Hey everybody Matt here for late in sports cards ripping 2022 Panini XR football hobby 7 box half case number two pick your team fix that There we go Alright, we have Adam D Steelers Andrew S Ravens Bowie S Colts Brett T. Dolphins Charles N. Chiefs Chris B. Panthers Daniel D. Bills Francis P Cowboys Henry J Jets James G. Broncos Jeff N. Saints and Niners Joe L. Vikings Jordan S. Washington Kyle B Packers Lenny N. Falcons Luke F. Giants Martin W. Rams Matthew R. Bengals Lions Michael H Browns Monty M. Bears Patrick I Raiders Philip N. Titans Ruel S. Chargers Russell P. Seahawks Shane W. Bucks Steven H. Eagles Talon H Patriots Tim V Cardinals Vaughn B. Jags and Victor F. Texans. Here we go. Good luck Vaughn I saw your note, man. I noticed MJD on the checklist. That is awesome. Hope I find you on here Jagd Goat Yeah, he was so much fun to watch When I was looking over the checklist I saw him I saw his name got really excited It's Chris Goblin 49 Justin Jefferson to 99 Andraic London rookie Christian Curt and Carson Wentz This is Texans Otto to 50 Niko Collins. This is Patriots Triple patches to 25 rookie Pierre Strong. That is exclusive rookie Breeze Hall There you go Jets That's one of the case hits right Yep, exclusive case hit. There you go. Congrats, New York Clear-ass state. Yeah. Mag that one for you. It's Cordero Patterson to 249 Tyree Kilt to 75 and Zonovan Knight rookie Josh Jacobs and Tyree Kilt Texans rookie triple patch Otto to 25 Jameon Pierce. There you go Texans They've been solid so far Number three has just the Cardinals Ravens Lions and Dolphins four teams to go on that. Let me drop a link here That's TJ Watt to 249 George Carl Aftis rookie to 99 and Jake Ferguson rookie Judy and Barkley and Washington that is patch six of ten RG three You go Washington That might be the first RG three card I've ever pulled Not sure on that He's gonna make you in his name for himself in the football world still. Yeah, it's Jaylen Tolbert rookie to 99 Dak Prescott to 199 and Lewis Sine rookie to 249 Kenneth Walker rookie He had some good games for me Oh, yeah, hi, you can Moseley and Packers rookie patch Otto to 49 Christian Watson There you go. Nice one Green Bay Yep, nice hit Packers cards Ravens Lions and Dolphins Still there for the next break. That is Rashad White rookie to 49 nice card Bucks Kennedy Brooks rookie to 99 and John Metchie rookie DJ Moran Davis Mills Rams that is rookie Otto to 199 Kyron Williams you go Rams And Cowboys triple relic to 49 rookie Jaylen Tolbert But two jerseys in a patch. I love the way the colors pop on these cards and XR That too is crazy. Yeah No, I can't I I would love to see a sit waddled or like something a little bit to you It's another case hit that is exploits Cardinals Kyler Murray You go Arizona really cool. It can acetate. It's a Kyle Pitts to 49 Derek Henry to 99 and Lewis Sine rookie. This is DK Metcalf and Damien Harris Jets rookie jumbo Jersey Otto to 99 Breece Hall. You go nice one Jets Two more to go. We haven't seen a one-of-one in the case yet either that is rookie Keyonte Ingram to 199 DJ Moore to 49 Cave on tibetan rookie Derek Henry and Kedarius Tony Commanders that is rookie Otto to 99 Brian Robinson luminous endorsements nice from Washington and Bucks dual jerseys to 99 or to 49 Chris goblin and Mike Evans Still have the Cardinals Ravens Lions and Dolphins for the next break. This is rookie Extreme rookies insert to 99 Breece Hall It was Kyle Phillips rookie to 99 and Miles Sanders to 199 Trival Walker rookie Rashad Penny and Justin Jefferson chiefs That's rookie triple patch Otto to 15 sky more. I said chiefs. That's Alvin Kamar 75 Christian Kurt to 199 and Alec Pierce rookie Is that 75 like silver That one I think so that's I like that color Elijah Moore and James Winston. This is chiefs rookie Otto gold eight of ten Justin Ross and Patriots rookie triple patch to 25 tyquan Thornton. Let's get that next break filled up four to go is case hit Inclusive Browns to Sean Watson you go Cleveland Matt Corral Sorry rookie. That's one of two forty nine and Andrew Booth rookie to 199 Chad mama cooks and golf and Jets rookie patch Otto to 35 Breece Hall. Holy cow, bro. There you go. Congrats Jets I'm pulling Breece Hall like Breece Hall was on my fantasy team this year Actually, my team went downhill right after he went out. I would assume people that had him were like heavily relying on him. Yeah There's Kyle Hamilton to 49 rookie And Tyquan Thornton rookie to 99 Two to go in the next break. There's Breece Hall rookie Just the Cardinals and Ravens homes and Gabriel Davis This is Eagles rookie triple Jersey Otto to 149 Carson Strong and Ravens Jersey to 75 Kyle Hamilton rookie Jersey. What's up Dean? Such a cool-looking card Extra Patrick Mahomes to 149. That's sick. Is that a red color match? Yeah This chiefs color match. This is Mitchell Trubisky 249 and Logan Hall. This is base X This is a case hit rookie for the Bucks. You go Tampa Bay Turn in the background there. That is the base X case hit Sam Howell rookie Jalen Hertz that Hertz has a crease in it across the right in there and Austin Eckler So this Titans one of one rookie laundry tag Otto Traylon Burks Congrats Tennessee Our first one-of-one of the day 130 That was Philip in what the Titans love these black one-of-ones You go Tennessee.  He's definitely showed some Signs of it this year. We waited until 15th box of the sorry the 13th box of the case to Find the one-of-one. Here's Devonta Smith 75 Rookie to 199 Reggie Robertson And Kyle Hamilton rookie Marietta Kirk and chiefs rookie Otto to 199 Leo Chenal This is Raiders Rookie Jersey to 75 is a mere white. Let's get that next one filled up. We have the Cardinals and Ravens left in our next break That is easy E rookie to 49 extreme rookies insert Darnell Mooney I'm sorry. That's to 249 And rookie Reggie Robertson 49 This is Kyler. Kyler. Ilam. Ilam rookie. There's Carson Wentz and Josh Jacobs and Steelers rookie Jersey Otto to 99 Kenny Pickett Great hit to close out the break congrats Pittsburgh. That'll do it for the break. Give me just a minute here. We'll do a recap So we had base X case hit bucks rookie. That's Logan Hall Patrick Mahomes to 149 That was the extra extra insert and then case hit exclusive to Sean Watson case hit exploits Kyler Murray relics We had Raiders rookie to 75 is a mere white Ravens rookie to 75 Kyle Hamilton This is Patriots Triple patch to 25 Taequann Thornton Bucks dual Jersey to 49 Chris Godwin Mike Evans That's Cowboys rookie triple relic to 49 Jalen Tolbert. That's commanders patch to 10 Robert Griffin the third Patriots triple patch to 25 rookie Pierre strong It's like a hair or dust right like right under my glasses That's chiefs rookie Otto to 199 Leo Chenal Eagles rookie triple Jersey Otto to 149 Carson strong chiefs rookie Otto to 10 Justin Ross Chiefs rookie triple patch Otto to 15 Skymore Commanders rookie Otto to 99 Brian Robinson That's Jets rookie jumbo Jersey Otto to 99 Breece Hall Rams rookie Otto to 199 Kyron Williams Packers rookie patch Otto to 49 Christian Watson Texans rookie triple patch Otto to 25 Damian Pierce It's Steelers rookie Jersey Otto to 99 Kenny Pickett Titans one-of-one rookie laundry tag Otto Traylon Berks Jets rookie patch Otto to 35 Breece Hall and Jets exclusive case hit rookie Breece Hall Good stuff. That'll do it for the break. Thank you everybody appreciate it. We have number three up next


It's from this camera right here. Right. Great, thank you. You're welcome. How are you doing? I'm good. Nice? I hope you're not disappointed. Over entertained 24 years on this night show. That show was magnificent. It was pretty much.  The string kids, I just felt it. Oh, I looked behind me. And I was fighting tears. And behind me was a gruff, tough guy. I looked like a man in eight wars. Crying like a baby. They got to him. They got to me too. Not hard, not the cry. I'm losing those words. She would have everything. I mean, she would have to look back at Briggs. Presentation. She was really touched. I think we hit her at the start of the beginning. Desi with Casley relationship and all those things, wrapped together, she's in the room too. Well I know everything I think I'm supposed to know. Except the ornament. Is there someone ornamental? We're going to do the walk up now. I was telling Santa when we went down earlier. Santa, do you want to come down the staircase? I'm gonna say I'm gonna come down first And then I'm gonna say and say, here's Santa. OK, terrific. All right, now is it all right if later on, in fact, they'll know that, I think, from then. But if later on, so he says it's Ed McMahon or whatever, and I can say, and now, ladies and gentlemen, he is Nancy. All right? Because what I think they'll pick that up USA Today is they'll pick that up. That'd be great. Do you want to come down the stairs? Do you want to come down the stairs? And Santa can just be peeking around. Yeah, and then I think I'll make reference to the fact that Helen was the one who asked me outside what the theme was. I said I'd keep it as a surprise for her, but that it obviously is a mother loose thing. And now, the other surprise is here, Santa. OK, very good. All right? And then we'll just wait to see what happens after the press corps or answers. And Santa knows that he is welcome. We invite his anticipation while you're in. I don't have any qualms about that. You'll have fun. And then over there is mother loose. Mother loose, yeah. Well, there's mother loose, yeah.  Yeah, lots of them. I'll handle it. OK, so now we're here. We'll get to here. And now Beth's going to take us to right now. I was already stopped to that. We're stopping. I'm the person who's got that. Before you start the tour. Beautiful. Hope I get one. Well, if you play your cards right. Every year, every year, I get one. And I always get mine before Johnny, which is great. Now, is there any cold on this, Elaine? Do we stop this at any time where someone say, that's enough questions. Now we have to move on. If they're talking about Christmas and wonderful things and you're making cute jokes, we'll let it go on. All right. I'll sort of judge if I don't want it to go on anymore. All right. OK. I will look to you. As long as everyone's having fun. OK, now we go to stay down here. And you know, they help out. Oh, here. And there might be more questions going on here that may be questions all the way along. Oh, yes. Yes. Yes. And you can just throw in whatever you want to show it. I will. I will. Yeah.  He'll be out. This is pretty standard. Did somebody find out the question I asked? Who inaugurated it? No, I didn't. I was talking to some people as to whether or not you are the first, first lady who's had a surprise sample. Correct. Is he there? Rex? Well, we'll continue making some calls. How dare Rex leave town without clearing with me. Bill, do you know from your photo? Who else would know here besides Rex? When did they say he'd be back? No, no, no. I mean, so that you could talk to him. You could not remember. No, I cannot remember the past 13 years. No, it's too late. Oh, it's so flying. Mrs. Reagan, Bill Fitzpatrick cannot remember for the last 13 years of ever having one, but we just want to, you know, really document it. All right. What do you even say I don't think? No, we're going this way. Oh, we're going this way. See you're right again. You're very early. She didn't take any chances. She didn't show up. I was here for ten. Gosh. Maybe you would do the dancing. Well, I didn't leave her. Well, if I could, you know, I would have, you know, everything set out. Oh, I knew you would. We don't do anything here. We're holding you here for a while. Betsy would be there for you. Hi. The Easter is coming up. Next stop. It is a great job as always. It's great. It's great. It's great. Well, it wouldn't be right unless you were here trimming the trees. Right. Thank you. The president for me. The second. The second. Thank you. Thank you. This is the key. Isn't that nice? Thank you. Thank you. Nice. Are you sure? Second genesis. Very nice. Thank you. All right. All day soon. Yeah. And you hold it. Yeah. It's great. And they do it every year. Oh, that's cool. That's a good one. And everything around the house, you know, this. And well, she can be coming down to the tree. And then we'll do it. And your stocking will be very empty this year. Very empty. I like to give this to some of you. Oh. Oh. Oh. Oh. See you later. Sensational last night. I'm sorry. We came in here after everybody left to see this painting. Yeah. Yeah. Yeah. Humpty Dumpty. Isn't it? Yes. All right. We'll be on their side. Thank you. Thank you. Going to town. Thank you. Now, what do we do in here? Well, you know, you mentioned Yankee Doodle because he's the closest than the other characters. Humpty Dumpty over there and mention again how beautiful the trees are. What is it? What is that throughout the rest of the year called? Over there we have High Diddle Diddle, Cat and the Fiddle. Right. The couch jumps over the room. If you know any of your nursery rhymes, you could do a little test. Oh, come on. I do have a baby, but I'm just learning. No. I'm trying to learn Twinkle, Twinkle, Little Star. Give me a break. I don't know that we have her here. I hear my wife, you know, on the speakers. She takes the baby up and she says the prayers and so forth. So I hear her up there. She's doing this like Twinkle, Twinkle. She's got it all wrong. She's making up the lids as she went along. I said, what are you doing to this child? We're going to get a book and get the right lyrics. Now, we don't do anything with a crush. This year? Well, that's a change. It's all described in the booklet. They have the same story. And once again, you'll do this time, right? No. They won't take Catherine Mary until we're taking our pictures. Oh, I see. Well, won't they be walking around with us, Catherine Mary? No, not through this. Oh, no? No, it's going to get a little craziness to do that. All right. And you've got the crooked man and the crooked house over here. Oh, OK. Oh, behind this tree, Linda? Uh-huh. Right on that mantle. And there's only four in here, right? Hey, Bill, Bill.  Now, back to the blue room of the tree. And then we'll have a press coming in two waves. And that's just right again. You'll actually be in here. We'll have come in the back door. Back door, OK.  Now, what is the ornament that is going to be supercated? No. The White House ornament. Is it not under yet? The White House ornament? Pardon me? On the tree. No, it's not under. OK. Last year, there was a problem finding it. So this year, we figured it would be better. Am I putting it on now? Yeah. Fine. Am I putting it on now? Or do you want to hang it when you have the press with you? And actually hang the ornament and talk about the new ornament? Or we can put it on the tree now and then you can just point it out. It is hard to find the ornament. Yeah, it is. I mean, if it were right, you know, I'd find that candy cane quickly. Well? You just laid it on that plank. Why doesn't somebody get a wire and secure that? As long as you know where it is, we get to it. Yeah. I tell you, if I had something... A little wire. I can't tie. We'll put a hook on it. Yeah, yeah. That's a good idea. But put it right by that cane so we can see the cane on the ornament. There we are. Right, Smarty. I think it will show up as nice and straight. And just set it off to its side. Right. Yeah. Great. OK. That's perfect. But don't hide the candy cane because that's your... No, it's not. Well, now we use this as our guide. I'll remember. I'll be my responsibility. I take that responsibility. Now, Betsy, how are we getting to the foyer from here? That's to go through one of the rooms. OK. But you're going to invite them to press them right down. Yeah, we're going to take your picture now with the... Yeah. We have half of you come around the other side. All right. It's killing me, too. Can you turn it off for a minute? Just turn it off for a minute. Thank you. And while we're out here now in the Grand Fourier, there's a little practice that volunteers from my office will join you in Santa City on your lap. Yeah, therefore it's time. See, your lights are throwing my meter off. And I'm showing you how much. Hot. Have we done that last time? Put some on. Well, you and Santa will go back upstairs. Now you're here. For now? You hope we're going to go upstairs. Sure. I'm going to put something. Sure, go ahead. You're going to be in there with this photo. Oh, of course. Right here. It's true. So that's where we're going. Oh, sorry. First lady doesn't want to be in there. Oh, I don't know. She says... Well, first lady doesn't want to be in there. No. She says it's fine. Santa gets to sit down in the first lady's chair. Well, that's prior. But Santa can try out something. Yes. Come on in. Thank you.


Transdermal drug delivery is a promising approach for administering medication through the skin. One way to do this is via micro needles, which are small needles made of polymer blends that can be used to penetrate the skin and deliver drugs. In this study, researchers investigated the effectiveness of various polymer blend ratios in creating micro needles with desirable properties such as regular surface morphologies, high thermal decomposition and melting temperatures, and good formability. They found that a 10% polyvinyl pyrrolidone, PVP, slash 2% sodium carboxymethylcellulose, CMCNA, ratio produced the best results. This combination of polymers resulted in micro needles with good formability in other desired properties, making them suitable for transdermal drug delivery applications. This article was authored by Na Chang, Zhu Lu, Ming Lu, and others.