we should be coming in there we are nice hi everyone this is jicho welcome to my channel and welcome to another live stream today is september 16th 2020 and we're doing a comic book reading we're down to three bucks we plan on reading today or the choices that we have first nice we got crime does not pay number 116 we got kid cold number 107 and we have exo amount of war number one and while we wait until notifications goes out for people to come here for the live stream uh cool you're excited for the so am i so what we're down to three and then there were three i set an alarm on my phone so i was here before you eggs how are you doing nice coolio nice fun stuff fun stuff uh what's going on chicho currently in online class ah you're an online class pay attention to your classes forget about the live stream the comic book i'll have the video up on bitchute and youtube in uh probably a couple of days okay so pay attention to your class uh but if you already know the stuff in class and if it's it's up to you you can watch you can watch a comic book reading instead elder god what are you doing hope you're doing well i know what you're voting for wait which x-man comic is that no x-man this is xo man of war xo man of war number one yeah xo man of war number one first appearance of xo man of war very important book i love this book actually what's up birdie here how are you doing welcome welcome gang i'm going to do my little intro um until the notifications goes out uh because it's early on uh that way we don't have to both notifications sent awesome okay awesome elder god so gang if you want to follow this work i'm on patreon let me click this up if you want to hello mr hezekiah how are you doing hope you're doing well if you want to follow this work i'm on patreon patreon.com forward slash chicho chy cho for the longest time i kept on saying backslash and then someone corrected me i was like oh my god for like two years i've been saying backslash and his forward slash chy cho so i'm on patreon if you want to support this work patreon is a great way to do so if you want to follow this work patreon is a great way to do so and for those who are supporting this work through patreon thank you very much for your support it is a huge part because of you that were able to do this work uh so very much appreciated coolio i actually want to get into those older comics from other uh companies beside more coolio i highly recommend i highly recommend really i highly highly recommend what's up chy cho felix how are you doing um what's up chy cho and everyone here just had a free day off school today nice caught up on some mass and politics homework been a good week so far awesome felix stay up to date stay on top of your classwork for sure mr mr hezekiah good how are you doing well thank you very much how's it going man jjc says felix i've been doing a lot of drawing as well very therapeutic drawing is amazing drawing is i don't do but writing for me was very therapeutic and reading comic books is very therapeutic coolio it was on the stream you were uh corrected oh were you okay it was a music lyrics it wasn't a music lyric stream man i can't believe i kept on saying it the wrong way king chy cho was back holding who's how are you doing we are live streaming on twitch twitch.tv four slash chy cholive chy cholive if you want to participate in these live streams in the chat twitch is where you want to be at okay and for those of you who are following subscribing through twitch thank you very much for the support and mods as always thank you for being here i do announce these live streams 30 minutes before we go live on elo mines vk parlor gap and twitter for now okay so you can follow the work there and we do share additional content there as well not just comic book related but comic book related there is some there for live streams where we don't have any visuals we record an external pal mike on an external recorder and we upload the audio to soundcloud us podcast so slowly we're going to build up our library there and there's a lot of live streams and asmr videos and math videos that i do have the external mic recording on that i will at some point i'm slowly loading them up on there so there's a lot more contact tomorrow to come on soundcloud and those audio files should be available on your favorite podcasting platform including spotify and we will be uploading this video to youtube and pitch you and if you want to support this work following liking sharing commenting um and if you're on youtube joining youtube membership is also a fantastic way to support this project aside from that welcome everyone cool you i got to move my car quick don't do the poll yet okay we won't do it i think sharyl has been the one doing the polls but i'm not sure if she's showing up today and we're down to three comic books so he shifted an easy way to make a poll when you come back coolio let us know i'm pretty sure he's already gone maybe holden who's just put in a job application to work at a movie theater nice there's gonna be a lot of movie theaters closing down i'm assuming i hope you get it if you want it hope it goes well brother yeah me too me too and the ones the movie theaters that survive slowly they're gonna get busier and busier i think she's driving at the at the moment she's driving at the moment okay okay i hope she's not driving too fast mr he's okay at chicho was there a particular comic that you read that got you into collecting comic books the first uh comics that i read were probably tintin okay asterix and tintin would have been the first uh comic books that i read and they're european comic books belgium i believe uh but the first american comic books uh the one that really got me intrigued was x-men and then i've gone through phases where i'm just gonna take these things down where i i pull out of comics and then come back into comics the main comic book series that got me into collecting comic books in a in a big way was flash the 1988 series because that's when i was older i was in university and when i read that series i hadn't been reading comic books for a few years right through high school i read random comic books pre-high school elementary school i was reading some comic books comic books whatever i could get my hands on doing a comic book uh high school period i read some comic books i wasn't really collecting uh but the one that really got me into collecting was the 1988 flash series i think that series was mature it was depressing it was heavy it was different than what i remembered comic books being so it got me really interested and then it was the independence once i went to the independent world there's no turning back birdie here i am reading venom lethal protector at the moment this is the first time i have read a comic really enjoying it awesome birdie here and man you're in for a ride if you're enjoying comic books you enter the comic book world realm it's it's a ride and a half it's beautiful it's exhausting it's depressing it's makes you angry makes you happy it's everything olden who's tintin i love tintin growing up i own several of them i'll post them later in the score awesome awesome i still have the tintins that they came with me from iran they're the iranian version with the text on them and i i put out a video showing that the first the comic books that really got me my the oldest comic books i have in my collection which are the tintins and i shared the story of the tintin comics and stuff felix i was planning to go to the movie theater on saturday since it's my birthday but the movie movie's release date got delayed unfortunately which movie were you going to go see felix i started reading tintin in the third grade yeah early on me too i'm back coolio right on mr hezekiah wb wb wb was wb wb wb i don't know elder god i just found out that your el topo director was supposed to do the original dune yeah elder god dune movie before lynched it in 1980 yeah and people and supposedly it was the cost on it was becoming so much because drow drow drugowski i forget his name warner brothers warner brothers drow drugowski i can't pronounce his name he was the proposal of him to make the movie was just going to be astronomical in terms of cost so they went with lynch i was able to get tintin in the congo which got banned really they banned tintin in the congo oh welcome back welcome back wb nice warner brothers coolio said and also welcome back oh my god so good fun so we're not going to wait for sharyl should we make a poll i could also do it as well i think let me uh coolio holy god let me know if you guys want me to make the poll i think i looked into it before maybe i think you just gotta go it is just poll yeah i think you do is it i think it's um backslash poll and it brings you up felix i was going to see the kings man a prequel set in world war one uh to the kingsman series oh really i think it's actually based on a comic books it is the kingsman series is based on comic books they banned the congo uh book because how uh they drew the people that lived in congo kind of oh really i didn't know that cool to know interesting i got seriously into calvin and hobs his fourth calvin and hobs is absolutely brilliant i've read every single calvin and hobs comic strip because i had the books to collect the works and i've read them multiple times you got it coolio awesome disillusion how are you doing welcome welcome can you spread the comics out so i see the full title sure this is by the way here is uh let me give you the intro for these things before we set the poll up so gang here are the comics that we're going to be reading or we've got a choice to read i have common account commemorate the book it's great that's amazing the first book is or one of the books is crime does not pay number 116 okay this book is from the golden age of comics came out in 1950 okay and this is lav glissen publishing and mainly i was interested in the dawn a john dillinger story in here okay and it should be i forget how many pages it is the john dillinger story is a nine page story okay and crime does not pay uh lav glissen one of the main publishers from the golden age of comics and they were known for crime does not pay and dare double and um what was the other one the other one i made a note here error boy okay error boy and some other comics that they published okay so crime does not pay from 1952 we got kit colt outlaw kit colt 107 from 1962 okay and kit colt is the longest running western comic book series ever it went from i have the dates here what did it go from it went from it was published from 1948 to 1979 with some reprints in the 1960s and stuff the cover for this the pencils are jack curvy the inks by decares okay the story in this comic is stan lee and a lot of decares artwork as well as jack keller and there's one other person that i forget what the what his name is but i'll bring it out if we do decide to do that one and the third book that we have is xo man of war number one from 1992 and this was from the kit colt is from 1962 and xo man of war is 1992 is from valiant comics okay first appearance of xo man of war pretty important book one of my favorite series it's a fantastic series it's one of the books that really blew people away okay in the 1990s with the emergence of valiant comics and the cover is done by jack latin i believe let me check this out make sure it could be i don't think it's bairowinzer smith no i believe it's latin the signature there well pull it up pull up the info if we decide to read this one okay to follow it so those are the three books that we have to choose from okay and what we're gonna do is we're gonna run a poll to see which one of these we're gonna read and these books except for this one this was a comic book haul we did in the last few months anyway okay that i showed you guys on a comic book haul but these two comic books are two of the comic books we decided to read when we did the set up the fourth reading set that we said we were going to read 32 books 16 was my choice 16 was reader's choice viewer's choice subscriber's choice i have the hardcover edition the kelvin hobs that's my horse the grand does not dare i'll put the poll together as soon as you're done intro in the comic sound good sounds good coolio i love that cover art thanks for that no worries brother just keep your sword at the ready so how much weird we're 15 minutes in let's run the polls gang let's see which comic we're going to choose and coolio set the poll for like a couple of minutes i think two minutes is plenty for people to make a vote because we only have three comics right my vote for those xo matter war don't know too much about comics but it looks cool it is very cool okay and as soon as coolio runs it and the poll is running gang i think we got two minutes to make votes okay and you can place your vote you make the little circle you dot it and you cast your vote and right now xo man of war is at three and crime does not pay is at one so xo man of war is at four so a lot of votes coming in for xo man of war crime does not pay is at two and kit colt is still in the gate hasn't left no votes for kit colt this is so much easier when there's only three horse rings right i wanted to put the years but the option uh have cleared the limits nowhere the years are this kit colt is 1962 silver age of comics crime does not pay is 1952 the golden age of comics and xo is 1992 modern comics and xos got five votes now crime does not pay is at three three votes okay so we're halfway through xo man of war is winning right now so if things do not change we're gonna read xo man of war crime does not pay is only two behind and kit colt is uh i don't think it's happening during this reading okay look at the top of the chat screen yeah look at the top of the chat screen there's a little arrow you can press it come on classic comic page oh crime does not pay is at four it's catching up four crime does not pay xos at five okay it could go either way we're down to about 30 seconds gang if you want to cast your votes you cast your votes let's get a five five tie and then we're gonna run two man race i should have brought a coin i should have brought a coin if it's a tie uh do we read them well i cool you i don't think we'll have time to read them both crime does not pay is a longer read than xo i believe okay because it's golden age they did a lot of reading xo wanted gang five votes four votes poor kit colt with jack Kirby dick heirs uh and stanley didn't get any votes oh no oh no xo man of war it is gang xo man of war let me put these guys here let's read xo man of war let me put this guy under it so elder god is like no elder god on the bright side in the next comic book reading there's only two choices now it'll be either kit colt or crime does not pay unless we introduce another reading unless we introduce another book okay xo by one vote xo by one vote next time i'll make it three minutes for more suspense yeah three this one it was only three votes so uh crime does not pay on nemo smokes too late too late we only made a two minute vote because we're 15 minutes in right i want to make sure we get the reading in and the suspense it was the suspense you've got to figure out which one we're going to read gang okay so i'm going to do the prep here gang i'm going to take down our notifications by the way gang thank you for the follows thank you for the subs okay i'm just going to take off the notifications so they don't pop up during the reading because this is really about focusing on the reading okay i'm sorry man i'm cooking in my hands we're covering food nemo says where were you elder god is asking him food cover hands don't touch the computer with food covered hands so i'm going to take off the notifications gang i'll take it off chat and i'm going to take off this camera so i'll be back after the reading and uh just to close things off when we can talk about the comic if you like you could have used your nose okay let me take this off and the chat is off already okay very cool very cool i'm gonna just do a quick little intro for this toes rumour jazzy and i've got this in my lard because it is an important book you can get it not a bad price right now we'll see where it goes chichu bedtime story hold on who's fun comic book reading got to love it got to love it okay and i'm just going to give a quick little intro as to who's in this book and stuff like this and then we'll get into the reading and i'm not sure if this is the one of the xo copies that i have that i've read or not hi everyone this is chichu welcome to my channel and welcome to another comic book reading and today we did a poll because we are live streaming this comic book reading and we had a choice between three comics and xo matter war number one won the poll that we ran and we're gonna end up reading this book from valiant comics okay and this is a book that came out in 1992 and it's one of the books that we chose to read when we did the sort of the reader choice viewer choice subscriber choice for reading set number three where i picked 16 books to read and you guys picked 16 books to read and i can't remember if this was one of my choices or one of your choices but i'm very happy to be reading this and this is again came out in 1992 by valiant comics and this is the first appearance of this character xo man of war okay eric now it's not the first appearance of the xo armor the xo armor the suit that eric is wearing made his first appearance in the first comic book series superhero comic book series that valiant comics put out aside from the gaming comics that they put out and i believe the first appearance of the xo armor was in magnus robot fighter it was the backup story of magnus robot fighter with the rye crossover so i believe it occurred in xo and magnus robot fighter either six seven or eight i might it might be number seven okay um it was i used to know this by heart and i try to find it on a couple websites uh just before the stream because i wasn't sure if we're gonna this was going to book that was going to be chosen to read but i couldn't find that speedy bonzala style so i'm just going by memory here okay now this book is neermann condition i want to crack it out of this and this is the mylar bag that i put it into okay let's take this out and take a look at it without the glare of the mylar bring it out i'll let you know who the creators for this comic car take a look at this thing and this book was it it was groundbreaking really uh what valiant did in 1990s was groundbreaking when they came up with their superhero line all in the same universe right and the creators of this comic book okay the main character is eric of dashia i hope i'm pronouncing that right so valiant hardcore valiant comic book people might not like my pronunciation of this okay and this was co-created by jim shooter and steve engelhardt and the art is by bob latin and barry winzer smith okay the inside art um i believe i don't think the cover art i believe the cover art is by bob latin what we're gonna do let's flip this now i can if you take a look at this this is a beautiful condition i would give this a 9.6 and valiant comics had this issue with the edges here right where most of the books have this cut on them okay so this would be you know 9.4 9.6 is there let me see if there's any dings on this what you can do just run your finger along the edge yeah i would give this 9.4 possibly possibly a 9.6 the edges are nice and sharp beautiful okay really and this exo armor is pretty unique in the comic book world what it is but i'm not going to give you guys any spoilers a double dragon explosion for your nes and gameboy nintendo acclaim and acclaim the gaming company ended up buying valiant comics in the late 1990s okay and they tried to do a relaunch of valiant but 1990s were a crazy period for comic books the even marvel comics ended up going bankrupt and they got bought out by toybiz i believe even jim shooter uh in the 1980s was trying to make a bit for marvel comics and then marvel comics did fantastic and wall street does what wall street does it ran it to the ground and the industry went through a bubble and bust and there was a major collapse of the comic book genre so we're not gonna flip through the buck oh this is beautiful look at this but what i'm gonna do is i'm gonna go to the back i'm just gonna make sure there's no because all the information that valiant puts out regarding who worked on the title and this is this is rye number one this is harbinger number three okay exo man of war number two and this is basically comics that were available the following month on sale in december this is exo man of war number two magnus the robot fighter number 10 solar man of the atom number seven so magnus was really the first comic that superhero comic that valiant comics put out and i'm just gonna read the we're not gonna try to avoid the last few pages of the thing but this is written by jim shooter let me show it to you jim shooter and steve engelhardt okay layouts are by barry windsor smith finished art is by bob latin and john heldridge coloris is george gonzales gonzales okay letter letter was jade an editor was david d david perlin okay now let's have a read through this and we're gonna go through all the pages for sure and this is uh choppers two rescuer survive get ready jvc is here with hot new games jvc was making games i didn't even know that crazy i had no idea jvc made games even though i've read this book i guess i must have forgotten save the hostages save the world oh my god cool chopper two so gang should we read this and this is eric of dashia and beautiful art valiant comics in the 1990s it you couldn't miss their artwork like they were so unique on the way they presented the pages the panels the coloring uh while a lot of people were going digital valiant comics was doing a lot of old school style of comic books very cool very cool so i'm not going to give you any spoilers on this we're just going to read this okay xo man of war retribution part one into the fire and the only spoiler i'm going to give you this this if you had stayed up with the valiant universe you were reading their comic books okay these creatures here you would have known from magnus robot fighter and solar man of the atom but since and we have read magnus robot fighter number five by the way we did a reading of that with the flip book and we flipped through magnus robot fighter number five which was sort of a double flip book where we read the first appearance of rye okay and we've read some other valiant comic books as well so xo man of war retribution part one into the fire this time i have to think to break the heart's skins with or this time i have a thing to break the heart's skins with he's got himself a little axe and this is the main character eric this time their juice flows this time i will kill them all they fear to make fire light lest they harm their house but i have harmed it i tore loose this thing it is hard and sharp this time it is eric the soft skin who keeps his juice their juice splatters and pulls on the floor but i will not drink it i'm not like them but soon i will i will have heart skin like them if the map is true still i will not drink their juice i will just kill them all now is the time to strike something has gone wrong with the heart skin something has filled them with fear many of them come to this house from outside seeking refuge i hear them make the clack clack for fire light and hiss for soft skin and the fear fear trip fear trill all of all at once but i know not what this means i do not care if the map is true if this forgotten forgotten crawl to you brings me unsmelt to the place then they then they should fear i he's just taking them all on we should read the fine print here gang we gotta read the fine print exo man award volume one number one february 1992 published by valiant a division of voyager communication jessica shooter president james shooter not jessica shooter james shooter president uh steve man manarski secretary office of publication 275 7th avenue new york new york 111001 copyright 1991 voyager communication ink all characters herein and the distinctive the likeness there of our trademarks of voyager communications inks all rights reserved dollar 95 per copy 250 canadian us subscription rate 2340 for 12 issues payable in us funds 30 30 dollars canadian printed where is it printed should be canada let's check it out printed in the us no similarity between any of the names characters person and or institutions in this magazine with those of any person living or dead or any inst institution is intended and any such similarity which may exist is purely coincidental we jumped at a reading before reading the fine print we always read the fine print so eric is making his way through the alien spaceship through the tunnels i crushed on their dried juices is like a hard skin over me i dreamt of this but it will take a harder skin to blunt their blows their fangs their fire there he's made his way to the exo armor this eric says this what good is this this will not cover me excess hard but not sharp too heavy a thing to wield it cannot help me help it cannot help me kill them a hard skin nowhere to flee nothing to fight with the map giver said find a ring seize it pull it loose here then i have done fully as bin but ah there's the ring right there and here's the ring right here and he slips in oh what is this the armor surrounds him they risk making fire light here this must be a good skin erics this skin is stronger than fire light would to see if there is would to see if theirs is so it's just deflecting the laser whatever it is they're firing at him right spaceship is blowing put a hole in it and these guys are called the eric calls them the hard skins right but they're called the spider creatures the aliens and they're prevalent in the valiant universe this is a good skin oh he says the way to outside is open outside is different than i remember but oh i want out and this skin carries me there this is a good skin erics says or rx says the house makes fire light if this skin will take me to the fangs that spit this fire light i would tear them loose destroying the ship blows it up falls to earth first till we zoom in and read the text so he lands in the snow takes off the hat let's see what he says the house gone in the ball of fire when i tore loose it's fangs the fire inside them turned on the house itself the hard skins are dead the map giver too worthy is a spirit i want this skin off it just walks away it was a good skin i wanted for a walking place underfoot after the house was gone and it brought me here it just leaves it behind this outside is much more like i remember soft skins but not like me their chatter makes less sense than hard skin talk i will talk i will take their food they will they will run away or i will kill them they do not run they bring me more they are crazy but the food is good they had better bring more now we are truly at risk prather the disintegration of our ship of our fleet leaves few options leaves options nonetheless lydia and we will not lose heart we are more than a fleet and even cut off we are never pray we are the predators don't lecture me doctor i know how much we have left and how much death it represents on this world but i must regret the loss of our lifeline all we need all we need my dear is the exo armor and it was tracked to peru the primitive has the ring but he cannot have gone far the primitive has the ring she asks so he controls the exo the primitive has the brain of an ox my dear he cannot conceive of what he has he is prey yellow sweet things grow on trees this folk is dark eyed dark skin dark skin they speak like spring thawed but brooks what place is this it is not my home our access we're thanks i'm sorry if i can't read this properly okay i don't read Spanish it is my i have no idea we just read it brutal teacher of pronunciation my god the ring pulls her eyes like she pulls mine mera maybe another tribe but her skin is soft how long says i love the woman 10 sons hola arek listo para el vajo vajo vajo trek adios arek at last i make the trek to their city maybe i will find the wizard there to tell me where i am and how to find my folk someone will tell tell me my laughs arm this i swear que esta esto looks like there's helicopters coming half a day in the city already and no sign of a wizards palace only more heat and worse air the letters of the heart skins never breathe smoke like arek arek that's the kid kid came after arek slaughter i run as fast as i could but i am soft soft after 10 sons in the heart skins house i have taken too long nothing could have saved the folk but oh that i could have caught the heart skins while they they yet fed look at the people the spider aliens they suck the people dry they grow slow themselves when they suck the juice the juice look at this this maria's head her head that's her the ring look at that was that in her hair the ornaments there's a thing not hers in her hair i have seen it in the house oh what is this it speaks in my own tongue oh no it's not the ring we have the exo armor arek leave the ring for us here and walk away we will feed on your friends no more oh so it's just uh it wasn't the ring it's just uh basically a note they left for arek they threatened me instead of killing me they fear me they fear the ring the ring is part of the good skin the ring talks with the voice in my head telling me where they're they've taken the good skin it's brother north the villagers people have survived north north he just keeps on walking north ampton massachusetts i don't understand your problem are arestides if you've located the primitive again why not handle it yourself why drag me into the sunlight he's coming this way lydia so eric is walking up from peru towards the us well he can't drive a car or fly a plane so he must be walking how long do you suppose it will take him to walk to new england from peru long enough for him to learn more about the rain perhaps haven't i told you how stupid he is he's a barbarian even by earth standards you've told me he says but he's a barbarian who's tasted power he's giving our task worth fits the exo suit is mad at war class even now it fights to be free as long as he's in touch with it the point is taken and we do not need the ring as soon as possible all right let me propose a piece of treasury she says look at eric he's just hiding making his way up north he has a destination to get to like the spider aliens it is good to have taken those skins off now i'm able to move our access i hate these things but if they make firelight for the heart skin they'll make firelight for me he doesn't like the guns the lasers the weapons they use there's the aliens base lydia this is costing me denizens and i don't like it yes there's new smoke rising from the south and their phone has gone dead if he kills enough of my uh perimeter guards he might get his hands on something wait a minute they look so big through through this hole so easy to hit he says such a barbarian awesome close it up and that's one thing with the valiant comics i'll i'll mention this they didn't do sound effects a lot of the other comics you've read they have sound effects these guys don't do sound effects they let the imagery represent the sound right blows up the helicopter maleche maleche are you there maleche good primitive you're in my web now she says nice paddle work another city how many can there be she's just walking around naked it's like this that uh that moment's chatter it is much like the sound of home that's because is from the european continent you are american yes you speak english i don't know we ever see anyone so ready uh jackie but this one sounds like a raven again can the one with hair like mine know my folk what's he grunting about as the dude says maybe he can't talk baby we can play king the king of the jungle if you want if you got money on you somewhere this one is very kind she makes me think of ma mara and jumps out die scum one of the heart skins sheriffs i hated them so much in the house arak is an amazing fighter by the way will not go back you shouldn't give me such a good grip on your head your neck is too weak he did break it look at that you see one of the ones with poison in their teeth no he has no green stripes on his clothing thank you low i am very fortunate an l u g h low that's uh like a cron crom for conan right one of their gods low magnificent my man truly magnificent someone says more chatter magnificent my man truly magnificent was this was this i came looking for local color but you surpassed my wildest dreams he talks that third tongue the one that sounds like ravens what does he want listen you better let me have a look at that wound it could get infected you know look at the size of the shadow placement he clocks like a woman over my wound puncture wounds the worst kind that needs dressing look at the alien just dead there on the porch the processes are like what the hell will you come with me i can buy what we need he is very birdlike like a wizard maybe he's the one i've been seeking first thing we've got to do is get you clean the water is actually pretty decent here it won't give you any more bugs my name's ken by the way what's yours with the strange oils and rituals he must be a wizard arach things well you could have knocked me over with a feather i mean people are generally so short in this country that i look like king kong but why does he not begin his wizardry ah he wants me to sleep here it is heart sticks and too short the only other bed i have to offer you is mine but i guess that's not for you i guess maybe i must be completely refreshed he's like sleeping in this little cup thing gross well good night if you get too cold he's making a proposal to exo to arach like all wizards he knows little of warriors i can sleep anywhere but with the fighting i've done and the light fighting i will do i was better off in a comfortable place darn it don't tell me he ran away holy jeez don't do that well yeah if i want it so brute to growl at me in the morning i'd buy a saint bernard the tree behind the planter you're really on somebody's hit list aren't you you've got a couple of i've got a couple of ideas about that i have not been without a beard since first it sprang from my face but this land is so warm i do not miss it ha now he brings me to the soft skins houses now the wizardry wizardry begins so you just look like pro wrestler look like a pro wrestler and once we get you out of the country you'll really be safe oh wager this is one of those houses like the heart skin a house that wizardry makes move listen you're probably nervous probably don't understand the thing about flying he's got his hand over rx army and there's the exo ring but so long as we hold on to each other we'll be all right that's a very attractive ring you're wearing do you mind if i thanks look he just pushes him back look at that is there something to matter the stewardess asks asks uh no no my drink just went down the wrong way wizard or not this ring is mine arc thanks new york i have never seen so many people of all different folk arc thanks it's not time for gracia yet big fella not while you're fugitive and have gotta got an underground to tap into wait right here while i make a phone call thank you ken oh he's working for these guys look at this maybe he's working for these guys this house annoys me even in the heart skins house there were not so many different folk i will walk north whoa big guy where are you going i've got us a place where you'll be safe i wish he spoke my tongue he has been very kind but the voice in my head says north i follow the ring what oh something something about the ring he's just pointing to it gracias me go he is one of those men who loves men i do not understand them but they can be good wizards he has brought me far north someday i will bring him great reward hey people are watching ken says gives him a gigantic hug an arc i do not understand them but they can be good wizards me go me go ken a me go ken look at his head huge he doesn't understand but no he does walk north listen big guy i know you don't understand but this isn't a nice world it probably wasn't when the spiders took you off this planet but it's got to be worse today we've all got to do things we don't want to do just to survive my life's been so so my life's been no better roses ken says i got an MBA went to work i was ambitious okay i did i didn't know who my bosses really were by the time i did i figured so they were weird so a lot of people think i'm weird so hell i can't do this listen to me understand me you've got to run away they're going to kill you ken says maybe he does understand me this is good arc thanks something's going wrong i think the little ones betraying us on my signal we attack spider alien so arach was gonna or ken was gonna betray arach and bring him to the spider aliens right heart skins ken is hurt oh they shot him how can they have found me after i came so far north even a wizard oh they blew up his arm look at that even a wizard can be stunned when he is hurt then his friends must help him my arm ken says he has never fought the heart skins he knows nothing of their cruelty i have fought them i must beat them fast now or ken will die big guy no i have a clear shot at the decoy commander forget him forget everything except the primitive oh ken they're going after arach he dodges well for having only two real legs i guess they had to develop that before they got civilized but i can blanket the area and watch what you're doing those are gasoline through truck those are gasoline truck trucks he was going to say the whole thing blows up boom messy but effective he must be dead the spider aliens say but what if he what if it melted the ring nonsense you cannot harm exo armor heavy things on top of me i cannot rise but my juices are still mine and even now the voice of my head calls north he's like totally buried in fire i cannot go north i need the good skin here if i hear it will it hear me the edge the edge the exo armor is breaking loose aris deeds what's happened what what what happens there's troubles the skins coming to him that's impossible it's our technology we control it but it has designed to adapt to its owner i told you i told you the barbarian had tasted power it's free the exo armor escapes the voice in my head is no longer whispers north it no longer whispers north i can hear it clearly now crying yes the exo armor is happy escaped its captivity yes yes flies out of the building the good skin it comes our excess it kicks the heavy things away from me nice exo man or what happened did someone else shoot at him no lilies calling it's the exo armor the exo the aliens just figured out what the hell's going on again the good skin wraps around me like a bear skin but this is a bear that's still that's still can bite where are you going what are you what are you doing you cowards it doesn't matter if he has the armor he doesn't know how to use it what are the aliens says does he have to know it knows we made it and we made the weapons which will destroy it i must jump away from the firelight all right thanks but i have jumped and cannot come down i do not like this and yet the jump carries me closer to the fire maker so you just learn how to fly it and the heart skin inside look at that he's sitting me on the console controlling the i guess the war machine right all right just tears it open i'll read through this long panel let's see what we got but i cannot reach him my jump has stopped and i cannot move forward backward or anywhere i float like a dead dog on a lake arc make me move law make me move make me your mind now primitive there was no need for you to die no need for you to murder and humiliate humiliate my denizens are floating there his clack clack i have heard it before his was the sound and the thing from the from mara's hair he sucked her juice he's the one that left the message for uh he must die at my hands our excess no need for you to die but watching your death will afford my great pleasure i catch his exo cut twist twist and turn as you will in the hands of my techno controller but we are the predators and you and all your kind are nothing but prey he must die at my hands exo says and my hand makes fire lights my hand cut off his hand this is truly a good skin an arc is truly a fool for almost losing it die by my hand hard skin die with with your hands die with your house just breaks through the glass and die with your hard hard skin be down you primitive for more mora for arc just grabs his head die die die squishes his head juices everywhere what do you think mac some secret government plane or dope deal gone bust probably gang warfare tommy there's was supposed to be a bunch of guys in fancy colors but hey people exaggerate there's a cops checking out the destruction now lydia now i admit we face risk all that savagery in our best armor prather we must plan the last two panels of the page with the comic right let's see what arac is thinking i knew ken was a wizard most men would have let their spirit fly away with their arm but he has clutched his spirit tight i have avenged you migo you and mora and all the others not that the crowded house is behind us i will find you a healer still alive oh my saint bernard i like it he's in love with exo awesome when the hard skins took me from my home i could not make them die but with this new skin i can with the new skin i am the strongest one with this new skin arac rules awesome excellent first issue for the beginning of an epic right of an epic introduction of one of the most important characters in comic book history really fantastic fantastic and jim shooter at the back of every issue of the early valiant comics he would write a letter and talk about what was going on in with valiant comics tweeze tweezing back formation featuring tweezers 1985 to examine closely and correct flaws especially minute flaws minute flaws ask the design director to the ad layout tweezer frank zappa 1985 a critic especially one particularly cautious of detail or fine points janet jackson valiant's design director is a tweezer i guess you'll hear tweeze in his various forms check this out you'll hear tweeze in his well let's get this focused you'll hear tweeze in his various forms a lot around here i.e the bob tweeze edit jim script yet these photo cast photo photo stats will be fine once their tweeze touched up ask that tweezer perfectionist emily to proof read this letter he's a good penciler but he needs some tweezing minor corrections you'll hear the word the most in reference to janet jackson janet jackson or jj as she prefers to be called is a superb designer a wizard like care technical expert on accomplished and accomplished editor the best colorist in the business and the pickiest tweezer in the universe she wants things right and this is jim shooter writes this and then signs it oh look at this next the grim truth about the industry should we read this should we read this let's check this out let's have a read through this game i think we got time let's check it out let's make sure our live stream is oh yeah we got time let's read through this speedy ones out style sometimes tweezer takes on a harsh connotation i.e that rotten tweezer picked me clean picked me clean headed on this job in fact that was a sense of the word as originally coined by frank zappa however no one would ever use that pejorative sense in reference to jj everybody knows that our constructive tweeziness is critical to our success me i'm known as the uber tweezer i can't imagine why janet tweezer hands was in reference to edward scissor hands right drawn by bob who drawn by rod ram ramos janet tweezer hands one of the biggest problems facing valiant from the start was finding enough creative talent to build the valiant universe it's not hard for independents to find the talents they need because they publish one shots limited series stand-alones and irregular titles short-term commitments are easy to come by but valiant isn't an independent we're a new major we're building a universe and that requires long-term commitment and dedication fortunately we had a new place of talented people around whom to build and fortunately we've been able to attract some outstanding creators who were willing to commit significant time and effort to valiant including such notables as steve ditko, stan drake, john dixon, steve engelhardt, dave miscellany, and barry windsor smith others are present presenting themselves daily but comics take a lot of work and we knew we'd need many hands bob latin bob latin our stealth gandhi suggested early on that we should try growing some talent in a vat and so knob row was born here's how it works knob row we review lots of portfolios the best and brightest potential stars are hired hired on as noobs i guess that's supposed to be noobs or knobs knobs bob calls them knobs because they say we have to turn them presumed oh knob turn them turn them preserve preserve presumably from the dark side of the force as knobs they do a lot of the less glamorous work inking backgrounds under paintings tracing roughs they earn not too much though they always seem to have enough to party working closely with art development supervisor jade art director don pearl jj and bob they learn the craft as they learn they take on more and more responsibility until they're ready for solo flight george gonzalez for instance has emerged as one of the premier color artists in the business watch for his work on xo manomore number one and his his talent doesn't end there soon you'll be seeing his name popping up all over the credits rob rob tom rider who's making his debut as an incur on magnus robot fighter number 10 and doing an incredible job watch for the names maria bachari bachari and john holdridge two and others i'll keep you posted a lot of our knobs come from the joe cubert school of cartoon and graphic arts by the way the most important thing they seem to learn there are professionalism good attitude and solid work habits if they've got those things and talent we can teach them the rest it's only a matter of showing them how giving them a chance and tweezing them here and there as they go and of course we are fully equipped with tweezers the constructive kind jj says i should add quote as one uber tweezers what does she mean by that and one uber tweezers sincerely jim shooter tweeze the knobs this is my quote says in the live chat and these were the these were the issues that were coming up next month december right ride number one this ride series was absolutely fantastic really i think in my opinion one of the most underrated series there is harbinger number three fantastic fantastic series xo number two magnus robot fighter number 10 and solar man of the atom number seven awesome and a movie advertisement hook with robin williams ride and double dragon nice nice nice awesome fun read fun read i hope you guys enjoyed xo man of war number one first appearance of aurek of dashia and xo man of war from valiant comics fantastic i'm going to turn on the chat for our live stream and turn on the notifications and turn on my fun that was a fun read fantastic read i hadn't read this for so long so long but surprisingly i retained a lot of the info i think maybe because there was a little bit of overlap with the 2012 relaunch right a little different but the 2012 relaunch goes into a lot more detail as to ended up finding the armor and you get a little bit of history of the armor and the it's it's beautiful okay and if you want to know the new lore of the xo armor from the 2012 relaunch read armor hard hunters it was a crossover that valiant comics put out with it crossed over the first harbingers theories the 2012 harbingers that actually crossed over all the 2012 valiant titles that came out that was from the third relaunch i guess and it was an around across 18 issues and it is absolutely magnificent and and the mythology the lore that it builds up regarding the xo armor is absolutely brilliant really highly highly recommend highly highly recommend let me put this thing under here so we don't get the glare okay aside from that i hope you guys like the read fun uh yes Cheryl how are you doing but i'm glad you were able to do it i was a double book for a while but so glad i could catch the end awesome Cheryl glad to have you and cool you the random poll for us it was fantastic clap clap clap my con oh my god it's not been made into a movie yet no not you know what there's sort of a online uh ninja versus the valiant universe that they made like shorts that were released on youtube but they weren't very good and man if they ever make an xo movie and i'm guessing they will at some point fingers crossed i hope they do do it justice this is one of the best sci-fi stories around especially with superhero related coolio according to wikipedia xo mana war appears in a video game alongside iron man yeah there was a crossover of valiant comics and marvel comics where their characters crossed over in video games uh and xo mana war would kick iron man's ass he would he would just wipe the sidewalk with iron man iron man couldn't do yeah tony stark could not do anything tony stark was a little rich boy uh that paid for his armor arach of dashia is a barbarian warrior that fought to get this armor totally different game totally different game coolio also from wikipedia in september 2016 newly formed valiant entertainment announced a feature film centered around arach of dashia xo mana war executives of the company stated that there were notable directors attached to the project and that the film will be true to the source material by april 2020 john uh sensa teased his involvement with the film via his social media platform really uh i knew about two two thousand and sixteen when they were trying to do stuff and then they would shake up in the valiant company but this is uh 2020 now so fingers crossed they do john sena is everywhere in september 2016 psycho says newly formed valiant entertainment announced a feature film uh center around oh so this is the same one you guys both coolio and psycho both went to wiki to find the duplicated elder god lives john sena the wrestler same as um he's what do you call it in gardens of the galaxy isn't it he'd make a good barbarian you make a good barbarian i'm not sure if you make a good xo really i'm not i'm not sure if you make a good xo um fingers crossed fingers crossed but arach isn't the sharpest uh crayon in the box stark we're outsmart him um my con i know because arach with the xo armor blows away iron man right arach is just a barbarian he's a brute right he just to give you guys a little bit of history like and i'm giving you spoilers now he got kidnapped by the aliens and really the the if you want to read the grander history lore of the xo armor and stuff i would recommend the 2012 xo mad award series the valiant this 1992 series the original series is fantastic really fun right but the 2012 one really amplifies the sci-fi aspect of it so i'm not uh i don't want to give any spoilers on it it's brilliant oh that's bat batista in is uh uh drag and go yeah that's right so which one's uh john censor i don't know john censors that's that's uh batista that's right of drags that's right sorry i got the names all confused and the rock is in a bunch of stuff too yeah maybe the rock the rock isn't brutal enough he's got a little bit too much comedic in him dave batista is a former wwe wrestler he plays drags and drags the destroying guardians that's right that's right i can see or hear john censor anymore without the audio from the mean with kid and recorder torture i gotta look up john censor john censor cool he was laughing and be confusing everybody i see chris hensworth nights of old comic chicho what makes xo such an important character of all time in your opinion i read one to ten or so when it came out but don't remember much it was is very unique character it takes it from earth right and introduces uh science fiction sci-fi opera really about who the aliens are and really connects it up to mythology that is very original incredibly original and the xo armor i can't give i can't tell you what makes it so unique without giving you spoilers uh regarding the armor hunters crossover okay nights of old comic highly recommend reading an 18 issue um armor hunters crossover from the 2012 relaunch of the valiant universe it really just kicks it up a couple orders of magnitude absolutely magnificent really very unique john censor is the rapper wrestler guy i don't know it's pronounced like sina oh john sina he was in bumblebee oh i saw bumblebee i can't remember bumblebee okay i gotta look this up man john sina john sina what does he look like oh this guy oh yeah he would make a good xo yeah that's right he would make a good xo he would make a great xo actually so the aliens held him captive ever since early days of man or was he in some crypto sleep thing uh my con they grabbed them you have to read it dude i don't want to give spoilers for other people that want to read it it would be good for the popularity of the movie but i don't think john sina is a very good actor i don't know him as an actor look wise he looks pretty good he looks pretty good he wouldn't be as good at eric okay i don't know if the director and writer is good though it might make up for yeah a lot of people for example a lot of people really didn't like before konan the barbarian came out arno schorzenegger is konan the barbarian the original movie but the original konan movie is fantastic right it's arno schorzenegger best movie it's better than terminator right terminator was really good but konan really put schorzenegger on the map as an actor right sina acts in film like a wrestler in a ring does he yeah he looks pretty spot on but he's not really an actor oh that's too bad when are they going to make a really good video game movie really good video game movie and you know gang uh i like sonic sonic movie was pretty good i enjoyed it it wasn't 10 out of 10 but it was enjoyable konan and durham were filmed at the same time but the same crew were they elder god what they probably use the same desert save money right i wonder if there was a same company that produced a sonic was a cartoon for years though yeah but there's a sonic movie with jim carrey as the bad guy and it was pretty good i enjoyed it ah true that true that sonic was video game first it was on comic book first so true that the detective uh pikachu was pretty good was it i haven't seen it detective pikachu hilarious gang should we call the stream let's call the stream same desert in mexico it was filmed in mexico i didn't know that cool cool cool cool cool cool racket ralph is pretty good yeah actually that was fun but not really based on actual game yeah i want to see the you want to see that the which one the detective pikachu i haven't seen it i even know if there was a detective pikachu mortal combat movie was pretty good i like that one the first one was really good that's true that's based on a video game so mortal combat was fun um and um um doom was good with uh the rapper the mars like doom was not a bad movie man like people were trash talking doom was good and uh what do you call it um uh not the virus uh oh my god i forget it uh oh i stippled my tongue um resident evil resident evil was pretty good doom was okay i like doom doom was fun low blow i said good movie gulips that too a mortal combat mortal combat was not bad it was pretty good doom i like doom i like doom and resident evil was pretty damn good resident evil was fantastic 18th december i would be the first man in the cinema for doom ah really other god they had the rock in it though it was doom was good man i enjoyed doom they could never do mortal combat justice unless the violence is a hyper realistic as the game possibly they do have a new mortal combat coming out next year though video game or movie have you seen hardcore henry i watched it i didn't like the first person i was getting motion sickness everyone except doom to be done like that produced produced by warner brothers and the ending of doom when they had the first person it was really good man it's going to be insane i think hi there chicho fita fita how are you doing hope you're doing well gang let's call the street thank you for being here maus thank you for taking care of business gang thank you for the conversations and the young pup quote will fit perfectly for new paul actor yeah he does look like a young pup indeed have you read valerian i've read one and the movie was not bad it was pretty good wait the tomb raider movies are based on the yeah tomb raider i think resident evil blows away tomb raider in terms of movies resident evil the first three were really good even the the animated one was really good too fun true true nice gang i'm on patreon if you want to follow this work patreon.com forward slash chicho chy cho you want to support this work patreon is a fantastic way to do so everything is great if con ones i don't put anything behind paywall share and share a like people laugh at the uh street mortal combat now but for me 1970s child it was awesome when it came out it had great soundtrack crazy music for its time the special effects were 10 out of 10 and also back then people were still experimenting and it and it was one of the first attempts to put a vg on the screen and in my opinion they say i think so too if we're talking about the mortal combat movie i think so too gang on live streaming on twitch you want to follow these live streams live watch these videos live participate in the chat over here twitch is where you want to be at and gang thank you for the follows thank you for the subs i do announce these live streams 30 minutes before we go live on aloe vk mines gab parlor and twitter you can follow the work there and we do with this share additional content there as well there's also alone in the dark movie haven't seen it though i can't remember if i've seen it are we on movies next round i'm not sure elder god i'm going to try to do something i might do set up two or three live streams where we go through my boxes of video games i think it's the only way i'm going to get to sort them because they're all over the place so i might bring all my boxes to the living room and we do like three days of streams in a row and we just open boxes and i show you what i got and then maybe sort of sort them out maybe i'll have to watch the mortal combat movie again add it to the next movie stream possibly your soul is mine there was a world of warcraft movie it was fun that's true i'd like the world war world of warcraft movie that was a fun movie for sure though mario brothers was horrendous good idea that would be fun video game stream i'll see i'll see i gotta do some leg raises and sit up to strengthen my stomach because i gotta lift a few boxes watch the mortal combat series on youtube the indian one it was really good really okay okay uh we'll put on our watch list uh for video for live streams where we don't have any visuals uh we will be uploading the audios to soundclad.com forward slash chicho as podcasts and they should be available on your favorite podcasting platform as well and we'll get a lot of videos hundreds that we're going to be uploading there at some point over the next couple of years or so trying to catch up and staying up with what we are doing and this video will be uploaded to youtube and bichute and if you want to support this work you can subscribe you can share you can turn on notifications you can comment uh and if you're on youtube you can support this work through youtube membership okay gang uh we don't mention mario here well to god's sense charles laughing they also made a movie of the hitman i like the hitman one actually the hitman one's pretty good i think i've seen it pleat thank you for the stream i joined 15 minutes ago i missed it again it is hard for me to watch it is uh 204 a.m for me and i rarely stay that late i am lucky i still have my job many many do not many do not and my pleasure for the stream and gang thank you for being here and uh i'll announce the next set of streams probably in about two or three days okay expect the next announcement to be made let's say by the weekend if not friday then saturday okay gang peace everyone xo maddo bore i hated the hitman movie i knew all the places they showed they showed him in uh sofia bg i don't know where bg is bg bg bg where would bg be where is bg sofia bg oh i don't know bulgaria oh wow sofia bulgaria i've been to bulgaria i like your country i think i've been to bulgaria anyway gang see you next set of streams or on discord of course bye everyone


Hello, welcome to the lecture number 24 of the course quantum mechanics and molecular spectroscopy ok. Now in the several classes we were looking at the transition moment integral and its relation to other quantities such as Einstein's E coefficient, B coefficient and the absorption spectrum through Pierre Lambert law. But from now onwards I am going to take a slightly different term and try to get the selection rules ok. Now if you go back quite a few classes then we came across this equation which I will write it down as probability of transition P of t if state f is given by E naught square divided by 4 h bar square omega f i by omega square sin square delta omega by 2 into t divided by delta omega by 2 square modulus of f mu dot E i square and we remember we called it as transition moment ok. Now it turns out that P f of t is proportional to your transition moment integral square. So, what are you doing here? You are going from a state i to state f ok and we also related all this to Einstein's E coefficient, Einstein's B coefficient and the extinction coefficient through Pierre Lambert. We also looked at the line shapes ok. All these experimental quantities could be related to this. Now it turns out that if I slightly rewrite so in the vicinity of omega f i ok that means what I am doing is omega f i is approximately equal to omega that means you will have a transition only when there is a resonance ok. So, in that scenario one can rewrite this equation P f of t. So, when you have omega f i is equal to omega I can ignore this term. So, I will get this will be equal to E naught square by 4 h bar square sin of delta omega by 2 divided by delta omega by 2 square mu dot epsilon ok. Now we know this function is the line shape ok it determines the line shape ok. Now what we have of course all these are non-zeros. So, the selection will be allowed or not is given by this integral ok. So, one can write transition moment integral T mi is equal to f dot epsilon i ok this is my transition moment integral and whether the transition from 1 to 2 or f 2 I will be allowed or not will depend on this integral. If this integral is 0 the transition is forbidden if this is 0 then it is forbidden this is not equal to 0 then we have allowed and 0 not equal to 0 they combine what is known as selection rules. Now what we will do in this lecture is to look at this operator mu what now let us think of a molecule AB ok. So, two atoms A and B are combined and A and B because they are not the same. So, there will be say let us say delta plus and delta minus. So, you have a dipole and if the distance equilibrium distances are not. So, for example, if you have a AB molecule one can draw a potential energy surface like this that is the zero of energy and the distance goes to infinity asymptotically ok. Now what I am trying to do is that of course if you go from here to say here there is a huge change in the geometry or the bond distance that it spans. So, one can always think that the movements are not. So, one is looking at around the equilibrium position if you look at around the equilibrium geometry one can write mu as a Taylor series expansion.  One can write a Taylor series. Now let us look at it in a slightly more useful way.  So, this is how I can write my mu as a Taylor series expansion around the equilibrium geometry and this mu naught is the permanent dipole. And what is d mu by d r how the dipole movement changes with respect to r ok. It is a first derivative and you have second derivative. So, one can write it as mu is equal to mu naught plus alpha dot r plus 1 over 2 beta r square plus 1 over 6 gamma r cube etcetera where alpha equals to where alpha equals to d mu by d r evaluated at r naught beta is nothing but d square mu by d r square evaluated at r naught and gamma equals to d square actually one could take even the constants into the. So, when I if I write this as half then I can delete this and if I delete this then one can write 1 over 6 d square mu by d r cube ok. So, one can write such equation. So, this is your permanent dipole there is a first derivative of mu this is second derivative coefficient and the third derivative coefficients ok. So, this is how one can write in terms of Taylor series expansion.  So, this is the transition moment that we need to evaluate ok. When I say dipole moment it is basically linear combination of permanent dipole moment and it is derivative at various levels of various degrees with respect to r ok. So, this is the transition moment integral that I need to consider.  So, that is the transition moment integral I am interested in ok. Now, let us look at this equations phi ok. So, what are my solutions? So, what are my solutions? I said H naught into i is equal to E i E i i and H naught into f is equal to ok. What are my H naught? H naught is the Hamiltonian for which I know the solutions. So, E and E f are the Eigen values of the functions Eigen functions i and f ok. Now, what is H naught? That is the thing that we have to figure out ok. To in this course from up till now we have never bothered what is the H naught. H naught we just assume is some Hamiltonian for which we know the solutions and once we know the solutions we can evaluate the transition moment integral and that transition moment integral can related to various experimentally measurable quantities. But right now we have not even thought about what the H naught could be. Now, if you write the entire molecular Hamiltonian which I am going to write. So, H molecule ok. So, H naught molecule is nothing but minus h bar square by 2 sum over alpha del square alpha by m alpha that is the kinetic energy of the nuclei where alpha is its index minus h bar square by 2 m e sigma over i del square i. So, i is the index on the electron. So, the kinetic energy of all the electrons minus attraction between the nucleus and all the electrons. So, this will be 1 by 4 pi epsilon naught sum over alpha sum over i z alpha e square by r alpha i. So, that is the distance between the electron and the nucleus. Then we have a nuclear-nuclear repulsion. So, that is equal to 1 over 4 pi epsilon naught sum over alpha sum over beta greater than alpha z alpha z beta e square by r alpha beta that is the nuclear repulsion because alpha and beta are 2 nucleus and you do not want to count the repulsion between the nuclei same nucleus that is why alpha is not equal to beta and then you have to have only 1 if alpha is if nucleus 1 is repelling 2 nucleus 2. So, it is same as nucleus 2 repelling a nucleus 1. So, it is. So, to make sure that you do not repeat the terms use this kind of notation plus similarly with the electron 4 pi epsilon naught sum over i sum over j greater than i e square by r i j. So, we have 5 terms. So, this is K e of nucleus K e of nuclei this is K e of electrons this is nothing but P e of electrons and nucleus that is attraction this is what P e of nucleus to nucleus that is repulsion and this is nothing but your P e of P e that is nothing but electron repulsion H naught of molecule multiplied by psi now which is a function of electrons and nucleus should be equal to E n psi which is function of electrons and nucleus. Now, it turns out that this is not a possible solution. So, what we do is what we use something called bond open Heimer this approximation says that the total wave function psi of electrons and nucleus can be separated as chi of nucleus and phi of electrons parametrically dependent on nuclei and the total Hamiltonian H naught can be written as H nuclei less H ok. Now, it turns out that when I look at H nucleus the H nucleus even though is this H nucleus the total energy is equal to H nucleus chi nucleus will give you E nucleus chi nucleus, but the total energy E is nothing but E n plus E electron. But you see the phi V. So, now, if you have H electron acting on phi electron and that is parametrically depends on nucleus what was parametrically depend on nucleus means for every different nuclei position the Hamiltonian of the electrons will be different give a different solution. So, that will nothing but E E plus phi. So, this E E also depends on nucleus because the wave function itself. So, if you take the total energy or the nuclear energy nuclear energy is just not the repulsion, but it also kind of has the electronic component into it and that is called potential energy ok. So, E so when you have P E that is nothing but you have E in electro nucleus plus E electron ok. So, what you do is you can draw make a potential surface ok that is E. So, that depends on how the electrons and the nuclei are arranged as a function of distance. Now, one of the issues that we have is the following. So, when you have total wave function which is in the total wave function psi of E comma n is nothing but chi of n into phi of E and parametrically depend on N ok. Now, this is my total solution and of course, it will have its own quantum numbers. So, what I am looking at is the following I am starting from a final function f. Now, this f function could be written as the following chi nucleus phi electron nucleus some quantum all of this having some quantum number let us say A, B, C or I will call it as A prime, B prime, C prime I will come to what these are and this multiplied by your mu dot E multiplied by function I which will I will call it as chi n phi E to N having quantum numbers A, B, C ok. So, what I am trying to do here I am going from a wave function initial wave function which will have quantum number A, B, C and this quantum number could involve the nuclear quantum numbers or quantum numbers related to the nuclear motion and the quantum numbers related to the electronic motion and with some values A, B, C and I am going from there and changing my quantum numbers to A prime, B prime, C prime ok. Now, what I am trying to do is the following I am going from one set of electronic and nuclear coordinates to a different set of electronic and nuclear coordinates and this transition is bought about by this operator. So, now we can think of it this way. So, this operator is really complicated in some sense is that chi n phi n E to N whole thing of A prime, B prime, C prime mu naught plus r plus beta r square plus gamma r cube whole pi chi n phi E N whole thing of A, B. So, I am looking at such a transient moment integral ok. So, when I take the total wave function ok. So, this is how we are going to look at this transient moment integral. But of course, the way it is written it is almost impossible to solve. So, we have to make right approximations to be able to solve this transient moment integral evaluate the transient moment integral and look at the selection rules which we will continue in the next lecture. Thank you.


Income tax 2023-2024, methods and tools for learning tax law. Get ready and some coffee because we're setting our refund to the max with income tax preparation 2023-2024. Learning income tax law can be daunting, can be overwhelming in part because there's a whole lot of income tax law, because the income tax law is often written in confusing legalese type language which can be confusing to understand at first and because the income tax law is constantly changing. The tax law being a human construction that adopts over time in a similar way as a living organism adopts to the environment. So in other words, we're not learning something like in physics where we have a particular formula that we have discovered which will remain constant through all of time. We're working with something that's going to be changing as time changes and we can think of that as a bad thing but it can also be a good thing because once we understand the fundamental workings and conditions of the tax law we can adopt with it and if we can keep up to date with the tax law once we have a grasp of it then that's going to give us a little bit more job security and it can actually be an interesting thing to track over time. So what we need then of course is a strategy and approach to learning the income tax law and then of course a strategy and approach to be staying on top of the tax law as the tax law changes over time. One of those strategies as we touched on in a prior presentation is specialization. In other words, because the tax code is so large, what we want to do is pick an area where we want to specialize in and possibly grow from that area over time. Sometimes this happens just naturally by your work experience. In other words, you go work at a CPA firm or a tax firm and they start having you work on a particular type of tax return and that becomes your specialty. Sometimes you're more mindful about what that specialty will be. Oftentimes if you're trying to start your own business, this can be quite difficult because people try to basically take on too many things rather than specializing in a particular area and they don't have that corporate structure which kind of forces them to specialize in a particular area. So you want to know what you know, you also want to know what you don't know. You want to know which clients are good fits that you can pick up and which clients you really need to be able to say no to and have the rationale as to why you're saying no to those particular clients which for many of us is actually one of the most difficult types of things to do because you just want to be able to pick up all the clients. Just do all the tax returns. Just do them for free. It'll be great. But no, you don't want to do that. That's not the way to go. So we talked about some of the ways that you can specialize if you're doing tax preparation would be are you doing a whole lot of more basic type of tax returns in which case your profit margins will typically be lower. However, you're going to do more tax returns because hopefully they will be easier or do you focus in on higher income tax returns in which case you're going to have higher profit margins but do less returns and possibly make more money with tax advice type of things, tax planning type of work. Again, you can also specialize in business taxes versus individual taxes. This course is going to be focused more on the individual taxes to form 1040 but we'll touch on some of the business components such as having a schedule C for example and schedule E which is going to be a sole proprietorship and the real estate but you can also specialize in flow through entities, S corporations, partnerships for example or corporations and have that as your focus. If you're more accounting oriented then those might be more of a natural fit because they have more of the accounting system kind of incorporated within it. When you're talking about individual income tax returns data input into say the form 1040 oftentimes we don't have that double entry accounting system and therefore we need to come up with our own systems internally to double check that we don't have data input errors because if you have an accounting background we know that if you put stuff into a software we usually feel more comfortable with it if your accounting came from QuickBooks and they reconciled the bank accounts then at least they're using a double entry accounting system I have a little bit more confidence over it but with taxes even if you're doing a business tax return we might just be entering in essence the income statement so we don't have that double check of the double entry accounting system and we don't have the double check of the bank reconciliations so we want to put in our own like internal controls to make sure that we're inputting the tax return properly. So in order to envision the whole process of learning the tax return how can we give advice about taxes and answer questions and so on and then how do we get to the actual data input of the tax returns I would suggest that we approach learning tax law with three fundamental tools the first is going to be formulas in other words when we envision the tax return we're probably, we do not want to unless you have some strange skill that you can just visualize every line item on the tax return that's not typically what you want to do because the line items on the tax return often are more detailed than you really need to be to get a general idea of what is going on you're not going to memorize, well I add line one to line two and then I subtract line five from line four you're not going to memorize the lines what you're going to memorize is a general formula that you have in your head which will basically be a type of income statement because it's an income tax and then if you're answering questions that are just broadly people are asking that's the type of thing that you kind of want in your head if they're asking you a question you're like okay what's that going to impact is it going to impact income, is that going to impact a deduction what's that going to do to the bottom line and so on that's thinking usually in terms of a formula we will create formulas mainly in Excel so we can practice that and then you want to basically put that in your mind we can also use the formula to kind of double check our data input then we have the actual forms now the forms of course have the formula in it but the forms are going to be a lot more extended versions of the formula and put out in a much more formal way meaning it's going to say stuff like add box one and box three and blah blah blah but you're not really looking at it as like an elegant formula that you can understand you're just basically going through and adding the boxes so it's important to note the form to be able to visualize the form but it's probably not the thing that you're holding in your mind you were trying to answer some quick questions about possible scenarios that could happen under different circumstances and then we have the software so software there's a whole lot of different kinds of tax software but because the tax law has become so complex the software is vitally important so when you're discussing with people of course you can discuss and say well this is basically what I think is going to happen you know this is the gist of what will happen this scenario or that scenario but it's going to be the software when you actually plug it into the software that you would like to have to basically double check because the software similar to the double entry accounting system in accounting helps to give us a double check it's not perfect because it's still just a data input you don't have a double entry accounting system in the software but it helps you to have a double check that the software is doing some of the calculations and can give you diagnostics and stuff if stuff is off so for us these two are going to coincide with each other a bit because we're going to use the software to then create the forms but you can think about these things differently if you don't have access to any software and you want to just look at the forms you can look up the forms on the IRS website and you can follow along with just the forms we're going to create the forms with the software if you have access to software that is great it's a great tool to work with because then you can run scenarios really easily