Tin is widely used in eletrolytic baths for which process that forms a metal coating?
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Tin(II) chloride Tin(II) chloride, also known as stannous chloride, is a white crystalline solid with the formula Sn Cl . It forms a stable dihydrate, but aqueous solutions tend to undergo hydrolysis, particularly if hot. SnCl is widely used as a reducing agent (in acid solution), and in electrolytic baths for tin-plating. Tin(II) chloride should not be confused with the other chloride of tin; tin(IV) chloride or stannic chloride (SnCl).
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Electroplating Electroplating is a process that uses electric current to reduce dissolved metal cations so that they form a thin coherent metal coating on an electrode. The term is also used for electrical oxidation of anions onto a solid substrate, as in the formation silver chloride on silver wire to make silver/silver-chloride electrodes. Electroplating is primarily used to change the surface properties of an object (such as abrasion and wear resistance, corrosion protection, lubricity, aesthetic qualities), but may also be used to build up thickness on undersized parts or to form objects by electroforming.
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Superforming Superforming is a hot metal forming process that uses similar principles to thermoforming plastics, where a sheet of material is heated and forced onto a male or female form using gas pressure. The process is useful for producing complex surfaces. The superforming process varies mostly in the way that the metal is introduced to the form; the main 4 variations are:
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Photolithography Photolithography, also termed optical lithography or UV lithography, is a process used in microfabrication to pattern parts of a thin film or the bulk of a substrate. It uses light to transfer a geometric pattern from a photomask to a light-sensitive chemical "photoresist", or simply "resist," on the substrate. A series of chemical treatments then either engraves the exposure pattern into, or enables deposition of a new material in the desired pattern upon the material underneath the photo resist. For example, in complex integrated circuits, a modern CMOS wafer will go through the photolithographic cycle up to 50 times.
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Mond process The Mond process, sometimes known as the carbonyl process, is a technique created by Ludwig Mond in 1890, to extract and purify nickel. The process was used commercially before the end of the 19th century. This process converts nickel oxides into pure nickel.
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Surface finishing Surface finishing is a broad range of industrial processes that alter the surface of a manufactured item to achieve a certain property. Finishing processes may be employed to: improve appearance, adhesion or wettability, solderability, corrosion resistance, tarnish resistance, chemical resistance, wear resistance, hardness, modify electrical conductivity, remove burrs and other surface flaws, and control the surface friction. In limited cases some of these techniques can be used to restore original dimensions to salvage or repair an item. An unfinished surface is often called "mill finish".
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Parts cleaning Parts cleaning is essential to many industrial processes, as a prelude to surface finishing or to protect sensitive components. Electroplating is particularly sensitive to part cleanliness, since molecular layers of oil can prevent adhesion of the coating. ASTM B322 is a standard guide for cleaning metals prior to electroplating. Cleaning processes include solvent cleaning, hot alkaline detergent cleaning, electrocleaning, and acid etch. The most common industrial test for cleanliness is the waterbreak test, in which the surface is thoroughly rinsed and held vertical. Hydrophobic contaminants such as oils cause the water to bead and break up, allowing the water to drain rapidly. Perfectly clean metal surfaces are hydrophilic and will retain an unbroken sheet of water that does not bead up or drain off. ASTM F22 describes a version of this test. This test does not detect hydrophilic contaminants, but the electroplating process can displace these easily since the solutions are water-based. Surfactants such as soap reduce the sensitivity of the test, so these must be thoroughly rinsed off.
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Ausforming Ausforming also known as Low and High temperature thermomechanical treatments is a method used to increase the hardness and toughness of an alloy by simultaneously tempering, rapid cooling, deforming and quenching to change its shape and refine the microstructure. This treatment is an important part in the processing of steel.
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Tarnish Tarnish is a thin layer of corrosion that forms over copper, brass, silver, aluminum, magnesium and other similar metals as their outermost layer undergoes a chemical reaction. Tarnish does not always result from the sole effects of oxygen in the air. For example, silver needs hydrogen sulfide to tarnish, although it may tarnish with oxygen over time. It often appears as a dull, gray or black film or coating over metal. Tarnish is a surface phenomenon that is self-limiting, unlike rust. Only the top few layers of the metal react, and the layer of tarnish seals and protects the underlying layers from reacting.
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Zincate In industry it can refer to the alkaline solutions used in a dipping (immersion) process to plate aluminium with zinc prior to electrolytic or electroless nickel plating. This immersion process is electroless (i.e. not electroplating) and involves the displacement of zinc from zincate by aluminum:
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Atomic layer epitaxy Atomic layer epitaxy (ALE), now more generally called Atomic Layer Deposition (ALD), is a specialized form of epitaxy that typically deposit alternating monolayers of two elements onto a substrate. The crystal lattice structure achieved is thin, uniform, and aligned with the structure of the substrate. The reactants are brought to the substrate as alternating pulses with "dead" times in between. ALE makes use of the fact that the incoming material is bound strongly until all sites available for chemisorption are occupied. The dead times are used to flush the excess material.
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Nickel electroplating Nickel electroplating is a technique of electroplating a thin layer of nickel onto a metal object. The nickel layer can be decorative, provide corrosion resistance, wear resistance, or used to build up worn or undersized parts for salvage purposes.
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Tintype A tintype, also known as a melainotype or ferrotype, is a photograph made by creating a direct positive on a thin sheet of metal coated with a dark lacquer or enamel and used as the support for the photographic emulsion. Tintypes enjoyed their widest use during the 1860s and 1870s, but lesser use of the medium persisted into the early 20th century and it has been revived as a novelty in the 21st.
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Vacuum deposition Vacuum deposition is a family of processes used to deposit layers of material atom-by-atom or molecule-by-molecule on a solid surface. These processes operate at pressures well below atmospheric pressure (i.e., vacuum). The deposited layers can range from a thickness of one atom up to millimeters, forming freestanding structures. Multiple layers of different materials can be used, for example to form optical coatings. The process can be qualified based on the vapor source; physical vapor deposition uses a liquid or solid source and chemical vapor deposition uses a chemical vapor.
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Type metal In printing, type metal (sometimes called hot metal) refers to the metal alloys used in traditional typefounding and hot metal typesetting. Lead is the main constituent of these alloys. Antimony and tin are added to make the character produced durable and tough while reducing the difference between the coefficients of expansion of the matrix and the alloy.
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Dip moulding In plastics processing, dip molding is a process of shaping of plastics by moulding. The coating of components with PVC has many applications. Plastic dip moulding is a technique where metal parts are coated with a plastic vinyl material. It is used to protect and make the metal parts more resistant to scratches and abrasions.
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Corona treatment Corona treatment (sometimes referred to as air plasma) is a surface modification technique that uses a low temperature corona discharge plasma to impart changes in the properties of a surface. The corona plasma is generated by the application of high voltage to an electrode that has a sharp tip. The plasma forms at the tip. A linear array of electrodes is often used to create a curtain of corona plasma. Materials such as plastics, cloth, or paper may be passed through the corona plasma curtain in order to change the surface energy of the material. All materials have an inherent surface energy. Surface treatment systems are available for virtually any surface format including dimensional objects, sheets and roll goods that are handled in a web format. Corona treatment is a widely used surface treatment method in the plastic film, extrusion, and converting industries.
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Electron-beam processing Electron-beam processing or electron irradiation is a process that involves using beta radiation, usually of high energy, to treat an object for a variety of purposes. This may take place under elevated temperatures and nitrogen atmosphere. Possible uses for electron irradiation include sterilization and cross-linking of polymers.
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Differential heat treatment Differential heat treatment (also called selective heat treatment or local heat treatment) is a technique used during heat treating to harden or soften certain areas of a steel object, creating a difference in hardness between these areas. There are many techniques for creating a difference in properties, but most can be defined as either "differential hardening" or "differential tempering". These were common heat treating techniques used historically in Europe and Asia, with possibly the most widely known example being from Japanese swordsmithing. Some modern varieties were developed in the twentieth century as metallurgical knowledge and technology rapidly increased.
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Parkerizing Parkerizing, bonderizing, phosphating, or phosphatizing is a method of protecting a steel surface from corrosion and increasing its resistance to wear through the application of a chemical phosphate conversion coating. Parkerizing is usually considered to be an improved zinc or manganese phosphating process, and not to be an improved iron phosphating process, although some use the term "parkerizing" as a generic term for applying phosphating (or phosphatizing) coatings that does include the iron phosphating process.
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Electrochemical fluorination Electrochemical fluorination (ECF), or electrofluorination, is a foundational organofluorine chemistry method for the preparation of fluorocarbon-based organofluorine compounds. The general approach represents an application of electrosynthesis. The fluorinated chemical compounds produced by ECF are useful because of their distinctive solvation properties and the relative inertness of carbon–fluorine bonds. Two ECF synthesis routes are commercialized and commonly applied: the Simons process and the Phillips Petroleum process. It is also possible to electrofluorinate in various organic media. Prior to the development of these methods, fluorination with fluorine, a dangerous oxidant, was a dangerous and wasteful process. Also, ECF can be cost-effective but it may also result in low yields.
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Thermal spraying Thermal spraying techniques are coating processes in which melted (or heated) materials are sprayed onto a surface. The "feedstock" (coating precursor) is heated by electrical (plasma or arc) or chemical means (combustion flame).