UNITED STATES ENVIRONMENTAL PROTECTION AGENCY WASHINGTON, D. C. 20460 OFFICE OF PREVENTION, PESTICIDES AND TOXIC SUBSTANCES March, 31st, 2004 MEMORANDUM SUBJECT: Probabilistic Chronic Dietary Exposure Estimates for Pentachloronitrobenzene ( PCNB), List A PC Code: 056502, DP Barcode D298352 No MRID. Rereg. Case No. 0128 FROM: Mohsen Sahafeyan, Chemist Reregistration Branch 2 Health Effects Division ( 7509C)

THROUGH: David Soderberg ( RRB1), Thomas Bloem ( RB2) Dietary Exposure Science Advisory Council And Alan Nielsen, Branch Senior Scientist Reregistration Branch 2 Health Effects Division ( 7509C)

TO: Diana Locke, Toxicologist Reregistration Branch 2 Health Effects Division ( 7509C) 2 Executive Summary The purpose of this memorandum is to report the results of a chronic dietary exposure analysis for Pentachloronitrobenzene ( PCNB). In this analysis the chronic dietary exposure and risk estimates resulting from food intake were determined for the general U. S. population and various population subgroups.

The analysis was performed to support the reregistration eligibility decision ( RED). This chronic dietary risk assessment is considered to be a highly refined assessment using all available monitoring data, % CT ( percent crop treated) information, and processing factors. However, because monitoring data did not analyze for all PCNB metabolites of concern ( 86 identified metabolites), the ratio of total radioactive residues ( TRR) to PCNB from available metabolism studies is used in combination with monitoring residue data on PCNB. Otherwise, TRR values by themselves were used to estimate the total residues of concern.

This risk assessment was performed with both Dietary Exposure Evaluation Model Food Consumption Intake Database ( DEEM FCID   ) and Lifeline models. The 1994 1998 USDA's Continuing Surveys of Food Intake by Individuals ( CSFII) was used by both models for a consumption data base. Since the results from both models were close, only those from DEEM FCID model are summarized below.

Two chronic dietary risk assessment are reported here. The first one includes both registered and unregistered commodities. This is because monitoring residue data show considerable number of detects in unregistered commodities. That is believed to be due to rotational crop effect based on the available studies and evidences. It is believed that the wide presence of PCNB and/ or its residues on unregistered crops are due to its uptake from soil by rotated crops ( rather than illegal use), which in turn is due to a very long half life ( 1555 days) of PCNB and/ or its metabolites in soil. The Chemistry Science Advisory Committee ( ChemSAC) has concluded that rotational crop restrictions to registered crops beyond 1 year is not enforceable and thus is impractical. Therefore, there is no practical expectation that dietary risks from PCNB on these unregistered crops could be mitigated by further restrictions on crop rotations.

The second risk assessment includes only registered commodities. The second assessment is presented here in the interest of completeness but may not reflect the existing total dietary risk in the food chain from use of PCNB and its metabolites.

An important reminder is that the chronic dietary risk estimates reported in this memorandum is subject to change should the 2004 monitoring data on milk samples ( unavailable yet) from United States Agriculture Department, Pesticide Data Program ( USDA PDP) indicate higher levels of PCNB and its metabolites than what was assumed in this assessment. Furthermore, a confirmatory study on ruminant metabolism study may be required ( to be addressed in RED), the results of which may also trigger a need to update this dietary risk assessment. 3 The results of these chronic dietary risk assessments show that the risk for all population subgroups are below the level of concern; i. e., 100% cPAD. For the chronic dietary risk due to all crops, i. e., both registered and unregistered crops, the general U. S. population had 12% cPAD and population subgroup children 1 2 years old had the highest estimated risk of 34% cPAD. For the chronic dietary risk due to registered crops, the general U. S. population had 10% cPAD and population subgroup children 1 2 years old had the highest estimated risk of 27% cPAD.

When water was added to the analysis, % cPAD exceeded 100% for all populations except youth 13 19 with % cPAD of 78% and adults 20 49 with % cPAD of 97%; all other population subgroups exceeded the 100% cPAD mark and thus are of concern. The estimated risk including water for general U. S. population is 105% cPAD and the highest estimated risk is for population subgroup all infants with the 313% cPAD.

I. Introduction Dietary risk assessment incorporates both exposure and toxicity of a given pesticide. For acute and chronic assessments, the risk is expressed as a percentage of a maximum acceptable dose ( i. e., the dose which HED has concluded will result in no unreasonable adverse health effects). This dose is referred to as the population adjusted dose ( PAD). The PAD is equivalent to the Reference Dose ( RfD) divided by the special FQPA Safety Factor.

For acute and non cancer chronic exposures, HED is concerned when estimated dietary risk exceeds 100% of the PAD. HED is generally concerned when estimated cancer risk exceeds one in one million ( i. e., the risk exceeds 1 x 10 6). References which discuss the acute and chronic risk assessments in more detail are available on the EPA/ pesticides web site: " Available Information on Assessing Exposure from Pesticides, A User's Guide", 6/ 21/ 2000, web link: http:// www. epa. gov/ fedrgstr/ EPA PEST/ 2000/ July/ Day 12/ 6061. pdf ; or see SOP 99.6 ( 8/ 20/ 99).

II. Residue Information Pentachloronitrobenzene ( PCNB) is an organochlorine fungicide registered on vegetables ( cole crops, peppers, beans, peas), field crops ( cotton, peanuts, potatoes), turf and ornamentals. It is applied both to soil and seeds and is a re registration chemical. PCNB formulations registered to the basic producers, Uniroyal Chemical Company and Amvac Chemical Corporation, for use on food/ feed crops include flowable concentrate ( FlC), water dispersible granular ( WDG), wettable powder ( WP), emulsifiable concentrate ( EC), granular ( G), dust ( D), and ready to use ( RTU) formulations. PCNB products are sold under the trade name QuintozeneTM. These products may be applied as pre plant incorporated applications, in furrow applications, broadcast applications, or banded applications using ground equipment or as seed treatments. The maximum total application rate for all crops ranges from 1.5 lbs ai/ A for hot peppers ( in furrow application) to 30 lbs ai/ A for cole crops as band or broadcast or row/ row drench type of application ( per draft use closure memo, Jill Bloom, 1/ 23/ 03). 4 The following Table summarizes PCNB tolerances.

Table 2.1: Summary of tolerances Type and Magnitude of Tolerance ( ppm) Tolerance Expression Crop/ Commodity 40 CFR Permanent, 0.1 ppm PCNB ( per se) cottonseed 180.291 ( a)

Regional registration, 0.2 ppm PCNB, PCA, MPCPS ( also known as PCTA) collards, kale, mustard greens 180.291 ( b)

Interim, 0.1 ppm PCNB ( per se) beans, broccoli, brussels sprouts, cabbage, cauliflower, garlic, peppers, potatoes1, tomatoes, 180.319 Interim, 1.0 ppm PCNB ( per se) peanuts 180.319 1. The only potato use by Uniroyal is as a Special Local Need ( SLN).

The Metabolism Assessment Review Committee ( MARC) met on April 16th, 2003 to determine the residues of concern and the tolerance expression for plants and livestock, as well as degradates of concern in water. The MARC determined that the residues of concern are all metabolites of PCNB identified in plant and animal metabolism studies; however, the tolerance expression, includes PCNB, pentachloroanilin ( PCA), and pentachlorothioaniosle ( PCTA) [ Sahafeyan, M., " The Outcome of the HED Metabolism Assessment Review Committee Held on April 16th, 2003 to discuss residues of concern in risk assessment and tolerance expression of Pentachloronitrobenzene ( PCNB). Chemical 056502", 5/ 27/ 2003]

IIa) Residue Data Used in Chronic Assessments General Consideration: As stated earlier the tolerance expression for PCNB also includes PCA and PCTA. Of the two major food and crop monitoring programs, however, only Food and Drug Administration ( FDA) usually analyzed for combined residues of PCNB, PCA, and PCTA while PDP only randomly analyzed samples for PCA and PCTA. However, since MARC, concluded that PCNB and all its 86 metabolites are of concern, residue data for other PCNB metabolites besides PCA, and PCTA were needed for conducting a dietary risk assessment. As mentioned above, monitoring program, i. e., PDP and FDA, do not look for all PCNB metabolites in their samples; at most they only analyze for PCNB and two of its metabolites. Furthermore, in the monitoring data, the number of 5 samples that are analyzed for more than one metabolite is generally insufficient (< 100) for use in the risk assessment according to HED guidelines. This is particularly true for FDA data on all PCNB registered crops; therefore, all monitoring data that were used in this dietary risk assessment were PDP data. In particular, PDP data from the two most recent years for each crop were utilized.

In order to estimate the total residues of PCNB and all its metabolites from PCNB alone and/ or PCA, an approach was taken that centers around the fact that that had there been a metabolism study conducted for every crop, the concentration of PCNB and all its identified metabolites which is termed Total Toxic Residue ( TTR), or total residues of concern, would have been equal or less than the Total Radioactive Residues ( TRR) in each crop which includes extractable as well as unextractable residues; therefore using TRR values to represent TTR will not result in underestimation of the risk. Another reason for using TRR values as an estimate of TTR is that any unextractable residue of PCNB has a high likelihood of having a polychlorinated phenyl structure ( when released under various biochemical enzymatic reactions). This is because all the identified extractable metabolites of PCNB were found to be of polychlorinated phenyl nature and therefore were considered to be of concern by MARC. In addition, since the metabolism study for each crop is not available and metabolism studies of potato, peanut and cabbage need to be used for other crops, using a TRR from these metabolism studies for other crops increases the confidence that the risk is not underestimated. Table 2.2 below contains the summary of the results of metabolism studies in peanut and potato.

Table 2.2  Summary of metabolism studies for peanut and potato.

PEANUT ( 5X application rate) 1 POTAO ( 1X or 3X application rate) 2 Peanut Nutmeat Peanut hay 1X 3X PCNB 1.7 3.1 0.084 0.28 PCA 0 0 0.047 0.085 PCTA 0 8.7 0.039 0.096 total Identified 1.7 15 0.722 2.13 total characterized3 1.7 0.5 0.329 1.14 Total extractable4 1.7 15.5 1.05 3.27 total bound 0.02 0.9 0.075 0.351 TRR 1.72 16.3 1.12 3.54 TRR / PCNB 1.01 5.26 13.3 12.6 TRR / PCA   23.8 41.6 1. Use pattern for peanut: two banded applications of [ 14C] PCNB totaling 10.0 lb ai/ A ( 5X) 2. Use pattern for potato: a pre plant incorporated application of [ 14C] PCNB at 20 or 60 lb ai/ A ( 1X or 3X). 3. Characterized ( here) = sum of all unidentified extractable residues 4. Extractable = identified + characterized 6 In this dietary risk assessment, the ratio of TRR: PCNB from potato metabolism study is used for most of the crops. This is because TRR: PCNB ratio from potato metabolism study does not depend on application rate. As PCNB application is almost all through soil, there is no concern about the difference in pre harvest interval between the crop in metabolism study and the translated to crops.

To calculate TRR, the ratio of TRR to PCNB ( TRR: PCNB) from metabolism studies and PCNB monitoring data ( from PDP or FDA) are used as shown in the following equation:

TRR/ PCNB ( from metabolism studies) X PCNB ( in monitoring samples) = TRR ( in monitoring samples)

The rational for using TRR: PCNB ratio from potato metabolism study, to translate to other crops, except brassica vegetables is explained below.

i) Not using TRR: PCA ratio: This is because as it is seen in table 2.2 , TRR: PCA ratio in potato metabolism study is dependent of the use rate and increases with the use rate; i. e., TRR: PCA ratio is 24 for 1X rate whereas this ratio is 42 for 3X use rate. This is not the case for TRR: PCNB ratio in the same study, i. e., for both 1X and 3X the value of this ratio is ~ 13. This information gives indication that the same trend may also prevail in peanut metabolism study in which this information can not be verified since the study was done only at one use rate; i. e., the TRR: PCNB may be independent of use rate whereas the TRR: PCA ratio may be use rate dependent in peanut metabolism study. The dependence of TRR: PCA ratio on use rate makes this ratio not ideal for translation to other crops whose application rate is different than potato or peanut. As PCNB application is almost all through soil, there is no concern about the difference in pre harvest interval between the crop in metabolism study and the translated to crops.

ii) Not using TRR: PCNB ratio from peanut metabolism study except for peanut itself: This is because TRR: PCNB ratio from peanut metabolism study ( peanut and hay) is lower than that from potato metabolism study and thus it is less conservative/ protective especially since the ratio from cabbage metabolism study can not be obtained for comparison.

iii) Not using TRR: PCNB ratio for brassica crops: For brassica crops a TRR of 17.9 ppm directly from the cabbage metabolism study was used. This is because the submitted cabbage metabolism study lacks any estimate for residues of PCNB, PCA or PCTA. Since the use rate in cabbage metabolism study ( 48 lb ai/ A) is higher than the registered rate for cabbage and other registered brassica crops ( 30 lb ai/ A), the estimated TRR of 17.9 ppm is not expected to be an underestimate.

Processing Factors: The preliminary review of submitted processing studies ( DP Barcode D225392, MRID 430976901) on cottonseed indicates that these studies may be inadequate or inconclusive due to a high LOQ ( 0.25 ppm for cotton oil), lack of recovery data ( for crude oil), likelihood of PCA presence, and presence of residues in untreated control samples. Moreover, PCA residues ( average of 0.0064 ppm) were found in soapstock which are commonly added to cottonseed meal. While these 7 studies need to undergo thorough review at a later date for a definite conclusion, in this risk assessment, due to the preliminary indications listed above, PCNB and its metabolites were assumed to be present in cottonseed processed items, i. e., the default DEEM 7.87 concentration factors ( 1) were used.

The preliminary review of submitted processing studies ( DP Barcode D225392, MRID 430976902) on peanut indicates that PCNB and/ or metabolites concentrate in crude ( 1.6X), refined oil ( 2.1X) and hulls ( 2.5X). These values, based on preliminary reviews, were used for this risk assessment when applicable, while thorough review of these studies will be done at a later date.

Based on submitted processing study by Uniroyal, a concentration factor of 5.4X for potato with peel, based on a processing study for potato wet peels was used. Although Amvac processing study shows higher concentration factors for potato wet peels ( average of 7X), the lower concentration factor from Uniroyal study, i. e., 5.4X, was used because the potato peel food forms in DEEM FCID also include potato itself, thus lowering the concentration of residues.

Also based on submitted processing studies on dry tomato pomace ( concentration factor of up to 63X), it was decided that a concentration factor is needed for dried tomato; however, since dry pomace has a different texture and matrix than dried tomato, the default dried tomato value ( 14.3X) was used. Submitted studies indicated that the residues will not concentrate in tomato puree and tomato paste and thus no concentration factor was used for these tomato food forms.

The other processing factor used in this risk assessment was for dried beef, for which a default processing factor of 1.92X was used.

Individual Crops: In the following section, residue data, ratios of TRR: PCNB from metabolism studies, % CT, and any other data or estimates that were used are discussed in detail for individual crops. Table 2.5 at the end of this section summarizes the input data and calculated residues for each crop.

Beans: PDP 2000 and 2001 data were used for fresh green beans; 720 + 707 samples were analyzed. Those samples were analyzed only for PCNB. The 1994 PDP samples were analyzed for both PCNB and PCA in fresh green beans, however, the samples count is only 41 ( since less than 100 data are not sufficient for use in a risk assessment according to HED guidelines); FDA analyzed only one bean sample ( Garbanzo beans, dried or paste ) for PCNB. The 1997 1998 PDP data were used for canned/ frozen beans. The average % CT ( reported by BEAD) of 2% for green was used. The ratio of TTR/ PCNB = 13 from potato metabolism study was used to estimate the total residues of concern based on reported PCNB residues in monitoring samples.

Brassica Crops: Cabbage metabolism study revealed that the TRR was 17.9 ppm. For brassica crops, i. e., broccoli, brussels sprouts, cabbage, cauliflower, chinese broccoli, and chinese cabbage, collards, kale, and mustard green, a TRR of 17.9 ppm directly from the cabbage metabolism study was used. This is because the submitted cabbage metabolism study lacks any estimate for residues of PCNB, PCA or PCTA. Since the use rate in cabbage metabolism study ( 48 lb ai/ A) is higher 8 than the registered rate for cabbage and other registered brassica crops ( 30 lb ai/ A), the estimated TRR of 17.9 ppm is not expected to be an underestimate.

The average % CT of 1% was used for broccoli, cabbage, chinese broccoli, chinese cabbage, collards, kale and mustard green, and 13% CT and 2% CT values were used for brussels sprouts and cauliflower respectively to estimate the chronic dietary burden.

Cotton : PDP does not sample cotton seeds. Consequently, the TRR value from one of the metabolism studies after correcting for application rate difference should have been translated to cotton. The highest TRR value per application rate ( TRR/ rate) is from peanut hay metabolism study ( 16.3/ 10). This ratio from cabbage or potato metabolism study is 17.8/ 48 or 3.54/ 60 respectively. The translated TRR from peanut hay metabolism study after adjustment for application rate difference ( 16.3/ 10 * 2.1) is 3.3 ppm. The chronic residue estimate calculated by incorporating the adjusted TRR from peanut hay metabolism study and the average 5% CT was 0.165 ppm.

Garlic: No PDP or FDA data is available for garlic. Consequently, the TRR value from one of the metabolism studies after correcting for application rate difference should have been translated to garlic. The highest TRR value per application rate ( TRR/ rate) is from peanut hay metabolism study ( 16.3/ 10). This ratio from cabbage or potato metabolism study is 17.8/ 48 or 3.54/ 60 respectively. The TRR from peanut hay metabolism study after adjustment for application rate difference ( 16.3/ 10 * 20.6) was 33 ppm. The chronic residue estimate calculated by incorporating the adjusted TRR from peanut hay metabolism study and the average 1% CT was 0.33 ppm.

Meat: MMPE is discussed following this section under livestock commodities.

Milk: PDP analyzed milk samples during 1996 to 1998 for PCNB only , i. e., no other metabolites were looked for ( total of 1892 samples with LOD of 0.001 ppm). Although no detected residues of PCNB were found, PDP data could not be used since PDP did not analyze for other metabolites of PCNB like PCA which was the major identified residue in milk in ruminants metabolism study ( 1989, MRID 41341205, MRID 41692802, summarized in John Abbots memorandum, DP Barcode 158943, 4/ 24/ 96). Therefore, to calculate the effective TRR value in this risk assessment, the TRR value from ruminant metabolism study, theoretical dietary burden, and % CT information were used. Further discussion of milk is covered under livestock commodities.

Peanuts: The peanut use rate is 2 10 lb ai/ A by ground or arial application. The peanut metabolism study, however, was done with PPI application ( 10 lb ai/ A). The average % CT of 1% was used for peanuts in this assessment. The PDP analyzed for PCA and PCNB in peanut butter samples during the year 2000. 90 out of 716 samples had detected residues. 89 detects had only PCA not PCNB and the maximum detected PCA was 0.095 ppm and 0.02 ppm for PCNB. These monitoring data, however, can not be used in this risk assessment. This is because while in peanut metabolism study there is no PCA detected, it is PCA that is detected in almost all samples containing residues in PDP peanut butter data. There is no method to convert the PCA residues from PDP to TRR. The reason PCA residues appear in peanut butter monitoring data is not clear. 9 Therefore, to estimate the chronic residue in peanuts, TRR from peanut metabolism study was adjusted to 1X rate and multiplied by % CT ( 1.72/ 5 X 1% = 0.00344 ppm). For peanut butter however since it is considered a blended commodity and monitoring data on this commodity is available ( PDP 2000), the average of all monitoring data, after summing PCNB and PCA on same samples and using TRR:( PCNB+ PCA) ratio from peanut nutmeat metabolism study ( 5.3) was used as the chronic point estimate for peanut butter; this value is 0.0049 ppm.

Peppers, sweet: PDP 2000 and 2002 monitoring data have samples analyzed for PCNB in sweet bell peppers ( 738+ 186 total samples with no detects, average ½ LOD value = 0.0021 ppm). The average % CT of 1% was used in calculation of a chronic point estimate for sweet peppers. The ratio of TRR/ PCNB = 13 from potato metabolism study and PCNB residues in/ on monitoring samples were used to estimate the total residues of concern in monitoring samples; the application method in potato metabolism study and the registered application method for peppers are both through ground application.

Pepper, hot: There are no PDP data on hot pepper. There are also not a sufficient number of FDA data on hot pepper that can be utilized in this risk assessment much less than 100. Those limited FDA data however show traces of total PCNB in hot peppers imported from Mexico. No detects were found in FDA data for domestic hot peppers. Because of lack of PDP data and insufficient number of FDA data on hot pepper, and since the application method on both types of peppers is via transplant solution and also since the use rate for sweet pepper is higher than that on hot pepper, PDP 2000 and 2002 monitoring data for sweet pepper were used as surrogate data for hot pepper ( 738+ 186 total samples with no detects, average ½ LOD value = 0.0021 ppm). The average % CT of 3% ( from BEAD) and the TRR: PCNB ratio from potato metabolism study ( TRR: PCNB = 13) were also used to estimate the total residues of concern in monitoring samples based on PCNB residues in/ on those samples; the application method in potato metabolism study and the registered application method for peppers are both through ground application.

Potato: PDP only analyzed for PCNB ( no metabolites) between years 2000 and 2002. Between 0.5% to 1.9% of those data had detectable levels of PCNB in the range of 0.058 ppm to 0.098 ppm. Potato has a Special Local Need ( SLN) tolerance of 0.1 ppm. The average % CT from QUA report ( BEAD, Tim Kiely, 10/ 12/ 2001) is 3%. The ratio of TTR/ PCNB ( i. e., the value of 13) from potato metabolism study at 1X rate was used to calculate TRR in each PDP sample.

Poultry/ Egg: MMPE is discussed following this section under livestock commodities.

Seed Treated Crops: A preliminary review of the submitted studies on barley, soybean, corn, wheat, peas, and sugar beets indicates that PCNB and/ or some of its metabolites may be found at detectable levels in some crop parts grown from treated seeds particularly wheat ( straw) and peas. However, presence of those residues in some of the control corps, i. e., those grown from untreated seeds, make the results dubious. In particular, this observation may indicate that the residues seen in the crops grown from treated seeds may be due to PCNB residues left in soil from previous crops, a very likely possibility considering the long half life of PCNB ( 1555 days). Because of this uncertainty indicated above, no chronic residue estimates were made due to the seed treatment of 10 barley, corn, cotton, oats, peas, rice, safflower, sorghum, soybeans, sugar beets, and wheat. This provision may change after more thorough review of the submitted studies.

Tomatoes: PDP 1998 1999 data for fresh tomatoes were used for fresh tomatoes; only PCNB was looked for in those samples ( 717 + 364 total samples with only 2 detected residues). PDP 1999 2000 canned tomato data were used for canned tomatoes; again only PCNB was looked for in those samples ( 368 + 369 total samples with no detected residues). PDP 2001 data for tomato paste were used for tomato paste; both PCNB and PCA were analyzed for in those samples ( 369 total samples with no detected residues). The average % CT of 1% is used for tomatoes. The ratio of TRR/ PCNB from potato metabolism study and PCNB residues in/ on monitoring samples were used to estimate the total residues of concern in monitoring samples Livestock Commodities  The US Department of Agriculture's Food Safety and Inspection Service ( FSIS) is responsible for monitoring pesticides in poultry and livestock. In particular, FSIS tests between 300 to 500 samples of more than 20 types of livestock each year for chlorinated hydrocarbons. Although FSIS does not specifically monitor for residues of PCNB in poultry and livestock, FSIS does routinely test these animals using a broad screen GPC/ GC/ EC method to detect a variety of chlorinated hydrocarbons. At HED's request FSIS has determined that residues of PCNB and PCA would be detected with this method if they were present in these animals. The exact sensitivity of the method to PCA and PCNB is not known, but is expected to be similar to the sensitivity of the method to other chlorinated hydrocarbons, which is approximately 0.01 0.1 ppm.

In routine monitoring, FSIS reports that they did detect PCA in one hog sample in 1998 at about 0.5 ppm. Otherwise, FSIS has not reported seeing either PCA or PCNB in recent monitoring. Therefore, there are not a lot of violative PCNB residues. Because FSIS does not specifically monitor for residues of PCNB in poultry and livestock, in this risk assessment calculated dietary burdens, animal metabolism studies, feeding studies, and % CT values were used to derive residue estimates in livestock commodities.

The calculation of dietary burden is shown in table 2.4 below. As it is seen in that table, TRR level residues in registered and unregistered crops which have associated feed items are used for estimating the dietary burden. As was discussed earlier, this is because detected levels of PCNB and/ or its metabolites have been widely observed on unregistered crops that were sampled by PDP and FDA, substantiating the very long half life of PCNB and/ or its residues in soil ( 1555 days, C. A. Sutton, " Pentachloronitrobenzene, Revised Drinking Water Assessment", D291286, 12/ 22/ 2003) reported in literature. Presence of PCNB and/ or its metabolites in untreated seeds in seed treatment studies may also hint to the transfer of PCNB residues left in the soil from previous treated crops.

To estimate the total residues of concern in feed items, a livestock diet had to be constructed. The diet could include unregistered feed items due to the transfer of residues from soil to the rotated crops ( registered or unregistered). Cultural practice and geographical have to be also considered in formulating a diet. Two scenarios of cultural practices and geographical areas that could result 11 in maximum residues of concern in the livestock were identified. However, only one was used in constructing the livestock diet. Those scenarios are discussed below:

a) One possible scenario would be to have a registered crop with a feed item ( cotton, peanut or potato) planted after brussels sprouts, a registered crop with the highest % CT ( 13%), in which case higher effective % CT ( i. e., 13% carry over of PCNB residues from brussels sprouts) could be conceivable for potato, peanut and cotton. However, these crops are not generally planted in the same geographical area and therefore it is an unlikely scenario.

b) Another scenario would involve unregistered rotated crops that have feed items and could be grown potentially in the same geographical area as registered crops with feed items. In particular, since cotton, peanut and potato are the only registered crops with feed items, any unregistered crop that has a feed item and is rotated after potato, cotton, or peanut was investigated. A review of the cultural practices ( personal communication with Bernard Schneider, HED senior plant biologists) revealed that this is in fact a very likely scenario since potato is generally rotated to sweet corn, soybeans or wheat and peanut is usually rotated to grass crops or cereal grains. In particular, potatoes can be rotated to major crops such as field corn, and alfalfa and wheat. Therefore, available rotational crop study for wheat was used for this purpose.

In a submitted rotational crop study ( MRID 41562905), the levels of PCNB and its analyzed metabolites in wheat straw planted 30 and 365 days after one year following a single soil application of [ 14C] PCNB at 30 lb ai/ A were quite high ( 22.2 25.9 ppm) and steady during the one year plant back interval; the total radioactive residues in wheat forage, straw, and grain were 2.59, 22.9, and 0.33 ppm, respectively, from the 30 day PBI, and were 5.05, 25.9, and 0.38 ppm, respectively, from the 365 day PBI. Comparison of TRR in peanut nutmeat and peanut hay in peanut metabolism study also reveals that PCNB and its metabolites concentrate by few fold in the hay part of peanut than nutmeat. This information can be directly used for calculating a dietary burden composed of potato hulls, peanut hay, and wheat straw since the application rate used in the rotational crop study ( 30 lb ai/ A) is not much higher than the maximum label rate for potato ( 20 lb ai/ A); 30 lb ai/ A is the maximum use rate for brassica vegetables.

Table 2.3 below shows how theoretical dietary burden was calculated.

Table 2.3  Calculation of chronic dietary burdens of livestock animals for PCNB residues. 12 Feed Commodity 1, 3 % Dry Matter 2 % Diet 2 TRR ( ppm) 2 Dietary Burden from Registered and Unregistered Crops ( ppm) 3,4, 6 Dietary Burden from Registered Crops ( ppm) 3,4,6 Beef Cattle potato waste5 15 40 8.0 21.3 21.3 peanut meal5 85 15 0.4 0.07 0.07 forage ( wheat source) 25 25 5.05 5.05

straw and hay ( wheat source) 88 20 25.9 5.89

TOTAL BURDEN 100 32.31 21.37 Dairy Cattle potato waste 15 40 8.0 21.3 21.3 peanut meal 85 15 0.4 0.07 0.07 forage ( wheat source) 25 25 5.05 5.05

straw and hay ( wheat source) 88 20 25.9 5.89

TOTAL BURDEN 100 32.31 21.37 Poultry peanut meal N/ A 25 0.4 0.1 0.1 wheat grain 89 75 0.38 0.285 0 TOTAL BURDEN 100 0.385 0.1 Swine potato culls N/ A 50 1.1 0.55 0.55 peanut meal N/ A 15 0.4 0.6 0.6 Other feed stuff  35 0 0 0 Feed Commodity 1, 3 % Dry Matter 2 % Diet 2 TRR ( ppm) 2 Dietary Burden from Registered and Unregistered Crops ( ppm) 3,4, 6 Dietary Burden from Registered Crops ( ppm) 3,4,6 13 TOTAL BURDEN 100 1.15 1.15 1. Diet was chosen based on consultation with HED scientist, Jerry Stokes in Dec. 2003; personal communication.

2. From Table 1 of residue chemistry 860 guideline series ( August 1996).

3. Residues for potato waste are based on the TRR in potato metabolism study ( 1.12 ppm) and average concentration factor for potato wet peel in Amvac processing study ( 7x) and those for peanut meal are based on TRR in peanut metabolism study (~ 1.72/ 5 to get TRR for 1x use rate); the highest combined residues of PCNB, PCA, and PCTA from potato field trials is 1.01 ppm ( for 2 lb/ gal EC in in furrow application almost equal to 10 lb ai/ 12,400 linear feet of row with PHI of 89 135 days), that for peanut nutmeat from field trials is 0.330 ppm ( for 2 lb ai/ gal EC for total application rate of 10 lb ai/ A with PHI of 45 47 days), and for peanut hulls, the highest combined residues of PCNB, PCA, and PCTA from field trials is 1.09 ppm ( for 10% G formulation in total application rate of 10 lb ai/ A and PHI of 43 45 days). The closeness of TRR from metabolism studies and field trial data further supports use of TRR values and that this value for potato waste, potato culls, and peanut meal is not an overestimate.

4. Contribution = [ TRR / % DM ( if cattle)] X % diet).

5. It is realized that the combination of potato waste and peanut meal in a beef/ diary cattle diet is not common since the growing regions for potato and peanut are different and shipping of potato waste or peanut meal for cattle diet is not common. It is done here in the interest of conservativeness.

6. Dietary burden from registered and unregistered crops for beef cattle/ dairy includes contribution from rotated wheat forage/ hay/ straw which contain carried over residues of PCNB and its metabolites ( see MRID 41562905). Dietary burden from registered crops assumes stringent rotational crop restriction ( will be addressed in the upcoming RED) will make the unregistered crops to be PCNB free.

The results in Table 2.3 in combination with feeding studies were used to estimate PCNB chronic secondary residues. The dosing in feeding studies were 0.1, 1, 10, and 1000 ppm. Cows dosed with 1000 ppm were sacrificed after 1 month of dosing, whereas other cows were sacrificed after 12 15 weeks. Since the dietary burden calculated in the above Table is more than 10 ppm and the 1000 ppm dosed cows were dosed for shorter periods than other cows, and since all metabolites of PCNB that are not analyzed in the feeding study are of concern and no reliable approximation for the rest of metabolites from feeding studies is available, it was decided to use goat metabolism study as feeding study to estimate the concentration of metabolites of concern in animals. The following Table contains all the data which were used to estimate the chronic secondary residues for PCNB. Since two estimates for TDB were made for cattle( see Table 2.3 above), two estimates for chronic secondary residues were also made. 14 Table 2.4  Calculation of secondary residues of PCNB in livestock commodities.

Tissue Theoretical Dietary Burden ( Based on TRR from Table 2.3) Tissue : Feed ( Ratio based on TRR in metabolism study) % CT Chronic Secondary Residue [ TDB X ( T: F) X % CT]

Low Bound High Bound From Registered and Unregistered Crops From Registered Crops Only Milk Fat 21.37 ppm 32.31 ppm 8.11 / 1400 = 0.0058 3% ( potato) 0.004 X 25 = 0.1 ppm 0.006 X 25 = 0.15 ppm Goat Kidney 21.37 ppm 32.31 ppm 49.1 : 1400 = 0.035 3% ( potato) 0.02 0.03 Goat Liver 21.37 ppm 32.31 ppm 45.5 : 1400 = 0.032 3% ( potato) 0.02 0.03 Goat Muscle 21.37 ppm 32.31 ppm 2.3 : 1400 = 0.0016 3% ( potato) 0.001 0.002 Goat Renal Fat 21.37 ppm 32.31 ppm 32.8 : 1400 = 0.023 3% ( potato) 0.015 0.02 Chicken Egg Yolk 0.1 0.385 5.75 : 512 = 0.11 1% ( peanut s) 0.00011 0.0004 Chicken Thigh Muscle 0.1 0.385 0.71 : 512 = 0.0014 1% ( peanut s) 0.0000014 0.0000054 Chicken Fat 0.1 0.385 10.1 : 512 = 0.020 1% ( peanut s) 0.00002 0.00008 Swine Kidney 1.15  0.035 ( used goat data above) 3% ( potato) 0.0012 0.0012 Swine Liver 1.15  0.032 ( used goat data above) 3% ( potato) 0.001 0.001 Table 2.4  Calculation of secondary residues of PCNB in livestock commodities.

Tissue Theoretical Dietary Burden ( Based on TRR from Table 2.3) Tissue : Feed ( Ratio based on TRR in metabolism study) % CT Chronic Secondary Residue [ TDB X ( T: F) X % CT]

Low Bound High Bound From Registered and Unregistered Crops From Registered Crops Only 15 Swine Muscle 1.15  0.0016 ( used goat dataabove) 3% ( potato) 0.00006 0.00006 Swine Fat 1.15  0.023 ( used goat data above) 3% ( potato) 0.00080 0.00080 1 The current TRR value for milk ( 8.1 ppm) was calculated by the Dynamac reviewer assuming that the reported 5.8 ppm value for PCA represented 72.0% of the TRR in milk. However, there is some question as the extract TRR value to use for milk. The original review reported TRRs from radioassay of 24.0 and 58.5 ppm in milk from the low and high dose goat, respectively. However, calculated TRR values of 8.3 11.7 ppm are obtained, when using data from the summary table of the previous Agency review ( J. Abbotts, 4/ 24/ 96)

IIb) Non Registered Crops: The available monitoring data ( 1994 2002 PDP and FDA) show detected residues of PCNB and/ or its metabolites in/ on a number of unregistered crops. The 1994 2002 PDP data shows detected residues of PCNB and/ or PCA on winter squash fresh, carrots, spinach, cucumbers, asparagus, pears and celery ( percent hit with the exception of squash for which one out of one had detected residues of PCNB or PCA, was from 5.9% for carrots on PCA 1995 to 0.1% for celery and pears in 1998 and 2001 for PCNB respectively). The 1998 2001 FDA data on crops with domestic origin shows detected residues of " Quintozene ( total)" which includes PCNB, PCA, and PCTA on domestic lettuce head, tilapia aquaculture harvested fishery ( FDA produce code 16X06), squash, carrot, and ginsing ( FDA produce code 54F12) but tilapia and ginseng had trace residues. Tilapia had maximum 0.01 ppm, with one detect in four samples. Ginseng had 3.22 ppm with one detect in 100 samples.) The 1998 2001 FDA data on imported commodities also show a number of unregistered commodities with detected residues of " Quintozene ( total)" in squash, carrots, spinach, ginger root, and ginseng with 73% of ginseng samples in all FDA data ( and 58'% in FDA survaillance data) from different countries having detected residues of " Quintozene ( total)" with a range from trace to 17.44 ppm! Besides ginseng, the detected residues of PCNB and/ or its metabolites on domestic and imported commodities can be attributed to its long half life in soil as the available studies and literature suggests. Therefore, these crops which have considerable number of detects in both PDP and FDA ( carrots, spinach, cucumber, ginseng) are incorporated into this chronic dietary risk assessment as a high bound estimate. 16 As was mentioned above, the detected residues of PCNB and/ or its metabolites in/ on unregistered crops have high likelihood to be due to the carry over of those residues in soil from previous registered crops to unregistered rotational crops. Although in the upcoming RED, the rotation of crops is going to be restricted to registered crops, available studies/ literature suggest that PCNB can last as long as a few years in soil and thus be taken up by crops planted after one or two crop rotations. ChemSAC in February 2004 ruled out the imposing of rotational crop limitations to registered crops for 4 years or more due to impracticality of enforcement. Consequently, incorporation of unregistered crops which have detectable residues of PCNB and/ or its metabolites in dietary risk assessment in unavoidable.

The other observation from monitoring data is that percent hit ( percent detect) is much higher for PCA than PCNB ( 10 20 fold higher for carrots and spinach). PCA is believed to be more typical of soil metabolism than plant metabolism.

The following unregistered crops were incorporated into the first risk assessment when exposure to both registered and unregistered crops were considered. For carrots, cucumber, and spinach PDP monitoring data were used to estimate the sum of concentration of PCNB and PCA. This was done by taking the average of all PCNB and PCA residue concentrations separately and then adding them together. Realizing that this is an underestimate since there is an inherent assumption of other metabolites being at zero concentrations, there was not however any better method to account for TTR. Use of plant metabolism studies may not be appropriate since the residues of PCNB an its metabolites are more likely due to crop rotation than to direct application and hence the ratios of TTR: PCNB or TTR: PCA would not apply. No % CT values could be incorporated since the residues are believed to be from rotational crop effect; direct use of monitoring data including their zero detects was thought to work as incorporating % CT.

Spinach: 1995 and 1996 PDP data were used; the sum of averages of PCNB and PCA residues was 0.0003 ppm.

Carrots: The 1994, 1995 and 1996 PDP data were used; the sum of averages of PCNB and PCA residues was 0.0005 ppm.

Cucumber: The 1999 and 2000 PDP data were used; the sum of averages of PCNB and PCA residues was 0.00006 ppm. Realizing that this is an underestimate since there is an inherent assumption of other metabolites being at zero concentrations, there was not however any other method to account for TTR. Using potato metabolism study is not perhaps appropriate since the residues of PCNB and its metabolites on carrots are more likely due to rotation than direct application Ginseng: The 1998, 1999, 2001 FDA data were used to estimate the combined residues of PCNB and PCA. All except one sample were from foreign countries. The 1999 sample had combined PCNB and PCA residues of 3 ppm ( average of duplicate samples). The average PCNB and PCA residues on imported samples was 3.6 ppm. Taking into account that 45% of consumption of ginseng roots in US is from imported ginseng, the estimated average residue on ginseng is 3.27 17 ppm ( calculated as: ( 3.6 X .45) + ( 3 X 0.55) = 3.27 ppm).

Table 2.5  Summary of Residue Data for Different Commodities Commodity Data Range of D e t e c t s ( ppm) Details of files used to derive the chronic point estimate. % CT Chronic Point estimate ( ppm);

Ratio used to estimate the total TRR Data Source Sampling D a t e ( year) Number of Samples Number of Detects Number of Data Number of Detects Number of ½ LOD Number of Zeroes Average ½ LOD ( ppm)

Beans Greenfresh ( and Dry) PDP 2000,

2001 1427 47 0.005

0.02 1427 47 0 1380 0.00221 2% Estimated residue for chronic exposure = 0.00348 TRR: PCNB = 13 ( potato metabolism study)

Beans Greencanned PDP 1997,

1998 857 0   100 0 2 98 0.002109 2% Estimated residue for chronic exposure = 0.000548 TRR: PCNB = 13 ( potato metabolism study)

Beans Greenfrozen PDP 1997,

1998 451 1 0.005 451 1 3 840 0.002109 2% Estimated residue for chronic exposure = 0.000329 TRR: PCNB = 13 ( potato metabolism study)

Broccoli Chronic point estimate was calculated based on TRR from cabbage metabolism study ( 17.9 ppm) and % CT ( 1%); i. e.,

17.9 X 1% = 0.179 ppm ; See text for mor information. 1% Estimated residue for chronic exposure = 0.179 ppm Table 2.5  Summary of Residue Data for Different Commodities Commodity Data Range of De t e c t s ( ppm) Details of files used to derive the chronic point estimate. % CT Chronic Point estimate ( ppm);

Ratio used to estimate the total TRR Data Source Sampling D a t e ( year) Number of Samples Number of Detects Number of Data Number of Detects Number of ½ LOD Number of Zeroes Average ½ LOD ( ppm)

18 Brussels Sprout Chronic point estimate was calculated based on TRR from cabbage metabolism study ( 17.9 ppm) and % CT ( 13%); i. e.,

17.9 X 13% = 2.33 ppm ; See text for more information. 13% Estimated residue for chronic exposure = 2.33 ppm Cabbage Chronic point estimate was calculated based on TRR from cabbage metabolism study ( 17.9 ppm) and % CT ( 1%); i. e.,

17.9 X 1% = 0.179 ppm ; See text for more information. 1% Estimated residue for chronic exposure = 0.179 ppm Cauliflower Chronic point estimate was calculated based on TRR from cabbage metabolism study ( 17.9 ppm) and % CT ( 2%); i. e.,

17.9 X 2% = 0.36 ppm ; See text for more information. 2% Estimated residue for chronic exposure = 0.36 ppm Chinese Broccoli Chronic point estimate was calculated based on TRR from cabbage metabolism study ( 17.9 ppm) and % CT ( 1%); i. e.,

17.9 X 1% = 0.179 ppm ; See text for more information. 1% Estimated residue for chronic exposure = 0.179 ppm Chinese Cabbage Chronic point estimate was calculated based on TRR from cabbage metabolism study ( 17.9 ppm) and % CT ( 1%); i. e.,

17.9 X 1% = 0.179 ppm ; See text for more information. 1% Estimated residue for chronic exposure = 0.179 ppm Table 2.5  Summary of Residue Data for Different Commodities Commodity Data Range of De t e c t s ( ppm) Details of files used to derive the chronic point estimate. % CT Chronic Point estimate ( ppm);

Ratio used to estimate the total TRR Data Source Sampling D a t e ( year) Number of Samples Number of Detects Number of Data Number of Detects Number of ½ LOD Number of Zeroes Average ½ LOD ( ppm)

19 Collards Chronic point estimate was calculated based on TRR from cabbage metabolism study ( 17.9 ppm) and % CT ( 1%); i. e.,

17.9 X 1% = 0.179 ppm ; See text for more information. 1% Estimated residue for chronic exposure = 0.179 ppm Cotton ( cottonseed oil) Chronic point estimate was calculated based on TRR from peanut hay metabolism study for ( 16.3 ppm), adjusted for use rate difference between cotton and peanut, and % CT ( 5%); i. e.,

[( 16.3 / 10) X 2.1] X 5% = 0.165 ppm ; See text for more information. 5% Estimated residue for chronic exposure = 0.165s ppm Garlic Chronic point estimate was calculated based on TRR from peanut hay metabolism study ( 16.3 ppm), adjusted for use rate difference between garlic and peanut, and % CT ( 1%); i. e.,

( 16.3 X 2) X 1% = 0.33 ppm ; See text for more information. 1% Estimated residue for chronic exposure = 0.33 ppm Kale Chronic point estimate was calculated based on TRR from cabbage metabolism study ( 17.9 ppm) and % CT ( 1%); i. e.,

17.9 X 1% = 0.179 ppm ; See text for more information. 1% Estimated residue for chronic exposure = 0.179 ppm Table 2.5  Summary of Residue Data for Different Commodities Commodity Data Range of De t e c t s ( ppm) Details of files used to derive the chronic point estimate. % CT Chronic Point estimate ( ppm);

Ratio used to estimate the total TRR Data Source Sampling D a t e ( year) Number of Samples Number of Detects Number of Data Number of Detects Number of ½ LOD Number of Zeroes Average ½ LOD ( ppm)

20 Mustard Green Chronic point estimate was calculated based on TRR from cabbage metabolism study ( 17.9 ppm) and % CT ( 1%); i. e.,

17.9 X 1% = 0.179 ppm ; See text for more information. 1% Estimated residue for chronic exposure = 0.179 ppm Peppers, Hot PDP for sweet pepper 2000,

2002 924 0   100 0 3 97 0.002084 3% Estimated residue for chronic exposure = 0.000813 TRR: PCNB = 13 ( potato metabolism study)

Peppers, Sweet PDP for sweet pepper 2000,

2002 924 0   100 0 1 99 0.002084 1% Estimated residue for chronic exposure = 0.000271 TRR: PCNB = 13 ( potato metabolism study) Table 2.5  Summary of Residue Data for Different Commodities Commodity Data Range of De t e c t s ( ppm) Details of files used to derive the chronic point estimate. % CT Chronic Point estimate ( ppm);

Ratio used to estimate the total TRR Data Source Sampling D a t e ( year) Number of Samples Number of Detects Number of Data Number of Detects Number of ½ LOD Number of Zeroes Average ½ LOD ( ppm)

21 Peanuts Chronic point estimate was calculated based on TRR from peanut metabolism study for nutmeat ( 1.72 ppm), adjusted for 1X rate ( reduce by factor 5), and % CT ( 1%); i. e.,

( 1.72 / 5) X 1% = 0.0034 ppm ; See text for more information.

Concentration factor for peanut oil= 2.1 X 1% Estimated residue for chronic exposure = 0.0034 Peanut Butter Peanut Butter: Chronic point estimate was calculated based on average of all 2000 PDP data ( 716 samples) after adding PCNB and PCA on same samples and using TRR:( PCNB+ PCA) ratio from peanut nutmeat metabolism study ( 5.3);

0.00092 ppm X 5.3 = 0.0049 ppm Estimated residue for chronic exposure =

0.0049 Table 2.5  Summary of Residue Data for Different Commodities Commodity Data Range of De t e c t s ( ppm) Details of files used to derive the chronic point estimate. % CT Chronic Point estimate ( ppm);

Ratio used to estimate the total TRR Data Source Sampling D a t e ( year) Number of Samples Number of Detects Number of Data Number of Detects Number of ½ LOD Number of Zeroes Average ½ LOD ( ppm)

22 Potato PDP 2001,

2002 1103 17 0.005 0.05 1103 17 16 1070 0.0019 3% Estimated residue for chronic exposure = 0.00335 TRR: PCNB = 13 ( potato metabolism study)

Concentration factor = 5.4 for " ptotato w/ peel baby food"

Tomato, Fresh PDP 1998,

1999 1081 2 0.005 1081 2 9 1070 0.0019 1% Estimated residue for chronic exposure = 0.000330 TRR: PCNB = 13 ( po t a to metabolism study)

Concentration factor: 14.3 for dried tomato.

Tomato, Canned PDP 1999,

2000 737 0   100 0 1 99 0.0017 1% Estimated residue for chronic exposure = 0.000216 TRR: PCNB = 13 ( potato metabolism study) Table 2.5  Summary of Residue Data for Different Commodities Commodity Data Range of De t e c t s ( ppm) Details of files used to derive the chronic point estimate. % CT Chronic Point estimate ( ppm);

Ratio used to estimate the total TRR Data Source Sampling D a t e ( year) Number of Samples Number of Detects Number of Data Number of Detects Number of ½ LOD Number of Zeroes Average ½ LOD ( ppm)

23 Tomato, Paste PDP 2001 369 0 0 100 0 1 99 0.0015 1% Estimated residue for chronic exposure = 0.000195 TRR: PCNB = 13 ( potato metabolism study)

IIIa. DEEM FCID   Program and Consumption Information PCNB chronic dietary exposure assessments were conducted using the Dietary Exposure Evaluation Model software with the Food Commodity Intake Database ( DEEM FCID   , Version 1.30), which incorporates consumption data from USDA's Continuing Surveys of Food Intakes by Individuals ( CSFII), 1994 1996 and 1998. The 1994 96, 98 data are based on the reported consumption of more than 20,000 individuals over two non consecutive survey days. Foods " as consumed" ( e. g., apple pie) are linked to EPA defined food commodities ( e. g. apples, peeled fruit  cooked; fresh or N/ S; baked; or wheat flour  cooked; fresh or N/ S, baked) using publicly available recipe translation files developed jointly by USDA/ ARS and EPA. For chronic exposure assessment, consumption data are averaged for the entire U. S. population and within population subgroups, but for acute exposure assessment are retained as individual consumption events. Based on analysis of the 1994 96, 98 CSFII consumption data, which took into account dietary patterns and survey respondents, HED concluded that it is most appropriate to report risk for the following population subgroups: the general U. S. 24 population, all infants (< 1 year old), children 1 2, children 3 5, children 6 12, youth 13 19, adults 20 49, females 13 49, and adults 50+ years old.

For chronic dietary exposure assessment, an estimate of the residue level in each food or food form ( e. g., orange or orange juice) on the food commodity residue list is multiplied by the average daily consumption estimate for that food/ food form. The resulting residue consumption estimate for each food/ food form is summed with the residue consumption estimates for all other food/ food forms on the commodity residue list to arrive at the total average estimated exposure. Exposure is expressed in mg/ kg body weight/ day and as a percent of the cPAD. This procedure is performed for each population subgroup.

III b. Lifeline   Program and Consumption Information Chronic dietary exposure estimates were also conducted using the Lifeline   model ( Version 2.0). These Lifeline   assessments were also conducted using the same consumption data as the DEEMFCID   ( CSFII, 1994 1996 and 1998 consumption data with FCID). Lifeline   uses the recipe file to relate RACs to foods " as eaten." Lifeline   converts the RAC residues into food residues by randomly selecting a RAC residue value from the " user defined" residue distribution ( created from the residue, percent crop treated, and processing factors data), and calculating a net residue for that food based on the ingredients' mass contribution to that food item. For example, ` apple pie' will have a residue distribution based on the residues provided for apples ( adjusted by the appropriate processing factors and percent crop treated), as well as the residues for each of the other ingredients in the apple pie recipe for which there may be tolerances. Lifeline   calculates dietary exposure from ` apple pie' based on the amount eaten, and the residue drawn from the ` apple pie' residue distribution for that eating occasion.

Lifeline   models the individual's dietary exposures over a season by selecting a new CSFII diary each day from a set of similar individuals based on age, season and socioeconomic attributes. Lifeline   groups CSFII diaries based on the respondents' age and the season during which the food diary was recorded. Further information regarding the Lifeline   model can be found at the following web site: www. theLifeline   group. org.

IV. Toxicological Information Since the HIARC has completed it review, a copy of the committee report is appended. A summary of toxicology endpoints are presented below. 25 Table 3.1: Summary of Toxicological Dose and Endpoints for PCNB Exposure Scenario Dose Used in Risk Assessment, UF Special FQPA SF* and Level of Concern for Risk Assessment Study and Toxicological Effects Acute Dietary ( All populations) N/ A N/ A None selected Chronic Dietary ( All populations) NOAEL= 1.0 mg/ kg/ day UF = 1000 Chronic RfD = 0.001 mg/ kg/ day FQPA SF = 1X cPAD = chronic RfD FQPA SF = 0.001 mg/ kg/ day Chronic/ Oncogenicity Study  rat LOAEL = 150 mg/ kg/ day based on hepatocelluar hypertrophy, hepatocellular hyperplasia, and thyroid hypertrophy Cancer ( oral, dermal, inhalation) HED's Carcinogenicity Peer Review Committee ( CARC) classified PCNB as a Group C  possible human carcinogen and recommended that for the purpose of risk characterization, the Reference Dose approach should be used for quantification of human risk.

UF = uncertainty factor, FQPA SF = Special FQPA safety factor, NOAEL = no observed adverse effect level, LOAEL = lowest observed adverse effect level, PAD = population adjusted dose ( a = acute, c = chronic) RfD = reference dose, MOE = margin of exposure, LOC = level of concern, NA = Not Applicable NOTE: The Special FQPA Safety Factor recommended by the HIARC assumes that the exposure databases ( dietary food, drinking water, and residential) are complete and that the risk assessment for each potential exposure scenario includes all metabolites and/ or degradates of concern and does not underestimate the potential risk for infants and children.

V. Results/ Discussion As stated above, for dietary risk assessments, HED is concerned when dietary risk exceeds 100% of the PAD. The DEEM FCID   analyses estimate the dietary exposure of the U. S. population and various population subgroups. The results reported in Table 5.1 are for the general U. S. Population, all infants (< 1 year old), children 1 2, children 3 5, children 6 12, youth 13 19, females 13 49, adults 20 49, and adults 50+ years.

Chronic dietary risks was also estimated using the Lifeline   model ( version 2.0). The Lifeline   chronic dietary exposure estimate is based on an average daily exposure from a profile of 1000 individuals over a one year period. Results of the Lifeline   analysis are fully consistent with DEEM FCID   results. 26 Table 5.1 Result of Chronic Dietary Exposure and Risk Estimates for PCNB.

Population Subgroup PAD,

mg/ kg / day Risk from all crops ( no water) Risk from registered crops ( no water) Risk from all crops Including risk from water DEEM FCID Lifeline DEEM FCID Lifeline DEEM FCID Exposure,

mg/ kg/ day % cPAD Exposure,

mg/ kg/ day % cPAD Exposure,

mg/ kg/ day % cPAD Exposure,

mg/ kg/ day % cPAD Exposure,

mg/ kg/ day % cPAD U. S. Population 0.001 0.000121 12% 0.000252 25% 0.000102 10% 0.000229 23% 0.001052 105%

All infants (< 1 yr) 0.001 0.000072 7% .00002 2% 0.000057 6% 0.000014 1% 0.003126 313%

Children 1 2 yrs 0.001 0.000345 34% 0.000331 33% 0.000269 27% 0.000276 28% 0.001729 173%

Children 3 5 yrs 0.001 0.000254 25% 0.000199 20% 0.000199 20% 0.000145 14% 0.001549 155%

Children 6 12 yrs 0.001 0.000161 16% 0.00013 13% 0.000128 13% 0.000093 9% 0.001054 105%

Youth 13 19 yrs 0.001 0.000104 10% 0.000092 9% 0.000086 9% 0.000066 7% 0.000777 78%

Adults 20 49 yrs 0.001 0.000097 10% 0.000263 26% 0.000084 8% 0.000244 24% 0.000967 97%

Adults 50+ yrs 0.001 0.000104 10% 0.000303 30% 0.000094 9% 0.000286 29% 0.001019 102%

Females 13 49 yrs 0.001 0.000096 10% 0.000261 26% 0.000083 8% 0.000236 24% 0.000962 96%

1. " Risk from all crops" indicates the risk from oral consumption of residues found in the food chain at present time, whether from registered or unregistered crops ( for details see discussion under residue section).

2. " Risk from registered crops" indicates the risk from oral consumption of residues found only on registered crops.

As it is seen from the results, for the chronic dietary risk without inclusion of contribution from water, show that the risk for all population subgroups are below the level of concern; i. e., 100% cPAD. For the chronic dietary risk due to all crops, i. e., both registered and unregistered crops, the general U. S. population had 12% cPAD and population subgroup children 1 2 years old had the highest estimated risk of 34% cPAD. For the chronic dietary risk due to registered crops, the general U. S. population had 10% cPAD and population subgroup children 1 2 years old had the highest estimated risk of 27% cPAD.

When water was added to the analysis, % cPAD exceeded 100% for all populations except youth 13 19 with % cPAD of 78% and adults 20 49 with % cPAD of 97%; all other population subgroups exceeded the 100% cPAD mark and thus are of concern. The estimated risk including water for general U. S. population is 105% cPAD and the highest estimated risk is for population subgroup all infants with the 27 313% cPAD.

The estimated chronic dietary risk when water was included in the assessment shows that contribution from water to the risk is quite high and results in almost all the population subgroups exceed or come close to the 100% cPAD mark.

VI. Characterization of Inputs/ Outputs In this chronic dietary risk assessment, the major portion of uncertainties is in the residue estimates; however, they are not believed to be all biased to one side, i. e., all toward underestimating or all toward overestimating the risk. In particular, using TRR: PCNB ratios from the metabolism study in combination with PCNB residues from the monitoring data and use of absolute TRR values from cabbage metabolism study to estimate TTR for brassica vegetables can be major sources of uncertainties. In addition, uncertainties in calculation of secondary residues can be significant. These have been thoroughly discussed under section II.

Despite the non existence of monitoring residue data on all PCNB metabolites and incomplete metabolism study of cabbage, this risk assessment is still considered highly refined because it includes all available residue information, % CT and processing factor information. Future refinement of this risk assessment would only be possible if monitoring programs like USDA PDP use validated common moiety methods for detection of PCNB and all its metabolites in supported and unsupported commodities.

VII. Conclusions The results of these chronic dietary risk assessments show that the risk for all population subgroups are below the level of concern; i. e., 100% cPAD. For the chronic dietary risk due to all crops, i. e., both registered and unregistered crops, the general U. S. population had 12% cPAD and population subgroup children 1 2 years old had the highest estimated risk of 34% cPAD. For the chronic dietary risk due to registered crops, the general U. S. population had 10% cPAD and population subgroup children 1 2 years old had the highest estimated risk of 27% cPAD.

When water was added to the analysis, % cPAD exceeded 100% for all populations except youth 13 19 with % cPAD of 78% and adults 20 49 with % cPAD of 97%; all other population subgroups exceeded the 100% cPAD mark and thus are of concern. The estimated risk including water for general U. S. population is 105% cPAD and the highest estimated risk is for population subgroup all infants with the 313% cPAD.

The chronic dietary risk estimates reported in this memorandum may change should the 2004 PDP monitoring data on milk samples ( unavailable yet) indicate higher levels of PCNB and its metabolites than what was assumed in this assessment. Furthermore, a confirmatory study on ruminant metabolism study may be required ( to be addressed in the upcoming RED), the results of which may 28 trigger a need to update this dietary risk assessment.

VIII. List of Attachments Attachment 1: DEEM output file ( results) for PCNB chronic dietary assessment for the registered crops ( water not included).

Attachment 2: DEEM output file ( results) for PCNB chronic dietary assessment for the registered crops ( water included).

Attachment 3: DEEM output file ( results) for PCNB chronic dietary assessment for all crops ( registered and unregistered) with detected residues of PCNB ( water not included).

Attachment 4: DEEM output file ( results) for PCNB chronic dietary assessment for all crops ( registered and unregistered) with detected residues of PCNB ( water included).

Attachment 5: DEEM input file ( i. e., the food list) for chronic dietary assessment for the registered crops ( water not included).

Attachment 6: DEEM input file ( i. e., the food list) for chronic dietary assessment for all crops ( registered and unregistered) with detected residues of PCNB ( water not included).

Attachment 7: DEEM input file ( i. e., the food list) for chronic dietary assessment for all crops ( registered and unregistered) with detected residues of PCNB ( water included).

Attachment 8: LifeLine input file ( i. e., the residue input for each food) for chronic dietary assessment for all crops ( registered and unregistered) ( water not included).

Attachment 9: Percent crop treated numbers from BEAD cc: Mohsen Sahafeyan ( HED), David Soderberg, Thomas Bloem ( DESAC Reviewers) 29 Attachment 1: DEEM output file ( results) for PCNB chronic dietary assessment for all the registered crops ( water not included).

U. S. Environmental Protection Agency Ver. 1.30 DEEM FCID Chronic analysis for PCNB ( 1994 98 data) Residue file name: C:\ msahafeyan\ 0 Mohsen\ Reviews\ Primary Reviews\ PCNB\ DEEM PCNB\ PCNB NoWater RegCrops 032704. R98 Adjustment factor # 2 NOT used. Analysis Date 03 27 2004/ 14: 27: 24 Residue file dated: 03 27 2004/ 14: 19: 49/ 8 Reference dose ( RfD, Chronic) = .001 mg/ kg bw/ day =============================================================================== Total exposure by population subgroup

Total Exposure  Population mg/ kg Percent of Subgroup body wt/ day Rfd    U. S. Population ( total) 0.000102 10.2%

U. S. Population ( spring season) 0.000101 10.1% U. S. Population ( summer season) 0.000103 10.3% U. S. Population ( autumn season) 0.000102 10.2% U. S. Population ( winter season) 0.000103 10.3%

Northeast region 0.000103 10.3% Midwest region 0.000101 10.1% Southern region 0.000098 9.8% Western region 0.000110 11.0%

Hispanics 0.000091 9.1% Non hispanic whites 0.000098 9.8% Non hispanic blacks 0.000123 12.3% Non hisp/ non white/ non black 0.000141 14.1%

All infants (< 1 year) 0.000057 5.7% Nursing infants 0.000023 2.3% Non nursing infants 0.000070 7.0% Children 1 6 yrs 0.000216 21.6% Children 7 12 yrs 0.000121 12.1%

Females 13 19 ( not preg or nursing) 0.000077 7.7% Females 20+ ( not preg or nursing) 0.000089 8.9% Females 13 50 yrs 0.000086 8.6% Females 13+ ( preg/ not nursing) 0.000064 6.4% Females 13+ ( nursing) 0.000091 9.1%

Males 13 19 yrs 0.000094 9.4% Males 20+ yrs 0.000087 8.7% Seniors 55+ 0.000093 9.3%

Children 1 2 yrs 0.000269 26.9% Children 3 5 yrs 0.000199 19.9% Children 6 12 yrs 0.000128 12.8% Youth 13 19 yrs 0.000086 8.6% Adults 20 49 yrs 0.000084 8.4% Adults 50+ yrs 0.000094 9.4% Females 13 49 yrs 0.000083 8.3% 30 Attachment 2: DEEM output file ( results) for PCNB chronic dietary assessment for all the registered crops ( water included).

U. S. Environmental Protection Agency Ver. 1.30 DEEM FCID Chronic analysis for PCNB ( 1994 98 data) Residue file name: C:\ msahafeyan\ 0 Mohsen\ Reviews\ Primary Reviews\ PCNB\ DEEM PCNB\ PCNB WaterIncluded RegCrops 032704. R98 Adjustment factor # 2 NOT used. Analysis Date 03 27 2004/ 14: 29: 36 Residue file dated: 03 27 2004/ 14: 21: 00/ 8 Reference dose ( RfD, Chronic) = .001 mg/ kg bw/ day =============================================================================== Total exposure by population subgroup

Total Exposure  Population mg/ kg Percent of Subgroup body wt/ day Rfd    U. S. Population ( total) 0.001034 103.4%

U. S. Population ( spring season) 0.001024 102.4% U. S. Population ( summer season) 0.001104 110.4% U. S. Population ( autumn season) 0.001002 100.2% U. S. Population ( winter season) 0.001003 100.3%

Northeast region 0.000953 95.3% Midwest region 0.001043 104.3% Southern region 0.000983 98.3% Western region 0.001177 117.7%

Hispanics 0.001149 114.9% Non hispanic whites 0.001007 100.7% Non hispanic blacks 0.001007 100.7% Non hisp/ non white/ non black 0.001283 128.3%

All infants (< 1 year) 0.003112 311.2% Nursing infants 0.001156 115.6% Non nursing infants 0.003854 385.4% Children 1 6 yrs 0.001518 151.8% Children 7 12 yrs 0.000968 96.8%

Females 13 19 ( not preg or nursing) 0.000732 73.2% Females 20+ ( not preg or nursing) 0.001019 101.9% Females 13 50 yrs 0.000987 98.7% Females 13+ ( preg/ not nursing) 0.000970 97.0% Females 13+ ( nursing) 0.001382 138.2%

Males 13 19 yrs 0.000780 78.0% Males 20+ yrs 0.000922 92.2% Seniors 55+ 0.001007 100.7%

Children 1 2 yrs 0.001652 165.2% Children 3 5 yrs 0.001494 149.4% Children 6 12 yrs 0.001021 102.1% Youth 13 19 yrs 0.000759 75.9% Adults 20 49 yrs 0.000954 95.4% Adults 50+ yrs 0.001009 100.9% Females 13 49 yrs 0.000950 95.0% 31 Attachment 3: DEEM output file ( results) for PCNB chronic dietary assessment for all crops ( registered and unregistered) with detected residues of PCNB ( water not included).

U. S. Environmental Protection Agency Ver. 1.30 DEEM FCID Chronic analysis for PCNB ( 1994 98 data) Residue file name: C:\ msahafeyan\ 0 Mohsen\ Reviews\ Primary Reviews\ PCNB\ DEEM PCNB\ PCNB NoWater AllCrops 032704. R98 Adjustment factor # 2 NOT used. Analysis Date 03 27 2004/ 14: 30: 34 Residue file dated: 03 27 2004/ 14: 22: 24/ 8 Reference dose ( RfD, Chronic) = .001 mg/ kg bw/ day =============================================================================== Total exposure by population subgroup

Total Exposure  Population mg/ kg Percent of Subgroup body wt/ day Rfd    U. S. Population ( total) 0.000121 12.1%

U. S. Population ( spring season) 0.000120 12.0% U. S. Population ( summer season) 0.000122 12.2% U. S. Population ( autumn season) 0.000121 12.1% U. S. Population ( winter season) 0.000121 12.1%

Northeast region 0.000124 12.4% Midwest region 0.000120 12.0% Southern region 0.000115 11.5% Western region 0.000129 12.9%

Hispanics 0.000114 11.4% Non hispanic whites 0.000116 11.6% Non hispanic blacks 0.000142 14.2% Non hisp/ non white/ non black 0.000159 15.9%

All infants (< 1 year) 0.000072 7.2% Nursing infants 0.000027 2.7% Non nursing infants 0.000089 8.9% Children 1 6 yrs 0.000277 27.7% Children 7 12 yrs 0.000152 15.2%

Females 13 19 ( not preg or nursing) 0.000092 9.2% Females 20+ ( not preg or nursing) 0.000099 9.9% Females 13 50 yrs 0.000099 9.9% Females 13+ ( preg/ not nursing) 0.000081 8.1% Females 13+ ( nursing) 0.000107 10.7%

Males 13 19 yrs 0.000114 11.4% Males 20+ yrs 0.000100 10.0% Seniors 55+ 0.000103 10.3%

Children 1 2 yrs 0.000345 34.5% Children 3 5 yrs 0.000254 25.4% Children 6 12 yrs 0.000161 16.1% Youth 13 19 yrs 0.000104 10.4% Adults 20 49 yrs 0.000097 9.7% Adults 50+ yrs 0.000104 10.4% Females 13 49 yrs 0.000096 9.6%

 32 Attachment 4: DEEM output file ( results) for PCNB chronic dietary assessment for all crops ( registered and unregistered) with detected residues of PCNB ( water included).

U. S. Environmental Protection Agency Ver. 1.30 DEEM FCID Chronic analysis for PCNB ( 1994 98 data) Residue file name: C:\ msahafeyan\ 0 Mohsen\ Reviews\ Primary Reviews\ PCNB\ DEEM PCNB\ PCNB WaterIncluded AllCrops 032704. R98 Adjustment factor # 2 NOT used. Analysis Date 03 27 2004/ 14: 35: 53 Residue file dated: 03 27 2004/ 14: 23: 49/ 8 Reference dose ( RfD, Chronic) = .001 mg/ kg bw/ day =============================================================================== Total exposure by population subgroup

Total Exposure  Population mg/ kg Percent of Subgroup body wt/ day Rfd    U. S. Population ( total) 0.001052 105.2%

U. S. Population ( spring season) 0.001043 104.3% U. S. Population ( summer season) 0.001122 112.2% U. S. Population ( autumn season) 0.001021 102.1% U. S. Population ( winter season) 0.001022 102.2%

Northeast region 0.000974 97.4% Midwest region 0.001062 106.2% Southern region 0.001000 100.0% Western region 0.001196 119.6%

Hispanics 0.001171 117.1% Non hispanic whites 0.001025 102.5% Non hispanic blacks 0.001026 102.6% Non hisp/ non white/ non black 0.001301 130.1%

All infants (< 1 year) 0.003126 312.6% Nursing infants 0.001160 116.0% Non nursing infants 0.003873 387.3% Children 1 6 yrs 0.001578 157.8% Children 7 12 yrs 0.000998 99.8%

Females 13 19 ( not preg or nursing) 0.000747 74.7% Females 20+ ( not preg or nursing) 0.001029 102.9% Females 13 50 yrs 0.001001 100.1% Females 13+ ( preg/ not nursing) 0.000987 98.7% Females 13+ ( nursing) 0.001398 139.8%

Males 13 19 yrs 0.000800 80.0% Males 20+ yrs 0.000935 93.5% Seniors 55+ 0.001017 101.7%

Children 1 2 yrs 0.001729 172.9% Children 3 5 yrs 0.001549 154.9% Children 6 12 yrs 0.001054 105.4% Youth 13 19 yrs 0.000777 77.7% Adults 20 49 yrs 0.000967 96.7% Adults 50+ yrs 0.001019 101.9% Females 13 49 yrs 0.000962 96.2%

 33 Attachment 5: DEEM input file ( i. e., the food list) for chronic dietary assessment for all the registered crops.

Filename: C:\ msahafeyan\ 0 Mohsen\ Reviews\ Primary Reviews\ PCNB\ DEEM PCNB\ PCNB NoWater RegCrops 032704. R98 Chemical: PCNB RfD( Chronic): .001 mg/ kg bw/ day NOEL( Chronic): 0 mg/ kg bw/ day RfD( Acute): 0 mg/ kg bw/ day NOEL( Acute): 0 mg/ kg bw/ day Date created/ last modified: 03 27 2004/ 14: 19: 49/ 8 Program ver. 1.30  EPA Crop Def Res Adj. Factors Comment Code Grp Commodity Name ( ppm) # 1 # 2        06030300 6C Bean, black, seed 210 Cooked; Fresh or N/ S; Cook Meth N/ S 0.003480 1.000 1.000 212 Cooked; Fresh or N/ S; Boiled 0.003480 1.000 1.000 230 Cooked; Dried; Cook Meth N/ S 0.003480 1.000 1.000 232 Cooked; Dried; Boiled 0.003480 1.000 1.000 242 Cooked; Canned; Boiled 0.000548 1.000 1.000 06020310 6B Bean, broad, succulent 0.003480 1.000 1.000 06030320 6C Bean, broad, seed 230 Cooked; Dried; Cook Meth N/ S 0.003480 1.000 1.000 232 Cooked; Dried; Boiled 0.003480 1.000 1.000 06020330 6B Bean, cowpea, succulent 212 Cooked; Fresh or N/ S; Boiled 0.003480 1.000 1.000 222 Cooked; Frozen; Boiled 0.000329 1.000 1.000 242 Cooked; Canned; Boiled 0.000548 1.000 1.000 06030340 6C Bean, cowpea, seed 210 Cooked; Fresh or N/ S; Cook Meth N/ S 0.003480 1.000 1.000 212 Cooked; Fresh or N/ S; Boiled 0.003480 1.000 1.000 232 Cooked; Dried; Boiled 0.003480 1.000 1.000 06030350 6C Bean, great northern, seed 210 Cooked; Fresh or N/ S; Cook Meth N/ S 0.003480 1.000 1.000 212 Cooked; Fresh or N/ S; Boiled 0.003480 1.000 1.000 230 Cooked; Dried; Cook Meth N/ S 0.003480 1.000 1.000 232 Cooked; Dried; Boiled 0.003480 1.000 1.000 242 Cooked; Canned; Boiled 0.000548 1.000 1.000 06030360 6C Bean, kidney, seed 210 Cooked; Fresh or N/ S; Cook Meth N/ S 0.003480 1.000 1.000 211 Cooked; Fresh or N/ S; Baked 0.003480 1.000 1.000 212 Cooked; Fresh or N/ S; Boiled 0.003480 1.000 1.000 213 Cooked; Fresh or N/ S; Fried 0.003480 1.000 1.000 221 Cooked; Frozen; Baked 0.000329 1.000 1.000 232 Cooked; Dried; Boiled 0.003480 1.000 1.000 240 Cooked; Canned; Cook Meth N/ S 34 0.000548 1.000 1.000 242 Cooked; Canned; Boiled 0.000548 1.000 1.000 06020370 6B Bean, lima, succulent 210 Cooked; Fresh or N/ S; Cook Meth N/ S 0.003480 1.000 1.000 212 Cooked; Fresh or N/ S; Boiled 0.003480 1.000 1.000 213 Cooked; Fresh or N/ S; Fried 0.003480 1.000 1.000 221 Cooked; Frozen; Baked 0.000329 1.000 1.000 222 Cooked; Frozen; Boiled 0.000329 1.000 1.000 240 Cooked; Canned; Cook Meth N/ S 0.000548 1.000 1.000 242 Cooked; Canned; Boiled 0.000548 1.000 1.000 06030380 6C Bean, lima, seed 210 Cooked; Fresh or N/ S; Cook Meth N/ S 0.003480 1.000 1.000 230 Cooked; Dried; Cook Meth N/ S 0.003480 1.000 1.000 232 Cooked; Dried; Boiled 0.003480 1.000 1.000 06030390 6C Bean, mung, seed 110 Uncooked; Fresh or N/ S; Cook Meth N/ S 0.003480 1.000 1.000 210 Cooked; Fresh or N/ S; Cook Meth N/ S 0.003480 1.000 1.000 211 Cooked; Fresh or N/ S; Baked 0.003480 1.000 1.000 212 Cooked; Fresh or N/ S; Boiled 0.003480 1.000 1.000 213 Cooked; Fresh or N/ S; Fried 0.003480 1.000 1.000 221 Cooked; Frozen; Baked 0.000329 1.000 1.000 232 Cooked; Dried; Boiled 0.003480 1.000 1.000 233 Cooked; Dried; Fried 0.003480 1.000 1.000 240 Cooked; Canned; Cook Meth N/ S 0.000548 1.000 1.000 06030400 6C Bean, navy, seed 210 Cooked; Fresh or N/ S; Cook Meth N/ S 0.003480 1.000 1.000 212 Cooked; Fresh or N/ S; Boiled 0.003480 1.000 1.000 230 Cooked; Dried; Cook Meth N/ S 0.003480 1.000 1.000 232 Cooked; Dried; Boiled 0.003480 1.000 1.000 242 Cooked; Canned; Boiled 0.000548 1.000 1.000 06030410 6C Bean, pink, seed 210 Cooked; Fresh or N/ S; Cook Meth N/ S 0.003480 1.000 1.000 212 Cooked; Fresh or N/ S; Boiled 0.003480 1.000 1.000 232 Cooked; Dried; Boiled 0.003480 1.000 1.000 06030420 6C Bean, pinto, seed 210 Cooked; Fresh or N/ S; Cook Meth N/ S 0.003480 1.000 1.000 211 Cooked; Fresh or N/ S; Baked 0.003480 1.000 1.000 212 Cooked; Fresh or N/ S; Boiled 0.003480 1.000 1.000 213 Cooked; Fresh or N/ S; Fried 0.003480 1.000 1.000 221 Cooked; Frozen; Baked 0.000329 1.000 1.000 230 Cooked; Dried; Cook Meth N/ S 0.003480 1.000 1.000 232 Cooked; Dried; Boiled 0.003480 1.000 1.000 06010430 6A Bean, snap, succulent 110 Uncooked; Fresh or N/ S; Cook Meth N/ S 0.003480 1.000 1.000 210 Cooked; Fresh or N/ S; Cook Meth N/ S 0.003480 1.000 1.000 211 Cooked; Fresh or N/ S; Baked 0.003480 1.000 1.000 212 Cooked; Fresh or N/ S; Boiled 35 0.003480 1.000 1.000 213 Cooked; Fresh or N/ S; Fried 0.003480 1.000 1.000 215 Cooked; Fresh or N/ S; Boiled/ baked 0.003480 1.000 1.000 221 Cooked; Frozen; Baked 0.000329 1.000 1.000 222 Cooked; Frozen; Boiled 0.000329 1.000 1.000 232 Cooked; Dried; Boiled 0.003480 1.000 1.000 240 Cooked; Canned; Cook Meth N/ S 0.000548 1.000 1.000 242 Cooked; Canned; Boiled 0.000548 1.000 1.000 06010431 6A Bean, snap, succulent babyfood 240 Cooked; Canned; Cook Meth N/ S 0.000548 1.000 1.000 21000440 M Beef, meat 0.001000 1.000 1.000 21000441 M Beef, meat babyfood 0.001000 1.000 1.000 21000450 M Beef, meat, dried 0.001000 1.920 1.000 21000460 M Beef, meat byproducts 0.020000 1.000 1.000 21000461 M Beef, meat byproducts babyfood 0.020000 1.000 1.000 21000470 M Beef, fat 0.015000 1.000 1.000 21000471 M Beef, fat babyfood 0.015000 1.000 1.000 21000480 M Beef, kidney 0.020000 1.000 1.000 21000490 M Beef, liver 0.020000 1.000 1.000 21000491 M Beef, liver babyfood 0.020000 1.000 1.000 05010610 5A Broccoli 110 Uncooked; Fresh or N/ S; Cook Meth N/ S 0.179000 1.000 1.000 210 Cooked; Fresh or N/ S; Cook Meth N/ S 0.179000 1.000 1.000 211 Cooked; Fresh or N/ S; Baked 0.179000 1.000 1.000 212 Cooked; Fresh or N/ S; Boiled 0.179000 1.000 1.000 213 Cooked; Fresh or N/ S; Fried 0.179000 1.000 1.000 220 Cooked; Frozen; Cook Meth N/ S 0.179000 1.000 1.000 221 Cooked; Frozen; Baked 0.179000 1.000 1.000 222 Cooked; Frozen; Boiled 0.179000 1.000 1.000 232 Cooked; Dried; Boiled 0.179000 1.000 1.000 242 Cooked; Canned; Boiled 0.179000 1.000 1.000 05010611 5A Broccoli babyfood 0.179000 1.000 1.000 05010620 5A Broccoli, Chinese 0.179000 1.000 1.000 05010640 5A Brussels sprouts 2.330000 1.000 1.000 05010690 5A Cabbage 0.179000 1.000 1.000 05020700 5B Cabbage, Chinese, bok choy 0.179000 1.000 1.000 05010710 5A Cabbage, Chinese, napa 0.179000 1.000 1.000 05010720 5A Cabbage, Chinese, mustard 0.179000 1.000 1.000 05010830 5A Cauliflower 0.360000 1.000 1.000 40000930 P Chicken, meat 0.000001 1.000 1.000 40000931 P Chicken, meat babyfood 0.000001 1.000 1.000 40000940 P Chicken, liver 0.000020 1.000 1.000 40000950 P Chicken, meat byproducts 0.000020 1.000 1.000 40000951 P Chicken, meat byproducts babyfoo 0.000020 1.000 1.000 40000960 P Chicken, fat 0.000020 1.000 1.000 40000961 P Chicken, fat babyfood 0.000020 1.000 1.000 40000970 P Chicken, skin 0.000020 1.000 1.000 40000971 P Chicken, skin babyfood 0.000020 1.000 1.000 05021170 5B Collards 0.179000 1.000 1.000 95001280 O Cottonseed, oil 0.165000 1.000 1.000 95001281 O Cottonseed, oil babyfood 0.165000 1.000 1.000 70001450 P Egg, whole 0.000110 1.000 1.000 70001451 P Egg, whole babyfood 0.000110 1.000 1.000 70001460 P Egg, white 0.000110 1.000 1.000 70001461 P Egg, white ( solids) babyfood 0.000110 1.000 1.000 70001470 P Egg, yolk 0.000110 1.000 1.000 70001471 P Egg, yolk babyfood 0.000110 1.000 1.000 03001640 3 Garlic 0.330000 1.000 1.000 03001650 3 Garlic, dried 0.330000 1.000 1.000 03001651 3 Garlic, dried babyfood 0.330000 1.000 1.000 23001690 M Goat, meat 0.001000 1.000 1.000 23001700 M Goat, meat byproducts 0.020000 1.000 1.000 36 23001710 M Goat, fat 0.015000 1.000 1.000 23001720 M Goat, kidney 0.020000 1.000 1.000 23001730 M Goat, liver 0.020000 1.000 1.000 24001890 M Horse, meat 0.001000 1.000 1.000 05021940 5B Kale 0.179000 1.000 1.000 27002220 D Milk, fat 0.100000 1.000 1.000 27002221 D Milk, fat  baby food/ infant for 0.100000 1.000 1.000 05022290 5B Mustard greens 0.179000 1.000 1.000 95002630 O Peanut 0.003400 1.000 1.000 95002640 O Peanut, butter 0.004900 1.000 1.000 95002650 O Peanut, oil 0.003400 2.100 1.000 08002700 8 Pepper, bell 0.000271 1.000 1.000 08002701 8 Pepper, bell babyfood 0.000271 1.000 1.000 08002710 8 Pepper, bell, dried 0.000271 1.000 1.000 08002711 8 Pepper, bell, dried babyfood 0.000271 1.000 1.000 08002720 8 Pepper, nonbell 0.000813 1.000 1.000 08002721 8 Pepper, nonbell babyfood 0.000813 1.000 1.000 08002730 8 Pepper, nonbell, dried 0.000813 1.000 1.000 25002900 M Pork, meat 0.000060 1.000 1.000 25002901 M Pork, meat babyfood 0.000060 1.000 1.000 25002910 M Pork, skin 0.000060 1.000 1.000 25002920 M Pork, meat byproducts 0.001200 1.000 1.000 25002921 M Pork, meat byproducts babyfood 0.001200 1.000 1.000 25002930 M Pork, fat 0.000800 1.000 1.000 25002931 M Pork, fat babyfood 0.000800 1.000 1.000 25002940 M Pork, kidney 0.001200 1.000 1.000 25002950 M Pork, liver 0.001000 1.000 1.000 01032960 1C Potato, chips 0.003400 1.000 1.000 01032970 1C Potato, dry ( granules/ flakes) 0.003400 1.000 1.000 01032971 1C Potato, dry ( granules/ flakes) b 0.003400 1.000 1.000 01032980 1C Potato, flour 0.003400 1.000 1.000 01032981 1C Potato, flour babyfood 0.003400 1.000 1.000 01032990 1C Potato, tuber, w/ peel 210 Cooked; Fresh or N/ S; Cook Meth N/ S 0.003400 5.400 1.000 211 Cooked; Fresh or N/ S; Baked 0.003400 5.400 1.000 212 Cooked; Fresh or N/ S; Boiled 0.003400 5.400 1.000 213 Cooked; Fresh or N/ S; Fried 0.003400 5.400 1.000 01032991 1C Potato, tuber, w/ peel babyfood 0.003400 5.400 1.000 01033000 1C Potato, tuber, w/ o peel 0.003400 1.000 1.000 01033001 1C Potato, tuber, w/ o peel babyfood 0.003400 1.000 1.000 60003010 P Poultry, other, meat 0.000005 1.000 1.000 60003020 P Poultry, other, liver 0.000080 1.000 1.000 60003030 P Poultry, other, meat byproducts 0.000080 1.000 1.000 60003040 P Poultry, other, fat 0.000080 1.000 1.000 60003050 P Poultry, other, skin 0.000080 1.000 1.000 26003390 M Sheep, meat 0.001000 1.000 1.000 26003391 M Sheep, meat babyfood 0.001000 1.000 1.000 26003400 M Sheep, meat byproducts 0.020000 1.000 1.000 26003410 M Sheep, fat 0.020000 1.000 1.000 26003411 M Sheep, fat babyfood 0.020000 1.000 1.000 26003420 M Sheep, kidney 0.030000 1.000 1.000 26003430 M Sheep, liver 0.030000 1.000 1.000 08003750 8 Tomato 110 Uncooked; Fresh or N/ S; Cook Meth N/ S 0.000330 1.000 1.000 150 Uncooked; Cured etc; Cook Meth N/ S 0.000330 1.000 1.000 210 Cooked; Fresh or N/ S; Cook Meth N/ S 0.000330 1.000 1.000 211 Cooked; Fresh or N/ S; Baked 0.000330 1.000 1.000 212 Cooked; Fresh or N/ S; Boiled 0.000330 1.000 1.000 213 Cooked; Fresh or N/ S; Fried 0.000330 1.000 1.000 214 Cooked; Fresh or N/ S; Fried/ baked 0.000330 1.000 1.000 215 Cooked; Fresh or N/ S; Boiled/ baked 37 0.000330 1.000 1.000 221 Cooked; Frozen; Baked 0.000330 1.000 1.000 222 Cooked; Frozen; Boiled 0.000330 1.000 1.000 232 Cooked; Dried; Boiled 0.000330 14.300 1.000 240 Cooked; Canned; Cook Meth N/ S 0.000216 1.000 1.000 242 Cooked; Canned; Boiled 0.000216 1.000 1.000 252 Cooked; Cured etc; Boiled 0.000330 1.000 1.000 08003751 8 Tomato babyfood 240 Cooked; Canned; Cook Meth N/ S 0.000216 1.000 1.000 08003760 8 Tomato, paste 110 Uncooked; Fresh or N/ S; Cook Meth N/ S 0.000195 1.000 1.000 210 Cooked; Fresh or N/ S; Cook Meth N/ S 0.000195 1.000 1.000 211 Cooked; Fresh or N/ S; Baked 0.000195 1.000 1.000 212 Cooked; Fresh or N/ S; Boiled 0.000195 1.000 1.000 213 Cooked; Fresh or N/ S; Fried 0.000195 1.000 1.000 215 Cooked; Fresh or N/ S; Boiled/ baked 0.000195 1.000 1.000 221 Cooked; Frozen; Baked 0.000195 1.000 1.000 232 Cooked; Dried; Boiled 0.000195 1.000 1.000 240 Cooked; Canned; Cook Meth N/ S 0.000195 1.000 1.000 242 Cooked; Canned; Boiled 0.000195 1.000 1.000 08003761 8 Tomato, paste babyfood 240 Cooked; Canned; Cook Meth N/ S 0.000195 1.000 1.000 08003770 8 Tomato, puree 110 Uncooked; Fresh or N/ S; Cook Meth N/ S 0.000330 1.000 1.000 210 Cooked; Fresh or N/ S; Cook Meth N/ S 0.000330 1.000 1.000 211 Cooked; Fresh or N/ S; Baked 0.000330 1.000 1.000 212 Cooked; Fresh or N/ S; Boiled 0.000330 1.000 1.000 213 Cooked; Fresh or N/ S; Fried 0.000330 1.000 1.000 215 Cooked; Fresh or N/ S; Boiled/ baked 0.000330 1.000 1.000 221 Cooked; Frozen; Baked 0.000330 1.000 1.000 232 Cooked; Dried; Boiled 0.000330 1.000 1.000 240 Cooked; Canned; Cook Meth N/ S 0.000216 1.000 1.000 242 Cooked; Canned; Boiled 0.000216 1.000 1.000 252 Cooked; Cured etc; Boiled 0.000330 1.000 1.000 08003771 8 Tomato, puree babyfood 240 Cooked; Canned; Cook Meth N/ S 0.000216 1.000 1.000 08003780 8 Tomato, dried 110 Uncooked; Fresh or N/ S; Cook Meth N/ S 0.000330 14.300 1.000 130 Uncooked; Dried; Cook Meth N/ S 0.000330 14.300 1.000 210 Cooked; Fresh or N/ S; Cook Meth N/ S 0.000330 14.300 1.000 211 Cooked; Fresh or N/ S; Baked 0.000330 14.300 1.000 212 Cooked; Fresh or N/ S; Boiled 0.000330 14.300 1.000 214 Cooked; Fresh or N/ S; Fried/ baked 0.000330 14.300 1.000 215 Cooked; Fresh or N/ S; Boiled/ baked 0.000330 14.300 1.000 230 Cooked; Dried; Cook Meth N/ S 0.000330 14.300 1.000 231 Cooked; Dried; Baked 0.000330 14.300 1.000 38 232 Cooked; Dried; Boiled 0.000330 14.300 1.000 08003781 8 Tomato, dried babyfood 211 Cooked; Fresh or N/ S; Baked 0.000330 1.000 1.000 08003790 8 Tomato, juice 110 Uncooked; Fresh or N/ S; Cook Meth N/ S 0.000330 1.000 1.000 210 Cooked; Fresh or N/ S; Cook Meth N/ S 0.000330 1.000 1.000 211 Cooked; Fresh or N/ S; Baked 0.000330 1.000 1.000 212 Cooked; Fresh or N/ S; Boiled 0.000330 1.000 1.000 240 Cooked; Canned; Cook Meth N/ S 0.000216 1.000 1.000 242 Cooked; Canned; Boiled 0.000216 1.000 1.000 50003820 P Turkey, meat 0.000001 1.000 1.000 50003821 P Turkey, meat babyfood 0.000001 1.000 1.000 50003830 P Turkey, liver 0.000020 1.000 1.000 50003831 P Turkey, liver babyfood 0.000020 1.000 1.000 50003840 P Turkey, meat byproducts 0.000020 1.000 1.000 50003841 P Turkey, meat byproducts babyfood 0.000020 1.000 1.000 50003850 P Turkey, fat 0.000020 1.000 1.000 50003851 P Turkey, fat babyfood 0.000020 1.000 1.000 50003860 P Turkey, skin 0.000020 1.000 1.000 50003861 P Turkey, skin babyfood 0.000020 1.000 1.000 39 Attachment 6: DEEM input file ( i. e., the food list) for chronic dietary assessment for all crops ( registered and unregistered).

Filename: C:\ msahafeyan\ 0 Mohsen\ Reviews\ Primary Reviews\ PCNB\ DEEM PCNB\ PCNB NoWater AllCrops 032704. R98 Chemical: PCNB RfD( Chronic): .001 mg/ kg bw/ day NOEL( Chronic): 0 mg/ kg bw/ day RfD( Acute): 0 mg/ kg bw/ day NOEL( Acute): 0 mg/ kg bw/ day Date created/ last modified: 03 27 2004/ 14: 22: 24/ 8 Program ver. 1.30  EPA Crop Def Res Adj. Factors Comment Code Grp Commodity Name ( ppm) # 1 # 2        06030300 6C Bean, black, seed 210 Cooked; Fresh or N/ S; Cook Meth N/ S 0.003480 1.000 1.000 212 Cooked; Fresh or N/ S; Boiled 0.003480 1.000 1.000 230 Cooked; Dried; Cook Meth N/ S 0.003480 1.000 1.000 232 Cooked; Dried; Boiled 0.003480 1.000 1.000 242 Cooked; Canned; Boiled 0.000548 1.000 1.000 06020310 6B Bean, broad, succulent 0.003480 1.000 1.000 06030320 6C Bean, broad, seed 230 Cooked; Dried; Cook Meth N/ S 0.003480 1.000 1.000 232 Cooked; Dried; Boiled 0.003480 1.000 1.000 06020330 6B Bean, cowpea, succulent 212 Cooked; Fresh or N/ S; Boiled 0.003480 1.000 1.000 222 Cooked; Frozen; Boiled 0.000329 1.000 1.000 242 Cooked; Canned; Boiled 0.000548 1.000 1.000 06030340 6C Bean, cowpea, seed 210 Cooked; Fresh or N/ S; Cook Meth N/ S 0.003480 1.000 1.000 212 Cooked; Fresh or N/ S; Boiled 0.003480 1.000 1.000 232 Cooked; Dried; Boiled 0.003480 1.000 1.000 06030350 6C Bean, great northern, seed 210 Cooked; Fresh or N/ S; Cook Meth N/ S 0.003480 1.000 1.000 212 Cooked; Fresh or N/ S; Boiled 0.003480 1.000 1.000 230 Cooked; Dried; Cook Meth N/ S 0.003480 1.000 1.000 232 Cooked; Dried; Boiled 0.003480 1.000 1.000 242 Cooked; Canned; Boiled 0.000548 1.000 1.000 06030360 6C Bean, kidney, seed 210 Cooked; Fresh or N/ S; Cook Meth N/ S 0.003480 1.000 1.000 211 Cooked; Fresh or N/ S; Baked 0.003480 1.000 1.000 212 Cooked; Fresh or N/ S; Boiled 40 0.003480 1.000 1.000 213 Cooked; Fresh or N/ S; Fried 0.003480 1.000 1.000 221 Cooked; Frozen; Baked 0.000329 1.000 1.000 232 Cooked; Dried; Boiled 0.003480 1.000 1.000 240 Cooked; Canned; Cook Meth N/ S 0.000548 1.000 1.000 242 Cooked; Canned; Boiled 0.000548 1.000 1.000 06020370 6B Bean, lima, succulent 210 Cooked; Fresh or N/ S; Cook Meth N/ S 0.003480 1.000 1.000 212 Cooked; Fresh or N/ S; Boiled 0.003480 1.000 1.000 213 Cooked; Fresh or N/ S; Fried 0.003480 1.000 1.000 221 Cooked; Frozen; Baked 0.000329 1.000 1.000 222 Cooked; Frozen; Boiled 0.000329 1.000 1.000 240 Cooked; Canned; Cook Meth N/ S 0.000548 1.000 1.000 242 Cooked; Canned; Boiled 0.000548 1.000 1.000 06030380 6C Bean, lima, seed 210 Cooked; Fresh or N/ S; Cook Meth N/ S 0.003480 1.000 1.000 230 Cooked; Dried; Cook Meth N/ S 0.003480 1.000 1.000 232 Cooked; Dried; Boiled 0.003480 1.000 1.000 06030390 6C Bean, mung, seed 110 Uncooked; Fresh or N/ S; Cook Meth N/ S 0.003480 1.000 1.000 210 Cooked; Fresh or N/ S; Cook Meth N/ S 0.003480 1.000 1.000 211 Cooked; Fresh or N/ S; Baked 0.003480 1.000 1.000 212 Cooked; Fresh or N/ S; Boiled 0.003480 1.000 1.000 213 Cooked; Fresh or N/ S; Fried 0.003480 1.000 1.000 221 Cooked; Frozen; Baked 0.000329 1.000 1.000 232 Cooked; Dried; Boiled 0.003480 1.000 1.000 233 Cooked; Dried; Fried 0.003480 1.000 1.000 240 Cooked; Canned; Cook Meth N/ S 0.000548 1.000 1.000 06030400 6C Bean, navy, seed 210 Cooked; Fresh or N/ S; Cook Meth N/ S 0.003480 1.000 1.000 212 Cooked; Fresh or N/ S; Boiled 0.003480 1.000 1.000 230 Cooked; Dried; Cook Meth N/ S 0.003480 1.000 1.000 232 Cooked; Dried; Boiled 0.003480 1.000 1.000 242 Cooked; Canned; Boiled 0.000548 1.000 1.000 06030410 6C Bean, pink, seed 210 Cooked; Fresh or N/ S; Cook Meth N/ S 0.003480 1.000 1.000 212 Cooked; Fresh or N/ S; Boiled 0.003480 1.000 1.000 232 Cooked; Dried; Boiled 0.003480 1.000 1.000 06030420 6C Bean, pinto, seed 210 Cooked; Fresh or N/ S; Cook Meth N/ S 0.003480 1.000 1.000 211 Cooked; Fresh or N/ S; Baked 0.003480 1.000 1.000 212 Cooked; Fresh or N/ S; Boiled 0.003480 1.000 1.000 213 Cooked; Fresh or N/ S; Fried 0.003480 1.000 1.000 221 Cooked; Frozen; Baked 0.000329 1.000 1.000 230 Cooked; Dried; Cook Meth N/ S 0.003480 1.000 1.000 232 Cooked; Dried; Boiled 0.003480 1.000 1.000 06010430 6A Bean, snap, succulent 110 Uncooked; Fresh or N/ S; Cook Meth N/ S 41 0.003480 1.000 1.000 210 Cooked; Fresh or N/ S; Cook Meth N/ S 0.003480 1.000 1.000 211 Cooked; Fresh or N/ S; Baked 0.003480 1.000 1.000 212 Cooked; Fresh or N/ S; Boiled 0.003480 1.000 1.000 213 Cooked; Fresh or N/ S; Fried 0.003480 1.000 1.000 215 Cooked; Fresh or N/ S; Boiled/ baked 0.003480 1.000 1.000 221 Cooked; Frozen; Baked 0.000329 1.000 1.000 222 Cooked; Frozen; Boiled 0.000329 1.000 1.000 232 Cooked; Dried; Boiled 0.003480 1.000 1.000 240 Cooked; Canned; Cook Meth N/ S 0.000548 1.000 1.000 242 Cooked; Canned; Boiled 0.000548 1.000 1.000 06010431 6A Bean, snap, succulent babyfood 240 Cooked; Canned; Cook Meth N/ S 0.000548 1.000 1.000 21000440 M Beef, meat 0.002000 1.000 1.000 21000441 M Beef, meat babyfood 0.002000 1.000 1.000 21000450 M Beef, meat, dried 0.002000 1.920 1.000 21000460 M Beef, meat byproducts 0.030000 1.000 1.000 21000461 M Beef, meat byproducts babyfood 0.030000 1.000 1.000 21000470 M Beef, fat 0.020000 1.000 1.000 21000471 M Beef, fat babyfood 0.020000 1.000 1.000 21000480 M Beef, kidney 0.030000 1.000 1.000 21000490 M Beef, liver 0.030000 1.000 1.000 21000491 M Beef, liver babyfood 0.030000 1.000 1.000 05010610 5A Broccoli 110 Uncooked; Fresh or N/ S; Cook Meth N/ S 0.179000 1.000 1.000 210 Cooked; Fresh or N/ S; Cook Meth N/ S 0.179000 1.000 1.000 211 Cooked; Fresh or N/ S; Baked 0.179000 1.000 1.000 212 Cooked; Fresh or N/ S; Boiled 0.179000 1.000 1.000 213 Cooked; Fresh or N/ S; Fried 0.179000 1.000 1.000 220 Cooked; Frozen; Cook Meth N/ S 0.179000 1.000 1.000 221 Cooked; Frozen; Baked 0.179000 1.000 1.000 222 Cooked; Frozen; Boiled 0.179000 1.000 1.000 232 Cooked; Dried; Boiled 0.179000 1.000 1.000 242 Cooked; Canned; Boiled 0.179000 1.000 1.000 05010611 5A Broccoli babyfood 0.179000 1.000 1.000 05010620 5A Broccoli, Chinese 0.179000 1.000 1.000 05010640 5A Brussels sprouts 2.330000 1.000 1.000 05010690 5A Cabbage 0.179000 1.000 1.000 05020700 5B Cabbage, Chinese, bok choy 0.179000 1.000 1.000 05010710 5A Cabbage, Chinese, napa 0.179000 1.000 1.000 05010720 5A Cabbage, Chinese, mustard 0.179000 1.000 1.000 01010780 1AB Carrot 0.000500 1.000 1.000 01010781 1AB Carrot babyfood 0.000500 1.000 1.000 01010790 1AB Carrot, juice 0.000500 1.000 1.000 05010830 5A Cauliflower 0.360000 1.000 1.000 40000930 P Chicken, meat 0.000005 1.000 1.000 40000931 P Chicken, meat babyfood 0.000005 1.000 1.000 40000940 P Chicken, liver 0.000005 1.000 1.000 40000950 P Chicken, meat byproducts 0.000080 1.000 1.000 40000951 P Chicken, meat byproducts babyfoo 0.000080 1.000 1.000 40000960 P Chicken, fat 0.000080 1.000 1.000 40000961 P Chicken, fat babyfood 0.000080 1.000 1.000 40000970 P Chicken, skin 0.000080 1.000 1.000 40000971 P Chicken, skin babyfood 0.000080 1.000 1.000 05021170 5B Collards 0.179000 1.000 1.000 95001280 O Cottonseed, oil 0.165000 1.000 1.000 95001281 O Cottonseed, oil babyfood 0.165000 1.000 1.000 09021350 9B Cucumber 0.000060 1.000 1.000 70001450 P Egg, whole 0.000400 1.000 1.000 42 70001451 P Egg, whole babyfood 0.000400 1.000 1.000 70001460 P Egg, white 0.000400 1.000 1.000 70001461 P Egg, white ( solids) babyfood 0.000400 1.000 1.000 70001470 P Egg, yolk 0.000400 1.000 1.000 70001471 P Egg, yolk babyfood 0.000400 1.000 1.000 03001640 3 Garlic 0.330000 1.000 1.000 03001650 3 Garlic, dried 0.330000 1.000 1.000 03001651 3 Garlic, dried babyfood 0.330000 1.000 1.000 01011680 1AB Ginseng, dried 3.270000 1.000 1.000 23001690 M Goat, meat 0.002000 1.000 1.000 23001700 M Goat, meat byproducts 0.030000 1.000 1.000 23001710 M Goat, fat 0.020000 1.000 1.000 23001720 M Goat, kidney 0.030000 1.000 1.000 23001730 M Goat, liver 0.030000 1.000 1.000 24001890 M Horse, meat 0.002000 1.000 1.000 05021940 5B Kale 0.179000 1.000 1.000 27002220 D Milk, fat 0.150000 1.000 1.000 27002221 D Milk, fat  baby food/ infant for 0.150000 1.000 1.000 05022290 5B Mustard greens 0.179000 1.000 1.000 95002630 O Peanut 0.003400 1.000 1.000 95002640 O Peanut, butter 0.004900 1.000 1.000 95002650 O Peanut, oil 0.003400 2.100 1.000 08002700 8 Pepper, bell 0.000271 1.000 1.000 08002701 8 Pepper, bell babyfood 0.000271 1.000 1.000 08002710 8 Pepper, bell, dried 0.000271 1.000 1.000 08002711 8 Pepper, bell, dried babyfood 0.000271 1.000 1.000 08002720 8 Pepper, nonbell 0.000813 1.000 1.000 08002721 8 Pepper, nonbell babyfood 0.000813 1.000 1.000 08002730 8 Pepper, nonbell, dried 0.000813 1.000 1.000 25002900 M Pork, meat 0.000060 1.000 1.000 25002901 M Pork, meat babyfood 0.000060 1.000 1.000 25002910 M Pork, skin 0.000060 1.000 1.000 25002920 M Pork, meat byproducts 0.001200 1.000 1.000 25002921 M Pork, meat byproducts babyfood 0.001200 1.000 1.000 25002930 M Pork, fat 0.000800 1.000 1.000 25002931 M Pork, fat babyfood 0.000800 1.000 1.000 25002940 M Pork, kidney 0.001200 1.000 1.000 25002950 M Pork, liver 0.001000 1.000 1.000 01032960 1C Potato, chips 0.003400 1.000 1.000 01032970 1C Potato, dry ( granules/ flakes) 0.003400 1.000 1.000 01032971 1C Potato, dry ( granules/ flakes) b 0.003400 1.000 1.000 01032980 1C Potato, flour 0.003400 1.000 1.000 01032981 1C Potato, flour babyfood 0.003400 1.000 1.000 01032990 1C Potato, tuber, w/ peel 210 Cooked; Fresh or N/ S; Cook Meth N/ S 0.003400 5.400 1.000 211 Cooked; Fresh or N/ S; Baked 0.003400 5.400 1.000 212 Cooked; Fresh or N/ S; Boiled 0.003400 5.400 1.000 213 Cooked; Fresh or N/ S; Fried 0.003400 5.400 1.000 01032991 1C Potato, tuber, w/ peel babyfood 0.003400 5.400 1.000 01033000 1C Potato, tuber, w/ o peel 0.003400 1.000 1.000 01033001 1C Potato, tuber, w/ o peel babyfood 0.003400 1.000 1.000 60003010 P Poultry, other, meat 0.000005 1.000 1.000 60003020 P Poultry, other, liver 0.000080 1.000 1.000 60003030 P Poultry, other, meat byproducts 0.000080 1.000 1.000 60003040 P Poultry, other, fat 0.000080 1.000 1.000 60003050 P Poultry, other, skin 0.000080 1.000 1.000 26003390 M Sheep, meat 0.002000 1.000 1.000 26003391 M Sheep, meat babyfood 0.002000 1.000 1.000 26003400 M Sheep, meat byproducts 0.030000 1.000 1.000 26003410 M Sheep, fat 0.020000 1.000 1.000 26003411 M Sheep, fat babyfood 0.020000 1.000 1.000 26003420 M Sheep, kidney 0.030000 1.000 1.000 26003430 M Sheep, liver 0.030000 1.000 1.000 04013550 4A Spinach 0.000300 1.000 1.000 04013551 4A Spinach babyfood 0.000300 1.000 1.000 08003750 8 Tomato 110 Uncooked; Fresh or N/ S; Cook Meth N/ S 0.000330 1.000 1.000 43 150 Uncooked; Cured etc; Cook Meth N/ S 0.000330 1.000 1.000 210 Cooked; Fresh or N/ S; Cook Meth N/ S 0.000330 1.000 1.000 211 Cooked; Fresh or N/ S; Baked 0.000330 1.000 1.000 212 Cooked; Fresh or N/ S; Boiled 0.000330 1.000 1.000 213 Cooked; Fresh or N/ S; Fried 0.000330 1.000 1.000 214 Cooked; Fresh or N/ S; Fried/ baked 0.000330 1.000 1.000 215 Cooked; Fresh or N/ S; Boiled/ baked 0.000330 1.000 1.000 221 Cooked; Frozen; Baked 0.000330 1.000 1.000 222 Cooked; Frozen; Boiled 0.000330 1.000 1.000 232 Cooked; Dried; Boiled 0.000330 14.300 1.000 240 Cooked; Canned; Cook Meth N/ S 0.000216 1.000 1.000 242 Cooked; Canned; Boiled 0.000216 1.000 1.000 252 Cooked; Cured etc; Boiled 0.000330 1.000 1.000 08003751 8 Tomato babyfood 240 Cooked; Canned; Cook Meth N/ S 0.000216 1.000 1.000 08003760 8 Tomato, paste 110 Uncooked; Fresh or N/ S; Cook Meth N/ S 0.000195 1.000 1.000 210 Cooked; Fresh or N/ S; Cook Meth N/ S 0.000195 1.000 1.000 211 Cooked; Fresh or N/ S; Baked 0.000195 1.000 1.000 212 Cooked; Fresh or N/ S; Boiled 0.000195 1.000 1.000 213 Cooked; Fresh or N/ S; Fried 0.000195 1.000 1.000 215 Cooked; Fresh or N/ S; Boiled/ baked 0.000195 1.000 1.000 221 Cooked; Frozen; Baked 0.000195 1.000 1.000 232 Cooked; Dried; Boiled 0.000195 1.000 1.000 240 Cooked; Canned; Cook Meth N/ S 0.000195 1.000 1.000 242 Cooked; Canned; Boiled 0.000195 1.000 1.000 08003761 8 Tomato, paste babyfood 240 Cooked; Canned; Cook Meth N/ S 0.000195 1.000 1.000 08003770 8 Tomato, puree 110 Uncooked; Fresh or N/ S; Cook Meth N/ S 0.000330 1.000 1.000 210 Cooked; Fresh or N/ S; Cook Meth N/ S 0.000330 1.000 1.000 211 Cooked; Fresh or N/ S; Baked 0.000330 1.000 1.000 212 Cooked; Fresh or N/ S; Boiled 0.000330 1.000 1.000 213 Cooked; Fresh or N/ S; Fried 0.000330 1.000 1.000 215 Cooked; Fresh or N/ S; Boiled/ baked 0.000330 1.000 1.000 221 Cooked; Frozen; Baked 0.000330 1.000 1.000 232 Cooked; Dried; Boiled 0.000330 1.000 1.000 240 Cooked; Canned; Cook Meth N/ S 0.000216 1.000 1.000 242 Cooked; Canned; Boiled 0.000216 1.000 1.000 252 Cooked; Cured etc; Boiled 0.000330 1.000 1.000 08003771 8 Tomato, puree babyfood 240 Cooked; Canned; Cook Meth N/ S 0.000216 1.000 1.000 08003780 8 Tomato, dried 110 Uncooked; Fresh or N/ S; Cook Meth N/ S 0.000330 14.300 1.000 130 Uncooked; Dried; Cook Meth N/ S 0.000330 14.300 1.000 44 210 Cooked; Fresh or N/ S; Cook Meth N/ S 0.000330 14.300 1.000 211 Cooked; Fresh or N/ S; Baked 0.000330 14.300 1.000 212 Cooked; Fresh or N/ S; Boiled 0.000330 14.300 1.000 214 Cooked; Fresh or N/ S; Fried/ baked 0.000330 14.300 1.000 215 Cooked; Fresh or N/ S; Boiled/ baked 0.000330 14.300 1.000 230 Cooked; Dried; Cook Meth N/ S 0.000330 14.300 1.000 231 Cooked; Dried; Baked 0.000330 14.300 1.000 232 Cooked; Dried; Boiled 0.000330 14.300 1.000 08003781 8 Tomato, dried babyfood 211 Cooked; Fresh or N/ S; Baked 0.000330 1.000 1.000 08003790 8 Tomato, juice 110 Uncooked; Fresh or N/ S; Cook Meth N/ S 0.000330 1.000 1.000 210 Cooked; Fresh or N/ S; Cook Meth N/ S 0.000330 1.000 1.000 211 Cooked; Fresh or N/ S; Baked 0.000330 1.000 1.000 212 Cooked; Fresh or N/ S; Boiled 0.000330 1.000 1.000 240 Cooked; Canned; Cook Meth N/ S 0.000216 1.000 1.000 242 Cooked; Canned; Boiled 0.000216 1.000 1.000 50003820 P Turkey, meat 0.000005 1.000 1.000 50003821 P Turkey, meat babyfood 0.000005 1.000 1.000 50003830 P Turkey, liver 0.000080 1.000 1.000 50003831 P Turkey, liver babyfood 0.000080 1.000 1.000 50003840 P Turkey, meat byproducts 0.000080 1.000 1.000 50003841 P Turkey, meat byproducts babyfood 0.000080 1.000 1.000 50003850 P Turkey, fat 0.000080 1.000 1.000 50003851 P Turkey, fat babyfood 0.000080 1.000 1.000 50003860 P Turkey, skin 0.000080 1.000 1.000 50003861 P Turkey, skin babyfood 0.000080 1.000 1.000 45 Attachment 7: DEEM input file ( i. e., the food list) for chronic dietary assessment for all crops ( registered and unregistered) with detected residues of PCNB ( water included).

Filename: C:\ msahafeyan\ 0 Mohsen\ Reviews\ Primary Reviews\ PCNB\ DEEM PCNB\ PCNB WaterIncluded AllCrops 032704. R98 Chemical: PCNB RfD( Chronic): .001 mg/ kg bw/ day NOEL( Chronic): 0 mg/ kg bw/ day RfD( Acute): 0 mg/ kg bw/ day NOEL( Acute): 0 mg/ kg bw/ day Date created/ last modified: 03 27 2004/ 14: 23: 49/ 8 Program ver. 1.30  EPA Crop Def Res Adj. Factors Comment Code Grp Commodity Name ( ppm) # 1 # 2        06030300 6C Bean, black, seed 210 Cooked; Fresh or N/ S; Cook Meth N/ S 0.003480 1.000 1.000 212 Cooked; Fresh or N/ S; Boiled 0.003480 1.000 1.000 230 Cooked; Dried; Cook Meth N/ S 0.003480 1.000 1.000 232 Cooked; Dried; Boiled 0.003480 1.000 1.000 242 Cooked; Canned; Boiled 0.000548 1.000 1.000 06020310 6B Bean, broad, succulent 0.003480 1.000 1.000 06030320 6C Bean, broad, seed 230 Cooked; Dried; Cook Meth N/ S 0.003480 1.000 1.000 232 Cooked; Dried; Boiled 0.003480 1.000 1.000 06020330 6B Bean, cowpea, succulent 212 Cooked; Fresh or N/ S; Boiled 0.003480 1.000 1.000 222 Cooked; Frozen; Boiled 0.000329 1.000 1.000 242 Cooked; Canned; Boiled 0.000548 1.000 1.000 06030340 6C Bean, cowpea, seed 210 Cooked; Fresh or N/ S; Cook Meth N/ S 0.003480 1.000 1.000 212 Cooked; Fresh or N/ S; Boiled 0.003480 1.000 1.000 232 Cooked; Dried; Boiled 0.003480 1.000 1.000 06030350 6C Bean, great northern, seed 210 Cooked; Fresh or N/ S; Cook Meth N/ S 0.003480 1.000 1.000 212 Cooked; Fresh or N/ S; Boiled 0.003480 1.000 1.000 230 Cooked; Dried; Cook Meth N/ S 0.003480 1.000 1.000 232 Cooked; Dried; Boiled 0.003480 1.000 1.000 242 Cooked; Canned; Boiled 0.000548 1.000 1.000 46 06030360 6C Bean, kidney, seed 210 Cooked; Fresh or N/ S; Cook Meth N/ S 0.003480 1.000 1.000 211 Cooked; Fresh or N/ S; Baked 0.003480 1.000 1.000 212 Cooked; Fresh or N/ S; Boiled 0.003480 1.000 1.000 213 Cooked; Fresh or N/ S; Fried 0.003480 1.000 1.000 221 Cooked; Frozen; Baked 0.000329 1.000 1.000 232 Cooked; Dried; Boiled 0.003480 1.000 1.000 240 Cooked; Canned; Cook Meth N/ S 0.000548 1.000 1.000 242 Cooked; Canned; Boiled 0.000548 1.000 1.000 06020370 6B Bean, lima, succulent 210 Cooked; Fresh or N/ S; Cook Meth N/ S 0.003480 1.000 1.000 212 Cooked; Fresh or N/ S; Boiled 0.003480 1.000 1.000 213 Cooked; Fresh or N/ S; Fried 0.003480 1.000 1.000 221 Cooked; Frozen; Baked 0.000329 1.000 1.000 222 Cooked; Frozen; Boiled 0.000329 1.000 1.000 240 Cooked; Canned; Cook Meth N/ S 0.000548 1.000 1.000 242 Cooked; Canned; Boiled 0.000548 1.000 1.000 06030380 6C Bean, lima, seed 210 Cooked; Fresh or N/ S; Cook Meth N/ S 0.003480 1.000 1.000 230 Cooked; Dried; Cook Meth N/ S 0.003480 1.000 1.000 232 Cooked; Dried; Boiled 0.003480 1.000 1.000 06030390 6C Bean, mung, seed 110 Uncooked; Fresh or N/ S; Cook Meth N/ S 0.003480 1.000 1.000 210 Cooked; Fresh or N/ S; Cook Meth N/ S 0.003480 1.000 1.000 211 Cooked; Fresh or N/ S; Baked 0.003480 1.000 1.000 212 Cooked; Fresh or N/ S; Boiled 0.003480 1.000 1.000 213 Cooked; Fresh or N/ S; Fried 0.003480 1.000 1.000 221 Cooked; Frozen; Baked 0.000329 1.000 1.000 232 Cooked; Dried; Boiled 0.003480 1.000 1.000 233 Cooked; Dried; Fried 0.003480 1.000 1.000 240 Cooked; Canned; Cook Meth N/ S 0.000548 1.000 1.000 06030400 6C Bean, navy, seed 210 Cooked; Fresh or N/ S; Cook Meth N/ S 0.003480 1.000 1.000 212 Cooked; Fresh or N/ S; Boiled 0.003480 1.000 1.000 230 Cooked; Dried; Cook Meth N/ S 0.003480 1.000 1.000 232 Cooked; Dried; Boiled 0.003480 1.000 1.000 242 Cooked; Canned; Boiled 0.000548 1.000 1.000 06030410 6C Bean, pink, seed 210 Cooked; Fresh or N/ S; Cook Meth N/ S 0.003480 1.000 1.000 212 Cooked; Fresh or N/ S; Boiled 0.003480 1.000 1.000 232 Cooked; Dried; Boiled 0.003480 1.000 1.000 06030420 6C Bean, pinto, seed 210 Cooked; Fresh or N/ S; Cook Meth N/ S 0.003480 1.000 1.000 211 Cooked; Fresh or N/ S; Baked 0.003480 1.000 1.000 212 Cooked; Fresh or N/ S; Boiled 0.003480 1.000 1.000 213 Cooked; Fresh or N/ S; Fried 0.003480 1.000 1.000 47 221 Cooked; Frozen; Baked 0.000329 1.000 1.000 230 Cooked; Dried; Cook Meth N/ S 0.003480 1.000 1.000 232 Cooked; Dried; Boiled 0.003480 1.000 1.000 06010430 6A Bean, snap, succulent 110 Uncooked; Fresh or N/ S; Cook Meth N/ S 0.003480 1.000 1.000 210 Cooked; Fresh or N/ S; Cook Meth N/ S 0.003480 1.000 1.000 211 Cooked; Fresh or N/ S; Baked 0.003480 1.000 1.000 212 Cooked; Fresh or N/ S; Boiled 0.003480 1.000 1.000 213 Cooked; Fresh or N/ S; Fried 0.003480 1.000 1.000 215 Cooked; Fresh or N/ S; Boiled/ baked 0.003480 1.000 1.000 221 Cooked; Frozen; Baked 0.000329 1.000 1.000 222 Cooked; Frozen; Boiled 0.000329 1.000 1.000 232 Cooked; Dried; Boiled 0.003480 1.000 1.000 240 Cooked; Canned; Cook Meth N/ S 0.000548 1.000 1.000 242 Cooked; Canned; Boiled 0.000548 1.000 1.000 06010431 6A Bean, snap, succulent babyfood 240 Cooked; Canned; Cook Meth N/ S 0.000548 1.000 1.000 21000440 M Beef, meat 0.002000 1.000 1.000 21000441 M Beef, meat babyfood 0.002000 1.000 1.000 21000450 M Beef, meat, dried 0.002000 1.920 1.000 21000460 M Beef, meat byproducts 0.030000 1.000 1.000 21000461 M Beef, meat byproducts babyfood 0.030000 1.000 1.000 21000470 M Beef, fat 0.020000 1.000 1.000 21000471 M Beef, fat babyfood 0.020000 1.000 1.000 21000480 M Beef, kidney 0.030000 1.000 1.000 21000490 M Beef, liver 0.030000 1.000 1.000 21000491 M Beef, liver babyfood 0.030000 1.000 1.000 05010610 5A Broccoli 110 Uncooked; Fresh or N/ S; Cook Meth N/ S 0.179000 1.000 1.000 210 Cooked; Fresh or N/ S; Cook Meth N/ S 0.179000 1.000 1.000 211 Cooked; Fresh or N/ S; Baked 0.179000 1.000 1.000 212 Cooked; Fresh or N/ S; Boiled 0.179000 1.000 1.000 213 Cooked; Fresh or N/ S; Fried 0.179000 1.000 1.000 220 Cooked; Frozen; Cook Meth N/ S 0.179000 1.000 1.000 221 Cooked; Frozen; Baked 0.179000 1.000 1.000 222 Cooked; Frozen; Boiled 0.179000 1.000 1.000 232 Cooked; Dried; Boiled 0.179000 1.000 1.000 242 Cooked; Canned; Boiled 0.179000 1.000 1.000 05010611 5A Broccoli babyfood 0.179000 1.000 1.000 05010620 5A Broccoli, Chinese 0.179000 1.000 1.000 05010640 5A Brussels sprouts 2.330000 1.000 1.000 05010690 5A Cabbage 0.179000 1.000 1.000 05020700 5B Cabbage, Chinese, bok choy 0.179000 1.000 1.000 05010710 5A Cabbage, Chinese, napa 0.179000 1.000 1.000 05010720 5A Cabbage, Chinese, mustard 0.179000 1.000 1.000 01010780 1AB Carrot 0.000500 1.000 1.000 01010781 1AB Carrot babyfood 0.000500 1.000 1.000 01010790 1AB Carrot, juice 0.000500 1.000 1.000 05010830 5A Cauliflower 0.360000 1.000 1.000 40000930 P Chicken, meat 0.000005 1.000 1.000 40000931 P Chicken, meat babyfood 0.000005 1.000 1.000 40000940 P Chicken, liver 0.000005 1.000 1.000 40000950 P Chicken, meat byproducts 0.000080 1.000 1.000 40000951 P Chicken, meat byproducts babyfoo 0.000080 1.000 1.000 40000960 P Chicken, fat 0.000080 1.000 1.000 40000961 P Chicken, fat babyfood 0.000080 1.000 1.000 40000970 P Chicken, skin 0.000080 1.000 1.000 48 40000971 P Chicken, skin babyfood 0.000080 1.000 1.000 05021170 5B Collards 0.179000 1.000 1.000 95001280 O Cottonseed, oil 0.165000 1.000 1.000 95001281 O Cottonseed, oil babyfood 0.165000 1.000 1.000 09021350 9B Cucumber 0.000060 1.000 1.000 70001450 P Egg, whole 0.000400 1.000 1.000 70001451 P Egg, whole babyfood 0.000400 1.000 1.000 70001460 P Egg, white 0.000400 1.000 1.000 70001461 P Egg, white ( solids) babyfood 0.000400 1.000 1.000 70001470 P Egg, yolk 0.000400 1.000 1.000 70001471 P Egg, yolk babyfood 0.000400 1.000 1.000 03001640 3 Garlic 0.330000 1.000 1.000 03001650 3 Garlic, dried 0.330000 1.000 1.000 03001651 3 Garlic, dried babyfood 0.330000 1.000 1.000 01011680 1AB Ginseng, dried 3.270000 1.000 1.000 23001690 M Goat, meat 0.002000 1.000 1.000 23001700 M Goat, meat byproducts 0.030000 1.000 1.000 23001710 M Goat, fat 0.020000 1.000 1.000 23001720 M Goat, kidney 0.030000 1.000 1.000 23001730 M Goat, liver 0.030000 1.000 1.000 24001890 M Horse, meat 0.002000 1.000 1.000 05021940 5B Kale 0.179000 1.000 1.000 27002220 D Milk, fat 0.150000 1.000 1.000 27002221 D Milk, fat  baby food/ infant for 0.150000 1.000 1.000 05022290 5B Mustard greens 0.179000 1.000 1.000 95002630 O Peanut 0.003400 1.000 1.000 95002640 O Peanut, butter 0.004900 1.000 1.000 95002650 O Peanut, oil 0.003400 2.100 1.000 08002700 8 Pepper, bell 0.000271 1.000 1.000 08002701 8 Pepper, bell babyfood 0.000271 1.000 1.000 08002710 8 Pepper, bell, dried 0.000271 1.000 1.000 08002711 8 Pepper, bell, dried babyfood 0.000271 1.000 1.000 08002720 8 Pepper, nonbell 0.000813 1.000 1.000 08002721 8 Pepper, nonbell babyfood 0.000813 1.000 1.000 08002730 8 Pepper, nonbell, dried 0.000813 1.000 1.000 25002900 M Pork, meat 0.000060 1.000 1.000 25002901 M Pork, meat babyfood 0.000060 1.000 1.000 25002910 M Pork, skin 0.000060 1.000 1.000 25002920 M Pork, meat byproducts 0.001200 1.000 1.000 25002921 M Pork, meat byproducts babyfood 0.001200 1.000 1.000 25002930 M Pork, fat 0.000800 1.000 1.000 25002931 M Pork, fat babyfood 0.000800 1.000 1.000 25002940 M Pork, kidney 0.001200 1.000 1.000 25002950 M Pork, liver 0.001000 1.000 1.000 01032960 1C Potato, chips 0.003400 1.000 1.000 01032970 1C Potato, dry ( granules/ flakes) 0.003400 1.000 1.000 01032971 1C Potato, dry ( granules/ flakes) b 0.003400 1.000 1.000 01032980 1C Potato, flour 0.003400 1.000 1.000 01032981 1C Potato, flour babyfood 0.003400 1.000 1.000 01032990 1C Potato, tuber, w/ peel 210 Cooked; Fresh or N/ S; Cook Meth N/ S 0.003400 5.400 1.000 211 Cooked; Fresh or N/ S; Baked 0.003400 5.400 1.000 212 Cooked; Fresh or N/ S; Boiled 0.003400 5.400 1.000 213 Cooked; Fresh or N/ S; Fried 0.003400 5.400 1.000 01032991 1C Potato, tuber, w/ peel babyfood 0.003400 5.400 1.000 01033000 1C Potato, tuber, w/ o peel 0.003400 1.000 1.000 01033001 1C Potato, tuber, w/ o peel babyfood 0.003400 1.000 1.000 60003010 P Poultry, other, meat 0.000005 1.000 1.000 60003020 P Poultry, other, liver 0.000080 1.000 1.000 60003030 P Poultry, other, meat byproducts 0.000080 1.000 1.000 60003040 P Poultry, other, fat 0.000080 1.000 1.000 60003050 P Poultry, other, skin 0.000080 1.000 1.000 26003390 M Sheep, meat 0.002000 1.000 1.000 26003391 M Sheep, meat babyfood 0.002000 1.000 1.000 26003400 M Sheep, meat byproducts 0.030000 1.000 1.000 26003410 M Sheep, fat 0.020000 1.000 1.000 26003411 M Sheep, fat babyfood 0.020000 1.000 1.000 26003420 M Sheep, kidney 0.030000 1.000 1.000 49 26003430 M Sheep, liver 0.030000 1.000 1.000 04013550 4A Spinach 0.000300 1.000 1.000 04013551 4A Spinach babyfood 0.000300 1.000 1.000 08003750 8 Tomato 110 Uncooked; Fresh or N/ S; Cook Meth N/ S 0.000330 1.000 1.000 150 Uncooked; Cured etc; Cook Meth N/ S 0.000330 1.000 1.000 210 Cooked; Fresh or N/ S; Cook Meth N/ S 0.000330 1.000 1.000 211 Cooked; Fresh or N/ S; Baked 0.000330 1.000 1.000 212 Cooked; Fresh or N/ S; Boiled 0.000330 1.000 1.000 213 Cooked; Fresh or N/ S; Fried 0.000330 1.000 1.000 214 Cooked; Fresh or N/ S; Fried/ baked 0.000330 1.000 1.000 215 Cooked; Fresh or N/ S; Boiled/ baked 0.000330 1.000 1.000 221 Cooked; Frozen; Baked 0.000330 1.000 1.000 222 Cooked; Frozen; Boiled 0.000330 1.000 1.000 232 Cooked; Dried; Boiled 0.000330 14.300 1.000 240 Cooked; Canned; Cook Meth N/ S 0.000216 1.000 1.000 242 Cooked; Canned; Boiled 0.000216 1.000 1.000 252 Cooked; Cured etc; Boiled 0.000330 1.000 1.000 08003751 8 Tomato babyfood 240 Cooked; Canned; Cook Meth N/ S 0.000216 1.000 1.000 08003760 8 Tomato, paste 110 Uncooked; Fresh or N/ S; Cook Meth N/ S 0.000195 1.000 1.000 210 Cooked; Fresh or N/ S; Cook Meth N/ S 0.000195 1.000 1.000 211 Cooked; Fresh or N/ S; Baked 0.000195 1.000 1.000 212 Cooked; Fresh or N/ S; Boiled 0.000195 1.000 1.000 213 Cooked; Fresh or N/ S; Fried 0.000195 1.000 1.000 215 Cooked; Fresh or N/ S; Boiled/ baked 0.000195 1.000 1.000 221 Cooked; Frozen; Baked 0.000195 1.000 1.000 232 Cooked; Dried; Boiled 0.000195 1.000 1.000 240 Cooked; Canned; Cook Meth N/ S 0.000195 1.000 1.000 242 Cooked; Canned; Boiled 0.000195 1.000 1.000 08003761 8 Tomato, paste babyfood 240 Cooked; Canned; Cook Meth N/ S 0.000195 1.000 1.000 08003770 8 Tomato, puree 110 Uncooked; Fresh or N/ S; Cook Meth N/ S 0.000330 1.000 1.000 210 Cooked; Fresh or N/ S; Cook Meth N/ S 0.000330 1.000 1.000 211 Cooked; Fresh or N/ S; Baked 0.000330 1.000 1.000 212 Cooked; Fresh or N/ S; Boiled 0.000330 1.000 1.000 213 Cooked; Fresh or N/ S; Fried 0.000330 1.000 1.000 215 Cooked; Fresh or N/ S; Boiled/ baked 0.000330 1.000 1.000 221 Cooked; Frozen; Baked 0.000330 1.000 1.000 232 Cooked; Dried; Boiled 0.000330 1.000 1.000 240 Cooked; Canned; Cook Meth N/ S 0.000216 1.000 1.000 242 Cooked; Canned; Boiled 0.000216 1.000 1.000 252 Cooked; Cured etc; Boiled 0.000330 1.000 1.000 08003771 8 Tomato, puree babyfood 240 Cooked; Canned; Cook Meth N/ S 50 0.000216 1.000 1.000 08003780 8 Tomato, dried 110 Uncooked; Fresh or N/ S; Cook Meth N/ S 0.000330 14.300 1.000 130 Uncooked; Dried; Cook Meth N/ S 0.000330 14.300 1.000 210 Cooked; Fresh or N/ S; Cook Meth N/ S 0.000330 14.300 1.000 211 Cooked; Fresh or N/ S; Baked 0.000330 14.300 1.000 212 Cooked; Fresh or N/ S; Boiled 0.000330 14.300 1.000 214 Cooked; Fresh or N/ S; Fried/ baked 0.000330 14.300 1.000 215 Cooked; Fresh or N/ S; Boiled/ baked 0.000330 14.300 1.000 230 Cooked; Dried; Cook Meth N/ S 0.000330 14.300 1.000 231 Cooked; Dried; Baked 0.000330 14.300 1.000 232 Cooked; Dried; Boiled 0.000330 14.300 1.000 08003781 8 Tomato, dried babyfood 211 Cooked; Fresh or N/ S; Baked 0.000330 1.000 1.000 08003790 8 Tomato, juice 110 Uncooked; Fresh or N/ S; Cook Meth N/ S 0.000330 1.000 1.000 210 Cooked; Fresh or N/ S; Cook Meth N/ S 0.000330 1.000 1.000 211 Cooked; Fresh or N/ S; Baked 0.000330 1.000 1.000 212 Cooked; Fresh or N/ S; Boiled 0.000330 1.000 1.000 240 Cooked; Canned; Cook Meth N/ S 0.000216 1.000 1.000 242 Cooked; Canned; Boiled 0.000216 1.000 1.000 50003820 P Turkey, meat 0.000005 1.000 1.000 50003821 P Turkey, meat babyfood 0.000005 1.000 1.000 50003830 P Turkey, liver 0.000080 1.000 1.000 50003831 P Turkey, liver babyfood 0.000080 1.000 1.000 50003840 P Turkey, meat byproducts 0.000080 1.000 1.000 50003841 P Turkey, meat byproducts babyfood 0.000080 1.000 1.000 50003850 P Turkey, fat 0.000080 1.000 1.000 50003851 P Turkey, fat babyfood 0.000080 1.000 1.000 50003860 P Turkey, skin 0.000080 1.000 1.000 50003861 P Turkey, skin babyfood 0.000080 1.000 1.000 86010000 O Water, direct, all sources 0.044200 1.000 1.000 86020000 O Water, indirect, all sources 0.044200 1.000 1.000 51 Attachment 8: LifeLine input file ( i. e., the residue input for each food) for chronic dietary assessment for all crops ( registered and unregistered) ( water not included).