Welcome you all to MSP lecture series on advanced transformative chemistry. This is the 10th lecture in the series. In my previous lecture I was discussing about the coordination concept brought out by very systematic and meticulous experiments with critical and analytical evaluation of his own work Alfred Werner and how nicely he postulated coordination theory. When a time there was no methodology or any instrumental facilities or any spectroscopic means that was available for him to convincingly understand the futures of coordination compounds nevertheless whatever the postulations he made by emphasizing for quantitative understanding was proved to be precisely correct later with experimental and spectroscopic evidences. Once coordination chemistry started evolving people started looking into various bonding concepts to explain how to characterize compounds and how to explain the bonding that happens between metal ions or metal atoms and ligands. In that context let us look into early bonding concepts. Before that let us look into few points about what are the factors that affect coordination number. The size of the central atom or ion has an influence on coordination number because if the size is larger it can accommodate more ligands surrounding it as a result coordination number can be more. Steric interactions between bulky ligands is also quite important. Despite the size of the metal is appropriate to have 4 or 6 ligands if the ligand size is much bigger like triphenyl phosphine it is very difficult to accommodate 4 ligands. In that context steric interactions are very very important and steric bulk of the ligands plays a major role in deciding the coordination number of a metal ion. The electronic structure of the metal atom or ion is also equally important. If the oxidation number is high the metal can accept more electrons from the ligands that is Lewis base because it has more empty orbitals metals with many D electrons will have lower coordination number. That is the reason when we go for to later transfer metals after D6 electronic configuration the coordination number the tendency to have less coordination number will be more pronounced compared to early metals which have a tendency to have a larger number of ligands surrounding it. So now let us look into some methodologies developed to explain bonding. By the time coordination chemistry was evolving after systematic understanding from Werner's coordination theory people began looking into bonding concepts. As I said by the time main group chemistry had very interesting concepts such as VSEPR theory wellness bond theory to explain the structure and bonding among main group elements and same strategy was attempted to expand or extend to coordination compounds. In that context electroneutrality principle developed by Pauling is very very important. Pauling's electroneutrality principle is an approximate method of estimating the charge distribution in molecules and complex ions. What it states is the distribution of charge in a molecule or ion is such that the charge on any single atom is within the range of plus 1 to minus 1 ideally close to 0. So that means in a metal complex all species involved should have a charge between plus 1 and minus 1 ideally close to 0. This is what the definition of electroneutrality principle. To test this principle let us consider one well known example hexamine cobalt 3 plus ion. So I am considering hexamine cobalt 3 plus ion. Let us look into first covalent method. If you consider covalent method we have 9 electrons in the well and shell that is 3D7 4S2 and assume that 6 electrons are used for covalent bonding leaving 3 charge on cobalt. That means out of 9 electrons from the valence orbital of cobalt utilize 6 for making covalent bond with amine or ammonia ligands. So that 3 electrons will be left and that should be considered as 3 minus charge on cobalt. This is the first assumption using covalent model. So this is simply unrealistic as cobalt cannot be negatively charged going to its positive, electro positive nature. We all know that in this one since it is positively charged it is not very appropriate to assume as negatively charged. So moving to this okay this covalent model was ruled out. So this is how the covalent model was depicted. Out of 9 electrons 6 are utilized for making the bond with ammonia and leaving 3 as excess considered as negative charges so that now we have a charge distribution like this. This is simply unrealistic. So let us look into ionic model. So plus 3 charge remains localized. We have 3 plus charge so cobalt is in plus 3 charge. So ionic model assumes that plus 3 charge remains localized on cobalt and 6 ammonia ligands remain neutral. Again this is flawed because the experimental evidence shows that the complex ion remains intact in solution or retains its identity in solution. That means a complex ion is not a double salt. That fact we know because here primary valence is, secondary valence everything is clearly spelled out and the electrostatic interactions implied by the ionic model are unlikely to be enough to all these things to happen. So that means if you just consider that cobalt 3 plus remains as an entity in that case what happens if you put into solution that disintegrate. So that is not going to happen as a result ionic model was also overruled. So this is how the ionic model was assumed. It appears like a double salt and in solution it will disintegrate. Since that is not the case this is also overruled. Then came electro neutrality model. What it says is we know the net charge on the metal center should be 0 or between plus 1 minus 1 close to 0. So that is cobalt 3 plus ion may accept a total of only 3 electrons from 6 ligands giving the charge distribution shown here. I am going to show you the electro neutrality principle results in a bonding description for the complex having 50% ionic character and 50% covalent character. So this is what the electro neutrality principle means. That means if you see the charge distribution all on all entities is well within plus 1 to minus 1 and cobalt being 0 here. Using this method let us try to understand one more problem. So let us consider hexa-sinoferrate a realistic charge distribution results in each ligand carrying a charge of minus 2 by 3. In this model what charge does the FE center carry and why is this charge consistent with the electro neutrality principle. That means whatever the example we saw from Hexamine cobalt 3 plus let us try to extend same analogy to this one okay in which ligands carrying a charge of minus 2 by 3. So that means here each cyanide is carrying a charge of minus 2 by 3 and that means we have now 6 cyanide ligands are there. So this will be minus 4 okay if it is minus 4. Now if you consider FE 3 plus we have 5 electrons 5 minus 4 equals plus 1. So in this one FE carries plus 1 charge. So according to electron neutrality principle the charge carried by iron center is plus 1. Let us look into another problem here. If the bonding in CrO4 2 minus were described in terms of a 100% ionic model what would be the charge carried by the chromium center and explain how this charge distribution can be modified by the introduction of covalent character into the bonds. That means we have to examine this example chromate 2 minus using both 100% ionic model and also a covalent model. If you just look into 100% ionic model the CrO4 2 minus here charge will be minus 2 okay in this case the charge will be minus 2 here. But if you consider covalent model so 6 electrons are there and these 6 electrons are utilized in making 6 metal to ligand bonds according to electron neutrality principle. In that case what happens number of electrons left on chromium will be 0 so that here the charge on chromium will be 0. Next after successfully applying VACPR theory to explain bonding among main group compounds okay attempts were made by Keppert to utilize VACPR theory to explain bonding in trans metal complexes. So for this one following examples were considered and here like all 6 coordinated compounds but having different valential electronic configuration were considered for example vanadium 3 plus has 2 D electrons and manganese 3 plus has 4 electrons and then cobalt 3 plus has 6 electrons and then hexa aqua nickel 2 plus has D8 8 electrons and zinc hexa aqua zinc okay here we have 3D 10 4 S2 so 10 electrons are there that means we are considering examples of vanadium manganese cobalt nickel and zinc having octahedral geometry homoelectric hexa aqua compounds but having different electrons left in their D orbitals that means D2 D4 D6 D8 and D10 however each of these species has an octahedral arrangement of ligands that we know in spite of having different electron configuration so obviously if you go by VACPR theory to count all electrons VACPR theory cannot explain the bonding among D block metal complexes as a result some assumptions were made in VACPR theory to accommodate the explanation of bonding in D block element complexes so what is the assumption that was made metal lies at the center of the sphere and the ligands are free to move around the surface of the sphere so that means metal assume as a sphere and the ligands are free to move about the surface of the sphere okay and occupy positions as far away from each other as possible to minimize repulsion between the ligands the ligands are considered to repel one another similar to those in VACPR model okay where we were using steric numbers but unlike VACPR model Kepert model ignores non-bonding electrons and assumes coordination geometry of a D block species is independent of ground state electronic configuration of the metal center so this is the assumption according to their convenience they postulated this assumption to employ VACPR model to explain bonding in coordination complexes okay so as a result what happens ions of the type mlnm plus or mlnm minus irrespective of their cationic in nature or anionic nature if the number of ligands are same they are bound to have the same geometry again we know that this cannot be used due to various reasons because most of the complexes if you look into its geometry reactivity properties and everything depends on the electronic configuration the oxygen state and many other factors as a result this initially made early method called Kepert model to imply VACPR theory did not work well. Kepert model rationalizes the shapes of D block metal complexes okay and by considering the repulsion between the groups L okay lone pairs of electrons are totally ignored and here also if two ligands are there they propose linear geometry if three ligands are there they propose trigonal planar geometry if four ligands are there they consider tetrahedral geometry and five are there square pyramidal or trigonal bipyramidal geometry and for six octahedral geometry so what they did was the number of ligands surrounding the metal ion was considered as steric number ignoring the electrons present non bonded electrons present in the orbital then it is bound to show results very similar to main group elements but certainly it does not explain and then when we have different type of ligands it can further deviate as a result it was concluded that Kepert model is not a suitable model okay and VACPR theory is not a suitable theory to explain bonding in coordination compounds. So example they showed this trees or trisino cuprate that we can use VACPR theory ignoring the D electrons to arrive at the geometry of course here trigonal planar geometry is correct but citing one or two example it is not an ideal way to accept the model. So now let us look into the bonding concepts that were later used to explain okay bonding in transformation metal complexes the first one was valence bond theory it was proposed in 1930 by Linus Pauling and he brought hybridization concept to explain bonding and also a couple of properties and using this bonding he could explain inner orbital complex outer orbital complex similarly high spin complex and low spin complex and only spin on the magnetic moment. So in fact when Linus Pauling wrote his very famous and popular book nature of bonding he gave emphasis for his theory and demonstrated giving importance to the recognizing magnetic properties of transmittal complexes using valence bond theory but however it can predict spin only magnetic moment and beyond that many other properties including color and effective magnetic moment geometrical distortions all those things Linus Pauling's valence bond theory could not explain as a result people were looking for an alternate that time crystal field theory was proposed by Beth and Van Blic mainly based on electrostatic forces that means if you take a metal ion and when you put a metal ion into the electric field generated or originated from ligands what happens the degeneracy of orbital will be twofold and this is how this work was started and then early electrostatic interactions and their utility was mentioned by Bakurl who is known for discovery of radio activity along with Mary Curie and Peary Curie for which he got a Nobel Prize in 1903. Crystal field theory looks very ideal and here it explains different type of interactions between metal and ligand if the metal is cationic and ligand is anionic then one can talk about ion-ion interaction and if the metal is cationic and the ligand is neutral one can bring ion dipolar interaction and but if the metal is neutral and ligands are neutral like what we see in case of zero valent metal carbonyl compounds such as chromium hexa carbonyl iron pentacarbonyl where metal is neutral and ligand is also neutral in that case we have to bring or evoke dipolar-dipolar interaction unfortunately crystal field theory does not explain the bonding arising out of dipolar-dipolar interaction when the metal is neutral and ligands are neutral okay that was the only limitation and later to accommodate this dipolar-dipolar interaction the covalency was included and accommodated in crystal field theory and that become ligand field theory and ligand field theory is a beautiful theory it is a very nice combination of molecular herbal theory crystal field theory and also to an extent valence bond theory. The advantage of crystal field theory is it can explain absorption spectra that means color of complexes and it can explain magnetism and also it can explain geometrical distortions and also relative stability because it brings a spectrochemical series and gives definite position in the spectrochemical series for a ligand to say whether it is a strong field ligand or a weak field ligand and bonding in neutral complexes was also brought through ligand field theory and overall molecular herbal theory explained bonding in all type of complexes whatever the bond molecular herbal theory presently we are using is nothing but ligand field theory having good parts of all these theories valence bond theory and Moulican's molecular orbital concept and also crystal field theory very nicely developed by Bieth and van blik okay and it is a very complete theory but it may appear like time consuming but nevertheless it can give you literally all information that is needed to understand the reactivity or their application in various aspects. So before we start digging deep into these bonding concepts it is better to understand the shapes of the orbitals and their relative orientation in space. So we know that S is spherically symmetrical and we have px orbital dumbbell shaped p y and pz they are orthogonal to each other and then we have dx z dy z and dz square and dx myy square and dx y. So these 5d orbitals are there. So S orbitals are spherically symmetrical and their orientation does not affect bonding but in a in a bond involving p orbitals d orbitals or f orbitals the orbitals will be oriented in a direction that maximizes the overlapping so that means their orientation matters if oriented in a direction does not maximize overlap the bond will be weaker. Let us start looking into valence bond theory. Let me tell you about the central theme of valence bond theory I am sure most of you are familiar with valence bond theory. The space generated due to the overlapping of orbitals has a maximum capacity of accommodating two electrons with opposite spins that means when you overlap orbitals from two atoms that can accommodate two electrons with opposite spins that means between two orbitals essentially electrons are localized that is the first concept. If the overlapping is greater the bond formed is stronger and more stable bond strength depends on attraction of the nuclei for the shared electrons that means if the overlapping is greater that means if the electronegativity is comparable and the size of the orbitals are comparable then these two nuclei can come very close to each other and establish a bond in that case what happens the bonds will be much stronger. When two atoms combine to form a covalent bond the valence orbital present in each atom overlap to form new hybrid orbitals with different shapes from the original spd or f orbitals from which they are made up of that means before two atoms combine to form a covalent bond the valence orbital in each atom overlap to form a new set of orbitals called hybrid orbitals that carries the properties of all the orbitals involved in that hybridization. For example if you consider sp hybridization in that one one s and one p involved so that sp hybrid orbit would have 50 percent s character and 50 percent p character and this is how it goes and in sp to what happens we have one third s character and two third p character whereas in case of sp three hybrid orbitals we have one fourth s character and three fourth p character that means 25 percent s character and 75 percent p character that means valence bond theory uses the concept of hybridization of atomic orbitals prior to the bond formation okay a covalent bond forms when orbitals of two atoms overlap and the overlap region which is between the nuclei is occupied by a pair of electron this is an important concept okay that was proposed by valence bond theory one is hybridization concept and the second one is concentration of electrons with opposite spin between the two atoms or that are combined okay or two nuclei okay that means it gives emphasis for localization of electrons between the two atoms okay let me stop at this stage and continue in my next lecture more discussion and with more examples on valence bond theory


You know what this reminds me of? Around a year ago, we made a video titled, A Vegan Diet Will Make You A Fairy Boy. And I really wanted to make that video titled, A Vegan Diet Will Make You Gay.  But basically, you're going to be into furries, you're going to be dreaming about animals if you go vegan. And I've made an awful lot of jokes that vegans are cute, caddy, animal lovers. And I might have mentioned that they want to get dressed up in fur suits, play with each other, all types of costume nonsense. And although I did observe that behavior on a few rare occasions, I didn't really think it held any legitimacy. Until now, that is. And I thought it just happened to be, you know, animal lovers decide to go vegan. You know, it was something before the vegan diet. But one of my viewers made me aware of Zephyllia psychosis. The idea here is that a vegan diet will induce mental disorders through nutrient deficiencies, possibly leading to Zephyllia. And Zephyllia is, well, we'll define it here.  Zephyllia is more common in comorbidity with other parapherias. When reviewing scholarly publications, a small number of articles has been found that connects Zephyllia and other psychiatric disorders, and they are shown here, precisely in those patients and also in the care of our patient that we described here. We can speak of Zephyllic behavior as one of the signs of psychosis. Zephyllia presented as an early sign of the psychotic process. It is for us to conclude how during noticing of such sexually deviant behavior, it is important to pay attention to all the other psychopathology as to get insight into the possible start or exacerbation of the psychotic process in order for the treatment to be more directional. So what that study basically said was it's important to notice if someone starts looking at animals funny because it can be an early hint that the person is going crazy. And most of the time people attempt to disregard nutrition, you know, blame these mental disorders on environment or genetics, which isn't entirely true. When talking about the etiology and pathophysiology of parapheria, all the information leading to now suggests an influence of psychosocial and neurobiological factors for the formation of deviant sexual behavior. Psychological factors which are thought to be most important are family violence, dysfunctional family relations, and sexual abuse and childhood. When talking about the neurobiological side, endocrine function in pedophilia research has shown an elevated response of luteinic hormone, the stimulation of the luteinic releasing hormone, or gonadotropin releasing hormone, which could also be present in zoophilia. So those hormones in the brain which are directly impacted by diet during developmental stages of life are altered in people with mental dysfunction. And research evidence and articles also shows specific case studies correlating zoophilia with mental disorders. Two psychiatric patients with zoophilia, where in both of the patients postmortem, had found atrophy of the hippocampal pyramidal cells. The first case was a man that suffered from hebiphrenic schizophrenia, and the second case was a man that suffered from bipolar affective disorder and chronic alcoholism. In both cases alongside zoophilia, records show incidents of other parapheria. Some of the research suggests a higher incidence of zoophilia in men, persons with mental retardation, poor social skills, and lower levels of education, as well as higher incidence of zoophilia in people from rural areas, especially among those who work with animals.  Schizophrenia like psychotic episode precipitated by cobalamin deficiency. We describe a young single male vegetarian who developed a cobalamin-induced psychotic episode without preceding neurologic manifestations and without any hematologic symptoms. He recovered after a short course of antipsychotics and oral cobalamin supplementation and remained asymptomatic and functionally independent at one year of follow-up. And it can be hard to find studies correlating a vegan or vegetarian diet to mental illness because that's obviously not the agenda. But you can readily find studies showing vitamin deficiencies and various mental disorders. Acute psychotic depression as a sole manifestation of vitamin B12 deficiency. This case suggests that B12 deficiency can present as an acute psychotic episode, correlation between total vitamin D levels and psychotic psychopathology in patients with schizophrenia. Vitamin D deficiency is highly prevalent in patients with schizophrenia, especially those in acute episodes. Vegans B12 and D3 are two very common supplements, especially for vegans. However, taking a supplement does not mean your body is utilizing it. B12 requires many other animal nutrients to be properly absorbed, as does vitamin D3, cholesterol being a big factor. Vegans don't have any cholesterol in their diet and after a few months of hormone production, body stores become very stressed, completely depleted. If these supplements that vegans were taking actually worked, the B12, vitamin D3, omega fatty acids, they simply wouldn't decay into a bunch of animal-loving, brainwashed zombies. And who knows, maybe this will let a couple bulbs in people's heads noticing behavior of certain vegans, but hey, we'll see. So thank you guys for joining me today, hopefully you enjoyed this little tidbit. If you guys could please leave a comment down below, like the video, or share the video on social media if you can. Make sure you are notified by clicking that bell icon. And if you guys do want to support me further, perfect your health, check out frank-tifano.com. Thanks again for joining me guys. I'll see you for tomorrow's video. If I don't lose my mind before then.


Going on everyone Sam here with Layton sports cards have been 23 Panina prison football hobby six box half case break number 17 Pick your team style names and teams at Amar with the Colts Alberto S Cowboys Alvin with the Dolphins Ashley W. Bengals Barry G Falcons and Titans Brandon S Patriots Christopher M with the Niners Cody W. Steelers Dallas v. Jets Dan M Seahawks and Lions Dawson C with the Raiders Ferran a Broncos goo H with the Jags Jason M Giants Jeffrey H Texans Ravens John S John than G Eagles Joseph C Vikings co-hack a Browns Mark M Rams Matthew B Cardinals Matthew S Chargers Michael G Bills Nathan a Packers Nicholas you Saints Nick a Panthers Robert Bobby are with the Bears were Dolpho C bucks and Troy as for the Chiefs So good luck everybody. Let's do it. Dolpho. Let me say for Sunday fun day That's 19 number 18 is that One two three four five six seven eight nine ten to go on the next one ten to go Ten to go all teams again mark down She'd go. Are you in shape hit a bet last night? That's awesome There you go Riz Ray Ray Lewis for sure. We got Cain and Larkin I'm here for the people and I can't love it right off. Oh Cain and Larkin to both go over two and a half shots on goal each that's pretty good actually That's pretty good means the red lanes must have been dominating. All right. Here we go Sava Gardner men shoe purple ice George Pickins the 225 Say and option Saba say throwback. There is Tony red wave 149 wanted to shoot out. Oh, that works, son I'm assuming if a game goes to a shootout, they counted shots on goal. No, Jay So is that true or no? Sorry kill Cleal Herbert to 249 Overshown and at will McDonald's you'll just shoot a lot and that's fair, too That is fair Silver PQ that is gonna be Ivan Pace Jr. Silver rookie autumn Nice one there Barry say that's a good. That's a good. It's a good pick chain. It's a good pick He's my favorite rate non-raven of all time. That's what I want to think about Silver Jordan Brooks will McDonald purple ice at 225 Jalen Carter and Sean click favorite my favorite non-raven of all time. I probably say is Luke Geekley said I just like watch Well, yeah, true true Lockdown Trevon digs purple power Josh Reynolds to 49 for the Lions basin payments Sava CJ Stroud Pukataku up blue ice to 99. Hey one there That's on that Rams. We'll get that into a mag very nice speaking of Rams guys see picking them up in number 19 Thank you, buddy JSN the day in Tomlinson. That's a good one to LT was Monster CJ Mosley Orange Wave Peter Skaronski Quentin Johnson Say oh Bill Cower. Yeah, uh, no One I hit one day auto so far silver of Aaron Rodgers Geron Hall silver rookie auto for the Vikings rice young and Jaden Reed Garrett Wilson Tyler Algear to 149 and Zach Harrison Silver Geron Hall Orange to 249 Brandon I up Rishi rice rookie and Dalton concaid Box one here's gonna be a hyper 175 Nick Bolton for the Chiefs Macintosh and we did so yeah, I know freakin blender bomb was impossible to hit in contenders.  No, I like I mean I don't I don't I don't like Tomlin because when he tripped Jacobi Jones I think he's a scumbag for that one but Yeah, Tomlin.  I don't like coward was I don't know. I don't like either I don't like either of them at all. Davis Mills orange Drake London To 249 Sharpen and Rishi rice. I think that was I think when he tripped Jacobi Jones. I was such a coward move Such a rat move Silver at Bill and Horton Smell the cheese orange wave is Vita fiat 260 Booty and Marvin Mims My god, yeah, that's everybody's been saying that to Anthony, but you know who got oh god Oh boy, she marches Ricky Williams the 49 can only imagine Bolton concaid and Ivan pace. How much worse? How much worse? It's gotta be bad How much worse can you get them? I guess yeah Yeah, I'll tell you Johnson 125 There is Davis Doreen Williams Yeah Yep, here we go Patrick Queen silver rookie or not not silver rookie silver auto nice one there for the Ravens. Let me some PQ pro bowler Jalen Carter. Yeah, well, it's kind of funny that he tried to Get away with it. It's like Jesus, dude Now we're talking about Tomlin there's Daniel Jones Quentin Johnson the 149 nice one there Jaren Hall and Luke schoonmaker Shad are with a couple of flawless collegiate spots. Thank you, buddy I'm gonna drop you guys a link against the next one and it's gonna be number 18 Browns Broncos Raiders Dolphins Patriots Jets Niners Seahawks Bucks Commanders 10 to go That's what I'm saying Jim bow. I'm a I'm a huge Ravens fan That's like that. That's that's my sports team like everybody's got their one sports team That's ahead of all of them and that is mine. Yeah, that's gonna say that's true. Yeah, very true Yeah, I'm gonna say yeah Travis Kelsey Luke Keekley to 199 Nolan Smith and CJ Stratman. Yeah, no, I respect Tomlin as a coach for sure. I think Tomlin's a great coach Here and there here in there Cody I pulled a couple. He's a redemption. So I pulled a couple of them That is a Darnell right rookie snakeskin Hey someone there for the Bears. Congrats on that bears. They're called to 99 Sean Clifford and Peter Swarovski Portals Anthony Richardson. Nice another Pijon with the Falcons rookie at Silverado Mr. Alvin Yes, it is new year. No, no, that's not Alvin Alvin as a dolphin It's not that not the Falcons who has Falcons Barry G. Congrats, Barry. Nice one there Hi, J. Spears Julie to be put to eat below two for a reason I could have sworn you had the Falcons of this one out of my bed Did somebody that's George Kittle Nick Bolton the one 25 QJ Brazil So we go on Jace. See you soon, buddy As always that was a stroud fireworks case of hill to 175 Can read and I Lockdown Joey Bosa to do the 225 place mingo and Hi made deal with the Niners in 21 Austin M with a three box mixer spot and Rob with a bowman's best university Ship it sealed very nice. So 21 another spot off the board in 21 Again 18 still looking at 10s 10 squads I Love it is marked down everything is marked down in the next one. I Kind of know what you're saying though I feel like no matter how good of a coach is you just kind of like it gets to a point where it's like we're ready to move on You know what I mean? I Think that's the issue there cuz it's not like he's not gonna have success elsewhere. That's probably the biggest thing Yeah, oh, yeah, that would be something else Do you imagine that'd be kind of wild actually, thank you Cody picking up the dolphins and Broncos. We're down to eight Cody Thank you, buddy. I'm gonna eat to go on the next one Eight to go Lou Wave. Jerry Judy There's one Johnson you a you a Michigan guy Redolfo. We got gold. Oh true gold Broncos Patrick Sir tan This one there Denver be five of ten well Anderson Emmanuel Forbes Silver Chandler Jones. Okay, gotcha two forty nine CPAP got you Redolfo Yeah, I don't know. I don't know if Harbaugh is a Pittsburgh guy. It's it takes it. It takes a Coat a different kind of coach to coach their Puka silver That is to 199 camp acres Puka again and kind of not saying it's like a bad thing Not saying that Pittsburgh is not a pet Pittsburgh. It would be an extremely Extremely attractive coaching destination. It's just what you have to deal with my homes Purple Power Zach Moss the 49 Ryan Branch Broderick Jones Because of how much money how much money Michigan gave them. That's why there's JSN orange Christian Wilkins and Hended Hooker Yeah, fair fair Fair Shane Silver Kyle pits that's Hines Ward the 149 Congrats on that Pittsburgh got Anthony Richardson and BJ. Oh, Jolari eight to go in the next one everybody into the single digits Let's get a guy's a great feeling being in the single digits Feeling silver Garrett Wilson blue ice down and cook to Joy Porter jr. Evan Hull So about a lockdown Max Crosby perforage Covey Myers to 125 shorter and Jordan Addison Your gifts red wave hija spears to 149 tune and Mojo, yes, it is mojo There we go on the variation. Let's go dude. 18 of 25. Congrats on that. There we go Carolina that is gonna play that is gonna play just fine right there everybody Carolina Panthers I can find them Is Nick a congrats Nick That's awesome, man. No, I know shady forest is gonna fix it when he comes in there in water 175 It's just a matter of It's a matter of when we yeah, we have J's Mike over here as well Yeah, can I move any more to that way or is it just yeah, I keep it there. Okay? Try not to pick it up as much Portals is Trevor Lawrence Tyler Scott silver rookie out of the Bears. I like the rookie variations. I really do Like those those are clean Good case so far. Yeah, that actually helped out perfect. Very nice Yeah, we have a top-loader Mike and it was J had it a little closer to me than normal. That's probably why my guess Yeah, so you have to push it far away for me, right? Exactly March a spread wave Dion to 149 nice one there for Falcon straight Tucker and Miles Murphy Yes to orange Evan Ingram to one to 49 he's on rookie and Erick Dickerson Hyper Bailey zappy to 175 for Patriots Tillman Jalen Hyatt silver Josh Allen purple ice Bobby Wagner to 225 Daniel Wilson and Zach Evans Purple ice Kyron Williams to 225 Eric Gray KJ Henry orange wave Chuba Hubbard Chuba this one there Lamar color black. Oh, I like that. That's in Bennett. I received and that'd be pretty sweet. Oh, I mean that'd be sweet, dude Lamar color glass. Hell, yeah Don't in Kincaid hyper to 175 nice rookie there for the bills Osgee Profiles are pretty cool. Yeah, profile is a little bit more affordable for sure That's straight London hype and Dalton Kincaid rookie autograph prism silver going to the bills congrats on that buffalo buffalo Very nice. Take that for sure Peace and base this w with a three box mixer spot. Thank you, buddy Go bills again Rice young silver nice one there for the Panthers That is an equal Audrey to 199 Benton and Josh Downs. Yeah, actually I'm release day Be the we hit a we had a dual of Stroud and Dell. I had one of those that was it was pretty awesome Yeah, it was massive card silver to bond witherspoon forest camo JSN. There we go Nice man 14 of 15 congrats on that one Seattle. Hell. Yeah, dude In this case this case is rocking so far everyone's cases totally rockin rockin that I am in on this for sure Congrats on that Jamir Gibbs and there it goes been good so far. It's been really good so far Blue ice can you pick it to 99? Orange waves at Charbonnet doing well against Seattle the 60. Not bad. Juju Branson Paris Johnson silver bristle That's Roshan Johnson silver rookie auto for the Bears nice one there Evan Hall and Michael Wilson. Yeah, the Manga's are sweet man. I like the Manga's a lot because it's super unique Yeah, and especially like just like the design the different. Yeah, they do a really good job in like prism football like Prism NFL football they do the best job to in my opinion Eight to go in the next one everybody eight to go Yeah, I know what you mean kind of remind you is the portraits from select that you kind of look very similar to that Grow with that Rodolfo. We're not wrong. I think it's just the obsession with prism. I think that's what it is Kwame I Think it's just how much people love prism beyond Sanders Jake Ferguson on the Silver Auto nice one there cowboys And then Hooker and Joey Porter, Jr. I think if the white color glass came out of a different a different product They would sell for less than the black ones. Oh 100% certain orange Broderick Jones They're also exactly what what what Shane said they're much much more rare, too Who got a press proof coming up? Oh? That is a Jalen Hertz press proof of Cortland sign Congrats on that one. They're Broncos Blue ice little Jordan Humphrey Evan Hall and Clayton tune Yeah, Shane that's true because obsidian as well as like it's it's a case hit in obsidian You're pretty much guaranteed to get one to end of a key. I sat heavens on the green scope to 75 ETR Versus prism. It's not the only case hit in prism. You can get you could go theoretically 10 cases and not get a color blast Not probably super Likely but it's possible DJ walk hyper of John Elway, Aiden O'Connell Darnell Washington some Lockdown Cam Hayward CJ Mosley blue ice the 99 then that's Elijah. Can't see Yeah, it is guaranteed in obsidian case Tyler. I was here to 225 Turner and will Anderson. I mean, it's not guaranteed like it's a It's not guaranteed That is guaranteed. It's it's supposed to be in there nine out of every 10 cases 19 out of 20 will get it That is Brandon Ipe Purple is Tyler Smith to 125 Porter and Chase Brown also very true, Shane You have to spend more money to get one theoretically and you do an obsidian Drake London hyper Jalen Hyatt to 175 Keanu Benton and Josh Downs Exactly results. Oh, yeah, there might there might be one case that I'm not thinking of in obsidian, but Silver's Jalen wall orange Deron Payne to To 49 Silver Kyle Pitts, we've got redemption There we go autograph prison silver going to Miami. There we go. That's mr. Alvin. That's Alvin Very nice. That's dolphins Michael Meyer rookie We'll get you out of the will canyx will canyx. I cut. Yeah. Yeah. Yep. Yep. Yep Tomorrow chase Mack Jones to 75 Scott and breezy kind of Walker Jamal Adams to 225 breezy and a hendon hooker They pick it louise debo to 99 Keon white Ryan branch Silver Travis Kelsey orange Deshaun Watson to 249 Joey Porter jr. Broderick jones red wave nick fulke to 149 Anthony Richardson vj. Ojalari vj. Ojalari manual Wilson 2175 and Jordan Addison And everybody let's get the next one sold out. We're almost there eight to go eight to go on eight No, five to go now on 18 one two three four five to go on number 18 somebody Or a couple that I didn't see Um, mr. Steven take the seahawks and Niners. Thank you buddy and Steve B took the jet So yeah, we are down to five to go now everybody. Thank you. Thanks to the two of you very very much five to go Guys are awesome killing it today. I appreciate it very much Very very much. We halfway through our prison breaks after the next one That means only four to go Silver is ross wilson lorenzo carter navy camo to 25 for the falcons ebb and hull and clayton tune Rogers prismatic marvin mince the 149 red wave auto congrats on that denver Denver hits a lot in this. You know in no connell darnell washington. Denver is the other team I try to recommend Depending on your I always try to have a couple teams depending on everybody's budget of what teams I would take and that's like uh Like a mid tier team. I would go after uh buda baker to 225 Silver shone cliford orange jordan brooks to 249 Bill and wharton and will love us rookie Silver throwback to uh blue ice chase brown to 99 for bangles tank del rookie and chris rodry gage jr Coming up here. We'll power insert. It is a j brown. Nice one there to 49 No blacks this morning.  Oh a year, dude. I haven't hit one yet Kind of pissed about that. I don't hit one hit marlin humphrey last year. It's super jealous So we're brian dawkins and sam la porta There we go 25.  That's big. That is sweet That is sweet Get that into a mag as well. Congrats to detroit iron young and darnel right To a quick recap great great case, man. Oh, thank you Uh, we had press group courtland Sutton snake skin of darnel right blue ice to 99. That is chase brown Evo cj moseley little jordan humphrey kenny pickett dowman cook to 75 mac jones and zack evans Orange to 60 zack charbonate juba hubbard vita vea cj moseley to 49 people power Josh reynolds ricky williams ej brown zack moss the 25 is uh, lorenzo carter to 10 patrick sertan Yeah, that'll sell stupidly quick Autos and mags. We've got like five mags in this half case pretty solid um, autos the van ashen Dalton concade hines ward jake ferguson toddler scott Roshan johnson jaren hall patrick queen Ivan pace and marvin mims mags guards variation mojo to 25 is brice young uh navy camo jsn to 15 blue ice puke and akua to 99 silver rookie auto of bijan robinson and then navy camo to 25 sam la porta That will do it for the break everybody. Thanks again for the fill awesome. Kate half case next on the break


Now reporting Six when the clock struck six it meant one thing. I want to go chase the squall. You know there's nothing interesting to say Now from the ESPN New York news desk here's frozen bomb or whatever that guy's name is And welcome ladies and gentlemen to e n n Which on this Wednesday night is brought Jersey for amazing locations They're taking extra care of those locations to make sure you're safe if you need to go in and get a new car So shout out to all American Ford will start off tonight by saying good evening to Michael my goodness Then we'll say good evening to Don A couple of great memories two of those former Diaper dandies how to run of the tournament years ago, but now without any further ado It's time to reveal the Don Region the final two rounds the sweet 16 and the elite eight will be taking place in Boston at the TD garden Yeah, empty arena, but it's gonna be special Are you ready for it? The number one overall don seat is unlike any number one don seat we've ever heard before here It is the number one overall don seed former Raven replied a current Raven. Oh like the game doesn't need it Sorry, he's a charger now. He's a charge. Oh, he's a ram That's our daughter Hard to argue and it's I mean to think to think that the following seed is a 16 is Mind-blowing. Here's the 16 seed. You want to be like Alan Alder? Yeah, I Mean a 16 All right, the number the eight nines beautiful. Here's the number eight seed nice back pedal hamstrings must be pretty strong after that Up against the nine seed he'll I would never do an interview with GQ. Just talking about The five seed which I have is the champion of my bracket the five seed you familiar with the work of David blow Wow up against that up against the maybe maybe someone who goes to the final four in the 12 seed I it's incredible listening is in like six figures, right? Oh, yeah, maybe four for me. I mean seven What that's on again bad it matters That's not going to the farms sorry after that was a different one Wait, so you know it, you know what we'll deal with it later Okay, that was the 512 now you have the number four gladiators 34 35 is Titanic No, we're moving here to eternity 36 saving father Ryan 37 up against the 30 so happy that I taped that up against the 13th seed, okay, I agree with you Michael because you're the man. That's not how I work at all How that's there, I don't that's embarrassing. I don't understand that job ever played on the air. No, it doesn't even exist I'm shocked. Well, let's go to the number six seed Up against the 11th seed cling on Jones not cling on Jones The three seed Budweiser nips over gypsy pond by and clicksies up against up against the feisty 14 seed I'll talk to me that way the seven seed Up against a really game 10 seed Don and Peter with you until seven and then we were gonna have the great Brewer's Pirates game coming up at seven o'clock It is I know get the get the slipper ready then you have the two seed I'll write all the numbers down for the capitals Up against the 15 hostile rage torment blood feast and there it is you're done region And it's beautifully done and unless I'm not gonna Michael. I don't want to like create a lot of problems here But the one thing I'll say is this the The a couple of these drops which I barely remember ever hearing the throws bottle the 13 seed How did you not use the one when Don did the math about the Yankees record and double headers? How how is that not here? I can't live with that. I'm not okay This is like a great team. That was like, you know 27 and 4 That you said the strength of schedule wasn't good enough and they didn't get to make the tour This is the worst job that Andrew's ever done the Yankees have played seven double headers this year Don and Peter That's 14 games. What do you think their record is six in one? So I think that one is labeled as Don and K or K and Don and so a lot of those drops that it's almost Heavily 50 50 if anything, that's almost 75 25 The funny part is the drop is the genius of the drop and the genius of the drop is done Well, how is it labeled? Is it labeled a Don drop or a K and Don drop?