What's the word y'all? I cannot believe I'm filming this video and I'm smiling because my team is living to see another day. I'm gonna be honest with you. And at first court I completely accepted the fact that the season was over. I watched this team for 82 games and I've seen them go down that big in the first half and not have a lot of fight to come back and win a game. They did it today. Oh boy, they did it today. And we're looking forward to Miami on Friday, but the only problem with that is our best player is not coming to Miami with us, man. Demarda Rose's daughter has to go back to school and she was one of the main reasons why we won tonight, man. So I'm a little bit scared because we need that screaming in the background. Now for real, overall it was just a very weird experience because we all were watching this game and we heard the screams in the background, but nobody knew exactly who it was coming from. It reminded me of, and if you watched baseball during the WBC, it reminded me of the first game with the WBC. There was this guy and I think he was representing Cuba where he was in the back with a blow horn for the entire game. And all the Twitter was like, somebody kick that man out. And that's what it felt like until we found out that as Demarda Rose was gone and they're like, there's a literal 0% chance to get kicked out of the game. Demarda Rose, the all-time leader, scored a French side system. Nah. People say, oh, she was a civilian, then maybe it don't matter. First of all, no, I don't think you would because it's a sporting event. People are yelling and screaming all the time, but because it's against your team, you think that that person had been kicked out? Either way, she was very, very critical in today's win. And Pascal Siakam came to the podium afterwards and he mentioned that he didn't even recognize that that was going on. And that's probably some truth. I'm assuming that because there's so much going on within the game that these players don't even think about the outside noise, but whether they heard it or not, they shot 50% from the free throw line and they should have won this game. This is an epic kid laugh for the Toronto Raptors. There's no way around it. They were up by 19 points. If you're just looking at the box score without looking at the final score, this is a game that you win. And I'll explain why. Now, neither these two teams are good three-point shooting teams. That's a fact. But in this game, the Toronto Raptors made four more threes on better efficiency. Again, they attempted 14, 14 more free throws. They got eight more offensive boards, 14 more boards in general. They won the assist battle and they lost by four points. Usually, this big of discrepancy on the free throw shooting and on the glass is enough to tell you what team won if you can't look at the final score, but they melted down. They did. Zach Levin and third quarter turned into Michael Jeffrey. And I'm just feeling good because I didn't have a lot of hope. It's a funny thing because the playing is basically two fan bases that have been put through the ringer. Well, I've watched all 82 games of the Bulls this season. Toronto Raptors fans has watched all 82 games of their favorite team. They're telling me that the Bulls are going to win because their team is trash. I'm telling them that the Raptors are going to win because our teams are trash. And it's just two fan bases that are like done with their favorite team, but still rooting for them going against each other. And the reason why I wasn't very optimistic about my team is not just because, again, I've watched them 82 times and I've seen that in a lot of cases, they don't come out with a lot of fight. DeMarco Rose has struggled against the Raptors all season long. In some of those games, Zach Levin didn't play at all. And I think that mattered. You know, Zach Levin, of course, again, almost had 40 tonight. But DeMarco Rose and Ed struggled. And the games that we played against them, they had the size and the rebounding to win majority of those games. And again, they did that today. They beat us on offensive glass. They beat us on the defensive glass. And I just thought with the length and athleticism across the board, that they were going to win this. And in the first quarter, this is how it is to be a Bulls fan. And I'm sure some of y'all can relate with y'all favorite teams. We're like, you watched the first half of the first quarter about your team. And because it's not going good, you kind of detach yourself from the results. You know what I'm saying? I was already thinking about, okay, what does offseason look like for us, man? Because let's be real. I was making videos about the Bulls making trades this February. They made no trades whatsoever. So I'm thinking about this offseason, like, okay, how can we make some money here? Do we trade this player there? And then in the second half, again, Zach Levin really turned it up. And I was happy to see, even though Patrick Williams ended with only 10 points and 33% shooting, I think he was critical today. And again, the shots were not falling, but the defense was there.  But his feel in this game felt very, and I mean, very, very impactful. Me and the guys on our podcast put together all NBA and all of the awards, whatever. And I think all of us at Alice Caruso on the first team, I remember looking through some comments and they're like, what are y'all talking about? Alice Caruso first team, if you watch this game, you recognize all of that. Yeah, it's going, he's always going to get a couple of fouls. And you're like, come on, Alex. But like, for the most part, he was all over the place. And that's saying something because in the very early in this game, Pascal Siakam was giving him the work.  I mean, they started to Martin Rosen, he's the four, but like they're a small team. Martin Rosen was, is a shooting guard in most cases, but the way the NBA is going, he can slad over to the forward in occasions. Alice Caruso had the Pascal Siakam assignment and Pascal was giving that man the work. But eventually we figured it out. And that's not something Billy has done notoriously, you know, making adjustments at halftime and the team having the fight. And maybe it is that the back is against the wall. If we do not win this game, then we do not play another game until October next year or October in a couple of months. I'm just happy that we won. Now, what happens on Friday against Miami? I don't know. But even if we win that one, what happens against the Bucks? We know what's going to happen. But it's cool to roof your favorite team. Even if you know that the outcome is going to be losing. You know, we know at 90% of us, 95% of us are going to walk out this season with an error on our record. At the end, it's going to end in an error. Most of some of y'all already got that. But it's about the time you have. And I was really, really having a lot of fun down the stretch in this game. So shout out to the Marta Brosnan and his family for coming out and helping us win. And Friday should be fun, bro. Friday should be fun. Jimmy Butler always try to get his little revenge against Chicago after they trade him away. And they don't look good either. So it's about to be another battle of two fan bases looking at each other saying, our team sucks. Y'all got this.  Y'all got this. And we'll see what team ultimately ends up winning.  Every single one of these games has been down to the wire. Some of them, of course, way uglier than others. But we got OKC versus the Pelicans. And yeah, we could spend a lot of time talking about the Toronto Raptors and what their office is like considering it feels like there's a ceiling on where they are right now. Or we can't talk about the Pelicans and Zion and all of this stuff now that their season is over. But we'll say those for another video. I would rather just talk about this individual game before getting into offseason stuff and team building and things like that. Of course, another back and forth game, back and forth game. The Pelicans had a lot of momentum when they decided to finally give Yonah's valence to Mr. Ball. But unfortunately, he gets injured. Like, he gets injured and they have to send him for the majority of the rest of the fourth quarter. And they finally put him back in the game. And immediately he gets one more bucket. I mean, it ended up with 18 rebounds. And I just keep thinking to myself, if the Thunder win against the Timberwolves, I'm not rooting for anybody. But I do want to say my enjoyment factor when watching the Thunder is up here and with the Wolves is like down here. I'm beyond a switcher. Who would I rather see in the playoff series versus the Nuggets? I have an idea as far as the enjoyment factor. But again, I see Big Val end up with 16 and 18. I'm like, what is Yonah's going to do to this team if they see each other? And at least the Timberwolves have some big bodies to throw at Yonah's, even if some of them aren't great defenders or some of them aren't as great a defender as they used to be. I'm already looking too far ahead. Let's stick to this series or this game. I don't want to put it on one person because obviously no one person loses a basketball game. I down the stretch in the last two games, whether it been the last game of the regular season against the Timberwolves to put the Pelicans in this spot. In this game, down the stretch season, McCullum had been pretty dread for what he's lost. Tough floater down the stretch, heavily contested. It's one of those shots that if it goes in, you don't care that it was a bad shot, but since it missed, it's like, why did we do this? Why did we not get a better opportunity? Especially because Brandon Ingram was starting to find things. Once he fouled on that last shot with Ludoar was contesting. I don't know. The last two minute report will probably tell you a little something deeper than what I can know. But it felt like down the stretch CJ wasn't as impactful or as good as we know he normally can be. Again, we've seen him in these high-leveraged games before. Game seven versus the Denver Nuggets a few years ago when he was the best player on the court. On court ahead, David Lillard and Nicola Jokic on it, you know what I'm saying? But then his last two games were the most important games of the entire season. And down the stretch, he just didn't look good. And was it him slipping or was it the her pass? I don't really know, but overall it was a very anticlimactic ending to this back and forth game where it ends in that turnover off the end bound. I mean, the previous play where it's a full court heave to Brandon Ingram and he catches and shoots. I mean, that's stuff that coaches dream about when they throw in the full court heaves. You know what I'm saying? And they have another opportunity to go tie it up or win the game and they go out of bounds. I'm like, again, I'm neutral in here, but I want to see more craziness. I'm like, oh, no. Again, probably the second best story of the season, only behind the Sacramento Kings being damn good. Is this is this Thunder team, man? I had always said the youngest team involved, but I forgot that Eric Gordon got traded away from the Houston Rockets. So the Houston Rockets at the end of the season technically had the youngest team in basketball, but the OKC Thunder are there as well. And here they are one game away from having to play off birth again. This is going to be a tough game, I think, just like this one was. But to foreshade to have the lowest amount of first half points of the season and still end up with his occasional 31 in some time. Bro, in that third quarter, there was tough bucket after tough bucket after tough bucket. I'm like, man, there's no way he could keep going. And then in the last 30 seconds of the game, he is his leaner going away from the basket to basically like ridiculous, bro. Seven points in the first quarter. You know, the defense was there on both sides. You know what I'm saying? Lou Dorre, again, he had 20 in the first half. He mentioned his names. My fault, Lou. 20 in the first half, good defense around the way. And the Herb Jones, like this was a battle that was for me as a nerd and a defensive guy to see Lou Dorre and to see Herb both have crazy assignments. This was something I was looking forward to and neither of them disappointed, at least on the defensive side. But offense, great offense is going to win. So eventually Brandon Negro got it going. And eventually St. Alexander got it going. And it's like, like in a lot of these cases, Lou and Herb are playing good D. But the offense is just going to do it. So he ends up having his game and hitting big shots. But like, Giddy, man, Giddy on our pot a little while ago, we were trying to redraft that draft. And I was making a case for Giddy to go even higher than where he was drafted in real life. Because even though he doesn't do this on a nightly basis, obviously if he was after the 30 points, we've been talking about just getting a lot more. But this is the type of performances I think he can have more regularly throughout the course of his career. And I really enjoy him watching him because he's at his own pace. And there are there are few people in the NBA that can get it done at the speed that he does. But you have people like James Harden, where if he's in gear one, he's hard to stop. If he's a gear two, he's hard to stop. But if he's in gear three, he's super hard to stop. This man Giddy has one gear. And if he can refine on that gear and make it perfect, I'm just, I'm just saying it's not going to be many people that can stop. He got to the basket a lot this game. Of course, the pass is always going to be there. I mean, this is something he's been doing. That's one of the main reasons he got drafted that high. But he's just getting better and better and better with time. Though our boy Jay Dove didn't have a great game, he had one bucket in this one. It might have been early fourth quarter. Like a screen came. He split the double team on the screen with a little like, threw the ball in front of him, went between the screen and get it. And then with a tough lay on the left, like, come on, bro. Basket, tough basket after tough basket. And he was hooping in D-Rose once. Oh, classics.  Classics.  But if you got a narrow foot, classics, bro. Any of them in the yellow colorway. This was a great game, bro. I'm a little bit afraid about the next playing games because I don't think they're going to live up to this level of intensity and this level of greatness. But if they do, again, Adam Silver, bro. Adam Silver did it again. Because the play-in has, every season had given us a few good games. Every game they had nothing to do with the Charlotte Hornets has been a good game in the play-in. And it's continued to be the case. So let me know what you think about these games. Who do you got? OKC versus Minnesota. Chicago versus Miami. And yeah, maybe tomorrow we'll talk about the future of some of these teams that got 11.


Hello, welcome to the course on quantum chemistry of atoms and molecules. Before getting into the course contents and what we will discuss and what the textbooks will be, let me first put Reddit where it is too. This course has developed over many years. We teach most of this as our first year course which is now called CH107 in IIT Bombay and many people have contributed to this course. The basic slides here are actually made by Professor Nareesh Patwari and others like Professor Shashidhar, Professor Tembe, Professor Ruchi Anand, Professor Rajasthi Chakravarty, Professor Arindam Chaudhary and Professor Sandipkar have contributed immensely over the times for development of this course content. Let me start with expression of gratitude for all of them.  For this course to start with we are going to use material from textbooks on physical chemistry by PW Atkins and that by Macquarie and Simon. Later on as we go a little deeper into the course we are going to use quantum chemistry by Piller and quantum chemistry by Macquarie. Occasionally one might have to refer to physical chemistry by Ira Levine. In case we refer to any other book I will give you the specific reference. Now what is this course all about? This course is about something that has been asked for a very very long time but before getting there one question that especially chemistry students often ask when they are offered a course like this is do I need to know math? And the answer is yes because after all quantum chemistry, quantum mechanics these are based on mathematics. Mathematics is the backbone of science. But then the mathematics that we need is not something that is of very high level. Mostly class 11, 12 level mathematics is sufficient and for those who may not have exposure to even that level of mathematics we will develop tools as we go along. But to give you a very brief idea we will need to know algebra and we will need to know little bit of operator algebra. As you will see we are going to work with linear operators all the time. They are the main tool of quantum mechanics. And then we will need a little bit of trigonometry we will need you to know what is sin kx cos kx e to the power ikx what is the relationship between them. We will need to do basic differentiation at times we will need to do partial differentiation little bit of integration not much and quantum mechanics is actually based or at least the version of quantum mechanics that we are going to talk about is based on a differential equation. So differential equation is something that will be very very useful for us. But then once again for those who may not have too much of preparation in mathematics there is nothing to worry this course is really meant for at least at the beginning for first year BSc students and whatever mathematics is required one can learn or we are going to develop as we go along. Now let us come to the question that we had proposed a couple of minutes ago. What is the course about? The course is about addressing a question that mankind has asked over millennia throughout civilizations. And the question is something that even a child asks and that is what is everything made up of? What am I made up of?  And humankind over hundreds and thousands of years have tried to find answer to this very basic question in different ways. In ancient India the answer was everything is made up of five elements Panchabhoot as we call them. In ancient China it was believed that everything is made up of two elements Yin and Yang. What is Yin and Yang? Two opposing forces up and down man and woman good and bad and so on and so forth. What they believed is that synthesis or coming together of two opposing forces makes everything up. Now that is rather philosophical way of looking at things. But if you think even in our modern way five elements and two elements are things that make sense. But then our knowledge has progressed from there and we know that it is not really five or two as far as chemistry is concerned there are many elements. There are many substances which are elemental and they come together to form more complicated compounds that forms the basis of chemistry. There are many elements and at this stage we all know that they can be arranged in a periodic table and one can even predict properties of elements that by looking at this periodic table. There was a point of time when properties or even undiscovered elements have been predicted using this periodic table. Now that is one side of the story. The second part of the story is that people asked what happens in fact this answer of five elements and two elements came from there. Okay we have a chemical element we have hydrogen let us say or we have oxygen or we have nitrogen. We start breaking them up or maybe it is easier to understand if I take a solid. Let us say I have elemental sodium. I start cutting up this piece of sodium into smaller and smaller pieces and let us say that I have the power of going down to as small size as possible. What will happen? Do I keep going until there is nothing or do I stop at some level? Do I stop at some particle that cannot be divided further? Answer to this question was also there in ancient Indian science. Kanath for example had proposed that there is smallest indivisible form of element which in ancient India in Sanskrit was called kana. Later on in more modern times they were called atoms and we have all studied Dalton's Atomic Theory when we were in class 7, 8 something. So atoms are supposed to be the smallest entity beyond which you cannot divide further that was the understanding until Dalton's time. But then towards the end of 19th century new discoveries were made as we know cathode rays and anode rays were discovered and they were found to be charged and in fact cathode rays and anode rays were found to be oppositely charged. Later on neutrons were discovered. So the understanding that developed was that atoms are not the smallest indivisible units after all. One could divide atoms and one could get what are called subatomic particles. At that time this concept of electron proton later on neutron came into being. And then the question that arose is that inside an atom how are these subatomic particles arranged? And there were several disparate attempts to explain what the arrangement within an atom is. One of these models that survive for some time was by Sir J. J. Thomson. It is called the Plum pudding model. The Thomson proposed that this is your atom in this we have this delocalized charge of one kind and you have the opposite charge embedded in it like seeds of pumpkin or like plum in plum cake. But of course this could not have been a realistic model because what this model proposes is that you have positively charged and negatively charged particles in close contact. And all of us know what happens if we take a copper wire and touch one end to the positive end of a cell and touch another end to the negative end. There is shorting and there is annihilation. So if you have this positively charged and negatively charged particles in close proximity then they are going to annihilate each other. So this model did not survive the test of time. The first plausible model of atom was proposed by Ernest Rutherford. And the way Rutherford model came into being is rather interesting and instructive for students and teachers alike. So the way it happened is that Rutherford was already a well-known scientist and in his lab came this new student named Marsden. And in any lab when a new student comes we usually give them experiments not with the purpose of making a new discovery but with the purpose of getting the acquainted with how to do experiments in the lab. So Rutherford gave similar such experiment to Marsden and the purpose was to get his fingers wet. Alpha particles were discovered by that time and it was known that they were highly energetic particles. So Rutherford handed Marsden a chamber of this kind and said that why do not you keep this alpha particle in the center and keep a gold foil and see how the alpha particles pass through the gold foil. Now while doing this experiment the idea was that a gold foil is something that is very thin. So if you shoot alpha particles that are highly energetic at the gold foil then everything is expected to go through. So Marsden's job was essentially to place a photographic plate as is shown in this cartoon he placed it all around and what he saw is that most of the alpha particles got through and that was evident in forming the spots on the photographic film in this region. Few of them got scattered to the right or to the left and most surprisingly one out of 20,000 turned right back almost 180 degrees almost reflected one out of 20,000. Herein lies the courage of Marsden more often than not when a student gets an unusual result like this and to say to point out how unusual this result is let me quote something that some well-known scientist had said at that point of time. It was said that it was almost as if you shot a cannon shell at a tissue paper and it came back and hit you that is how surprising the result is and then the number was 1 in 20,000. So it is it was Marsden courage to have not neglected this seemingly negligible result he walked up to Rutherford and reported what he saw that was his courage and it was Rutherford's greatness that he did not hand wave this new students results away saying it is just a freak observation Rutherford took it seriously and then after repeating the experiment many times and after putting in a lot of thought the model of Rutherford were proposed and that model was fashioned after the planetary model we all know that planets go around a star so Rutherford proposed that similarly what we have is the analogy to the star here is the positive charge and mass he said that first of all most of the atom is empty that is why most of the alpha particles go through straight and he said that since this 1 in 20,000 alpha particles actually turned back most of the mass and all of the positive charge is located in a central position like the star and then the electron is somewhere in the void outside and now the issue is that once again if you have a static nucleus with all the positive charge and you have a static electron with a negatively charge then the electron is going to go and follow the nucleus and is going to get annihilated there will be no charge anymore to account for that Rutherford proposed that like planets go around the sun the electrons are also going around the sun and the advantage of that is that the electrostatic attraction of the electron for the nucleus can be exactly offset by the centrifugal force that would act on an electron going around in a circular orbit so that was Rutherford's model so electrons going around but then this model had several shortcomings and the biggest shortcoming was that in classical physics it was known that a charge particle in motion is expected to emit its energy continually that gives rise to two problems one problem we are going to come to a little later first problem there is that if energy is emitted continually then you expect the emission spectrum of any element of compound to be continuous but it is not as we are going to show you one gets line spectra more important issue with this model is that if the electron keeps on losing its energy continually then what will happen is that continually it will get slowed down so centrifugal force will decrease electrostatic force remains the same so it will keep getting closer and closer and closer to the nucleus and is going to spiral into the nucleus and once again there is going to be annihilation and the time required for this spiraling can actually be calculated and it turns out to be about 10 to the power minus 12 second picosecond so this is the major problem that you do not get a stable atom if atoms live only for picosecond then it is impossible for me to complete this half an hour module because I not exist for more than a picosecond it is impossible for you to sit through this lecture because you would not exist for more than a picosecond so this is not a happy situation and obviously it cannot be correct but then there was no explanation in classical theory which could circumvent this problem so it required the courage and foresight of Niels Bohr to propose a model that was better than Rutherford model remember Bohr model is essentially Bohr model takes Rutherford model as a starting point it is not as if Rutherford model is completely thrown in the sea and Bohr model comes in it is not Bohr model also works with circular orbits the only difference is that Bohr remember this is a phenomenological model it is a model that was proposed to explain experimental results and this model involves the electron residing in certain orbits so what Bohr said essentially is that the electron can rotate in circular orbits only for certain values of radius well he put actually put it in a different way he said that only those orbits are allowed where m v r equal to n h by 2 pi angular momentum is quantized and it is an integral multiple of h by 2 pi of where h is Planck's constant what is Planck's constant we will come to that in a minute and from there we will come back to Bohr model well to get to Planck's constant and to understand this whole quantization business one needs to look back at the end of 19th century once again and that was the time when well shortly before that time everybody thought that whatever is to be discovered in physics is discovered because Newtonian model sort of explained everything in the macro scale and everything was known things sort of hunkidory however towards the end of 19th century indications started coming that when you try to go down to atomic or molecular level Newtonian mechanics does not really work all that well and there are many examples one example that we are not going to discuss in this course is Einstein's treatment of heat capacity we I am sure all of us have studied Dullong and Pettis treatment then when Einstein looked at it then again quantization had to be invoked we will not get into that we will try and restrict our discussion here to spectroscopy and to atomic structure molecular structure and so on so forth. So, one thing that we will refer to is once again something that has been introduced in class 11 physics black body radiation what is a black body a black body is something that absorbs all the energy that impinges on it and in an ideal black body what you have is you have an aperture through which the radiation can leak out a little bit. So, you heat the black body and you look at the radiation coming out of it that is seemingly very very simple experiment well seemingly simple but with profound implications as we will see. So, if one looks at the emission of the black body as a function of wavelength. So, if you plot intensity versus wavelength or distribution versus wavelength for example, then we get an emission spectrum and the emission spectrum of black body looks like this what you see here is emission spectra at different temperatures. So, first point to note is that this is all the spectra go through a maximum. Of course, as you heat as you increase the temperature the intensity becomes more and more and more because heating means you are supplying energy. So, more energy supplied to the body more it will limit if you do not supply any energy any energy if temperature is absolute zero or something you do not expect the black body to radiate anything because unless energy supplied what will it radiate. So, first point to note is spectra go through a maximum for every temperature there is a characteristic maximum characteristic wavelength or frequency where maximum distribution or maximum intensity is obtained. And then means displacement law once again I am sure all of us have studied in class 11 physics means displacement law says that this maximum moves to higher energies as the temperature is increased that is a mathematical relationship which is not really of relevance to us in this course. So, I am not going to write it means displacement law is what it is. Now, this is the experimental observation to explain this there are lot of attempt to come up with theoretical models that can explain why black body radiation goes through a maximum and why is it that goes that the maximum moves to higher frequencies at higher temperature numerous attempts were made using classical physics everything failed. So, we are going to discuss a model that came close but did not succeed finally and that model is proposed by Rayleigh and Jeans Lord Rayleigh and Sir John Jeans. So, what Rayleigh and Jeans did is that they considered this oscillation of electromagnetic field within the cavity of the black body. This oscillation can take place with several frequencies what they did is they did a classical mechanical treatment and came up with this kind of a law where D equal to rho d lambda rho is a proportionality constant rho is actually what is called density of states and is given by the formula in Rayleigh's model 8 pi kT divided by lambda to the power 4 D is the energy density in the wavelength range of lambda to lambda plus d lambda. Now, the problem is this this rho is what you have on the y axis of the experimental spectrum and if you look at the expression for rho it has lambda to the power 4 in the denominator. So, what happens at what happens as lambda becomes smaller and smaller rho becomes larger and larger and larger and larger and larger it does not go to a maximum. So, the problem is in using Rayleigh's model one can actually get a good match at longer wavelengths, but for shorter wavelengths the mismatch starts creeping in and it keeps getting larger and larger and larger as we go to smaller wavelengths that is higher energies and in the ultraviolet region there is a very big mismatch between the theoretical prediction of Rayleigh's model and the experimental observation this goes by the name of ultraviolet catastrophe it completely breaks down in the UV region. To address this problem Max Planck tried a different approach we are not going to do any of these derivations here because these derivations generally are done in quantum physics courses not very difficult if you go through any of basic physics or quantum chemistry quantum mechanics book one can understand without much difficulty because it is explained nicely. So, Max Planck came up with this distribution where rho is equal to 8 pi hc divided by lambda to the power 5 multiplied by e to the power hc by lambda kt minus 1 to arrive at this distribution he had to make an assumption he showed that this is only going to happen when energy is quantized e equal to n h nu where nu is the frequency of light h is a constant named after Planck and n is a whole number positive whole number 0 1 2 where did this quantization come from it was assumed so this is really one of the beginnings of quantum mechanics and the reason why Planck's distribution is a great thing is that well let us see what happens to it when we work in long wavelength regime for long wavelength one can assume that e to the power hc by lambda kt is going to be much smaller than 1 in that case one can write e to the power hc by lambda kt as 1 plus hc by lambda kt once again this is something that we learn in class 11 12 math so what happens what is there in the denominator the denominator we have this exponential term minus 1 so let us subtract 1 from both sides what do we get we get hc by lambda kt so this entire exponential term becomes hc by lambda kt you multiply it by lambda to the power 5 what do you get you get rho equal to 8 pi kt divided by lambda by lambda to the power 4 same expression as what we saw in Rayleigh's distribution and remember Rayleigh's distribution works well for long wavelength so in long wavelength Planck's distribution is the same as Rayleigh's distribution and things are good but more importantly at short wavelength e to the power hc by lambda kt has to be much much larger than 1 what happens then it is a large number so if you go to short enough wavelength then this denominator is going to be huge close to infinity and rho is going to become 0 so what I am what we are saying is that this Planck's distribution actually goes through a maximum and becomes 0 at very high frequency and you look at this distribution and the experimental spectrum at a given temperature they match perfectly that is why Planck's distribution is widely accepted and this attempt of Planck what was Planck's goal Planck's goal was simply to get a distribution that can explain blackbody radiation while doing so two important things came up first is we get to learn that at atomic and molecular level energy is quantized we get to know what Planck's constant is and as we will see over the course Planck's constant is a fundamental constant that we use all the time in quantum mechanics and the other important thing is an Indian scientist was SN Bose if you know this life story of SN Bose he was very good in mathematics and in his childhood he once scored 110 out of 100 because not only had he solved all the problems correctly he had solved them in many different ways and the teacher felt that he deserves more credit for that so solving a problem in many different ways was his forte and that is exactly what he did with Planck's derivation Bose tried to derive Planck's law in a different way and in doing so he arrived at something that gave rise to something that is much more profound and that is called Bose Einstein statistics as most of us would know Bose is the only Indian scientist after whom a fundamental class of particles is named bosons you have bosons and you have fermions so what we have discussed in this introductory module is the early days the early dawn of quantum mechanics where many discoveries were made great minds were sort of drooping in the dark and they were finding treasure that was yet unknown to humankind which we are going to have profound implication in the years to come so we stop here now and in the next module we are going to talk about Atomic Spectra


The following is a presentation of TFNN Trade what you see With Larry Pezzavento Call now toll free at 1-877-927-6648 or internationally at<PHONE_NUMBER> Now Larry Pezzavento Okay looking good Billy Ray feeling good Lewis our guest today will be Jim Bartolioni. He'll be on at 830 tomorrow We have Jeff huge alpha insights Wednesday. We have Shane Smollion Thursday and Friday are still open But I'm working on a couple of guests that might be able to join us I posted the chart of the Dax I posted the chart of the footsie both of those you can see in the den But we need to cover a few other things Beforehand what I've done is I posted into the room the video that I sent out on Sunday evening early To show what I thought was going to be the highs and the e-mini the Nasdaq and the S&P if you'll take a look at those You'll see that they all came within $500 and that's a total of all of them I mean that's a debt that Dow Jones was just with it I think within 10 points of the exact high as a matter of fact You know, we've been talking about that for a great deal of time here and we finally reached that level I'll just get this up here to put it up here today This is the Dow Jones industrial index itself and you'll notice here the number We were looking at was for a 35,000 913 and we actually hit 36,000 for a minute or two We backed off about 200 points of that but it doesn't that doesn't mean very much all of these things folks are just numbers They're that's all they are they help you control risk they help you to get into things also We were in we were talked about the gold market on Friday We had that beautiful pattern down there at the 19 excuse me 1773 level We got up to our profit objective today that made you know over a couple grand doesn't mean a whole lot But we'll keep an eye on maybe for future use when we get a little bit of a pullback We're going to be buying the gold Again, so that's the main thing right now folks. I want to take a minute or two to tell you a story You know, we hear a lot just give me I'm going to post this in here because this is right directly out of the Out of the newsletter this week, and I think it's an important story for me to tell you You know, it's nice when people talk about things that have happened in the past But when people talk to you about things in the future, that's the thing. It's important I met John James in about 16 years ago. He was living in Perth, Australia and We started to be we communicated back and forth. I went back to see him there he came here several times and He is a very smart fellow, but this is something that happened in October of 2017 John was trying to get me to do a service for cryptocurrencies, but at that time, you know, it was pretty tough go The Bitcoin was trading at 6,000 but here listen what this he says Here's what he said to me said if you think you missed the party on these crystal crypto currencies That hasn't even started John sent me down explained to me that block chains are Encapsulating layers engulfing the old Internet with a new smart layer that provides proof of ownership Like a Russian doll engulfed in a larger version of itself Think of the Internet as being engulfed by this new layer The world government know it's happening and big money know it's happening and big money is going to be moving in John said if you understand that then you're already way ahead of the game Why because that's what this business is about. It's about the construction of what boys and girls a metaverse And what did the Facebook just do changed their name to meta? It's a construction of a new virtual real estate It's going to be land grab and the vast majority of population are clueless Of what's going on? So this word metaverse is now coming into it The reason why I bring it to your attention now because you know We have a Bitcoin trading above 60,000 and we have it listed on the exchanges It's being quoted on Bloomberg CNBC Beijing China Hong Kong everywhere. So this is a live thing. This is not a bubble anymore folks If you think it's a bubble I can understand that I I'm very difficult to understand this stuff four years ago I I couldn't understand it. So I didn't want to get into it. I should have but I didn't but This is stuff is here today. So we'll start talking about more and more about it But it you know if it is the bubble it'll be the greatest one ever perpetrated on man, which it has possible to So we'll we'll take a quick look at that. So that's why it's so very important. He He believes that you know, these things are starting to looking at this You know see what we're looking at what was watching these things here Okay, let's talk about a couple of markets See where we were talking about if you remember last week. We were talking about Tesla that the important price on the Tesla was 11,000 1128 was the 1.618 expansion I've seen we've been above that were fact we're trading above it right now with another gap up But that is a major expansion number up in that area. So we had that one in our watch list also We were chatting with the gentleman. I believe he was from Becky somewhere with his stock which zs and that also If you'll notice here went back and made another new high at the 1.618 expansion up there at 320 It's down a couple dollars from that But that's the ones we were mentioning and then also we won we talk about all the time You of course is Apple because it trades so nicely and as you can see here from the chart here on Apple All we did on that Thursday before the earnings report You'll see or the day of the earnings report as we got up to that 153 level we're trying to get training around 159 now no big deal, but it did hit the exact You know 78% retracement So those are just a couple of the things that I'm looking at. I'm talking. I'm here. I'm hearing reports here about the Russell Making new highs that's certainly certainly a possibility once we got above I think 2315 it looked like it was going to go up now the S&P and some of these have already backed off about 30 handles from what the expected high was but that doesn't mean it can't go up and make another new high That's that's certainly possible To do that. So those were just a few of the things that I wanted to bring to your attention today Because they are very important, especially that part of the newsletter where John explained about metaverse You know four years ago before I didn't know what the word what it was until this past week when when they changed the name to to that and so That's it's an important basically what it is folks. It's data plus data plus data plus data plus data They're going to mind the heck out of it and the more data they have the more they have information on you the more They can push information your direction that they want to read and see and so We've got to be on our tolls to try to find out what is right and what is wrong And that's the the whole key to some of these things. We're looking at So that's primary what we're paying attention to the crude oil got right up into the zone We were looking at which was right up at the area of 24 84 I believe 84 70 was a 78% retracement. We're trading about 60 cents below that and A couple other ones that we were watching or we're doing okay. Also so we're going to be looking at a Another Hold on one second. I wanted to bring up the chart One of the futures that we're paying attention to because it's been in the news Recently and it's it's getting ready to reach reach some really big levels up here and let me get this up here to see here This is the this is December wheat folks. We'll be right back You might think that if you want to be successful at trading in the stock market You're going to need a crystal ball after all it's impossible to predict the future, right? Like any endeavor in life before you decide it's impossible get some advice from the experts You might find that it's not so impossible after all for daily market overviews that give you direction on the key indices Selective stocks and commodities Subscribe to the opening call newsletter at tfnn.com The opening call newsletter is written by Basil Chapman Creator of the trading methodology known as the Chapman wave the Chapman wave up-down sequence gives you an edge in Identifying price turns finding the peaks and valleys in stock prices get the opening call newsletter by Basil Chapman and your inbox Every day first time subscribers also get a 30-day money back guarantee if you're not satisfied Let us know and you'll get a full refund within 30 days of signing up tfnn.com educating investors What's separating you from the most successful men and women on Wall Street? That's right Information having all the information gives us the perspective We need to place the right trades at the right time The TAS profile scanner is the premier market profile base scanner powered by its acclaimed TAS proprietary algorithms This feature rich scanner instantly filters over 2,500 plus global financial markets such as stocks ETFs commodities futures and forex This powerful suite of tools Leverages instant trade filtering and strategy formulation to show you emerging trades Before they happen for a limited time You can save $100 off your first month by using the promo code upgrade and you still get a 30-day money back guarantee So you have nothing to risk Level the playing field with the TAS profile scanner which you can find under the services tab at tfnn.com Sign up today Sharpening your skills as an investor is like getting better at playing a musical instrument You have to practice sure, but you also need excellent instruction from experts at tfnn You'll get advice and guidance from the authority in technical market analysis And it's not just dry tedious text either tfnn airs live financial content streamed live on tfnn.com and tfnn's YouTube channel with Tiger TV live every market day from 8 30 a.m. To 4 p.m. Eastern for free each host is an experienced trader and gives their take on the market while taking calls and questions Live from around the world from the moment the market opens until the closing bell sounds Tiger TV has eight different shows with Expert hosts to help you make the right moves with your money watch online at tfnn.com or on tfnn's YouTube channel and become the investor you were born to be tfnn educating investors All now toll-free at 1-877-927-6648 internationally at<PHONE_NUMBER> Okay, we're back folks, and I'm going to post a chart here of the Treasury notes want to bring this to your attention right here You'll notice here that we had that big top up here at 140 But the high was up around 175 if you'll remember it's been in the downtrend for several years If you remember during that time they were feeding us the information about Negative interest rates and all the countries that had it well those have all disappeared I bring this to your attention is to follow what the charts are telling you and Not what the news is telling you so whether that's an interesting thing or not, you know We'll have to we'll have to pay attention to it to see if that is going to be the case okay now I Had one other one that I wanted to mention I posted a chart of the December wheat and Comment bill made a comment about the fact that there's no head and shoulders there Bill all I'm looking at is I'm looking at multiple patterns coming in right near the $8 level in wheat I've been we've been friendly for this for quite some time And so what we've done here is we've been able to Determine that it should be an area where there should be some resistance coming in and at that point It tells us the amount of money that we have to risk is very very small and that's what these patterns are basically for Therefore risk control they have some degree of a predictability They have some degree of risk control, but they are not infallible. We've seen this before over and over again So I keep reminding you because repetition is the mother of knowledge Anyway, let's take a look at this and hold on one one other question that Someone asked me about was the gold market why I took profits in the gold Folks we had a really nice move in the gold and we've had these before in the market You know this market the gold market is still basically in a downtrend So all I was looking at when we were risking $7 on this I put the Limitminder up here to tell me that once we got to 17 95 okay, that was that's it that was 20 that was little $2,200 higher than where we paid for it So I mean now I have to risk too much to see this So if I book a profit here and we're right at the 61% retracement of the high of The October the 28th. So that's a lot and we're still in a downtrend So I basically felt that this is a place to take profits and so that's what I was doing now when I do the When I do these you know videos and stuff I posted the three video or the video that I posted in early Sunday night looking at where these stock indices might go These were just patterns of what what had happened in the past. That's all it was now, you know We had a we had a I think a high on the S&P was at 46 18 we were looking at with a little bit higher than that I think 46 19 and we dropped a 30 handles from there and that's all that is that's just a trade, you know, it's a it's nothing more You know nothing less those those are the things that we're you know We're looking at to see if they're if they're going to be any good or not That's that's the bottom line and sometimes they work sometimes they don't I'd like to be able to you know Be a little closer to the market on some of these things But you know interday and in the middle of the night and stuff you can't always get to those Areas of what we're looking at now I have a really interesting chart here since we were talking about the wheat market I want you to see what's happening folks to the price of a nitrogen nitrogen fertilizer This is for the the planters for the for the soybean wheat and corn stuff That's going to be coming in here in the spring but look at the price of these things folks these things have gone up a Huge amounts we're approaching levels that we haven't seen since a 2008 and I'm talking about the ammonia ammonia area and the 26% solution of the both of the Fertilizer that they use and so fertilizer costs are going through the roof This will be passed on most probably you know in the grain markets because these grain markets The way the world situation is now folks. We are only one crop away from a disaster I mean we really are if we have a disaster here and Brazil has problems That that's it. That's the growing belt of the world. I mean I I know there's only 7.7 billion people on the planet But if you think COVID is a problem You would be really surprised if people can't get food That's the that's the main thing to pay attention to as we're as we're looking at some of these Things here today Now I've had a request to take a look at a stock here for just a second that we've looked at before and I'll bring it up Just give me one second and we'll get it up here We've already done the apple and everything and we wanted to take a look at the where is it?  All right. Here's Amazon. We'll get this up here Take a look at it It's down a little bit today It's followed pretty much what we were looking at last week if you remember we were watching that 78% level up there at 34 75 we hit that exactly now We're now down a hundred and twenty dollars from that level so as until Amazon can get above 34 75 We would assume that that would be that would be the Level that it's that she has very very strong resistance now if you look if you look at that head and shoulders pattern folks That is a Symmetrical head and shoulders pattern you see with the left shoulder and the right shoulder the big red S's either equal if the red S On the right is lower than the S on the left That tells you that that is a head and shoulders pattern now if that had gone higher than that by just a dollar or two That would have negated that head and shoulders pattern That's why when we were looking at that wheat pick that wheat chart the wheat chart has nothing to do with the head and shoulders pattern That's a three drive pattern with multiple ABCDs. That's all it really is So this is the one that's the true head and shoulders pattern the 78 six takes out the previous weeks high by four dollars And then immediately drops a hundred and sixty dollars that that's not bullish action folks Now I know it's bullish action and everything else on the on the Nasdaq and stuff like that But those are just some of the things, you know that we're paying close attention to Let me get this up here and we'll see here what we were looking at here this evening Hold on just a second. I've got to clean everything out and we'll see where we are hold on time out time out time Out time out. Okay, we got to go I got to clean this up a little bit. So there's too many lines on it This is the I want to get the Dow Jones up here So you'll be able to say I'll let you do the work yourself, but this was the Dow Jones E-mini and we'll see that There we go. Anyway, that's the ABCD patterns that we were looking at we had a break of we went from 36 basically 36 Down to Let's say dropped about 300 points and so far We'll just check with the with the countertrend rally has been here because we look at these all the time And then we'll take a quick look at it. There was the high and the countertrend rally Came with it. In fact, we're almost there. We're trading right there right now on the 38 to retracement So that'll be interesting to see how the market reacts around this level right here. So Yes short G7, I don't know what that means we'll be sorry on dear. I don't know. Okay. Anyway, that's that's what we're looking at the s&p We've rallied back to a 98.  Oh boy. Oh boy. Oh boy. 48 18. Give me a second. I've got hold on for folks. I have to I have to fix something. Hey, we'll be right back with Jim Bartolioni folks Are you having fun trading the markets but having trouble finding like-minded individuals to discuss your trading and investment ideas? Become an apex predator in the trading markets and join the tiger's den trading room only at tfnn.com The tiger's den is an exclusive trading room where successful traders from around the world come to exchange trades and ideas Join the den and surround yourself with the sharpest minds in the trading world Subscribers to the tiger's den are also the first to have their questions answered live on air And can privately chat with our tfnn hosts live during their shows Interact with other tigers and tigers as they share trading ideas news analysis and discuss the market action all trading day Subscribe to the tiger's den risk free with our 30-day money back guarantee and become part of the tfnn trading community tfnn educating investors You could be making money off the stock market and if you're already making money off the stock market You could be making a lot more Check out tfnn and tiger tv and get expert investing advice to give you the power to control your financial future Go to tfnn.com and find the newsletter for you Whether you're into trading gold metals futures Currencies or options you'll get advice and analysis to help you seriously get ahead tfnn also features trading services with a 30-day money back guarantee for new subscribers As well as tfnn's tiger den trading room trading software and educational webinars for all trading levels And make sure you check out tiger tv for free on tfnn.com or tfnn's youtube channel for live financial content From 8 30 a.m. To 4 p.m. Eastern on market days Stop watching on the sidelines while other people get rich and become the investor you were born to be tfnn educating investors Tfnn is excited about our new software charting program the art of timing the trade charts In collaboration with tom o'brien and using his best-selling book the art of timing the trade your ultimate trading mastery system David white has programmed an outstanding piece of software that will complement any trader's methodology Using this first of its kind program the art of timing the trade charts allows you to scan thousands of stocks for Fibonacci formation setups including guardleafs abc's butterflies and much more the art of timing the trade charts Is designed to help you when scouring the markets for stocks Just beginning to form the trading patterns that many investors spend days weeks or even months Searching to find and right now we're offering licenses available at only $79 a month We are so confident that you're going to love this new charting software that will even give you a 30 day Unconditional money back guarantee don't miss out on this incredible new piece of software Get your copy of the art of timing the trade charts today by visiting tfnn.com This segment is brought to you by think or swim for more information Just click the think or swim banner on the front page of tfnn.com Okay, we're back folks, and I believe we have jim bardo leone from southern california on the line today jim. How are you doing? I'm wonderful larry. How about yourself? Good morning? Very very good. Jim We have a question you have a youtube channel called barge charts. Is that what it is? Well, you know, I don't have a channel, but I do have a blog barge charts.com And every once in a while I get interviewed like by you jc couple other people and they post it on youtube I probably should get one larry. I guess right? Yeah Yeah, you should because you're certainly got some great stuff now today. We're going to be talking about lithium and bitcoin tell us what you're looking at on these charts part Yeah, you know larry. It's kind of interesting. I've been watching Or been reading and just seeing the amazing battery shortages that are coming up most of it being run by lithium and cobalt I tried to take a look at cobalt futures and there was there wasn't really anything there So what I decided was, you know, there was an etf called lit l it And it's essentially the lithium and battery Business and so I'm like, okay I want to get long this because I think the shortage is going to be around for a while And the bottom line is it's a fast-moving market So I think it'll be really interesting for us to work together and show the readers or show the listeners You know how we can get into a fast-moving market. So this is just like I think three or four days ago Yeah, october 26 They're talking about driverless cars We've got the stuff going on outside the la, you know ports up about an hour and a half north of me So when you call to chart a lithium, you know, lift, excuse me of etf This thing's a rocket ship. I think it's up over 400 in the past year or so So what's been fascinating to me is on each one of the projections You can see that the market has air quote respected it a little bit But the bottom line is it keeps flowing through. So I'm trying to find a level above maybe here I don't know where I can try to get into this because it's a rocket ship right now So, uh, I wanted to show the you know, your listeners that lit lit for their, uh, edification So I'm not seeing it on the chart right now if you want to call it up Okay, uh, let me get it up here right now. I thought that I'd posted it, but this is my fault I'm technically challenged as you know I'm technically challenged too. We're technical analysis technicians too larry. We're technically challenged Yeah, amen to that now do you have We've had a uh Upside breakout on this. Do you have any price targets higher than what we're looking at here? I mean, what are you? Oh, you've got them up there. You got them up. Oh, I see him. Yeah, okay. Got it. Yeah Yeah, I can't see the chart right now larry out. Let me call up on my computer I've got your global lithium and battery etf lit. I've got that lit chart up is what I've got up Okay, boom now now. I see it. So, you know, what I'm doing is that, you know We have that low as you can see and what I'm doing is I'm projecting off of that low and that first impulse high And it's just fascinating. You can see a gap that the abcd It gapped again at the 1.6 and 8 times abcd and found some resistance at 2.0, right? Uh, found again resistance at the 2.6 and 8 So I'm just throwing some more numbers up there trying to figure out when you know, we could find You know at least some resistance And and that's just, you know, just a little higher up by those two red lines It has kind of broken out too because she's broken out from that trend line. So Sure, we want to get long bit We this thing could go up into the 150 200 from where it's at right now So, you know, I'm hoping hope hoping the strategy right there I'm hoping that you know two areas that I could find will cause it to at least cause And then we'll have to figure out using patterns It's probably a 382 retracement of some one of these swings To try to get long lithium for what I think could be a multi-year run Wow, boy, it's had a heck of a run. My goodness. That's for sure Now the next one you want to percent Larry. Yeah, that's well, is that is that monthly or daily or? Yeah, that's not a weekly right now Let's take a look here at this banking index that you've shown up here. Yeah, you know showed this Yeah, we showed this last time Larry and you know as the market goes as we as we all know the market Goes up and goes down based on the banks And we've just got a massive target coming in on the banks Specifically the the blue measured moves which equals a perfect abcd And you can see the extensions that is coming into so for me I'm really watching that to see how the market's going to react to that overall But that's that's a huge chart Oh, wow that that is certainly Unbelievable and I watch Goldman Sachs quite a bit because you know, that's one of the leaders of the banking index and yeah Yeah, it certainly has a has a big run Now the next one we're going to talk about is you got to be careful when these abcds Don't work because this is netflix boy that you talk about a rocket ship boy. This is uh, yeah I know I honestly think Things were really lining up nicely for that one and it was uh, as you can see it was a perfect little abcd But for your books and for what you taught me, right? A valid abcd is when that bc leg goes 50% It obviously didn't so but I still wanted to project up into that and it just wiped it out So, um, netflix is still charging I'm gonna do a little bit of work probably the next day or two because I do think it's it's coming to an end of This run I'm not gonna say the end of the run, but uh, yeah, that abcd was beautiful. But yeah, I don't think it liked it very much Yeah, I was I'm right larry. Well, I I've never traded. Well, I hardly ever trade stocks I mean, that's understatement of the year, but I was looking at a pattern up there At that 669 level and it went through there like it didn't even exist So that's the beauty of what these things are is when they don't work you've got to get out of the way You know, that's just that's right You taught me that right? Yeah, well, I learned it. I learned it the hard way Hey, you know this next one's going to inter Make people very happy because they have a lot of interest in this one and that is the the tbt Which is the etf for those uh notes and bonds This looks like we're in a pretty bear pretty much of a bear market here Yeah, and and what's fascinating is um, I really I really liked this pattern tbt. I went long down lower And um, I'm looking to add but I see that little adc there That we just got to wait and see because it could hit and and just crumble this thing also But that's a beautiful buy pattern right there It sure is they went right down there. This is when the whole world didn't want them That's when you want to start buying when they're crying and sell them when they're yelling Hey Bart listen, yeah, go ahead Larry. I was just gonna say I love also When we have nested patterns, right? And so you can see I made that there's obviously the guardly buy But then, you know people forget that all these different inflection points Are important and you can see that yellow was just an extension off of that, you know That pivot point before it went up and made that high So there was a lot going on at that level and now we have this little minor abcd Where the question marks are So if that fails off we go But if it doesn't then unfortunately, we'll definitely go down to the 786, but so we'll see but tbt is a huge deal Bart, how can the folks reach you if they'd like to see some of your work? Can you tell us what you're absolutely Larry? Thank you, and I always love talking to you. It's always so much fun But you know, I do have my blog barge charts Dot com and you can just contact me there at info at and then i'm at bart at barge charts dot com Anybody can email me anytime and uh, I really I really love the market. I love what we do together. It's just a blast Yeah, it's been a bit a lot of fun. It's been over 20 years, bubba hard to believe I know I don't say that you keep mentioning that Yeah Hey, listen, thanks for joining us. We'll have you on in a few weeks. Okay pal Sounds good. Larry. Yeah, let's keep an eye on list together. We'll uh, It's on my watch list. We'll be right back folks eight seven seven nine two seven six. 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That's tfnn.com then hit watch tiger tv Okay, folks i've been asked to take a look at the december hogs and if you notice that we had that bottom down there That's when we talked about john hill's yum yum trade Where he uh, you know looks for a complete reversal and uh, it's uh, it's really really we've already gone through that You can see the 382 pullback. I marked that that was the low on friday And also where we're watching when you have a strong strong thrust like that you look for that Now we've got a market that's started to move up and you want to start looking for You know buy patterns is the way that you would start to work with this now. Let's get let's go into the world series folks If you ever watch baseball folks, it's a great way of Relating it to trading because in trading if you make a mistake You have to correct it right away And if you don't the difference between a neophyte trader and the professional trader the professional trader will usually 99 of the time take care of the problem right away. Otherwise, he's losing capital and they don't like to do that However, there's sometimes that you don't do that and that's what happened in baseball yesterday When they start issuing base on balls free passes to first base This is one of the quick ways to lose the game and that's exactly what happened to atlanta They left the pitchers in too long I mean you walk two two pitchers right in a row in a really close game You know something is wrong and that's what happened, but this is where we are This is take a look here. We're in the major leagues now folks. This is the dollar index this trades over Well, the euro does this index itself doesn't trade what the euro does but the euro trades about a million One trillion dollars a day But you'll notice here that we have this huge abcd pattern right up here at the 382 level at right under 95 I think it's 94 99 or something like that So we need to pay very very close attention to that because if the dollar gets really strong in here And I don't think that it's going to be able to just because this pattern on a longer term basis after that double top Just doesn't look that good because if that bottom was really good down there That we made in late 2020 and then retested in 2021 We would be going like we were back in 2018 You see how that bottom at the 61 percent retracement stayed there for You know well over five months and look what happened when it broke out from that 61 percent retracement We went up and made a double top So this market is acting differently. It's it's not you know exceedingly strong and that's you know, it's not too weak either But the fact that it can't even make the 382 retracement And that's been uh almost a year that we've been doing this So this is one that that makes you wonder, you know, what's really going to be going on with it Now if we look at the dollar index on a little bit A little bit closer time frame will go down to the dailies here and look at this by the way folks If you have any questions, it's<PHONE_NUMBER>. All right now There is the low that we made the other day We had a little bit below the 382 with a big wide bar down the next day boom away We went but this if this can make new highs now folks because that number for that The number for the for the dollar index on that weekly chart is 90 Let's call it 95. We're trading at 94 plus 94 20 or something like that Now if that could get above that Then then you've got something to really check out now if the dollar is strong that usually means that gold is weak So that's another reason to pay attention to this thing because there could be a big correlation But sometimes these correlations, you know, don't work. That's why you've got to look at You know, what you're what you're trading is what you want to be is the thing you want to be trading is they the The instrument let's take a look here now We'll go move this over to the euro because that's that's an important one watch too. You notice here the euro We went up. We had that big wide range there and I thought that I made a I thought was a perfect trade after that broke out above 116 70 All I did was to buy a 382 retracement and folks the amount of time that I was in that I actually cut the loss down to $290 but As soon as I saw that that 382 was not holding I assumed that we were going to go down and of course The market, you know collapsed well over a point From that level. I didn't go short But I protected myself because I knew that the pattern if it's not going to hold Then we're going to be looking like the market is actually a strong dollar. You're absolutely right. Tommy's Tommy O'Brien's in there talking about the dollar and folks look at that Hey, you got to give you got to let's give Tommy some really great credit here because To me, this was one of the the best ones of them all I want you to look down here folks You didn't I didn't bring this up to you But I keep this on this chart because it was so profound Look back here in 2012 folks. This is where tom Tom O'Brien senior said this he coined the phrase king dollar And then you see we had the 50 retracement there in 2014 and then we had the The butterfly top in 2017, but that remember that thing went from 72 Up to 103. I mean, that's that's a heck of a call I keep that on there because one of the best calls of the decade In my opinion, but it was certainly, you know spot on watching it But let's look at the euro on a weekly basis because to me this chart is really telegraphing That this is where we're going on the weekly basis and that's down to this 61 retracement down at that 113 level Now will that have any effect on the stock market? I don't know Because this isn't the stock market. This is the euro versus the u.s. Dollar It's the largest thing traded in the whole world. They traded trillion dollars a day That high we made last week was exactly a 382 You took out the old high by just a little bit and to me this is what we're doing We're heading down into this area for the euro So I think it's important to remind ourselves That that's what that chart looks like. I can't do anything Any easier than that Here's another one that that looks really interesting now. We had some We had a little bit of strength in the crude oil this morning But but look at the difference between the crude oil and the heating oil You know and heating oil Gee whiz it just start to get cold back east heating oil should be skyrocketing because this is a strong seasonal period And so far it's not been able to get above. I haven't checked it this morning But it hasn't been able to get above the 382 that last high Now we went to the 78 percent level in the in the uh the crude, but the other one did not so Those are just a couple that we're paying close attention to so remind ourselves that uh these patterns uh are have some good deal of predictability now another one that has been You know really spot on For predictability and is working well today is the uh australian dollar You'll see here the we're making that same pattern in the australian dollar We just saw the dollar index. This we've had a really nice abcd correction So we should be heading down in the australian dollar and that's uh, that's what you're watching as you're seeing I know you get a little bit Uh bored with these patterns, but I don't get bored with them. So because uh, it's just a giant chess game for me It's just the ones that you want to line up and say, okay, this one's going to work or this one isn't And that's what you're trying to do as you're starting to understand You know, which ones of these are going to work and uh, you know, which ones aren't so that's the the real key To watching these markets the bonds continue to work lower folks as are the notes We have it higher interest rates coming. We've got higher costs coming And I think those are the things that that we need to pay very very close attention to as we As we look at these uh Different things unfold here. We've got to take a break here. We get back. We're going to take one last One last look at the wheat market and then we will call it a day 877-976648 Sharpening your skills as an investor is like getting better at playing a musical instrument You have to practice sure, but you also need excellent instruction from experts at tfn You'll get advice and guidance from the authority and technical market analysis And it's not just dry tedious text either tfn airs live financial content streamed live on tfnn.com and tfnn's youtube channel with tiger tv Live every market day from 8 30 a.m. To 4 p.m. Eastern for free Each host is an experienced trader and gives their take on the market while taking calls and questions live from around the world From the moment the market opens until the closing bell sounds tiger tv has eight different shows with expert hosts To help you make the right moves with your money Watch online at tfnn.com or on tfnn's youtube channel and become the investor you were born to be Educating investors You might think that if you want to be successful at trading in the stock market You're going to need a crystal ball after all it's impossible to predict the future, right? Like any endeavor in life before you decide it's impossible get some advice from the experts You might find that it's not so impossible after all for daily market overviews that give you direction on the key indices selective stocks and commodities Subscribe to the opening call newsletter at tfnn.com The opening call newsletter is written by basil Chapman creator of the trading methodology known as the Chapman wave The Chapman wave up down sequence gives you an edge in identifying price turns Finding the peaks and valleys and stock prices get the opening call newsletter by basil Chapman and your inbox every day First time subscribers also get a 30-day money back guarantee If you're not satisfied, let us know and you'll get a full refund within 30 days of signing up tfnn.com educating investors Are you looking for a secured investment which pays you on a monthly basis The target first mortgage program may be the program for you The best rate on a five-year cd in the country right now according to bankrate.com is paying 1 per year or $1,000 per $100,000 invested The target first mortgage program pays 7 per year paid monthly on secured high value buildable properties in st. Petersburg, florida The investment is for four years paying 7 per year or $7,000 per $100,000 invested Your investment is secured by high value real estate in st. Petersburg, florida Your investment can be anywhere from 100,000 to 500,000 You want to make 1,000 per year on 100,000 dollars invested or 7,000 per year on a secured tiger first mortgage The tiger first mortgage program may be just the program for you The tiger first mortgage program pays 7 per year paid monthly for more information You can call<PHONE_NUMBER>. That's<PHONE_NUMBER> Okay, folks, instead of looking at the wheat market, I want to give you a little bit of heads up This is the euro 15 minute chart. You see the first black line there. That's where I was buying the 382 retracement of that move thinking that was going to be The low and of course as you can see it didn't once it went below that It told me we were going to go much lower. So why stand in front of that? That's the main thing and here we are the year olds getting up here now to the 382 Of that range up here at 15 95. We're trading at 15 91 We have the same situation So these are the types of things that i'm going to be teaching on our day the november the 10th That'll be on my last one for quite a while Way into next year, I guess because i'm going to be doing some traveling after the first of the year we're going to be going east and west and catch up with some folks that we haven't been able to see for a long time but tommy who guard will be Uh joining me on the show, which is always fun. He's a nice young man plus. He really knows this stuff quite a well So let's uh, let's remind ourselves here folks that These patterns are there for two reasons risk control. Okay, and a and a little segment of predictability That's the main thing. I'll also we're going to start watching the cryptocurrency markets a little more closely In the newsletter i'm going to be following ethereum and a few others that are on the On the watch list that john will help us with to get us moving This is a real thing folks these block chains are here to stay They've got these exchanges bringing them in big monies in it, you know, it's trillions of dollars now So that's not like the tulip bulb. It's not like the south sea island bubble or anything like that This is this is here to say when someone can show you Four years ago. What was going to happen in the future? I think that metaverse pretty much describes everything so we need to pay attention to these things because that's why You know, they work the way they do so remind ourselves that now Live every day in an attitude of gratitude and may god bless do something nice for your neighbors because there's some people out there They're still having trouble and I think that we can all Benefit by helping other people. So we'll see you tomorrow with jeff huge as our guests third wednesday will be shane's million So


So Taylor Nicole Dean is fresh out of rehab and it looks like she's already found a brand new boo after breaking up with Johnny Craig and this is very concerning and I'm worried about her recovery and that's exactly what we're going to talk about in this video. What is up everybody this is Chris from the Rewired Soul where we talk about the problem but focus on the solution and if you're new to my channel what I try to do is take different topics from the YouTube community and see what lessons we can pull from them to improve our own mental and emotional well-being and something I'm very passionate about is mental health as well as addiction recovery so if you're into any of that stuff make sure you subscribe and ring that notification bell and yeah before I get started real quick if you're following me on social media you probably already got the memo well Instagram's actually been pretty wonky today acting kind of ratchet so you might not have seen it but anyways my brand new book Rewire Your Anxiety is out now and since it is the launch week I'm running a sale on it so if you get Rewire Your Anxiety the ebook or the audiobook you get another copy of any of my other books for free one of my books is about my recovery from addiction anxiety and depression the other one is how to help a loved one who struggles with addiction and then I also have Rewire Your Anger so you get to get one of those for free pretty sweet deal in the book the ebooks only five bucks and the audio books only seven bucks so buy one get one free all right that'll all be down in the description below okay but anyways yeah let's talk about Taylor Nicole Dean so before I get started with that let me just say for anybody who's new here what my qualifications are so hi my name is Chris I'm a recovering drug addict and alcoholic I just celebrated seven years clean and sober in my recovery I worked at an addiction treatment center for a little over three years and I am also a certified sober coach all right so when I'm looking at this situation and talking about it that's where I'm coming from and I hope anybody watching this can learn some valuable lessons or it'll help you help somebody else you know who might be in early recovery so those of you who don't know about Taylor Nicole Dean she recently just came back from rehab so months ago I think it was back in April she was dating Johnny Craig and he got her into heroin she ended up going to treatment and she came back and she made a video but then she disappeared again so she went back to rehab and I made a video just the other day I'll link it up in the info card where she finally called it quicks with Johnny Craig and I was like oh oh thank god because I was like okay cool somebody maybe a therapist or somebody in her rehab got through to her and was like listen this is a bad relationship this will lead to relapse you need to get out of it I was so proud of her but after I made that video I got some DMs and people were sharing this picture with me saying it looked like Taylor and Nicole Dean had to pick these up like no no no no if her therapist just got her out of a relationship there's no way she would think it would be a good idea to start her cooking up with somebody and don't worry I'm going to get into the whole idea of why people in early recovery should not be doing this all right but I was like no no no because I'm a little bit of an optimist but then I saw this picture right where she shows this guy who she went to rehab with and talks about how she's crushing on him hard and I'm like oh no please don't tell me this is a rehab relationship please sweet baby Jesus don't tell me this is a rehab relationship all right and then she just posted this picture today it says yo we are cool bro friends his name is Jake for those of you wanting to know not going to spill my whole life story on this but I know a good thing when I see one now and we have what we have is really cool and genuinely helpful with my recovery and not full of codependent BS if you don't know what happened and why I went away for 30 days I don't want to keep explaining it I'll do a video when I'm ready so clearly I'm not the only one who sees this being an issue and potentially something that can mess with her recovery because then she posted this where she says y'all gotta realize I didn't swap my drug addiction with a new guy I was mentally single for over a year now and didn't have any romantic interaction for 12 plus months with my ex I just am moving on I just am allowing myself to have fun after feeling stuck for so long not getting dependent on another person and it's like oh my god all right so here's the thing like I said I have I've been in this game for seven years now I have literally worked with thousands of recovering drug addicts and alcoholics and I'm sitting here and I'm like Taylor and Nicole Dean like who do you think you're fooling right like something my dad would say is I was born at night but it wasn't last night all right like for anybody to look at this and to actually buy in that she's not catching some feelings like let's let's look at this right she talks about how she's crushing on this guy and then she's posting pictures with him and she has over a million subscribers on youtube hundreds of thousands on instagram and acting like this isn't a big deal like okay this is something like even if you're not an addict or an alcoholic like this is something that so many people do where it's like I don't really want a relationship I'm not looking for anything serious but imagine saying that and then bringing your hookup to come meet your family all right those actions are not aligning with words okay but just to put it in perspective for you real quick okay like I just want you to imagine Taylor Nicole Dean going to rehab okay working with counselors therapists social workers right maybe even a psychologist can you imagine any of them telling Taylor Nicole Dean that it would be a good idea to start hooking up with a guy that she just met in rehab like I want you to sit and ponder on that for a second like something I just talked about in my Tricia Paytas video is you can go to rehab as much as you want you can go to therapy as much as you want but if you're not doing what they suggest to you then it doesn't matter you are wasting your time and I hope the best for Taylor Nicole Dean I hope this doesn't lead to a relapse but it's something that I've seen play out in a bad way so so many times because here's the thing in early recovery we are in such a fragile vulnerable state right and we can get hurt really easily and that's one of the reasons we need to focus on ourselves and strengthen the foundation of our recovery and not be fooling around with any guys or girls all right like this is the biggest suggestion in early recovery it's not to date for the first year oftentimes not even to hook up like I saw this play out so many times in my early recovery where my friends would drop off like flies because they started to hook up in early recovery either one person would relapse or both people would relapse okay and I saw this happen many many many more times in the treatment center so here's the other thing especially when you're hooking up with somebody else in early recovery it is one of the most selfish and self-centered things you could do because they are in a vulnerable state all right this isn't you just going out and hooking up with a random dude or random woman off of Tinder you are hooking up with somebody who came to a mental health treatment center okay like think about that for a second and the reason I'm so passionate about this is because I have seen so many horror stories that would blow your mind I do not have the hours in a day to tell you all of them but I'll tell you one that sticks out in the front of my mind when I see somebody like Taylor Nicole Dean saying I'm not looking for anything serious I'm not looking for a relationship so I'm fine there was a young woman who came through our treatment center and she didn't really care about being in treatment she was like forced there like her parents forced her to go they didn't care just like kind of slept in groups and everything like that but anyways she started hooking up with a bunch of guys in treatment and by the way that's against the rules don't do that okay and she was just like oh I'm not looking for a relationship I'm just having fun and just hooking up with guys right well she ended up hooking up with a guy who had a lot of psychological issues remember this is a mental health treatment center and even though she wasn't catching feelings this dude caught feelings for her he fell in love with her all right like remember the people you meet in rehab the people you meet in a mental health treatment center they have emotional issues right they struggle with things like depression they struggle with things like codependency so it's not all about you and yeah that story doesn't end there either because this guy caught such strong feelings for her and she said no I'm not looking for anything serious the dude tried to take his own life okay so that again is why I'm so passionate about this subject so when I see somebody like Taylor Nicole Dean meeting somebody in rehab meeting somebody who is fighting for their life every single day it is such a selfish and self-centered move to be like oh well I'm not looking for a relationship like think about this guy's recovery all right and here's why this stuff doesn't work out when people come into treatment okay it's not like everything was honky dory all right Taylor Nicole Dean was not living an amazing life on heroin things were wrong and she has things that she needs to work through as we all do right the other dude who came into rehab he came in broken as well like imagine this for a second imagine taking two glasses breaking them on the ground scooping them together and being like okay look this can work because that's basically what you're doing when you're taking two newly sober addicts and and trying to have any kind of semblance of a relationship one of the best things I did for my recovery was the first year not only did I stay single but I also stayed celibate because I'm the type of person I used to do this crap that Taylor and Nicole Dean did right I used to go and be like oh I'm not looking for anything serious this is just for fun we're just hooking up but then I'm like taking pictures with them and doing all these other things like I was lying to myself that's why in recovery they say we have to be honest we have to be honest not just with other people but with ourselves as well so again I hope the best for Taylor Nicole Dean and her recovery but this kind of stuff makes me very worried and check this out I've been doing this for a long time now and I hate I hate being right about these things but there is a reason why those of us with clean time have certain suggestions for those who are new like think about it for a second like I used to tell this to my clients all the time in rehab like do you think I get a bonus if you don't get in a relationship like do you think why do you think I'm telling you this right like why do you think it's recommended it's because we've seen this play out way too many times like I've seen thousands of people try I've seen probably less than four actually work out all right so think about that for a second and maybe maybe some of you in recovery can help me out in the comments below let me know let me know your experience did you try a little rehab relationship or a little like 12-step meeting relationship let me know how that worked out all right down in the comments below but anyways don't forget rewire your anxiety is out now and it's on sale get a copy of rewire your anxiety get another copy of any of my books feel free pretty sweet deal link down in the description and down in the pin comment below all right that's all I got for this video if you like this video please give it a thumbs up if you're new make sure you subscribe and ring that notification bell because I make a ton of videos and a huge huge thank you to everybody out there supporting the channel over on patreon you're all amazing and if you would like to become a patron support what I'm doing here get access to some other perks and benefits like all my books for free you can click a tap right there all right thanks again so so much for watching I'll see you next time


Ladies and gentlemen to this session on critical raw materials. But before I reduce the speakers and the subject, let me just mention one incredible experience which I had this morning. I used the time very early in the morning to go to a place, 10 minutes from here, the Abrahamic family house. I was not familiar that this exists, but a friend of mine had told me about it. It's a church, a synagogue and a mosque, all on one compound. And it is a strong sign of tolerance that the United Arab Emirates send with this wonderful architecture, which is not just a museum, but where people pray, people sing, people have masses, services. It was deeply moving and especially in these times, I can only encourage you to use the time to go there and see it and one can only wish that this message that the Emirates send with this wonderful institution will be heard in all major Abrahamic religions. Well, we have a very important subject and that is critical raw materials. And last year, after the Russian invasion in Ukraine, we woke up and I say it as a German, also we and especially we woke up and immediately recognized how much dependent we were on, in this case, Russian gas. And at that time, at the last World Policy Conference, the 15th edition, we already had a panel on critical raw materials with a representative from the EU Commission. And we all stated, well, the dependency on critical raw materials, on some critical raw materials on China, for instance, are even higher than those dependencies that we had with Russian gas. And we urged the Commission and urged the policymakers, do something to diversify, do something to start mining again in Europe, look for other places. And the question that we asked today and which is the lead question here for the panel is what has changed during last year? Was this strong demand heard by policymakers in Brussels and Washington and the Gulf elsewhere in the world not to rely on one or two countries alone but to diversify?