Once again, welcome you all to MSB lecture series on interpretive spectroscopy. In my last couple of lectures, I have been discussing on mass spectrometry and discussing about different type of organic molecules having different functionalities, how they fragment, how the molecular ion look like and what are the incremental degradation of molecules and all those things. Let's continue from where I had stopped. Let's look into mass spectra of amides. So in case of amides, we do get intense molecular ion peaks. Primary amides show a strong peak at MZ44 due to H2NCO cation and this is how the fragmentation happens initially. This bond cleaves here and we get a species of mass M by Z equals 44 and also beta cleavage is quite possible and it dominates when we are considering secondary amides having more than three carbon-carbon bonds in this R group and then that leads to eventually the carbon monoxide cleavage to form something like this, this species, this is the base peak it becomes and M by Z equals 30 here. You can see here, bond breaks here, this is called beta cleavage and then this radical comes out and after that one in the subsequent step in from this radical cation, this bond breaks, Cn bond breaks and then this species come out and this is formed here. So this is a typical fragmentation of amides and let's look into mass spectra of aromatic amides. In case of aromatic amides, loss of NH2 radical results in resonance stabilized benzoil cation that also eventually cleaves to form phenyl cation. For example, you can see this is the base peak for benzamide and then one NH2 comes out and then eventually CO also comes out and we get 77, this is for phenyl cation. So this is how steps involved in the degradation or decomposition or fragmentation of benzamide here and base peak can be clearly seen here. Now let's look into mass spectra of nitro compounds. In nitro compounds initially elimination of NO2 is possible or NO is possible. In those cases, what we get is characteristic peak with M by Z value of 92 or 108 and if NO2 is lost, we get 92 and in case NO is lost, we get 108 which eventually gives a phenyl cation similar to what we saw in case of amides after CO elimination. For example, initially it can break here or it can break here. When it breaks here, we get NO, NO2 will come out if it breaks here and then we get anilinium cation and from that one HCN comes out and we get C5H5 and then if NO is eliminated and then we get this radical cation and this one eliminates one CO to form this one here phenyl cation. So this is also very similar to what we saw in case of aromatic amides. Now let's look into mass spectra of sulfur compounds. So sulfur containing compounds can be readily identified by characteristic M plus 2 peaks due to the presence of 4.4 percent of 34 S isotope here. The size of M plus 2 peaks provides information about the number of sulfur atoms. So this is one advantage with sulfur, invariably we see M plus 2 characteristic peaks. Thiols such as oralkyl SH form fragments similar to corresponding alcohols. The fragmentation is very similar to considering alkyl alcohols and beta cleavage results in the elimination of this cation with M by Z value of 47 and again primary thiols eliminate H2S to give a strong M minus 34 peak which in turn eliminates ethylene and primary and secondary thiols lose readily branches if there are any. And cleavage of sulfates are very similar to beta cleavage we come across in case of ethers. Let's look into one example here for example let's look into this compound here. Firstly cleavage happens next to beta and then we get the elimination of C4H9 radical that results in the formation of this mass fragment with M by Z 117 and then it further decomposition happens this are the possible cleavage pass either it can H migration can happen or CS bond can break and we can get a species here and also eventually what we are getting is this species cation with M by Z value. 47 you can see here this is the base peak here from this one what we lose is this 47 goes off and then we get 117 where we have this portion this breaks to give this one but initially this one would break another CH2M to give 103 peak and then from 103 peak this goes off to give the 71 that means basically one goes here and then this migration takes place and then this portion will be there C5H10 that's what it shows here and also you can see the relative intensities of peaks here M is 174100 percent M plus 1 is 11.33 percent and M plus 2 is 4.6 so you can see here. Let's look into mass spectra of halogen compounds characteristic isotopic patterns can be readily recognized in case of halogenated compounds similar to what we saw in case of sulfur compounds compounds containing one chlorine atom will have M plus 2 peak with one-third of the intensity of M for example M 37 Cl by M 35 Cl is 32.5 by 100 roughly it is one-third of the intensity. So M plus 2 peak in a compound with one bromine atom will have the same intensity as that of M and compounds containing two halogen atoms so then it can be Cl2, ClBr or Br2 display a distinct M plus 4 peak from which we should be able to distinguish and we can immediately tell or we can get information about the presence of halogens in the molecules. If we have instead of chlorine or bromine if we have fluorine or iodine they have only one isotopes this is 19 of 100 percent abundant it's 127 100 percent abundant. This chart what I have given I would tell you about molecular and peaks for bromide and chloride compounds the application of isotope contribution is limited by weak molecular ion peaks but the fragments containing halides can be readily recognized. So you can see here in case of chlorine and Cl2 when you have Cl3 and also when you have Br is there and BrCl is there BrCl2, BrCl3, Br2, Br2Cl, Br2Cl2, Br2Cl3, Br3Cl. So all these combination is shown here typical ion peaks containing bromide and chlorides. So this is a very useful chart that I have shown here a guide to interpreting mass spectra for example if a methyl cation is coming out you know what the m by z value is 15 or ethyl is coming 29 so or if you are getting a nitrogen carbon fragment this is coming so all this information is there and also some vital information is also given at the left hand side of the chart here and also the sample how mass is detected how mass spectrometry typical mass spectrometry instrument works also shown here this is a useful chart got it from this site here so please go through it this is very useful site for as a reference. So let us look into some more spectra here this is the mass spectrum of ferrocein and of course this one I simulated and collected the data here and 100 percent abundant one can be seen here 269 and 270 and this is for diacetyl ferrocein here the base peak should be around 170 271 and then it fragments out I have another one to show here and the different masses I have shown here just look into it what fragment is coming out whether first acetyl group is coming out and then eventually cp group comes out and it is getting stabilized with eventually cpfe plus it will become that finally we get it but here we should go further to see that one that is the typical peak we observed the end in case of ferrocein if the number of atoms with more than one isotope increases in a molecule the distribution becomes more complex for example if you have too many atoms having many isotopes in the system then the distribution becomes more complex and also understanding becomes more difficult so I have shown here one such ccl4 here of course you should remember when you are considering ccl4 we are considering 35cl, 37cl and also 12c and 13c and ccl3 it shows the pattern something like this and if you have ccl2 it shows and ccl it shows 2 and cl it shows 2 I think I have more examples so let us look into fulerine c60 despite fulerine not having halogens or sulphurs shows 4 ions with significant abundances so 1 2 3 4 here and then if you look into the parent peak because it is 60 and molecular weight will be 720 and this is how it is split with m peak 720 m plus 1 m plus 2 and m plus 3 of course the combination also I have shown here this is 100 percent and this you can see combination of 13c and 12 and here we have 13c2 and then 12 and here we have 13c3 here and base peak comes here plus m plus 1 is shown here so what would happen if the number of carbon atoms in the molecule increases then what kind of molecular peaks we get to see is shown here for example if molecular m is 100 and if let us say we have 10 carbon atoms then we will see m plus 1 and 11 in case of and then 27, 55 and 100 and if you have m plus 2 in case of this one c25 we will see 3 and 15 and 49 and similarly m plus 3 we will see one in case of c50 and above and c90 it is 60 and m plus 4 one in case of c90 and that means when you have 90 carbon atoms we will see here 3 so this shows give some information about higher analogs of further in molecules so this shows typical isotopic pattern for compounds containing different elements the first one is about main group elements of course when hydrogen is there it is very simple carbon is there we will see 2 this because of 13c and 12c and nitrogen we will see because of 14n and 15n and oxygen we will see 16 and 17 and then fluorine only one because 19f is 100% abundant the same thing is to in case of phosphorus 31 per 100% abundant sulfur we have 32 34 and 33 so we see 3 here and in case of cl again we have 35 and 37 so this is the typical isotopic pattern one should remember whenever we look into the mass spectra having these elements in the molecule so now similar chart I have given here for transfer metals for example ruthenium this is the typical pattern and rhodium again 103 we have 100% we don't see anything else and palladium we have this and silver we have and then in case of cadmium it's a little bit more complex and indium we have 2 and tin again it's a bit more complex and in case of anti-money we will see 2 isotopic patterns 2 peaks here so isotope patterns of polyatomic ions are calculated using binomial expansion as I mentioned if you have more atoms having more number of isotopes then how to calculate the isotopic patterns we see in the molecular n peak that can be simply understood by using the binomial expansion this is a binomial expansion we use here and what is a a b a or c a etc are the fractional abundances of the isotopes of x a y a and z a of element a and the n number of atoms of a present in the ion n number of i present in the ion so then represent similarly for m atoms of b it continues like this if you have more than 2 or 3 different atoms having different isotopes simply we can calculate using this formula so now let us look into one example here this is di carbonyl dichloro iridium anion iridium has 2 isotopes 191 that's about 37% and 193 that is 63% and similarly we have 2 isotopes of chlorine 35 cl is 76% or 77% and 37 cl is 24% the contributions of minor isotopes of carbon is 13c 1% and oxygen 17 very minute 0.00038% and also 18 o is about 0.008% or one can neglect this oxygen isotopes such as o 17 and o 18 following table what I have shown is shows how to calculate the relative abundances of each of the peaks in the isotope pattern with mass spectrum of this one mass spectrum also I will be showing you in the next slide for example one can start writing ion composition one should not do any mistake first you can consider 191 iridium and 35 cl2 both are 35 and co2 is there and this is 317 and fractional abundance we have to take 0.37 for this one and 0.76 for 35 chlorine and here the total value will be 0.214 and this will constitute 43% and then if you consider 193 iridium and instead of 191 now we are considering second case 193 iridium and same 35 chlorine we are considering both of them and here this is 319 because it increases and then by 2 and now 0.63 is considered for 193 iridium and then 0.76 continues so when you sum up we will get 0.364 this constitutes 100% and then we can take the combination now take 191 iridium and take the combination of both 35 chlorine and 37 chlorine so here the fractional abundance can be calculated like this so into 2 we have to use because the ion intensity is made up of contribution from 35 and 37 cl so here it is 0.135 it is a small quantity and then of course in the same combination we can also have 193 35 and 37 so this also comes here similarly we have taken the fractions here and some of these two will be coming around 50% and then another one is now change the iridium to 193 to 191 and consider both cl and that is 323 and then we get this calculation done and it shows 0.021 and now we can consider 193 iridium and both 37 so that amounts to this value and under the end we get the value of 7% so that means basically we can see three peaks with almost 1 is to 2 is to 1 ratio in the spectrum of this one iridium dichlorodicarbonyl anion so you can see here this shows three so one is coming around about 43% one is coming around and one is coming around 50% close to and then other is 100% you can see the peaks here so whatever the calculation we have made here is reflected in the spectrum we have observed here so this how one can calculate and get to know how to interpret the molecular ion peak or fragment peaks in this fashion if you have more isotopes and this is a very beautiful mass spectrum of hexa phenyl tin compound this is a cationic compound and then here I have identified here the major peaks here and of course this comes something like this very beautiful one this is again simulated using simple software I simulated this one and also collected all the data for all the peaks observed here and this is a very useful periodic table this gives about the entire period table and then all possible isotopes and their abundance everything is listed in this period table so whenever you get time you just go through it for example cadmium is there and almost all for reference cadmium is taken here and now let us look into one example here inorganic complex ruthenium simin pta cl2 pta is phosphatriazide adamantane is a monophosphine here this is bound to ruthenium and this is the simine we call this is methyl 4 isopropyl benzene that is called the simine this is taken in methanol in the presence of lithium salt li plus and the left one what I have shown here is a normal scan and resolution is 1000 you see the broader peaks for the weakly bound solvent like here you can see the broad one for weakly bound solvent and the right one is expanded one the resolution of m plus li peak has improved to 3000 and the weakly bound solvent products have disappeared to be replaced by undrizzled peak here so this is again a very interesting mass spectrum of ruthenium two compound ruthenium is in plus two state so now before I conclude this lecture I will show you one more this is a crown ether and I am sure you know how to name the crown ether you start numbering like this one so this one the number of atoms in the ring are 18 crown and six oxygen atoms are there so this is called 18 crown six ether and this can conveniently encapsulate a positive ion such as alkali metals or alkane earth metal ion to impose a octahedral geometry so this one will go up and this will come out and they will be remained in the plane this is the typical mass spectrum of 18 crown six ether the malcher ion peak is 264 from 264 it becomes 221 that means basically it is losing one C2H3O cation and you get 221 from onwards what happens then incremental decrease in the loss of C2H4O C2H4O moiety is coming here and then you can see here incrementally it is losing and at the end eventually we get 45 so if you see here this one we are losing and from here we are losing another one and one more we are losing and then one more we are losing and this becomes the base peak for C2H4OH plus so this is again a typical for crown ether and in case of crown ethers the fragmentation happens with regular decrease in the molecular ion peak with a mass of 44 that corresponds to CH2 OH so let me continue in my next lecture with more examples before I include mass spectrometry and of course I have a lot of problems on mass spectrometry as well so in the end I would try to combine some of these issues related with mass spectrometry with NMR or IR to solve the problems until then have an excellent time thank you.


Hello, this is Laptop Media, and today, we will show you how to open the Asus ROG Strix G17 G713P and what's inside of it. To get inside this device, you need to undo a total of 11 Philips head screws. One of them is captive and lifts the bottom panel, so you can start the prying process from there. Please remember, it would be of great help to us if you just hit the like button and subscribe to our channel. That would motivate us to make even more and better videos for you. Inside, we see a 90Wh battery pack, which only lasts for 4 hours and 30 minutes of web browsing, or 3 hours of video playback. To take the battery out, unplug its connector from the motherboard, and undo the 4 Philips head screws that keep it in place. Memory-wise, there are 2 Sodom slots that work with DDR5 RAM in dual channel mode. As for storage, you get 2 M.2 PCI-EX4 slots, both of which support Gen4 SSDs. In terms of cooling, there are 2 heat pipes shared between the CPU and the GPU, with one more dedicated to each of them. Furthermore, you get a heat pipe cooling the graphics memory and the VRMs, while 4 heat sinks and 2 fans deal with heat dissipation. If you'd like to see more disassembly videos of the latest notebooks we would highly appreciate if you hit the like button and subscribe to the channel.


You are about to hear a romantic drama, Devil Wind, adapted from a story in Street and Smith's Love Story magazine and featuring the love story girl in the role of Dusky Burke. This is the love story of Dusky Burke, who had always had wealth and position and everything she wanted, until her father died. Then even the beautiful home in Beverly Hills had to be sold. And for the first time in her life, Dusky Burke found herself in need of a job. Six weeks in the business school, and we find her now on her way to her first position as secretary to Jim McKay, builder of yachts for California's millionaire. Dusky is being driven out to interview her new employer by Sam Ashworth, her faithful suitor. Gosh, this wind is terrible, Sam. Yes, it brings the dust from the desert for a hundred miles. Dumps it on the coast here and on everyone who's unfortunate enough to be in the way. I hope I don't have to meet my new employer for the first time until I've washed my face. I must look terrible. Well, naturally, no woman would want to see Jim McKay unless she looked her best. Oh, no? Why not? Jim McKay's as well known as Clark Gable, breaker of hearts, builder of women, the one and only man who can flood her feminine hearts and go through life unscathed. Listen, what makes you so sure of that? You remember Marnie Davis? Oh, slightly. She was a friend of my sister Sylvia's. Uh, wasn't there something about a broken engagement? There was plenty about it. Marnie was all dressed up in white satin waiting at the church. The rector was there and all the guests. Marnie waited for an hour until the bridegroom sent a note saying he'd gone to South America. His name, by the way, was Jim McKay. Oh. But Marnie married. Yes. She and Jerry Atherton went directly to Mexico after their marriage. Well, what else has Jim McKay done? I don't know. Isn't that enough? I suppose so.  No, it isn't a pittance. It's good money and I need it. Now listen, if you're afraid I'll fall for Jim McKay, stop worrying. I couldn't stand a man who'd done a thing like that.  You can stop now and let me tell him I'm in town, even if my face is dirty. Oh, I get it. You can't wait. You've got to see this, Don Juan, the minute you spot his office sign. All right, here we are. McKay yachts. This is it. And there's a smudge of dirt on the end of your patrician nose, Dusky. Well, since I'm only a stenographer, what difference does it make how I look? All right, it's your funeral. Nobody here. Well, I guess this is his office, all right? Golly, look at all those yacht models. I know I'm going to like working here. Are you looking for me? Oh, I'm the new stenographer. Oh, yes, I was expecting you, Miss Burke. I'm just on my way down to the yacht basin. You want to come along and see the Collette Yacht? It's the best 98-footer we ever built. Well, I'm afraid I can't. I've got a friend outside. I only drop by to tell you that I'd be to work in the morning. Oh, I see. Jim, darling, I couldn't leave without coming in to see you again, even if my husband is outside, raging to be on our way. Oh, of course.  Come here. Don't take too long about it. I'll be at work in the morning, Mr. McKay. Sam was right. He's a heartbreaker. Well, he won't find me an easy victim. Hello. How'd you like Jim McKay? I despise him. Finish that letter up so I can sign it and get it in the mail before lunch. I'll do it right away. Anything the matter, Mr. McKay? What do you mean, is anything the matter? Well, I just noticed that you seemed so preoccupied for the last day or two that... Oh. How long have you been here with me? Just two months now. Well, it's just about two months that Collette owes me for that boat I built for him. Oh. It's been finished and fueled and ready to go for six weeks, and I wish he'd come for it. I need the money for the business. I tied up practically all I had for this Yacht of his. Oh, I see. They warned me Collette was a bad man to do business with, but he wanted this yacht and he should pay for it. Of course. Oh, wait a minute. Here comes the messenger boy now. Maybe it's a telegram from Collette. Oh, couldn't be. A telegram from McKay? Thanks. Hi, George, it is. Collette's coming for the yacht this afternoon. He wants to sail it once. He's bringing the crew with him. Oh, I'm so glad. Well, we're all set now, honey. Come here.  Just because I worked for you is no sign you can take advantage of me. You ought to know that this means as much to me as it does to you. I have a good mind to slap you. Oh. Get a dust rag and a can of brass polish. Collette will be here in two hours, and we've got to get everything on that boat in shape. Collette's taken his boat, and I've got $300,000 in cash right here in my hand. Oh, that's an awful lot of money to have in cash. I wonder why he didn't give you a check. I don't know, Collette, that way. You lock it in the safe. I've got to go down the street and send a telegram. I'll be back in a few minutes. $300,000 and $1,000 bills. That's an awful lot of money. I'd better put it in the safe. What was that? I thought I saw someone looking in the window. Gosh, I wish he didn't leave me here with all this money. I'm sure that was a man's face looking in the window. Well, I'd better lock it up quick. I feel a little better now. That's an awful lot of money hanging around, even in a safe. I wish Jim wasn't so casual about things. Hello. Is Jim there? Yes, but he's gone out for a few minutes. I'm Mr. McKay's secretary, Dusky Burke. May I take a message for him? Oh, not? Yeah. Well, this is Marnie Davis Atherton. Oh, yes, Mrs. Atherton. Oh, for goodness sake, call me Marnie. I want to invite you to a weekend party along with Jim. Well, I really... Now, absolutely no excuses accepted. Jim's coming along, so are you. Tell him you're booked to come down tonight as soon as he's through with the art business. But I... By the way, a friend of yours is here, Sam Ashford. Now, don't forget, I'll be expecting both of you. Jim's coming and so are you. Oh. Yes, I'll go. I'll stop this uncertainty about Marnie Davis. She evidently doesn't want to stage you, but then this will cure me for all time. Hello, how about some dinner? Well, Marnie Davis Atherton just called up and wants us to go up there tonight for the weekend. That's swell. You'll go, of course. It'll be a nice trip. We'll get down in the bay in my speedboat. Oh, that'll be wonderful. You might as well get started as soon as possible.  I'll meet you back here in the office in half an hour. That'll save time. Right. But, uh, how about the $300,000? What? Oh, that'll be all right until Monday. Are you sure? I thought I saw a man looking in the window. Oh, nonsense. Don't let your nerves get the best of you. Go on now and get ready. You here already? Yes, I was here in a half an hour on the minute. Oh, I hope I didn't keep you waiting. Not more than 10 minutes. All right, come along. We'll go out this way. I've got the boat over here at the landing.  All right. Buddy, I'll cast off. This is something like it. I know we haven't had any dinner, but we'll get something to eat when we get there. You should see the place she's got down there. Jim, how long has Marnie been here? Well, a few days. By the way, you're sure you locked up that money? It's safe. Good. And I've got nothing to worry about until next Monday. Pretty, isn't it? With the bay all blue and the hills violet and the gulls darting about. It's my favorite time of day, just when it starts to get dark. Dusky, I've decided I've got to get something settled. I love you, and I want you to tell me exactly how you feel toward me. I love you, too, Jim. I just knew you did, honey. You love me from the first minute, and I love you. Oh, Dusky. You do love me, honestly. You bet I do. Well, Dusky, has the yacht-building lady had enough to eat? It was a lovely dinner, Sam, but where are the... You'd better have a seat and make yourself at home. We have the place to ourselves, if I'm any judge. What do you mean? Your employer and our hostess have gone for a drive in the summer moonlight. Oh. Ready to consider a marriage proposition from me? Sorry, Sam, but I don't love you. All right, first thought I'd ask. Would you have a drink? No, thanks. Might as well. Looks like it might be a long and lonesome evening. Three hours. Morning's the limit. I came down here with her to help get the place ready for guests. Jerry and the crowd will arrive in the morning. I guess Jim and Marnie figured this would be the last night they could be alone.  It's none of your business. Might as well marry me this time. You know what Jim is by now? You've had your fling? Why not call it a day? Listen, Sam Ashford, maybe I have had my fling, but I'm not going to marry you. I'm going to marry Jim McKay. What? Has he asked you? Not exactly, but I'm going to marry him just the same. I'll swear Jim must be a superman. Never yet saw a woman who could say a word against him. You in love with him and defending him. All the time he's out riding with Marnie. You know what he did to her? Oh, stop it. Maybe they've had a wreck or something. Well, I hope so for your sake. Oh, there's a car now. They're back. And it's about time. Jim, what's the matter? I'm ruined. Absolutely ruined. Oh, it was awful. What was awful? The office. Burglars blew the safe and tore the whole place to pieces. The police phoned me here. It's all gone, dusky. All that money for the yacht. And I'm ruined. You and Marnie. You and Marnie. What's the matter? You were out looking for the money, and we thought you were out making love. What's that got to do with it? Didn't you guilt Marnie? Oh, you tell her about it, Marnie. I've got enough on my mind without going into all that. Well, goodness sake, do I have to go over all that when Jim's out so much money? Yes. It's more important to me than the money. All right. It was this way. Jim overheard mother telling me that I'd have to marry some money soon, or the family would be ruined. The only man with money I knew was a playboy named Carl Townley. But I told mother I'd marry him if necessary. Well, Jim overheard all this, and he proposed to me. And the next thing I knew, I was at the church in White Satin. And knowing all the time that I was in love with Jerry Atherton. Oh. Well, to make a long story short, Jerry came back from Mexico and saw Jim before the wedding. When Jim understood how it was between Jerry and me, he politely jilted me at the altar. That's all there ever was between us. Oh, but now poor Jim's money is gone. We don't know where to find it. Jim's money is upstairs in my bag. What? I was afraid to leave it in the office, so I just brought it along with me. Dusky, you darling, you loved me even when you doubted me, didn't you? Yes, but I'm through with doubt.  Oh, that was my sister. You're worried about her, too. You don't know the man you're going to marry very well, do you?  Oh, now, Dusky, you ought to thank me. If I hadn't made a good story about Jim, you probably wouldn't even have been interested. Is that true, darling? I'd have loved you, Jim McKay, no matter what anyone told me about you. You have been listening to a romantic drama featuring the Love Story girl and presented with the permission of Street and Smith publishers of Love Story magazine.


What's up everyone? It's your girl Kinty here from Lane Sports Guards. We're breaking the line for the national. We've got 2022 Leaf Metal Pop Sentry, 12 box, case break, number two, random hit style, two hits a spot. This is going to work is we're going to go ahead and open up the box as I pull the cards out. Force is going to take them into a Google Sheet and we will do the random to see which two hits you get after we're done opening everything. All right, best of luck. I'm going to do this one, then Force is going to hop in for soccer because you all do not want me to rip soccer. That's for sure. Mystery cut signature redemption. 2022 Leaf Pop Sentry cut signature card. Again, they don't tell you who it is until you go to redeem it. So good luck everybody on that one. Growing up graphs blue of Hal Linden, that is nine of 25. We've got ticket stub of Billy Joel, Billy Joel from 1987, 1987 ticket stub, and a Chevy Chase Auto. We have four on that one. Cool Chase. Next hit up, we've got a cool Houser, cool Houser Auto 10 of 10. Blue auto of Mark Boone Jr. Boone Jr. Blue 10 of 25. Got dual auto of John Amos and Jimmy Walker. That is a one of one. Amos and Walker and Ice of Harry Hamlin. Harry Hamlin auto 21 of 40. We've got Kathleen Turner. Kathleen Turner auto three of 12. Richard E. Grant. Richard E. Grant auto 204. Swatch is cool. We've got Star Studded Swatches of Jack Nicholson. Nicholson, that is authentic wardrobe worn by Jack Nicholson. And purple of James Codd. Two of 10. This redemption. How about a Harrison Ford? Good luck on that one everybody. Harrison Ford. Again, it'll tell you what it's numbered out of. Tobolowski on the black auto. Tobolowski three of 10. Nicole Eckert. Nicole Eckert. And Star Studded Swatches out of 25. Christian Bale. That's nasty. Christian Bale, authentic wardrobe. We've got Star Studded Swatches of 25. Brittany Merle, 25. And we've got Blue Tom Webber. Paging my check. One, two, three. Eight out of 30. Pretty sure he's in that new series on Hulu. Cleaningly. Butch Patrick on the growing up graph. 10 of 15. T. Butler and T. Butler, 21 of 35. Ticket stub of Don Henley. That is from 1990, Florida's Suncoast Stone. 1990 ticket stub. Adam Driver on the red. Good afternoon. Adam Driver. Two of two. Please take this opportunity to designate the leading place with your children in the event you get separated. Parents, please create a meeting space for you and your children in the event you get separated. Thank you. Bridges. Todd, Bridges, one of 15. Duel, Off, Machio, and I guess so. On the orange. One of three on that one. Now we've got Orange Vinyl Signs. Vince Neil. Vince Neil. Six of seven. Another Rick Flare. We got a John Amos and Jimmy Walker. So we have the one of one earlier. And now we've got Purple that is out of 15. Four of 15. Amos and Walker. And we've got Pink, Robert Wagner. Pink. Nine of 15. And Dean Cain Blue. 13 of 15. We have a 35 on that one. Lorenzo Lamos. Six out of 20. Owl Sharp. Cut out of there. And Michael Battalucco. All right. Last four boxes here. Yeah, everyone still have some spots left for N.T. football. Both case breezes. One is random team. The other one is tier random. And then Tom Sizemore. Sizemore. 30 out of 50. Green growing up graphs of Emilio Estevez. One of seven. Starstoded swatches of Buddy Holly. Not numbered on that one. Buddy Holly. And a Christie Brinkley. Christie Brinkley. It's so good, dude. Three of 12. Growing up graphs. Blue, Michael Anthony Michael Hall. 14 of 25. We've got a ticket stub of Iggy Pop from 2003. Iggy Pop and Fisher Spooner. Eat Boston's Pavilion. And Blue Auto of Norman Reedus. Lena Wood. Three of 35. Of Angelica Hudson. Houston. Huh? Houston. Houston like a city. Oh, Houston. It's six of seven. Vinyl signs red. D. Snyder. D. Snyder. That is nine of 25. And the last hit here, we've got a Sophia Milos. Milos. Six of seven on the glamour graphs. Give me just a minute here. I'm going to do the names first. Again, everyone's name is in there twice. Two per spot. Since there's 48 hits, you get two hits per spot. Let's see what we got. Eight times on the random names first. One, two, three, four, five, six, seven, eight. John A. Down to Jayman L. Eight times on the hands. Good luck, everybody. One, two, three, four, five, six, seven. Down to Kate Landry Auto. Board redemption. Congrats on that, William. Matt N. Robert Wagner. Von B. Tom Welley. Elmer H. Boone Jr. Nick D. Angelica Houston. Melissa R. Christian Bale. Riley, that was a cool one, too. NLP with the Tobolowski. Brandon H. Brinkley Auto. NLP, Yancey Butler. Ryan Machio. Roger H. with the Hall. Sorry, Elmer H. with the Haircut Redemption. Melissa R. Iggy with the James Cahn. Jayman L. The Machio and Swank Duel out of three. Yicheng with the Brittany Murphy Relic. Brandon H. Jack Nicholson Swatch. Gordon P. with the Dean Kane. Ray J. with the House. Force will be starting soccer here in just a few minutes. Thank you, everybody.


So that's where they shot through the tire tracks up here in the front of the yard where Swanson came in, parked and then busted through the door. If you look at the front door, you can tell like bathroom ramp where they hit it in and then busted it down right here. And if you come out here, so shot one through here, I'll go show you that bathroom. Shoot through this window as well.


Nugita lokata kwita, katuhu kwa mahi watu kwa buki ya hwja ujud. Tata kwa hii mtambukha kwa kutua na kwa kwa kuni yubayu kuida. Nijawas, mii wa kutua jende kwa kuna kutisha kikia. Meia hwja na kwa hane kaka mtambukha kikia. Weawe Kusayu Weawe Weawe Weawe Weawe Iwana Maoka Oda Kusayu so kisha kisha. nightsi mae hrda diffuse ongeri atama toki bifuohu humbold maes profession gere is wan na maa menters and both in the private seksa onionchatch I know that I love the Lord and I serve the Lord wherever it is going to. I'm seeing that my screen is not popping up but I'm hoping that when I spoke to Kate and I asked her, first of all I spoke to a person and he said, at the Kedenda, can you come? Can you come to Nairobi Central and talk to the youth? He had called me a number of times, always at the last minute and I have not said yes. So this time I said yes. I think this one, yeah. And so this time I agreed to come and speak. And unfortunately time is not on my side because I need to be at the airport by noon. But I want to talk about leadership. Maybe I want to start by asking you to imagine that car that's called the Prado. You know the Prado? The Toyota Prado? Which part of the Prado do you think is the most important part of that car? Which is the most important part of a Prado car? Take your car. Which is the most important part of your car? Which one? The engine. How many parts do you think make up a car? How many? 5,000? 2,000? It is said that you need over 40,000 parts to make up a car. If you are to count those parts, there are over 40,000. But which parts do you think is the most important again? Which one? All of them. I think you are clever. Yes. Because someone will say it is the battery. But you know the battery will not work without the spark plug. Someone may say it is the alternator. But again the alternator will not work without the connector. And even all those ones, if you don't have the key to get in, it will not work. So all parts are equal. Let's see the next one. So which is the most important part of the car? Every part is important and complements the other. Let me see the next part. So who do you think is the most important person in that organization? Is it the manager? Is it the secretary? Is it the driver? What about your t-boy? What about the messenger who delivers that document? For us it is clearing and for the agents we need the messenger to give the document in time. What about the seller and the buyer? Who is the most important person in that organization? Again the answer is all of them are important. Everyone is a leader in his or her own area of functioning. However, I want to say that no manager is necessarily a leader. Although you can have a leader who is a manager. And why do I say that? It's because managers tend to maintain status quo, but leaders aim to transform the status to a better position. You will find that managers work with policies. They will say 9 to 5. And that is what will work in that office. If you keep another time they will read the policy for you. If you spend beyond on the trip they will read the policy because they are maintaining the status quo. Their job is to keep the policy. But leaders follow policy. While the manager follows policy you find that the leader creates the policy. The leader is the type who will come in and say how long are you going to function like this? You must change this. Corona came. People are now working at home. The manager will be afraid to let people go and work at home. The leader will say go and work at home. I will explain to the board. That's the difference between the manager and the leader. But all of them are important. You cannot say that because the leader is creating policies therefore the manager has no role. You still need to implement it. Let's move on. And that takes us to quarantine. First quarantine is 12. If you want to turn 7, all of us know that the eye cannot claim to be the most important part. Neither my legs do that. Neither my hands are working out there. Everybody. Every part is important. To the extent that I would be a madman standing here talking if you are not there. If you call the meeting and brought these people here and the other people are not there we would be just mad people talking to themselves. So everyone is important. We must take that into consideration as leaders. We must know that everyone contributes to the well-being of us. Let's move on. So what is leadership? It is primarily focused on strategic goals of the organization. But also motivating people to do their work. So that leadership will improve things. It will change things. It will develop. It will correct. It will advance things. And it will eventually bring success. And I want to just give an example that leadership brings changes. Some of us have read about the black Americans and their struggle in the U.S. To the extent that they could be removed from the vehicles and be told to go outside because our brothers, the whites were getting into the vehicle and they had to come out. It took one lady called Rosa Parks to go mad and say that I am not going to. I am not coming out of this car. I am not coming out of this bus. Whatever you say. And sometimes it takes a leader to bring that change. It sometimes takes a leader to say no to what is going on. So leadership is very important. Let's go to the next stage. Okay, sorry. So a leader is someone who takes charge. He is a person who is able to convince people to move on. My sister, you know you are very good at doing that. Okay, when we come to chambers and we want to talk to the associations there are people who can stand and persuade people. And sometimes naturally people default on them. Although some people are very talkative but negatively in the end. So it is a gift that you can have and use positively and here we are talking of positive use of the gift of the gap. So a leader is a leader you want to find the best way to manage your people. You need to be able to have a style that fits in with the people that is able to give direction without overwhelming them giving them the confidence that yes you know that they are contributing to this work and you do want to listen to them not dictate to them. Reminds me of an example I was in Mombasa managing a company. We had a lot of trucks and during El Nino the road to Mombasa was very bad. And suddenly we found that there is a part of the truck that is called the bell housing. The bell housing houses the gearbox and the engine and normally the cover of it is made up of aluminum. So when the roads became bad on a weekly basis we were replacing like three to four bell houses and a bell house would cost almost 150,000. So I went to my transport manager and said what's happening why are we replacing bell houses three in a week and they couldn't tell me they couldn't tell me the transport manager could not tell me why we were losing them so I said I'm coming to the transport department and I want to meet you with the workshop manager because you want to find out why it's not working. We came they could not tell us what. So I called the I called the whole workshop the drivers and the turnboys I know the turnboys don't talk in front of drivers but that day I said anyone who is going to give me a solution to this problem I'm going to give 10,000 and then I saw someone move sideways and he came and said we have been telling them but they don't listen to us we are the drivers we know but they don't listen to us. The problem is that because the roads were rough they are what we call rubber mountains for the engine falling off and as they fall off then the body is hitting against the body and aluminum bodies were cracking but the transport manager could not believe that and so we went and bought the rubbers which were costing us 400 shengs each and we put them there and we solved them and that takes us back to what we were saying that everyone in the organization is important that person and is 10,000 but you know how much he saved us millions, millions because it was terrible doing that time let's move on to the next one next so why leadership? because nothing happens without leadership nothing changes without leadership nothing develops without someone taking leadership nothing improves in any situation without leadership and you can come down and you are always in the end led by someone even here we have been led by someone so leadership is important for all of us do you know sometimes it even takes a madman to be a leader because someone can come to your home and insult you my elder but you need a mad brother to take leadership and throw him out of that place so leadership is a mud of initiative a mud of taking responsibility but on a positive banner we have situations where people have been elected into leadership but they destroy more than build let's move on so good leadership take me back good leadership will not entertain mediocrity good leadership will not allow things to go wrong because the boss is not there and it is the responsibility of the boss good leadership will take the initiative do it and explain it afterwards leaders are usually angry people that is a fact you most likely find that it is it is only when we get angry that things change and sometimes you can go on a routine for so long in an organization until you get one person who works into the manager's office and say this cannot work so it is it it calls for initiative it calls for being brave in doing things brave in a positive manner you know there are people who want to talk loud to the manager to be heard so that he can say but did you hear me talk that is not brave that is foolishness you ought to be an honorable man honorable lady who is able to but there must be a limit for you to be able to say this can no longer work it must change and it must change must not be seen to be rude you can be able to say it firmly to the extent that your boss will be you understand that this is a matter of concern and it will be taken in seriously so it involves tolerance it looks for improvement in everything that is done let's move on so I think the question that appears at the bottom is why are we here so why have we been called here is it because it is an annual meeting where did you come what cost you to live home to be here is it you came to see my elder Prof. Sungeri or you wanted to see the architect what is it that you are hoping to get from this I've heard instances where young people face a lot of challenges in church because the way that young people plant things are different from the way that elders plant things because elders would want to look in and say why are you going to Longonot and youth will say it is an English program and the elders will say it is an outing and sometimes you will struggle over that the youth feeling that they are not being understood sometimes the elders feel that they are wasting money but I always tell the elders that you know if they don't go to Longonot they may not come here I might talk on behalf of some people if they don't go to Longonot just guess where they could be spending their time so when we say are you going to give youth a lunch on Sabbath and some people feel that as a ways they say sometimes it is good to give them that lunch because it keeps them to be in the company of the brethren rather than running out there so you use the opportunity to bring about positive change even when it is difficult and sometimes it takes leadership to be in the charge board to be able to say that it also takes leadership for one of the youth or one of the young professionals to be able to say that indeed what the elders saying is also right because they give and take in leadership so good the organizations that thrive normally thrive out of good leadership good leadership includes allowing others to play their role they don't feel they don't feel intimidated we had a leader in Mombasa that in his organization if he came and met you in the lift he would do this to you and once he has done that he actually sends out a lot of termination just because he doesn't like your face eventually this thing got around and one day the owners of the company came from Europe and they also did this to him and when that was done for him then we on a flight from Mombasa and here he is mourning at how many years he had put in that name and I'm saying to myself does he know how many people he has put into misery by just that you don't like the face of a person when you do this and you actually go to your office and write to show that you have power leadership must have limits and I want to say that transformational leadership moves to the people people must be able to benefit I want to give you an example that we did in Mombasa again just before the 90s customs declarations was done on paper it's still printed on paper but you had to do it on paper and we were clearing motor vehicles in what we call CKDs completely knocked down kits you see them at General Motors you see them packed there you come and you bring them because it used to take us two weeks to do an entry two weeks the lady is just typing to do that so I decided that this cannot happen it cannot continue my elder I went to customs I said I want to computerize my customs declaration I went and approached someone from KPA and brought him into the company he was a systems analyst I went to IBM and approached a programmer then I said I want to computerize our customs declaration now I then decided to have a meeting with my staff the head of declaration came to me and said this can't happen this is impossible I wrote in my heart that this man cannot be in the team he has already blocked his head he has already blocked his mind so I said you go in there talk to these people and get to know how this system works give me a program we did the program in a record time and by just doing the entry on computer we cut the time for doing the declaration from two weeks to four days the problem that we had is that customs say that you must declare on what is called a flimsy paper for us to speed up we were declaring on computer paper and when we got there all our entries were rejected the calculations were right but the paper was wrong so I went to customs and asked them what do you want is it the figures or is it the paper and they said Mr. Kedenda this is the law it is written in the customs act flimsy paper it took us 10 years 10 years to get to the point where we could declare on computer and there were people sitting in those offices who could see that the government could save time and could do but unwilling to change and so if you don't have a transformational mind all that you see are obstacles all that you see is how this is going and you know it was causing us money because every entry that you are passing now demands some money because things are delaying when we got a transformational leader it turned out to be also a terrorist in a way because now it had to be done and be done whether you like it or not and in that instance the country lost a lot of money I am talking to you because you are going to be the managers of tomorrow you are going to make decisions tomorrow some of you are in government some of you are in private organization but you must be able to understand that change is taking place you must be able to go ahead I went to the system commission of customers and look here is the proof why don't we go to Nairobi to prove that it is happening he told me Mr. Kenana looked behind me and when I looked behind him there was a computer that had been donated by the British government that was there that was being used I want you to be men and women of excellence men who are willing to make changes men and women who when you see good things happen you are able to buy that idea and you know even in church we have a problem sometimes because we also have elders who are 19 to Rudy they will not change this is how it has always been done and some of you are going to go in and you will be in that regiment that this is how work is being done in this company I want you to be a different lot of people I want people who can challenge and challenge with humility and be able to present your case so that changes can come through because unless you do it Kenya will always be behind I want to say something that I don't know how to place it All of us who are here it is good to pray and I pray but do something you know there is that prayer that is praying until something happens sometimes nothing is going to happen sometimes it will take you to happen am I making sense that you are praying indefinitely for work and you are not applying you are planning for business in your mind and you are never going out to do business and you are a professional well educated but you have in your mind that you must be employed who said that everyone who graduates must be employed good morning class who said that everyone everyone who leaves college must be employed I have a guy at home in the village and I am telling him that you know people who graduated with you are contractors he comes and works here with some Chinese he goes home and he calls that I am unemployed I said I am stuck in there I said why are you unemployed why are you not employing until we have that transformational mind that says I can do it if my classmate is doing it if he is contracting if he is able to be a contractor of a house in my village why am I looking for employment and some young people young ladies men will be spending time at home and could still be spending time at home now and when you ask them they say that I don't have an employment he is an electrical engineer he is a water engineer people are doing plumbing all over the place but he is saying that he is unemployed and he is living in Nairobi commuting, seeing friends and asking for bus fare good morning class is this what you expected me to talk about or am I insulting you I just want to talk about the truth that our young professionals must be able to go beyond employment sometimes it is your better off starting of non-employed than being employed I want to give you an example quickly so that I can move on I thank God that when I graduated from Nairobi within one week I was employed within one week I had a company come as thank God I could drive around I had a subaru, a very good car then I went to Mombasa I got a good job in Mombasa but the company belonged to the owners one day when I am in Nairobi I get a phone call and I am told to report to the Ministry of Transport and when I get to the Ministry of Transport the P.S. removes a letter and gives me and says I have been appointed to head a parasitinal I said I have not applied I have not applied for this job I don't know who is giving me this job I don't know, I don't know but the ones appointing me is the owner of the company so I go do you know that my employment there ended like that I could not say no I am staying because the one who is appointing me is the owner of the company and is the owner of the government so it went it went so I went to that company I served for three years and then one day someone calls me Mr. Kidanda do you know that so and so has been appointed to take your position I want you to know this because some people may not tell you experience of what goes on you are fighting for jobs you are trying to be appointed when you are appointed those days used to be appointed at one o'clock you could also be disappointed at one o'clock so even today you can be appointed and be disappointed there are people who just saw in the papers that their positions have been taken in the recent appointments so how do you handle that for the last five years you've been driven around and now you don't even have a car you had someone who was appointing the door for you ok now no one is opening the door and all this time you are spending your time with the people who are rioting if your friend buys a car you also buy a car if they change the TV you change the TV it happens I'm talking to these young people because that is that I'll give you one last time so I'm staying here in Westlands and my neighbor is competing with the other neighbor there are young people like us this is the early 80s ok so they buy a colored TV and I think his darling was saying how can we remain here with the white black and white they won't buy then this guy goes and buys a new car a saloon car this guy goes to the office ok he takes a loan buys a new car after a while this gentleman arrives with a range rover he has recently just taken a loan he doesn't know how this guy is working ok all he knows is that this guy he looks like my age mate our children so if he buys a car I'll buy a car let me tell you how this guy was buying a car this guy used to go and siphoned oil from pipeline he goes and takes a whole tanka few of charge and when he says it he can buy he can buy the range rover in those days so I want you to be level minded I want you as good Christians I thank God for the lesson for this lesson did you hear about covetousness did you read about it did it mean anything to you there are people who will not tell you these stories now I want you to take these stories look after your work be exceptional in your work do a good job your company is able to pay for you your medical bills do a good job your company is able to train you do a good job because there is a time that is coming and that company is going to restructure then you will find out you will find out how difficult it is to go to the hospital am I making sense to anyone here you know when you have the medical medical card you go to the hospital what happens when you are stretched and now you can't go to the hospital and you didn't invest in that line I am talking to you young professionals to be good stewards to learn how to save to learn how to invest learn how to invest last comment have you heard about Amazon have you heard about ebay how many of you buy through ebay just say I am not going to say a bad thing I want to tell you something that is happening to Africa that I want you to remember while Africans are fighting themselves in business Europe is merging to do business in Africa they are clearing and foreign companies are merging if you hear something it is a merger I wish I had one Ongeri Kidenda that I could work with learn to start working as a team and just be diligent in your work don't think that you can win that contract on your own you are going to borrow too much you will call your wife if you are married you will call your parents and everyone else learn to work in partnerships and just be faithful just be faithful to the work that you do so that you can grow it is no use working into the city here looking for contracts which are going to cause you to borrow a lot of money which you could have shared and then one day you are sold off I would like to kindly request that as good adventists as good professionals I am going to share with you my people professionalism in your work bring it in there and do it just like those other people are doing it be diligent in it and be willing to be patient to grow your business don't be in a hurry because when you get into a hurry you become corrupt you do not want to say it but it will force you to be corrupt it will cause you to get into debt that you cannot afford and yet you have partners here in church that you can partner with choose them well choose them well because even here in church they are conmen they will con you they will go with your man but look diligently look carefully and get into business because the government that used to employers you come from you come from graduation and you get a lot of appointment that government is no longer there there is no one who is going to give you that you are waiting for a lot of appointment even the teachers are not getting those letters of appointment I don't know whether I am making sense to you you must have a transformed mind and this professional body here can take you far if what my sister here is teaching you the things that they are talking about here if you put them in practice you will go far but if you walk alone you will walk long but you will not go far you will just be wasting money in things that you can't afford have I talked badly if I have talked badly forgive me but I wanted to tell you this because I see it I see it and I have walked it I have walked it I told you one time I was given a lot of the place where I was appointed I was now terminated on a fax machine they asked Mr. Kenanda are you there yes are you in your fax machine yes I got this appointment that you are looking for here unless you want to go and steal but you are there if you are going to you are better off doing your own business than going in some of the disappointments because at the end of the day at the end of the day you will pay idiot for it go and do it but I am saying be careful be faithful be a good steward in Jesus name


Sai wakes up one day and discovers that the world is now filled with INFJs by assembling upon the front page of the newspaper. Breaking news, a new century of empathy. Entire population, now INFJs. He goes to turn on the TV to find out more, but the power is out, and his phone won't turn on. He looks up at the ceiling and wonders, what in the world is going on? To find out what happens in the world run by INFJs? Keep watching. When Rare Becomes Ordinary To understand what an INFJ world would look like, we first have to visit Sai's favorite class, Psychology. Sai's teacher, Mrs. Lapper, helps explain where the INFJ personality was born. She explains that in World War II, Isabel Myers and her mom Catherine Briggs began researching and developing a personality test based on the work of Swiss psychiatrist, Carl Jung. Over the next two decades, their instrument was developed and the Myers-Briggs type indicator, MBTI, was created, which includes 16 different personality types, with the INFJ personality being the rarest of them all. Sai looks down at his textbook and it reads, INFJ, the advocate, the principal, the people dedicated to making the world a better place, the earth. With the entire population now INFJs, there are no cars on the road, as INFJs aren't suited to a career in engineering. Instead, there's a community of people using the roads as one big sidewalk. The earth is starting to heal and more sustainable practices are being implemented. The economy is focused on locally and ethically made products. Community gardens with organic produce are found in every neighborhood. Packaging now produces less waste and the oceans are receiving less plastic. Air is cleaner and the oceans and sea life are starting to replenish. Storms still come to visit but the population stays calm and kind in moments of intense weather offering emotional assistance but it struggles to offer practical solutions and build emergency shelters for its people. Families have been separated with the retirement of airplanes, boats and trains. No time for fun. The recess bell rings and Sai makes his way to the corner convenience store. He had forgotten his snack and they always carry his favorite treats. But as soon as Sai opens the door he quickly notices the shelves are empty and in their place are chairs facing towards one another in pairs. Sai takes a step back and reads the store sign, a safe place for conversation. On the magazine rack a title reads, Is world peace now possible? Conflict in the era of the INFJ. In a world run by INFJs, opportunities for meaningful discussions have taken precedence over the need for things like convenience stores or treats wrapped in plastic. Critical care. As Sai makes his way back to school he runs into a group of protesters protesting for better medical intervention. In the new era of an INFJ population, chronic and long-term illnesses are improving but emergency medicine has almost become obsolete and people are dying unnecessarily. INFJs struggle with making quick decisions in high-intensity environments which has meant that emergency medicine has almost become extinct. Let there be light. As Sai's school day ends and he makes his way back home, the sun sets over the town. Candlelight shimmers in the windows of the homes and businesses along the street. With no electricians anymore, society now runs on candlelight in the warps of fires. Smoke fills the air and the world starts to turn grey. The illusion. Sai opens his front door and reaches for his phone, forgetting it no longer exists. Advancements in technology have stopped and Sai misses communicating with his friends around the world. He makes his way to the kitchen and sits down to eat under candlelight with his grandmother. She asks how she can support him and how his day was. They have a deep conversation on the meaning of life and their existence on earth. Their sensitivity for him and his day means a lot. But he can't help but feel that the dinner conversation is starting to become all too familiar. As he slips into bed, he looks over at the quote hanging over his bedroom desk and it reads, in diversity there is beauty and there is strength. Maya Angelou. He falls asleep, knowing tomorrow will be a better day. Because today was just a dream. What do you think the world would be like if everyone was an INFJ? Let us know below. Thanks for watching and we'll see you again real soon. And remember, you matter.