Hello everyone, once again I welcome you all to MSP lecture series on Transmittal Chemistry. We have been discussing in length about the classification of ligands by donor atoms. In the middle of discussion about phosphorus donor ligands and we came to know I did mention about how phosphines can be tuned both electronically and sterically to make ideal candidates for the application of the complexes containing phosphines in coordination chemistry, ergonomatically chemistry and catalysis. So when we talk about ligands they are the most important components of chemistry especially coordination chemistry, ergonomatically chemistry and ultimate use in catalysis. And among all ligands the so called we know how to classify them as classical and non-classical. So these non-classical type of ligands stand out as most important class of anserative ligands or silent ligands or supporting ligands compared to any other donor system essentially because of their remarkable flexibility in tuning their electronic and steric properties and also the remarkable flexibility in the ligand design process. So from that point of view especially phosphines offer a great deal of flexibility in designing a several types of phosphines of course that goes with our imagination. One can make mono dented to poly dented with different linkers, linkers can be alkyl groups aryl groups or any other hetero donor atoms or any other hetero atoms for that matter. And another important thing I am highlighting here is about steric and electronic properties they can be easily tuned and once when you tune and use them they offer remarkable flexibility to the geometries around central metal atoms. And another advantage with phosphines is phosphorus 31P phosphorus is 100% abundant and has nuclear spin I equals half very easy to analyze and record spectra. With this let us continue to show about with this let us talk little bit more about phosphines. This is a simple phosphine it is very similar to ammonia we have and once when you start replacing this hydrogen atoms with alkyl groups aryl groups we will be having secondary phosphines and eventually tertiary phosphines this are all with carbon linkers you can see here one carbon is there are two carbons are there and even chiral is there as I mentioned it goes with our imagination we have several starting compounds are there at our disposal and to hook on these phosphorus mites. So this is an interesting chiral phosphorus lead called duphos and of course this is quite well known this called DPPF bisadiphenylphosphinoferosine and widely used in catalysis I have shown one palladium complex of this one and this is a stereogenic complex here we have binab and of course one can also have bulky groups on top position and also one can have cyclohexyl groups on phosphorus and also a bulky group here so that we can stabilize with low coordination number and these are some of the phosphines that we made in our group we have been working with phosphorus chemistry since 25 years we have been focused on making a variety of phosphines with an intention of using them in catalysis we can see we have made also octophosphine and also we have other donor atoms are they like triazole is there or you can have some other oxygen donors and also one can also make very bulky phosphines here they show interesting properties these are some of very interesting phosphines generated from this cyclo-diphosphazine you can see having a different structure some of them are macro cycles you can see we have as many as 8 phosphorus atoms are there this is ferrocene based one shows very interesting chemistry and this is the one I have shown here so this has something like this structure and using these phosphines we have been carrying out lot of catalytic reactions most of the catalytic reactions we perform are listed here you can go through it if you are interested in whenever you get time when we started again making phosphines we also looked into adding some of these functional groups with donor atoms as I mentioned earlier they have a very totally different and interesting chemistry and only this one was known having a phosphine on one of the triazole carbon but these two are not known so then when we started digging we understood the synthetic problems people came across for example the best way to put a phosphorus moiety on a carbon is by lithiation and then replacing that lithium with chlorophosphines you know for example when this bromodorivity was taken and treated with n-butyl lithium at minus 78 degree centigrade lithium goes here through halogen exchange and then at minus 78 degree centigrade maintain for couple of hours or even 8 hours and then add chlorodiphenylphosphine it gives this one as expected in contrast of lithiation if you warm the lithiated compound to room temperature and add chlorodiphenylphosphine it does not go to ortho position of phenyl ring instead it goes to triazole carbon that means when you warm it what happens lithium halogen exchange takes place okay this requires small energy for the cn rotation and it should come here it should interact and then lithium exchange takes place and as a result now when you add later chlorodiphenylphosphine we get phosphinated on triazole carbon okay so these things we came to know when one of my students was working on this system and eventually we investigated in detail using spectroscopic and means and other kinetics and we concluded that yes this is very temperature dependent reaction once we did this one and we generated a series of phosphines here and also we also immobilized on a heterogeneous surface such as graphene oxide so now it is very easy to perform catalysis here this system can be called as homogenized heterogeneous surface okay that means homogenized heterogeneous system so in this case what happened this portion okay of course graphene oxide is insoluble in any organic solvent but when you attach these things like here and we have put a metal and now this entire moiety is soluble in organic solvents that means if you just soak it in organic solvent what happens this will remain but on the other this goes into the solution if it goes into the solution you can carry out homogeneous catalysis and the interesting thing is once the product is formed if you just do filtration along with this heterogeneous surface it comes out so that means contamination of organic product with complex and a tedious job of its separation does not exist here that is the advantage so one can conveniently fix some of this organic soluble ligand systems especially this phosphine and then complexation you can do with whatever the metals of your choice and in a particular oxygen state and then one can perform homogeneous catalysis this is the advantage of homogenizing heterogeneous surface by phosphines or any other ligands for that matter so now with this one you can see the versatility of this kind of ligands this phosphines are there besides that we also have at least two nerds are not of that can coordinate to metals and these are also called hemilabial ligands because what happens either phosphorous and nerds can coordinate or with C and rotation both the peak can come on to the same side to form PP coordination you can see all these things are happening here and also in isobaration also happens in case of valve dirham and tungsten complexes you can see PN coordination is there whereas here PP coordination is there and in this one again P coordination is there and here PP coordination is there along with another phenanthonyligand PP coordination this is an interesting 16 electron species in palladium zero state this is a wonderful catalyst for lot of organic reactions so that means as I mentioned it goes with your imagination but you should know the basics and very nicely these factors like electronic and steric property should be imbibed into the design so that you can make desired phosphines and attached to right kind of transient metals to explore their catalytic activities and as I mentioned here you can see initially if you take this phosphine and treat with tungsten tetra carbonyl with two labile ligands such as papyridine they can be replaced at room temperature in dichloromethane to initially form a PN compound on standing this one in solution for 72 hours it undergoes isomerization to form PP compound whereas in case of malmdenum also same thing happens but this PN coordinated compound is relatively unstable compared to tungsten complex and in on keeping in solution of the completion of the reaction within two hours it isomerization from PN to PP compound whereas here it takes 72 hours so why that happens one can also do DFT calculations to understand the energy profile and to conclude that why malmdenum is much faster whereas in case of tungsten it takes little longer time. You can see here this conversion was monitored using phosphor cinema as I mentioned phosphor cinema comes very handy in characterizing the component also in understanding the reaction sequence for example you take here before the reaction started we have two distinct chemical shifts for two phosphorus atoms which are very different they are chemically and magnetically non-equivalent I shall tell you little bit more about NMR then you will understand these terms magnetically and chemically non-equivalent and all those things if you have already studied it is very easy so once you add a metal immediately what happens one of the phosphorus is coordinated that is shifted here other one is uncoordinated it does not change with very few PPM changes there that is expected and with time what happens this one would start diminishing here you can see this the chemical shift due to uncoordinated is diminishing because simultaneously formation of this that has started here at the end of two hours in case of malmdenum everything is converted this phosphine from PN coordination to PP coordination and same thing is also carried out same experiment was also carried out with Nungsten compound whereas here it takes 72 hours you can say after 72 hours we have these two these two corresponds to both coordinated one whereas here this corresponds to one coordinated that is shifted another one is not shifted it is still in the ligand free ligand region that is for this one so that means you can see now how important phosphorus NMR in diagnosing the reaction sequence in coordination chemistry and of course as I mentioned since we know the strategy of performing reactions we can conveniently carry out and make all kind of phosphines here and of course temperature is very critical you can see here at what temperature what is added and what you get at the end you go through this sequence of reactions to get to know about the synthetic strategies usually planned by people who design ligands and again when you perform this reaction you never know which product is formed but however when you just look into the 31 PNMR it can guide you yes that nature of product that is formed in a particular reaction even if all these three are formed in a reaction in various proportions again by looking into the intensity you should be able to tell the percentage of formation of these compounds I shall show you more interesting reactions that were monitored using phosphorus NMR when I go to the interpretive part after completing all aspects of coordination chemistry so you can see here this trisolic hydrogen is there that one is coupled with two phosphorus atoms as a result it can show triplet that can also be seen here and also once if it is replaced can and a metal comes here through CH activation disappearance of this hydrogen can also be seen in one HMR so that concludes that yes this hydrogen has been replaced and probably this ligand is acting as a tridentate where we have a carbon to metal covalent bond and when we have carbon to metal covalent bond the chemical shift of carbon in a in its 13 C NMR spectrum will also vary so that means NMR is an important tool in characterizing metal complexes or organometallic compounds we make so this is another interesting reaction I was just telling about phosphorus to carbon bond activation on a coordinated phosphine in my last lecture so this one we observed in our own reaction for example this is a very interesting ligand prepared by one of my students and when it was treated with palladium and platinum you can see what happens if you take this one and treat in prints of a base forms a compound like this pincer compound it is called because N H is there H is gone HCl is eliminated because we started with a palladium chloride having some labile ligand such as chord that is gone with base and whereas in this case even without base it forms a compound and then with base usually this HCl is eliminated and you can see this ligand acting as a tridentate ligand another interesting feature of this ligand system is this one you can see here in this one without base when you add palladium to palladium to complex to this one okay there is interesting a pc bond is broken here and pc bond is broken that phenyl fragment has abstracted H from N to come out as benzene and then that resulted in formation of a five-membered azafospholene ring and now phosphorus is still in trivalent this lone pair comes to palladium so now we have some sort of unsymmetrical phosphate very rarely seen probably this is the first example we have reported and then in this case what happened this phenyl group comes out it binds to the metal very interesting whether we can use this in in alkylation or a reaction yes there is an answer okay we are still our group is working on to see whether we can see a catalytic reaction emerging out of it one interesting thing is all compounds can be nicely crystallized and assess it by performing single crystal X-ray analysis most of the complexes we make we always try to crystallize and look into single crystal structure to understand the bonding features and how the reactions were carried out systematically is shown through this reaction sequence here of course I am not going to elaborate all those things when you get time just look into it and try to understand how these intermediates have been formed and what is the reason the another interesting thing is here you can see now platinum is just a 12 electron species with platinum is 0 it is a 12 electron species formed as a transient species and then this phosphonium salt what happens one of the phenyl group is now added oxidative to platinum to form this kind of compound here and then PTCL bond is established here so now it comes back from platinum 0 to platinum 2 some sort of oxidative addition of course I shall elaborate more about oxidative addition of the completion of this topic I am discussing at present once after making this one initially we did not had this kind of ligand we had NH was there and we have PPH2 but during this time azophosphoryl in ring formation took place whether we can get free ligand that is the next step of course one can do it but reading with bisadiphenyl phosphinobenzene what happens this has more affinity to palladium to chelate as a result this is chelated and this was freed from the metal this is some sort of electrophilic substitution you can see this ligand is freed so that means very interesting chemistry one can carry out with phosphine ligands and why we make as I mentioned we are using several catalytic reactions one such reaction I have shown here this is called N-alkylation of benzene alcohol N-alkylation of benzyl alcohol here these three compounds were used we formed this compound is much more superior in terms of its catalytic activity in forming both of these compounds and initially both the compounds are formed and then again this H can go as H2 and then that can also give this one that means we can control the formation of either this one or this one by changing the reaction conditions and this is a consolidation I have shown this is very interesting result one is breaking of PC bond and then formation of N this PN bond is formed in fact PN bond is much more reactive but however PC bond is less reactive and more stable but it is against that one so PC bond is broken and less stable PN bond is formed so always unusual and interesting chemistry emerges that you can see here that means R can be taken out and then whatever the R- comes out as carbon anion it binds to the metal migration takes place so very interesting result this was with this we shall move on to classification of ligands by donor atom center so now we shall move on to halogen based ligands so far we completed and this is the last ligand series the halogens group 16 elements so when we talk about group 16 elements usually they are denoted by term X in coordination chemistry and we know that halides are very good sigma donors and very good pi donors because they have low energy field sigma orbitals and low energy field pi orbitals and when they interact with metal especially when the metals are there in high valence state metals are electron deficient in that case what happens these ligands not only perform as sigma donors they can also perform as pi donors because pi orbitals on metals are empty and they can readily pass on electrons from halogens to metal orbitals so these ligands usually terminal but often they can act as bridging ligands when they act as bridging ligands they can bridge two metal centers they can bridge three metal centers interestingly they can also bridge four metal centers we have several examples in our own laboratory I shall show you later due to their pi basicity the halide ligands are weak field ligands of course when you look into spectrochemical series you know where these halides stand among rest of the ligands if you just look into spectrochemical series it can be broadly classified into again three categories in the beginning what we have is pure sigma donor and pi donor ligands and later we have only sigma donor ligands at the end where strong field ligands emerge there we have sigma donor and pi acceptor ligands and due to a smaller crystal field splitting energy I have shown clearly in a more diagram how the crystal field splitting energy decreases shrinks when we have halogens because of their donor properties and as a result what happens halide complexes are very labile in most of the reactions we use anhydrous halogen complexes for performing substitution reaction to generate other coordination compounds and also argumentary compounds and most of the halide complexes are high spin complexes and hexahalide that means homolyptic halides are also known with most of the metals and when you have six halogen atoms or six halides are there they adopt preferably octahedral geometry whereas four coordination they prefer tetrahedral geometries but in some cases especially with platinum metals they are still form squab and are complexes and due to the presence of field p pi orbitals due to the presence of field p pi orbitals halide ligands and trans metals are able to reinforce pi back bonding on to pi acid that means those metals which are oxophilic and oxohalic we call them especially early metals in their high valent state high oxo state they are electron deficient in that case what happens metals conveniently drift electrons from halogens of course if you take any halogen for example if I take Cl minus if I take we know that we have 8 electrons are there and out of 8 electrons this electrons may go for making metal to covalent bond still we will be left with strictly speaking still it can coordinate all known pairs but most common ones are something like this just I have taken chloride it can also be in general it can also be X so that any halide so this is the one now basically if this is covalent bond you should remember this is a coordinate bond this lone pair is coming if another is there this can also come like this always if it is a triply bridging one is covalent bond other two are coordinate bonds so let me stop at this and maybe continue discussing more interesting chemistry of halogens in my next lecture until then have an excellent time


New music segment and here for the very first time from Zeta Junior University, Pasimu Nyt and Skira, sukuna chils I'm trying to shine here all the way from Zeta Junior University, Pasimu Nyt and despite all that, he decided to also worship God and serve God through music, Zion very beautiful lady Karibu San, how are you? Thank you and I had to go to fishing variance. Did you want to do that? Audio Rail We need to catch up with Zion from Zeta University. What made you start singing? So you went to I.T. when they let you in, you know? Kujo papasya. Papasiya kwa? And how did you find out about your papasya? You know you have to discover yourself first. Papasiya kwa metenei kwa. So nika discover.  Ah, but yu aiku leta vita, kuvrutana, kidogo with your mum and dad Pakau pa tei degree. Where were you? Pakau pa tei degree? I listen to you so many times, but I like you when you talk. So are they supportive? I am a fan. I am a good fan of Zion. And what side? Hey, on the watch. On the watch. Kia na mum. Hey, they are watching you. Supportive, very supportive. So apart from you, Zion, do you have Magina Zahidi? Magina Zahidi Zion Jerry? Oh, so Zion is actually your name? It sounds like it's a stage name for a baby boy, Zion, and then he's going to teach me how to sing. Who's the engineer? The engineer. The mum is creative. Hi mum, hi mum. It's really creative.  You understand.   Yes, okay. What's your name again? Humbo. Humbo and humbo. So tell us more about this song. When did you begin singing? At four years. I came to Gubatini later in Sunday school. I went to Pombele in Naimba. I went to Naimba Church in Naimba. Later on I went to high school. I went to a drama. I went to music festivals. So you went to a drama? So you went to a drama festival? I went to a music festival. I went to a summer world time. I went to a music festivals. I went to a out going. I went to a out going. Out going. It's out going. No one has found this opportunity.   I've never felt I was in your shoes. I've never felt that way before. I've never felt that way before.  Thank God. You sing something in me that I did not see. And I didn't see it, I didn't know that Ill have no idea what he'd be saying So when did you begin singing professionally? Apart from me, I went to the drama festival Or the music festival Last year if you are going to take another step Let me use what God has given you So I would say We recorded the song then on the end of last year. It was in November and December. So, we recorded the song and November, we just started to talk. Then we made a video. If it was another song, did you destroy that song? So, we only made one song. So, you did the video actually. This month. This month?  We didn't want the people to believe in God and have faith. Like me, I did audio, in some videos the people in Chaitanya were reporting on me. I don't know if it's because they didn't want to, but I've heard that. Was it because I didn't have a chance to learn, I neverized it. Because I wrote a video for the few I know and it doesn't suit the language I was hearing. People were looking for it in a video and they already knew. So I told that person that we don't need to write a lot of it. tomatoes. Taking to the�� na багat ki ya she kakutik operators Kwa na slope? Raishi tu na terimu katum terimu? Achi raishi Aa ok, aiko wa raishi tawa Aiko wa raishi tawa Kwa na yaa uko anza ka bila ito Nili rako doktoba Muna sumbo na kwa ni peya udiya Ako ni peya udiya Nguwa jangoja Nguwa jya Nika nga jadi November eki What other challenges did you face? Kufu kuzo story manze No. 1 is me Mano kumbewa situinbe tu secular We don't have beautiful medicine in the music industry Kwa mi am not doing industry and doing ministry So am watching me if I am in ministry Baby sita, sita meki tumaka kwa niye minataka Lakin ni meza richum kwa moja moha wiki And maybe we say am going to come in suicide The moment cha ta kwa miske kuka ta kiwa Kunye ma jeu zi ma Mata fila kwa You've mentioned something really nice You're not doing industry, you're doing ministry Nasa hi kuna Kuna ele na itua exodas Kwa say wana hama gospel Wana indase kuna Should you expect that from you? No, kwa zangoja in the industry And what do you think? Why are people exodasing? Ula kua wabeta wak Ula kujua pa pasiake We also should not judge them Ula kuju kiansa kitu na faku Kujua pa pasiake koni gani What's my aim? Why am I doing this? Some of us we do because of fame We do because of fame We do because of fame We do because of fame We do because of fame We do because of fame So if it's your calling and you know who missteep kwa gospel, I trust you can I trust you can Nice of you ma jeu zi ma What inspired it? What made you sit down and write ma jeu zi ma? Okay ma jeu zi ma is a long story So I was like ma jeu nika nama mishtepe I was like because kwa kwa kwa na ni I think I can make it in life but upon I imagine we can't be like the same ya ni kwenye ni ya kwenye na unveil si kwenye ngo pei na unveil So I talked to a friend I kwa ma bia nina taga chua song but nika na idea but sijiwa na tani tani employer kwa na mbea tani saini I wrote the song and I recorded it Actually it's talking about me It's talking about you ma jeu zi ma it's about me my life ya ni like nuna fanyam seki tu na kata kukulipa ya ni naka despise na na tu like kwa we say kwa zia ke tu ima na ni ya brand influencing na social media na kutipia utu ma kwa life na kujawa na kwa encourage na kuna the same time na kujawa na unveil vishonia kwa na kumanya na kujawa kwa leta chimi nuna So when you focus on iso ma discouragement and my disappointments always you make it All you have to do is pray na kwa have strength kwa mbe tu munga kwa pay strength any thing you takam kwa pay tu mgo Did you get support from friends, classmates, college men support here Did they support your music journey I am friends and we have never met de kind of friends you keep ni upto na najifa na najika nziwa Nana jokal na nani wach Sharon Ah, ya me shouta di Nisha nisha wam gade Sharon Getich Nisha naji wakale Wakale Ya kusahibiananga witu kama hizu Uke mbe bestia kama uke mbe kevinski Uke mbe bestia kama wami o kama Amma DJ and DC wkw Oni the studio Strong bro, strong Ako na katawa na kutupi Naka mbe strong, goda ta kama Have faith Have faith Wajumia mbe ya mbe Uwia mbe ya wafu naka zidi kisha na Nani na ta mbe Inakun kareja actually Inajotu koo nyu ptushwaisu zengi Hihihihi Anyway Kamera 4 Shoutout wa sayo watia wama e kusapkot Navilya wa sayo aneza getu miuzikiya ko Na samea handle You have a YouTube channel right? Also mention your YouTube channel Your Facebook page and handle and everything else And also shoutout everyone One. Mi mwami ku support camera fo Killam to sisa. Letermu mwam en dad. Very important. You can get me on social media platform kama Zy umjeri. Zote Zy umjeri. Lakin instagram atu takeo na hasco zyon asco Unjeri. YouTube Zy Umjeri. So mi ma je wzaima many other coming still at disappointing. Nkwa ni lilze yos wali afiqiwa projects. Afá te ingo mo sabundi wia kwenza like ya-kwenza. Soch no stuntangao jya intervals We will be back to Kusinakani. I will see you there. I will speak with my big mum and dad, Rikisa whom I invited to my 13th visit to the children's home. This room was named after me. So, where's the home? Kasaran So they have a family day for the kids and they just enjoy the water to share the love The child come as a baby Na kila mtua nani watch nani support kila mtua nani penda masibdru naku penda automatikali Na shout out to my family my friends kila masibdru kila Steve Wise kila Grace Wambukenya I shout out to you we need another music kumenya mazo sana and everyone who is watching I'm thankful Anyway, thank you so much for coming It's on your project we will release this year with the launch Hapa When you were sharing this music it was I think one week to your birthday na wukasema pia nisongi na tokia ikiwa na birthday kwa i celebrate diana I was informed keki ndi watuku pata Uja leta keki Tina waga na rules ahapa Tina waga na rules kwa jesitako If it's your birthday una leta kek according to the number of years Ña celebrating the 20th birthday una leta 20 cakes Kwa api?  When you get your two in, you get confused nothing. Anyway, guys for the very first time on Jesus Sacco Show Magi, Ozima, by Zion Jerry the beautiful lady. Drop it, next! Tuk��yenda!


big news out of the Philadelphia Eagles camp. I believe he's currently a free agent, but Jason Kelsey has announced that he will be back. He says, I have put much thought into whether it makes sense to play another season. After talking it over with my wife and many other friends and family, I've decided to return for another year. Thank you to all my supporters and detractors for fueling me. I ain't done yet.  Let's go. Hey, all right, hey, all right. Jason Kelsey is back. I think he's a free agent now then. So let's assume that the Philadelphia Eagles will bring him back because we had Siriani on this particular program. And he said that however many kegs he needs to buy, whatever he needs to do to keep Jason Kelsey a Philadelphia Eagle, he will do that because Jason Kelsey personifies what a dog is. And Siriani said he only wants dogs as Philadelphia Eagles. So what will the Jason Kelsey courting process be? I'll tell you what, there's a team in the Midwest that potentially is about to trade their center and would love to have Jason Kelsey. I know there's teams all over the NFL that would love to have Jason Kelsey services. I'm happy he's back.


God is not a lottery, people of God. You will come here and you see, oh, that guy won the ticket today of healing. Whoa, congratulations. That guy won the ticket of deliverance. I want to receive my deliverance today. And they come and they're like, oh, God. And you hope and you think that it's by luck that you receive your deliverance. It's not. It's not by luck that you receive your deliverance. In fact, a better mindset to have rather than thinking that God is some kind of a lottery, is to think that that deliverance that you're looking for, the breakthrough or that salvation to the family member, it's actually the inheritance of the saints. It's not something you win by luck. It's something that is rightfully yours. You just need to claim it.


Whether you're dating someone with anxiety or you're anxious yourself, anxiety can feel like there's a third person stealthily crashing your date. When anxiety is involved, every interaction can feel blanketed by the fear of being rejected or misunderstood, but anxiety doesn't have to break your relationship or put a strain on it to the point where it's hard to enjoy. So here are 7 practical dating tips that you can rely on for assistance. Awareness. The more you know about anxiety, the better you can help your partner. Explains mental health author Arlan Kuncek. No one should ever have to be asked, why are you so anxious all the time? When you learn more about anxiety, it can make you kinder to both yourself and others. And if you're on a date with an anxious person, you can extend this understanding with a reassuring comment like, if you're feeling anxious, I want you to know it's completely okay. Patience. If a date asks you to chill out, it's crucial to understand that it's not as simple as flipping a switch. Explains Arlan Kuncek. Instead, it is something that can be supported through patience. Patience is not only attractive, but it can help regulate your crush's nervous system and make them feel safe with you. Like the poet Atticus says, watch carefully the magic that occurs when you give a person enough comfort to just be themselves. Reassurance. According to the Anxiety and Depression Association of America, when loving someone with anxiety, you may be tempted to criticize their thoughts or actions. But this isn't helpful and can actually worsen it. Instead, try reassuring them by saying, I understand that your fear may not seem rational to others, but I recognize that it's very real for you. Is there anything specific I can do to help you feel more comfortable or secure in the situation? Playfulness. There's a reason you can lose track of time when you're having fun. The same thing can be said when it comes to anxiety. Engaging in activities that both of you find fun and light-hearted can bring on those flirty giggles and lessen their worries. Check In. When dating someone struggling with anxiety, it can be helpful to check in with your partner and ask them what feels supportive and what doesn't. Says therapist Kate Rosenblatt. Sometimes it can feel impossible to know what you want in the intensity of a panic attack or at a particularly anxious time. This is why scheduling weekly or daily check-ins can be so helpful, especially if you both struggle with anxiety. Control. If you struggle with anxiety, your mind can overwhelm you with all the ways a date could go wrong. It's Highland Park therapy. In the world of dating and love, it can feel like you're losing all control. So one way to help ease your date's anxiety is to let them plan the date so they know what to expect. They can decide what kind of activities to schedule, which can help ease their worries. Says medical news today. Compliment. You aren't a burden and the right person won't make you feel like one. According to psychologist Mark Travers, it's essential to check in with yourself and make sure you're dating someone because you want to, not because you need their approval. And for those of you who are dating someone anxious, let them know how proud you are to be with them. You can even reassure them by saying something like, sharing your feelings with me is a sign of strength and I admire you for it. Your presence in my life brings me great joy and I'm grateful to have you. Will you be trying out these tips? Let us know below. And if you found this video helpful, let us know by giving it a like and subscribing for more if you haven't already. Until next time, thanks for being you.


I'm George Nahas, an interventional cardiologist. I have been practicing for over 20 years. I do cardiac care, I take care of people with vascular disease, and also take care of people with venous disease. Venous disease, as you may know by now, is very common. Patients with varicose veins or patients who have leg pain, ulcers in their legs, pigmentation, discoloration are often ignored in our medical society because we always worry about the arterial side of the circulation, the heart side, but people actually don't pay attention to the venous side that much. I've seen many patients with a lot of swelling in their legs, ulcers who were told to just wear compression stockings, use some antibiotic creams, and live with it. Fortunately, this strategy has changed in our medical community for the past 10 years. We have invented new ways to take care of varicose veins that are very simple, much simpler than what used to happen before with surgery when the veins used to be stripped and patients will be in the hospital for an extended period of time. They will have clots in their legs, they will need blood transfusion. Thank God for office-based procedures, now we can do everything in the office without even needing to go anywhere else. For example, if patients have varicose vein, we evaluate them, we give them stockings, if they don't respond to stockings after three months or so, then we do ultrasound on their legs. After that, we can plan series of minimally invasive procedures based on their anatomy and based on how extensive the disease is. Some patients may need one procedure, some may need more than one, it all depends on the case. So let me take you through a little journey about a patient who I'm going to do next. His name is John, I will not say his last name for confidential reasons. He is 62 years old, a retired policeman. He was referred to me by another cardiologist who asked me to take care of his legs. He has been having ulcers in both legs, he has been struggling to treat those or heal them. He has pigmentation, he has swelling, discomfort. When he stands, he has to sit down because of the achiness of his legs. So we did ultrasound on him, he has many veins that are leaking in his legs and let me just explain that one more time. The mechanism of varicose veins is really leakage in valves inside the veins and those are usually superficial veins and when the valve leaks the blood comes back down with gravity and the veins under high pressure start to balloon up, they start to leak blood and they stain the skin with brown color, the skin become inflamed, sometimes you see eczema, sometimes you see ulcers and they don't go away. We need to really be careful of telling patients to ignore them because 20% of those patients will have ulcers in their heels that will never heal without some invasive measures. So today we will treat his left leg, we will ablate the left great softness vein. This is a vein that is the longest vein on the body, starts at the foot and goes all the way to the groin. It's very commonly involved with this process. So we will do something called the radiofrequency ablation procedure. It's a catheter I will insert in his vein around the knee area with ultrasound guidance under local anesthesia and we are going to shut down that vein with radiofrequency energy. So we are in the procedure here with our patient. He is prepped in the office with the sterile techniques and basically we'll do this procedure under local anesthesia. He's fully awake and we didn't give him any sedation or any he doesn't have IV, he doesn't have to fast for this and we will do this with ultrasound guidance. As you can see this is the ultrasound probe. I have the monitor over there showing the vein. The black circle is actually the vein that we will enter under local anesthesia. So that's the softness vein. Now we're going to numb the skin.  Did you eat breakfast? I did not. Well you're going to have to go somewhere and eat after this huh? Drink a lot of fluids too. Okay if you feel any significant pain let me know. So now we're entering the vein with the ultrasound. You can see the vein is going to dip down like that and this is my needle coming in to bend it. You can see the blood coming back in the needle. We will put this wire. You don't feel any of this. Okay John okay and we will make a tiny, tiny, tiny nick. Take the needle out and then put the catheter in. So now we will insert the radio frequency catheter. So this is the catheter. It's very simple. This is the part that oblates the vein, this copper tip here. And the patient doesn't feel any of this when we insert in the catheter. Take this. So we'll push it until we see it on the monitor by the groin with ultrasound. And as you see this white line is the catheter and as you can tell from the procedure everything is done with ultrasound guidance. So we know exactly where everything is. We don't do it blindly. So we will position the tip of the catheter about three centimeter from the end of the vein where it comes to the deep vein which is seen on the bottom of the screen that white, black, you see the end there. That's the valve, point the valve Laura. So that's the valve that is broken that we talked about earlier. That's the main reason why people have varicose veins. That valve is broken, is not opening or closing. You can see it fixed in place and the blood leaks backward from the big deep vein, the big black circle to the superficial vein. And this is something called thymicent anesthesia. We inject it through a pump. It's basically saline with lidocaine and bicarbonate to take away the acidity of the lidocaine so it doesn't burn as much. And we'll start here by injecting the fluid around the vein. Pushing away the tissue to protect the tissue from the radiofrequency heat. You can see that black space forming around the white line.  So now we have a protective layer of fluid and lidocaine around this vein. So the tip of the needle is in the black space around the vein. So I inject and you can see how the fluid push away the muscle and the tissue and the skin away from this vein. The goal of this process is to shut down the leaky vein that is causing the high pressure down at the ankle and the ulcers and the swelling and the skin pigmentation. By shutting it down we're taking the pressure away from the skin, from the vein, from the tissue and then normal healing process starts after that and usually those ulcers heal within weeks and most of all, best of all is that they usually don't come back. Sometimes they do after many years we have to visit them again and see what else is leaking and treated because you know very good veins is a genetic disorder meaning the patients who have them are always going to be predisposed to having them and they come back sometimes and we have to deal with the new branches that come back. Now we're done with the numbing process which we call the mucent anesthesia and the final step is to ablate the vein to close it. So my assistant is going to push where the tip is push it down to achieve better contact with the vein. I'm going to push this spot on here and the machine behind me is delivering the energy. We do two ablation treatment for the first part of the vein and the machine behind me heats the vein to 120 degrees so each segment will get 120 degrees heating up to 20 seconds. It's timed by the manufacturer 20 seconds for each segment. This cut is very simple it has markers to mark how long the segment is so you don't miss any part of the vein and I'm going to pull the sheet back one time and we'll do a final segment. You can see when you see those markers this is a sign that this is the last segment that we can ablate before we go inside the sheet. This is the sheet, this is the catheter. Okay and we're done.  Those are pokes with a needle to deliver the the mesent anesthesia or the lidocaine and that's all what you see and we're going to clean his leg going to put the stockings and he's going to be going home. So now we are done with the procedure we will put the stocking on him while he's still laying down. It will be thigh high for two weeks he'll wear it day and night except to shower. First time you can shower John is two days from now. You can take a bath without wetting the stockings of the left leg. Okay after two weeks you can use stockings up to the knees not necessarily up to the thigh. I will ask him to us will use more than 400 milligram every eight hours to thin the blood to achieve some pain control which is very minimal and to decrease inflammation. John I'm going to ask you to walk a lot. When you're awake every hour or so walk for five ten minutes avoid long sitting laying down and especially today and tomorrow. All right so activity is very important avoid lifting that makes you grunt or hold your breath. If you see any bleeding outside the stocking call us right away. I have not had any patient bleed on me but there's always a first. You will see some spots on the stockings where we poked to give you the numbing that's normal you see some staining of blood-tinged fluid because we injected lidocaine under the skin it will start to ooze out slowly in the next few hours. Your thigh area will be numb for a few hours just like lidocaine does usually when you go to a dentist it goes away in a couple hours.


An E3, Equivariant Deep Learning Interatomic Potential, is introduced for accelerating molecular dynamics simulations. The method obtained state-of-the-art accuracy, can faithfully describe dynamics of complex systems with remarkable sample efficiency. This article was authored by Simon Batzner, Albert Musserlian, Lisin Sun, and others.


To such people I will reveal myself. Let them breathe easy when they hear of the good in me. Let them sigh when they hear of the bad. Then Lord, may you have mercy upon me, according to your great mercy, for your name's shake, and do not abandon what you have begun, but bring to its consummation all that in me is unfinished. Such marvelous humility, such confident faith, such a gracious invitation to all of us who are reading his words so many centuries later, to allow them to bear good fruit within us, not just of thanksgiving and prayer, but also of repentance and conversion of heart.


There are around two million boy and girl scouts in America, but only around five percent of them will go on to earn the rank of Eagle Scout. One scout in Pequod Lakes earned that recognition over the weekend despite facing one very tough obstacle, and Anthony Scott has more.  Always has a smile on his face. Everyone in Boy Scout Troop 102 knows Sam Clement from his infectious smile and can-do attitude. And thanks to that positivity, after 11 years, Sam earned the Eagle Scout rank. My whole life for Boy Scouts has just been an adventure.  Just, I mean, for my whole life, honestly, has just been a never-ending, adventurous story. Sam's story started before Boy Scouts when he was diagnosed with cerebral palsy, a disease that affects a person's muscles and can make some daily tasks very difficult. However, no disease could stop Sam from earning 36 of the required 21 merit badges to become an Eagle Scout. He's Superman, cerebral palsy. I mean, that's a debilitating disease, and he's overcome that, which is amazing. So, yeah, he's a true one-percenter. Sam thought he was going to fall short of becoming an Eagle Scout when he turned 18, which is the maximum age for a Boy Scout, but... We found a clause that said he could continue in Boy Scouts, and so we submitted the paperwork, and the Pine Tree District and the Central Minnesota Council authorized it, so he was encouraged, and he said, hey, I'm going to get this done. For his final Eagle Scout project, Sam created a unique picnic table for campers at Camp Confidence. I love to build things, and it's actually a convertible picnic table and bench, and so that way it's wheelchair accessible. It may have taken Sam a little extra time, but the determination was always there. Yeah, you never gave up. No, no, and yeah, it would have been easy many times. A lot of the requirements are pretty physical, which obviously was a struggle for Sam, but yeah, he pushed through them. Sam Clement may have earned his Eagle Scout status on Sunday, but he says his work with the Boy Scouts is just getting started.  And Sam definitely has the right personality for the adult leader position. Reporting from Pequot Lakes, Anthony Scott, Lakeland News. Of the 36 merit badges Sam earned, he said his favorite is his chest badge, which led to Sam starting his own chest club at Pequot Lakes High School. Wow, what a story. Way to go, Sam. Congratulations. Absolutely. If you enjoyed this segment of Lakeland News, please consider making a tax-deductible contribution to Lakeland PBS.


Rochester, I'm sure that golf ball sliced over here to the right. No, no, it's not here. Boys, why don't you give up? We've been looking for that ball all week. We'll find it. Don't be so impatient. Now, let's see. When I hit it, I know it went over here by these trees. Hey, Jack, Jack. Oh, hello, Mary. Hurry up. We've got to get to the studio. It's Sunday again. Oh, my goodness. How time does fly. Come on, Rochester. We better get going. Come on. J T L L O The Jell-O program brought to you by Jell-O and Jell-O Pudding starring Jack Benny with Mary Livingston, Phil Harris, Dennis Day, Rochester, and yours truly, Don Wilson. The orchestra opens the program with deep in the heart of Encino. Flavor, flavor, and still more flavor. That's what you get in Jell-O, ladies and gentlemen, thanks to Jell-O's marvelous new process that locks in its delightful goodness. The tang of Jell-O with swell intriguing taste are there for you to enjoy as never before. For today, Jell-O offers you a new high in flavor, a new peak in pleasure. You find that Jell-O is more than ever a glorious dessert, a grand treat that everybody loves. A clear, colorful mold of Jell-O, what an attractive side it is, and how it glistens with goodness. And never have you tasted anything better than the lively, refreshing flavor of Jell-O. Flavor that makes you think of the juicy, ripe fruit itself. Flavor that is locked in for your added enjoyment. Prove to yourself how much richer Jell-O's locked in flavor really is. Open a package of Jell-O, notice that there's no telltale aroma, no sign of escaping fragrance and flavor. Then dissolve the tiny Jell-O particles, and notice how Jell-O's captive goodness comes pouring out in a rush of richness. Get Jell-O tomorrow and thrill at the extra delight of Jell-O's locked in flavor. Sunset and Vine, played by the orchestra. Ladies and gentlemen, as we announced last week, we present our four-year entertainment, Doc Benny and his world-renowned minstrel show. That's right, so let's get going. Is everybody here? I think so. Say, Mary, where's Dennis? Dennis? I don't know. I haven't seen him. He must be around here someplace. That's you, ya dodo. Come here, Dennis, we've got a minstrel show to do. I see you've got burnt cork on your face. Where were ya? I was over in the corner practicing how to talk like Amos and Andy. Good. Good nothing. It comes out like Lumen Abner. Oh. Wonderful world. Never mind, you'll get rolling. Now, Mary, we have to do this right. So straighten things out and put the chairs in a semicircle. What's a semicircle? Look, put the chairs in a circle and then take half of them away. Now, Phil, we want some real old time minstrel music tonight. You know, a lot of loud, corny brass. Do you think your band can do it? Well, it ain't our style, but we can try. Oh, brother. Now, let's see, where's Virgil? We gotta have our props. Is the sound man here? No, I'm in a Turkish bath. Want me to steam some clams for ya? Now, Virgil. Virgil, you don't have to get cute about it. We're doing a minstrel show tonight, so pass out the tambourines. I passed them out already. You did? Yeah, and they're swell, nice and juicy. Those are tangerines. Now, Virgil, there's a whole pile of tambourines right there on your table. Now, pass them out. Okay, here they are. You don't have to throw them on the floor.  That's too bad about him. Well, I guess we're all set, so let's get started. Come on, Don, give us an introduction. Okay. The minstrel's including the incomparable Mary Sweetstuff Livingston. Mary. That sentimental gentleman from Georgia, Phil Honeyboy Harris. Take it easy, gals. I'll get to you. Also our own silver voice tenor, Dennis Sugarfoot Day. Very good, Dennis. And only Don Blubberlip Wilson. Yes, sir. The time was a bright summer afternoon many years ago. The place, Main Street of St. Joe, Missouri. They love me there. Take it away. Mrs. Farrell. Come here, Charles.  I see you've got some new traveling salesmen sitting on the porch of the mansion house. They ain't you. We just dusted them off. Every house counts to be old. Follow the parade, folks. The show starts. Candy popcorn and sandwiches. You can't enjoy these hams without a sandwich. Sandwiches, get your... Please, right this way. Here you are, sir. B2 on the aisle. There's someone sitting there. Oh, yes. I'm sorry, madam. You've got the wrong seat. I've got the right seat. Well, you've got it in the wrong place. Here. I got a ticket for him. Nothing else. The show hasn't started yet. Dub, dub, please. Ladies and gentlemen, your attention, please, for a few moments before the big show begins. Now, I have here a selection of the latest song hits of the day. Toons, they're all a whistlet. In the shade of the old apple tree. On a bicycle built for two. Only a bird in a gilded cage. Down by the old bill stream. And a zoop suit with a reed plate. I kill hay, while, sir. All the latest songs, folks. Take me out to the ballgame. Wait till the sun shines now, Ed. Hey, have you got that old sweet heart of mine? The song will flash change before the curtain goes up. Over! To Mississippi, on the Mississippi. Where the? To the Mississippi. Here, oh, Mississippi. That's where I- Hello, Mr. Harris. How are you feeling this evening? Mr. Interlocutor, I am in the mood to mango some merriment. Well, I must say, Mr. Harris, that you do look good. Well, boss, why shouldn't I look good? I just had myself a Kentucky breakfast. A Kentucky breakfast? What's that?  Well, what's the bulldog for? Somebody's got to eat that meat. Very good, very good. It didn't impress me. Now, now, Mr. Day, you mean to say you can do better than that? Ask me what the difference between a man with asthma, a farmer milking a cow, and an Eskimo fan dancer. Well, I don't know, Mr. Day. What is the difference between a man with asthma, a farmer milking a cow, and an Eskimo fan dancer? One is wheezing and one is squeezing. Well, what about the Eskimo fan dancer? She's freezing. Get her blanket. Excellent, Mr. Day. Excellent. I ain't convolved. Why, Ms. Livingston? Say, Mr. Interlocutor, do you mind if I ask you a riddle? No, no, Ms. Livingston, go right ahead. What's the difference between you and a jackass? I don't know. What is the difference?  Well, so do I wear a collar. Well, then I guess there ain't no difference. Mr. Interlocutor, when it gets to me, I wish you to convey that I'm mentally and physically fastidious. Well, Brother Wilson, what makes you so happy? I got a wife and a cigarette lighter and they both workin'. Very funny, Brother Wilson. Very funny. And now, ladies and gentlemen, our Silver Boy's tenor, Dennis Sugarfoot Day, will favor us with a song and dance. That ever-popular ballad, Can't You Hear Me, Colin Caroline, and dedicated to Mrs. George Primrose. Miss you in the morning when all papa and kisses call captain shadows fall. Rendered with feeling, sweetness, and tenderness. I didn't like it. Why, Mr. Harris, I noticed that you and Mr. Day have been quarreling quite a bit of late. What have you got against him? Nothing, that he's dishonest, disloyal, and hand-to-conscious. Oh, come now. Who cares?  Remember, boy, I recognized it. Mr. Harris, that's a bold allegation. I think you should apologize. I'll say he should. I can't believe that Mr. Day has been stealing your chicken. Not only that, boss, he stole my wife. I didn't steal that old thing. She jumped in the bag with the rest of the hen.  I'll bring them back. I'll bring them all back.   Don't worry me, nun.  Who is? Hi. How you going to get back? Gentlemen, gentlemen, please let this bickering cease. Gentlemen, yours truly, Doc Bendy, will render that renowned and melodious selection entitled, A Sleep in the Deep, assisted by the Alabama Four Music Professor. Cough, cough, cough. Loud, clink, clink, clink. Leigh the bell, clink, clink, clink. In the old towering, clink, clink, clink, clink. Big, clink, clink, clink. Ding a sling, clink, clink, clink. To the warning it brings, clink, clink, clink, clink, clink. Say, Lord, take care, take care. Oh, Jack, I'll be well. I'll be. I may be late, but I'll be in the deep. I'll be. I'll be. I'll be. Yes, Miss Livingston. I just thought of another riddle. Another one? Well, let's hear it. Why are the Japs nervous like a man on his way to the dentist to get a tooth pulled? I don't know, Miss Livingston. Why are the Japs nervous like a man on his way to the dentist to get a tooth pulled? Cause the Yanks are coming, yippee! Now, that was really brilliant, Miss Livingston.  I don't know, what is it? Berger, you stay out of this! We don't want any more riddles. I'm awful sorry to hit you, Miss Interlocutor, cause I got one that's not only entertaining but appetizing as well. All right, blubber lips, let's have it. When you go down to your neighborhood, Grosso, what is the very first thing that you ask for? Credit. Now, Mr. Harris, please. I don't know, Mr. Wilson. What is the very first thing you ask for at your neighborhood grocer? Jello, G-E-L-L-O. A blubber lips never went to school, folks. And now, ladies and gentlemen, as a special added attraction, Doc Benny offers for your enjoyment and amusement Benny offers for your enjoyment and amusement that well-known minstrel man, Rochester Van Jones. Yeah, Mr. Interlocutor! Mr. Van Jones will sing that ever popular song, a success made famous by the late Bert Williams entitled, Somebody Else, Not Me. At moments come to ever man some situation where he can obtain such fame, folks acclaim the very mention of his name. The circus played our town one day, three bingo tigers got away. The manager looked right at me, he said he, yes, opportunity. Somebody's got to catch them cats. Somebody's got to go.  Put on your hat and coat, he said.  It's a wonderful chance for somebody, somebody else, not me. Three bones with ebony dots off time's lead to cemetery lies.  I was the brothers from the door. All the others got out before somebody lay on the floor dead and through the trance somebody said. Somebody's got to stay behind. Somebody must remain and when the officers arrived explain how came he ain't alive. The man who stays and sees it through gains notoriety. It was a wonderful chance for somebody, somebody else, not me. Thank you, that was somebody else, not me, rendered by Rochester Van Jones. Oh, Rochester. Yes, Mr. Bennett, Mr. Interlocutor. I, uh... That mistake didn't either hurt or help the program, Rochester. I noticed that in looking over your expense account for your costume and so forth, you put down a dollar and a half for makeup. Is that correct? Yes, sir. Well, that seems a little unnecessary. Would you mind explaining what you spent that money for? Well, I heard you tell everybody to buy burnt cork for their faces. Uh-huh. And then as much as I didn't need it, I bought a cork with a bottle of gin around it. Oh, I see. Well, I, uh... I have news for you, Rochester. You may collect that dollar and a half, but it'll be from somebody else, not me. And now, ladies and gentlemen, as you all know, every minstrel show has an after-piece, and ours will be no exception. So tonight, we are going to offer Doc Benny's version of the greatest love story of all time, Romeo and Juliet. The scene is the balcony of the home of Miss Juliet Johnson on Beale Street in Memphis, Tennessee. Curtain. Music. Uh-huh. Romeo and Juliet were sweet hugs. And oh, how that Romeo could love. That's me, folks. Yeah-de-de-de. Oh, Julie. Julie, climb down this ladder. You know, we're going to rope tonight. I can't see you down there. Romeo, Romeo. Where for is you, Romeo? Here I is, gal. Right below Yarden balcony. Well, get thee on that ladder, son. Forsooth, honey. I'll be there forsooth. Yuck! I'll be right up, sugar. Just a minute, Rummy. Get thee down from that ladder. Hush up, son. I'm ascending to my lady friend, Juliet. I'll then move over because I am the local, and this is the express coming through. I don't know what you did with that gag. Those, you can be the local, and the express. I must be the local. Now, wait a minute.  Now, wait a minute. Who, uh, who is you, anyway? Here's my card. Hmm. Julius, Mushmile Caesar, and his orchestra, appearing nightly at ye Biltmore Arena. That's me. Now, listen here, Mushmile.   Don't mess around with me, Romeo. Remember, flowers don't care who they lays on. I understand. A pass, friend. Guzzoox. Mm. Who had a Romeo? Somebody else, not me. Now listen, Romeo, you're coming up here, or is you ain't? Be patient, woman. Keep thy cloak on. Yuck! Oh, but sure, that's me. Hey, you, get off that ladder. What? You hear me? Juliet is my gal. Oh, no, she ain't, son. She's my gal. So you better hide the away-knee. Well, I'm going to take my razor, and you're going to be grinning from ear to ear. Understand? You make one pass at me, and you're going to be playing love and bloom on a harp. Well, in that case... pass, friend. He gasped. Hey, Romeo, Romeo, what is this pain and vile? I'm caught in traffic, honey. Well, here I come, Julie. Here I come. I'll be right with you, Julie. Oh, pardon me, brother, but you'll stand it directly in my path. Now, who that? Who that? Who is you? Othello. Othello who? Othello Jello. Oh, then you is the merchant of Venice. Pass, friend, unhindered. Look at that latter bend. Hey, Julie, can it be that you is unfaithful? I ain't unfaithful, honey. I'm going to look tonight. With me or not with me? That am the question. All these men climbing that ladder. I's regusted.  I'm just raffling off a Plymouth up here. A Plymouth? Oh, that's right. Where did I put my ticket? Oh, here it is. Here it is. The lucky number am 987X42. That's me. That's my number. I've got it. Here I come. Here's the dessert, friends, that will make a big hit with everyone because it's so good-lucking and so downright delicious. It's jellied plums, a swell attractive treat that combines luscious plums and rich emerald lime jello. Yes, here's a dessert that is really a masterpiece.  Jellied plums is truly a treat of treats and easy to make. Simply dissolve one package of lime jello in a pint of hot water and chill until slightly thickened. Next, fold in one cup of canned plums. Then mold and serve plain or with whipped cream. And you'll say you've never tasted anything that was more delightful. Never laid eyes on a dessert that looked more enticing. Make up this grand treat. Tomorrow, get a package of lime jello. But be sure it's genuine jello because jello's new locked-in flavor is extra rich. This is the last number of the 26th program in the current jello series, and we'll be with you again next Sunday night at the same time. Jack had a runaway and do a show for the Motion Picture Relief Fund. Good night, folks. J-E-L-L-4. The jello program is written by Bill Miro and Ed Beloin and is broadcasted each week by Shortway to our armed forces throughout the world.


Amanda check out this overheard post it got over 500 likes Wow, Jerry. That's more likes than I've ever gotten combined. I have an idea Let's become overheard stars like Bosch Feinstein His post get over a thousand likes damn. That's a lot. My profile picture only has two likes one from my mom and some guy in Egypt I'm so stressed out when I get stressed out. I just study Worrying I like the conversations that sprawl better. I know what we can do When I get horny, I just study But that's not even what she said look I just posted it. It's getting so many likes. Oh my god Bosch Feinstein Just like that. That's how you know it's going to be a hit. We need more Wow, we got over 10,000 likes in one day, we're gonna be campus Oh, it's fine, I know We need to fix that let's post more Come on What you get for number 26? I got cosine of X Frappro with ADG at cafe strata if a girl's last name is ho.  You're literally lying That's not okay. Um, you didn't seem to have a problem with lying this whole week loser. Anyways You know what Jerry? You're fraud.    Nah, bro, you're gooping the house.   I'd say I think what I do. Dude, you're just jealous that we're top house Whoa, I'll show you goop What have we done? Is that Bosch Feinstein? No He's the biggest part of them all. I transferred to UC Merced


Hey, this is Brett with Summit Automotive in Fond du Lac, Wisconsin today. We're checking out this Super clean trade. This is a fresh trade just taken in over the weekend. This is a 2015 Dodge Challenger Hellcat yes, it has the 6.2 liter supercharged V8 Hemi motor with 707 horsepower billet silvers the color we just took this in trade Doing a first quick walk around on it. This car is super clean locally owned and operated clean title history no accidents Nothing like that and just in really nice condition, of course the Brembo brakes the 20-inch rims the tires have decent tread on them I always want to do these videos just to kind of show you what's coming You got heated seats and this car only has 11,272 miles heated steering wheel. This is a six-speed manual dual-climate control 8.4 with the factory Navigation auto headlamps power windows power locks. It has the Harman Kardon sound system And this is exactly how this thing was traded in very clean. No rips. It's a non-smoker the headliners clean has home link and just wanted to do a quick walk around for you and thanks for checking out and As always remember to like subscribe and share on this video and all the videos on our YouTube channel and Call for more information on this super clean 2015 Dodge Challenger Hellcat. Thanks for checking out the video


Hello, this is a Jesse from Douglas, here you have a kit for $55 Yes, this is our DVR kit with 700 TV lines And this is it? 700 TV lines? Is that good or not? 700 TV lines? Of course, this is a demo for the 700 TV lines So it's right here? Yes Is this one? 700? 700 TV lines Alright, seven Yes, and there are DVR and 4 cameras and all the accessories with one kit And this is a kit box A kit box right here? Yes, I show you right now And people can buy one sample for how much? Around 60 And for $55 is 300 pieces, right? Yes, of course But to be said by your content, maybe we can give you better price for your more content So here you have four different ones, right? What is the other one? Let me introduce this one This one is our AHD DVR kit And with this high resolution, one megapixel, 720p 720p, is it connected now? Yes, connected So it's on this one there? Yes Very high quality Yes And this is how it looks? Yes It's good quality? Yes 720p So you can see in detail if somebody steals something from you? Yes, and all of them can connect to the internet And also very easy to view by your mobile phone And this is our new Wi-Fi DVR kit Wi-Fi what? NVR kit What does that mean? There is one NVR with Wi-Fi and four cameras also with Wi-Fi It's very connected with Wi-Fi and it needs around 100 meters 100 mps? 100 meters Yes, from DVR and IP cameras So no need to connect the cable all the way? Yes, no need Just wireless? Yes Very easy to install And if you see the local image, no need to connect the internet Maybe some IP cameras must connect the internet This one cannot, no need Cool, and so is one of these the sample here? Which one is that one? There's another one you have? Same this one Same as there? Yes And there's the last one here? And this one is our 1.3 HD cameras Alright, and what is all this that you have here? This is our P2P IP new cameras IP new? Yes P2P, yes, with Wi-Fi So what is that one? Yes, this is portable ones and this is indoor ones This is indoor and this is indoor ones It can rotate it, a new shell Which one is going to be the best seller? Best seller? Decided what you mean? What's the most interesting? Yes, and this one later last time I introduced is very hostile Right now this kind is also hostile too You have good price? Yes, this one with wire press, maybe $16 $16? Yes And for $100, the price goes better and better, right? Of course, and this one maybe around $20 $20? Yes And what is that stuff here? This is our Wi-Fi mode for this can, just to show you And I want to introduce this one This is the camera too? Yes, it's just like a bomb, right? But it's a camera And with the remote control? Yes, there is a remote control and you can turn off the light Yes, turn it off And there is LEDs and for the net reading Right And this one also with Wi-Fi This can connect to Wi-Fi, you can view it from above And this is for the new shell and new models, pendant models for us Cool, so everybody needs security, right? Yes, of course Everywhere in the world, everybody needs to monitor what's going on Make sure that these guys don't come in And if they come in, you can see how they look like Yes Alright Okay


Inflammable. In ancient times, meteors were supposed to be generated in the air by inflammable gases.


The past 25 years haven't actually been a walk in the park for democracy but idea has done a lot to promote the quality of democratic processes. These days we see the fragility of democracy on full display in the United States but right there you see what matters counting, tabulation, the quality professionalism, independence and integrity of election officials. Those are the things where idea has contributed so much and where there is so much more to do. So happy birthday and all the best for the important fight for democracy going forward.


The challenge of the Yukon King the swiftest and strongest of Eskimo lead dogs Blazes the trail through storm and snow for Sergeant Preston as he meets the challenge of the Yukon Sergeant Preston was typical of the small band of Northwest mounted police Who preserved law and order in the Yukon during the gold rush of 98? That was the year that brought over 50,000 men swarming into the Klondike region and the greed for gold led to frequent violence and bloodshed But in spite of the odds against them the force preserved a splendid record in maintaining the right the challenge of the north was answered and justice rule triumphant Dan McGregor's cabin was in one of the most isolated stretches of the Yukon wilderness Far off the trail. It was a long tedious journey to civilization even in good weather in the blast of the terrible winter It was almost impossible to travel Inside the cabin was warm and cozy Dan's young wife Mary busied herself putting dishes away While Dan and an old sourdough Clancy O'Connell sat talking before the heartening blaze of a good fire Dan held a young baby on his knee Clancy broke the friendly silence that had fallen on the happy group Yes, sir, I got it that young inshore is growing. Just look at how he's watching you Dan Rise of button aren't you son?  You're right there, Mary I declare I ain't ever seen a smarter-looking tyke. He'll be a rich man someday Bet your life you'll be Say Danny. Yeah last time you was to town. Do you see anything in the plane? Mm-hmm. Did he have anything to say about the mine? Just ask me how I was coming You gave him all the details I reckon for sure it hadn't been for him We wouldn't be so well off this winter. I don't mind telling you I was ready to give up when he staked me.   Yeah. Yeah, I Guess you're pretty well fixed for supply now. We took care of that a long time ago We've got enough caribou meat to see us through the winter. That's good. I'm glad to hear it You're better fixed than anyone this out of millville. How's that the supply boats ain't come through yet. Oh, yeah Then that ain't half of it. We have plenty here a few men need food We'll be glad to share some of our supplies with you sure that ain't exactly what I had in mind Miss McGregor, but isn't food you want? Oh, it's food. We want all right But we don't aim to take no share of what you got here. Welcome to it. We're taking all of it Dan You're what?  He always knew he wanted to get to that gun gram You just do what I say You're holding the gun Mac go ahead What's on your mind?  He calls it yet started out with all the supplies We could get our hands on buying supplies of course. Come on McLean get to the point Yeah, boss cut out the gap and give it to him.  I'm running this outfit Now that we're here We're willing to let you and mr. McGregor have a day supplies for you and the dog. I'll wait a minute We're not leaving this car. You're leaving Right now the baby that's your concern not mine, but it's murder You know, we can't reach the trading post why to take us three days My my my my now ain't that too bad I'm sorry Dan.  We'll stay here if I have to take a thing about you go on Oh, you're staying here. I figure we need a hand to take care of washing dishes and the like what you better start getting your Dogs ready McGregor. You got a long trip ahead of you A Sharp wind whipped sergeant Preston mercilessly as he urged his team over the trail Head of the pack ran the great dog King alert and watchful Watching him the Mountie smile for a new the wilderness held no terror for King He's glad to have a job to do Seems to enjoy running against the wind I'm king We've got a job to do this time. All right, they'll feel doesn't soon get some surprise What is it? What is it? What's wrong King?  Oh Look, we don't want to waste any time boy this trail is Very well King you win which way? Don't pull me I'm coming Can't see a thing this wind is Over the crest of that hill a fella Well, we'll have a look Man and woman Who in the world would be on the trail and whether like this?  Yeah, that's right boy. I'm going down there Sickly looking fire like that. They need help Hello there wait Stan McGregor it and Mary and she's holding their young baby Mary and Dan what? Last time I saw Dan in town. He told me you're all set to hold in for the winter What happened? We're all set, but Mac McClain came up to the cabin yesterday and drove us out I have some supplies on the sled We'll add more wood to the fire and have some ready for you in a few minutes Meanwhile, I want you to tell me about McClain. It was shortly after dark in Dan McGregor's cabin the fire burned brightly Mac McClain faced the floor restlessly with his hands in his pockets Outlining a recently hatched scheme to his men Clancy the rugged old prospector washed at the dishes sullenly his sharp ears taking in every word of the conversation Yeah, it was a lucky break for us when you spotted the morning start on the river Pete We take over the supply.  He's stuck solid. Yeah Stuck solid. What could be better?  All right, won't take us more than 15 minutes Make sure it don't we can't afford to waste much time Hey, where you going grandpa just going out for a breath of fresh air what I don't get in here Oh, no, you ain't you weren't so busy planning how to keep food from starving miles. You don't notice the fires burn alone We need wood you're going to get it or do I? Well, all right swore. I saw someone moving over in that timber But I don't see him now Rotten bombings, and when you hope Dan and Mary Hey, what in the like a dog coming from the trees Well, I'll be a friendly one ain't your boy Good-looking husky. Yeah, what's this? Looks like a notice something in this collar See but yeah, it's a pencil Have to go over here gotta keep down Like from the window ought to be enough to eat by Dottie, it's from sergeant Preston Right there boy. I'll send this back with you hurry back here for the get suspicious I Back in the cabin a half hour later Clancy puffed silently on his pipe while Mac McClain peered anxiously out of the window seems like they ought to be back by now Mac What's keeping up? Blasted wolves get on my nerves sounds like a whole pack. Yeah, you're dead. That's nothing beaten left. He'd be back here by now I'll lay your tender one. They ran into trouble a pack of it Come on.  I'll ask you for it Get your gun red you two slam. I don't like this. I ain't asking if you do or not I'm bored in the morning star. See you the day after tomorrow We'll start from Melville with enough supplies to sell to set us up for life As the three men left the cabin sharply silhouetted against the snow. They were watched by Sergeant Preston King stood at his master's side every muscle tense his keen eyes following the progress of McClain and his men You're right sergeant. There they go. They're free of them out to look for our friends here It's a good job of gagging in them then I'd like to rainbow them.  This ain't the best look they were strong quick We have no time to lose Clancy.  How'd you oh? Don't worry now sergeant. I'll take good care of them both come with me Dan ready King Thanks, we'll need it. They are a sergeant. Yes. I see them Making slow progress All right, King Start hauling like a wolf. Come on Dan. Let's see how good our imitations are down King Doc Dan That was close like the real thing only one man fired Dan. I'm sure it wasn't McClain Now see he's turning on those two like a savage morning star must be just around that bend your plan works Got to work. Come on Dan. I'm the protection of these rocks King.   Look again McClain. It's no wolf Hey, what's wrong with you bud? I mean hurt the shot captain oaks. That's right Sergeant Preston of the modern police these men were planning to force their way on board your boat to steal the supplies We thought when we heard the gunfire you come to investigate trapping them between two fires It seems like you had the situation pretty well under control before we even got here sergeant Somebody good thing is stopping we've been stuck us along with a probably welcomed them as a committee for never under arrest McClain You and your men There's nothing short of an attempted murder when you turn the McGregor's out to freeze on the trail She is a cablin this wild-looking country within walking distance captain We'll carry some of your supplies to Melville on sleds. They're badly needed. I know they are We've been helpless here got stuck in the sandbar on the river by the time we got loose rat the free-set in This your aid run the corner schedule history on your feet McClain You're heading back to town that dog and I thought it was a wolf. Are your friends thought the same thing But we managed to capture them without any gunplay Yes, King. You've done a good job We've done all we set out to do And more With your help the case is closed Challenge of the Yukon a copyrighted feature of the challenge of the Yukon incorporated brought you each week at this same time Originated in the studios of WXYZ Detroit the characters and events in tonight's drama were fictitious Bob height speaking


As you guys know from Kickin' There Bass TV, today I'm going to be talking about the tournament that's upcoming Saturday, October 18th, it's the East Hall Tournament, it's a high school tournament on Lanier, and if you guys are looking to fish a tournament and drink in high school, I'm definitely recommend it. I fished it last year, it was a great tournament, there was around 50 boats, so a big show up. We actually ended up winning and it was a really fun tournament and I can't wait to lose Saturday. So I'm pretty much going to go over the details, what times of registration, the prizes, big fish, first place, the waivers, the weigh-in time, everything like that. I want to go over all the details. So starting off the registration is from 5.30 to 6.30 am in the morning before the tournament, so that's when the registration starts, the Saturday of the tournament which is the 18th. It's $80 per boat which is $40 per person. The weigh-in is at 2 o'clock, so they're trying to get you off the water a little bit early, especially on New York's all the boat traffic and everything. And for the waivers, you need a waiver per person. Both the fishing partners and the boat captain. Not just one waiver for all three people, you need a waiver for each person. So the boat captain and both the fishing partners. Also the prizes, first place, $500 gift card to Bass Pro Shops, it doesn't matter how many boats, they're going to be 200 boats, they're going to be five boats. Either way you're going to get $500 for first place. Big fish is $250 from Oakwood and Farley Bates. It's pretty much like a little bait price pack for big fish. The first 20 boats of the tournament actually get goody bags. It's going to have some swarm hornet looters, it's going to have some zoom baits, whacking baits, all the sort of baits in the bag, so the first 20 boats get a goody bag. There's also a side raffle going on. It's $5 per ticket, a Yeti Cooler raffle, so that's just a side raffle. There's going to be tons of prizes, giveaways, goody bags, everything, me, Noah, from Kickin' the Bass TV. I'm going to be giving some hats, t-shirts, some of my cards, some stuff out, some goody bags for the top, I would say five to ten places for the tournament. So I'll definitely check it out, it's October 18th, this upcoming Saturday, and if you guys go, definitely say hi to me, I'd love to meet some of you guys, and comment below if you're going, if you have any questions, also you can email Kevin Merck, I'll pop his email right here, and also I'll have it down in the description. So if you have any further questions, definitely email him, he'll answer all your questions. So thank you guys for watching, hope you guys come to the tournament, see you guys next time.


Here are eight tips for using subject-specific vocabulary in your classroom. Number one, obvious display words COVID and now at the moment it's going to make it a challenge, but do you have a live display board? Are students also part of it? Do you have a list where you can develop subject-specific vocabulary? Do you develop a bank? Does it involve overtime? Can students also contribute to it? And it's really important when we think out a language to define and contextualize key words and I would also advocate use the listen, say it back to me method. It really helps students practice key words and develops their long-term retention. Always overuse new words, keep repeating it until it's a mantra. Kids say it back, helps develop their schema. Start the next lesson, we know all about retrieval practice. Start each lesson with a recap and number seven, use as many different synonyms as possible to help develop this schema. And then my favorite one is to develop etymology, I forgot for a second, develop the etymology of keywords. Nothing better than exploring root meanings to elicit new thinking. Did I tell you I have a new book coming out, Mark Plantish 2.0? Thanks for watching, I hope you're well. I hope these little tips make a difference. You can download this on the site and all the slides, use it as a training resource, develop it yourself, adapt it into a different teacher training resource. It comes from 60 Second CPD. Thanks for watching.


All right guys, I'm recording this real quick before work, just to kind of explain where things are at, and also why not a whole lot has been done recently. It's a temporary thing. I've got a lot going on, but they're good things. We'll get the camera switched over and explain a bit of what it is. After eight years of my old car being on the road, I got a new one, and she's a beaut. But you'll notice that's manual. I've driven manual before, but only little bits on friends' vehicles. So it's been a bit of a learning experience, and I've been spending some of my free time getting the gear transitions right, and especially starting off, because that's a little easier, that's what it clutches most. Sensitive, that's when you stall the most, so yeah, I've been getting a lot of practice in that with that in my free time. That's obviously more important. Being able to drive well is important. So I also got this, and what the hell was this? The Cubiboard A20. I might have turned it off. Oh no, there we go. I don't want to shut you down, though. Oops. Well, anyways, this comes with the all-winner A20 chip, which for those of you who know your processor stuff, that's one of the ARM processors. So I intend to use this as a test bed for the ARM, just because testing on real hardware is definitely preferable to testing on an emulator. Emulators have their uses, of course, especially when it comes to debugging. They're a lot easier to debug on. But I still want to test it on a real device, and so this is, I mean, essentially a tablet just with the actual ports that you would expect out of a computer. I got to get this set up. Unfortunately, there was a little bit of a misunderstanding when I bought it. I thought it had an M.2 port, and it actually has an M-SATA port, but I have an M-SATA drive coming that should be here pretty early into next week. And I'll get this booting Linux of some variety, probably Arch, but yeah, it'll be running Linux of some variety. And that means Liban, I'll be able to validate that it at least works on the ARM V8. The AARCH64 stuff is going to be, I'll need to get another device for that, but you know, I want to make sure it works on a broad variety of platforms. I'm editing this video, and it looks like I forgot to add some kind of important information. One of the other things that's been going on is things with a girl have been getting rather spicy, and obviously that's kind of a distracting thing. My mind has been elsewhere and not on code.  I'll do what I can. I am supposed to be getting a storage device I need for that QB board. At some point today, I'll get that switched over and assuming I can figure it out, boot process on the ARM is not like the boot process on the x86, but I will try to get that set up and start getting everything tested and verify that it works on ARM today. I just, not really in the headspace for development all that much, but that kind of thing should wean me back into it.