I shall welcome you all once again to MSB lecture series on Interpretive Spectroscopy. In my last lecture, I started talking about UV visible spectroscopy. So let me continue from where I had stopped in my previous lecture. We started talking about electronic transitions. Of course, electronic transitions can be broadly classified into four types, sigma, sigma star, n to sigma star, n to pi star and pi to pi star. And sigma to sigma star are shown by saturated hydrocarbons in which all valential electrons are involved in the formation of sigma bond. That means no electrons are left unutilized for bond formation in the valential. So these transitions require very high energy and occur at lesser wavelengths, less than 200 nanometer and fall in vacuum UV region. And if we consider n to sigma star transition, compounds having non-bonding electrons on hetero atoms such as oxygen, nitrogen, sulfur or halogens can show such type of transitions. The energy required for these transitions decrease with the decrease in electron activity of hetero atom and therefore the wavelength of absorption increases. And then the third type is n to pi star. Compounds having double bond between hetero atoms, for example, C double bond O, C double bond ES, n double bond Y, etcetera show these kind of n to pi star transitions. These transitions requires only small amount of energy and takes place within the range of ordinary ultraviolet region. However, the intensity of absorption is generally very low and these transitions have an epsilon value of less than 10 raised to 4. Of course here when you look into overall the energy difference between these levels n to pi star is the least energetic. That is the reason it requires very low energy for the promotion of the electrons. Pi pi star compounds having double bonds show these transitions. The intensity of transition is very high for these transitions. These transitions have epsilon value in the range of 10 to the power of 4 or more and they are also allowed transitions. All these electronics spectroscopy if you look into it, all these compounds having different region of usable range. So that means definitely we have substituent effects. So what are those? A functional group capable of having a characteristic electron transition is called a chromophore. We should remember the chromophore is responsible for electronic transition. The attachment of a substituent group other than hydrogen can shift the energy of the transition. So that means substituents that increase the intensity and often wavelength of an absorption are called axochromes. And then substituents may have any one of the four effects on chromophore. What is that one? We call it as bathochromic shift that is also known as red shift. What happens in this one? Shift to longer wavelength. When it goes to longer wavelength means probably we are thinking of decreasing the gap between HOMO and LUMO. So then it requires low energy that is the reason it is called bathochromic shift or red shift or shifting to longer wavelength or it is a low energy transition. Then the second one is hypsochromic shift that is also called blue shift that means shifting to shorter wavelength and higher energy. That means when the gap increases we need to give more energy that is the reason it is called blue shift and also shift to shorter wavelength and also high energy transition. What is hypochromic effect? An increase in the intensity of the transition then hypochromic effect is a decrease in intensity. So these four terms we come across and these four comes as a consequence of the influence of substituent on chromophore. You can see here in this plot you can see if you say here it is a 200 nanometer and here is 700 nanometer and this is epsilon value. You can see hypochromic and hypochromic this is hyperchromic and this is hypochromic and this is bathochromic and hypsochromic. The moment you see the shift from left to right it has to be hypsochromic blue shift and right to left means it is bathochromic red shift and as the intensity is going high it is called hyperchromic and intensity is dropping it is called hypochromic. So these are the influence of substituents on chromophore which is responsible for electronic transition. So now here I have given a list of chromophores and with a specific example in each case and also the solvent in which we have looked into the transition and the lambda maximum and epsilon and also the type of transition very useful table this is. For example if you look into alkene we know that we have a double bond so immediately we can say it should be a pi pi transition and once it is a pi pi transition you can anticipate little higher epsilon value this is in the 13000 and lambda maximum is 177 nanometer the solvent consider is n heptane. Then if you take alkene we have a triple bond and again solvent user is n heptane it can show lambda maximum in the range of 178 to 1, 225 and then here epsilon value varies 10000, 2000 or 160 and here it is pi pi star transition other transitions can also be seen. And then if you consider carbonyl carbonyl group make aldehyde acid or a ketone. So in this case for example if you consider aldehyde n hexane is there and here you can anticipate 186 as well as 280 and for 186 epsilon value is little higher compared to 280 it is low and then for this acetone n hexane 180 and 293 and in case of 180 large epsilon value will be there in 293 it is low and here in the large one is due to n to sigma star and the lower one is due to n to pi star. We know that n to pi star is of weak intensity and same thing here whenever weak intensity is there you can conclude that it is not n to sigma star it is not even pi to pi star it is n to pi star. And then carboxylic group if you consider acetic acid an example recorded in the ethanol it shows 204 and then 41 so immediately when you look into the epsilon value one can conclude that certain it is due to n to pi star transition. And in case of amide group for example if you take acetylamide water is taken as a solvent because soluble in water this is 214 and then 60 again same thing it is n to pi star and then with azo compounds are there n double bond in ethanol and 339 and then 5 very low so again you can conclude that it is n to pi star. In case of nitro iso octane is a solvent taken and values 280 and epsilon value is again low 22 so this also again due to n pi star transition. If you take nitroso group recorded in ethyl ether 300 base or 100 where in case of 665 20 it is again n to pi star and then in case nitrate it is dioxane is the solvent chosen and then lambda maximum is 270 and then epsilon is very low again. So what we can see clearly is pi to pi star has higher epsilon value and n to sigma star also has reasonably higher epsilon value but wherever the epsilon absorptive coefficient is very low without any hesitation we can tell this is due to n to pi star transition. This gives some idea about the different type of chromo force and their characteristic lambda maximum and epsilon maximum and also the type of transition we come across. Then looking to substituent effect let us look into solvent effect. When we talk about the polarity comes into the picture increasing the polarity of the solvents shifts n to pi star transition to shorter wavelength that means addition of polar solvent results in blue shift n to pi star goes to shorter wavelength or higher energy that means gap is increasing. So this blue shift is mainly due to the greater stabilization of the ground state than the excited state through dipole-dipole interaction that means polar solvent induces dipole-dipole interaction as a result what happens the ground state will be dropped in energy than the excited state and hence the energy gap increases and the wavelength decreases and the energy required increases in frequency. So this is a typical polar solvent for example when you take non-polar solvent this is a situation when you add a polar solvent the ground state is more stabilized means it drops in energy as a result n pi star gap homo-homo gap increases and hence it shifts to blue region it is called blue shift. That means if a group is more polar in the ground state than in the excited state increasing the polarity of the solvent shifts the absorption to shorter wavelength. So this we should remember we come across hypsochromic shift blue shift. On the other hand increasing polarity of the solvent shifts pi to pi star transition to longer wavelength then it is called red shift. So the red shift is mainly due to the greater stabilization of the excited state than the ground state through dipole-dipole interaction formation of hydrogen bonds or solvent effect with the polar solvent is responsible for this kind of rearrangement. So that means increasing the polarity of the solvent brings down the pi-pi star gap to the lower level as a result what happens longer wavelength radiation is required for electronic transition this is called red shift. Red shift is mainly due to the greater stabilization of the excited state than the ground state. In case of earlier one we saw the blue shift is mainly due to the greater stabilization of ground state than the excited state opposite is true here. The red shift is mainly due to the greater stabilization of the excited state than the ground state through dipole-dipole interaction this is probably due to hydrogen bonding or solvation with the polar solvent. So you can see the situation in non-polar solvent this is the one and in the polar solvent this gap decreases and it goes to red shift that means longer wavelength that means if a group is more polar in the excited state than in the ground state the increasing the polarity of the solvent shifts the absorption to longer wavelength. This is a second type of solvent effect on pi-pi star transition previous one was n to pi star transition then what would happen if there is an extended conjugation an increase in conjugation decreases the energy required for electronic excitation that means extensive conjugation brings the gap between pi-pi star if the pi is homo and pi star is lumo this gap is considerably brought down if we have extended conjugation. From molecular orbital diagram shown here two atomic p orbitals form two sets of sp2 hybrid carbons here and here so form pi-pi star in ethylene so here you can see this is simple ethylene but if we compare this one to butadiene here mixing of 4p orbitals results in energetically symmetrical distribution of 4 MOs compared to ethylene due to which homo-lomo gap is reduced and hence transition energy goes to longer wavelength. So that means you can compare here this is what typical ethylene and this first butadiene here the gap is considerably lower here compared to what we see in case of ethylene. So that means delta e or energy required for homo-lomo transition is reduced here that means conjugation conjugation decreases the homo-lomo gap and hence it will be a redshift. So conjugation effect can be seen for different transitions here with the different systems the longer conjugated systems decreases the energy gap between homo and lumo and it progressively it becomes smaller and absorption shifts to longer wavelengths so you can see here ethylene to butadiene to hexatrine to octatetroine so that means you start from one double bond two double bonds conjugated three double bonds conjugated and four double bonds conjugated you can see very nicely the energy gap is diminishing and shifting to mostly longer wavelength so this is called conjugation effect. So now let us look into important rules such as Woodward Fischer rules for calculating lambda maximum for a given compound by considering all functional groups present in it. If you consider homo annular diene a cyclic diene with conjugated double bonds in the same ring they are called homo annular diene if you have conjugation or conjugated double bonds in the same ring this is called cyclic diene and then we look into hetero annular diene a cyclic diene with conjugated double bonds present in different rings it can be something like this or it can be something like this. So hetero annular diene is one in which we have a typical cyclic diene with conjugation are two double bonds present in different rings and endocyclic double bond a double bond present in a ring is called endocyclic double bond exocyclic double bond a double bond outside the ring with one of the doubly bonded atom is a part of a ring so this is something like this and here we have both endocyclic double bond and exocyclic double bond this is a typical example here where you have both so this how some of these unsaturated compounds are defined with terms homo annular diene hetero annular diene endocyclic double bond and exocyclic double bond with example in each case is given here. What are the Woodward Fischer rules for conjugated dienes trienes, Pauline etc let us look into it. Let us consider a parent value so by identifying the type of cyclic system we have to give a parent value what are those parent value a cyclic conjugated diene the value is 270 nanometer for homo annular conjugated diene it is 253 nanometer in case of hetero annular conjugated diene it is 214 nanometer we should remember now we should look into the increment provided we add something else to it for example each alkyze substituent or a ring residue add 5 nanometer and each exocyclic double bond we should add another 5 nanometer and then double bond extending conjugation 30 nanometer if we have oxochrome such as war 6 nanometer and SR 30 nanometer and if you have OCOH3 carboxylic group then there's no need to add anything and if you have chlorine or bromine add 5 nanometer and if you have an amide group Nr2 add 60 nanometer so one typical example is given here and calculated value here comes 234 nanometers by considering the hetero annular diene here and then the three ring residue is there so add one ring is 5 so three are there 15 and one exocyclic double bond is there another 5 increment so it comes around calculated lambda maximum comes around 234 and if you actually measure it would come very close to this value given here then if you see homo annular diene conjugation within the ring the value designated is 253 and two ring residue so 10 nanometer two alkyze substituents 10 nanometer it comes around 273 nanometer so this how one can effectively use Woodward-Fischer rules for conjugated dienes to predict the lambda maximum value okay now further continue if you have alpha beta unsaturated compounds also Woodward-Fischer rules are available parent values are given here alpha beta unsaturated acyclic or 6-membered ring ketone the value is 250 nanometer and alpha beta unsaturated 5-membered ring ketone is 202 and alpha beta unsaturated aldehyde is 207 nanometer is the parent value and then increments follows this order at alpha position if you have alkyze substituent or ring residue then add 10 nanometer at alpha position at beta position add 12 nanometer and at gamma and higher position add 18 nanometer and for every exocyclic double bond add 5 nanometer and double bond exocyclic to two rings simultaneously there's a 10 nanometer so that means we have to watch carefully the structure before we give this increments for the parent value and then double bond extending conjugation give 30 nanometer and homo annular conjugated dienes at 39 nanometer so one such example is considered here parent value is 215 here because this is alpha beta unsaturated 6-membered ring here and then one alpha ring is there 10 nanometer and one delta ring is there 18 nanometer one exocyclic double bond is there 5 nanometer one double bond extended conjugation 30 nanometer one homo annular conjugated diene is there 39 nanometer so calculated lambda maximum value for this compound considering the increments added to the parent value it comes around 317 nanometer so one can conveniently use this method to predict the lambda maximum value and then that can always compare with the experimental value so here some axochromes values are given if alpha position for hydroxy group 35 beta 30 and gamma 50 and similarly for over group alkoxy or iloxy group 35 30 37 respectively for alpha beta and gamma positions and if you have SR value SR is there function group so in this case what happens alpha nil beta it's 85 and gamma nil and if you have carboxylic group alpha position 6 beta also 6 and gamma whether it's in alpha beta or gamma 6 increment has to be given nanometer and for chlorine alpha position 15 beta position 12 and nothing need to be added if it's in gamma position and then similarly for bromine we add 25 and 30 so this is how we can carefully look into the increments by identifying the groups and their position and adding the increments for various oxochromes or other fragments to the parent value very conveniently very nicely very precisely we can calculate the lambda maximum value now let's look into the type of electronic transitions responsible for color of compound especially coordination compounds so that means in complexes instead of looking into the several transitions I showed you most of this transition whatever I showed you sigma to sigma star pi to pi star n to sigma star this are all mostly confined to organic moieties nevertheless we can also see in the metal complexes originating from ligands or metals to an extent and we get one more extra transition that's called DD transition in metal complexes for example if you consider 3d 4d or 5d series they have anywhere from D1 to D10 electrons in their valence shell and then in case of octahedral compounds we know from crystal field theory that they are split into t2g and eg and in case of tetrahedral complexes e and t2 opposite of that one and in case of square planar complexes we have dxy and homo and dx my square as lumo and between them electronic transition takes place that we call it as DD transitions so what are the conditions for DD transitions do really DD transitions are allowed or not all those things we shall look into detail in my next lecture now just I have given one example here hexa aqua titanium 3 plus a D1 system and here you can see when the electron is there and this electron after giving the energy it is promoted here this is called DD transition similarly if you take cobalt tetrachlorocobaltate 2 minus it is tetrahedral compound we have four electrons it's a high spin complex we have four electrons in e and three electrons in t2 so here which electron is responsible so either e this electron can go or this electron can go that's what we have seen so here we can see the transition so let us look into more details of DD transitions in my next lecture so until then see you all have a nice time


A bankruptcy court has cleared the way for Iron Range mining company Magnetation to shut down its remaining operations. The court on Thursday approved a motion to wind down the company and terminate its pellet purchase agreement with Axe Steel. The company says its focus is now shifting to shutting down its iron ore concentrate plant in Grand Rapids and its pellet plant in Reynolds, Indiana. If you've enjoyed this segment of Lakeland news, please consider making a tax-deductible contribution to Lakeland Public Television.


Pre-season's been going great. Players have had a lot of energy. Coaching staff's been doing really well. I feel fortunate to have Brenton LaRose and Tommy Holcomb on our staff, and they've been doing a really great job. So very organized, and players are really excited and ready to go. Early season takeaways, I would say we have some depth and athleticism. So defensively, I would expect to be pretty good this year in the infield behind the dish, in the outfield. So very pleased with how that's going so far. Also, just the tireless, relentless work ethic that I'm seeing from our guys. The position players are getting extra swings in all the time, always out doing some extra throwing, extra running. And if that's any indication of what they're going to be like as competitors, I think we're going in the right direction. I would also say I'm really impressed with our pitching staff lately. Those guys executed a really good throwing program this off season and came back stronger than ever. And I've been very pleased with how they're doing so far. As a first-year head coach, I think it's easy to say that we want to rebuild or have a five-year plan. And I understand that this would be the third time that I've been a first-year coach at a program. I don't think your players want to hear that. So for me, my expectations are pretty high. We expect to compete in the Mac this year. I plan on being a playoff team this year and have a chance to compete for a championship right away. That being said, I also think the future is very bright here at Stevenson and that this is a program that there should be no limitations to what our expectations are. Sure. One thing I would say is Coach LaRose and our previous coach here, Coach Gage, they did a very good job of recruiting. And we have a really talented group of young first-year players. So I'm really excited to see how they do. They'll get a lot of opportunities. And we have seven or eight transfers that are in also that it's great to have them on board. And it just gives us depth and some experience on a pretty inexperienced team, to be honest. You have a couple guys coming back that have a legitimate experience on our staff, Labrador, Pellegrino, and then we have some guys with injuries that are coming back, like Sandsbury, for example. And then Nick Tamborino as a hitter, he's a guy that's going to be the middle of our lineup and someone that could make a serious-running player of the year type of guy. So Brandon Perillo, he's one of our captains, along with Jason Labrador as a pitcher. The three of them, I think, they set the standard, they set the tone for this team. And you could tell, the guys are responding well to them.  Well, we look at the season, kind of break it up into three or four different seasons. And we have hood starting off the second part of our season, which is conference. And before that is our first season, we got Mary Baldwin, Leslie, Franciscan, McDaniel. And these are all games that you can't take lightly. We go in there, we play to win those games. They're going to be good competitive games with good coaches and good programs. And there's also going to be opportunities for our guys, all of our guys, to play. Because we still have guys trying to earn positions and earn time. And I want to have the opportunities for those guys. When season two comes around, we'll have our best nine on the field. So I'm so excited for this season. I really love this group of guys. I've had some really good people I've been around these past 10 years as a head coach. And these guys are right there in the mix with some of the best people I've got to coach. And I feel very thankful to be here. And I'm excited about what we're doing right now here at Stevenson. And I think these guys are ready to go.


In a critique of the scientific validity of the Dietary Advice in Men's Health magazine, they discovered nuggets like this, claiming meat can give men a testosterone boost, which we've known for a quarter century, that a meal with that much fat drops testosterone levels nearly a third within hours, in fact a significant drop of both free and bound testosterone in the bloodstream, within just an hour of it going in one's mouth, whereas a low-fat meal, mostly carbs, has no such effect.   But even more importantly, all their cortisol levels go down. Cortisol is a stress hormone produced by our adrenal glands. Having low stress hormone levels is a good thing, because high cortisol levels may strongly predict cardiovascular death in men and women, both with and without pre-existing cardiovascular disease. In fact, this may help explain death from a broken heart, the heightened heart attack and stroke risk in the immediate weeks following losing a spouse. The higher cortisol levels, days, months, or even years after losing someone you love, may increase cardiac risk and reduce immune function. And you'll note that rise in stress hormone levels losing a spouse, a bump of about 50 points, is less than the bump you may get eating a high meat diet. Cortisol may also help explain why those who are depressed tend to put on abdominal fat.  And so the accumulation of fat around our internal organs may be an adaptation by which our body deals with excess stress. These spikes in stress hormone levels every time we eat a lot of meat may not just affect our health, but that of our children. Substantial evidence now suggests that high protein diets during pregnancy has adverse effects on the fetus. For example, back in the 60s, an experiment was performed on pregnant women in Motherwell, Scotland, in which they were told to eat a high meat diet in hopes of preventing preeclampsia, a disease of pregnancy. It didn't work. In fact, the lowest preeclampsia rates I've ever seen were among women eating strictly plant-based diets, only one case out of 775 pregnancies. Preeclampsia normally strikes about 5% of pregnancy. So there should have been dozens of cases suggesting a plant-based diet could alleviate most, if not all, of the signs and symptoms of this potentially serious condition. But what did happen when pregnant women went from eating about one portion of meat a day to like two portions of meat every day? Mothers who ate more meat and fewer vegetables during pregnancy gave birth to children who grew up to have higher blood pressure. One explanation for the adverse effects of high meat and fish consumption is that this may have increased maternal cortisol concentrations, which in turn affected the developing fetus, resetting his or her stress hormone thermostat to a higher level. But you don't know until you put it to the test, and indeed researchers found higher blood cortisol levels in both the sons and daughters of women who had reported higher meat and fish consumption, about a 5% increase for every daily meat serving. Such diets may present a metabolic stress to the mother and kind of reprogram the adrenal access of their children, leading to lifelong hypercordazolemia, elevated levels of stress hormones in the blood. This may help explain why every daily portion of meat during late pregnancy may lead to a 1% greater fat mass in their children by the time they reach adolescence. So this could increase the risk of their children becoming obese later in life, and so have important public health implications in terms of prevention of obesity. Now, if they're already born, you may be able to bring down their stress hormone levels with similar dietary changes. But this is just baseline stress hormone levels. Do children of mothers who ate more meat during pregnancy also have exaggerated responses to life stressors? Researchers put them through a stressful challenge, public speaking, mental arithmetic, and measured their cortisol responses. If their moms ate less than two servings of meat and fish a day while she was carrying them, they got little shots of stress hormones from their adrenal glands. But those whose moms ate more really got stressed out, and those whose moms ate the most, 17 or more servings a week, that's more than two servings of meat a day, appeared to really be quaking in their boots. So in a way, you are what your mother ate.


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Welcome folks, this is Tom O'Brien of TFNN. We have five days a week, we go seven hours a day, we go 24 hours a day on the internet, acttfnn.com. Always remember folks, whatever you think about, you bring about whatever you focus on grows. Hope everyone's having a great day, safe day. It's making a great night, folks. Serve the one you love. Once you decide to be a couple, you're there to serve the one you love, to serve your love to your lover. And every kiss and every touch, you feel you're there to please the one you love without expecting anything back. Mockin' wise, let's take a look at it out here. We have the Dow Industrial's down 60, Nasdaq's up 117, S&P's up 17. Gold, Gold contract down $25.50 trading at $19.78 an ounce. We have Silver down 22 cents, $23.67 an ounce. Lightsweak crude down a buck, $71.79 a barrel, notes and bonds, a 10-year note. Down 26th, trading $113.30, the 30-year off 27 at $127.30 and Kingdoll, Kingdoll's on the move top side. Up 697 ticks, 103.578, the euro's at 107, the yen is trading at 138 and the British pound is at 124 to one at U.S. dollar. Our phone number's<PHONE_NUMBER>. Give us a call, folks. One note's going on in your world and the world of the S&P's, let's take a look at them. What do you have? We go over to the spy first. We have had some nice volatility out here today, no doubt. We take a look at the spy. Right now the spy's up a buck 80. You're going after the swing high. Now the swing high that we're dealing with out here is the swing high that was back in January. That's 418.31. Now we hit 418.06 today. So the bottom line is that it's getting close to tagging it. It hasn't tagged it yet. I wish that it actually did tag it today. I mean, we got close to it, we didn't tag it. Because what you have here is that you're doing volume of 60 million versus that 101. So a test is a test, but a test, folks, is when it actually tags it and it hasn't tagged it yet. So close, but hasn't done it yet. Now the other swing that we're talking about which it took out was the 417.62. And right now we're at 417.13. What the difference is, is this, is that this wouldn't be a failure even if it closed underneath it because of the fact that we're already at 62 million shares versus that last high, or 60 million shares versus that last high of 62 million. That's how that works when you look at a price and volume and inside of the context. That's how it works, that's the bottom line. So we need a few more pennies up there. We go into the NDX100, you get a whole different animal happening inside the NDX. There's no doubt about this, man. So inside the NDX, what do we have happening? You get a higher high. Now the swing point we're dealing with in the NDX and this is gonna be on the weekly now. And we just went from 304 and accused at 335 in a heartbeat. And you can see what's happening here. The swing you're going after there is the 334.47. And right now we are at 335.67. So you're buck 20 over it. On the weekly basis, it can make it. It can make the volume too. It's the volume they were talking about is 270, 223 you need. And right now we're already at 170. So that can make it, you know. And if that's the case, then you're really gonna see because the next swing point up there is 371. So it's pretty intense. Notes and bonds. We take a look at the note and bond market. Ten year note right now is coming down to 1.5 million contracts. You know, you're coming into still larger contract volume, much larger actually. But let's see what kind of retracement we've already done thus far. So you're coming into the 0.618. I suspect you're gonna get it because if you look at this, watch this. You're gonna see that's where all the volume is too. All the volume is right here on that bar. That bar there, look at this. You're talking about the bottom of that bars. We're at 113, the bottom of the bar of strength is two of them actually. But the first one that's coming into right now is 112.23. That's a monster bar. The bar before it is also a monster bar. So, you know, we'll see how that baby shakes out. We get over to the gold contract. Going south as the dollar's going north. And to take a look at the gold contract, we have with the gold contract, you're down with, interesting. Okay, so what do you see? One second. Yeah, we're rolling. I see what's happening here too. Okay, we're rolling. This has a lot lower to go. That's the real bottom line. Okay, so we're at 1977 on this contract. We already broke the consolidation on the contract. That sets up. You know, the next leg here, well, we already hit 1962, 1930, 1930s game. If you go to the XAU, the HUI, we were talking about this this week, bottom line. It's making its way down to the last time we had any volume. It's pretty amazing actually that it's made its way down there in four days. You know, bottom line on Monday, we sold in the gold report. I sold specifically because of this. So, and the XAU, we're talking about that number 125. And that seemed like a big number on Monday. It was a big number, but it came down there fast and furious. On the gold, on the gold bugs index did the same type of setup, you know, and it's going to be interesting to see how it hits this inside of the XAU and the HUI. Cause if that baby comes back with too much volume into it, you know, that's going to be a little, that's going to be not only a little problem, it's going to be a larger problem. And you can see the gold bugs index, we're down at 249, the number we're talking about is 244. And in four days, we just went from 271. So, GEDX is going to be the same type of setup. That's how, this is how a trick gold trades to folks. That's the bottom line. It's just our trades, man. The GEDX has an expansion of volume out here today. The number on the GEDX is the 3103. And we just went from that Monday morning from 34 to 3,170. We'll see how it handles us down there. So, some of the higher volume equities out here, we take a look at, you have Teslas up a buck and a half. You got Advanced Micro up three bucks. Nvidia, look at Nvidia. Oh my God, Nvidia is up 15 bucks. And you still only have a 1.5% shot position on it. But bottom line is that when they move in Nvidia, they move Nvidia in a monster way. Stay right there, folks. We got our man, Mr. Tim Wood, coming back as he does each and every Thursday to recap the indices out here. We have the Dow Industries down 28. And as that goes up 130, SAP is up 21. We're going to come right back with Tim.


Hey, this is Brett and this brand new 2023 Jeep Wrangler Unlimited Willis Package is stock number 23J15. I'm here at Summit Automotive in Fond du Lac, Wisconsin. You're new and used Jeep and Jeep Wrangler headquarters. This brand new 2023 Jeep Wrangler has the three liter eco diesel V6 engine. It puts out 260 horsepower, 442 foot-pounds of torque. It's going to get you 29 miles per gallon on the highway, 22 city for an average of 25 miles per gallon. This is a brand new color for 2023. This is Earl Clearcoat. And I think it is instantly one of my favorite colors on the Wranglers. Really a cool. It's like a got a little bit of blue hint to it, almost like a sea foam green. Really a good looking color. I'm going to go all the way around in this video go over all the options. This thing is loaded up really nicely. And we'll go through all those options.  It also gives you the gloss black fog light bezels there, as well as the Willis writing on the hood there. This one does have the premium lighting group up front. So you get the LED headlamps, the LED running lights, as well as the LED fog lamps. And I'm going to turn those on at the end of the video. So definitely stick around for that. You also get the, I believe they're called Moab Black alloy rims. And it has Firestone Destination MT2 tires. These are LT255, 75 R17s. Definitely have a mud terrain tread pattern to them. Get the blacked out little bezel there. Notice you get the sandals on there. Jeep climbing up the side. You get the T50 door hinge removal there. We actually have a video showing you how to take your doors off your JL Wrangler, if you want to check that out. You get the rock rails with the Willis Package as well. I'm going to show you the original window sticker and feel free to pause this. I'm not going to go through everything, but most of everything. 2023 Wrangler four door Willis 4x4 Earl clear coat, black interior, three liter V6 turbo diesel, eight speed automatic transmission. Everything on the left there is your standard equipment that you get with the Sport Package. Because this is a Sport Package with the Willis Package on top of it. Down here is your Earl clear coat, 495. Customer preferred package 26W, which is the Willis Package is a $6,935 option. You get the LED headlamps and fog lamp group, 17 inch Moab black aluminum wheels, rock protection, sill rails, deep tint sunscreen, power heated mirrors, remote keyless entry, anti-spin rear axle, front LED fog lamps, LED premium reflector headlamps, which I think they already said, sun visors with aluminum vanity mirror and all weather floor mats by Mopar, as well as mold in color bumper with gloss black, which is those fog light bezels. Convenience group is 795 gives you the universal garage or opener. This one has the cold weather group. So you get heated seats, remote start and heated steering wheel, eight speed automatic transmissions, 2,500 bucks. The three liter V6 eco diesel is $4,000.  And it does come with the Alpine premium audio system, which is $1,295. Serious XM for $2,995 with a six month subscription and a total MSRP is $55,750. If you wanna get your summit price in the upper right-hand part of the screen, it's a link to our website. Click that and get all the pricing and rebates and availability on this Wrangler warranty. Three year 36 bumper to bumper, five year 100,000 powertrain. They're your miles per gallon, 29 highway, 22 city, 25 average and it's not really rated for any safety radians except roller, which is three. We'll get to the interior in just a little bit, but just kinda wanna highlight how good that Earl clear coat looks. You also get the four wheel drive sticker on the back that's just a sticker. So if you didn't like it, you could always take it off. LED tail lamps, always liked the EcoDiesel logo. Back storage area, this is your carrier for your front hardtop pieces. And there's your Alpine premium subwoofer. Notice that you get all the bars are painted color matched to the outside of the vehicle. So when you have the top off, looks really good. Speaking of that top, you got three bolts on the side, two on the top, total of four bolts, two quick disconnects. Actually did a demo on how to take your hardtop off of your jail. A lot of people really like that. That's in the upper right hand part of screen if you wanna check that out. Get a really good idea of that Earl clear coat. You get the jail badge back here with the wheel base and overall length for the two door four door and water forwarding on there as well. Those shut really nice and easily. Get the blacked out fuel door. Willis package, really a good looking package. You get the trail rated four by four logo, Jeep logo and Wrangler logo there. I just noticed they took the unlimited away from the Wrangler there. Normally that says unlimited. Black cloth interior. You get the driver's seat, head adjuster, lumbar. These do come with airbags on the side now. You get the all-weather topographical floor mats really like those. Power locks, power mirrors, power windows as well. Hop inside, this one gives you the smaller LCD display. And you get a digital speedometer there. Only 12 miles on this one. You get the heated leather wrapped steering wheel. Cruise controls on the right. Bluetooth and information center controls on the left. It does have the audio controls on the back of the steering wheel. This one comes with the seven inch Uconnect radio, AM FM and Sirius XM radio capabilities. You can do your heated seats and heated steering wheel here. This is also where your backup camera shows up. You can see that that is crystal clear. I love that they made the backup cameras HD on the Wranglers. That was always the downfall of the older Wranglers on the JKs, no backup cam standard from the factory. And then you have all your different apps that you can do here. You can project your cell phone to the screen via Android Auto Rapid CarPlay, connected to your Bluetooth cell phone. So you could project your phone up there if you have a nav system like Waze or Google Maps projected to the screen, then it's like you have nav right on the screen.  There is a little Jeep on the top of there. And this one does have the keyless entry with the remote start. You get the flipper key on there. I always thought those were nice chunky key fobs. You always know which key you have in your pocket. You get the mineral gray dash trim. It's actually got just a little bit of metal flake to it. And that comes on the Sport package. On the Rubikons, they're red. On the Sahara's, they're leather. You get all the quick disconnects for your hardtop, home link buttons for your garage door security systems and lighting systems. We'll take a quick look at the back seats and then we'll turn on all those lights and I'll do a walk around and then I'll turn the lights off in the studio here and show you to all lit up with the lights off. Back seats, latch child safety system. You can put these headrests down for better visibility and they can stay down while the seats are up. And then these seats do fold down pretty nice and flat, which is nice to haul extra stuff. Get that topographical floor mat back here as well. Power window buttons, child safety locks on the back doors and let's start it up. We'll do a final walk around and then we'll turn all the lights off in here and do a walk around like that. Like the, really like the eco-diesels, they're quiet. A lot quieter than you think a diesel is. All right, there are all the lights on. So the tail lamps are not LEDs. The license plate light is. We'll do a final walk around here. I would personally like to thank you for checking out the video today and hopefully from this HD video, you've been able to verify the looks, styling and options and check out the brand new Earl clear coat color. See those LED headlamps are super bright.  All right, you can see just how nice and bright those lights are. Now the lights in the fenders are not LEDs. This is just the headlight and fog light LED group. So you can see just how nice and bright that lights up everything. And license plate lights look good as well. All right, I'm gonna turn everything or mostly everything back on. And I would personally like to thank you for checking out the video today and hopefully from this HD video, like I said, you've been able to get a really good idea of the overall looks and styling of this vehicle. And to see more pictures of this 2023 Jeep Wrangler or one of our other 550 new new cars, trucks, SUVs, minivans, Wranglers, you name it, we gotta go to that website right there, summitauto.com for pictures and descriptions of every single vehicle from two locations, all at summitauto.com. And if you'd like to check out more HD videos, you can go to youtube.com slash summitauto. Remember to like, subscribe and share on this video and all the videos that you see there. Click the bell notifications, you'll get updates on the videos I do each and every day here at Summit Automotive. In fact, in a second you will see a link to subscribe to my YouTube channel on the upper left, a link to more Wrangler videos that I've done in the upper right, a link to this vehicle on our website. In the lower left and a link to one of our latest YouTube videos in the lower right, click those, check this out. We're super excited to help you with the brand new 2023 Jeep Wrangler Willis Sport Package and Earl Clear Coat. Thanks again for checking out the video. Remember to like, subscribe and share on the YouTube channel, I really appreciate it.


In this video I'm going to show you how to set up a very basic docker file for our project. Now one thing I like to do is as I work through these courses, if you're not familiar with taking any of my courses, I will create a new branch. So I'm going to come in here and add in a new branch. I'm just going to call this docker base. So we were previously on the main branch, now we are going to docker base. And this gives you the ability to see exactly what was changed in this video. So I will be doing that for the remaining videos where I'm actually changing code and you'll be getting a new branch. So you can do a compare of your code to a specific branch and see what was changed or what you're missing. So very handy tool to give you. So now I am on docker base and let's go ahead and set up a docker file. Now there's a couple of different ways that you can approach this. I'm going to put things under the main folder for the Maven project structure. Some people when they're doing projects, especially if they are using a build script, they'll put it in the docker file into the root of the project, which is perfectly fine. That is a valid way of doing that.  I'm going to call this docker base. And let's go ahead and create a new docker file. And by convention that is capitalized. So docker file all lowercase. And I will be adding that to the branch. And here I'm going to show you just a very basic vanilla docker file for running our spring boot application. So I'm going to say from open JDK. You can see I'm getting the autocomplete there from Tel-J, I'm going to say JRE. And I want the slim build, so this is a more efficient. And to be honest, you see I'm getting code complete for Buster, SID, and Stretch. I honestly don't know what those are. So I do know the slim build is a more efficient image. It doesn't have a lot of the tooling in there. So it's a very small lightweight image for us to work with. It does have the JRE, the Java runtime. So we are going to be putting in a JAR file, so that is already compiled so we don't need the JDK. The JRE is much smaller, so we have a much smaller image that we're going to be working with. And here we want to set up some environment. I'm going to steal from my working file here to the clipboard. I'm just going to paste this in from my clipboard. And here I'm setting an environment variable, Java Ops, and I'm setting up some memory limits for the JVM. And then this security from memory that goes through and helps initialize the JVM quicker and improves the startup time by setting that, I'm going to say WorkDir application. Now the trick is, we need to copy into our file. So we're going to be copying into the image that we're building in our Docker build script. And what we want to do is, we don't have it here yet. So if you don't see it, we want to run the package command. So in the lifecycle, we want to run package or verify either one of those or install, but package is the minimal one that we need. So I'm going to go ahead and package that. So now we do, in fact, get the JAR build, and that does run our test as well. So we only have, I think, one test out there that brings up the context of a pretty lightweight project. So we actually have four tests. I'm a spoke. So now what we want to do is copy. And this copy command is going to be relative to the location of the Docker file. So we need to go up a couple directories, and then we want to say, we're getting a target. It's not seeing it as a project file. And I see what I made, made a mistake. I actually put this here. I want that under main, let me do that quick refactor. So we have that under main, I mistakenly put it under Java, which is our class files. So we did not want that there. Now we're getting target in the auto complete. And we can see that we have these two. So the dot original is the slim jar. We want the fat jar. So that is going to be the executable jar there. So we'll go ahead and take that. That tells us to copy it, and we are going to copy it into the work directory. So the dot slash is saying copy it into the working directory of application. And then we want to do entry point. Now we're going to pass it a command line. So we're going to say Java. And here we want to give it the name of the jar. So this is a little lengthy and easy to mistype. So I'm going to copy that to the clipboard and we'll paste that in. So this is a very minimal Docker file for running in the spring boot application. So at the top we are seeing the Docker image that we want to pull from the JRE slim. We are setting environment variable for Java ops. We're just setting some memory limits and then the security and that helps with our application startup time. We are telling it the working directory called application. We are copying from our local file system. So we are doing a relative path there to target to the generated jar file. We are copying that into our Docker image. And then we are setting the entry point. And this is the command that is going to be running on startup. So this is the Docker file. In the next video I'll show you how we can run this from the command line.


Here. I've seen better. I mean it's pretty. I like the tiara thing here. But I've definitely, oh the bracelet's good. I've definitely seen better Christmas Barbies in that. I mean I've seen like red velvet ones with green. But that's a good one. Because Barbie's one of those toys, it's still, still pretty good. The ruffles are messy, Jackie's saying. I think that's supposed to be the style. I do like the tiara. That's pretty. But I've definitely seen better Christmas Barbies. Do you think they'll have a gender neutral Barbie next? I don't even want to see what that would look like. I'm gonna stay in this. Who's gonna let it drop? Who's gonna let it go to the bigger target? Who's gonna be out when it breaks the low? Who wants to get out right now? I don't know. I don't know if this goes in the next five, ten minutes. It's just sitting here, isn't it? Let's look up and see if there's any more tariff news. Gyro's gonna get out of sun. That's fine. Mark, it's rallying. Let's see. As soon as this gets through this level, I think it just drops and goes. Koala Bear's trailing the stop. I don't like to do that, but if you do that and you know how to do that, that's perfectly fine.  That's why I say don't lower the stop. I mean you'd literally have to put, and this is just basing here for like the last, I don't know, ten minutes. So, I mean if it pushes back, it's you're gonna lose profits.  This is gonna keep going. It's a question of it's gonna go right now between now and 1040, 1045, or if it's gonna take to 11 o'clock, or if it's gonna take till noon. This is worth holding if you, here it goes. Here it goes right now. Thank you, working out for perfectly, here. Here it goes. Everyone should still be in it if you're in it. We're at least gonna get it done at 22 and we'll see if it breaks out if not we're out. Well, this was a nice call. Congratulations. Great job everybody and good month. Here it goes. Wow, so happy I picked the best one today. I can't believe none of you like this as much as I did. I was the only one that was gung-ho about this this morning. What was up with that? Alright, 45, 41, 40. I want a nice trade. I do not want this to back up again in the 50s. See what it's gonna do. You can get out of this right here. If you don't have the stomach to hold it, I'm gonna try. That's all that I can say. But if you want to get out of this right here, you can. It just went down to the low and then did a little bouncy. This is a nice trade right here. So we really can get out right here if we want. 34. Now it keeps going. There. Hand of the button here for one more push down or I am gonna get out. This is too nice now with the ad and I don't want to be in it for three more hours. But I really do think it keeps going. So even if it doesn't keep going right now, I think it keeps going.  There, out, out, out, out. Not sitting through it. Good job everyone. In fact, great job everyone. If you're still in this and you want to be in this, I absolutely think it continues. But I can't say how long that's gonna take. Great job everyone. And we held it as long as we could. That could have just collapsed right down to 22. Didn't want to take the chance. Just didn't want to take the chance at all. I think any exit in the 30s or the 40s is perfect and you could still get out right here. And I really do think it continues though. So I just didn't want to sit through a bounce on the 15 minute chart here because there's 17 red bars down and one bar is gonna be green eventually. So you know, could be this one could be the next one and then you're gonna have to wait and then you have to wait for hours for it to fall again. I do like this so low or absolutely do. Great job everyone. All right. Any quick questions here got five more minutes with you guys I can talk about anything you want. What do you want to go over? It was a good day. Let's go over the gap. So beautiful move. Gap rated well and worked out better than expected. And like I said the stock can move. It was on its own. It had nothing to do with the market. The market's actually rallying now. I couldn't find anything when I but I Google was going on but it's rallying. So again I'm not a hundred percent sure we go straight back up if we do we do if we don't we don't. Not calling any trades in this though. Just don't have any conviction that we do go straight back up again. So just leaving the market be. If you're still in this look at it. It's gonna try to go again. It didn't fall and collapse under the low. Just pretty much touched it in bounce but I think this continues. It was a nice trade. And Tiff was a nice trade two days in a row. And I said to leave that today. And so hopefully everybody did. And Mar any questions from anyone about anything at all at all. This was worth doing the ad simply because of the size of the stop. But again you had to be willing to take more risk. But if you didn't do it and you're still in it. Look it's continuing right now. Once this breaks 40 it's going to do it right now. This is probably goes right down. If you're still in this it's perfectly fine. I just didn't want to sit through an enormous bounce. It looks like it didn't really even do it. So you could still be in this. It's breaking down right now. Here it goes here. Here it goes right now. Is anyone still in it. Just made a new low. S F M. Is anyone still in this at all.  Fred still in it.  It's pain. Listen have it. Oh Jair was still in it too. Listen have a great weekend everyone. If you're interested in the class email me. Deadline for all the renewals for the 40% off is Sunday. And I will see you guys next week. You made $2060 even after the spy trade lost. That's great job Jackie. So that's fantastic. Good for you. Pray for us. Pray for us in Mexico. Alright have a good weekend everyone. You're welcome.


Welcome to CTN Member Highlights, I'm Leslie McVane, and today I'm with Alice Spencer, the Chair of Tempo Arts. Hi, Alice. Hi. It's great to have you here again. Thank you. I think the last time was maybe in the park with the installation. So let's update everybody about Tempo Art and what's happening. There's a lot coming up this summer. Where do you want to begin with the first Fridays maybe? Sure. Our first piece, which is called The American Dream, has been up now a year. It will be up until next October. And we decided this summer to invite artists to respond to that piece, and to respond to it in the context of our present world situation. That's one of the wonderful things about Tempo Art Public Art is that it has the ability to address issues and ideas that are current, quite different from permanent public art. So we put out a call for artists. We got a number of responses, and we chose three artists that are going to do pieces, and I'll tell you a little bit about them. That would be wonderful. I would love to know. The first artist, his name is John Sunderling, and he is going to do an installation that takes Lincoln Park and shows its original boundary using a fence, so that it will go across the Franklin Arterial, turn a corner, and then come back again. So it will give the audience a sense of what was lost in installing the arterial back in the 1970s, and we're hoping to have historic photographs and other materials to show what happened. So are you working with greater Portland landmarks on this? We probably will be with some of their documentation for that. Our second piece is actually a kind of a performance piece. We're working with an artist called Kristina Bekstein, and she is working with a group of mainly Syrian Muslims who live in the Kennedy Housing Projects and doing gardening with them. And it's a community project, and it's a project to talk about community and connection and welcoming our immigrants from other parts of the world. And I know they do have a wonderful garden area there. And they'll be all sorts of beautiful signage along the arterial that we'll be talking about the project. The public can see this sort of evolving. Exactly. Oh, wonderful. Exactly. And you're third. And the final one is by a young artist called Kristine Prash, and it's going to be in Post Office Park, which is right across the street, actually it's part of Tommy's Park in the Old Port. And he is building blocks, and the blocks are going to be configured either to make an archway or a wall. And he's going to invite his audience to talk about what they want to make, whether they want to build worlds to prevent people from entering the park or whether they want to create an archway. A welcoming. Yeah. So it's a performance piece. He's going to have to be there to work with his audience. And I think it's full of potential. It gave me goosebumps, actually. I think it sounds wonderful. We're hoping that all of them, it starts conversations. That's the point. So will these be the start? You'll do some sort of an introduction on the first Fridays? Yes. They'll be an opening for each of them. And what we're hoping this year is that we'll have an actual table here right in the middle of the Bustle of Congress. And then have maps and send people off, because they're not right in the center of town, but we want people to go there. To go and explore the creativity that's around the city. So we had, I think that John wants to do some sort of a picnic in the medium. Invite people to come and have a picnic. Where they would have been able to. In the park. I think that's tentatively his thinking. Christina is actually going to have a potluck. She wants to have people eating together. People who come from afar eating with the women. And eating from the garden. Maybe something will be ready. I don't know. Or some other gardens. Her project is supposed to last only a month, but I think it's going to last much longer than that. Carry through even after her projected time. Now the house that's here now, the piece of art, the American Dream. Which is in the park. What will happen to that after October? We're not sure. There's been some interest in buying it by a real estate agent. It would, because it's a temporary piece, some of the rivets in it are not permanent. So there would have to be some remaking of it. But basically it's the artist's choice. She's been paid by us. If you can sell it again for her own benefit, that's wonderful. But she's in charge of removing it. I think it's been such a delight to have it here. I thank tempo art every day when I go buy it. We can look forward to the next art, and you've chosen a curator for choosing that piece coming up. Right, right. So we can look forward to that. I don't know. There's probably not a lot happening right now, but... Well, we are actually in the process of meeting with our new curator, just a little bit about her. We again put out a call for curators. We have quite a limited budget. We were astonished by the number of curators that responded. The young woman that has been chosen is a well-known national curator. She's curated over a hundred public art projects. She's from the Boston area, and she was so interested in our city and our arts that she wanted to play a role in our next piece. I'm so excited. The next piece is going to be on the back cove path, and it may be more than one piece. Oh, we're not sure. Oh, well, so... Stay tuned, everybody. Stay tuned. Well, thank you, Alice. And if people want to know more about tempo art, they can go to your web page and find out everything they need to know. And we have a Facebook page as well. Terrific, though. Thank you for being here, and we look forward to talking with you again and seeing all these wonderful things evolve. Great. Thank you. Thank you.


One the future could be like this Well, we are literally drowning in data That's kind of already. I think some people already feel like you know constant notifications or we could become superhuman right Where we can reach the universe, right? No limit to what we can know It's funny now every second movie that's made in Hollywood these days has the same motif Which is that we become superhuman by plugging into the internet directly I called the singularity Now this is a very dangerous thought obviously