Okay. Hello guys. Good afternoon. Please type in your name in the comment box. Hi Sushant. Okay. So today we are going to discuss P block elements. Okay. So, so here in this P block elements, first, we will discuss here, carbon family, carbon family. So in class 11, we have two groups which we have to discuss here in P block elements, that is boron and carbon. Right. So we are discussing carbon first, since this is a combined class with HSR students also. And for them, I have already done boron family. Okay. We are doing carbon family first and then we'll continue with boron. Okay. So they have exam also tomorrow, some lab exam they have, practical exam they have tomorrow. So once we finish carbon family if they want, they can leave also. Okay. That's why I'm discussing this carbon family first. You also have exam right? Sushant Ashutosh, RLR students. And the school is now, now it's closed, right? For preparation holiday. So Monday onwards, you have, you have exams, right? School exam. Okay. Last day for the school. So when can we have our class on Monday? Okay. Monday is chemistry. When can we have our class on Monday? Sorry, on Saturday? Yes, we'll let you know after 20 seconds, what is the schedule that I'm not sure with? Okay, we'll let you know Bharat. That's what I'm asking since I'm waiting for more of more students to join this. That's why I'm asking all these things. What do you want me to do on Saturday? Can we do some basic revision of class 11 on Saturday since you have exams? No, Bharat, we cannot take organic problem solving. We have to take care of other students also. Yes, mostly we'll finish P block today, boron family and carbon. Like I said, we will not discuss everything. You have to study and CRT. Important thing we'll discuss today. Okay. Anyway, so we'll figure it out. What we'll discuss on Saturday. We'll let you know. So today we are going to start carbon family, right? And then we'll do boron also. So you see in carbon family, these are the elements of group 14 group 14. I'm not sure with this Ashutosh. Maybe may not be. I'm not sure with this. Anyone told you this thing that we don't have class till March? Usually it happens every year. We don't conduct classes during exam. That's the thing. Right. So does anybody told you this Ashutosh? So you see group 14 and the elements of group 14 or what? The elements are carbon, then we have silicon, then germanium in the last we have lead. Yeah, that's what. Let's see. Let's see what happens. Anyways, so these are the elements of carbon family we have. Okay. So carbon is C, silicon is S, I is germanium is GE, SN and TB. Okay. Atomic number. What is the atomic number we have here? Atomic number, if we write down, that would be for carbon, it is 6. For silicon, it is 14. Then 32 plus 18, 50 plus 32 is 82. Right. So the magic number here is this difference is 8, then this difference is 18, 18 and here we have 32. So magic number of P blocks are 8, 18, 18 and 32. Okay. Electronic configuration if you draw. Right. So for the first one we can write 1S2, 2S2, 2P2 or we can also write the configuration of helium is H, helium is 1S2. So helium 2S2, 2P2. Right. Then we can write down the electronic configuration of silicon that is neon, 3S2, 3P2, argon, 4S2, 4P2, krypton, 5S2, 5P2, 5S2, 5P2. Then this is krypton, then we have in the last xenon, XE, 6S2, 6P2. Right. One thing important here again, you have to understand this, that in germanium what happens before this 4S, we have completely filled 3D orbital, 3D10. Right. Similarly in 10, before this 5S, we have completely filled 4D orbital, 4D10. Similarly in lead, before this 6S, we have completely filled 4F orbital and 5D orbital, 4S and 5D10. And we know that this DNF orbital, DNF orbital shows weak screening effect. So this thing we will use later on in this chapter to explain the trends, weak screening effect. So these are the electronic configurations. Now you see few trends if I discuss like few general thing if I tell you. Right. Carbon, like from this electronic configuration, one thing is clear that general electronic configuration if I ask you for carbon family, it will be NS2, NP2. Right. N is the number of period, NS2, NP2. For the carbon it is 2S2, 2P2 since it is in the second period, silicon 3S3, 3P2, third period, 4S2, 4P2, 5th, sorry, 4th, 5th and then 6th. Right. So okay. So now with this electronic configuration only, the trends if you want to discuss here, few trends that will be, first of all we will discuss oxidation state, oxidation state. So in oxidation state what happens? The carbon and silicon. Okay. Carbon and silicon shows plus 4 oxidation state generally, plus 4 oxidation state. Okay. But the other three elements which is germanium, tin and lead, they shows plus 4 and plus 2 oxidation state. Okay. So for germanium and tin, these three, these three element shows plus 4 and plus 2, both oxidation state, but for carbon and silicon it shows only plus 4. Right. What happens here actually you see there is a term called inert pair effect. You know what is inert pair effect? What is inert pair effect? Do you know that? Tell me. What S orbital? All these S orbital, this S orbital also, this S orbital also and this also. See that is not the thing and this is important for a school exam also. They ask you this, what is inert pair effect? See first of all if I ask you what is the order of shielding effect of orbitals? Okay. So shielding effect for orbitals. It is maximum for S, then P, then D and then F. Right. And usually we say what DNF orbital shows weak screening effect or shielding effect. I have written here weak effect DNF orbital. So when the electrons present beyond this DNF orbital, then those electrons are strongly attracted towards the nucleus since because of weak shielding effect of DNF orbital. Okay. So what happens here you see how this plus 4 oxidation state forms or get when these 4 electrons which is present in the outermost electronic shell takes part in the bonding. Okay. Takes part in the bonding. So these 4 electrons when it loses then only it forms plus 4 oxidation state and when only these 2 electrons take part in the reaction that gives you plus 2 oxidation state of the element. Right. So these oxidation state plus 4 and plus 2 depends on how many electrons present in the outermost shell takes part in the bonding. Correct. So here you see what happens. That's why I have written 3D10, 4D10 and this here. What happens when you go from silicon to zermanium since we do not have D orbital present here or here, we don't have D orbital present. Right. So what happens these electrons, these electrons and the inner orbital of these electrons or what we have S here and here we have SP both. The inner shell orbital, this is the outer shell. Right. The inner shell orbital we have 1S2, 2S2, 2P6. Here it is only 1S2. Right. So here we have SNP orbital. Here we have only S orbital but both SNP orbital shows a strong shielding effect. Right. That's why what happens these 4 electrons present in carbon and silicon. Right. Is weakly bonded to the nucleus because of strong shielding effect of SNP orbital here. Since these 4 electrons are weakly bonded, bonded so these two may take part in the reaction and that's why the carbon and silicon shows plus 4 oxidation state. Is it clear? Clear yes or no. Tell me. Clear understood. Right. So now next what happens, so this is one thing. Why carbon and silicon shows plus 4 oxidation state. Now coming back to the zermanium tin and lead, what happens when this electron goes into 4S and 4P orbital. So before going into these orbital, electron has to fill this 3D orbital here. So the penultimate shell or the inner shell here we have is nothing but the 4D orbital. Right. So the penultimate shell contains completely filled D orbital which shows weak shielding effect. So because of the weak shielding effect of D orbital, these outermost electrons which is 5S2 and 5P2 is strongly attracted towards the nucleus and this is true in the case of zermanium also tin and lead because we have 3D, 4D, 4F, 5D. Right. So because of the completely filled D and F orbital here, these electrons which is SNP, 2 electrons in S, 2 electron in P are strongly attracted towards the nucleus and this attraction is more dominating over this S orbital than this P orbital. Because why this orbital is closer to the nucleus in comparison to this P orbital. Right. So what we can say is in the case of zermanium, tin and lead, these two electrons which is present in these two electrons which is present in P sub-shell P orbital here, these electrons and these electrons. When these electrons donates, it forms plus 2 oxidation state and plus 2 oxidation state here. But comparatively, electron present in S orbital are strongly attracted towards the nucleus. That is why it is very difficult for these elements to lose electrons present in S orbital and hence they have difficulty in the formation of plus 4 oxidation state. Is it clear? Both electrons in SNP orbital is strongly attracted towards the nucleus as compared to the electrons in carbon and silicon. But when you compare the electrons of SNP orbital as will be more tightly bonded to nucleus than the P electrons. So what happens because of this D and F orbital that 2 electrons present in S orbital or in other words we can say a pair of electron present in S orbital is become inert towards the bonding. Correct. Because of weak shielding effect of D and F orbital, so a pair of electron which is present in S orbital becomes inert towards bonding. Hence we call it as what? Inert pair effect. Understood? Clear? Yes, tell me. Understood? Yeah, I'll just first try to understand what I'm saying. Definition I'll give you. Right? So what happens here? What happens here? The pair of electron becomes inert towards the bonding and hence we are calling it as inert pair effect. Why it happens? Because of completely filled D and F orbital present in the penultimate shell. Okay? This is what inert pair effect is. Now definition if you want to write down, write down here. Definition. Inert pair effect. Definition you write down. It is the it is the reluctance of NS2 electron. It is the reluctance of NS2 electrons, reluctance of NS2 electron to unpair and participate in chemical bond formation. It is the reluctance of reluctance of NS2 electrons to unpair and participate in chemical bond formation comma which arises due to which arises due to the presence of arises due to the presence of weak shielding, weak shielding, fully filled D or F electrons, fully filled D or F orbital you write down. Fully filled D or F orbitals between between the valence electron, the valence electron and the noble gas core, the noble gas core, C-O-R-E. Right? These are noble gas. So valence electron is S262 and these are D and F orbital fully filled. So what happens you see here? This is important now. As we go down the group from down the group from germanium, what happens the tendency to form plus 2 oxidation state increases right down here. Tendency to form, tendency to form plus 2 oxidation state increases. Tendency to form plus 4 oxidation state decreases. So what we can say one thing is here you write down next slide I use stability order write down stability order in this only. For plus 4 oxidation state the stability is this it is most stable in germanium then Sn plus 4 and then Pb plus 4 because plus 4 oxidation state increases down the tendency to form right but for plus 2 the stability is reverse g e plus 2 is minimum then Sn plus 2 and then Pb plus 2. This is the stability order of the two oxidation state we have okay. Now you tell me one thing here for germanium you see germanium is more stable in plus 4 oxidation state right. So whenever you have g e plus 2 it has tendency to convert into g e plus 4 right. Similarly lead is more stable in plus 2 oxidation state. So whenever you have lead Pb plus 4 it has tendency to convert into I'll write down this sign it has tendency to convert into Pb plus 2. So what is this behavior and what is this behavior tell me what is the first one and what is the second one what kind of behavior is this oxidation and reduction this part oxidation number is increasing so what happens germanium is getting oxidized is getting oxidized right means here it is behaving as a reducing agent listen to me carefully here don't get confused reducing agent right and this is what lead Pb is getting reduced right so we call it as what getting reduced so it is an oxidizing agent oxidizing agent okay. So if I write down here tendency to behave as a reducing agent tendency to behave as reducing agent right will be more for germanium than Sn and then Pb here I will write down tendency to behave as oxidizing agent is minimum for germanium then we have 10 in and then we have lead so Pb plus 4 you can say it is strongest oxidizing agent oxidizing agent here and this one is the strongest reducing agent this one sorry this one is the strongest reducing agent this property is very important okay you must remember so when you write down PbCl2 PbCl4 it always has tendency to convert into PbCl2 because here the oxidation state is plus 4 and here it is plus 2 and we know lead in plus 2 oxidation state is more stable that's why the answer will be this so if I write down here the last thing like for all the elements we have carbon silicon germanium tin and then lead carbon shows only plus 4 oxidation state silicon can show plus 2 plus 4 but generally it is plus 4 only germanium can show plus 2 plus 4 tin can show plus 2 plus 4 and lead will show generally plus 2 so in all these oxidation state this is only possible oxidation state for carbon for silicon plus 4 is the most common for germanium plus 2 is the most common then tin we have plus 2 and then for lead we have plus 2 plus 2 no germanium can have plus 4 also both oxidation state for germanium is common but this is the important part which you have to memorize as far as the oxidation state is concerned understood okay okay next write down what about the covalent radius the trend of covalent radius and red eye so that's the same thing as we go down the group as we go down the group it increases because you are adding an extra cell of extra energy shell into it so carbon will have minimum right what is the order here we get so write down the statement here first then we'll see first write down the statement in this group in this group there is considerable increase in this group covalent radius write down the statement in this group there is a considerable increase in the covalent radius from carbon to silicon thereafter from silicon to lead and thereafter from silicon to red there is a small increase in radius is observed sorry silicon to lead a small increase in radius is observed a small increase in radius is observed this is the statement for covalent radius from carbon to silicon first of all down the group it increases okay but from carbon to silicon the increase is much larger than from silicon to lead whatever the increase we have okay now the reason for this word this is due to the addition of a new shell in each each succeeding element that we already know the increase in radius from silicon to lead is a small why because of the ineffective shielding of valence shell of electron that also we have discussed since we have as we are going down the group the electrons are going into d and f orbital which has weak skinning effect and hence they appear strong attraction towards the nucleus and hence the increase in size decreases comparatively understood see gargi electronegativity is the relative concept okay we always define electronegativity in a bonding state you see what happens if you write rcl correct rcl here we say because of electronegativity here we have partial negative partial positive charge right but when you have an atom chlorine in this free state for an atom we cannot define electronegativity it is not possible because electronegativity is what it is a compare it is a relative concept it is not absolute right carbon when attached with chlorine right so here the carbon having positive charge when carbon is attached with right hydrogen in that case carbon has slightly more electronegativity so carbon will have then slightly negative charge over there so it means what this electronegativity is a relative concept it won't it we can already explain electronegativity between the two atoms for an atom which is independent free we cannot define electronegativity understood clear yes electronegativity we can only explain in bonding state to what element it is bonded with right so here the point we are talking about the covalent red eye of an element so electronegativity does not have any effect okay so the reason is same extra shell of electron we are adding and then as we are moving down the growth electron is going into dnf orbital which shows the weak screening effect so there will be a little bit of contraction in the size hence the increase in covalent red eye from top to bottom decreases right initially the increase will be more then it will be comparatively less right next right down ionization enthalpy tell me the order of ionization enthalpy increases down the group how you see the first of all write down the order of ionization enthalpy it is maximum for carbon then silicon then germanium and then lead and then tin this is the exception you can say lead has more than tin okay so first of all you write down this is the you know trend now you write down few points here first of all you write down the first ionization enthalpy of group 14 the first ionization enthalpy of group 14 so i e 1 of the elements of group 14 the first ionization enthalpy of group 14 elements are higher than are higher than that of higher than that of the corresponding elements of group 13 what is the meaning of this if you compare the first ionization enthalpy of carbon it is more than to that of boron silicon it is more than to that of aluminium this is the meaning of this point first of all okay we cannot compare you know these two or these two it it is then you know factual we have to see the energy involved here then we can say okay but this is one thing now for this order you see what happens write down as we go down the group as we go down the group the first ionization energy decreases but the first ionization energy of lead it's slightly more than to that of tin the general trend of don't write this as you listen to me the general trend of ionization energy is what as we go down the group ionization energy decreases and why it happens because the size is excuse me because the size is increasing right so size has an important role here because according to size only we have electrostatic force of attraction between the nucleus and the electron that actually defines or explains the ionization energy right so as we go down the group you see we have a factor which we call it as inert pale effect and because of inert pale effect the size starts you know the difference in size from germanium to tin is not germanium to lead is not that much high it is increasing but that that the gap is not no as high as it is in carbon and silicon correct so size is getting contracted as we go down the group that's why in case of lead the ionization energy is slightly higher than to that of tin so we have a little bit of irregularities in this order in this trend that is most important you must remember this trend understood yeah you can say that but it is an exception actually just a second yes yeah oh no no i'm not interested no i i have already so i don't require it i have already other lines so i don't require it now if you want to give me the information about the benefits and all you can call me tomorrow right i can be a bit easy okay so you can call me tomorrow 11 o'clock that would be fine okay so this is the trend we have correct so you must remember these values exceptions that we have here next to write down electronegativity write on quickly electronegativity as we go down the group electronegativity decreases right no it's not it's there is a change here a bit okay write down electronegativity first don't write down down the group it decreases so for electronegativity you see the general trend is what general trend is down the group electronegat down the group electronegativity decreases now what happens here in electronegativity write down as we go write down the electronegativity decreases from electronegativity decreases from from carbon to silicon remains constant and remains constant from slightly increases and then slightly increases from from tin to lead pb right generally what happens we say if it decreases from there's one more thing which is written in some other book decreases from carbon to silicon then after silicon onwards silicon to lead it is almost same remains same this is also written in some of the book so this also you can consider if option is like that okay these two things so there's a slight increase but that increase is not that enough okay so in some book they have written this also and some book they have written this also so any one of these you can consider according to the given option okay right again the reason is same because of the deal filling of d electrons in germanium and tin and in lead we have we have f electrons also and d electrons also that is the reason we have here okay next should write down metallic character what is the order of metallic character general trend is what as we go down the group electron enthalpy decreases metallic character increases and and what happens electro positive nature also increases right in this you write down as we go down the group as we go down the group the metallic character increases as we go down the group metallic character increases carbon here series carbon and silicon these are actually non metals germanium is metalloid tin and lead are metals soft metals these are actually metals and that is soft metal the reason behind this is what as we go down the group the effective new that we have less effective nuclear charge and the number of available orbitals also increases with increase in size of the atom okay so thing is because of less effective nuclear charge okay one more point to write down the elements of group 14 if you compare this character with group 13 and group 14 the elements of group 14 are the elements of group 14 are solids are solids and they are more electro positive and metallic and they are more electro positive and metallic as compared to the elements of group 13 they are more electro positive metallic as compared to the elements of group 13 next one write down tendency to form multiple bond tendency to form multiple bond this is again important the first type of bond you write down here which is p pi p pi bond p pi p pi so write down in this quickly carbon has a strong tendency to form p pi p pi bond carbon has a strong tendency to form p pi p pi bond with other elements of similar size this is due to other elements of similar size means what other elements of similar size means what we can have c double bond o c double bond n like this okay c triple bond n also you can write n h c triple bond n also you can write right so carbon has strong tendency to form this kind of you know p pi p pi bond with the elements of similar size this is due to the small size this is due to the small size and high electronegativity small size and high electronegativity of carbon atom next line as we go down the group as we go down the group the tendency to form p pi p pi bond decreases as we go down the group the tendency to form p pi p pi bond decreases the size increases and electronegativity decreases right so it is basically when you talk about silicon with oxygen nitrogen and all so this has you see here the thing is here we have 2p 2p orbital here also we have 2p 2p orbital all the elements here has 2p 2p orbital and that's why the lateral overlapping we have good lateral overlapping here over here but in case of silicon zermenium and all we have 3p 4p like that the orbital so overlapping of 3p and 3p and 2p orbital 4p and 2p orbital is not that possible yeah that's what the effective overlapping is not there and hence p pi p pi bond does not form okay now the second type of bond we have here which is p pi d pi p pi d pi right now since carbon does not have d orbital since carbon does not have d orbital in its valence shell its valence shell it does not form p pi d pi bond it does not form p pi d pi bond but other elements of group 14 has tendency has tendency to form p pi d pi bond right so on the basis of this only we have examples and I think I have done this example and this kind of bond p pi d pi bond is very silicon has very strong tendency to form this kind of bond like on the basis of this only if I write down this example si h3 whole thrice n and ch3 whole thrice n which one is more basic here which one is more basic into these two which one is more basic ch3 whole thrice n yeah you see what kind of base is this this is louis base right electron pair donor what happens here you see this has lone pair and this also has lone pair but since here we have silicon which has vacant d orbital the silicon has vacant d orbital so this lone pair is donated to this vacant d orbital of silicon to form p pi d pi back bonding okay and hence this lone pair is not available here and hence it is not a base weaker base yeah but here since carbon does not have d orbital no d orbital so this lone pair is available here so it can donate to the other molecule this behaves as a louis base understood yes understood this is important example okay must remember this okay next write down reactivity towards oxygen reactivity towards oxygen write down the elements of group 14 the elements of group 14 when heated with oxygen the elements of group 14 when heated with oxygen forms an oxide of forms an oxide of mo2 type mo2 type this is as you can see it is dioxide and this is monoxide one note you write down here all these small small notes points are important write down si o exist only at high temperature at high temperature where it is where it is reduced sorry where it is exist at high temperature just a second where it is formed by the reduction of si o2 dioxide with si silicon itself so the reaction will write down si o2 plus si gives you two si only at high temperature reactivity towards water reactivity towards water write down carbon silicon and germanium carbon silicon and germanium do not react with water do not react with water okay no issue carbon silicon and germanium do not react with water however on red heating red heating means what strong heating also you can assume at high temperature however on red heating these elements except lead important this one these elements except lead decomposes a steam except lead decomposes a steam you see carbon solid form plus h2o plus h2o on red heat gives co plus h2o gas si solid react with 2 h2o on red heat it gives si o2 plus h2 sn solid plus h2o gives sn o2 plus h2 gas but no do you write down lead is not attacked by is not attacked by pure air free water pure air free water except at boiling point except at boiling point except at boiling point next line it is it is easily corroded by water it is easily corroded water containing dissolved air containing dissolved air forming lead hydroxide forming lead hydroxide lead hydroxide which is soluble in water which is soluble in water this property you have to memorize which is soluble in water this reaction you write down 2 pb plus 2 h2o o2 gives pb OH whole twice soluble in water this one this last one point to write down the solvent action of water solvent action of water is known as is known as plumboso valency b o s o plumboso valency nothing we have to understand here the point here it is what that lead is generally not attacked by pure air free water except at the boiling point what happens if you have air dissolved in water right and that air contains oxygen so this oxygen is coming from air if water contains air in it right and when it reacts with lead it forms pb OH whole twice which is a water soluble right this is it we have so the point is all these elements reacts with water but lead generally does not react with water right it it reacts with water but that water should be pure and air free right if it is not air free then it forms pb OH whole twice which is again water soluble now we see some general characteristics of compounds okay we'll see the compounds of this group and its characteristics the first one you write down hydrides hydrides write down these elements forms covalent hydride covalent hydrides like we have for carbon also those will discuss this in the last okay let me finish this first the hydrides of carbons are what alkene alkene alkynes correct you already know this hydrides of carbons are alkene alkene alkynes aromatic hydrocarbons and all write down few points into this write down germanium hydrides are straight chain compounds straight chain compounds write on the hydrides of tin the hydrides of tin we call it as stanon hydrides of tin sta double n a n e stanon for germanium we call it as germanium hydrides or you also call it as germans both are same thing this stanon you write down these are less stable and strong reducing agent next write down this is done next write down acidic character of oxides oxides we have already discussed that it forms two types of hydride one is mono and other one is dia mo2 type okay write down as we do as we go down the generally we discuss about dioxides which is generally more stable state write down for dioxides as we go down the group for dioxides as we go down the group the acidic character decreases acidic character decreases and basic nature increases right down the group acidic character decreases and basic character increases so if i write down co2 si o2 sn o2 and pb o2 so down the group acidity decreases and basicity increases can you tell me the reason for this not stability it is acidity acidity decreases anyone can you tell me the reason yeah you can also say the accessible deorbiters to accept the pair of electrons or you can also say as we go down the group that is not true here correct see as we go down the group deorbitals are there and size also increases right so it can easily accommodate the pair of electrons and that's why the acidity basicity increases acidity decreases next you write down halides halides you write down write down all elements of this group yeah stability of plus 4 will decrease down the group write down all halides of sorry all elements of this group forms tetrahelides forms tetrahelides mx4 type tetrahelides of mx4 type okay write down write down among simple tetrahelides among simple tetrahelides the tetrafluorides fluorides fluorine geo has amphotonic character it is not completely acidic or completely base among simple halides tetrahelides the tetrafluorides of carbon silicon and germanium the tetrafluorides of carbon silicon and germanium are gases exist in gaseous form however this snf4 and pbf4 is are actually solids why because these are halides are covalent in nature and because of its covalent nature it is a volatile gas not important only the state sometimes asks gases are solid these two halides are have any character this is also you remember any character tetrafluoromethane cf4 will discuss few points just few facts we should know first of all since it is tetrahelides all atoms are sp3 hybridized for halides carbons are sp3 hybridized okay cf4 write down it is carbon tetrafluoride write down it is exceptionally unreactive gas and highly stable cf4 write down it is exceptionally unreactive gas and highly stable right the preparation method of cf4 is what when this co2 carbon dioxide is allowed to react with sulfur tetrafluoride it gives cf4 and so2 displacement kind of reaction it is this is the laboratory method of preparation laboratory now the industrial method is what we use chlorofluoromethane right which is you know cf2 diphenol diphenol when this is allowed to react with fluorine itself it forms cf4 and chlorine evolve now why we are discussing this here because this is actually a monomer cf4 right it is dimer if you see cf4 the dimer of cf4 is okay just a second it is not it is dimer just a second just a second see we get cf4 carbon tetrafluoride but there are also possibility of getting of ended up getting hexafluoromethane into this which is nothing but c2f6 or we can also get tetrafluoromethane which is c2f4 hexafluoromethane or tetrafluoromethane now this c2o4 which is tetrafluoromethane when it is polymerizes to c2f4n this we call it as poly tetrafluoromethylene okay this is what poly tetrafluoromethylene PTFE poly tetrafluoromethylene is the polymer of tetrafluoromethane now few uses of this is important that's why I have given you this uses of this you write down poly tetrafluoromethylene poly tetrafluoromethylene uses you write down write down used as uses you write down good electrical insulator for coating non-stick pans and razor blade for coating non-stick pans and razor blade it is chemically inert in nature heavier and more dense inert in nature heavier and more dense now the last compound we'll see here write down carbonates and bicarbonates just just a second this is not required here I guess it is carbonacea this we have done not required let it be okay so the next thing we'll discuss here that like we have generally it is we have not discussed the general trends some compounds halides hydrides okay oxides the you know acidity of oxides reaction towards water all these things we have discussed inert bare effect okay now there are few compounds which is important here to understand few reactions into that that we'll discuss and then you can follow NCRT actually okay the first compound you write down that is of you know these elements are you write down heading you write down poly halogen compounds few compounds we'll discuss and the heading you write down poly halogen compounds the first compound in this write down dichloromethane dichloromethane which we also call it as methylene chloride methylene chloride what is the chemical formula for this can you tell me methylene chloride what is the chemical formula CH2Cl2 correct dry chloromethane okay you see it is prepared by direct chlorination of methane and we have done this in organic Cl2 H nu right and then with Cl2 H nu we'll get CH2 Cl2 CH2 Cl2 the another method of preparation is what when chloroform write down we can also prepare it by the reaction of chloroform with metal and acid reduction of chloroform chloroform with metal and acid which is nothing but ZN plus HCl metal and acid we use what is the formula of chloroform do you know the formula of chloroform what is the formula chloroform is CHCl3 okay CHCl3 so when you do this reaction CHCl3 reduction ZN and HCl so it forms CH2Cl2 plus HCl this is the two preparation method of dichloromethane we have which is not that much important what is the use of this it is used as a solvent inert solvent we have already seen this okay inert solvent it is we can also use this as paint remover paint remover metal cleaning metal cleaning and finishing solvent finishing solvent manufacturing drug there also we can use this as a solvent manufacturing drug this is actually harmful for human also right because it harms the central nervous system right few things i'll just tell you just listen to me on exposure of CH2 Cl2 in air it leads to slightly impaired hearing and vision okay so that's a no harmful effect we have on human because of this you can have nausea dizziness numbness numbness in the fingers actually right direct contact with the skin it causes burning sensation and mild redness of the skin will be there if a direct contact with eye it will burn your cornea okay so it is very harmful actually right so we always use this whenever use this in laboratory we take a lot of you know measures it can possible see it depends like the exposure to what extent you are in you know influence of these things if it is little bit you will have slightly you know burning sensation and all but if it can burn right and if you have exposed to it to a very large extent then it may knock people out it's not a big deal right depends on what extent or what amount it is there depends on that okay so these are the few you know uses and and what we say the harmful effects we have which is actually you know using school exam botism right on uses and harmful effects or like that okay how it is harmful to human this kind of questions for one or two months usually they ask that's why i've given you this in jay they don't ask all this question okay so the next compound you write down is trichloromethane trichloromethane trichloromethane is chcl3 which is chloroform right now it is used in the manufacturing of it is used in the manufacturing of freon refrigerant what is the refrigerant it is used in the manufacturing of freon refrigerant freon refrigerant which was like it has f22 and the molecular formula is c2f2 cl4 this is also the same thing it caused dizziness headache right if you have exposure to this to a large extent it may cause damage to liver right kidneys it is also widely used in anesthetic like an anesthesia for an anesthetic purpose we use this as an anesthesia because of its toxic in nature it is toxic in nature right but since it is toxic so nowadays we don't use this as an anesthetic it is again how do we manufacture this it is again manufactured by the chlorination of methane right so write down the single one line here it is manufactured by the chlorination of ethane chlorination of ethane when it reacts with oxygen in presence of air in presence of light when it reacts with oxygen in presence of light it forms phosphine gas for seen gas for example you see chcl3 when it reacts with o2 in presence of light it forms phosphine which is cocl2 plus hcl this is phosphine g e n e one more point to write down when phosphine reacts with ethanol when phosphine reacts with ethanol it converts into diethylcarbonate it converts into diethylcarbonate which is harmless so phosphine is this two c2h5 OH HCl and HCl goes out so two moles of HCl goes out C double bond O and this will join okay you see this H and this CL goes out so it is joined with C2H5O C double bond O O C2H5 plus two moles of HCl we get here so this phosphine gas it is actually toxic in nature so when it reacts with ethanol it forms harmless diethyl ketone this is again one reaction we have write down it can also be prepared by hydrolysis of chloral hydrolysis of hydrolysis of chloral by COH whole twice it can also be prepared by the hydrolysis of chloral by COH whole twice so you see what is chloral here suppose we have ethanol CS3CHO when it reacts with CL2 in presence of COH whole twice chlorination then it forms CL3CCHO plus three moles of HCl so all these chlorine atom knocks out these hydrogen atom here and forms HCl just a second okay I'll tell you what is the use for phosphine right this we call it as chloral right now when this chloral is allowed to react with COH whole twice which is nothing but this like this if I write down plus we have CL3CCHO and we are taking two moles of this here so CL3CCHO two molecules we have here right so the product we get here is two molecules of CHCl3 plus HCOO whole twice CA so here what happens this H combines with this CCL3 and knocks out as CHCl3 this is how we prepare chloroform right now like you said what is the use of phosphine okay phosphine actually used to prepare this COH whole twice with removal of CL2 you see here CAO CL2 I'll write down this reaction which is probably this this is phosphine and when it is react with water and is put into water it forms slag lime which is CAOH whole twice and chlorine evolves here chlorine gas right which we further use here chlorine gas we further use here with ethanol for the preparation of chloroform further if you react this with water you'll get phosphine again few points write down here like it is few points write down quickly it is a sweet smelling colorless liquid it is a sweet smelling colorless liquid which is immiscible with water and miscible with organic solvent immiscible in water and miscible in organic solvent next line it is slowly oxidized by it is slowly oxidized by air it is slowly oxidized by air in presence of in presence of light in presence of light to a poisonous gas in braggartite right on phosphine to a poisonous gas in braggartite right on phosphine hence it is stored in colored bottles hence it is stored in colored bottles which is completely filled which is completely filled so that air is kept out the bottle must be completely filled so that air is kept out one important reaction of this i'll give you one already we have done that is idoform reduced with silver it gives you acetylene two moles of idoform is used see phosphine is a you know toxic gas okay so like you know the chemical warfare if you see you must have heard that in you know somewhere in iraq or syria russia has used some chemical weapon you must have heard that in the news yes this all these things that i have given you now it is for chloroform c h cl 3 not for fasting have you heard this that russia has used some chemical weapons against syria right which was not actually right it was just you know just as an allegation on russia that that he has used it is not we are not very sure that he has used it or not actually okay but the point is what is that chemical weapons chemical weapons are you know are those kind of weapons that we have which when you explode it some chemical reaction takes place and it releases a very toxic gas which actually gives you know some skin sensation some burning and some you know business or or you know some kind of nausea you'll get okay or even if it is more toxic and if someone in health it will die also so that since fasting is also a toxic gas so we can use this into the chemical weapons that's that's that's the thing it's right chemical warfare we use it okay chloroform also we use but it depends again right you know when the reaction takes place so these kind of toxic gases we can always use in chemical warfare for you know chemical weapons that's true right basically all those gases which are you know harmful for human okay those gases we can use and there are possibilities that with few reactions this can give even more toxic gases so those kind of reaction we use to you know we make them happen in chemical weapons so this is a thing right so so one reaction that you have already seen when iidoform reacts with silver it gives you acetylene right in preparation of alkyne we have done that another reaction you see here so in case of like for instead of iidoform we can also use chloroform over there you'll get agCl another reaction you see here if this chloroform CSCl3 is allowed to react with HNO nitrous acid it gives you Cl3NO2 plus H2O right this we call it as chloropikrin PIC RIN chloropikrin which is used as tear gas which is used as tear gas so this is a few compounds also we have discussed i like you must go through with NCRT first of all all the things you have studied from NCRT and like i haven't discussed about glass okay different types of glasses that you must go through with NCRT only composition things you have to memorize about glass you must study okay and some behavior anomalous behavior of carbon behavior of carbon basically NCRT you have to go through from beginning to end okay and few more compounds are given in NCRT which you can go through so that that may help you in the exam okay the board exam that you have but this is a glass thing i have seen few questions on to this they ask some parax glass and all some companies types of glasses okay you just can go through and there are probably few structures of the compounds of silicon also it is given if it is not you let it be but you just go through with that okay so this is it we are done with this one more thing i forgot to tell you you have to go through with allotrops of carbon also diamond graphite no buckyballs phylidines all those c60 it is given in NCRT okay so that much is enough like if i if i give you now i'll just dictate your theory so i am not giving you that because it is given in NCRT you can go through with that okay so allotrops of carbon is also important understood we'll take a break now okay i'm tired of contain Islam is speaking in right so i'll take a break now 10 minutes break we'll take so it's already 6 10 we'll start at 6 20 or 6 12 something like that 6 22 yes we'll take a break and then we'll start okay then we'll discuss geolites also okay we'll take a break now we'll start in 10 12 minutes


Miguel Keith is an interesting and versatile ship. If you bring it, we can operate it. For Exercise Balacatan 22, Miguel Keith had an integral part. We had air operations with HMLA 369, conducting air ops with the Philippines. And then additionally, we had the maritime portion, which had us operating with Ashland and the Philippine ship Tarlak conducting some maritime operations off the coast. Miguel Keith is a floating flight deck and mission deck. Our primary focus is air operations, boat operations, special operations. We're designed to support different forces. Miguel Keith can operate anywhere, anytime.


This paper reviews several indices commonly used to analyze the structure of a mega-region, such as weighted degree centrality, hub and authority score, and S-score decomposition. It then applies these indices to the case of Guangdong Province, China, to explore its city hierarchy and spatial structure. The results show that Guangzhou and Shenzhen have the highest node degrees and strength of mobility flows, while the Guangzhou-Dongguan-Shenzhen corridor has been identified as the most connected region by the hub and authority score. Additionally, the comparison between the three indices reveals that each index has its own advantages and disadvantages, thus it is necessary to select the appropriate one according to the study context. This article was authored by Yang Yang, Ji Yu, Run Sha, Yang Zhuang, and others.


What's going on everyone Sam here with late in sports cards. We are ripping 2022 Panini origins football hobby 8 box half case break number 37 pick your team style Gonna read off the list of names and teams Adam L with the Texans Chance H Jags Eagles and Lions Corey W. Chiefs Dolphins Derek G bangles Derek you Seahawks Devon M with the Vikings Greg B Browns Titans James B Packers Jason O with the Broncos G lun J Raiders John H Rams John M Steelers John L with the Ravens Joseph a Giants Kevin O Colts Martin W football team Robert s Panthers Thank You Robert Robert a with the Bucks Ronnie Y Falcons Shane D. Bill's Chargers Thomas R with the Jets Tim B Patriots Todd C Bears Tyler F Cowboys Niners and Tyler K with the Saints. It's a good luck here everybody Let's get going. Let me get tick tock set up And then we'll get ripping on this Here we go. Got some origins. Let's do it. See what we can get out of here See a nice blank slate. I'm just gonna blank slate in a while Sean's been hiding a while we've got Trevor Lawrence to 99 Trevor and Mark Andrews the 299 this I guess is for the top seat in the West right now this game Brandon cooks and Breece Hall nice Breece Hall right there variation looks Got Rashad penny 10 out of 25 three-color patch. There we go Derek with the Seahawks John Dotson on the receiving stars four out of 25 going to the football team of the Commanders It's gonna be Martin W. There you go Martin nice short print John Dotson on and Alec Pierce rookie Jersey Auto for the Colts If you have to eat DeAndre Hopkins for the Cardinals and DK Mecca after 99 See how Bass and Hassan Haskins rookie. What just marinate. Yeah, I know There's a Alec Pierce two out of 99 for the Colts We've got Hassan Haskins there you go for the Titans 80 out of 99 there we go Tennessee I think that's Greg B right there. They go Greg and Sameer White rookie at Jersey Auto for the Raiders From there am I gonna eat that Wendy's burger in the fridge? How long has it been in there for probably not There's no gravy in there, I don't know the gravy's Patrick Mahomes the 75 gravy and orange Justin Fields to 199. Oh, that's so gross Terry McLaurin Christian Watson rookie, we've got George Pickens 158 out of 199 Right Kenneth Walker nice one there there you go again Derek with the Seahawks For us through the gravy thing out Yeah, we got redemption of Damian Pierce rookie jumbo patch autographs read don't add them with the Texans I thought it just walked out of here Wouldn't be surprised Also for us I have a new I have a new funny thing. Yeah, Texans. I have a new funny thing if we pull the player You're gonna have to you have to listen in because it really drives Sean Got a Darren Waller to 199 The Andre Swift to 299 base David Montgomery and Drake London on the rookie auto Or not rookie auto just a rookie There's Sam Howell to 199 Got a Alec Pierce 98 out of 99 that's going to the Colts on-card rookie auto And Kyle Hamilton rookie jumbo Jersey autographs for the Ravens and grads Baltimore Who's it kind of Ravens I've never wanted to pull this guy more in my life Monro St. Brown 49 out of 50 and Mark Andrews to 199 Dallas Goddard rookie Johan Dotson commanders We've got Coral and Sutton 89 out of 99 by a George Pickens going to the Steelers on-card rookie auto not numbered and Tyrion Davis price rookie Jersey Otto for the Niners also not numbered we have left on this next one We've got just four to go guys Falcons Panthers Seahawks and Buccaneers Who likes to walk out walk out of here I had to lock the door Knocked on in the middle of the break you guys walk the door Yeah, I got you, baby. That's your baby. I got you, baby Okay Um, I don't know how much we have origins for right now They don't sell about packs Keenan Allen to 199 and Chris Godd went to 299 Awesome Echler Skymore rookie Nice one here going to the Broncos. That's gonna be four out of ten. Javante Williams Nice one there for the Broncos Javante We've got a breeze all on card rookie auto for the Jets Dobbs 40 out of 99 Packers Congrats Packers Leonard Fournette to 199 Elijah Morta 299 I have no idea Zack Wilson, there's a Malik Willis variation rookie. We've got a Chris Olave 41 out of 99 three-color patch That is a New Orleans sink That's nice James Cook 20 out of 25 on the gold ink. There you go. Bills. That's pretty sick There we go. That's sick. That's sick Congrats Bills and then on the back breeze all 60 out of 75 three-colored RPA on the orange Nice one there. Last box. Good luck. That's right Not the not for sale None of these are for sale. This is a group break. We got a booklet. Yes. We got our booklet We've got our booklet booklet alert Yandre Hopkins to 299 Adam Thielen to 199. That was got her Got Eli Mitchell to 99. That's going to the Niners. That's gonna be Carson Strong rookie jersey auto 21 out of 49. This is gonna be so sick. It's like Juan Thorin We've got going to the Bills a cookbook, but that's a one-of-one laundry tag laundry tag Let's go Congrats Shane One of the last teams were taken right there, too. That was like our last six teams taken There's a snowman for his moon sending us the snowman go. Wow a cookbook Ho-ho man. Oh boy. That's dope.  This is the the cookbook right here I'm just gonna take a pic of that too. Do a quick recap here We've got Tyquan Thornton Patriots Eli Mitchell Niners Chris Olave Saints Givante Williams Broncos Corlyn Sutton Broncos. That's Sam Howell commanders George Pickens Steelers Alec Pierce Colts Rashad Penny Seahawks Carson Strong Eagles Resolve Jets James another James Cook to there he is. There's Shane There you go, and you got this one too Shane the gold ink to 25 Brie Saul Jets Romeo Dobbs Packers Tyrion Davis Price Niners George Pickens Steelers Alec Pierce Colts Kenneth Walker Seahawks Hassan Haskins Titans Zemir White Raiders Alec Pierce Colts Johan Dotson for the commanders that is a Damian Pierce Texans Kyle Hamilton Ravens and Once again the James Cook So gorgeous that'll do it for the break guys. Thanks again for the fill next up. We have another half case of origins


J-P-L-L-O! The Jello Program starring Jack Benny with Mary Livingston, Phil Harris, Kenny Baker, and yours truly, Don Wilson. The Orchestra opens a program with San Francisco. Ladies and gentlemen, there are all sorts of quiz programs on the air nowadays. So tonight, I'm going to hold one. Are you ready? OK. There is one word in the English language which stands for the following. Amazingly quick and easy to prepare. Delightfully inexpensive. Lovely to look at with six glowing colors. Filled with delicious extra-rich fruit flavor. Swell-eating. Now, what's the one little word that means all of those things? Yes, sir, you've guessed it, Jello. America's favorite gelatin desserts. Easy to make while you do is add hot water and chill until firm. Economical. One package costs only a few cents and serves the average family generously. Beautiful for those six gay colors are as cheerful as spring sunshine. And the best tasting dessert you can serve to your family. For Jello brings you wonderful extra-rich fruit flavor that's as delicious as the real ripe fruit itself. So look for the big red letters on the box. They spell Jello. San Francisco played by the orchestra. And now, ladies and gentlemen, last Sunday night we brought you a man who thought he was going to win the Motion Picture Academy Award this year, and he didn't. I was robbed. So tonight, we bring you the same man who thinks he's going to win it next year, Jack Benny. Jello again, this is Jack Benny, the optimist talking. And Don, weren't you surprised when you picked up the papers Friday morning and found out I wasn't on that list of winners? Well, frankly, Jack, I wasn't. Oh, well, I was just checking. Phil, weren't you surprised that I wasn't on that list? Yes and no. What do you mean yes and no? Yes, we have no bananas, and no, I wasn't surprised. I ought to have my head examined. I've been doing comedy for 15 years, and I fall for a yes and no. Anyway, you fellas can believe it or not, but I wasn't a bit envious about Spencer Tracy winning the award last Thursday. In fact, when they handed Tracy that gold statue, I was positively thrilled. Wasn't I merry? Yes, sir. Jack sat right down and cheered. Sit down. What was he standing up for? The darn fool thought that we're going to give it to him. Yeah, gosh, I was so embarrassed. But Jack, what in the world made you think you were in line for the award anyway? Well, Don, I had every reason to suspect it, because all through the dinner, people kept looking at me and whispering and then looking at me again. In fact, I was the center of attraction. Well, no wonder your toupee was favoring one ear. Now, Mary, I was not wearing a toupee. You weren't? No, it just so happened that before the banquet, I had my hair cut by a barber with one short leg. Yeah. So don't make up lies. Well, let me tell you something, Jack. You should be tickled at that that you didn't win the Academy Award. Oh, I should. Yes, your head's big enough now. Oh, so besides all my other faults, I've got a big head too. But just to show you how wrong you are, Mr. Harris, I only wear a 6th and 7th hat. Don't I, Mary? Yeah, way up on top. Well, let's not dwell on that subject any longer. The Academy Award is over. To tell you the truth, I was only kidding. I never expected to win it anyway. Not much. That's all you were thinking of. Who, me? Yes, when the fellow next to you passed you the salt, you said, I accept this on behalf of Parama. All right, you little snoop. Now, let's forget it. Say, Don, we've got quite a long play to do tonight. Is everybody here? I think so. Oh, by the way, where's Kenny? I'll go out and look for him. Wait a minute. I'll go along with you. Why? Why, Kenny, I didn't see you. Why didn't you join the conversation? Oh, I don't know, Jack. I just felt kind of blue about you not winning the Academy Award last Thursday. Oh, don't let it bother you, Kenny. It's not that serious. I didn't win it this year. So what? So hurry up. You're not a kid anymore. Now, just don't worry about it. As a matter of fact, I've got the whole thing figured out. The reason I didn't get the award is because I don't make enough picture. You make enough for me. Is that so? Well, it might interest you to know that I'm dickering with Paramount to play the lead in Cecil B. DeMille's Union Pacific. Well, stop dickering. They previewed it last night. Well, it was some railroad story anyway. Now, look, fellas, we've got more important things to take care of tonight. And now that we're all here, I guess we can get started. So tonight, ladies and gentlemen, as I announced last week, the Benny Bargain basement players will present their version of Daryl Evzanik's 20th Century Fox production, that screen classic, that gripping melodrama, that sensational hunk of film, Jesse James. I said Jesse James.  Sorry, I was in another world. Well, stay in this one, please. Now, in this epic, I will play the part of Jesse that fearless, daring, courageous Desperado was portrayed on the screen by Tyrone Power. And Phil, you're going to play the part of Bar-She, the villain. Why can't I be the hero? I'm prettier than you are. No, Phil, it's already decided.  Quiet, this isn't a beauty contest, Miss Encino. I'm going to be Jesse James. And Mary, you're going to be my sweetheart, Zarelda. Your sweetheart? Yes, we fall in love, get married, live together 20 years, and then I get shot. Why did she wait so long?  She doesn't shoot me, Phil. I'm shot by a dirty, low-down trader, a man that hates me. I bet he sells toothpaste on Wednesday night. I know who you're referring to, Kenny, and I don't want that man's name mentioned on this program. It takes all the class out of it. Now, let's see. Who are you talking about, Jack? I'm referring to an ex-juggler who talks through his nose, wraps his wallet and barbed wire, and is as yellow as those corny shoes he wears. That's the gentleman I'm discussing. Incidentally, Don, did you ever notice that pained expression on his face? Yes, Jack, he always seems to be in agony. Why is that? Well, he's worn those same shoes since he was 12 years old, and in the meantime, his feet have grown. Now, getting back to our play. The same shoes, eh? I don't see I can stand it. Well, every two or three years, he has the buttons moved over. Now, getting back to our play. Jack, when Alan takes off his shoes at night, how does he get them back on in the morning? Who said he takes them all? His toes haven't wiggled since the Chicago fire. Now, getting back to our play, Mary, you're my sweetheart, fills the villain. Say, Jack, am I going to be in it?  Fine casting. Well, that's your part, Kenny, you're going to build a railroad all the way from St. Louis to California. He couldn't build one around a Christmas tree. Quiet. And, Don, you have a very important part in this play, too. Really? Yes, you're going to be a crowd of people that I hold up on the train. You've got to be a Scotchman, a Southerner, an Irishman, a Greek, and a Swede. Do you think you can do it? Oh, sure, I'm quite versatile. OK, let's hear you try it. Now, remember, Don, a Scotchman, a Southerner, an Irishman, a Greek, and a Swede.  Ladies and gentlemen, as long as it's a brow-bricked, moon-lick, nick-to-nick, why don't you all go down to your little old neighborhood grocery store and say, sure, and begata, it's a package of jello I'm a wanton. Very good. Push them off six flavors, strawberry, rosemary, cherries, orange, lemon, and lime, by yump and yemeny. Say, that was all right, Don. Yes, sir. You likey very much? All right, Don, don't overjure it. Now, let's see. Oh, yes, my mother, Mrs. James, will be played by, where is that lady I hired for the part? Here I am, Mr. Benny. Now, Mrs. Felton, do you think you can handle the part of my mother? I think so. I have three lovely air deals. You'll do. Yes. Well, I think we're all set now, so our play folks will go on immediately after Kenny's song. Take it, Kenny. Hey, Buck, ain't I going to be in this? Oh, yes, Andy, of course. I forgot all about you. I was sleeping over in the corner.  You're going to play my brother, one of the James boys. OK, Buck. What are you laughing at? I was just thinking of you at the Academy banquet last Thursday night. Well, what about it?  I didn't stick my tongue out at Tracy. My doctor was sitting across the room, and he wanted to know how I was feeling.  Andy, go over in the corner and get dressed for our play. Sing, Kenny. Mary, put on your hoop skirt and sunbond, will you? This night was made for free. This night will be as fair as the night of night. This night will be. Because this night will be my souvenir sung by Kenny Baker. And now, ladies and gentlemen, for the main event of the evening, our dramatic highlight, Jesse. How was my song, Jack? Very good, Kenny. James. The year is 1867 in the thriving little town of I'm from Missouri. There is much excitement as the St. Louis Midland Railroad has invaded this peaceful hamlet, determined to buy for a song the property of the simple, hearty pioneers. As the scene opens, we take you to the farm of Mrs. James, located on the outskirts of I'm from. There, we find her two sons, Jesse and Juicy, at work in the barn. Juicy is gathering the eggs while Jesse is milking the cow. Curtain, music. Boom, boom, boom, boom, boom, boom, boom, boom, boom, boom, boom, boom, boom, boom, boom. Steady, Lulu. That's it. Steady now. Don't kick the pail. One, two. Well, well, I guess that's about all. Oh, sorry, old girl. Three quarts as darn good, Lulu. Tonight, I'll take you down to the gym theater to see Ferdinand the Bull. Control yourself, Lulu. Now it's your turn, Petunia. Oh, Jesse? Yes, Juicy? How much milk did you get? I got three quarts from Lulu, two from Cleopatra, and Petunia's gauge says full. How are you making out with the eggs? Fine, Jesse. I got 14 and a half. You got half an egg? Yep, I'm afraid Geraldine ain't trying. Darn it, I told her 1,000 times to concentrate. Watch your tail, Petunia. I'm slap happy now. Be careful. Hello, Zirelda. Hi, Juicy. Juicy, Jesse. Here I am, gal, behind the cow. Oh, hello, Jesse. Say, when did you grow the mustache? Mustache nothing. Petunia, pull in your tail. Say, you're looking mighty sweet, Zirelda, but your bustle's kind of flat, ain't it? Yeah, darn that billy goat of yours. Oh, he's just being playful. He wasn't mad at you. He is now. I braided his horns. Well, it serves him right. Here's a stool, Zirelda. It's kind of hard, but sit down. No, thanks. My feet don't hurt. Well, you know best. Hey, Jesse, you ought to do something about that darn goat. He's getting too familiar. He is, eh? Yep, I've been over to tie my shoelace yesterday. And the next thing I knew, I was tracking. Time to straighten you out, eh? Say, Jesse, I came down here to tell you that those railroad men are up at the house talking to your ma again. They are, eh? Well, they're a waste in time. We ain't going to sell our farm, not for any $0.07 an acre. How much would that amount, too? Well, $0.35 at $0.07. Let's see, $0.07 times five is, uh, well, $0.07 times five. That's, uh, how much is that, you see? Don't ask me. You went nearer to school than I did. Zirelda, how much is $0.35 at $0.07 an acre? Well, let's see, $0.07 times five. I tried that. That ain't no good. I'd like to find out, though. Why don't you count it up on your fingers? Shucks. I only got 10, and I know it's more than that. Well, anyway, they're offering enough.  Come on, Zirelda. Better be careful, Jesse. They mean business, and they're armed to the teeth. Well, I am armed, too. How you fix for teeth?  Come on, gal, let's go. Will you need me, Jesse? No, juicy. I can handle those varmints myself. Let's go, Zirelda. I'll take care of them highbinders, or my name ain't Jesse James. Now listen, Mrs. James. I'm tired of all this hamin' and hawing. I'm going to give you just one minute to sign this paper. Yeah, one minute. Now, hold on, gentlemen. Hold on, nothing. We're aiming to run a railroad through this land, and there's nothing going to stop us. Yeah, nothing. But gentlemen, this little farm is all we have. Fakes no difference. The railroad's going through. Yeah, through. Boy, I'm all in. Now, here's the paper, Mrs. James. Sign right here. Very well, gentlemen. I suppose I must. Hold on, them all. Drop that quill. I'll listen here, Barshee. I told you yesterday to stay off of this land. Well, supposing I don't. If you don't, I'll take this thick shooter of mine.  So get going.  A deed? What's that?  Hey, it easy. That's Mr. McCoy, president of the St. Louis Midland Railroad. President of the railroad, eh? That's me. Boop, boop.  Lay off of him, James. Listen, Barshee, I had enough of you.  Yeah, skunk. Say, who are you with, anyway? I don't know, but my heart belongs to Daddy. Fine president. Now get out of here, Barshee, before I lose my temper, which is easily misplaced. Be careful, son. Be careful.  Oh, Jesse, you and I are going to get married in two weeks, so please don't fight with him. I must, gal. You don't want to marry a weak, spineless power, do you? That's right. Let's call the whole thing off. But Zarelda, come on, come on. Quit your stalling. Are you going to sign this paper or not? No, I'm not. And reach me a shoot, Nair and Barshee. Who, me? Yes, you. Not me. Come on, Barshee. I'll give you one more chance. Are you getting out of here or not? I'm not a budget. What are you going to do about it? This is what I'm going to do. Take that. Oh, yeah, take that. All right, now you take that. You guys sure can take it. Well, Barshee, if you had enough, you keep out of this, Ma. Well, how about it, Barshee? Are you willing to call it quits? Yeah, I'll call it quits. But you ain't heard the last of me, Jesse James. We're going to build a railroad through this farm and we're starting tomorrow. A pretty speech, Mr. Barshee. But it ain't going to happen here. You find out, goodbye. So long. Lift me up, Ma. I'm full of lead. In the fact one, act two will follow immediately after a short rendition by Professor Harris and his silver cornet band. Play, Barshee. A few popular selections played by Professor Harris and his band. And now for the second act of our play, Jesse James. Take it, Mr. Wilson. Two years later, the James family has stubbornly refused to give up their land and we find that the railroad company has built its tracks not only on the farm, but right through the middle of the James house. So let us tune in on this happy little group. Yes, Ma. Breakfast is ready. I'm coming. Me too. What are we having, Ma? Orange juice, ham, and eggs, wheat, cakes, apple pie, and cinders. Cinders, we've been getting a lot of them ever since those during trains have been running through the house. Last night when I was sound asleep, a cattle train came through and woke me up.   Well, don't complain. On Mother's Day, they may throw candy at you. Dog gone that railroad. I was eating a piece of toast the other morning and the conductor reached out and punched me and it. It sure is a nuisance.  Just a minute, Ma. I'm going in the bathroom and wash my hands. All right, son. Be careful crossing the track. Ah, well. Dog gone. I was marooned in there three hours yesterday on account of a slow freight. Be right back, Ma. Hey, Ma, is the back door open? Yes. Well, open the front one quick. Here comes the 715. Hey, that train was really flying this morning. Yeah, it must have been doing at least 60 through the living room. Yes, sir, read.  Here's your orange juice, Jesse. I don't want any more. Give them a juice to juice. I'm going to dig into these ham and eggs. Boy, this sure looks good. Yes, see how long are you going to keep on being so stubborn? Why don't we move to another farm where it's peaceful and quiet? Listen, Ma, what's the use of moping? These railroads won't last to just a fad. That's all. That's what they said about underwear, and now everybody's wearing it. All but me, I'm a holdout. Say, Ma, these wheat cakes are sure humdingers. How do you make them? I take two hums and three dingers and stir them up. Well, they're mighty good. You just wait till tonight, son. I got a treat in store for you. We're going to have some jello. Jello, what's that? Well, it's a new fangled dessert. Something new, eh? Yes, but I think you'll be crazy about it. No kidding. It's economical, easy to make, and comes in six delicious flavors. Strawberry, raspberry, cherry, orange, lemon, and lime. But you've got to insist on the genuine jello and look for the big red letters on the box. Well, I'm sure looking forward to it. Say, Jesse, look who's coming down the track. Oh, yes. Hello, Zirelda. Hi, boys. Hello, Mrs. James. Hello, Zirelda. Sit down on that switch and have some breakfast. Oh, no, the last time I sat down there, it threw me. Well, Zirelda's been two years now that you promised to marry me, and we still ain't hitched.  I can't stand all these trains going through. Why not, gal? There ain't no privacy. Them traveling sales can keep winking back at me. Well, I can't help it, Zirelda. I love you, but my mind's made up, and I ain't a mover. All right, then, Jesse, you win. I'll marry you. Now you're talking, Zirelda, and we'll be very happy here. Zirelda, get off the track. Here comes the 810 right on schedule. Good heavens, what's that? Another train, and it's coming the other way. Oh, my goodness, there's only one track. There'll be a wreck. Yeah, here they come. Not Jesse! Jump, Juicy! Look out, ma'am! Look out, Zirelda! Here it comes! Darn it, my wheat cage is ruined. Are you all right, ma'am? Yeah, Juicy and Zirelda. Here I am. Well, this is the last straw. Come on, everybody. We're a mover. This will be continued next Sunday night. What's the next step in the career of Jesse James? Will he be coming out, ma'am? Will he marry Zirelda? Will they have any children? Tune in next Sunday night and find out. Play, then. You know, I think that a plain meal really demands an extra delicious dessert, and a fancy meal deserves one. Well, here's the perfect dessert for either one. It's the new Jell-O Butterscotch pudding, and really it is the most tempting treat you've tried and many a long day. Remember when you were a youngster and used to bake for a Butterscotch candy? Well, Jell-O Butterscotch pudding has the same old-fashioned goodness, the same true Butterscotch flavor that's rich and mellow. And it has a smooth, lovely color like golden taffy that makes your mouth just watered to look at it. Your family will love it, and they'll love Jell-O Vanilla pudding, too, creamy and delicate. And Jell-O Chocolate pudding, rich and smooth and real chocolatey. All three new Jell-O Puttings are made with fine, wholesome ingredients. And all three are quick and easy to prepare, for there's only a few minutes cooking required. You'll find the simple directions on every package, and it's a handy idea to buy three packages at a time. So ask your grocer tomorrow for Jell-O Butterscotch, Vanilla, and Chocolate Putting, the real homemade kind. The last number of the 22nd program in the new Jell-O series, and we will be with you again next Sunday night at the same time when we will continue with the adventures of Jesse James. Well, Mary, I got to run along now. Carmichael, my polar bear, has a bad cold. He has. Yes, he's acting so ornery. I think I'll give him a hot lemonade. You better give it to him through a long straw. That's an idea. Good night, folks. The filmmaker appears on the Jell-O program through courtesy of Mervyn Leroy Productions. This is the national broadcast in California.


Hey y'all, what's up? My name is Snollie, welcome to a new vlog. Today I'm doing something super fun that has been on my bucket list ever since I moved to Austin and that is going to the Fredericksburg wineries. We're celebrating one of my friend's birthdays today, so we got a bus, we're doing the whole thing. I think we're going to three wineries, so I thought it'd be fun to vlog. I've actually never been to a winery really before. Well, I went with my parents, but that was like when I was really young, so now I get to join them. We're at the house pre-gaming. We got some bread over here. Allie's big four 24. I'm looking gorgeous, this is. We're at Sonora, right, Molina? Anyone? Is this Sonora? Where are we? I'm just showing you. Do we know where we are, Jackie? We're at Sonora winery and it's going to be so good. We're going to have a tasting. This is beautiful. It really is. It's really nice. I'm going to get married. Oh, that would be so cute. Let's do it. This is stunning. The flowers and everything. We're praying that the rain doesn't come down on us. We are those people on our land. This is so nice. The wine barn. Even the back part of it is beautiful. It's in your... Signore vineyard. At least, yeah. So, we're going to do this one. The momma said there would be days like this. He recommended it to me because I like sweet wines, so I think we're going to split that. I'm also an influencer, but I do all mine right here. Yeah? Oh, you influenced me to get the wine, right? Just for getting started. Thank you. What about the Rochambe? Also. She's so good. Jackie said it was Sonora vineyards. Okay, I said it was Signore, and then he said it's... It's Ignore. But like, so, we're here. Okay, okay, same thing. What's this market over here? Did you go in?  Oh, that's cute. They have like home goods. It's cute. Believing, Signore vineyards. How drunk are you? One to 10. Five. I would say five. Five. I would say like maybe even four. And I like drink a lot of champagne, you know? Like, why? Why does this happen to me? Five. This is our next location. This is what it's called. All stuff. We're going to go find out if we can order food because I think this is the... I think... Which is where we can get food and we're hungry. Is it a brewery or a winery? We don't know. We'll find out. I got a pretzel, a splig with live. It was like seven bucks, and then the spree sling was like 13. And then the last place, we split a bottle. So it was like, I want to say like 36. Maybe even cheaper. And we split it between five people. So it was a little cheaper than buying it by the glass.  So you guys are interested in coming to Fredericksburg. And that's how we did it.   So we're gonna get food. And it's... It doesn't did it? Yeah, time to nap on the bus. It literally is. It's four o'clock and we're ready. We've been baking in the sun and we're ready for a nap. So... It's time, time. We're gonna go back to Austin. We're on our 70s bus. That's how I want to be right now. It's almost seven PM and we got home around like 5.30, I think. The bus ride was like an hour and 30 minutes. So on the way, it kind of felt like a long time, but on the way back, you know, your girl was passed out. I definitely took a nap and that made it go a lot faster, but I'm so glad I got to experience like the wineries. I definitely think the first one was my favorite, the Signor vineyards. The second one we went to was more like a beer garden vibe. It was definitely a lot more beer and they had like a pretzel and a sausage you could choose from.  And then the third one, I didn't get anything out, but I tried Jackie's. I think it was like peach frozen sangria and it was pretty good, but it was definitely more of like a touristy place. It was definitely more lively, actually had live music. So it was more like fun, dancy vibes. Personally, I just like the first one better. So if I went back, I'd probably really only stick with that one or maybe like check if there's other like really chill wineries like that kind of thing, but I'm glad we got to like get a taste for them all. I actually switched out my camera this morning because I wanted something more compact to bring it my purse. And so I was vlogging with my old camera, which is a Sony a5 100. So that's why the quality is kind of like changed a little bit, but I kind of missed that camera. It's just, you know, there's so many great things about this camera that I'm using, which is the Sony a7 III. Right now my apartment is glowing and it makes me so sad because obviously we're leaving here in like a month or so and I'm gonna keep you guys updated with the apartment stuff. I'll probably post an update in the next week or so when things are official, but I did order some swatches online because I just kind of want to revamp and get some new furniture. I feel like I haven't really treated myself in a while. I was literally telling Ryan that I wanted to go on vacation to like Cancun and in all inclusive and just chill for a week on the beach, but then it's hard to like spend your money on a vacation when you're so used to like your parents paying for it when you grew up, you know what I mean? Like it's just a weird thing. Like they haven't really paid for a vacation in a while.  I feel like I'd rather just have something that I could hold on to for a while, you know? Part of me is like, okay, a vacation would be really nice. And then the other part of me is like, okay, but this piece of furniture is gonna be in my house like all the time, you know? Comment down below what you guys feel. Are you more of the experienced person?  But anyway, so I wanted to show you guys just like the swatches that I got because I freaking love my couch, like I adore it and it still is still pretty good, but I kind of want to switch it up, you know? So let's see what I got. All right, so I got some swatches from Crate & Barrel first. Okay, so this is like an interesting texture. I mean, it looks like similar to my couch right now. And then I got these two. It's hard because you can't really tell. This is more like a velvet almost, which I don't really like that. But I do like a more white color because our couch right now is an off white and I'll link it down below if you guys are interested. There's really nothing wrong with our couch. The best reason I want to look into a new couch is because the place we want to move into like this specific unit, this couch is like left hand-facing, but if we brought this couch into the new place, then it would be blocking like the door to go outside.  When I was again, Pinterest for apartment decor, I found this company called Made in Home and I'm just gonna post a picture of this chair. Please let me know what you guys think because I think this might be my treat to myself. I just don't know. It is pretty freaking expensive for a chair. I won't even lie to you guys, but it's so beautiful. I feel like this could be like our accent piece. Like we'll get a sofa and then this chair. I've noticed that I really like just single chairs, especially when I'm editing, like when I was home, we have these like orange or Kleiner kind of chairs and they're just like so perfect to just sit and edit and like work and like really sit up, you know, instead of like being on the couch, like really just wanting to lay down if that makes sense. Okay, these are the swatches for this chair. So we have this one. I don't know if you can really even see it. I'm not sure if it's focusing. This one is that trendy fabric. No, wait, is it? Yeah. Okay, so you know those CB2 chairs that literally every influencer has? It's in this texture called Bouclei and it kind of looks like your couch is kind of already pilling, which is very interesting because my couch is pilling right now and you know, I don't love the look of it. And then we have just like this normal, just white, white, good texture. I'm so bad at this, what texture is this? I don't even, okay, performance, texture, linen. And you know what's great about all of the couches that I was looking at is that they are performance textured so they don't really stain easily. They're like dirt resistant and everything like that. So that is another reason why I kind of want to give a new couch. But again, there's like nothing wrong with my couch. It's just that the layout of the new apartment that we might be moving into just doesn't fit it. So all good. I'm excited. But also like getting new furniture takes forever. So that's why I'm trying to like, you know, figure out where we're living. So I can order it ASAP because a lot of couches are like, yeah, it'll get there in 22 weeks. Like what the hell, like 22 weeks? That's like almost half of my lease, you know? Like who knows if we're gonna stay there another year. But yeah, so that is the updates for that. It's just so bright in my apartment right now. Like seriously, I'm gonna be really, really sad at this unit that we get doesn't have good lighting like this, but kind of a feeling it's not gonna have this grade of lighting because there's so many windows in here, you know? But like I said, I'm gonna keep you guys updated and I'm really excited to be filming like moving content and just like apartment content. And since I'm doing like more furniture shopping and just like kind of revamping like decor videos and everything like that. Because in the guest room, my filming room or whatever, that has like all of my college dorm decor. So I haven't really decorated except for my bedroom and it was pretty minimal. Like I got a lot off of Facebook Marketplace. We got our headboard custom actually and I'll show you guys because I actually get some comments on this headboard which is so awesome because I love it so much. This headboard is custom. So I literally just showed the guy the design I wanted. It's kind of this like hair and bone design. And I think it's so pretty. He did it with post oak wood. And then I got these frames, I think from like Target or something and I printed those prints out like FedEx. I'm not even sure, something like that. And then these are actually from Facebook Marketplace. And when I moved them in here, I wanna say I saw an opal house sticker on them. So they're from Target maybe. And then these lamps are from Target too. Since we were just talking about our couch, I'll just show you guys really quick if you haven't seen it already. Seriously, it is so comfortable. I feel like people always ask me is it actually comfortable? Yes, like we always fall asleep on it. Me and Ryan can fit. Me and Ryan can cuddle on it. It doesn't look super huge. It doesn't look super deep, which I do wanna get like a deeper couch. Well, I'm getting a new couch, but it is still pretty deep for like a couch to size. It's 110 inches that way. And I think we're gonna look into getting something tiny bit smaller, just so it can really fit in our new unit. But like I said, I'm not really even sure what's going on with that. And then here's our coffee table. On Facebook Marketplace. If you guys are furnishing a home or apartment, highly recommended to check Facebook Marketplace because you never know what you can find. Can we just appreciate the lighting in here? Oh my God. I mean, it's really not always like this. It's just a really sunny day and it has been gloomy for a while. So it sucks, but I also need to do a lot of organization like in this pantry and just like in that back room in my closet. So I got a lot to do before we even really think about moving. Good morning, y'all. It is Sunday and the room is kind of a mess because I'm about to film a Princess Polly Hall. Last night, Ryan actually came home really late. Like his flight got delayed a little bit. I picked him up at 10 and now he's out playing golf. I was supposed to have a grad session this morning, but I canceled it because it was set. It was gonna rain. Last night when I looked, it was 80% this morning and I don't think it rained. I really don't think it rained at all.   I can't get over it because literally like this is my busiest season and I'm just like so stressed out trying to like reschedule people. And I really tried to give myself like the weekend for like a me time kind of thing, but now I'm gonna have to reschedule people to the weekends and it's just a little crazy. So I'm really, really hoping that everything clears up this week because our friends are coming in town on Thursday. So I don't want to have to like reschedule some grads to like the time that they're here. I mean, I can always do it like really early in the morning when they're sleeping or something, but I don't really want to because that's kind of like my vacation too. So we'll see about that. But yeah, I just combed my hair with like the wand, like the OG wand that you get at the mall or whatever. Actually, I got mine from Bombay hair, but literally the same thing, like the black just like stick. And I really like how it turned out. I feel like my hair is gonna last a little bit longer instead of doing those like beachy waves with like the actual iron clamp, if that makes sense. So I wanted to just like switch it up and see what it would look like. And I think I like this. I have so many random curlers that I get into phases of using. So maybe this will be a new phase, but I do need to clean up this little room and I'm just getting a little stressed, not gonna lie because I feel like I need to sell a shitload of stuff that is in this room and just like in our apartment in general. Like I have a guitar that I literally haven't used since, like really used since like maybe high school and it's just chilling in this room and I need to get rid of it because I'm not really gonna play guitar ever again. I don't think like it was nice to have because at one point Ryan wanted to like learn how to play and you know, I like to, you know, strum on it sometimes, but it's just not a thing that I do often at all. Like I don't touch it for months. So I need to get rid of that. I need to get rid of like so much of this decor. I think I said this yesterday when I was talking about the couch, but I want to just like revamp my filming room, the guest room and just get rid of like all this decor. I mean, I love the shelves though. I'll show you guys, hold on, you're on my tripod. This is the decor I'm talking about. I am obsessed with those shelves. So I might not sell those, but just like kind of do some different decor on the shelves because I feel like that's just too kitty and I'm an adult now and I'm just like kind of over the stars and I might keep that base because I feel like that's cute. I'm also thinking I'm gonna get rid of that chair which was like the best freaking Facebook marketplace find. I really need to do like a tech talk on everything I got off of Facebook marketplace. So basically it was just this ratan, is that what it's called? Ratan chair. And this is what it looks like. And then I just throw this little blanket on top to make it look a little bit better because this like cushion over here is just not cute at all. So that's what I do for that and it doesn't look bad. And then for my guest office room thing, whatever, I think I'm gonna get rid of the bed and just get like a pullout couch because people don't really even visit us that often. So it's like, you know, I'd rather have this space to like film and do my stuff and just work in the office. It's almost 12.30 so I'm gonna really quickly film this princess polyhull. And then the girl that I was supposed to photograph this morning, I think we're just gonna start at three because on the radar it says it's not gonna rain from like three to five. This radar thing has been really helping me out if you guys didn't know like on the weather channel app, you can press this little button and you can like see ahead of time. So the green is like the rain and when you go further, there's no rain in Austin. So I've been really like banking on that to tell me what the heck is up because, oh, okay, now the hourly changed and it's not gonna rain but it's so annoying and I'm really sad because it looks like in my rain like next week in winter, my friends are in town and I just like don't love when like people come to see a city and then the city's like not at its best. I mean, obviously you can't change anything but for example, the first time I went to Nashville was on New Year's Eve and it was like not the best weather and like things were closed on New Year's Day. So that was on me just like not going at the right time but I'm actually going to a bachelor party in September to Nashville. So hopefully I'll get a redo then but I also wanted to do a boat day with them and I was like, you know, getting all my friends to come and everything like that. And then I was just like honestly, like I think we should not do it because the weather looked so iffy. It was like 50% then it's now at 30 for next Saturday but I was just like, eh, I don't want it to like be like 70 degrees and we're on a bone and we're freezing in this miserable and we can't swim. You know, I feel like I'd rather just like push it back till later in the summer. Anyways, okay, I'm going to stop rambling need to film this haul. I think I'm going to do it like a different way than usual because usually I just set up my tripod and like show you guys my outfit but I really like, I did like an Abercrombie like my must haves from Abercrombie and I just filmed it in my mirror like a little OTD kind of video. So I think I'm going to do it that way. I feel like it's easier for me to talk that way. It just like feels more natural. So I think I'm going to do that and let's get this stuff filmed. I need some energy really quickly. I need to put on some more lip stuff. I've been really liking lip oils recently. This one's actually from Merit and it's a newer brand at Sephora. Just going to put this on top of my lipstick. This is in the color on natural or on natural roll. I don't know. It's really pretty though. It feels so good. Okay. I swear. Now I'm ready. I just finished filming my princess Polly haul and I made it in time to have like a chill like 30 minutes before I have to go to the graduate. I think I should leave it like 230 but guess what? The sky is blue. The sky is blue. There's no rain. Just want to thank God and let's keep it this way. That's all I have to say. Like the weather. Oh my God. The weather. Like let's see if it changed. If any day this week is not raining on the forecast. Again, nevermind. Tomorrow is 60, Tuesday is 50. Wednesday is 50. Thursday is 50. Friday is 50. You get the gist. Oh my God. Next, not this coming Tuesday but the next Tuesday is like the only sunny day. Hopefully it like just clears up because I'm just like really worried about the grads because this weekend is their graduation at UT. So I want them to have their photos like by graduation or like a little after. I don't want to have to reschedule them to after graduation because I know they're trying to get their photos like ASAP and I feel that. I did want to edit a video but I feel like 30 minutes isn't enough time but honestly, I should just edit it because I feel like whenever Ryan's here I just want to chill.  So yesterday I was supposed to edit but I was like, okay, this is so bad and me if I like even touch my computer.  I feel like that was like a big problem of mine is just like I never knew when to stop.  But yeah, I need to edit that video. I actually have a lot of content to edit. I have my hair video because I just got my hair redone. I went to my friend, Mariana, she killed it. I'm actually going to take her maternity photos in June and it's going to be epic. I just have a feeling because she's extra and I freaking love it. I think I'm going to change into something more like athletic so I can like be ready to sweat. It kind of sucks because I put on makeup and they did my hair. So hopefully I don't really sweat that much but I have a feeling it's going to be a little bit humid outside. So I'm just going to prepare myself to sweat. I just took Sophie out and that's why I'm out of breath but I changed into a set active set. Kind of wanted to be a little bit more colorful. It's a Sunday. The sun's out. We need to celebrate with some color but I'm just packing a little camera bag. I actually got this one on Amazon. It's pretty little and I have a bigger one like a think tank one that's like really strong and fits like way more lenses. But for graduate, I really only use just two lenses.  Every time I shoot for like hours, my back gets so like burnt out or like, I don't know. It just feels like I'm about to have a back spasm at the end of the day and it does not feel good. So the less amount of weight on my shoulders and like back, the better. And that's actually why I didn't really get into wedding photography while I tried to get into it and then the few times I did it, it was just really painful for me. Like a long eight hour day, nine hour day sometimes and you'd be standing up on your feet the whole day and you would have like a big chunky camera and like a couple lenses on you. It was just a lot.  So you couldn't really drink on a Friday because you didn't want to be hungover on a Saturday for the whole wedding. And then your whole Sunday is just like recovering because it was just a long day on Saturday. So I just didn't want like all my weekends to be taken up since Ryan works a normal job and like we do fun things on the weekends and I really look forward to them. So I don't want to like live my life dreading the weekends if that makes sense, especially because I already have a part-time job in the week. So that would be like just a lot of work. So I'm really glad I didn't make the decision not to photograph weddings anymore. I mean, at first I thought it was going to be like the most stressful thing to photograph but it really wasn't that bad. Like that part of it wasn't that bad and it was kind of fun but just like the long days I cannot do that. Like I'm just not physically made for that. So I'm just going to be sticking to like shorter sessions like grad sessions, obviously engagement sessions. I love to do couples, families and all of that. I literally do everything except weddings and I also do videography too and I just chose to do or try out photography and not do like videography for weddings because I already knew that like the gimbal really makes my back hurt. So I definitely knew I couldn't do that but I just thought photography would be different but it's kind of not. It's kind of the same in terms of like physical work kind of. I mean, you're still getting like different angles. You're like moving your body around a lot. So I just like wasn't used to it and I really need to look into getting a back brace for longer shoots because today I have like a two hour shoot and I think like a couple of days this week or like in the past I've had like a two hour shoot that I don't want to have our shoot and then like a one hour like it's a lot. It's about to get a little bit hotter here so I'm going to be pretty much dead but I'm going to go ahead over to UT's campus for this graduate and I'm hoping we're going to get tacos tonight because I feel like every time Ryan is away I always crave tacos from our taco truck lost troncos on the east side and I try to like wait for him to come home so that we can get them together because I would think that he would want them. I feel like we're always craving tacos when we get back from a trip. So I'm hoping we're going to get that for dinner. It's basically a Sunday tradition at this point but I will keep you guys updated after my grad shoot. It's 5.30. I just got done with my grad session and now I'm actually meeting Annie at Gloria's which is one of my favorite places to eat. I actually went here and vlogged it literally right before I left for my work trip. Ryan went to play golf with her fiance and apparently they ended up at a pub.  So maybe they can just meet us at Gloria's. We're going to get some chips and salsa and it's going to be a good day because we're going to sit out on the patio and it's just so nice outside.


I want to ask one question about my country Pakistan. What do you think about the political situation of the Pakistan? Well, my first question as a journalist would be to ask, what do you think of the political situation in Pakistan? Particle situation in Pakistan. Yet now, I think it will be better because Nawashi will again gain in the power and he will be next Prime Minister of the Pakistan. I think, inshallah, it will be very, very good for Pakistan, inshallah.


Well, about the only place in the world where beans will bring people together is Pequot Lakes. Our Anthony Scott has more on Bean Hole Day. Beans were the topic of discussion today as part of the 80th Bean Hole Day. It's a festival that's unique to Pequot Lakes. It is the only place that we know of that has a festival where you bury beans in the ground and giant kettles. Bean Hole Day is a two-day festival that first involves burying the beans, letting them cook overnight, and then serving them the day after, something that started as a way to honor the local farmers. It started back in the 1930s as one pot of beans, a very small pot, and it was done after the fall harvest of the farmers, and it was the bankers and businessmen getting together to do a potluck of beans and everything else that was brought together for food as a thank, thanking the farmers for their harvest. Since then, it has blossomed into an event that has gathered worldwide attention with guests coming from Florida, California, and even Brazil. I'm actually living in LA, came out, we rented a cabin up here as a family of bean hole days. Before the beans could be enjoyed, a king and queen had to be announced for their work in helping with this year's festival. The Central Bean Company has been donating the beans for many, many years, so we selected a person from Central Bean Company to do that. Lakes Gas donates the propane gas every year, so we selected a person from there. After the bean king and queen gave the beans their seal of approval, it was finally time for the public to try out the beans. The beans are the best they've ever been. They're delicious. Fantastic. Amazing beans. I think this is fit, I think. Many volunteers were needed to help prepare the beans, businesses sponsored and gave each kettle a name, and it's a festival that the locals are happy to call their own. I think everyone who's from here has pride in this festival and the people who come to visit love it too. Reporting from Pequaw Lakes, Anthony Scott, Lakeland News. The beans were free to try, and Pequaw Lakes has no plans to stop the 80-year-old tradition. If you enjoyed this segment of Lakeland News, please consider making a tax-deductible contribution to Lakeland PBS.