Okay, welcome back. Got a good breather. All right, let's continue where we left off. So in the last class, in the last session, we covered the origins of the church and how church is Jesus' idea, God's idea. It belongs to Him and He is the head and the church is His body. And because He is eternal, the church is also eternal because we are part of His body, right? We started looking at the spiritual dimension of the church, which is the church is the Christ's body. We'll continue from there on, okay? The section says the church is Christ's instrument to execute His purposes. The church is Christ's instrument to execute His purposes here, okay? So the notes, it says the body executes what the head commands, isn't it? So, you know, push this, hit someone, okay? So the body executes what the head commands, isn't it? So both here in the present age and in the millennium. So when you look at Daniel chapter 7, verse 18, it says forever and ever and ever. Okay, so it's pointing towards millennium. So you can look at the verse a little later. But here's the thing. And the section says the church is His instrument to execute His purposes, okay? So remember, we are His instrument. Now I just want to play us something which kind of will give you a nice idea of what I'm talking about. So let's see. I hope you can all hear this, okay? Or it would have been nice for you all to see it, but it's okay. I'll share the link. This is on YouTube, okay? So he's giving a demonstration or something. Hey, James, back on the sound board guy. Is this guitar on? Turn this guitar. What I want to do, I want this guitar to be very loud in the house. And I want my voice. You don't want the guitar real loud in that monitor, of course, because you'll get some feedback. I want my voice very loud in this monitor. Okay, guitar loud in the house, voice loud in the monitor. Hallelujah. Oops, sorry, moved too close. Hallelujah. Holy Lord. Holy Lord. See, that guitar is responding to the sound of my voice. Holy, holy, holy. Okay, very quickly. Can you all hear how the guitar is responding to the sound of his voice? Okay, let's continue. See what it's doing. It's hearing the sound of my voice and it's saying, I agree. And the Lord is speaking to a generation that is waiting for us to hear this sound of his voice and become instruments of worship. Did you know what I was talking about last night or this morning? When I was talking about the enemy Satan himself, he didn't have to leave worship with a guitar. He was a guitar. And then we got his place. And now we become instruments of worship unto a holy God. Because we hear the sound of his voice come into agreement with it. Holy, holy, holy. Okay, so yeah, we can... That whole teaching is amazing. I'll share that link with us when we can, when I can. But the point I wanted to make was that it's here. It says that we are God's instrument to execute his purpose. Just like what was happening as an example there as a demonstration is that if we have the year to hear the things of heaven, what he is saying, like the guitar will come in agreement and say amen and release that sound of heaven here on earth. Isn't it? You see how praise and worship is still linked with the local church. Even we are called as God's instrument.  He could have used the angels or any creation for that matter, isn't it? To accomplish his purpose, but he chooses to co-partner with us. One of the points that we learned in healing and deliverance class is that he's just looking for that opportunity to join hands with us, to partner with us and to establish his will here on earth.  He's looking for a human being to accomplish what he wants to do. He's looking for someone who will say amen and come in agreement with him. So that is another spiritual dimension to the fact that we are called as the local church, is that we are called to execute his purposes. As it says in Ephesians chapter 1 verse 23, we are called to be the complete representation or representation of Jesus, of Jesus Christ. Ephesians 1.23, I'll read the message Bible version in your notes. It says, the church you see is not peripheral to the world. The world is peripheral to the church. Now what is the meaning of peripheral? We say peripheral vision. What does that mean? I'm looking at you, but with my peripheral vision, I can see it in, that's called the peripheral vision, like towards the thing, isn't it? So that's what it is. So here is saying, see the church is not peripheral to the world, but the world is peripheral to the church. That means our eyes is fixed on church, not on the world. But like Peter, my eyes is not fixed on the waves, on the storm. It's fixed on Jesus. I'm sorry, I'm pointing my finger at you too because... So it says, the church you see is not peripheral to the world. The world is peripheral to the church. The church is Christ's body in which he speaks. Look at that, that's amazing. The church is Christ's body. He's not just saying that, in which he speaks and acts. If he wanted to, he can just show up to the world and say, stop having these debates, guys.  If he wanted to, he can do that, isn't it? But he wants to co-partner with us and through the church, his body, he wants to speak. That means he wants the church to be his voice. And he's saying if he wants to act, that means he wants the church to be his hands and his feet, like do what I want you to do. Go where I want you to go. Are you with me? And by which he fills everything with his presence. Let's read the amplified classic edition as well, Efficiency 123. It says, which is his body, the fullness of him who fills all in all for in that body lives the full measure of him who makes everything complete and who fills everything everywhere with himself. It's a very good version to say, wow. Okay. Right? Yeah. So the church is a complete representation or the re-presentation of Jesus Christ. Okay. And then again, it goes on to say another spiritual dimension to it is that every believer is a member of Christ's body. As it says in 1 Corinthians 12 27. Now you are the body of Christ and members individually. So individually and as a collective, we are the body of Christ. Okay. Now we've looked at the spiritual dimension. So let's look at some of the natural dimensions of the church. Natural dimensions. It simply means the tangibles. Okay. Anything that is natural means okay. Anything that you can see, touch, feel is what we would call it as natural, right? Everything that is off the other kingdom, we call it a supernatural, which is natural in that kingdom. Okay. But the natural dimensions of the church, that means the tangibles, the things that you can see and hear and feel. Okay. So let's look at those dimensions of the church. So first Timothy chapter three was 14 and 15. Paul is writing to Timothy who is the overseer of the church Ephesus, right? Timothy is overseeing. He's one of the leaders at this time before he becomes an elder and a pastor. In other words, Paul is writing to Timothy in first Timothy chapter three was 14 and 15. These things are right to you that I hope to come to you shortly. Now this chapter, you know, if you go to any church website, if you go to their employment page, if they have an employment page, or if they are hiring a pastor and whatnot. Let's just say, for example, so-and-so church is looking for an associate pastor. The requirements are he should have a heart according to first Timothy chapter three. So all of this will be mentioned. Okay. So it's like, yeah, guys. He's saying when verse 14, these things are right to you, though I hope to come to you shortly. But if I'm delayed, I write so that you may know how you ought to conduct yourself in the house of God, which is the church of the living God, the pillar and the ground of the truth. Now eventually we're going to look and focus on all those words separately. But you see the choice of words that Apostle Paul is choosing to say to refer to the house of God church is the house of God. Okay. And hence the publication. Okay. The name is titled house of God, household of God, household of faith is all used as synonyms. It's, you know, as alternative to the local church basics. So when you say the local church, I'm saying it's the house of God. I'm saying it's the household of God. It's house of God means that means that's where God kind of dwells. Yes. No, maybe. Okay. Okay. So look at Ephesians chapter 2 verse 19 and Galatians chapter 6 verse 10. They're all in the notes. Let's just give a quick glance at it. Ephesians 2 19 it says, now therefore you are no longer strangers and foreigners. Okay. I've said this many times. Anytime you see the word there for you need to ask yourself, why is it there for? Okay. That means you have to go into chapter 2 from verse 1 to 18. Okay. We're not going to do that, but we'll come. So now therefore you are no longer strangers and foreigners, but fellow citizens with the saints and the members of the household of God. In other words, the local church, in other words, the house of God. Okay. So in chapter 16, it says, once again, therefore, as we have the opportunity, let us do good to all, especially to those who are off the household of faith. Wow. Okay. There's so many titles to the house of God, right? To the local church, the household of faith. Okay. So the notes that says the term house or household refers to a family. Okay. It simply refers to a family. Now we'll discuss about this in second section. Maybe talk about God's blueprint in detail and whatnot. Okay. So let me just ask this question. Is it important for us to be part of a local church? What would be some of the reasons some individuals are not part of the local church? What would be some of the reasons? Why is a few individuals who claim to be Christians, borderline Christians, Christians, borderline Christians, agnostics, atheists, atheists forget it. But what would be some of the reasons why a few individuals choose not to be part of the local church? They don't like rules and regulations. So they don't like to come under the supervision or in other words, they don't like to come under the leadership or they don't like to come under the authority. All the words I'm thinking. Okay. Supervision leadership. They don't like to submit submission. All of that. Denominations. Okay. Clean shave, white and white. Okay. The doctrine, the doctrine might not be right for them. Okay. Of a local church. Okay. Sorry. Lazy. The nail on the head. Who's going to get a brush? One day leave. I get six days. I work for 18 hours. I work. Some of them go to the evening chat, but they go. No. My point is my question is, okay, why do they do want to be part of a local church? The challenge is the lifetime. They want. Isn't it? You don't have a lot for Jesus. You can't even go for work on Sunday. Work on Sunday. Okay. Nina says the significance or the importance of is lost of being part of his body. Okay. Yeah. Okay. Some of them, let's say experience. Some of them might be offended or hurt by the church. Yeah. Like, okay. Because I don't like the way that this church treated me. So I'm not going to believe in Christianity. It's a possibility. That is the reason why some of them would not want to be part of a local church. It's like hypocrites or hypocrites, you know, Christians. Christians are supposed to be known for their unconditional love and extravagant love.  University Christians are not known for that. Isn't it? They should be. If we are, if we are the exact representation of how Jesus is called us to be, the whole world will be evangelized. Isn't it? Some of our church names are bigger than and longer than, you know, I don't know. Okay. The church also, some more names to the church and full India will be evangelized, you know. So, but yeah, so what are some of the reasons that can you think of that? Everything that you've said, yeah. Okay. Fear. Yeah. Okay. Fear. They'll judge me because how I look and what I do, etc. Okay. All right. Let's talk about, sorry. Right. He has something like anything like anything. So he is doing like this and what he teaches. So some local people used to think like this. Okay. If he's like, he's doing this and he's teaching us and he's not able to apply these things and what he will teach us, what he will, so. So not leading by example, in other words. Okay. The leader of the church is not leading by example. Okay. So you're, you're not walking the talk. In other words, as I say, right? They're just talking. Practice what you practice, what you preach. There used to be on older Sunday school song. I'm not sure if you know this, but your walk talks and your talk talks, but your walk talks louder than your talk talks. Have you heard of it? Yes. Your walk, not in darkness. Okay. But it's a lovely song. I sung this in like my Sunday school and I still remember it.  And so one of, I forget this person, but the name of this person because a very complicated name. He said the greatest form of influence is example. It's not one of the form of influence. It is the only form of influence that the greatest form of influence is example. So you say you want influence as leaders as church. We want to influence people as a father, as a son, daughter, whatever. Or let's just say as a parent, for example, when I read the quote that my first thought went, that's the thing. It's like the only, the greatest form of influence is example. And so it's so dangerous living with my son because I will do 99 good things. I will do one wrong thing. And he'll happen to notice only that. And so is this, is this crazy, isn't it? So we are called to represent Jesus as a local church and whatnot. So the notes, it says, why should you be part of a local church? A couple of points, I just don't want to go through the whole thing. It says it is within the local church that you and I live out of membership in Christ's spiritual body, which is the church, right? It is in the church that we grow spiritually in our maturity and whatnot. So that way you look at it is very important to be part of a local church, like to be part of a community where you are strengthened and equipped and empowered where God's word is taught without compromise, isn't it? Right? So it's important that way to be part of a local church. I mean your motivations and your intentions can be questioned, will be questioned. Are you going to be part of a local church simply because you want a space in the burial ground when you pass away or you can have access to the church when you get married? You know, sometimes that's exactly what happens. Yeah, yeah. So, you know, there can be certain benefits of being part of the local church. Now, are you part of a local church for the benefits you get from them? Or you are just part of the local church because you love Jesus and because you are growing spiritually, right? So that's where we grow spiritually and in our maturity example, right? And so when we say that we are the body of Christ, parts of our body is not flying around floating somewhere, you know, it's like the head is somewhere, the hand is somewhere, the leg is somewhere. It's a very weird image, isn't it? Yeah, it's not a very pleasant. So, but we all function together. He is the head, he speaks, we obey. And that's why it's very important for us to come together. And I think God made that point very clear when he said that it is not good for man to be alone, right? In his intention. So, and from the beginning, and I've said this so many times from Genesis to Revelation, one of the things that he keeps saying, you're repeating book after book after book is that I will be your God and you will be my individual. You will be my people, you will be my people, you will be my people. And the last chapter, why does last chapter of the Bible in Revelation 22, it finishes with the city, God talking about a city. It's a collective thing, isn't it? Right? And even about when you talk about the life of Jonah, the only thing we think about is the whale, fish, whatever, and three days that he was in the belly. But the last verse of the chapter says, should I not have compassion on this great city? And city is made of what? All of you are listening and awake. Okay, so the city is made of people. Exactly. So his heart is always for the people. And that's why it's important for us as a church to come together in unity and understand all this truth about the beauty of the church and the wonder of the church and be his instrument. Are you with me? Yeah, okay. So now let's move on to the next chapter. I'm skipping a lot of things because it's all, go through it when you can. The second chapter talks about the purpose of the local church, its mission, message, and methods. In chapter one, we looked at the origin and its spiritual and the natural dimensions of it. So here in this chapter, we look at the purpose of the local church. It has three purposes, three simple basic purposes. Now remember, again, when we started off the session, I did not say that I'm going to give you a bunch of steps. This course is not about giving you a bunch of methods, ten methods, or techniques, or skills, but it's about the heart of God, what the Bible has to say about it, isn't it? So according to the word of God, the purpose of the local church, one is its mission. So what is its mission? We look at Matthew chapter 28, verse 18 to 20. It says, and Jesus came and spoke to them and saying, all authority has been given to me. You see from Matthew 16 to Matthew 28 how the language changes now, when it comes to authority, right? Has been given to me in heaven and on earth. So now it says, go therefore and make the disciples of all the nations, baptizing them in the name of the Father, and of the Son, and of the Holy Spirit. Teaching them to observe, another translation would say obey, teaching them to obey all things that I have commanded you. I am with you always, even to the end of the age. Now all he is saying is now, okay Jesus has won the victory. He is saying all authority has been given to me in heaven and on earth, okay? And now then he says, therefore go and make disciples of all nations, baptizing them. The key point here is, he says go and make disciples, basically he is saying go preach and teach, but he is not saying how to preach or how to teach. He is not giving them any methods or techniques. He just says go preach and teach. Are you with me? And he tends to do this a lot across the Bible when you read even Joshua chapter 1, Joshua chapter 1 between verse 6 and verse 9. Okay, you can read it later.  He is saying, but instead be encouraged. Sorry? I will never leave you in office. Let us be encouraged. Don't be dismayed. Be strong, be encouraged. Be very strong, be encouraged. So between verse 6 and verse 9, he is saying that at least three times. He is saying don't be discouraged or you are saying be encouraged and be strong. Be encouraged, be strong, be very encouraged, be very strong. Not once does he say how to be strong and how to be encouraged. But in verse 8, between verse 7 and verse 9, he gives a small hint.  Meditate on the word. You know, he is kind of giving you a clue. Okay, so similarly here, he is saying go and baptize them, you know, and make disciples of all the nations and whatnot. It doesn't exactly give the exact methods. Okay, start one, step one, etc. This is how you are to preach and teach and whatnot. So the mission of the local church is very simple. What is it? We just looked at it. The great commission. Yeah, go make disciples. Yeah, baptize them, preach the gospel, teach the gospel. That's the mission. So and how is that connected with the local church is now the great commission help establish the local churches and the local church helps in accomplishing the great commission. You see how that goes hand in hand, right? The great commission helps establishing the local church and the local church helps accomplish. It's like a cycle. Is that clear? Right? So that is the mission, you know, and the purpose when it comes to the local church. And so when Jesus says preach and teach or make disciples, so that means what is the message? What should be the message? The gospel. It's as simple as that, right? The gospel is the message of the church. Okay? So we are to preach the gospel of our Lord Jesus Christ. Right? The work that he completed on the cross, the healing, the salvation, the deliverance that he's made available to all of us. Okay? Hey, just a side note. Are you not feeling warm? I mean, you can put on the fan if you want to. Guys, ask and you shall receive. The Bible says you have not because you ask not. Hey, how's everybody online doing? All okay? Samuel, Lovely, Prabhu, Nina. Awesome. Okay. Okay. So what should be the message of the local church as we are at is the gospel of Jesus declaring what he has done, the message of the cross. That was pretty much the only message of the first century church. Right? They preached Christ crucified and that he rose again from the dead. Right? That was the only message. Like now somewhere along the way, we've kind of seemed to have lost the wonder of it, of that message of the gospel. But as again, Paul says, and you know, time and time again he says, this is the gospel of power. We don't need to add anything to it or subtract anything from it. Right? It is powerful enough. So he's encouraging us to preach the gospel and that is the purpose of the local church. And then he also says that preach the whole council of God. So it's in your notes and if you're looking at PDF or in your hard copy, where are we? Page 16. At the bottom, it says as ministers, we are to preach, teach and proclaim the whole council of God. So that means that the whole council simply refers to the sound doctrine. Nickel. Doctrine. Right? So we said some of the reasons can be the doctrine of the church and whatnot. So he is saying, preach the whole council of God. Preach and teach the whole council of God. So it simply means don't just preach grace, grace, grace, grace, grace, grace, grace. Now if you preach just about grace and miss out and you don't preach about truth, you're missing out on the whole council. Right? And if you don't teach about, say if you're only teaching about the truth and you just leave, you don't talk about the holiness of God or you don't talk about any other different aspects of God. How about he's faithful? He's merciful. So many other things, isn't it? So what we are encouraged here to do is to preach and teach the whole council of God. Everything about who he is needs to be taught. Don't get caught up in just one thing. And that's what people need to hear. Everything about who he is, isn't it? So I mean, I let y'all go through the Bible verses there that is mentioned in your notes. I don't want to go through it. And so what that will do is when you're preaching and teaching the whole council of God, that will guard you from every false doctrine. Now because, let's say you focus on just one topic.  Why is that important? Because another attribute or another aspect can validate another aspect. Right? Now the truth can validate what the, what the grace of God is. Now when you're speaking only about grace of God, you might miss out some of the truth that can support this. So it's very important to go back and forth. And so that will protect you from all the other false doctrine, isn't it? So when people understand the truth, they will be able to identify the error and stay away from it. So you all know how people identify fake currencies, right? How do they identify fake currencies? By being in touch with the real. By being in touch with the real. Yeah, thanks. So what they do is the person study the authentic note really well. They don't, because they can be any number of fake notes, fake currencies, isn't it? Like, there can be so many things. So they study the real, authentic, credible currency really well. And so when they know the truth really well, okay, so this is how it feels. This is how everything should be. When they look at a fake one, they're not wasting time. It's like, yeah, this is fake. Are you with me? So when you understand the whole counsel of God really well, and you let the Holy Spirit teach and reveal the things of God to you really well, you will know it. You will know when a doctrine is false. Yeah, so yeah, that's that we are to preach and teach the gospel. We are to preach and teach the whole counsel of God. And that will help us identify false doctrines and whatnot. Okay, so we have the mission. We have the message. And then finally we'll talk about the methods. Okay, so the methods we must be, when we use must be aligned to the standards and the directives set forth in the word of God. You know, you might be like, okay, hey, Roshan, I thought we're not going to discuss about methods. You know, we are not. We're simply looking at what the word of God has to say. Okay, the word of God says our methods must be pure. In other words, it shouldn't be impure or we shouldn't deceive or manipulate God's word for our own benefit. Okay, we must not use deceit or manipulation to achieve our objectives. Now the objectives can be anything.  So I will do whatever I have to do to make it rich and famous. I was taking a class for the final years on worship ministry and I was just telling them how worship ministry is a priesthood and how worship ministry is now become an industry. And so ministry in general, in a sense, it's lost that essence that it's a priesthood, guys. It's only about serving. It's not about fame or gain or to make your name known, your name famous. It's not about that. But somewhere along the way, we have lost, right? The blueprint of God has become peripheral for us and the world has become the main focus. Isn't it? The who? The K-love awards, okay. I've heard of it, yeah. Essentially. Right, right. Yeah, as in we learn more about that in worship ministry next year about what do you think about awards and whatnot. We won't discuss about it now. But in general, the point here is that our intentions and motives should be pure. That's the point here, right? Methods, it doesn't say what methods you should be using but whatever you choose to do, that should be pure. Right, is it acceptable unto God? That should be the question. Isn't it? I mean, it's so important all the time for us to get the question right. We need to know how to ask the right questions, okay? Because there was a time, so I was helping out a ministry called Face to Face along back and I mean, still friends with them. But in 2011, we started doing the leader of the ministry wanted to do like a seven day nonstop, you know, praise, worship and word intercession and whatnot, right? So seven days, when we started doing that, one week, one seven days, I think it has 166 hours. I'm not sure. 24 times seven, you can calculate and tell me.  We were inviting people, you know, it's like, hey, we're going to have this 24 seven prayer word and worship and whatnot come and join us. I think in 2011, it had not happened a lot. So it was, I think, happening for the first time for seven days. So the question, these were the questions that kept coming up. Hey, why are you all doing it? Are you all trying to set a record, a world record of some sort? You know, the questions were very different when the question should have actually been this. Is Jesus worthy? Is Jesus worthy of your seven days of 24 hours worship and intercession? Is he worthy? He is worthy, isn't it? So that is the question. So when you ask, when you look from that perspective, everything changes. It's like, yeah, he is worthy. And that's why we're going to do this, not because to make our name famous, right? Not to create a record or whatever, whatever, right? And so, I think as leaders and everything that we do, we need to keep our hearts pure and, you know, very transparent. Make that prayer like the psalmist cries, or search me and know me and see if there's any wicked ways in me. Constantly be before him. Lord, search me and know me. The audacity of that prayer is so profound. Search me, Lord, and know me. I want to do this. Is it aligning with your will? Is this what I'm hearing, right? Because we were called to be instruments and whatnot. So methods ought to be pure. And another important point there is not offensive yet without compromise. Let's go to page 19 at the bottom. Because I'm leaving out a lot of scriptures so that you can just read by yourselves, okay? Not offensive yet without compromise. That simply means you have to speak the truth and you speak it in love, okay? You speak the truth but you speak it in love. Now, let's take an example of LGBTQ or homosexuality, you know, homosexuals. There's only two response to that community from the world. The response one is they are hated on other responses that they are accepted or they are affirmed. They are hated or accepted. Now, as a Christian, I cannot hate them because of the Word of God. I cannot hate them because of the Word of God. I cannot affirm them also because of the Word of God. Yes or no? I cannot hate them because of the Word of God. I also cannot affirm them because of the Word of God. But that does that mean do I compromise or dilute the truth of what the Word of God says? I cannot change the Word of God or add to the Word of God. It's not my book for me to change anything. If I was the author of the book, I will go back, re-edited, okay, version 2.0. I can't do that to the Word of God. Isn't it? Just to accommodate a community. I speak the truth. This is what it says. But I do it in love. I'm not hated. Isn't it? So that's the method it says, don't be offensive. And yet there are times when you speak the truth in love and you don't mean to offend someone. People will still get offended. But you cannot help. But what is your intention? Is your intention going up the pulpit just to offend people? Again, it comes down to the purity and the intentions of your heart. Isn't it? Everything kind of flows from the abundance of your heart. Isn't it? You speak. So you don't compromise yet. You speak the truth in love. You demonstrate spirit and power. Be spirit-led. That's the point of all of this. Be spirit-led. The methods or the methodology has changed over the years. It will change. The worship that happened in the Tabernacle of Moses was not the same methods used in the Tabernacle of David. The methods changed, but the principle remained the same. The methods of giving 2,000 years ago could be very different from the methods we give. But the principle is what? Giving. It's the same. It doesn't change. And so we are constantly inclined to the Holy Spirit, to His leading, to His guiding. What He has to say, what He has to teach, what He wants to do in and through us. So that's basically chapter 2, guys, is that we remain sensitive to the voice of God, to the leading of His voice. That we remain a sheep of flock that knows the Master and hears the Master's voice and knows His voice. Are you with me? Right? We know the Master's voice and hear His voice. And one of the things that I'm concluding with this, one of the things that God wanted to instill into the people of Israel when He was bringing them out of the land of Egypt, is that for 400 years that they were in Egypt, 400 years is equivalent to 10 generations. For 10 generations they are used to seeing the gods of Egypt. They are used to seeing and the land where they come from called Goshen, land of Goshen where you read in Exodus, isn't it? It's a plain. That means you could see for 10 kilometers of what is ahead, who is coming, who is going. They could see.  But when they came out of Egypt, now they are suddenly in the wilderness. They are these mountains and hills. They don't, they can't see around 10 meters and they panic. They cannot see. They don't know where exactly they are going. And so what God wanted to teach them was to become the people who will hear His voice and follow His voice, that He is the shepherd. Now you read the Scriptures time and time again in Deuteronomy. It says that He led them like a shepherd in the wilderness. And the sheep will only follow by the leading of the shepherd's voice. And so we as a church in John 1010, I mean John, not 1010, but in John chapter 10, He says He is the good shepherd. He is the good shepherd. And time and time again in Scripture says He is the great shepherd. He is the chief shepherd. And so as a local church, we ought to live life or live according to what we hear, what He has to say continuously. Okay. So that's chapter one and chapter two. Thank you all for joining. We'll conclude today's session and I'll see you all again next week. Okay. Thanks for joining everybody. God bless you. See you.


Hey everybody what's going on it's your man Kory welcome to the digital dash I'll be giving you guys tips on how to market your songs and get those numbers booming now for those of you who don't know who I am I'm a digital marketer myself I specialize in helping artists like you guys get their songs heard through platforms like Spotify Instagram YouTube and a bunch of others now what I want to talk to you guys about today is how you can go about getting your songs onto these streaming platforms like Spotify like Apple Music like Pandora and so forth I've realized that a lot of newer artists don't necessarily know how to move their songs from free platforms like SoundCloud and AudioMac onto these pay streaming services so that they can start to utilize them so I want to show you guys how you can do so now if this is something that you already know how to do may not want to stick around for this video unless you just want to know what I think about these two platforms that I'm about to mention so with that being said let's get right into it now in order to upload your music to these platforms you need what is known as a distributor or a distribution service now the two that I always recommend are digital kid and tune core mainly because I know they're both pretty professional and pretty reliable that ones that I've worked with in the past myself I also have friends and peers who swear about them both for various reasons depending on the platform now as of right now I have a digital kid account so what I want to do is walk you guys through the back end and show you what it's like to upload your songs directly through the platform while using digital kid itself so with that being said let's get right into it all right guys so here we are inside of the digital kid account now obviously the first thing you need to do is come to their website sign up and make you an account once you do it or take you to the option to pick between one of their three tier plans so as you can see here they have the 1999 a year plan the 35 99 a year plan and the 79 99 a year plan now each of them does allow you to upload as many songs as you want a year which is one of digital kids biggest plus personally I would recommend that you guys go for the musician plus account the reason being is as you can see each of them has their own unique benefits you know that kind of coincides with what the plan is the reason I say go for the musician plus account is because it's one that allows you to create your own label name for your releases so if you know anyone with a digital kid account you've ever seen something underneath their song that says like DK 10096 or something like that that means they have a musician account and personally I think that's ugly I think that you guys should definitely be naming the label place for your releases even if you don't have a label just make something up like make up a company name or something but don't just leave that little you know number that they create like I said I don't like the way that that looks so once you create your account it pretty much takes you to the homepage and that's what we'll get started guys so here we are inside of my dashboard I created a digital kid account just for this video from my company Artic Society I used to have a digital kid account a couple of years ago for this job that I was working for but once I stopped working for it obviously they didn't let me keep the login information so I have to show you guys how to do this kind of from scratch so you just want to come to click here to upload music and once you do it takes you to the page that you need to upload your music to Apple Music to Spotify to title to Deezer all of that so as you can see they do distribute to all of the main stores so all of the ones I just mentioned plus some like iHeart Pandora Amazon all of pretty much the main services and then some so it's a pretty standard release form you know you need all of the simple information just like how many songs are you releasing has this song been previous released on streaming platforms before your artist name the release date do you want to have it pre-ordered do you want your fans to be able to buy this song before it actually hits the stores you know that way you can put a little extra money in your pocket before see who really supports you do you want to just leave that blank and then we have the record label name which like I was talking about earlier guys this is very important I like I said I think that DK with the number is very ugly very unprofessional looking so that's what I would shoot for one of the higher tier plans if you can if for nothing else for this reason alone this show kid also creates UPC codes for you and your music so if you don't know how or if you don't have a UPC code for any of your releases they'll do it for you which is actually pretty helpful and then like I said all of the other basic things like the album cover what language the genre you're in and then the track title it also has an option here for if you're someone who's uploading a cover song that they'll let you release those songs to platforms through this show kid which is actually pretty helpful I'm not sure if other streaming services allow you to do this and I know they also have a kind of blanket protection for songwriters who are doing cover songs which I'll show you guys a little later in the video and then once you get all the information typed in so your track price for things like iTunes and Google you have the files uploaded let them know the lyrics so once you get all the information typed in you would just want to scroll down here to the bottom and they have a couple of extra options for your releases that you don't have to go with but some of them are actually pretty useful for instance the store maximizer which pretty much less this show kid put your song into any new stores as they get created so let's say for example that I wake up tomorrow morning go hmm I want to create a streaming service I think I could compete with Spotify I'm gonna make XYZ streaming then this show kid would automatically put your song into XYZ streaming without you having to do any extra work so it's pretty useful especially for today where we have streaming services popping up left and right and then there are also streaming services out there that you guys may not even know about and there are literally dozens or even hundreds of these streaming sites that you guys probably have never even heard of and having something like this keeps you from having to keep up with all of that and another cool feature is the lever legacy feature which isn't necessarily as needed as something like the store maximizer I just think it's pretty cool about this show kid is they won't delete your song from a store just because you stop paying your membership fee so if you were to you know worst-case scenario die and you couldn't afford to keep paying to keep your song on these platforms they won't delete it so that way your family or whoever you know gets your stuff would still be able to collect your royalties from this show kid from your songs while this even while you're gone which is which is pretty cool and then you would just check all these boxes and then click done and boom there you would have it your stuff will be on its way to being into stores so one of the things that I do like about this show kid is it does seem to be a lot faster than some of the other distributors so I have friends who personally use this show kid and they swear by it one of my best friends uploaded his song to this show kid on a Monday and it was in Spotify by Thursday which I think is absolutely insane that's actually pretty fast I use other distributors and sometimes it takes them like a week even a little bit longer to get songs into these other stores so that's another one of their major selling points is that they are actually pretty fast and I also want to show you guys the settings page just because it has a couple of other cool features that this show kid does have so as you can see here you can get your lyrics uploaded into Apple music and iTunes have this function called the hyperfollow function which it pretty much creates a link for you and as soon as someone clicks on the link it automatically follows you on Spotify and automatically saves your song to that library which is pretty cool you can get your Spotify for artists account created through this show kid and you also have the ability to whitelist certain songs from the YouTube money claims so if you did some kind of like collaborative effort with a YouTube channel let's say you got your stuff on to no jumper and they were like we're gonna claim the money for this you can just easily come into your digital kid and take that claim off the video so that you could under the partnership and like I was talking earlier about the cover songs for the songwriters they do help you with the licenses so that way you don't get sued and your stuff doesn't get taken down which is another thing that I also find very cool about this show kid I don't know how many other distribution services actually help songwriters and cover artists keep their stuff online or even put it up for that matter but you know even past that help you actually make sure it stays online and doesn't get taken down and that you're legally protected to keep your music out so yeah that's something else that I think is really cool about the platform so yeah there it is guys I just wanted to show you all the back end of digital kid just so you can get the idea of it see if it's something that you would like like I said some of the key points of it I really like is that it is a lot faster some of the other distributors it's pretty cheap as you saw the 1999 plan and the other two plans like that's not a lot especially for a year you know that's like dollars a month to save up just to make sure your music stays out there so yeah check it out see if it's something you're interested in if it is you know get to it guys all right guys so there it is that's how you will go through that process if you decide to go with digital kid now another one that I could definitely recommend is tune cord it's a service that I reliably use for the past couple of years until I start to get into this joke it now for the most part they do pretty much the same things meaning that you can also get your songs into all the major platforms to tune cord you can also monetize your YouTube use it as a publishing administration all of that their biggest draw at the moment is that the only distribution service that allows you to monetize your music on Facebook and Instagram now I'm sure that is something that all the others will offer in the future but as of right now that the only one that does so so if that's something that you're interested in I would definitely check out tune cord now if you were to come to me and say Kory I've looked into them both I like what they have the offer but I can't decide between the two which distribution service should I go with I would look in your eyes and I would say this joke it now I know earlier I said that for the most part they both pretty much do the exact same thing so I'm sure that you're wondering why and the reason being is money now in the long run tune court can definitely add up to being the most expensive option of the two with tune cord is a fee for you to create your account there's also an additional fee for every album or song that you want to upload so if you're an artist who drops a lot of songs you'll definitely start to run those pockets a lot more I also know that a lot of indie artists watch this channel and I'm pretty sure that you guys are trying to stretch your dollar for as far as it can possibly go so luckily for you guys I partnered up with this show kid to get you a little something off your sign-off fee if you go into the description and check out that link and use it and make sure you get like seven percent of something off your sign-up total if there's something that you're interested in definitely go ahead and check that out now as always guys if you feel like you learned anything today please like and share this video hit those post notifications as well as I wouldn't want you guys to miss anything once again my name is Kory and I'll see y'all next time


Hello everyone and welcome back to the series of lecture on actinical chemistry. In the last lecture we have studied about some spectroscopic aspects of proletariat and actinide and in continuation to that we will try to understand some of the utilities of the emission spectroscopy and here as we have also discussed in the last slide last lecture that how we can record this spectra that is the excitation spectra emission spectra and actin spectra and here the excitation source we are using is basically some electromagnetic wave that is basically UVVs generally we use we generally say it is like photo luminescence and in short form we also say it like PL studies so in this photo luminescence we excite with the source and then we measure the emission and we will try to extract some of the information that we are getting from this excitation spectra and emission spectra as well as on the lifetime spectra. So in brief I have told you that how to measure this excitation spectra in the excitation spectra or to measure the excitation spectra first thing you have to do you have to fix the emission wavelength you have to fix it and once you fix it then you just scan the excitation monochromator and then you will be getting some peak so suppose I am taking an example of europium 3 and this peak generally comes around 394 nanometer so this is my excitation in which my emission is fixed my emission is fixed when I talk about the emission spectra what I will do in emission spectra since I know this is the peak that is the giving the maximum excitation I will fix my excitation at this peak and then I record the emission spectra so by that we are having information about the excitation spectra we are having information about the emission spectra then what we will do we will take this maxima this maxima we will fix this to maxima and we will try to record the decay half life or the half life of the or the decay life of the complex that we are interested in so as I showed you that we can measure excitation spectra you can also measure the emission half lives we will talk about that emission half life later so what are the information that we can get from this excitation spectra I have shown you several excitation spectra that I have taken from Google so you can see there is a difference when you start from A to E you can say sometime you are getting and most of the time you are getting peak in this reason and that is the excitation spectra of europium with some complex so you are getting a peak at 394 but if you see there is a difference here and sometimes you get a peak here so what this suggests and marking of information we can draw on this kind of spectra let us assume that you are having a two complex then one complex I say is europium L and the other complex you can say like europium L2 let us say this is one and I am just arbitrarily assigning europium L1 to this spectra and the L2 to this spectra so just by looking at this spectra what I can say there is a difference in this but it says that this sharp transitions are in both this spectra so we know that the FF transitions are sharp but you can see this transition is not sharp this is a broad addition and it is not an FF transition rather it is a charge transfer band or charge transfer transition so what we can say from this charge transfer transition or charge transfer transition band is that out of these two complex that I have written to say L1 L2 this particular ligand that is L2 having a better overlap or more overlap to europium rather than L1 so what it is doing there is a charge transfer you are exciting the ligand and ligand is transferring to the europium and from there you are getting some emission so we can get this kind of information from the extension spectra even in certain complexes the charge transfer band is so large or you can say so intense because you take this spectra of europium with TTA I hope you must have heard this name TTA in your extraction classes if you take the spectra of this the charge transfer band is too huge you can say as these transitions are just like very very small as compared to the charge transfer band so the information of the metal ligand or overlap can be seen from this kind of spectra okay now you have some excitation spectra and then you are sitting on the excitation maxima let us say here or here whatever excitation maxima you choose and then you record an emission spectra so suppose I hit on some maxima and then I record the spectra and suppose again I am just arbitrarily assigning it L1 and L2 and you get some kind of spectra like this European L1 and L2 so what just by seeing this spectra one thing is very clear to me the spectra do not look very much similar so what I can say that the environment around europium in these two complexes are different what it is we will see later but it is different as we see this is different from this so this is the direct information that we can get from emission spectra but we should do it very closely then we can see there are several transitions that I have marked there and you know that we start with FD0, FD0, FD0 and we give transition to 7F0, 7F1, 7F2 and all the transitions are marked here so let us say the first transition that is 5D02, F1, F2, 0 many times we just say this is J0 and this is J0 so many times we just say it is like 0, 0 transition sometime I am also using the term like 0, 0 transition so if you see this 0, 0 transition then it is like 0, 1 this is 0, 2 like that you can name like that also so the information that is there in the 0, 0 transition let us see pure 0, 0 transition but this is my 0, 0 transition that happened to be found near 550 nanometer for europium we also know that the transitions that we say that are coming from 5D0 to 7, 0 to 7F1 we have seen that there is a splitting of J level there is a splitting of J level and this J level will be split into 2J plus 1 states that I have seen in the previous slide like this yeah you can see that this J level depending on the symmetry can split maximum into 2J plus 1 so but when we see about the 0, 0 transition what is the J value, J is 0 so you have 2J plus 1V, 1 so you can say even in symmetries of different environment this transition cannot split what is the use of this let us say let us say I have a spectra I have just recorded a spectra I am getting it like this and the reason that is maybe 577 to 579 or so I am getting these 2 peaks one thing I am sure this is not the splitting why because it is a 0, 0 transition so what information it gives to me that there is at least present of 2 europium species with 2 different dominant species of europium are present in the complex so this kind of information I can that figure from this 0, 0 peak let us say the other peak that is 0, 1 peak the 0, 1 peak can split into J plus 1 giving rise to 3 so if you are having this peak as you can say in this spectra there is some splitting similarly when you are having to 0, 2 this can give you 5 peaks so it can split into maximum 5 this all depends on the symmetry around the europium ion so lower is the symmetry more is the splitting so we can get information about the symmetry class if you know splitting of all the lines and then you have to just see the table and suppose you are having some system which is having XR on the symmetry and if you just see the first should be 1 then the second should be split into 2, third should be 3 likewise if you see if you are matching with splitting of your splitting of the pattern is matching with this table then you can safely say that that the symmetry around my europium ion in this particular complex is XR 1 so you can get that information also from this there is one more thing that we can know as asymmetry ratio so suppose they are having a transition 0, 1 and then 0, 2 and we have two transitions 0, 1 transition we have discussed it is called magnetic dipole whereas 0, 2 transition is called electric dipole we have also seen that this magnetic dipole transition do not get much affected by the ligand environment so if we take the ratio of the electric dipole transition to the magnetic dipole transition we are getting something that is called asymmetry ratio that is we are taking a ratio of the electric dipole transition with the magnetic dipole transition what it means that the 0, 2 transition divide the 0, 1 transition and in a typical spectrum of water if you take this ratio the water spectrum is like this one then this this is your 0, 1 this is your 0, 2 and if you take the ratio it will be somewhere between 0.6 so generally it so happens that when there is an increase in this ratio we say that the asymmetry around the europium ion is increasing so that asymmetry information also sometime we can derive just by using this asymmetry ratio so now we can derive some information okay we know this is the symmetry and this is the kind of complex that is there with europium now let's try to see how we can deal about the lifetimes I'll come back to this slide after sometime yeah so we also kind of record the lifetime in which we fix the excertion spectrum we fix the excertion wavelength we fix the emission wavelength we fix both that's certain wavelength and then we give an excertion pulse and then we monitor the decay and when we are getting this kind of decay we simply use this equation to fit this decay and depending on the nature of the complex we can get different lifetime but generally we start with the mono exponential we fit and then suppose we are not able to fit then we go for the bio exponential and try exponential but generally we restrict ourselves to bio exponential only but can fit it into different kind of exponential until once you are getting a good fit but not more than bio try because if you are using a very high exponential then it gives a good fit but it is logically not very valid so why the lifetime is getting decreased generally assume that for the lengthenite cases or the ignite cases the decrease in lifetime is mainly due to the water we can say it is the OH vibrations of the water molecule so most of the time we assume that the decay in the lifetime is mainly concerned with the vibration of the OH excertion of the water if water is the only responsible ion for the molecule for the decay then we can directly relate the number of water molecule in the primary sphere to this decay curve and it has been done and this is the relation this is the linear relation basically that directly relates the number of water in the primary adjacent sphere to the decay line so you have to just fit the curve you will get the decay constant and from the decay constant you are just putting into this equation and from this equation you can getting the number of water in the primary adjacent sphere and for european it so happens that the lifetime in water is coming around 110 microsecond which is giving you a life water molecule around 809 so for european we can get this 809 water molecule with lifetime of around 110 microsecond okay what is the utility of this let us assume that you are having european with let us say eight water molecules one two three four five six seven eight and then you add a ligand in the system and suppose your ligand is a bioenter system what will happen we assume that it will just go and bind to the mental ion so that now my ligand is here so you can say out of the eight position two positions are occupied by the ligand molecule now if I just measure the lifetime of this molecule and we will get the number of water molecule which we are getting eight in the case of european with the aqua ions or in the aqua adjacent sphere this should be reduced to six so if the hydration number is reduced to six we can say yes there is some complex formation similarly suppose you increase the ligand concentration or the pH depending on the nature of the ligand you may be getting minus two two complex assuming again a bioenter ligand then four water molecules should be deployed and then by putting this equation you should be able to get four water molecules only so that to exemplify that I've given you the example of a compensation with some polyamino carboxylate and this is for a curium and they again for the curium we can see this is the equation they use these are the various different polyamino carboxylate ligand and if you see the first one here you can see you start here which is the hydration number of around nine to ten and the movement you add this ligand at pH two there is a sharp difference in the number of hydration sphere what does it mean that at this pH there is a strong complexion that now the ligand is complex then most of your water molecule has been removed compared to that if you see this curve if you see this curve there the number of primary hydration sphere are still intact there are some water molecule in the primary hydration sphere you can say about the density of the ligand that will affect the by the density of the ligand here you can maybe having a one to one complex or here maybe you are having one or two complex but whether it is one of two one or one to two we cannot say directly by this because that will depend on the density suppose you are having a ligand which is having such as ADTA even with one is to one it can remove mostly all the water molecule from the your inner sphere of the metal ion this is for NTMA again you can see the two plateau at certain pH you are having one is to one if you increase the pH you are getting one is to two so just by recording the lifetime a different pH you can have some information about the number of water in the primary hydration sphere and you can also tell something about whether it is a one is to one complex or one is to two complex till now it is okay let us say we are having only one species the things are looking very easy till now but suppose in the system we are having more than one species suppose you are having let us say two species you are one of two one and fewer ones to two you are having a mixture in those cases what will happen that instead of a mono exponential curve you will get some curve which is it can easily be fitted into a bi exponential curve you will get a curve like this and when you fit it into the mono exponential you may not be getting very good fitting then you go to the bi exponential fitting and you are getting some good fitting so now we know that your system is having more than one based on the lifetime spectra but suppose I want to know that what is the emission or excitation spectra remember that this excitation and emission spectra that we have recorded that we have recorded in the steady state when I say steady state it means there is nothing to do with the time we have just excited and we have recorded but the decay lifetime says there are two species and suppose I am interested in getting the spectra of both the species that okay what is the spectra of the short lived or one of two one complex and what is the spectra of the long lived or must do complex so now as I was telling about that suppose you are having two species and you want to know that what is the contribution or rather what is the nature of the spectra of one of two one and one of two two for those kind of cases we cannot use the steady state emission profile why because there is no mining information but from the timing information that is the lifetime spectroscopy we know that one species is decaying faster than the other for simplicity I have assumed two species let us say you have a system which is having two species one is decaying with the lifetime worker 100 micro second and another with the micro second when I say lifetime I mean this is 100 micro second when we record the spectra if you look it carefully suppose you record a spectra which is giving like this these pieces with 100 micro second will decay first and that species with 500 micro second will be having a long tail why because the the key constant that we derived is just by fitting this equation if you see this equation these two equation then we can say okay 100 is decaying very fast compared to the 500 which is obviously giving you a tail and I want to record the spectra so initially with a steady state suppose I record a spectra which looks like this that I've given here and this is the steady state that's I have written t is equal to 0 and for simplicity I assume that these two peaks this peak and this shoulder is coming from the shorter component that is the 100 micro second component and the rest of the spectra is the from the 500 micro second component so what I want to record I want to record both I cannot do with the steady state so now what I will do I will do time residual fluorescence spectroscopy and this what I will do I will excite my complex with a wavelength that is say 394 in this case and then I'll wait for certain amount of time why to wait because suppose I excited this particular time and I'm waiting for this time this is my waiting time this is time I'm waiting and then I'm recording spectra what will happen let us say you have 100 and 500 and you are waiting for around the 500 micro seconds suppose this limit is around 500 micro second if you see the decay of the 100 micro second species in the 500 micro second species you'll find that if I am waiting up to 500 micro second you have given almost 5 life to the 100 micro second species whereas for the 500 micro second every one only 1 so if you see the decrease if you see that the intensity which is a combination of both 500 and 100 but if you see the decrease the decrease is this the intensity decrease is proportional to e to the power t by tau in this case is my t is my waiting time so my t is 500 and my rho is only 100 so here I'm getting a value of 5 it is the power 5 you can see my intensity at around 500 micro second is nothing but I know divided by it is power 5 which means that there is a decrease of almost 140 times so there is a decrease of around 148 times in the excitation state of the smaller component whereas if you see the longer component it has only one half life or one decay life so for this the decrease is just like 2.72 times or mainly the signal that is there is 63 percent from the L2 and hardly 1 percent from the L1 or you can see the shorter component so if we are giving a decay and you are missing after a decay the profile which you'll get is mainly composed of the long live component so I'm expecting that this peak should be not there the first peak then we are getting second peak and the shoulder should not be there and where should there be so if it is a spectra of a plus b then this should be the spectra of the b assuming that b is having a lifetime of 500 micro second so in this way you know a plus b you know b and you can you can subtract a plus b minus b this is not that direct we have to understand the quantum also but assuming that everything is the similar for both the complexes I can say that you can just subtract it to get the a so you can record the exception spectra as well as emission spectra using this time results in spectroscopy so now we have some idea and some application of for this spectroscopy now I just want to have a very brief discussion about the retrospective that we have already discussed but I just want to give you some of the examples that for the ectonites I have already discussed to you about this table that what are the redox potential of different ectonites and from this table you can easily see that some of the redox potentials are way on higher side so let us say for thorium it is high so it is very difficult to reduce thorium 4 to thorium 3 but some of the ectonites such as the plutonium having redox all of around one volt so there are a lot of chemistry a lot of redox chemistry can happen so why we require this redox chemistry because many a time it happens that we require this for the separation because most of the time our separation is based on the oxygen state of the metal ion and you must have heard and you must have listened this purest process about the purest process many a time we play with the oxygen state for their determination that is the generally we do for the pyronym estimation using a Davies Gray method and suppose you want to understand the chemistry of the retinal oxygen state even in those cases we want to have information about the redox potential so that we can play with the redox potential and with certain complexing agent or we can add some you know some different kind of redox couple that can either easily reduce or oxidize my metal ion so to exemplify suppose I've given a very simple example let us say that from our class book chemistry suppose you have here having a couple of iron that is getting reduced to iron 2 and you are having a couple that is between iodide and iodine gas so suppose I take these two and I will mix them and after that I'll just add a drop of starch what I found then the color of the solution is becoming blue why the color of solution is becoming blue because if you see this couple it so happens that the reduction potential of this is 0.77 the first one iron and reduction potential of this is low that is 0.54 so it so happens that iron will get reduced whereas this will go oxidize to iodine gas and when you are adding starch to the iodine gas it will make a complex that will be blue in color now to this blue color you add two drops of edda now what edda will do edda can complex iron 3 plus and iron 2 plus and the moment it will complex their redox behavior will change now the reduction of couple is no more 0.77 rather it decreases to something like 0.12 and since the redox potential has been changed so the course of reduction will change and you will get a colorless solution why because now there is no more iodine now what you are getting is now iodine is getting reduced to iodide and your iron is getting oxidized to iron 3 plus so this is the variation in the redox couple I just want to emphasize just by addition of some ligand how we can do it mathematically it is a very simple equation that I've taken from a paper you can just easily see that suppose we are having a redox couple that is m plus is going to mn minus 1 and you can always write delta g for that similarly similarly suppose there is a complexation for the complexation you can again write so this is the you have started with the oxidized one this is the product that I do use one again you can write for the complexation I am assuming that l is a neutral ligand and when you write this you can write the corresponding stability constants also that is k m and k mn and with simple mathematical juggling what you found that you can easily write this equation and if you closely look at this equation then now you are not talking about the pure meta line now you are talking about the complexes the ml complex is getting reduced to ml2 complex with the total gain of n electrons so now we are talking about the redox potential of this particular couple and if you see mathematically what we found if you write the equation for this you found that the e0 complex is nothing but e0 aqa minus rt upon nfl km upon kmn this is the important term why because now your potential is totally dependent on the stability of these two complexes as I have shown you that edt example that the complexes of edt with iron 3 and iron 2 their stability must be different so their stability constant must be different so which is more stable depending on that you will get a potential which is either left shifted or right shifted your potential may be more negative than the original or maybe more positive than the original one generally it so happens that when you are adding some kind of complexing agent some of the complexes get stabilized and you will get a reduction of the lower potential and this is again just I have shown you that the davis gray meta it is a very important method in the estimation of uroname in the nuclear industries here what people have done that they played cleverly with the product potential of iron complex iron couple and iron couple so if you see that the iron couple having a potential of around 660 millivolts in sulfuric acid but the moment you start adding phosphoric acid there is a decrease in the reduction potential whereas under similar condition if you see the couple of uranium that is almost unchanged and then rising so here if you see that the reduction couple of iron is higher side than the uranium whereas the reverse is true here what it means that here iron will try to reduce and uranium will get oxidized whereas here uranium will get reduced so now you are having uranium 6 that will get reduced to uranium 4 so now uranium 6 will get to uranium 4 uranium will get reduced and iron will get oxidized so just by changing the media we can see there is a huge effect of medium and the potential and just by with the playing the media we can play with the reduced potential and that is generally used to carry out different transformation that a lot of transformation even for the actinides but instead of metallic reducing or oxidizing agent we are mainly preffering something which is the kind of more organic so hydroxylamine hydrochloride or hydrazine or some time hydrogen peroxide they are mostly used in changing this couple of actinide and some of the reagent that are generally used for necronium in aqueous phase are given here and similarly for protonium also have given here so this is just to make you understand that in different kind of media the potential can shift here and there and this understanding of potential and this understanding of their shifting with different kind of reagents are generally used for their either selective reduction or selective oxidation and this process along with the acceptance that we use are generally used for the operation chemistry or understanding the chemistry of the lanthanides and actinides into the aqueous phase and with this I just want to end the today's lecture and thank you thank you very much


Keep fighting keep fighting everybody. All right. I'm leaving the office and going home for the day Well, I'm working tonight, but I'm going home for the day true love's gonna give me a haircut. Thank you, hun Basically, though. I got it guys. Don't give up The biggest what just happened. I'm gonna geek out for a second the biggest youtuber slash vlogger In the world in the world Just liked My tweet on the Twitterverse. I know that's like not a big big deal But yes, you guys know him Roman at wood. He has I think 13 Million subscribers are just under 13 million subscribers on YouTube. That's a big deal That's he basically has his own TV network. So he I was just making a shout out to him saying thank you for Three words because he shared these three words maybe about a year ago, and they are this Just keep Uploading just keep uploading three words. It's like such a simple reality, but for whatever, you know, this could be just keep Mowing just keep painting just keep studying just keep running just keep Working on your car. Okay, that's more than three words basically like don't give up don't give up Don't ever give up. Thank you, Roman. If you're watching this for giving me a little a little love there on Twitter It's just a big deal. Thank you, Roman. Appreciate it. I just had to geek out there for a second.  Yeah, I guess what's hair stylist hair stylist.  How do what I cut my own hair? Just like I guess I could watch them YouTube videos on it But yeah, you cuz I got my Joe huzz and Joseph and Cephas, but I go and get mine cut It's like a it's amazing. It's like Stonehenge, but with fire trucks and dump trucks and stuff Into this filming event for work again, I don't want to forget again. Basically, this is amazing I've been waiting for this for over a year to so you know at the end of all the vlogs all the videos There's the end screen where you can click to the next vlog or click to the previous vlog Well, I've actually been the the previous one doesn't really make that much sense because you don't really watch videos in backwards Chronologically so backwards chronologically So I am going to now replace that previous little text there with one Year ago so now well on the end screen so watch all the way to end this vlog and at the bottom It's gonna say next so which I update tomorrow, but it's gonna say next but more importantly To remember our roots remember where we came from remember with the journey that we have been on on this vlog is We're gonna have it jump back to one year ago. So May 4th 2016 will be that vlog that thumbnail on the left hand side of the end screen. All right, so go check it out May 4th 2016 I'm excited. I have no clue what I was doing a year ago But this is how we remember our story and guide our story to a better place Because if we don't remember where we came from how we're gonna room how we're gonna know where to go So we've got to remember our story and make our story better. All right, so one year ago. Check it out Enjoy this enjoy the sun sunset here. All right ready Go Talk is over and yes, I hope you enjoyed that sunset My filming responsibilities were through now the trick it was a rabbit You probably can't see me at all right now, but the trick to Seeking beauty not be afraid to take risks. Oh my gosh the camera is still going. I love it All right, and have a good memory as to where you left the camera, but it's still going Not too shabby won't too shabby at all. All right. Love you guys. Thank you. Thank you. Thanks for coming back Like in the videos commenting Sharing and yes subscribing. I appreciate it pick this guy up at home Anyway, seek beauty work hard of each other