0 100 200 300 400 500 0 100 200 300 400 500 Lab: 1 ALUMINUM, UG/ L Measurement Results vs Spike Concentrations ( Matrix A, Method EPA 200.7 ICP/ AES)

AAMA Metals Data Page 1 of 13 APPENDIX B  1  2 Measured Concentration Spike Concentration 0 100 200 300 400 500 0 200 400 600 Lab: 2 ALUMINUM, UG/ L 0 100 200 300 400 500 0 100 200 300 400 Lab: 3 ALUMINUM, UG/ L 0 100 200 300 400 500 0 200 400 600 800 1000 Lab: 4 ALUMINUM, UG/ L 0 100 200 300 400 500 100 200 300 400 500 Lab: 5 ALUMINUM, UG/ L 0 100 200 300 400 500 100 200 300 400 500 600 Lab: 6 ALUMINUM, UG/ L 0 100 200 300 400 500  100 0 100 200 300 400 500 Lab: 7 ALUMINUM, UG/ L 0 100 200 300 400 500 0 100 200 300 400 500 Lab: 8 ALUMINUM, UG/ L 0 100 200 300 400 500 0 200 400 600 Lab: 9 ALUMINUM, UG/ L 0 100 200 300 400 500 600 0 100 200 300 400 500 600 Lab: 1 ARSENIC, UG/ L Measurement Results vs Spike Concentrations ( Matrix A, Method EPA 200.7 ICP/ AES)

AAMA Metals Data Page 2 of 13 Measured Concentration Spike Concentration c:/ pw/ ostmdl/ req005/ r005sd1. s Wed Mar 20 13: 31: 40 2002 0 100 200 300 400 500 600 0 200 400 600 Lab: 2 ARSENIC, UG/ L 0 100 200 300 400 500 600 0 100 200 300 400 500 Lab: 3 ARSENIC, UG/ L 0 100 200 300 400 500 600 0 200 400 600 Lab: 4 ARSENIC, UG/ L 0 100 200 300 400 500 600 0 100 200 300 400 500 Lab: 5 ARSENIC, UG/ L 0 100 200 300 400 500 600 0 100 200 300 400 500 600 Lab: 6 ARSENIC, UG/ L 0 100 200 300 400 500 600 0 200 400 600 Lab: 7 ARSENIC, UG/ L 0 100 200 300 400 500 600 0 100 200 300 400 500 600 Lab: 8 ARSENIC, UG/ L 0 100 200 300 400 500 600 0 200 400 600 Lab: 9 ARSENIC, UG/ L 0 20 40 60 80 100 0 20 40 60 80 100 Lab: 1 CADMIUM, UG/ L Measurement Results vs Spike Concentrations ( Matrix A, Method EPA 200.7 ICP/ AES)

AAMA Metals Data Page 3 of 13 Measured Concentration Spike Concentration c:/ pw/ ostmdl/ req005/ r005sd1. s Wed Mar 20 13: 31: 42 2002 0 20 40 60 80 100 0 20 40 60 80 100 Lab: 2 CADMIUM, UG/ L 0 20 40 60 80 100 0 20 40 60 80 Lab: 3 CADMIUM, UG/ L 0 20 40 60 80 100 0 20 40 60 80 100 Lab: 4 CADMIUM, UG/ L 0 20 40 60 80 100 0 20 40 60 80 100 Lab: 5 CADMIUM, UG/ L 0 20 40 60 80 100 0 20 40 60 80 100 Lab: 6 CADMIUM, UG/ L 0 20 40 60 80 100 0 20 40 60 80 Lab: 7 CADMIUM, UG/ L 0 20 40 60 80 100 0 20 40 60 80 100 Lab: 8 CADMIUM, UG/ L 0 20 40 60 80 100 0 20 40 60 80 100 Lab: 9 CADMIUM, UG/ L 0 50 100 150 200 250 0 50 100 150 200 250 Lab: 1 CHROMIUM, UG/ L Measurement Results vs Spike Concentrations ( Matrix A, Method EPA 200.7 ICP/ AES)

AAMA Metals Data Page 4 of 13 Measured Concentration Spike Concentration c:/ pw/ ostmdl/ req005/ r005sd1. s Wed Mar 20 13: 31: 44 2002 0 50 100 150 200 250 0 50 100 150 200 250 Lab: 2 CHROMIUM, UG/ L 0 50 100 150 200 250 0 50 100 150 200 Lab: 3 CHROMIUM, UG/ L 0 50 100 150 200 250 0 50 100 150 200 250 Lab: 4 CHROMIUM, UG/ L 0 50 100 150 200 250 0 50 100 150 200 250 Lab: 5 CHROMIUM, UG/ L 0 50 100 150 200 250 0 50 100 150 200 250 Lab: 6 CHROMIUM, UG/ L 0 50 100 150 200 250 0 50 100 150 200 250 Lab: 7 CHROMIUM, UG/ L 0 50 100 150 200 250 0 50 100 150 200 250 Lab: 8 CHROMIUM, UG/ L 0 50 100 150 200 250 0 50 100 150 200 250 Lab: 9 CHROMIUM, UG/ L 0 50 100 150 200 0 50 100 150 200 Lab: 1 COPPER, UG/ L Measurement Results vs Spike Concentrations ( Matrix A, Method EPA 200.7 ICP/ AES)

AAMA Metals Data Page 5 of 13 Measured Concentration Spike Concentration c:/ pw/ ostmdl/ req005/ r005sd1. s Wed Mar 20 13: 31: 46 2002 0 50 100 150 200 0 50 100 150 200 Lab: 2 COPPER, UG/ L 0 50 100 150 200 0 50 100 150 Lab: 3 COPPER, UG/ L 0 50 100 150 200 0 50 100 150 200 250 300 Lab: 4 COPPER, UG/ L 0 50 100 150 200 0 50 100 150 200 Lab: 5 COPPER, UG/ L 0 50 100 150 200 0 50 100 150 200 Lab: 6 COPPER, UG/ L 0 50 100 150 200 0 50 100 150 200 Lab: 7 COPPER, UG/ L 0 50 100 150 200 0 50 100 150 Lab: 8 COPPER, UG/ L 0 50 100 150 200 0 50 100 150 200 Lab: 9 COPPER, UG/ L 0 100 200 300 400 500 0 100 200 300 400 500 Lab: 1 LEAD, UG/ L Measurement Results vs Spike Concentrations ( Matrix A, Method EPA 200.7 ICP/ AES)

AAMA Metals Data Page 6 of 13 Measured Concentration Spike Concentration c:/ pw/ ostmdl/ req005/ r005sd1. s Wed Mar 20 13: 31: 48 2002 0 100 200 300 400 500 0 100 200 300 400 500 600 Lab: 2 LEAD, UG/ L 0 100 200 300 400 500 0 100 200 300 400 Lab: 3 LEAD, UG/ L 0 100 200 300 400 500 0 100 200 300 400 500 600 Lab: 4 LEAD, UG/ L 0 100 200 300 400 500 0 100 200 300 400 500 Lab: 5 LEAD, UG/ L 0 100 200 300 400 500 0 100 200 300 400 500 Lab: 6 LEAD, UG/ L 0 100 200 300 400 500 0 100 200 300 400 500 Lab: 7 LEAD, UG/ L 0 100 200 300 400 500 0 100 200 300 400 500 Lab: 8 LEAD, UG/ L 0 100 200 300 400 500 0 100 200 300 400 500 Lab: 9 LEAD, UG/ L 0 10 20 30 40 50 0 10 20 30 40 50 Lab: 1 MANGANESE, UG/ L Measurement Results vs Spike Concentrations ( Matrix A, Method EPA 200.7 ICP/ AES)

AAMA Metals Data Page 7 of 13 Measured Concentration Spike Concentration c:/ pw/ ostmdl/ req005/ r005sd1. s Wed Mar 20 13: 31: 50 2002 0 10 20 30 40 50 0 20 40 Lab: 2 MANGANESE, UG/ L 0 10 20 30 40 50 0 10 20 30 40 Lab: 3 MANGANESE, UG/ L 0 10 20 30 40 50 0 50 100 150 200 250 Lab: 4 MANGANESE, UG/ L 0 10 20 30 40 50 0 10 20 30 40 50 Lab: 5 MANGANESE, UG/ L 0 10 20 30 40 50 0 10 20 30 40 50 Lab: 6 MANGANESE, UG/ L 0 10 20 30 40 50 0 10 20 30 40 50 Lab: 7 MANGANESE, UG/ L 0 10 20 30 40 50 0 10 20 30 40 50 Lab: 8 MANGANESE, UG/ L 0 10 20 30 40 50 0 10 20 30 40 50 Lab: 9 MANGANESE, UG/ L 0.0 0.5 1.0 1.5 2.0 0.0 0.5 1.0 1.5 2.0 Lab: 1 MERCURY, UG/ L Measurement Results vs Spike Concentrations ( Matrix A, Method EPA 200.7 ICP/ AES)

AAMA Metals Data Page 8 of 13 Measured Concentration Spike Concentration c:/ pw/ ostmdl/ req005/ r005sd1. s Wed Mar 20 13: 31: 52 2002 0.0 0.5 1.0 1.5 2.0 0.0 0.5 1.0 1.5 2.0 Lab: 2 MERCURY, UG/ L 0.0 0.5 1.0 1.5 2.0 0.0 0.5 1.0 1.5 2.0 Lab: 3 MERCURY, UG/ L 0.0 0.5 1.0 1.5 2.0 0.0 0.5 1.0 1.5 2.0 Lab: 4 MERCURY, UG/ L 0.0 0.5 1.0 1.5 2.0 0.0 0.5 1.0 1.5 2.0 Lab: 5 MERCURY, UG/ L 0.0 0.5 1.0 1.5 2.0 0 2 4 6 8 Lab: 6 MERCURY, UG/ L 0.0 0.5 1.0 1.5 2.0 0.0 0.5 1.0 1.5 2.0 Lab: 7 MERCURY, UG/ L 0.0 0.5 1.0 1.5 2.0 0.0 0.5 1.0 1.5 2.0 Lab: 8 MERCURY, UG/ L 0.0 0.5 1.0 1.5 2.0 0.0 0.5 1.0 1.5 2.0 Lab: 9 MERCURY, UG/ L 0 50 100 150 200 250 0 50 100 150 200 250 Lab: 1 MOLYBDENUM, UG/ L Measurement Results vs Spike Concentrations ( Matrix A, Method EPA 200.7 ICP/ AES)

AAMA Metals Data Page 9 of 13 Measured Concentration Spike Concentration c:/ pw/ ostmdl/ req005/ r005sd1. s Wed Mar 20 13: 31: 54 2002 0 50 100 150 200 250  50 0 50 100 150 200 250 Lab: 2 MOLYBDENUM, UG/ L 0 50 100 150 200 250 0 50 100 150 200 250 Lab: 3 MOLYBDENUM, UG/ L 0 50 100 150 200 250 0 50 100 150 200 250 Lab: 4 MOLYBDENUM, UG/ L 0 50 100 150 200 250 0 50 100 150 200 250 Lab: 5 MOLYBDENUM, UG/ L 0 50 100 150 200 250 0 50 100 150 200 250 Lab: 6 MOLYBDENUM, UG/ L 0 50 100 150 200 250 0 50 100 150 200 250 Lab: 7 MOLYBDENUM, UG/ L 0 50 100 150 200 250 0 50 100 150 200 Lab: 8 MOLYBDENUM, UG/ L 0 50 100 150 200 250 0 50 100 150 200 250 Lab: 9 MOLYBDENUM, UG/ L 0 50 100 150 200 0 50 100 150 200 Lab: 1 NICKEL, UG/ L Measurement Results vs Spike Concentrations ( Matrix A, Method EPA 200.7 ICP/ AES)

AAMA Metals Data Page 10 of 13 Measured Concentration Spike Concentration c:/ pw/ ostmdl/ req005/ r005sd1. s Wed Mar 20 13: 31: 56 2002 0 50 100 150 200 0 50 100 150 200 Lab: 2 NICKEL, UG/ L 0 50 100 150 200 0 50 100 150 Lab: 3 NICKEL, UG/ L 0 50 100 150 200 0 50 100 150 200 Lab: 4 NICKEL, UG/ L 0 50 100 150 200 0 50 100 150 200 Lab: 5 NICKEL, UG/ L 0 50 100 150 200 0 200 400 600 800 Lab: 6 NICKEL, UG/ L 0 50 100 150 200 0 50 100 150 Lab: 7 NICKEL, UG/ L 0 50 100 150 200 0 50 100 150 200 Lab: 8 NICKEL, UG/ L 0 50 100 150 200 0 50 100 150 200 Lab: 9 NICKEL, UG/ L 0 200 400 600 800 1000 0 200 400 600 800 1000 Lab: 1 SELENIUM, UG/ L Measurement Results vs Spike Concentrations ( Matrix A, Method EPA 200.7 ICP/ AES)

AAMA Metals Data Page 11 of 13 Measured Concentration Spike Concentration c:/ pw/ ostmdl/ req005/ r005sd1. s Wed Mar 20 13: 31: 58 2002 0 200 400 600 800 1000 0 200 400 600 800 1000 Lab: 2 SELENIUM, UG/ L 0 200 400 600 800 1000 0 200 400 600 800 Lab: 3 SELENIUM, UG/ L 0 200 400 600 800 1000 0 200 400 600 800 Lab: 4 SELENIUM, UG/ L 0 200 400 600 800 1000 0 200 400 600 800 Lab: 5 SELENIUM, UG/ L 0 200 400 600 800 1000 0 200 400 600 800 1000 Lab: 6 SELENIUM, UG/ L 0 200 400 600 800 1000 0 200 400 600 800 Lab: 7 SELENIUM, UG/ L 0 200 400 600 800 1000 0 200 400 600 800 Lab: 8 SELENIUM, UG/ L 0 200 400 600 800 1000 0 200 400 600 800 1000 Lab: 9 SELENIUM, UG/ L 0 20 40 60 80 100 0 20 40 60 80 100 Lab: 1 SILVER, UG/ L Measurement Results vs Spike Concentrations ( Matrix A, Method EPA 200.7 ICP/ AES)

AAMA Metals Data Page 12 of 13 Measured Concentration Spike Concentration c:/ pw/ ostmdl/ req005/ r005sd1. s Wed Mar 20 13: 32: 00 2002 0 20 40 60 80 100 0 20 40 60 80 100 Lab: 2 SILVER, UG/ L 0 20 40 60 80 100 0 20 40 60 80 Lab: 3 SILVER, UG/ L 0 20 40 60 80 100 0 50 100 150 200 Lab: 4 SILVER, UG/ L 0 20 40 60 80 100 0 20 40 60 80 100 Lab: 5 SILVER, UG/ L 0 20 40 60 80 100 0 50 100 150 200 250 Lab: 6 SILVER, UG/ L 0 20 40 60 80 100 0 20 40 60 80 Lab: 7 SILVER, UG/ L 0 20 40 60 80 100 0 20 40 60 80 Lab: 8 SILVER, UG/ L 0 20 40 60 80 100 0 20 40 60 80 100 Lab: 9 SILVER, UG/ L 0 50 100 150 200 250 0 50 100 150 200 250 Lab: 1 ZINC, UG/ L Measurement Results vs Spike Concentrations ( Matrix A, Method EPA 200.7 ICP/ AES)

AAMA Metals Data Page 13 of 13 Measured Concentration Spike Concentration c:/ pw/ ostmdl/ req005/ r005sd1. s Wed Mar 20 13: 32: 02 2002 0 50 100 150 200 250 0 100 200 Lab: 2 ZINC, UG/ L 0 50 100 150 200 250 0 50 100 150 200 Lab: 3 ZINC, UG/ L 0 50 100 150 200 250 0 100 200 300 Lab: 4 ZINC, UG/ L 0 50 100 150 200 250 0 50 100 150 200 Lab: 5 ZINC, UG/ L 0 50 100 150 200 250 0 50 100 150 200 250 Lab: 6 ZINC, UG/ L 0 50 100 150 200 250 50 100 150 200 250 Lab: 7 ZINC, UG/ L 0 50 100 150 200 250 0 50 100 150 200 250 Lab: 8 ZINC, UG/ L 0 50 100 150 200 250 0 50 100 150 200 250 300 Lab: 9 ZINC, UG/ L 5 10 50 100 1 5 10 50 100 Classicals, Method 130.2 HARDNESS, MG/ L Measurement Results vs Spike Concentrations ( Log 10 Scale) Episode 6000 Data Page 1 of 32 APPENDIX B  2  1 Log 10 of Measured Concentration Log 10 of Spike Concentration 0.5 5.0 50.0 1 5 10 50 100 Classicals, Method 160.2 TOTAL SUSPENDED SOLIDS, MG/ L 0.5 1.0 5.0 10.0 50.0 0.5 1.0 5.0 10.0 50.0 Classicals, Method 1677 WAD CYANIDE, UG/ L 0.001 0.005 0.050 0.500 0.05 0.10 0.50 1.00 Classicals, Method 350.3 AMMONIA AS NITROGEN, MG/ L 0.005 0.050 0.500 0.001 0.005 0.010 0.050 0.100 0.500 1.000 Classicals, Method 365.2 TOTAL PHOSPHORUS, MG/ L 10^ 4 10^ 2 10^ 0 10^ 2 10^ 4 1 10 100 1000 10000 Metals, Method ICP/ MS Ag 107, ppt 10^ 4 10^ 2 10^ 0 10^ 2 10^ 4 1 10 100 1000 10000 Metals, Method ICP/ MS Cd 111, ppt 0.1 1.0 10.0 100.0 1000.0 10 50 100 500 1000 5000 10000 Metals, Method ICP/ MS Cu 63, ppt 0.1 1.0 10.0 100.0 1000.0 10 100 1000 10000 Metals, Method ICP/ MS Ni 60, ppt 10^ 4 10^ 2 10^ 0 10^ 2 10^ 4 1 10 100 1000 10000 Metals, Method ICP/ MS Pb 206, ppt 10 50 500 5000 10 50 100 500 1000 5000 10000 Metals, Method ICP/ MS Pb 207, ppt 10 50 500 5000 1 10 100 1000 10000 Metals, Method ICP/ MS Pb 208, ppt 10^ 4 10^ 2 10^ 0 10^ 2 10^ 4 1 10 100 1000 10000 Metals, Method ICP/ MS Sb 123, ppt Measurement Results vs Spike Concentrations ( Log 10 Scale) Episode 6000 Data Page 2 of 32 Log 10 of Measured Concentration Log 10 of Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 40: 05 2002 10^ 4 10^ 2 10^ 0 10^ 2 10^ 4 10 100 1000 10000 Metals, Method ICP/ MS Se 82, ppt 10^ 4 10^ 2 10^ 0 10^ 2 10^ 4 10 100 1000 10000 Metals, Method ICP/ MS Tl 205, ppt 10^ 4 10^ 2 10^ 0 10^ 2 10^ 4 50 100 500 1000 5000 10000 Metals, Method ICP/ MS Zn 66, ppt 1 5 10 50 100 500 1 5 10 50 100 500 1000 Metals, Method 1620 ALUMINUM, UG/ L 0.1 0.5 5.0 50.0 0.1 0.5 1.0 5.0 10.0 50.0 100.0 Metals, Method 1620 ANTIMONY, UG/ L 0.5 1.0 5.0 10.0 50.0 0.1 0.5 1.0 5.0 10.0 50.0 100.0 Metals, Method 1620 ARSENIC, UG/ L 0.5 1.0 5.0 50.0 0.1 0.5 1.0 5.0 10.0 50.0 100.0 Metals, Method 1620 BARIUM, UG/ L 0.5 1.0 5.0 10.0 50.0 0.1 0.5 1.0 5.0 10.0 50.0 100.0 Metals, Method 1620 BERYLLIUM, UG/ L 100 500 1000 5 10 50 100 500 1000 Metals, Method 1620 BORON, UG/ L 0.5 1.0 5.0 10.0 0.01 0.10 1.00 10.00 Metals, Method 1620 CADMIUM, UG/ L 5 10 50 100 500 1 10 100 1000 Metals, Method 1620 CALCIUM, UG/ L 0.1 0.5 5.0 50.0 0.01 0.10 1.00 10.00 100.00 Metals, Method 1620 CHROMIUM, UG/ L Measurement Results vs Spike Concentrations ( Log 10 Scale) Episode 6000 Data Page 3 of 32 Log 10 of Measured Concentration Log 10 of Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 40: 18 2002 1 5 10 50 100 500 0.1 1.0 10.0 100.0 1000.0 Metals, Method 1620 COBALT, UG/ L 0.5 5.0 50.0 0.5 1.0 5.0 10.0 50.0 100.0 Metals, Method 1620 COPPER, UG/ L 1 5 10 50 100 500 1 5 10 50 100 500 1000 Metals, Method 1620 IRON, UG/ L 0.5 5.0 50.0 0.1 0.5 1.0 5.0 10.0 50.0 100.0 Metals, Method 1620 LEAD, UG/ L 5 10 50 100 500 5000 1 10 100 1000 Metals, Method 1620 MAGNESIUM, UG/ L 0.1 0.5 5.0 50.0 0.1 0.5 1.0 5.0 10.0 50.0 100.0 Metals, Method 1620 MANGANESE, UG/ L 5 10 50 100 0.5 1.0 5.0 10.0 50.0 100.0 Metals, Method 1620 MOLYBDENUM, UG/ L 5 10 50 100 500 5 10 50 100 500 1000 Metals, Method 1620 NICKEL, UG/ L 0.5 1.0 5.0 10.0 50.0 0.1 0.5 1.0 5.0 10.0 50.0 100.0 Metals, Method 1620 SELENIUM, UG/ L 0.5 5.0 50.0 500.0 0.5 1.0 5.0 10.0 50.0 100.0 500.0 Metals, Method 1620 SILVER, UG/ L 5 10 50 100 500 5000 1 10 100 1000 Metals, Method 1620 SODIUM, UG/ L 0.1 0.5 5.0 50.0 0.1 0.5 1.0 5.0 10.0 50.0 100.0 Metals, Method 1620 THALLIUM, UG/ L Measurement Results vs Spike Concentrations ( Log 10 Scale) Episode 6000 Data Page 4 of 32 Log 10 of Measured Concentration Log 10 of Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 40: 31 2002 1 5 10 50 100 0.5 1.0 5.0 10.0 50.0 100.0 500.0 Metals, Method 1620 TIN, UG/ L 0.5 5.0 50.0 0.5 1.0 5.0 10.0 50.0 100.0 500.0 Metals, Method 1620 TITANIUM, UG/ L 1 5 10 50 100 500 1 5 10 50 100 500 1000 Metals, Method 1620 VANADIUM, UG/ L 0.1 0.5 5.0 50.0 0.1 0.5 1.0 5.0 10.0 50.0 100.0 Metals, Method 1620 YTTRIUM, UG/ L 0.5 5.0 50.0 0.1 0.5 1.0 5.0 10.0 50.0 100.0 Metals, Method 1620 ZINC, UG/ L 0.5 5.0 50.0 500.0 5 10 50 100 500 1000 Metals, Method 200.8 ALUMINUM, UG/ L 0.01 0.10 1.00 10.00 0.01 0.05 0.10 0.50 1.00 5.00 10.00 Metals, Method 200.8 ANTIMONY, UG/ L 0.1 0.5 5.0 50.0 0.01 0.10 1.00 10.00 100.00 Metals, Method 200.8 ARSENIC, UG/ L 0.01 0.10 1.00 10.00 0.001 0.010 0.100 1.000 10.000 Metals, Method 200.8 BARIUM, UG/ L 0.005 0.050 0.500 5.000 0.001 0.010 0.100 1.000 Metals, Method 200.8 BERYLLIUM, UG/ L 0.001 0.005 0.050 0.500 0.0001 0.0010 0.0100 0.1000 1.0000 Metals, Method 200.8 CADMIUM, UG/ L 0.01 0.05 0.50 5.00 0.1 0.5 1.0 5.0 10.0 Metals, Method 200.8 CHROMIUM, UG/ L Measurement Results vs Spike Concentrations ( Log 10 Scale) Episode 6000 Data Page 5 of 32 Log 10 of Measured Concentration Log 10 of Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 40: 45 2002 0.0005 0.0050 0.0500 0.5000 0.0005 0.0010 0.0050 0.0100 0.0500 0.1000 0.5000 Metals, Method 200.8 COBALT, UG/ L 0.01 0.05 0.50 5.00 0.1 0.5 1.0 5.0 10.0 Metals, Method 200.8 COPPER, UG/ L 0.05 0.50 5.00 50.00 0.05 0.10 0.50 1.00 5.00 10.00 50.00 Metals, Method 200.8 LEAD, UG/ L 0.001 0.005 0.050 0.500 0.05 0.10 0.50 1.00 Metals, Method 200.8 MANGANESE, UG/ L 0.005 0.050 0.500 5.000 0.001 0.010 0.100 1.000 Metals, Method 200.8 MERCURY, UG/ L 0.0005 0.0050 0.0500 0.5000 0.005 0.010 0.050 0.100 0.500 1.000 Metals, Method 200.8 MOLYBDENUM, UG/ L 0.01 0.10 1.00 10.00 0.05 0.10 0.50 1.00 5.00 10.00 Metals, Method 200.8 NICKEL, UG/ L 0.1 0.5 5.0 50.0 0.1 1.0 10.0 100.0 Metals, Method 200.8 SELENIUM, UG/ L 0.001 0.005 0.050 0.500 0.01 0.05 0.10 0.50 1.00 Metals, Method 200.8 SILVER, UG/ L 0.0005 0.0050 0.0500 0.005 0.010 0.050 0.100 Metals, Method 200.8 THALLIUM, UG/ L 0.001 0.010 0.100 1.000 0.005 0.010 0.050 0.100 0.500 1.000 Metals, Method 200.8 THORIUM, UG/ L 0.0001 0.0005 0.0050 0.0500 0.005 0.010 0.050 0.100 Metals, Method 200.8 URANIUM, UG/ L Measurement Results vs Spike Concentrations ( Log 10 Scale) Episode 6000 Data Page 6 of 32 Log 10 of Measured Concentration Log 10 of Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 40: 59 2002 0.5 5.0 50.0 0.01 0.10 1.00 10.00 100.00 Metals, Method 200.8 VANADIUM, UG/ L 0.1 0.5 5.0 50.0 0.5 1.0 5.0 10.0 50.0 100.0 Metals, Method 200.8 ZINC, UG/ L 0.05 0.50 5.00 0.005 0.010 0.050 0.100 0.500 1.000 5.000 10.000 Organics, Method 502.2 ELCD 1,1,1,2 TETRACHLOROETHANE, UG/ L 0.05 0.50 5.00 0.01 0.05 0.10 0.50 1.00 5.00 10.00 Organics, Method 502.2 ELCD 1,1,1 TRICHLOROETHANE, UG/ L 1 5 10 0.5 1.0 5.0 10.0 Organics, Method 502.2 ELCD 1,1,2,2 TCE+ 1,2,3 TCP, UG/ L 0.05 0.50 5.00 0.01 0.10 1.00 10.00 Organics, Method 502.2 ELCD 1,1,2 TRICHLOROETHANE, UG/ L 0.05 0.50 5.00 0.1 0.5 1.0 5.0 10.0 Organics, Method 502.2 ELCD 1,1 DICHLOROETHANE, UG/ L 0.1 0.5 1.0 5.0 10.0 0.5 1.0 5.0 10.0 Organics, Method 502.2 ELCD 1,1 DICHLOROETHENE, UG/ L 0.0001 0.0010 0.0100 0.1000 1.0000 0.5 1.0 5.0 10.0 Organics, Method 502.2 ELCD 1,2,3 TRICHLOROBENZENE, UG/ L 0.0001 0.0010 0.0100 0.1000 1.0000 0.5 1.0 5.0 10.0 Organics, Method 502.2 ELCD 1,2,4 TRICHLOROBENZENE, UG/ L 0.5 1.0 5.0 10.0 0.5 1.0 5.0 10.0 Organics, Method 502.2 ELCD 1,2 DIBROMOETHANE, UG/ L 0.05 0.50 5.00 0.01 0.05 0.10 0.50 1.00 5.00 10.00 Organics, Method 502.2 ELCD 1,2 DICHLOROBENZENE, UG/ L Measurement Results vs Spike Concentrations ( Log 10 Scale) Episode 6000 Data Page 7 of 32 Log 10 of Measured Concentration Log 10 of Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 41: 12 2002 0.05 0.50 5.00 0.01 0.05 0.10 0.50 1.00 5.00 10.00 Organics, Method 502.2 ELCD 1,2 DICHLOROETHANE, UG/ L 0.05 0.50 5.00 0.005 0.010 0.050 0.100 0.500 1.000 5.000 10.000 Organics, Method 502.2 ELCD 1,2 DICHLOROPROPANE, UG/ L 0.01 0.05 0.50 5.00 0.5 1.0 5.0 10.0 Organics, Method 502.2 ELCD 1,3 DICHLOROBENZENE, UG/ L 0.1 0.5 1.0 5.0 10.0 0.05 0.10 0.50 1.00 5.00 10.00 Organics, Method 502.2 ELCD 1,3 DICHLOROPROPANE, UG/ L 0.05 0.50 5.00 0.01 0.05 0.10 0.50 1.00 5.00 10.00 Organics, Method 502.2 ELCD 1,4 DICHLOROBENZENE, UG/ L 0.05 0.50 5.00 0.5 1.0 5.0 10.0 Organics, Method 502.2 ELCD 2 CHLOROTOLUENE, UG/ L 0.05 0.50 5.00 0.05 0.10 0.50 1.00 5.00 10.00 Organics, Method 502.2 ELCD 4 CHLOROTOLUENE, UG/ L 0.5 1.0 5.0 10.0 1 5 10 Organics, Method 502.2 ELCD BROMOBENZENE, UG/ L 0.1 0.5 1.0 5.0 10.0 0.5 1.0 5.0 10.0 Organics, Method 502.2 ELCD BROMOCHLOROMETHANE, UG/ L 0.05 0.50 5.00 0.5 1.0 5.0 10.0 Organics, Method 502.2 ELCD BROMODICHLOROMETHANE, UG/ L 0.5 1.0 5.0 10.0 1 5 10 Organics, Method 502.2 ELCD BROMOFORM, UG/ L 1 5 10 4 5 6 7 8 9 10 Organics, Method 502.2 ELCD BROMOMETHANE, UG/ L Measurement Results vs Spike Concentrations ( Log 10 Scale) Episode 6000 Data Page 8 of 32 Log 10 of Measured Concentration Log 10 of Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 41: 25 2002 0.1 0.5 1.0 5.0 10.0 0.05 0.10 0.50 1.00 5.00 10.00 Organics, Method 502.2 ELCD CARBONTET+ 1,1 DCP, UG/ L 0.1 0.5 1.0 5.0 10.0 0.5 1.0 5.0 10.0 Organics, Method 502.2 ELCD CHLOROBENZENE, UG/ L 0.5 1.0 5.0 10.0 5 10 Organics, Method 502.2 ELCD CHLOROETHANE, UG/ L 0.05 0.50 5.00 0.05 0.10 0.50 1.00 5.00 10.00 Organics, Method 502.2 ELCD CHLOROFORM, UG/ L 0.01 0.05 0.50 5.00 5 10 Organics, Method 502.2 ELCD CHLOROMETHANE, UG/ L 0.1 0.5 1.0 5.0 10.0 0.01 0.10 1.00 10.00 Organics, Method 502.2 ELCD CIS 1,2 DCE+ 2,2 DCP, UG/ L 0.05 0.50 5.00 0.1 0.5 1.0 5.0 10.0 Organics, Method 502.2 ELCD CIS 1,3 DICHLOROPROPENE, UG/ L 0.1 0.5 1.0 5.0 10.0 0.5 1.0 5.0 10.0 Organics, Method 502.2 ELCD DIBROMOCHLOROMETHANE, UG/ L 0.1 0.5 1.0 5.0 10.0 0.5 1.0 5.0 10.0 Organics, Method 502.2 ELCD DIBROMOMETHANE, UG/ L 0.05 0.50 5.00 0.5 1.0 5.0 10.0 Organics, Method 502.2 ELCD DICHLORODIFLUOROMETHANE, UG/ L 0.0001 0.0010 0.0100 0.1000 1.0000 0.005 0.010 0.050 0.100 0.500 1.000 5.000 10.000 Organics, Method 502.2 ELCD HEXACHLOROBUTADIENE, UG/ L 0.05 0.50 5.00 0.05 0.10 0.50 1.00 5.00 10.00 Organics, Method 502.2 ELCD METHYLENE CHLORIDE, UG/ L Measurement Results vs Spike Concentrations ( Log 10 Scale) Episode 6000 Data Page 9 of 32 Log 10 of Measured Concentration Log 10 of Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 41: 38 2002 0.05 0.50 5.00 0.005 0.010 0.050 0.100 0.500 1.000 5.000 10.000 Organics, Method 502.2 ELCD TETRACHLOROETHENE, UG/ L 0.05 0.50 5.00 0.05 0.10 0.50 1.00 5.00 10.00 Organics, Method 502.2 ELCD TRANS 1,2 DICHLOROETHENE, UG/ L 0.05 0.50 5.00 0.5 1.0 5.0 10.0 Organics, Method 502.2 ELCD TRANS 1,3 DICHLOROPROPENE, UG/ L 0.05 0.50 5.00 0.05 0.10 0.50 1.00 5.00 10.00 Organics, Method 502.2 ELCD TRICHLOROETHENE, UG/ L 0.5 1.0 5.0 10.0 1 5 10 Organics, Method 502.2 ELCD TRICHLOROFLUOROMETHANE, UG/ L 0.5 1.0 5.0 10.0 5 10 Organics, Method 502.2 ELCD VINYL CHLORIDE, UG/ L 0.0001 0.0010 0.0100 0.1000 1.0000 0.05 0.10 0.50 1.00 5.00 10.00 Organics, Method 502.2 PID 1,2,3 TRICHLOROBENZENE, UG/ L 0.05 0.50 5.00 0.05 0.10 0.50 1.00 5.00 10.00 Organics, Method 502.2 PID 1,2,4 TRICHLOROBENZENE, UG/ L 0.05 0.50 5.00 0.5 1.0 5.0 10.0 Organics, Method 502.2 PID 1,2,4 TRIMETHYLBENZENE, UG/ L 0.1 0.5 1.0 5.0 10.0 0.1 0.5 1.0 5.0 10.0 Organics, Method 502.2 PID 1,2 DICHLOROBENZENE, UG/ L 0.05 0.50 5.00 0.05 0.10 0.50 1.00 5.00 10.00 Organics, Method 502.2 PID 1,3,5 TMB+ 4 CHLOROTOLUENE, UG/ L 0.05 0.50 5.00 0.01 0.05 0.10 0.50 1.00 5.00 10.00 Organics, Method 502.2 PID 1,3 DICHLOROBENZENE, UG/ L Measurement Results vs Spike Concentrations ( Log 10 Scale) Episode 6000 Data Page 10 of 32 Log 10 of Measured Concentration Log 10 of Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 41: 51 2002 0.05 0.50 5.00 0.05 0.10 0.50 1.00 5.00 10.00 Organics, Method 502.2 PID 2 CHLOROTOLUENE, UG/ L 0.05 0.50 5.00 0.01 0.05 0.10 0.50 1.00 5.00 10.00 Organics, Method 502.2 PID BENZENE, UG/ L 0.05 0.50 5.00 0.05 0.10 0.50 1.00 5.00 10.00 Organics, Method 502.2 PID BROMOBENZENE, UG/ L 0.05 0.50 5.00 0.01 0.05 0.10 0.50 1.00 5.00 10.00 Organics, Method 502.2 PID CHLOROBENZENE, UG/ L 0.1 0.5 1.0 5.0 10.0 0.05 0.10 0.50 1.00 5.00 10.00 Organics, Method 502.2 PID CIS 1,3 DICHLOROPROPENE, UG/ L 0.05 0.50 5.00 0.05 0.10 0.50 1.00 5.00 10.00 Organics, Method 502.2 PID ETHYLBENZENE, UG/ L 0.0001 0.0100 1.0000 0.5 1.0 5.0 10.0 Organics, Method 502.2 PID HEXCHLOBUTADIENE+ NAPHTHALENE, UG/ L 0.05 0.50 5.00 0.05 0.10 0.50 1.00 5.00 10.00 Organics, Method 502.2 PID ISOPROPYLBENZENE, UG/ L 0.05 0.50 5.00 0.1 0.5 1.0 5.0 10.0 Organics, Method 502.2 PID M+ P XYLENE, UG/ L 0.05 0.50 5.00 0.5 1.0 5.0 10.0 Organics, Method 502.2 PID N BUTYLBENZENE, UG/ L 0.05 0.50 5.00 0.01 0.05 0.10 0.50 1.00 5.00 10.00 Organics, Method 502.2 PID N PROPYLBENZENE, UG/ L 0.05 0.50 5.00 0.01 0.05 0.10 0.50 1.00 5.00 10.00 Organics, Method 502.2 PID O XYLENE+ STYRENE, UG/ L Measurement Results vs Spike Concentrations ( Log 10 Scale) Episode 6000 Data Page 11 of 32 Log 10 of Measured Concentration Log 10 of Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 42: 05 2002 0.05 0.50 5.00 0.1 0.5 1.0 5.0 10.0 Organics, Method 502.2 PID P ISOPROPTOL+ 1,4 DCB, UG/ L 0.05 0.50 5.00 0.05 0.10 0.50 1.00 5.00 10.00 Organics, Method 502.2 PID SEC BUTYLBENZENE, UG/ L 0.05 0.50 5.00 0.05 0.10 0.50 1.00 5.00 10.00 Organics, Method 502.2 PID TERT BUTYLBENZENE, UG/ L 0.5 1.0 5.0 10.0 0.05 0.10 0.50 1.00 5.00 10.00 Organics, Method 502.2 PID TETRACHLOROETHENE, UG/ L 0.05 0.50 5.00 0.005 0.010 0.050 0.100 0.500 1.000 5.000 10.000 Organics, Method 502.2 PID TOLUENE, UG/ L 0.1 0.5 1.0 5.0 10.0 0.05 0.10 0.50 1.00 5.00 10.00 Organics, Method 502.2 PID TRANS 1,3 DICHLOROPROPENE, UG/ L 0.1 0.5 1.0 5.0 10.0 0.05 0.10 0.50 1.00 5.00 10.00 Organics, Method 502.2 PID TRICHLOROETHENE, UG/ L 0.5 5.0 50.0 0.1 1.0 10.0 100.0 Organics, Method 524.2 1,1,1,2 TETRACHLOROETHANE, UG/ L 0.5 5.0 50.0 0.1 0.5 1.0 5.0 10.0 50.0 100.0 Organics, Method 524.2 1,1,1 TRICHLOROETHANE, UG/ L 0.5 1.0 5.0 50.0 0.1 1.0 10.0 100.0 Organics, Method 524.2 1,1,2,2 TETRACHLOROETHANE, UG/ L 0.5 1.0 5.0 50.0 0.1 0.5 1.0 5.0 10.0 50.0 100.0 Organics, Method 524.2 1,1,2 TRICHLOROETHANE, UG/ L 0.5 5.0 50.0 0.1 1.0 10.0 100.0 Organics, Method 524.2 1,1 DICHLOROETHANE, UG/ L Measurement Results vs Spike Concentrations ( Log 10 Scale) Episode 6000 Data Page 12 of 32 Log 10 of Measured Concentration Log 10 of Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 42: 18 2002 0.5 5.0 50.0 0.1 0.5 1.0 5.0 10.0 50.0 100.0 Organics, Method 524.2 1,1 DICHLOROETHENE, UG/ L 50 100 10 50 100 Organics, Method 524.2 1,1 DICHLOROPROPANONE, UG/ L 0.5 5.0 50.0 0.1 0.5 1.0 5.0 10.0 50.0 100.0 Organics, Method 524.2 1,1 DICHLOROPROPENE, UG/ L 0.5 5.0 50.0 0.1 0.5 1.0 5.0 10.0 50.0 100.0 Organics, Method 524.2 1,2,3 TRICHLOROBENZENE, UG/ L 0.5 1.0 5.0 50.0 0.5 1.0 5.0 10.0 50.0 100.0 Organics, Method 524.2 1,2,3 TRICHLOROPROPANE, UG/ L 0.5 5.0 50.0 0.1 1.0 10.0 100.0 Organics, Method 524.2 1,2,4 TRICHLOROBENZENE, UG/ L 0.1 0.5 5.0 50.0 0.1 1.0 10.0 100.0 Organics, Method 524.2 1,2,4 TRIMETHYLBENZENE, UG/ L 5 10 50 100 5 10 50 100 Organics, Method 524.2 1,2 DIBROMO 3 CHLOROPROPANE, UG/ L 0.5 1.0 5.0 50.0 0.1 1.0 10.0 100.0 Organics, Method 524.2 1,2 DIBROMOETHANE, UG/ L 0.1 0.5 5.0 50.0 0.1 1.0 10.0 100.0 Organics, Method 524.2 1,2 DICHLOROBENZENE, UG/ L 0.5 1.0 5.0 50.0 0.5 1.0 5.0 10.0 50.0 100.0 Organics, Method 524.2 1,2 DICHLOROETHANE, UG/ L 0.5 1.0 5.0 50.0 0.5 1.0 5.0 10.0 50.0 100.0 Organics, Method 524.2 1,2 DICHLOROPROPANE, UG/ L Measurement Results vs Spike Concentrations ( Log 10 Scale) Episode 6000 Data Page 13 of 32 Log 10 of Measured Concentration Log 10 of Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 42: 31 2002 0.1 0.5 5.0 50.0 0.1 1.0 10.0 100.0 Organics, Method 524.2 1,3,5 TRIMETHYLBENZENE, UG/ L 0.1 0.5 5.0 50.0 0.01 0.10 1.00 10.00 100.00 Organics, Method 524.2 1,3 DICHLOROBENZENE, UG/ L 0.5 5.0 50.0 0.1 1.0 10.0 100.0 Organics, Method 524.2 1,3 DICHLOROPROPANE, UG/ L 0.1 0.5 5.0 50.0 0.1 1.0 10.0 100.0 Organics, Method 524.2 1,4 DICHLOROBENZENE, UG/ L 0.1 0.5 5.0 50.0 0.01 0.10 1.00 10.00 100.00 1000.00 Organics, Method 524.2 1 CHLOROBUTANE, UG/ L 1 5 10 50 100 0.5 1.0 5.0 10.0 50.0 100.0 Organics, Method 524.2 2,2 DICHLOROPROPANE, UG/ L 5 10 50 100 1 5 10 50 100 Organics, Method 524.2 2 BUTANONE, UG/ L 0.1 0.5 5.0 50.0 0.1 1.0 10.0 100.0 Organics, Method 524.2 2 CHLOROTOLUENE, UG/ L 5 10 50 100 1 5 10 50 100 Organics, Method 524.2 2 HEXANONE, UG/ L 5 10 50 100 5 10 50 100 Organics, Method 524.2 2 NITROPROPANE, UG/ L 0.1 0.5 5.0 50.0 0.01 0.10 1.00 10.00 100.00 Organics, Method 524.2 4 CHLOROTOLUENE, UG/ L 0.1 0.5 5.0 50.0 0.01 0.10 1.00 10.00 100.00 Organics, Method 524.2 4 ISOPROPYLTOLUENE, UG/ L Measurement Results vs Spike Concentrations ( Log 10 Scale) Episode 6000 Data Page 14 of 32 Log 10 of Measured Concentration Log 10 of Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 42: 45 2002 5 10 50 100 5 10 50 100 Organics, Method 524.2 4 METHYL 2 PENTANONE, UG/ L 5 10 50 100 0.5 1.0 5.0 10.0 50.0 100.0 Organics, Method 524.2 ACETONE, UG/ L 5 10 50 100 5 10 50 100 Organics, Method 524.2 ACRYLONITRILE, UG/ L 0.5 5.0 50.0 0.1 0.5 1.0 5.0 10.0 50.0 100.0 Organics, Method 524.2 ALLYL CHLORIDE, UG/ L 0.1 1.0 10.0 100.0 0.01 0.10 1.00 10.00 100.00 Organics, Method 524.2 BENZENE, UG/ L 0.5 5.0 50.0 0.1 0.5 1.0 5.0 10.0 50.0 100.0 Organics, Method 524.2 BROMOBENZENE, UG/ L 0.5 1.0 5.0 50.0 0.5 1.0 5.0 10.0 50.0 100.0 Organics, Method 524.2 BROMOCHLOROMETHANE, UG/ L 0.5 5.0 50.0 0.1 1.0 10.0 100.0 Organics, Method 524.2 BROMODICHLOROMETHANE, UG/ L 0.5 1.0 5.0 50.0 0.5 1.0 5.0 10.0 50.0 100.0 Organics, Method 524.2 BROMOFORM, UG/ L 0.5 5.0 50.0 0.1 0.5 1.0 5.0 10.0 50.0 100.0 Organics, Method 524.2 BROMOMETHANE, UG/ L 0.1 0.5 5.0 50.0 0.1 1.0 10.0 100.0 Organics, Method 524.2 CARBON DISULFIDE, UG/ L 0.5 5.0 50.0 0.1 0.5 1.0 5.0 10.0 50.0 100.0 Organics, Method 524.2 CARBON TETRACHLORIDE, UG/ L Measurement Results vs Spike Concentrations ( Log 10 Scale) Episode 6000 Data Page 15 of 32 Log 10 of Measured Concentration Log 10 of Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 42: 58 2002 10 50 100 10 50 100 Organics, Method 524.2 CHLOROACETONITRILE, UG/ L 0.1 0.5 5.0 50.0 0.01 0.10 1.00 10.00 100.00 Organics, Method 524.2 CHLOROBENZENE, UG/ L 0.5 1.0 5.0 50.0 0.5 1.0 5.0 10.0 50.0 100.0 Organics, Method 524.2 CHLOROETHANE, UG/ L 0.5 5.0 50.0 0.05 0.10 0.50 1.00 5.00 10.00 50.00 100.00 Organics, Method 524.2 CHLOROFORM, UG/ L 0.5 5.0 50.0 0.1 0.5 1.0 5.0 10.0 50.0 100.0 Organics, Method 524.2 CHLOROMETHANE, UG/ L 0.5 1.0 5.0 50.0 0.5 1.0 5.0 10.0 50.0 100.0 Organics, Method 524.2 CIS 1,2 DICHLOROETHENE, UG/ L 0.5 5.0 50.0 0.1 1.0 10.0 100.0 Organics, Method 524.2 CIS 1,3 DICHLOROPROPENE, UG/ L 0.5 1.0 5.0 50.0 0.5 1.0 5.0 10.0 50.0 100.0 Organics, Method 524.2 DIBROMOCHLOROMETHANE, UG/ L 0.5 1.0 5.0 50.0 0.5 1.0 5.0 10.0 50.0 100.0 Organics, Method 524.2 DIBROMOMETHANE, UG/ L 0.5 1.0 5.0 50.0 10 50 100 Organics, Method 524.2 DICHLORODIFLUOROMETHANE, UG/ L 0.5 1.0 5.0 50.0 0.5 1.0 5.0 10.0 50.0 100.0 Organics, Method 524.2 DIETHYL ETHER, UG/ L 0.5 1.0 5.0 50.0 0.1 1.0 10.0 100.0 Organics, Method 524.2 ETHYL METHACRYLATE, UG/ L Measurement Results vs Spike Concentrations ( Log 10 Scale) Episode 6000 Data Page 16 of 32 Log 10 of Measured Concentration Log 10 of Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 43: 13 2002 0.5 5.0 50.0 0.01 0.10 1.00 10.00 100.00 Organics, Method 524.2 ETHYLBENZENE, UG/ L 0.5 5.0 50.0 0.1 0.5 1.0 5.0 10.0 50.0 100.0 Organics, Method 524.2 HEXACHLOROBUTADIENE, UG/ L 0.5 5.0 50.0 0.1 1.0 10.0 100.0 Organics, Method 524.2 HEXACHLOROETHANE, UG/ L 0.1 0.5 5.0 50.0 0.01 0.10 1.00 10.00 100.00 Organics, Method 524.2 ISOPROPYLBENZENE, UG/ L 0.1 0.5 5.0 50.0 0.01 0.10 1.00 10.00 100.00 Organics, Method 524.2 M+ P XYLENE, UG/ L 5 10 50 100 1 5 10 50 100 Organics, Method 524.2 METHACRYLONITRILE, UG/ L 0.5 5.0 50.0 0.1 1.0 10.0 100.0 Organics, Method 524.2 METHYL IODIDE, UG/ L 0.5 1.0 5.0 50.0 0.5 1.0 5.0 10.0 50.0 100.0 Organics, Method 524.2 METHYL TERT BUTYL ETHER, UG/ L 0.5 1.0 5.0 50.0 0.5 1.0 5.0 10.0 50.0 100.0 Organics, Method 524.2 METHYLACRYLATE, UG/ L 0.5 5.0 50.0 0.1 0.5 1.0 5.0 10.0 50.0 100.0 Organics, Method 524.2 METHYLENE CHLORIDE, UG/ L 0.5 1.0 5.0 50.0 0.5 1.0 5.0 10.0 50.0 100.0 Organics, Method 524.2 METHYLMETHACRYLATE, UG/ L 0.1 0.5 5.0 50.0 0.01 0.10 1.00 10.00 100.00 Organics, Method 524.2 N BUTYLBENZENE, UG/ L Measurement Results vs Spike Concentrations ( Log 10 Scale) Episode 6000 Data Page 17 of 32 Log 10 of Measured Concentration Log 10 of Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 43: 27 2002 0.5 5.0 50.0 0.1 0.5 1.0 5.0 10.0 50.0 100.0 Organics, Method 524.2 N PROPYLBENZENE, UG/ L 0.5 5.0 50.0 0.1 1.0 10.0 100.0 Organics, Method 524.2 NAPHTHALENE, UG/ L 0.5 5.0 50.0 0.1 1.0 10.0 100.0 Organics, Method 524.2 O XYLENE, UG/ L 0.5 5.0 50.0 0.1 1.0 10.0 100.0 Organics, Method 524.2 PENTACHLOROETHANE, UG/ L 0.1 0.5 5.0 50.0 0.1 1.0 10.0 100.0 Organics, Method 524.2 SEC BUTYLBENZENE, UG/ L 0.1 0.5 5.0 50.0 0.01 0.10 1.00 10.00 100.00 Organics, Method 524.2 STYRENE, UG/ L 0.1 0.5 5.0 50.0 0.01 0.10 1.00 10.00 100.00 Organics, Method 524.2 TERT BUTYLBENZENE, UG/ L 0.5 5.0 50.0 0.1 0.5 1.0 5.0 10.0 50.0 100.0 Organics, Method 524.2 TETRACHLOROETHENE, UG/ L 0.1 0.5 5.0 50.0 0.1 1.0 10.0 100.0 Organics, Method 524.2 TOLUENE, UG/ L 0.5 5.0 50.0 0.1 0.5 1.0 5.0 10.0 50.0 100.0 Organics, Method 524.2 TRANS 1,2 DICHLOROETHENE, UG/ L 0.5 1.0 5.0 50.0 0.5 1.0 5.0 10.0 50.0 100.0 Organics, Method 524.2 TRANS 1,3 DICHLOROPROPENE, UG/ L 5 10 50 100 1 5 10 50 100 Organics, Method 524.2 TRANS 1,4 DICHLORO 2 BUTENE, UG/ L Measurement Results vs Spike Concentrations ( Log 10 Scale) Episode 6000 Data Page 18 of 32 Log 10 of Measured Concentration Log 10 of Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 43: 42 2002 0.5 5.0 50.0 0.1 1.0 10.0 100.0 Organics, Method 524.2 TRICHLOROETHENE, UG/ L 0.5 1.0 5.0 50.0 0.1 0.5 1.0 5.0 10.0 50.0 100.0 Organics, Method 524.2 TRICHLOROFLUOROMETHANE, UG/ L 0.5 5.0 50.0 0.1 0.5 1.0 5.0 10.0 50.0 100.0 Organics, Method 524.2 VINYL CHLORIDE, UG/ L 0.1 0.5 5.0 50.0 0.01 0.10 1.00 10.00 100.00 Organics, Method 524.2 XYLENE ( TOTAL), UG/ L 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 0 1,2,3 TRICHLOROBENZENE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 0 1,2,4 TRICHLOROBENZENE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 0 1,2 DICHLOROBENZENE, NG/ UL 0.05 0.50 5.00 50.00 0.1 1.0 10.0 100.0 Organics, Method 1625: T= 0 1,2 DIPHENYLHYDRAZINE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 0 1,3 DICHLOROBENZENE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.05 0.10 0.50 1.00 5.00 10.00 50.00 100.00 Organics, Method 1625: T= 0 1,4 DICHLOROBENZENE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.1 1.0 10.0 100.0 Organics, Method 1625: T= 0 2,3,6 TRICHLOROPHENOL, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 0 2,4,5 TRICHLOROPHENOL, NG/ UL Measurement Results vs Spike Concentrations ( Log 10 Scale) Episode 6000 Data Page 19 of 32 Log 10 of Measured Concentration Log 10 of Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 43: 57 2002 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 0 2,4,6 TRICHLOROPHENOL, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.1 0.5 1.0 5.0 10.0 50.0 100.0 Organics, Method 1625: T= 0 2,4 DICHLOROPHENOL, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 0 2,4 DIMETHYLPHENOL, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.1 1.0 10.0 100.0 Organics, Method 1625: T= 0 2,4 DINITROPHENOL, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 0 2,4 DINITROTOLUENE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.1 1.0 10.0 100.0 Organics, Method 1625: T= 0 2,6 DINITROTOLUENE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.1 1.0 10.0 100.0 Organics, Method 1625: T= 0 2 CHLORONAPHTHALENE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.1 1.0 10.0 100.0 Organics, Method 1625: T= 0 2 CHLOROPHENOL, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.1 1.0 10.0 100.0 Organics, Method 1625: T= 0 2 NITROPHENOL, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 0 2 PICOLINE, NG/ UL 0.05 0.50 5.00 50.00 0.05 0.10 0.50 1.00 5.00 10.00 50.00 100.00 Organics, Method 1625: T= 0 3,3' DICHLOROBENZIDINE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 0 4 BROMOPHENYL PHENYL ETHER, NG/ UL Measurement Results vs Spike Concentrations ( Log 10 Scale) Episode 6000 Data Page 20 of 32 Log 10 of Measured Concentration Log 10 of Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 44: 12 2002 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.5 1.0 5.0 10.0 50.0 100.0 Organics, Method 1625: T= 0 4 CHLORO 3 METHYLPHENOL, NG/ UL 0.05 0.50 5.00 50.00 0.05 0.10 0.50 1.00 5.00 10.00 50.00 100.00 Organics, Method 1625: T= 0 4 CHLOROPHENYLPHENYL ETHER, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 0 4 NITROPHENOL, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 0 ACENAPHTHENE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.001 0.010 0.100 1.000 10.000 100.000 Organics, Method 1625: T= 0 ACENAPHTHYLENE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 0 ALPHA TERPINEOL, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 0 ANTHRACENE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 0 BENZIDINE, NG/ UL 0.05 0.50 5.00 50.00 0.05 0.10 0.50 1.00 5.00 10.00 50.00 100.00 Organics, Method 1625: T= 0 BENZO( A) ANTHRACENE, NG/ UL 0.05 0.50 5.00 50.00 0.1 1.0 10.0 100.0 Organics, Method 1625: T= 0 BENZO( A) PYRENE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 0 BENZO( B) FLUORANTHENE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 0 BENZO( GHI) PERYLENE, NG/ UL Measurement Results vs Spike Concentrations ( Log 10 Scale) Episode 6000 Data Page 21 of 32 Log 10 of Measured Concentration Log 10 of Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 44: 28 2002 0.05 0.50 5.00 50.00 0.1 1.0 10.0 100.0 Organics, Method 1625: T= 0 BENZO( K) FLUORANTHENE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 0 BETA NAPHTHYLAMINE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.1 1.0 10.0 100.0 Organics, Method 1625: T= 0 BIPHENYL, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 0 BIS( 2 CHLOROETHOXY) METHANE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 0 BIS( 2 CHLOROETHYL) ETHER, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.1 1.0 10.0 100.0 Organics, Method 1625: T= 0 BIS( 2 CHLOROISOPROPYL) ETHER, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.05 0.10 0.50 1.00 5.00 10.00 50.00 100.00 Organics, Method 1625: T= 0 BIS( 2 ETHYLHEXYL) PHTHALATE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.1 1.0 10.0 100.0 Organics, Method 1625: T= 0 BUTYL BENZYL PHTHALATE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 0 CARBAZOLE, NG/ UL 0.05 0.50 5.00 50.00 0.05 0.10 0.50 1.00 5.00 10.00 50.00 100.00 Organics, Method 1625: T= 0 CHRYSENE, NG/ UL 0.05 0.50 5.00 50.00 0.05 0.10 0.50 1.00 5.00 10.00 50.00 100.00 Organics, Method 1625: T= 0 DI N BUTYL PHTHALATE, NG/ UL 0.05 0.50 5.00 50.00 0.05 0.10 0.50 1.00 5.00 10.00 50.00 100.00 Organics, Method 1625: T= 0 DI N OCTYL PHTHALATE, NG/ UL Measurement Results vs Spike Concentrations ( Log 10 Scale) Episode 6000 Data Page 22 of 32 Log 10 of Measured Concentration Log 10 of Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 44: 43 2002 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 0 DI N PROPYLNITROSAMINE, NG/ UL 0.05 0.50 5.00 50.00 0.1 1.0 10.0 100.0 Organics, Method 1625: T= 0 DIBENZO( A, H) ANTHRACENE, NG/ UL 0.05 0.50 5.00 50.00 0.1 1.0 10.0 100.0 Organics, Method 1625: T= 0 DIBENZOFURAN, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 0 DIBENZOTHIOPHENE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.1 1.0 10.0 100.0 Organics, Method 1625: T= 0 DIETHYL PHTHALATE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 0 DIMETHYL PHTHALATE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 0 DIPHENYL ETHER, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 0 DIPHENYLAMINE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 0 FLUORANTHENE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 0 FLUORENE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 0 HEXACHLOROBENZENE, NG/ UL 0.05 0.50 5.00 50.00 0.05 0.10 0.50 1.00 5.00 10.00 50.00 100.00 Organics, Method 1625: T= 0 HEXACHLOROBUTADIENE, NG/ UL Measurement Results vs Spike Concentrations ( Log 10 Scale) Episode 6000 Data Page 23 of 32 Log 10 of Measured Concentration Log 10 of Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 44: 57 2002 0.05 0.50 5.00 50.00 0.05 0.10 0.50 1.00 5.00 10.00 50.00 100.00 Organics, Method 1625: T= 0 HEXACHLOROCYCLOPENTADIENE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.1 1.0 10.0 100.0 Organics, Method 1625: T= 0 HEXACHLOROETHANE, NG/ UL 0.05 0.50 5.00 50.00 0.05 0.10 0.50 1.00 5.00 10.00 50.00 100.00 Organics, Method 1625: T= 0 INDENO( 1,2,3 CD) PYRENE, NG/ UL 0.05 0.50 5.00 50.00 0.05 0.10 0.50 1.00 5.00 10.00 50.00 100.00 Organics, Method 1625: T= 0 ISOPHORONE, NG/ UL 0.05 0.50 5.00 50.00 0.05 0.10 0.50 1.00 5.00 10.00 50.00 100.00 Organics, Method 1625: T= 0 N DECANE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 0 N DOCOSANE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 0 N DODECANE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 0 N EICOSANE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.1 1.0 10.0 100.0 Organics, Method 1625: T= 0 N HEXACOSANE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 0 N HEXADECANE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 0 N NITROSODIMETHYLAMINE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 0 N NITROSODIPHENYLAMINE, NG/ UL Measurement Results vs Spike Concentrations ( Log 10 Scale) Episode 6000 Data Page 24 of 32 Log 10 of Measured Concentration Log 10 of Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 45: 11 2002 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.1 1.0 10.0 100.0 Organics, Method 1625: T= 0 N OCTACOSANE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 0 N OCTADECANE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.5 1.0 5.0 10.0 50.0 Organics, Method 1625: T= 0 N TETRACOSANE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 0 N TETRADECANE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 0 N TRIACONTANE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 0 NAPHTHALENE, NG/ UL 0.05 0.50 5.00 50.00 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 0 NITROBENZENE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 0 P CYMENE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.1 1.0 10.0 100.0 Organics, Method 1625: T= 0 PENTACHLOROPHENOL, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 0 PHENANTHRENE, NG/ UL 0.05 0.50 5.00 50.00 0.05 0.10 0.50 1.00 5.00 10.00 50.00 100.00 Organics, Method 1625: T= 0 PHENOL, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.1 1.0 10.0 100.0 Organics, Method 1625: T= 0 PHENOL, 2 METHYL 4,6 DINITRO, NG/ UL Measurement Results vs Spike Concentrations ( Log 10 Scale) Episode 6000 Data Page 25 of 32 Log 10 of Measured Concentration Log 10 of Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 45: 25 2002 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 0 PYRENE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 0 STYRENE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 1000 1,2,3 TRICHLOROBENZENE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 1000 1,2,4 TRICHLOROBENZENE, NG/ UL 0.05 0.50 5.00 50.00 0.05 0.10 0.50 1.00 5.00 10.00 50.00 100.00 Organics, Method 1625: T= 1000 1,2 DICHLOROBENZENE, NG/ UL 0.05 0.50 5.00 50.00 0.05 0.10 0.50 1.00 5.00 10.00 50.00 100.00 Organics, Method 1625: T= 1000 1,2 DIPHENYLHYDRAZINE, NG/ UL 0.05 0.50 5.00 50.00 0.05 0.10 0.50 1.00 5.00 10.00 50.00 100.00 Organics, Method 1625: T= 1000 1,3 DICHLOROBENZENE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.05 0.10 0.50 1.00 5.00 10.00 50.00 100.00 Organics, Method 1625: T= 1000 1,4 DICHLOROBENZENE, NG/ UL 0.05 0.50 5.00 50.00 0.1 1.0 10.0 100.0 Organics, Method 1625: T= 1000 2,3,6 TRICHLOROPHENOL, NG/ UL 0.05 0.50 5.00 50.00 0.05 0.10 0.50 1.00 5.00 10.00 50.00 100.00 Organics, Method 1625: T= 1000 2,4,5 TRICHLOROPHENOL, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.1 1.0 10.0 100.0 Organics, Method 1625: T= 1000 2,4,6 TRICHLOROPHENOL, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.1 0.5 1.0 5.0 10.0 50.0 100.0 Organics, Method 1625: T= 1000 2,4 DICHLOROPHENOL, NG/ UL Measurement Results vs Spike Concentrations ( Log 10 Scale) Episode 6000 Data Page 26 of 32 Log 10 of Measured Concentration Log 10 of Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 45: 39 2002 0.05 0.50 5.00 50.00 0.05 0.10 0.50 1.00 5.00 10.00 50.00 100.00 Organics, Method 1625: T= 1000 2,4 DIMETHYLPHENOL, NG/ UL 0.05 0.50 5.00 50.00 0.1 1.0 10.0 100.0 Organics, Method 1625: T= 1000 2,4 DINITROPHENOL, NG/ UL 0.05 0.50 5.00 50.00 0.1 1.0 10.0 100.0 Organics, Method 1625: T= 1000 2,4 DINITROTOLUENE, NG/ UL 0.1 0.5 5.0 50.0 0.1 0.5 1.0 5.0 10.0 50.0 100.0 Organics, Method 1625: T= 1000 2,6 DINITROTOLUENE, NG/ UL 0.05 0.50 5.00 50.00 0.05 0.10 0.50 1.00 5.00 10.00 50.00 100.00 Organics, Method 1625: T= 1000 2 CHLORONAPHTHALENE, NG/ UL 0.05 0.50 5.00 50.00 0.1 1.0 10.0 100.0 Organics, Method 1625: T= 1000 2 CHLOROPHENOL, NG/ UL 0.05 0.50 5.00 50.00 0.05 0.10 0.50 1.00 5.00 10.00 50.00 100.00 Organics, Method 1625: T= 1000 2 NITROPHENOL, NG/ UL 0.5 1.0 5.0 10.0 50.0 0.5 1.0 5.0 10.0 50.0 100.0 Organics, Method 1625: T= 1000 2 PICOLINE, NG/ UL 0.05 0.50 5.00 50.00 0.1 1.0 10.0 100.0 Organics, Method 1625: T= 1000 3,3' DICHLOROBENZIDINE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 1000 4 BROMOPHENYL PHENYL ETHER, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.1 1.0 10.0 100.0 Organics, Method 1625: T= 1000 4 CHLORO 3 METHYLPHENOL, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 1000 4 CHLOROPHENYLPHENYL ETHER, NG/ UL Measurement Results vs Spike Concentrations ( Log 10 Scale) Episode 6000 Data Page 27 of 32 Log 10 of Measured Concentration Log 10 of Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 45: 52 2002 1 5 10 50 100 0.5 1.0 5.0 10.0 50.0 100.0 Organics, Method 1625: T= 1000 4 NITROPHENOL, NG/ UL 0.05 0.50 5.00 50.00 0.05 0.10 0.50 1.00 5.00 10.00 50.00 100.00 Organics, Method 1625: T= 1000 ACENAPHTHENE, NG/ UL 0.05 0.50 5.00 50.00 0.1 1.0 10.0 100.0 Organics, Method 1625: T= 1000 ACENAPHTHYLENE, NG/ UL 0.05 0.50 5.00 50.00 0.1 1.0 10.0 100.0 Organics, Method 1625: T= 1000 ALPHA TERPINEOL, NG/ UL 0.05 0.50 5.00 50.00 0.05 0.10 0.50 1.00 5.00 10.00 50.00 100.00 Organics, Method 1625: T= 1000 ANTHRACENE, NG/ UL 0.05 0.50 5.00 50.00 0.05 0.10 0.50 1.00 5.00 10.00 50.00 100.00 Organics, Method 1625: T= 1000 BENZIDINE, NG/ UL 0.05 0.50 5.00 50.00 0.05 0.10 0.50 1.00 5.00 10.00 50.00 100.00 Organics, Method 1625: T= 1000 BENZO( A) ANTHRACENE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 1000 BENZO( A) PYRENE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.1 1.0 10.0 100.0 Organics, Method 1625: T= 1000 BENZO( B) FLUORANTHENE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.1 1.0 10.0 100.0 Organics, Method 1625: T= 1000 BENZO( GHI) PERYLENE, NG/ UL 0.05 0.50 5.00 50.00 0.1 1.0 10.0 100.0 Organics, Method 1625: T= 1000 BENZO( K) FLUORANTHENE, NG/ UL 0.05 0.50 5.00 50.00 0.1 1.0 10.0 100.0 Organics, Method 1625: T= 1000 BETA NAPHTHYLAMINE, NG/ UL Measurement Results vs Spike Concentrations ( Log 10 Scale) Episode 6000 Data Page 28 of 32 Log 10 of Measured Concentration Log 10 of Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 46: 06 2002 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.1 1.0 10.0 100.0 Organics, Method 1625: T= 1000 BIPHENYL, NG/ UL 0.05 0.50 5.00 50.00 0.05 0.10 0.50 1.00 5.00 10.00 50.00 100.00 Organics, Method 1625: T= 1000 BIS( 2 CHLOROETHOXY) METHANE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 1000 BIS( 2 CHLOROETHYL) ETHER, NG/ UL 0.1 0.5 5.0 50.0 0.05 0.10 0.50 1.00 5.00 10.00 50.00 100.00 Organics, Method 1625: T= 1000 BIS( 2 CHLOROISOPROPYL) ETHER, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.1 1.0 10.0 100.0 Organics, Method 1625: T= 1000 BIS( 2 ETHYLHEXYL) PHTHALATE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.1 1.0 10.0 100.0 Organics, Method 1625: T= 1000 BUTYL BENZYL PHTHALATE, NG/ UL 0.05 0.50 5.00 50.00 0.05 0.10 0.50 1.00 5.00 10.00 50.00 100.00 Organics, Method 1625: T= 1000 CARBAZOLE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 1000 CHRYSENE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 1000 DI N BUTYL PHTHALATE, NG/ UL 0.05 0.50 5.00 50.00 0.1 1.0 10.0 100.0 Organics, Method 1625: T= 1000 DI N OCTYL PHTHALATE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 1000 DI N PROPYLNITROSAMINE, NG/ UL 0.05 0.50 5.00 50.00 0.1 0.5 1.0 5.0 10.0 50.0 100.0 Organics, Method 1625: T= 1000 DIBENZO( A, H) ANTHRACENE, NG/ UL Measurement Results vs Spike Concentrations ( Log 10 Scale) Episode 6000 Data Page 29 of 32 Log 10 of Measured Concentration Log 10 of Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 46: 20 2002 0.05 0.50 5.00 50.00 0.05 0.10 0.50 1.00 5.00 10.00 50.00 100.00 Organics, Method 1625: T= 1000 DIBENZOFURAN, NG/ UL 0.05 0.50 5.00 50.00 0.05 0.10 0.50 1.00 5.00 10.00 50.00 100.00 Organics, Method 1625: T= 1000 DIBENZOTHIOPHENE, NG/ UL 0.05 0.50 5.00 50.00 0.05 0.10 0.50 1.00 5.00 10.00 50.00 100.00 Organics, Method 1625: T= 1000 DIETHYL PHTHALATE, NG/ UL 0.05 0.50 5.00 50.00 0.1 0.5 1.0 5.0 10.0 50.0 100.0 Organics, Method 1625: T= 1000 DIMETHYL PHTHALATE, NG/ UL 0.05 0.50 5.00 50.00 0.05 0.10 0.50 1.00 5.00 10.00 50.00 100.00 Organics, Method 1625: T= 1000 DIPHENYL ETHER, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.1 0.5 1.0 5.0 10.0 50.0 100.0 Organics, Method 1625: T= 1000 DIPHENYLAMINE, NG/ UL 0.05 0.50 5.00 50.00 0.05 0.10 0.50 1.00 5.00 10.00 50.00 100.00 Organics, Method 1625: T= 1000 FLUORANTHENE, NG/ UL 0.05 0.50 5.00 50.00 0.05 0.10 0.50 1.00 5.00 10.00 50.00 100.00 Organics, Method 1625: T= 1000 FLUORENE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.05 0.10 0.50 1.00 5.00 10.00 50.00 100.00 Organics, Method 1625: T= 1000 HEXACHLOROBENZENE, NG/ UL 0.05 0.50 5.00 50.00 0.05 0.10 0.50 1.00 5.00 10.00 50.00 100.00 Organics, Method 1625: T= 1000 HEXACHLOROBUTADIENE, NG/ UL 0.05 0.50 5.00 50.00 0.05 0.10 0.50 1.00 5.00 10.00 50.00 100.00 Organics, Method 1625: T= 1000 HEXACHLOROCYCLOPENTADIENE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.1 0.5 1.0 5.0 10.0 50.0 100.0 Organics, Method 1625: T= 1000 HEXACHLOROETHANE, NG/ UL Measurement Results vs Spike Concentrations ( Log 10 Scale) Episode 6000 Data Page 30 of 32 Log 10 of Measured Concentration Log 10 of Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 46: 33 2002 0.05 0.50 5.00 50.00 0.1 0.5 1.0 5.0 10.0 50.0 100.0 Organics, Method 1625: T= 1000 INDENO( 1,2,3 CD) PYRENE, NG/ UL 0.05 0.50 5.00 50.00 0.05 0.10 0.50 1.00 5.00 10.00 50.00 100.00 Organics, Method 1625: T= 1000 ISOPHORONE, NG/ UL 0.05 0.50 5.00 50.00 0.1 0.5 1.0 5.0 10.0 50.0 100.0 Organics, Method 1625: T= 1000 N DECANE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.001 0.010 0.100 1.000 10.000 100.000 Organics, Method 1625: T= 1000 N DOCOSANE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.1 1.0 10.0 100.0 Organics, Method 1625: T= 1000 N DODECANE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 1000 N EICOSANE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 1000 N HEXACOSANE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 1000 N HEXADECANE, NG/ UL 0.05 0.50 5.00 50.00 0.05 0.10 0.50 1.00 5.00 10.00 50.00 100.00 Organics, Method 1625: T= 1000 N NITROSODIMETHYLAMINE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.1 0.5 1.0 5.0 10.0 50.0 100.0 Organics, Method 1625: T= 1000 N NITROSODIPHENYLAMINE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.1 1.0 10.0 100.0 Organics, Method 1625: T= 1000 N OCTACOSANE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.001 0.010 0.100 1.000 10.000 100.000 Organics, Method 1625: T= 1000 N OCTADECANE, NG/ UL Measurement Results vs Spike Concentrations ( Log 10 Scale) Episode 6000 Data Page 31 of 32 Log 10 of Measured Concentration Log 10 of Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 46: 47 2002 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.5 1.0 5.0 10.0 50.0 Organics, Method 1625: T= 1000 N TETRACOSANE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.1 1.0 10.0 100.0 Organics, Method 1625: T= 1000 N TETRADECANE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 1000 N TRIACONTANE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 1000 NAPHTHALENE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.1 1.0 10.0 100.0 Organics, Method 1625: T= 1000 NITROBENZENE, NG/ UL 0.05 0.50 5.00 50.00 0.05 0.10 0.50 1.00 5.00 10.00 50.00 100.00 Organics, Method 1625: T= 1000 P CYMENE, NG/ UL 0.05 0.50 5.00 50.00 0.1 0.5 1.0 5.0 10.0 50.0 100.0 Organics, Method 1625: T= 1000 PENTACHLOROPHENOL, NG/ UL 0.05 0.50 5.00 50.00 0.05 0.10 0.50 1.00 5.00 10.00 50.00 100.00 Organics, Method 1625: T= 1000 PHENANTHRENE, NG/ UL 0.05 0.50 5.00 50.00 0.05 0.10 0.50 1.00 5.00 10.00 50.00 100.00 Organics, Method 1625: T= 1000 PHENOL, NG/ UL 0.05 0.50 5.00 50.00 0.05 0.10 0.50 1.00 5.00 10.00 50.00 100.00 Organics, Method 1625: T= 1000 PHENOL, 2 METHYL 4,6 DINITRO, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 1000 PYRENE, NG/ UL 10^ 4 10^ 3 10^ 2 10^ 1 10^ 0 10^ 1 10^ 2 0.01 0.10 1.00 10.00 100.00 Organics, Method 1625: T= 1000 STYRENE, NG/ UL Measurement Results vs Spike Concentrations ( Log 10 Scale) Episode 6000 Data Page 32 of 32 Log 10 of Measured Concentration Log 10 of Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 47: 01 2002 0.1 1.0 10.0 100.0 50 100 500 Lab: 1 ALUMINUM, UG/ L Measurement Results vs Spike Concentrations ( Log 10 Scale)

( Matrix A, Method EPA 200.7 ICP/ AES)

AAMA Metals Data Page 1 of 13 APPENDIX B  2  2 Log

10 of Measured Concentration Log 10 of Spike Concentration 0.1 1.0 10.0 100.0 10 50 100 500 Lab: 2 ALUMINUM, UG/ L 0.1 1.0 10.0 100.0 0.5 1.0 5.0 10.0 50.0 100.0 500.0 Lab: 3 ALUMINUM, UG/ L 0.1 1.0 10.0 100.0 50 100 500 1000 Lab: 4 ALUMINUM, UG/ L 0.1 1.0 10.0 100.0 90 100 200 300 400 500 600 Lab: 5 ALUMINUM, UG/ L 0.1 1.0 10.0 100.0 50 100 500 Lab: 6 ALUMINUM, UG/ L 50 100 500 5 10 50 100 500 Lab: 7 ALUMINUM, UG/ L 5 10 50 100 500 50 100 500 Lab: 8 ALUMINUM, UG/ L 0.1 1.0 10.0 100.0 5 10 50 100 500 Lab: 9 ALUMINUM, UG/ L 0.1 1.0 10.0 100.0 5 10 50 100 500 Lab: 1 ARSENIC, UG/ L Measurement Results vs Spike Concentrations ( Log 10 Scale)

( Matrix A, Method EPA 200.7 ICP/ AES)

AAMA Metals Data Page 2 of 13 Log

10 of Measured Concentration Log 10 of Spike Concentration c:/ pw/ ostmdl/ req005/ r005sd1. s Tue Mar 26 17: 16: 51 2002 0.1 1.0 10.0 100.0 50 100 500 Lab: 2 ARSENIC, UG/ L 0.1 1.0 10.0 100.0 1 5 10 50 100 500 Lab: 3 ARSENIC, UG/ L 5 10 50 100 500 5 10 50 100 500 Lab: 4 ARSENIC, UG/ L 5 10 50 100 500 0.1 1.0 10.0 100.0 Lab: 5 ARSENIC, UG/ L 0.1 1.0 10.0 100.0 5 10 50 100 500 Lab: 6 ARSENIC, UG/ L 5 10 50 100 500 1 5 10 50 100 500 Lab: 7 ARSENIC, UG/ L 5 10 50 100 500 5 10 50 100 500 Lab: 8 ARSENIC, UG/ L 5 10 50 100 500 0.1 1.0 10.0 100.0 Lab: 9 ARSENIC, UG/ L 1 5 10 50 100 1 5 10 50 100 Lab: 1 CADMIUM, UG/ L Measurement Results vs Spike Concentrations ( Log 10 Scale)

( Matrix A, Method EPA 200.7 ICP/ AES)

AAMA Metals Data Page 3 of 13 Log

10 of Measured Concentration Log 10 of Spike Concentration c:/ pw/ ostmdl/ req005/ r005sd1. s Tue Mar 26 17: 16: 54 2002 1 5 10 50 100 5 10 50 100 Lab: 2 CADMIUM, UG/ L 1 5 10 50 100 1 5 10 50 100 Lab: 3 CADMIUM, UG/ L 1 5 10 50 100 0.5 1.0 5.0 10.0 50.0 100.0 Lab: 4 CADMIUM, UG/ L 1 5 10 50 100 0.5 1.0 5.0 10.0 50.0 100.0 Lab: 5 CADMIUM, UG/ L 0.1 0.5 1.0 5.0 10.0 50.0 1 5 10 50 100 Lab: 6 CADMIUM, UG/ L 0.1 0.5 1.0 5.0 10.0 50.0 1 5 10 50 100 Lab: 7 CADMIUM, UG/ L 1 5 10 50 100 1 5 10 50 100 Lab: 8 CADMIUM, UG/ L 1 5 10 50 100 1 5 10 50 100 Lab: 9 CADMIUM, UG/ L 0.1 0.5 1.0 5.0 50.0 5 10 50 100 Lab: 1 CHROMIUM, UG/ L Measurement Results vs Spike Concentrations ( Log 10 Scale)

( Matrix A, Method EPA 200.7 ICP/ AES)

AAMA Metals Data Page 4 of 13 Log

10 of Measured Concentration Log 10 of Spike Concentration c:/ pw/ ostmdl/ req005/ r005sd1. s Tue Mar 26 17: 16: 56 2002 0.1 0.5 1.0 5.0 50.0 0.5 1.0 5.0 10.0 50.0 100.0 Lab: 2 CHROMIUM, UG/ L 5 10 50 100 1 5 10 50 100 Lab: 3 CHROMIUM, UG/ L 0.1 0.5 1.0 5.0 50.0 5 10 50 100 Lab: 4 CHROMIUM, UG/ L 0.1 0.5 1.0 5.0 50.0 5 10 50 100 Lab: 5 CHROMIUM, UG/ L 0.1 0.5 1.0 5.0 50.0 1 5 10 50 100 Lab: 6 CHROMIUM, UG/ L 5 10 50 100 5 10 50 100 Lab: 7 CHROMIUM, UG/ L 5 10 50 100 5 10 50 100 Lab: 8 CHROMIUM, UG/ L 5 10 50 100 5 10 50 100 Lab: 9 CHROMIUM, UG/ L 0.1 0.5 1.0 5.0 50.0 5 10 50 100 Lab: 1 COPPER, UG/ L Measurement Results vs Spike Concentrations ( Log 10 Scale)

( Matrix A, Method EPA 200.7 ICP/ AES)

AAMA Metals Data Page 5 of 13 Log

10 of Measured Concentration Log 10 of Spike Concentration c:/ pw/ ostmdl/ req005/ r005sd1. s Tue Mar 26 17: 16: 59 2002 0.1 0.5 1.0 5.0 50.0 0.5 1.0 5.0 10.0 50.0 100.0 Lab: 2 COPPER, UG/ L 0.1 0.5 1.0 5.0 50.0 0.5 1.0 5.0 10.0 50.0 100.0 Lab: 3 COPPER, UG/ L 0.1 0.5 1.0 5.0 50.0 5 10 50 100 Lab: 4 COPPER, UG/ L 0.1 0.5 1.0 5.0 50.0 5 10 50 100 Lab: 5 COPPER, UG/ L 0.1 0.5 1.0 5.0 50.0 1 5 10 50 100 Lab: 6 COPPER, UG/ L 5 10 50 100 5 10 50 100 Lab: 7 COPPER, UG/ L 5 10 50 100 5 10 50 100 Lab: 8 COPPER, UG/ L 0.1 0.5 1.0 5.0 50.0 1 5 10 50 100 Lab: 9 COPPER, UG/ L 5 10 50 100 500 1 5 10 50 100 500 Lab: 1 LEAD, UG/ L Measurement Results vs Spike Concentrations ( Log 10 Scale)

( Matrix A, Method EPA 200.7 ICP/ AES)

AAMA Metals Data Page 6 of 13 Log

10 of Measured Concentration Log 10 of Spike Concentration c:/ pw/ ostmdl/ req005/ r005sd1. s Tue Mar 26 17: 17: 01 2002 0.1 1.0 10.0 100.0 1 5 10 50 100 500 Lab: 2 LEAD, UG/ L 0.1 1.0 10.0 100.0 5 10 50 100 500 Lab: 3 LEAD, UG/ L 0.1 1.0 10.0 100.0 5 10 50 100 500 Lab: 4 LEAD, UG/ L 0.1 1.0 10.0 100.0 5 10 50 100 500 Lab: 5 LEAD, UG/ L 0.1 1.0 10.0 100.0 5 10 50 100 500 Lab: 6 LEAD, UG/ L 0.1 1.0 10.0 100.0 5 10 50 100 500 Lab: 7 LEAD, UG/ L 5 10 50 100 500 5 10 50 100 500 Lab: 8 LEAD, UG/ L 0.1 1.0 10.0 100.0 5 10 50 100 500 Lab: 9 LEAD, UG/ L 0.5 1.0 5.0 10.0 50.0 5 10 50 Lab: 1 MANGANESE, UG/ L Measurement Results vs Spike Concentrations ( Log 10 Scale)

( Matrix A, Method EPA 200.7 ICP/ AES)

AAMA Metals Data Page 7 of 13 Log

10 of Measured Concentration Log 10 of Spike Concentration c:/ pw/ ostmdl/ req005/ r005sd1. s Tue Mar 26 17: 17: 04 2002 5 10 50 1 5 10 50 Lab: 2 MANGANESE, UG/ L 0.5 1.0 5.0 10.0 50.0 0.1 0.5 1.0 5.0 10.0 50.0 Lab: 3 MANGANESE, UG/ L 0.1 0.5 1.0 5.0 10.0 50.0 0.5 1.0 5.0 10.0 50.0 Lab: 4 MANGANESE, UG/ L 0.1 0.5 1.0 5.0 10.0 50.0 0.5 1.0 5.0 10.0 50.0 Lab: 5 MANGANESE, UG/ L 0.1 0.5 1.0 5.0 10.0 50.0 0.5 1.0 5.0 10.0 50.0 Lab: 6 MANGANESE, UG/ L 0.5 1.0 5.0 10.0 50.0 0.5 1.0 5.0 10.0 50.0 Lab: 7 MANGANESE, UG/ L 0.5 1.0 5.0 10.0 50.0 0.5 1.0 5.0 10.0 50.0 Lab: 8 MANGANESE, UG/ L 0.1 0.5 1.0 5.0 10.0 50.0 0.01 0.10 1.00 10.00 Lab: 9 MANGANESE, UG/ L 0.01 0.05 0.10 0.50 1.00 0.01 0.05 0.10 0.50 1.00 Lab: 1 MERCURY, UG/ L Measurement Results vs Spike Concentrations ( Log 10 Scale)

( Matrix A, Method EPA 245 CVA)

AAMA Metals Data Page 8 of 13 Log

10 of Measured Concentration Log 10 of Spike Concentration c:/ pw/ ostmdl/ req005/ r005sd1. s Tue Mar 26 17: 17: 07 2002 0.01 0.05 0.10 0.50 1.00 0.01 0.05 0.10 0.50 1.00 Lab: 2 MERCURY, UG/ L 0.01 0.05 0.10 0.50 1.00 0.05 0.10 0.50 1.00 Lab: 3 MERCURY, UG/ L 0.001 0.005 0.050 0.500 0.01 0.05 0.10 0.50 1.00 Lab: 4 MERCURY, UG/ L 0.001 0.005 0.050 0.500 0.01 0.05 0.10 0.50 1.00 Lab: 5 MERCURY, UG/ L 0.001 0.005 0.050 0.500 0.05 0.10 0.50 1.00 5.00 10.00 Lab: 6 MERCURY, UG/ L 0.01 0.05 0.10 0.50 1.00 0.005 0.010 0.050 0.100 0.500 1.000 Lab: 7 MERCURY, UG/ L 0.01 0.05 0.10 0.50 1.00 0.05 0.10 0.50 1.00 Lab: 8 MERCURY, UG/ L 0.001 0.005 0.050 0.500 0.05 0.10 0.50 1.00 Lab: 9 MERCURY, UG/ L 0.1 0.5 1.0 5.0 50.0 5 10 50 100 Lab: 1 MOLYBDENUM, UG/ L Measurement Results vs Spike Concentrations ( Log 10 Scale)

( Matrix A, Method EPA 200.7 ICP/ AES)

AAMA Metals Data Page 9 of 13 Log

10 of Measured Concentration Log 10 of Spike Concentration c:/ pw/ ostmdl/ req005/ r005sd1. s Tue Mar 26 17: 17: 10 2002 5 10 50 100 10 50 100 Lab: 2 MOLYBDENUM, UG/ L 0.1 0.5 1.0 5.0 50.0 0.5 1.0 5.0 10.0 50.0 100.0 Lab: 3 MOLYBDENUM, UG/ L 5 10 50 100 0.5 1.0 5.0 10.0 50.0 100.0 Lab: 4 MOLYBDENUM, UG/ L 0.1 0.5 1.0 5.0 50.0 1 5 10 50 100 Lab: 5 MOLYBDENUM, UG/ L 0.1 0.5 1.0 5.0 50.0 5 10 50 100 Lab: 6 MOLYBDENUM, UG/ L 5 10 50 100 5 10 50 100 Lab: 7 MOLYBDENUM, UG/ L 5 10 50 100 1 5 10 50 100 Lab: 8 MOLYBDENUM, UG/ L 0.1 0.5 1.0 5.0 50.0 1 5 10 50 100 Lab: 9 MOLYBDENUM, UG/ L 5 10 50 100 5 10 50 100 Lab: 1 NICKEL, UG/ L Measurement Results vs Spike Concentrations ( Log 10 Scale)

( Matrix A, Method EPA 200.7 ICP/ AES)

AAMA Metals Data Page 10 of 13 Log

10 of Measured Concentration Log 10 of Spike Concentration c:/ pw/ ostmdl/ req005/ r005sd1. s Tue Mar 26 17: 17: 13 2002 0.1 0.5 1.0 5.0 50.0 1 5 10 50 100 Lab: 2 NICKEL, UG/ L 0.1 0.5 1.0 5.0 50.0 0.5 1.0 5.0 10.0 50.0 100.0 Lab: 3 NICKEL, UG/ L 0.1 0.5 1.0 5.0 50.0 50 100 Lab: 4 NICKEL, UG/ L 0.1 0.5 1.0 5.0 50.0 5 10 50 100 Lab: 5 NICKEL, UG/ L 0.1 0.5 1.0 5.0 50.0 5 10 50 100 500 1000 Lab: 6 NICKEL, UG/ L 5 10 50 100 5 10 50 100 Lab: 7 NICKEL, UG/ L 5 10 50 100 1 5 10 50 100 Lab: 8 NICKEL, UG/ L 5 10 50 100 5 10 50 100 Lab: 9 NICKEL, UG/ L 10 50 100 500 1000 10 50 100 500 1000 Lab: 1 SELENIUM, UG/ L Measurement Results vs Spike Concentrations ( Log 10 Scale)

( Matrix A, Method EPA 200.7 ICP/ AES)

AAMA Metals Data Page 11 of 13 Log

10 of Measured Concentration Log 10 of Spike Concentration c:/ pw/ ostmdl/ req005/ r005sd1. s Tue Mar 26 17: 17: 16 2002 10 50 100 500 1000 1 5 10 50 100 500 1000 Lab: 2 SELENIUM, UG/ L 0.1 1.0 10.0 100.0 1000.0 0.5 1.0 5.0 10.0 50.0 100.0 500.0 1000.0 Lab: 3 SELENIUM, UG/ L 10 50 100 500 1000 10 50 100 500 1000 Lab: 4 SELENIUM, UG/ L 0.1 1.0 10.0 100.0 1000.0 1 10 100 1000 Lab: 5 SELENIUM, UG/ L 0.1 1.0 10.0 100.0 1000.0 1 5 10 50 100 500 1000 Lab: 6 SELENIUM, UG/ L 10 50 100 500 1000 5 10 50 100 500 1000 Lab: 7 SELENIUM, UG/ L 0.1 1.0 10.0 100.0 1000.0 5 10 50 100 500 1000 Lab: 8 SELENIUM, UG/ L 0.1 1.0 10.0 100.0 1000.0 10 50 100 500 1000 Lab: 9 SELENIUM, UG/ L 0.1 0.5 1.0 5.0 10.0 50.0 1 5 10 50 100 Lab: 1 SILVER, UG/ L Measurement Results vs Spike Concentrations ( Log 10 Scale)

( Matrix A, Method EPA 200.7 ICP/ AES)

AAMA Metals Data Page 12 of 13 Log

10 of Measured Concentration Log 10 of Spike Concentration c:/ pw/ ostmdl/ req005/ r005sd1. s Tue Mar 26 17: 17: 19 2002 0.5 1.0 5.0 10.0 50.0 0.5 1.0 5.0 10.0 50.0 100.0 Lab: 2 SILVER, UG/ L 0.1 0.5 1.0 5.0 10.0 50.0 0.5 1.0 5.0 10.0 50.0 100.0 Lab: 3 SILVER, UG/ L 0.1 0.5 1.0 5.0 10.0 50.0 5 10 50 100 Lab: 4 SILVER, UG/ L 0.1 0.5 1.0 5.0 10.0 50.0 0.1 0.5 1.0 5.0 10.0 50.0 100.0 Lab: 5 SILVER, UG/ L 0.1 0.5 1.0 5.0 10.0 50.0 0.5 1.0 5.0 10.0 50.0 100.0 Lab: 6 SILVER, UG/ L 0.1 0.5 1.0 5.0 10.0 50.0 1 5 10 50 100 Lab: 7 SILVER, UG/ L 0.5 1.0 5.0 10.0 50.0 1 5 10 50 100 Lab: 8 SILVER, UG/ L 0.1 0.5 1.0 5.0 10.0 50.0 0.01 0.10 1.00 10.00 100.00 Lab: 9 SILVER, UG/ L 0.1 0.5 1.0 5.0 50.0 5 10 50 100 Lab: 1 ZINC, UG/ L Measurement Results vs Spike Concentrations ( Log 10 Scale)

( Matrix A, Method EPA 200.7 ICP/ AES)

AAMA Metals Data Page 13 of 13 Log

10 of Measured Concentration Log 10 of Spike Concentration c:/ pw/ ostmdl/ req005/ r005sd1. s Tue Mar 26 17: 17: 21 2002 5 10 50 100 1 5 10 50 100 Lab: 2 ZINC, UG/ L 0.1 0.5 1.0 5.0 50.0 5 10 50 100 Lab: 3 ZINC, UG/ L 0.1 0.5 1.0 5.0 50.0 5 10 50 100 Lab: 4 ZINC, UG/ L 0.1 0.5 1.0 5.0 50.0 5 10 50 100 Lab: 5 ZINC, UG/ L 0.1 0.5 1.0 5.0 50.0 5 10 50 100 Lab: 6 ZINC, UG/ L 0.1 0.5 1.0 5.0 50.0 50 100 Lab: 7 ZINC, UG/ L 0.1 0.5 1.0 5.0 50.0 5 10 50 100 Lab: 8 ZINC, UG/ L 0.1 0.5 1.0 5.0 50.0 0.1 0.5 1.0 5.0 10.0 50.0 100.0 Lab: 9 ZINC, UG/ L 0 50 100 150 0.4 0.6 0.8 1.0 1.2 1.4 Classicals, Method 130.2 HARDNESS, MG/ L Standard Deviations vs Spike Concentrations ( Original Scale) Episode 6000 Data Page 1 of 32 APPENDIX B  3  1 Observed Standard Deviation Spike Concentration 0 50 100 150 200 0.0 0.5 1.0 1.5 Classicals, Method 160.2 TOTAL SUSPENDED SOLIDS, MG/ L 0 10 20 30 40 50 0.1 0.2 0.3 0.4 Classicals, Method 1677 WAD CYANIDE, UG/ L 0.0 0.2 0.4 0.6 0.8 1.0 0.0 0.01 0.02 0.03 0.04 0.05 0.06 Classicals, Method 350.3 AMMONIA AS NITROGEN, MG/ L 0.0 0.2 0.4 0.6 0.8 1.0 0.002 0.003 0.004 0.005 0.006 Classicals, Method 365.2 TOTAL PHOSPHORUS, MG/ L 0 5000 10000 15000 20000 25000 0 50 100 150 200 250 Metals, Method ICP/ MS Ag 107, ppt 0 5000 10000 15000 20000 25000 0 50 100 150 Metals, Method ICP/ MS Cd 111, ppt 0 5000 10000 15000 20000 25000 0 20 40 60 80 100 120 140 Metals, Method ICP/ MS Cu 63, ppt 0 5000 10000 15000 20000 25000 0 50 100 150 200 250 Metals, Method ICP/ MS Ni 60, ppt 0 5000 10000 15000 20000 25000 0 50 100 150 200 250 Metals, Method ICP/ MS Pb 206, ppt 0 5000 10000 15000 20000 25000 0 50 100 150 200 Metals, Method ICP/ MS Pb 207, ppt 0 5000 10000 15000 20000 25000 0 50 100 150 200 250 Metals, Method ICP/ MS Pb 208, ppt 0 5000 10000 15000 20000 25000 0 50 100 150 200 Metals, Method ICP/ MS Sb 123, ppt Standard Deviations vs Spike Concentrations ( Original Scale) Episode 6000 Data Page 2 of 32 Observed Standard Deviation Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 03: 03 2002 0 5000 10000 15000 20000 25000 100 200 300 400 500 600 Metals, Method ICP/ MS Se 82, ppt 0 5000 10000 15000 20000 25000 0 50 100 150 200 250 300 Metals, Method ICP/ MS Tl 205, ppt 0 5000 10000 15000 20000 25000 0 50 100 150 200 250 300 Metals, Method ICP/ MS Zn 66, ppt 0 200 400 600 800 1000 1200 0 50 100 150 Metals, Method 1620 ALUMINUM, UG/ L 0 20 40 60 80 100 0.4 0.6 0.8 1.0 1.2 Metals, Method 1620 ANTIMONY, UG/ L 0 20 40 60 0.4 0.6 0.8 1.0 1.2 Metals, Method 1620 ARSENIC, UG/ L 0 20 40 60 0.2 0.4 0.6 0.8 1.0 1.2 Metals, Method 1620 BARIUM, UG/ L 0 10 20 30 40 50 60 0.5 1.0 1.5 2.0 Metals, Method 1620 BERYLLIUM, UG/ L 0 500 1000 1500 5 10 15 20 25 Metals, Method 1620 BORON, UG/ L 0 5 10 15 0.05 0.10 0.15 0.20 Metals, Method 1620 CADMIUM, UG/ L 0 200 400 600 800 1000 1200 1400 5 10 15 20 Metals, Method 1620 CALCIUM, UG/ L 0 20 40 60 80 0.2 0.4 0.6 0.8 Metals, Method 1620 CHROMIUM, UG/ L Standard Deviations vs Spike Concentrations ( Original Scale) Episode 6000 Data Page 3 of 32 Observed Standard Deviation Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 03: 16 2002 0 200 400 600 800 1000 1200 5 10 15 Metals, Method 1620 COBALT, UG/ L 0 100 200 300 2 4 6 8 10 Metals, Method 1620 COPPER, UG/ L 0 200 400 600 800 0 100 200 300 Metals, Method 1620 IRON, UG/ L 0 50 100 150 200 250 0.5 1.0 1.5 2.0 2.5 Metals, Method 1620 LEAD, UG/ L 0 1000 2000 3000 4000 5000 20 30 40 50 60 Metals, Method 1620 MAGNESIUM, UG/ L 0 20 40 60 80 100 120 1 2 3 Metals, Method 1620 MANGANESE, UG/ L 0 50 100 150 200 0.5 1.0 1.5 2.0 Metals, Method 1620 MOLYBDENUM, UG/ L 0 500 1000 1500 5 10 15 20 25 30 Metals, Method 1620 NICKEL, UG/ L 0 20 40 60 80 100 120 0.5 1.0 1.5 Metals, Method 1620 SELENIUM, UG/ L 0 100 200 300 400 500 2 3 4 5 6 Metals, Method 1620 SILVER, UG/ L 0 1000 2000 3000 4000 20 30 40 50 60 70 Metals, Method 1620 SODIUM, UG/ L 0 20 40 60 80 0.2 0.3 0.4 0.5 0.6 0.7 Metals, Method 1620 THALLIUM, UG/ L Standard Deviations vs Spike Concentrations ( Original Scale) Episode 6000 Data Page 4 of 32 Observed Standard Deviation Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 03: 29 2002 0 100 200 300 0.5 1.0 1.5 2.0 2.5 3.0 3.5 Metals, Method 1620 TIN, UG/ L 0 100 200 300 1 2 3 4 Metals, Method 1620 TITANIUM, UG/ L 0 200 400 600 5 10 15 Metals, Method 1620 VANADIUM, UG/ L 0 20 40 60 80 0.5 1.0 1.5 2.0 Metals, Method 1620 YTTRIUM, UG/ L 0 50 100 150 200 250 0 2 4 6 8 10 12 14 Metals, Method 1620 ZINC, UG/ L 0 200 400 600 800 1000 0 5 10 15 20 25 30 Metals, Method 200.8 ALUMINUM, UG/ L 0 2 4 6 8 10 0.0 0.05 0.10 0.15 Metals, Method 200.8 ANTIMONY, UG/ L 0 20 40 60 80 100 0.0 0.5 1.0 1.5 Metals, Method 200.8 ARSENIC, UG/ L 0 5 10 15 20 0.0 0.05 0.10 0.15 Metals, Method 200.8 BARIUM, UG/ L 0 1 2 3 4 5 0.0 0.05 0.10 0.15 Metals, Method 200.8 BERYLLIUM, UG/ L 0.0 0.5 1.0 1.5 2.0 0.0 0.005 0.010 0.015 0.020 0.025 0.030 Metals, Method 200.8 CADMIUM, UG/ L 0 5 10 15 20 0.05 0.10 0.15 0.20 0.25 0.30 0.35 Metals, Method 200.8 CHROMIUM, UG/ L Standard Deviations vs Spike Concentrations ( Original Scale) Episode 6000 Data Page 5 of 32 Observed Standard Deviation Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 03: 44 2002 0.0 0.2 0.4 0.6 0.8 1.0 0.0 0.01 0.02 0.03 Metals, Method 200.8 COBALT, UG/ L 0 5 10 15 20 0.0 0.1 0.2 0.3 0.4 0.5 0.6 Metals, Method 200.8 COPPER, UG/ L 0 10 20 30 40 50 0.0 0.2 0.4 0.6 0.8 Metals, Method 200.8 LEAD, UG/ L 0.0 0.5 1.0 1.5 2.0 0.0 0.02 0.04 0.06 Metals, Method 200.8 MANGANESE, UG/ L 0 2 4 6 8 10 0.0 0.05 0.10 0.15 0.20 0.25 0.30 Metals, Method 200.8 MERCURY, UG/ L 0.0 0.2 0.4 0.6 0.8 1.0 0.0 0.05 0.10 0.15 0.20 Metals, Method 200.8 MOLYBDENUM, UG/ L 0 2 4 6 8 10 0.0 0.2 0.4 0.6 0.8 1.0 Metals, Method 200.8 NICKEL, UG/ L 0 20 40 60 80 100 0.0 0.5 1.0 1.5 Metals, Method 200.8 SELENIUM, UG/ L 0.0 0.2 0.4 0.6 0.8 1.0 0.0 0.005 0.010 0.015 0.020 0.025 Metals, Method 200.8 SILVER, UG/ L 0.0 0.05 0.10 0.15 0.20 0.0005 0.0010 0.0015 0.0020 Metals, Method 200.8 THALLIUM, UG/ L 0.0 0.2 0.4 0.6 0.8 1.0 0.0 0.005 0.010 0.015 0.020 0.025 Metals, Method 200.8 THORIUM, UG/ L 0.0 0.02 0.04 0.06 0.08 0.10 0.0 0.0005 0.0010 0.0015 0.0020 Metals, Method 200.8 URANIUM, UG/ L Standard Deviations vs Spike Concentrations ( Original Scale) Episode 6000 Data Page 6 of 32 Observed Standard Deviation Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 04: 01 2002 0 50 100 150 200 0.5 1.0 1.5 2.0 2.5 Metals, Method 200.8 VANADIUM, UG/ L 0 50 100 150 200 0 1 2 3 4 5 6 Metals, Method 200.8 ZINC, UG/ L 0 2 4 6 8 10 0.0 0.1 0.2 0.3 0.4 0.5 Organics, Method 502.2 ELCD 1,1,1,2 TETRACHLOROETHANE, UG/ L 0 2 4 6 8 10 0.0 0.2 0.4 0.6 Organics, Method 502.2 ELCD 1,1,1 TRICHLOROETHANE, UG/ L 0 5 10 15 20 0.0 0.2 0.4 0.6 0.8 1.0 1.2 1.4 Organics, Method 502.2 ELCD 1,1,2,2 TCE+ 1,2,3 TCP, UG/ L 0 2 4 6 8 10 0.0 0.1 0.2 0.3 0.4 Organics, Method 502.2 ELCD 1,1,2 TRICHLOROETHANE, UG/ L 0 2 4 6 8 10 0.0 0.1 0.2 0.3 0.4 0.5 Organics, Method 502.2 ELCD 1,1 DICHLOROETHANE, UG/ L 0 2 4 6 8 10 0.0 0.1 0.2 0.3 0.4 0.5 0.6 Organics, Method 502.2 ELCD 1,1 DICHLOROETHENE, UG/ L 0 2 4 6 8 10 0.0 0.2 0.4 0.6 Organics, Method 502.2 ELCD 1,2,3 TRICHLOROBENZENE, UG/ L 0 2 4 6 8 10 0.0 0.1 0.2 0.3 0.4 0.5 Organics, Method 502.2 ELCD 1,2,4 TRICHLOROBENZENE, UG/ L 0 2 4 6 8 10 0.0 0.1 0.2 0.3 Organics, Method 502.2 ELCD 1,2 DIBROMOETHANE, UG/ L 0 2 4 6 8 10 0.0 0.1 0.2 0.3 0.4 0.5 Organics, Method 502.2 ELCD 1,2 DICHLOROBENZENE, UG/ L Standard Deviations vs Spike Concentrations ( Original Scale) Episode 6000 Data Page 7 of 32 Observed Standard Deviation Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 04: 15 2002 0 2 4 6 8 10 0.0 0.2 0.4 0.6 0.8 Organics, Method 502.2 ELCD 1,2 DICHLOROETHANE, UG/ L 0 2 4 6 8 10 0.0 0.1 0.2 0.3 0.4 0.5 Organics, Method 502.2 ELCD 1,2 DICHLOROPROPANE, UG/ L 0 2 4 6 8 10 0.0 0.1 0.2 0.3 0.4 Organics, Method 502.2 ELCD 1,3 DICHLOROBENZENE, UG/ L 0 2 4 6 8 10 0.0 0.1 0.2 0.3 0.4 Organics, Method 502.2 ELCD 1,3 DICHLOROPROPANE, UG/ L 0 2 4 6 8 10 0.0 0.1 0.2 0.3 0.4 Organics, Method 502.2 ELCD 1,4 DICHLOROBENZENE, UG/ L 0 2 4 6 8 10 0.0 0.2 0.4 0.6 0.8 1.0 1.2 Organics, Method 502.2 ELCD 2 CHLOROTOLUENE, UG/ L 0 2 4 6 8 10 0.0 0.5 1.0 1.5 Organics, Method 502.2 ELCD 4 CHLOROTOLUENE, UG/ L 0 2 4 6 8 10 0.1 0.2 0.3 0.4 0.5 0.6 Organics, Method 502.2 ELCD BROMOBENZENE, UG/ L 0 2 4 6 8 10 0.0 0.1 0.2 0.3 0.4 0.5 Organics, Method 502.2 ELCD BROMOCHLOROMETHANE, UG/ L 0 2 4 6 8 10 0.0 0.1 0.2 0.3 0.4 Organics, Method 502.2 ELCD BROMODICHLOROMETHANE, UG/ L 0 2 4 6 8 10 0.0 0.1 0.2 0.3 Organics, Method 502.2 ELCD BROMOFORM, UG/ L 2 4 6 8 10 0.10 0.15 0.20 0.25 Organics, Method 502.2 ELCD BROMOMETHANE, UG/ L Standard Deviations vs Spike Concentrations ( Original Scale) Episode 6000 Data Page 8 of 32 Observed Standard Deviation Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 04: 28 2002 0 5 10 15 20 0.0 0.2 0.4 0.6 0.8 1.0 1.2 Organics, Method 502.2 ELCD CARBONTET+ 1,1 DCP, UG/ L 0 2 4 6 8 10 0.0 0.1 0.2 0.3 0.4 0.5 Organics, Method 502.2 ELCD CHLOROBENZENE, UG/ L 0 2 4 6 8 10 0.0 0.1 0.2 0.3 0.4 Organics, Method 502.2 ELCD CHLOROETHANE, UG/ L 0 2 4 6 8 10 0.0 0.1 0.2 0.3 0.4 0.5 0.6 Organics, Method 502.2 ELCD CHLOROFORM, UG/ L 0 2 4 6 8 10 0.0 0.1 0.2 0.3 Organics, Method 502.2 ELCD CHLOROMETHANE, UG/ L 0 5 10 15 20 0.0 0.2 0.4 0.6 0.8 1.0 1.2 Organics, Method 502.2 ELCD CIS 1,2 DCE+ 2,2 DCP, UG/ L 0 2 4 6 8 10 0.0 0.1 0.2 0.3 0.4 0.5 Organics, Method 502.2 ELCD CIS 1,3 DICHLOROPROPENE, UG/ L 0 2 4 6 8 10 0.0 0.1 0.2 0.3 Organics, Method 502.2 ELCD DIBROMOCHLOROMETHANE, UG/ L 0 2 4 6 8 10 0.0 0.1 0.2 0.3 0.4 Organics, Method 502.2 ELCD DIBROMOMETHANE, UG/ L 0 2 4 6 8 10 0.0 0.5 1.0 1.5 2.0 Organics, Method 502.2 ELCD DICHLORODIFLUOROMETHANE, UG/ L 0 2 4 6 8 10 0.0 0.1 0.2 0.3 0.4 0.5 0.6 Organics, Method 502.2 ELCD HEXACHLOROBUTADIENE, UG/ L 0 2 4 6 8 10 0.0 0.2 0.4 0.6 0.8 Organics, Method 502.2 ELCD METHYLENE CHLORIDE, UG/ L Standard Deviations vs Spike Concentrations ( Original Scale) Episode 6000 Data Page 9 of 32 Observed Standard Deviation Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 04: 44 2002 0 2 4 6 8 10 0.0 0.1 0.2 0.3 0.4 0.5 0.6 Organics, Method 502.2 ELCD TETRACHLOROETHENE, UG/ L 0 2 4 6 8 10 0.0 0.1 0.2 0.3 0.4 0.5 Organics, Method 502.2 ELCD TRANS 1,2 DICHLOROETHENE, UG/ L 0 2 4 6 8 10 0.0 0.1 0.2 0.3 0.4 Organics, Method 502.2 ELCD TRANS 1,3 DICHLOROPROPENE, UG/ L 0 2 4 6 8 10 0.0 0.2 0.4 0.6 Organics, Method 502.2 ELCD TRICHLOROETHENE, UG/ L 0 2 4 6 8 10 6.835908* 10^ 6 1.000055* 10^ 1 2.000041* 10^ 1 3.000027* 10^ 1 4.000013* 10^ 1 5* 10^ 1 Organics, Method 502.2 ELCD TRICHLOROFLUOROMETHANE, UG/ L 0 2 4 6 8 10 0.1 0.2 0.3 Organics, Method 502.2 ELCD VINYL CHLORIDE, UG/ L 0 2 4 6 8 10 0.0 0.1 0.2 0.3 0.4 Organics, Method 502.2 PID 1,2,3 TRICHLOROBENZENE, UG/ L 0 2 4 6 8 10 0.0 0.1 0.2 0.3 0.4 Organics, Method 502.2 PID 1,2,4 TRICHLOROBENZENE, UG/ L 0 2 4 6 8 10 0.0 0.1 0.2 0.3 0.4 0.5 Organics, Method 502.2 PID 1,2,4 TRIMETHYLBENZENE, UG/ L 0 2 4 6 8 10 0.0 0.1 0.2 0.3 0.4 0.5 Organics, Method 502.2 PID 1,2 DICHLOROBENZENE, UG/ L 0 5 10 15 20 0.0 0.2 0.4 0.6 0.8 Organics, Method 502.2 PID 1,3,5 TMB+ 4 CHLOROTOLUENE, UG/ L 0 2 4 6 8 10 0.0 0.1 0.2 0.3 0.4 0.5 Organics, Method 502.2 PID 1,3 DICHLOROBENZENE, UG/ L Standard Deviations vs Spike Concentrations ( Original Scale) Episode 6000 Data Page 10 of 32 Observed Standard Deviation Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 05: 01 2002 0 2 4 6 8 10 0.1 0.2 0.3 0.4 0.5 Organics, Method 502.2 PID 2 CHLOROTOLUENE, UG/ L 0 2 4 6 8 10 0.0 0.1 0.2 0.3 0.4 0.5 Organics, Method 502.2 PID BENZENE, UG/ L 0 2 4 6 8 10 0.0 0.1 0.2 0.3 0.4 Organics, Method 502.2 PID BROMOBENZENE, UG/ L 0 2 4 6 8 10 0.0 0.1 0.2 0.3 0.4 0.5 Organics, Method 502.2 PID CHLOROBENZENE, UG/ L 0 2 4 6 8 10 0.0 0.1 0.2 0.3 0.4 0.5 0.6 Organics, Method 502.2 PID CIS 1,3 DICHLOROPROPENE, UG/ L 0 2 4 6 8 10 0.0 0.1 0.2 0.3 0.4 0.5 0.6 Organics, Method 502.2 PID ETHYLBENZENE, UG/ L 0 5 10 15 20 0.1 0.2 0.3 0.4 0.5 Organics, Method 502.2 PID HEXCHLOBUTADIENE+ NAPHTHALENE, UG/ L 0 2 4 6 8 10 0.0 0.1 0.2 0.3 0.4 0.5 Organics, Method 502.2 PID ISOPROPYLBENZENE, UG/ L 0 5 10 15 20 0.0 0.2 0.4 0.6 0.8 1.0 Organics, Method 502.2 PID M+ P XYLENE, UG/ L 0 2 4 6 8 10 0.0 0.1 0.2 0.3 0.4 Organics, Method 502.2 PID N BUTYLBENZENE, UG/ L 0 2 4 6 8 10 0.0 0.1 0.2 0.3 0.4 Organics, Method 502.2 PID N PROPYLBENZENE, UG/ L 0 5 10 15 20 0.0 0.2 0.4 0.6 0.8 Organics, Method 502.2 PID O XYLENE+ STYRENE, UG/ L Standard Deviations vs Spike Concentrations ( Original Scale) Episode 6000 Data Page 11 of 32 Observed Standard Deviation Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 05: 18 2002 0 5 10 15 20 0.0 0.2 0.4 0.6 0.8 1.0 Organics, Method 502.2 PID P ISOPROPTOL+ 1,4 DCB, UG/ L 0 2 4 6 8 10 0.0 0.1 0.2 0.3 0.4 0.5 Organics, Method 502.2 PID SEC BUTYLBENZENE, UG/ L 0 2 4 6 8 10 0.0 0.1 0.2 0.3 0.4 0.5 Organics, Method 502.2 PID TERT BUTYLBENZENE, UG/ L 0 2 4 6 8 10 0.0 0.1 0.2 0.3 0.4 0.5 0.6 Organics, Method 502.2 PID TETRACHLOROETHENE, UG/ L 0 2 4 6 8 10 0.0 0.1 0.2 0.3 0.4 Organics, Method 502.2 PID TOLUENE, UG/ L 0 2 4 6 8 10 0.1 0.2 0.3 0.4 Organics, Method 502.2 PID TRANS 1,3 DICHLOROPROPENE, UG/ L 0 2 4 6 8 10 0.0 0.1 0.2 0.3 0.4 0.5 0.6 Organics, Method 502.2 PID TRICHLOROETHENE, UG/ L 0 50 100 150 200 0 2 4 6 8 Organics, Method 524.2 1,1,1,2 TETRACHLOROETHANE, UG/ L 0 50 100 150 200 0 2 4 6 8 10 Organics, Method 524.2 1,1,1 TRICHLOROETHANE, UG/ L 0 50 100 150 200 0 2 4 6 8 10 Organics, Method 524.2 1,1,2,2 TETRACHLOROETHANE, UG/ L 0 50 100 150 200 0 1 2 3 4 5 Organics, Method 524.2 1,1,2 TRICHLOROETHANE, UG/ L 0 50 100 150 200 0 2 4 6 8 Organics, Method 524.2 1,1 DICHLOROETHANE, UG/ L Standard Deviations vs Spike Concentrations ( Original Scale) Episode 6000 Data Page 12 of 32 Observed Standard Deviation Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 05: 42 2002 0 50 100 150 200 0 5 10 15 Organics, Method 524.2 1,1 DICHLOROETHENE, UG/ L 50 100 150 200 2 3 4 5 Organics, Method 524.2 1,1 DICHLOROPROPANONE, UG/ L 0 50 100 150 200 0 2 4 6 8 10 Organics, Method 524.2 1,1 DICHLOROPROPENE, UG/ L 0 50 100 150 200 0 2 4 6 8 10 12 14 Organics, Method 524.2 1,2,3 TRICHLOROBENZENE, UG/ L 0 50 100 150 200 0 1 2 3 4 5 6 Organics, Method 524.2 1,2,3 TRICHLOROPROPANE, UG/ L 0 50 100 150 200 0 2 4 6 8 10 12 Organics, Method 524.2 1,2,4 TRICHLOROBENZENE, UG/ L 0 50 100 150 200 0 1 2 3 4 5 6 Organics, Method 524.2 1,2,4 TRIMETHYLBENZENE, UG/ L 0 50 100 150 200 0 5 10 15 Organics, Method 524.2 1,2 DIBROMO 3 CHLOROPROPANE, UG/ L 0 50 100 150 200 0 1 2 3 4 5 6 Organics, Method 524.2 1,2 DIBROMOETHANE, UG/ L 0 50 100 150 200 0 2 4 6 8 10 12 Organics, Method 524.2 1,2 DICHLOROBENZENE, UG/ L 0 50 100 150 200 0 1 2 3 4 5 Organics, Method 524.2 1,2 DICHLOROETHANE, UG/ L 0 50 100 150 200 0 2 4 6 Organics, Method 524.2 1,2 DICHLOROPROPANE, UG/ L Standard Deviations vs Spike Concentrations ( Original Scale) Episode 6000 Data Page 13 of 32 Observed Standard Deviation Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 06: 06 2002 0 50 100 150 200 0 2 4 6 Organics, Method 524.2 1,3,5 TRIMETHYLBENZENE, UG/ L 0 50 100 150 200 0 2 4 6 8 10 Organics, Method 524.2 1,3 DICHLOROBENZENE, UG/ L 0 50 100 150 200 0 1 2 3 4 5 Organics, Method 524.2 1,3 DICHLOROPROPANE, UG/ L 0 50 100 150 200 0 2 4 6 8 10 Organics, Method 524.2 1,4 DICHLOROBENZENE, UG/ L 0 50 100 150 200 0 100 200 300 Organics, Method 524.2 1 CHLOROBUTANE, UG/ L 0 50 100 150 200 0 2 4 6 8 10 Organics, Method 524.2 2,2 DICHLOROPROPANE, UG/ L 0 50 100 150 200 0 2 4 6 8 Organics, Method 524.2 2 BUTANONE, UG/ L 0 50 100 150 200 0 2 4 6 8 Organics, Method 524.2 2 CHLOROTOLUENE, UG/ L 0 50 100 150 200 0 2 4 6 8 10 12 14 Organics, Method 524.2 2 HEXANONE, UG/ L 0 50 100 150 200 0 2 4 6 8 10 Organics, Method 524.2 2 NITROPROPANE, UG/ L 0 50 100 150 200 0 2 4 6 8 Organics, Method 524.2 4 CHLOROTOLUENE, UG/ L 0 50 100 150 200 0 1 2 3 4 5 6 Organics, Method 524.2 4 ISOPROPYLTOLUENE, UG/ L Standard Deviations vs Spike Concentrations ( Original Scale) Episode 6000 Data Page 14 of 32 Observed Standard Deviation Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 06: 27 2002 0 50 100 150 200 0 2 4 6 8 10 12 Organics, Method 524.2 4 METHYL 2 PENTANONE, UG/ L 0 50 100 150 200 0 2 4 6 8 10 12 Organics, Method 524.2 ACETONE, UG/ L 0 50 100 150 200 0 2 4 6 8 Organics, Method 524.2 ACRYLONITRILE, UG/ L 0 50 100 150 200 0 2 4 6 8 10 Organics, Method 524.2 ALLYL CHLORIDE, UG/ L 0 50 100 150 200 0 1 2 3 4 5 6 Organics, Method 524.2 BENZENE, UG/ L 0 50 100 150 200 0 2 4 6 8 10 Organics, Method 524.2 BROMOBENZENE, UG/ L 0 50 100 150 200 0 1 2 3 4 5 6 Organics, Method 524.2 BROMOCHLOROMETHANE, UG/ L 0 50 100 150 200 0 1 2 3 4 5 6 Organics, Method 524.2 BROMODICHLOROMETHANE, UG/ L 0 50 100 150 200 0 2 4 6 8 Organics, Method 524.2 BROMOFORM, UG/ L 0 50 100 150 200 0 2 4 6 8 10 Organics, Method 524.2 BROMOMETHANE, UG/ L 0 50 100 150 200 0 2 4 6 8 10 12 Organics, Method 524.2 CARBON DISULFIDE, UG/ L 0 50 100 150 200 0 2 4 6 8 10 12 Organics, Method 524.2 CARBON TETRACHLORIDE, UG/ L Standard Deviations vs Spike Concentrations ( Original Scale) Episode 6000 Data Page 15 of 32 Observed Standard Deviation Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 06: 40 2002 50 100 150 200 1 2 3 4 5 Organics, Method 524.2 CHLOROACETONITRILE, UG/ L 0 50 100 150 200 0 2 4 6 8 Organics, Method 524.2 CHLOROBENZENE, UG/ L 0 50 100 150 200 0 2 4 6 8 10 Organics, Method 524.2 CHLOROETHANE, UG/ L 0 50 100 150 200 0 2 4 6 Organics, Method 524.2 CHLOROFORM, UG/ L 0 50 100 150 200 0 5 10 15 Organics, Method 524.2 CHLOROMETHANE, UG/ L 0 50 100 150 200 0 2 4 6 8 Organics, Method 524.2 CIS 1,2 DICHLOROETHENE, UG/ L 0 50 100 150 200 0 1 2 3 4 5 Organics, Method 524.2 CIS 1,3 DICHLOROPROPENE, UG/ L 0 50 100 150 200 0 1 2 3 4 5 6 Organics, Method 524.2 DIBROMOCHLOROMETHANE, UG/ L 0 50 100 150 200 0 1 2 3 4 Organics, Method 524.2 DIBROMOMETHANE, UG/ L 0 50 100 150 200 0 5 10 15 Organics, Method 524.2 DICHLORODIFLUOROMETHANE, UG/ L 0 50 100 150 200 0 2 4 6 8 Organics, Method 524.2 DIETHYL ETHER, UG/ L 0 50 100 150 200 0 2 4 6 Organics, Method 524.2 ETHYL METHACRYLATE, UG/ L Standard Deviations vs Spike Concentrations ( Original Scale) Episode 6000 Data Page 16 of 32 Observed Standard Deviation Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 06: 53 2002 0 50 100 150 200 0 2 4 6 8 10 Organics, Method 524.2 ETHYLBENZENE, UG/ L 0 50 100 150 200 0 5 10 15 Organics, Method 524.2 HEXACHLOROBUTADIENE, UG/ L 0 50 100 150 200 0 5 10 15 Organics, Method 524.2 HEXACHLOROETHANE, UG/ L 0 50 100 150 200 0 2 4 6 Organics, Method 524.2 ISOPROPYLBENZENE, UG/ L 0 50 100 150 200 0 2 4 6 Organics, Method 524.2 M+ P XYLENE, UG/ L 0 50 100 150 200 0 1 2 3 4 5 Organics, Method 524.2 METHACRYLONITRILE, UG/ L 0 50 100 150 200 0 2 4 6 8 10 Organics, Method 524.2 METHYL IODIDE, UG/ L 0 50 100 150 200 0 2 4 6 8 Organics, Method 524.2 METHYL TERT BUTYL ETHER, UG/ L 0 50 100 150 200 0 2 4 6 8 Organics, Method 524.2 METHYLACRYLATE, UG/ L 0 50 100 150 200 0 2 4 6 Organics, Method 524.2 METHYLENE CHLORIDE, UG/ L 0 50 100 150 200 0 1 2 3 4 5 6 Organics, Method 524.2 METHYLMETHACRYLATE, UG/ L 0 50 100 150 200 0 2 4 6 Organics, Method 524.2 N BUTYLBENZENE, UG/ L Standard Deviations vs Spike Concentrations ( Original Scale) Episode 6000 Data Page 17 of 32 Observed Standard Deviation Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 07: 07 2002 0 50 100 150 200 0 2 4 6 8 10 Organics, Method 524.2 N PROPYLBENZENE, UG/ L 0 50 100 150 200 0 2 4 6 8 10 12 Organics, Method 524.2 NAPHTHALENE, UG/ L 0 50 100 150 200 0 2 4 6 8 10 Organics, Method 524.2 O XYLENE, UG/ L 0 50 100 150 200 0 2 4 6 8 10 Organics, Method 524.2 PENTACHLOROETHANE, UG/ L 0 50 100 150 200 0 2 4 6 Organics, Method 524.2 SEC BUTYLBENZENE, UG/ L 0 50 100 150 200 0 2 4 6 8 Organics, Method 524.2 STYRENE, UG/ L 0 50 100 150 200 0 2 4 6 8 Organics, Method 524.2 TERT BUTYLBENZENE, UG/ L 0 50 100 150 200 0 2 4 6 8 10 12 Organics, Method 524.2 TETRACHLOROETHENE, UG/ L 0 50 100 150 200 0 2 4 6 Organics, Method 524.2 TOLUENE, UG/ L 0 50 100 150 200 0 2 4 6 8 10 Organics, Method 524.2 TRANS 1,2 DICHLOROETHENE, UG/ L 0 50 100 150 200 0 1 2 3 4 5 Organics, Method 524.2 TRANS 1,3 DICHLOROPROPENE, UG/ L 0 50 100 150 200 0 2 4 6 Organics, Method 524.2 TRANS 1,4 DICHLORO 2 BUTENE, UG/ L Standard Deviations vs Spike Concentrations ( Original Scale) Episode 6000 Data Page 18 of 32 Observed Standard Deviation Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 07: 20 2002 0 50 100 150 200 0 2 4 6 8 10 Organics, Method 524.2 TRICHLOROETHENE, UG/ L 0 50 100 150 200 0 5 10 15 Organics, Method 524.2 TRICHLOROFLUOROMETHANE, UG/ L 0 50 100 150 200 0.0 4.9998 9.9995 14.9993 19.9990 Organics, Method 524.2 VINYL CHLORIDE, UG/ L 0 50 100 150 200 0 2 4 6 Organics, Method 524.2 XYLENE ( TOTAL), UG/ L 0 20 40 60 80 100 0 1 2 3 Organics, Method 1625: T= 0 1,2,3 TRICHLOROBENZENE, NG/ UL 0 20 40 60 80 100 0.0 0.5 1.0 1.5 2.0 Organics, Method 1625: T= 0 1,2,4 TRICHLOROBENZENE, NG/ UL 0 20 40 60 80 100 0.0 0.2 0.4 0.6 0.8 1.0 Organics, Method 1625: T= 0 1,2 DICHLOROBENZENE, NG/ UL 0 20 40 60 80 100 0 2 4 6 8 10 12 14 Organics, Method 1625: T= 0 1,2 DIPHENYLHYDRAZINE, NG/ UL 0 20 40 60 80 100 0.0 0.5 1.0 1.5 2.0 Organics, Method 1625: T= 0 1,3 DICHLOROBENZENE, NG/ UL 0 20 40 60 80 100 0.0 0.5 1.0 1.5 2.0 2.5 Organics, Method 1625: T= 0 1,4 DICHLOROBENZENE, NG/ UL 0 20 40 60 80 100 0 1 2 3 4 5 Organics, Method 1625: T= 0 2,3,6 TRICHLOROPHENOL, NG/ UL 0 20 40 60 80 100 0 2 4 6 Organics, Method 1625: T= 0 2,4,5 TRICHLOROPHENOL, NG/ UL Standard Deviations vs Spike Concentrations ( Original Scale) Episode 6000 Data Page 19 of 32 Observed Standard Deviation Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 07: 34 2002 0 20 40 60 80 100 0 2 4 6 8 Organics, Method 1625: T= 0 2,4,6 TRICHLOROPHENOL, NG/ UL 0 20 40 60 80 100 0 1 2 3 4 5 6 Organics, Method 1625: T= 0 2,4 DICHLOROPHENOL, NG/ UL 0 20 40 60 80 100 0.0 0.2 0.4 0.6 0.8 1.0 1.2 1.4 Organics, Method 1625: T= 0 2,4 DIMETHYLPHENOL, NG/ UL 0 20 40 60 80 100 0.0 0.5 1.0 1.5 Organics, Method 1625: T= 0 2,4 DINITROPHENOL, NG/ UL 0 20 40 60 80 100 0 2 4 6 8 10 12 14 Organics, Method 1625: T= 0 2,4 DINITROTOLUENE, NG/ UL 0 20 40 60 80 100 0 1 2 3 4 Organics, Method 1625: T= 0 2,6 DINITROTOLUENE, NG/ UL 0 20 40 60 80 100 0.0 0.5 1.0 1.5 2.0 2.5 Organics, Method 1625: T= 0 2 CHLORONAPHTHALENE, NG/ UL 0 20 40 60 80 100 0.0 0.1 0.2 0.3 0.4 0.5 Organics, Method 1625: T= 0 2 CHLOROPHENOL, NG/ UL 0 20 40 60 80 100 0.0 0.5 1.0 1.5 2.0 Organics, Method 1625: T= 0 2 NITROPHENOL, NG/ UL 0 20 40 60 80 100 0.0 0.5 1.0 1.5 2.0 Organics, Method 1625: T= 0 2 PICOLINE, NG/ UL 0 20 40 60 80 100 0 1 2 3 4 Organics, Method 1625: T= 0 3,3' DICHLOROBENZIDINE, NG/ UL 0 20 40 60 80 100 0 1 2 3 4 Organics, Method 1625: T= 0 4 BROMOPHENYL PHENYL ETHER, NG/ UL Standard Deviations vs Spike Concentrations ( Original Scale) Episode 6000 Data Page 20 of 32 Observed Standard Deviation Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 07: 51 2002 0 20 40 60 80 100 0.0 0.5 1.0 1.5 2.0 2.5 Organics, Method 1625: T= 0 4 CHLORO 3 METHYLPHENOL, NG/ UL 0 20 40 60 80 100 0.0 0.5 1.0 1.5 2.0 Organics, Method 1625: T= 0 4 CHLOROPHENYLPHENYL ETHER, NG/ UL 0 20 40 60 80 100 0 5 10 15 Organics, Method 1625: T= 0 4 NITROPHENOL, NG/ UL 0 20 40 60 80 100 0 2 4 6 Organics, Method 1625: T= 0 ACENAPHTHENE, NG/ UL 0 20 40 60 80 100 0 1 2 3 4 5 6 Organics, Method 1625: T= 0 ACENAPHTHYLENE, NG/ UL 0 20 40 60 80 100 0 1 2 3 Organics, Method 1625: T= 0 ALPHA TERPINEOL, NG/ UL 0 20 40 60 80 100 0 1 2 3 4 5 6 Organics, Method 1625: T= 0 ANTHRACENE, NG/ UL 0 20 40 60 80 100 0 5 10 15 Organics, Method 1625: T= 0 BENZIDINE, NG/ UL 0 20 40 60 80 100 0 1 2 3 Organics, Method 1625: T= 0 BENZO( A) ANTHRACENE, NG/ UL 0 20 40 60 80 100 0.0 0.5 1.0 1.5 2.0 2.5 Organics, Method 1625: T= 0 BENZO( A) PYRENE, NG/ UL 0 20 40 60 80 100 0 1 2 3 4 5 Organics, Method 1625: T= 0 BENZO( B) FLUORANTHENE, NG/ UL 0 20 40 60 80 100 0.0 0.5 1.0 1.5 2.0 2.5 3.0 Organics, Method 1625: T= 0 BENZO( GHI) PERYLENE, NG/ UL Standard Deviations vs Spike Concentrations ( Original Scale) Episode 6000 Data Page 21 of 32 Observed Standard Deviation Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 08: 07 2002 0 20 40 60 80 100 0 2 4 6 8 Organics, Method 1625: T= 0 BENZO( K) FLUORANTHENE, NG/ UL 0 20 40 60 80 100 0 2 4 6 8 10 Organics, Method 1625: T= 0 BETA NAPHTHYLAMINE, NG/ UL 0 20 40 60 80 100 0 1 2 3 4 5 Organics, Method 1625: T= 0 BIPHENYL, NG/ UL 0 20 40 60 80 100 0 1 2 3 4 5 Organics, Method 1625: T= 0 BIS( 2 CHLOROETHOXY) METHANE, NG/ UL 0 20 40 60 80 100 0 1 2 3 Organics, Method 1625: T= 0 BIS( 2 CHLOROETHYL) ETHER, NG/ UL 0 20 40 60 80 100 0 1 2 3 4 5 Organics, Method 1625: T= 0 BIS( 2 CHLOROISOPROPYL) ETHER, NG/ UL 0 20 40 60 80 100 0.0 0.5 1.0 1.5 2.0 2.5 3.0 Organics, Method 1625: T= 0 BIS( 2 ETHYLHEXYL) PHTHALATE, NG/ UL 0 20 40 60 80 100 0.0 0.5 1.0 1.5 2.0 2.5 3.0 Organics, Method 1625: T= 0 BUTYL BENZYL PHTHALATE, NG/ UL 0 20 40 60 80 100 0 1 2 3 4 Organics, Method 1625: T= 0 CARBAZOLE, NG/ UL 0 20 40 60 80 100 0 1 2 3 4 Organics, Method 1625: T= 0 CHRYSENE, NG/ UL 0 20 40 60 80 100 0.0 0.5 1.0 1.5 2.0 Organics, Method 1625: T= 0 DI N BUTYL PHTHALATE, NG/ UL 0 20 40 60 80 100 0.0 0.5 1.0 1.5 2.0 2.5 Organics, Method 1625: T= 0 DI N OCTYL PHTHALATE, NG/ UL Standard Deviations vs Spike Concentrations ( Original Scale) Episode 6000 Data Page 22 of 32 Observed Standard Deviation Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 08: 29 2002 0 20 40 60 80 100 0 2 4 6 8 10 12 Organics, Method 1625: T= 0 DI N PROPYLNITROSAMINE, NG/ UL 0 20 40 60 80 100 0.0 0.5 1.0 1.5 2.0 2.5 3.0 Organics, Method 1625: T= 0 DIBENZO( A, H) ANTHRACENE, NG/ UL 0 20 40 60 80 100 0 2 4 6 Organics, Method 1625: T= 0 DIBENZOFURAN, NG/ UL 0 20 40 60 80 100 0 1 2 3 4 5 Organics, Method 1625: T= 0 DIBENZOTHIOPHENE, NG/ UL 0 20 40 60 80 100 0.0 0.5 1.0 1.5 2.0 2.5 Organics, Method 1625: T= 0 DIETHYL PHTHALATE, NG/ UL 0 20 40 60 80 100 0.0 0.5 1.0 1.5 2.0 2.5 3.0 Organics, Method 1625: T= 0 DIMETHYL PHTHALATE, NG/ UL 0 20 40 60 80 100 0 1 2 3 4 Organics, Method 1625: T= 0 DIPHENYL ETHER, NG/ UL 0 20 40 60 80 100 0 2 4 6 Organics, Method 1625: T= 0 DIPHENYLAMINE, NG/ UL 0 20 40 60 80 100 0 1 2 3 4 5 Organics, Method 1625: T= 0 FLUORANTHENE, NG/ UL 0 20 40 60 80 100 0 2 4 6 8 Organics, Method 1625: T= 0 FLUORENE, NG/ UL 0 20 40 60 80 100 0 1 2 3 4 Organics, Method 1625: T= 0 HEXACHLOROBENZENE, NG/ UL 0 20 40 60 80 100 0.0 0.1 0.2 0.3 0.4 Organics, Method 1625: T= 0 HEXACHLOROBUTADIENE, NG/ UL Standard Deviations vs Spike Concentrations ( Original Scale) Episode 6000 Data Page 23 of 32 Observed Standard Deviation Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 08: 46 2002 0 20 40 60 80 100 0 1 2 3 4 5 Organics, Method 1625: T= 0 HEXACHLOROCYCLOPENTADIENE, NG/ UL 0 20 40 60 80 100 0.0 0.5 1.0 1.5 2.0 Organics, Method 1625: T= 0 HEXACHLOROETHANE, NG/ UL 0 20 40 60 80 100 0 5 10 15 20 25 Organics, Method 1625: T= 0 INDENO( 1,2,3 CD) PYRENE, NG/ UL 0 20 40 60 80 100 0.0 0.5 1.0 1.5 2.0 2.5 Organics, Method 1625: T= 0 ISOPHORONE, NG/ UL 0 20 40 60 80 100 0 5 10 15 20 25 Organics, Method 1625: T= 0 N DECANE, NG/ UL 0 20 40 60 80 100 0 5 10 15 Organics, Method 1625: T= 0 N DOCOSANE, NG/ UL 0 20 40 60 80 100 0 1 2 3 4 5 6 Organics, Method 1625: T= 0 N DODECANE, NG/ UL 0 20 40 60 80 100 0 2 4 6 8 Organics, Method 1625: T= 0 N EICOSANE, NG/ UL 0 20 40 60 80 100 0 5 10 15 20 Organics, Method 1625: T= 0 N HEXACOSANE, NG/ UL 0 20 40 60 80 100 0 2 4 6 8 10 12 Organics, Method 1625: T= 0 N HEXADECANE, NG/ UL 0 20 40 60 80 100 0 2 4 6 8 10 12 Organics, Method 1625: T= 0 N NITROSODIMETHYLAMINE, NG/ UL 0 20 40 60 80 100 0.0 0.5 1.0 1.5 Organics, Method 1625: T= 0 N NITROSODIPHENYLAMINE, NG/ UL Standard Deviations vs Spike Concentrations ( Original Scale) Episode 6000 Data Page 24 of 32 Observed Standard Deviation Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 09: 01 2002 0 20 40 60 80 100 0 5 10 15 20 Organics, Method 1625: T= 0 N OCTACOSANE, NG/ UL 0 20 40 60 80 100 0 2 4 6 8 10 12 14 Organics, Method 1625: T= 0 N OCTADECANE, NG/ UL 0 20 40 60 80 100 0.0 0.5 1.0 1.5 2.0 2.5 3.0 Organics, Method 1625: T= 0 N TETRACOSANE, NG/ UL 0 20 40 60 80 100 0 2 4 6 8 10 12 14 Organics, Method 1625: T= 0 N TETRADECANE, NG/ UL 0 20 40 60 80 100 0 2 4 6 8 Organics, Method 1625: T= 0 N TRIACONTANE, NG/ UL 0 20 40 60 80 100 0.0 0.5 1.0 1.5 Organics, Method 1625: T= 0 NAPHTHALENE, NG/ UL 0 20 40 60 80 100 0 1 2 3 Organics, Method 1625: T= 0 NITROBENZENE, NG/ UL 0 20 40 60 80 100 0 2 4 6 Organics, Method 1625: T= 0 P CYMENE, NG/ UL 0 20 40 60 80 100 0.0 0.2 0.4 0.6 0.8 Organics, Method 1625: T= 0 PENTACHLOROPHENOL, NG/ UL 0 20 40 60 80 100 0 1 2 3 Organics, Method 1625: T= 0 PHENANTHRENE, NG/ UL 0 20 40 60 80 100 0 2 4 6 8 10 Organics, Method 1625: T= 0 PHENOL, NG/ UL 0 20 40 60 80 100 0.0 0.5 1.0 1.5 2.0 Organics, Method 1625: T= 0 PHENOL, 2 METHYL 4,6 DINITRO, NG/ UL Standard Deviations vs Spike Concentrations ( Original Scale) Episode 6000 Data Page 25 of 32 Observed Standard Deviation Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 09: 20 2002 0 20 40 60 80 100 0 1 2 3 4 5 Organics, Method 1625: T= 0 PYRENE, NG/ UL 0 20 40 60 80 100 0 1 2 3 4 Organics, Method 1625: T= 0 STYRENE, NG/ UL 0 20 40 60 80 100 0.0 0.5 1.0 1.5 2.0 2.5 3.0 Organics, Method 1625: T= 1000 1,2,3 TRICHLOROBENZENE, NG/ UL 0 20 40 60 80 100 0.0 0.5 1.0 1.5 2.0 Organics, Method 1625: T= 1000 1,2,4 TRICHLOROBENZENE, NG/ UL 0 20 40 60 80 100 0 1 2 3 Organics, Method 1625: T= 1000 1,2 DICHLOROBENZENE, NG/ UL 0 20 40 60 80 100 0 2 4 6 8 10 Organics, Method 1625: T= 1000 1,2 DIPHENYLHYDRAZINE, NG/ UL 0 20 40 60 80 100 0.0 0.5 1.0 1.5 2.0 Organics, Method 1625: T= 1000 1,3 DICHLOROBENZENE, NG/ UL 0 20 40 60 80 100 0.0 0.5 1.0 1.5 2.0 2.5 3.0 Organics, Method 1625: T= 1000 1,4 DICHLOROBENZENE, NG/ UL 0 20 40 60 80 100 0 1 2 3 4 5 6 Organics, Method 1625: T= 1000 2,3,6 TRICHLOROPHENOL, NG/ UL 0 20 40 60 80 100 0 1 2 3 4 5 6 Organics, Method 1625: T= 1000 2,4,5 TRICHLOROPHENOL, NG/ UL 0 20 40 60 80 100 0 2 4 6 Organics, Method 1625: T= 1000 2,4,6 TRICHLOROPHENOL, NG/ UL 0 20 40 60 80 100 0 1 2 3 Organics, Method 1625: T= 1000 2,4 DICHLOROPHENOL, NG/ UL Standard Deviations vs Spike Concentrations ( Original Scale) Episode 6000 Data Page 26 of 32 Observed Standard Deviation Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 09: 39 2002 0 20 40 60 80 100 0.0 0.5 1.0 1.5 Organics, Method 1625: T= 1000 2,4 DIMETHYLPHENOL, NG/ UL 0 20 40 60 80 100 0.2 0.4 0.6 0.8 1.0 1.2 Organics, Method 1625: T= 1000 2,4 DINITROPHENOL, NG/ UL 0 20 40 60 80 100 0 1 2 3 4 5 6 Organics, Method 1625: T= 1000 2,4 DINITROTOLUENE, NG/ UL 0 20 40 60 80 100 0 1 2 3 Organics, Method 1625: T= 1000 2,6 DINITROTOLUENE, NG/ UL 0 20 40 60 80 100 0 1 2 3 4 Organics, Method 1625: T= 1000 2 CHLORONAPHTHALENE, NG/ UL 0 20 40 60 80 100 0.0 0.2 0.4 0.6 0.8 1.0 Organics, Method 1625: T= 1000 2 CHLOROPHENOL, NG/ UL 0 20 40 60 80 100 0.0 0.5 1.0 1.5 2.0 Organics, Method 1625: T= 1000 2 NITROPHENOL, NG/ UL 0 20 40 60 80 100 0 1 2 3 4 Organics, Method 1625: T= 1000 2 PICOLINE, NG/ UL 0 20 40 60 80 100 0.0 0.5 1.0 1.5 2.0 2.5 Organics, Method 1625: T= 1000 3,3' DICHLOROBENZIDINE, NG/ UL 0 20 40 60 80 100 0.0 0.5 1.0 1.5 Organics, Method 1625: T= 1000 4 BROMOPHENYL PHENYL ETHER, NG/ UL 0 20 40 60 80 100 0.0 0.5 1.0 1.5 2.0 Organics, Method 1625: T= 1000 4 CHLORO 3 METHYLPHENOL, NG/ UL 0 20 40 60 80 100 0.0 0.2 0.4 0.6 0.8 1.0 1.2 1.4 Organics, Method 1625: T= 1000 4 CHLOROPHENYLPHENYL ETHER, NG/ UL Standard Deviations vs Spike Concentrations ( Original Scale) Episode 6000 Data Page 27 of 32 Observed Standard Deviation Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 09: 54 2002 0 20 40 60 80 100 0 2 4 6 8 Organics, Method 1625: T= 1000 4 NITROPHENOL, NG/ UL 0 20 40 60 80 100 0 1 2 3 4 5 Organics, Method 1625: T= 1000 ACENAPHTHENE, NG/ UL 0 20 40 60 80 100 0 2 4 6 8 10 Organics, Method 1625: T= 1000 ACENAPHTHYLENE, NG/ UL 0 20 40 60 80 100 0.0 0.5 1.0 1.5 Organics, Method 1625: T= 1000 ALPHA TERPINEOL, NG/ UL 0 20 40 60 80 100 0 1 2 3 4 5 Organics, Method 1625: T= 1000 ANTHRACENE, NG/ UL 0 20 40 60 80 100 0 1 2 3 4 5 6 Organics, Method 1625: T= 1000 BENZIDINE, NG/ UL 0 20 40 60 80 100 0 1 2 3 4 5 Organics, Method 1625: T= 1000 BENZO( A) ANTHRACENE, NG/ UL 0 20 40 60 80 100 0.0 0.5 1.0 1.5 2.0 Organics, Method 1625: T= 1000 BENZO( A) PYRENE, NG/ UL 0 20 40 60 80 100 0 1 2 3 4 Organics, Method 1625: T= 1000 BENZO( B) FLUORANTHENE, NG/ UL 0 20 40 60 80 100 0 1 2 3 Organics, Method 1625: T= 1000 BENZO( GHI) PERYLENE, NG/ UL 0 20 40 60 80 100 0 2 4 6 Organics, Method 1625: T= 1000 BENZO( K) FLUORANTHENE, NG/ UL 0 20 40 60 80 100 0 5 10 15 Organics, Method 1625: T= 1000 BETA NAPHTHYLAMINE, NG/ UL Standard Deviations vs Spike Concentrations ( Original Scale) Episode 6000 Data Page 28 of 32 Observed Standard Deviation Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 10: 07 2002 0 20 40 60 80 100 0 1 2 3 4 5 6 Organics, Method 1625: T= 1000 BIPHENYL, NG/ UL 0 20 40 60 80 100 0.0 0.5 1.0 1.5 2.0 2.5 Organics, Method 1625: T= 1000 BIS( 2 CHLOROETHOXY) METHANE, NG/ UL 0 20 40 60 80 100 0 2 4 6 Organics, Method 1625: T= 1000 BIS( 2 CHLOROETHYL) ETHER, NG/ UL 0 20 40 60 80 100 0 2 4 6 8 10 12 Organics, Method 1625: T= 1000 BIS( 2 CHLOROISOPROPYL) ETHER, NG/ UL 0 20 40 60 80 100 0.0 0.2 0.4 0.6 0.8 1.0 1.2 Organics, Method 1625: T= 1000 BIS( 2 ETHYLHEXYL) PHTHALATE, NG/ UL 0 20 40 60 80 100 0 1 2 3 Organics, Method 1625: T= 1000 BUTYL BENZYL PHTHALATE, NG/ UL 0 20 40 60 80 100 0 1 2 3 4 Organics, Method 1625: T= 1000 CARBAZOLE, NG/ UL 0 20 40 60 80 100 0.0 0.5 1.0 1.5 2.0 Organics, Method 1625: T= 1000 CHRYSENE, NG/ UL 0 20 40 60 80 100 0 1 2 3 4 5 6 Organics, Method 1625: T= 1000 DI N BUTYL PHTHALATE, NG/ UL 0 20 40 60 80 100 0 1 2 3 4 5 Organics, Method 1625: T= 1000 DI N OCTYL PHTHALATE, NG/ UL 0 20 40 60 80 100 0 2 4 6 8 10 Organics, Method 1625: T= 1000 DI N PROPYLNITROSAMINE, NG/ UL 0 20 40 60 80 100 0.0 0.5 1.0 1.5 2.0 2.5 3.0 Organics, Method 1625: T= 1000 DIBENZO( A, H) ANTHRACENE, NG/ UL Standard Deviations vs Spike Concentrations ( Original Scale) Episode 6000 Data Page 29 of 32 Observed Standard Deviation Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 10: 21 2002 0 20 40 60 80 100 0.0 0.5 1.0 1.5 2.0 2.5 Organics, Method 1625: T= 1000 DIBENZOFURAN, NG/ UL 0 20 40 60 80 100 0.0 0.5 1.0 1.5 2.0 2.5 Organics, Method 1625: T= 1000 DIBENZOTHIOPHENE, NG/ UL 0 20 40 60 80 100 0.0 0.5 1.0 1.5 2.0 2.5 3.0 Organics, Method 1625: T= 1000 DIETHYL PHTHALATE, NG/ UL 0 20 40 60 80 100 0.0 0.5 1.0 1.5 2.0 Organics, Method 1625: T= 1000 DIMETHYL PHTHALATE, NG/ UL 0 20 40 60 80 100 0.0 0.5 1.0 1.5 2.0 Organics, Method 1625: T= 1000 DIPHENYL ETHER, NG/ UL 0 20 40 60 80 100 0 2 4 6 8 Organics, Method 1625: T= 1000 DIPHENYLAMINE, NG/ UL 0 20 40 60 80 100 0.0 0.5 1.0 1.5 2.0 2.5 3.0 Organics, Method 1625: T= 1000 FLUORANTHENE, NG/ UL 0 20 40 60 80 100 0 2 4 6 8 Organics, Method 1625: T= 1000 FLUORENE, NG/ UL 0 20 40 60 80 100 0 1 2 3 4 Organics, Method 1625: T= 1000 HEXACHLOROBENZENE, NG/ UL 0 20 40 60 80 100 0.0 0.5 1.0 1.5 2.0 Organics, Method 1625: T= 1000 HEXACHLOROBUTADIENE, NG/ UL 0 20 40 60 80 100 0 2 4 6 8 10 Organics, Method 1625: T= 1000 HEXACHLOROCYCLOPENTADIENE, NG/ UL 0 20 40 60 80 100 0.0 0.5 1.0 1.5 Organics, Method 1625: T= 1000 HEXACHLOROETHANE, NG/ UL Standard Deviations vs Spike Concentrations ( Original Scale) Episode 6000 Data Page 30 of 32 Observed Standard Deviation Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 10: 35 2002 0 20 40 60 80 100 0 5 10 15 20 Organics, Method 1625: T= 1000 INDENO( 1,2,3 CD) PYRENE, NG/ UL 0 20 40 60 80 100 0.0 0.2 0.4 0.6 0.8 1.0 Organics, Method 1625: T= 1000 ISOPHORONE, NG/ UL 0 20 40 60 80 100 0 2 4 6 8 10 12 Organics, Method 1625: T= 1000 N DECANE, NG/ UL 0 20 40 60 80 100 0 2 4 6 8 10 12 Organics, Method 1625: T= 1000 N DOCOSANE, NG/ UL 0 20 40 60 80 100 0.0 0.5 1.0 1.5 2.0 2.5 3.0 Organics, Method 1625: T= 1000 N DODECANE, NG/ UL 0 20 40 60 80 100 0 1 2 3 4 Organics, Method 1625: T= 1000 N EICOSANE, NG/ UL 0 20 40 60 80 100 0 5 10 15 Organics, Method 1625: T= 1000 N HEXACOSANE, NG/ UL 0 20 40 60 80 100 0 1 2 3 4 5 Organics, Method 1625: T= 1000 N HEXADECANE, NG/ UL 0 20 40 60 80 100 0 2 4 6 8 Organics, Method 1625: T= 1000 N NITROSODIMETHYLAMINE, NG/ UL 0 20 40 60 80 100 0 1 2 3 4 Organics, Method 1625: T= 1000 N NITROSODIPHENYLAMINE, NG/ UL 0 20 40 60 80 100 0 5 10 15 Organics, Method 1625: T= 1000 N OCTACOSANE, NG/ UL 0 20 40 60 80 100 0 2 4 6 8 Organics, Method 1625: T= 1000 N OCTADECANE, NG/ UL Standard Deviations vs Spike Concentrations ( Original Scale) Episode 6000 Data Page 31 of 32 Observed Standard Deviation Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 10: 49 2002 0 20 40 60 80 100 0.0 0.5 1.0 1.5 2.0 2.5 3.0 Organics, Method 1625: T= 1000 N TETRACOSANE, NG/ UL 0 20 40 60 80 100 0 1 2 3 4 Organics, Method 1625: T= 1000 N TETRADECANE, NG/ UL 0 20 40 60 80 100 0 2 4 6 Organics, Method 1625: T= 1000 N TRIACONTANE, NG/ UL 0 20 40 60 80 100 0 1 2 3 4 Organics, Method 1625: T= 1000 NAPHTHALENE, NG/ UL 0 20 40 60 80 100 0.0 0.5 1.0 1.5 Organics, Method 1625: T= 1000 NITROBENZENE, NG/ UL 0 20 40 60 80 100 0 1 2 3 4 5 Organics, Method 1625: T= 1000 P CYMENE, NG/ UL 0 20 40 60 80 100 0.0 0.2 0.4 0.6 0.8 1.0 1.2 1.4 Organics, Method 1625: T= 1000 PENTACHLOROPHENOL, NG/ UL 0 20 40 60 80 100 0.0 0.5 1.0 1.5 2.0 2.5 3.0 Organics, Method 1625: T= 1000 PHENANTHRENE, NG/ UL 0 20 40 60 80 100 0 1 2 3 Organics, Method 1625: T= 1000 PHENOL, NG/ UL 0 20 40 60 80 100 0.0 0.5 1.0 1.5 2.0 2.5 Organics, Method 1625: T= 1000 PHENOL, 2 METHYL 4,6 DINITRO, NG/ UL 0 20 40 60 80 100 0 1 2 3 Organics, Method 1625: T= 1000 PYRENE, NG/ UL 0 20 40 60 80 100 0.0 0.5 1.0 1.5 2.0 2.5 Organics, Method 1625: T= 1000 STYRENE, NG/ UL Standard Deviations vs Spike Concentrations ( Original Scale) Episode 6000 Data Page 32 of 32 Observed Standard Deviation Spike Concentration c:/ pw/ ostmdl/ req004/ r004sd1. s Mon Mar 18 16: 11: 03 2002 0 100 200 300 400 500 10 12 14 16 18 20 Lab: 1 ALUMINUM, UG/ L Standard Deviations vs Spike Concentrations ( Original Scale)

( Matrix A, Method EPA 200.7 ICP/ AES)

AAMA Metals Data Page 1 of 13 APPENDIX B  3  2 Observed Standard Deviation Spike Concentration 0 100 200 300 400 500 50 60 70 80 90 100 Lab: 2 ALUMINUM, UG/ L 0 100 200 300 400 500 8 9 10 11 Lab: 3 ALUMINUM, UG/ L 0 100 200 300 400 500 260 270 280 290 300 Lab: 4 ALUMINUM, UG/ L 0 100 200 300 400 500 12 14 16 18 20 22 24 Lab: 5 ALUMINUM, UG/ L 0 100 200 300 400 500 15 20 25 30 35 Lab: 6 ALUMINUM, UG/ L 0 100 200 300 400 500 45 50 55 60 Lab: 7 ALUMINUM, UG/ L 0 100 200 300 400 500 20 30 40 50 60 70 Lab: 8 ALUMINUM, UG/ L 0 100 200 300 400 500 120 130 140 150 160 170 Lab: 9 ALUMINUM, UG/ L 0 100 200 300 400 500 600 8 10 12 14 16 Lab: 1 ARSENIC, UG/ L Standard Deviations vs Spike Concentrations ( Original Scale)

( Matrix A, Method EPA 200.7 ICP/ AES)

AAMA Metals Data Page 2 of 13 Observed Standard Deviation Spike Concentration c:/ pw/ ostmdl/ req005/ r005sd1. s Wed Mar 20 13: 32: 21 2002 0 100 200 300 400 500 600 30 40 50 60 70 Lab: 2 ARSENIC, UG/ L 0 100 200 300 400 500 600 3 4 5 6 7 8 9 Lab: 3 ARSENIC, UG/ L 0 100 200 300 400 500 600 15 20 25 30 35 40 45 Lab: 4 ARSENIC, UG/ L 0 100 200 300 400 500 600 2 4 6 8 Lab: 5 ARSENIC, UG/ L 0 100 200 300 400 500 600 6 7 8 9 10 11 Lab: 6 ARSENIC, UG/ L 0 100 200 300 400 500 600 15 20 25 30 35 40 45 Lab: 7 ARSENIC, UG/ L 0 100 200 300 400 500 600 0 5 10 15 20 Lab: 8 ARSENIC, UG/ L 0 100 200 300 400 500 600 15 20 25 30 Lab: 9 ARSENIC, UG/ L 0 20 40 60 80 100 1 2 3 4 Lab: 1 CADMIUM, UG/ L Standard Deviations vs Spike Concentrations ( Original Scale)

( Matrix A, Method EPA 200.7 ICP/ AES)

AAMA Metals Data Page 3 of 13 Observed Standard Deviation Spike Concentration c:/ pw/ ostmdl/ req005/ r005sd1. s Wed Mar 20 13: 32: 23 2002 0 20 40 60 80 100 3 4 5 6 Lab: 2 CADMIUM, UG/ L 0 20 40 60 80 100 0.5 1.0 1.5 2.0 Lab: 3 CADMIUM, UG/ L 0 20 40 60 80 100 6 8 10 12 Lab: 4 CADMIUM, UG/ L 0 20 40 60 80 100 0.5 1.0 1.5 2.0 Lab: 5 CADMIUM, UG/ L 0 20 40 60 80 100 1 2 3 4 Lab: 6 CADMIUM, UG/ L 0 20 40 60 80 100 1.0 1.5 2.0 2.5 3.0 3.5 Lab: 7 CADMIUM, UG/ L 0 20 40 60 80 100 1 2 3 4 5 Lab: 8 CADMIUM, UG/ L 0 20 40 60 80 100 1 2 3 4 5 Lab: 9 CADMIUM, UG/ L 0 50 100 150 200 250 6.0 6.5 7.0 7.5 8.0 8.5 9.0 Lab: 1 CHROMIUM, UG/ L Standard Deviations vs Spike Concentrations ( Original Scale)

( Matrix A, Method EPA 200.7 ICP/ AES)

AAMA Metals Data Page 4 of 13 Observed Standard Deviation Spike Concentration c:/ pw/ ostmdl/ req005/ r005sd1. s Wed Mar 20 13: 32: 24 2002 0 50 100 150 200 250 2 4 6 8 10 12 Lab: 2 CHROMIUM, UG/ L 0 50 100 150 200 250 1 2 3 4 5 Lab: 3 CHROMIUM, UG/ L 0 50 100 150 200 250 6 8 10 12 14 16 18 Lab: 4 CHROMIUM, UG/ L 0 50 100 150 200 250 2 4 6 Lab: 5 CHROMIUM, UG/ L 0 50 100 150 200 250 1 2 3 4 5 Lab: 6 CHROMIUM, UG/ L 0 50 100 150 200 250 2 4 6 8 10 Lab: 7 CHROMIUM, UG/ L 0 50 100 150 200 250 2 4 6 8 10 12 Lab: 8 CHROMIUM, UG/ L 0 50 100 150 200 250 4 6 8 10 12 Lab: 9 CHROMIUM, UG/ L 0 50 100 150 200 2 3 4 5 6 Lab: 1 COPPER, UG/ L Standard Deviations vs Spike Concentrations ( Original Scale)

( Matrix A, Method EPA 200.7 ICP/ AES)

AAMA Metals Data Page 5 of 13 Observed Standard Deviation Spike Concentration c:/ pw/ ostmdl/ req005/ r005sd1. s Wed Mar 20 13: 32: 26 2002 0 50 100 150 200 2 4 6 8 10 Lab: 2 COPPER, UG/ L 0 50 100 150 200 1 2 3 4 Lab: 3 COPPER, UG/ L 0 50 100 150 200 40 41 42 43 44 45 Lab: 4 COPPER, UG/ L 0 50 100 150 200 1 2 3 4 5 6 7 Lab: 5 COPPER, UG/ L 0 50 100 150 200 1 2 3 4 5 Lab: 6 COPPER, UG/ L 0 50 100 150 200 4 6 8 Lab: 7 COPPER, UG/ L 0 50 100 150 200 2 4 6 8 10 Lab: 8 COPPER, UG/ L 0 50 100 150 200 0 10 20 30 40 50 60 Lab: 9 COPPER, UG/ L 0 100 200 300 400 500 6 8 10 12 14 16 18 20 Lab: 1 LEAD, UG/ L Standard Deviations vs Spike Concentrations ( Original Scale)

( Matrix A, Method EPA 200.7 ICP/ AES)

AAMA Metals Data Page 6 of 13 Observed Standard Deviation Spike Concentration c:/ pw/ ostmdl/ req005/ r005sd1. s Wed Mar 20 13: 32: 28 2002 0 100 200 300 400 500 50 100 150 200 Lab: 2 LEAD, UG/ L 0 100 200 300 400 500 2 4 6 8 10 12 Lab: 3 LEAD, UG/ L 0 100 200 300 400 500 20 25 30 35 Lab: 4 LEAD, UG/ L 0 100 200 300 400 500 0 2 4 6 8 10 Lab: 5 LEAD, UG/ L 0 100 200 300 400 500 5 10 15 20 Lab: 6 LEAD, UG/ L 0 100 200 300 400 500 10 15 20 25 Lab: 7 LEAD, UG/ L 0 100 200 300 400 500 5 10 15 20 Lab: 8 LEAD, UG/ L 0 100 200 300 400 500 10 12 14 16 18 20 22 Lab: 9 LEAD, UG/ L 0 10 20 30 40 50 1.0 1.2 1.4 Lab: 1 MANGANESE, UG/ L Standard Deviations vs Spike Concentrations ( Original Scale)

( Matrix A, Method EPA 200.7 ICP/ AES)

AAMA Metals Data Page 7 of 13 Observed Standard Deviation Spike Concentration c:/ pw/ ostmdl/ req005/ r005sd1. s Wed Mar 20 13: 32: 30 2002 0 10 20 30 40 50 5.8 6.0 6.2 6.4 6.6 Lab: 2 MANGANESE, UG/ L 0 10 20 30 40 50 0.2 0.4 0.6 0.8 Lab: 3 MANGANESE, UG/ L 0 10 20 30 40 50 20 40 60 80 100 120 Lab: 4 MANGANESE, UG/ L 0 10 20 30 40 50 0.5 1.0 1.5 2.0 Lab: 5 MANGANESE, UG/ L 0 10 20 30 40 50 1 2 3 4 Lab: 6 MANGANESE, UG/ L 0 10 20 30 40 50 0.5 1.0 1.5 2.0 Lab: 7 MANGANESE, UG/ L 0 10 20 30 40 50 0.8 1.0 1.2 1.4 1.6 1.8 2.0 Lab: 8 MANGANESE, UG/ L 0 10 20 30 40 50 2 3 4 5 Lab: 9 MANGANESE, UG/ L 0.0 0.5 1.0 1.5 2.0 0.0 0.2 0.4 0.6 0.8 Lab: 1 MERCURY, UG/ L Standard Deviations vs Spike Concentrations ( Original Scale)

( Matrix A, Method EPA 200.7 ICP/ AES)

AAMA Metals Data Page 8 of 13 Observed Standard Deviation Spike Concentration c:/ pw/ ostmdl/ req005/ r005sd1. s Wed Mar 20 13: 32: 32 2002 0.0 0.5 1.0 1.5 2.0 0.04 0.05 0.06 0.07 0.08 0.09 Lab: 2 MERCURY, UG/ L 0.0 0.5 1.0 1.5 2.0 0.05 0.10 0.15 0.20 0.25 0.30 Lab: 3 MERCURY, UG/ L 0.0 0.5 1.0 1.5 2.0 0.05 0.10 0.15 0.20 0.25 0.30 Lab: 4 MERCURY, UG/ L 0.0 0.5 1.0 1.5 2.0 0.02 0.04 0.06 0.08 0.10 0.12 0.14 Lab: 5 MERCURY, UG/ L 0.0 0.5 1.0 1.5 2.0 0.5 1.0 1.5 2.0 2.5 3.0 Lab: 6 MERCURY, UG/ L 0.0 0.5 1.0 1.5 2.0 0.05 0.10 0.15 0.20 Lab: 7 MERCURY, UG/ L 0.0 0.5 1.0 1.5 2.0 0.1 0.2 0.3 0.4 Lab: 8 MERCURY, UG/ L 0.0 0.5 1.0 1.5 2.0 0.05 0.10 0.15 Lab: 9 MERCURY, UG/ L 0 50 100 150 200 250 3 4 5 Lab: 1 MOLYBDENUM, UG/ L Standard Deviations vs Spike Concentrations ( Original Scale)

( Matrix A, Method EPA 200.7 ICP/ AES)

AAMA Metals Data Page 9 of 13 Observed Standard Deviation Spike Concentration c:/ pw/ ostmdl/ req005/ r005sd1. s Wed Mar 20 13: 32: 34 2002 0 50 100 150 200 250 18 20 22 24 26 Lab: 2 MOLYBDENUM, UG/ L 0 50 100 150 200 250 0 2 4 6 8 10 Lab: 3 MOLYBDENUM, UG/ L 0 50 100 150 200 250 8 10 12 14 16 18 Lab: 4 MOLYBDENUM, UG/ L 0 50 100 150 200 250 1 2 3 4 5 Lab: 5 MOLYBDENUM, UG/ L 0 50 100 150 200 250 5 10 15 20 Lab: 6 MOLYBDENUM, UG/ L 0 50 100 150 200 250 6 8 10 12 14 16 Lab: 7 MOLYBDENUM, UG/ L 0 50 100 150 200 250 1 2 3 4 Lab: 8 MOLYBDENUM, UG/ L 0 50 100 150 200 250 4 6 8 10 12 14 Lab: 9 MOLYBDENUM, UG/ L 0 50 100 150 200 1.5 2.0 2.5 3.0 3.5 4.0 4.5 Lab: 1 NICKEL, UG/ L Standard Deviations vs Spike Concentrations ( Original Scale)

( Matrix A, Method EPA 200.7 ICP/ AES)

AAMA Metals Data Page 10 of 13 Observed Standard Deviation Spike Concentration c:/ pw/ ostmdl/ req005/ r005sd1. s Wed Mar 20 13: 32: 36 2002 0 50 100 150 200 20 40 60 80 Lab: 2 NICKEL, UG/ L 0 50 100 150 200 1 2 3 4 Lab: 3 NICKEL, UG/ L 0 50 100 150 200 10 15 20 25 30 35 Lab: 4 NICKEL, UG/ L 0 50 100 150 200 1 2 3 4 5 Lab: 5 NICKEL, UG/ L 0 50 100 150 200 0 100 200 300 Lab: 6 NICKEL, UG/ L 0 50 100 150 200 2.5 3.0 3.5 4.0 4.5 5.0 Lab: 7 NICKEL, UG/ L 0 50 100 150 200 2 4 6 8 Lab: 8 NICKEL, UG/ L 0 50 100 150 200 4 6 8 10 Lab: 9 NICKEL, UG/ L 0 200 400 600 800 1000 10 20 30 40 Lab: 1 SELENIUM, UG/ L Standard Deviations vs Spike Concentrations ( Original Scale)

( Matrix A, Method EPA 200.7 ICP/ AES)

AAMA Metals Data Page 11 of 13 Observed Standard Deviation Spike Concentration c:/ pw/ ostmdl/ req005/ r005sd1. s Wed Mar 20 13: 32: 38 2002 0 200 400 600 800 1000 100 200 300 400 Lab: 2 SELENIUM, UG/ L 0 200 400 600 800 1000 10 20 30 40 Lab: 3 SELENIUM, UG/ L 0 200 400 600 800 1000 40 50 60 70 Lab: 4 SELENIUM, UG/ L 0 200 400 600 800 1000 5 10 15 20 25 Lab: 5 SELENIUM, UG/ L 0 200 400 600 800 1000 0 100 200 300 Lab: 6 SELENIUM, UG/ L 0 200 400 600 800 1000 20 30 40 50 60 Lab: 7 SELENIUM, UG/ L 0 200 400 600 800 1000 5 10 15 20 25 30 Lab: 8 SELENIUM, UG/ L 0 200 400 600 800 1000 40 60 80 100 Lab: 9 SELENIUM, UG/ L 0 20 40 60 80 100 1.0 1.5 2.0 Lab: 1 SILVER, UG/ L Standard Deviations vs Spike Concentrations ( Original Scale)

( Matrix A, Method EPA 200.7 ICP/ AES)

AAMA Metals Data Page 12 of 13 Observed Standard Deviation Spike Concentration c:/ pw/ ostmdl/ req005/ r005sd1. s Wed Mar 20 13: 32: 40 2002 0 20 40 60 80 100 5 10 15 Lab: 2 SILVER, UG/ L 0 20 40 60 80 100 0.5 1.0 1.5 2.0 2.5 Lab: 3 SILVER, UG/ L 0 20 40 60 80 100 43 44 45 46 47 Lab: 4 SILVER, UG/ L 0 20 40 60 80 100 0.5 1.0 1.5 2.0 Lab: 5 SILVER, UG/ L 0 20 40 60 80 100 0 20 40 60 80 Lab: 6 SILVER, UG/ L 0 20 40 60 80 100 3.0 3.5 4.0 4.5 5.0 Lab: 7 SILVER, UG/ L 0 20 40 60 80 100 1 2 3 4 Lab: 8 SILVER, UG/ L 0 20 40 60 80 100 0 1 2 3 4 5 6 Lab: 9 SILVER, UG/ L 0 50 100 150 200 250 2 3 4 5 Lab: 1 ZINC, UG/ L Standard Deviations vs Spike Concentrations ( Original Scale)

( Matrix A, Method EPA 200.7 ICP/ AES)