No you're juicers, dude. Oh, I remember this. It's like beginning here. I just It's actually so good Let's take a look at Nim's New Year's show Nim's New Year's show awards best pog champ moment Katie in with the play of his life. That's the all-up and kills the guy CT.   That's that's a massive amount of weight Wait, he can play you can play with I think it's the flute I think the flute is most pog champ moment I just like this one the most pulse JP slippery stars. This is for best funny By the way, if you guys want to vote on this I'm gonna link this in the chat if you guys want to vote said about when you else a game award show This was really funny.  I'm not negative. Why are you so negative? That is funny I don't think this is Great, let's talk about it Look listen, I think a lot of times people say scripted and planned interchangeably. I'm sure What why does it look like a dick? Anyway, I'm sure what happened was chance was like, yeah I'm kind of gonna spark out at the end and they were probably like, okay, sure whatever There's so many things that are planned or even a hard scripted that are still funny poke chase a stranger in GTRP What do you want? How'd you find us?  Oh, you remember this. It's like beginning here. I just I think that oh It's actually so good. I think it has to be this one By the way, Chubby is gonna come visit around the end of the month She's gonna come visit and she's gonna stay here for a little bit We'll do a whole bunch of stuff with her when when she's around is it not rugby? What is it called then field hockey? Is that what it's called football? I'm not soccer. What is it? What's the word we're looking for? This is I was watching Nick stream before I went live And I and I saw this this clip already. This is like cricket. It's football. We we we uh Cricket, it's no, it's cricket. It's called cricket Crockett rugby is that what's called with the paddle with the big-ass paddle, dude.   That's crochet. That's what I thought No, that's sewing It is what sport they've been talking about grow okay Wait, so really xqc was the one who was walking I want to say best pepega moment because this this whole conversation This is like a very real thing right here. And it's just like my friends are idiots best cringe moment We are currently waiting right now to go inside. I think we are currently waiting right now to go inside I think we're gonna do some announcements. I didn't think we had anything to really announce so Oh, sorry. Sorry about that Uh honestly my eyes are kind of dirty so if I were you I'd get over this guy wouldn't There you go. I played chess all day and yeah, I know you're in jail Oh, thank you. Yeah, this is uh my very exciting night out Um Oh, yeah, I'm just gonna stream but sorry about that. Yeah, I want to just talk with chat and catch up a little bit Yeah, I'll let you know. Thank you It's gotta be this one poke skips tiktok at the worst time Oh, oh no, the worst.  How does it happen? It's a bug all the time actually eats his foot skin for the snipers sniper. Are you watching?  Yeah, but okay, so you know why she threw it because the way they teach them to do golf I think she was like this And like she was just trying to like hold her hand in the right position without actually squeezing the thing You are so talkative, huh? Yeah, a lot of saying she not say loser I remember this now. I forgot about this twitch gets leaked Oh, yeah. Yeah, that's a pretty big fail. I think a lot of people are gonna vote for this anyway Uh, let's just say this best rage moment one back off prayer.  I did 14 hours 16 hours every single day.  Yeah, that was good Dude, he's about to do a he's about to do a real uh, uh, uh, he's going for the uh, the rear double glute spread Oh, hey, I'm watching canoe. I just do this whenever I get bored sometimes Me too. I just watch canoe flexing highlights. Yeah Canute I'm gonna go for canoe that's tts donation forson bank robbery Wait, we had a clip. We're famous. I think your clip was the best Steve and michael's with michael's and bicycles times I recently found out my wife is cheating on me with the mailman and my son resents me for not taking That has nothing to do. What are the goals for the rest of the season? I miss my wife The legend of steven michael's The legend of steven michael's Yeah, i'm voting for myself the best up and coming streamer Um I think all of these guys are good at something None of them are good at everything one of them is good at nothing and that's because he watches eras streamer of the year, um Am I being a homer if I pick miss i'm gonna say miss friend equals win Yeah, but I'm friends with all these people except for forson who I don't know if he has any friends and tylan one Also, I don't know if he has any friends. Okay, this is it. This is my ballot submit. Thank you for voting Your picks have been saved the winner will be announcing the big show on the 30th of december You didn't vote for e-robby voted for sage. I watched e-rob Yeah


For more videos on people's struggles, please subscribe to our YouTube channel. Last week, a series of investigative reports in India revealed that the far-right government of Narendra Modi had opened windows for the purchase of electoral bonds to fund political parties on six occasions. These occasions were two more than the permitted number. This happened in two consecutive years. This revelation caused an uproar as the government was accused of breaking the law. It also led to a fresh focus on the electoral bond system itself. This system, which was inaugurated in 2018, has been severely criticised by the left and other sections of the opposition. It has also received plaque from key institutions in India. The critics of this system point out that it legitimises the role of big money in elections and destroys any possibility of transparency in political funding. Let's look at this system and how it is subverting democracy in India. So, what are electoral bonds? The proposal for electoral bonds was mooted by the Narendra Modi government in 2017. It allows political parties in the country to receive funds from individuals and entities, including corporations and NGOs, without the source being disclosed to the public. These bonds can be bought by any Indian citizen or any entity incorporated in India. Designated branches of the State Bank of India sell the bonds during four windows that open at the beginning of each quarter of the financial year. The bonds are worth multiples of Rs. 1,000 or US dollars 13.99 and can go up to 1 crore or US dollars 139,875. The bonds are then deposited as donations in the bank accounts of the beneficiary political parties. The parties have to encash it within 15 days. Neither the political parties, which receive the donation in this form, nor the companies or individuals making the contribution, are obliged to disclose them. The bond itself bears only a serial number and only the bank branch supposedly has the information about who bought it and who encashed it. The details cannot be accessed even under India's Right to Information Act, although there are certain exceptions as we will see. Why are electoral bonds dangerous? Both the left parties in the Election Commission of India have expressed the concern that the electoral bonds will allow foreign companies and international finance to pour unlimited funds into Indian political parties through shell companies. These reports were based on documents obtained by the RTI activist, Komador Lokesh Badra. Earlier, any donation in excess of Rs. 20,000, which is US dollars 279, was to be listed out in a contribution report, which every political party is obliged to prepare by the end of the financial year. Now, this has been amended to exempt donations received through electoral bonds. Similarly, while introducing the scheme, another law was amended that obliged companies to declare their political contributions. The companies earlier also had to disclose which party they were contributing to. Now, they just had to disclose the amount and not the name of the party. Most importantly, earlier laws ensured that a company could not donate over 7.5% of its average profit over three years to political parties. This was to ensure that money would not be routed through shell companies to political parties. However, even this cap has been removed. India's Election Commission has warned that this could lead to a huge inflow of black money into the electoral process. The new scheme can also help foreign corporations who have no legitimate business in India to route money through shell companies. How do the bonds affect the financial system? India Central Bank, the Reserve Bank of India too, has expressed many reservations. It is pointed out that these bonds could be transferred by hand and are thus mired in opacity. While the identity of the original buyer can be traced, how many hands the bond changes before finally reaching a political party cannot be known. This could lead to a huge increase in money laundering. The bank is also worried that these bonds could end up as serving its currency and will thus seriously undermine the core principle of central banking legislation and set a bad precedent. Incidentally, the government did not even properly consult the Reserve Bank ahead of the decision. The scheme was even passed in an improper manner. The government introduced the bill for the electoral bonds in the lower house of parliament where it has a majority and bypassed the upper house where it was in a minority. This is despite the fact that this scheme had the potential to drastically alter the very nature of Indian democracy. How does a ruling party benefit from electoral bonds? When the scheme was introduced, the then finance minister Arun Jaitley of the Bharati Janta Party or the BJP declared that this would introduce transparency and cleanse the system of political funding in India. At the same time, he also claimed that this would ensure secrecy as it would help corporations fund opposition parties. However, a government note few months later clarified that the records of the purchaser could always be accessed by the government's financial enforcement agencies. This is even as the credibility of these agencies is at an all-time low. These financial enforcement agencies have been used to crack down on the government's opponents. Thus, it does seem that the electoral bond scheme will in fact further discourage anyone from funding opposition parties as enforcement agencies can always track down this data and persecute them. Thus, it's not surprising that nearly 95% of the first batch of the bonds worth over rupees 222 crore that's over 31 million US dollars were donated to the ruling party that is the BJP. The total number of bonds released so far in 12 separate batches are worth rupees 6000 crore that's US dollars 839 million a majority of which are also believed to have been encached by the ruling party. The question of election financing is an existential one for the country's democracy. In the 2019 general election, political parties spent 8.7 billion dollars making it the most expensive election in the world. India has 2,293 political parties including eight national parties. Yet the ruling Bharatya Janata party alone spent nearly 50% of this 8.7 billion. The party has been experimenting with targeted campaigns, big data and a number of other techniques along with this traditional polarization based on religious lines. The electoral bond scheme could give the party the resources to further divide the people and spread its divisive messages. The left in India has been consistently resisting this scheme. The Communist Party of India Marxist the CPIM is currently fighting a case in the Supreme Court against his opaque funding mechanism. The party is now examining the possibility of filing an additional affidavit seeking an immediate stay on the use of the bonds till the final verdict is out. This is a battle for the very soul of democracy in India.


Wait, hold on. Did I just die because an axe made by Pepega killed me? It was me! It was me the whole time! The plan to re-roll priests! Oh, wait, wait. I need a level of my weapon skill. I'm gonna be Zaria. He's playing the same half. Yeah, I know, right? Uh-oh.  I'll show you some real speed. Nope. I misclicked! I misclicked! I just blanked.  Did my green axe kill you? Yes, because I need to level up my weapon skill. Wait, hold on. Did I just die because an axe made by Pepega killed me? I literally just died because an axe made by Pepega killed me. A few thousand years ago, there was a man who was sent down to Azeroth to die for the sins of the people. Today, Esfand has died. Today. Esfand has died for the sins of Blizzard, but 19,000, 99, 900, like, like, 1,999 days, years, and 362 days later, what happened, champ? He rose again. It was me! It was me the whole time! The plan to re-roll priests! The plan to re-roll the second account, making sure the name was not stolen! Yes, we're re-rolling priests, chat. Pre-planned, easy, easy. Never trust a streamer. What? It's good. You gotta admit that was good.   I'm a streamer. I've been lying my whole life.  No, I'm actually done. If I die, I'm actually done, chat. But also, I don't know if I want to start again. Already re-regretting?  Okay, it's scary for me to play something new, okay? But I like Paladin because Paladin gets fun at level 60 for me. But I won't get to 60 anyway. That's why, that's why I wanted to re-roll. I don't think I'll get to 60 anyway. That's why I want to re-roll Paladin. But see, now, now I'm having second thoughts because I'm like, what if I just, what if priests actually sucks? Because priests, when you level a priest, it's not like you're like using your wand the whole time. And I didn't really think about that. It like just now occurred to me. Frick! The biggest cop in battle X. Oh, buddy, what if me, though, if I dueled somebody with Soul of Iron and I control them and I run them all clean up? It would be really fun to be here.  I don't know, maybe I have to decide and we'll see next stream. But if I do that, then I'm gonna have to re-level the Paladin. If I don't do that, then I have to re-level the Paladin. But I actually have to 100% not troll whatever at that point. I think going all the way to rag is a lot. I mean, do you really want to go that far?  I mean, like, yeah, that's, that's kind of the way it works. Cause like I did it. I mean, I, I did it for the, for the thing, right? Oh yeah. For the bit, but, but if I do it, I can't, I can't do that again because I, I, I mean, first off, I really wasn't going to do that after level 10. Huge ways, but I know we don't throw again because it's not funny if I do it a second time. It's only funny the first time. It'd be funny every time. No, it wouldn't. It's funny each time. No, it would not get funnier. I mean, it would be funny in a different way. Do I just try hard the Paladin? I, man, I really thought Priest would be better though, but like as I'm thinking about it more and more, it's just like leveling with Wandsbam and yeah, the thing is shadow priest. If I play a shadow priest and raid at level 60, that's probably pretty freaking nasty to have a shadow priest in your raid with all the people playing warlocks and the debuff limit being so high. Have like every raid is going to probably want a shadow priest. That's kind of what I thought, but I'm not going to get the 60 anyway. So you're trying to tell me that you did all this for a meme. That's so unlike you. I'm probably just going to end up re-leveling the Paladin at 10 and keep going from level 10. It's probably what I'm going to end up doing, I guess. I'll either do that or I'm going to re-roll another class. I was thinking Priest.


Hey everybody, welcome back to another exciting episode, another edition of A Week in Geekdom here on YouTube, Geo here, and today we're going to be talking about the VizManga series Comey Can't Communicate Volume 1. Unfortunately, I do not have the physical release with me, but I do own the digital version here on my tablet. As you can see, Comey Can't Communicate Volume 1. The art in it is pretty freaking awesome. I love how clean and gorgeous the drawings are. Let me show you randomly some of the art right there. Just, it looks fantastic and if you don't know what the story is about, we follow the character of Shoko Comey who suffers from extreme social anxiety and communication problems and, you know, it makes her largely unable to talk to others in her class. This is a high school romcom and it's not really played in a negative way. The character is trying to acquire at least a hundred friends and it isn't until the character of Hitohito Tadano that, you know, he falls for her and finds out that she's having this issue, she, they become friends. He becomes her first friend and he is going to set out on this journey to help her get 99 more friends and, you know, make her a little bit more sociable. When the story begins, you start reading into the character and everybody in the school thinks that Comey is this bright, beautiful, regal character and she is, but it, there's just sort of like this false image where everybody thinks like she won't talk to somebody because it's not worth her time, stuff like that. Like she's an elite high schooler but the truth of the matter is she's either extremely nervous or frightened and will not talk to that person. She'll just simply freeze up and I think that is, at the beginning when you first learn of it, it's played for laughs but at the same time there's a seriousness and a realness to the story because I do think it's a universal message that people, you know, they will, we will freeze up on occasions. Not everybody is comfortable talking to everybody. Everybody's going through stuff so I think having a story like this makes it a little bit more relatable to people and you can laugh and have a good time but at the same time get inspired by a wholesome character trying to do her best and I think that's the key to a story like this where other manga maybe could play it on a different angle but this is more sincere in the way it presents its characters and the way Comey is trying to communicate, you know, a particular scene that I really loved and I'm gonna find it as I'm talking with you guys here on my tablet is that when the two characters are two main characters they finally sort of understand what's happening with each other. They have this really great conversation on the chalk board in their homeroom classroom that I thought was really, was really hard warming and fascinating that they can have this sweet chat. Here you can see it a little bit better. Have this sweet chat, this sweet tender moment between the two characters. I thought that was really cool and really speaks to the heart of the series that we can have something endearing like that. Along the way Comey's gonna meet other characters, some are more interesting than others and for the most part the series plays it like each chapter is a mini story. There is an overarching theme throughout the book but each story is like separate gags or episodic adventures within this world that we're reading about and I thought that was pretty cool because you can just pick up the first book, enjoy it, read it for what it is, have a fun time. You don't necessarily need to set out to read the second volume but if you do you are going to be rewarded with more great stories and characters and Comey honestly trying to do her best. Part of me wants a story like this to continue on forever. I do believe there's been like 15 volumes in Japan so we're now getting the US releases. I think we've gotten four manga volumes and hopefully there's a lot more. We can get it in oversized format and stuff like that because I think it's a fun addition to your library, a fun addition to your manga reading about just characters trying to live out their best lives and trying to make friends and overcome fears and doubts and all that stuff so I do wholeheartedly recommend Comey Can't Communicate. I think it is a fine manga and a wonderful story that everybody should check out. If you want something light-hearted, a little bit more comedic and happier then yeah definitely give Comey a shot and I just went all dark. This is a typical reaction for the character. Let me zoom in on Comey right there. As you can see you know she's nervous and her heart's thumping so she feels it. There's that chalkboard that I was talking about and the art is really smooth and clean and gorgeous to look at. Look at this. See they're both having that intense conversation but it's it's kind of fourth wall meta-breaking if you will because you're reading about people reading or writing so I thought that was pretty cool and then definitely a highlight of one of my favorite scenes in manga. Here's the part. What's your dream Comey to make 100 Friends and that you know if you've ever had bad luck with people and friends and school and stuff like that you feel it. You understand her anxiety and her pain and what she is going through even if it's played for laughs sometimes with her reactions to like socializing with people playing musical games or going to a store to buy a drink stuff like that. So I think having the character of Tadano sort of be that anchor that first anchor that's going to help break the ice is fantastic. There's also another character called Najimi Osana. He is or she is gender fluid and I thought that was really cool that they didn't really make a fuss over it. Here's this character. He feels the way that he feels or she feels the way that she feels and does her own thing and it should be like that. It should be fun that we shouldn't have to discriminate against people for what they believe and how they want to live their lives. Najimi is a great addition to the cast and the world of Comey can't communicate. So that in a nutshell is sort of my first impressions on Comey. I do want to pick up the physical volumes eventually and I do recommend it. I think it's a fun read for you guys to check out. Have you read it? Let me know in the comment section down below. The art is super clean, crisp, and beautiful to look at. Fantastic wholesome characters trying to you know live out their best lives in high school and a wonderful heartwarming story that I think you're gonna enjoy. Check it out if you can. Follow me on social media, Facebook, Twitter, Instagram, all that fun stuff. Like, comment, subscribe, hit that little bell icon so you know when new videos come up on this channel. I've got to go. I will catch all of you on our next video.


Everybody forced here ripping 20 21 flawless football hobby 2 box case number 79. It's a tiered random team style break There's a link for the results in chat You can always find these at latent sports cards comm scroll down to the bottom of the page click the results quick link You can also search for the results in the search bar as well, which helps if you're looking for older results So I keep going back page by page Anyway, here we go. Thanks again everybody best of luck All right, you're gonna start off with a Chargers patch card Austin Eckler 5 out of 15 Eckler 5 of 15 It is game worn three color game word Eckler patch is pretty nice another nice car dual patch Mahomes and Hill 9 of 10 chiefs Those are player worn patches there nice card connections flawless connections They were flawless connections Emerald patch auto Brian Burns 5 out of 5 Carolina The player worn Brian Burns as the R looks like from a From the nameplate. I think don't know if there's anywhere in their jerseys as Panthers with the or but Nice when they're 5 of 5 emerald patch auto Rookie debut signatures Kenneth gain well the third 2 out of 5 for the Eagles back-to-back emerald hits there Greats auto Falcons Michael Vick one of 20. Yeah, Burns is a beast Got a Patriots distinguished patch auto Drew Bledsoe 5 of 15 Player worn Drew Bledsoe 4 color patch Rookie dual patch auto Kyle Trask 9 out of 10 bucks Trask attend dual patch rookie auto bucks I'll do it for the inner box Emerald or not emerald but a sapphire Jim Jim Kelly 11 of 15 bills with a diamond guarantee there Super Bowl patch card a Game worn Tom Brady patch 5 out of 10 Patriots That's freaking awesome Dwight M. There you go three-color game used Brady patch just says game worn and a Zack Wilson rookie auto 2 out of 15 jets nice hit for the jets Hopefully he can get back on the field soon Pull it all together There we go jets nice card. All right next one guys Last one. Yes, be in soon. That's what you see on the highlights a lot of sports that oh, yeah for sure Tile has you going crazy right now? all my son's friends go to Florida State they're all probably Destroyed right now All right triple patch Broncos Steve Atwater Bill Romanowski Tarell Davis 18 of 25 Super Bowl patch card Packers Charles woods in 20 of 25 Seahawks the Scridge rookie dual patch auto 16 of 20 Dwayne Eskridge Jets greats auto Martin Gaston 0 3 of 25 Cowboys greats auto Tony Dorsett 7 of 15 Nice Dorsett Callin mon rookie Nike swoosh RPA 5 out of 5 Vikings Go Vikings on the mon swoosh a Signature gloves with the Nike vapor logo Rookie auto Najee Harris. That's a sick card for the Steelers We'll mag that for you big chunky glove relic Sapphire gem Derek Carr 15 of 15 Raiders a Emerald gem legends Curtis Martin three of five Patriots Diamond guarantee there look back on the break Is a star swatch signatures 10 of 10 Aaron Rogers? Beautiful hit Packers two color patch player worn Star swatch a rod congrats James a with the Packers that's sick man. I Love star swatches one of my favorite designs of out of any out of any high-end product Beauty on the back right there nice Rogers That'll do it. Thanks again everybody. We've got person's come up in a few minutes here


Hello everyone. It is my pleasure once again to welcome you all to MSP lecture series on transformative chemistry. This is the 49th lecture in the series. Probably I may take another 3 lectures to complete the inert reaction mechanisms. Then I shall move on to electronic spectroscopy and NMR spectroscopy and then I would conclude this course and the 60th lecture would be a concluding lecture. So let me continue discussion on inorganic reaction mechanisms. Under that I shall focus again today on substitution reactions in octahedral complexes. And yesterday I spoke about water exchange reactions after concluding discussion on trans effect. So let me continue from where I had stopped. You can see how the rate constant in an octahedral complex when you perform substitution reaction do not depend on atomic or ionic radii and also the charge. But of course to an extent charge can have influence but more pronounced is crystal field effects. Especially with case of a trans metal complexes when we talk about substitution reaction we can see profound influence of crystal field effect. You can see here for 3D series the first order rate constant K for water exchange reaction vary greatly as all are high spin complexes. Crystal field effect is also less pronounced in case of 3D. For example if you consider chromium 2 plus and copper 2 plus they respectively have D4 and D9 electronic configuration are very labile and you can see the value that can tell you. And then if you consider chromium 3 plus with D3 electronic configuration it is kinetically inert you can see the drop in the rate.  And when we look into vanadium 2 plus having D2 electronic configuration this is also considerably less labile than the later M2 plus ions. So this is some information about the influence of crystal field effect on substitution reactions in octahedral complexes. And although these trends relate to CFS effects charge effects are also important I mentioned charge do have some influence. Let us look into di cationic and trichatonic species. When we look into hexa aqua manganium 2 plus this is the value and other hand when you look into hexa aqua iron 3 plus you can see the drop both are of high spin complexes because of that increased charge here. Increased charge makes this one less labile or little bit more stable complex. The rates of water exchange in high spin hexa aqua ions follow this trend for di cationic species this follows this of course this is very similar to increase in the atomic number you can see more or less it follows the same pattern except for these two of course here you should recall D4 and D9 because of John Taylor effect. John Taylor effect is more pronounced in these two as a result there is some anomaly when you look into the increasing order of atomic number it does not really follow of course here also it does not follow it is coming back so that means you cannot really take the atomic number increase in atomic number or something it goes with the electronic configuration and when we look into trivalent species this is order followed by metal complexes. For a series of ions of the same charge and about the same size undergoing the same reaction by the same mechanism collision frequencies and entropy change remain constant. The variations in rate arise from variation in delta h hash that is enthalpy of activation. For example what is important to remember when we perform substitution reaction is we should assume that enthalpy of activation arise from loss or gain of CFSE on going from starting complex to the transit state. So when we go from starting compound to the transit state transit state can have either 5 coordination or 7 coordination. So then how this varies is what matters the delta h hash a loss of CFSE indicates an increase in the activation energy for the reaction and hence a decrease in its rate. The splitting of the d orbitals depends on the coordination geometry so we can calculate the change in CFSE on the formation of a transition state. So now I have given some values the calculations may make invalid assumptions because bond lengths are kept constant and that may be unlikely but for comparison the results make some sense I have given the change in the CFSE on conversion of a high spin octahedral complex into a square pyramidal complex if it is following dissociative pathway or pentagonal bipyramidal intermediate or transit state if it is following associative pathway. So you can see here this is the CFSE difference for square pyramidal when it is going from octahedral and similarly and this is for dissociative pathway and the second one when you change a coordination number from 6 to 7 in associative pathway assume pentagonal bipyramidal this is the values CFSE values for starting from D1 to D10. So although it appears empirical it gives some vital information for example CN coordination number equals 5 is dissociative and coordination number 7 is associated that is what I mentioned this data show moderate agreement between the calculated order of liability and that observed is with which one can perform substitution reaction and of course in case of D4 and D9 if you see the values this is due to the net John Taylor effects contribution towards the high rate you see here. So that means crystal field splitting and the geometry ligand field has some influence on substitution reactions. So now let us you know introduce another term called Eigen Wilkins mechanism so what is this one let us try to understand. So in a water exchange process what would happen is an entering ligand very similar to any other ligand comes and then we get the product. So that means we should remember that among all substitution reactions we carry out in case of octahedral complexes water exchange process is more rapid than substitutions with any other entering ligands when we try to form a product. So mechanism may be different whether it can be dissociative or associative or ID or even IA and it is not easy to distinguish between these pathways. We have 4 options to explain substitution but it is not very easy to distinguish between these pathways and associative pathway involves 7 coordinated intermediate or trans state on steric ground it is less favor than dissociative pathway especially when we consider 3D metals because of smaller size what happens expansion of coordination number from 6 to 7 is not very easy of course one can anticipate associative pathway more readily for 4D and 5D series because of the larger size whereas in case of 3D you must have noticed less pronounced it is the higher coordination number than octahedral even if ligands are little bit bulky they tend to have coordination number 4 preferring either square pen or geometry or tetrahedral geometry depending upon the type of electronic configuration they have. So a dissociative pathway looks feasible because it involves a 5 coordinate intermediate or trans state even on steric ground it is more favorable that is the reason in case of 3D series 3D metro series if you come across the substitution reaction we can tell with little hesitation that yes they follow dissociative pathway. For most of the ligand substitution reactions in octahedral complexes experimental evidence is also supported dissociative mechanism that means for a typical substitution reaction two limiting cases are observed so at higher concentration of Y the rate of substitution is independent of Y pointing to a D mechanism. So that means the entering ligand concentration is very high means it really do not participate in the rate determining step that is what it means so that is essentially we see in case of D dissociative mechanism but at low concentration of Y the rate of substitution reaction depends on both Y and the substrate molecule that is the starting complex. So these two are the limiting cases for a typical substitution reaction so these limiting factors are explained by Eigen Wilkins mechanism now let us look into Eigen Wilkins mechanism in a little bit more detail now Eigen Wilkins mechanism is applicable to substitution reactions in octahedral complexes according to this mechanism initially a trans state complex called encounter complex this is called encounter complex is formed between the starting complex and the entering ligand in a pre equilibrium step this is very important a pre equilibrium step is established between the substrate molecule and entering the ligand that is called as encounter complex this is followed by loss of the leaving ligand in the rate determining step once this encounter complex is obtained then in the slow step or rate determining step leaving ligand departs from the metal and eventually Y is Y secures its position in the fast step usually the rate of formation of this encounter complex and the back reaction to give back substrate molecule and Y are much faster than the subsequent conversion of encounter complex to the product you should remember this is very important the rate of formation of encounter complex and the back reaction of encounter complex giving the substrate molecule and Y are much faster than the subsequent conversion of encounter complex into the product does the formation of encounter complex is a pre equilibrium so that means these facts prove that formation of encounter complex is a pre equilibrium state of substitution reaction this equilibrium constant Ke can rarely be determined experimentally for encounter complex but it can be estimated using theoretical models so the rate determining step in the Eigen Wilkins mechanism is given by this equation here or this is the rate constant so overall rate constant or rate law can be given in this form this is equilibrium constant into the concentration of encounter complex. So since the concentration of encounter complex cannot be measured directly because the pre equilibrium is a much faster one and estimated value of K hash has to be considered which is given by this equation here this is the concentration of encounter complex to the concentration of substrate molecule and concentration of entering ligand Y it is possible to measure the total concentration of ML 6 that means starting complex and that of encounter complex because it is the initial concentration of the complex so initial concentration whatever we have taken so that would give you clue about the concentration of encounter complex. So let us look into the relationship between how we can arrive at relationship between these terms so M total is equivalent to concentration of substrate molecule plus concentration of encounter complex so again here we can substitute here this one for encounter complex from this equation and then it becomes simplifies now if we take out this common we will get this one into 1 plus equilibrium constant into concentration of Y so now we know the concentration of ML 6 it is equal to the concentration M total the total is nothing but these two terms over 1 plus K e to Y though now we can determine the rate very readily for this reaction accounting encounter complex here so this is the rate equation one can think of this is called Eigen Wilkins mechanism the equation looks little bit complicated but at low concentration of Y where K e Y is much less than 1 in that case if the equation approximate or simplifies into this one. Since K observed can be measured experimentally and K e can be estimated theoretically K can be estimated from the expression K equals K observed over K e from this equation we can take from this equation the once you consider from this equation what would happen so you can determine it now let us look into a typical reaction of hexa aqua nickel reacting with Y to give a product for this reaction K values are given for various entering ligands these are the entering ligands various entering ligands the K vary very little and is consistent with ID mechanism if the pathway is associative the rate would depend more significantly on the nature of Y so that means by just looking into the K values one can get an idea about what mechanism this reaction is followed if the pathway is associative then we have to account for the concentration of Y as well it is independent of concentration of Y and with very little variation in the K values it indicates that it is consistent with ID mechanism or even I would say dissociative mechanism some values are given you can see they are very close here so at higher concentration of Y so Y is a solvent in this case this will be much greater than one the rate equation approximates to this one it will be simplified further and it would be having this value the value of K can be measured directly as K observed equals K so the watery exchange reaction given below so here exemplifies a case where the entering ligand is the solvent so this is a very exemplified case of water exchange reaction the experimental trends consistent with D dissociative or ID mechanisms for substitution in octahedral complexes and ID is also supported in many instances with experimental data so in this reaction for this reaction if we look into the rate of substitution increases with in the following order so various anions in this reaction is carried out the order of rate follows this here the this whatever the trends I showed correlates with the MX bond strength you should remember MX bond strength how stable a complex depends also the what is the bond strength of that particular bond the stronger the bond slower the rate if it is the leaving group stronger the bond slower the rate because it takes little more time for detaching or departing the leaving group from the metal coordination sphere and is consistent with the rate determining step involving bond breaking in a dissociative step of course you should remember once again bond breaking is very very important in dissociative step whereas bond making with the entering is what matters in case of associative mechanism so if it plot a graph of log K where of course you should remember K is the rate constant for forward reaction against log K where K is here equilibrium constant for this particular reaction with different entering ligands this plot is going to be linear with a gradient of 1.0 I am going to show you in the next slide delta G the Gibbs energy of activation is directly proportional to minus log K and Gibbs energy of reaction is directly proportional to log equilibrium constant let me show you the plot you can see here this is linear for different entering groups here I am referring to this group here a plot of log K you should remember log K what we have taken here this is rate constant for the forward reaction and then what we have considered along x axis and if it is y axis so this is equilibrium constant for the substitution reaction is linear with gradient 1 so thus this delta G gives energy of activation and Gibbs energy of reaction have relationship in their proportional to log K and log K respectively the linear relationship between this term and this term represents a linear relationship between delta G hash and delta G that means Gibbs energy of activation and Gibbs energy of reaction there is a linear relationship so this is called linear free energy relationship abbreviated as LFER so linear free energy relationship that means if somebody asks what is the linear free energy relationship this explanation has to be given using Eigen Wilkinson's mechanism the plot indicates that the transition state is closely related to this one and hence has only a weak COX interaction and hence it is a DRID process. This is all about Eigen Wilkinson's mechanism with this information on substitution reactions in octahedral complexes now let us try to understand the stereochemical consequences of substitution reactions in octahedral complexes what happens when we perform a reaction if there is a possibility of formation of isomers whether geometrical or optical isomers then what kind of complexes isomers that are formed that information is very vital so the reactions of geometrical and optical isomers of octahedral complexes furnish information on the stereochemical changes that accompany the replacement of one ligand by the another one so that means the majority of substitution reactions carried out with cobalt 3 plus have provided valuable information in this regard and some of the results go back to Werner's studies on stereochemical changes he observed while working with cobalt 3 octahedral complexes of course he not only worked with cobalt 3 octahedral complexes or chromium 2 octahedral complexes he also worked exclusively on platinum 2 complexes to understand the reaction mechanism of substitution reactions in square planar complexes that also we saw also we studied when I was talking about Werner's concepts and this identification and understanding stereochemical consequences began with Werner's work once he proposed his excellent coordination theory so what matters here is the specific orientation of the entering group in the second coordination sphere that means when we are performing substitution reaction the entering group is ready in the second coordination sphere to come to the first coordination sphere to establish a new bond where the ligand leaving group departs the entering group may prefer to approach the metal in a position let us take if an octahedral complex is there the entering group may prefer to approach the metal in a position opposite to the leaving group if it is the leaving group it can come here here here here then this isomer the trans isomer would eat a cis isomer because we are talking about cis and trans with respect to this one and if this is the leaving group and if it entering group is here in a position opposite we get a cis isomer since y is separated by 4 a groups if you consider m a 4 b x or something like that as x leaves one of the a group moved to its position to make way for the entering ligand y adjacent to b so this is how a trans isomer would give a cis isomer on the other hand if the entering group is y located near the leaving group if you assume it is a leaving group and if the entering group also comes in its close vicinity to establish a bond so there is no change in the structure and the trans product would result so similarly a cis product is expected to yield cis if the entering group is linear if the entering group is near the leaving group so however if it is opposite to the leaving group then a mixture of isomer cis predicted statistically one can say this the ratio of cis to trans is 3 is to 1. Let us look into some of these things in more detail with you know considering both dissociative as associative pathway for various complexes even for optically active complexes in my next lecture until then have an excellent time reading in organic chemistry and once again I thank you for your kind attention.


Good morning everybody JR Fisher here Broadcasting live from the Cleveland Clinic Hospital complex guys. This place is huge If you ever get a chance and you're in Cleveland check out the Cleveland Clinic. It is amazing. My son's here Was operated on oh gosh when was it it was? Saturday here He had also been operated on over a week ago and well some mistakes for me So anyhow, he is recuperating. I want to tell you thank you for all your kind wishes and your prayers and everything It was very touch and go with him It didn't look good and now it looks really good, which is great I've been up to his room already today just to fill you guys in I got up it like and we're gonna get into the meat of this in just a second Okay, so for those of you who don't care about any of this I get it But we're gonna get into the meat of a growing your online business, but I couldn't sleep last night So I got up at a little after four. I was at the gym at about 445 Got in a nice workout and I got to his room at about six o'clock this morning And he's doing pretty good You know, they're starting to maybe give him some food today He hasn't eaten since Friday and this is Tuesday So that's pretty long time to go But he's had a lot of tubes and wires and IVs and all that stuff in him But he is doing a lot better and I do appreciate all the kind wishes from everybody that I've gotten here I want you to feel free to comment I have another little iPad right here so I can converse with you and talk back and forth Or I may just talk to you when you type something if you're not watching this live Feel free to put something in the comment section. Don't forget to give me a thumbs up. Don't forget to subscribe and Ring the bell. I usually have a bell. I don't have a bell to ring. So that's the best I can do you get it, right? I'm bringing a bell here. Okay, so I'm bringing a bell Do me a favor do that turn in we're basically ringing the bell is turning on all your notifications So that when I do go live I can actually notify you and you won't get left out I don't want you to do that or it waste your time looking for videos that I haven't done too So I don't want you have to do that So all that out of the way Today, I want to talk to you about actually setting up your online business yesterday Yesterday we talked about getting the right attitude to run an online business, which is not easy to do. Okay? It's not easy to do You know I've talked to a lot of people about Attitude and being positive and a lot of people struggle with that. So if that's an issue that you were having I want you to go back and watch yesterday's video. I think there's some things in there that will help you I know they helped me not everybody is born a positive person I was not born a positive person. I can tell you that I'm a very positive person now But I was not born that way.  You got to get good at certain things James Bray What's going on buddy? He says loud and clear in Surly Savannah surly Savannah. He's always funny or like listen to him Of course, we're interested in how things are going with your son. Thank you so much. I do appreciate it And you know, he's a very healthy guy.  So he's in really really good shape I think that helped him a lot through the operation We did talk to the doctor that messed up the first operation yesterday and the one that corrected it yesterday And it was really good to talk to them and you know get their insights on stuff But he is heading in the right direction. So we're pretty excited about that You know, and I got to spend some time with him. I spent 12 hours just talking to my son sitting in his room yesterday We've always been close and it was nice to spend more time with him I want to talk to you a little bit about, you know, you know, we say online business And we're kind of talk to you about the history of it first You know, it really goes back as much as 40 years ago when the World Wide Web is just about to get its worldwide You know use Amazon Is an original back to the days and a front of the the news nowadays But back then it was brand new it's an example of how we nowadays bear in mind that e-commerce Experience which is quite convenient and safe and user friendly at this point I think most people are pretty good with buying online now every now and then, you know We get some people who say I want to call in my order, but that's pretty rare Most people are like, you know, hey, if somebody steals my credit card I knew my credit card company is going to give me the money back or it's not a problem show You know, it's it's important to look at the big dream Okay, the new technologies the innovations the thousands of businesses and the millions Dollar ideas that all began with, you know, online businesses. I know ours did, you know We sold millions of dollars of products and it was me just starting something online. I didn't I didn't have any knowledge I didn't know how to send emails. I didn't do anything. So don't think that you got to have all this knowledge This is all stuff that can be gained and pretty quick too And it's much easier to start an online business now than it was years ago because of all this technology And I want to talk to you a little bit about the different kinds of businesses Most of you who listen to me are trying to start e-commerce business. You're trying to sell products But understand that's not the only thing you can do online and I've done a lot of different things online e-commerce websites work You know a site that sells products or services over the internet, you know Examples would be Apple or Adidas or you know Home Depot. They all sell products online You could do online shops or marketplaces like Google Shopping. You could do Amazon.  You know, I have this blog here This is a blog really on YouTube now I have recorded videos upload to but I do a lot of these lives here and I have links below or you could buy stuff You can opt in you can learn more information And then of course last but not least is social media accounts One of the most popular and appealing ways to sell is to use social media accounts Some of you guys already have a following and you can do that you can use your Instagram You can use your YouTube YouTube or Facebook All of those are used by nearly everybody. So, you know, you can still sell to almost anybody Since they perform Or excuse me since they provide a platform for people to use for free, which is pretty cool Like I mean YouTube's free in exchange for seeing ads You can sell Some of your products on other people's videos or you can sell it with it within your own videos You can do that too. Let's say if you're doing a YouTube So Why are you in the online market? Okay? Why why do you want to do that? Entrepreneur starting a brand new e-commerce Business this year could be super successful. They could do really well, you know a brand spreading its wings, you know from the very beginning Independent stores start on here the most common are like nest on things like eBay and Amazon and stuff like that I started on eBay, but you certainly don't have to start there Business-to-consumer sites selling directly from, you know, their sites to the end user of the product no matter who you are You know whether you're a newbie or you're a seasoned online entrepreneur knowing yourself is the first step towards building your online legacy and brand So what I want to do today is talk about some of the steps. There's actually gonna be 10 steps I'm gonna go through this is Tuesday. So we got Tuesday Wednesday Thursday Friday. I'm flying so I can't go live Unfortunately, but I will be back Saturday to wrap this up. So the first thing I want to talk about is Owning the great idea owning the great idea. Okay now the great idea is not what you think It's not coming up with a product that nobody's ever heard of that. Nobody's ever done It's it's really owning the idea of starting an online business. So what is your business going to be about? What are you gonna do? What are you gonna sell don't get caught up in saying well I've got to find the perfect thing because if that doesn't work and I've got to start something else You could always switch you can always change and I changed a lot in the beginning I originally started selling cell phone cases and then I started selling some of camping equipment Then I started selling somebody else's survival food and my business grew out of that and to this day We do sell survival food and I have my own brand but in addition to that I have courses online. I've done a consulting We had services. I mean we've done all kinds of different things So I want you to think about who is your customer, you know, and you could jot some of this down as I'm talking today I've got some notes in front of me so I can read them. So it's a little bit easier for me But who's your customer?  Okay, so you got to really think about that You got to think about who you're going after don't go broad go niche. Do not go broad. Please don't do that That's not what you want to do What are some of the key products you want to sell? What are the key services you want to sell?   Of course, it's not really as easy as just doing those steps You're gonna have a little bit more work into it But you can figure out all kinds of right answers to fulfill the question However, it is important to remember your core values and the only one purpose that is driving your whole business It all lies with that word the why okay, the why why are you doing this? So before All of the what's and who's and all that good stuff. Let's first think about the why be it as easy as much as possible Online businesses should start simple practical and really just out of the box Okay, what kind of solution will your business offer for people and that's how I want you to think about online business You are actually providing a solution. You are solving a problem start-up ideas are not Really rare to find you can look up many places and see them all around you in startups But the point is what is your why? Approach it like this try to sit back for a minute and look about all the problems that you are having in life In the past and present how could you solve some of those problems? How could you solve some other people's problems or even the future? It doesn't matter small concerns big dilemmas It doesn't matter you can turn your normal daily life upside down Do you have any solution to any of those problems? It does not have to be the ultimate way out of a problem deal, right? You can make the process of dealing with some of these problems easier or less consuming or consuming for people You are winning already if you can do that now I was on the Virginia Beach Rescue Squad for years. I was a EMT on an ambulance. This was not my paid job This is my volunteer job But one thing I noticed when I was like saying going out after hurricanes and some of these disasters It's nobody was prepared. They didn't have all the supplies they need now I didn't want to sell everything you need to you know survive a hurricane I wanted to focus on the one thing that I thought was most important and that was food So I started a survival food company now. That's a multi-million dollar company. It's called survival cave food and let me put this in here I'll put in here survival Cave Food I want you guys to look that up and you'll find it James is saying wooden beginning as an affiliate be best for newbies. You know, there is no really best Starting is an affiliate. Yeah, it's it's a good thing But starting as an affiliate has its challenges like everything else The one thing that's challenging for a newbie is Learning how to get traffic and that's all affiliate marketing is is you have to get traffic to somebody's offer I think that can be challenging, but I think it can be easy for some people. It's really what your skills are I know in the beginning if I would have tried to do affiliate marketing I wouldn't have done that well because I know anything about marketing online. I didn't have a market That was my big problem. So I had to come up with some kind of product Which I fortunately did I kind of fell into a product, but it's it affiliate marketing is great If you know how to drive traffic, let's say you have a following already on social media Then you could bring up some products and you could show it to your social media following and yeah, you could do that I had no following. You're right I had I had nobody who was looking at anything I did So affiliate marketing would have been tough for me and I didn't even know about affiliate marketing Be honest with you. I didn't understand it. I didn't know what it was So the next thing I want you to think about is number two is I want you to think about finding the needs and Choosing your market find the needs and choose the market the first winning move Look for the needs and fill them begin from the right market Okay, so my needs and what I looked at in the beginning were the fact that most people weren't prepared So I went for preparedness now to this day. It says survival K food helping families prepare That's our tagline. Okay, and that's what I always went with. I've been with that for 11 years now So once you come up with a good idea The the I guess the pre-step now you're going to take the first winning move Yes in details finding the needs and choosing the market Remember you already have a winning idea once you come up with whatever idea mine was survival food But the how you know you look for a solution for a number of people to a certain problem that they may have in life You just started right and that's the best way to start many startups You know bear in mind the desire to look for unique and desirable product foremost and then a market which comes Second after the magnificent product that you've come up with mine was survival food However start with a market. There's always and that's what I did My market was people who weren't prepared for disasters Okay, there's always a group of people searching for a solution or problem But not finding many results and when I started out there were hardly any survival food companies There's a bunch of them that came when it when the wave hit that a bunch of them went away And we're still around and we're still doing well too many services and products are called themselves Innovative and trend leading, but they're really not, you know We're so lost to the world of you know for a better cause of humanity and branding identities and all that that's simply when it comes to Finding a solution for a small problem in our daily life Thinking about having one direction and a functional solution seems too far away Mine was survival food a simple thing. It's a super simple thing. Okay, so Here's what you may want to do is just ask people about their problems. We know. What are they solutions? The internet is an open world You can visit online forums and see what people are talking about see what they're having problems about Ask these people questions another way around it is to search for what people are looking for Oh, I just got a text from my wife there. I'll let it sit since I'm going live right now But not many sites are offering that's that's another thing What are they searching for but a whole lot of sites don't offer those things, you know Also, you can do a bit further on this step by checking up on some of the sites that are already offering some kind of services or products To your would-be customers you are taking note of work of your potential Competitors and doing what you need to do to fill their needs take advantage and learn from it because somebody already went before you They already did some of the stuff You kind of see what they're doing and you can see what results they're getting now the next thing The next thing step three the niche the product that sells product by ability Okay, the leading move the product that fights for itself my product fights for itself Okay, it sells really well. We we do some canned meats that are the best meat you'll ever eat in your life It's time to move forward for the star of the show Okay at this point your key product services you have to determine your niche in this do not worry Okay, you have already done the parts of the niche process in the previous steps I just talked about which is making sure that the product you are about to sell is the right product with the potential for Serious profitability, okay, you got to be profitable too. Let's let's face it in another way The step requires you to take a further step in resolving the problem given in the need And the idea that you came up with okay, what exactly will you do to solve your people's problems or concern? What are you gonna do? How will that be done in a retail setting? Okay? How are you gonna do that? So I want you to think about some of these questions. What is or are your product services, okay? Your products and services. What are they? What are you offering people? How will your products or services work themselves out to really solve problems? Okay?  What is the connection between your products and services and its potential users? What is that connection? Is the product or service itself strong enough to fight for itself in the market? Mine is, you know, I put our canned meats out there and they're more expensive than canned meat You buy the grocery store by far, but they're so much better and they last so much longer and they taste so much better And they don't have chemicals in them and it has its own market. If somebody's looking to just have anything, you know Just eat anything just so I don't starve to death. My product's not for them My product is for the people who want good food to eat.   Isn't that the truth? The truth is it is always about a matter of demand and supply Where there is a need there is a way which is of course your product or service that you're going to be selling Now, I know some of you have already sold some stuff online And I would love to see some of the things you sold put that in the chat box there put it in the comment section You know, let me know what it is that you sold or what it is that you're thinking about selling I want to know those things. I want to see what you're doing Now I want to get into one more step today And that's market research market research is huge guys And market research is huge because the more market research you do the better positioned you are To actually make some money if you don't do market reset or market research You're going to be better positioned to make mistakes. Okay. That's what's going to happen Understand Whatever product service you've come up with at this point. I think I think somebody's probably already did it But that's a great thing. It's not a bad thing. It's not a negative thing It's a great thing because They've already gone through some of the obstacles that you've got to go through And if they've already gone through and they've already figured out some stuff If they've already figured out some stuff, you can borrow that knowledge from them I want you to take a step back to win further steps ahead Okay validating your product evaluating trend products You've got to do that guys You got to look at who's out there and what they've done and you know, how they've succeeded and how they've failed and How they've built their audience all that is so so very important um You've got the idea and you've figured out the potential market and you have even come up with a detailed solution Great. Okay, but market research guys market research Now is the time to take a step back and link all the parts together. So we're talking about your idea We're talking about your market. We're talking about your product your services how it all relates thoroughly. Okay So in short, you have to conduct market research a market research consists of many parts. Okay It is important That your key product or service hits the market perfectly. Okay, if you can hit the market perfectly You're going to make a lot of money. You don't have to fight about price. You don't have to fight about selling people and your ideas In order to ensure that you have the You have to take time to validate and review your product and service Consider and evaluate some product trend ideas do some keyword research a lot of these tools are free I mean one of the easiest keyword research tools is google You start to type something in and it starts to suggest things that people are already searching for You want to estimate your potential customers reaction to your product or service? There are so many things you can do to have a deeper understanding of the current market That you are about to be part of. Okay, don't skip over the step I think this is one of the biggest steps people skip on is they think. Oh my gosh. I don't have to worry about it I found this product. I'm just going to sell it. No figure out what everybody else is doing first um A secret revealed is that you can easily try these two validation techniques I'm going to talk about build a simple landing page. Okay, you can do this in kartra I'll have a link to kartra in the description with this video is actually published You'll see the link there And tell people about your product of service and see if they're interested and willing to pay for it Have them opt in okay for a sample or a discount or something like that When you do that, um, you're going to see what the demand is for your product Let's say you want to do a coffee shop test All you need to do is head out to some local coffee shop Prepare some simple slideshows or concept photos And then put a sign outside the shop That in exchange for a drink you will need a few minutes of somebody's time You can gather as much information as you want from the people there What do they like? What do they not like about your product or service? Are they interested? Are they willing to pay for it in tons of other useful information guys? If you follow through with this market research, which you know to me is very interesting Some people think it's not interesting and they don't enjoy it. Okay I like it. Uh, but the one thing is for sure you've got to do it Okay, whether you like it or not you've got to do this. It's so very important. I did tons of market research I looked at all my competitors out there. I wanted to see what they were doing Uh, and now I have a lot of people look at me and copy my stuff. Matter of fact recently In a past year and a half We've had companies that are selling our product who are not retailers for our product who are just ripping people off They're in china or they're in the cayman islands or whatever And they'll they'll take one of our products and they'll offer it for like a quarter of the price that we do And they rip people off They just take their money and never send them anything because we I know this because I have so many people contact us and say Hey, we bought this stuff from you on facebook, which we don't advertise our stuff on facebook Not our survival food and we've never gotten the order. Well, they never got the order because they didn't buy it from us They got ripped off. Um, so you you got it That's another thing I would tell you guys if you're buying online and you see a product And it's way cheaper than it should be way way cheaper. There's probably a problem. There's probably a problem And that's what a lot of these people did With our product and our name because we have a big name now is they they were just, you know Hijacking the mango. Well, they sell it for 300 bucks. We'll sell it for 100 bucks And then they never they never supply anything at all It's a shame because I've seen a lot of people ripped off in the past year and a half two years Something like that on our product We didn't sell it to them. Um, and we have to break the news to them that they probably got ripped off They need to contact their credit card company. Uh happens all the time happens. I mean, I think it happened three times last week alone Uh, so that's just craziness, but it goes on um So, yeah, that's what I've got for you today I'm a little short today. I'm six minutes short If you've got any questions or comments, you feel free to put them in that Chat section there. Um, you want to stick with me? This is tuesday We got wednesday thursday and saturday. We've got a lot to cover on online businesses So, um, you want to stick with me on all these live sessions? Each one of these live sessions. I'm going to cover a different series of steps That you're going to help you along the way Today, of course, I'm going to go back to my son's hospital room We're going to try to get him nurse back to health. Hopefully they can have him eat real food today And if all that goes through him, uh, then hopefully he can get out of here. Maybe tomorrow that would be great He's been in here since friday, which is a pretty long time to be in a hospital Um, you know, it's it's not fun here And the gleevelyn clinic is such a huge place guys that people come from around the world You know, it's saudi crown princess flying here for their heart operations Because they have some of the best medical care in the world I think it's the number three hospital in the world number one for heart surgery. So Yeah, it's a big place. Uh, so I guess he's he's in good hands all all the uh staff has been really good with him They've helped him out a lot and he's coming along. So, uh, I want to go spend the day with him I don't want to stay here all day, uh, though. I love you guys very much I gotta go spend some time with him and get him healed up Don't forget if you haven't subscribed, please hit that subscribe button down there If it's red, you need to click it turn it gray. Don't forget to ring the bell. Look, here's the bell Here's the bell right here. I don't have a bell. I need a bell But you want to ring the bell turn on all notifications so you're notified each and every time I go live Um, I had I like as I've had an early day today. I've been up since four o'clock in the morning I'm gonna probably be pretty tired by the end of the day. I can assure myself of that Uh, but it's well worth it. I get to see my son. I get to be here I get to watch him heal up and hopefully if he gets out in time Maybe we go out to dinner or something that would be really cool But either way if I if I have spent all the hours in the hospital room, then that's what I'll do I'll spend all the hours in the hospital room. Uh, that's still spending some good time with him So guys, I appreciate you being here today. Thank you so much for showing up Don't forget. I have some links below once this video is published Um, and uh, you know, it's on my channel then you can you know get to some of those links I have some free courses in there. There's 97 dollar course. You can get absolutely free So you want to click on that too? No credit card required. It's absolutely free guys. Thank you so much for listening today I'm glad you're here. I'm glad you're happy and healthy Be happy if you're not happy be happy just choose to do that choose to be a positive person Go back and watch my video from yesterday if you're not positive watch that video from yesterday Thank you so much guys for being here. I appreciate it.


Hi everyone and many of you will be aware of the whole class feedback sheet where you know a stack of 30 books and to reduce that marking burden which drives every teacher crazy in schools across the world and I look through the 30 books and I annotate the sheet and then etymologically speaking the word assessment to sit beside I sit beside the children in my class and I provide them with the feedback I've written on this sheet this sheet is for me, not the students and and you know think of all the different types of students that you have in class. In class most classrooms have at least three groups at the students when you provide feedback go off and fly and the students need a little bit more script, a little bit more support and in the students that will always struggle. And then if we think of types of feedback, verbal written non verbal feed up feedback feed forward, there are many ways that we can work in our classroom so we're all familiar with this results, I'm going to take it a little bit further for you. When we asked students so number one here we are our ultimate goal as teachers to help children learn or to behave you know self regulating metacognition being aware of what I know about volcanoes and what I don't know about volcanoes. Number one, right kids in your books draw this volcano could you label the the sections of the volcano and then write a paragraph to describe how the volcano erupts and how the lava cools down in this grey zone so using research from Nicole and McFarland Dick 2007. This is a model and seven principles of good feedback and all this grey zone are what happens internally within the students that we don't necessarily see or observe in the lesson. You know kids cultural capital their motivations their strategies their knowledge their schema. I set a goal based on what Mr McGill's told me to do I select tactics and strategies that I have almost McGill gives me, and then I set my own goals based on what Mr McGills asked me to do this influences my cognition pain attention my motivation, my excitement and my focus my behavior and how I interact. Six, I observe this so in the lesson in the moment teachers are constantly evaluating verbal non verbal cues and many other things and then seven we use this data to reteach in the lesson. So in class assessment or outside the lesson to reshape our curriculum plans. So that's looking a little bit of theory but let's take this original resource whole class feedback a little bit further seven principles here's Mr McGill and McFarland Dick now some of you will be familiar 17 principles of Barrett Rosenstein published recently in just 10 to make it a bit more manageable. I would say the seven could be squeezed down to four. And so number one. Here's a great example. Let's do it this way I do we do you do. So four and five on the screen, I would argue that you could squeeze it into one I off you go kids here's a question well done Ross, have you thought about a instead of be. This is pretty much me facilitating self assessment, providing feedback, thumbs up thumbs down show me many whiteboards discuss for your partner. And share write it down all those retrieval practice methods, and that kind of positive feedback to encourage the challenge and support. But where all teachers focus their time energy and effort is on number six interventions in and out of the lesson, and then using all this data assessment to use it as a feedback look for planning the next lesson or even in the number seven. So it looks like so I've done a plan. It looks like this. So you might want to use this as a way of scripting your feedback to the class taking this original resource one step further back by this research. Number six, you look at this area in particular which pupils what intervention at what point of the intervention will be used time day location, which adults and what next and how you evaluate that impact. Now here's the resource I would like you to download and use it is get the right slide this one. Most teachers always use the word feedback but are we aware of feed up and feed forward. Now there's a great blog I'm just going to put it on the screen by john hefty published quite recently using his original work with Helen template in Power Feedback at visible learning. He kind of references a lot of duplicate research papers that may have influenced these original findings. So this new meta analysis published this academic year in 2020 looks at it a little bit further Here's the definition this is the blog the power of feedback if you want to read it but the resource using hatties findings and then come up with this resource, whole class feedback sheet. Now remember, there's two things you can use here one, be a better understanding of feedback. Number two, using this sheet to annotate those 30 books that I then use as a script to sit beside students. Here's what a good performance. Here's what a good one looks like. And then using it as feed up feed up is this is the actual status of your work Ross, compared to your target. That's feeding up to improve to reach that target to groups of students in your class feedback. This is your actual status of your work Ross this is your drawn of your volcano compared to where you were before. And let me explicitly explain the things that you've done or maybe ask yourself feed forward, explaining the target status based on the actual status so you know moderation exam. This is the grade C and this is the criteria and this is why it's a grade four or grade C, or whatever you're using in your classroom assessment. It's critical that teachers we become a bit more aware of feed up feedback and feed forward, and then you've got looking at missed opportunities misconceptions and then use this to influence your next lesson plan in your curriculum scheme. So this offers you something a little bit further to think about whole class feedback. Here is probably the original been well circulated online, looking at the research into metacognition and the principles of good feedback. This is now my take on using it as a feedback plan for your own curriculum planning, but then we're looking at the template so I'm getting my slides mixed up here. And reshaping whole class feedback for those three groups of learners kids that fly kids that need a little bit of script before they go off and do it and then the kids will all need a bit of support. And then also improving our own understanding of that feed up feedback feed forward mechanisms and hope it helps. And while we're at it, don't forget to check out the verbal feedback research I published in 2009. When it's structured and routine and we abandon some form of written feedback, the verbal feedback techniques have no detrimental impact on people's engagement, or indeed their outcomes, and it might just save your work in your mark and burden, and that workload issue that all teachers face. Anyway, thanks for watching and getting touching up any questions.


Today's quick tip is to problem solve out loud. Now this is about being a role model to your child or the children in your care because if we can problem solve out loud and learn out loud and basically take the things that are happening in our head and say them and show them then our children or the children in our care can begin to learn from those processes. So what it can look like sometimes to our kids is that we just know how to do stuff that we've got our stuff together and we just know what to do perfectly first time every time. That, believe it or not, no matter how it might feel to you that is how it sometimes looks from the outside looking in for your kids. We know, I can't speak for you, I know for me that's certainly not the case and actually it's really important and helpful for my children to know that I face challenges every day too. I don't always know what to do, where to turn. I'm not always quite sure how to manage a situation. I'm not quite sure what a reliable source of advice might be here or who to talk to, et cetera. And actually making the effort to share these uncertainties, share these thought processes. Think with my children about where I might go and actually sometimes engage them and ask for their advice as well increasingly as they get a bit bigger. That's a really helpful line of thought too. Can be really helpful for all of us. It's kind of weird for your kids at first when they realize that you're not infallible, that you don't know all of the answers. That can be a bit of a strange moment of reckoning for them. But them learning how you learn, them observing how you problem solve and them being able to copy some of your strategies for doing this can be incredibly helpful for them. Also, when you start to do this and you begin to engage a little bit more in problem solving out loud, learning out loud then A, you can often get really interesting input from the others around you who might have other ideas and B, you become a lot more conscious of the process and sometimes actually that means you do it better or more thoroughly or you turn back to things that you might not have remembered to do otherwise because you're a bit more conscious of the process. So it's kind of a win-win in my view, although it can feel a little bit strange at first. I would love to hear in the comments whether you find this to be a helpful thing, whether you try to share the ups and downs and the challenges and your processes with your kids or whether you prefer to be the kind of stage on the stage and appear wise and as if you know the answers. What's the approach that you take and why does that one work for you? Thank you for watching and if you are enjoying my content please, consider heading over to my Patreon page and subscribing there. The subscribers on my Patreon page help to enable me to keep creating content for parents and carers. This content rarely gets commissioned but I really, really want to keep making it. So head over there, join that community and please consider supporting me. Thank you.


everybody. Welcome to the Wallach Way. I'm Jessica. And today's video is a back to school haul. Today's back to school haul is Us Born. If you haven't seen all of the rest of our back to school hauls, I'm gonna link the playlist right here so you can check them out because if you love hauls, you're going to love them. Mostly today's haul was things that I thought we could use in our fifth grade home school but they might be used other times as well. I got a lot of activity books for Emily so those will be a lot of car schooling. I got tons of nonfiction books for her to read just at her leisure and stuff like that so I can't wait to share it all with you. So we're just gonna jump right in. So one of the first series that I picked up for her to read was Leo's Map of Monsters. This was a new book series that just released. There's four in the series. So we have Leo's Map of Monsters and The Frightmare, Leo's Map of Monsters and The Shrieking Serpent, Leo's Map of Monsters and The Spit Fang Lizard, and then Leo's Map of Monsters, The Armored Gore-Turk. Each of these books is approximately, let's see here, 140 pages. It's a very large font and then in the back of each of them there is almost like a information about the monsters and there's multiple pages. That's that series. The next series I got for her was the Extreme Adventure series. Since she loved the Bear Grill series so much and she really liked the survival I thought these would be really fun for her. So we have the Crocodile Attack, the Bushfire Rescue, Shark Bait, Scorpion Sting, Spider Bite, Man Eater, and then Grizzly Trap. Now these are approximately 150 pages. Here is a look at what level they are. That way you can make informed decisions for your kiddos. The next books that I got her were actually Continuation. So she has I believe the first and second and I think these are the third and the fourth. So we have the Cursed Unicorn and the Blazing Unicorn and of course she loves anything that has to do with unicorns. So when she saw that there was new books released she was dying to get those. I also got her the Impossible Quest series. There are five books in that series. We have Escape from Wolf Haven Castle, The Wolfs of Witchwood, The Beast of Blackmore Bog, The Drowned Kingdom, and Battles of the Heroes. And these books are about 180-ish pages and then here is what level they're at. And now I will probably be reading some of, pre-reading some of these books series. I'm not sure if this will be one of them, but I know for sure that this next series I'm gonna show you will be one.  And so this is the Makeup and the Breakup, a hot cold summer, and The Call of the Wild. Now again these I'm definitely gonna pre-read just because they may be too advanced content-wise for her, but I like that they were Choose Your Own Like Ever After and I love the Choose Your Own books for her. So we'll see if they're appropriate then I'll let her read them. Oh I'm sorry you guys I didn't show you. So these are approximately 275 pages and this is the level of them. Alright next we have the Mystery series. These are the Mystery of and then there are mysteries of different things. She absolutely loves mystery books so I thought these would be fun. So we have the Mystery of the Painted Dragon, the Mystery of the Jeweled Moth, the Mystery of Clockwork Sparrow, and the Mystery of the Midnight Peacock. These are approximately 330 pages-ish and that is the level that these are. Alright and then I think I just have one more nonfiction book series from us born this time around and that is the Kinsey and Mack books. Kinsey and Mack. Oh that's gonna fall. So there's seven in that series and these just looked like really really fun so it says that there are twins and they're constantly trying to solve like mystery type things. It's like top secret. So we have Kinsey and Mack's Breaking News, Kinsey and Mack's Disappearing Act, Kinsey and Mack's Undercover, Kinsey and Mack's Out of Sight, Kinsey and Mack's Freefall, Kinsey and Mack's Full Speed, and then Kinsey and Mack's Takedown. Well these are about, let's see, 350 pages a piece and that is the level that these are written at. So that's all of the nonfiction books that I got for her for this school year or maybe the next. I also got her a few other things or a few other things for our school year. If you watched the Plan With Me video then you know that Fractions is one of the concepts that I wanted to work on with her this year. So when I found the Fraction Wrap Up on the Usborn site I knew we had to have it. We love these. We have the addition, subtraction, multiplication, division, and states and capitals and now Fractions. It's a really fun hands-on way to practice different skills. I also picked up the My Year Around the World. We have the My Year of Writing. There's also a My Year of Art and it's just fun kind of diary type of thing. There's 365 different activities. They're not dated so you don't have to start them January 1st, which I like. You could just start them whenever.  So this one is Global Activities and I also grabbed her the 100 Things to Know About Saving the Planet. These 100 Things books are amazing. They're all these like small little bite-sized chunks of information so it's not overwhelming at all and they're sometimes the most random cases of information that we never would have learned or known otherwise. So I love them because you can pull them out on like any topic. They have tons of them and they're really really great. A new addition that was a new release are these 24 hours books. So there's 24 hours in the jungle and then 24 hours in space and they're actual like comic books or graphic books. I really really felt they looked fun because it takes you through exactly like 24 hours of them doing like what a day in space would look like or what a day in the jungle would look like. So I thought she would really like that. I know she's gonna love this base one. We'll see if she likes the jungle one but I think she will. I also picked up this Mindful Activities book. This is a new one and I love some of their mindful things from Usborne. This is Enjoy Moments of Calm with these mindful activities from gentle breathing to peaceful doodling. Each activity will help you tune into the here and now. So it's just a book of activities that will help you focus and unwind. And then along those same lines I also grabbed two Magic Paint Yourself Calm books. I actually got one for each of us. I thought this would be kind of a fun activity for us to sit down and do together on days where we seem to be having a more difficult time with our you know emotions or whatever and it's just a paint with water so we would just need a couple water and we could just sit down and paint together. So I really like that. We'll probably just keep that in our bedtime basket. And then she loves the Magic Painting books so I grabbed a Wild Animals one for her just for her to do in her own free time. A lot of the activity books that I grabbed this year for our homeschool will be used for strewing because if I'm finding it harder and harder to find things to strew the order that she's getting so I thought you know like the paint with water books and some of these other ones I'm gonna show you would be great for that so I purchased with that in mind. So I got the Usborne STEM Science Scribble book. Now I actually ordered this one first and I just assumed that it would be like graph paper like just a book of graph paper. And I got it thinking it would be kind of fun for her to have a place to like jot down some of the things that her and Kevin do together for their experiments. But it's not just like graph paper book. It's actually this fun book full of like activities and different things that you can do like are you left or right handed. This is a coding activity. Just all kinds of different things. So then after I realized what these scribble books actually were I thought well that would be really fun to strew. So then I picked up the inventions one as well as the math one and the technology one and the engineering one because they're all different they all have different types of little activities in them. I don't know why I always just thought it was quite literally a scribble or doodle book and so I've looked past these every time but it's a book full of really fun activities that are stem related. So I got all of those to use for screwing this year. And then along those same lines I also got the design activity book because I thought she would love this. It's full of different things you can design. We're talking from like pretty handwriting a fancy handwriting is what she calls it to grids all the way to like it has like web design and software design in it as well. So I thought that would be kind of fun to strew and build your own website for beginners. Same thing along the same line something really fun for her to kind of learn on her own. Then some activity books just to keep her busy marbles of the USA is one of the new USA activity books there's animals of the USA and like roadmap to the USA these are always so much fun. And it's an easy way for her to learn more about the United States without us diving deep into it or if we're not diving deep into it at the moment. So let's see we also have some spy mazes. I love the us more maze books and so does she because they're not like super simple but they're also not too complicated and they're colorful and fun and they're all like a little bit different spy mazes. And then these after I got her an ocean one recently have become something she's asked to do more of. And so it's the build your own sticker books. I got her an ocean animal one when we're doing the ocean unit study. And she's like I really like these mom so I got her the build your own dragon sticker book. Build your own mythical beast sticker book. Build your own deadly animal sticker book and then the build your own dinosaur sticker book. And I think what she likes most is it is really really fun and they're big build your own but you get to see like the skeleton and then you put the stickers over it and then there's also fact like factual information about each one too. So it's not just like a regular sticker book she's learning as she's doing them and she's really really likes that kind of thing. So like here's the dragon and there's like statistics on it and everything. So she gets to learn as she stickers and she loves that kind of thing. I also grabbed her two of these write your own activity books again for shrewing and just to have something extra to do. Both of these will probably be added into like a language arts loop. We have write your own scripts and write and design your own magazines.  She may know most of what's in here but it just seemed like kind of a cool okay just different. So it's like how to spot a leopard from a jaguar. How to dress horses up like zebras. How high can which birds go and why it's just like interesting things like not just your standard animal encyclopedia like which animal would live the longest. It's like quirky animal facts which is perfect for her animal architects. So I knew she would love that one. There was a new sea inside book. So I had to grab that there's actually two this one sea inside the solar system. We love the any kind of look the flat books I love that they're interactive. It makes them so much more fun but especially the sea inside because those are for the older kids and the information is a little bit more. And so we really really like those. I love adding those to our collection sea inside the microscopic world. Again, it's one of those that has like the lift the flaps and it's a lot of different things. Kevin is very excited to go through this one with her. They had a lift the flap question and answer about feelings. So I grabbed that one to add to our collection. I love the question and answer ones too because they're interactive and they ask questions that most kids would ask. And then they have the answers for you. We have the that's a job I like performing arts what jobs are there. This book series is amazing. There's I like animals what jobs are there I like space what jobs are there I like the outdoors what jobs are there and I like art what jobs are there I think maybe even a sports one but it's just so cool like if you have a kid who likes to performing arts and they're like I don't know what I want to do when I grow up it's such a fun way to see some of the different jobs that tie into performing arts and it goes into you like what a day in that person's life would look like what kind of schooling they had or what kind of like what it took to get the job the best and the worst parts of their job and so it's just you were talking about stand up comic actress actor and there's so many different things in here. So I love that it's showing different careers that your kids could have a critic a screenwriter a pop singer a movie director a vlogger a lighting technicians radio DJ a stunt artist. There's just so many different things so it exposes to so many like Emily has always said she wanted to be a vet and I think mainly that's because it's the only job that she knew that works with animals and then we got the I like animals what jobs are there and now after learning how many different things work with animals she's pretty sure now that she wants to be a wildlife conservationist because she loves the idea of conserving the animal species or the population. So I just I think those books are amazing for kids. So if you if they have one that ties into the topic your kid is interested in you should buy it. The last thing I got for her just because I thought she would really like these is yoga animals. So it's a book series and it's all animal based yoga and she loves like the Cosmic Kids Yoga on YouTube. So I thought she would enjoy this because it's all like I said animal based yoga. She's going to think it's a blast. So this one is yoga animals in the Arctic. Yoga animals on Savannah. Yoga animals in the forest. Yoga animals at the seashore which this is the book that started at all because I was looking for ocean stuff or ocean unit and then I you know kind of fell down this whole full of yoga animal books. So we have yoga animals on the farm as well. So each of these have like 13 different poses to jump stretch balance breathe and relax with those animals and so I think she will think yoga is a lot more fun and I'm hoping that maybe it will lead down you know some like mindfulness and relaxation types of rabbit trails. We'll see. I'll let you guys know but that's it. That is everything that I purchased from us born for our back to school fifth grade year. I'm sure that there will be things that we add in as they release new titles. That's what we've gotten so far. Don't forget to check out the rest of our back to school hall and stay tuned for more.