This is stock number 10303. We are here at Summit Automotive in Fond du Lac, Wisconsin. You're new and used heavy duty truck headquarters. Today we are checking out this super clean 2016 Ford F450 crew cab long box dual rear wheel. This truck has the 6.7 liter power stroke diesel and from this HD video you will hopefully be able to tell just how clean this truck is all the way around. Platinum tri-coat metallic is the color we shoot all of our videos in 1080p so if you have HD capabilities on your computer tablet or smartphone device turn them on right now because it is like you're right here looking at the truck with me and definitely your best way to check out the vehicle before seeing it in person. If you want to check out this vehicle on our website you can click the upper right hand part of your screen the link there goes right to this vehicle on our website polished aluminum rims Continental HSR 22570R 19.5 tires have about half the tread left frame and under body on this truck is exceptionally clean and you'll see when we get to the back of the vehicle just how clean that frame and under body is. Driver side fender is an excellent condition no scuffs or scrapes on that you get the kind of silver painted grille with the platinum package hoods very clean no dents or dings on that passenger side fenders in excellent shape as well and the passenger side rim pretty nice and clean passenger side tire is just as much tread as the driver side as you go down this side of the vehicle you can see just how clean the body is how reflective and mirror like that paint is we take these HD videos so if you are far away or even if you are close by and just cannot make the trip down you can still see the truck hear the truck and have confidence in the vehicle that you're looking at before you even get here so that you can make a smart buying decision from the comfort of your own home in fact we offer a fast pass option where you can apply for financing find out your payment numbers get a trade number basically work your entire deal right on our website from the comfort of your own home look how clean this frame and underbody is on this truck wow it is like new under here as all the remaining factory exhaust has not been messed with so it has all the all the factory exhaust factory chrome step bars back rim is an excellent condition as well and the back tires have just as much tread as those front tires frame and under body under here is just as clean look at those box rails like new has the anti sway bars camper package and just very very clean underneath this truck get the platinum block lettering on the box there as we come around to the back of the truck you'll notice the rear bumpers and really nice condition no major dents or dings and that does have full towing package of course being an f450 with the full towing with the receiver hitch four pin and seven pin wiring tailgates in excellent shape no dents or dings on that get the cool platinum styling on the back there has the tailgate step assist which works good has a line x brand bed liner and a Reese elite re 26.5 fifth wheel in here you also have the seven pin wiring and the line x logo right there it has a retracts rolling tonneau cover that's a really nice tonneau cover on there and down the driver's side just as clean as that passenger side the dents or dings on that dually tub and this back rim is an excellent condition as well for full disclosure down the rest of the side of the truck very clean has driver's side door code entry we do have the code for that inside the platinum package gives you the power windows power locks power mirrors it has the telescopic tow mirrors or power scope as Ford calls them they power fold in they also power telescope out like so and telescope in just to show you that both sides are working properly there you go power windows power locks power mirrors inside the platinum package gives you the brown and black two-tone leather interior platinum stitching to the backrest both these seats are heated both these seats are cooled I believe factory floor mats throughout auto headlamps power pedals and as we hop inside the truck here you can see that this one has 46,852 miles instrument cluster is very nice and clean comes with a leather wrapped and wood grain trim steering wheel you got bluetooth and audio controls on the right cruise controls and information center controls on the left and this is actually a heated steering wheel on here and six speed automatic transmission how do I know it's heated because the my forward touch radio shows me the climate controls you got your heated and cooled seat buttons as well as your heated steering wheel buttons dual climate control this one also has the factory navigation system and the backup camera shows up right there as well if you don't like the buttons on the radio you can do the more tactile buttons down here factory exhaust brake you started that in 2015 turned out four-wheel drive factory brake controller 110 volt 150 watt plug-in and it does have the sync system for your bluetooth phone connectivity passenger seat is very clean no rips or tears on that headliner is in excellent shape side current airbags and it does have the power sunroof homemade buttons for your drive jar security systems and lighting systems power sliding rear windows and map lights up there we'll take a quick look at the back seats and then we'll check out under the hood really nice and clean inside and outside wouldn't mind having this truck myself the back seats are heated on the outboard side has the platinum stitched into the backrest power slide rear window with the built-in rear defrost these seats do fold up for extra storage and it is a lockable storage compartment underneath here that locks with your ignition key factory floor mats and carpeting is an excellent excellent shape back here another 110 150 watt plug-in plus a power point and this one does have the sony sound system which gives you the factory subwoofer back here you also have the tether anchors for child safety seats and those heated seat buttons are located on the doors on each side for the outboard side of the seats and finally it does have the child safety locks right there we'll take a quick look under the hood and I would personally like to thank you very much for checking out the video we work really hard at these videos to make sure that you get the most accurate representation possible so that when you get here there's absolutely no surprises under the hood we have the 6.7 liter power stroke diesel engine bay is very clean runs very smooth this truck has been fully safety to and inspected by our service shop has a fresh oil and filter change all the fluids have been checked and topped off the truck has been gone through mechanically 100% and is 100% ready to go I'd highly recommend it from a quality and condition standpoint and to see more pictures of this truck or one of our other 450 new and used cars trucks SUVs minivans wranglers half tons three quarter tons one tons you name it we got it go to our website www.summitauto.com full pictures and descriptions of every single vehicle from two locations all at summitauto.com and if you'd like to check out more HD videos you can go to youtube.com slash summit auto remember to like subscribe and share on this video and all the videos that you see there in fact in a second you'll see a link to subscribe to our youtube channel on your left a link to more heavy duty truck videos like this one on your right if you have not been to our website on the bottom link to this vehicle on our website click those check us out and we really look forward to helping with this super clean 2016 Ford F450 crew cab long box dual rear wheel platinum power stroke diesel thanks again


Good morning everyone. Good morning everyone and welcome to my self-care morning routine. I'm going to spin class this morning.  So I wanted to take you guys with me on my little self-care morning routine to show you guys what I'm doing this morning. I'm so excited. It's gonna be awesome. So if you guys have not already be sure to subscribe and comment down below.  Okay, I'm picking out my outfit. I'm gonna wear this in joggers after I work out and to Alfred into like my massage. Something like cozy. I'm going to pull my hair back into a really tight bun. I washed my hair last night so I really don't want to wash it after this workout because I've been washing it too frequently. Which isn't good. Alexa, what time is it? The time is 740 a.m. Okay, I just put my hair back in a bun.  Let's be real. My tiger grass stuff that you guys are definitely tired of reading about. I feel like I look like a ballerina right now. I'm gonna brush out my brows, then I'm gonna put a little facial oil on. I need to brush my teeth. Okay, I'm gonna read in my bun. It's just like half my life is that fixing my buns. I fixed it. I like this one better. It's not as ballerina-y. It's just right in the back. I'm a fan. Okay, so this is the little bag I bring in my gym bag and I don't know if I'm gonna wash my hair after. So I need to bring both brushes just so I have options. Here we go. Here we go. And here we go. Then I have this for when I take myself out for coffee after. My water bottle and that should be good. All right, so I will quickly show you guys what I'm wearing. All right, so I have this matching set. This is actually from Forever 21. I really like this for all the leggings are like I'm kind of over them. They're not really holding up well keeping shape, but like what do you expect the forever 21 leggings, you know? Since I'm going to spin I'm just wearing slides because you have to wear spin shoes and then I just throw my denim jacket. I'm gonna wear this after but it would just be easier. My hair is back in a bun. I have little earrings on. I really like wearing little earrings when I work out very random, but this is my look.  I have some in the fridge that are so good. I made a vlog where I show how I make them too that I will have a link down below. But I'm heading to the kitchen and then we are out of here. And of course, gotta grab my purse and make sure that my lip balm is in there. Me with my 15 bags. It's great. Love that for me. Oh, look who it is. Still me with my 15 bags. Okay, what are you doing? There's just some good overnight oats, you know? Love that. Love this. I'm tired. This morning is just kind of like a me morning taking care of myself. I booked a spin class that's soon. This lighting is just not good, so we're just not gonna. Great, great, great, great, okay. In the spirit of self-care, I'm just gonna put on some really motivational, inspirational music. Yeah, but listen to the song. Please go listen to it. Oh my gosh. So, like I was saying, this is just a self-care morning routine. So I'm going to spin class, I'm going to get some coffee and do a little reading, and then I'm going to get a massage, which I'm very excited for. And sometimes you just need to take some time to. I always do my morning routine and I'm always doing my like routines, but sometimes you need to take extra time on yourself. And it's Friday and that's what I wanted to do. So I hope you guys are enjoying this video. If you guys are, let me know and comment. I posted a little mini Instagram video of this video. So if you guys are coming from there, you guys should comment on it and comment that you're coming from the morning routine. But yeah, I'm about to pull up, eat some overnight oats, and go spin. I love spin. It's like so fun to me. Oh my god. Okay, so I have a few minutes.  I don't know what to eat. Now I'm walking next door to Alfred. It's so cute. Like that was like literally the head of my life. Coolest thing that's ever happened to me. Just got my beautiful ice chai. Ice dirty chai. So freaking good. I just read on first crampions, which is incredible. And then I posted an Instagram photo and I'm just feeling so good and so grateful for my life. And I got an ice dirty chai. But I am about to drive over to my massage just down the street. I'm really excited. I'm trying this new place. I'll tell you guys about it in the car. Saying I'm going to this new massage place. So if you guys are familiar with Drybar, which I feel like the majority of people who watch my videos would be familiar with Drybar, then you guys know Allie Webb is the founder of that. And she just started another company, like Massage Place, whatever called Squeeze. And they gifted me a massage. So I'm so excited for this, guys. I've been at a massage in forever. I really take self-care more seriously. And self-care to me is a massage, you know? What's self-care to you? Mine is definitely massage. So I'm going to drive over there. It's like super, super quick. Guys, I just went into Squeeze and I got the best parking spot. It's literally right in front. It's little things that really make your day. All right, here we are. This is the coolest massage experience I've ever seen. Like, you can completely customize it. This thing, I'm using a flash right now. You can just like, you'll see on the screen. I'll put it on the screen with my phone. But like, you can customize everything.  Wow, love it is. Just finished my massage. It was incredible. I feel so good. Oh my gosh. All right, guys, I just got out of my massage. I feel like I should be talking slowly. Like, they do at massage places. This Tesla is trying to take my spot. I wasn't really trying to leave yet. Ma'am, sir, whatever. So, um, one second. I feel so amazing. I figured it was going to be incredible because Ali Webb is just incredible. But squeeze. Oh my gosh, I'm calling it out. This is going to be the next big thing. They're going to be everywhere. So if you guys don't have one near you, they'll have one soon. But if you live in Los Angeles or you're anywhere around there, like 10 out of 10 recommend, it was so incredible. Basically, you're able to customize every single thing from the light settings to the music to like, obviously the massage, the heat, like you're completely in charge. So for like control freaks or people who are very specific, I'm thinking of like Lauren from the skinny confidential. I actually need to send that to her because she would love squeeze. I need to tell her about it. Actually, I'm going to, I'm literally going to tell her right now, but it is so freaking, it was just incredible. Like I can't even explain to you how amazing the massage that is. And I just feel so good. It's so important to spend time on yourself and for yourself. And I'm so glad that I did this because I just feel really good and very happy and very grateful and really relaxed. So I hope this inspires some of you guys to just take a nice morning. If you guys do, please, I love when you guys tweet me and tag me and things on Instagram or whatever, Twitter, all of that. It's always linked down below and I'll have it on the screen. If you guys want me to do an entire podcast on self care, let me know in our secret Facebook group or the comments down below or whatever. But I'm going to head home now and start off my day.  If you did, let me know by giving it a thumbs up, subscribe, do all of that stuff. I love you guys so much. I feel so amazing and I'm so glad that I did this. So be sure to subscribe again. Love you guys and I will see you soon. Bye.


back to my channel everybody or welcome if you are new here in this video let's talk about children and cavities so if the dentist tells you your child needs the cavity filled right away or if the dentist says oh we're gonna have to put your child to sleep or we don't have to worry about that cavity it's not big enough this can often be very confusing because you might be thinking well why was it last time they had to get a filling right away my my child's only five or my child's two but they're recommending we put them to sleep for dental work or this cavity is nothing to worry about they noticed a sticky spot they said it's okay they took x-rays no worries what are the differences between all of those so basically the earlier a cavity is caught the better especially in children for a number of reasons one of them is because your child isn't going to want to sit there to get a needle to put the tooth to sleep and then they're not going to cooperate for half an hour while we try to fix the filling because how fillings work is we have to take the cavity out first that is with the high-speed handpiece nobody likes that and then we have to put the filling back in or sorry the filling in once the tooth is you know drilled out for lack of a better word and once we put the filling in it's going to be kind of lumpy so then we have to polish it out make it smooth it's no fun for adults remember when you had your cavity filled you had to sit there well we kind of do our thing it's no different for children but we do try to work much faster so anytime the dentist says we don't have to worry about your child's cavity you're probably thinking oh my goodness thank goodness because I don't want them to have to go through that or on the opposite side of things what if the dentist says mmm your child needs to be put to sleep this is why so if the cavity or cavities aren't caught early enough sometimes a child can have what's called rampant decay where there's cavities on five or more teeth and they're just not in very good shape we know as dental professionals we know that that let's say five-year-old or younger isn't going to sit through that for two hours while we fix everything so often it's recommended in that case to have the child be put to sleep so so they can do all the fillings at once the child's put to sleep nothing to worry about and of course the child is cooperating because they're put to sleep so everything can be done in one shot just as a side note I always try to avoid children being put to sleep because they're under general anesthetic they're put to sleep so I always prefer to get to those cavities before they have a number of them where they do have to be put to sleep and it's also very expensive you're looking at $2,000 or more just to fix maybe five cavities so imagine the more they have the more expensive it's going to be so I always try to catch cavities early there is such a thing called silver diamine fluoride which is a liquid I call it the cavity killing liquid if they have a cavity or even five cavities if it's caught early enough where it's not quite through the enamel yet it's not going to be near the pulp near the nerve we can apply that simple drop to kill that cavity it takes half a second often the child doesn't even know we're doing it I put it on a little micro brush a little drop on that micro brush while I'm polishing you know getting all excited about polishing their teeth wow those teeth are looking so shiny I take the micro brush I kind of dab it on and then just continue polishing they don't even know I'm doing it if the cavity is caught early enough we can do that to one or more cavities it's a lot cheaper the child doesn't even know they don't even need a needle none of that so I'd say that's a lot more exciting right and having to pay thousands of dollars to put them to sleep but we talked earlier about what if your child needs a filling or several fillings we can only do fillings on children if they're cooperative because that mouth has to be kept open maintain a dry field but we have to put the tooth to sleep using a needle we try to kind of sneak the needle in there you know so they don't know we're doing it but they often do it's just not a nice situation but some children obviously do much better than others but a filling is needed if let's say there is a cavity in there there's this big hole that's through the enamel and there's this big hole we can't just leave the hole there by putting in that simple drop the cavity killing liquid we're not putting a filling in to bring that tooth back a drop isn't a filling it's just kind of killing the cavity what's there but with the big hole you don't want to keep that big hole there right because when the child's kind of chewing they're not going to be chewing well so we need to bring that tooth structure back by putting in a white filling but if we find that the child's not going to cooperate or there's many many feelings to do this is when we recommend the child is put to sleep so we can do our work and not have to worry this can happen so if you're doing everything you can but you don't go to the dental office often enough to get a checkup and those cavities are bigger there's a big hole or maybe you didn't notice now your child needs a filling we will try to do it in the dental office if it's caught early enough or they may have to be put to sleep but often too we look at how long is that child's tooth going to be in the mouth for let's say they're two years old and they have two fillings their first tooth isn't going to be lost until age five so we can't keep an active cavity in there for a couple years that's just not going to work it's going to get bigger it's going to cause them pain we can't do a filling on a two-year-old so this is when we have to put them to sleep but let's say we notice a cavity where that tooth is going to fall out within six months sometimes even a year we might say to you they do have a cavity here we could fix it if you want but that tooth is going to fall out soon anyway so why waste the money why put them through that by doing a filling just brush it well so it doesn't get bigger because we don't want it to get bigger within the time it's going to fall out and then it causes the child pain right so there's many different instances and many different things we look at so just as a recap get your child in earlier at least every six months for their dental checkup because we can catch cavities early enough even if I'm looking at a cavity and I say that cavity is really small I never say let's just check it next time I put that drop on right away so it doesn't have a chance to get bigger that cavity killing liquid if I wait six months it's probably going to get bigger and then we need to do a filling or something else right so get your child in earlier the earlier the better once we do find a cavity we look at well how big is the cavity can we just use the cavity killing liquid or do they need a filling if there's a big hole we need to put a filling in to kind of make it look like a tooth again or are there so many cavities is the child so young where we need to put them to sleep to get the work done so these are the different things we look at so I know it's a lot but let me know if you have any questions comment below I've been a dental hygienist I've been a dental professional for 18 years I've had my own mobile dental practice since 2018 where I come to patients homes to clean their teeth and do dental hygiene checkups so if you're in the Winnipeg area you can book an appointment with me I would love to see you thank you guys so much for watching click like if you do like this video that does help me in my channel and I'll see you guys in the next one


Hey y'all, what's up? My name is Sonali, welcome to a new week in my life. Last week, I didn't do one because I had so many random appointments, which all ended up getting canceled. Lovely, I know.  I thought I was a pain pill, but I guess it just calmed my anxiety down. Anyways, so I just didn't vlog last week because I literally thought I was gonna be drugged like two days out of like the five, but that didn't happen. But anyways, we're here this week and we're gonna make it a good one, we're gonna make it a productive week because in like two weeks, or maybe am I going next week? Okay, so Ryan's going home this week for a wedding and then I'm going to California next week. So I'm really excited, but I feel like I have a lot of work to get done before that so I can like actually chill and not really have to worry about like filming and you know, TikToks and all that. Obviously I'm gonna like still make TikToks in California, but I'll mostly be with my family. So I want to like make sure I get everything done before I go there. It is Monday and I had an early morning shoot. It was a maternity shoot and we shot at UT Austin, which I shoot there like literally every single day from I don't know, March through May because I do a lot of grads and I'm a photographer here in Austin if you guys are new here. So we went there to beat the heat in the morning and it's just such a versatile photo location. So I feel like I recommend it for like a lot of things like senior photos or obviously grads, maternity, family photos, anything, honestly, especially in the summer when there's not that many people on campus. When I came home and showered during my skincare routine, I have this little pimple patch on my face. I would die for pimple patches. The fact that they were not invented earlier, like, especially in my teen years, I wish I had them even though I didn't have like that much acne, but they do so much in so little time and it would have just been so helpful back then. But it is currently 9.30 and I actually have a nail person coming to my apartment at 10 a.m. Later this week, I'm going to an influencer event for Essie, the nail polish company. So they gifted us an appointment with Cherry, which is an app that you can book nail artists or like just give you a pedicure or manicure at home. I'm pretty sure they have other services, maybe, but I've actually worked with Cherry, the company before, so I actually have had a couple of these people come to my house and they do a really good job. I'm pretty sure you can do gel too, but I think today's manicure might just be the regular nail polish. I'm very excited because my nails do need some lovin'. I got like gel on them. They are a little bit grown out so it's like literally perfect timing.  Have a minute to set it up. Okay. I think I'll go for the white. I feel like this is very trendy. Hailey Bieber chrome nails. Yeah, I think I'll do the white then. Here are my nails. I thought they were gonna be more of a white chrome, but they're more of a purple chrome, which are still cute, very different, though, for me.  They freaking hurt so bad. So yeah, I definitely need to chill with the gel X and even just gel. Maybe I'll try to start painting on my own or just stick to the press-ons. But it is lunchtime already and I'm gonna make a chicken snack wrap. I got frozen chicken tender things from Costco and then it's so easy from there and I'll show you guys how I make it. So I use these tortillas. They're the card balance and there's so many calories for one tortilla. I usually just use one because it's pretty filling. So you literally just take your tortilla. I don't toast it because I don't think the McDonald's ones are toasted. I just have this bag of lettuce. I just put it, spread it out kind of. Then we got our mild cheddar cheese and I literally just air fried some frozen chicken strips. And I personally like to like pull them apart and just like cut them up a little bit and honestly like one chicken strip should be good enough.  And you could put like honey mustard with this or ranch. Then I'm gonna do ranch though. So it can be just like the McDonald's one. And that's literally it. I mean, I don't know how to wrap it like they do. I definitely probably need it like a bigger tortilla to wrap it. But like, look how good that looks.  So I'm gonna enjoy this, have my little lunch and I need to get to some emails for the day. Kitchen's a mess. I'm frantically trying to cook dinner. Vacuum's going because my friends are coming over tonight for Bachelorette. I feel like this is gonna be like a every Monday thing. Bachelorette literally just started last Monday. And I think I might be like one of the only ones with cable. I'm not really sure. But anyways, I love having my girls over. So I don't even mind it at all. But I'm cooking some butter chicken, literally just chopped up chicken, added some random seasonings.  And I'm randomly obsessed with this brown rice. I don't know why, but it like just tastes so good. So I'm just gonna do a quick little meal. And I also wanted to make like a fun drink. Some agua fresca. I saw a TikTok of this girl making it. And I was like, ooh, that looks so refreshing and good. And sometimes I like to make stuff like that when I have friends around. So that I don't have to like drink it all.  So I might do that if I have time. I'm trying to rush, make my dinner. And then if we do have time, I'm gonna be making some agua fresca. It's not loving Daisy right now, but you can be honest. What does it mean more? I like it. Does it mean more lime? It's really good. I wish there was more. Well, good to know. Then maybe I'll make it one day. Yay. Should I put more lime? Yeah. Okay. Am I? Yeah. She always bartons. Ooh. Oh, yeah. Still in the same outfit because I woke up at 6 a.m. for an early morning shoot. And it was already out. I didn't really want to like rummage through my clothes to find something to wear. So just in the same sweat set. Also, this is from Outdoor Voices. Ryan just got me a surprise coffee from Starbucks. My order is a grande iced waimoka with oat milk. Half, wait, does this say halfty calf? So it's half calf, Ryan, you got me. No whipped cream, but like substitute the whipped cream for salted. Wait, what is it called? Salted caramel cold foam. That is my order. Today is a very exciting day. But first we are taking out Sophie on a walk. How far are we gonna go? Just a little light walk. Hmm? Just around the block. Just around the block. Okay, let's go. Come on. Have you guys switched over to the small camera which I've honestly been really contemplating just fully switching back to this one. It's the Sony A5100. And I currently film my vlogs on the Sony A74. But it's so big and so chunky. And I feel like I would definitely vlog a lot more outside of my home if I like switch back to the smaller camera which is this one right now. So tell me what you guys think about the quality. I feel like I just get so embarrassed pulling out that big chunky Sony A74. So I don't know, I've been really thinking about it. But we're headed to Culture ATX because I'm gonna do something different to my hair. And that is going completely dark. We're gonna go natural.  Kent Lime is definitely inspired by the Kardashians and Kim's hair in the new Kardashian show is just so long and black and it just looks so good. So I was like, you know what, let's do it. Also, Ryan has no idea that I'm doing this and he has been just telling me like I should dye it back for the longest time probably since I dyed my hair, honestly. I think he just prefers me with black hair. And honestly, I have a lot of trust in him. He like styles outfits better than me. He knows like the trends before I do. Not to reference the Kardashians again but I feel like he is my Kanye. Hopefully just like the good beginning part. Like he's my stylist and he just like knows what looks good for me and what looks good on me.  And I'm so excited. I'm very nervous though. Like, what if I hate it? Because I do love the dimension in my hair but it's honestly just so much maintenance. Like the brassiness in my hair I can't deal with. Can't remember the last time I got it toned. But I feel like it wasn't that long ago and it's already brassy. And I know I'm like swimming a lot and washing my hair a lot more in the summer. So that could definitely be the reason. But I'm just like, you know what? Let's just dye it black. So hopefully I don't have to deal with that. I don't know if like it lightens back up or what but hopefully it doesn't. I'm with Rihanna at Culture ATX. Yeah, literally again. I feel like I come here a little too often. But we're going darker. So like, I don't know how do you do it? You just take the color and just. I don't know. What are we doing? Like we're going this. Like all over that. Like no dimension. Just straight out. No. Okay. Are you sad? All your hard work? Well, we're definitely going to do a toner. I just would never suggest doing permanent because I know at some point you're going to want to go back to your life. The same? Well, it's just if you did this to me. I don't want to side fade that much. That's my issue. Because I feel like the last time we did toner I don't know. I don't remember when but I was like not that long ago and I just feel like it's so brassy. Yeah. So we're going to do, it's still going to be non-permanent for sure. Like there's nobody I would suggest doing permanent all over. Like it's just going to look one color. It doesn't even look natural.  Yeah. So, I mean it will fade eventually but we'll use something stronger and then we'll apply it dry so that your hair really absorbs it. Okay. And hope for the best. And I'm thinking like it should last you at least like six months. I feel like my hair just looks like thicker too. Not crazy. Yay. Here's the final product. It already looks so much shinier and more healthy. And I'm just so happy that I did it.   Just frames the face so well. I just feel like it was about time for me to go back and just like the maintenance of dyeing your hair. I can definitely add up. It's pricey sometimes. And I'm not even like blonde. I know some of my blonde friends that pay so much like every six weeks or something like that. I was mind blown when my friend told me that was like, that's like almost every single month. Maybe it's a little bit longer of a duration but still at so often to pay that much money. But with my cut and color, I paid 285 with tip. So I mean, that's still a lot but I feel like I was there for so long and I'm hoping it doesn't fade so I don't have to like go back for a while. Like I don't have to get my hair done every six weeks. So thank God. I'm kind of feeling chatty. I might get on TikTok live. Feel like I haven't done that in a while and I already have my makeup done but I'm going to get in my cozies and maybe like cook some dinner. I had the leftover butter chicken for lunch. So I don't know if I really want to do like a chicken dish. I also have like dye still on my face. I'm going to wash it off later. I was already like marinating the chicken. I was just going to do like some sheet pan taco situation but I think I might make euros instead because we bought the Euro meat from Costco and I'm hoping we sell pitas. If not, we have tortillas and then I can cut up like bell peppers and onions and all of that jazz. I feel like I'm just all about the easy meals but guys, oh my gosh. I totally forgot to give you guys my review on the Agua Fresca that we had last night. I'm literally craving it again. It was so freaking good. It was like a lot of cucumbers. I didn't really do like an exact measurement but I did follow a TikTok recipe. So I'll link that down below. I've just like what to put in it but like not how much I guess. So I think I did like six cucumbers and then I did a bunch of lime and then I kept kind of like adding in like lime and sugar and water to get that taste right. And then the tijin ram was like the cherry on top. Oh my God, it was so good. I'm also probably dehydrated because I feel like I have been so bad at drinking water today. So I'm gonna go fill up my water bottle and get on that. I just went on live for a little bit and I was just kind of like prepping dinner while I was doing it so we're doing a little chicken taco sheet pan kind of thing. I'm always telling you guys about this little chicken taco packet but seriously I have like 10 of these in my pantry just in case we have one of these nights which is very, very often. So that's why I like to stock up but I also made this really freaking good drink. I am obsessed with Sprite. So I think it was like a couple of years ago. No, I don't know. I was in this low calorie phase and we found these at our grocery store, Sprite Zeroes. So that and then these like little true lime packets. I saw this TikTok girl using these and she puts them in her Diet Coke and there's not like much in the packet so I was like, is this even gonna like make a difference? But it really, really tastes like a fresh lime that squeezed into my Sprite and I'm kind of like shook because I always do like a little bit of lime and then if I have some, I usually like to put mint leaves in it so it's like a virgin mojito. Tonight we're doing it without the mint leaves. It still tastes like so good and this whole thing in zero calories because the freaking true lime thing is zero calories too. I'm not counting calories right now but like I said, Sprite is my weakness so knowing that this is like literally zero calories is quite crazy.  I got guys, guest one just arrived. Okay, in my last weekly vlog, I got the Bottega Banana Dew for the noodle bag and I talked about how I bought some stuff off of DHgate. Honestly, I'm kind of surprised that this is even here right now because I didn't know it would be that fast. Well, I guess that was kind of a couple of weeks ago. So anyways, oh, there we go. Okay, let's do an unboxing. So like I said, this is not real. It's a dupe, comes in this little duster bag. Smells like leather. Do we love? So this is what it looks like and it clasps right over here. You put the little L in that little loop right there. Wait, Ryan, look. What do you think? It looks nice. This is the YSL Hobo bag. I'm gonna put the exact DHgate link down below because there's a lot of listings for similar bags. So I feel like now that you guys know what this listing looks like, I don't know the differences between them. Also, if you guys have this bag, let me know what you guys think. Like, does it look real? Does it look fake? I can't really tell, honestly. Like, I don't really have designer items so I wouldn't be able to tell, but I really like it. I actually just went to YSL as a domain and I saw this in person, but I don't know, I would need to see it side by side to like know the difference, you know, and like the feeling of it. Morning, it is Wednesday and I went in for some cavity fill, so I'm very numb still and he said it would wear off like an hour, an hour and a half after the appointment. The appointment was at nine, it's almost 12 and he said not to eat anything until the numbing goes away and I'm starving. I was literally starving going to the appointment so I wish I would have known that. So I just made myself a smoothie and it's actually so hard to drink because the cavities are like on the top of my mouth, I guess the top row of my teeth. So like my lips like just don't work, but hopefully this chills out because I literally have an event to go to and I have a really important call at like 2 p.m. And I'm pretty sure it's a video call, so can you not? It's so weird, it feels so weird, but I'm really happy because I was supposed to go in for three appointments to do all my cavities, like he was gonna do like a section at a time and I was just like, why can't you just do it all at once? Cause I don't just, I don't really want to go in and be numbed like three times, three different times, that would be so annoying. So luckily like today he was like, I'll just do two today and then come back for another one. I'm gonna try to drink this smoothie and edit some photos and then probably edit a video. I don't know, I'm just really trying to wait for this numbness to go away and then I'll do my makeup and I just have some filling to do if I can. Other than that today is the event with Essie at 5 p.m. And it's on the east side, so it's super close to me and it's at Ossington, which they have like the best little bow buns. So I'm really, really hoping that they give us like their food, cause sometimes it's like catered by a different company. I think the last event, the Charlotte Tilbury event, I'm not sure if it was like actually Wax Myrtle's food or if it was like a catering event. I've never been to Wax Myrtle, so I'm not really sure. I'd be interested to know that. But yeah, I'm really, really hoping for some good food. I don't even know if it's, well yeah, it's at a restaurant, so why would they not give us food, right? I don't know. Also, like I said, I'm going to California next week and not that I'm doing anything like crazy, cute and fun and picturesque. I'll probably just be hanging out with my family, but I do kind of just want to buy like maybe like two outfits, three outfits, just like a couple new pieces so that I can take some cute content like on the beach and stuff. So I do want to look at that ASAP because I'm probably gonna have to do like express shipping just to make sure it gets here in time.  I didn't put mascara on because my eyes are like so watery. I don't know why I've been sneezing so bad these past few days. It's getting so annoying. Going to head to an event soon so I need to like remember to actually put mascara on because it is not a look without it, but I was on video call with a management agency and I'm just like really interested in getting a manager because I feel like that's just like the next step to take since I quit my job in December and just like going full-time content creation. It is a big step though and I'm kind of like hesitant because usually managers take 20% of every brand deal that they get you and also brand deals that come directly to you even though they didn't pitch you or they didn't like reach out to the brand or have that connection. So like I knew that was normal. I knew that's like kind of the standard but that just gives me some hesitation. And then also I didn't know that apparently managers take 20% of your affiliate sales so like like to know it or Amazon affiliates which I feel like both of those platforms I get like a good amount of my income per month. So that's just what's kind of like making me take a step back and be like, okay, like do I actually need them? Like I know it would help me grow and like I know that they could get me more brand deals and negotiate higher rates maybe even not get me more brand deals but have, you know, the brand deals that I have right now every month and then just like negotiate those higher rates so I don't have to really put in more work but I'm not really sure about like what my rates would be in their eyes, I guess until I like, you know, sign with them obviously but I don't know. I'm just like kind of scared to do it and like take that step even though I know that maybe that is just like the next best thing that I can do for like everything that I'm doing right now. The laundry's going on right now so I'm sorry about the background noise but also some like life updates I guess like business updates. I think I said this on vlog before but I'm not really sure my assistant that has been working with me since I wanna say like February or March. She got a full-time job so she's not really helping me as much as she did. The things I had her do were slowing down anyways because I wasn't in the middle of like my busy season with photography and so it kind of like worked out perfectly and then I also don't have a video editor I just did one month with her and that didn't work out so I'm back on my own and I think that's why I've been just having a hard time like being consistent with my videos on YouTube at least because I feel like I don't have anyone to hold me accountable which is another reason why I wanna manage her is to just like, you know kind of like motivate me more to get things done and do more and be more productive and just like reach my highest potential and I know that's like what they're made for so like it's like a devil and an angel telling me like okay you literally need this like this is the next best thing that you can do for yourself and then the devil saying like okay well what if you can get brand deals on your own and then you wouldn't have to give the 20% so I'm not really sure and that is what I'm struggling with but right now I'm just kind of like going through all my analytics and pulling them, screenshotting them I'm gonna put them in like a little Canva document so I can send that over to the girl I was just talking to so that they can kind of have a look on their end to see if I would be a good fit for them I do think I need to pause on this and like actually put on my mascara and like pick out my outfit because I feel like picking out the outfit is going to take the most amount of time but luckily the place is not that far away for me that I have to be there at five so let's get ready I am so happy with this outfit like I'm shook so this bag is from Pop Bay I unboxed it in my last weekly vlog but yeah, it's a Bottega Veneta dupe I was actually referencing this last night when I was opening that YSL bag but yeah, not real so cute though I'm freaking obsessed with it my noodle bag and then this top is from Princess Polly and then these jeans are from Zara and I'm kind of mad that I've been sleeping on Zara jeans for so long but they are the most flattering fit I'm usually a size 10 in jeans these are a size 44 and fit perfectly and then my heels are my usual Dolce Vida clear strap knolls heels they're like so comfortable they are always my go-to I think I might have a snack here and chill out for a little bit because I don't want to be the first one there maybe I can change up my jewelry or something like that ooh wait, I want to film a TikTok give like a little outfit of the day so I will see you guys at the event after almost three years of living in Austin Ryan finally got a inflatable paddle board and he blew it up in the living room and I told him, why did you do that? Why did you do that, Ryan? So I didn't see it but you're going to have to deflate it and then go on the leg and then inflate it again and then deflate it again I'll have an electric one though Yeah, maybe you need to do some research what is this brand hosts for? It's pretty large, like it's really long I mentioned it's 10.6 10.6? And you're sure I can't be on it with you? No, you cannot I feel like it's so long and big let's stand on it What the heck? It feels so like sturdy Where'd you buy it? Walmart.com Walmart.com And it was on sale or something? How much was it? 150 of them It's not bad We're waiting a little more than 70 See how long it lasts Why? It looks, it feels so like sturdy Oh, it has this like nice wood texture I didn't even realize it's like a wood texture Okay, well I'm going to head to the event soon I am starving I'm really, really hoping for some little light bites I just got home from the event and it was such a fun event I felt like so frazzled walking in there I don't know why But I saw all my influencer friends and it's like so fun because at first when I started going to these like events I was so intimidated I was like dreading it the whole day even though they're so exciting I was like scared to like walk in alone because well I think I can't remember if I could have gotten a plus one for this event I think the last event I couldn't have a plus one So I was really scared to walk in alone but then I just saw like people I knew and I was like, wait, this is so fun and I feel like I'm always one of the last ones that leave because I'm like, I don't want to leave like I just love having conversations with people that like do the similar things and they just get it and I feel like I didn't even take that much content because I was just like talking the whole time but it was such a fun event they had like a little drag show It was so cool I've never seen that in person before So that was like my first one ever and it was really, really awesome I'm very happy that I got to see all my like creator friends and got to meet some new people too So I'm very surprised it's like still light out I thought it would be like dark when I got home I'm still kind of hungry because the food was so good but I feel like I was just talking so much that I didn't really have time to eat So I need to fill my stomach up with something good something healthy because I literally brought home the donuts that were like out on display One of the Essie girls said that they were Krispy Kreme and I was like, I'm taking some home because Ryan is going to die when he sees them Welcome home everyone She knew she could smell Every time like Ryan comes home before me and like I'm with Sophie she like drags me to the door because she smells him like on the corner of the wall It's so weird It's like not like we bump into the wall or anything It's so weird how she knows but she just knows Okay Well I'm gonna go shower and get in my cosies but I'll talk to you guys later Good morning, it is Thursday I feel like this week is flying by but I feel like this vlog is gonna be so good and so long I could just already feel it It's like a good week But I am headed off to a shoot I filmed a campaign this morning I shopped for the scroll before and I did her maternity photos and then after that I have a coffee date with my friend Hannah She also does TikTok and we're gonna go to Lucky Lab Coffee I think that's what it's called near UT I went there before and their chai was so good So I'm very excited to be going back because they have like really cool, interesting drinks So I wonder if they have like summer specials or anything like that I also waxed my eyebrows this morning Last time I went to the eyebrow place they like chopped a bunch of hairs off my brows so they're not as fluffy when I brushed them up and it just made me really sad So I was just like I should probably just try it on my own and there wasn't that much It was just like little stragglers and I was like I'll just get the wax out So I used this hard wax right here Gigi strip free and you basically microwave it and it melts and then you take like a little popsicle stick and apply it, which is kind of scary because I was really scared of it dropping into my eyelash and like me having to literally pluck my eyelashes out Thank God that didn't happen But anyways, I'm gonna pack up my camera bag and then head out the door I just got done with the shoot and I got to meet her new baby and it's so weird that like we were even that small like every time I see like a newborn baby I'm just like literally how there's this one blogger I shoot with every single month and she has two kids every time I go back each month I feel like the kids already grow so much and they're like speaking different words just sound so much more mature and it's just weird it's just wild how did we even like grow to be like an actual human being doing shit and making money? I just, I don't know it's like mind blowing like the day I birth the baby I feel like that will like change me forever I've definitely heard that it does that but anyways, it was good to see her she's super sweet and now I'm at Lucky Lab so it's near UT and I'm meeting my friend Hannah I'm pretty sure I already said all this so these glasses are one of my favorite styles ever I swear I've purchased like more than five in my lifetime because I keep losing them but the great thing about these are they're so cheap, they're on Amazon and I just feel like this style is very, very flattering I'm gonna link them down below and they're the like best sunglass brand on Amazon so if you guys don't like this style definitely recommend to just like check out that brand on Amazon my hands fall I got a citrus chai I don't even understand but it's good definitely come here what did you get? just vanilla chai love a chai so Ryan's going home tomorrow for a wedding so tonight's our last night together for a while so we wanted to bring out the paddle board to the river and see how it does it shall be interesting blowing up this thing because I think it takes a lot of work to do it on a grouse holy shit happy Friday I am doing some press-ons I just did these static nails this is the brand and they're like way too long so I'm gonna have to file them down and I just got like some fuzzies on them anyways I think they look good but yeah I don't think I can like live life with long nails like this here are the final nails I filed them down so they're still kind of like have like the little loose threads I don't know it's kind of weird but anyways Ryan get it and then also my makeup just got all over them but I think they're so cute but I'm gonna go for a matcha date I need to attend to that pile of laundry when I get back and I wanted to get dressed up and just like put on a cool girl fit so this is what I came up with so this little green shirt is from Princess Polly I've had it for so long now and it's really good quality honestly I usually just wear it as like a cover up or like a button down over like a crop top or like a swimsuit but I've never really worn it just as a shirt and I really like it and then I also have these shoes from Puma and they have like this little green accent it's pretty like more on the neutral side but still kind of like goes together and we have my favorite top shop shorts I literally cannot find these exact ones anywhere it's so annoying cause I wanna link them for you guys like they're called the A-line shorts you can try to find them on like Poshbuck or something I found like different colors but the colors that they have are like not the best well actually they have a white one so I'll try to link that one but the other ones are like really weird like blue denim like this is blue but like those are like dark blue and I just like it's not the vibe so anyways I really like these shorts but I'm gonna try to like scout out more shorts that are like these I think it's just like the A-line fit is just so flattering cause it is not like hugging me on my butt also if I know a review on my hair and just dyeing it back I am obsessed I know I said that the first day but like I'm truly obsessed now that I've gone to sleep with it I'm woken up with it and like filmed content with it like I just like feel like myself again which is weird also my mom's already in California and I facetimed her and I told her not to tell my grandma because my grandma's gonna be so happy to see that my hair is not dyed anymore she like loves when I go natural everything so can't wait to show her my new hair looks incredible oh thanks I love my girl is it I know? oh my god I'm excited about it you guys, Sonali I'm like a fan thank you but her hair looks oh my gosh thank you I was literally just saying how it's a couple hours later and Ryan was working when I came home so I ended up just doing some of his laundry so that his packing would go faster and now I'm heating up some like frozen burrito egg breakfast thingies and they're really good they're from Costco but we're just like really hungry right now and I don't know what to make so we're just making those in the air fryer I also need to go to HEB because tomorrow we're going floating on the San Marcos River for one of my friend's birthdays and I wanted to bring some kind of food item and I was trying to think about it for so long I asked Ryan just now and he said I should make those like little sandwiches with the Hawaiian rolls I'm pretty sure I showed you in two separate vlogs they're so freaking good and they're just so easy to transport you basically just keep the Hawaiian rolls like in the package but like make the sandwiches while they're all still together it's like so clutch so I think I'm gonna bring like just two packets of those so that we can eat them on the bus before we go on the tubes I think that would be smart just so you know we're not too hungry and like if we don't have like enough food in our systems you know that would be bad if we're drinking so that is the plan once I drop Ryan to the airport I'm also gonna like clean the house I feel like that needs to be done for sure and I really really really want to take this TV off this wall and you're probably like what the fuck but we never use this TV it's kind of old and it's not a smart TV and I hate to sound like a brat but like I feel like smart TVs are just so clutch we do have an Apple TV but it's just not as easy I feel like the Apple TV is just so slow anyway so I wanted to take this down take off the bracket fill in the holes and then use this wall as a screen for my projector because I don't know if you guys remember this but I did a brand deal with this Samsung projector I forgot what it's called crap what is this called anyways it's a really really cool projector and I feel like I haven't really used it because there's not many blank spots on our walls anymore but since we don't use this TV I feel like this is such a vibe and I just ordered like this acrylic shelf and Velcro clear Velcro so I could put a little shelf on here and I could take it off when I'm not using this projector how freaking cool would that be or we can just shoot it up and the screen will like play on the ceiling but the fans kind of in the way Ryan, do we have time to take off the TV? Please, can I do it myself? Is it heavy? It's not gonna take that long I'll take off the bracket I just need you to lift the TV to me, now I just have to unscrew this which shouldn't be that hard you can barely tell but there's like just three holes that I need to get some putty for and clean up a little bit but I think it's gonna be so fun It is 8.47, it's a lot later I dropped Ryan off at the airport and then I got kind of a lot done I went to H.E.B. I grabbed way more things than was on my list but I mean, it's okay I'm gonna eat up, I'm gonna eat everything I'm here till next Wednesday it's currently Friday so I feel like I have time and I just got some things for tomorrow's tubing thing so I got like a pack of 18 like chip bags for the bus and then I also did my Hawaiian rolls sandwich thing and now I'm making butter chicken again Did I make it this week? I feel like I did but I'm kind of loving it and I was really craving it This was one of the things that was not on my list that I ended up getting I don't know what I wanna watch on TV I think I might like go through like my watch later playlist cause now these past few months Ryan has been so obsessed with watching golf videos You guys know he loves to golf and so when he comes home from golfing and in between his golfing he watches golf videos on the TV so he always hogs it which I totally understand cause I love watching YouTube on the TV like it's such a better experience rather than playing it on just like your phone or your laptop like I love casting it, it's so easy and that's again, the thing about like smart TVs it's just so easy to like cast it Anyways, I might watch some YouTube or I might watch some Netflix cause I feel like there's so many shows that I haven't really started just because I feel like Ryan wouldn't be into him but like honestly, he watches a lot of my shows and like, I feel like once you are like two, three episodes into any show you kinda get into it even though they're kinda cringy so not that he wouldn't watch him with me if I asked him to but sometimes especially the more girly shows I feel like it would be fun to watch alone I think somebody recommended Boo Bitch they said it was super cringy but just like a good binging show and since I'm alone we'll probably be doing a lot of binge watching television and YouTube so I might do that I'll let you guys know if I start a new series but I think it was this week or last week me and Ryan actually started a show called Cruel Summer and we got this recommendation from our waitress at a sushi restaurant and she was like, I can't remember the name but I'm gonna go text my friend cause it was so good and so I was like, okay like I looked it up and I was very intrigued by the description so we ended up watching it and it's actually pretty good they are cringy the acting's super cringy one of the main actresses is just like not very good but the whole show is very very interesting so you can watch that on Shoe I think it's Hulu I'm pretty sure it's Hulu but again, it's Cruel Summer so that's one we just started watching so we tried to start watching Love Island UK and I wanna say somebody told me to watch like season two so we started off with season two and I just couldn't get into it so then I tried to watch the most recent season and I still couldn't get into it every time I hear about Love Island someone is obsessing over it I don't get it like what do I need to be watching? What season do I need to be watching? Please let me know cause I'm not understanding the hype and also it's kind of hard for me to understand what they're saying maybe it would be helpful to have some subtitles on the show but anyways, I'm gonna end the vlog here enjoy my butter chicken I actually bade Sophie too so she's all clean and we can cuddle and it's just gonna be a fun night alone which is kind of scary but it's okay, I am making do if you guys are not already subscribed make sure you do so before you leave the video and I will see y'all in the next one bye


So, whatever principles that we discussed decentralization reduction of solid waste at the source itself segregation all these have been put under one conceptual framework which is known as integrated solid waste management. This is recently being introduced it was there from the beginning itself, but it was recently given a name under CPH EO manual 2016 and under solid waste management rules 2016. So, the basic principle is again minimum amount of waste should go to the landfill. It is an inverted pyramid sort of a framework. You have to segregate reduce recycle at as much as possible before you are releasing everything into the landfill. So, this is an integrated solid waste management framework. Under this again as I said that you have to add source minimization you have to do. One thing which I want to draw your attention is extended producer responsibility through brand auditing. Are you aware this term extended the producer responsibility? Extended producer responsibility is the extended what we call responsibility given to the producer like just like what an example of clip card only they are using a lot of material. So, I would say like they are engaging it, but there should be a responsibility of these people that what happens to this packaging material waste. So, if they are managing it then they are adding to their extended producer responsibility. So, was it clear? So, it is like when you buy something like for example, a packet of lanes ok you pay for the product you do not pay for the wrapping or the rapport. So, that is what they say and what are these are the claims of people who ever you know propose this phenomenon this concept. So, what they do is that you want the producer to take the responsibility of managing this waste and how do you do that? So, for that there is one exercise which was done in different parts of India for different cities which is called brand auditing. So, we tried this thing in Kerala. So, what we did is that we have aerobic bins ok. And there are plastic and other kind of waste is being deposited by the household. So, what we do is that we sort waste according to the brands like how many packets of lays are being or chips are being you know from a particular brand. So, lays or other kind of uncle chips and different kind of thing and how many packets of waste are from local producers or international brands. And then we weigh them and then we find the weight of that and then accordingly we can we want to tell the producer that you are you are producing this much waste you should be taking responsibility of that. So, that is what is known as brand auditing ok. So, this is a report that was released on 5th of June this environment day you can find it on internet actually. And there are other things that you can do to reduce you know usage of such kind of material. Segregation I have spoken about before. So, there is a three bin system for wet dry and domestic hazardous waste which is collected in black container. I think most of the bigger cities have started to adopt this particular model of segregation. Collection and transportation. So, there are two kind of collections can happen one is primary and another is secondary. Primary is directly from the household or the or the producer and secondary which is from the community bins, waste storage depots, transfer stations like in Hallaby you have secondary system of collection. So, households have to deposit their waste in a community bin or aerobic bin and from there the municipality takes care of the waste. And in other cities you might find that collection is happening at the household level. So, these are the two basic types of collection systems that the cities can adopt. So, primary type can work for the small larger towns and this might can work in all the cities that is needed. Recycling I do not have to tell you what are the benefits of recycling right. Material recovery. So, this is the thing that we were talking about how do you recover different types of material. Ok, I am going to talk about this is the material recovery facility which is in Trivandrum for plastic waste. Ok, so what they do is that all the plastic waste comes to this particular facility and what they do is that whatever is the recyclable plastic is shredded and is then sell at 20 INR per kg to the to making for making the roads to mix it with vitamin. So, this is MRF facility for the plastic waste similar kind of MRF facility you can have for other kind of waste like batteries, aluminium and all kind of things you can have. Since for treating and utilizing different kind of municipal solid waste management. Ok, biodegradable waste can be managed through composting everybody knows what is composting right and then there is another process called biomethanation through which biogas is reduced and you can use it for cooking and heating purposes and other kind of purposes. Combustion is another process which is used for non-biodegradable waste. In India there are three methods for that gasification, incineration and pyrolysis. In India incineration is most famous although two are still being tried and tested there is no proven technology that kind of fits Indian condition because India is quite humid in that sense. So, you need to maintain certain kind of temperature that is one thing and the second thing is that for these two methods gasification and pyrolysis you need to have a well sorted waste which is not possible in Indian cities. No matter how much you segregate there will be issues. Ok, need to explain to you what is composting? Sure? Yes. Oh great, my work is reduced. So, we have four different type of composting technologies. I am not going to explain to you or do you want me to explain? I can show you the graphs. So, I am not for graphs, photographs. So, this is windrow composting. I think one of the participants mentioned that they have windrow. So, yeah. So, can you explain little bit more about it? Just shortly. Windrow basically they will have yards that may be covered. It is covered in my case. They have sheds and they will segregated organic waste is layered with cow dung or other organic material which is collected from the place and they will there is a cycle.  So, after this is complete they will see it for other solid matter or something and then they will directly apply wherever needed. So, which city are you talking about? No, I am talking about town panchayat in Coimbatore. So, are there any other examples in your city which you are like using what we composting? This is the bin composting that we have in Trivandrum and it is there in Ellipi also. And this is the pipe composting which is meant for households. So, this is pipe composting I was talking about pipe composting is it was tried in Ellipi in the city which is suitable for household level because in Ellipi as I said that they do not have much of land available. So, they wanted to process the biodegradable waste whatever the constraints of land were there. So, this was the pipe composting that they tried and Sriritha is going to talk about that if it succeeded or failed in help in this context. This is summary of compost technology. It actually talks about what should be the scale where you can you know employ different kind of technology like windrow and in vessel could be large scale where you have to deal with large scale biodegradable waste. And what we composting is obviously small but what we composting is very temperature sensitive you know technology and you need experts for that. So, these are the different methods and appropriate links of different methods for that.


Welcome to this course on Transition Metal Organometallics in Catalysis and Biology. In continuation with our earlier discussion on various types of olefin metathesis reactions, we have been talking about ring opening metathesis. In particular, we have been talking about two variations of ring opening metathesis. One is just simple ring opening metathesis, the other is ring opening cross metathesis reactions. Now in this discussion, it is important to note that this ring opening metathesis reactions are favorable for substrates, which are under strain, like they have physical ring strain, which is the driving force for carrying out this ring opening metathesis reactions. So today we are going to look at various examples of both types of ring opening metathesis as well as ring opening cross metathesis reactions and see how they have been used for synthesizing a variety of novel structures, which are of importance commercially as well as from biological point of view. So with these, let us move on to various examples of ring opening metathesis reactions that we would be discussing in today's lecture. This is popularly called R-O-C-M, and a nice example is given by the reaction as shown. This is called oxanorbonine, the reaction of this with vinyl acetate gives this five-membered cyclic compound, which is a major product along with the other product, which is O-S-C. Now this reaction can be understood in the context of the transition state that may arise from binding of O-acetate in one way resulting in the formation of this product or the same can be understood also understood by the reaction with the substrate in opposite way, which will give the other product. Now this will lead to formation of two different products of which the major product is the one which is shown over here. As seen that here, we see that the ring strain of oxanorbonine is the driving force for carrying out this ring opening cross metathesis reaction. Now, as we had discussed earlier that these metathesis reactions are often are thermonutrile reactions by the fact that the energy required for breaking a double bond is also almost equal to energy required in the formation of double bond, so there is no enthalpy gain as such from in metathesis reactions. However, there are other factors like the ring strain or elimination of a gaseous ethylene molecule, which is formed as a product, which sort of leads to the formation of this ring opening cross metathesis products. Look at another interesting reaction for ROCM ring opening cross metathesis, another interesting example. This is a cyclopropene ketol that reacts with and subsequent hydrolysis give this product. Now, this is an interesting molecule, this cyclopropene ketol. If seen closely, this is nothing but derived from the protection or protection of the carbonyl group to give this ketal moiety, and this is cyclopropene ketone. In this structure, it is not very stable, it has a more stable structure, which is in its zwitterionic form. This is cyclopropyl cation, and now this is conjugated aromatic compound. This cyclopropene cation is an interesting compound, which is derived from cyclopropene ketone, and which is stabilized in its zwitterionic resonance form. As far as this ROCM cross metathesis reaction goes, then one can envision the reaction between the two olefinic substrates leading to the formation of the desired compound. Proceeding further, we are going to take a look at another example of ring opening cross metathesis reaction. In this case, the substrate is also a strain compound, a bicyclic compound with considerable ring strain, that reacts with this olefin to give this compound, so it becomes a five membered cyclic compound, as is shown over here, and if one looks at how the reaction goes plus 11, and then if the orientation of the two olefin are such, then this goes through the four-membered cyclic intermediate transition state to give the desired product, which would have one moiety of this and the other moiety of this, this CH2 group arising on this end and the rest of the fragment being over here. Here also we see that this is a highly strain substrate, where there is a five-membered as well as a four-membered ring, and of these the four-membered ring, which is under severe strain, opens up to give the corresponding ring opening cross metathesis product. This compound is called Bicyclo320-320-Heptam. These have gone beyond eukaryl substrates to even the chiral forms of this has been reported, and in this case the metathesis catalyst used for the study is a chiral compound, so we are going to take a look at several of the chiral examples that have been reported for ring opening cross metathesis reaction, asymmetric ROCM or ring opening cross metathesis reaction, and the substrate for this is called mesonarbonyne, the structure of which is shown here, mesonarbonyne in reaction with allyl borane. In this cross metathesis reaction, the catalyst is an asymmetric or chiral complex, as is shown here, there is a tibial group, and this is highly sterically demanding with another tibial group, both bound to molybdenum, and this is a molybdenum imido carbene compound with phenyl and 2-methyl R equals adamantyl to give the compound, which is shown over here, and the transition state can be envisioned from the reaction of this allyl borane in a conformation similar to this, so that this is corresponding to the vinyl substituent over here, and this fragment is corresponding to the boronic ester substrate over here, and needless to mention that this also has considerable ring strain that is so characteristic of this ring opening cross metathesis reaction, and has been successfully utilized for preparing this asymmetric chiral compound using asymmetric ring opening cross metathesis reaction. We are going to look at another interesting example of asymmetric ring opening cross metathesis reaction, and here also another bicyclic steric substrate is used, which is oxa-bicyclo 321 octane, that reaction with styrene again using chiral catalyst, which I will draw over here to ruthenium, and in heterocyclic carbene with a mesital moiety on one end by null with the oxygen bound to ruthenium, as is shown over here to give the corresponding product, and the catalyst used is a chiral ruthenium carbene complex. Here too, we see that highly strained bicyclic octane ring has been used using a chiral sterically demanding chiral ruthenium carbene complex to give the product. Further, we are going to take a look at another example of ROCM ring opening cross metathesis, in which this reaction has been attempted two times. First one is an intermolecular cross metathesis, and the second one is an intramolecular cross metathesis. This is an interesting reaction, so here too one starts with an strained oxanorbonane, which is highly strained ring that reacts with butadiene to give the corresponding ring opened cross metathesis product, it is a protecting group. One can see that this is intermolecular ROCM, and that happens from the reaction of two substrates as is shown here giving to the desired product in which the fragment comes from the reaction of this, and the other fragment comes from the reaction of this. The reaction does not stop here, it further undergoes intramolecular ROCM, in which these two olefin reacts in an intramolecular fashion to give the product as is shown here, and this is a ring expansion that happens over here. This is an interesting example where we saw two types of ring opening cross metathesis happening, the first one is intramolecular ROCM, followed by intermolecular ROCM, followed by intramolecular ROCM again resulting in a bicyclic ring. However, this is in much more expanded form than it is over here, and hence this release of steering ring strain on going from here to here occurs using this nice example of intermolecular and intramolecular ROCM ring opening cross metathesis reaction. With this, I come to the end of today's discussion, where we have seen various examples of ring opening cross metathesis reaction starting from the a chiral variant to the asymmetric variant, and what we had observed that in all of these cases of ring opening metathesis reactions that the substrates are bicyclic compounds, mostly bicyclic compounds with substantial ring strain, which provides the impetus for the reaction. We have also looked into the chiral versions in which sterically demanding chiral catalysts have been used mainly with binol fragments bound to the metal, and they also successfully carry out this ring opening cross metathesis in asymmetric fashion. We have also looked at a very nice example in the last slide in which oxo-norbanine compound undergoes reaction with butadiene first in an intermolecular ROCM fashion followed by intramolecular ROCM fashion resulting in the ring expansion to give another bicyclic compound. With this, I come to the conclusion of today's lecture, we are going to take up this more on this ring opening reactions particularly with regard to ring opening metathesis polymerization or RONP as we start in the next lecture. Till then, goodbye and thank you.