism, and the corresponding absorption cross sections and quantum yields are given in Table A-3 in Appendix A. See footnotes to Table A-2 for the documentation for the values used.
   e1	Assumed to have the same photolysis rate as propionaldehyde (model species RCHO).
   e2	Assumed to have the same photolysis rate as methacrolein (model species MACR)
   e3	Assumed to have the same absorption cross sections of methyl ethyl ketone, but with overall quantum yields depending on the carbon number, based on quantum yields that give the best simulations of the chamber data for methyl ethyl ketone, methyl propyl ketone, methyl isopropyl ketone, and 2-heptanol. Based on these data, overall quantum yields for simple ketones with carbon numbers of 4, 5, 6, 8, and 8 are assumed to be 0.174, 0.1, 0.02, 0.004, and ~0, respectively. For oxygenated ketones such as hydroxyacetone or the PROD2 species, the effective carbon number is the sum of the carbons + OH groups. For the purpose of computing an average quantum yield and a photolysis mechanism for PROD2, quantum yields of 0.0001 were used for PROD2 species with 8 or more carbons + OH groups. This was necessary in order for the mechanisms for these species to be generated.
   e4	Assumed to have the same photolysis rate as isopropyl nitrate, as used in the base mechanism for RNO3.

Table B-7.	Listing of compounds for which mechanisms have been derived. 4. Rate constants and mechanisms for reactions with chlorine atoms, where used.
Compound
                                Rate const. [a]
Mechanism [b]

Ethane
                                   5.95E-11
                                       1
ETHANE + CL = xHO2 + RO2C + HCL + xCCHO + yROOH
Propane
                                   1.37E-10
                                       2
PROPANE + CL = #.97 xHO2 + #.97 RO2C + #.03 RO2XC + #.03 zRNO3 + HCL + #.482 xRCHO + #.488 xACET + yROOH + #-.09 XC
n-Butane
                                   2.05E-10
                                       1
N-C4 + CL = HCL + #1.418 RO2C + #.077 RO2XC + #.077 zRNO3 + #.923 xHO2 + #.481 xCCHO + #.313 xRCHO + #.37 xMEK + yROOH + #.16 XC
n-Pentane
                                   2.80E-10
                                       2
N-C5 + CL = HCL + #1.577 RO2C + #.143 RO2XC + #.143 zRNO3 + #.857 xHO2 + #.105 xCCHO + #.328 xRCHO + #.177 xMEK + #.352 xPROD2 + yR6OOH + #.127 XC
n-Hexane
                                   3.40E-10
                                       2
N-C6 + CL = HCL + #1.591 RO2C + #.22 RO2XC + #.22 zRNO3 + #.78 xHO2 + #.009 xCCHO + #.215 xRCHO + #.585 xPROD2 + yR6OOH + #.51 XC
n-Heptane
                                   3.90E-10
                                       2
N-C7 + CL = HCL + #1.519 RO2C + #.29 RO2XC + #.29 zRNO3 + #.71 xHO2 + #.143 xRCHO + #.575 xPROD2 + yR6OOH + #1.386 XC
n-Octane
                                   4.60E-10
                                       2
N-C8 + CL = HCL + #1.449 RO2C + #.352 RO2XC + #.352 zRNO3 + #.648 xHO2 + #.088 xRCHO + #.561 xPROD2 + yR6OOH + #2.263 XC
n-Nonane
                                   4.80E-10
                                       2
N-C9 + CL = HCL + #1.393 RO2C + #.398 RO2XC + #.398 zRNO3 + #.602 xHO2 + #.068 xRCHO + #.535 xPROD2 + yR6OOH + #3.203 XC
n-Decane
                                   5.50E-10
                                       2
N-C10 + CL = HCL + #1.355 RO2C + #.428 RO2XC + #.428 zRNO3 + #.572 xHO2 + #.057 xRCHO + #.515 xPROD2 + yR6OOH + #4.17 XC
n-Undecane
                                   6.27E-10
                                      e1
N-C11 + CL = HCL + #1.331 RO2C + #.448 RO2XC + #.448 zRNO3 + #.552 xHO2 + #.049 xRCHO + #.503 xPROD2 + yR6OOH + #5.147 XC
n-Dodecane
                                   6.89E-10
                                      e1
N-C12 + CL = HCL + #1.315 RO2C + #.46 RO2XC + #.46 zRNO3 + #.54 xHO2 + #.044 xRCHO + #.497 xPROD2 + yR6OOH + #6.131 XC
n-Tridecane
                                   7.51E-10
                                      e1
N-C13 + CL = HCL + #1.305 RO2C + #.467 RO2XC + #.467 zRNO3 + #.533 xHO2 + #.039 xRCHO + #.494 xPROD2 + yR6OOH + #7.118 XC
Isobutane
                                   1.43E-10
                                       2
2-ME-C3 + CL = HCL + #1.19 RO2C + #.049 RO2XC + #.049 zRNO3 + #.651 xHO2 + #.3 xTBUO + #.239 xHCHO + #.422 xRCHO + #.23 xACET + yROOH + #.314 XC
Iso-Pentane
                                   2.20E-10
                                       2
2-ME-C4 + CL = HCL + #1.734 RO2C + #.123 RO2XC + #.123 zRNO3 + #.869 xHO2 + #.008 xMEO2 + #.044 xHCHO + #.482 xCCHO + #.381 xRCHO + #.439 xACET + #.042 xMEK + yR6OOH + #.623 XC
2,2-Dimethyl Butane
                                   1.96E-10
                                      e1
22-DM-C4 + CL = HCL + #2.068 RO2C + #.167 RO2XC + #.167 zRNO3 + #.549 xHO2 + #.016 xMEO2 + #.268 xTBUO + #.409 xHCHO + #.638 xCCHO + #.185 xRCHO + #.363 xACET + #.016 xMEK + yR6OOH + #.513 XC
2,3-Dimethyl Butane
                                   2.30E-10
                                       2
23-DM-C4 + CL = HCL + #1.733 RO2C + #.164 RO2XC + #.164 zRNO3 + #.836 xHO2 + #.047 xHCHO + #.039 xCCHO + #.456 xRCHO + #.734 xACET + #.001 xMEK + yR6OOH + #1.315 XC
2-Methyl Pentane
                                   2.90E-10
                                       2
2-ME-C5 + CL = HCL + #1.661 RO2C + #.193 RO2XC + #.193 zRNO3 + #.807 xHO2 + #.001 xHCHO + #.004 xCCHO + #.625 xRCHO + #.234 xACET + #.006 xMEK + #.183 xPROD2 + yR6OOH + #1.139 XC
3-Methylpentane
                                   2.80E-10
                                       2
3-ME-C5 + CL = HCL + #1.832 RO2C + #.191 RO2XC + #.191 zRNO3 + #.809 xHO2 + #.019 xHCHO + #.784 xCCHO + #.282 xRCHO + #.344 xMEK + #.047 xPROD2 + yR6OOH + #.762 XC
2,3-Dimethyl Pentane
                                   2.79E-10
                                      e1
23-DM-C5 + CL = HCL + #1.846 RO2C + #.253 RO2XC + #.253 zRNO3 + #.747 xHO2 + #.038 xHCHO + #.415 xCCHO + #.313 xRCHO + #.41 xACET + #.203 xMEK + #.047 xPROD2 + yR6OOH + #1.351 XC
2,4-Dimethyl Pentane
                                   2.90E-10
                                       2
24-DM-C5 + CL = HCL + #1.857 RO2C + #.234 RO2XC + #.234 zRNO3 + #.766 xHO2 + #.213 xHCHO + #.009 xCCHO + #.661 xRCHO + #.23 xACET + #.008 xMEK + #.082 xPROD2 + yR6OOH + #2.163 XC
2-Methyl Hexane
                                   3.50E-10
                                       2
2-ME-C6 + CL = HCL + #1.585 RO2C + #.267 RO2XC + #.267 zRNO3 + #.733 xHO2 + #.008 xHCHO + #.019 xCCHO + #.362 xRCHO + #.121 xACET + #.378 xPROD2 + yR6OOH + #1.633 XC
3-Methyl Hexane
                                   3.30E-10
                                      e1
3-ME-C6 + CL = HCL + #1.67 RO2C + #.269 RO2XC + #.269 zRNO3 + #.731 xHO2 + #.005 xHCHO + #.171 xCCHO + #.433 xRCHO + #.133 xMEK + #.289 xPROD2 + yR6OOH + #1.479 XC
2,4-Dimethyl Hexane
                                   3.41E-10
                                      e1
24-DM-C6 + CL = HCL + #1.752 RO2C + #.34 RO2XC + #.34 zRNO3 + #.66 xHO2 + #.103 xHCHO + #.212 xCCHO + #.427 xRCHO + #.055 xACET + #.065 xMEK + #.227 xPROD2 + yR6OOH + #2.365 XC
2-Methyl Heptane
                                   3.91E-10
                                      e1
2-ME-C7 + CL = HCL + #1.489 RO2C + #.338 RO2XC + #.338 zRNO3 + #.662 xHO2 + #.006 xHCHO + #.01 xCCHO + #.229 xRCHO + #.021 xACET + #.45 xPROD2 + yR6OOH + #2.494 XC
4-Methyl Heptane
                                   3.92E-10
                                      e1
4-ME-C7 + CL = HCL + #1.542 RO2C + #.338 RO2XC + #.338 zRNO3 + #.662 xHO2 + #.002 xHCHO + #.004 xCCHO + #.326 xRCHO + #.041 xMEK + #.411 xPROD2 + yR6OOH + #2.353 XC
2,4-Dimethyl Heptane
                                   4.03E-10
                                      e1
24-DM-C7 + CL = HCL + #1.588 RO2C + #.396 RO2XC + #.396 zRNO3 + #.604 xHO2 + #.071 xHCHO + #.007 xCCHO + #.387 xRCHO + #.019 xACET + #.014 xMEK + #.339 xPROD2 + yR6OOH + #3.226 XC
2-Methyl Octane
                                   4.53E-10
                                      e1
2-ME-C8 + CL = HCL + #1.447 RO2C + #.4 RO2XC + #.4 zRNO3 + #.6 xHO2 + #.001 xHCHO + #.136 xRCHO + #.013 xACET + #.469 xPROD2 + yR6OOH + #3.336 XC
4-Methyl Octane
                                   4.54E-10
                                      e1
4-ME-C8 + CL = HCL + #1.472 RO2C + #.395 RO2XC + #.395 zRNO3 + #.605 xHO2 + #.001 xHCHO + #.012 xCCHO + #.188 xRCHO + #.004 xMEK + #.482 xPROD2 + yR6OOH + #3.132 XC
2,6-Dimethyl Octane
                                   4.64E-10
                                      e1
26DM-C8 + CL = HCL + #1.507 RO2C + #.429 RO2XC + #.429 zRNO3 + #.571 xHO2 + #.001 xHCHO + #.071 xCCHO + #.262 xRCHO + #.054 xACET + #.036 xMEK + #.318 xPROD2 + yR6OOH + #4.283 XC
2-Methyl Nonane
                                   5.14E-10
                                      e1
2-ME-C9 + CL = HCL + #1.399 RO2C + #.435 RO2XC + #.435 zRNO3 + #.565 xHO2 + #.106 xRCHO + #.012 xACET + #.46 xPROD2 + yR6OOH + #4.279 XC
4-Methyl Nonane
                                   5.15E-10
                                      e1
4-ME-C9 + CL = HCL + #1.418 RO2C + #.429 RO2XC + #.429 zRNO3 + #.571 xHO2 + #.001 xHCHO + #.007 xCCHO + #.161 xRCHO + #.002 xMEK + #.466 xPROD2 + yR6OOH + #4.121 XC
2,6-Dimethyl Nonane
                                   5.26E-10
                                      e1
26DM-C9 + CL = HCL + #1.455 RO2C + #.458 RO2XC + #.458 zRNO3 + #.542 xHO2 + #.001 xHCHO + #.001 xCCHO + #.219 xRCHO + #.049 xACET + #.003 xMEK + #.371 xPROD2 + yR6OOH + #5.21 XC
3-Methyl Decane
                                   5.77E-10
                                      e1
3-ME-C10 + CL = HCL + #1.391 RO2C + #.458 RO2XC + #.458 zRNO3 + #.542 xHO2 + #.001 xHCHO + #.032 xCCHO + #.096 xRCHO + #.01 xMEK + #.449 xPROD2 + yR6OOH + #5.166 XC
4-Methyl Decane
                                   5.77E-10
                                      e1
4-ME-C10 + CL = HCL + #1.396 RO2C + #.458 RO2XC + #.458 zRNO3 + #.542 xHO2 + #.001 xHCHO + #.001 xCCHO + #.118 xRCHO + #.002 xMEK + #.462 xPROD2 + yR6OOH + #5.118 XC
3,6-Dimethyl Decane
                                   5.89E-10
                                      e1
36DM-C10 + CL = HCL + #1.46 RO2C + #.482 RO2XC + #.482 zRNO3 + #.518 xHO2 + #.001 xHCHO + #.056 xCCHO + #.165 xRCHO + #.029 xMEK + #.406 xPROD2 + yR6OOH + #5.955 XC
3-Methyl Undecane
                                   6.39E-10
                                      e1
3-ME-C11 + CL = HCL + #1.367 RO2C + #.469 RO2XC + #.469 zRNO3 + #.531 xHO2 + #.001 xHCHO + #.029 xCCHO + #.084 xRCHO + #.009 xMEK + #.449 xPROD2 + yR6OOH + #6.146 XC
5-Methyl Undecane
                                   6.39E-10
                                      e1
5-ME-C11 + CL = HCL + #1.366 RO2C + #.469 RO2XC + #.469 zRNO3 + #.531 xHO2 + #.003 xCCHO + #.098 xRCHO + #.464 xPROD2 + yR6OOH + #6.098 XC
2,4,6,8-Tetramethyl Nonane
                                   5.49E-10
                                      e1
2468TMC9 + CL = #.488 xHO2 + #1.531 RO2C + #.512 RO2XC + #.512 zRNO3 + HCL + #.011 xHCHO + #.001 xCCHO + #.35 xRCHO + #.038 xACET + #.001 xMEK + #.28 xPROD2 + yR6OOH + #7.067 XC
3,6-Dimethyl Undecane
                                   6.51E-10
                                      e1
36DM-C11 + CL = HCL + #1.428 RO2C + #.488 RO2XC + #.488 zRNO3 + #.512 xHO2 + #.001 xHCHO + #.046 xCCHO + #.152 xRCHO + #.023 xMEK + #.406 xPROD2 + yR6OOH + #6.993 XC
3-Methyl Dodecane
                                   7.01E-10
                                      e1
3-ME-C12 + CL = HCL + #1.351 RO2C + #.476 RO2XC + #.476 zRNO3 + #.524 xHO2 + #.001 xHCHO + #.026 xCCHO + #.076 xRCHO + #.008 xMEK + #.45 xPROD2 + yR6OOH + #7.13 XC
5-Methyl Dodecane
                                   7.01E-10
                                      e1
5-ME-C12 + CL = HCL + #1.352 RO2C + #.478 RO2XC + #.478 zRNO3 + #.522 xHO2 + #.003 xCCHO + #.087 xRCHO + #.461 xPROD2 + yR6OOH + #7.099 XC
Cyclopentane
                                   3.09E-10
                                      e1
CYCC5 + CL = HCL + #2.438 RO2C + #.224 RO2XC + #.224 zRNO3 + #.776 xHO2 + #.054 xCO + #.756 xRCHO + #.02 xMEK + yR6OOH + #1.255 XC
Cyclohexane
                                   3.50E-10
                                       2
CYCC6 + CL = HCL + #1.272 RO2C + #.201 RO2XC + #.201 zRNO3 + #.799 xHO2 + #.203 xRCHO + #.597 xPROD2 + yR6OOH + #.608 XC
Methylcyclopentane
                                   3.21E-10
                                      e1
ME-CYCC5 + CL = HCL + #2.241 RO2C + #.31 RO2XC + #.31 zRNO3 + #.596 xHO2 + #.092 xMECO3 + #.003 xRCO3 + #.028 xCO + #.052 xHCHO + #.679 xRCHO + #.001 xMEK + #.007 xPROD2 + yR6OOH + #1.785 XC
1,2-dimethylcyclopentane
                                   3.32E-10
                                      e1
2468TMC9 + CL = #.488 xHO2 + #1.531 RO2C + #.512 RO2XC + #.512 zRNO3 + HCL + #.011 xHCHO + #.001 xCCHO + #.35 xRCHO + #.038 xACET + #.001 xMEK + #.28 xPROD2 + yR6OOH + #7.067 XC
Ethyl Cyclopentane
                                   3.83E-10
                                      e1
2468TMC9 + CL = #.488 xHO2 + #1.531 RO2C + #.512 RO2XC + #.512 zRNO3 + HCL + #.011 xHCHO + #.001 xCCHO + #.35 xRCHO + #.038 xACET + #.001 xMEK + #.28 xPROD2 + yR6OOH + #7.067 XC
Methylcyclohexane
                                   3.90E-10
                                       2
ME-CYCC6 + CL = HCL + #1.6 RO2C + #.318 RO2XC + #.318 zRNO3 + #.682 xHO2 + #.044 xHCHO + #.003 xCCHO + #.377 xRCHO + #.31 xPROD2 + yR6OOH + #2.057 XC
Ethylcyclohexane
                                   4.45E-10
                                      e1
ET-CYCC6 + CL = HCL + #1.528 RO2C + #.365 RO2XC + #.365 zRNO3 + #.634 xHO2 + #.002 xHCHO + #.135 xCCHO + #.298 xRCHO + #.34 xPROD2 + yR6OOH + #2.602 XC
Propene
                                   2.67E-10
                                       3
PROPENE + CL = #.124 HCL + #.971 RO2C + #.029 RO2XC + #.029 zRNO3 + #.971 xHO2 + #.124 xMACR + yROOH + #2.328 XC
1-Butene
                                   3.39E-10
                                       4
2468TMC9 + CL = #.488 xHO2 + #1.531 RO2C + #.512 RO2XC + #.512 zRNO3 + HCL + #.011 xHCHO + #.001 xCCHO + #.35 xRCHO + #.038 xACET + #.001 xMEK + #.28 xPROD2 + yR6OOH + #7.067 XC (Mechanism is average of those for propene and 1-butene)
1-Pentene
                                   4.05E-10
                                       4
1-PENTEN + CL = #.408 HCL + #1.666 RO2C + #.136 RO2XC + #.136 zRNO3 + #.864 xHO2 + #.039 xHCHO + #.225 xCCHO + #.079 xRCHO + #.223 xMACR + #.021 xMVK + #.042 xIPRD + yR6OOH + #2.271 XC
3-Methyl-1-Butene
                                   3.52E-10
                                       5
Use mechanism derived for the 2-butenes
1-Hexene

Use mechanism and rate constant of 1-pentene
1-Heptene

Use mechanism and rate constant of 1-pentene
1-Octene

Use mechanism and rate constant of 1-pentene
1-Nonene

Use mechanism and rate constant of 1-pentene
1-Decene

Use mechanism and rate constant of 1-pentene
1-Undecene

Use mechanism and rate constant of 1-pentene
Isobutene
                                   3.25E-10
                                       5
2468TMC9 + CL = #.488 xHO2 + #1.531 RO2C + #.512 RO2XC + #.512 zRNO3 + HCL + #.011 xHCHO + #.001 xCCHO + #.35 xRCHO + #.038 xACET + #.001 xMEK + #.28 xPROD2 + yR6OOH + #7.067 XC
2-Methyl-1-Butene
                                   3.82E-10
                                       5
2468TMC9 + CL = #.488 xHO2 + #1.531 RO2C + #.512 RO2XC + #.512 zRNO3 + HCL + #.011 xHCHO + #.001 xCCHO + #.35 xRCHO + #.038 xACET + #.001 xMEK + #.28 xPROD2 + yR6OOH + #7.067 XC
cis-2-Butene
                                   3.88E-10
                                       5
C-2-BUTE + CL = #.199 HCL + #.971 RO2C + #.079 RO2XC + #.079 zRNO3 + #.919 xHO2 + #.002 xMEO2 + #.047 xHCHO + #.104 xMVK + #.08 xIPRD + yROOH + #2.66 XC
trans-2-Butene
                                   3.55E-10
                                       3
T-2-BUTE + CL = #.199 HCL + #.923 RO2C + #.077 RO2XC + #.077 zRNO3 + #.921 xHO2 + #.002 xMEO2 + #.104 xMVK + #.082 xIPRD + yROOH + #2.709 XC
2-Methyl-2-Butene
                                   3.23E-10
                                       5
Use mechanism derived for the 2-butenes
cis-2-Pentene
                                   3.94E-10
                                      e1
C-2-PENT + CL = #.33 HCL + #1.729 RO2C + #.14 RO2XC + #.14 zRNO3 + #.282 xHO2 + #.001 xMEO2 + #.577 xCL + #.116 xHCHO + #.742 xCCHO + #.577 xRCHO + #.052 xMVK + #.231 xIPRD + yR6OOH + #-.535 XC
trans-2-Pentene
                                   3.94E-10
                                      e1
T-2-PENT + CL = #.33 HCL + #1.634 RO2C + #.134 RO2XC + #.134 zRNO3 + #.287 xHO2 + #.002 xMEO2 + #.577 xCL + #.078 xHCHO + #.687 xCCHO + #.577 xRCHO + #.052 xMVK + #.237 xIPRD + yR6OOH + #-.381 XC
Cis-2-Hexene

Use mechanism and rate constant derived for the 2-pentenes
Trans-2-Hexene

Use mechanism and rate constant derived for the 2-pentenes
Trans-2-Heptene

Use mechanism and rate constant derived for the 2-pentenes
Trans-3-Heptene

Use mechanism and rate constant derived for the 2-pentenes
Trans-4-Octene

Use mechanism and rate constant derived for the 2-pentenes
Trans-4-Nonene

Use mechanism and rate constant derived for the 2-pentenes
3,4-Diethyl-2-Hexene

Use mechanism and rate constant derived for the 2-pentenes
Trans-4-Decene

Use mechanism and rate constant derived for the 2-pentenes
Trans-5-Undecene

Use mechanism and rate constant derived for the 2-pentenes
Cyclohexene

Use mechanism and rate constant derived for the 2-pentenes
1,3-Butadiene
                                   4.90E-10
                                       2
13-BUTDE + CL = #.39 xHO2 + #.541 xCL + #1.884 RO2C + #.069 RO2XC + #.069 zRNO3 + #.863 xHCHO + #.457 xMACR + #.473 xIPRD + yROOH + #-1.47 XC
alpha Pinene
                                   5.46E-10
                                      e1
A-PINENE + CL = #.548 HCL + #2.258 RO2C + #.582 RO2XC + #.582 zRNO3 + #.252 xHO2 + #.034 xMECO3 + #.05 xRCO3 + #.016 xMACO3 + #.068 xCL + #.035 xCO + #.158 xHCHO + #.185 xRCHO + #.274 xACET + #.007 xGLY + #.003 xBACL + #.006 xAFG1 + #.006 xAFG2 + #.003 xMVK + #.158 xIPRD + yROOH + #-6.231 XC
Toluene
                                   6.20E-11
                                       6
TOLUENE + CL = #.894 RO2C + #.106 RO2XC + #.106 zRNO3 + #.894 xHO2 + #.894 xBALD + yR6OOH + #.106 XC
Ethyl Benzene
                                   1.70E-10
                                      e1
C2-BENZ + CL = #.864 RO2C + #.136 RO2XC + #.136 zRNO3 + #.864 xHO2 + #.864 xPROD2 + yR6OOH + #2 XC
n-Propyl Benzene
                                   2.28E-10
                                      e1
N-C3-BEN + CL = #.838 RO2C + #.162 RO2XC + #.162 zRNO3 + #.838 xHO2 + #.838 xPROD2 + yR6OOH + #3 XC
Isopropyl Benzene (cumene)
                                   1.56E-10
                                      e1
I-C3-BEN + CL = #.838 RO2C + #.162 RO2XC + #.162 zRNO3 + #.838 xHO2 + #.838 xPROD2 + yR6OOH + #3 XC
C10 Monosubstituted Benzenes
                                   2.48E-10
                                      e1
C10-BEN1 + CL = #.82 RO2C + #.18 RO2XC + #.18 zRNO3 + #.82 xHO2 + #.82 xPROD2 + yR6OOH + #4 XC
t-Butyl Benzene
                                   9.82E-11
                                      e1
T-C4-BEN + CL = #.82 RO2C + #.18 RO2XC + #.18 zRNO3 + #.82 xHO2 + #.82 xPROD2 + yR6OOH + #4 XC
C11 Monosubstituted Benzenes
                                   3.10E-10
                                      e1
C11-BEN1 + CL = #.808 RO2C + #.192 RO2XC + #.192 zRNO3 + #.808 xHO2 + #.808 xPROD2 + yR6OOH + #5 XC
C12 Monosubstituted Benzenes
                                   3.72E-10
                                      e1
C12-BEN1 + CL = #.8 RO2C + #.2 RO2XC + #.2 zRNO3 + #.8 xHO2 + #.8 xPROD2 + yR6OOH + #6 XC
C13 Monosubstituted Benzenes
                                   4.33E-10
                                      e1
C13-BEN1 + CL = #.795 RO2C + #.205 RO2XC + #.205 zRNO3 + #.795 xHO2 + #.795 xPROD2 + yR6OOH + #7 XC
C14 Monosubstituted Benzenes
                                   4.95E-10
                                      e1
C14-BEN1 + CL = #.792 RO2C + #.208 RO2XC + #.208 zRNO3 + #.792 xHO2 + #.792 xPROD2 + yR6OOH + #8 XC
C15 Monosubstituted Benzenes
                                   5.57E-10
                                      e1
C15-BEN1 + CL = #.791 RO2C + #.209 RO2XC + #.209 zRNO3 + #.791 xHO2 + #.791 xPROD2 + yR6OOH + #9 XC
C16 Monosubstituted Benzenes
                                   6.19E-10
                                      e1
C16-BEN1 + CL = #.789 RO2C + #.211 RO2XC + #.211 zRNO3 + #.789 xHO2 + #.789 xPROD2 + yR6OOH + #10 XC
m-Xylene
                                   1.35E-10
                                       6
M-XYLENE + CL = #.864 RO2C + #.136 RO2XC + #.136 zRNO3 + #.864 xHO2 + #.864 xBALD + yR6OOH + #1.136 XC
o-Xylene
                                   1.40E-10
                                       6
O-XYLENE + CL = #.864 RO2C + #.136 RO2XC + #.136 zRNO3 + #.864 xHO2 + #.864 xBALD + yR6OOH + #1.136 XC
p-Xylene
                                   1.44E-10
                                       6
P-XYLENE + CL = #.864 RO2C + #.136 RO2XC + #.136 zRNO3 + #.864 xHO2 + #.864 xBALD + yR6OOH + #1.136 XC
m-Ethyl Toluene
                                   2.39E-10
                                      e1
M-ET-TOL + CL = #.838 RO2C + #.162 RO2XC + #.162 zRNO3 + #.838 xHO2 + #.243 xBALD + #.595 xPROD2 + yR6OOH + #2.757 XC
o-Ethyl Toluene
                                   2.39E-10
                                      e1
O-ET-TOL + CL = #.838 RO2C + #.162 RO2XC + #.162 zRNO3 + #.838 xHO2 + #.243 xBALD + #.595 xPROD2 + yR6OOH + #2.757 XC
p-Ethyl Toluene
                                   2.39E-10
                                      e1
P-ET-TOL + CL = #.838 RO2C + #.162 RO2XC + #.162 zRNO3 + #.838 xHO2 + #.243 xBALD + #.595 xPROD2 + yR6OOH + #2.757 XC
m-c10 disubstituted benzenes
                                   3.02E-10
                                      e1
MC10BEN2 + CL = #.82 RO2C + #.18 RO2XC + #.18 zRNO3 + #.82 xHO2 + #.094 xBALD + #.725 xPROD2 + yR6OOH + #3.906 XC
o-c10 disubstituted benzenes
                                   3.02E-10
                                      e1
OC10BEN2 + CL = #.82 RO2C + #.18 RO2XC + #.18 zRNO3 + #.82 xHO2 + #.094 xBALD + #.725 xPROD2 + yR6OOH + #3.906 XC
p-c10 disubstituted benzenes
                                   3.02E-10
                                      e1
PC10BEN2 + CL = #.82 RO2C + #.18 RO2XC + #.18 zRNO3 + #.82 xHO2 + #.094 xBALD + #.725 xPROD2 + yR6OOH + #3.906 XC
1-methyl-4-isopropylbenzene (p-cymene)
                                   2.25E-10
                                      e1
P-CYMENE + CL = #.82 RO2C + #.18 RO2XC + #.18 zRNO3 + #.82 xHO2 + #.253 xBALD + #.567 xPROD2 + yR6OOH + #3.747 XC
m-c11 disubstituted benzenes
                                   3.53E-10
                                      e1
MC11BEN2 + CL = #.808 RO2C + #.192 RO2XC + #.192 zRNO3 + #.808 xHO2 + #.054 xBALD + #.754 xPROD2 + yR6OOH + #4.946 XC
o-c11 disubstituted benzenes
                                   3.53E-10
                                      e1
OC11BEN2 + CL = #.808 RO2C + #.192 RO2XC + #.192 zRNO3 + #.808 xHO2 + #.054 xBALD + #.754 xPROD2 + yR6OOH + #4.946 XC
p-c11 disubstituted benzenes
                                   3.53E-10
                                      e1
PC11BEN2 + CL = #.808 RO2C + #.192 RO2XC + #.192 zRNO3 + #.808 xHO2 + #.054 xBALD + #.754 xPROD2 + yR6OOH + #4.946 XC
m-c12 disubstituted benzenes
                                   4.00E-10
                                      e1
MC12BEN2 + CL = #.8 RO2C + #.2 RO2XC + #.2 zRNO3 + #.8 xHO2 + #.035 xBALD + #.765 xPROD2 + yR6OOH + #5.965 XC
o-c12 disubstituted benzenes
                                   4.00E-10
                                      e1
OC12BEN2 + CL = #.8 RO2C + #.2 RO2XC + #.2 zRNO3 + #.8 xHO2 + #.035 xBALD + #.765 xPROD2 + yR6OOH + #5.965 XC
p-c12 disubstituted benzenes
                                   4.00E-10
                                      e1
PC12BEN2 + CL = #.8 RO2C + #.2 RO2XC + #.2 zRNO3 + #.8 xHO2 + #.035 xBALD + #.765 xPROD2 + yR6OOH + #5.965 XC
m-c13 disubstituted benzenes
                                   4.58E-10
                                      e1
MC13BEN2 + CL = #.795 RO2C + #.205 RO2XC + #.205 zRNO3 + #.795 xHO2 + #.795 xPROD2 + yR6OOH + #7 XC
o-c13 disubstituted benzenes
                                   4.58E-10
                                      e1
OC13BEN2 + CL = #.795 RO2C + #.205 RO2XC + #.205 zRNO3 + #.795 xHO2 + #.795 xPROD2 + yR6OOH + #7 XC
p-c13 disubstituted benzenes
                                   4.58E-10
                                      e1
PC13BEN2 + CL = #.795 RO2C + #.205 RO2XC + #.205 zRNO3 + #.795 xHO2 + #.795 xPROD2 + yR6OOH + #7 XC
m-c14 disubstituted benzenes
                                   5.20E-10
                                      e1
MC14BEN2 + CL = #.792 RO2C + #.208 RO2XC + #.208 zRNO3 + #.792 xHO2 + #.792 xPROD2 + yR6OOH + #8 XC
o-c14 disubstituted benzenes
                                   5.20E-10
                                      e1
OC14BEN2 + CL = #.792 RO2C + #.208 RO2XC + #.208 zRNO3 + #.792 xHO2 + #.792 xPROD2 + yR6OOH + #8 XC
p-c14 disubstituted benzenes
                                   5.20E-10
                                      e1
PC14BEN2 + CL = #.792 RO2C + #.208 RO2XC + #.208 zRNO3 + #.792 xHO2 + #.792 xPROD2 + yR6OOH + #8 XC
m-c15 disubstituted benzenes
                                   5.81E-10
                                      e1
MC15BEN2 + CL = #.791 RO2C + #.209 RO2XC + #.209 zRNO3 + #.791 xHO2 + #.791 xPROD2 + yR6OOH + #9 XC
o-c15 disubstituted benzenes
                                   5.81E-10
                                      e1
OC15BEN2 + CL = #.791 RO2C + #.209 RO2XC + #.209 zRNO3 + #.791 xHO2 + #.791 xPROD2 + yR6OOH + #9 XC
p-c15 disubstituted benzenes
                                   5.81E-10
                                      e1
PC15BEN2 + CL = #.791 RO2C + #.209 RO2XC + #.209 zRNO3 + #.791 xHO2 + #.791 xPROD2 + yR6OOH + #9 XC
m-c16 disubstituted benzenes
                                   6.43E-10
                                      e1
MC16BEN2 + CL = #.789 RO2C + #.211 RO2XC + #.211 zRNO3 + #.789 xHO2 + #.789 xPROD2 + yR6OOH + #10 XC
o-c16 disubstituted benzenes
                                   6.43E-10
                                      e1
OC16BEN2 + CL = #.789 RO2C + #.211 RO2XC + #.211 zRNO3 + #.789 xHO2 + #.789 xPROD2 + yR6OOH + #10 XC
p-c16 disubstituted benzenes
                                   6.43E-10
                                      e1
PC16BEN2 + CL = #.789 RO2C + #.211 RO2XC + #.211 zRNO3 + #.789 xHO2 + #.789 xPROD2 + yR6OOH + #10 XC
1,2,3-Trimethyl Benzene
                                   2.42E-10
                                      e2
123-TMB + CL = #.838 RO2C + #.162 RO2XC + #.162 zRNO3 + #.838 xHO2 + #.838 xBALD + yR6OOH + #2.162 XC
1,2,4-Trimethyl Benzene
                                   2.42E-10
                                      e2
124-TMB + CL = #.838 RO2C + #.162 RO2XC + #.162 zRNO3 + #.838 xHO2 + #.838 xBALD + yR6OOH + #2.162 XC
1,3,5-Trimethyl Benzene
                                   2.42E-10
                                       7
135-TMB + CL = #.838 RO2C + #.162 RO2XC + #.162 zRNO3 + #.838 xHO2 + #.838 xBALD + yR6OOH + #2.162 XC
1,2,3-c10 trisubstituted benzenes
                                   3.09E-10
                                      e1
3C10BEN3 + CL = #.808 RO2C + #.192 RO2XC + #.192 zRNO3 + #.808 xHO2 + #.363 xBALD + #.445 xPROD2 + yR6OOH + #3.637 XC
1,2,4-c10 trisubstituted benzenes
                                   3.09E-10
                                      e1
4C10BEN3 + CL = #.808 RO2C + #.192 RO2XC + #.192 zRNO3 + #.808 xHO2 + #.363 xBALD + #.445 xPROD2 + yR6OOH + #3.637 XC
1,3,5-c10 trisubstituted benzenes
                                   3.09E-10
                                      e1
5C10BEN3 + CL = #.808 RO2C + #.192 RO2XC + #.192 zRNO3 + #.808 xHO2 + #.363 xBALD + #.445 xPROD2 + yR6OOH + #3.637 XC
1,2,3-c11 trisubstituted benzenes
                                   3.88E-10
                                      e1
3C11BEN3 + CL = #.8 RO2C + #.2 RO2XC + #.2 zRNO3 + #.8 xHO2 + #.215 xBALD + #.585 xPROD2 + yR6OOH + #4.785 XC
1,2,4-c11 trisubstituted benzenes
                                   3.88E-10
                                      e1
4C11BEN3 + CL = #.8 RO2C + #.2 RO2XC + #.2 zRNO3 + #.8 xHO2 + #.215 xBALD + #.585 xPROD2 + yR6OOH + #4.785 XC
1,3,5-c11 trisubstituted benzenes
                                   3.88E-10
                                      e1
5C11BEN3 + CL = #.8 RO2C + #.2 RO2XC + #.2 zRNO3 + #.8 xHO2 + #.215 xBALD + #.585 xPROD2 + yR6OOH + #4.785 XC
1,2,3-c12 trisubstituted benzenes
                                   4.13E-10
                                      e1
3C12BEN3 + CL = #.795 RO2C + #.205 RO2XC + #.205 zRNO3 + #.795 xHO2 + #.179 xBALD + #.616 xPROD2 + yR6OOH + #5.821 XC
1,2,4-c12 trisubstituted benzenes
                                   4.13E-10
                                      e1
4C12BEN3 + CL = #.795 RO2C + #.205 RO2XC + #.205 zRNO3 + #.795 xHO2 + #.179 xBALD + #.616 xPROD2 + yR6OOH + #5.821 XC
1,3,5-c12 trisubstituted benzenes
                                   4.13E-10
                                      e1
5C12BEN3 + CL = #.795 RO2C + #.205 RO2XC + #.205 zRNO3 + #.795 xHO2 + #.179 xBALD + #.616 xPROD2 + yR6OOH + #5.821 XC
1,2,3-c13 trisubstituted benzenes
                                   4.87E-10
                                      e1
3C13BEN3 + CL = #.792 RO2C + #.208 RO2XC + #.208 zRNO3 + #.792 xHO2 + #.113 xBALD + #.679 xPROD2 + yR6OOH + #6.887 XC
1,2,4-c13 trisubstituted benzenes
                                   4.87E-10
                                      e1
4C13BEN3 + CL = #.792 RO2C + #.208 RO2XC + #.208 zRNO3 + #.792 xHO2 + #.113 xBALD + #.679 xPROD2 + yR6OOH + #6.887 XC
1,3,5-c13 trisubstituted benzenes
                                   4.87E-10
                                      e1
5C13BEN3 + CL = #.792 RO2C + #.208 RO2XC + #.208 zRNO3 + #.792 xHO2 + #.113 xBALD + #.679 xPROD2 + yR6OOH + #6.887 XC
1,2,3-c14 trisubstituted benzenes
                                   5.50E-10
                                      e1
3C14BEN3 + CL = #.792 RO2C + #.208 RO2XC + #.208 zRNO3 + #.792 xHO2 + #.075 xBALD + #.717 xPROD2 + yR6OOH + #7.925 XC
1,2,4-c14 trisubstituted benzenes
                                   5.50E-10
                                      e1
4C14BEN3 + CL = #.792 RO2C + #.208 RO2XC + #.208 zRNO3 + #.792 xHO2 + #.075 xBALD + #.717 xPROD2 + yR6OOH + #7.925 XC
1,3,5-c14 trisubstituted benzenes
                                   5.50E-10
                                      e1
5C14BEN3 + CL = #.792 RO2C + #.208 RO2XC + #.208 zRNO3 + #.792 xHO2 + #.075 xBALD + #.717 xPROD2 + yR6OOH + #7.925 XC
1,2,3-c15 trisubstituted benzenes
                                   5.88E-10
                                      e1
3C15BEN3 + CL = #.791 RO2C + #.209 RO2XC + #.209 zRNO3 + #.791 xHO2 + #.047 xBALD + #.744 xPROD2 + yR6OOH + #8.953 XC
1,2,4-c15 trisubstituted benzenes
                                   5.88E-10
                                      e1
4C15BEN3 + CL = #.791 RO2C + #.209 RO2XC + #.209 zRNO3 + #.791 xHO2 + #.047 xBALD + #.744 xPROD2 + yR6OOH + #8.953 XC
1,3,5-c15 trisubstituted benzenes
                                   5.88E-10
                                      e1
5C15BEN3 + CL = #.791 RO2C + #.209 RO2XC + #.209 zRNO3 + #.791 xHO2 + #.047 xBALD + #.744 xPROD2 + yR6OOH + #8.953 XC
1,2,3-c16 trisubstituted benzenes
                                   6.49E-10
                                      e1
3C16BEN3 + CL = #.789 RO2C + #.211 RO2XC + #.211 zRNO3 + #.789 xHO2 + #.021 xBALD + #.768 xPROD2 + yR6OOH + #9.979 XC
1,2,4-c16 trisubstituted benzenes
                                   6.49E-10
                                      e1
4C16BEN3 + CL = #.789 RO2C + #.211 RO2XC + #.211 zRNO3 + #.789 xHO2 + #.021 xBALD + #.768 xPROD2 + yR6OOH + #9.979 XC
1,3,5-c16 trisubstituted benzenes
                                   6.49E-10
                                      e1
5C16BEN3 + CL = #.789 RO2C + #.211 RO2XC + #.211 zRNO3 + #.789 xHO2 + #.021 xBALD + #.768 xPROD2 + yR6OOH + #9.979 XC
PROD2 Species #1
                                   1.35E-10
                                      e1
PROD2-1 + CL = HCL + #.512 HO2 + #.456 RO2C + #.032 RO2XC + #.032 zRNO3 + #.512 RCHO + #.429 xHO2 + #.018 xMECO3 + #.009 xRCO3 + #.438 xHCHO + #.447 xRCHO + #.488 yR6OOH + #1.431 XC
PROD2 Species #2
                                   1.46E-10
                                      e1
PROD2-2 + CL = HCL + #.476 HO2 + #.651 RO2C + #.063 RO2XC + #.063 zRNO3 + #.476 RCHO + #.445 xHO2 + #.016 xMECO3 + #.621 xHCHO + #.208 xRCHO + #.253 xMEK + #.524 yR6OOH + #1.904 XC
PROD2 Species #3
                                   1.78E-10
                                      e1
PROD2-3 + CL = HCL + #.255 HO2 + #.687 RO2C + #.107 RO2XC + #.107 zRNO3 + #.255 PROD2 + #.568 xHO2 + #.069 xRCO3 + #.124 xHCHO + #.313 xCCHO + #.624 xRCHO + #.745 yR6OOH + #1.994 XC
PROD2 Species #4
                                   2.41E-10
                                      e1
PROD2-4 + CL = HCL + #.18 HO2 + #.782 RO2C + #.164 RO2XC + #.164 zRNO3 + #.18 PROD2 + #.629 xHO2 + #.027 xRCO3 + #.231 xCCHO + #.882 xRCHO + #.002 xPROD2 + #.82 yR6OOH + #2.73 XC
PROD2 Species #5
                                   3.02E-10
                                      e1
PROD2-5 + CL = HCL + #.146 HO2 + #.821 RO2C + #.214 RO2XC + #.214 zRNO3 + #.146 PROD2 + #.634 xHO2 + #.007 xRCO3 + #.796 xRCHO + #.2 xPROD2 + #.854 yR6OOH + #3.237 XC
RNO3 Species #1
                                   5.05E-11
                                      e1
RNO3-1 + CL = HCL + #.105 NO2 + #1.408 RO2C + #.065 RO2XC + #.065 zRNO3 + #.105 MEK + #.115 xNO2 + #.715 xHO2 + #.23 xCCHO + #.715 xRNO3 + #.895 yROOH + #.065 XN + #-1.559 XC
RNO3 Species #2
                                   1.56E-10
                                      e1
RNO3-2 + CL = HCL + #.052 NO2 + #.291 HO2 + #.837 RO2C + #.058 RO2XC + #.058 zRNO3 + #.052 RCHO + #.291 RNO3 + #.599 xHO2 + #.003 xHCHO + #.373 xCCHO + #.599 xRNO3 + #.657 yR6OOH + #.058 XN + #-1.594 XC
RNO3 Species #3
                                   1.45E-10
                                      e1
RNO3-3 + CL = HCL + #.037 NO2 + #1.511 RO2C + #.185 RO2XC + #.185 zRNO3 + #.037 PROD2 + #.405 xNO2 + #.373 xHO2 + #.077 xHCHO + #.991 xCCHO + #.05 xRCHO + #.031 xMEK + #.06 xPROD2 + #.373 xRNO3 + #.963 yR6OOH + #.185 XN + #-.261 XC
RNO3 Species #4
                                   2.43E-10
                                      e1
RNO3-4 + CL = HCL + #.021 NO2 + #.036 HO2 + #1.158 RO2C + #.178 RO2XC + #.178 zRNO3 + #.021 PROD2 + #.036 RNO3 + #.159 xNO2 + #.605 xHO2 + #.008 xCCHO + #.011 xRCHO + #.159 xPROD2 + #.605 xRNO3 + #.943 yR6OOH + #.178 XN + #.952 XC
RNO3 Species #5
                                   1.61E-10
                                      e1
RNO3-5 + CL = HCL + #1.449 RO2C + #.304 RO2XC + #.304 zRNO3 + #.27 xNO2 + #.426 xHO2 + #.188 xHCHO + #.197 xCCHO + #.058 xRCHO + #.016 xACET + #.216 xMEK + #.054 xPROD2 + #.426 xRNO3 + yR6OOH + #.304 XN + #1.625 XC
RNO3 Species #6
                                   3.99E-10
                                      e1
RNO3-6 + CL = HCL + #.013 NO2 + #1.33 RO2C + #.42 RO2XC + #.42 zRNO3 + #.013 PROD2 + #.003 xNO2 + #.564 xHO2 + #.003 xPROD2 + #.564 xRNO3 + #.987 yR6OOH + #.42 XN + #4 XC
[a]	Rate constant for the reaction with Cl atoms in cm[3] molec-1 s-1. The temperature dependences are unknown, so they are assumed to be temperature independent. Footnotes for measured rate constants are as follows:
   1	IUPAC (2006) Recommendation
   2	Atkinson (1997) Recommendation
   3	Average of values tabulated by Wang et al (2002). Value of Wang et al (2002) placed on an absolute basis using the Atkinson (1997)-recommended rate constant for n-heptane.
   4	Average of value of Coquet et al (2000), placed on an absolute basis using the Atkinson (1997)-recommended n-hexane rate constant, and the value of Wang et al (2002), placed on an absolute basis using the Atkinson (1997)-recommended rate constant for n-heptane.
   5	Value of Wang et al (2002), placed on an absolute basis using the Atkinson (1997)-recommended rate constant for n-heptane.
   6	Average of values tabulated by Wang et al (2005).
   7	Wang et al (2005)
   Footnotes for estimated rate constants are as follows:
   e1	Estimated using the group-additivity estimation assignments as indicated on Table 3.
   e2	Estimated to have the same rate constant as 1,3,5-trimethylbenzene.
[b]	Mechanisms derived for the mechanism generation system except for the aromatics, whose mechanisms were derived as discussed in the "Updated Aromatics Mechanisms" section.

Table B-8.	Absorption cross sections used for the photolysis reactions for represented photoreactive VOCs that are not in the base mechanism.
                 a) Phot set HOCCHO: Glycolaldehyde photolysis
   Note: Quantum yield of 0.75 is used for all wavelengths (not shown below)
                                      wl
                                      abs

                                      wl
                                      abs

                                      wl
                                      abs

                                      wl
                                      abs

                                      wl
                                      abs

                                      wl
                                      abs

                                      205
                                   3.91E-19

                                      228
                                   6.37E-21

                                      251
                                   2.50E-20

                                      274
                                   5.40E-20

                                      297
                                   3.29E-20

                                      320
                                   3.29E-21
                                      206
                                   3.37E-19

                                      229
                                   6.37E-21

                                      252
                                   2.65E-20

                                      275
                                   5.41E-20

                                      298
                                   3.17E-20

                                      321
                                   2.85E-21
                                      207
                                   2.87E-19

                                      230
                                   6.49E-21

                                      253
                                   2.82E-20

                                      276
                                   5.39E-20

                                      299
                                   3.02E-20

                                      322
                                   2.49E-21
                                      208
                                   2.46E-19

                                      231
                                   6.44E-21

                                      254
                                   2.97E-20

                                      277
                                   5.42E-20

                                      300
                                   2.90E-20

                                      323
                                   2.13E-21
                                      209
                                   2.12E-19

                                      232
                                   6.80E-21

                                      255
                                   3.09E-20

                                      278
                                   5.37E-20

                                      301
                                   2.74E-20

                                      324
                                   1.85E-21
                                      210
                                   1.81E-19

                                      233
                                   7.23E-21

                                      256
                                   3.21E-20

                                      279
                                   5.34E-20

                                      302
                                   2.51E-20

                                      325
                                   1.47E-21
                                      211
                                   1.53E-19

                                      234
                                   7.85E-21

                                      257
                                   3.39E-20

                                      280
                                   5.34E-20

                                      303
                                   2.26E-20

                                      326
                                   1.28E-21
                                      212
                                   1.30E-19

                                      235
                                   8.33E-21

                                      258
                                   3.59E-20

                                      281
                                   5.37E-20

                                      304
                                   2.07E-20

                                      327
                                   1.05E-21
                                      213
                                   1.12E-19

                                      236
                                   8.80E-21

                                      259
                                   3.75E-20

                                      282
                                   5.37E-20

                                      305
                                   1.91E-20

                                      328
                                   8.70E-22
                                      214
                                   9.40E-20

                                      237
                                   9.39E-21

                                      260
                                   3.89E-20

                                      283
                                   5.25E-20

                                      306
                                   1.77E-20

                                      329
                                   8.40E-22
                                      215
                                   7.84E-20

                                      238
                                   1.03E-20

                                      261
                                   4.02E-20

                                      284
                                   5.12E-20

                                      307
                                   1.64E-20

                                      330
                                   6.80E-22
                                      216
                                   6.49E-20

                                      239
                                   1.11E-20

                                      262
                                   4.13E-20

                                      285
                                   5.01E-20

                                      308
                                   1.50E-20

                                      331
                                   5.80E-22
                                      217
                                   5.30E-20

                                      240
                                   1.20E-20

                                      263
                                   4.24E-20

                                      286
                                   4.93E-20

                                      309
                                   1.36E-20

                                      332
                                   4.30E-22
                                      218
                                   4.26E-20

                                      241
                                   1.28E-20

                                      264
                                   4.40E-20

                                      287
                                   4.80E-20

                                      310
                                   1.25E-20

                                      333
                                   4.00E-22
                                      219
                                   3.37E-20

                                      242
                                   1.38E-20

                                      265
                                   4.60E-20

                                      288
                                   4.67E-20

                                      311
                                   1.15E-20

                                      334
                                   4.00E-22
                                      220
                                   2.65E-20

                                      243
                                   1.50E-20

                                      266
                                   4.75E-20

                                      289
                                   4.58E-20

                                      312
                                   1.03E-20

                                      335
                                   3.90E-22
                                      221
                                   2.13E-20

                                      244
                                   1.59E-20

                                      267
                                   4.85E-20

                                      290
                                   4.50E-20

                                      313
                                   8.84E-21

                                      336
                                   0.00E+00
                                      222
                                   1.65E-20

                                      245
                                   1.71E-20

                                      268
                                   4.92E-20

                                      291
                                   4.41E-20

                                      314
                                   7.71E-21

                                      223
                                   1.36E-20

                                      246
                                   1.83E-20

                                      269
                                   4.99E-20

                                      292
                                   4.19E-20

                                      315
                                   6.89E-21

                                      224
                                   1.12E-20

                                      247
                                   1.95E-20

                                      270
                                   5.05E-20

                                      293
                                   3.96E-20

                                      316
                                   5.97E-21

                                      225
                                   9.33E-21

                                      248
                                   2.09E-20

                                      271
                                   5.14E-20

                                      294
                                   3.76E-20

                                      317
                                   5.16E-21

                                      226
                                   7.83E-21

                                      249
                                   2.22E-20

                                      272
                                   5.23E-20

                                      295
                                   3.59E-20

                                      318
                                   4.55E-21

                                      227
                                   6.91E-21

                                      250
                                   2.36E-20

                                      273
                                   5.36E-20

                                      296
                                   3.46E-20

                                      319
                                   3.96E-21

Wavelengths in nm and absorption cross-sections in cm[-2]. IUPAC (2006) recommendation (including 0.75 overall quantum yield)

        b) Phot set CONO: Absorption cross-sections for methyl nitrite
                                      wl
                                      abs

                                      wl
                                      abs

                                      wl
                                      abs

                                      wl
                                      abs

                                      wl
                                      abs

                                      wl
                                      abs
                                      250
                                   1.55e-18

                                      295
                                   8.60e-20

                                      320
                                   1.45e-19

                                      345
                                   1.45e-19

                                      370
                                   1.24e-19

                                      395
                                   2.70e-20
                                      260
                                   1.00e-18

                                      300
                                   7.00e-20

                                      325
                                   9.70e-20

                                      350
                                   2.91e-19

                                      375
                                   9.70e-20

                                      400
                                   1.10e-20
                                      280
                                   1.83e-19

                                      305
                                   6.50e-20

                                      330
                                   2.37e-19

                                      355
                                   1.78e-19

                                      380
                                   4.90e-20

                                      405
                                   1.40e-20
                                      285
                                   1.49e-19

                                      310
                                   9.10e-20

                                      335
                                   1.19e-19

                                      360
                                   1.62e-19

                                      385
                                   4.30e-20

                                      410
                                       -
                                      290
                                   1.08e-19

                                      315
                                   8.10e-20

                                      340
                                   3.07e-19

                                      365
                                   1.67e-19

                                      390
                                   4.30e-20

Wavelengths in nm and absorption cross-sections in cm[-2]. Absorption cross-sections from Calvert and Pitts (1966). Unit quantum yields assumed.

        c) Phot set CS2: Absorption cross-sections for carbon disulfide
                                      wl
                                      abs

                                      wl
                                      abs

                                      wl
                                      abs

                                      wl
                                      abs

                                      wl
                                      abs

                                      wl
                                      abs
                                      280
                                   5.30e-22

                                      296
                                   1.13e-20

                                      312
                                   6.69e-20

                                      328
                                   2.85e-20

                                      344
                                   5.56e-21

                                      360
                                   1.19e-21
                                      281
                                   6.20e-22

                                      297
                                   1.86e-20

                                      313
                                   8.15e-20

                                      329
                                   2.85e-20

                                      345
                                   3.53e-21

                                      361
                                   4.20e-22
                                      282
                                   8.00e-22

                                      298
                                   2.29e-20

                                      314
                                   7.84e-20

                                      330
                                   3.80e-20

                                      346
                                   3.50e-21

                                      362
                                   4.80e-22
                                      283
                                   1.03e-21

                                      299
                                   2.02e-20

                                      315
                                   9.44e-20

                                      331
                                   1.30e-20

                                      347
                                   3.28e-21

                                      363
                                   2.10e-22
                                      284
                                   1.22e-21

                                      300
                                   1.88e-20

                                      316
                                   7.04e-20

                                      332
                                   3.06e-20

                                      348
                                   1.09e-21

                                      364
                                   3.70e-22
                                      285
                                   1.58e-21

                                      301
                                   3.27e-20

                                      317
                                   9.46e-20