So this one should be fairly straightforward, I guess. Which of the following substances exhibits hydrogen bonding? And for those that do, draw two molecules of the substances with hydrogen bonds between them, clearly indicating the acceptor and donated portions of that hydrogen bond. OK? Is everybody OK with that? So I guess the first thing I would like you guys probably to do with these is draw the Lewis structure so you can see whether they hydrogen bonded. But hopefully you guys can tell me, through just looking up there, whether they have the ability to hydrogen bond, right? So does the top one even have the ability to hydrogen bond? No. Why not? It doesn't have nitrogen, oxygen, or fluorine in it. So even though it's got these hydrogens in it, right, it can't hydrogen bond. But I think it's still beneficial to draw the Lewis structure. So let's draw the Lewis structure of this molecule here, ethane. So hopefully you guys all drew it like this. And by now I don't think I need to draw it from this institute. So hopefully you guys can see, especially now, definitely there's no hydrogen, oxygen, hydrogen, hydrogen, or hydrogen bond. Is everybody OK with that? So let's just kind of delete this from the system and just look at these two. So do these ones potentially have the ability to hydrogen bond? Yes. Yes, right? Already we can say yes, because we see that they have both hydrogen and oxygen in them or hydrogen and nitrogen in this. OK? So it looks like this one's pretty much already showing us the Lewis structure, right? Let's draw the Lewis structure of this one over here. So CH3OH methanol. So when it's written like this, it's kind of showing you which atoms are bonded to which atoms. So here we're saying that that carbon is bonded to those three hydrogens. Is everybody OK with that? And also that carbon is bonded to that oxygen. Let's draw that. This group here is called a methyl group. CH3 group is called a methyl group. In fact, this molecule is known as methanol. But we said that carbon is bonded to that oxygen there. And that oxygen, of course, is bonded to that hydrogen. Is there anything missing on this Lewis structure? The lone pairs, right? So lone pairs on oxygen, there's two. OK, remember, this is just the Lewis structure. So this doesn't tell us any structural information except for where the atoms are bonded to each other. But we see that there's this oxygen-hydrogen bond. Is everybody OK with that? So when we see that, we should realize automatically that this thing is going to be able to hydrogen bond. OK? And so it wants us to draw a hydrogen bond to another member of the same species. OK, so let's do that. So hopefully you guys have already done this. So again, this is just another way to draw methanol. It's kind of like on its side. And I'm going to draw. Remember, those intermolecular forces we draw is kind of dashed lines. So who didn't remember that? So this itself would be a hydrogen bond. And it wants us to label the hydrogen bond acceptors and donators. So in this hydrogen bond, if we have a hydrogen bond, there has to be an acceptor and a donator. So what portion is the acceptor of the hydrogen bond? The oxygen lone pair. So the oxygen lone pair is the acceptor. So in fact, this lone pair can make a hydrogen bond with another one. So we'll just say there's another one down here like that. And we'll just label this acceptor. For the hydrogen bond that we're directly showing here, this is the actual acceptor. This over here, of course, is the donor of the hydrogen bond. And of course, you've got these two more acceptors here. So if I asked you for the number of acceptors and the number of donors in this molecule, what would you say? So let's say, so hydrogen bond acceptors, how many are there in that one? Two in one molecule. That's all I'm looking for. How many are in one molecule? Two. Why? Because there's only two oxygen lone pairs where that oxygen, well, it doesn't have to be bonded to the hydrogen, but there's two oxygen lone pairs, one of those really electronegative bonds, so two. And how many donors do I have in one molecule? Just one, right? Why? Only one? Because there's only one hydrogen bonded to one of those electronegative bonds. So those electronegative atoms, they have those lone pairs, and they'll always be hydrogen bonded acceptors, no matter what they're bonded to. So in other words, when we look at this structure, hopefully you can see that there's a portion that has hydrogen bonded acceptors, but not donors. So let's draw this one out from this kind of condensed structure to its big Lewis structure. And again, this is just the Lewis structure. I gave away the lone pairs. So instead of drawing another one of these molecules and drawing a bunch of hydrogen bonds, why don't we just figure out how many donors and how many acceptors this molecule has? So who wants to tell me how many acceptors this thing has? Three, why? Three lone pairs on those particular electronegative atoms that would look, right? So the acceptors would be here, here, and here. And what about donors? How many hydrogen bond donors does this have? Two, right? Why didn't you say these ones? Well, I'm assuming that you're saying these two hydrogens, right? Why wouldn't these three be if they're not attached to one of those collections? So what if we noticed about this molecule, right? There's an atom that has acceptors, but not donors. This top oxygen up there, what we say is the carbonyl oxygen. This thing here is a carbonyl C double bond O, where it's singly bonded to 2O. You'll learn more about that in organic. Any questions on that one? What exactly is that? Well, it's one of those van der Waals forces, the binomial-agular forces. Yeah, so there's that partial positive. It's the difference of electronegativity. So those really electronegative atoms really want those electrons. And hydrogen likes to give them up.  You know about strong masses. Those are molecules that have a hydrogen atom attached to a really electronegative atom that can form a polyatomic ion that's more stable than the actual uncharged structure. So it would prefer to have that hydrogen missing than have it there. So that's what makes a strong acid, is that you have this what we call conjugate base that's actually more stable than the acid itself. The conjugate base being the polyatomic ion that's formed from the loss of the hydrogen atom. I'll show you right now.


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Friends, I would like to draw your attention to another form of land degradation, which if not prevented would be impossible to reverse. This is the manes of plastic waste. Apart from having adverse health implications, this is going to render land unproductive and unfit for agriculture. My government hatch announced that India will put an end to single-use plastic in the coming years. We are committed to development of environment-friendly substitutes and also an efficient plastic collection and disposal method. I believe the time has come for even the world to say goodbye to single-use plastic. Friends, human empowerment is closely linked to the state of the environment. We eat harnessing water resources or reducing usage of single-use plastic. The way ahead is behavioural change. It is only when all sections of society decide to achieve something, we can see the desired results. We may introduce any number of frameworks, but real change will be powered by teamwork on the ground. India saw this in the case of the Swachh Bharat mission. People from all walks of life took part and ensured sanitation coverage was up from 38% in 2014 to 99% today. I am seeing the same spirit when it comes to ensuring the end of single-use plastic. Youngsters in particular are most supportive and are taking the lead to bring positive change. Media is also playing a very valuable role.


Hi everyone, Joe for jaspyscasebreaks.com coming at you with 2020 upper deck Goodwin champions. This is random letter break number six from jaspyscasebreaks.com. A very big thank you to all of these folks for getting into the action. Number seven coming up right after this in a separate video. So we sold 14 spots. I think you know the drill by now only numbered cards, Lomron, Jordan, base, and obviously the inserts and hits will ship. All of these guys right here. I think everyone knows how we're doing these by now. If we pull at ASOP's fables, if you pull one of those booklets, it's going to go to the name of the artist. That's because that's what the names are on the checklist. I think if it's the lion, it'll go to L. I think that makes sense. LeBron, LR, too. Lots of stuff right here. All right. I think everyone knows this by now or on break six. Let's roll it. Let's randomize it. Three and a two. Do your names first. One, two, three, four, and five. After five times, I said five, right? Five times. Edwin down to Adam. And then three and a two. Five times for the letters, one, two, and fifth and final time. After five times, we got D down to C. All right. So Edwin with D, TJ, W, Matthew, I, F, E, plus all the other letters not on this list. Mike with A, Matthew with J, last spot mojo. Josh with P and L, James with B, Paul with R and N, Adam with B, Paul with S, Zach with T. We're pretty close to BTS right there and instead it's BST. Matthew with M. And then we've got Adam with C. I don't know why Matthew has three different last spot mojo stars on his name. I guess he got three spots in the last order. I think Sean does not know how to do last spot mojo, ladies and gentlemen. All right, let's sort of, yeah, three last spot mojo. What is he doing here? It's only for pick your teams. All right. Now, there's only two boxes right here. I'm going to switch away from that screen. I'll come back to it in just a second. There's two boxes right here left over from last night's break. We've got a fresh case right here. We're going to find four more boxes and then that'll be a six box break right there. So let's pop that open. It's kind of hard to see, but we've got, oh, now you can see it right there, L and R, left and right. So we'll roll the die, we'll select A die, we'll select that Vegas one right there. One, two, three for L, four, five, six for R, five for R, and there's R right there. Now let's pop this guy, can I just put it in my pocket? There it is. They used to be 12 box cases. They threw us off of this eight box thing. That's why we're happy to do this. All right. So now, these are the two we're going to do already. Once again, we'll go one, two, three for the left four and four, five, six for the right four. Three. So I'm going to do the left side right here. So that makes one, two, three, four, five, six, your six box break. And we'll save this for break seven. And then we'll have to dig up two more boxes from the other inner case. All right. We'll look back to this screen right here. We're going to pause the video. When we come back, we're going to see if there's any trades. I'm going to drop it. Find a checklist for you guys too. And then we'll have the break itself. Stick around. All right. Welcome back, folks. No trades, checklists in the chat. This is random letter break number six, six box number six. On the 23rd, thanks everyone for getting into the action, appreciate it. Three hits per box is kind of what we're looking for here. Good luck. Yeah. That was the big news of the day. Juan Soto, testing positive for COVID, has to have two negative tests in a row before he can, before he can get back. Could be this week, could be in two weeks. I don't know. We'll see. Yeah. It was surprising. It's kind of, I mean, at this point, you kind of think, well, how did he get it? You know, if they're getting regularly tested, if he is kind of just kind of pseudo quarantine with his team, I mean, he kind of has to, right? For the safety of his teammates, so is he doing something that he wasn't supposed to be doing? I don't know. So I'm sure the nationals are investigating that, trace that back. Oh, that's awesome. There's like condos right outside the stadium. It looks like, looks like people are watching from up there. That's pretty cool. Or is a hotel made? Oh, Hampton Inn and Suites. Wow. They got people on the roof watching. All right. I think I'm most of a mast up. There you go. Right. Exactly, Brad. How many other players did he come into contact with? Do any of them have it? Can they pass it on to the Yankees and biological warfare right there? This is part of the reason why, the main part of the main reason why this Goodwin Champion six box break takes so long is these packs. This is definitely what, what makes this, this 30 minute break turn into an hour long break. Half the time is trying to figure out these packs here. All right. So these are considered base cards. They, they won't go. Obviously the minis will ship unless these are Michael Jordan or LeBron James and those of this will ship. That's a parallel. I think everyone gets it. Nice Jason Dominguez mini. These will ship of course. I don't know how much are these Goodwin boxes? These must be maybe under a couple hundred bucks a box. I have no idea. $50 a box? Anyone know actually, you know what? I have cardboardconnection.com. They usually have the price. I think they snag the cheap up. $122. Yeah. A little over a hundred a box. There's Nick Lucena, a beach volleyball player. It'll go to N and it'll be for Paul. I think that cardboardconnection.com price is a little on the cheaper side but I think most hobby shops maybe a little bit more. I don't know what we're charging for it. Our first sea creature. Love these guys. The manatee. M. Matthew Shearer with the manatee. Yeah. Just cows of the sea, right? Just grazing on sea grass and even more top loaders folks but we'll make sure all those are sleeved up and top loaded before they go out. Our first autograph is Simone Manuel. Swimmer. I do have regular top loaders here. Yeah. These are kind of a quirky card. It's definitely a different look. Not the usual stuff that we see all the time so it's pretty quirky if you're into that and you're going to love this. Some people don't like it. Some people love it. I feel like there's really no in-betweens though. I love it. I think these are really goofy. I like the sea creatures. I like the different animal ones. I think they're doing cats this year. A little more of a diverse checklist, you know, because you've got like actors and soccer players and field hockey players in the mix. You know, you kind of see all these musicians, you kind of see all sorts of different things here. And yeah, some of the autos can be pretty valuable on the secondary market too. And the animals in here too. I need another container here, hang on a second. That's one in the books box two. Yeah, this is definitely a vehicle for Upper Decks exclusive autos. That's actually why it does pretty well. People love, it's good when it's been around for a little bit, people love building the sets of these as well. So a lot of set builders really love this product if there's still any set builders out there. Yep, and the cat and the sea creature subsets have like four, five different tier levels. And some of the really short printed ones, at least in the past, I've seen some of the really short printed ones go for a ton of money. I've seen some close to a thousand dollars, some old sets, and it might depend on the animal and everything, but yeah, some of them could go for a lot of money. I don't know how they're doing this here, but it's possible. They'll build the sets of these too. There was a year they did a pug set, which was the shortest, like a tier five pug. I think they still go for a couple hundred dollars even now, but a lot of times that's what drives the price up for some of those relics because people are trying to complete sets. Oh yeah, Corey, I am ready. I got my Dodgers hat right here. We had some media here today talking to us, so I had to did my hair. The hair and makeup girl was here, but I've got my Dodger hat right there. It's going to happen right after this game. I'm looking forward to it. Yankee's up 3-1 right now, folks. Real baseball happening. I have some financial interest in the Nationals winning this game as home dogs. The Maxers seem to be getting into a groove here. 55 pitches already for Maxers, or through four. I think they got three or four more innings left in them. Yeah, it feels really nice to have sports back, especially baseball. Perfect for me. The soccer season, the EPL season, Liverpool already clinched the Premier League title a while ago, but they clinched that, and there's only one more Premier League game left, and that's this Sunday, so that dovetails nicely in with the baseball season restarting. We've got basketball next Thursday or so, and we've got hockey in early August first, maybe. Shortly after that, we'll have some hockey as well, so from no sports, from no team sports in the United States, we're suddenly going to have a ton. Tiger. Go on to tee. Zack. And we've got a Nick Lucena Beach volleyball rally. Part of a shirt, maybe? Oh, yeah. I don't want to be a top loader here. We'll top load all these later. N, that'll go to Paul with letter N. And, whoa, look at this, space relics? Wow. The space shuttle Challenger S with that one. Paul with the letter S. This is part of the Challenger? Oh, right, that Fertinand. I was going to say, not that much, should we have a mission? That's crazy. That's pretty awesome from an early 80s mission, pre-disaster, of course, early 80s mission. Some of you, I'm not, but some of you may be old enough to remember that. That's crazy. Got to watch out for these minis that want to slide out and get weird. All right, four boxes to go, ladies and gentlemen. All right, so this is good when six, good when seven is going to happen right after that. And then we'll go through, like, 80 some odd orders and figure out what the rest of our evening is going to look like. I know there's already stuff sold out, folks, so we'll get to those. Let's see if I can figure out. I don't know what the order, the first fill, first to break. I don't know what the exact order is going to be. But I think that clearly authentic is going to happen. Top Sterling is going to happen. One of those prism hobby breaks to give away mixer spots will happen. That mixer could happen tonight, too. Obsidian Two Box will happen a little bit later tonight. We'll give away spots in the fallist collegiate break. Mosaic Pack 39 will eventually happen, and 38, maybe. We'll go through orders, we'll figure out what the numbering is on that. What else? Sterling 3 will happen. We already did Optic 5 and 6 Spectra will happen, and then once we kind of go through some orders and go through a lot of stuff, we'll see what else we can reload onto the site. Kind of a wild day today because of some media that was here doing a little story on Jaspies. I think we can focus right back on group breaks for a good chunk of the night. Which many? Adam Cofferman? Was there one that I missed? I was numbered. Oh, yeah. There it was. So that's Bianca Andrescu for letter B, Adam Cofferman. There you go. That's why he had the best interest in that letter. Adam, I only just learned yesterday that she beat Serena in last years in a U.S. Open. I think last year, and I was like, how in the world do we miss that? How did I miss that? I like tennis. And I think Brad was saying these sideways ones are a little more rare as well. And I was like, how did I miss it? I think that was the week we were maybe moving between the old shop and the new shop. And then remember we didn't have cable TV for like a week or two because direct TV hadn't come in yet. So I think we, why does this only have two cards in here? But yeah, so I think that was, that might have been the week or two. We didn't have TV here. And so I just kind of missed that tennis U.S. Open. So that's why I have no recollection of last year's tennis U.S. Open, which is something that I would watch every year. Well, I mean, there really is no bubble, right? He shouldn't. I mean, yeah, that's what I'm thinking too. He's someone who's not following the rules.  And he was asymptomatic too, so I, but he, I mean, I don't know, NBA, yeah, I mean, right, exactly. But the baseball is going to be difficult. Where though? Like we're going to have that many football fields, right, right. But yeah, but I mean, there's so many football rosters are even bigger than the baseball rosters. So what are you going to do? It's going to be crazy. You know what, Eric? We just saw, I just saw that news earlier today. Mike Tyson and who's, who's he fighting? Jones Jr. How old is he? It's kind of fun. A couple of old guys beating up on each other and we got Christian Coleman. Roy Jones Jr. Is in his mid 40s here. I'll show you again, Paul. That's pretty cool from an early 80s challenger mission where it produced the first spacewalk of the space shuttle program. Christian Coleman track and field goes to Adam Cupperman, letter C. And we got Colonel Nicole Malachowski of the United States Air Force. A genuine hero. That'll go to N. Paul, nice, nice, lumberjack card, Stephen Root goes to S. Ten Jennings, lumberjacks, that kind of has a wood sort of texture on the front of that. Which is pretty cool. Oh, you can win a home run ball. That's pretty cool. Where do I go?  It's a lot of fun. I got to look that up. I don't think there's going to be a good win eight. Good win seven looks like it's going to be our last one. And good win seven is coming up right after this. Axel, what's going on? How are you? Is Stephen Root in because of dodgeball or office space or all the other work he's done? Yeah, man, me too. It's just been home to work, work to home, Axel. Can't really do anything else. Oh, does he really? In this set, Brad? Brad's saying that he has specialty signatures in the set that say Stapler and Red Stapler. What a goofy set. I love this. This might be top, this is in the top five worst packs ever. Pack quality, top five worst, maybe top three worst. An autograph? Did I not notice the Stapler comment in his autograph? I don't remember that. I don't know. The worst might be another upper deck product actually, SP authentic maybe had pretty terrible packs. I think those are, I think those are worse than this. Yeah, Noir is up there too. I think that's the top four right there, maybe another product I'm not thinking of. Oh, Eric, you must have missed it. I think Oliver is saying that Roy Jones Jr. is in his mid 40s. I guess we'll have to watch that fight and see if Nick Jaspy can match up against Mike Tyson. Lumberjack card right here. When's that fight supposed to happen? That's Michael Jordan right there. And we've got Denny Avigia, D, Edwin, Dennis Morris is September. You think it's free? Or you think it's pay-per-view? I guess Cable really isn't free. There's Nick Lucena, another upper deck volleyball relic here, letter N. Edwin has letter D, letter N is for Paul. And Steven Root, autograph. No staple reference in this particular one. Now I wish there was one. I'm just talking about him. Letter S, Paul Chung. So just an exhibition fight? All right, so maybe it'll just be on cable. It'll be a lot of fun to watch. Next box, do we know what network's carrying it? Is ESPN going to carry it? All right, two boxes to go. Oh, Jones is 51. And it will be pay-per-view according to Adam Coverman. Damn. Are we buying this fight? Would our stream get canceled if, like, the audio of the fight in the background? Probably. Interesting. Interesting. All right. I'm sure we'll find a way to get it. That's so random. A couple filler cards in there. One ruined. Oh, you can't turn the, uh, breaking news. Oh, no, we already saw this. MLB posting to expand 16 teams this year. Two more teams, up from 14. David, Emmy, you're saying you don't think the Giants have a single pair that would start in the Dodgers right now? It might be. Mauricio DuBond, maybe. No, I don't think so. That's a tops thing. I don't think they're going to straight up copy. It's close enough. Another lumberjack card right here. Might be some lightning in Washington, DC. And we've got Manet Rayoum. She's going to go to letter M. That'll be for Matthew Shearer. Yeah, there's Ken Jennings autographs in here, too, Joey V. So that's a possibility for a K. And many will go to all other letters on the list. Matthew Shearer. Yeah, Danny Trejo's in this. The checklist is wild, folks. All veteran comments, Eric. We, uh, we end up selling and donating all the proceeds to charity. L.A.'s Best Boys and Girls Club, Children's Hospital L.A. Some of the organizations we support with those proceeds. Oh, what's coming up here? A cat. We've got a cat coming up, ladies and gentlemen. Cat alert. We've got a bangle cat. Adam with the letter B. I'm not sure if Adam's a cat guy or not, but there it is. With the coat of a wild cat, the bangle's popularity came from its beauty and distinct history.  Breeder, Gene Mill, was the original proponent of the breed, which he created by crossing the wild Asian leopard and domestic cat. Since then, the cat has become extremely popular for pet enthusiasts. There you go, knowledge. Knowledge. Ooh, heads of state. Edward VII. This is one of his official stamps right there. There he is. Yeah, he was, uh, 60 when he became king of England, king of the United Kingdom, and other common, January 22, 1901, upon the death of his mother, Queen Victoria, then the longest reigning monarch in the history of the British Isles. He was uncle to Russia's Tsar Nicholas II and German Emperor Wilhelm II, both key figures in the Great War, and they began four years after Edward's death. E for Edward. That will be for Matthew Shearer. All right, last box coming up. I don't know what the, I'll have to look at the checklist, Daniel. I don't know what the most rare cat is. Here, here's the checklist for everybody. Now I'm curious, we just look it up. Scroll down to cat. The rarest cat, so the bangle, the bangle cat, is tier one. The tier six cat, tiger, cheetah, and lion. Yeah, the Black Panther card from yesterday, right? Wakanda Forever, the Black Panther card from yesterday was a tier four, which is one out of every, I'm not sure what these designations are. They say one out of every H-E and then B. What are the differences there? Maybe blaster and hobby? Wow, Giancarlo Stan already has three RBI's on the day. Base is loaded, four one Yankees, top of the fifth. Giancarlo Stan looks a little slimmer, maybe takes a little weight off of his joints and muscles. About a lower body injuries for him. Right, Tony Gonson would love that cat set. No, no coins yet, right? We've seen a few stamps, no coins. Ah, John is saying H-E is hobby and electronic, there's electronic, and B is blaster, gotcha, gotcha, gotcha. Yeah, I was like, I couldn't tell what those odds were. I knew what the odds were, I didn't know what the letter designations were, but there you go. So, going back to the cat odds. So, in hobby boxes for us, Tiger Cheetah Lion, our tier six, the highest tier, one out of every 6,600 packs. And one out of every 33,000 packs if you're opening blasters. Wow, did you draw, Mike Howard, did you draw a MC Scat Cat reference? That's from the classic music video, Opposites Tracked, with Paula Abdul. One of the more revolutionary music videos of the time. Opening day is today, officially. Yankees Nationals, and then later on, it will be Giants At Dodgers. An Opposites Tracked video must have been possibly pre-Hoo Frame Roger Rabbit, which was another kind of important animation and live action sort of combo. I gotta do one more of these. I love the stuff inside the packs, though. The packs themselves are a nightmare. I'm gonna watch out for those minis. All of these LeBron James-based cards, of course, will ship. Sorry, mess with Ozil, letter M. And that's it, ladies and gentlemen, there is your break, a lot of fun minis, a lot of fun stuff. We've got a stamp, we got a cat, some autographs, some relics, space relics, that was pretty cool. Those 3D lenticular cards, that mini was numbered to eight. So a lot of fun stuff. We'll get all those top-loaded. I just ran out, didn't have top-loaders for this. A sea creature, I think I like the sea creature set. And there's Nick Lucena right there as well. And there you have it, boys and girls. Thanks for watching, thanks for breaking with us. We have Goodwin Champions number, this was number six, Goodwin Champions number seven is coming up right after this in a separate video. I'm Joe for jessbyscasebreaks.com. Talk to you later.