When did Rudolf Clausius introduce the second law of thermodynamics?
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Theory of heat In the history of science, the theory of heat or mechanical theory of heat was a theory, introduced in 1798 by Sir Benjamin Thompson (better known as 'Count Rumford'), and developed more thoroughly in 1824 by the French physicist Sadi Carnot, that heat and mechanical work are equivalent. It is related to the mechanical equivalent of heat. Over the next century, with the introduction of the second law of thermodynamics in 1850 by Rudolf Clausius, this theory evolved into the science of thermodynamics. In 1851, in his "On the Dynamical Theory of Heat", William Thomson outlined the view, as based on recent experiments by those such as James Joule, that “heat is not a substance, but a dynamical form of mechanical effect, we perceive that there must be an equivalence between mechanical work and heat, as between cause and effect.”
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Rudolf Clausius Rudolf Julius Emanuel Clausius (2 January 1822 – 24 August 1888) was a German physicist and mathematician and is considered one of the central founders of the science of thermodynamics. By his restatement of Sadi Carnot's principle known as the Carnot cycle, he gave the theory of heat a truer and sounder basis. His most important paper, "On the Moving Force of Heat", published in 1850, first stated the basic ideas of the second law of thermodynamics. In 1865 he introduced the concept of entropy. In 1870 he introduced the virial theorem which applied to heat.
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Theodor Grotthuss Freiherr Christian Johann Dietrich Theodor von Grotthuss (January 20, 1785 – March 26, 1822) was a German chemist known for establishing the first theory of electrolysis in 1806 and formulating the first law of photochemistry in 1817. His theory of electrolysis is considered the first description of the so-called Grotthuss mechanism.
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Johannes Rydberg Johannes (Janne) Robert Rydberg (8 November 1854 – 28 December 1919) was a Swedish physicist mainly known for devising the Rydberg formula, in 1888, which is used to predict the wavelengths of photons (of light and other electromagnetic radiation) emitted by changes in the energy level of an electron in a hydrogen atom.
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Ideal gas law The ideal gas law, also called the general gas equation, is the equation of state of a hypothetical ideal gas. It is a good approximation of the behavior of many gases under many conditions, although it has several limitations. It was first stated by Émile Clapeyron in 1834 as a combination of the empirical Boyle's law, Charles's law and Avogadro's Law. The ideal gas law is often written as
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First law of thermodynamics The first law of thermodynamics is a version of the law of conservation of energy, adapted for thermodynamic systems. The law of conservation of energy states that the total energy of an isolated system is constant; energy can be transformed from one form to another, but can be neither created nor destroyed. The first law is often formulated
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Eigenstate thermalization hypothesis The Eigenstate Thermalization Hypothesis (or ETH) is a set of ideas which purports to explain when and why an isolated quantum mechanical system can be accurately described using equilibrium statistical mechanics. In particular, it is devoted to understanding how systems which are initially prepared in far-from-equilibrium states can evolve in time to a state which appears to be in thermal equilibrium. The phrase "eigenstate thermalization" was first coined by Mark Srednicki in 1994, after similar ideas had been introduced by Josh Deutsch in 1991. The principal philosophy underlying the eigenstate thermalization hypothesis is that instead of explaining the ergodicity of a thermodynamic system through the mechanism of dynamical chaos, as is done in classical mechanics, one should instead examine the properties of matrix elements of observable quantities in individual energy eigenstates of the system.
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Noosphere The noosphere ( ; sometimes noösphere) is the sphere of human thought. The word derives from the Greek νοῦς (nous "mind") and σφαῖρα (sphaira "sphere"), in lexical analogy to "atmosphere" and "biosphere". It was introduced by Pierre Teilhard de Chardin in 1922 in his "Cosmogenesis". Another possibility is the first use of the term by Édouard Le Roy (1870–1954), who together with Teilhard was listening to lectures of Vladimir Ivanovich Vernadsky at the Sorbonne. In 1936, Vernadsky accepted the idea of the noosphere in a letter to Boris Leonidovich Lichkov (though he states that the concept derives from Le Roy). Citing the work of Teilhard's biographer—Rene Cuenot—Sampson and Pitt stated that although the concept was jointly developed by all three men (Vernadsky, LeRoy, and Teilhard), Teilhard believed that he actually invented the word: "I believe, so far as one can ever tell, that the word 'noosphere' was my invention: but it was he [Le Roy] who launched it."
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Exergy In thermodynamics, the exergy (in older usage, available work and/or availability) of a system is the maximum useful work possible during a process that brings the system into equilibrium with a heat reservoir. When the surroundings are the reservoir, exergy is the potential of a system to cause a change as it achieves equilibrium with its environment. Exergy is the energy that is available to be used. After the system and surroundings reach equilibrium, the exergy is zero. Determining exergy was also the first goal of thermodynamics. The term "exergy" was coined in 1956 by Zoran Rant (1904–1972) by using the Greek "ex" and "ergon" meaning "from work" , but the concept was developed by J. Willard Gibbs in 1873.
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Eugenius Warming Johannes Eugenius Bülow Warming (3 November 1841 – 2 April 1924), known as Eugen Warming, was a Danish botanist and a main founding figure of the scientific discipline of ecology. Warming wrote the first textbook (1895) on plant ecology, taught the first university course in ecology and gave the concept its meaning and content.
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Maxwell relations Maxwell's relations are a set of equations in thermodynamics which are derivable from the symmetry of second derivatives and from the definitions of the thermodynamic potentials. These relations are named for the nineteenth-century physicist James Clerk Maxwell.
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Friedrich Bergius Friedrich Karl Rudolf Bergius (11 October 1884 – 30 March 1949) was a German chemist known for the Bergius process for producing synthetic fuel from coal, Nobel Prize in Chemistry (1931, together with Carl Bosch) in recognition of contributions to the invention and development of chemical high-pressure methods. Having worked with IG Farben during World War II, his citizenship came into question following the war, causing him to ultimately flee to Argentina, where he acted as adviser to the Ministry of Industry.
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Gibbs paradox In statistical mechanics, a semi-classical derivation of the entropy that does not take into account the indistinguishability of particles, yields an expression for the entropy which is not extensive (is not proportional to the amount of substance in question). This leads to a paradox known as the Gibbs paradox, after Josiah Willard Gibbs. The paradox allows for the entropy of closed systems to decrease, violating the second law of thermodynamics. A related paradox is the "mixing paradox". If one takes the perspective that the definition of entropy must be changed so as to ignore particle permutation, the paradox is averted.
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Rankine scale The Rankine scale ( ) is an absolute scale of thermodynamic temperature named after the Glasgow University engineer and physicist William John Macquorn Rankine, who proposed it in 1859. (The Kelvin scale was first proposed in 1848.) It may be used in engineering systems where heat computations are done using degrees Fahrenheit.
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Calorimeter constant A calorimeter constant (denoted "C") is a constant that quantifies the heat capacity of a calorimeter. It may be calculated by applying a known amount of heat to the calorimeter and measuring the calorimeter's corresponding change in temperature. In SI units, the calorimeter constant is then calculated by dividing the change in enthalpy (Δ"H") in joules by the change in temperature (Δ"T") in kelvins or degrees Celsius:
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Newton's law of universal gravitation Newton's law of universal gravitation states that a particle attracts every other particle in the universe using a force that is directly proportional to the product of their masses and inversely proportional to the square of the distance between their centers. This is a general physical law derived from empirical observations by what Isaac Newton called inductive reasoning. It is a part of classical mechanics and was formulated in Newton's work "Philosophiæ Naturalis Principia Mathematica" ("the "Principia""), first published on 5 July 1687. (When Newton's book was presented in 1686 to the Royal Society, Robert Hooke made a claim that Newton had obtained the inverse square law from him; see the History section below.)
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Sergei Podolinsky Sergei Andreević Podolinsky (Ukrainian: Сергі́й Подоли́нський , Russian: Сергей Андреевич Подолинский ) (19 July 1850-1891) was a pioneer of ecological economics. He set out to reconcile socialist thought and the Second law of thermodynamics by synthesising the approaches of Karl Marx, Charles Darwin and Sadi Carnot.
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Thomas Johann Seebeck Thomas Johann Seebeck (] ; 9 April 1770 – 10 December 1831) was a Baltic German physicist who in 1821 discovered the thermoelectric effect.
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Gustav Zeuner Gustav Anton Zeuner (30 November 1828 – 17 October 1907) was a German physicist, engineer and epistemologist, considered the founder of technical thermodynamics and of the Dresden School of Thermodynamics.
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Amedeo Avogadro Lorenzo Romano Amedeo Carlo Avogadro, ( ) Count of Quaregna and Cerreto (9 August 17779 July 1856), was an Italian scientist, most noted for his contribution to molecular theory now known as Avogadro's law, which states that equal volumes of gases under the same conditions of temperature and pressure will contain equal numbers of molecules. In tribute to him, the number of elementary entities (atoms, molecules, ions or other particles) in 1 mole of a substance, , is known as the Avogadro constant, one of the seven SI base units and represented by "N".
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Rudolf Hoppe Rudolf Hoppe (29 October 1922 – 24 November 2014), a German chemist, discovered the first covalent noble gas compounds.
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History of magnetic resonance imaging The history of magnetic resonance imaging includes many researchers who have described its underlying physics, but it is regarded to be invented by Paul C. Lauterbur in September 1971; he published the theory behind it in March 1973. The factors leading to image contrast (differences in tissue relaxation time values) had been described nearly 20 years earlier by Erik Odeblad (physician and scientist) and Gunnar Lindström.